# Supplementary Information (SI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_0907
_database_code_depnum_ccdc_archive 'CCDC 2117234'
loop_
_audit_author_name
_audit_author_address
'Shujie Chen'
;Guangzhou University
China
;
_audit_update_record             
;
2021-10-22 deposited with the CCDC.	2025-03-31 downloaded from the CCDC.
;
_audit_creation_date             2021-08-04
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6272)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C27 H34 Cl F2 N O Si'
_chemical_formula_sum            'C27 H34 Cl F2 N O Si'
_chemical_formula_weight         490.09
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   7.4228(3)
_cell_length_b                   12.3770(4)
_cell_length_c                   15.3766(5)
_cell_angle_alpha                76.468(3)
_cell_angle_beta                 76.054(3)
_cell_angle_gamma                81.669(3)
_cell_volume                     1327.10(8)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    7799
_cell_measurement_temperature    149.99(10)
_cell_measurement_theta_max      29.1190
_cell_measurement_theta_min      2.4100
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    0.222
_exptl_absorpt_correction_T_max  0.974
_exptl_absorpt_correction_T_min  0.969
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.38.43f (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.227
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             520
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0518
_diffrn_reflns_av_unetI/netI     0.0568
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.875
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            18104
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.875
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.399
_diffrn_reflns_theta_min         1.963
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      149.99(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.2684
_diffrn_detector_type            AtlasS2
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.875
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -76.00  20.00   1.00    1.45    --  -11.27 -77.00-150.00   96
  2  ω    -58.00  36.00   1.00    1.45    --   11.90 -57.00 -30.00   94
  3  ω    -15.00  80.00   1.00    1.45    --   11.90  57.00 120.00   95
  4  ω    -69.00 -26.00   1.00    1.45    --  -11.27 127.00-108.84   43
  5  ω    -88.00 -51.00   1.00    1.45    --  -11.27 155.00  -0.48   37
  6  ω    -68.00  75.00   1.00    1.45    --   11.90   0.00  30.00  143
  7  ω    -15.00  27.00   1.00    1.45    --   11.90 -99.00-120.00   42
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0755717000
_diffrn_orient_matrix_UB_12      -0.0296077000
_diffrn_orient_matrix_UB_13      0.0189487000
_diffrn_orient_matrix_UB_21      -0.0592830000
_diffrn_orient_matrix_UB_22      -0.0408105000
_diffrn_orient_matrix_UB_23      0.0276245000
_diffrn_orient_matrix_UB_31      0.0235533000
_diffrn_orient_matrix_UB_32      -0.0310348000
_diffrn_orient_matrix_UB_33      -0.0351893000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Mo) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4950
_reflns_number_total             7313
_reflns_odcompleteness_completeness 99.47
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.43f (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'XS  (Sheldrick, 2008)'
_refine_diff_density_max         0.311
_refine_diff_density_min         -0.449
_refine_diff_density_rms         0.057
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     304
_refine_ls_number_reflns         6397
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0669
_refine_ls_R_factor_gt           0.0495
_refine_ls_restrained_S_all      1.016
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0900P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1372
_refine_ls_wR_factor_ref         0.1582
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C16(H16), C19(H19), C25(H25), C22(H22)
2.b Secondary CH2 refined with riding coordinates:
 C9(H9A,H9B), C8(H8A,H8B)
2.c Aromatic/amide H refined with riding coordinates:
 C6(H6), C3(H3), C2(H2), C5(H5), C12(H12), C13(H13), C14(H14), C15(H15)
2.d Idealised Me refined as rotating group:
 C24(H24A,H24B,H24C), C21(H21A,H21B,H21C), C20(H20A,H20B,H20C), C23(H23A,H23B,
 H23C), C26(H26A,H26B,H26C), C27(H27A,H27B,H27C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.49347(6) 0.48773(4) 0.27089(3) 0.02583(15) Uani 1 1 d . . . . .
Cl1 Cl 0.57434(7) 0.08605(4) -0.21064(3) 0.04676(17) Uani 1 1 d . . . . .
F2 F 0.87614(15) 0.17846(10) 0.47250(7) 0.0454(3) Uani 1 1 d . . . . .
F1 F 1.09269(16) 0.24809(10) 0.35904(8) 0.0498(3) Uani 1 1 d . . . . .
