# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2423496'
loop_
_audit_author_name
_audit_author_address
'Mohamed Saber Lassoued'
;Xian Jiaotong University School of Chemistry
China
;
_audit_update_record             
;
2025-02-13 deposited with the CCDC.	2025-04-02 downloaded from the CCDC.
;
_audit_creation_date             2025-01-29
_audit_creation_method           
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_chemical_name_common            ?
_chemical_name_systematic        
;
 ? 
;
_chemical_formula_moiety         'Cd Se9 Sn3, 2(C13 H28 N2)'
_chemical_formula_sum            'C26 H51 Cd N4 Se9 Sn3'
_chemical_formula_weight         1598.82
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           9
_space_group_name_H-M_alt        'C 1 c 1'
_space_group_name_Hall           'C -2yc'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 'x, -y, z+1/2'
3 'x+1/2, y+1/2, z'
4 'x+1/2, -y+1/2, z+1/2'

_cell_length_a                   17.143(4)
_cell_length_b                   28.047(6)
_cell_length_c                   11.365(3)
_cell_angle_alpha                90.00
_cell_angle_beta                 123.359(3)
_cell_angle_gamma                90.00
_cell_volume                     4564.2(17)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    7170
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.19
_cell_measurement_theta_min      2.59
_exptl_absorpt_coefficient_mu    9.282
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   ?
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    2.327
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2956
_exptl_crystal_size_max          ?
_exptl_crystal_size_mid          ?
_exptl_crystal_size_min          ?
_exptl_special_details           
;
 ? 
;
_diffrn_reflns_av_R_equivalents  0.0238
_diffrn_reflns_av_unetI/netI     0.0458
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       30
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            12877
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.45
_diffrn_ambient_temperature      296.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_number         ?
_reflns_number_gt                5436
_reflns_number_total             6257
_reflns_threshold_expression     >2sigma(I)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_refine_diff_density_max         1.216
_refine_diff_density_min         -0.795
_refine_diff_density_rms         0.161
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.020(10)
_refine_ls_extinction_coef       ?
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     388
_refine_ls_number_reflns         6257
_refine_ls_number_restraints     154
_refine_ls_R_factor_all          0.0436
_refine_ls_R_factor_gt           0.0365
_refine_ls_restrained_S_all      1.069
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0579P)²+8.0317P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1035
_refine_ls_wR_factor_ref         0.1078
_refine_special_details          
;
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All N(H,H) groups
2. Restrained distances
 C28-C24
 1.45 with sigma of 0.01
 C27-C28
 1.45 with sigma of 0.01
 N4-C27
 1.45 with sigma of 0.01
 C26-N4
 1.45 with sigma of 0.01
 C25-C26
 1.45 with sigma of 0.01
 C24-C25
 1.45 with sigma of 0.01
 C23-C24
 1.45 with sigma of 0.01
 C16-C21
 1.45 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
C21 \\sim C22 \\sim C23 \\sim C24 \\sim C25 \\sim C26 \\sim C27 \\sim C28 \\sim
C16 \\sim C7 \\sim C15: within 2A with sigma of 0.01 and sigma for terminal
atoms of 0.02
Uanis(C8) \\sim Ueq, Uanis(C14) \\sim Ueq, Uanis(C12) \\sim Ueq, Uanis(N4)
\\sim Ueq, Uanis(C21) \\sim Ueq, Uanis(C22) \\sim Ueq, Uanis(C23) \\sim Ueq,
Uanis(C24) \\sim Ueq, Uanis(C25) \\sim Ueq, Uanis(C26) \\sim Ueq, Uanis(C27)
\\sim Ueq, Uanis(C28) \\sim Ueq, Uanis(C16) \\sim Ueq, Uanis(C7) \\sim Ueq,
Uanis(C15) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
4.a Ternary CH refined with riding coordinates:
 C1(H1), C10(H10), C16(H16), C24(H24)
4.b Secondary CH2 refined with riding coordinates:
 N1(H1A,H1B), N2(H2A,H2B), C2(H2C,H2D), C0AA(H0AA,H0AB), C5(H5A,H5B), C6(H6A,
 H6B), C7(H7A,H7B), C8(H8A,H8B), C9(H9A,H9B), C11(H11A,H11B), C12(H12A,H12B),
 C14(H14A,H14B), C15(H15A,H15B), N3(H3A,H3B), C17(H17A,H17B), C18(H18A,H18B),
 C19(H19A,H19B), C20(H20A,H20B), C21(H21A,H21B), C23(H23A,H23B), C22(H22A,H22B),
  N4(H4A,H4B), C28(H28A,H28B), C27(H27A,H27B), C25(H25A,H25B), C26(H26A,H26B)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Cd1 Cd 0.63692(5) 0.31428(3) 0.88687(9) 0.0520(2) Uani 1 d . . . .
