# Supplementary Information (SI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_250409a_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2448156'
loop_
_audit_author_name
_audit_author_address
hahawa
;Chongqing university
China
;
_audit_update_record             
;
2025-05-01 deposited with the CCDC.	2025-06-30 downloaded from the CCDC.
;
_audit_creation_date             2025-04-09
_audit_creation_method           
;
Olex2 1.5
(compiled 2025.03.04 svn.red2d20d0 for OlexSys, GUI svn.r7188)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H36 Cl N O4 Si'
_chemical_formula_sum            'C32 H36 Cl N O4 Si'
_chemical_formula_weight         562.16
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   9.5508(7)
_cell_length_b                   11.5289(7)
_cell_length_c                   28.804(2)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     3171.6(4)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9866
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      22.64
_cell_measurement_theta_min      2.25
_shelx_estimated_absorpt_T_max   0.936
_shelx_estimated_absorpt_T_min   0.927
_exptl_absorpt_coefficient_mu    0.193
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6071
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1390 before and 0.0870 after correction.
The Ratio of minimum to maximum transmission is 0.8142.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.177
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1192
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.35
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1176
_diffrn_reflns_av_unetI/netI     0.0479
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       37
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            91502
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.534
_diffrn_reflns_theta_min         2.247
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.777
_reflns_Friedel_fraction_full    0.998
_reflns_Friedel_fraction_max     0.996
_reflns_number_gt                4951
_reflns_number_total             7276
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.349
_refine_diff_density_min         -0.457
_refine_diff_density_rms         0.040
_refine_ls_abs_structure_details 
;
 Flack x determined using 1735 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.02(4)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     358
_refine_ls_number_reflns         7276
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0912
_refine_ls_R_factor_gt           0.0517
_refine_ls_restrained_S_all      1.040
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0582P)²+0.7117P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1162
_refine_ls_wR_factor_ref         0.1400
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C10(H10)
2.b Secondary CH2 refined with riding coordinates:
 C17(H17A,H17B), C20(H20A,H20B)
2.c Aromatic/amide H refined with riding coordinates:
 C5(H5), C6(H6), C7(H7), C8(H8), C12(H12), C13(H13), C14(H14), C15(H15),
 C16(H16), C22(H22), C24(H24), C25(H25), C26(H26)
2.d Idealised Me refined as rotating group:
 C19(H19A,H19B,H19C), C27(H27A,H27B,H27C), C28(H28A,H28B,H28C), C30(H30A,H30B,
 H30C), C31(H31A,H31B,H31C), C32(H32A,H32B,H32C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl 0.85044(17) 1.15536(16) 0.75038(5) 0.1152(6) Uani 1 1 d . . . . .
Si1 Si 0.03081(11) 0.76093(9) 0.59410(4) 0.0561(3) Uani 1 1 d . . . . .
O1 O 0.2604(3) 0.8626(3) 0.64490(13) 0.0827(10) Uani 1 1 d . . . . .
O2 O 0.1770(3) 0.6809(2) 0.59220(11) 0.0628(7) Uani 1 1 d . . . . .
O3 O 0.2799(4) 0.3999(3) 0.49340(12) 0.0915(11) Uani 1 1 d . . . . .
O4 O 0.4916(4) 0.3201(3) 0.49471(12) 0.0890(10) Uani 1 1 d . . . . .
N1 N 0.4384(3) 0.7611(3) 0.67747(11) 0.0566(8) Uani 1 1 d . . . . .
C1 C 0.3264(4) 0.7715(3) 0.64798(15) 0.0582(10) Uani 1 1 d . . . . .
C2 C 0.2901(4) 0.6697(3) 0.62047(13) 0.0480(8) Uani 1 1 d . . . . .
C3 C 0.3649(4) 0.5703(3) 0.62172(12) 0.0441(7) Uani 1 1 d . . . . .
C4 C 0.4844(4) 0.5636(3) 0.65313(12) 0.0462(8) Uani 1 1 d . . . . .
C5 C 0.5649(4) 0.4633(3) 0.65830(13) 0.0553(9) Uani 1 1 d . . . . .