C10 C 0.8564(2) 0.16492(13) 0.32386(10) 0.0247(3) Uani 1 1 d . . . . .
C1 C 0.8707(2) 0.14395(13) -0.00470(10) 0.0266(4) Uani 1 1 d . . . . .
C7 C 0.9746(2) 0.15803(13) 0.06323(11) 0.0274(4) Uani 1 1 d . . . . .
O1 O 1.13994(17) 0.17012(12) 0.04185(8) 0.0425(3) Uani 1 1 d . . . . .
C11 C 0.7487(2) 0.06074(13) 0.35959(10) 0.0241(3) Uani 1 1 d . . . . .
N1 N 0.8569(2) -0.03460(12) 0.37722(10) 0.0328(3) Uani 1 1 d . . . . .
C6 C 0.6783(2) 0.14160(15) 0.01583(11) 0.0299(4) Uani 1 1 d . . . . .
H6 H 0.6105 0.1507 0.0734 0.036 Uiso 1 1 calc R U . . .
C9 C 0.9825(2) 0.15914(14) 0.22748(11) 0.0279(4) Uani 1 1 d . . . . .
H9A H 1.0517 0.2245 0.2050 0.034 Uiso 1 1 calc R U . . .
H9B H 1.0715 0.0936 0.2326 0.034 Uiso 1 1 calc R U . . .
C3 C 0.8803(3) 0.11636(14) -0.15614(11) 0.0329(4) Uani 1 1 d . . . . .
H3 H 0.9470 0.1082 -0.2141 0.040 Uiso 1 1 calc R U . . .
C4 C 0.6892(3) 0.11180(14) -0.13272(12) 0.0321(4) Uani 1 1 d . . . . .
C17 C 0.7326(2) 0.26883(14) 0.31585(10) 0.0254(3) Uani 1 1 d . . . . .
C2 C 0.9709(2) 0.13317(14) -0.09273(11) 0.0291(4) Uani 1 1 d . . . . .
H2 H 1.0991 0.1374 -0.1083 0.035 Uiso 1 1 calc R U . . .
C5 C 0.5861(2) 0.12604(15) -0.04728(12) 0.0324(4) Uani 1 1 d . . . . .
H5 H 0.4572 0.1251 -0.0330 0.039 Uiso 1 1 calc R U . . .
C18 C 0.6348(2) 0.35454(14) 0.30168(11) 0.0290(4) Uani 1 1 d . . . . .
C12 C 0.5575(2) 0.06463(14) 0.36967(10) 0.0275(4) Uani 1 1 d . . . . .
H12 H 0.4866 0.1324 0.3566 0.033 Uiso 1 1 calc R U . . .
C13 C 0.4741(2) -0.03451(15) 0.39958(11) 0.0307(4) Uani 1 1 d . . . . .
H13 H 0.3460 -0.0344 0.4069 0.037 Uiso 1 1 calc R U . . .
C16 C 0.9815(2) 0.16277(15) 0.38986(12) 0.0323(4) Uani 1 1 d . . . . .
H16 H 1.0583 0.0912 0.3977 0.039 Uiso 1 1 calc R U . . .
C8 C 0.8664(2) 0.15390(15) 0.16019(11) 0.0294(4) Uani 1 1 d . . . . .
H8A H 0.8053 0.0854 0.1812 0.035 Uiso 1 1 calc R U . . .
H8B H 0.7699 0.2158 0.1604 0.035 Uiso 1 1 calc R U . . .
C19 C 0.3319(2) 0.46557(15) 0.19973(12) 0.0323(4) Uani 1 1 d . . . . .
H19 H 0.2126 0.4491 0.2419 0.039 Uiso 1 1 calc R U . . .
C25 C 0.3635(3) 0.52837(16) 0.38146(12) 0.0354(4) Uani 1 1 d . . . . .
H25 H 0.4576 0.5401 0.4126 0.043 Uiso 1 1 calc R U . . .
C14 C 0.5832(3) -0.13291(15) 0.41818(11) 0.0346(4) Uani 1 1 d . . . . .
H14 H 0.5306 -0.2006 0.4383 0.042 Uiso 1 1 calc R U . . .
C22 C 0.6642(2) 0.59161(15) 0.20409(12) 0.0349(4) Uani 1 1 d . . . . .
H22 H 0.5921 0.6613 0.1823 0.042 Uiso 1 1 calc R U . . .
