# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_jc288b_mp
_database_code_depnum_ccdc_archive 'CCDC 2408662'
loop_
_audit_author_name
_audit_author_address
'Maria Uttendorfer'
;University of Regensburg
Germany
;
_audit_update_record             
;
2024-12-09 deposited with the CCDC.	2025-04-17 downloaded from the CCDC.
;
_audit_creation_date             2024-12-09
_audit_creation_method           
;
Olex2 1.5-alpha
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2016/6
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C36 H31 Ge2 P'
_chemical_formula_sum            'C36 H31 Ge2 P'
_chemical_formula_weight         639.76
_chemical_absolute_configuration ?
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C11 H10 N O'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge -1.0885 0.8855 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_H-M_alt        'P 1 21 1'
_space_group_name_Hall           'P 2yb'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'

_cell_length_a                   9.67692(3)
_cell_length_b                   18.31240(5)
_cell_length_c                   17.49013(6)
_cell_angle_alpha                90
_cell_angle_beta                 105.3799(3)
_cell_angle_gamma                90
_cell_volume                     2988.388(17)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    123262
_cell_measurement_temperature    123.00(10)
_cell_measurement_theta_max      75.1480
_cell_measurement_theta_min      2.6180
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    3.148
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.715
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.41.93a (Rigaku Oxford Diffraction, 2020)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.422
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1304
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 0 11 0.0285
-4 -3 10 0.0396
-3 -2 -8 0.0272
3 10 2 0.0444
-6 3 6 0.0312
-3 -10 -1 0.0578
-2 10 5 0.0475
2 -10 -5 0.0667
0 -10 5 0.0451
0 4 -10 0.0490
4 -7 2 0.0446
1 -3 -11 0.0496
-2 10 -2 0.0618

_exptl_crystal_size_max          0.129
_exptl_crystal_size_mid          0.115
_exptl_crystal_size_min          0.078
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.0872 0.1552 10.9859 0.2855 -0.9574 0.0425
-4.1450 -2.8323 9.7882 0.1930 -0.6608 0.7253
-2.9626 -2.3231 -7.9920 -0.2535 0.8395 0.4805
2.5593 10.4073 1.6197 0.7288 -0.0904 -0.6787
-5.8606 2.8687 5.7300 0.5969 -0.0820 0.7981
-2.9839 -10.0760 -1.1609 -0.6751 0.0831 0.7330
-1.9980 10.2659 5.2368 0.9917 -0.1285 0.0091
2.4909 -9.8631 -5.4910 -0.9872 0.1284 -0.0945
-0.0307 -10.3203 5.4464 -0.6509 -0.6861 0.3251
0.1399 3.7710 -10.4450 0.0247 0.9861 -0.1641
4.4450 -7.1769 1.8839 -0.6804 -0.5869 -0.4388
1.0331 -3.3900 -10.8309 -0.5664 0.8196 -0.0864
-2.4651 10.2377 -2.3497 0.8219 0.5670 0.0552

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0318
_diffrn_reflns_av_unetI/netI     0.0135
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            174471
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         75.322
_diffrn_reflns_theta_min         2.620
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      123.15
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            'HyPix-Arc 150'
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω     58.00 131.00   0.50    0.05    --   82.00  21.00 -36.84  146
  2  ω     75.00 124.00   0.50    0.05    --   74.12  30.00   0.00   98
  3  ω     73.00 128.00   0.50    0.05    --   78.42  27.00 -79.00  110
  4  ω     55.00 110.00   0.50    0.05    --   60.54  27.00 -79.00  110
  5  ω     62.00 110.00   0.50    0.05    --   60.54  30.00-150.00   96
  6  ω     39.00 118.00   0.50    0.05    --   78.42   0.00-180.00  158
  7  ω     38.00  68.00   0.50    0.05    --   82.00 -57.00-157.31   60
  8  ω     23.00  94.00   0.50    0.05    --   60.54-132.00  70.00  142
  9  ω     35.00 107.00   0.50    0.05    --   78.42-125.00  60.00  144
 10  ω     31.00 113.00   0.50    0.05    --   74.12-139.00-105.00  164
 11  ω     39.00  89.00   0.50    0.05    --   78.42 -96.00 -39.00  100
 12  ω    -72.00 -22.00   0.50    0.05    --  -61.07  96.00  69.00  100
 13  ω    -74.00 -45.00   0.50    0.05    --  -80.00  66.00 -65.11   58
 14  ω    -62.00 -35.00   0.50    0.05    --  -80.00  57.00 -16.84   54
 15  ω    -62.00 -35.00   0.50    0.05    --  -80.00  57.00 166.10   54
 16  ω   -125.00 -70.00   0.50    0.05    --  -75.70 -27.00 117.00  110
 17  ω   -117.00 -81.00   0.50    0.05    --  -80.00 -77.00  37.85   72
 18  ω   -123.00 -87.00   0.50    0.05    --  -80.00 -61.00 -76.11   72
 19  ω   -126.00 -89.00   0.50    0.05    --  -80.00 -51.00-159.20   74
 20  ω   -110.00 -62.00   0.50    0.05    --  -61.07 -30.00  60.00   96
 21  ω   -117.00 -79.00   0.50    0.05    --  -80.00 -85.00  70.34   76
 22  ω   -120.00 -69.00   0.50    0.05    --  -75.70-132.00  70.00  102
 23  ω     46.00  72.00   0.50    0.05    --   78.42-103.00  60.00   52
 24  ω     11.00  36.00   0.50    0.05    --   60.54 -30.00-120.00   50
 25  ω     11.00  37.00   0.50    0.05    --   60.54 -30.00  90.00   52
 26  ω     77.00 103.00   0.50    0.05    --   78.42   0.00-150.00   52
 27  ω   -112.00 -86.00   0.50    0.05    --  -80.00 -84.00  91.67   52
 28  ω     64.00  91.00   0.50    0.05    --   82.00  21.00 -80.34   54
 29  ω     49.00  92.00   0.50    0.05    --   82.00-108.00  22.60   86
 30  ω     45.00  85.00   0.50    0.05    --   82.00-114.00  59.32   80
 31  ω     74.00 100.00   0.50    0.05    --   82.00-122.00-101.24   52
 32  ω     43.00  68.00   0.50    0.05    --   82.00 -57.00 -98.15   50
 33  ω     85.00 111.00   0.50    0.05    --   82.00  81.00  16.62   52
 34  ω    106.00 131.00   0.50    0.05    --   82.00  21.00 -80.34   50
 35  ω     98.00 124.00   0.50    0.05    --   82.00  23.00 124.10   52
 36  ω     12.00  38.00   0.50    0.05    --   60.54 -30.00 -90.00   52
 37  ω     12.00  38.00   0.50    0.05    --   60.54 -30.00-120.00   52
 38  ω     13.00  39.00   0.50    0.05    --   60.54 -30.00   0.00   52
 39  ω     37.00  63.00   0.50    0.05    --   60.54 -95.00 -30.00   52
 40  ω   -110.00 -84.00   0.50    0.05    --  -61.38 -30.00  30.00   52
 41  ω     37.00  63.00   0.50    0.05    --   74.12 -95.00 -90.00   52
 42  ω     52.00  79.00   0.50    0.05    --   74.12 -95.00 120.00   54
 43  ω     43.00  68.00   0.50    0.05    --   78.42-125.00   0.00   50
 44  ω    -89.00 -63.00   0.50    0.05    --  -80.00 116.00-159.38   52
 45  ω    -80.00 -40.00   0.50    0.05    --  -80.00  95.00  93.54   80
 46  ω    -99.00 -71.00   0.50    0.05    --  -80.00 109.00  84.84   56
 47  ω   -117.00 -80.00   0.50    0.05    --  -80.00 136.00 102.38   74
 48  ω    -88.00 -63.00   0.50    0.05    --  -80.00  91.00  55.49   50
 49  ω    -74.00 -49.00   0.50    0.05    --  -80.00  68.00-155.54   50
 50  ω    -62.00 -37.00   0.50    0.05    --  -80.00  57.00 -81.54   50
 51  ω    -93.00 -48.00   0.50    0.05    --  -80.00 126.00  73.15   90
 52  ω   -111.00 -61.00   0.50    0.05    --  -80.00 127.00  54.05  100
 53  ω   -117.00 -92.00   0.50    0.05    --  -80.00 136.00 -96.38   50
 54  ω   -110.00 -74.00   0.50    0.05    --  -80.00 145.00   0.94   72
 55  ω     70.00  96.00   0.50    0.05    --   82.00  24.00 133.25   52
 56  ω     70.00 108.00   0.50    0.05    --   82.00-128.00-167.99   76
 57  ω     67.00 112.00   0.50    0.05    --   82.00-128.00 -49.96   90
 58  ω     37.00  63.00   0.50    0.05    --   82.00-128.00-167.99   52
 59  ω     40.00  68.00   0.50    0.05    --   82.00  -4.00-107.79   56
