# Supplementary Information (SI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_mo_230801a_0m_5
_database_code_depnum_ccdc_archive 'CCDC 2286698'
loop_
_audit_author_name
_audit_author_address
'xiaolin wang'
;Tongji University
China
;
_audit_update_record             
;
2025-06-05 deposited with the CCDC.	2025-06-23 downloaded from the CCDC.
;
_audit_creation_date             2025-06-05
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.08.24 svn.re1ec1418 for OlexSys, GUI svn.r6817)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C26 H25 F3 O'
_chemical_formula_sum            'C26 H25 F3 O'
_chemical_formula_weight         410.46
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   9.6418(5)
_cell_length_b                   10.6417(7)
_cell_length_c                   11.9051(7)
_cell_angle_alpha                110.343(2)
_cell_angle_beta                 93.003(2)
_cell_angle_gamma                114.109(2)
_cell_volume                     1018.10(11)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    3865
_cell_measurement_temperature    100.0
_cell_measurement_theta_max      27.477
_cell_measurement_theta_min      2.671
_shelx_estimated_absorpt_T_max   0.987
_shelx_estimated_absorpt_T_min   0.973
_exptl_absorpt_coefficient_mu    0.099
_exptl_absorpt_correction_T_max  0.745553
_exptl_absorpt_correction_T_min  0.655055
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
 TWINABS-2012/1 (Bruker,2012) was used for absorption correction.
 
For component 1:
 wR2(int) was 0.0688 before and 0.0580 after correction.
 
For component 2:
 wR2(int) was 0.0704 before and 0.0582 after correction.
 The Ratio of minimum to maximum transmission is 0.88.

Final HKLF 4 output contains 26618 reflections, Rint = 0.0565
 (16419 with I > 3sig(I), Rint = 0.0485)
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.339
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             432
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.13
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  ?
_diffrn_reflns_av_unetI/netI     0.0495
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            4638
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.985
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.538
_diffrn_reflns_theta_min         2.671
_diffrn_ambient_temperature      100.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker APEX-III CMOS'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3904
_reflns_number_total             4638
_reflns_special_details          
;
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'XT  (Sheldrick, 2015)'
_refine_diff_density_max         0.466
_refine_diff_density_min         -0.336
_refine_diff_density_rms         0.076
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     276
_refine_ls_number_reflns         4638
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0772
_refine_ls_R_factor_gt           0.0607
_refine_ls_restrained_S_all      1.045
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0721P)²+1.0644P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1464
_refine_ls_wR_factor_ref         0.1582
_refine_special_details          
;
 Refined as a 2-component twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.5139(17)
 0.4861(17)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
3.a Secondary CH2 refined with riding coordinates:
 C9(H9A,H9B), C18(H18A,H18B), C25(H25A,H25B)
3.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C6(H6), C8(H8), C12(H12), C13(H13), C14(H14),
 C15(H15), C16(H16), C20(H20), C21(H21), C22(H22), C23(H23), C24(H24)
3.c Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F1 F 0.1810(2) 0.90159(19) 0.83359(16) 0.0252(4) Uani 1 1 d . . . . .
F2 F 0.2645(2) 0.86596(19) 0.66688(17) 0.0228(4) Uani 1 1 d . . . . .
F3 F 0.0262(2) 0.82329(19) 0.66085(16) 0.0221(4) Uani 1 1 d . . . . .
O1 O 0.6622(3) 0.8035(3) 0.5027(2) 0.0324(6) Uani 1 1 d . . . . .
H1 H 0.653(5) 0.755(5) 0.417(4) 0.049 Uiso 1 1 d . U . . .
C1 C 0.3534(3) 0.5292(3) 0.3477(3) 0.0167(6) Uani 1 1 d . . . . .
C2 C 0.3698(4) 0.5916(4) 0.2596(3) 0.0221(6) Uani 1 1 d . . . . .
H2 H 0.408292 0.697228 0.285554 0.027 Uiso 1 1 calc R U . . .
