# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_p
_database_code_depnum_ccdc_archive 'CCDC 2471148'
loop_
_audit_author_name
_audit_author_address
'Fuling Liu'
;Linyi university
China
;
_audit_update_record             
;
2025-07-09 deposited with the CCDC.	2025-11-14 downloaded from the CCDC.
;
_audit_creation_date             2025-04-28
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C136 H112 Au9 Fe4 P8, Cl'
_chemical_formula_sum            'C136 H112 Au9 Cl Fe4 P8'
_chemical_formula_weight         4025.56
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe -1.1336 3.1974 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   14.3461(3)
_cell_length_b                   39.2560(8)
_cell_length_c                   26.9606(5)
_cell_angle_alpha                90
_cell_angle_beta                 92.3430(10)
_cell_angle_gamma                90
_cell_volume                     15170.7(5)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9597
_cell_measurement_temperature    223.00
_cell_measurement_theta_max      72.61
_cell_measurement_theta_min      3.28
_shelx_estimated_absorpt_T_max   0.081
_shelx_estimated_absorpt_T_min   0.052
_exptl_absorpt_coefficient_mu    20.136
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.7469
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   ?
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.763
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             7520
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.25
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0426
_diffrn_reflns_av_unetI/netI     0.0358
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.984
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       47
_diffrn_reflns_limit_k_min       -48
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            116027
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.984
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         73.049
_diffrn_reflns_theta_min         2.251
_diffrn_ambient_temperature      223.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_source_current           1.1
_diffrn_source_power             0.05500000000000001
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                25713
_reflns_number_total             29883
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'olex2.solve 1.5 (Bourhis et al., 2015)'
_refine_diff_density_max         1.356
_refine_diff_density_min         -1.033
_refine_diff_density_rms         0.115
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1503
_refine_ls_number_reflns         29883
_refine_ls_number_restraints     332
_refine_ls_R_factor_all          0.0401
_refine_ls_R_factor_gt           0.0340
_refine_ls_restrained_S_all      1.026
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0253P)²+53.2621P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0766
_refine_ls_wR_factor_ref         0.0789
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2. Restrained distances
 C75-C76 \\sim C75-C58A
 with sigma of 0.02
 C75-C80 \\sim C75-C1B
 with sigma of 0.02
 C76-C77 \\sim C58A-C84A
 with sigma of 0.02
 C77-C78 \\sim C84A-C137
 with sigma of 0.02
 C80-C79 \\sim C1B-C1A
 with sigma of 0.02
 C78-C79 \\sim C137-C1A
 with sigma of 0.02
 C77-C79 \\sim C84A-C1A
 with sigma of 0.04
 C80-C78 \\sim C1B-C137
 with sigma of 0.04
 C75-C77 \\sim C75-C84A
 with sigma of 0.04
 C75-C79 \\sim C75-C1A
 with sigma of 0.04
 C76-C78 \\sim C58A-C137
 with sigma of 0.04
 C7-C11 \\sim C7-C1C
 with sigma of 0.04
 C12-C10 \\sim C138-C1D
 with sigma of 0.04
 C8-C9 \\sim C97A-C1E
 with sigma of 0.02
 C12-C11 \\sim C138-C1C
 with sigma of 0.02
 C8-C10 \\sim C97A-C1D
 with sigma of 0.04
 C9-C10 \\sim C1E-C1D
 with sigma of 0.02
 C9-C11 \\sim C1E-C1C
 with sigma of 0.04
 C11-C10 \\sim C1C-C1D
 with sigma of 0.02
 C7-C9 \\sim C7-C1E
 with sigma of 0.04
 C7-C8 \\sim C7-C97A
 with sigma of 0.02
 C7-C12 \\sim C7-C138
 with sigma of 0.02
3. Restrained planarity
 P2, C75, C1B, C1A, C137, C84A, C58A
 with sigma of 0.01
4. Uiso/Uaniso restraints and constraints
C75 \\sim C76 \\sim C77 \\sim C80 \\sim C78 \\sim C79 \\sim C58A \\sim C84A
\\sim C137 \\sim C1A \\sim C1B: within 2A with sigma of 0.001 and sigma for
terminal atoms of 0.002 within 2A
C7 \\sim C8 \\sim C12 \\sim C9 \\sim C11 \\sim C10 \\sim C138 \\sim C1C \\sim
C1D \\sim C1E \\sim C97A: within 2A with sigma of 0.001 and sigma for terminal
atoms of 0.002 within 2A
5. Others
 Sof(C58A)=Sof(H58A)=Sof(C84A)=Sof(H84A)=Sof(C137)=Sof(H137)=Sof(C1A)=Sof(H1A)=
 Sof(C1B)=Sof(H1B)=1-FVAR(1)
 Sof(C76)=Sof(H76)=Sof(C77)=Sof(H77)=Sof(C80)=Sof(H80)=Sof(C78)=Sof(H78)=
 Sof(C79)=Sof(H79)=FVAR(1)
 Sof(C138)=Sof(H138)=Sof(C1C)=Sof(H1C)=Sof(C1D)=Sof(H1D)=Sof(C1E)=Sof(H1E)=
 Sof(C97A)=Sof(H97A)=1-FVAR(2)
 Sof(C8)=Sof(H8)=Sof(C12)=Sof(H12)=Sof(C9)=Sof(H9)=Sof(C11)=Sof(H11)=Sof(C10)=
 Sof(H10)=FVAR(2)
6.a Aromatic/amide H refined with riding coordinates:
 C52(H52), C58(H58), C68(H68), C82(H82), C69(H69), C17(H17), C130(H130),
 C59(H59), C58A(H58A), C84A(H84A), C137(H137), C1A(H1A), C1B(H1B), C64(H64),
 C87(H87), C73(H73), C55(H55), C102(H102), C104(H104), C71(H71), C67(H67),
 C108(H108), C132(H132), C119(H119), C49(H49), C22(H22), C101(H101), C34(H34),
 C70(H70), C42(H42), C24(H24), C53(H53), C50(H50), C72(H72), C20(H20), C51(H51),
  C86(H86), C18(H18), C76(H76), C54(H54), C62(H62), C89(H89), C19(H19),
 C46(H46), C60(H60), C98(H98), C16(H16), C45(H45), C14(H14), C121(H121),
 C66(H66), C48(H48), C83(H83), C2(H2), C126(H126), C61(H61), C30(H30), C84(H84),
  C90(H90), C37(H37), C40(H40), C6(H6), C114(H114), C105(H105), C77(H77),
 C118(H118), C129(H129), C65(H65), C116(H116), C39(H39), C36(H36), C107(H107),
 C28(H28), C110(H110), C117(H117), C100(H100), C99(H99), C8(H8), C25(H25),
 C136(H136), C106(H106), C112(H112), C123(H123), C80(H80), C43(H43), C44(H44),
 C38(H38), C33(H33), C5(H5), C133(H133), C96(H96), C15(H15), C92(H92), C85(H85),
  C111(H111), C120(H120), C127(H127), C94(H94), C3(H3), C26(H26), C27(H27),
 C12(H12), C128(H128), C135(H135), C31(H31), C32(H32), C124(H124), C4(H4),
 C134(H134), C78(H78), C113(H113), C9(H9), C11(H11), C10(H10), C95(H95),
 C79(H79), C93(H93), C138(H138), C1C(H1C), C1D(H1D), C1E(H1E), C97A(H97A)
6.b Fitted hexagon refined as free rotating group:
 C75(C58A,C84A,C137,C1A,C1B)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au5 Au 0.48907(2) 0.62126(2) 0.74917(2) 0.03715(5) Uani 1 1 d . . . . .
Au6 Au 0.57431(2) 0.61312(2) 0.66449(2) 0.03836(6) Uani 1 1 d . . . . .
Au4 Au 0.44902(2) 0.56341(2) 0.69818(2) 0.03863(6) Uani 1 1 d . . . . .
Au9 Au 0.41096(2) 0.67786(2) 0.78008(2) 0.04228(6) Uani 1 1 d . . . . .
Au2 Au 0.55036(2) 0.56461(2) 0.79232(2) 0.04128(6) Uani 1 1 d . . . . .
Au1 Au 0.48256(2) 0.62795(2) 0.84762(2) 0.04345(6) Uani 1 1 d . . . . .
Au3 Au 0.36156(2) 0.58350(2) 0.79278(2) 0.04187(6) Uani 1 1 d . . . . .
Au8 Au 0.56780(2) 0.67922(2) 0.71713(2) 0.04267(6) Uani 1 1 d . . . . .
Au7 Au 0.40571(2) 0.65264(2) 0.67172(2) 0.04641(6) Uani 1 1 d . . . . .
Fe4 Fe 0.77820(7) 0.68329(2) 0.60594(3) 0.0431(2) Uani 1 1 d . . . . .
Fe3 Fe 0.20496(7) 0.73536(2) 0.69344(4) 0.0458(2) Uani 1 1 d . . . . .
Fe2 Fe 0.19428(7) 0.49973(3) 0.72494(3) 0.0472(2) Uani 1 1 d . . . . .
Fe1 Fe 0.67228(9) 0.56717(3) 0.94562(4) 0.0614(3) Uani 1 1 d . . . . .
P8 P 0.68438(10) 0.60323(4) 0.60722(5) 0.0382(3) Uani 1 1 d . . . . .
Cl1 Cl 0.68915(10) 0.62933(4) 0.77395(6) 0.0529(4) Uani 1 1 d . . . . .
P3 P 0.27950(10) 0.66734(4) 0.62289(6) 0.0441(3) Uani 1 1 d . . . . .
P1 P 0.22809(10) 0.55942(4) 0.81844(5) 0.0412(3) Uani 1 1 d . . . . .
P7 P 0.65197(11) 0.72516(4) 0.69321(6) 0.0426(3) Uani 1 1 d . . . . .
P2 P 0.38856(11) 0.51765(4) 0.65413(5) 0.0412(3) Uani 1 1 d . . . . .
P4 P 0.33220(11) 0.72602(4) 0.80093(6) 0.0446(3) Uani 1 1 d . . . . .
P6 P 0.65521(11) 0.52922(4) 0.83122(5) 0.0427(3) Uani 1 1 d . . . . .
P5 P 0.52090(13) 0.63425(4) 0.93055(5) 0.0469(4) Uani 1 1 d . . . . .
C56 C 0.7827(4) 0.63190(15) 0.6142(2) 0.0420(13) Uani 1 1 d . . . . .
C52 C 0.8101(4) 0.64767(16) 0.6594(2) 0.0440(13) Uani 1 1 d . . . . .
H52 H 0.780885 0.645056 0.689771 0.053 Uiso 1 1 calc R U . . .
C63 C 0.7345(4) 0.56067(16) 0.6103(2) 0.0408(13) Uani 1 1 d . . . . .
C57 C 0.6400(4) 0.60968(16) 0.5437(2) 0.0445(13) Uani 1 1 d . . . . .
C74 C 0.3939(4) 0.51945(16) 0.5861(2) 0.0432(13) Uani 1 1 d . . . . .
C125 C 0.4273(5) 0.64967(17) 0.9670(2) 0.0488(15) Uani 1 1 d . . . . .
C58 C 0.5566(5) 0.62671(17) 0.5362(3) 0.0592(18) Uani 1 1 d . . . . .
H58 H 0.522423 0.633409 0.563526 0.071 Uiso 1 1 calc R U . . .
C91 C 0.2322(5) 0.55506(18) 0.8856(2) 0.0498(15) Uani 1 1 d . . . . .
C23 C 0.4054(5) 0.75346(18) 0.8401(3) 0.0559(17) Uani 1 1 d . . . . .
C68 C 0.6846(5) 0.53450(16) 0.6316(2) 0.0462(14) Uani 1 1 d . . . . .
H68 H 0.625933 0.539026 0.644430 0.055 Uiso 1 1 calc R U . . .
C109 C 0.7439(4) 0.51495(17) 0.7904(2) 0.0454(14) Uani 1 1 d . . . . .
C35 C 0.5879(4) 0.76512(16) 0.6899(3) 0.0515(15) Uani 1 1 d . . . . .
C82 C 0.2053(5) 0.53784(19) 0.6735(2) 0.0533(16) Uani 1 1 d . . . . .
H82 H 0.221907 0.560629 0.679863 0.064 Uiso 1 1 calc R U . . .
C115 C 0.7205(5) 0.55013(18) 0.8810(2) 0.0509(15) Uani 1 1 d . . . . .
C7 C 0.3056(6) 0.6929(2) 0.5694(3) 0.0741(12) Uani 1 1 d D U . . .
C47 C 0.6913(4) 0.71975(15) 0.6312(2) 0.0444(13) Uani 1 1 d . . . . .
C69 C 0.4510(4) 0.54332(15) 0.5651(2) 0.0431(13) Uani 1 1 d . . . . .
H69 H 0.487753 0.557838 0.585558 0.052 Uiso 1 1 calc R U . . .
