# Supplementary Information (SI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_cu_20240489_0m
_database_code_depnum_ccdc_archive 'CCDC 2474762'
loop_
_audit_author_name
_audit_author_address
Fit
;Shandong Laboratory of Yantai Drug Discovery
China
;
_audit_update_record             
;
2025-07-22 deposited with the CCDC.	2025-10-02 downloaded from the CCDC.
;
_audit_creation_date             2025-07-22
_audit_creation_method           
;
Olex2 1.5
(compiled 2025.07.13 svn.rb7424aed for OlexSys, GUI svn.r7308)
;
_shelx_SHELXL_version_number     2019/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C15 H3 Ag3 F18 N6, 2(C20 H32 O)'
_chemical_formula_sum            'C55 H67 Ag3 F18 N6 O2'
_chemical_formula_weight         1509.75
_chemical_absolute_configuration rmad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_H-M_alt        P1
_space_group_name_Hall           'P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'

_cell_length_a                   12.0210(5)
_cell_length_b                   15.3300(6)
_cell_length_c                   17.4835(7)
_cell_angle_alpha                84.639(2)
_cell_angle_beta                 71.705(2)
_cell_angle_gamma                85.554(2)
_cell_volume                     3041.7(2)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9471
_cell_measurement_temperature    170(2)
_cell_measurement_theta_max      63.75
_cell_measurement_theta_min      2.67
_shelx_estimated_absorpt_T_max   0.674
_shelx_estimated_absorpt_T_min   0.380
_exptl_absorpt_coefficient_mu    8.561
_exptl_absorpt_correction_T_max  0.7524
_exptl_absorpt_correction_T_min  0.3144
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1602 before and 0.1063 after correction.
The Ratio of minimum to maximum transmission is 0.4179.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.648
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1516
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0703
_diffrn_reflns_av_unetI/netI     0.1006
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            30119
_diffrn_reflns_point_group_measured_fraction_full 0.836
_diffrn_reflns_point_group_measured_fraction_max 0.836
_diffrn_reflns_theta_full        63.806
_diffrn_reflns_theta_max         63.806
_diffrn_reflns_theta_min         2.669
_diffrn_ambient_temperature      170(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_source_current           1.2
_diffrn_source_power             0.06
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.684
_reflns_Friedel_fraction_full    0.679
_reflns_Friedel_fraction_max     0.679
_reflns_number_gt                14372
_reflns_number_total             16776
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences. Completness statistics refer to single and
 composite reflections containing twin component 1 only.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40A (Bruker, 2019)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40A (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         2.007
_refine_diff_density_min         -0.542
_refine_diff_density_rms         0.207
_refine_ls_abs_structure_details 
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.052(9)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1530
_refine_ls_number_reflns         16776
_refine_ls_number_restraints     5
_refine_ls_R_factor_all          0.0932
_refine_ls_R_factor_gt           0.0857
_refine_ls_restrained_S_all      1.084
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1414P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2115
_refine_ls_wR_factor_ref         0.2266
_refine_special_details          
;
 Refined as a 2-component inversion twin.
;
_olex2_refinement_description    
;
1. Twinned data refinement
 Scales: 0.948(9)
 0.052(9)
2. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
3. Rigid bond restraints
 C95, C101
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
 N5, N9
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.02
4.a Ternary CH refined with riding coordinates:
 C31(H31), C32(H32), C62(H62), C83(H83), C56(H56), C65(H65), C72(H72),
 C78(H78), C16(H16), C20(H20), C60(H60), C71(H71), C1(H1), C8(H8), C29(H29),
 C48(H48)
4.b Secondary CH2 refined with riding coordinates:
 C74(H74A,H74B), C80(H80A,H80B), C90(H90A,H90B), C91(H91A,H91B), C94(H94A,
 H94B), C95(H95A,H95B), C101(H10A,H10B), C2(H2A,H2B), C23(H23A,H23B), C64(H64A,
 H64B), C96(H96A,H96B), C99(H99A,H99B), C104(H10H,H10I), C105(H10J,H10K),
 C33(H33B,H33A), C43(H43A,H43B), C45(H45A,H45B), C67(H67A,H67B), C88(H88A,H88B),
  C107(H10L,H10M), C108(H10N,H10O), C27(H27A,H27B), C35(H35A,H35B), C49(H49A,
 H49B), C50(H50A,H50B), C52(H52A,H52B), C54(H54A,H54B), C89(H89A,H89B)
4.c Aromatic/amide H refined with riding coordinates:
 C55(H55), C59(H59), C87(H87), C5(H5), C12(H12), C81(H81)
4.d X=CH2 refined with riding coordinates:
 C106(H10F,H10G), C63(H63A,H63B), C44(H44A,H44B), C4(H4A,H4B)
4.e Idealised Me refined as rotating group:
 C24(H24A,H24B,H24C), C58(H58A,H58B,H58C), C76(H76A,H76B,H76C), C103(H10C,H10D,
 H10E), C40(H40A,H40B,H40C), C53(H53A,H53B,H53C), C69(H69A,H69B,H69C), C92(H92A,
 H92B,H92C), C7(H7A,H7B,H7C), C41(H41A,H41B,H41C), C61(H61A,H61B,H61C),
 C98(H98A,H98B,H98C), C14(H14A,H14B,H14C), C28(H28A,H28B,H28C), C47(H47A,H47B,
 H47C), C77(H77A,H77B,H77C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.26773(6) 0.68891(5) 0.19408(4) 0.07735(19) Uani 1 1 d . . . . .
Ag2 Ag 1.39271(6) 0.84322(5) 0.26656(5) 0.0795(2) Uani 1 1 d . . . . .
Ag4 Ag 1.15166(6) 0.74402(5) 0.38424(5) 0.07932(19) Uani 1 1 d . . . . .
F1 F 0.7750(6) 0.6123(5) 0.4708(4) 0.096(2) Uani 1 1 d . . . . .
F2 F 0.8119(8) 0.7477(5) 0.4381(5) 0.113(3) Uani 1 1 d . . . . .
F4 F 0.9163(6) 0.6664(7) 0.4975(4) 0.110(3) Uani 1 1 d . . . . .
F5 F 0.9737(7) 0.5329(7) 0.1464(5) 0.127(3) Uani 1 1 d . . . . .
F6 F 1.3616(7) 0.6528(7) 0.0043(6) 0.126(3) Uani 1 1 d . . . . .
F7 F 1.1176(11) 0.4707(6) 0.1764(6) 0.145(3) Uani 1 1 d . . . . .
F12 F 1.5312(8) 0.6622(7) -0.0718(5) 0.121(3) Uani 1 1 d . . . . .
F13 F 1.4984(10) 0.5871(6) 0.0368(6) 0.140(3) Uani 1 1 d . . . . .
F18 F 1.4839(9) 1.0134(7) 0.4522(8) 0.158(4) Uani 1 1 d . . . . .
F19 F 1.1365(9) 0.5873(6) 0.1079(5) 0.134(3) Uani 1 1 d . . . . .
F26 F 1.5326(10) 0.9939(7) 0.1174(12) 0.201(7) Uani 1 1 d . . . . .
F29 F 1.5859(9) 0.9102(9) 0.3994(12) 0.199(7) Uani 1 1 d . . . . .
F31 F 1.1499(11) 0.7980(10) 0.6535(5) 0.163(4) Uani 1 1 d . . . . .
F32 F 1.4981(12) 0.9869(10) 0.3371(9) 0.222(5) Uani 1 1 d . . . . .
F33 F 1.6382(17) 0.9737(10) 0.0196(10) 0.263(6) Uani 1 1 d . . . . .
F34 F 1.6776(11) 0.9184(8) 0.1143(12) 0.275(5) Uani 1 1 d . . . . .
F35 F 1.1407(17) 0.7015(9) 0.5837(8) 0.241(7) Uani 1 1 d . . . . .
F36 F 1.0436(10) 0.8122(14) 0.5852(10) 0.209(7) Uani 1 1 d . . . . .
N1 N 1.1022(7) 0.6462(6) 0.2592(5) 0.075(2) Uani 1 1 d . . . . .
N4 N 1.0491(7) 0.6742(5) 0.3345(6) 0.076(2) Uani 1 1 d . . . . .
N6 N 1.4558(7) 0.8198(5) 0.1433(5) 0.077(2) Uani 1 1 d . . . . .
N7 N 1.2518(7) 0.8065(6) 0.4419(5) 0.076(2) Uani 1 1 d . . . . .
N11 N 1.4175(7) 0.7485(6) 0.1203(5) 0.073(2) Uani 1 1 d . . . . .
N12 N 1.3448(8) 0.8542(6) 0.3937(5) 0.083(2) Uani 1 1 d . . . . .
C13 C 1.0636(8) 0.5453(7) 0.1709(6) 0.077(3) Uani 1 1 d . . . . .
C17 C 0.9420(9) 0.6428(8) 0.3635(6) 0.080(3) Uani 1 1 d . . . . .
C18 C 0.8616(10) 0.6677(9) 0.4421(7) 0.086(3) Uani 1 1 d . . . . .
C22 C 1.0285(8) 0.5924(7) 0.2435(6) 0.076(3) Uani 1 1 d . . . . .
C46 C 1.2409(11) 0.8201(8) 0.5179(7) 0.088(3) Uani 1 1 d . . . . .
C55 C 0.9227(9) 0.5885(7) 0.3092(7) 0.078(3) Uani 1 1 d . . . . .
H55 H 0.855324 0.556813 0.314912 0.093 Uiso 1 1 calc R U . . .
C59 C 1.3238(11) 0.8751(9) 0.5195(8) 0.098(3) Uani 1 1 d . . . . .
H59 H 1.335780 0.894926 0.566085 0.118 Uiso 1 1 calc R U . . .
C66 C 1.4842(9) 0.7358(9) 0.0420(7) 0.083(3) Uani 1 1 d . . . . .
C75 C 1.4682(9) 0.6596(8) 0.0018(7) 0.084(3) Uani 1 1 d . . . . .
C79 C 1.5989(9) 0.9309(9) 0.0846(8) 0.092(4) Uani 1 1 d . . . . .
C82 C 1.4903(11) 0.9478(9) 0.4070(9) 0.101(4) Uani 1 1 d . . . . .
C84 C 1.3871(10) 0.8964(8) 0.4397(7) 0.086(3) Uani 1 1 d . . . . .
C87 C 1.5658(8) 0.8012(9) 0.0153(7) 0.084(3) Uani 1 1 d . . . . .
H87 H 1.624694 0.808350 -0.035565 0.100 Uiso 1 1 calc R U . . .
C93 C 1.5412(8) 0.8527(8) 0.0794(7) 0.082(3) Uani 1 1 d . . . . .
C97 C 1.1453(11) 0.7825(9) 0.5853(8) 0.096(4) Uani 1 1 d . . . . .
Ag3 Ag 0.75039(6) 0.30716(5) 0.62890(5) 0.0799(2) Uani 1 1 d . . . . .
Ag5 Ag 0.91724(6) 0.13964(5) 0.68601(5) 0.0805(2) Uani 1 1 d . . . . .
Ag6 Ag 0.71102(6) 0.25771(5) 0.82527(5) 0.0805(2) Uani 1 1 d . . . . .
F3 F 0.5650(7) 0.3946(8) 0.9458(5) 0.128(3) Uani 1 1 d . . . . .
F8 F 0.9681(13) 0.3757(7) 0.3512(5) 0.151(5) Uani 1 1 d . . . . .
F9 F 1.2252(9) 0.0904(7) 0.4373(5) 0.129(3) Uani 1 1 d . . . . .
F10 F 0.6340(7) 0.1790(6) 1.0167(5) 0.110(2) Uani 1 1 d . . . . .
F11 F 0.3994(9) 0.4990(8) 0.6351(7) 0.145(4) Uani 1 1 d . . . . .
F14 F 0.4128(8) 0.4720(6) 0.9462(6) 0.127(3) Uani 1 1 d . . . . .
F15 F 0.4810(14) 0.3821(8) 0.5895(7) 0.177(4) Uani 1 1 d . . . . .
F16 F 0.7791(8) 0.2546(6) 1.0045(5) 0.117(3) Uani 1 1 d . . . . .
F17 F 0.4047(10) 0.3340(7) 0.9599(6) 0.144(3) Uani 1 1 d . . . . .
F20 F 0.7626(9) 0.1298(8) 1.0746(4) 0.125(3) Uani 1 1 d . . . . .
F21 F 0.8086(11) 0.3708(8) 0.4404(7) 0.154(4) Uani 1 1 d . . . . .
F22 F 1.0569(12) -0.0815(7) 0.8540(8) 0.164(4) Uani 1 1 d . . . . .
F23 F 0.9328(12) 0.4459(7) 0.4554(6) 0.144(4) Uani 1 1 d . . . . .
F24 F 0.5855(8) 0.4880(11) 0.5790(6) 0.171(5) Uani 1 1 d . . . . .
F25 F 1.1150(11) 0.0403(10) 0.5482(10) 0.192(6) Uani 1 1 d . . . . .
F27 F 1.1035(11) 0.0005(8) 0.7519(9) 0.189(6) Uani 1 1 d . . . . .
F28 F 1.2308(11) 0.1311(10) 0.5464(8) 0.238(4) Uani 1 1 d . . . . .