 60  ω     85.00 116.00   0.50    0.05    --   82.00-132.00  65.92   62
 61  ω     59.00  85.00   0.50    0.05    --   82.00  19.00-120.94   52
 62  ω     90.00 129.00   0.50    0.05    --   82.00  19.00-120.94   78
 63  ω     52.00  81.00   0.50    0.05    --   82.00-131.00-105.66   58
 64  ω     73.00 113.00   0.50    0.05    --   82.00   2.00 175.97   80
 65  ω     38.00  71.00   0.50    0.05    --   82.00-132.00  65.92   66
 66  ω     89.00 115.00   0.50    0.05    --   82.00  14.00  87.10   52
 67  ω     55.00  81.00   0.50    0.05    --   82.00  -4.00  83.04   52
 68  ω     65.00  91.00   0.50    0.05    --   82.00  18.00 -46.41   52
 69  ω     67.00  93.00   0.50    0.05    --   82.00-104.00  52.02   52
 70  ω     48.00 112.00   0.50    0.05    --   82.00  18.00  50.90  128
 71  ω     43.00  69.00   0.50    0.05    --   82.00-103.00   4.85   52
 72  ω     55.00  93.00   0.50    0.05    --   82.00-117.00   6.26   76
 73  ω     49.00  90.00   0.50    0.05    --   82.00-108.00-152.38   82
 74  ω     97.00 131.00   0.50    0.05    --   82.00  24.00 133.25   68
 75  ω     49.00 106.00   0.50    0.05    --   82.00-116.00 -36.64  114
 76  ω     90.00 115.00   0.50    0.05    --   82.00-131.00-105.66   50
 77  ω     44.00  88.00   0.50    0.05    --   82.00   0.00 -22.37   88
 78  ω     48.00 113.00   0.50    0.05    --   82.00-127.00  99.91  130
 79  ω     49.00  75.00   0.50    0.05    --   74.12-125.00 150.00   52
 80  ω     -9.00  16.00   0.50    0.05    --    4.00  99.00  38.67   50
 81  ω     -5.00  20.00   0.50    0.05    --    8.00 100.00 154.58   50
 82  ω    -57.00 -30.00   0.50    0.05    --   -8.00 154.00 124.25   54
 83  ω     12.00  37.00   0.50    0.05    --   20.00  91.00 141.93   50
 84  ω    -44.00 -19.00   0.50    0.05    --  -20.00 117.00  46.76   50
 85  ω     11.00  36.00   0.50    0.05    --   20.00  92.00 -16.28   50
 86  ω     15.00  40.00   0.50    0.05    --   24.00  92.00-108.98   50
 87  ω     16.00  41.00   0.50    0.05    --   24.00  91.00  58.31   50
 88  ω     16.00  41.00   0.50    0.05    --   24.00  91.00-159.17   50
 89  ω     17.00  42.00   0.50    0.05    --   24.00  90.00 155.84   50
 90  ω     29.00  54.00   0.50    0.05    --   28.00  77.00  97.22   50
 91  ω     29.00  54.00   0.50    0.05    --   28.00  77.00  35.82   50
 92  ω     29.00  54.00   0.50    0.05    --   28.00  77.00 -55.37   50
 93  ω     33.00  58.00   0.50    0.05    --   32.00  77.00  -5.71   50
 94  ω     33.00  58.00   0.50    0.05    --   32.00  77.00 103.99   50
 95  ω     42.00  67.00   0.50    0.05    --   36.00  67.00-100.70   50
 96  ω     39.00  64.00   0.50    0.05    --   36.00  73.00-123.95   50
 97  ω     40.00  65.00   0.50    0.05    --   36.00  72.00-148.05   50
 98  ω     38.00  63.00   0.50    0.05    --   36.00  75.00 -81.89   50
 99  ω     37.00  62.00   0.50    0.05    --   36.00  77.00 117.34   50
100  ω     42.00  67.00   0.50    0.05    --   36.00  68.00 -47.99   50
101  ω    -64.00 -38.00   0.50    0.05    --  -36.00 -76.00 128.77   52
102  ω     40.00  65.00   0.50    0.05    --   36.00  72.00 -20.25   50
103  ω     42.00  67.00   0.50    0.05    --   40.00  75.00  33.44   50
104  ω     41.00  66.00   0.50    0.05    --   40.00  77.00  54.03   50
105  ω     42.00  67.00   0.50    0.05    --   40.00  76.00-177.03   50
106  ω     44.00  69.00   0.50    0.05    --   40.00  72.00 164.43   50
107  ω     45.00  70.00   0.50    0.05    --   40.00  70.00 154.21   50
108  ω     50.00  75.00   0.50    0.05    --   44.00  68.00-155.58   50
109  ω     49.00  74.00   0.50    0.05    --   44.00  70.00 159.00   50
110  ω     47.00  72.00   0.50    0.05    --   44.00  74.00 -85.37   50
111  ω     49.00  74.00   0.50    0.05    --   44.00  70.00  57.79   50
112  ω     49.00  74.00   0.50    0.05    --   44.00  69.00-141.10   50
113  ω     50.00  75.00   0.50    0.05    --   44.00  68.00-111.15   50
114  ω     47.00  72.00   0.50    0.05    --   44.00  73.00  68.01   50
115  ω     48.00  73.00   0.50    0.05    --   44.00  72.00  18.07   50
116  ω     47.00  72.00   0.50    0.05    --   44.00  74.00 126.45   50
117  ω     47.00  72.00   0.50    0.05    --   44.00  74.00 169.19   50
118  ω     50.00  75.00   0.50    0.05    --   48.00  76.00 -49.07   50
119  ω    -81.00 -55.00   0.50    0.05    --  -48.00 -65.00  71.52   52
120  ω     53.00  78.00   0.50    0.05    --   48.00  70.00  70.82   50
121  ω     52.00  77.00   0.50    0.05    --   48.00  72.00 -73.00   50
122  ω     53.00  78.00   0.50    0.05    --   48.00  71.00-130.61   50
123  ω     57.00  82.00   0.50    0.05    --   52.00  71.00  79.47   50
124  ω     57.00  82.00   0.50    0.05    --   52.00  70.00  -2.30   50
125  ω    -86.00 -60.00   0.50    0.05    --  -52.00 -64.00 105.87   52
126  ω     57.00  82.00   0.50    0.05    --   52.00  70.00-161.95   50
127  ω    -83.00 -57.00   0.50    0.05    --  -52.00 -69.00 -26.15   52
128  ω     56.00  81.00   0.50    0.05    --   52.00  72.00 -90.12   50
129  ω     63.00  88.00   0.50    0.05    --   56.00  62.00 -99.24   50
130  ω     61.00  86.00   0.50    0.05    --   56.00  70.00 116.02   50
131  ω     61.00  86.00   0.50    0.05    --   56.00  70.00  82.01   50
132  ω     60.00  85.00   0.50    0.05    --   56.00  72.00 158.36   50
133  ω     63.00  88.00   0.50    0.05    --   56.00  61.00 -57.94   50
134  ω    -89.00 -63.00   0.50    0.05    --  -56.00 -62.00  34.61   52
135  ω    -83.00 -57.00   0.50    0.05    --  -56.00 -77.00  10.71   52
136  ω     61.00  86.00   0.50    0.05    --   56.00  71.00 -88.26   50
137  ω     61.00  86.00   0.50    0.05    --   56.00  70.00 149.82   50
138  ω    -82.00 -57.00   0.50    0.05    --  -56.00 -77.00 -42.54   50
139  ω     60.00  85.00   0.50    0.05    --   56.00  72.00  87.25   50
140  ω     61.00  86.00   0.50    0.05    --   56.00  70.00-145.03   50
141  ω     66.00  98.00   0.50    0.05    --   60.00  70.00 114.68   64
142  ω     65.00  90.00   0.50    0.05    --   60.00  70.00 -16.90   50
143  ω     65.00  90.00   0.50    0.05    --   60.00  71.00 -87.16   50
144  ω     65.00  90.00   0.50    0.05    --   60.00  69.00 171.26   50
145  ω     64.00  89.00   0.50    0.05    --   60.00  72.00  88.89   50
146  ω     64.00  89.00   0.50    0.05    --   60.00  72.00-171.05   50
147  ω     64.00  89.00   0.50    0.05    --   60.00  72.00-153.01   50
148  ω     11.00  36.00   0.50    0.05    --   60.54 -30.00 -60.00   50
149  ω     13.00  39.00   0.50    0.05    --   60.54 -30.00-150.00   52
150  ω     11.00  36.00   0.50    0.05    --   60.54 -30.00 120.00   50
151  ω     12.00  40.00   0.50    0.05    --   60.54 -30.00  30.00   56
152  ω     13.00  39.00   0.50    0.05    --   60.54 -30.00  60.00   52
153  ω     21.00  58.00   0.50    0.05    --   60.54-125.00 -90.00   74
154  ω     67.00  92.00   0.50    0.05    --   64.00  73.00 -57.82   50
155  ω     68.00  93.00   0.50    0.05    --   64.00  72.00  30.04   50
156  ω    -94.00 -68.00   0.50    0.05    --  -64.00 -75.00  75.29   52
157  ω     67.00  92.00   0.50    0.05    --   64.00  73.00  90.39   50
158  ω     69.00  94.00   0.50    0.05    --   64.00  70.00 141.29   50
159  ω     68.00  93.00   0.50    0.05    --   64.00  72.00-136.64   50
160  ω    -95.00 -69.00   0.50    0.05    --  -64.00 -70.00-131.81   52
161  ω    -97.00 -72.00   0.50    0.05    --  -68.00 -72.00 -62.88   50
162  ω     70.00  95.00   0.50    0.05    --   68.00  75.00   9.48   50
163  ω     71.00  96.00   0.50    0.05    --   68.00  74.00  25.96   50
164  ω     70.00  95.00   0.50    0.05    --   68.00  75.00 146.84   50
