# Supplementary Information (SI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_230914f_0m
_database_code_depnum_ccdc_archive 'CCDC 2296122'
loop_
_audit_author_name
_audit_author_address
HQ
;WUT
China
;
_audit_update_record             
;
2023-09-20 deposited with the CCDC.	2025-03-05 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C32 H26 N2 O4'
_chemical_formula_weight         502.55

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 21'
_space_group_name_Hall           'P 2yb'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   8.6168(6)
_cell_length_b                   15.7680(12)
_cell_length_c                   9.6852(7)
_cell_angle_alpha                90
_cell_angle_beta                 103.245(3)
_cell_angle_gamma                90
_cell_volume                     1280.92(16)
_cell_formula_units_Z            2
_cell_measurement_temperature    200(2)
_cell_measurement_reflns_used    9889
_cell_measurement_theta_min      4.88
_cell_measurement_theta_max      72.26

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.303
_exptl_crystal_F_000             528
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.200
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.100
_exptl_absorpt_coefficient_mu    0.443
_shelx_estimated_absorpt_T_min   0.917
_shelx_estimated_absorpt_T_max   0.957
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.6121
_exptl_absorpt_correction_T_max  0.7536
_exptl_absorpt_process_details   
; 
 SADABS 2016/2: Krause, L., Herbst-Irmer, R., Sheldrick G.M. & Stalke D., 
 J. Appl. Cryst. 48 (2015) 3-10 
;
_exptl_absorpt_special_details   ?
_diffrn_ambient_temperature      200(2)
_diffrn_radiation_wavelength     1.34139
_diffrn_radiation_type           GaK\a
_diffrn_source                   ?
_diffrn_measurement_device_type  'Bruker PHOTON III'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_reflns_number            29868
_diffrn_reflns_av_unetI/netI     0.0520
_diffrn_reflns_av_R_equivalents  0.0560
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         4.080
_diffrn_reflns_theta_max         72.345
_diffrn_reflns_theta_full        53.594
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_point_group_measured_fraction_full 0.995
_reflns_number_total             7579
_reflns_number_gt                6544
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.908
_reflns_Friedel_fraction_max     0.967
_reflns_Friedel_fraction_full    0.995

_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;

_computing_data_collection       'Bruker APEX3'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0556P)²] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_extinction_coef       0.009(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_abs_structure_details 
; 
 Flack x determined using 2735 quotients [(I+)-(I-)]/[(I+)+(I-)] 
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259). 
;
_refine_ls_abs_structure_Flack   0.01(12)
_chemical_absolute_configuration ad
_refine_ls_number_reflns         7579
_refine_ls_number_parameters     344
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0467
_refine_ls_R_factor_gt           0.0386
_refine_ls_wR_factor_ref         0.1008
_refine_ls_wR_factor_gt          0.0962
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.60223(19) 0.48298(10) 0.31842(16) 0.0242(3) Uani 1 1 d . . . . .
H1 H 0.554536 0.518540 0.233840 0.029 Uiso 1 1 calc R U . . .
C2 C 0.78134(19) 0.47509(11) 0.33285(16) 0.0250(3) Uani 1 1 d . . . . .
C3 C 0.8206(2) 0.39263(11) 0.35765(17) 0.0271(3) Uani 1 1 d . . . . .
C4 C 0.9702(2) 0.34349(12) 0.38397(18) 0.0304(3) Uani 1 1 d . . . . .
C5 C 0.9677(3) 0.26280(14) 0.3245(2) 0.0439(5) Uani 1 1 d . . . . .
H5 H 0.870668 0.240371 0.269695 0.053 Uiso 1 1 calc R U . . .
C6 C 1.1060(3) 0.21538(17) 0.3451(3) 0.0548(6) Uani 1 1 d . . . . .
H6 H 1.103416 0.160450 0.304382 0.066 Uiso 1 1 calc R U . . .
C7 C 1.2484(3) 0.24729(18) 0.4248(3) 0.0529(6) Uani 1 1 d . . . . .