F30 F 0.9674(13) -0.0808(10) 0.7699(10) 0.195(5) Uani 1 1 d . . . . .
N2 N 0.8110(6) 0.1549(6) 0.8639(5) 0.071(2) Uani 1 1 d . . . . .
N3 N 0.8845(8) 0.0999(6) 0.8087(4) 0.081(2) Uani 1 1 d . . . . .
N5 N 0.9117(8) 0.2677(6) 0.5456(5) 0.078(2) Uani 1 1 d . U . . .
N8 N 0.5974(7) 0.3580(7) 0.7121(6) 0.085(3) Uani 1 1 d . . . . .
N9 N 0.9746(7) 0.1984(5) 0.5691(5) 0.072(2) Uani 1 1 d . U . . .
N10 N 0.5894(7) 0.3473(6) 0.7901(5) 0.076(2) Uani 1 1 d . . . . .
C3 C 0.5007(8) 0.3966(8) 0.8336(8) 0.084(3) Uani 1 1 d . . . . .
C5 C 0.4480(10) 0.4436(9) 0.7802(9) 0.094(4) Uani 1 1 d . . . . .
H5 H 0.382652 0.484717 0.793118 0.113 Uiso 1 1 calc R U . . .
C9 C 0.8159(8) 0.1259(7) 0.9379(7) 0.077(3) Uani 1 1 d . . . . .
C11 C 0.4962(9) 0.4457(9) 0.6280(8) 0.088(3) Uani 1 1 d . . . . .
C12 C 0.8919(9) 0.0519(8) 0.9298(7) 0.083(3) Uani 1 1 d . . . . .
H12 H 0.912629 0.016989 0.971629 0.099 Uiso 1 1 calc R U . . .
C15 C 1.0142(11) -0.0276(9) 0.8083(8) 0.096(4) Uani 1 1 d . . . . .
C19 C 0.9310(9) 0.0397(8) 0.8479(8) 0.088(3) Uani 1 1 d . . . . .
C21 C 0.9683(10) 0.2939(7) 0.4715(6) 0.081(3) Uani 1 1 d . . . . .
C26 C 0.5124(9) 0.4170(8) 0.7041(8) 0.085(3) Uani 1 1 d . . . . .
C42 C 1.0722(9) 0.1864(9) 0.5038(7) 0.085(3) Uani 1 1 d . . . . .
C57 C 0.9245(13) 0.3684(10) 0.4267(8) 0.101(4) Uani 1 1 d . . . . .
C73 C 1.1649(14) 0.1127(13) 0.5084(10) 0.115(5) Uani 1 1 d . . . . .
C81 C 1.0735(13) 0.2467(10) 0.4394(8) 0.100(4) Uani 1 1 d . . . . .
H81 H 1.130570 0.253809 0.387753 0.120 Uiso 1 1 calc R U . . .
C86 C 0.4716(11) 0.4005(9) 0.9214(9) 0.097(4) Uani 1 1 d . . . . .
C102 C 0.7482(12) 0.1691(9) 1.0090(8) 0.099(4) Uani 1 1 d . . . . .
O1 O 1.3440(7) 0.6032(7) 0.3135(5) 0.103(3) Uani 1 1 d . . . . .
C24 C 1.6746(9) 0.6541(9) 0.1723(9) 0.093(4) Uani 1 1 d . . . . .
H24A H 1.698274 0.713805 0.152007 0.139 Uiso 1 1 calc R U . . .
H24B H 1.629727 0.633224 0.140137 0.139 Uiso 1 1 calc R U . . .
H24C H 1.744678 0.615232 0.167995 0.139 Uiso 1 1 calc R U . . .
C31 C 1.5231(9) 0.4983(7) 0.2718(6) 0.078(3) Uani 1 1 d . . . . .
H31 H 1.542738 0.511393 0.212068 0.094 Uiso 1 1 calc R U . . .
C32 C 1.5925(8) 0.5608(8) 0.3028(7) 0.079(3) Uani 1 1 d . . . . .
H32 H 1.674851 0.535158 0.288202 0.095 Uiso 1 1 calc R U . . .
C51 C 1.3905(9) 0.5129(11) 0.3079(7) 0.096(4) Uani 1 1 d . . . . .
C58 C 1.2163(15) 0.5293(13) 0.4401(10) 0.124(6) Uani 1 1 d . . . . .
H58A H 1.162728 0.535731 0.407469 0.186 Uiso 1 1 calc R U . . .
H58B H 1.190840 0.570522 0.482589 0.186 Uiso 1 1 calc R U . . .
H58C H 1.215669 0.469142 0.464820 0.186 Uiso 1 1 calc R U . . .
C62 C 1.6003(9) 0.6542(8) 0.2588(8) 0.089(3) Uani 1 1 d . . . . .
H62 H 1.519057 0.675024 0.259456 0.107 Uiso 1 1 calc R U . . .
C70 C 1.3393(11) 0.5483(8) 0.3868(8) 0.091(4) Uani 1 1 d . . . . .
C74 C 1.7062(14) 0.2804(10) 0.2942(13) 0.124(6) Uani 1 1 d . . . . .
H74A H 1.682782 0.283289 0.353519 0.149 Uiso 1 1 calc R U . . .
H74B H 1.791027 0.263440 0.274672 0.149 Uiso 1 1 calc R U . . .
C76 C 1.6461(14) 0.7213(11) 0.2997(11) 0.116(5) Uani 1 1 d . . . . .
H76A H 1.720809 0.698626 0.307088 0.174 Uiso 1 1 calc R U . . .
H76B H 1.588857 0.731567 0.352468 0.174 Uiso 1 1 calc R U . . .
H76C H 1.657793 0.776491 0.265826 0.174 Uiso 1 1 calc R U . . .
C80 C 1.5489(10) 0.5554(9) 0.3931(8) 0.093(3) Uani 1 1 d . . . . .
H80A H 1.594936 0.593702 0.412903 0.112 Uiso 1 1 calc R U . . .
H80B H 1.562176 0.494384 0.413816 0.112 Uiso 1 1 calc R U . . .
C83 C 1.5543(10) 0.3987(9) 0.2867(7) 0.089(3) Uani 1 1 d . . . . .
H83 H 1.533135 0.387867 0.346774 0.106 Uiso 1 1 calc R U . . .
C85 C 1.6827(12) 0.3684(9) 0.2548(10) 0.104(4) Uani 1 1 d . . . . .
C90 C 1.3500(11) 0.3599(11) 0.2961(9) 0.113(4) Uani 1 1 d . . . . .
H90A H 1.303542 0.322767 0.275480 0.136 Uiso 1 1 calc R U . . .
H90B H 1.326431 0.348755 0.355571 0.136 Uiso 1 1 calc R U . . .
C91 C 1.4206(14) 0.5821(10) 0.4266(8) 0.104(4) Uani 1 1 d . . . . .
H91A H 1.412420 0.646964 0.422890 0.124 Uiso 1 1 calc R U . . .
H91B H 1.393698 0.561989 0.484645 0.124 Uiso 1 1 calc R U . . .
C94 C 1.3217(11) 0.4538(11) 0.2759(9) 0.105(4) Uani 1 1 d . . . . .
H94A H 1.236552 0.467284 0.299998 0.126 Uiso 1 1 calc R U . . .
H94B H 1.341577 0.465073 0.216541 0.126 Uiso 1 1 calc R U . . .
C95 C 1.636(2) 0.2130(12) 0.2731(14) 0.140(7) Uani 1 1 d . U . . .
H95A H 1.647145 0.155287 0.301102 0.169 Uiso 1 1 calc R U . . .
H95B H 1.664374 0.206652 0.214222 0.169 Uiso 1 1 calc R U . . .
C101 C 1.5040(16) 0.2435(11) 0.2997(12) 0.127(5) Uani 1 1 d . U . . .
H10A H 1.458719 0.199907 0.285290 0.152 Uiso 1 1 calc R U . . .
H10B H 1.475557 0.245979 0.359113 0.152 Uiso 1 1 calc R U . . .
C103 C 1.5164(19) 0.3355(14) 0.1705(10) 0.137(6) Uani 1 1 d . . . . .
H10C H 1.510925 0.396364 0.148622 0.205 Uiso 1 1 calc R U . . .
H10D H 1.463459 0.300449 0.154780 0.205 Uiso 1 1 calc R U . . .
H10E H 1.597147 0.311516 0.149159 0.205 Uiso 1 1 calc R U . . .
C106 C 1.7624(13) 0.4094(11) 0.1982(11) 0.121(5) Uani 1 1 d . . . . .
H10F H 1.839917 0.384084 0.179750 0.145 Uiso 1 1 calc R U . . .
H10G H 1.743341 0.464945 0.175170 0.145 Uiso 1 1 calc R U . . .
C110 C 1.4824(12) 0.3329(10) 0.2601(9) 0.106(4) Uani 1 1 d . . . . .
O2 O 0.7083(6) 0.1161(5) 0.6565(4) 0.081(2) Uani 1 1 d . . . . .
C2 C 0.4384(9) 0.0892(8) 0.6753(8) 0.088(3) Uani 1 1 d . . . . .
H2A H 0.366639 0.127932 0.693396 0.105 Uiso 1 1 calc R U . . .
H2B H 0.419177 0.040057 0.649541 0.105 Uiso 1 1 calc R U . . .
C23 C 0.7846(9) -0.0333(8) 0.6205(7) 0.081(3) Uani 1 1 d . . . . .
H23A H 0.821373 -0.046517 0.663889 0.097 Uiso 1 1 calc R U . . .
H23B H 0.842798 -0.005036 0.573100 0.097 Uiso 1 1 calc R U . . .
C30 C 0.6792(9) 0.0277(7) 0.6488(7) 0.079(3) Uani 1 1 d . . . . .
C37 C 0.4618(10) -0.1498(9) 0.7705(8) 0.092(4) Uani 1 1 d . . . . .
C39 C 0.6544(11) 0.0998(8) 0.5949(7) 0.088(3) Uani 1 1 d . . . . .
C40 C 0.7127(14) -0.1993(11) 0.7326(9) 0.113(5) Uani 1 1 d . . . . .
H40A H 0.726396 -0.149878 0.759680 0.169 Uiso 1 1 calc R U . . .
H40B H 0.787485 -0.230998 0.707743 0.169 Uiso 1 1 calc R U . . .
H40C H 0.659671 -0.238980 0.772159 0.169 Uiso 1 1 calc R U . . .
C53 C 0.5016(13) 0.0886(10) 0.8793(8) 0.103(4) Uani 1 1 d . . . . .
H53A H 0.494016 0.136030 0.914718 0.154 Uiso 1 1 calc R U . . .
H53B H 0.579614 0.059086 0.868981 0.154 Uiso 1 1 calc R U . . .
H53C H 0.441597 0.046204 0.905381 0.154 Uiso 1 1 calc R U . . .
C56 C 0.5506(9) -0.1002(7) 0.7023(7) 0.079(3) Uani 1 1 d . . . . .
H56 H 0.513038 -0.086457 0.658740 0.095 Uiso 1 1 calc R U . . .
C63 C 0.4346(12) -0.1370(10) 0.8447(9) 0.102(4) Uani 1 1 d . . . . .
H63A H 0.380318 -0.173144 0.883566 0.122 Uiso 1 1 calc R U . . .
H63B H 0.468327 -0.091146 0.861474 0.122 Uiso 1 1 calc R U . . .
C64 C 0.5349(11) 0.1415(7) 0.6122(8) 0.087(3) Uani 1 1 d . . . . .
H64A H 0.514749 0.150331 0.561182 0.104 Uiso 1 1 calc R U . . .
H64B H 0.535163 0.200162 0.631549 0.104 Uiso 1 1 calc R U . . .
C65 C 0.5818(8) -0.0103(7) 0.7229(6) 0.073(2) Uani 1 1 d . . . . .
H65 H 0.614712 -0.021385 0.769003 0.087 Uiso 1 1 calc R U . . .
C68 C 0.6573(10) -0.1648(8) 0.6672(8) 0.088(3) Uani 1 1 d . . . . .
C69 C 0.3796(12) 0.1927(10) 0.8163(10) 0.109(4) Uani 1 1 d . . . . .
H69A H 0.308486 0.164728 0.850353 0.164 Uiso 1 1 calc R U . . .
H69B H 0.369539 0.213958 0.764090 0.164 Uiso 1 1 calc R U . . .
H69C H 0.393906 0.242260 0.842969 0.164 Uiso 1 1 calc R U . . .
C72 C 0.4858(9) 0.1251(8) 0.8026(7) 0.085(3) Uani 1 1 d . . . . .
H72 H 0.557668 0.157111 0.772053 0.102 Uiso 1 1 calc R U . . .
C78 C 0.4741(9) 0.0526(7) 0.7487(7) 0.082(3) Uani 1 1 d . . . . .
H78 H 0.408542 0.016248 0.782942 0.099 Uiso 1 1 calc R U . . .
C92 C 0.7319(13) 0.1168(9) 0.5118(8) 0.098(4) Uani 1 1 d . . . . .
H92A H 0.721222 0.178533 0.493836 0.146 Uiso 1 1 calc R U . . .
H92B H 0.712315 0.079242 0.475966 0.146 Uiso 1 1 calc R U . . .
H92C H 0.813716 0.104116 0.510169 0.146 Uiso 1 1 calc R U . . .