165  ω   -110.00 -76.00   0.50    0.05    --  -68.00 -57.00  34.01   68
166  ω     70.00  95.00   0.50    0.05    --   68.00  75.00  33.58   50
167  ω   -102.00 -76.00   0.50    0.05    --  -72.00 -74.00 -62.60   52
168  ω   -101.00 -75.00   0.50    0.05    --  -72.00 -74.00  10.73   52
169  ω   -100.00 -74.00   0.50    0.05    --  -72.00 -75.00-174.07   52
170  ω   -102.00 -76.00   0.50    0.05    --  -72.00 -72.00-109.88   52
171  ω   -108.00 -79.00   0.50    0.05    --  -72.00 -64.00 -89.08   58
172  ω   -104.00 -79.00   0.50    0.05    --  -72.00 -63.00 -34.84   50
173  ω   -119.00 -94.00   0.50    0.05    --  -75.27-125.00   0.00   50
174  ω   -118.00 -83.00   0.50    0.05    --  -76.00 -65.00-154.97   70
175  ω     40.00  66.00   0.50    0.05    --   78.42-125.00  30.00   52
176  ω     43.00  69.00   0.50    0.05    --   78.42-125.00 -30.00   52
177  ω     44.00  70.00   0.50    0.05    --   78.42-125.00 -60.00   52
178  ω   -107.00 -81.00   0.50    0.05    --  -80.00 -76.00-158.46   52
179  ω   -105.00 -80.00   0.50    0.05    --  -80.00 -78.00  28.77   50
180  ω   -106.00 -80.00   0.50    0.05    --  -80.00 -78.00 162.94   52
181  ω   -106.00 -80.00   0.50    0.05    --  -80.00 -79.00 -30.31   52
182  ω   -114.00 -82.00   0.50    0.05    --  -80.00 -77.00  32.04   64
183  ω   -109.00 -84.00   0.50    0.05    --  -80.00 -72.00  88.52   50
184  ω   -110.00 -81.00   0.50    0.05    --  -80.00 -77.00 -79.99   58
185  ω   -106.00 -80.00   0.50    0.05    --  -80.00 -79.00 171.86   52
186  ω   -105.00 -80.00   0.50    0.05    --  -80.00 -79.00 -26.42   50
187  ω   -105.00 -79.00   0.50    0.05    --  -80.00 -86.00 -89.73   52
188  ω   -105.00 -79.00   0.50    0.05    --  -80.00 -80.00  57.45   52
189  ω   -109.00 -80.00   0.50    0.05    --  -80.00 -79.00  13.55   58
190  ω   -112.00 -81.00   0.50    0.05    --  -80.00 -77.00 -71.75   62
191  ω   -105.00 -80.00   0.50    0.05    --  -80.00 -79.00  17.66   50
192  ω   -108.00 -82.00   0.50    0.05    --  -80.00 -76.00-144.23   52
193  ω   -109.00 -83.00   0.50    0.05    --  -80.00 -76.00 -61.97   52
194  ω   -110.00 -81.00   0.50    0.05    --  -80.00 -76.00 -16.27   58
195  ω   -108.00 -80.00   0.50    0.05    --  -80.00 -80.00 145.27   56
196  ω   -107.00 -81.00   0.50    0.05    --  -80.00 -76.00  76.09   52
197  ω   -107.00 -81.00   0.50    0.05    --  -80.00 -82.00 -38.22   52
198  ω   -104.00 -79.00   0.50    0.05    --  -80.00 -81.00 120.70   50
199  ω   -105.00 -80.00   0.50    0.05    --  -80.00 -78.00  46.53   50
200  ω   -108.00 -82.00   0.50    0.05    --  -80.00 -79.00-111.65   52
201  ω    -67.00 -40.00   0.50    0.05    --  -80.00 108.00 124.61   54
202  ω   -105.00 -79.00   0.50    0.05    --  -80.00 -82.00-126.02   52
203  ω    -62.00 -36.00   0.50    0.05    --  -80.00  60.00-168.68   52
204  ω   -107.00 -81.00   0.50    0.05    --  -80.00 -76.00  84.31   52
205  ω   -107.00 -80.00   0.50    0.05    --  -80.00 -79.00  51.85   54
206  ω   -104.00 -79.00   0.50    0.05    --  -80.00 -80.00-120.61   50
207  ω   -106.00 -80.00   0.50    0.05    --  -80.00 -78.00 148.69   52
208  ω   -111.00 -81.00   0.50    0.05    --  -80.00 -76.00 125.87   60
209  ω   -108.00 -82.00   0.50    0.05    --  -80.00 -76.00-175.42   52
210  ω   -115.00 -89.00   0.50    0.05    --  -80.00-155.00 -34.13   52
211  ω   -107.00 -79.00   0.50    0.05    --  -80.00 -80.00   6.81   56
212  ω   -119.00 -93.00   0.50    0.05    --  -80.00-141.00 -87.21   52
213  ω   -108.00 -82.00   0.50    0.05    --  -80.00 -76.00 104.22   52
214  ω   -107.00 -81.00   0.50    0.05    --  -80.00 -79.00-102.53   52
215  ω   -107.00 -82.00   0.50    0.05    --  -80.00 -75.00-153.79   50
216  ω   -108.00 -82.00   0.50    0.05    --  -80.00 -75.00 -88.17   52
217  ω    -62.00 -36.00   0.50    0.05    --  -80.00  60.00  97.71   52
218  ω     55.00  81.00   0.50    0.05    --   82.00  -3.00  61.54   52
219  ω     85.00 110.00   0.50    0.05    --   82.00  80.00  24.45   50
220  ω     44.00 110.00   0.50    0.05    --   82.00   1.00 134.71  132
221  ω     88.00 123.00   0.50    0.05    --   82.00-142.00 -70.97   70
222  ω     53.00  79.00   0.50    0.05    --   82.00-142.00 -70.97   52
223  ω     41.00  67.00   0.50    0.05    --   82.00  -4.00 -73.17   52
224  ω     64.00  90.00   0.50    0.05    --   82.00  20.00-151.97   52
225  ω     95.00 121.00   0.50    0.05    --   82.00   4.00-100.36   52
226  ω     44.00  78.00   0.50    0.05    --   82.00   4.00-100.36   68
227  ω     70.00 114.00   0.50    0.05    --   82.00  -2.00  -1.38   88
228  ω     42.00  68.00   0.50    0.05    --   82.00  -2.00  -1.38   52
229  ω     44.00  76.00   0.50    0.05    --   82.00-102.00 106.07   64
230  ω     95.00 120.00   0.50    0.05    --   82.00  -3.00  61.54   50
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix-Arc 150'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0405185000
_diffrn_orient_matrix_UB_12      0.0761666000
_diffrn_orient_matrix_UB_13      0.0245945000
_diffrn_orient_matrix_UB_21      -0.0620652000
_diffrn_orient_matrix_UB_22      0.0202596000
_diffrn_orient_matrix_UB_23      -0.0879291000
_diffrn_orient_matrix_UB_31      -0.1475382000
_diffrn_orient_matrix_UB_32      -0.0294166000
_diffrn_orient_matrix_UB_33      0.0031142000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Cu) X-ray Source'
_reflns_Friedel_coverage         0.927
_reflns_Friedel_fraction_full    1.000
_reflns_Friedel_fraction_max     0.987
_reflns_number_gt                12052
_reflns_number_total             12237
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_collection       'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_data_reduction        'CrysAlisPro 1.171.41.93a (Rigaku OD, 2020)'
_computing_molecular_graphics    'Olex2 1.5-alpha (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-alpha (Dolomanov et al., 2009)'
_computing_structure_refinement  'olex2.refine 1.5-alpha (Bourhis et al., 2015)'
_computing_structure_solution    'olex2.solve 1.5-alpha (Bourhis et al., 2015)'
_refine_diff_density_max         0.253
_refine_diff_density_min         -0.163
_refine_diff_density_rms         0.035
_refine_ls_abs_structure_details 
;
 Flack x determined using 5701 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.031(3)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     716
_refine_ls_number_reflns         12237
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0172
_refine_ls_R_factor_gt           0.0168
_refine_ls_restrained_S_all      1.040
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0250P)²+0.5195P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0426
_refine_ls_wR_factor_ref         0.0427
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Others
 Sof(H2B)=1-FVAR(1)
 Sof(H2A)=FVAR(1)
3.a Aromatic/amide H refined with riding coordinates:
 C61(H61), C50(H50), C49(H49), C17(H17), C10(H10), C53(H53), C11(H11),
 C43(H43), C48(H48), C52(H52), C51(H51), C22(H22), C21(H21), C56(H56), C33(H33),
  C31(H31), C32(H32), C47(H47), C60(H60), C14(H14), C57(H57), C65(H65),
 C18(H18), C12(H12), C72(H72), C7(H7), C13(H13), C55(H55), C30(H30), C36(H36),
 C16(H16), C34(H34), C27(H27), C58(H58), C45(H45), C59(H59), C8(H8), C20(H20),
 C54(H54), C24(H24), C9(H9), C19(H19), C62(H62), C68(H68), C46(H46), C67(H67),
 C23(H23), C26(H26), C35(H35), C69(H69), C44(H44), C28(H28), C66(H66), C29(H29),
  C25(H25), C63(H63), C15(H15), C64(H64), C70(H70), C71(H71)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ge3 Ge 1.00162(3) 0.63035(2) 0.61065(2) 0.02040(6) Uani 1 1 d . . . . .