H7 H 1.343230 0.214515 0.438181 0.064 Uiso 1 1 calc R U . . .
C8 C 1.2519(2) 0.32682(16) 0.4845(2) 0.0452(5) Uani 1 1 d . . . . .
H8 H 1.349628 0.348677 0.539014 0.054 Uiso 1 1 calc R U . . .
C9 C 1.1136(2) 0.37558(14) 0.4658(2) 0.0351(4) Uani 1 1 d . . . . .
H9 H 1.116549 0.430062 0.508251 0.042 Uiso 1 1 calc R U . . .
C10 C 0.55973(19) 0.51990(11) 0.44980(16) 0.0248(3) Uani 1 1 d . . . . .
C11 C 0.4225(2) 0.56823(13) 0.43649(19) 0.0340(4) Uani 1 1 d . . . . .
H11 H 0.355631 0.577488 0.345123 0.041 Uiso 1 1 calc R U . . .
C12 C 0.3814(2) 0.60325(15) 0.5548(2) 0.0392(4) Uani 1 1 d . . . . .
H12 H 0.287494 0.636561 0.544104 0.047 Uiso 1 1 calc R U . . .
C13 C 0.4778(2) 0.58949(14) 0.6888(2) 0.0378(4) Uani 1 1 d . . . . .
H13 H 0.450288 0.613483 0.769926 0.045 Uiso 1 1 calc R U . . .
C14 C 0.6140(3) 0.54068(15) 0.70358(19) 0.0401(4) Uani 1 1 d . . . . .
H14 H 0.679395 0.530610 0.795313 0.048 Uiso 1 1 calc R U . . .
C15 C 0.6557(2) 0.50637(13) 0.58516(18) 0.0339(4) Uani 1 1 d . . . . .
H15 H 0.750109 0.473463 0.596228 0.041 Uiso 1 1 calc R U . . .
C16 C 0.89050(19) 0.54766(11) 0.34274(17) 0.0268(3) Uani 1 1 d . . . . .
C17 C 0.7416(2) 0.61060(12) 0.11297(17) 0.0304(3) Uani 1 1 d . . . . .
C18 C 0.7923(2) 0.74977(13) 0.1731(2) 0.0367(4) Uani 1 1 d . . . . .
H18A H 0.714210 0.770807 0.225748 0.044 Uiso 1 1 calc R U . . .
H18B H 0.838623 0.798746 0.132736 0.044 Uiso 1 1 calc R U . . .
C19 C 0.9224(2) 0.69737(11) 0.26942(17) 0.0275(3) Uani 1 1 d . . . . .
H19 H 0.935858 0.715098 0.370605 0.033 Uiso 1 1 calc R U . . .
C20 C 1.0788(2) 0.70442(11) 0.22439(17) 0.0272(3) Uani 1 1 d . . . . .
C21 C 1.1840(2) 0.76878(14) 0.2846(2) 0.0409(4) Uani 1 1 d . . . . .
H21 H 1.162481 0.801764 0.360207 0.049 Uiso 1 1 calc R U . . .
C22 C 1.3197(3) 0.78483(17) 0.2348(3) 0.0515(6) Uani 1 1 d . . . . .
H22 H 1.390302 0.829037 0.275632 0.062 Uiso 1 1 calc R U . . .
C23 C 1.3521(3) 0.73668(17) 0.1260(3) 0.0488(5) Uani 1 1 d . . . . .
H23 H 1.444229 0.748306 0.090966 0.059 Uiso 1 1 calc R U . . .
C24 C 1.2517(3) 0.67203(16) 0.0684(2) 0.0462(5) Uani 1 1 d . . . . .
H24 H 1.275790 0.638116 -0.004976 0.055 Uiso 1 1 calc R U . . .
C25 C 1.1141(2) 0.65575(13) 0.1171(2) 0.0373(4) Uani 1 1 d . . . . .
H25 H 1.044641 0.611070 0.076265 0.045 Uiso 1 1 calc R U . . .