C96 C 0.4132(13) -0.2203(9) 0.7386(11) 0.114(5) Uani 1 1 d . . . . .
H96A H 0.374821 -0.193632 0.698853 0.136 Uiso 1 1 calc R U . . .
H96B H 0.353073 -0.250491 0.783448 0.136 Uiso 1 1 calc R U . . .
C99 C 0.5137(15) -0.2896(9) 0.6966(10) 0.112(5) Uani 1 1 d . . . . .
H99A H 0.542803 -0.324155 0.737850 0.135 Uiso 1 1 calc R U . . .
H99B H 0.482636 -0.330499 0.668677 0.135 Uiso 1 1 calc R U . . .
C104 C 0.7492(12) -0.1192(8) 0.5973(8) 0.092(4) Uani 1 1 d . . . . .
H10H H 0.717782 -0.106063 0.551245 0.110 Uiso 1 1 calc R U . . .
H10I H 0.819631 -0.159252 0.579666 0.110 Uiso 1 1 calc R U . . .
C105 C 0.6136(15) -0.2403(10) 0.6360(9) 0.109(5) Uani 1 1 d . . . . .
H10J H 0.680471 -0.282857 0.615719 0.131 Uiso 1 1 calc R U . . .
H10K H 0.587228 -0.217127 0.589379 0.131 Uiso 1 1 calc R U . . .
O3 O 0.8400(6) 0.4044(5) 0.7489(5) 0.090(2) Uani 1 1 d . . . . .
C7 C 0.7974(10) 0.5306(8) 0.6605(8) 0.088(3) Uani 1 1 d . . . . .
H7A H 0.718796 0.528401 0.699868 0.132 Uiso 1 1 calc R U . . .
H7B H 0.797423 0.505812 0.610869 0.132 Uiso 1 1 calc R U . . .
H7C H 0.819794 0.591716 0.648293 0.132 Uiso 1 1 calc R U . . .
C10 C 0.8830(9) 0.4789(7) 0.6948(6) 0.073(3) Uani 1 1 d . . . . .
C16 C 1.0215(8) 0.5418(7) 0.8336(6) 0.073(3) Uani 1 1 d . . . . .
H16 H 1.054486 0.578032 0.781839 0.088 Uiso 1 1 calc R U . . .
C20 C 0.9853(9) 0.4588(8) 0.8106(6) 0.079(3) Uani 1 1 d . . . . .
H20 H 0.961448 0.418334 0.860637 0.094 Uiso 1 1 calc R U . . .
C25 C 0.8764(9) 0.4779(8) 0.7812(7) 0.080(3) Uani 1 1 d . . . . .
C33 C 1.1049(9) 0.4614(7) 0.6656(6) 0.078(3) Uani 1 1 d . . . . .
H33B H 1.118730 0.523037 0.670939 0.094 Uiso 1 1 calc R U . . .
H33A H 1.176283 0.436781 0.626208 0.094 Uiso 1 1 calc R U . . .
C38 C 1.1175(9) 0.5310(8) 0.8740(6) 0.081(3) Uani 1 1 d . . . . .
C41 C 1.1734(14) 0.2718(11) 0.6802(10) 0.112(5) Uani 1 1 d . . . . .
H41A H 1.248453 0.281088 0.688386 0.169 Uiso 1 1 calc R U . . .
H41B H 1.171769 0.300444 0.628031 0.169 Uiso 1 1 calc R U . . .
H41C H 1.164133 0.208736 0.680819 0.169 Uiso 1 1 calc R U . . .
C43 C 1.0051(10) 0.4608(9) 0.6323(7) 0.087(3) Uani 1 1 d . . . . .
H43A H 1.006324 0.402941 0.611167 0.105 Uiso 1 1 calc R U . . .
H43B H 1.016434 0.505738 0.586421 0.105 Uiso 1 1 calc R U . . .
C44 C 1.1443(10) 0.4581(10) 0.9142(7) 0.092(3) Uani 1 1 d . . . . .
H44A H 1.199487 0.459162 0.942783 0.110 Uiso 1 1 calc R U . . .
H44B H 1.108119 0.405148 0.914111 0.110 Uiso 1 1 calc R U . . .
C45 C 0.7786(11) 0.5306(12) 0.8352(9) 0.108(5) Uani 1 1 d . . . . .
H45A H 0.745020 0.496233 0.887215 0.130 Uiso 1 1 calc R U . . .
H45B H 0.715805 0.544410 0.809799 0.130 Uiso 1 1 calc R U . . .
C60 C 1.0733(9) 0.3108(8) 0.7478(7) 0.084(3) Uani 1 1 d . . . . .
H60 H 0.997683 0.302631 0.737399 0.101 Uiso 1 1 calc R U . . .
C61 C 1.0705(11) 0.2626(9) 0.8270(9) 0.102(4) Uani 1 1 d . . . . .
H61A H 1.069889 0.199404 0.822640 0.152 Uiso 1 1 calc R U . . .
H61B H 0.999664 0.281691 0.869164 0.152 Uiso 1 1 calc R U . . .
H61C H 1.140030 0.275271 0.841111 0.152 Uiso 1 1 calc R U . . .
C67 C 1.1739(11) 0.6147(9) 0.8737(8) 0.095(3) Uani 1 1 d . . . . .
H67A H 1.212488 0.636740 0.817180 0.114 Uiso 1 1 calc R U . . .
H67B H 1.235037 0.603083 0.900816 0.114 Uiso 1 1 calc R U . . .
C71 C 1.0877(9) 0.4103(8) 0.7470(6) 0.078(3) Uani 1 1 d . . . . .
H71 H 1.160384 0.416222 0.761940 0.094 Uiso 1 1 calc R U . . .
C88 C 0.8248(13) 0.6165(10) 0.8504(9) 0.107(4) Uani 1 1 d . . . . .
H88A H 0.854609 0.651569 0.798332 0.129 Uiso 1 1 calc R U . . .
H88B H 0.758857 0.651137 0.885792 0.129 Uiso 1 1 calc R U . . .
C98 C 0.8767(16) 0.5625(15) 0.9739(9) 0.131(6) Uani 1 1 d . . . . .
H98A H 0.830320 0.607348 1.008779 0.196 Uiso 1 1 calc R U . . .
H98B H 0.943204 0.540783 0.992649 0.196 Uiso 1 1 calc R U . . .
H98C H 0.827418 0.513826 0.975916 0.196 Uiso 1 1 calc R U . . .
C107 C 0.9776(15) 0.6919(10) 0.8839(10) 0.122(5) Uani 1 1 d . . . . .
H10L H 1.002419 0.716201 0.826971 0.146 Uiso 1 1 calc R U . . .
H10M H 0.917695 0.733580 0.915749 0.146 Uiso 1 1 calc R U . . .
C108 C 1.0858(16) 0.6837(10) 0.9160(9) 0.113(5) Uani 1 1 d . . . . .
H10N H 1.122849 0.740809 0.906585 0.135 Uiso 1 1 calc R U . . .
H10O H 1.059687 0.667753 0.974913 0.135 Uiso 1 1 calc R U . . .
C109 C 0.9212(11) 0.6016(10) 0.8891(8) 0.100(4) Uani 1 1 d . . . . .
O4 O 1.1391(7) 0.8825(4) 0.2688(4) 0.0759(19) Uani 1 1 d . . . . .
C1 C 1.0526(10) 0.8468(7) 0.1252(7) 0.083(3) Uani 1 1 d . . . . .
H1 H 1.073742 0.815012 0.171790 0.099 Uiso 1 1 calc R U . . .
C4 C 1.1262(9) 1.0904(8) -0.0033(6) 0.079(3) Uani 1 1 d . . . . .
H4A H 1.124696 1.119572 -0.053336 0.094 Uiso 1 1 calc R U . . .
H4B H 1.158641 1.031960 -0.001626 0.094 Uiso 1 1 calc R U . . .
C6 C 1.0841(9) 1.1301(7) 0.0626(7) 0.076(3) Uani 1 1 d . . . . .
C8 C 1.0941(8) 1.0963(7) 0.1441(6) 0.072(3) Uani 1 1 d . . . . .
H8 H 1.015955 1.110981 0.183686 0.087 Uiso 1 1 calc R U . . .
C14 C 1.1564(13) 0.8394(9) 0.0514(7) 0.099(4) Uani 1 1 d . . . . .
H14A H 1.175138 0.777528 0.040668 0.149 Uiso 1 1 calc R U . . .
H14B H 1.223782 0.864506 0.059904 0.149 Uiso 1 1 calc R U . . .
H14C H 1.138373 0.871482 0.005190 0.149 Uiso 1 1 calc R U . . .
C27 C 0.9058(10) 0.9537(8) 0.2177(8) 0.090(4) Uani 1 1 d . . . . .
H27A H 0.883006 1.016834 0.222903 0.108 Uiso 1 1 calc R U . . .
H27B H 0.841003 0.925231 0.207631 0.108 Uiso 1 1 calc R U . . .
C28 C 1.3046(10) 1.1459(8) 0.1008(9) 0.093(3) Uani 1 1 d . . . . .
H28A H 1.331879 1.083962 0.098662 0.139 Uiso 1 1 calc R U . . .
H28B H 1.359735 1.179339 0.115832 0.139 Uiso 1 1 calc R U . . .
H28C H 1.299801 1.168871 0.047602 0.139 Uiso 1 1 calc R U . . .
C29 C 1.1150(8) 0.9946(7) 0.1578(6) 0.074(3) Uani 1 1 d . . . . .
H29 H 1.190673 0.976852 0.117050 0.088 Uiso 1 1 calc R U . . .
C34 C 1.1299(10) 0.9757(7) 0.2413(7) 0.081(3) Uani 1 1 d . . . . .
C35 C 1.2207(10) 1.0295(8) 0.2575(8) 0.088(3) Uani 1 1 d . . . . .
H35A H 1.223725 1.013806 0.313100 0.105 Uiso 1 1 calc R U . . .
H35B H 1.299174 1.015433 0.219443 0.105 Uiso 1 1 calc R U . . .
C36 C 1.1829(8) 1.1544(7) 0.1636(7) 0.076(3) Uani 1 1 d . . . . .
C47 C 0.9510(11) 0.8033(10) 0.1152(9) 0.101(4) Uani 1 1 d . . . . .
H47A H 0.924886 0.836075 0.072520 0.152 Uiso 1 1 calc R U . . .
H47B H 0.886355 0.802429 0.166101 0.152 Uiso 1 1 calc R U . . .
H47C H 0.975253 0.743052 0.100491 0.152 Uiso 1 1 calc R U . . .
C48 C 1.0177(9) 0.9433(7) 0.1453(6) 0.075(3) Uani 1 1 d . . . . .
H48 H 0.999026 0.973573 0.097259 0.089 Uiso 1 1 calc R U . . .
C49 C 1.1909(10) 1.1247(8) 0.2480(7) 0.087(3) Uani 1 1 d . . . . .
H49A H 1.251395 1.157918 0.258536 0.105 Uiso 1 1 calc R U . . .
H49B H 1.114843 1.138936 0.288678 0.105 Uiso 1 1 calc R U . . .
C50 C 1.1359(11) 1.2513(8) 0.1634(8) 0.092(3) Uani 1 1 d . . . . .
H50A H 1.194136 1.288848 0.171360 0.111 Uiso 1 1 calc R U . . .
H50B H 1.062564 1.257793 0.208918 0.111 Uiso 1 1 calc R U . . .
C52 C 0.9228(10) 0.9137(9) 0.2955(7) 0.090(3) Uani 1 1 d . . . . .
H52A H 0.922720 0.849104 0.295650 0.108 Uiso 1 1 calc R U . . .
H52B H 0.854765 0.932522 0.340791 0.108 Uiso 1 1 calc R U . . .
C54 C 1.0320(10) 1.2220(8) 0.0634(8) 0.087(3) Uani 1 1 d . . . . .
H54A H 1.021080 1.240395 0.010364 0.105 Uiso 1 1 calc R U . . .
H54B H 0.954219 1.224653 0.105173 0.105 Uiso 1 1 calc R U . . .
C77 C 1.0206(14) 0.9492(10) 0.3965(8) 0.104(4) Uani 1 1 d . . . . .
H77A H 0.967949 1.000770 0.413253 0.156 Uiso 1 1 calc R U . . .
H77B H 1.097234 0.958053 0.402478 0.156 Uiso 1 1 calc R U . . .
H77C H 0.987129 0.897202 0.430344 0.156 Uiso 1 1 calc R U . . .
C89 C 1.1107(11) 1.2828(9) 0.0810(9) 0.098(4) Uani 1 1 d . . . . .
H89A H 1.073388 1.342800 0.084664 0.118 Uiso 1 1 calc R U . . .
H89B H 1.185719 1.284646 0.036386 0.118 Uiso 1 1 calc R U . . .
C100 C 1.0349(12) 0.9366(9) 0.3112(7) 0.092(4) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag4 3.3383(11) . ?
Ag1 N1 2.080(8) . ?
Ag1 N11 2.077(8) . ?
Ag2 Ag4 3.3613(10) . ?
Ag2 N6 2.104(8) . ?
Ag2 N12 2.134(8) . ?
Ag4 N4 2.115(10) . ?
Ag4 N7 2.122(10) . ?
F1 C18 1.337(14) . ?
F2 C18 1.327(15) . ?
F4 C18 1.329(15) . ?