Ge4 Ge 0.70990(3) 0.61448(2) 0.42416(2) 0.02326(6) Uani 1 1 d . . . . .
Ge2 Ge 0.14101(3) 0.31885(2) 0.06639(2) 0.02304(6) Uani 1 1 d . . . . .
Ge1 Ge 0.29938(3) 0.36846(2) -0.10177(2) 0.02432(6) Uani 1 1 d . . . . .
P2 P 0.79740(6) 0.56374(4) 0.54973(4) 0.02774(13) Uani 1 1 d . . . . .
P1 P 0.23334(9) 0.41464(4) 0.00773(4) 0.03553(15) Uani 1 1 d . . . . .
C37 C 1.1725(2) 0.58492(12) 0.59178(14) 0.0228(4) Uani 1 1 d . . . . .
C1 C 0.4500(2) 0.43404(13) -0.11626(13) 0.0261(5) Uani 1 1 d . . . . .
C61 C 1.0154(3) 0.56610(16) 0.29973(16) 0.0373(6) Uani 1 1 d . . . . .
H61 H 1.039189 0.524640 0.273132 0.045 Uiso 1 1 calc R U . . .
C50 C 1.0929(2) 0.61729(14) 0.88999(13) 0.0268(5) Uani 1 1 d . . . . .
H50 H 1.115793 0.614247 0.946180 0.032 Uiso 1 1 calc R U . . .
C39 C 0.9941(2) 0.73405(13) 0.58425(13) 0.0233(4) Uani 1 1 d . . . . .
C49 C 1.0166(3) 0.56165(14) 0.84416(14) 0.0273(5) Uani 1 1 d . . . . .
H49 H 0.987325 0.520514 0.869026 0.033 Uiso 1 1 calc R U . . .
C17 C 0.0012(3) 0.35971(14) -0.19998(14) 0.0299(5) Uani 1 1 d . . . . .
H17 H -0.022168 0.345826 -0.152584 0.036 Uiso 1 1 calc R U . . .
C42 C 0.6090(3) 0.70620(13) 0.42713(15) 0.0280(5) Uani 1 1 d . . . . .
C3 C 0.1421(3) 0.37603(13) -0.19811(14) 0.0263(5) Uani 1 1 d . . . . .
C38 C 1.0259(2) 0.62541(13) 0.72490(12) 0.0225(4) Uani 1 1 d . . . . .
C10 C 0.6757(3) 0.45644(16) -0.14680(16) 0.0346(6) Uani 1 1 d . . . . .
H10 H 0.760166 0.438119 -0.157876 0.042 Uiso 1 1 calc R U . . .
C2 C 0.3695(3) 0.26807(14) -0.09217(14) 0.0269(5) Uani 1 1 d . . . . .
C53 C 0.8760(3) 0.77645(14) 0.58830(15) 0.0298(5) Uani 1 1 d . . . . .
H53 H 0.796697 0.754054 0.601348 0.036 Uiso 1 1 calc R U . . .
C11 C 0.5735(3) 0.40803(15) -0.13354(15) 0.0318(5) Uani 1 1 d . . . . .
H11 H 0.588170 0.356905 -0.136310 0.038 Uiso 1 1 calc R U . . .
C43 C 1.1865(3) 0.57433(15) 0.51559(15) 0.0320(5) Uani 1 1 d . . . . .
H43 H 1.111003 0.588831 0.471403 0.038 Uiso 1 1 calc R U . . .
C5 C 0.2939(3) 0.27930(13) 0.15315(14) 0.0250(5) Uani 1 1 d . . . . .
C48 C 0.9827(2) 0.56553(13) 0.76197(14) 0.0251(5) Uani 1 1 d . . . . .
H48 H 0.929842 0.527192 0.730901 0.030 Uiso 1 1 calc R U . . .
C40 C 0.8617(2) 0.62484(14) 0.37085(13) 0.0258(4) Uani 1 1 d . . . . .
C52 C 1.1025(2) 0.68129(13) 0.77174(14) 0.0255(5) Uani 1 1 d . . . . .
H52 H 1.132210 0.722446 0.747086 0.031 Uiso 1 1 calc R U . . .
C51 C 1.1359(3) 0.67759(14) 0.85409(14) 0.0279(5) Uani 1 1 d . . . . .
H51 H 1.187818 0.716022 0.885479 0.034 Uiso 1 1 calc R U . . .
C22 C -0.0839(3) 0.23733(16) -0.04969(15) 0.0350(6) Uani 1 1 d . . . . .
H22 H -0.143348 0.278585 -0.049478 0.042 Uiso 1 1 calc R U . . .
C21 C 0.1740(3) 0.39629(14) -0.26817(14) 0.0318(5) Uani 1 1 d . . . . .
H21 H 0.270041 0.407679 -0.267513 0.038 Uiso 1 1 calc R U . . .
C56 C 1.1079(3) 0.84336(15) 0.55303(16) 0.0365(6) Uani 1 1 d . . . . .
H56 H 1.188315 0.866316 0.541723 0.044 Uiso 1 1 calc R U . . .
C33 C -0.1194(3) 0.38732(14) 0.21429(16) 0.0324(6) Uani 1 1 d . . . . .
H33 H -0.117446 0.382883 0.268687 0.039 Uiso 1 1 calc R U . . .
C31 C 0.2616(3) 0.22460(14) 0.20129(14) 0.0284(5) Uani 1 1 d . . . . .
H31 H 0.166438 0.206361 0.190553 0.034 Uiso 1 1 calc R U . . .
C32 C -0.0082(3) 0.35854(13) 0.18740(14) 0.0257(5) Uani 1 1 d . . . . .
H32 H 0.069068 0.334581 0.223695 0.031 Uiso 1 1 calc R U . . .
C47 C 1.2839(3) 0.56296(14) 0.65553(15) 0.0310(5) Uani 1 1 d . . . . .
H47 H 1.275509 0.569390 0.708014 0.037 Uiso 1 1 calc R U . . .
C60 C 1.0981(3) 0.62867(18) 0.30774(16) 0.0410(6) Uani 1 1 d . . . . .
