# Supplementary Information (SI) for Organic & Biomolecular Chemistry.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_240703sf_zgk
_database_code_depnum_ccdc_archive 'CCDC 2479112'
loop_
_audit_author_name
_audit_author_address
'Y.-C. Zhang Zhang'
;Jiangsu Normal University 
China
;
_audit_update_record             
;
2025-08-08 deposited with the CCDC.	2025-09-25 downloaded from the CCDC.
;
_audit_creation_date             2024-07-03
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C33 H25 O2 P'
_chemical_formula_sum            'C33 H25 O2 P'
_chemical_formula_weight         484.50
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2543 0.3332 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.3252(2)
_cell_length_b                   14.4115(3)
_cell_length_c                   17.2540(3)
_cell_angle_alpha                90
_cell_angle_beta                 101.6140(10)
_cell_angle_gamma                90
_cell_volume                     2514.86(8)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9871
_cell_measurement_temperature    170.00
_cell_measurement_theta_max      54.944
_cell_measurement_theta_min      3.507
_shelx_estimated_absorpt_T_max   0.962
_shelx_estimated_absorpt_T_min   0.880
_exptl_absorpt_coefficient_mu    0.771
_exptl_absorpt_correction_T_max  0.7508
_exptl_absorpt_correction_T_min  0.5904
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1403 before and 0.0684 after correction.
The Ratio of minimum to maximum transmission is 0.7864.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.280
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1016
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.05
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0569
_diffrn_reflns_av_unetI/netI     0.0332
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            29733
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         54.940
_diffrn_reflns_theta_min         3.506
_diffrn_ambient_temperature      170.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker D8 Venture'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34139
_diffrn_source                   ?
_diffrn_source_current           2.86
_diffrn_source_power             0.1995708
_diffrn_source_voltage           69.78
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4103
_reflns_number_total             4771
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.297
_refine_diff_density_min         -0.478
_refine_diff_density_rms         0.046
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.063
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     325
_refine_ls_number_reflns         4771
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0460
_refine_ls_R_factor_gt           0.0380
_refine_ls_restrained_S_all      1.063
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0526P)²+0.9136P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0992
_refine_ls_wR_factor_ref         0.1051
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Ternary CH refined with riding coordinates:
 C9(H9)
2.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C6(H6), C11(H11), C12(H12), C13(H13), C14(H14),
 C15(H15), C17(H17), C18(H18), C19(H19), C20(H20), C21(H21), C23(H23), C24(H24),
  C25(H25), C26(H26), C27(H27), C29(H29), C30(H30), C31(H31), C32(H32), C33(H33)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.41908(4) 0.69788(3) 0.64888(2) 0.02039(12) Uani 1 1 d . . . . .
O1 O 0.42516(10) 0.52479(7) 0.75862(6) 0.0250(2) Uani 1 1 d . . . . .
O2 O 0.42970(11) 0.79523(7) 0.67793(6) 0.0282(3) Uani 1 1 d . . . . .
C1 C 0.54366(15) 0.55240(10) 0.74046(8) 0.0213(3) Uani 1 1 d . . . . .
C2 C 0.55594(15) 0.62558(10) 0.68996(8) 0.0216(3) Uani 1 1 d . . . . .
C3 C 0.68276(16) 0.64437(11) 0.67524(9) 0.0271(3) Uani 1 1 d . . . . .
H3 H 0.693965 0.693484 0.640460 0.032 Uiso 1 1 calc R U . . .
C4 C 0.79071(16) 0.59253(12) 0.71055(9) 0.0300(4) Uani 1 1 d . . . . .
H4 H 0.875635 0.606091 0.700167 0.036 Uiso 1 1 calc R U . . .
C5 C 0.77522(16) 0.52017(11) 0.76151(9) 0.0275(3) Uani 1 1 d . . . . .
H5 H 0.850040 0.485008 0.786202 0.033 Uiso 1 1 calc R U . . .
C6 C 0.65174(15) 0.49909(10) 0.77646(8) 0.0237(3) Uani 1 1 d . . . . .
H6 H 0.640885 0.449237 0.810608 0.028 Uiso 1 1 calc R U . . .
C7 C 0.28539(15) 0.63209(10) 0.67209(8) 0.0216(3) Uani 1 1 d . . . . .
C8 C 0.30497(14) 0.55894(10) 0.72165(8) 0.0216(3) Uani 1 1 d . . . . .
C9 C 0.19520(15) 0.50257(10) 0.74571(8) 0.0221(3) Uani 1 1 d . . . . .