C15 C 0.7730(3) -0.12939(15) 0.40642(13) 0.0389(4) Uani 1 1 d . . . . .
H15 H 0.8462 -0.1962 0.4194 0.047 Uiso 1 1 calc R U . . .
C24 C 0.7899(3) 0.55315(19) 0.11958(13) 0.0473(5) Uani 1 1 d . . . . .
H24A H 0.8694 0.4880 0.1390 0.071 Uiso 1 1 calc R U . . .
H24B H 0.8649 0.6118 0.0838 0.071 Uiso 1 1 calc R U . . .
H24C H 0.7139 0.5357 0.0832 0.071 Uiso 1 1 calc R U . . .
C21 C 0.3968(3) 0.36705(17) 0.15144(14) 0.0412(4) Uani 1 1 d . . . . .
H21A H 0.5149 0.3793 0.1100 0.062 Uiso 1 1 calc R U . . .
H21B H 0.3067 0.3607 0.1179 0.062 Uiso 1 1 calc R U . . .
H21C H 0.4095 0.2995 0.1962 0.062 Uiso 1 1 calc R U . . .
C20 C 0.2925(3) 0.57216(17) 0.12972(14) 0.0449(5) Uani 1 1 d . . . . .
H20A H 0.2488 0.6331 0.1606 0.067 Uiso 1 1 calc R U . . .
H20B H 0.1992 0.5609 0.0999 0.067 Uiso 1 1 calc R U . . .
H20C H 0.4050 0.5891 0.0849 0.067 Uiso 1 1 calc R U . . .
C23 C 0.7827(3) 0.61708(19) 0.26425(15) 0.0492(5) Uani 1 1 d . . . . .
H23A H 0.7035 0.6503 0.3122 0.074 Uiso 1 1 calc R U . . .
H23B H 0.8714 0.6679 0.2277 0.074 Uiso 1 1 calc R U . . .
H23C H 0.8476 0.5491 0.2906 0.074 Uiso 1 1 calc R U . . .
C26 C 0.2403(3) 0.63841(18) 0.36649(15) 0.0513(6) Uani 1 1 d . . . . .
H26A H 0.3142 0.6957 0.3271 0.077 Uiso 1 1 calc R U . . .
H26B H 0.1870 0.6591 0.4244 0.077 Uiso 1 1 calc R U . . .
H26C H 0.1423 0.6295 0.3386 0.077 Uiso 1 1 calc R U . . .
C27 C 0.2512(3) 0.43651(19) 0.44569(14) 0.0543(6) Uani 1 1 d . . . . .
H27A H 0.1524 0.4254 0.4192 0.081 Uiso 1 1 calc R U . . .
H27B H 0.1991 0.4577 0.5035 0.081 Uiso 1 1 calc R U . . .
H27C H 0.3311 0.3685 0.4549 0.081 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Si1 C18 1.8482(18) . ?
Si1 C19 1.8920(18) . ?
Si1 C25 1.8824(18) . ?
Si1 C22 1.8817(17) . ?
Cl1 C4 1.7360(18) . ?
F2 C16 1.3625(19) . ?
F1 C16 1.360(2) . ?
C10 C11 1.536(2) . ?
C10 C9 1.562(2) . ?
C10 C17 1.467(2) . ?
C10 C16 1.526(2) . ?
C1 C7 1.493(2) . ?
C1 C6 1.389(2) . ?
C1 C2 1.405(2) . ?
C7 O1 1.2135(19) . ?
C7 C8 1.506(2) . ?
C11 N1 1.338(2) . ?
C11 C12 1.385(2) . ?
N1 C15 1.340(2) . ?
C6 H6 0.9300 . ?
C6 C5 1.376(2) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C9 C8 1.515(2) . ?
C3 H3 0.9300 . ?
C3 C4 1.383(2) . ?
C3 C2 1.377(2) . ?
C4 C5 1.388(2) . ?
C17 C18 1.202(2) . ?
C2 H2 0.9300 . ?
C5 H5 0.9300 . ?
C12 H12 0.9300 . ?
C12 C13 1.385(2) . ?
C13 H13 0.9300 . ?
C13 C14 1.373(3) . ?
C16 H16 0.9800 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C19 H19 0.9800 . ?
C19 C21 1.533(3) . ?