H60 H 1.179573 0.629931 0.287143 0.049 Uiso 1 1 calc R U . . .
C14 C 0.4669(3) 0.12400(16) -0.08080(17) 0.0389(6) Uani 1 1 d . . . . .
H14 H 0.499552 0.074868 -0.076618 0.047 Uiso 1 1 calc R U . . .
C57 C 1.1096(3) 0.76863(14) 0.56666(15) 0.0302(5) Uani 1 1 d . . . . .
H57 H 1.190996 0.740766 0.563914 0.036 Uiso 1 1 calc R U . . .
C65 C 0.3661(3) 0.4523(2) 0.2690(2) 0.0563(10) Uani 1 1 d . . . . .
H65 H 0.295115 0.421087 0.237495 0.068 Uiso 1 1 calc R U . . .
C18 C -0.1062(3) 0.36355(15) -0.27097(16) 0.0357(6) Uani 1 1 d . . . . .
H18 H -0.202575 0.352358 -0.271975 0.043 Uiso 1 1 calc R U . . .
C12 C 0.4871(3) 0.24662(14) -0.03061(15) 0.0311(5) Uani 1 1 d . . . . .
H12 H 0.534614 0.281352 0.007763 0.037 Uiso 1 1 calc R U . . .
C6 C -0.0081(2) 0.36428(13) 0.10792(13) 0.0261(5) Uani 1 1 d . . . . .
C72 C 0.6097(3) 0.76148(16) 0.37333(18) 0.0405(6) Uani 1 1 d . . . . .
H72 H 0.662679 0.755589 0.335124 0.049 Uiso 1 1 calc R U . . .
C7 C 0.4304(3) 0.50954(14) -0.11415(16) 0.0327(5) Uani 1 1 d . . . . .
H7 H 0.346376 0.528278 -0.102906 0.039 Uiso 1 1 calc R U . . .
C13 C 0.5346(3) 0.17498(16) -0.02540(17) 0.0369(6) Uani 1 1 d . . . . .
H13 H 0.614413 0.160839 0.016624 0.044 Uiso 1 1 calc R U . . .
C4 C 0.0574(3) 0.23726(14) -0.00272(14) 0.0276(5) Uani 1 1 d . . . . .
C55 C 0.9896(3) 0.88443(14) 0.55586(15) 0.0349(6) Uani 1 1 d . . . . .
H55 H 0.987945 0.935443 0.545779 0.042 Uiso 1 1 calc R U . . .
C30 C 0.3667(3) 0.19651(15) 0.26471(16) 0.0345(6) Uani 1 1 d . . . . .
H30 H 0.342964 0.159933 0.297609 0.041 Uiso 1 1 calc R U . . .
C36 C -0.1231(3) 0.40056(15) 0.05653(16) 0.0353(6) Uani 1 1 d . . . . .
H36 H -0.124627 0.405805 0.002281 0.042 Uiso 1 1 calc R U . . .
C16 C 0.3033(3) 0.21620(15) -0.14801(15) 0.0326(5) Uani 1 1 d . . . . .
H16 H 0.224189 0.229934 -0.190613 0.039 Uiso 1 1 calc R U . . .
C34 C -0.2334(3) 0.42250(15) 0.16243(17) 0.0354(6) Uani 1 1 d . . . . .
H34 H -0.309582 0.441909 0.181033 0.043 Uiso 1 1 calc R U . . .
C27 C 0.4347(3) 0.30369(14) 0.16904(16) 0.0321(5) Uani 1 1 d . . . . .
H27 H 0.459180 0.340341 0.136495 0.038 Uiso 1 1 calc R U . . .
C58 C 0.9454(3) 0.68780(14) 0.37707(14) 0.0310(5) Uani 1 1 d . . . . .
H58 H 0.921930 0.729781 0.402993 0.037 Uiso 1 1 calc R U . . .
C45 C 1.4195(3) 0.52190(14) 0.56762(18) 0.0366(6) Uani 1 1 d . . . . .
H45 H 1.504044 0.500611 0.559515 0.044 Uiso 1 1 calc R U . . .
C59 C 1.0628(3) 0.68924(16) 0.34546(17) 0.0387(6) Uani 1 1 d . . . . .
H59 H 1.119236 0.732271 0.349876 0.046 Uiso 1 1 calc R U . . .
C8 C 0.5320(3) 0.55766(15) -0.12826(17) 0.0359(6) Uani 1 1 d . . . . .
H8 H 0.516793 0.608855 -0.127109 0.043 Uiso 1 1 calc R U . . .
C20 C 0.0675(3) 0.40010(15) -0.33897(15) 0.0361(6) Uani 1 1 d . . . . .
H20 H 0.090674 0.413906 -0.386447 0.043 Uiso 1 1 calc R U . . .
C54 C 0.8737(3) 0.85104(15) 0.57342(16) 0.0362(6) Uani 1 1 d . . . . .
H54 H 0.792220 0.879154 0.575328 0.043 Uiso 1 1 calc R U . . .
C41 C 0.5706(3) 0.54472(14) 0.36289(15) 0.0284(5) Uani 1 1 d . . . . .
C24 C -0.0536(3) 0.11606(19) -0.09613(16) 0.0463(7) Uani 1 1 d . . . . .
H24 H -0.091313 0.074879 -0.127848 0.056 Uiso 1 1 calc R U . . .
C9 C 0.6550(3) 0.53092(16) -0.14394(16) 0.0344(6) Uani 1 1 d . . . . .
H9 H 0.725360 0.563678 -0.152749 0.041 Uiso 1 1 calc R U . . .
C19 C -0.0719(3) 0.38376(14) -0.34012(15) 0.0358(6) Uani 1 1 d . . . . .
H19 H -0.145048 0.386365 -0.388557 0.043 Uiso 1 1 calc R U . . .
C62 C 0.8971(3) 0.56424(14) 0.33092(14) 0.0297(5) Uani 1 1 d . . . . .
H62 H 0.839758 0.521430 0.325055 0.036 Uiso 1 1 calc R U . . .
C68 C 0.5291(3) 0.71574(15) 0.48214(19) 0.0390(6) Uani 1 1 d . . . . .
H68 H 0.526983 0.678232 0.519341 0.047 Uiso 1 1 calc R U . . .
C46 C 1.4070(3) 0.53181(15) 0.64363(18) 0.0385(6) Uani 1 1 d . . . . .
H46 H 1.482613 0.517298 0.687773 0.046 Uiso 1 1 calc R U . . .
C67 C 0.5504(3) 0.47521(15) 0.38849(18) 0.0362(6) Uani 1 1 d . . . . .
H67 H 0.607185 0.458646 0.438435 0.043 Uiso 1 1 calc R U . . .
C23 C -0.1383(3) 0.17713(19) -0.09690(16) 0.0434(7) Uani 1 1 d . . . . .
H23 H -0.233776 0.178016 -0.129727 0.052 Uiso 1 1 calc R U . . .
C26 C 0.1409(3) 0.17530(15) -0.00329(16) 0.0343(6) Uani 1 1 d . . . . .
H26 H 0.237215 0.174328 0.028358 0.041 Uiso 1 1 calc R U . . .
C35 C -0.2352(3) 0.42910(16) 0.08305(17) 0.0390(6) Uani 1 1 d . . . . .
H35 H -0.312847 0.453037 0.047003 0.047 Uiso 1 1 calc R U . . .
C69 C 0.4528(3) 0.77964(17) 0.4827(2) 0.0511(8) Uani 1 1 d . . . . .
H69 H 0.397995 0.785548 0.519996 0.061 Uiso 1 1 calc R U . . .
C44 C 1.3094(3) 0.54283(16) 0.50292(18) 0.0375(6) Uani 1 1 d . . . . .
H44 H 1.317805 0.535749 0.450525 0.045 Uiso 1 1 calc R U . . .
C28 C 0.5400(3) 0.27505(16) 0.23206(19) 0.0409(6) Uani 1 1 d . . . . .
H28 H 0.635845 0.292168 0.242232 0.049 Uiso 1 1 calc R U . . .
C66 C 0.4471(4) 0.42900(18) 0.3416(2) 0.0511(8) Uani 1 1 d . . . . .
H66 H 0.433025 0.381474 0.360012 0.061 Uiso 1 1 calc R U . . .
C29 C 0.5059(3) 0.22189(16) 0.27983(17) 0.0395(6) Uani 1 1 d . . . . .
H29 H 0.577989 0.202722 0.323104 0.047 Uiso 1 1 calc R U . . .
C25 C 0.0855(3) 0.11511(17) -0.04929(18) 0.0443(7) Uani 1 1 d . . . . .