C26 C 0.5068(2) 0.37140(12) 0.14120(18) 0.0318(4) Uani 1 1 d . . . . .
H26A H 0.502155 0.308908 0.131252 0.038 Uiso 1 1 calc R U . . .
H26B H 0.592766 0.392307 0.097501 0.038 Uiso 1 1 calc R U . . .
C27 C 0.3494(2) 0.40893(11) 0.06319(18) 0.0303(4) Uani 1 1 d . . . . .
C28 C 0.2116(2) 0.39770(14) 0.1128(2) 0.0393(4) Uani 1 1 d . . . . .
H28 H 0.217517 0.371078 0.201849 0.047 Uiso 1 1 calc R U . . .
C29 C 0.0651(3) 0.42526(17) 0.0326(2) 0.0472(5) Uani 1 1 d . . . . .
H29 H -0.028549 0.417411 0.067177 0.057 Uiso 1 1 calc R U . . .
C30 C 0.0552(3) 0.46412(16) -0.0975(2) 0.0477(5) Uani 1 1 d . . . . .
H30 H -0.045243 0.481642 -0.153213 0.057 Uiso 1 1 calc R U . . .
C31 C 0.1919(3) 0.47719(14) -0.1457(2) 0.0455(5) Uani 1 1 d . . . . .
H31 H 0.185753 0.504934 -0.233876 0.055 Uiso 1 1 calc R U . . .
C32 C 0.3392(3) 0.44995(13) -0.0658(2) 0.0370(4) Uani 1 1 d . . . . .
H32 H 0.432910 0.459413 -0.099595 0.044 Uiso 1 1 calc R U . . .
N1 N 0.54523(17) 0.39375(9) 0.29364(15) 0.0276(3) Uani 1 1 d . . . . .
N2 N 0.84614(17) 0.61365(9) 0.24574(14) 0.0274(3) Uani 1 1 d . . . . .
O1 O 0.68872(14) 0.34213(8) 0.35129(13) 0.0310(3) Uani 1 1 d . . . . .
O2 O 1.00955(16) 0.55716(9) 0.43671(15) 0.0421(3) Uani 1 1 d . . . . .
O3 O 0.68209(19) 0.54941(11) 0.04855(13) 0.0440(4) Uani 1 1 d . . . . .
O4 O 0.71774(16) 0.69047(10) 0.06203(14) 0.0377(3) Uani 1 1 d . . . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.491(2) . ?
C1 C10 1.518(2) . ?
C1 C2 1.523(2) . ?
C1 H1 1.0000 . ?
C2 C3 1.351(2) . ?
C2 C16 1.470(2) . ?
C3 O1 1.377(2) . ?
C3 C4 1.475(2) . ?
C4 C5 1.395(3) . ?
C4 C9 1.401(3) . ?
C5 C6 1.382(3) . ?
C5 H5 0.9500 . ?
C6 C7 1.386(4) . ?
C6 H6 0.9500 . ?
C7 C8 1.378(4) . ?
C7 H7 0.9500 . ?
C8 C9 1.395(3) . ?
C8 H8 0.9500 . ?
C9 H9 0.9500 . ?
C10 C11 1.388(2) . ?
C10 C15 1.397(2) . ?
C11 C12 1.389(3) . ?
C11 H11 0.9500 . ?
C12 C13 1.388(3) . ?
C12 H12 0.9500 . ?
C13 C14 1.384(3) . ?
C13 H13 0.9500 . ?
C14 C15 1.388(3) . ?
C14 H14 0.9500 . ?
C15 H15 0.9500 . ?
C16 O2 1.2146(19) . ?
C16 N2 1.395(2) . ?
C17 O3 1.199(2) . ?
C17 O4 1.351(2) . ?
C17 N2 1.391(2) . ?
C18 O4 1.459(2) . ?
C18 C19 1.526(2) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 N2 1.469(2) . ?
C19 C20 1.512(2) . ?
C19 H19 1.0000 . ?
C20 C25 1.381(3) . ?