F5 C13 1.313(14) . ?
F6 C75 1.281(14) . ?
F7 C13 1.280(14) . ?
F12 C75 1.271(13) . ?
F13 C75 1.300(16) . ?
F18 C82 1.318(19) . ?
F19 C13 1.321(13) . ?
F26 C79 1.262(17) . ?
F29 C82 1.219(18) . ?
F31 C97 1.256(17) . ?
F32 C82 1.29(2) . ?
F33 C79 1.23(2) . ?
F34 C79 1.21(2) . ?
F35 C97 1.25(2) . ?
F36 C97 1.27(2) . ?
N1 N4 1.364(12) . ?
N1 C22 1.359(15) . ?
N4 C17 1.337(14) . ?
N6 N11 1.360(13) . ?
N6 C93 1.346(13) . ?
N7 N12 1.384(12) . ?
N7 C46 1.329(16) . ?
N11 C66 1.375(13) . ?
N12 C84 1.315(17) . ?
C13 C22 1.449(15) . ?
C17 C18 1.474(15) . ?
C17 C55 1.401(17) . ?
C22 C55 1.422(13) . ?
C46 C59 1.363(19) . ?
C46 C97 1.471(17) . ?
C55 H55 0.9500 . ?
C59 H59 0.9500 . ?
C59 C84 1.385(17) . ?
C66 C75 1.473(19) . ?
C66 C87 1.401(17) . ?
C79 C93 1.455(18) . ?
C82 C84 1.453(18) . ?
C87 H87 0.9500 . ?
C87 C93 1.373(18) . ?
Ag3 Ag6 3.3370(11) . ?
Ag3 N5 2.111(8) . ?
Ag3 N8 2.101(8) . ?
Ag5 N3 2.096(7) . ?
Ag5 N9 2.081(8) . ?
Ag6 N2 2.098(8) . ?
Ag6 N10 2.121(9) . ?
F3 C86 1.316(18) . ?
F8 C57 1.255(16) . ?
F9 C73 1.289(18) . ?
F10 C102 1.335(16) . ?
F11 C11 1.347(16) . ?
F14 C86 1.291(16) . ?
F15 C11 1.292(19) . ?
F16 C102 1.378(17) . ?
F17 C86 1.340(17) . ?
F20 C102 1.299(17) . ?
F21 C57 1.34(2) . ?
F22 C15 1.287(18) . ?
F23 C57 1.355(19) . ?
F24 C11 1.317(15) . ?
F25 C73 1.33(2) . ?
F27 C15 1.280(17) . ?
F28 C73 1.24(2) . ?
F30 C15 1.36(2) . ?
N2 N3 1.387(12) . ?
N2 C9 1.346(14) . ?
N3 C19 1.295(15) . ?
N5 N9 1.364(13) . ?
N5 C21 1.302(13) . ?
N8 N10 1.331(14) . ?
N8 C26 1.343(15) . ?
N9 C42 1.371(13) . ?
N10 C3 1.327(13) . ?
C3 C5 1.403(19) . ?
C3 C86 1.47(2) . ?
C5 H5 0.9500 . ?
C5 C26 1.393(18) . ?
C9 C12 1.390(15) . ?
C9 C102 1.443(17) . ?
C11 C26 1.429(19) . ?
C12 H12 0.9500 . ?
C12 C19 1.386(18) . ?
C15 C19 1.443(18) . ?
C21 C57 1.481(19) . ?
C21 C81 1.388(18) . ?
C42 C73 1.54(2) . ?
C42 C81 1.385(19) . ?
C81 H81 0.9500 . ?
O1 C51 1.452(19) . ?
O1 C70 1.453(16) . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C24 C62 1.496(18) . ?
C31 H31 1.0000 . ?
C31 C32 1.554(16) . ?
C31 C51 1.526(14) . ?
C31 C83 1.561(18) . ?
C32 H32 1.0000 . ?
C32 C62 1.556(17) . ?
C32 C80 1.496(17) . ?
C51 C70 1.459(19) . ?
C51 C94 1.52(2) . ?
C58 H58A 0.9800 . ?
C58 H58B 0.9800 . ?
C58 H58C 0.9800 . ?
C58 C70 1.51(2) . ?
C62 H62 1.0000 . ?
C62 C76 1.53(2) . ?
C70 C91 1.51(2) . ?
C74 H74A 0.9900 . ?
C74 H74B 0.9900 . ?
C74 C85 1.50(2) . ?
C74 C95 1.52(3) . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
C80 H80A 0.9900 . ?
C80 H80B 0.9900 . ?
C80 C91 1.506(19) . ?
C83 H83 1.0000 . ?
C83 C85 1.518(17) . ?
C83 C110 1.57(2) . ?
C85 C106 1.29(2) . ?
C90 H90A 0.9900 . ?
C90 H90B 0.9900 . ?
C90 C94 1.49(2) . ?
C90 C110 1.555(19) . ?
C91 H91A 0.9900 . ?
C91 H91B 0.9900 . ?
C94 H94A 0.9900 . ?
C94 H94B 0.9900 . ?
C95 H95A 0.9900 . ?
C95 H95B 0.9900 . ?
C95 C101 1.56(3) . ?
C101 H10A 0.9900 . ?
C101 H10B 0.9900 . ?
C101 C110 1.52(2) . ?
C103 H10C 0.9800 . ?
C103 H10D 0.9800 . ?
C103 H10E 0.9800 . ?
C103 C110 1.49(2) . ?
C106 H10F 0.9500 . ?
C106 H10G 0.9500 . ?
O2 C30 1.453(14) . ?
O2 C39 1.468(16) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C2 C64 1.544(16) . ?
C2 C78 1.523(19) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C23 C30 1.495(15) . ?
C23 C104 1.540(19) . ?
C30 C39 1.460(17) . ?
C30 C65 1.549(14) . ?
C37 C56 1.515(15) . ?
C37 C63 1.26(2) . ?
C37 C96 1.50(2) . ?
C39 C64 1.479(17) . ?
C39 C92 1.471(17) . ?
C40 H40A 0.9800 . ?
C40 H40B 0.9800 . ?
C40 H40C 0.9800 . ?
C40 C68 1.53(2) . ?
C53 H53A 0.9800 . ?
C53 H53B 0.9800 . ?
C53 H53C 0.9800 . ?
C53 C72 1.466(19) . ?
C56 H56 1.0000 . ?
C56 C65 1.558(16) . ?
C56 C68 1.557(15) . ?
C63 H63A 0.9500 . ?
C63 H63B 0.9500 . ?
C64 H64A 0.9900 . ?
C64 H64B 0.9900 . ?
C65 H65 1.0000 . ?
C65 C78 1.528(14) . ?
C68 C104 1.522(17) . ?
C68 C105 1.52(2) . ?
C69 H69A 0.9800 . ?
C69 H69B 0.9800 . ?
C69 H69C 0.9800 . ?
C69 C72 1.553(18) . ?
C72 H72 1.0000 . ?
C72 C78 1.562(17) . ?
C78 H78 1.0000 . ?
C92 H92A 0.9800 . ?
C92 H92B 0.9800 . ?
C92 H92C 0.9800 . ?
C96 H96A 0.9900 . ?
C96 H96B 0.9900 . ?
C96 C99 1.59(2) . ?
C99 H99A 0.9900 . ?
C99 H99B 0.9900 . ?
C99 C105 1.53(2) . ?
C104 H10H 0.9900 . ?
C104 H10I 0.9900 . ?
C105 H10J 0.9900 . ?
C105 H10K 0.9900 . ?
O3 C10 1.431(13) . ?
O3 C25 1.460(15) . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C7 C10 1.489(17) . ?
C10 C25 1.486(16) . ?
C10 C43 1.553(14) . ?
C16 H16 1.0000 . ?
C16 C20 1.504(17) . ?
C16 C38 1.522(16) . ?
C16 C109 1.580(16) . ?
C20 H20 1.0000 . ?
C20 C25 1.549(16) . ?
C20 C71 1.568(14) . ?
C25 C45 1.491(18) . ?
C33 H33B 0.9900 . ?
C33 H33A 0.9900 . ?
C33 C43 1.488(18) . ?
C33 C71 1.522(16) . ?
C38 C44 1.337(19) . ?
C38 C67 1.495(18) . ?
C41 H41A 0.9800 . ?
C41 H41B 0.9800 . ?
C41 H41C 0.9800 . ?
C41 C60 1.526(19) . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
C44 H44A 0.9500 . ?
C44 H44B 0.9500 . ?
C45 H45A 0.9900 . ?
C45 H45B 0.9900 . ?
C45 C88 1.55(2) . ?
C60 H60 1.0000 . ?
C60 C61 1.50(2) . ?
C60 C71 1.546(17) . ?
C61 H61A 0.9800 . ?
C61 H61B 0.9800 . ?
C61 H61C 0.9800 . ?
C67 H67A 0.9900 . ?
C67 H67B 0.9900 . ?
C67 C108 1.51(2) . ?
C71 H71 1.0000 . ?
C88 H88A 0.9900 . ?
C88 H88B 0.9900 . ?
C88 C109 1.51(2) . ?
C98 H98A 0.9800 . ?
C98 H98B 0.9800 . ?
C98 H98C 0.9800 . ?
C98 C109 1.49(2) . ?
C107 H10L 0.9900 . ?
C107 H10M 0.9900 . ?
C107 C108 1.56(3) . ?
C107 C109 1.57(2) . ?
C108 H10N 0.9900 . ?
C108 H10O 0.9900 . ?
O4 C34 1.471(13) . ?
O4 C100 1.476(14) . ?
C1 H1 1.0000 . ?
C1 C14 1.493(16) . ?
C1 C47 1.500(19) . ?
C1 C48 1.548(15) . ?
C4 H4A 0.9500 . ?
C4 H4B 0.9500 . ?
C4 C6 1.292(15) . ?
C6 C8 1.508(16) . ?
C6 C54 1.497(16) . ?
C8 H8 1.0000 . ?
C8 C29 1.568(15) . ?
C8 C36 1.575(15) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C27 C48 1.541(15) . ?
C27 C52 1.51(2) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C28 C36 1.534(14) . ?
C29 H29 1.0000 . ?
C29 C34 1.525(17) . ?
C29 C48 1.539(16) . ?
C34 C35 1.526(19) . ?
C34 C100 1.500(16) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C35 C49 1.483(18) . ?
C36 C49 1.532(17) . ?
C36 C50 1.548(16) . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C48 H48 1.0000 . ?
C49 H49A 0.9900 . ?
C49 H49B 0.9900 . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C50 C89 1.59(2) . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?
C52 C100 1.53(2) . ?
C54 H54A 0.9900 . ?
C54 H54B 0.9900 . ?
C54 C89 1.49(2) . ?
C77 H77A 0.9800 . ?
C77 H77B 0.9800 . ?
C77 H77C 0.9800 . ?
C77 C100 1.47(2) . ?
C89 H89A 0.9900 . ?
C89 H89B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 Ag4 62.0(3) . . ?
N11 Ag1 Ag4 119.2(2) . . ?
N11 Ag1 N1 170.1(4) . . ?
N6 Ag2 Ag4 118.8(2) . . ?
N6 Ag2 N12 172.7(4) . . ?
N12 Ag2 Ag4 62.2(2) . . ?
Ag1 Ag4 Ag2 61.59(2) . . ?
N4 Ag4 Ag1 61.7(2) . . ?
N4 Ag4 Ag2 121.4(2) . . ?
N4 Ag4 N7 175.5(3) . . ?
N7 Ag4 Ag1 121.0(2) . . ?
N7 Ag4 Ag2 62.2(2) . . ?
N4 N1 Ag1 118.8(7) . . ?
C22 N1 Ag1 133.5(7) . . ?
C22 N1 N4 107.6(7) . . ?
N1 N4 Ag4 117.0(6) . . ?
C17 N4 Ag4 133.8(8) . . ?
C17 N4 N1 108.9(9) . . ?
N11 N6 Ag2 117.2(6) . . ?
C93 N6 Ag2 134.5(8) . . ?
C93 N6 N11 107.6(8) . . ?
N12 N7 Ag4 118.0(6) . . ?
C46 N7 Ag4 134.9(7) . . ?
C46 N7 N12 106.7(9) . . ?
N6 N11 Ag1 120.6(6) . . ?
N6 N11 C66 107.9(8) . . ?
C66 N11 Ag1 131.0(8) . . ?
N7 N12 Ag2 117.0(7) . . ?
C84 N12 Ag2 133.7(7) . . ?
C84 N12 N7 109.3(8) . . ?
F5 C13 F19 103.8(10) . . ?
F5 C13 C22 111.7(8) . . ?
F7 C13 F5 107.8(11) . . ?
F7 C13 F19 103.4(9) . . ?
F7 C13 C22 115.1(10) . . ?
F19 C13 C22 113.9(9) . . ?
N4 C17 C18 120.5(11) . . ?
N4 C17 C55 110.6(9) . . ?
C55 C17 C18 128.8(10) . . ?
F1 C18 C17 111.2(11) . . ?
F2 C18 F1 107.1(9) . . ?
F2 C18 F4 106.7(11) . . ?
F2 C18 C17 112.8(10) . . ?
F4 C18 F1 106.8(9) . . ?
F4 C18 C17 111.9(10) . . ?
N1 C22 C13 121.4(8) . . ?