H25 H 0.143513 0.073127 -0.048523 0.053 Uiso 1 1 calc R U . . .
C63 C 0.4879(3) 0.56730(18) 0.28852(17) 0.0437(7) Uani 1 1 d . . . . .
H63 H 0.500917 0.614866 0.269876 0.052 Uiso 1 1 calc R U . . .
C15 C 0.3520(3) 0.14431(15) -0.14206(17) 0.0384(6) Uani 1 1 d . . . . .
H15 H 0.305832 0.109268 -0.180406 0.046 Uiso 1 1 calc R U . . .
C64 C 0.3870(4) 0.5209(2) 0.2416(2) 0.0563(9) Uani 1 1 d . . . . .
H64 H 0.332412 0.536292 0.190732 0.068 Uiso 1 1 calc R U . . .
C70 C 0.4559(3) 0.83432(16) 0.4299(2) 0.0519(8) Uani 1 1 d . . . . .
H70 H 0.404489 0.878269 0.431282 0.062 Uiso 1 1 calc R U . . .
C71 C 0.5331(4) 0.82600(17) 0.3748(2) 0.0513(8) Uani 1 1 d . . . . .
H71 H 0.534268 0.863891 0.337840 0.062 Uiso 1 1 calc R U . . .
H2A H 0.857(7) 0.500(4) 0.536(4) 0.04(2) Uiso 0.48(6) 1 d . . P A 1
H2B H 0.733(5) 0.595(3) 0.585(3) 0.020(16) Uiso 0.52(6) 1 d . . P A 2
H1 H 0.118(4) 0.437(2) -0.031(2) 0.058(10) Uiso 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ge3 P2 2.3263(6) . ?
Ge3 C37 1.956(2) . ?
Ge3 C39 1.951(2) . ?
Ge3 C38 1.951(2) . ?
Ge4 P2 2.3276(6) . ?
Ge4 C42 1.950(2) . ?
Ge4 C40 1.947(2) . ?
Ge4 C41 1.957(2) . ?
Ge2 P1 2.3269(7) . ?
Ge2 C5 1.956(2) . ?
Ge2 C6 1.964(2) . ?
Ge2 C4 1.957(2) . ?
Ge1 P1 2.3325(7) . ?
Ge1 C1 1.956(2) . ?
Ge1 C3 1.953(2) . ?
Ge1 C2 1.951(2) . ?
P2 H2A 1.35(7) . ?
P2 H2B 1.14(5) . ?
P1 H1 1.21(4) . ?
C37 C43 1.388(3) . ?
C37 C47 1.389(3) . ?
C1 C11 1.392(3) . ?
C1 C7 1.397(4) . ?
C61 H61 0.9500 . ?
C61 C60 1.383(4) . ?
C61 C62 1.394(4) . ?
C50 H50 0.9500 . ?
C50 C49 1.382(3) . ?
C50 C51 1.388(4) . ?
C39 C53 1.398(3) . ?
C39 C57 1.389(3) . ?
C49 H49 0.9500 . ?
C49 C48 1.389(3) . ?
C17 H17 0.9500 . ?
C17 C3 1.388(3) . ?
C17 C18 1.394(3) . ?
C42 C72 1.383(4) . ?
C42 C68 1.396(4) . ?
C3 C21 1.391(3) . ?
C38 C48 1.393(3) . ?
C38 C52 1.395(3) . ?
C10 H10 0.9500 . ?
C10 C11 1.392(4) . ?
C10 C9 1.381(4) . ?
C2 C12 1.400(3) . ?
C2 C16 1.391(4) . ?
C53 H53 0.9500 . ?
C53 C54 1.390(4) . ?
C11 H11 0.9500 . ?
C43 H43 0.9500 . ?
C43 C44 1.391(4) . ?
C5 C31 1.397(3) . ?
C5 C27 1.389(3) . ?
C48 H48 0.9500 . ?
C40 C58 1.396(3) . ?
C40 C62 1.401(3) . ?
C52 H52 0.9500 . ?
C52 C51 1.392(3) . ?
C51 H51 0.9500 . ?
C22 H22 0.9500 . ?
C22 C4 1.396(4) . ?
C22 C23 1.394(4) . ?
C21 H21 0.9500 . ?
C21 C20 1.387(4) . ?
C56 H56 0.9500 . ?
C56 C57 1.388(4) . ?
C56 C55 1.382(4) . ?
C33 H33 0.9500 . ?
C33 C32 1.388(4) . ?
C33 C34 1.387(4) . ?
C31 H31 0.9500 . ?
C31 C30 1.390(4) . ?
C32 H32 0.9500 . ?
C32 C6 1.394(3) . ?
C47 H47 0.9500 . ?
C47 C46 1.385(4) . ?
C60 H60 0.9500 . ?
C60 C59 1.379(4) . ?
C14 H14 0.9500 . ?
C14 C13 1.380(4) . ?
C14 C15 1.375(4) . ?
C57 H57 0.9500 . ?
C65 H65 0.9500 . ?
C65 C66 1.372(5) . ?
C65 C64 1.377(6) . ?
C18 H18 0.9500 . ?
C18 C19 1.387(4) . ?
C12 H12 0.9500 . ?
C12 C13 1.385(4) . ?
C6 C36 1.399(3) . ?
C72 H72 0.9500 . ?
C72 C71 1.399(4) . ?
C7 H7 0.9500 . ?
C7 C8 1.390(4) . ?
C13 H13 0.9500 . ?
C4 C26 1.395(4) . ?
C55 H55 0.9500 . ?
C55 C54 1.381(4) . ?
C30 H30 0.9500 . ?
C30 C29 1.383(4) . ?
C36 H36 0.9500 . ?
C36 C35 1.390(4) . ?
C16 H16 0.9500 . ?
C16 C15 1.393(4) . ?
C34 H34 0.9500 . ?
C34 C35 1.389(4) . ?
C27 H27 0.9500 . ?
C27 C28 1.390(4) . ?
C58 H58 0.9500 . ?
C58 C59 1.390(4) . ?
C45 H45 0.9500 . ?
C45 C46 1.379(4) . ?
C45 C44 1.387(4) . ?
C59 H59 0.9500 . ?
C8 H8 0.9500 . ?
C8 C9 1.380(4) . ?
C20 H20 0.9500 . ?
C20 C19 1.377(4) . ?
C54 H54 0.9500 . ?
C41 C67 1.380(4) . ?
C41 C63 1.397(4) . ?
C24 H24 0.9500 . ?
C24 C23 1.384(5) . ?
C24 C25 1.377(4) . ?
C9 H9 0.9500 . ?
C19 H19 0.9500 . ?
C62 H62 0.9500 . ?
C68 H68 0.9500 . ?
C68 C69 1.385(4) . ?
C46 H46 0.9500 . ?
C67 H67 0.9500 . ?
C67 C66 1.397(4) . ?
C23 H23 0.9500 . ?
C26 H26 0.9500 . ?
C26 C25 1.386(4) . ?
C35 H35 0.9500 . ?
C69 H69 0.9500 . ?
C69 C70 1.368(5) . ?
C44 H44 0.9500 . ?
C28 H28 0.9500 . ?
C28 C29 1.379(4) . ?
C66 H66 0.9500 . ?
C29 H29 0.9500 . ?
C25 H25 0.9500 . ?
C63 H63 0.9500 . ?
C63 C64 1.387(4) . ?
C15 H15 0.9500 . ?
C64 H64 0.9500 . ?
C70 H70 0.9500 . ?
C70 C71 1.375(5) . ?
C71 H71 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C37 Ge3 P2 110.69(7) . . ?
C39 Ge3 P2 115.34(7) . . ?
C39 Ge3 C37 110.75(10) . . ?
C39 Ge3 C38 105.92(10) . . ?
C38 Ge3 P2 107.55(7) . . ?
C38 Ge3 C37 106.00(9) . . ?
C42 Ge4 P2 112.22(8) . . ?
C42 Ge4 C41 107.45(10) . . ?
C40 Ge4 P2 111.04(7) . . ?
C40 Ge4 C42 112.05(11) . . ?
C40 Ge4 C41 107.39(10) . . ?
C41 Ge4 P2 106.34(8) . . ?
C5 Ge2 P1 108.74(7) . . ?
C5 Ge2 C6 110.41(10) . . ?
C5 Ge2 C4 107.48(10) . . ?
C6 Ge2 P1 104.44(7) . . ?
C4 Ge2 P1 116.59(7) . . ?
C4 Ge2 C6 109.13(10) . . ?
C1 Ge1 P1 105.04(7) . . ?