C17 C 0.1696(4) 0.68584(16) 0.7055(2) 0.0471(14) Uani 1 1 d . . . . .
H17 H 0.199444 0.670686 0.727974 0.057 Uiso 1 1 calc R U . . .
C130 C 0.4200(5) 0.64270(19) 1.0173(2) 0.0558(17) Uani 1 1 d . . . . .
H130 H 0.464546 0.628578 1.033458 0.067 Uiso 1 1 calc R U . . .
C59 C 0.5228(6) 0.63404(19) 0.4880(3) 0.068(2) Uani 1 1 d . . . . .
H59 H 0.465101 0.645058 0.482735 0.081 Uiso 1 1 calc R U . . .
C41 C 0.7558(4) 0.73586(16) 0.7304(2) 0.0484(14) Uani 1 1 d . . . . .
C75 C 0.4422(4) 0.47775(16) 0.6739(2) 0.0723(12) Uani 1 1 d DG U . . .
C58A C 0.4926(12) 0.4794(3) 0.7190(4) 0.0724(12) Uani 0.371(14) 1 d DG U P A 2
H58A H 0.496848 0.500073 0.736474 0.087 Uiso 0.371(14) 1 calc R U P A 2
C84A C 0.5368(13) 0.4505(4) 0.7381(5) 0.0727(12) Uani 0.371(14) 1 d DG U P A 2
H84A H 0.570948 0.451571 0.768573 0.087 Uiso 0.371(14) 1 calc R U P A 2
C137 C 0.5306(9) 0.4199(3) 0.7122(6) 0.0729(12) Uani 0.371(14) 1 d DG U P A 2
H137 H 0.560469 0.400310 0.725140 0.087 Uiso 0.371(14) 1 calc R U P A 2
C1A C 0.4801(13) 0.4182(2) 0.6671(6) 0.0729(12) Uani 0.371(14) 1 d DG U P A 2
H1A H 0.475891 0.397549 0.649609 0.087 Uiso 0.371(14) 1 calc R U P A 2
C1B C 0.4359(12) 0.4472(2) 0.6480(5) 0.0727(12) Uani 0.371(14) 1 d DG U P A 2
H1B H 0.401791 0.446050 0.617509 0.087 Uiso 0.371(14) 1 calc R U P A 2
C64 C 0.8209(5) 0.55298(18) 0.5918(2) 0.0526(16) Uani 1 1 d . . . . .
H64 H 0.855976 0.570300 0.577315 0.063 Uiso 1 1 calc R U . . .
C103 C 0.6021(5) 0.49108(18) 0.8572(2) 0.0517(16) Uani 1 1 d . . . . .
C29 C 0.2302(5) 0.71805(17) 0.8356(2) 0.0482(14) Uani 1 1 d . . . . .
C87 C 0.2813(5) 0.49377(18) 0.7856(2) 0.0550(16) Uani 1 1 d . . . . .
H87 H 0.345553 0.498592 0.787340 0.066 Uiso 1 1 calc R U . . .
C73 C 0.3380(5) 0.49825(18) 0.5560(2) 0.0560(17) Uani 1 1 d . . . . .
H73 H 0.298148 0.482310 0.570199 0.067 Uiso 1 1 calc R U . . .
C131 C 0.6154(5) 0.66430(18) 0.9416(2) 0.0530(16) Uani 1 1 d . . . . .
C55 C 0.8456(4) 0.64251(17) 0.5775(2) 0.0501(15) Uani 1 1 d . . . . .
H55 H 0.844253 0.635731 0.544051 0.060 Uiso 1 1 calc R U . . .
C102 C 0.1109(5) 0.60140(17) 0.7619(3) 0.0524(15) Uani 1 1 d . . . . .
H102 H 0.161289 0.602835 0.740772 0.063 Uiso 1 1 calc R U . . .
C104 C 0.5065(5) 0.48951(19) 0.8569(3) 0.0572(17) Uani 1 1 d . . . . .
H104 H 0.470707 0.508219 0.845579 0.069 Uiso 1 1 calc R U . . .
C81 C 0.2670(4) 0.51064(17) 0.6634(2) 0.0464(14) Uani 1 1 d . . . . .
C97 C 0.1201(4) 0.58236(16) 0.8048(2) 0.0465(14) Uani 1 1 d . . . . .
C71 C 0.3986(5) 0.52453(18) 0.4837(2) 0.0562(17) Uani 1 1 d . . . . .
H71 H 0.400251 0.526357 0.448988 0.067 Uiso 1 1 calc R U . . .
C1 C 0.2152(4) 0.63055(17) 0.5988(2) 0.0495(15) Uani 1 1 d . . . . .
C21 C 0.2952(5) 0.75143(16) 0.7485(3) 0.0502(15) Uani 1 1 d . . . . .
C67 C 0.7206(5) 0.50191(18) 0.6340(3) 0.0593(17) Uani 1 1 d . . . . .
H67 H 0.686645 0.484496 0.649004 0.071 Uiso 1 1 calc R U . . .
C108 C 0.6549(5) 0.4643(2) 0.8766(3) 0.065(2) Uani 1 1 d . . . . .
H108 H 0.720397 0.465538 0.877961 0.078 Uiso 1 1 calc R U . . .
C132 C 0.6698(5) 0.67292(19) 0.9027(3) 0.0595(18) Uani 1 1 d . . . . .
H132 H 0.655452 0.663886 0.871038 0.071 Uiso 1 1 calc R U . . .
C119 C 0.7328(5) 0.58572(18) 0.8846(2) 0.0517(16) Uani 1 1 d . . . . .
H119 H 0.706891 0.602048 0.862620 0.062 Uiso 1 1 calc R U . . .
C49 C 0.6943(6) 0.70323(19) 0.5499(2) 0.0616(19) Uani 1 1 d . . . . .
H49 H 0.678033 0.693073 0.519142 0.074 Uiso 1 1 calc R U . . .
C122 C 0.5581(6) 0.59565(19) 0.9607(2) 0.062(2) Uani 1 1 d . . . . .
C22 C 0.3412(5) 0.75018(17) 0.7017(2) 0.0516(15) Uani 1 1 d . . . . .
H22 H 0.393841 0.736974 0.694996 0.062 Uiso 1 1 calc R U . . .
C101 C 0.0284(5) 0.6185(2) 0.7494(3) 0.067(2) Uani 1 1 d . . . . .
H101 H 0.023236 0.631432 0.720083 0.080 Uiso 1 1 calc R U . . .
C13 C 0.1927(4) 0.69107(16) 0.6539(2) 0.0452(14) Uani 1 1 d . . . . .
C88 C 0.2094(5) 0.51715(17) 0.7960(2) 0.0475(14) Uani 1 1 d . . . . .
C34 C 0.1933(5) 0.68535(18) 0.8378(3) 0.0568(17) Uani 1 1 d . . . . .
H34 H 0.223046 0.667526 0.821351 0.068 Uiso 1 1 calc R U . . .
C70 C 0.4542(5) 0.54592(17) 0.5140(2) 0.0524(15) Uani 1 1 d . . . . .
H70 H 0.493547 0.562005 0.499740 0.063 Uiso 1 1 calc R U . . .
C42 C 0.7976(5) 0.76764(18) 0.7266(3) 0.0617(18) Uani 1 1 d . . . . .
H42 H 0.769895 0.784279 0.705707 0.074 Uiso 1 1 calc R U . . .
C24 C 0.4811(6) 0.7386(2) 0.8664(3) 0.070(2) Uani 1 1 d . . . . .
H24 H 0.490392 0.714914 0.864377 0.084 Uiso 1 1 calc R U . . .
C53 C 0.8884(4) 0.66789(17) 0.6513(3) 0.0544(17) Uani 1 1 d . . . . .
H53 H 0.920913 0.681130 0.675400 0.065 Uiso 1 1 calc R U . . .
C50 C 0.7722(6) 0.72421(19) 0.5594(3) 0.0626(19) Uani 1 1 d . . . . .
H50 H 0.817087 0.730077 0.536454 0.075 Uiso 1 1 calc R U . . .
C72 C 0.3420(5) 0.50098(18) 0.5045(2) 0.0538(16) Uani 1 1 d . . . . .
H72 H 0.305407 0.486470 0.483958 0.065 Uiso 1 1 calc R U . . .
C20 C 0.2210(5) 0.77523(17) 0.7426(3) 0.0559(17) Uani 1 1 d . . . . .
H20 H 0.180355 0.781808 0.767326 0.067 Uiso 1 1 calc R U . . .
C51 C 0.7717(5) 0.73511(17) 0.6098(3) 0.0543(16) Uani 1 1 d . . . . .
H51 H 0.815422 0.749553 0.626072 0.065 Uiso 1 1 calc R U . . .
C86 C 0.2413(6) 0.46231(19) 0.7723(3) 0.0631(19) Uani 1 1 d . . . . .
H86 H 0.273649 0.442538 0.763425 0.076 Uiso 1 1 calc R U . . .
C18 C 0.2942(6) 0.77184(19) 0.6686(3) 0.0624(19) Uani 1 1 d . . . . .
H18 H 0.309432 0.775673 0.635451 0.075 Uiso 1 1 calc R U . . .
C76 C 0.4827(11) 0.4738(3) 0.7200(5) 0.0723(12) Uani 0.629(14) 1 d D U P A 1
H76 H 0.482612 0.492093 0.742451 0.087 Uiso 0.629(14) 1 calc R U P A 1
C54 C 0.9103(5) 0.66505(18) 0.6008(3) 0.0552(16) Uani 1 1 d . . . . .
H54 H 0.959437 0.676220 0.585476 0.066 Uiso 1 1 calc R U . . .
C62 C 0.6901(5) 0.59921(19) 0.5023(2) 0.0575(17) Uani 1 1 d . . . . .
H62 H 0.746552 0.587225 0.506811 0.069 Uiso 1 1 calc R U . . .
C89 C 0.1225(5) 0.49947(18) 0.7889(2) 0.0510(15) Uani 1 1 d . . . . .
H89 H 0.062721 0.508594 0.792903 0.061 Uiso 1 1 calc R U . . .
C19 C 0.2186(6) 0.78732(19) 0.6933(3) 0.069(2) Uani 1 1 d . . . . .
H19 H 0.175158 0.802802 0.679156 0.083 Uiso 1 1 calc R U . . .
C46 C 0.7961(5) 0.71184(17) 0.7621(2) 0.0493(15) Uani 1 1 d . . . . .
H46 H 0.767975 0.690377 0.765464 0.059 Uiso 1 1 calc R U . . .
C60 C 0.5748(7) 0.6250(2) 0.4485(3) 0.081(3) Uani 1 1 d . . . . .
H60 H 0.554881 0.631411 0.416196 0.097 Uiso 1 1 calc R U . . .
C98 C 0.0446(5) 0.58042(19) 0.8354(3) 0.0585(17) Uani 1 1 d . . . . .
H98 H 0.048874 0.567182 0.864435 0.070 Uiso 1 1 calc R U . . .
C16 C 0.0950(5) 0.70747(19) 0.7155(3) 0.0585(18) Uani 1 1 d . . . . .
H16 H 0.066521 0.709278 0.746210 0.070 Uiso 1 1 calc R U . . .
C45 C 0.8783(5) 0.7195(2) 0.7890(3) 0.0627(19) Uani 1 1 d . . . . .
H45 H 0.905628 0.703198 0.810531 0.075 Uiso 1 1 calc R U . . .
C14 C 0.1301(4) 0.71569(18) 0.6342(3) 0.0535(16) Uani 1 1 d . . . . .
H14 H 0.128041 0.724044 0.601503 0.064 Uiso 1 1 calc R U . . .
C121 C 0.5300(7) 0.56255(18) 0.9454(3) 0.073(2) Uani 1 1 d . . . . .
H121 H 0.489553 0.557191 0.918248 0.087 Uiso 1 1 calc R U . . .
C66 C 0.8056(6) 0.4946(2) 0.6147(3) 0.069(2) Uani 1 1 d . . . . .
H66 H 0.828705 0.472240 0.615676 0.083 Uiso 1 1 calc R U . . .
C48 C 0.6440(5) 0.69976(18) 0.5936(2) 0.0524(16) Uani 1 1 d . . . . .
H48 H 0.589719 0.686751 0.597315 0.063 Uiso 1 1 calc R U . . .
C83 C 0.1122(5) 0.5238(2) 0.6720(3) 0.065(2) Uani 1 1 d . . . . .
H83 H 0.056916 0.535903 0.677245 0.078 Uiso 1 1 calc R U . . .
C2 C 0.2628(6) 0.6071(2) 0.5702(3) 0.072(2) Uani 1 1 d . . . . .
H2 H 0.326064 0.610688 0.564095 0.087 Uiso 1 1 calc R U . . .
C126 C 0.3574(6) 0.6703(2) 0.9449(3) 0.067(2) Uani 1 1 d . . . . .