H9 H 0.111740 0.538249 0.726852 0.027 Uiso 1 1 calc R U . . .
C10 C 0.21226(15) 0.49596(10) 0.83591(9) 0.0228(3) Uani 1 1 d . . . . .
C11 C 0.30439(16) 0.43789(11) 0.88224(9) 0.0280(3) Uani 1 1 d . . . . .
H11 H 0.360853 0.400270 0.858234 0.034 Uiso 1 1 calc R U . . .
C12 C 0.31361(17) 0.43508(13) 0.96385(10) 0.0343(4) Uani 1 1 d . . . . .
H12 H 0.377207 0.395904 0.995411 0.041 Uiso 1 1 calc R U . . .
C13 C 0.23093(19) 0.48884(14) 0.99940(10) 0.0381(4) Uani 1 1 d . . . . .
H13 H 0.237245 0.485978 1.055048 0.046 Uiso 1 1 calc R U . . .
C14 C 0.13945(18) 0.54654(13) 0.95398(10) 0.0372(4) Uani 1 1 d . . . . .
H14 H 0.082676 0.583612 0.978210 0.045 Uiso 1 1 calc R U . . .
C15 C 0.13057(16) 0.55026(11) 0.87231(9) 0.0289(4) Uani 1 1 d . . . . .
H15 H 0.067891 0.590422 0.841160 0.035 Uiso 1 1 calc R U . . .
C16 C 0.17511(15) 0.40829(11) 0.70423(8) 0.0241(3) Uani 1 1 d . . . . .
C17 C 0.27810(17) 0.35190(11) 0.69132(10) 0.0308(4) Uani 1 1 d . . . . .
H17 H 0.367025 0.371795 0.708236 0.037 Uiso 1 1 calc R U . . .
C18 C 0.25169(18) 0.26672(12) 0.65386(10) 0.0345(4) Uani 1 1 d . . . . .
H18 H 0.322757 0.229151 0.644779 0.041 Uiso 1 1 calc R U . . .
C19 C 0.12322(19) 0.23607(12) 0.62967(9) 0.0341(4) Uani 1 1 d . . . . .
H19 H 0.105991 0.177319 0.604753 0.041 Uiso 1 1 calc R U . . .
C20 C 0.01985(19) 0.29137(13) 0.64191(10) 0.0368(4) Uani 1 1 d . . . . .
H20 H -0.068817 0.270818 0.625254 0.044 Uiso 1 1 calc R U . . .
C21 C 0.04583(16) 0.37699(12) 0.67859(10) 0.0317(4) Uani 1 1 d . . . . .
H21 H -0.025737 0.414918 0.686351 0.038 Uiso 1 1 calc R U . . .
C22 C 0.14995(15) 0.66478(11) 0.63437(8) 0.0229(3) Uani 1 1 d . . . . .
C23 C 0.06733(17) 0.61141(12) 0.57766(9) 0.0305(4) Uani 1 1 d . . . . .
H23 H 0.096250 0.552414 0.563357 0.037 Uiso 1 1 calc R U . . .
C24 C -0.05690(18) 0.64381(13) 0.54193(10) 0.0353(4) Uani 1 1 d . . . . .
H24 H -0.112989 0.606622 0.503779 0.042 Uiso 1 1 calc R U . . .
C25 C -0.09932(17) 0.72992(13) 0.56162(10) 0.0338(4) Uani 1 1 d . . . . .
H25 H -0.184158 0.752135 0.536767 0.041 Uiso 1 1 calc R U . . .
C26 C -0.01836(18) 0.78351(13) 0.61736(11) 0.0382(4) Uani 1 1 d . . . . .
H26 H -0.047737 0.842624 0.631057 0.046 Uiso 1 1 calc R U . . .
C27 C 0.10614(17) 0.75155(12) 0.65371(10) 0.0328(4) Uani 1 1 d . . . . .
H27 H 0.161575 0.789068 0.691915 0.039 Uiso 1 1 calc R U . . .
C28 C 0.40248(15) 0.69326(10) 0.54266(8) 0.0228(3) Uani 1 1 d . . . . .
C29 C 0.39468(19) 0.60894(12) 0.50271(10) 0.0348(4) Uani 1 1 d . . . . .
H29 H 0.396246 0.552447 0.531259 0.042 Uiso 1 1 calc R U . . .
C30 C 0.3846(2) 0.60709(14) 0.42125(10) 0.0424(5) Uani 1 1 d . . . . .
H30 H 0.378867 0.549381 0.394160 0.051 Uiso 1 1 calc R U . . .