C3 Ge1 P1 111.24(7) . . ?
C3 Ge1 C1 106.35(10) . . ?
C2 Ge1 P1 115.83(7) . . ?
C2 Ge1 C1 109.60(10) . . ?
C2 Ge1 C3 108.35(10) . . ?
Ge3 P2 Ge4 105.97(2) . . ?
Ge3 P2 H2A 100(3) . . ?
Ge3 P2 H2B 91(2) . . ?
Ge4 P2 H2A 104(3) . . ?
Ge4 P2 H2B 101(2) . . ?
Ge2 P1 Ge1 108.03(3) . . ?
Ge2 P1 H1 95.3(17) . . ?
Ge1 P1 H1 94.6(17) . . ?
C43 C37 Ge3 121.57(18) . . ?
C43 C37 C47 118.5(2) . . ?
C47 C37 Ge3 119.89(18) . . ?
C11 C1 Ge1 122.01(19) . . ?
C11 C1 C7 118.3(2) . . ?
C7 C1 Ge1 119.54(18) . . ?
C60 C61 H61 120.2 . . ?
C60 C61 C62 119.6(3) . . ?
C62 C61 H61 120.2 . . ?
C49 C50 H50 119.9 . . ?
C49 C50 C51 120.1(2) . . ?
C51 C50 H50 119.9 . . ?
C53 C39 Ge3 120.55(18) . . ?
C57 C39 Ge3 120.95(18) . . ?
C57 C39 C53 118.3(2) . . ?
C50 C49 H49 119.8 . . ?
C50 C49 C48 120.4(2) . . ?
C48 C49 H49 119.8 . . ?
C3 C17 H17 119.8 . . ?
C3 C17 C18 120.4(2) . . ?
C18 C17 H17 119.8 . . ?
C72 C42 Ge4 121.3(2) . . ?
C72 C42 C68 118.7(2) . . ?
C68 C42 Ge4 119.9(2) . . ?
C17 C3 Ge1 122.75(18) . . ?
C17 C3 C21 118.8(2) . . ?
C21 C3 Ge1 118.37(18) . . ?
C48 C38 Ge3 122.93(17) . . ?
C48 C38 C52 118.8(2) . . ?
C52 C38 Ge3 117.92(17) . . ?
C11 C10 H10 119.8 . . ?
C9 C10 H10 119.8 . . ?
C9 C10 C11 120.4(2) . . ?
C12 C2 Ge1 121.59(19) . . ?
C16 C2 Ge1 119.87(18) . . ?
C16 C2 C12 118.5(2) . . ?
C39 C53 H53 119.7 . . ?
C54 C53 C39 120.6(3) . . ?
C54 C53 H53 119.7 . . ?
C1 C11 C10 120.4(2) . . ?
C1 C11 H11 119.8 . . ?
C10 C11 H11 119.8 . . ?
C37 C43 H43 119.5 . . ?
C37 C43 C44 121.1(2) . . ?
C44 C43 H43 119.5 . . ?
C31 C5 Ge2 119.26(18) . . ?
C27 C5 Ge2 122.41(19) . . ?
C27 C5 C31 118.3(2) . . ?
C49 C48 C38 120.3(2) . . ?
C49 C48 H48 119.9 . . ?
C38 C48 H48 119.9 . . ?
C58 C40 Ge4 122.60(18) . . ?
C58 C40 C62 118.6(2) . . ?
C62 C40 Ge4 118.47(18) . . ?
C38 C52 H52 119.5 . . ?
C51 C52 C38 120.9(2) . . ?
C51 C52 H52 119.5 . . ?
C50 C51 C52 119.4(2) . . ?
C50 C51 H51 120.3 . . ?
C52 C51 H51 120.3 . . ?
C4 C22 H22 119.8 . . ?
C23 C22 H22 119.8 . . ?
C23 C22 C4 120.3(3) . . ?
C3 C21 H21 119.5 . . ?
C20 C21 C3 121.0(2) . . ?
C20 C21 H21 119.5 . . ?
C57 C56 H56 119.9 . . ?
C55 C56 H56 119.9 . . ?
C55 C56 C57 120.2(3) . . ?
C32 C33 H33 119.7 . . ?
C34 C33 H33 119.7 . . ?
C34 C33 C32 120.6(2) . . ?
C5 C31 H31 119.6 . . ?
C30 C31 C5 120.9(2) . . ?
C30 C31 H31 119.6 . . ?
C33 C32 H32 119.5 . . ?
C33 C32 C6 121.0(2) . . ?
C6 C32 H32 119.5 . . ?
C37 C47 H47 119.5 . . ?
C46 C47 C37 120.9(2) . . ?
C46 C47 H47 119.5 . . ?
C61 C60 H60 119.8 . . ?
C59 C60 C61 120.3(2) . . ?
C59 C60 H60 119.8 . . ?
C13 C14 H14 120.0 . . ?
C15 C14 H14 120.0 . . ?
C15 C14 C13 120.0(3) . . ?
C39 C57 H57 119.5 . . ?
C56 C57 C39 120.9(2) . . ?
C56 C57 H57 119.5 . . ?
C66 C65 H65 119.8 . . ?
C66 C65 C64 120.4(3) . . ?
C64 C65 H65 119.8 . . ?
C17 C18 H18 120.1 . . ?
C19 C18 C17 119.7(2) . . ?
C19 C18 H18 120.1 . . ?
C2 C12 H12 119.9 . . ?
C13 C12 C2 120.3(2) . . ?
C13 C12 H12 119.9 . . ?
C32 C6 Ge2 122.12(17) . . ?
C32 C6 C36 117.7(2) . . ?
C36 C6 Ge2 120.06(18) . . ?
C42 C72 H72 119.7 . . ?
C42 C72 C71 120.5(3) . . ?
C71 C72 H72 119.7 . . ?
C1 C7 H7 119.5 . . ?
C8 C7 C1 121.0(2) . . ?
C8 C7 H7 119.5 . . ?
C14 C13 C12 120.5(2) . . ?
C14 C13 H13 119.8 . . ?
C12 C13 H13 119.8 . . ?
C22 C4 Ge2 122.9(2) . . ?
C26 C4 Ge2 118.69(18) . . ?
C26 C4 C22 118.4(2) . . ?
C56 C55 H55 120.1 . . ?
C54 C55 C56 119.7(2) . . ?
C54 C55 H55 120.1 . . ?
C31 C30 H30 120.1 . . ?
C29 C30 C31 119.9(3) . . ?
C29 C30 H30 120.1 . . ?
C6 C36 H36 119.2 . . ?
C35 C36 C6 121.5(2) . . ?
C35 C36 H36 119.2 . . ?
C2 C16 H16 119.7 . . ?
C2 C16 C15 120.6(2) . . ?
C15 C16 H16 119.7 . . ?
C33 C34 H34 120.3 . . ?
C33 C34 C35 119.4(2) . . ?
C35 C34 H34 120.3 . . ?
C5 C27 H27 119.6 . . ?
C5 C27 C28 120.7(3) . . ?
C28 C27 H27 119.6 . . ?
C40 C58 H58 119.9 . . ?
C59 C58 C40 120.2(2) . . ?
C59 C58 H58 119.9 . . ?
C46 C45 H45 119.8 . . ?
C46 C45 C44 120.4(2) . . ?
C44 C45 H45 119.8 . . ?
C60 C59 C58 120.5(3) . . ?
C60 C59 H59 119.8 . . ?
C58 C59 H59 119.8 . . ?
C7 C8 H8 120.1 . . ?
C9 C8 C7 119.9(3) . . ?
C9 C8 H8 120.1 . . ?
C21 C20 H20 120.2 . . ?
C19 C20 C21 119.7(2) . . ?
C19 C20 H20 120.2 . . ?
C53 C54 H54 119.9 . . ?
C55 C54 C53 120.2(3) . . ?
C55 C54 H54 119.9 . . ?
C67 C41 Ge4 124.1(2) . . ?
C67 C41 C63 118.7(3) . . ?
C63 C41 Ge4 117.2(2) . . ?
C23 C24 H24 120.0 . . ?
C25 C24 H24 120.0 . . ?
C25 C24 C23 119.9(3) . . ?
C10 C9 H9 120.1 . . ?
C8 C9 C10 119.9(2) . . ?
C8 C9 H9 120.1 . . ?
C18 C19 H19 119.8 . . ?
C20 C19 C18 120.4(2) . . ?
C20 C19 H19 119.8 . . ?
C61 C62 C40 120.7(2) . . ?
C61 C62 H62 119.6 . . ?
C40 C62 H62 119.6 . . ?