H126 H 0.360538 0.675696 0.911016 0.080 Uiso 1 1 calc R U . . .
C61 C 0.6555(7) 0.6067(2) 0.4557(3) 0.071(2) Uani 1 1 d . . . . .
H61 H 0.687629 0.599173 0.428080 0.085 Uiso 1 1 calc R U . . .
C30 C 0.1822(5) 0.7447(2) 0.8603(3) 0.0626(19) Uani 1 1 d . . . . .
H30 H 0.204027 0.767281 0.859364 0.075 Uiso 1 1 calc R U . . .
C84 C 0.1192(5) 0.4892(3) 0.6613(3) 0.073(2) Uani 1 1 d . . . . .
H84 H 0.068665 0.473961 0.658096 0.088 Uiso 1 1 calc R U . . .
C90 C 0.1434(7) 0.4658(2) 0.7747(3) 0.074(2) Uani 1 1 d . . . . .
H90 H 0.099433 0.448464 0.767976 0.089 Uiso 1 1 calc R U . . .
C37 C 0.5120(6) 0.8111(2) 0.7307(4) 0.086(3) Uani 1 1 d . . . . .
H37 H 0.495460 0.822077 0.760086 0.103 Uiso 1 1 calc R U . . .
C40 C 0.5630(6) 0.7807(2) 0.6447(3) 0.070(2) Uani 1 1 d . . . . .
H40 H 0.580105 0.770423 0.614921 0.083 Uiso 1 1 calc R U . . .
C6 C 0.1260(5) 0.62376(19) 0.6092(3) 0.0607(18) Uani 1 1 d . . . . .
H6 H 0.094184 0.639125 0.629205 0.073 Uiso 1 1 calc R U . . .
C114 C 0.8003(6) 0.5397(2) 0.7707(3) 0.067(2) Uani 1 1 d . . . . .
H114 H 0.789446 0.562864 0.777412 0.081 Uiso 1 1 calc R U . . .
C105 C 0.4630(6) 0.4606(2) 0.8732(3) 0.082(3) Uani 1 1 d . . . . .
H105 H 0.397506 0.459425 0.872540 0.098 Uiso 1 1 calc R U . . .
C77 C 0.5238(11) 0.4435(3) 0.7344(5) 0.0727(12) Uani 0.629(14) 1 d D U P A 1
H77 H 0.531921 0.438262 0.768376 0.087 Uiso 0.629(14) 1 calc R U P A 1
C118 C 0.7912(6) 0.5926(2) 0.9274(3) 0.070(2) Uani 1 1 d . . . . .
H118 H 0.810897 0.614281 0.938435 0.084 Uiso 1 1 calc R U . . .
C129 C 0.3483(7) 0.6562(2) 1.0440(3) 0.073(2) Uani 1 1 d . . . . .
H129 H 0.344934 0.651330 1.077980 0.087 Uiso 1 1 calc R U . . .
C65 C 0.8563(5) 0.5200(2) 0.5943(3) 0.066(2) Uani 1 1 d . . . . .
H65 H 0.915188 0.515217 0.581911 0.079 Uiso 1 1 calc R U . . .
C116 C 0.7726(5) 0.5345(2) 0.9221(2) 0.065(2) Uani 1 1 d . . . . .
H116 H 0.777929 0.511087 0.928903 0.077 Uiso 1 1 calc R U . . .
C39 C 0.5135(6) 0.8108(2) 0.6432(5) 0.093(3) Uani 1 1 d . . . . .
H39 H 0.497939 0.821066 0.612441 0.112 Uiso 1 1 calc R U . . .
C36 C 0.5605(5) 0.7809(2) 0.7336(3) 0.067(2) Uani 1 1 d . . . . .
H36 H 0.575104 0.770966 0.764635 0.081 Uiso 1 1 calc R U . . .
C107 C 0.6102(7) 0.4358(2) 0.8939(3) 0.082(3) Uani 1 1 d . . . . .
H107 H 0.645506 0.417891 0.908273 0.099 Uiso 1 1 calc R U . . .
C28 C 0.3931(7) 0.7875(2) 0.8441(4) 0.086(3) Uani 1 1 d . . . . .
H28 H 0.342581 0.797908 0.826682 0.103 Uiso 1 1 calc R U . . .
C110 C 0.7587(6) 0.48119(19) 0.7782(3) 0.066(2) Uani 1 1 d . . . . .
H110 H 0.718696 0.464061 0.789208 0.079 Uiso 1 1 calc R U . . .
C117 C 0.8141(7) 0.5615(2) 0.9501(3) 0.078(2) Uani 1 1 d . . . . .
H117 H 0.851222 0.558847 0.979428 0.094 Uiso 1 1 calc R U . . .
C100 C -0.0447(5) 0.6166(2) 0.7798(3) 0.070(2) Uani 1 1 d . . . . .
H100 H -0.100777 0.627914 0.771287 0.084 Uiso 1 1 calc R U . . .
C99 C -0.0369(5) 0.5980(2) 0.8231(3) 0.072(2) Uani 1 1 d . . . . .
H99 H -0.087039 0.597184 0.844433 0.087 Uiso 1 1 calc R U . . .
C8 C 0.3867(19) 0.7118(9) 0.5760(9) 0.0743(12) Uani 0.389(16) 1 d D U P B 1
H8 H 0.421986 0.709180 0.605901 0.089 Uiso 0.389(16) 1 calc R U P B 1
C25 C 0.5426(6) 0.7581(2) 0.8955(4) 0.085(3) Uani 1 1 d . . . . .
H25 H 0.593892 0.747951 0.912544 0.101 Uiso 1 1 calc R U . . .
C136 C 0.6361(7) 0.6786(2) 0.9875(3) 0.073(2) Uani 1 1 d . . . . .
H136 H 0.598883 0.673349 1.014339 0.087 Uiso 1 1 calc R U . . .
C106 C 0.5154(7) 0.4332(3) 0.8904(4) 0.092(3) Uani 1 1 d . . . . .
H106 H 0.485852 0.412942 0.899576 0.110 Uiso 1 1 calc R U . . .
C112 C 0.8891(5) 0.4976(2) 0.7311(3) 0.068(2) Uani 1 1 d . . . . .
H112 H 0.939094 0.491709 0.711361 0.082 Uiso 1 1 calc R U . . .
C123 C 0.6208(8) 0.5919(2) 1.0040(3) 0.088(3) Uani 1 1 d . . . . .
H123 H 0.650949 0.609720 1.021615 0.106 Uiso 1 1 calc R U . . .
C80 C 0.4748(11) 0.4545(3) 0.6365(5) 0.0726(12) Uani 0.629(14) 1 d D U P A 1
H80 H 0.461145 0.459034 0.602707 0.087 Uiso 0.629(14) 1 calc R U P A 1
C43 C 0.8790(6) 0.7750(2) 0.7531(3) 0.071(2) Uani 1 1 d . . . . .
H43 H 0.907144 0.796507 0.750100 0.086 Uiso 1 1 calc R U . . .
C44 C 0.9196(5) 0.7506(2) 0.7843(3) 0.066(2) Uani 1 1 d . . . . .
H44 H 0.975546 0.755443 0.802213 0.079 Uiso 1 1 calc R U . . .
C38 C 0.4873(7) 0.8256(2) 0.6853(5) 0.092(3) Uani 1 1 d . . . . .
H38 H 0.452254 0.845841 0.683977 0.111 Uiso 1 1 calc R U . . .
C33 C 0.1135(6) 0.6783(2) 0.8636(3) 0.074(2) Uani 1 1 d . . . . .
H33 H 0.090205 0.655904 0.864774 0.089 Uiso 1 1 calc R U . . .
C5 C 0.0796(6) 0.5953(2) 0.5916(4) 0.083(3) Uani 1 1 d . . . . .
H5 H 0.017432 0.591060 0.599633 0.100 Uiso 1 1 calc R U . . .
C133 C 0.7457(7) 0.6947(2) 0.9093(3) 0.084(3) Uani 1 1 d . . . . .
H133 H 0.782630 0.700226 0.882456 0.101 Uiso 1 1 calc R U . . .
C96 C 0.2541(7) 0.5829(2) 0.9147(3) 0.083(3) Uani 1 1 d . . . . .
H96 H 0.270506 0.603509 0.899659 0.100 Uiso 1 1 calc R U . . .
C15 C 0.0699(5) 0.7258(2) 0.6730(3) 0.065(2) Uani 1 1 d . . . . .
H15 H 0.021793 0.742040 0.670024 0.077 Uiso 1 1 calc R U . . .
C92 C 0.2119(8) 0.5249(2) 0.9091(3) 0.085(3) Uani 1 1 d . . . . .
H92 H 0.199095 0.505371 0.889872 0.101 Uiso 1 1 calc R U . . .
C85 C 0.2134(5) 0.4804(2) 0.6559(2) 0.0605(19) Uani 1 1 d . . . . .
H85 H 0.236673 0.458679 0.648762 0.073 Uiso 1 1 calc R U . . .
C111 C 0.8338(6) 0.4730(2) 0.7491(3) 0.078(2) Uani 1 1 d . . . . .
H111 H 0.846289 0.450023 0.742022 0.093 Uiso 1 1 calc R U . . .
C120 C 0.5743(9) 0.5388(2) 0.9788(4) 0.106(4) Uani 1 1 d . . . . .
H120 H 0.568396 0.515016 0.977226 0.127 Uiso 1 1 calc R U . . .
C127 C 0.2841(6) 0.6832(2) 0.9711(3) 0.082(3) Uani 1 1 d . . . . .
H127 H 0.236706 0.696165 0.955048 0.098 Uiso 1 1 calc R U . . .
C94 C 0.2334(9) 0.5508(3) 0.9880(3) 0.114(4) Uani 1 1 d . . . . .
H94 H 0.236554 0.549316 1.022849 0.137 Uiso 1 1 calc R U . . .
C3 C 0.2180(7) 0.5787(3) 0.5510(4) 0.089(3) Uani 1 1 d . . . . .
H3 H 0.249578 0.563481 0.530653 0.107 Uiso 1 1 calc R U . . .
C26 C 0.5274(7) 0.7921(3) 0.8989(4) 0.101(4) Uani 1 1 d . . . . .
H26 H 0.568186 0.805506 0.918928 0.122 Uiso 1 1 calc R U . . .
C27 C 0.4532(7) 0.8075(2) 0.8735(4) 0.098(3) Uani 1 1 d . . . . .
H27 H 0.443623 0.831140 0.875974 0.117 Uiso 1 1 calc R U . . .
C12 C 0.2503(15) 0.7000(7) 0.5273(6) 0.0745(12) Uani 0.389(16) 1 d D U P B 1
H12 H 0.192975 0.688768 0.521987 0.089 Uiso 0.389(16) 1 calc R U P B 1
C128 C 0.2822(6) 0.6766(2) 1.0208(3) 0.079(2) Uani 1 1 d . . . . .
H128 H 0.234883 0.686178 1.039494 0.095 Uiso 1 1 calc R U . . .
C135 C 0.7109(7) 0.7004(3) 0.9944(3) 0.090(3) Uani 1 1 d . . . . .
H135 H 0.723819 0.709830 1.025961 0.107 Uiso 1 1 calc R U . . .
C31 C 0.1026(6) 0.7367(3) 0.8859(3) 0.077(2) Uani 1 1 d . . . . .
H31 H 0.071393 0.754020 0.902560 0.093 Uiso 1 1 calc R U . . .
C32 C 0.0689(6) 0.7043(3) 0.8873(3) 0.081(3) Uani 1 1 d . . . . .
H32 H 0.014758 0.699709 0.904550 0.097 Uiso 1 1 calc R U . . .
C124 C 0.6285(10) 0.5571(3) 1.0147(3) 0.119(5) Uani 1 1 d . . . . .
H124 H 0.663770 0.547531 1.041348 0.143 Uiso 1 1 calc R U . . .
C4 C 0.1271(7) 0.5729(2) 0.5619(4) 0.083(3) Uani 1 1 d . . . . .
H4 H 0.096339 0.553544 0.548929 0.099 Uiso 1 1 calc R U . . .
C134 C 0.7665(7) 0.7084(3) 0.9562(4) 0.087(3) Uani 1 1 d . . . . .
H134 H 0.818055 0.722954 0.961407 0.105 Uiso 1 1 calc R U . . .
C78 C 0.5536(11) 0.4205(3) 0.6990(5) 0.0730(12) Uani 0.629(14) 1 d D U P A 1
H78 H 0.591527 0.401826 0.708236 0.088 Uiso 0.629(14) 1 calc R U P A 1
C113 C 0.8728(6) 0.5304(2) 0.7412(3) 0.079(3) Uani 1 1 d . . . . .
H113 H 0.911032 0.547326 0.728018 0.095 Uiso 1 1 calc R U . . .