H5 H 0.541001 0.397443 0.641437 0.066 Uiso 1 1 calc R U . . .
C6 C 0.6787(5) 0.4590(4) 0.68763(15) 0.0661(11) Uani 1 1 d . . . . .
H6 H 0.731359 0.391425 0.690171 0.079 Uiso 1 1 calc R U . . .
C7 C 0.7143(5) 0.5570(4) 0.71348(15) 0.0724(13) Uani 1 1 d . . . . .
H7 H 0.791093 0.554985 0.733326 0.087 Uiso 1 1 calc R U . . .
C8 C 0.6368(5) 0.6554(4) 0.70968(14) 0.0660(11) Uani 1 1 d . . . . .
H8 H 0.661777 0.720559 0.726843 0.079 Uiso 1 1 calc R U . . .
C9 C 0.5200(4) 0.6604(3) 0.68034(12) 0.0507(8) Uani 1 1 d . . . . .
C10 C 0.3272(4) 0.4708(3) 0.58996(12) 0.0464(8) Uani 1 1 d . . . . .
H10 H 0.243775 0.496494 0.572998 0.056 Uiso 1 1 calc R U . . .
C11 C 0.2824(4) 0.3629(3) 0.61616(13) 0.0509(9) Uani 1 1 d . . . . .
C12 C 0.1883(5) 0.3747(4) 0.65254(15) 0.0674(11) Uani 1 1 d . . . . .
H12 H 0.156397 0.448114 0.660786 0.081 Uiso 1 1 calc R U . . .
C13 C 0.1411(6) 0.2780(5) 0.67683(18) 0.0945(17) Uani 1 1 d . . . . .
H13 H 0.079044 0.287446 0.701422 0.113 Uiso 1 1 calc R U . . .
C14 C 0.1847(8) 0.1705(5) 0.6650(2) 0.105(2) Uani 1 1 d . . . . .
H14 H 0.151031 0.106223 0.680993 0.126 Uiso 1 1 calc R U . . .
C15 C 0.2783(7) 0.1558(4) 0.6294(2) 0.0956(18) Uani 1 1 d . . . . .
H15 H 0.308484 0.081761 0.621383 0.115 Uiso 1 1 calc R U . . .
C16 C 0.3280(5) 0.2516(3) 0.60529(17) 0.0735(12) Uani 1 1 d . . . . .
H16 H 0.392653 0.241230 0.581517 0.088 Uiso 1 1 calc R U . . .
C17 C 0.4403(4) 0.4529(4) 0.55291(13) 0.0604(10) Uani 1 1 d . . . . .
H17A H 0.475495 0.528102 0.543342 0.072 Uiso 1 1 calc R U . . .
H17B H 0.517669 0.410473 0.566647 0.072 Uiso 1 1 calc R U . . .
C18 C 0.3912(5) 0.3891(4) 0.51108(15) 0.0638(11) Uani 1 1 d . . . . .
C19 C 0.4594(8) 0.2552(6) 0.4536(2) 0.136(3) Uani 1 1 d . . . . .
H19A H 0.466148 0.305020 0.426952 0.205 Uiso 1 1 calc R U . . .
H19B H 0.365975 0.224973 0.455803 0.205 Uiso 1 1 calc R U . . .
H19C H 0.524463 0.192249 0.450423 0.205 Uiso 1 1 calc R U . . .
C20 C 0.4656(5) 0.8605(4) 0.70789(15) 0.0661(11) Uani 1 1 d . . . . .
H20A H 0.491863 0.831626 0.738304 0.079 Uiso 1 1 calc R U . . .
H20B H 0.379331 0.903979 0.711470 0.079 Uiso 1 1 calc R U . . .
C21 C 0.5778(4) 0.9417(3) 0.69123(13) 0.0542(9) Uani 1 1 d . . . . .
C22 C 0.6573(5) 1.0005(3) 0.72341(14) 0.0610(10) Uani 1 1 d . . . . .
H22 H 0.646049 0.985396 0.754905 0.073 Uiso 1 1 calc R U . . .