C19 C20 1.536(3) . ?
C25 H25 0.9800 . ?
C25 C26 1.529(3) . ?
C25 C27 1.522(3) . ?
C14 H14 0.9300 . ?
C14 C15 1.382(3) . ?
C22 H22 0.9800 . ?
C22 C24 1.537(3) . ?
C22 C23 1.529(3) . ?
C15 H15 0.9300 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C18 Si1 C19 108.37(8) . . ?
C18 Si1 C25 106.87(8) . . ?
C18 Si1 C22 106.02(8) . . ?
C25 Si1 C19 112.55(8) . . ?
C22 Si1 C19 111.82(8) . . ?
C22 Si1 C25 110.84(8) . . ?
C11 C10 C9 109.21(12) . . ?
C17 C10 C11 112.57(13) . . ?
C17 C10 C9 108.56(13) . . ?
C17 C10 C16 110.46(13) . . ?
C16 C10 C11 107.45(13) . . ?
C16 C10 C9 108.51(13) . . ?
C6 C1 C7 122.38(13) . . ?
C6 C1 C2 118.75(15) . . ?
C2 C1 C7 118.87(14) . . ?
C1 C7 C8 117.16(13) . . ?
O1 C7 C1 121.55(13) . . ?
O1 C7 C8 121.27(15) . . ?
N1 C11 C10 114.02(14) . . ?
N1 C11 C12 122.95(15) . . ?
C12 C11 C10 122.99(14) . . ?
C11 N1 C15 117.35(15) . . ?
C1 C6 H6 119.3 . . ?
C5 C6 C1 121.31(15) . . ?
C5 C6 H6 119.3 . . ?
C10 C9 H9A 109.5 . . ?
C10 C9 H9B 109.5 . . ?
H9A C9 H9B 108.0 . . ?
C8 C9 C10 110.94(13) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
C4 C3 H3 120.3 . . ?
C2 C3 H3 120.3 . . ?
C2 C3 C4 119.32(14) . . ?
C3 C4 Cl1 119.79(13) . . ?
C3 C4 C5 121.39(16) . . ?
C5 C4 Cl1 118.81(14) . . ?
C18 C17 C10 174.64(16) . . ?
C1 C2 H2 119.8 . . ?
C3 C2 C1 120.41(15) . . ?
C3 C2 H2 119.8 . . ?
C6 C5 C4 118.75(16) . . ?
C6 C5 H5 120.6 . . ?
C4 C5 H5 120.6 . . ?
C17 C18 Si1 175.77(15) . . ?
C11 C12 H12 120.7 . . ?
C11 C12 C13 118.63(16) . . ?
C13 C12 H12 120.7 . . ?
C12 C13 H13 120.5 . . ?
C14 C13 C12 119.05(16) . . ?
C14 C13 H13 120.5 . . ?
F2 C16 C10 110.22(13) . . ?
F2 C16 H16 109.9 . . ?
F1 C16 F2 105.79(13) . . ?
F1 C16 C10 111.06(14) . . ?
F1 C16 H16 109.9 . . ?
C10 C16 H16 109.9 . . ?
C7 C8 C9 114.69(13) . . ?
C7 C8 H8A 108.6 . . ?
C7 C8 H8B 108.6 . . ?
C9 C8 H8A 108.6 . . ?
C9 C8 H8B 108.6 . . ?
H8A C8 H8B 107.6 . . ?
Si1 C19 H19 106.8 . . ?
C21 C19 Si1 114.63(12) . . ?
C21 C19 H19 106.8 . . ?
C21 C19 C20 109.89(16) . . ?
C20 C19 Si1 111.56(12) . . ?
C20 C19 H19 106.8 . . ?
Si1 C25 H25 106.8 . . ?
C26 C25 Si1 112.73(13) . . ?
C26 C25 H25 106.8 . . ?
C27 C25 Si1 112.63(13) . . ?
C27 C25 H25 106.8 . . ?
C27 C25 C26 110.69(16) . . ?
C13 C14 H14 120.7 . . ?
C13 C14 C15 118.64(16) . . ?
C15 C14 H14 120.7 . . ?
Si1 C22 H22 107.5 . . ?
C24 C22 Si1 112.08(13) . . ?
C24 C22 H22 107.5 . . ?
C23 C22 Si1 111.59(13) . . ?