C9 C 0.4194(15) 0.7348(6) 0.5404(8) 0.0744(12) Uani 0.389(16) 1 d D U P B 1
H9 H 0.476247 0.746404 0.545768 0.089 Uiso 0.389(16) 1 calc R U P B 1
C11 C 0.2797(14) 0.7241(7) 0.4923(7) 0.0746(12) Uani 0.389(16) 1 d D U P B 1
H11 H 0.239927 0.729602 0.464885 0.089 Uiso 0.389(16) 1 calc R U P B 1
C10 C 0.3659(16) 0.7397(7) 0.4977(8) 0.0745(12) Uani 0.389(16) 1 d D U P B 1
H10 H 0.387625 0.753574 0.472197 0.089 Uiso 0.389(16) 1 calc R U P B 1
C95 C 0.2523(9) 0.5810(3) 0.9656(3) 0.107(4) Uani 1 1 d . . . . .
H95 H 0.264238 0.600520 0.984992 0.128 Uiso 1 1 calc R U . . .
C79 C 0.5258(11) 0.4258(3) 0.6498(5) 0.0729(12) Uani 0.629(14) 1 d D U P A 1
H79 H 0.541510 0.409873 0.625481 0.087 Uiso 0.629(14) 1 calc R U P A 1
C93 C 0.2098(11) 0.5227(3) 0.9604(3) 0.126(5) Uani 1 1 d . . . . .
H93 H 0.192501 0.502338 0.975823 0.151 Uiso 1 1 calc R U . . .
C138 C 0.2483(10) 0.6863(4) 0.5261(4) 0.0744(12) Uani 0.611(16) 1 d D U P B 2
H138 H 0.199711 0.670234 0.526343 0.089 Uiso 0.611(16) 1 calc R U P B 2
C1C C 0.2676(10) 0.7049(5) 0.4829(4) 0.0746(12) Uani 0.611(16) 1 d D U P B 2
H1C H 0.228145 0.702754 0.454384 0.090 Uiso 0.611(16) 1 calc R U P B 2
C1D C 0.3440(11) 0.7262(5) 0.4824(5) 0.0746(12) Uani 0.611(16) 1 d D U P B 2
H1D H 0.356405 0.737920 0.453002 0.090 Uiso 0.611(16) 1 calc R U P B 2
C1E C 0.4022(11) 0.7308(4) 0.5232(5) 0.0745(12) Uani 0.611(16) 1 d D U P B 2
H1E H 0.453781 0.745564 0.521973 0.089 Uiso 0.611(16) 1 calc R U P B 2
C97A C 0.3836(13) 0.7131(6) 0.5671(6) 0.0743(12) Uani 0.611(16) 1 d D U P B 2
H97A H 0.424627 0.715140 0.594991 0.089 Uiso 0.611(16) 1 calc R U P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au5 Au6 2.6530(3) . ?
Au5 Au4 2.7040(3) . ?
Au5 Au9 2.6388(3) . ?
Au5 Au2 2.6436(3) . ?
Au5 Au1 2.6725(3) . ?
Au5 Au3 2.6648(3) . ?
Au5 Au8 2.6980(3) . ?
Au5 Au7 2.6654(3) . ?
Au6 Au4 2.8279(3) . ?
Au6 Au8 2.9608(3) . ?
Au6 Au7 2.8867(3) . ?
Au6 P8 2.2864(14) . ?
Au4 Au2 2.8733(3) . ?
Au4 Au3 2.9938(3) . ?
Au4 P2 2.3036(15) . ?
Au9 Au1 2.8386(4) . ?
Au9 Au8 2.8736(4) . ?
Au9 Au7 3.0827(3) . ?
Au9 P4 2.2845(15) . ?
Au2 Au1 3.0774(3) . ?
Au2 Au3 2.8088(3) . ?
Au2 P6 2.2721(15) . ?
Au1 Au3 2.8344(4) . ?
Au1 P5 2.2940(14) . ?
Au3 P1 2.2686(15) . ?
Au8 Au7 2.7862(4) . ?
Au8 P7 2.2782(16) . ?
Au7 P3 2.2691(14) . ?
Fe4 C56 2.031(6) . ?
Fe4 C52 2.047(6) . ?
Fe4 C47 2.034(6) . ?
Fe4 C55 2.036(6) . ?
Fe4 C49 2.049(7) . ?
Fe4 C53 2.051(6) . ?
Fe4 C50 2.038(7) . ?
Fe4 C51 2.039(7) . ?
Fe4 C54 2.036(7) . ?
Fe4 C48 2.045(7) . ?
Fe3 C17 2.038(6) . ?
Fe3 C21 2.030(7) . ?
Fe3 C22 2.043(7) . ?
Fe3 C13 2.043(6) . ?
Fe3 C20 2.057(6) . ?
Fe3 C18 2.051(7) . ?
Fe3 C19 2.049(7) . ?
Fe3 C16 2.029(7) . ?
Fe3 C14 2.039(7) . ?
Fe3 C15 2.028(7) . ?
Fe2 C82 2.051(7) . ?
Fe2 C87 2.030(7) . ?
Fe2 C81 2.040(6) . ?
Fe2 C88 2.037(6) . ?
Fe2 C86 2.043(8) . ?
Fe2 C89 2.044(6) . ?
Fe2 C83 2.045(8) . ?
Fe2 C84 2.032(7) . ?
Fe2 C90 2.047(7) . ?
Fe2 C85 2.037(6) . ?
Fe1 C115 2.016(6) . ?
Fe1 C119 2.026(6) . ?
Fe1 C122 2.038(8) . ?
Fe1 C121 2.049(10) . ?
Fe1 C118 2.054(9) . ?
Fe1 C116 2.048(7) . ?
Fe1 C117 2.046(9) . ?
Fe1 C123 2.015(8) . ?
Fe1 C120 2.029(10) . ?
Fe1 C124 2.029(8) . ?
P8 C56 1.808(6) . ?
P8 C63 1.819(6) . ?
P8 C57 1.821(6) . ?
P3 C7 1.810(8) . ?
P3 C1 1.819(7) . ?
P3 C13 1.790(6) . ?
P1 C91 1.817(6) . ?
P1 C97 1.816(7) . ?
P1 C88 1.783(7) . ?
P7 C35 1.818(7) . ?
P7 C47 1.798(6) . ?
P7 C41 1.810(6) . ?
P2 C74 1.841(6) . ?
P2 C75 1.815(7) . ?
P2 C81 1.794(6) . ?
P4 C23 1.814(7) . ?
P4 C29 1.795(7) . ?
P4 C21 1.792(7) . ?
P6 C109 1.805(6) . ?
P6 C115 1.802(7) . ?
P6 C103 1.832(7) . ?
P5 C125 1.801(6) . ?
P5 C131 1.812(7) . ?
P5 C122 1.791(7) . ?
C56 C52 1.409(9) . ?
C56 C55 1.429(8) . ?
C52 H52 0.9400 . ?
C52 C53 1.400(9) . ?
C63 C68 1.390(9) . ?
C63 C64 1.388(8) . ?
C57 C58 1.378(10) . ?
C57 C62 1.412(9) . ?
C74 C69 1.381(9) . ?
C74 C73 1.392(9) . ?
C125 C130 1.392(9) . ?
C125 C126 1.403(10) . ?
C58 H58 0.9400 . ?
C58 C59 1.397(9) . ?
C91 C96 1.374(10) . ?
C91 C92 1.379(10) . ?
C23 C24 1.401(10) . ?
C23 C28 1.354(10) . ?
C68 H68 0.9400 . ?
C68 C67 1.380(9) . ?
C109 C114 1.385(9) . ?
C109 C110 1.384(10) . ?
C35 C40 1.397(10) . ?
C35 C36 1.401(10) . ?
C82 H82 0.9400 . ?
C82 C81 1.420(9) . ?
C82 C83 1.442(10) . ?
C115 C119 1.411(10) . ?
C115 C116 1.449(9) . ?
C7 C8 1.386(17) . ?
C7 C12 1.385(17) . ?
C7 C138 1.422(14) . ?
C7 C97A 1.375(15) . ?
C47 C51 1.442(9) . ?
C47 C48 1.431(9) . ?
C69 H69 0.9400 . ?
C69 C70 1.384(9) . ?
C17 H17 0.9400 . ?
C17 C13 1.458(9) . ?
C17 C16 1.401(9) . ?
C130 H130 0.9400 . ?
C130 C129 1.383(10) . ?
C59 H59 0.9400 . ?
C59 C60 1.372(12) . ?
C41 C42 1.390(9) . ?
C41 C46 1.383(9) . ?
C75 C58A 1.3900 . ?
C75 C1B 1.3900 . ?
C75 C76 1.359(13) . ?
C75 C80 1.452(12) . ?
C58A H58A 0.9400 . ?
C58A C84A 1.3900 . ?
C84A H84A 0.9400 . ?
C84A C137 1.3900 . ?
C137 H137 0.9400 . ?
C137 C1A 1.3900 . ?
C1A H1A 0.9400 . ?
C1A C1B 1.3900 . ?
C1B H1B 0.9400 . ?
C64 H64 0.9400 . ?
C64 C65 1.391(10) . ?
C103 C104 1.373(10) . ?
C103 C108 1.385(9) . ?
C29 C34 1.391(10) . ?
C29 C30 1.433(9) . ?
C87 H87 0.9400 . ?
C87 C88 1.418(9) . ?
C87 C86 1.402(10) . ?
C73 H73 0.9400 . ?
C73 C72 1.396(9) . ?
C131 C132 1.375(10) . ?
C131 C136 1.379(9) . ?
C55 H55 0.9400 . ?
C55 C54 1.411(10) . ?
C102 H102 0.9400 . ?
C102 C97 1.379(9) . ?
C102 C101 1.391(10) . ?
C104 H104 0.9400 . ?
C104 C105 1.377(11) . ?
C81 C85 1.423(9) . ?
C97 C98 1.389(9) . ?
C71 H71 0.9400 . ?
C71 C70 1.398(10) . ?
C71 C72 1.366(10) . ?
C1 C2 1.396(9) . ?
C1 C6 1.349(10) . ?
C21 C22 1.447(9) . ?
C21 C20 1.420(9) . ?
C67 H67 0.9400 . ?
C67 C66 1.375(11) . ?
C108 H108 0.9400 . ?
C108 C107 1.382(11) . ?
C132 H132 0.9400 . ?
C132 C133 1.392(12) . ?
C119 H119 0.9400 . ?
C119 C118 1.423(10) . ?
C49 H49 0.9400 . ?
C49 C50 1.404(11) . ?
C49 C48 1.414(10) . ?
C122 C121 1.417(11) . ?
C122 C123 1.451(12) . ?
C22 H22 0.9400 . ?
C22 C18 1.389(10) . ?
C101 H101 0.9400 . ?
C101 C100 1.360(11) . ?
C13 C14 1.408(9) . ?
C88 C89 1.432(9) . ?
C34 H34 0.9400 . ?
C34 C33 1.391(11) . ?
C70 H70 0.9400 . ?
C42 H42 0.9400 . ?
C42 C43 1.375(10) . ?
C24 H24 0.9400 . ?
C24 C25 1.387(11) . ?
C53 H53 0.9400 . ?
C53 C54 1.414(10) . ?
C50 H50 0.9400 . ?
C50 C51 1.426(10) . ?
C72 H72 0.9400 . ?
C20 H20 0.9400 . ?
C20 C19 1.411(10) . ?
C51 H51 0.9400 . ?
C86 H86 0.9400 . ?
C86 C90 1.416(12) . ?
C18 H18 0.9400 . ?
C18 C19 1.431(11) . ?
C76 H76 0.9400 . ?
C76 C77 1.378(13) . ?
C54 H54 0.9400 . ?
C62 H62 0.9400 . ?
C62 C61 1.363(10) . ?
C89 H89 0.9400 . ?
C89 C90 1.412(10) . ?
C19 H19 0.9400 . ?
C46 H46 0.9400 . ?
C46 C45 1.393(10) . ?
C60 H60 0.9400 . ?
C60 C61 1.370(12) . ?
C98 H98 0.9400 . ?
C98 C99 1.385(11) . ?
C16 H16 0.9400 . ?
C16 C15 1.390(11) . ?
C45 H45 0.9400 . ?
C45 C44 1.362(11) . ?
C14 H14 0.9400 . ?
C14 C15 1.439(10) . ?
C121 H121 0.9400 . ?
C121 C120 1.426(13) . ?
C66 H66 0.9400 . ?
C66 C65 1.362(11) . ?
C48 H48 0.9400 . ?
C83 H83 0.9400 . ?
C83 C84 1.396(12) . ?
C2 H2 0.9400 . ?
C2 C3 1.376(12) . ?
C126 H126 0.9400 . ?
C126 C127 1.387(11) . ?
C61 H61 0.9400 . ?
C30 H30 0.9400 . ?
C30 C31 1.394(11) . ?
C84 H84 0.9400 . ?
C84 C85 1.408(11) . ?
C90 H90 0.9400 . ?
C37 H37 0.9400 . ?