C23 C 0.7536(5) 1.0817(4) 0.70888(16) 0.0695(12) Uani 1 1 d . . . . .
C24 C 0.7751(5) 1.1037(4) 0.66301(17) 0.0750(13) Uani 1 1 d . . . . .
H24 H 0.841744 1.157903 0.653831 0.090 Uiso 1 1 calc R U . . .
C25 C 0.6972(5) 1.0449(4) 0.63025(15) 0.0736(12) Uani 1 1 d . . . . .
H25 H 0.710627 1.059559 0.598810 0.088 Uiso 1 1 calc R U . . .
C26 C 0.5985(5) 0.9638(4) 0.64442(15) 0.0662(11) Uani 1 1 d . . . . .
H26 H 0.546012 0.924120 0.622361 0.079 Uiso 1 1 calc R U . . .
C27 C -0.0375(5) 0.7766(5) 0.65393(16) 0.0810(13) Uani 1 1 d . . . . .
H27A H -0.028381 0.704054 0.670040 0.122 Uiso 1 1 calc R U . . .
H27B H -0.134376 0.798505 0.652784 0.122 Uiso 1 1 calc R U . . .
H27C H 0.014914 0.835216 0.669984 0.122 Uiso 1 1 calc R U . . .
C28 C 0.0543(6) 0.9022(4) 0.56492(18) 0.0840(14) Uani 1 1 d . . . . .
H28A H 0.109236 0.952409 0.584292 0.126 Uiso 1 1 calc R U . . .
H28B H -0.035646 0.936913 0.559475 0.126 Uiso 1 1 calc R U . . .
H28C H 0.101345 0.890846 0.535834 0.126 Uiso 1 1 calc R U . . .
C29 C -0.0933(4) 0.6687(4) 0.55937(17) 0.0695(11) Uani 1 1 d . . . . .
C30 C -0.2381(5) 0.7282(6) 0.5577(3) 0.120(2) Uani 1 1 d . . . . .
H30A H -0.278486 0.728662 0.588219 0.179 Uiso 1 1 calc R U . . .
H30B H -0.298360 0.686478 0.536900 0.179 Uiso 1 1 calc R U . . .
H30C H -0.227522 0.806553 0.546932 0.179 Uiso 1 1 calc R U . . .
C31 C -0.1123(6) 0.5506(5) 0.5826(2) 0.1016(18) Uani 1 1 d . . . . .
H31A H -0.026756 0.507254 0.580449 0.152 Uiso 1 1 calc R U . . .
H31B H -0.186079 0.508767 0.567374 0.152 Uiso 1 1 calc R U . . .
H31C H -0.136147 0.561488 0.614732 0.152 Uiso 1 1 calc R U . . .
C32 C -0.0413(7) 0.6506(6) 0.50995(19) 0.111(2) Uani 1 1 d . . . . .
H32A H -0.031172 0.724469 0.494906 0.167 Uiso 1 1 calc R U . . .
H32B H -0.107481 0.604161 0.493131 0.167 Uiso 1 1 calc R U . . .
H32C H 0.047649 0.611865 0.510647 0.167 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 C23 1.734(4) . ?
Si1 O2 1.674(3) . ?
Si1 C27 1.851(5) . ?
Si1 C28 1.847(4) . ?
Si1 C29 1.881(5) . ?
O1 C1 1.228(5) . ?
O2 C2 1.359(4) . ?
O3 C18 1.186(5) . ?
O4 C18 1.332(5) . ?
O4 C19 1.435(6) . ?
N1 C1 1.371(5) . ?
N1 C9 1.400(5) . ?
N1 C20 1.466(4) . ?
C1 C2 1.458(5) . ?
C2 C3 1.351(5) . ?
C3 C4 1.458(5) . ?
C3 C10 1.511(5) . ?
C4 C5 1.397(5) . ?
C4 C9 1.405(5) . ?
C5 H5 0.9300 . ?
C5 C6 1.377(6) . ?
C6 H6 0.9300 . ?
C6 C7 1.395(6) . ?
C7 H7 0.9300 . ?
C7 C8 1.359(7) . ?
C8 H8 0.9300 . ?