Sn1 Sn 0.40258(5) 0.39099(3) 0.60939(7) 0.0466(2) Uani 1 d . . . .
Sn2 Sn 0.39700(4) 0.24413(2) 0.62265(6) 0.03874(18) Uani 1 d . . . .
Sn3 Sn 0.42815(5) 0.32357(3) 0.95238(7) 0.0458(2) Uani 1 d . . . .
Se1 Se 0.32775(11) 0.45900(5) 0.44950(16) 0.0761(4) Uani 1 d . . . .
Se2 Se 0.32674(8) 0.31633(4) 0.45734(12) 0.0484(3) Uani 1 d . . . .
Se3 Se 0.35700(8) 0.39659(4) 0.78965(13) 0.0542(3) Uani 1 d . . . .
Se4 Se 0.57473(8) 0.39194(5) 0.72937(15) 0.0690(4) Uani 1 d . . . .
Se5 Se 0.31462(7) 0.17148(4) 0.48626(13) 0.0498(3) Uani 1 d . . . .
Se6 Se 0.35042(7) 0.24951(4) 0.80059(12) 0.0442(3) Uani 1 d . . . .
Se7 Se 0.56847(7) 0.23675(4) 0.73055(12) 0.0525(3) Uani 1 d . . . .
Se8 Se 0.36639(9) 0.32807(6) 1.10271(14) 0.0677(4) Uani 1 d . . . .
Se9 Se 0.60166(8) 0.31739(5) 1.08554(12) 0.0647(4) Uani 1 d . . . .
N1 N 0.0467(7) 0.1861(4) -0.0617(11) 0.071(3) Uani 1 d . . . .
H1A H -0.0142 0.1865 -0.1316 0.085 Uiso 1 calc . . R .
H1B H 0.0506 0.1860 0.0205 0.085 Uiso 1 calc . . R .
N2 N 0.6476(8) 0.1799(4) 0.0550(15) 0.087(4) Uani 1 d . . . .
H2A H 0.6137 0.2039 -0.0038 0.104 Uiso 1 calc . . R .
H2B H 0.7070 0.1837 0.0800 0.104 Uiso 1 calc . . R .
C1 C 0.2451(9) 0.1820(5) 0.0347(16) 0.073(4) Uani 1 d . . . .
H1 H 0.2445 0.1822 -0.0521 0.088 Uiso 1 calc . . R .
C2 C 0.1903(9) 0.1372(5) 0.0392(15) 0.080(4) Uani 1 d . . . .
H2C H 0.2170 0.1083 0.0288 0.096 Uiso 1 calc . . R .
H2D H 0.1974 0.1361 0.1299 0.096 Uiso 1 calc . . R .
C0AA C 0.0912(10) 0.1395(5) -0.0727(16) 0.088(5) Uani 1 d . . . .
H0AA H 0.0592 0.1122 -0.0656 0.106 Uiso 1 calc . . R .
H0AB H 0.0837 0.1383 -0.1636 0.106 Uiso 1 calc . . R .
C5 C 0.0908(9) 0.2298(5) -0.0700(15) 0.080(4) Uani 1 d . . . .
H5A H 0.0647 0.2575 -0.0526 0.096 Uiso 1 calc . . R .
H5B H 0.0797 0.2329 -0.1631 0.096 Uiso 1 calc . . R .
C6 C 0.1992(9) 0.2263(6) 0.0451(17) 0.089(5) Uani 1 d . . . .
H6A H 0.2296 0.2541 0.0368 0.107 Uiso 1 calc . . R .
H6B H 0.2090 0.2273 0.1377 0.107 Uiso 1 calc . . R .
C7 C 0.3419(12) 0.1820(6) 0.1601(19) 0.100(5) Uani 1 d . . . U
H7A H 0.3410 0.1834 0.2447 0.120 Uiso 1 calc . . R .
H7B H 0.3748 0.2099 0.1585 0.120 Uiso 1 calc . . R .