C37 C36 1.374(12) . ?
C37 C38 1.383(14) . ?
C40 H40 0.9400 . ?
C40 C39 1.380(11) . ?
C6 H6 0.9400 . ?
C6 C5 1.375(11) . ?
C114 H114 0.9400 . ?
C114 C113 1.385(10) . ?
C105 H105 0.9400 . ?
C105 C106 1.380(12) . ?
C77 H77 0.9400 . ?
C77 C78 1.394(13) . ?
C118 H118 0.9400 . ?
C118 C117 1.402(12) . ?
C129 H129 0.9400 . ?
C129 C128 1.372(13) . ?
C65 H65 0.9400 . ?
C116 H116 0.9400 . ?
C116 C117 1.417(12) . ?
C39 H39 0.9400 . ?
C39 C38 1.343(14) . ?
C36 H36 0.9400 . ?
C107 H107 0.9400 . ?
C107 C106 1.363(13) . ?
C28 H28 0.9400 . ?
C28 C27 1.390(12) . ?
C110 H110 0.9400 . ?
C110 C111 1.396(10) . ?
C117 H117 0.9400 . ?
C100 H100 0.9400 . ?
C100 C99 1.377(12) . ?
C99 H99 0.9400 . ?
C8 H8 0.9400 . ?
C8 C9 1.412(17) . ?
C25 H25 0.9400 . ?
C25 C26 1.358(12) . ?
C136 H136 0.9400 . ?
C136 C135 1.379(12) . ?
C106 H106 0.9400 . ?
C112 H112 0.9400 . ?
C112 C111 1.354(11) . ?
C112 C113 1.337(11) . ?
C123 H123 0.9400 . ?
C123 C124 1.401(13) . ?
C80 H80 0.9400 . ?
C80 C79 1.383(13) . ?
C43 H43 0.9400 . ?
C43 C44 1.387(12) . ?
C44 H44 0.9400 . ?
C38 H38 0.9400 . ?
C33 H33 0.9400 . ?
C33 C32 1.378(13) . ?
C5 H5 0.9400 . ?
C5 C4 1.387(12) . ?
C133 H133 0.9400 . ?
C133 C134 1.393(12) . ?
C96 H96 0.9400 . ?
C96 C95 1.376(11) . ?
C15 H15 0.9400 . ?
C92 H92 0.9400 . ?
C92 C93 1.388(11) . ?
C85 H85 0.9400 . ?
C111 H111 0.9400 . ?
C120 H120 0.9400 . ?
C120 C124 1.412(18) . ?
C127 H127 0.9400 . ?
C127 C128 1.367(12) . ?
C94 H94 0.9400 . ?
C94 C95 1.361(14) . ?
C94 C93 1.365(14) . ?
C3 H3 0.9400 . ?
C3 C4 1.367(13) . ?
C26 H26 0.9400 . ?
C26 C27 1.381(13) . ?
C27 H27 0.9400 . ?
C12 H12 0.9400 . ?
C12 C11 1.411(18) . ?
C128 H128 0.9400 . ?
C135 H135 0.9400 . ?
C135 C134 1.366(13) . ?
C31 H31 0.9400 . ?
C31 C32 1.359(13) . ?
C32 H32 0.9400 . ?
C124 H124 0.9400 . ?
C4 H4 0.9400 . ?
C134 H134 0.9400 . ?
C78 H78 0.9400 . ?
C78 C79 1.385(13) . ?
C113 H113 0.9400 . ?
C9 H9 0.9400 . ?
C9 C10 1.37(2) . ?
C11 H11 0.9400 . ?
C11 C10 1.38(2) . ?
C10 H10 0.9400 . ?
C95 H95 0.9400 . ?
C79 H79 0.9400 . ?
C93 H93 0.9400 . ?
C138 H138 0.9400 . ?
C138 C1C 1.412(15) . ?
C1C H1C 0.9400 . ?
C1C C1D 1.380(19) . ?
C1D H1D 0.9400 . ?
C1D C1E 1.366(18) . ?
C1E H1E 0.9400 . ?
C1E C97A 1.407(13) . ?
C97A H97A 0.9400 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au6 Au5 Au4 63.716(9) . . ?
Au6 Au5 Au1 154.495(13) . . ?
Au6 Au5 Au3 131.421(12) . . ?
Au6 Au5 Au8 67.184(9) . . ?
Au6 Au5 Au7 65.744(9) . . ?
Au9 Au5 Au6 126.135(11) . . ?
Au9 Au5 Au4 141.581(12) . . ?
Au9 Au5 Au2 135.020(11) . . ?
Au9 Au5 Au1 64.608(9) . . ?
Au9 Au5 Au3 91.207(11) . . ?
Au9 Au5 Au8 65.146(10) . . ?
Au9 Au5 Au7 71.065(10) . . ?
Au2 Au5 Au6 96.931(10) . . ?
Au2 Au5 Au4 64.989(9) . . ?
Au2 Au5 Au1 70.741(9) . . ?
Au2 Au5 Au3 63.891(10) . . ?
Au2 Au5 Au8 135.586(13) . . ?
Au2 Au5 Au7 149.773(12) . . ?
Au1 Au5 Au4 124.899(11) . . ?
Au1 Au5 Au8 105.499(11) . . ?
Au3 Au5 Au4 67.778(9) . . ?
Au3 Au5 Au1 64.153(9) . . ?
Au3 Au5 Au8 156.103(12) . . ?
Au3 Au5 Au7 107.976(12) . . ?
Au8 Au5 Au4 128.934(11) . . ?
Au7 Au5 Au4 84.867(10) . . ?
Au7 Au5 Au1 134.421(12) . . ?
Au7 Au5 Au8 62.591(10) . . ?
Au5 Au6 Au4 59.020(9) . . ?
Au5 Au6 Au8 57.133(8) . . ?
Au5 Au6 Au7 57.335(8) . . ?
Au4 Au6 Au8 114.699(10) . . ?
Au4 Au6 Au7 78.686(10) . . ?
Au7 Au6 Au8 56.894(9) . . ?
P8 Au6 Au5 163.13(4) . . ?
P8 Au6 Au4 124.42(4) . . ?
P8 Au6 Au8 120.58(4) . . ?
P8 Au6 Au7 137.78(4) . . ?
Au5 Au4 Au6 57.263(8) . . ?
Au5 Au4 Au2 56.489(8) . . ?
Au5 Au4 Au3 55.488(8) . . ?
Au6 Au4 Au2 88.121(10) . . ?
Au6 Au4 Au3 112.701(10) . . ?
Au2 Au4 Au3 57.162(8) . . ?
P2 Au4 Au5 169.99(4) . . ?
P2 Au4 Au6 127.12(4) . . ?
P2 Au4 Au2 129.37(4) . . ?
P2 Au4 Au3 118.85(4) . . ?
Au5 Au9 Au1 58.271(8) . . ?
Au5 Au9 Au8 58.421(9) . . ?
Au5 Au9 Au7 54.870(8) . . ?
Au1 Au9 Au8 96.899(10) . . ?
Au1 Au9 Au7 112.360(10) . . ?
Au8 Au9 Au7 55.645(8) . . ?
P4 Au9 Au5 174.40(4) . . ?
P4 Au9 Au1 125.66(4) . . ?
P4 Au9 Au8 122.48(4) . . ?
P4 Au9 Au7 120.39(4) . . ?
Au5 Au2 Au4 58.521(8) . . ?
Au5 Au2 Au1 55.068(8) . . ?
Au5 Au2 Au3 58.421(9) . . ?
Au4 Au2 Au1 106.412(10) . . ?
Au3 Au2 Au4 63.577(8) . . ?
Au3 Au2 Au1 57.353(8) . . ?
P6 Au2 Au5 156.84(4) . . ?
P6 Au2 Au4 134.37(4) . . ?
P6 Au2 Au1 119.12(4) . . ?
P6 Au2 Au3 141.23(4) . . ?
Au5 Au1 Au9 57.121(8) . . ?
Au5 Au1 Au2 54.191(8) . . ?
Au5 Au1 Au3 57.792(8) . . ?
Au9 Au1 Au2 111.113(10) . . ?
Au3 Au1 Au9 83.826(10) . . ?
Au3 Au1 Au2 56.555(8) . . ?
P5 Au1 Au5 164.12(5) . . ?
P5 Au1 Au9 128.09(4) . . ?
P5 Au1 Au2 119.43(4) . . ?
P5 Au1 Au3 133.80(4) . . ?
Au5 Au3 Au4 56.734(8) . . ?
Au5 Au3 Au2 57.688(9) . . ?
Au5 Au3 Au1 58.055(9) . . ?
Au2 Au3 Au4 59.260(8) . . ?
Au2 Au3 Au1 66.092(9) . . ?
Au1 Au3 Au4 109.721(10) . . ?
P1 Au3 Au5 165.80(4) . . ?
P1 Au3 Au4 122.58(4) . . ?
P1 Au3 Au2 135.84(4) . . ?
P1 Au3 Au1 127.15(4) . . ?
Au5 Au8 Au6 55.683(8) . . ?
Au5 Au8 Au9 56.433(8) . . ?
Au5 Au8 Au7 58.133(9) . . ?
Au9 Au8 Au6 107.916(10) . . ?
Au7 Au8 Au6 60.213(9) . . ?
Au7 Au8 Au9 65.983(9) . . ?
P7 Au8 Au5 172.72(4) . . ?
P7 Au8 Au6 122.04(4) . . ?
P7 Au8 Au9 128.23(4) . . ?
P7 Au8 Au7 127.92(4) . . ?
Au5 Au7 Au6 56.921(8) . . ?
Au5 Au7 Au9 54.065(8) . . ?
Au5 Au7 Au8 59.276(9) . . ?
Au6 Au7 Au9 104.387(10) . . ?
Au8 Au7 Au6 62.893(9) . . ?
Au8 Au7 Au9 58.371(9) . . ?
P3 Au7 Au5 153.36(4) . . ?
P3 Au7 Au6 138.45(4) . . ?
P3 Au7 Au9 117.13(4) . . ?
P3 Au7 Au8 142.33(5) . . ?
C56 Fe4 C52 40.4(2) . . ?
C56 Fe4 C47 132.8(2) . . ?
C56 Fe4 C55 41.1(2) . . ?
C56 Fe4 C49 118.4(3) . . ?
C56 Fe4 C53 67.8(3) . . ?
C56 Fe4 C50 148.3(3) . . ?
C56 Fe4 C51 170.7(3) . . ?
C56 Fe4 C54 68.5(3) . . ?
C56 Fe4 C48 110.9(3) . . ?
C52 Fe4 C49 152.7(3) . . ?
C52 Fe4 C53 40.0(2) . . ?
C47 Fe4 C52 111.5(2) . . ?
C47 Fe4 C55 170.6(3) . . ?
C47 Fe4 C49 68.2(3) . . ?
C47 Fe4 C53 118.4(3) . . ?
C47 Fe4 C50 68.9(3) . . ?
C47 Fe4 C51 41.5(2) . . ?
C47 Fe4 C54 148.8(3) . . ?
C47 Fe4 C48 41.1(3) . . ?
C55 Fe4 C52 68.4(3) . . ?
C55 Fe4 C49 107.3(3) . . ?
C55 Fe4 C53 68.1(3) . . ?
C55 Fe4 C50 113.4(3) . . ?
C55 Fe4 C51 145.8(3) . . ?
C55 Fe4 C48 130.2(3) . . ?
C49 Fe4 C53 165.5(3) . . ?
C50 Fe4 C52 167.1(3) . . ?
C50 Fe4 C49 40.2(3) . . ?
C50 Fe4 C53 127.7(3) . . ?
C50 Fe4 C51 40.9(3) . . ?
C50 Fe4 C48 68.6(3) . . ?
C51 Fe4 C52 130.9(3) . . ?
C51 Fe4 C49 68.3(3) . . ?
C51 Fe4 C53 107.4(3) . . ?
C51 Fe4 C48 69.4(3) . . ?
C54 Fe4 C52 68.0(3) . . ?
C54 Fe4 C55 40.5(3) . . ?
C54 Fe4 C49 127.2(3) . . ?
C54 Fe4 C53 40.5(3) . . ?
C54 Fe4 C50 104.6(3) . . ?
C54 Fe4 C51 113.5(3) . . ?
C54 Fe4 C48 166.6(3) . . ?
C48 Fe4 C52 120.8(3) . . ?
C48 Fe4 C49 40.4(3) . . ?
C48 Fe4 C53 152.6(3) . . ?
C17 Fe3 C22 119.8(3) . . ?
C17 Fe3 C13 41.8(2) . . ?
C17 Fe3 C20 130.2(3) . . ?
C17 Fe3 C18 151.7(3) . . ?
C17 Fe3 C19 166.9(3) . . ?
C17 Fe3 C14 68.7(3) . . ?
C21 Fe3 C17 109.6(3) . . ?
C21 Fe3 C22 41.6(3) . . ?