C23 C22 H22 107.5 . . ?
C23 C22 C24 110.31(15) . . ?
N1 C15 C14 123.38(17) . . ?
N1 C15 H15 118.3 . . ?
C14 C15 H15 118.3 . . ?
C22 C24 H24A 109.5 . . ?
C22 C24 H24B 109.5 . . ?
C22 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C25 C27 H27A 109.5 . . ?
C25 C27 H27B 109.5 . . ?
C25 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cl1 C4 C5 C6 177.21(14) . . . . ?
C10 C11 N1 C15 -178.33(14) . . . . ?
C10 C11 C12 C13 177.88(14) . . . . ?
C10 C9 C8 C7 175.02(14) . . . . ?
C1 C7 C8 C9 175.21(14) . . . . ?
C1 C6 C5 C4 0.4(3) . . . . ?
C7 C1 C6 C5 -178.54(15) . . . . ?
C7 C1 C2 C3 177.85(15) . . . . ?
O1 C7 C8 C9 -3.4(2) . . . . ?
C11 C10 C9 C8 59.71(17) . . . . ?
C11 C10 C16 F2 -67.85(16) . . . . ?
C11 C10 C16 F1 175.24(13) . . . . ?
C11 N1 C15 C14 0.5(3) . . . . ?
C11 C12 C13 C14 0.0(2) . . . . ?
N1 C11 C12 C13 0.2(2) . . . . ?
C6 C1 C7 O1 -173.18(17) . . . . ?
C6 C1 C7 C8 8.2(2) . . . . ?
C6 C1 C2 C3 -2.4(2) . . . . ?
C9 C10 C11 N1 66.30(17) . . . . ?
C9 C10 C11 C12 -111.59(16) . . . . ?
C9 C10 C16 F2 174.19(13) . . . . ?
C9 C10 C16 F1 57.27(18) . . . . ?
C3 C4 C5 C6 -2.0(3) . . . . ?
C4 C3 C2 C1 0.9(2) . . . . ?
C17 C10 C11 N1 -173.04(13) . . . . ?
C17 C10 C11 C12 9.1(2) . . . . ?
C17 C10 C9 C8 -63.37(17) . . . . ?
C17 C10 C16 F2 55.30(18) . . . . ?
C17 C10 C16 F1 -61.62(17) . . . . ?
C2 C1 C7 O1 6.5(2) . . . . ?
C2 C1 C7 C8 -172.05(15) . . . . ?
C2 C1 C6 C5 1.7(2) . . . . ?
C2 C3 C4 Cl1 -177.87(13) . . . . ?
C2 C3 C4 C5 1.3(3) . . . . ?
C18 Si1 C19 C21 -22.77(15) . . . . ?
C18 Si1 C19 C20 -148.47(13) . . . . ?
C18 Si1 C25 C26 179.71(14) . . . . ?
C18 Si1 C25 C27 -54.16(17) . . . . ?
C18 Si1 C22 C24 57.09(15) . . . . ?
C18 Si1 C22 C23 -67.20(15) . . . . ?
C12 C11 N1 C15 -0.4(2) . . . . ?
C12 C13 C14 C15 0.1(2) . . . . ?
C13 C14 C15 N1 -0.4(3) . . . . ?
C16 C10 C11 N1 -51.21(17) . . . . ?
C16 C10 C11 C12 130.90(15) . . . . ?
C16 C10 C9 C8 176.55(14) . . . . ?
C19 Si1 C25 C26 -61.44(16) . . . . ?
C19 Si1 C25 C27 64.69(17) . . . . ?
C19 Si1 C22 C24 -60.82(15) . . . . ?
C19 Si1 C22 C23 174.89(13) . . . . ?
C25 Si1 C19 C21 -140.74(14) . . . . ?
C25 Si1 C19 C20 93.57(14) . . . . ?
C25 Si1 C22 C24 172.71(13) . . . . ?
C25 Si1 C22 C23 48.42(16) . . . . ?
C22 Si1 C19 C21 93.72(14) . . . . ?
C22 Si1 C19 C20 -31.97(15) . . . . ?
C22 Si1 C25 C26 64.62(16) . . . . ?
C22 Si1 C25 C27 -169.25(15) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
- Detector area scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 118.460
_oxdiff_exptl_absorpt_empirical_full_min 0.511