C20 C21 1.396(3) . ?
C21 C22 1.387(3) . ?
C21 H21 0.9500 . ?
C22 C23 1.378(4) . ?
C22 H22 0.9500 . ?
C23 C24 1.370(4) . ?
C23 H23 0.9500 . ?
C24 C25 1.396(3) . ?
C24 H24 0.9500 . ?
C25 H25 0.9500 . ?
C26 N1 1.480(2) . ?
C26 C27 1.514(2) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C28 1.391(3) . ?
C27 C32 1.392(3) . ?
C28 C29 1.392(3) . ?
C28 H28 0.9500 . ?
C29 C30 1.386(3) . ?
C29 H29 0.9500 . ?
C30 C31 1.378(4) . ?
C30 H30 0.9500 . ?
C31 C32 1.394(3) . ?
C31 H31 0.9500 . ?
C32 H32 0.9500 . ?
N1 O1 1.4787(18) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C10 111.27(13) . . ?
N1 C1 C2 103.13(13) . . ?
C10 C1 C2 112.86(13) . . ?
N1 C1 H1 109.8 . . ?
C10 C1 H1 109.8 . . ?
C2 C1 H1 109.8 . . ?
C3 C2 C16 127.38(15) . . ?
C3 C2 C1 107.58(14) . . ?
C16 C2 C1 124.21(15) . . ?
C2 C3 O1 112.23(14) . . ?
C2 C3 C4 135.17(16) . . ?
O1 C3 C4 112.54(14) . . ?
C5 C4 C9 119.43(18) . . ?
C5 C4 C3 118.53(17) . . ?
C9 C4 C3 122.04(17) . . ?
C6 C5 C4 120.2(2) . . ?
C6 C5 H5 119.9 . . ?
C4 C5 H5 119.9 . . ?
C5 C6 C7 120.6(2) . . ?
C5 C6 H6 119.7 . . ?
C7 C6 H6 119.7 . . ?
C8 C7 C6 119.7(2) . . ?
C8 C7 H7 120.2 . . ?
C6 C7 H7 120.2 . . ?
C7 C8 C9 120.7(2) . . ?
C7 C8 H8 119.6 . . ?
C9 C8 H8 119.6 . . ?
C8 C9 C4 119.4(2) . . ?
C8 C9 H9 120.3 . . ?
C4 C9 H9 120.3 . . ?
C11 C10 C15 118.66(16) . . ?
C11 C10 C1 119.78(14) . . ?
C15 C10 C1 121.56(15) . . ?
C10 C11 C12 120.96(16) . . ?
C10 C11 H11 119.5 . . ?
C12 C11 H11 119.5 . . ?
C13 C12 C11 119.86(18) . . ?
C13 C12 H12 120.1 . . ?
C11 C12 H12 120.1 . . ?
C14 C13 C12 119.74(18) . . ?
C14 C13 H13 120.1 . . ?
C12 C13 H13 120.1 . . ?
C13 C14 C15 120.35(17) . . ?
C13 C14 H14 119.8 . . ?
C15 C14 H14 119.8 . . ?
C14 C15 C10 120.43(17) . . ?
C14 C15 H15 119.8 . . ?
C10 C15 H15 119.8 . . ?
O2 C16 N2 117.81(15) . . ?
O2 C16 C2 124.24(16) . . ?
N2 C16 C2 117.65(13) . . ?
O3 C17 O4 123.29(15) . . ?
O3 C17 N2 128.18(17) . . ?
O4 C17 N2 108.51(15) . . ?
O4 C18 C19 103.98(15) . . ?
O4 C18 H18A 111.0 . . ?
C19 C18 H18A 111.0 . . ?
O4 C18 H18B 111.0 . . ?
C19 C18 H18B 111.0 . . ?
H18A C18 H18B 109.0 . . ?
N2 C19 C20 114.67(14) . . ?
N2 C19 C18 98.71(13) . . ?
C20 C19 C18 111.23(14) . . ?
N2 C19 H19 110.6 . . ?