C21 Fe3 C13 133.2(3) . . ?
C21 Fe3 C20 40.7(3) . . ?
C21 Fe3 C18 68.6(3) . . ?
C21 Fe3 C19 68.5(3) . . ?
C21 Fe3 C14 171.9(3) . . ?
C22 Fe3 C13 111.2(3) . . ?
C22 Fe3 C20 68.4(3) . . ?
C22 Fe3 C18 39.7(3) . . ?
C22 Fe3 C19 68.0(3) . . ?
C13 Fe3 C20 171.2(3) . . ?
C13 Fe3 C18 117.7(3) . . ?
C13 Fe3 C19 148.4(3) . . ?
C18 Fe3 C20 68.0(3) . . ?
C19 Fe3 C20 40.2(3) . . ?
C19 Fe3 C18 40.8(3) . . ?
C16 Fe3 C17 40.3(3) . . ?
C16 Fe3 C21 115.7(3) . . ?
C16 Fe3 C22 150.8(3) . . ?
C16 Fe3 C13 69.1(3) . . ?
C16 Fe3 C20 106.8(3) . . ?
C16 Fe3 C18 167.3(3) . . ?
C16 Fe3 C19 127.8(3) . . ?
C16 Fe3 C14 68.6(3) . . ?
C14 Fe3 C22 131.6(3) . . ?
C14 Fe3 C13 40.3(3) . . ?
C14 Fe3 C20 146.5(3) . . ?
C14 Fe3 C18 108.9(3) . . ?
C14 Fe3 C19 115.0(3) . . ?
C15 Fe3 C17 68.0(3) . . ?
C15 Fe3 C21 146.1(3) . . ?
C15 Fe3 C22 169.1(3) . . ?
C15 Fe3 C13 68.9(3) . . ?
C15 Fe3 C20 113.3(3) . . ?
C15 Fe3 C18 130.0(3) . . ?
C15 Fe3 C19 105.9(3) . . ?
C15 Fe3 C16 40.1(3) . . ?
C15 Fe3 C14 41.4(3) . . ?
C87 Fe2 C82 124.6(3) . . ?
C87 Fe2 C81 111.2(3) . . ?
C87 Fe2 C88 40.8(3) . . ?
C87 Fe2 C86 40.3(3) . . ?
C87 Fe2 C89 68.6(3) . . ?
C87 Fe2 C83 158.9(3) . . ?
C87 Fe2 C84 160.8(4) . . ?
C87 Fe2 C90 67.7(3) . . ?
C87 Fe2 C85 126.3(3) . . ?
C81 Fe2 C82 40.6(3) . . ?
C81 Fe2 C86 119.5(3) . . ?
C81 Fe2 C89 168.1(3) . . ?
C81 Fe2 C83 68.5(3) . . ?
C81 Fe2 C90 151.3(3) . . ?
C88 Fe2 C82 112.5(3) . . ?
C88 Fe2 C81 131.0(3) . . ?
C88 Fe2 C86 68.5(3) . . ?
C88 Fe2 C89 41.1(3) . . ?
C88 Fe2 C83 122.5(3) . . ?
C88 Fe2 C90 68.2(3) . . ?
C88 Fe2 C85 166.0(3) . . ?
C86 Fe2 C82 156.2(3) . . ?
C86 Fe2 C89 68.5(3) . . ?
C86 Fe2 C83 159.3(3) . . ?
C86 Fe2 C90 40.5(3) . . ?
C89 Fe2 C82 129.0(3) . . ?
C89 Fe2 C83 107.2(3) . . ?
C89 Fe2 C90 40.4(3) . . ?
C83 Fe2 C82 41.2(3) . . ?
C83 Fe2 C90 123.3(4) . . ?
C84 Fe2 C82 68.3(3) . . ?
C84 Fe2 C81 68.1(3) . . ?
C84 Fe2 C88 153.5(3) . . ?
C84 Fe2 C86 122.1(4) . . ?
C84 Fe2 C89 116.3(3) . . ?
C84 Fe2 C83 40.1(3) . . ?
C84 Fe2 C90 103.3(3) . . ?
C84 Fe2 C85 40.5(3) . . ?
C90 Fe2 C82 163.3(4) . . ?
C85 Fe2 C82 68.7(3) . . ?
C85 Fe2 C81 40.8(3) . . ?
C85 Fe2 C86 104.5(3) . . ?
C85 Fe2 C89 149.3(3) . . ?
C85 Fe2 C83 68.3(3) . . ?
C85 Fe2 C90 114.9(3) . . ?
C115 Fe1 C119 40.9(3) . . ?
C115 Fe1 C122 131.4(3) . . ?
C115 Fe1 C121 110.2(3) . . ?
C115 Fe1 C118 68.7(3) . . ?
C115 Fe1 C116 41.8(3) . . ?
C115 Fe1 C117 68.9(3) . . ?
C115 Fe1 C120 117.9(4) . . ?
C115 Fe1 C124 149.3(4) . . ?
C119 Fe1 C122 109.8(3) . . ?
C119 Fe1 C121 119.3(3) . . ?
C119 Fe1 C118 40.8(3) . . ?
C119 Fe1 C116 69.1(3) . . ?
C119 Fe1 C117 68.2(3) . . ?
C119 Fe1 C120 152.0(4) . . ?
C119 Fe1 C124 166.9(5) . . ?
C122 Fe1 C121 40.6(3) . . ?
C122 Fe1 C118 117.6(3) . . ?
C122 Fe1 C116 170.5(3) . . ?
C122 Fe1 C117 148.6(4) . . ?
C121 Fe1 C118 151.6(3) . . ?
C116 Fe1 C121 131.1(3) . . ?
C116 Fe1 C118 68.2(4) . . ?
C117 Fe1 C121 168.2(3) . . ?
C117 Fe1 C118 40.0(3) . . ?
C117 Fe1 C116 40.5(3) . . ?
C123 Fe1 C115 170.0(3) . . ?
C123 Fe1 C119 130.0(4) . . ?
C123 Fe1 C122 41.9(3) . . ?
C123 Fe1 C121 69.4(4) . . ?
C123 Fe1 C118 106.6(4) . . ?
C123 Fe1 C116 145.9(3) . . ?
C123 Fe1 C117 113.7(4) . . ?
C123 Fe1 C120 68.7(4) . . ?
C123 Fe1 C124 40.5(4) . . ?
C120 Fe1 C122 68.6(3) . . ?
C120 Fe1 C121 40.9(4) . . ?
C120 Fe1 C118 165.8(5) . . ?
C120 Fe1 C116 107.6(4) . . ?
C120 Fe1 C117 128.2(4) . . ?
C124 Fe1 C122 69.0(4) . . ?
C124 Fe1 C121 68.9(5) . . ?
C124 Fe1 C118 127.3(5) . . ?
C124 Fe1 C116 114.2(4) . . ?
C124 Fe1 C117 105.6(5) . . ?
C124 Fe1 C120 40.7(5) . . ?
C56 P8 Au6 112.41(19) . . ?
C56 P8 C63 105.2(3) . . ?
C56 P8 C57 104.6(3) . . ?
C63 P8 Au6 114.09(19) . . ?
C63 P8 C57 107.0(3) . . ?
C57 P8 Au6 112.8(2) . . ?
C7 P3 Au7 114.7(3) . . ?
C7 P3 C1 105.9(4) . . ?
C1 P3 Au7 112.7(2) . . ?
C13 P3 Au7 114.6(2) . . ?
C13 P3 C7 104.7(4) . . ?
C13 P3 C1 103.2(3) . . ?
C91 P1 Au3 110.5(2) . . ?
C97 P1 Au3 117.1(2) . . ?
C97 P1 C91 103.9(3) . . ?
C88 P1 Au3 113.7(2) . . ?
C88 P1 C91 104.4(3) . . ?
C88 P1 C97 106.1(3) . . ?
C35 P7 Au8 115.1(2) . . ?
C47 P7 Au8 111.1(2) . . ?
C47 P7 C35 103.5(3) . . ?
C47 P7 C41 105.1(3) . . ?
C41 P7 Au8 117.4(2) . . ?
C41 P7 C35 103.3(3) . . ?
C74 P2 Au4 117.0(2) . . ?
C75 P2 Au4 112.1(2) . . ?
C75 P2 C74 106.9(3) . . ?
C81 P2 Au4 113.3(2) . . ?
C81 P2 C74 103.0(3) . . ?
C81 P2 C75 103.3(3) . . ?
C23 P4 Au9 110.8(2) . . ?
C29 P4 Au9 113.9(2) . . ?
C29 P4 C23 105.4(3) . . ?
C21 P4 Au9 113.6(2) . . ?
C21 P4 C23 105.9(3) . . ?
C21 P4 C29 106.6(3) . . ?
C109 P6 Au2 112.3(2) . . ?
C109 P6 C103 107.1(3) . . ?
C115 P6 Au2 112.3(2) . . ?
C115 P6 C109 103.7(3) . . ?
C115 P6 C103 107.4(3) . . ?
C103 P6 Au2 113.5(2) . . ?
C125 P5 Au1 114.4(2) . . ?
C125 P5 C131 105.1(3) . . ?
C131 P5 Au1 112.2(2) . . ?
C122 P5 Au1 114.0(2) . . ?
C122 P5 C125 104.6(3) . . ?
C122 P5 C131 105.6(4) . . ?
P8 C56 Fe4 125.9(3) . . ?
C52 C56 Fe4 70.4(3) . . ?
C52 C56 P8 123.6(4) . . ?
C52 C56 C55 108.0(6) . . ?
C55 C56 Fe4 69.7(4) . . ?
C55 C56 P8 128.5(5) . . ?
Fe4 C52 H52 126.4 . . ?
C56 C52 Fe4 69.2(3) . . ?
C56 C52 H52 125.9 . . ?
C53 C52 Fe4 70.2(4) . . ?
C53 C52 C56 108.2(6) . . ?
C53 C52 H52 125.9 . . ?
C68 C63 P8 119.2(5) . . ?
C64 C63 P8 122.7(5) . . ?
C64 C63 C68 118.1(6) . . ?
C58 C57 P8 118.2(5) . . ?
C58 C57 C62 119.5(6) . . ?
C62 C57 P8 122.2(5) . . ?
C69 C74 P2 118.9(4) . . ?
C69 C74 C73 120.3(6) . . ?
C73 C74 P2 120.7(5) . . ?
C130 C125 P5 123.6(5) . . ?
C130 C125 C126 116.5(6) . . ?
C126 C125 P5 119.9(5) . . ?
C57 C58 H58 119.9 . . ?
C57 C58 C59 120.1(7) . . ?
C59 C58 H58 119.9 . . ?
C96 C91 P1 119.4(5) . . ?
C96 C91 C92 117.9(6) . . ?
C92 C91 P1 122.7(6) . . ?
C24 C23 P4 117.8(6) . . ?
C28 C23 P4 124.0(6) . . ?
C28 C23 C24 118.2(7) . . ?
C63 C68 H68 119.8 . . ?
C67 C68 C63 120.4(6) . . ?
C67 C68 H68 119.8 . . ?
C114 C109 P6 116.9(5) . . ?
C110 C109 P6 124.1(5) . . ?
C110 C109 C114 118.9(6) . . ?
C40 C35 P7 122.0(6) . . ?
C40 C35 C36 118.0(7) . . ?
C36 C35 P7 120.0(6) . . ?
Fe2 C82 H82 126.6 . . ?
C81 C82 Fe2 69.3(4) . . ?
C81 C82 H82 126.5 . . ?
C81 C82 C83 106.9(7) . . ?
C83 C82 Fe2 69.2(4) . . ?
C83 C82 H82 126.5 . . ?
P6 C115 Fe1 127.5(4) . . ?
C119 C115 Fe1 70.0(4) . . ?
C119 C115 P6 124.3(5) . . ?
C119 C115 C116 107.8(6) . . ?
C116 C115 Fe1 70.3(4) . . ?
C116 C115 P6 127.9(6) . . ?
C8 C7 P3 113.2(9) . . ?
C12 C7 P3 129.4(11) . . ?
C12 C7 C8 116.6(13) . . ?
C138 C7 P3 114.9(8) . . ?
C97A C7 P3 123.4(8) . . ?
C97A C7 C138 120.9(9) . . ?
P7 C47 Fe4 127.9(3) . . ?
C51 C47 Fe4 69.5(4) . . ?
C51 C47 P7 127.5(5) . . ?
C48 C47 Fe4 69.9(4) . . ?
C48 C47 P7 124.4(5) . . ?
C48 C47 C51 108.1(6) . . ?
C74 C69 H69 119.9 . . ?
C74 C69 C70 120.1(6) . . ?
C70 C69 H69 119.9 . . ?
Fe3 C17 H17 126.6 . . ?
C13 C17 Fe3 69.3(4) . . ?
C13 C17 H17 126.1 . . ?
C16 C17 Fe3 69.5(4) . . ?