C3 C 0.3301(4) 0.4994(4) 0.1346(3) 0.0263(7) Uani 1 1 d . . . . .
H3 H 0.342130 0.542411 0.075788 0.032 Uiso 1 1 calc R U . . .
C4 C 0.2734(4) 0.3464(4) 0.0962(3) 0.0258(7) Uani 1 1 d . . . . .
H4 H 0.244900 0.284688 0.010665 0.031 Uiso 1 1 calc R U . . .
C5 C 0.2570(4) 0.2796(4) 0.1803(3) 0.0216(6) Uani 1 1 d . . . . .
C6 C 0.2988(3) 0.3733(3) 0.3049(3) 0.0180(6) Uani 1 1 d . . . . .
H6 H 0.289916 0.329764 0.363214 0.022 Uiso 1 1 calc R U . . .
C7 C 0.3921(3) 0.6262(3) 0.4824(3) 0.0159(6) Uani 1 1 d . . . . .
C8 C 0.3222(3) 0.5692(3) 0.5596(3) 0.0159(6) Uani 1 1 d . . . . .
H8 H 0.243471 0.467630 0.523053 0.019 Uiso 1 1 calc R U . . .
C9 C 0.3530(3) 0.6464(3) 0.6977(3) 0.0158(5) Uani 1 1 d . . . . .
H9A H 0.406176 0.756779 0.722440 0.019 Uiso 1 1 calc R U . . .
H9B H 0.424575 0.619547 0.735597 0.019 Uiso 1 1 calc R U . . .
C10 C 0.2032(3) 0.6044(3) 0.7484(3) 0.0142(5) Uani 1 1 d . . . . .
C11 C 0.1260(3) 0.4332(3) 0.7136(2) 0.0149(5) Uani 1 1 d . . . . .
C12 C 0.2120(4) 0.3748(4) 0.7589(3) 0.0204(6) Uani 1 1 d . . . . .
H12 H 0.312722 0.441101 0.811465 0.025 Uiso 1 1 calc R U . . .
C13 C 0.1511(4) 0.2203(4) 0.7275(3) 0.0238(7) Uani 1 1 d . . . . .
H13 H 0.210949 0.182346 0.758358 0.029 Uiso 1 1 calc R U . . .
C14 C 0.0044(4) 0.1224(3) 0.6520(3) 0.0216(6) Uani 1 1 d . . . . .
H14 H -0.036438 0.017242 0.630162 0.026 Uiso 1 1 calc R U . . .
C15 C -0.0827(4) 0.1787(3) 0.6083(3) 0.0202(6) Uani 1 1 d . . . . .
H15 H -0.184168 0.111918 0.557064 0.024 Uiso 1 1 calc R U . . .
C16 C -0.0224(3) 0.3328(3) 0.6391(3) 0.0179(6) Uani 1 1 d . . . . .
H16 H -0.083657 0.369940 0.608814 0.022 Uiso 1 1 calc R U . . .
C17 C 0.1969(4) 0.1121(4) 0.1397(3) 0.0263(7) Uani 1 1 d . . . . .
H17A H 0.083512 0.061215 0.108588 0.039 Uiso 1 1 calc R U . . .
H17B H 0.222280 0.090839 0.209686 0.039 Uiso 1 1 calc R U . . .
H17C H 0.245987 0.075263 0.074309 0.039 Uiso 1 1 calc R U . . .
C18 C 0.5129(4) 0.7880(3) 0.5231(3) 0.0224(6) Uani 1 1 d . . . . .
H18A H 0.476394 0.835459 0.478072 0.027 Uiso 1 1 calc R U . . .
H18B H 0.523152 0.842627 0.611844 0.027 Uiso 1 1 calc R U . . .
C19 C 0.2399(3) 0.6846(3) 0.8904(3) 0.0157(5) Uani 1 1 d . . . . .
C20 C 0.1163(4) 0.6546(3) 0.9490(3) 0.0189(6) Uani 1 1 d . . . . .