C31 C 0.38300(19) 0.68926(14) 0.37944(10) 0.0387(4) Uani 1 1 d . . . . .
H31 H 0.377956 0.687906 0.323861 0.046 Uiso 1 1 calc R U . . .
C32 C 0.38870(18) 0.77291(14) 0.41854(10) 0.0378(4) Uani 1 1 d . . . . .
H32 H 0.386293 0.829252 0.389698 0.045 Uiso 1 1 calc R U . . .
C33 C 0.39801(16) 0.77532(12) 0.50045(9) 0.0294(4) Uani 1 1 d . . . . .
H33 H 0.401264 0.833193 0.527144 0.035 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O2 1.4865(11) . ?
P1 C2 1.7838(15) . ?
P1 C7 1.7854(15) . ?
P1 C28 1.8072(15) . ?
O1 C1 1.3812(18) . ?
O1 C8 1.3677(18) . ?
C1 C2 1.390(2) . ?
C1 C6 1.394(2) . ?
C2 C3 1.409(2) . ?
C3 H3 0.9500 . ?
C3 C4 1.378(2) . ?
C4 H4 0.9500 . ?
C4 C5 1.394(2) . ?
C5 H5 0.9500 . ?
C5 C6 1.384(2) . ?
C6 H6 0.9500 . ?
C7 C8 1.347(2) . ?
C7 C22 1.495(2) . ?
C8 C9 1.519(2) . ?
C9 H9 1.0000 . ?
C9 C10 1.5336(19) . ?
C9 C16 1.530(2) . ?
C10 C11 1.392(2) . ?
C10 C15 1.390(2) . ?
C11 H11 0.9500 . ?
C11 C12 1.393(2) . ?
C12 H12 0.9500 . ?
C12 C13 1.384(3) . ?
C13 H13 0.9500 . ?
C13 C14 1.378(3) . ?
C14 H14 0.9500 . ?
C14 C15 1.395(2) . ?
C15 H15 0.9500 . ?
C16 C17 1.392(2) . ?
C16 C21 1.394(2) . ?
C17 H17 0.9500 . ?
C17 C18 1.388(2) . ?
C18 H18 0.9500 . ?
C18 C19 1.381(3) . ?
C19 H19 0.9500 . ?
C19 C20 1.382(3) . ?
C20 H20 0.9500 . ?
C20 C21 1.388(2) . ?
C21 H21 0.9500 . ?
C22 C23 1.393(2) . ?
C22 C27 1.393(2) . ?
C23 H23 0.9500 . ?
C23 C24 1.387(2) . ?
C24 H24 0.9500 . ?
C24 C25 1.381(3) . ?
C25 H25 0.9500 . ?
C25 C26 1.377(3) . ?
C26 H26 0.9500 . ?
C26 C27 1.390(2) . ?
C27 H27 0.9500 . ?
C28 C29 1.391(2) . ?
C28 C33 1.385(2) . ?
C29 H29 0.9500 . ?
C29 C30 1.389(2) . ?
C30 H30 0.9500 . ?
C30 C31 1.385(3) . ?
C31 H31 0.9500 . ?
C31 C32 1.377(3) . ?
C32 H32 0.9500 . ?
C32 C33 1.398(2) . ?
C33 H33 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O2 P1 C2 114.74(7) . . ?
O2 P1 C7 115.69(7) . . ?
O2 P1 C28 111.24(7) . . ?
C2 P1 C7 100.78(7) . . ?
C2 P1 C28 106.70(7) . . ?
C7 P1 C28 106.75(7) . . ?
C8 O1 C1 123.54(11) . . ?
O1 C1 C2 123.89(13) . . ?
O1 C1 C6 113.99(13) . . ?
C2 C1 C6 122.12(14) . . ?
C1 C2 P1 121.83(11) . . ?
C1 C2 C3 117.65(14) . . ?
C3 C2 P1 120.43(11) . . ?
C2 C3 H3 119.5 . . ?
C4 C3 C2 120.96(14) . . ?
C4 C3 H3 119.5 . . ?
C3 C4 H4 120.0 . . ?
C3 C4 C5 119.95(15) . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 119.7 . . ?
C6 C5 C4 120.57(15) . . ?
C6 C5 H5 119.7 . . ?
C1 C6 H6 120.6 . . ?
C5 C6 C1 118.74(14) . . ?
C5 C6 H6 120.6 . . ?
C8 C7 P1 122.29(12) . . ?
C8 C7 C22 122.06(13) . . ?
C22 C7 P1 115.64(10) . . ?
O1 C8 C9 109.70(12) . . ?
C7 C8 O1 125.73(13) . . ?