N1 C22 C55 109.7(9) . . ?
C55 C22 C13 128.9(10) . . ?
N7 C46 C59 109.7(11) . . ?
N7 C46 C97 121.0(12) . . ?
C59 C46 C97 129.2(12) . . ?
C17 C55 C22 103.1(9) . . ?
C17 C55 H55 128.5 . . ?
C22 C55 H55 128.5 . . ?
C46 C59 H59 126.8 . . ?
C46 C59 C84 106.3(12) . . ?
C84 C59 H59 126.8 . . ?
N11 C66 C75 120.6(10) . . ?
N11 C66 C87 108.8(11) . . ?
C87 C66 C75 130.4(10) . . ?
F6 C75 F13 106.3(11) . . ?
F6 C75 C66 113.0(10) . . ?
F12 C75 F6 107.9(11) . . ?
F12 C75 F13 107.1(10) . . ?
F12 C75 C66 111.7(10) . . ?
F13 C75 C66 110.6(11) . . ?
F26 C79 C93 116.2(10) . . ?
F33 C79 F26 93.6(14) . . ?
F33 C79 C93 114.2(15) . . ?
F34 C79 F26 108.4(16) . . ?
F34 C79 F33 107.0(15) . . ?
F34 C79 C93 115.1(12) . . ?
F18 C82 C84 110.2(11) . . ?
F29 C82 F18 106.2(14) . . ?
F29 C82 F32 105.3(14) . . ?
F29 C82 C84 117.7(13) . . ?
F32 C82 F18 103.1(14) . . ?
F32 C82 C84 113.2(13) . . ?
N12 C84 C59 108.0(11) . . ?
N12 C84 C82 122.3(11) . . ?
C59 C84 C82 129.4(13) . . ?
C66 C87 H87 127.9 . . ?
C93 C87 C66 104.3(9) . . ?
C93 C87 H87 127.9 . . ?
N6 C93 C79 120.7(11) . . ?
N6 C93 C87 111.3(10) . . ?
C87 C93 C79 127.9(10) . . ?
F31 C97 F36 104.1(14) . . ?
F31 C97 C46 113.4(13) . . ?
F35 C97 F31 108.5(15) . . ?
F35 C97 F36 103.5(17) . . ?
F35 C97 C46 112.8(12) . . ?
F36 C97 C46 113.8(13) . . ?
N5 Ag3 Ag6 118.2(3) . . ?
N8 Ag3 Ag6 61.9(3) . . ?
N8 Ag3 N5 174.4(4) . . ?
N9 Ag5 N3 167.1(4) . . ?
N2 Ag6 Ag3 120.7(2) . . ?
N2 Ag6 N10 171.1(3) . . ?
N10 Ag6 Ag3 61.0(2) . . ?
N3 N2 Ag6 120.2(6) . . ?
C9 N2 Ag6 131.7(7) . . ?
C9 N2 N3 108.0(8) . . ?
N2 N3 Ag5 117.0(6) . . ?
C19 N3 Ag5 133.9(8) . . ?
C19 N3 N2 108.2(8) . . ?
N9 N5 Ag3 117.8(6) . . ?
C21 N5 Ag3 134.0(8) . . ?
C21 N5 N9 108.1(8) . . ?
N10 N8 Ag3 117.6(7) . . ?
N10 N8 C26 107.9(9) . . ?
C26 N8 Ag3 132.8(8) . . ?
N5 N9 Ag5 120.4(6) . . ?
N5 N9 C42 105.3(8) . . ?
C42 N9 Ag5 134.2(8) . . ?
N8 N10 Ag6 118.3(6) . . ?
C3 N10 Ag6 130.8(8) . . ?
C3 N10 N8 110.9(9) . . ?
N10 C3 C5 107.5(11) . . ?
N10 C3 C86 123.5(11) . . ?
C5 C3 C86 128.9(11) . . ?
C3 C5 H5 127.5 . . ?
C26 C5 C3 104.9(10) . . ?
C26 C5 H5 127.5 . . ?
N2 C9 C12 107.9(9) . . ?
N2 C9 C102 121.6(10) . . ?
C12 C9 C102 130.4(11) . . ?
F11 C11 C26 113.0(11) . . ?
F15 C11 F11 103.8(13) . . ?
F15 C11 F24 106.4(12) . . ?
F15 C11 C26 113.0(12) . . ?
F24 C11 F11 107.0(12) . . ?
F24 C11 C26 112.9(11) . . ?
C9 C12 H12 127.3 . . ?
C19 C12 C9 105.4(11) . . ?
C19 C12 H12 127.3 . . ?
F22 C15 F30 103.4(13) . . ?
F22 C15 C19 116.4(12) . . ?
F27 C15 F22 105.0(13) . . ?
F27 C15 F30 102.7(14) . . ?
F27 C15 C19 115.2(12) . . ?
F30 C15 C19 112.7(12) . . ?
N3 C19 C12 110.4(10) . . ?
N3 C19 C15 122.6(12) . . ?
C12 C19 C15 126.9(12) . . ?
N5 C21 C57 122.6(10) . . ?
N5 C21 C81 113.8(11) . . ?
C81 C21 C57 123.5(10) . . ?
N8 C26 C5 108.8(11) . . ?
N8 C26 C11 123.2(10) . . ?
C5 C26 C11 128.0(11) . . ?
N9 C42 C73 120.0(11) . . ?
N9 C42 C81 112.3(11) . . ?
C81 C42 C73 127.8(11) . . ?
F8 C57 F21 105.1(14) . . ?
F8 C57 F23 108.1(13) . . ?
F8 C57 C21 117.9(12) . . ?
F21 C57 F23 99.1(13) . . ?
F21 C57 C21 113.5(12) . . ?
F23 C57 C21 111.3(12) . . ?
F9 C73 F25 105.7(16) . . ?
F9 C73 C42 111.1(14) . . ?
F25 C73 C42 111.3(13) . . ?
F28 C73 F9 110.6(14) . . ?
F28 C73 F25 104.3(17) . . ?
F28 C73 C42 113.3(16) . . ?
C21 C81 H81 129.8 . . ?
C42 C81 C21 100.5(10) . . ?
C42 C81 H81 129.8 . . ?
F3 C86 F17 107.2(13) . . ?
F3 C86 C3 112.8(10) . . ?
F14 C86 F3 107.4(13) . . ?
F14 C86 F17 106.8(10) . . ?
F14 C86 C3 112.2(12) . . ?
F17 C86 C3 110.1(13) . . ?
F10 C102 F16 102.3(11) . . ?
F10 C102 C9 113.2(12) . . ?
F16 C102 C9 111.1(10) . . ?
F20 C102 F10 109.8(10) . . ?
F20 C102 F16 107.6(12) . . ?
F20 C102 C9 112.2(12) . . ?
C51 O1 C70 60.3(8) . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C62 C24 H24A 109.5 . . ?
C62 C24 H24B 109.5 . . ?
C62 C24 H24C 109.5 . . ?
C32 C31 H31 107.3 . . ?
C32 C31 C83 114.3(10) . . ?
C51 C31 H31 107.3 . . ?
C51 C31 C32 112.7(10) . . ?
C51 C31 C83 107.6(10) . . ?
C83 C31 H31 107.3 . . ?
C31 C32 H32 105.6 . . ?
C31 C32 C62 113.2(10) . . ?
C62 C32 H32 105.6 . . ?
C80 C32 C31 109.0(9) . . ?
C80 C32 H32 105.6 . . ?
C80 C32 C62 116.9(10) . . ?
O1 C51 C31 117.0(11) . . ?
O1 C51 C70 59.9(9) . . ?
O1 C51 C94 114.1(10) . . ?
C70 C51 C31 120.9(11) . . ?
C70 C51 C94 120.9(10) . . ?
C94 C51 C31 113.0(11) . . ?
H58A C58 H58B 109.5 . . ?
H58A C58 H58C 109.5 . . ?
H58B C58 H58C 109.5 . . ?
C70 C58 H58A 109.5 . . ?
C70 C58 H58B 109.5 . . ?
C70 C58 H58C 109.5 . . ?
C24 C62 C32 112.3(10) . . ?
C24 C62 H62 107.4 . . ?
C24 C62 C76 108.5(11) . . ?
C32 C62 H62 107.4 . . ?
C76 C62 C32 113.5(12) . . ?
C76 C62 H62 107.4 . . ?
O1 C70 C51 59.8(9) . . ?
O1 C70 C58 114.2(12) . . ?
O1 C70 C91 109.3(11) . . ?
C51 C70 C58 122.2(14) . . ?
C51 C70 C91 118.3(11) . . ?
C91 C70 C58 117.1(12) . . ?
H74A C74 H74B 108.3 . . ?
C85 C74 H74A 109.9 . . ?
C85 C74 H74B 109.9 . . ?
C85 C74 C95 108.7(17) . . ?
C95 C74 H74A 109.9 . . ?
C95 C74 H74B 109.9 . . ?
C62 C76 H76A 109.5 . . ?
C62 C76 H76B 109.5 . . ?
C62 C76 H76C 109.5 . . ?
H76A C76 H76B 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
C32 C80 H80A 108.9 . . ?
C32 C80 H80B 108.9 . . ?
C32 C80 C91 113.2(11) . . ?
H80A C80 H80B 107.8 . . ?
C91 C80 H80A 108.9 . . ?
C91 C80 H80B 108.9 . . ?
C31 C83 H83 105.1 . . ?
C31 C83 C110 116.2(11) . . ?
C85 C83 C31 117.0(10) . . ?
C85 C83 H83 105.1 . . ?
C85 C83 C110 107.0(11) . . ?
C110 C83 H83 105.1 . . ?
C74 C85 C83 111.4(12) . . ?
C106 C85 C74 123.0(14) . . ?
C106 C85 C83 125.5(14) . . ?
H90A C90 H90B 107.8 . . ?
C94 C90 H90A 109.0 . . ?
C94 C90 H90B 109.0 . . ?
C94 C90 C110 113.1(11) . . ?
C110 C90 H90A 109.0 . . ?
C110 C90 H90B 109.0 . . ?
C70 C91 H91A 108.1 . . ?
C70 C91 H91B 108.1 . . ?
C80 C91 C70 116.7(12) . . ?
C80 C91 H91A 108.1 . . ?
C80 C91 H91B 108.1 . . ?
H91A C91 H91B 107.3 . . ?
C51 C94 H94A 109.6 . . ?
C51 C94 H94B 109.6 . . ?
C90 C94 C51 110.3(13) . . ?
C90 C94 H94A 109.6 . . ?
C90 C94 H94B 109.6 . . ?
H94A C94 H94B 108.1 . . ?
C74 C95 H95A 109.8 . . ?
C74 C95 H95B 109.8 . . ?
C74 C95 C101 109.3(15) . . ?
H95A C95 H95B 108.3 . . ?
C101 C95 H95A 109.8 . . ?
C101 C95 H95B 109.8 . . ?
C95 C101 H10A 109.2 . . ?
C95 C101 H10B 109.2 . . ?
H10A C101 H10B 107.9 . . ?
C110 C101 C95 112.2(14) . . ?
C110 C101 H10A 109.2 . . ?
C110 C101 H10B 109.2 . . ?
H10C C103 H10D 109.5 . . ?
H10C C103 H10E 109.5 . . ?
H10D C103 H10E 109.5 . . ?
C110 C103 H10C 109.5 . . ?
C110 C103 H10D 109.5 . . ?
C110 C103 H10E 109.5 . . ?
C85 C106 H10F 120.0 . . ?
C85 C106 H10G 120.0 . . ?
H10F C106 H10G 120.0 . . ?
C90 C110 C83 107.8(11) . . ?
C101 C110 C83 106.5(13) . . ?
C101 C110 C90 107.7(12) . . ?
C103 C110 C83 110.4(13) . . ?
C103 C110 C90 110.4(15) . . ?
C103 C110 C101 113.8(14) . . ?
C30 O2 C39 60.0(7) . . ?
H2A C2 H2B 107.8 . . ?
C64 C2 H2A 109.0 . . ?
C64 C2 H2B 109.0 . . ?
C78 C2 H2A 109.0 . . ?
C78 C2 H2B 109.0 . . ?
C78 C2 C64 113.0(10) . . ?
H23A C23 H23B 108.1 . . ?
C30 C23 H23A 109.6 . . ?
C30 C23 H23B 109.6 . . ?
C30 C23 C104 110.2(10) . . ?
C104 C23 H23A 109.6 . . ?
C104 C23 H23B 109.6 . . ?
O2 C30 C23 113.3(9) . . ?
O2 C30 C39 60.5(8) . . ?
O2 C30 C65 114.0(9) . . ?
C23 C30 C65 114.0(9) . . ?
C39 C30 C23 120.6(9) . . ?
C39 C30 C65 121.8(9) . . ?
C63 C37 C56 125.8(13) . . ?
C63 C37 C96 123.7(13) . . ?
C96 C37 C56 110.4(12) . . ?
O2 C39 C64 111.4(10) . . ?
O2 C39 C92 113.3(11) . . ?
C30 C39 O2 59.5(8) . . ?
C30 C39 C64 120.2(10) . . ?
C30 C39 C92 122.2(11) . . ?
C92 C39 C64 115.3(11) . . ?
H40A C40 H40B 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C68 C40 H40A 109.5 . . ?