C20 C19 H19 110.6 . . ?
C18 C19 H19 110.6 . . ?
C25 C20 C21 118.98(18) . . ?
C25 C20 C19 122.74(15) . . ?
C21 C20 C19 117.96(17) . . ?
C22 C21 C20 120.4(2) . . ?
C22 C21 H21 119.8 . . ?
C20 C21 H21 119.8 . . ?
C23 C22 C21 120.0(2) . . ?
C23 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
C24 C23 C22 120.1(2) . . ?
C24 C23 H23 120.0 . . ?
C22 C23 H23 120.0 . . ?
C23 C24 C25 120.4(2) . . ?
C23 C24 H24 119.8 . . ?
C25 C24 H24 119.8 . . ?
C20 C25 C24 120.16(19) . . ?
C20 C25 H25 119.9 . . ?
C24 C25 H25 119.9 . . ?
N1 C26 C27 112.02(15) . . ?
N1 C26 H26A 109.2 . . ?
C27 C26 H26A 109.2 . . ?
N1 C26 H26B 109.2 . . ?
C27 C26 H26B 109.2 . . ?
H26A C26 H26B 107.9 . . ?
C28 C27 C32 119.07(17) . . ?
C28 C27 C26 121.07(17) . . ?
C32 C27 C26 119.68(18) . . ?
C27 C28 C29 120.31(19) . . ?
C27 C28 H28 119.8 . . ?
C29 C28 H28 119.8 . . ?
C30 C29 C28 120.3(2) . . ?
C30 C29 H29 119.9 . . ?
C28 C29 H29 119.9 . . ?
C31 C30 C29 119.64(19) . . ?
C31 C30 H30 120.2 . . ?
C29 C30 H30 120.2 . . ?
C30 C31 C32 120.4(2) . . ?
C30 C31 H31 119.8 . . ?
C32 C31 H31 119.8 . . ?
C27 C32 C31 120.3(2) . . ?
C27 C32 H32 119.9 . . ?
C31 C32 H32 119.9 . . ?
O1 N1 C26 102.84(13) . . ?
O1 N1 C1 104.03(11) . . ?
C26 N1 C1 112.05(13) . . ?
C17 N2 C16 128.02(14) . . ?
C17 N2 C19 110.30(13) . . ?
C16 N2 C19 121.42(13) . . ?
C3 O1 N1 107.97(12) . . ?
C17 O4 C18 108.88(13) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 -16.93(16) . . . . ?
C10 C1 C2 C3 103.24(16) . . . . ?
N1 C1 C2 C16 172.84(14) . . . . ?
C10 C1 C2 C16 -67.0(2) . . . . ?
C16 C2 C3 O1 174.44(15) . . . . ?
C1 C2 C3 O1 4.60(18) . . . . ?
C16 C2 C3 C4 -8.7(3) . . . . ?
C1 C2 C3 C4 -178.51(18) . . . . ?
C2 C3 C4 C5 -141.7(2) . . . . ?
O1 C3 C4 C5 35.1(2) . . . . ?
C2 C3 C4 C9 38.0(3) . . . . ?
O1 C3 C4 C9 -145.14(16) . . . . ?
C9 C4 C5 C6 -0.7(3) . . . . ?
C3 C4 C5 C6 179.1(2) . . . . ?
C4 C5 C6 C7 0.0(4) . . . . ?
C5 C6 C7 C8 0.3(4) . . . . ?
C6 C7 C8 C9 0.1(3) . . . . ?
C7 C8 C9 C4 -0.8(3) . . . . ?
C5 C4 C9 C8 1.1(3) . . . . ?
C3 C4 C9 C8 -178.66(17) . . . . ?
N1 C1 C10 C11 -95.72(18) . . . . ?
C2 C1 C10 C11 148.90(16) . . . . ?
N1 C1 C10 C15 84.18(19) . . . . ?
C2 C1 C10 C15 -31.2(2) . . . . ?
C15 C10 C11 C12 0.6(3) . . . . ?