C7 C8 C9 124.57(14) . . ?
C8 C9 H9 106.1 . . ?
C8 C9 C10 111.78(12) . . ?
C8 C9 C16 112.67(12) . . ?
C10 C9 H9 106.1 . . ?
C16 C9 H9 106.1 . . ?
C16 C9 C10 113.37(12) . . ?
C11 C10 C9 123.06(14) . . ?
C15 C10 C9 117.86(14) . . ?
C15 C10 C11 119.07(14) . . ?
C10 C11 H11 120.1 . . ?
C10 C11 C12 119.85(15) . . ?
C12 C11 H11 120.1 . . ?
C11 C12 H12 119.7 . . ?
C13 C12 C11 120.60(16) . . ?
C13 C12 H12 119.7 . . ?
C12 C13 H13 120.0 . . ?
C14 C13 C12 119.93(15) . . ?
C14 C13 H13 120.0 . . ?
C13 C14 H14 120.1 . . ?
C13 C14 C15 119.73(16) . . ?
C15 C14 H14 120.1 . . ?
C10 C15 C14 120.82(16) . . ?
C10 C15 H15 119.6 . . ?
C14 C15 H15 119.6 . . ?
C17 C16 C9 123.88(14) . . ?
C17 C16 C21 118.30(15) . . ?
C21 C16 C9 117.82(14) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 C16 120.40(16) . . ?
C18 C17 H17 119.8 . . ?
C17 C18 H18 119.7 . . ?
C19 C18 C17 120.69(16) . . ?
C19 C18 H18 119.7 . . ?
C18 C19 H19 120.2 . . ?
C18 C19 C20 119.60(16) . . ?
C20 C19 H19 120.2 . . ?
C19 C20 H20 120.1 . . ?
C19 C20 C21 119.87(17) . . ?
C21 C20 H20 120.1 . . ?
C16 C21 H21 119.4 . . ?
C20 C21 C16 121.14(16) . . ?
C20 C21 H21 119.4 . . ?
C23 C22 C7 121.24(14) . . ?
C27 C22 C7 119.94(14) . . ?
C27 C22 C23 118.78(15) . . ?
C22 C23 H23 119.8 . . ?
C24 C23 C22 120.45(16) . . ?
C24 C23 H23 119.8 . . ?
C23 C24 H24 119.9 . . ?
C25 C24 C23 120.25(16) . . ?
C25 C24 H24 119.9 . . ?
C24 C25 H25 120.1 . . ?
C26 C25 C24 119.85(16) . . ?
C26 C25 H25 120.1 . . ?
C25 C26 H26 119.8 . . ?
C25 C26 C27 120.35(16) . . ?
C27 C26 H26 119.8 . . ?
C22 C27 H27 119.8 . . ?
C26 C27 C22 120.31(16) . . ?
C26 C27 H27 119.8 . . ?
C29 C28 P1 121.25(11) . . ?
C33 C28 P1 119.22(12) . . ?
C33 C28 C29 119.53(14) . . ?
C28 C29 H29 119.9 . . ?
C30 C29 C28 120.21(16) . . ?
C30 C29 H29 119.9 . . ?
C29 C30 H30 120.0 . . ?
C31 C30 C29 120.10(17) . . ?
C31 C30 H30 120.0 . . ?
C30 C31 H31 120.0 . . ?
C32 C31 C30 119.90(15) . . ?
C32 C31 H31 120.0 . . ?
C31 C32 H32 119.8 . . ?
C31 C32 C33 120.31(16) . . ?
C33 C32 H32 119.8 . . ?
C28 C33 C32 119.92(16) . . ?
C28 C33 H33 120.0 . . ?
C32 C33 H33 120.0 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 C2 C3 C4 175.97(12) . . . . ?
P1 C7 C8 O1 -1.3(2) . . . . ?
P1 C7 C8 C9 177.81(11) . . . . ?
P1 C7 C22 C23 113.15(14) . . . . ?
P1 C7 C22 C27 -64.54(16) . . . . ?
P1 C28 C29 C30 -178.70(14) . . . . ?
P1 C28 C33 C32 178.32(13) . . . . ?
O1 C1 C2 P1 5.0(2) . . . . ?
O1 C1 C2 C3 -178.35(13) . . . . ?
O1 C1 C6 C5 179.26(13) . . . . ?
O1 C8 C9 C10 52.79(16) . . . . ?
O1 C8 C9 C16 -76.25(15) . . . . ?
O2 P1 C2 C1 112.38(13) . . . . ?
O2 P1 C2 C3 -64.21(14) . . . . ?