C68 C40 H40B 109.5 . . ?
C68 C40 H40C 109.5 . . ?
H53A C53 H53B 109.5 . . ?
H53A C53 H53C 109.5 . . ?
H53B C53 H53C 109.5 . . ?
C72 C53 H53A 109.5 . . ?
C72 C53 H53B 109.5 . . ?
C72 C53 H53C 109.5 . . ?
C37 C56 H56 105.9 . . ?
C37 C56 C65 115.3(10) . . ?
C37 C56 C68 107.8(9) . . ?
C65 C56 H56 105.9 . . ?
C68 C56 H56 105.9 . . ?
C68 C56 C65 115.3(9) . . ?
C37 C63 H63A 120.0 . . ?
C37 C63 H63B 120.0 . . ?
H63A C63 H63B 120.0 . . ?
C2 C64 H64A 108.6 . . ?
C2 C64 H64B 108.6 . . ?
C39 C64 C2 114.7(10) . . ?
C39 C64 H64A 108.6 . . ?
C39 C64 H64B 108.6 . . ?
H64A C64 H64B 107.6 . . ?
C30 C65 C56 108.2(9) . . ?
C30 C65 H65 107.9 . . ?
C56 C65 H65 107.9 . . ?
C78 C65 C30 112.6(9) . . ?
C78 C65 C56 112.1(8) . . ?
C78 C65 H65 107.9 . . ?
C40 C68 C56 110.4(11) . . ?
C104 C68 C40 109.1(11) . . ?
C104 C68 C56 110.4(10) . . ?
C105 C68 C40 110.2(12) . . ?
C105 C68 C56 108.0(11) . . ?
C105 C68 C104 108.7(11) . . ?
H69A C69 H69B 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
C72 C69 H69A 109.5 . . ?
C72 C69 H69B 109.5 . . ?
C72 C69 H69C 109.5 . . ?
C53 C72 C69 111.5(11) . . ?
C53 C72 H72 107.3 . . ?
C53 C72 C78 112.7(11) . . ?
C69 C72 H72 107.3 . . ?
C69 C72 C78 110.5(11) . . ?
C78 C72 H72 107.3 . . ?
C2 C78 C65 110.1(9) . . ?
C2 C78 C72 113.4(10) . . ?
C2 C78 H78 106.1 . . ?
C65 C78 C72 114.3(9) . . ?
C65 C78 H78 106.1 . . ?
C72 C78 H78 106.1 . . ?
C39 C92 H92A 109.5 . . ?
C39 C92 H92B 109.5 . . ?
C39 C92 H92C 109.5 . . ?
H92A C92 H92B 109.5 . . ?
H92A C92 H92C 109.5 . . ?
H92B C92 H92C 109.5 . . ?
C37 C96 H96A 109.4 . . ?
C37 C96 H96B 109.4 . . ?
C37 C96 C99 111.0(13) . . ?
H96A C96 H96B 108.0 . . ?
C99 C96 H96A 109.4 . . ?
C99 C96 H96B 109.4 . . ?
C96 C99 H99A 110.0 . . ?
C96 C99 H99B 110.0 . . ?
H99A C99 H99B 108.3 . . ?
C105 C99 C96 108.6(11) . . ?
C105 C99 H99A 110.0 . . ?
C105 C99 H99B 110.0 . . ?
C23 C104 H10H 109.2 . . ?
C23 C104 H10I 109.2 . . ?
C68 C104 C23 112.2(10) . . ?
C68 C104 H10H 109.2 . . ?
C68 C104 H10I 109.2 . . ?
H10H C104 H10I 107.9 . . ?
C68 C105 C99 116.0(13) . . ?
C68 C105 H10J 108.3 . . ?
C68 C105 H10K 108.3 . . ?
C99 C105 H10J 108.3 . . ?
C99 C105 H10K 108.3 . . ?
H10J C105 H10K 107.4 . . ?
C10 O3 C25 61.8(7) . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C10 C7 H7A 109.5 . . ?
C10 C7 H7B 109.5 . . ?
C10 C7 H7C 109.5 . . ?
O3 C10 C7 116.6(9) . . ?
O3 C10 C25 60.0(7) . . ?
O3 C10 C43 113.6(9) . . ?
C7 C10 C43 114.3(9) . . ?
C25 C10 C7 122.8(9) . . ?
C25 C10 C43 117.8(9) . . ?
C20 C16 H16 105.9 . . ?
C20 C16 C38 116.0(9) . . ?
C20 C16 C109 116.8(9) . . ?
C38 C16 H16 105.9 . . ?
C38 C16 C109 105.2(9) . . ?
C109 C16 H16 105.9 . . ?
C16 C20 H20 107.3 . . ?
C16 C20 C25 110.3(9) . . ?
C16 C20 C71 112.9(9) . . ?
C25 C20 H20 107.3 . . ?
C25 C20 C71 111.5(9) . . ?
C71 C20 H20 107.3 . . ?
O3 C25 C10 58.1(7) . . ?
O3 C25 C20 115.6(9) . . ?
O3 C25 C45 114.9(10) . . ?
C10 C25 C20 122.7(8) . . ?
C10 C25 C45 117.9(10) . . ?
C45 C25 C20 114.8(11) . . ?
H33B C33 H33A 107.5 . . ?
C43 C33 H33B 108.5 . . ?
C43 C33 H33A 108.5 . . ?
C43 C33 C71 115.0(9) . . ?
C71 C33 H33B 108.5 . . ?
C71 C33 H33A 108.5 . . ?
C44 C38 C16 125.8(11) . . ?
C44 C38 C67 120.5(11) . . ?
C67 C38 C16 113.4(10) . . ?
H41A C41 H41B 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?
C60 C41 H41A 109.5 . . ?
C60 C41 H41B 109.5 . . ?
C60 C41 H41C 109.5 . . ?
C10 C43 H43A 108.8 . . ?
C10 C43 H43B 108.8 . . ?
C33 C43 C10 114.0(10) . . ?
C33 C43 H43A 108.8 . . ?
C33 C43 H43B 108.8 . . ?
H43A C43 H43B 107.7 . . ?
C38 C44 H44A 120.0 . . ?
C38 C44 H44B 120.0 . . ?
H44A C44 H44B 120.0 . . ?
C25 C45 H45A 109.7 . . ?
C25 C45 H45B 109.7 . . ?
C25 C45 C88 109.8(11) . . ?
H45A C45 H45B 108.2 . . ?
C88 C45 H45A 109.7 . . ?
C88 C45 H45B 109.7 . . ?
C41 C60 H60 108.4 . . ?
C41 C60 C71 109.6(10) . . ?
C61 C60 C41 109.5(11) . . ?
C61 C60 H60 108.4 . . ?
C61 C60 C71 112.6(10) . . ?
C71 C60 H60 108.4 . . ?
C60 C61 H61A 109.5 . . ?
C60 C61 H61B 109.5 . . ?
C60 C61 H61C 109.5 . . ?
H61A C61 H61B 109.5 . . ?
H61A C61 H61C 109.5 . . ?
H61B C61 H61C 109.5 . . ?
C38 C67 H67A 109.3 . . ?
C38 C67 H67B 109.3 . . ?
C38 C67 C108 111.7(11) . . ?
H67A C67 H67B 107.9 . . ?
C108 C67 H67A 109.3 . . ?
C108 C67 H67B 109.3 . . ?
C20 C71 H71 106.5 . . ?
C33 C71 C20 107.4(9) . . ?
C33 C71 C60 115.2(9) . . ?
C33 C71 H71 106.5 . . ?
C60 C71 C20 114.2(8) . . ?
C60 C71 H71 106.5 . . ?
C45 C88 H88A 108.9 . . ?
C45 C88 H88B 108.9 . . ?
H88A C88 H88B 107.7 . . ?
C109 C88 C45 113.3(12) . . ?
C109 C88 H88A 108.9 . . ?
C109 C88 H88B 108.9 . . ?
H98A C98 H98B 109.5 . . ?
H98A C98 H98C 109.5 . . ?
H98B C98 H98C 109.5 . . ?
C109 C98 H98A 109.5 . . ?
C109 C98 H98B 109.5 . . ?
C109 C98 H98C 109.5 . . ?
H10L C107 H10M 107.8 . . ?
C108 C107 H10L 109.1 . . ?
C108 C107 H10M 109.1 . . ?
C108 C107 C109 112.6(12) . . ?
C109 C107 H10L 109.1 . . ?
C109 C107 H10M 109.1 . . ?
C67 C108 C107 110.3(13) . . ?
C67 C108 H10N 109.6 . . ?
C67 C108 H10O 109.6 . . ?
C107 C108 H10N 109.6 . . ?
C107 C108 H10O 109.6 . . ?
H10N C108 H10O 108.1 . . ?
C88 C109 C16 107.4(11) . . ?
C88 C109 C107 107.7(13) . . ?
C98 C109 C16 112.5(13) . . ?
C98 C109 C88 111.7(12) . . ?
C98 C109 C107 112.2(14) . . ?
C107 C109 C16 105.0(10) . . ?
C34 O4 C100 61.2(7) . . ?
C14 C1 H1 108.0 . . ?
C14 C1 C47 110.1(11) . . ?
C14 C1 C48 112.1(10) . . ?
C47 C1 H1 108.0 . . ?
C47 C1 C48 110.4(10) . . ?
C48 C1 H1 108.0 . . ?
H4A C4 H4B 120.0 . . ?
C6 C4 H4A 120.0 . . ?
C6 C4 H4B 120.0 . . ?
C4 C6 C8 125.6(10) . . ?
C4 C6 C54 122.2(11) . . ?
C54 C6 C8 111.8(9) . . ?
C6 C8 H8 105.3 . . ?
C6 C8 C29 116.5(9) . . ?
C6 C8 C36 107.4(8) . . ?
C29 C8 H8 105.3 . . ?
C29 C8 C36 115.7(9) . . ?
C36 C8 H8 105.3 . . ?
C1 C14 H14A 109.5 . . ?
C1 C14 H14B 109.5 . . ?
C1 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
H27A C27 H27B 107.9 . . ?
C48 C27 H27A 109.2 . . ?
C48 C27 H27B 109.2 . . ?
C52 C27 H27A 109.2 . . ?
C52 C27 H27B 109.2 . . ?
C52 C27 C48 112.0(10) . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C36 C28 H28A 109.5 . . ?
C36 C28 H28B 109.5 . . ?
C36 C28 H28C 109.5 . . ?
C8 C29 H29 107.7 . . ?
C34 C29 C8 107.7(9) . . ?
C34 C29 H29 107.7 . . ?
C34 C29 C48 113.5(9) . . ?
C48 C29 C8 112.3(9) . . ?
C48 C29 H29 107.7 . . ?
O4 C34 C29 116.0(9) . . ?
O4 C34 C35 112.5(10) . . ?
O4 C34 C100 59.5(7) . . ?
C29 C34 C35 114.9(9) . . ?
C100 C34 C29 121.7(11) . . ?
C100 C34 C35 119.3(11) . . ?
C34 C35 H35A 109.5 . . ?
C34 C35 H35B 109.5 . . ?
H35A C35 H35B 108.1 . . ?
C49 C35 C34 110.8(10) . . ?
C49 C35 H35A 109.5 . . ?
C49 C35 H35B 109.5 . . ?
C28 C36 C8 110.7(9) . . ?
C28 C36 C50 109.7(9) . . ?
C49 C36 C8 109.0(8) . . ?
C49 C36 C28 109.9(10) . . ?
C49 C36 C50 108.7(9) . . ?
C50 C36 C8 108.8(9) . . ?
C1 C47 H47A 109.5 . . ?
C1 C47 H47B 109.5 . . ?
C1 C47 H47C 109.5 . . ?
H47A C47 H47B 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C1 C48 H48 106.2 . . ?
C27 C48 C1 113.5(9) . . ?
C27 C48 H48 106.2 . . ?
C29 C48 C1 115.2(9) . . ?
C29 C48 C27 108.9(9) . . ?
C29 C48 H48 106.2 . . ?
C35 C49 C36 112.9(10) . . ?
C35 C49 H49A 109.0 . . ?
C35 C49 H49B 109.0 . . ?
C36 C49 H49A 109.0 . . ?
C36 C49 H49B 109.0 . . ?
H49A C49 H49B 107.8 . . ?
C36 C50 H50A 109.4 . . ?
C36 C50 H50B 109.4 . . ?
C36 C50 C89 111.3(11) . . ?
H50A C50 H50B 108.0 . . ?
C89 C50 H50A 109.4 . . ?
C89 C50 H50B 109.4 . . ?
C27 C52 H52A 108.4 . . ?
C27 C52 H52B 108.4 . . ?
C27 C52 C100 115.7(10) . . ?
H52A C52 H52B 107.4 . . ?
C100 C52 H52A 108.4 . . ?
C100 C52 H52B 108.4 . . ?
C6 C54 H54A 109.6 . . ?
C6 C54 H54B 109.6 . . ?
H54A C54 H54B 108.1 . . ?
C89 C54 C6 110.1(10) . . ?
C89 C54 H54A 109.6 . . ?
C89 C54 H54B 109.6 . . ?
H77A C77 H77B 109.5 . . ?
H77A C77 H77C 109.5 . . ?
H77B C77 H77C 109.5 . . ?
C100 C77 H77A 109.5 . . ?