C42 C68 H68 119.9 . . ?
C69 C68 C42 120.3(3) . . ?
C69 C68 H68 119.9 . . ?
C47 C46 H46 120.1 . . ?
C45 C46 C47 119.9(3) . . ?
C45 C46 H46 120.1 . . ?
C41 C67 H67 119.7 . . ?
C41 C67 C66 120.6(3) . . ?
C66 C67 H67 119.7 . . ?
C22 C23 H23 119.9 . . ?
C24 C23 C22 120.2(3) . . ?
C24 C23 H23 119.9 . . ?
C4 C26 H26 119.5 . . ?
C25 C26 C4 121.0(3) . . ?
C25 C26 H26 119.5 . . ?
C36 C35 H35 120.1 . . ?
C34 C35 C36 119.8(3) . . ?
C34 C35 H35 120.1 . . ?
C68 C69 H69 119.8 . . ?
C70 C69 C68 120.4(3) . . ?
C70 C69 H69 119.8 . . ?
C43 C44 H44 120.4 . . ?
C45 C44 C43 119.3(3) . . ?
C45 C44 H44 120.4 . . ?
C27 C28 H28 119.9 . . ?
C29 C28 C27 120.2(3) . . ?
C29 C28 H28 119.9 . . ?
C65 C66 C67 119.9(3) . . ?
C65 C66 H66 120.0 . . ?
C67 C66 H66 120.0 . . ?
C30 C29 H29 120.0 . . ?
C28 C29 C30 119.9(3) . . ?
C28 C29 H29 120.0 . . ?
C24 C25 C26 120.1(3) . . ?
C24 C25 H25 120.0 . . ?
C26 C25 H25 120.0 . . ?
C41 C63 H63 119.7 . . ?
C64 C63 C41 120.6(3) . . ?
C64 C63 H63 119.7 . . ?
C14 C15 C16 120.1(3) . . ?
C14 C15 H15 119.9 . . ?
C16 C15 H15 119.9 . . ?
C65 C64 C63 119.9(3) . . ?
C65 C64 H64 120.0 . . ?
C63 C64 H64 120.0 . . ?
C69 C70 H70 119.8 . . ?
C69 C70 C71 120.4(3) . . ?
C71 C70 H70 119.8 . . ?
C72 C71 H71 120.2 . . ?
C70 C71 C72 119.7(3) . . ?
C70 C71 H71 120.2 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ge3 C37 C43 C44 179.1(2) . . . . ?
Ge3 C37 C47 C46 -178.9(2) . . . . ?
Ge3 C39 C53 C54 176.7(2) . . . . ?
Ge3 C39 C57 C56 -175.7(2) . . . . ?
Ge3 C38 C48 C49 173.00(18) . . . . ?
Ge3 C38 C52 C51 -173.63(18) . . . . ?
Ge4 C42 C72 C71 178.0(2) . . . . ?
Ge4 C42 C68 C69 -177.6(2) . . . . ?
Ge4 C40 C58 C59 172.5(2) . . . . ?
Ge4 C40 C62 C61 -172.5(2) . . . . ?
Ge4 C41 C67 C66 179.1(2) . . . . ?
Ge4 C41 C63 C64 180.0(2) . . . . ?
Ge2 C5 C31 C30 -178.4(2) . . . . ?
Ge2 C5 C27 C28 179.0(2) . . . . ?
Ge2 C6 C36 C35 175.7(2) . . . . ?
Ge2 C4 C26 C25 178.0(2) . . . . ?
Ge1 C1 C11 C10 177.26(19) . . . . ?
Ge1 C1 C7 C8 -176.7(2) . . . . ?
Ge1 C3 C21 C20 177.7(2) . . . . ?
Ge1 C2 C12 C13 -179.9(2) . . . . ?
Ge1 C2 C16 C15 180.0(2) . . . . ?
C37 C43 C44 C45 -0.1(4) . . . . ?
C37 C47 C46 C45 -0.4(4) . . . . ?
C1 C7 C8 C9 -0.6(4) . . . . ?
C61 C60 C59 C58 1.1(4) . . . . ?
C50 C49 C48 C38 0.4(4) . . . . ?
C39 C53 C54 C55 -1.2(4) . . . . ?
C49 C50 C51 C52 -0.4(4) . . . . ?
C17 C3 C21 C20 -0.1(4) . . . . ?
C17 C18 C19 C20 -0.1(4) . . . . ?
C42 C72 C71 C70 -0.3(5) . . . . ?
C42 C68 C69 C70 -0.6(5) . . . . ?
C3 C17 C18 C19 0.0(4) . . . . ?
C3 C21 C20 C19 0.1(4) . . . . ?
C38 C52 C51 C50 0.2(4) . . . . ?
C2 C12 C13 C14 0.1(4) . . . . ?
C2 C16 C15 C14 -0.3(4) . . . . ?
C53 C39 C57 C56 -0.3(4) . . . . ?
C11 C1 C7 C8 -0.5(4) . . . . ?
C11 C10 C9 C8 -0.3(4) . . . . ?
C43 C37 C47 C46 0.6(4) . . . . ?
C5 C31 C30 C29 -1.1(4) . . . . ?
C5 C27 C28 C29 -0.1(4) . . . . ?
C48 C38 C52 C51 0.2(3) . . . . ?
C40 C58 C59 C60 0.0(4) . . . . ?
C52 C38 C48 C49 -0.5(3) . . . . ?
C51 C50 C49 C48 0.1(4) . . . . ?
C22 C4 C26 C25 0.0(4) . . . . ?
C21 C20 C19 C18 0.0(4) . . . . ?
C56 C55 C54 C53 0.1(4) . . . . ?
C33 C32 C6 Ge2 -176.02(18) . . . . ?
C33 C32 C6 C36 0.6(4) . . . . ?
C33 C34 C35 C36 -0.1(4) . . . . ?
C31 C5 C27 C28 -0.9(4) . . . . ?
C31 C30 C29 C28 0.1(4) . . . . ?
C32 C33 C34 C35 -0.3(4) . . . . ?
C32 C6 C36 C35 -1.0(4) . . . . ?
C47 C37 C43 C44 -0.4(4) . . . . ?
C60 C61 C62 C40 -0.5(4) . . . . ?
C57 C39 C53 C54 1.3(4) . . . . ?
C57 C56 C55 C54 0.9(4) . . . . ?
C18 C17 C3 Ge1 -177.7(2) . . . . ?
C18 C17 C3 C21 0.1(4) . . . . ?
C12 C2 C16 C15 0.9(4) . . . . ?
C6 C36 C35 C34 0.7(4) . . . . ?
C72 C42 C68 C69 -0.3(4) . . . . ?
C7 C1 C11 C10 1.2(4) . . . . ?
C7 C8 C9 C10 1.0(4) . . . . ?
C13 C14 C15 C16 -0.4(4) . . . . ?
C4 C22 C23 C24 1.6(4) . . . . ?
C4 C26 C25 C24 0.7(4) . . . . ?
C55 C56 C57 C39 -0.8(4) . . . . ?
C16 C2 C12 C13 -0.8(4) . . . . ?
C34 C33 C32 C6 0.1(4) . . . . ?
C27 C5 C31 C30 1.5(4) . . . . ?
C27 C28 C29 C30 0.5(4) . . . . ?
C58 C40 C62 C61 1.5(4) . . . . ?
C41 C67 C66 C65 0.8(4) . . . . ?
C41 C63 C64 C65 1.2(5) . . . . ?
C9 C10 C11 C1 -0.8(4) . . . . ?
C62 C61 C60 C59 -0.8(4) . . . . ?
C62 C40 C58 C59 -1.3(4) . . . . ?
C68 C42 C72 C71 0.7(4) . . . . ?
C68 C69 C70 C71 1.0(5) . . . . ?
C46 C45 C44 C43 0.4(4) . . . . ?
C67 C41 C63 C64 0.4(4) . . . . ?
C23 C22 C4 Ge2 -179.06(19) . . . . ?
C23 C22 C4 C26 -1.2(4) . . . . ?
C23 C24 C25 C26 -0.3(4) . . . . ?
C69 C70 C71 C72 -0.6(5) . . . . ?
C44 C45 C46 C47 -0.1(4) . . . . ?
C66 C65 C64 C63 -1.7(5) . . . . ?
C25 C24 C23 C22 -0.8(4) . . . . ?
C63 C41 C67 C66 -1.3(4) . . . . ?
C15 C14 C13 C12 0.5(4) . . . . ?
C64 C65 C66 C67 0.7(5) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.270
_oxdiff_exptl_absorpt_empirical_full_min 0.766
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent'