C8 C9 1.401(6) . ?
C10 H10 0.9800 . ?
C10 C11 1.516(5) . ?
C10 C17 1.533(5) . ?
C11 C12 1.387(6) . ?
C11 C16 1.391(6) . ?
C12 H12 0.9300 . ?
C12 C13 1.391(6) . ?
C13 H13 0.9300 . ?
C13 C14 1.352(9) . ?
C14 H14 0.9300 . ?
C14 C15 1.371(9) . ?
C15 H15 0.9300 . ?
C15 C16 1.388(7) . ?
C16 H16 0.9300 . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C17 C18 1.488(6) . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C20 C21 1.502(5) . ?
C21 C22 1.377(5) . ?
C21 C26 1.387(6) . ?
C22 H22 0.9300 . ?
C22 C23 1.377(6) . ?
C23 C24 1.361(6) . ?
C24 H24 0.9300 . ?
C24 C25 1.380(6) . ?
C25 H25 0.9300 . ?
C25 C26 1.388(6) . ?
C26 H26 0.9300 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 C30 1.544(7) . ?
C29 C31 1.529(7) . ?
C29 C32 1.522(7) . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
C31 H31A 0.9600 . ?
C31 H31B 0.9600 . ?
C31 H31C 0.9600 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 Si1 C27 112.2(2) . . ?
O2 Si1 C28 111.7(2) . . ?
O2 Si1 C29 101.35(17) . . ?
C27 Si1 C29 109.2(2) . . ?
C28 Si1 C27 112.4(2) . . ?
C28 Si1 C29 109.4(2) . . ?
C2 O2 Si1 134.1(2) . . ?
C18 O4 C19 116.7(5) . . ?
C1 N1 C9 122.9(3) . . ?
C1 N1 C20 116.1(3) . . ?
C9 N1 C20 121.0(3) . . ?
O1 C1 N1 121.4(3) . . ?
O1 C1 C2 121.8(4) . . ?
N1 C1 C2 116.9(3) . . ?
O2 C2 C1 116.0(3) . . ?
C3 C2 O2 121.1(3) . . ?
C3 C2 C1 122.9(3) . . ?
C2 C3 C4 118.4(3) . . ?
C2 C3 C10 120.1(3) . . ?
C4 C3 C10 121.5(3) . . ?
C5 C4 C3 122.7(3) . . ?
C5 C4 C9 117.7(3) . . ?
C9 C4 C3 119.6(3) . . ?
C4 C5 H5 119.0 . . ?
C6 C5 C4 122.0(4) . . ?
C6 C5 H5 119.0 . . ?
C5 C6 H6 120.3 . . ?
C5 C6 C7 119.4(4) . . ?
C7 C6 H6 120.3 . . ?
C6 C7 H7 120.0 . . ?
C8 C7 C6 120.0(4) . . ?
C8 C7 H7 120.0 . . ?
C7 C8 H8 119.5 . . ?
C7 C8 C9 121.1(4) . . ?
C9 C8 H8 119.5 . . ?
N1 C9 C4 119.4(3) . . ?
N1 C9 C8 120.8(3) . . ?
C8 C9 C4 119.8(4) . . ?
C3 C10 H10 105.5 . . ?
C3 C10 C11 112.9(3) . . ?
C3 C10 C17 110.8(3) . . ?
C11 C10 H10 105.5 . . ?
C11 C10 C17 115.7(3) . . ?
C17 C10 H10 105.5 . . ?
C12 C11 C10 118.6(3) . . ?
C12 C11 C16 117.6(4) . . ?
C16 C11 C10 123.8(4) . . ?
C11 C12 H12 119.6 . . ?
C11 C12 C13 120.7(5) . . ?
C13 C12 H12 119.6 . . ?
C12 C13 H13 119.7 . . ?
C14 C13 C12 120.5(5) . . ?
C14 C13 H13 119.7 . . ?
C13 C14 H14 119.9 . . ?
C13 C14 C15 120.2(5) . . ?
C15 C14 H14 119.9 . . ?
C14 C15 H15 120.0 . . ?