C16 C17 H17 126.1 . . ?
C16 C17 C13 107.7(6) . . ?
C125 C130 H130 119.4 . . ?
C129 C130 C125 121.2(7) . . ?
C129 C130 H130 119.4 . . ?
C58 C59 H59 120.4 . . ?
C60 C59 C58 119.3(8) . . ?
C60 C59 H59 120.4 . . ?
C42 C41 P7 121.0(5) . . ?
C46 C41 P7 119.8(5) . . ?
C46 C41 C42 119.1(6) . . ?
C58A C75 P2 114.6(5) . . ?
C58A C75 C1B 120.0 . . ?
C1B C75 P2 125.4(5) . . ?
C76 C75 P2 121.8(7) . . ?
C76 C75 C80 115.2(10) . . ?
C80 C75 P2 118.9(6) . . ?
C75 C58A H58A 120.0 . . ?
C75 C58A C84A 120.0 . . ?
C84A C58A H58A 120.0 . . ?
C58A C84A H84A 120.0 . . ?
C137 C84A C58A 120.0 . . ?
C137 C84A H84A 120.0 . . ?
C84A C137 H137 120.0 . . ?
C84A C137 C1A 120.0 . . ?
C1A C137 H137 120.0 . . ?
C137 C1A H1A 120.0 . . ?
C137 C1A C1B 120.0 . . ?
C1B C1A H1A 120.0 . . ?
C75 C1B H1B 120.0 . . ?
C1A C1B C75 120.0 . . ?
C1A C1B H1B 120.0 . . ?
C63 C64 H64 119.5 . . ?
C63 C64 C65 121.0(7) . . ?
C65 C64 H64 119.5 . . ?
C104 C103 P6 117.7(5) . . ?
C104 C103 C108 119.9(7) . . ?
C108 C103 P6 122.3(6) . . ?
C34 C29 P4 120.2(5) . . ?
C34 C29 C30 117.6(7) . . ?
C30 C29 P4 122.2(6) . . ?
Fe2 C87 H87 125.9 . . ?
C88 C87 Fe2 69.9(4) . . ?
C88 C87 H87 125.5 . . ?
C86 C87 Fe2 70.4(4) . . ?
C86 C87 H87 125.5 . . ?
C86 C87 C88 109.1(7) . . ?
C74 C73 H73 120.4 . . ?
C74 C73 C72 119.2(7) . . ?
C72 C73 H73 120.4 . . ?
C132 C131 P5 118.6(5) . . ?
C132 C131 C136 118.4(7) . . ?
C136 C131 P5 123.0(6) . . ?
Fe4 C55 H55 126.3 . . ?
C56 C55 Fe4 69.2(3) . . ?
C56 C55 H55 126.3 . . ?
C54 C55 Fe4 69.7(4) . . ?
C54 C55 C56 107.3(6) . . ?
C54 C55 H55 126.3 . . ?
C97 C102 H102 119.5 . . ?
C97 C102 C101 121.1(7) . . ?
C101 C102 H102 119.5 . . ?
C103 C104 H104 120.0 . . ?
C103 C104 C105 120.1(7) . . ?
C105 C104 H104 120.0 . . ?
P2 C81 Fe2 132.7(3) . . ?
C82 C81 Fe2 70.1(4) . . ?
C82 C81 P2 121.9(5) . . ?
C82 C81 C85 108.5(6) . . ?
C85 C81 Fe2 69.5(4) . . ?
C85 C81 P2 129.1(5) . . ?
C102 C97 P1 119.3(5) . . ?
C102 C97 C98 118.5(6) . . ?
C98 C97 P1 122.1(5) . . ?
C70 C71 H71 120.0 . . ?
C72 C71 H71 120.0 . . ?
C72 C71 C70 120.0(6) . . ?
C2 C1 P3 118.0(6) . . ?
C6 C1 P3 123.7(5) . . ?
C6 C1 C2 118.3(7) . . ?
P4 C21 Fe3 124.3(3) . . ?
C22 C21 Fe3 69.6(4) . . ?
C22 C21 P4 122.5(5) . . ?
C20 C21 Fe3 70.7(4) . . ?
C20 C21 P4 130.6(5) . . ?
C20 C21 C22 106.9(6) . . ?
C68 C67 H67 119.7 . . ?
C66 C67 C68 120.7(7) . . ?
C66 C67 H67 119.7 . . ?
C103 C108 H108 120.4 . . ?
C107 C108 C103 119.2(8) . . ?
C107 C108 H108 120.4 . . ?
C131 C132 H132 119.3 . . ?
C131 C132 C133 121.3(7) . . ?
C133 C132 H132 119.3 . . ?
Fe1 C119 H119 125.9 . . ?
C115 C119 Fe1 69.2(4) . . ?
C115 C119 H119 125.9 . . ?
C115 C119 C118 108.3(6) . . ?
C118 C119 Fe1 70.7(4) . . ?
C118 C119 H119 125.9 . . ?
Fe4 C49 H49 127.2 . . ?
C50 C49 Fe4 69.5(4) . . ?
C50 C49 H49 125.3 . . ?
C50 C49 C48 109.4(6) . . ?
C48 C49 Fe4 69.6(4) . . ?
C48 C49 H49 125.3 . . ?
P5 C122 Fe1 126.9(4) . . ?
C121 C122 Fe1 70.1(5) . . ?
C121 C122 P5 124.6(6) . . ?
C121 C122 C123 107.5(7) . . ?
C123 C122 Fe1 68.2(5) . . ?
C123 C122 P5 127.9(7) . . ?
Fe3 C22 H22 126.5 . . ?
C21 C22 Fe3 68.7(4) . . ?
C21 C22 H22 125.9 . . ?
C18 C22 Fe3 70.5(4) . . ?
C18 C22 C21 108.3(6) . . ?
C18 C22 H22 125.9 . . ?
C102 C101 H101 120.1 . . ?
C100 C101 C102 119.8(7) . . ?
C100 C101 H101 120.1 . . ?
P3 C13 Fe3 129.8(3) . . ?
C17 C13 Fe3 68.9(3) . . ?
C17 C13 P3 124.2(5) . . ?
C14 C13 Fe3 69.7(4) . . ?
C14 C13 P3 128.8(5) . . ?
C14 C13 C17 106.9(6) . . ?
P1 C88 Fe2 129.8(3) . . ?
C87 C88 Fe2 69.3(4) . . ?
C87 C88 P1 124.7(5) . . ?
C87 C88 C89 107.2(6) . . ?
C89 C88 Fe2 69.7(4) . . ?
C89 C88 P1 127.9(5) . . ?
C29 C34 H34 119.0 . . ?
C33 C34 C29 121.9(7) . . ?
C33 C34 H34 119.0 . . ?
C69 C70 C71 119.8(6) . . ?
C69 C70 H70 120.1 . . ?
C71 C70 H70 120.1 . . ?
C41 C42 H42 119.6 . . ?
C43 C42 C41 120.7(7) . . ?
C43 C42 H42 119.6 . . ?
C23 C24 H24 119.4 . . ?
C25 C24 C23 121.2(8) . . ?
C25 C24 H24 119.4 . . ?
Fe4 C53 H53 126.7 . . ?
C52 C53 Fe4 69.9(3) . . ?
C52 C53 H53 125.8 . . ?
C52 C53 C54 108.5(6) . . ?
C54 C53 Fe4 69.2(4) . . ?
C54 C53 H53 125.8 . . ?
Fe4 C50 H50 125.8 . . ?
C49 C50 Fe4 70.4(4) . . ?
C49 C50 H50 125.8 . . ?
C49 C50 C51 108.4(6) . . ?
C51 C50 Fe4 69.6(4) . . ?
C51 C50 H50 125.8 . . ?
C73 C72 H72 119.7 . . ?
C71 C72 C73 120.6(6) . . ?
C71 C72 H72 119.7 . . ?
Fe3 C20 H20 127.6 . . ?
C21 C20 Fe3 68.6(4) . . ?
C21 C20 H20 125.8 . . ?
C19 C20 Fe3 69.6(4) . . ?
C19 C20 C21 108.4(7) . . ?
C19 C20 H20 125.8 . . ?
Fe4 C51 H51 126.5 . . ?
C47 C51 Fe4 69.1(4) . . ?
C47 C51 H51 126.6 . . ?
C50 C51 Fe4 69.5(4) . . ?
C50 C51 C47 106.9(7) . . ?
C50 C51 H51 126.6 . . ?
Fe2 C86 H86 126.0 . . ?
C87 C86 Fe2 69.4(4) . . ?
C87 C86 H86 126.3 . . ?
C87 C86 C90 107.5(7) . . ?
C90 C86 Fe2 69.9(5) . . ?
C90 C86 H86 126.3 . . ?
Fe3 C18 H18 126.5 . . ?
C22 C18 Fe3 69.8(4) . . ?
C22 C18 H18 125.7 . . ?
C22 C18 C19 108.5(7) . . ?
C19 C18 Fe3 69.5(4) . . ?
C19 C18 H18 125.7 . . ?
C75 C76 H76 119.3 . . ?
C75 C76 C77 121.3(11) . . ?
C77 C76 H76 119.3 . . ?
Fe4 C54 H54 125.6 . . ?
C55 C54 Fe4 69.7(4) . . ?
C55 C54 C53 108.1(6) . . ?
C55 C54 H54 126.0 . . ?
C53 C54 Fe4 70.3(4) . . ?
C53 C54 H54 126.0 . . ?
C57 C62 H62 120.4 . . ?
C61 C62 C57 119.1(7) . . ?
C61 C62 H62 120.4 . . ?
Fe2 C89 H89 126.1 . . ?
C88 C89 Fe2 69.2(3) . . ?
C88 C89 H89 126.4 . . ?
C90 C89 Fe2 69.9(4) . . ?
C90 C89 C88 107.3(7) . . ?
C90 C89 H89 126.4 . . ?
Fe3 C19 H19 125.6 . . ?
C20 C19 Fe3 70.2(4) . . ?
C20 C19 C18 107.8(7) . . ?
C20 C19 H19 126.1 . . ?
C18 C19 Fe3 69.7(4) . . ?
C18 C19 H19 126.1 . . ?
C41 C46 H46 120.1 . . ?
C41 C46 C45 119.8(6) . . ?
C45 C46 H46 120.1 . . ?
C59 C60 H60 119.7 . . ?
C61 C60 C59 120.6(7) . . ?
C61 C60 H60 119.7 . . ?
C97 C98 H98 119.9 . . ?
C99 C98 C97 120.1(7) . . ?
C99 C98 H98 119.9 . . ?
Fe3 C16 H16 126.1 . . ?
C17 C16 Fe3 70.2(4) . . ?
C17 C16 H16 125.4 . . ?
C15 C16 Fe3 69.9(4) . . ?
C15 C16 C17 109.2(6) . . ?
C15 C16 H16 125.4 . . ?
C46 C45 H45 119.8 . . ?
C44 C45 C46 120.5(7) . . ?
C44 C45 H45 119.8 . . ?
Fe3 C14 H14 126.7 . . ?
C13 C14 Fe3 70.0(4) . . ?
C13 C14 H14 126.0 . . ?
C13 C14 C15 108.0(6) . . ?
C15 C14 Fe3 68.9(4) . . ?
C15 C14 H14 126.0 . . ?
Fe1 C121 H121 127.2 . . ?
C122 C121 Fe1 69.3(5) . . ?
C122 C121 H121 126.2 . . ?
C122 C121 C120 107.5(9) . . ?
C120 C121 Fe1 68.8(6) . . ?
C120 C121 H121 126.2 . . ?
C67 C66 H66 120.1 . . ?
C65 C66 C67 119.9(7) . . ?
C65 C66 H66 120.1 . . ?
Fe4 C48 H48 126.1 . . ?
C47 C48 Fe4 69.1(4) . . ?
C47 C48 H48 126.4 . . ?
C49 C48 Fe4 70.0(4) . . ?
C49 C48 C47 107.2(6) . . ?
C49 C48 H48 126.4 . . ?
Fe2 C83 H83 126.4 . . ?
C82 C83 Fe2 69.6(4) . . ?
C82 C83 H83 126.2 . . ?
C84 C83 Fe2 69.5(5) . . ?
C84 C83 C82 107.7(7) . . ?
C84 C83 H83 126.2 . . ?
C1 C2 H2 119.7 . . ?
C3 C2 C1 120.7(8) . . ?
C3 C2 H2 119.7 . . ?
C125 C126 H126 118.7 . . ?
C127 C126 C125 122.5(7) . . ?
C127 C126 H126 118.7 . . ?
C62 C61 C60 121.2(8) . . ?
C62 C61 H61 119.4 . . ?
C60 C61 H61 119.4 . . ?
C29 C30 H30 120.6 . . ?
C31 C30 C29 118.9(8) . . ?
C31 C30 H30 120.6 . . ?
Fe2 C84 H84 125.9 . . ?