O2 P1 C7 C8 -113.33(13) . . . . ?
O2 P1 C7 C22 65.33(12) . . . . ?
O2 P1 C28 C29 178.18(13) . . . . ?
O2 P1 C28 C33 -1.55(15) . . . . ?
C1 O1 C8 C7 -10.3(2) . . . . ?
C1 O1 C8 C9 170.43(12) . . . . ?
C1 C2 C3 C4 -0.8(2) . . . . ?
C2 P1 C7 C8 11.03(14) . . . . ?
C2 P1 C7 C22 -170.31(11) . . . . ?
C2 P1 C28 C29 52.35(15) . . . . ?
C2 P1 C28 C33 -127.38(13) . . . . ?
C2 C1 C6 C5 0.3(2) . . . . ?
C2 C3 C4 C5 0.2(2) . . . . ?
C3 C4 C5 C6 0.7(2) . . . . ?
C4 C5 C6 C1 -0.9(2) . . . . ?
C6 C1 C2 P1 -176.13(11) . . . . ?
C6 C1 C2 C3 0.6(2) . . . . ?
C7 P1 C2 C1 -12.62(14) . . . . ?
C7 P1 C2 C3 170.79(12) . . . . ?
C7 P1 C28 C29 -54.76(15) . . . . ?
C7 P1 C28 C33 125.51(13) . . . . ?
C7 C8 C9 C10 -126.45(15) . . . . ?
C7 C8 C9 C16 104.51(17) . . . . ?
C7 C22 C23 C24 -178.49(14) . . . . ?
C7 C22 C27 C26 178.31(15) . . . . ?
C8 O1 C1 C2 8.2(2) . . . . ?
C8 O1 C1 C6 -170.76(13) . . . . ?
C8 C7 C22 C23 -68.2(2) . . . . ?
C8 C7 C22 C27 114.12(17) . . . . ?
C8 C9 C10 C11 -76.23(18) . . . . ?
C8 C9 C10 C15 104.32(16) . . . . ?
C8 C9 C16 C17 40.49(19) . . . . ?
C8 C9 C16 C21 -140.10(14) . . . . ?
C9 C10 C11 C12 -179.54(14) . . . . ?
C9 C10 C15 C14 178.99(15) . . . . ?
C9 C16 C17 C18 179.35(14) . . . . ?
C9 C16 C21 C20 -178.70(14) . . . . ?
C10 C9 C16 C17 -87.72(17) . . . . ?
C10 C9 C16 C21 91.69(16) . . . . ?
C10 C11 C12 C13 0.7(3) . . . . ?
C11 C10 C15 C14 -0.5(2) . . . . ?
C11 C12 C13 C14 -0.7(3) . . . . ?
C12 C13 C14 C15 0.1(3) . . . . ?
C13 C14 C15 C10 0.5(3) . . . . ?
C15 C10 C11 C12 -0.1(2) . . . . ?
C16 C9 C10 C11 52.44(19) . . . . ?
C16 C9 C10 C15 -127.01(15) . . . . ?
C16 C17 C18 C19 -0.8(3) . . . . ?
C17 C16 C21 C20 0.7(2) . . . . ?
C17 C18 C19 C20 0.9(3) . . . . ?
C18 C19 C20 C21 -0.2(3) . . . . ?
C19 C20 C21 C16 -0.6(3) . . . . ?
C21 C16 C17 C18 -0.1(2) . . . . ?
C22 C7 C8 O1 -179.87(13) . . . . ?
C22 C7 C8 C9 -0.8(2) . . . . ?
C22 C23 C24 C25 0.7(3) . . . . ?
C23 C22 C27 C26 0.6(2) . . . . ?
C23 C24 C25 C26 -0.5(3) . . . . ?
C24 C25 C26 C27 0.3(3) . . . . ?
C25 C26 C27 C22 -0.3(3) . . . . ?
C27 C22 C23 C24 -0.8(2) . . . . ?
C28 P1 C2 C1 -123.93(12) . . . . ?
C28 P1 C2 C3 59.48(14) . . . . ?
C28 P1 C7 C8 122.30(13) . . . . ?
C28 P1 C7 C22 -59.05(12) . . . . ?
C28 C29 C30 C31 0.3(3) . . . . ?
C29 C28 C33 C32 -1.4(2) . . . . ?
C29 C30 C31 C32 -1.3(3) . . . . ?
C30 C31 C32 C33 0.9(3) . . . . ?
C31 C32 C33 C28 0.5(3) . . . . ?
C33 C28 C29 C30 1.0(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