H20 H 0.013430 0.584725 0.901671 0.023 Uiso 1 1 calc R U . . .
C21 C 0.1420(4) 0.7260(3) 1.0767(3) 0.0191(6) Uani 1 1 d . . . . .
H21 H 0.056519 0.706230 1.115538 0.023 Uiso 1 1 calc R U . . .
C22 C 0.2921(4) 0.8257(3) 1.1467(3) 0.0204(6) Uani 1 1 d . . . . .
H22 H 0.310124 0.873918 1.233541 0.024 Uiso 1 1 calc R U . . .
C23 C 0.4152(4) 0.8544(3) 1.0892(3) 0.0213(6) Uani 1 1 d . . . . .
H23 H 0.518218 0.922868 1.136899 0.026 Uiso 1 1 calc R U . . .
C24 C 0.3897(3) 0.7839(3) 0.9618(3) 0.0178(6) Uani 1 1 d . . . . .
H24 H 0.475645 0.804129 0.923472 0.021 Uiso 1 1 calc R U . . .
C25 C 0.0890(3) 0.6458(3) 0.6910(3) 0.0142(5) Uani 1 1 d . . . . .
H25A H 0.061404 0.587429 0.600871 0.017 Uiso 1 1 calc R U . . .
H25B H -0.007883 0.610747 0.720828 0.017 Uiso 1 1 calc R U . . .
C26 C 0.1409(3) 0.8077(3) 0.7142(3) 0.0183(6) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F1 C26 1.344(3) . ?
F2 C26 1.354(3) . ?
F3 C26 1.343(3) . ?
O1 H1 0.95(5) . ?
O1 C18 1.424(4) . ?
C1 C2 1.407(4) . ?
C1 C6 1.399(4) . ?
C1 C7 1.500(4) . ?
C2 H2 0.9500 . ?
C2 C3 1.393(4) . ?
C3 H3 0.9500 . ?
C3 C4 1.374(5) . ?
C4 H4 0.9500 . ?
C4 C5 1.396(5) . ?
C5 C6 1.392(4) . ?
C5 C17 1.509(5) . ?
C6 H6 0.9500 . ?
C7 C8 1.336(4) . ?
C7 C18 1.509(4) . ?
C8 H8 0.9500 . ?
C8 C9 1.509(4) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C9 C10 1.550(4) . ?
C10 C11 1.542(4) . ?
C10 C19 1.549(4) . ?
C10 C25 1.549(4) . ?
C11 C12 1.404(4) . ?
C11 C16 1.391(4) . ?
C12 H12 0.9500 . ?
C12 C13 1.395(5) . ?
C13 H13 0.9500 . ?
C13 C14 1.381(5) . ?
C14 H14 0.9500 . ?
C14 C15 1.384(5) . ?
C15 H15 0.9500 . ?
C15 C16 1.394(4) . ?
C16 H16 0.9500 . ?
C17 H17A 0.9800 . ?
C17 H17B 0.9800 . ?
C17 H17C 0.9800 . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C19 C20 1.393(4) . ?
C19 C24 1.388(4) . ?
C20 H20 0.9500 . ?
C20 C21 1.398(4) . ?
C21 H21 0.9500 . ?
C21 C22 1.385(4) . ?
C22 H22 0.9500 . ?
C22 C23 1.380(4) . ?
C23 H23 0.9500 . ?
C23 C24 1.394(4) . ?
C24 H24 0.9500 . ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
C25 C26 1.498(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C18 O1 H1 109(3) . . ?
C2 C1 C7 121.1(3) . . ?
C6 C1 C2 117.6(3) . . ?
C6 C1 C7 121.3(3) . . ?
C1 C2 H2 119.8 . . ?
C3 C2 C1 120.4(3) . . ?
C3 C2 H2 119.8 . . ?
C2 C3 H3 119.9 . . ?
C4 C3 C2 120.2(3) . . ?
C4 C3 H3 119.9 . . ?