C14 C15 C16 119.9(5) . . ?
C16 C15 H15 120.0 . . ?
C11 C16 H16 119.5 . . ?
C15 C16 C11 121.0(5) . . ?
C15 C16 H16 119.5 . . ?
C10 C17 H17A 108.7 . . ?
C10 C17 H17B 108.7 . . ?
H17A C17 H17B 107.6 . . ?
C18 C17 C10 114.1(3) . . ?
C18 C17 H17A 108.7 . . ?
C18 C17 H17B 108.7 . . ?
O3 C18 O4 123.8(4) . . ?
O3 C18 C17 125.3(4) . . ?
O4 C18 C17 110.8(4) . . ?
O4 C19 H19A 109.5 . . ?
O4 C19 H19B 109.5 . . ?
O4 C19 H19C 109.5 . . ?
H19A C19 H19B 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
N1 C20 H20A 108.5 . . ?
N1 C20 H20B 108.5 . . ?
N1 C20 C21 115.0(3) . . ?
H20A C20 H20B 107.5 . . ?
C21 C20 H20A 108.5 . . ?
C21 C20 H20B 108.5 . . ?
C22 C21 C20 119.0(3) . . ?
C22 C21 C26 119.0(4) . . ?
C26 C21 C20 121.8(3) . . ?
C21 C22 H22 120.1 . . ?
C21 C22 C23 119.9(4) . . ?
C23 C22 H22 120.1 . . ?
C22 C23 Cl1 118.7(3) . . ?
C24 C23 Cl1 119.8(3) . . ?
C24 C23 C22 121.5(4) . . ?
C23 C24 H24 120.3 . . ?
C23 C24 C25 119.4(4) . . ?
C25 C24 H24 120.3 . . ?
C24 C25 H25 120.1 . . ?
C24 C25 C26 119.7(4) . . ?
C26 C25 H25 120.1 . . ?
C21 C26 C25 120.4(4) . . ?
C21 C26 H26 119.8 . . ?
C25 C26 H26 119.8 . . ?
Si1 C27 H27A 109.5 . . ?
Si1 C27 H27B 109.5 . . ?
Si1 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
Si1 C28 H28A 109.5 . . ?
Si1 C28 H28B 109.5 . . ?
Si1 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C30 C29 Si1 109.3(4) . . ?
C31 C29 Si1 110.2(3) . . ?
C31 C29 C30 107.6(5) . . ?
C32 C29 Si1 111.7(3) . . ?
C32 C29 C30 108.9(5) . . ?
C32 C29 C31 109.1(5) . . ?
C29 C30 H30A 109.5 . . ?
C29 C30 H30B 109.5 . . ?
C29 C30 H30C 109.5 . . ?
H30A C30 H30B 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C29 C31 H31A 109.5 . . ?
C29 C31 H31B 109.5 . . ?
C29 C31 H31C 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C29 C32 H32A 109.5 . . ?
C29 C32 H32B 109.5 . . ?
C29 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cl1 C23 C24 C25 -179.8(4) . . . . ?
Si1 O2 C2 C1 -28.4(5) . . . . ?
Si1 O2 C2 C3 153.0(3) . . . . ?
O1 C1 C2 O2 -1.6(6) . . . . ?
O1 C1 C2 C3 177.0(4) . . . . ?
O2 Si1 C29 C30 179.1(4) . . . . ?
O2 Si1 C29 C31 61.0(4) . . . . ?
O2 Si1 C29 C32 -60.3(4) . . . . ?
O2 C2 C3 C4 -179.4(3) . . . . ?
O2 C2 C3 C10 2.5(5) . . . . ?
N1 C1 C2 O2 178.6(3) . . . . ?
N1 C1 C2 C3 -2.8(6) . . . . ?
N1 C20 C21 C22 -149.1(4) . . . . ?
N1 C20 C21 C26 34.4(6) . . . . ?
C1 N1 C9 C4 -2.1(5) . . . . ?
C1 N1 C9 C8 177.5(4) . . . . ?
C1 N1 C20 C21 -98.4(4) . . . . ?
C1 C2 C3 C4 2.1(5) . . . . ?