C100 C77 H77B 109.5 . . ?
C100 C77 H77C 109.5 . . ?
C50 C89 H89A 109.5 . . ?
C50 C89 H89B 109.5 . . ?
C54 C89 C50 110.5(11) . . ?
C54 C89 H89A 109.5 . . ?
C54 C89 H89B 109.5 . . ?
H89A C89 H89B 108.1 . . ?
O4 C100 C34 59.3(7) . . ?
O4 C100 C52 113.2(11) . . ?
C34 C100 C52 117.6(11) . . ?
C77 C100 O4 116.0(11) . . ?
C77 C100 C34 123.9(13) . . ?
C77 C100 C52 114.4(11) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 N1 N4 Ag4 -8.6(10) . . . . ?
Ag1 N1 N4 C17 176.9(7) . . . . ?
Ag1 N1 C22 C13 5.2(16) . . . . ?
Ag1 N1 C22 C55 -177.8(8) . . . . ?
Ag1 N11 C66 C75 -12.4(16) . . . . ?
Ag1 N11 C66 C87 171.2(8) . . . . ?
Ag2 N6 N11 Ag1 18.4(10) . . . . ?
Ag2 N6 N11 C66 -169.1(7) . . . . ?
Ag2 N6 C93 C79 -11.7(16) . . . . ?
Ag2 N6 C93 C87 165.7(8) . . . . ?
Ag2 N12 C84 C59 -176.6(9) . . . . ?
Ag2 N12 C84 C82 -2.1(18) . . . . ?
Ag4 N4 C17 C18 10.9(16) . . . . ?
Ag4 N4 C17 C55 -170.2(8) . . . . ?
Ag4 N7 N12 Ag2 -9.1(9) . . . . ?
Ag4 N7 N12 C84 172.5(7) . . . . ?
Ag4 N7 C46 C59 -171.8(9) . . . . ?
Ag4 N7 C46 C97 4.7(18) . . . . ?
F5 C13 C22 N1 -149.4(10) . . . . ?
F5 C13 C22 C55 34.3(16) . . . . ?
F7 C13 C22 N1 87.2(13) . . . . ?
F7 C13 C22 C55 -89.1(14) . . . . ?
F18 C82 C84 N12 150.1(13) . . . . ?
F18 C82 C84 C59 -37(2) . . . . ?
F19 C13 C22 N1 -32.1(15) . . . . ?
F19 C13 C22 C55 151.6(11) . . . . ?
F26 C79 C93 N6 -45(2) . . . . ?
F26 C79 C93 C87 137.8(16) . . . . ?
F29 C82 C84 N12 -88(2) . . . . ?
F29 C82 C84 C59 85(2) . . . . ?
F32 C82 C84 N12 35.2(18) . . . . ?
F32 C82 C84 C59 -151.6(15) . . . . ?
F33 C79 C93 N6 -152.7(14) . . . . ?
F33 C79 C93 C87 30(2) . . . . ?
F34 C79 C93 N6 82.9(16) . . . . ?
F34 C79 C93 C87 -94.0(18) . . . . ?
N1 N4 C17 C18 -175.9(10) . . . . ?
N1 N4 C17 C55 3.0(12) . . . . ?
N1 C22 C55 C17 -0.7(12) . . . . ?
N4 N1 C22 C13 -174.4(9) . . . . ?
N4 N1 C22 C55 2.5(12) . . . . ?
N4 C17 C18 F1 -162.4(10) . . . . ?
N4 C17 C18 F2 77.2(14) . . . . ?
N4 C17 C18 F4 -43.1(15) . . . . ?
N4 C17 C55 C22 -1.4(12) . . . . ?
N6 N11 C66 C75 176.1(10) . . . . ?
N6 N11 C66 C87 -0.3(12) . . . . ?
N7 N12 C84 C59 1.5(13) . . . . ?
N7 N12 C84 C82 176.0(11) . . . . ?
N7 C46 C59 C84 0.7(15) . . . . ?
N7 C46 C97 F31 177.0(13) . . . . ?
N7 C46 C97 F35 53(2) . . . . ?
N7 C46 C97 F36 -64.2(19) . . . . ?
N11 N6 C93 C79 178.9(10) . . . . ?
N11 N6 C93 C87 -3.7(12) . . . . ?
N11 C66 C75 F6 53.4(16) . . . . ?
N11 C66 C75 F12 175.3(11) . . . . ?
N11 C66 C75 F13 -65.5(14) . . . . ?
N11 C66 C87 C93 -1.8(13) . . . . ?
N12 N7 C46 C59 0.2(13) . . . . ?
N12 N7 C46 C97 176.6(11) . . . . ?
C13 C22 C55 C17 175.9(11) . . . . ?
C18 C17 C55 C22 177.4(12) . . . . ?
C22 N1 N4 Ag4 171.1(7) . . . . ?
C22 N1 N4 C17 -3.4(12) . . . . ?
C46 N7 N12 Ag2 177.4(7) . . . . ?
C46 N7 N12 C84 -1.1(12) . . . . ?
C46 C59 C84 N12 -1.3(14) . . . . ?
C46 C59 C84 C82 -175.3(13) . . . . ?
C55 C17 C18 F1 18.9(17) . . . . ?
C55 C17 C18 F2 -101.5(15) . . . . ?
C55 C17 C18 F4 138.1(12) . . . . ?
C59 C46 C97 F31 -7(2) . . . . ?
C59 C46 C97 F35 -131.1(18) . . . . ?
C59 C46 C97 F36 111.4(19) . . . . ?
C66 C87 C93 N6 3.4(13) . . . . ?
C66 C87 C93 C79 -179.5(12) . . . . ?
C75 C66 C87 C93 -177.8(12) . . . . ?
C87 C66 C75 F6 -131.1(13) . . . . ?
C87 C66 C75 F12 -9.2(19) . . . . ?
C87 C66 C75 F13 110.0(14) . . . . ?
C93 N6 N11 Ag1 -170.1(7) . . . . ?
C93 N6 N11 C66 2.4(11) . . . . ?
C97 C46 C59 C84 -175.4(13) . . . . ?
Ag3 N5 N9 Ag5 -3.9(11) . . . . ?
Ag3 N5 N9 C42 178.8(8) . . . . ?
Ag3 N5 C21 C57 1.8(19) . . . . ?
Ag3 N5 C21 C81 -179.2(10) . . . . ?
Ag3 N8 N10 Ag6 -13.2(10) . . . . ?
Ag3 N8 N10 C3 167.8(7) . . . . ?
Ag3 N8 C26 C5 -164.7(9) . . . . ?
Ag3 N8 C26 C11 14.7(18) . . . . ?
Ag5 N3 C19 C12 168.3(8) . . . . ?
Ag5 N3 C19 C15 -9.9(19) . . . . ?
Ag5 N9 C42 C73 3.2(19) . . . . ?
Ag5 N9 C42 C81 -176.3(9) . . . . ?
Ag6 N2 N3 Ag5 12.5(10) . . . . ?
Ag6 N2 N3 C19 -176.6(7) . . . . ?
Ag6 N2 C9 C12 176.2(7) . . . . ?
Ag6 N2 C9 C102 -2.8(16) . . . . ?
Ag6 N10 C3 C5 -179.7(8) . . . . ?
Ag6 N10 C3 C86 2.8(17) . . . . ?
F11 C11 C26 N8 174.4(12) . . . . ?
F11 C11 C26 C5 -6.3(19) . . . . ?
F15 C11 C26 N8 56.8(16) . . . . ?
F15 C11 C26 C5 -123.9(15) . . . . ?
F22 C15 C19 N3 177.5(13) . . . . ?
F22 C15 C19 C12 0(2) . . . . ?
F24 C11 C26 N8 -64.0(17) . . . . ?
F24 C11 C26 C5 115.3(15) . . . . ?
F27 C15 C19 N3 54(2) . . . . ?
F27 C15 C19 C12 -123.9(16) . . . . ?
F30 C15 C19 N3 -63.3(17) . . . . ?
F30 C15 C19 C12 118.8(15) . . . . ?
N2 N3 C19 C12 -0.5(13) . . . . ?
N2 N3 C19 C15 -178.7(11) . . . . ?
N2 C9 C12 C19 0.3(12) . . . . ?
N2 C9 C102 F10 53.2(15) . . . . ?
N2 C9 C102 F16 -61.3(16) . . . . ?
N2 C9 C102 F20 178.2(11) . . . . ?
N3 N2 C9 C12 -0.6(11) . . . . ?
N3 N2 C9 C102 -179.6(10) . . . . ?
N5 N9 C42 C73 179.9(12) . . . . ?
N5 N9 C42 C81 0.4(14) . . . . ?
N5 C21 C57 F8 -163.0(14) . . . . ?
N5 C21 C57 F21 -39.5(19) . . . . ?
N5 C21 C57 F23 71.3(17) . . . . ?
N5 C21 C81 C42 1.3(16) . . . . ?
N8 N10 C3 C5 -0.9(13) . . . . ?
N8 N10 C3 C86 -178.5(11) . . . . ?
N9 N5 C21 C57 179.9(12) . . . . ?
N9 N5 C21 C81 -1.1(15) . . . . ?
N9 C42 C73 F9 156.8(13) . . . . ?
N9 C42 C73 F25 39(2) . . . . ?
N9 C42 C73 F28 -77.9(18) . . . . ?
N9 C42 C81 C21 -1.0(15) . . . . ?
N10 N8 C26 C5 -0.7(13) . . . . ?
N10 N8 C26 C11 178.8(11) . . . . ?
N10 C3 C5 C26 0.5(13) . . . . ?
N10 C3 C86 F3 35.5(18) . . . . ?
N10 C3 C86 F14 157.0(11) . . . . ?
N10 C3 C86 F17 -84.2(14) . . . . ?
C3 C5 C26 N8 0.1(14) . . . . ?
C3 C5 C26 C11 -179.3(12) . . . . ?
C5 C3 C86 F3 -141.5(13) . . . . ?
C5 C3 C86 F14 -20.0(19) . . . . ?
C5 C3 C86 F17 98.8(16) . . . . ?
C9 N2 N3 Ag5 -170.3(7) . . . . ?
C9 N2 N3 C19 0.7(12) . . . . ?
C9 C12 C19 N3 0.1(13) . . . . ?
C9 C12 C19 C15 178.3(12) . . . . ?
C12 C9 C102 F10 -125.6(14) . . . . ?
C12 C9 C102 F16 119.9(14) . . . . ?
C12 C9 C102 F20 -0.6(19) . . . . ?
C21 N5 N9 Ag5 177.7(8) . . . . ?
C21 N5 N9 C42 0.4(13) . . . . ?
C26 N8 N10 Ag6 179.9(7) . . . . ?
C26 N8 N10 C3 1.0(12) . . . . ?
C57 C21 C81 C42 -179.7(13) . . . . ?
C73 C42 C81 C21 179.6(15) . . . . ?
C81 C21 C57 F8 18(2) . . . . ?
C81 C21 C57 F21 141.6(14) . . . . ?
C81 C21 C57 F23 -107.6(15) . . . . ?
C81 C42 C73 F9 -24(2) . . . . ?
C81 C42 C73 F25 -141.3(17) . . . . ?
C81 C42 C73 F28 101.5(18) . . . . ?
C86 C3 C5 C26 177.9(12) . . . . ?
C102 C9 C12 C19 179.2(12) . . . . ?
O1 C51 C70 C58 101.2(14) . . . . ?
O1 C51 C70 C91 -96.9(12) . . . . ?
O1 C51 C94 C90 -162.1(10) . . . . ?
O1 C70 C91 C80 -81.0(14) . . . . ?
C31 C32 C62 C24 -68.2(12) . . . . ?
C31 C32 C62 C76 168.3(10) . . . . ?
C31 C32 C80 C91 -60.5(14) . . . . ?
C31 C51 C70 O1 105.3(14) . . . . ?
C31 C51 C70 C58 -153.5(13) . . . . ?
C31 C51 C70 C91 8.4(19) . . . . ?
C31 C51 C94 C90 60.9(14) . . . . ?
C31 C83 C85 C74 162.4(13) . . . . ?
C31 C83 C85 C106 -21(2) . . . . ?
C31 C83 C110 C90 -50.1(14) . . . . ?
C31 C83 C110 C101 -165.4(11) . . . . ?
C31 C83 C110 C103 70.6(15) . . . . ?
C32 C31 C51 O1 42.6(14) . . . . ?
C32 C31 C51 C70 -26.8(17) . . . . ?
C32 C31 C51 C94 178.2(11) . . . . ?
C32 C31 C83 C85 -54.6(14) . . . . ?
C32 C31 C83 C110 177.3(9) . . . . ?
C32 C80 C91 C70 43.0(17) . . . . ?
C51 O1 C70 C58 -114.5(15) . . . . ?
C51 O1 C70 C91 112.2(11) . . . . ?
C51 C31 C32 C62 -80.2(11) . . . . ?
C51 C31 C32 C80 51.6(13) . . . . ?
C51 C31 C83 C85 179.4(12) . . . . ?
C51 C31 C83 C110 51.3(13) . . . . ?
C51 C70 C91 C80 -15.6(18) . . . . ?
C58 C70 C91 C80 147.2(13) . . . . ?
C62 C32 C80 C91 69.3(14) . . . . ?
C70 O1 C51 C31 -111.8(13) . . . . ?