C8 C 0.3943(15) 0.1352(7) 0.162(2) 0.131(7) Uani 1 d . . . U
H8A H 0.3579 0.1078 0.1564 0.157 Uiso 1 calc . . R .
H8B H 0.4540 0.1336 0.2519 0.157 Uiso 1 calc . . R .
C9 C 0.4123(11) 0.1317(8) 0.038(2) 0.122(7) Uani 1 d . . . .
H9A H 0.3834 0.1026 -0.0144 0.147 Uiso 1 calc . . R .
H9B H 0.3805 0.1582 -0.0259 0.147 Uiso 1 calc . . R .
C10 C 0.5084(9) 0.1320(5) 0.0796(16) 0.078(4) Uani 1 d . . . .
H10 H 0.5424 0.1054 0.1438 0.093 Uiso 1 calc . . R .
C11 C 0.5517(11) 0.1780(6) 0.150(2) 0.096(5) Uani 1 d . . . .
H11A H 0.5133 0.2040 0.0892 0.115 Uiso 1 calc . . R .
H11B H 0.5538 0.1802 0.2367 0.115 Uiso 1 calc . . R .
C12 C 0.6448(14) 0.1832(6) 0.181(2) 0.108(6) Uani 1 d . . . U
H12A H 0.6843 0.1585 0.2470 0.130 Uiso 1 calc . . R .
H12B H 0.6698 0.2138 0.2260 0.130 Uiso 1 calc . . R .
C14 C 0.6121(11) 0.1350(6) -0.0194(18) 0.093(5) Uani 1 d . . . U
H14A H 0.6513 0.1089 0.0397 0.111 Uiso 1 calc . . R .
H14B H 0.6123 0.1353 -0.1045 0.111 Uiso 1 calc . . R .
C15 C 0.5134(12) 0.1283(6) -0.056(2) 0.110(5) Uani 1 d . . . U
H15A H 0.4905 0.0973 -0.0998 0.132 Uiso 1 calc . . R .
H15B H 0.4733 0.1524 -0.1240 0.132 Uiso 1 calc . . R .
N3 N 1.2329(8) 0.5951(4) 0.6355(12) 0.081(3) Uani 1 d . . . .
H3A H 1.2746 0.6128 0.6302 0.097 Uiso 1 calc . . R .
H3B H 1.2598 0.5856 0.7255 0.097 Uiso 1 calc . . R .
C17 C 1.131(2) 0.5252(7) 0.526(3) 0.163(10) Uani 1 d . . . .
H17A H 1.1075 0.5056 0.4425 0.196 Uiso 1 calc . . R .
H17B H 1.1564 0.5035 0.6053 0.196 Uiso 1 calc . . R .
C18 C 1.2077(13) 0.5526(6) 0.544(2) 0.109(6) Uani 1 d . . . .
H18A H 1.1920 0.5630 0.4516 0.131 Uiso 1 calc . . R .
H18B H 1.2619 0.5320 0.5829 0.131 Uiso 1 calc . . R .
C19 C 1.1494(9) 0.6244(5) 0.5932(15) 0.079(4) Uani 1 d . . . .
H19A H 1.1212 0.6358 0.4975 0.095 Uiso 1 calc . . R .
H19B H 1.1669 0.6517 0.6551 0.095 Uiso 1 calc . . R .
C16 C 1.054(2) 0.5465(13) 0.513(4) 0.203(9) Uani 1 d . . D U
H16 H 1.0115 0.5559 0.4143 0.244 Uiso 1 calc . . R .
C24 C 0.796(2) 0.4904(14) 0.289(4) 0.240(7) Uani 1 d . . D U
H24 H 0.8216 0.4587 0.2928 0.288 Uiso 1 calc . . R .
C20 C 1.0795(11) 0.5928(7) 0.603(2) 0.123(7) Uani 1 d . . . .
H20A H 1.0230 0.6109 0.5715 0.148 Uiso 1 calc . . R .
H20B H 1.1064 0.5841 0.7008 0.148 Uiso 1 calc . . R .
C21 C 1.002(2) 0.5129(12) 0.545(4) 0.225(8) Uani 1 d . . D U
H21A H 1.0349 0.5071 0.6452 0.270 Uiso 1 calc . . R .
H21B H 0.9924 0.4828 0.4964 0.270 Uiso 1 calc . . R .