C3 C4 H4 119.3 . . ?
C3 C4 C5 121.4(3) . . ?
C5 C4 H4 119.3 . . ?
C4 C5 C17 122.1(3) . . ?
C6 C5 C4 117.7(3) . . ?
C6 C5 C17 120.2(3) . . ?
C1 C6 H6 118.7 . . ?
C5 C6 C1 122.6(3) . . ?
C5 C6 H6 118.7 . . ?
C1 C7 C18 116.1(2) . . ?
C8 C7 C1 120.6(3) . . ?
C8 C7 C18 123.3(3) . . ?
C7 C8 H8 116.0 . . ?
C7 C8 C9 128.0(3) . . ?
C9 C8 H8 116.0 . . ?
C8 C9 H9A 108.9 . . ?
C8 C9 H9B 108.9 . . ?
C8 C9 C10 113.5(2) . . ?
H9A C9 H9B 107.7 . . ?
C10 C9 H9A 108.9 . . ?
C10 C9 H9B 108.9 . . ?
C11 C10 C9 108.0(2) . . ?
C11 C10 C19 107.8(2) . . ?
C11 C10 C25 109.7(2) . . ?
C19 C10 C9 111.9(2) . . ?
C19 C10 C25 109.3(2) . . ?
C25 C10 C9 110.1(2) . . ?
C12 C11 C10 117.8(3) . . ?
C16 C11 C10 124.3(2) . . ?
C16 C11 C12 117.9(3) . . ?
C11 C12 H12 119.6 . . ?
C13 C12 C11 120.7(3) . . ?
C13 C12 H12 119.6 . . ?
C12 C13 H13 119.8 . . ?
C14 C13 C12 120.4(3) . . ?
C14 C13 H13 119.8 . . ?
C13 C14 H14 120.3 . . ?
C13 C14 C15 119.5(3) . . ?
C15 C14 H14 120.3 . . ?
C14 C15 H15 119.8 . . ?
C14 C15 C16 120.4(3) . . ?
C16 C15 H15 119.8 . . ?
C11 C16 C15 121.1(3) . . ?
C11 C16 H16 119.5 . . ?
C15 C16 H16 119.5 . . ?
C5 C17 H17A 109.5 . . ?
C5 C17 H17B 109.5 . . ?
C5 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
O1 C18 C7 113.3(3) . . ?
O1 C18 H18A 108.9 . . ?
O1 C18 H18B 108.9 . . ?
C7 C18 H18A 108.9 . . ?
C7 C18 H18B 108.9 . . ?
H18A C18 H18B 107.7 . . ?
C20 C19 C10 118.2(2) . . ?
C24 C19 C10 123.2(3) . . ?
C24 C19 C20 118.6(3) . . ?
C19 C20 H20 119.6 . . ?
C19 C20 C21 120.8(3) . . ?
C21 C20 H20 119.6 . . ?
C20 C21 H21 120.0 . . ?
C22 C21 C20 120.0(3) . . ?
C22 C21 H21 120.0 . . ?
C21 C22 H22 120.3 . . ?
C23 C22 C21 119.5(3) . . ?
C23 C22 H22 120.3 . . ?
C22 C23 H23 119.7 . . ?
C22 C23 C24 120.6(3) . . ?
C24 C23 H23 119.7 . . ?
C19 C24 C23 120.5(3) . . ?
C19 C24 H24 119.7 . . ?
C23 C24 H24 119.7 . . ?
C10 C25 H25A 107.7 . . ?
C10 C25 H25B 107.7 . . ?
H25A C25 H25B 107.1 . . ?
C26 C25 C10 118.4(2) . . ?
C26 C25 H25A 107.7 . . ?
C26 C25 H25B 107.7 . . ?
F1 C26 F2 105.7(2) . . ?
F1 C26 C25 114.7(2) . . ?
F2 C26 C25 113.8(2) . . ?
F3 C26 F1 106.2(2) . . ?