C1 C10 C11 C12 -179.53(18) . . . . ?
C10 C11 C12 C13 -0.5(3) . . . . ?
C11 C12 C13 C14 -0.2(3) . . . . ?
C12 C13 C14 C15 0.8(3) . . . . ?
C13 C14 C15 C10 -0.7(3) . . . . ?
C11 C10 C15 C14 0.0(3) . . . . ?
C1 C10 C15 C14 -179.87(18) . . . . ?
C3 C2 C16 O2 -41.8(3) . . . . ?
C1 C2 C16 O2 126.50(19) . . . . ?
C3 C2 C16 N2 144.70(17) . . . . ?
C1 C2 C16 N2 -47.0(2) . . . . ?
O4 C18 C19 N2 -29.68(16) . . . . ?
O4 C18 C19 C20 91.14(17) . . . . ?
N2 C19 C20 C25 28.0(2) . . . . ?
C18 C19 C20 C25 -82.9(2) . . . . ?
N2 C19 C20 C21 -158.54(16) . . . . ?
C18 C19 C20 C21 90.5(2) . . . . ?
C25 C20 C21 C22 1.6(3) . . . . ?
C19 C20 C21 C22 -172.0(2) . . . . ?
C20 C21 C22 C23 -0.6(4) . . . . ?
C21 C22 C23 C24 -1.0(4) . . . . ?
C22 C23 C24 C25 1.5(4) . . . . ?
C21 C20 C25 C24 -1.1(3) . . . . ?
C19 C20 C25 C24 172.22(18) . . . . ?
C23 C24 C25 C20 -0.4(3) . . . . ?
N1 C26 C27 C28 -51.5(2) . . . . ?
N1 C26 C27 C32 133.38(18) . . . . ?
C32 C27 C28 C29 1.6(3) . . . . ?
C26 C27 C28 C29 -173.56(19) . . . . ?
C27 C28 C29 C30 0.0(4) . . . . ?
C28 C29 C30 C31 -1.5(4) . . . . ?
C29 C30 C31 C32 1.4(3) . . . . ?
C28 C27 C32 C31 -1.7(3) . . . . ?
C26 C27 C32 C31 173.48(18) . . . . ?
C30 C31 C32 C27 0.3(3) . . . . ?
C27 C26 N1 O1 172.66(14) . . . . ?
C27 C26 N1 C1 -76.20(18) . . . . ?
C10 C1 N1 O1 -99.42(14) . . . . ?
C2 C1 N1 O1 21.83(15) . . . . ?
C10 C1 N1 C26 150.19(14) . . . . ?
C2 C1 N1 C26 -88.55(15) . . . . ?
O3 C17 N2 C16 -8.9(3) . . . . ?
O4 C17 N2 C16 172.58(16) . . . . ?
O3 C17 N2 C19 165.24(19) . . . . ?
O4 C17 N2 C19 -13.31(19) . . . . ?
O2 C16 N2 C17 162.90(18) . . . . ?
C2 C16 N2 C17 -23.1(3) . . . . ?
O2 C16 N2 C19 -10.6(2) . . . . ?
C2 C16 N2 C19 163.34(15) . . . . ?
C20 C19 N2 C17 -91.47(17) . . . . ?
C18 C19 N2 C17 26.79(18) . . . . ?
C20 C19 N2 C16 83.09(19) . . . . ?
C18 C19 N2 C16 -158.65(16) . . . . ?
C2 C3 O1 N1 10.05(18) . . . . ?
C4 C3 O1 N1 -167.57(13) . . . . ?
C26 N1 O1 C3 96.65(14) . . . . ?
C1 N1 O1 C3 -20.33(16) . . . . ?
O3 C17 O4 C18 173.58(19) . . . . ?
N2 C17 O4 C18 -7.78(19) . . . . ?
C19 C18 O4 C17 24.58(19) . . . . ?

_refine_diff_density_max         0.206
_refine_diff_density_min         -0.172
_refine_diff_density_rms         0.034