C23 C 0.875(2) 0.5225(12) 0.334(4) 0.244(8) Uani 1 d . . D U
H23A H 0.8563 0.5493 0.2701 0.293 Uiso 1 calc . . R .
H23B H 0.9258 0.5058 0.3376 0.293 Uiso 1 calc . . R .
C22 C 0.905(2) 0.5398(12) 0.487(4) 0.238(8) Uani 1 d . . . U
H22A H 0.8680 0.5263 0.5195 0.285 Uiso 1 calc . . R .
H22B H 0.9107 0.5742 0.4995 0.285 Uiso 1 calc . . R .
N4 N 0.6228(18) 0.4416(9) 0.059(3) 0.199(9) Uani 1 d . . D U
H4A H 0.5666 0.4279 0.0016 0.239 Uiso 1 calc . . R .
H4B H 0.6649 0.4276 0.0462 0.239 Uiso 1 calc . . R .
C28 C 0.711(2) 0.4806(12) 0.281(4) 0.243(8) Uani 1 d . . D U
H28A H 0.6716 0.5086 0.2407 0.292 Uiso 1 calc . . R .
H28B H 0.7273 0.4783 0.3774 0.292 Uiso 1 calc . . R .
C27 C 0.652(3) 0.4398(12) 0.206(3) 0.238(9) Uani 1 d . . D U
H27A H 0.5975 0.4402 0.2119 0.286 Uiso 1 calc . . R .
H27B H 0.6863 0.4106 0.2496 0.286 Uiso 1 calc . . R .
C25 C 0.721(2) 0.4962(14) 0.139(4) 0.256(8) Uani 1 d . . D U
H25A H 0.7431 0.4755 0.0950 0.307 Uiso 1 calc . . R .
H25B H 0.7338 0.5282 0.1213 0.307 Uiso 1 calc . . R .
C26 C 0.619(2) 0.4934(9) 0.036(4) 0.266(9) Uani 1 d . . D U
H26A H 0.5830 0.5103 0.0655 0.319 Uiso 1 calc . . R .
H26B H 0.5992 0.5023 -0.0587 0.319 Uiso 1 calc . . R .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cd1 Se4 2.6431(16) . ?
Cd1 Se5 2.6328(14) 4 ?
Cd1 Se7 2.6398(15) . ?
Cd1 Se9 2.6405(15) . ?
Sn1 Se1 2.4541(15) . ?
Sn1 Se2 2.5672(14) . ?
Sn1 Se3 2.5677(14) . ?
Sn1 Se4 2.4786(14) . ?
Sn2 Se2 2.5675(13) . ?
Sn2 Se5 2.4783(13) . ?
Sn2 Se6 2.5547(13) . ?
Sn2 Se7 2.4948(12) . ?
Sn3 Se3 2.5733(15) . ?
Sn3 Se6 2.5569(14) . ?
Sn3 Se8 2.4588(13) . ?
Sn3 Se9 2.4935(14) . ?
Se5 Cd1 2.6328(14) 4_454 ?
N1 C0AA 1.552(18) . ?
N1 C5 1.470(16) . ?
N2 C12 1.46(2) . ?
N2 C14 1.453(19) . ?
C1 C2 1.587(19) . ?
C1 C6 1.511(19) . ?
C1 C7 1.48(2) . ?
C2 C0AA 1.461(19) . ?
C5 C6 1.582(19) . ?
C7 C8 1.58(2) . ?
C8 C9 1.61(2) . ?
C9 C10 1.443(18) . ?
C10 C11 1.49(2) . ?
C10 C15 1.60(2) . ?
C11 C12 1.44(2) . ?
C14 C15 1.51(2) . ?
N3 C18 1.483(18) . ?
N3 C19 1.484(17) . ?
C17 C18 1.44(3) . ?
C17 C16 1.38(4) . ?
C19 C20 1.54(2) . ?
C16 C20 1.56(4) . ?
C16 C21 1.462(10) . ?
C24 C23 1.461(10) . ?
C24 C28 1.445(10) . ?
C24 C25 1.471(10) . ?
C21 C22 1.60(4) . ?
C23 C22 1.59(5) . ?
N4 C27 1.465(10) . ?
N4 C26 1.470(10) . ?
C28 C27 1.448(10) . ?
C25 C26 1.479(10) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Se5 Cd1 Se4 96.10(4) 4 . ?
Se5 Cd1 Se7 113.26(4) 4 . ?