C1 C2 C3 C10 -176.0(3) . . . . ?
C2 C3 C4 C5 177.4(3) . . . . ?
C2 C3 C4 C9 -1.2(5) . . . . ?
C2 C3 C10 C11 -117.3(4) . . . . ?
C2 C3 C10 C17 111.1(4) . . . . ?
C3 C4 C5 C6 179.0(4) . . . . ?
C3 C4 C9 N1 1.2(5) . . . . ?
C3 C4 C9 C8 -178.3(3) . . . . ?
C3 C10 C11 C12 45.9(5) . . . . ?
C3 C10 C11 C16 -135.5(4) . . . . ?
C3 C10 C17 C18 -158.9(3) . . . . ?
C4 C3 C10 C11 64.8(4) . . . . ?
C4 C3 C10 C17 -66.9(4) . . . . ?
C4 C5 C6 C7 0.8(6) . . . . ?
C5 C4 C9 N1 -177.5(3) . . . . ?
C5 C4 C9 C8 2.9(5) . . . . ?
C5 C6 C7 C8 0.1(6) . . . . ?
C6 C7 C8 C9 0.6(6) . . . . ?
C7 C8 C9 N1 178.4(4) . . . . ?
C7 C8 C9 C4 -2.1(6) . . . . ?
C9 N1 C1 O1 -177.0(4) . . . . ?
C9 N1 C1 C2 2.8(5) . . . . ?
C9 N1 C20 C21 84.2(5) . . . . ?
C9 C4 C5 C6 -2.3(5) . . . . ?
C10 C3 C4 C5 -4.6(5) . . . . ?
C10 C3 C4 C9 176.8(3) . . . . ?
C10 C11 C12 C13 178.2(4) . . . . ?
C10 C11 C16 C15 -177.2(4) . . . . ?
C10 C17 C18 O3 38.3(6) . . . . ?
C10 C17 C18 O4 -143.9(4) . . . . ?
C11 C10 C17 C18 70.9(5) . . . . ?
C11 C12 C13 C14 -0.9(8) . . . . ?
C12 C11 C16 C15 1.4(7) . . . . ?
C12 C13 C14 C15 1.3(9) . . . . ?
C13 C14 C15 C16 -0.3(9) . . . . ?
C14 C15 C16 C11 -1.1(8) . . . . ?
C16 C11 C12 C13 -0.4(7) . . . . ?
C17 C10 C11 C12 175.1(4) . . . . ?
C17 C10 C11 C16 -6.3(5) . . . . ?
C19 O4 C18 O3 -0.8(8) . . . . ?
C19 O4 C18 C17 -178.5(5) . . . . ?
C20 N1 C1 O1 5.6(6) . . . . ?
C20 N1 C1 C2 -174.6(3) . . . . ?
C20 N1 C9 C4 175.2(3) . . . . ?
C20 N1 C9 C8 -5.3(5) . . . . ?
C20 C21 C22 C23 -175.2(4) . . . . ?
C20 C21 C26 C25 175.9(4) . . . . ?
C21 C22 C23 Cl1 179.2(4) . . . . ?
C21 C22 C23 C24 -1.6(7) . . . . ?
C22 C21 C26 C25 -0.6(7) . . . . ?
C22 C23 C24 C25 1.1(8) . . . . ?
C23 C24 C25 C26 -0.3(8) . . . . ?
C24 C25 C26 C21 0.1(7) . . . . ?
C26 C21 C22 C23 1.4(6) . . . . ?
C27 Si1 O2 C2 -37.0(4) . . . . ?
C27 Si1 C29 C30 60.6(5) . . . . ?
C27 Si1 C29 C31 -57.5(4) . . . . ?
C27 Si1 C29 C32 -178.9(4) . . . . ?
C28 Si1 O2 C2 90.2(4) . . . . ?
C28 Si1 C29 C30 -62.8(5) . . . . ?
C28 Si1 C29 C31 179.2(4) . . . . ?
C28 Si1 C29 C32 57.8(5) . . . . ?
C29 Si1 O2 C2 -153.4(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