C70 O1 C51 C94 113.0(12) . . . . ?
C70 C51 C94 C90 -94.0(15) . . . . ?
C74 C95 C101 C110 58(2) . . . . ?
C80 C32 C62 C24 163.9(10) . . . . ?
C80 C32 C62 C76 40.4(13) . . . . ?
C83 C31 C32 C62 156.4(8) . . . . ?
C83 C31 C32 C80 -71.7(11) . . . . ?
C83 C31 C51 O1 169.6(10) . . . . ?
C83 C31 C51 C70 100.1(14) . . . . ?
C83 C31 C51 C94 -54.8(14) . . . . ?
C85 C74 C95 C101 -56(2) . . . . ?
C85 C83 C110 C90 177.1(12) . . . . ?
C85 C83 C110 C101 61.7(14) . . . . ?
C85 C83 C110 C103 -62.3(17) . . . . ?
C94 C51 C70 O1 -101.7(13) . . . . ?
C94 C51 C70 C58 0(2) . . . . ?
C94 C51 C70 C91 161.4(13) . . . . ?
C94 C90 C110 C83 53.1(16) . . . . ?
C94 C90 C110 C101 167.7(14) . . . . ?
C94 C90 C110 C103 -67.5(17) . . . . ?
C95 C74 C85 C83 62.6(19) . . . . ?
C95 C74 C85 C106 -114(2) . . . . ?
C95 C101 C110 C83 -60.0(18) . . . . ?
C95 C101 C110 C90 -175.4(16) . . . . ?
C95 C101 C110 C103 62(2) . . . . ?
C110 C83 C85 C74 -65.2(17) . . . . ?
C110 C83 C85 C106 111.6(19) . . . . ?
C110 C90 C94 C51 -59.5(16) . . . . ?
O2 C30 C39 C64 -98.5(12) . . . . ?
O2 C30 C39 C92 99.9(13) . . . . ?
O2 C30 C65 C56 173.8(9) . . . . ?
O2 C30 C65 C78 49.4(13) . . . . ?
O2 C39 C64 C2 -81.1(13) . . . . ?
C23 C30 C39 O2 -101.2(11) . . . . ?
C23 C30 C39 C64 160.3(11) . . . . ?
C23 C30 C39 C92 -1.3(19) . . . . ?
C23 C30 C65 C56 -53.9(13) . . . . ?
C23 C30 C65 C78 -178.3(10) . . . . ?
C30 O2 C39 C64 113.3(10) . . . . ?
C30 O2 C39 C92 -114.8(12) . . . . ?
C30 C23 C104 C68 -57.8(14) . . . . ?
C30 C39 C64 C2 -14.8(17) . . . . ?
C30 C65 C78 C2 47.1(12) . . . . ?
C30 C65 C78 C72 -81.8(12) . . . . ?
C37 C56 C65 C30 176.1(10) . . . . ?
C37 C56 C65 C78 -59.2(13) . . . . ?
C37 C56 C68 C40 -60.1(14) . . . . ?
C37 C56 C68 C104 179.1(12) . . . . ?
C37 C56 C68 C105 60.4(14) . . . . ?
C37 C96 C99 C105 -51.1(19) . . . . ?
C39 O2 C30 C23 113.2(11) . . . . ?
C39 O2 C30 C65 -114.3(11) . . . . ?
C39 C30 C65 C56 104.8(12) . . . . ?
C39 C30 C65 C78 -19.6(16) . . . . ?
C40 C68 C104 C23 -68.6(14) . . . . ?
C40 C68 C105 C99 64.9(17) . . . . ?
C53 C72 C78 C2 170.8(10) . . . . ?
C53 C72 C78 C65 -61.9(12) . . . . ?
C56 C37 C96 C99 61.4(16) . . . . ?
C56 C65 C78 C2 -75.1(11) . . . . ?
C56 C65 C78 C72 155.9(9) . . . . ?
C56 C68 C104 C23 52.9(15) . . . . ?
C56 C68 C105 C99 -55.7(17) . . . . ?
C63 C37 C56 C65 -18.7(19) . . . . ?
C63 C37 C56 C68 111.6(16) . . . . ?
C63 C37 C96 C99 -116.2(16) . . . . ?
C64 C2 C78 C65 -61.0(12) . . . . ?
C64 C2 C78 C72 68.5(12) . . . . ?
C65 C30 C39 O2 101.5(11) . . . . ?
C65 C30 C39 C64 3.0(18) . . . . ?
C65 C30 C39 C92 -158.7(12) . . . . ?
C65 C56 C68 C40 70.3(13) . . . . ?
C65 C56 C68 C104 -50.5(15) . . . . ?
C65 C56 C68 C105 -169.2(10) . . . . ?
C68 C56 C65 C30 49.4(13) . . . . ?
C68 C56 C65 C78 174.2(10) . . . . ?
C69 C72 C78 C2 45.3(12) . . . . ?
C69 C72 C78 C65 172.5(10) . . . . ?
C78 C2 C64 C39 44.2(15) . . . . ?
C92 C39 C64 C2 148.0(12) . . . . ?
C96 C37 C56 C65 163.8(11) . . . . ?
C96 C37 C56 C68 -65.9(14) . . . . ?
C96 C99 C105 C68 50(2) . . . . ?
C104 C23 C30 O2 -168.5(9) . . . . ?
C104 C23 C30 C39 -100.0(13) . . . . ?
C104 C23 C30 C65 59.0(13) . . . . ?
C104 C68 C105 C99 -175.5(13) . . . . ?
C105 C68 C104 C23 171.2(12) . . . . ?
O3 C10 C25 C20 101.9(11) . . . . ?
O3 C10 C25 C45 -103.5(12) . . . . ?
O3 C10 C43 C33 -78.4(13) . . . . ?
O3 C25 C45 C88 -167.9(11) . . . . ?
C7 C10 C25 O3 104.1(11) . . . . ?
C7 C10 C25 C20 -154.0(11) . . . . ?
C7 C10 C25 C45 0.6(17) . . . . ?
C7 C10 C43 C33 144.4(11) . . . . ?
C10 O3 C25 C20 -114.0(9) . . . . ?
C10 O3 C25 C45 108.6(12) . . . . ?
C10 C25 C45 C88 -102.3(13) . . . . ?
C16 C20 C25 O3 173.7(8) . . . . ?
C16 C20 C25 C10 106.5(11) . . . . ?
C16 C20 C25 C45 -48.8(13) . . . . ?
C16 C20 C71 C33 -75.1(12) . . . . ?
C16 C20 C71 C60 155.9(10) . . . . ?
C16 C38 C67 C108 58.9(13) . . . . ?
C20 C16 C38 C44 -23.6(14) . . . . ?
C20 C16 C38 C67 163.2(9) . . . . ?
C20 C16 C109 C88 -51.2(14) . . . . ?
C20 C16 C109 C98 72.1(15) . . . . ?
C20 C16 C109 C107 -165.6(11) . . . . ?
C20 C25 C45 C88 54.3(15) . . . . ?
C25 O3 C10 C7 -114.2(11) . . . . ?
C25 O3 C10 C43 109.6(11) . . . . ?
C25 C10 C43 C33 -11.1(15) . . . . ?
C25 C20 C71 C33 49.8(12) . . . . ?
C25 C20 C71 C60 -79.2(12) . . . . ?
C25 C45 C88 C109 -59.3(15) . . . . ?
C38 C16 C20 C25 172.3(8) . . . . ?
C38 C16 C20 C71 -62.2(12) . . . . ?
C38 C16 C109 C88 178.4(11) . . . . ?
C38 C16 C109 C98 -58.3(15) . . . . ?
C38 C16 C109 C107 64.0(12) . . . . ?
C38 C67 C108 C107 -49.5(15) . . . . ?
C41 C60 C71 C20 176.4(11) . . . . ?
C41 C60 C71 C33 51.4(14) . . . . ?
C43 C10 C25 O3 -102.6(11) . . . . ?
C43 C10 C25 C20 -0.6(16) . . . . ?
C43 C10 C25 C45 154.0(12) . . . . ?
C43 C33 C71 C20 -66.2(13) . . . . ?
C43 C33 C71 C60 62.2(12) . . . . ?
C44 C38 C67 C108 -114.7(13) . . . . ?
C45 C88 C109 C16 55.4(14) . . . . ?
C45 C88 C109 C98 -68.3(16) . . . . ?
C45 C88 C109 C107 168.0(11) . . . . ?
C61 C60 C71 C20 -61.5(13) . . . . ?
C61 C60 C71 C33 173.5(9) . . . . ?
C71 C20 C25 O3 47.4(12) . . . . ?
C71 C20 C25 C10 -19.8(15) . . . . ?
C71 C20 C25 C45 -175.1(11) . . . . ?
C71 C33 C43 C10 45.9(14) . . . . ?
C108 C107 C109 C16 -61.2(14) . . . . ?
C108 C107 C109 C88 -175.5(11) . . . . ?
C108 C107 C109 C98 61.2(16) . . . . ?
C109 C16 C20 C25 47.2(12) . . . . ?
C109 C16 C20 C71 172.7(10) . . . . ?
C109 C16 C38 C44 107.2(13) . . . . ?
C109 C16 C38 C67 -66.0(11) . . . . ?
C109 C107 C108 C67 53.7(16) . . . . ?
O4 C34 C35 C49 -166.1(9) . . . . ?
O4 C34 C100 C52 -101.9(12) . . . . ?
O4 C34 C100 C77 102.4(14) . . . . ?
C4 C6 C8 C29 -23.2(15) . . . . ?
C4 C6 C8 C36 108.5(12) . . . . ?
C4 C6 C54 C89 -109.3(13) . . . . ?
C6 C8 C29 C34 176.5(8) . . . . ?
C6 C8 C29 C48 -57.8(11) . . . . ?
C6 C8 C36 C28 -61.6(11) . . . . ?
C6 C8 C36 C49 177.4(8) . . . . ?
C6 C8 C36 C50 59.0(10) . . . . ?
C6 C54 C89 C50 -55.9(13) . . . . ?
C8 C6 C54 C89 63.7(12) . . . . ?
C8 C29 C34 O4 174.3(8) . . . . ?
C8 C29 C34 C35 -51.6(11) . . . . ?
C8 C29 C34 C100 105.4(11) . . . . ?
C8 C29 C48 C1 157.6(9) . . . . ?
C8 C29 C48 C27 -73.6(11) . . . . ?
C8 C36 C49 C35 54.2(11) . . . . ?
C8 C36 C50 C89 -54.6(11) . . . . ?
C14 C1 C48 C27 176.0(11) . . . . ?
C14 C1 C48 C29 -57.5(14) . . . . ?
C27 C52 C100 O4 -81.6(13) . . . . ?
C27 C52 C100 C34 -15.4(16) . . . . ?
C27 C52 C100 C77 142.6(12) . . . . ?
C28 C36 C49 C35 -67.2(12) . . . . ?
C28 C36 C50 C89 66.6(13) . . . . ?
C29 C8 C36 C28 70.5(12) . . . . ?
C29 C8 C36 C49 -50.5(10) . . . . ?
C29 C8 C36 C50 -168.9(9) . . . . ?
C29 C34 C35 C49 58.2(12) . . . . ?
C29 C34 C100 O4 103.6(11) . . . . ?
C29 C34 C100 C52 1.7(16) . . . . ?
C29 C34 C100 C77 -154.0(12) . . . . ?
C34 O4 C100 C52 109.4(12) . . . . ?
C34 O4 C100 C77 -115.6(14) . . . . ?
C34 C29 C48 C1 -79.9(11) . . . . ?
C34 C29 C48 C27 48.9(12) . . . . ?
C34 C35 C49 C36 -58.4(12) . . . . ?
C35 C34 C100 O4 -100.4(12) . . . . ?
C35 C34 C100 C52 157.8(11) . . . . ?
C35 C34 C100 C77 2.0(18) . . . . ?
C36 C8 C29 C34 48.7(10) . . . . ?
C36 C8 C29 C48 174.5(8) . . . . ?
C36 C50 C89 C54 53.5(13) . . . . ?
C47 C1 C48 C27 52.9(14) . . . . ?
C47 C1 C48 C29 179.4(10) . . . . ?
C48 C27 C52 C100 46.9(15) . . . . ?
C48 C29 C34 O4 49.3(12) . . . . ?
C48 C29 C34 C35 -176.6(9) . . . . ?
C48 C29 C34 C100 -19.5(14) . . . . ?
C49 C36 C50 C89 -173.1(9) . . . . ?
C50 C36 C49 C35 172.7(9) . . . . ?
C52 C27 C48 C1 65.9(14) . . . . ?
C52 C27 C48 C29 -63.9(13) . . . . ?
C54 C6 C8 C29 164.1(8) . . . . ?
C54 C6 C8 C36 -64.1(10) . . . . ?
C100 O4 C34 C29 -113.0(12) . . . . ?
C100 O4 C34 C35 111.8(11) . . . . ?
C100 C34 C35 C49 -99.4(12) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.948(9)
2 0.052(9)

# start Validation Reply Form
_vrf_PLAT973_cu_20240489_0m      
;
PROBLEM: Check Calcd Positive Resid. Density on Ag6 1.85 eA-3 
RESPONSE: Ag is a heavy atom and this alert is often found for molecules of 
this type.
;
# end Validation Reply Form