Se5 Cd1 Se9 112.52(5) 4 . ?
Se7 Cd1 Se4 111.01(6) . . ?
Se7 Cd1 Se9 112.12(5) . . ?
Se9 Cd1 Se4 110.80(5) . . ?
Se1 Sn1 Se2 105.69(5) . . ?
Se1 Sn1 Se3 106.19(5) . . ?
Se1 Sn1 Se4 112.24(6) . . ?
Se2 Sn1 Se3 108.86(5) . . ?
Se4 Sn1 Se2 112.84(5) . . ?
Se4 Sn1 Se3 110.68(5) . . ?
Se5 Sn2 Se2 108.31(5) . . ?
Se5 Sn2 Se6 103.01(4) . . ?
Se5 Sn2 Se7 110.57(4) . . ?
Se6 Sn2 Se2 107.91(4) . . ?
Se7 Sn2 Se2 112.15(4) . . ?
Se7 Sn2 Se6 114.36(4) . . ?
Se6 Sn3 Se3 107.24(5) . . ?
Se8 Sn3 Se3 104.09(5) . . ?
Se8 Sn3 Se6 104.28(5) . . ?
Se8 Sn3 Se9 114.06(5) . . ?
Se9 Sn3 Se3 115.30(5) . . ?
Se9 Sn3 Se6 110.99(5) . . ?
Sn1 Se2 Sn2 106.89(5) . . ?
Sn1 Se3 Sn3 107.03(5) . . ?
Sn1 Se4 Cd1 106.18(5) . . ?
Sn2 Se5 Cd1 105.70(4) . 4_454 ?
Sn2 Se6 Sn3 107.96(4) . . ?
Sn2 Se7 Cd1 103.30(4) . . ?
Sn3 Se9 Cd1 103.94(5) . . ?
C5 N1 C0AA 113.9(11) . . ?
C14 N2 C12 113.2(12) . . ?
C6 C1 C2 107.7(11) . . ?
C7 C1 C2 109.8(12) . . ?
C7 C1 C6 106.4(13) . . ?
C0AA C2 C1 111.3(11) . . ?
C2 C0AA N1 110.8(11) . . ?
N1 C5 C6 107.9(12) . . ?
C1 C6 C5 114.3(12) . . ?
C1 C7 C8 110.0(15) . . ?
C7 C8 C9 114.8(15) . . ?
C10 C9 C8 116.7(15) . . ?
C9 C10 C11 108.9(15) . . ?
C9 C10 C15 110.0(13) . . ?
C11 C10 C15 107.4(12) . . ?
C12 C11 C10 112.2(14) . . ?
C11 C12 N2 112.5(16) . . ?
N2 C14 C15 108.5(12) . . ?
C14 C15 C10 111.8(14) . . ?
C18 N3 C19 111.2(11) . . ?
C16 C17 C18 122(2) . . ?
C17 C18 N3 114.6(14) . . ?
N3 C19 C20 107.9(12) . . ?
C17 C16 C20 112(3) . . ?
C17 C16 C21 111(3) . . ?
C21 C16 C20 112(3) . . ?
C23 C24 C25 113(3) . . ?
C28 C24 C23 148(4) . . ?
C28 C24 C25 75(2) . . ?
C19 C20 C16 112.5(17) . . ?
C16 C21 C22 103(3) . . ?
C24 C23 C22 105(3) . . ?
C23 C22 C21 87(3) . . ?
C27 N4 C26 101(3) . . ?
C24 C28 C27 123(3) . . ?
C28 C27 N4 110(3) . . ?
C24 C25 C26 144(3) . . ?
N4 C26 C25 90(2) . . ?

_olex2_submission_special_instructions 'No special instructions were received'
# start Validation Reply Form
_vrf_PLAT410_1                   
;
PROBLEM:hort Intra H...H Contact  H21B     ..H23B     .       1.65 Ang.  
                                                      x,y,z  =      1_555 Check 
RESPONSE:This is due to the relatively non-strong diffraction of crystal.
However, this alert do not affect the main results in this manuscript.
;
_vrf_PLAT414_1                   
;
PROBLEM:Short Intra D-H..H-X       H4B      ..H25A     .       1.76 Ang.  
                                                      x,y,z  =      1_555 Check 
RESPONSE:This is due to the relatively non-strong diffraction of crystal.
However, this alert do not affect the main results in this manuscript.
;
# end Validation Reply Form