F3 C26 F2 105.4(2) . . ?
F3 C26 C25 110.3(2) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 0.4(5) . . . . ?
C1 C7 C8 C9 176.0(3) . . . . ?
C1 C7 C18 O1 -62.8(3) . . . . ?
C2 C1 C6 C5 -1.8(4) . . . . ?
C2 C1 C7 C8 153.0(3) . . . . ?
C2 C1 C7 C18 -27.3(4) . . . . ?
C2 C3 C4 C5 -1.2(5) . . . . ?
C3 C4 C5 C6 0.5(5) . . . . ?
C3 C4 C5 C17 -179.2(3) . . . . ?
C4 C5 C6 C1 1.1(4) . . . . ?
C6 C1 C2 C3 1.1(4) . . . . ?
C6 C1 C7 C8 -26.7(4) . . . . ?
C6 C1 C7 C18 153.0(3) . . . . ?
C7 C1 C2 C3 -178.6(3) . . . . ?
C7 C1 C6 C5 177.8(3) . . . . ?
C7 C8 C9 C10 141.5(3) . . . . ?
C8 C7 C18 O1 116.9(3) . . . . ?
C8 C9 C10 C11 60.9(3) . . . . ?
C8 C9 C10 C19 179.4(2) . . . . ?
C8 C9 C10 C25 -58.8(3) . . . . ?
C9 C10 C11 C12 60.8(3) . . . . ?
C9 C10 C11 C16 -118.5(3) . . . . ?
C9 C10 C19 C20 -178.6(2) . . . . ?
C9 C10 C19 C24 1.1(4) . . . . ?
C9 C10 C25 C26 -61.6(3) . . . . ?
C10 C11 C12 C13 -177.9(3) . . . . ?
C10 C11 C16 C15 177.9(3) . . . . ?
C10 C19 C20 C21 -178.7(3) . . . . ?
C10 C19 C24 C23 179.1(3) . . . . ?
C10 C25 C26 F1 -58.3(3) . . . . ?
C10 C25 C26 F2 63.6(3) . . . . ?
C10 C25 C26 F3 -178.2(2) . . . . ?
C11 C10 C19 C20 -59.9(3) . . . . ?
C11 C10 C19 C24 119.7(3) . . . . ?
C11 C10 C25 C26 179.7(2) . . . . ?
C11 C12 C13 C14 -0.5(4) . . . . ?
C12 C11 C16 C15 -1.3(4) . . . . ?
C12 C13 C14 C15 -0.6(4) . . . . ?
C13 C14 C15 C16 0.7(4) . . . . ?
C14 C15 C16 C11 0.3(4) . . . . ?
C16 C11 C12 C13 1.4(4) . . . . ?
C17 C5 C6 C1 -179.2(3) . . . . ?
C18 C7 C8 C9 -3.7(5) . . . . ?
C19 C10 C11 C12 -60.3(3) . . . . ?
C19 C10 C11 C16 120.4(3) . . . . ?
C19 C10 C25 C26 61.7(3) . . . . ?
C19 C20 C21 C22 -1.3(5) . . . . ?
C20 C19 C24 C23 -1.3(4) . . . . ?
C20 C21 C22 C23 0.5(5) . . . . ?
C21 C22 C23 C24 -0.1(5) . . . . ?
C22 C23 C24 C19 0.5(5) . . . . ?
C24 C19 C20 C21 1.7(4) . . . . ?
C25 C10 C11 C12 -179.2(2) . . . . ?
C25 C10 C11 C16 1.5(4) . . . . ?
C25 C10 C19 C20 59.2(3) . . . . ?
C25 C10 C19 C24 -121.1(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.5139(17)
2 0.4861(17)
# start Validation Reply Form
_vrf_PLAT420_mo_230801a_0m_5     
;
PROBLEM: D-H Bond Without Acceptor  O1       --H1       .     Please Check 
RESPONSE: No acceptor atoms present in structure that would facilitate this.
;
# end Validation Reply Form