C83 C84 Fe2 70.5(4) . . ?
C83 C84 H84 125.2 . . ?
C83 C84 C85 109.6(7) . . ?
C85 C84 Fe2 70.0(4) . . ?
C85 C84 H84 125.2 . . ?
Fe2 C90 H90 126.8 . . ?
C86 C90 Fe2 69.6(4) . . ?
C86 C90 H90 125.5 . . ?
C89 C90 Fe2 69.7(4) . . ?
C89 C90 C86 108.9(7) . . ?
C89 C90 H90 125.5 . . ?
C36 C37 H37 119.5 . . ?
C36 C37 C38 121.0(9) . . ?
C38 C37 H37 119.5 . . ?
C35 C40 H40 119.5 . . ?
C39 C40 C35 120.9(9) . . ?
C39 C40 H40 119.5 . . ?
C1 C6 H6 118.7 . . ?
C1 C6 C5 122.7(7) . . ?
C5 C6 H6 118.7 . . ?
C109 C114 H114 120.0 . . ?
C113 C114 C109 119.9(7) . . ?
C113 C114 H114 120.0 . . ?
C104 C105 H105 120.0 . . ?
C104 C105 C106 120.1(8) . . ?
C106 C105 H105 120.0 . . ?
C76 C77 H77 119.8 . . ?
C76 C77 C78 120.3(11) . . ?
C78 C77 H77 119.8 . . ?
Fe1 C118 H118 127.3 . . ?
C119 C118 Fe1 68.5(4) . . ?
C119 C118 H118 126.1 . . ?
C117 C118 Fe1 69.7(5) . . ?
C117 C118 C119 107.9(8) . . ?
C117 C118 H118 126.1 . . ?
C130 C129 H129 119.9 . . ?
C128 C129 C130 120.1(7) . . ?
C128 C129 H129 119.9 . . ?
C64 C65 H65 120.0 . . ?
C66 C65 C64 120.0(7) . . ?
C66 C65 H65 120.0 . . ?
Fe1 C116 H116 127.2 . . ?
C115 C116 Fe1 67.9(4) . . ?
C115 C116 H116 126.7 . . ?
C117 C116 Fe1 69.7(5) . . ?
C117 C116 C115 106.5(7) . . ?
C117 C116 H116 126.7 . . ?
C40 C39 H39 119.8 . . ?
C38 C39 C40 120.4(10) . . ?
C38 C39 H39 119.8 . . ?
C35 C36 H36 120.2 . . ?
C37 C36 C35 119.6(9) . . ?
C37 C36 H36 120.2 . . ?
C108 C107 H107 119.6 . . ?
C106 C107 C108 120.8(8) . . ?
C106 C107 H107 119.6 . . ?
C23 C28 H28 119.2 . . ?
C23 C28 C27 121.5(8) . . ?
C27 C28 H28 119.2 . . ?
C109 C110 H110 120.5 . . ?
C109 C110 C111 119.0(7) . . ?
C111 C110 H110 120.5 . . ?
Fe1 C117 H117 126.1 . . ?
C118 C117 Fe1 70.3(5) . . ?
C118 C117 C116 109.5(7) . . ?
C118 C117 H117 125.3 . . ?
C116 C117 Fe1 69.8(5) . . ?
C116 C117 H117 125.3 . . ?
C101 C100 H100 119.9 . . ?
C101 C100 C99 120.2(7) . . ?
C99 C100 H100 119.9 . . ?
C98 C99 H99 119.8 . . ?
C100 C99 C98 120.3(7) . . ?
C100 C99 H99 119.8 . . ?
C7 C8 H8 118.1 . . ?
C7 C8 C9 123.7(16) . . ?
C9 C8 H8 118.1 . . ?
C24 C25 H25 120.6 . . ?
C26 C25 C24 118.8(8) . . ?
C26 C25 H25 120.6 . . ?
C131 C136 H136 119.6 . . ?
C131 C136 C135 120.8(8) . . ?
C135 C136 H136 119.6 . . ?
C105 C106 H106 120.2 . . ?
C107 C106 C105 119.7(8) . . ?
C107 C106 H106 120.2 . . ?
C111 C112 H112 119.8 . . ?
C113 C112 H112 119.8 . . ?
C113 C112 C111 120.4(7) . . ?
Fe1 C123 H123 125.3 . . ?
C122 C123 Fe1 69.9(4) . . ?
C122 C123 H123 126.1 . . ?
C124 C123 Fe1 70.3(5) . . ?
C124 C123 C122 107.8(10) . . ?
C124 C123 H123 126.1 . . ?
C75 C80 H80 119.6 . . ?
C79 C80 C75 120.9(10) . . ?
C79 C80 H80 119.6 . . ?
C42 C43 H43 120.2 . . ?
C42 C43 C44 119.7(7) . . ?
C44 C43 H43 120.2 . . ?
C45 C44 C43 120.1(7) . . ?
C45 C44 H44 119.9 . . ?
C43 C44 H44 119.9 . . ?
C37 C38 H38 120.0 . . ?
C39 C38 C37 120.0(9) . . ?
C39 C38 H38 120.0 . . ?
C34 C33 H33 120.3 . . ?
C32 C33 C34 119.3(8) . . ?
C32 C33 H33 120.3 . . ?
C6 C5 H5 121.0 . . ?
C6 C5 C4 118.0(9) . . ?
C4 C5 H5 121.0 . . ?
C132 C133 H133 120.3 . . ?
C132 C133 C134 119.4(8) . . ?
C134 C133 H133 120.3 . . ?
C91 C96 H96 119.6 . . ?
C91 C96 C95 120.9(8) . . ?
C95 C96 H96 119.6 . . ?
Fe3 C15 H15 126.0 . . ?
C16 C15 Fe3 70.0(4) . . ?
C16 C15 C14 108.3(6) . . ?
C16 C15 H15 125.9 . . ?
C14 C15 Fe3 69.7(4) . . ?
C14 C15 H15 125.9 . . ?
C91 C92 H92 119.2 . . ?
C91 C92 C93 121.7(8) . . ?
C93 C92 H92 119.2 . . ?
Fe2 C85 H85 126.0 . . ?
C81 C85 Fe2 69.7(3) . . ?
C81 C85 H85 126.3 . . ?
C84 C85 Fe2 69.6(4) . . ?
C84 C85 C81 107.3(7) . . ?
C84 C85 H85 126.3 . . ?
C110 C111 H111 119.6 . . ?
C112 C111 C110 120.9(8) . . ?
C112 C111 H111 119.6 . . ?
Fe1 C120 H120 126.0 . . ?
C121 C120 Fe1 70.3(5) . . ?
C121 C120 H120 125.7 . . ?
C124 C120 Fe1 69.6(6) . . ?
C124 C120 C121 108.6(8) . . ?
C124 C120 H120 125.7 . . ?
C126 C127 H127 120.8 . . ?
C128 C127 C126 118.4(8) . . ?
C128 C127 H127 120.8 . . ?
C95 C94 H94 119.7 . . ?
C95 C94 C93 120.7(8) . . ?
C93 C94 H94 119.7 . . ?
C2 C3 H3 120.4 . . ?
C4 C3 C2 119.2(8) . . ?
C4 C3 H3 120.4 . . ?
C25 C26 H26 119.3 . . ?
C25 C26 C27 121.3(8) . . ?
C27 C26 H26 119.3 . . ?
C28 C27 H27 120.5 . . ?
C26 C27 C28 118.9(9) . . ?
C26 C27 H27 120.5 . . ?
C7 C12 H12 119.8 . . ?
C7 C12 C11 120.4(17) . . ?
C11 C12 H12 119.8 . . ?
C129 C128 H128 119.5 . . ?
C127 C128 C129 121.1(8) . . ?
C127 C128 H128 119.5 . . ?
C136 C135 H135 119.4 . . ?
C134 C135 C136 121.1(8) . . ?
C134 C135 H135 119.4 . . ?
C30 C31 H31 119.2 . . ?
C32 C31 C30 121.7(8) . . ?
C32 C31 H31 119.2 . . ?
C33 C32 H32 119.7 . . ?
C31 C32 C33 120.6(8) . . ?
C31 C32 H32 119.7 . . ?
Fe1 C124 H124 127.0 . . ?
C123 C124 Fe1 69.2(5) . . ?
C123 C124 C120 108.5(9) . . ?
C123 C124 H124 125.7 . . ?
C120 C124 Fe1 69.6(5) . . ?
C120 C124 H124 125.7 . . ?
C5 C4 H4 119.5 . . ?
C3 C4 C5 121.0(8) . . ?
C3 C4 H4 119.5 . . ?
C133 C134 H134 120.5 . . ?
C135 C134 C133 119.0(9) . . ?
C135 C134 H134 120.5 . . ?
C77 C78 H78 120.8 . . ?
C79 C78 C77 118.3(11) . . ?
C79 C78 H78 120.8 . . ?
C114 C113 H113 119.6 . . ?
C112 C113 C114 120.9(8) . . ?
C112 C113 H113 119.6 . . ?
C8 C9 H9 121.0 . . ?
C10 C9 C8 118.0(17) . . ?
C10 C9 H9 121.0 . . ?
C12 C11 H11 119.4 . . ?
C10 C11 C12 121.1(16) . . ?
C10 C11 H11 119.4 . . ?
C9 C10 C11 119.6(15) . . ?
C9 C10 H10 120.2 . . ?
C11 C10 H10 120.2 . . ?
C96 C95 H95 119.9 . . ?
C94 C95 C96 120.2(9) . . ?
C94 C95 H95 119.9 . . ?
C80 C79 C78 120.0(11) . . ?
C80 C79 H79 120.0 . . ?
C78 C79 H79 120.0 . . ?
C92 C93 H93 120.7 . . ?
C94 C93 C92 118.6(9) . . ?
C94 C93 H93 120.7 . . ?
C7 C138 H138 121.5 . . ?
C1C C138 C7 117.1(12) . . ?
C1C C138 H138 121.5 . . ?
C138 C1C H1C 119.9 . . ?
C1D C1C C138 120.3(12) . . ?
C1D C1C H1C 119.9 . . ?
C1C C1D H1D 118.9 . . ?
C1E C1D C1C 122.2(11) . . ?
C1E C1D H1D 118.9 . . ?
C1D C1E H1E 120.7 . . ?
C1D C1E C97A 118.7(13) . . ?
C97A C1E H1E 120.7 . . ?
C7 C97A C1E 120.4(12) . . ?
C7 C97A H97A 119.8 . . ?
C1E C97A H97A 119.8 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au6 P8 C56 Fe4 -63.2(4) . . . . ?
Au6 P8 C56 C52 25.9(6) . . . . ?
Au6 P8 C56 C55 -154.7(5) . . . . ?
Au6 P8 C63 C68 22.8(5) . . . . ?
Au6 P8 C63 C64 -157.7(5) . . . . ?
Au6 P8 C57 C58 14.5(6) . . . . ?
Au6 P8 C57 C62 -168.3(5) . . . . ?
Au4 P2 C74 C69 14.6(6) . . . . ?
Au4 P2 C74 C73 -162.4(5) . . . . ?
Au4 P2 C75 C58A 14.9(9) . . . . ?
Au4 P2 C75 C1B -165.2(9) . . . . ?
Au4 P2 C75 C76 24.2(11) . . . . ?
Au4 P2 C75 C80 -131.9(8) . . . . ?
Au4 P2 C81 Fe2 -60.8(5) . . . . ?
Au4 P2 C81 C82 30.9(6) . . . . ?
Au4 P2 C81 C85 -158.6(5) . . . . ?
Au9 P4 C23 C24 -22.1(7) . . . . ?
Au9 P4 C23 C28 155.7(7) . . . . ?
Au9 P4 C29 C34 -14.7(6) . . . . ?
Au9 P4 C29 C30 167.5(5) . . . . ?
Au9 P4 C21 Fe3 62.0(4) . . . . ?
Au9 P4 C21 C22 -24.2(6) . . . . ?
Au9 P4 C21 C20 155.3(6) . . . . ?
Au2 P6 C109 C114 61.6(6) . . . . ?
Au2 P6 C109 C110 -118.6(6) . . . . ?
Au2 P6 C115 Fe1 67.7(5) . . . . ?
Au2 P6 C115 C119 -22.3(6) . . . . ?
Au2 P6 C115 C116 161.0(6) . . . . ?
Au2 P6 C103 C104 -8.4(6) . . . . ?
Au2 P6 C103 C108 171.4(5) . . . . ?
Au1 P5 C125 C130 152.9(5) . . . . ?
Au1 P5 C125 C126 -28.1(7) . . . . ?
Au1 P5 C131 C132 -17.0(7) . . . . ?
Au1 P5 C131 C136 164.0(6) . . . . ?
Au1 P5 C122 Fe1 62.7(6) . . . . ?
Au1 P5 C122 C121 -27.5(7) . . . . ?
Au1 P5 C122 C123 152.4(6) . . . . ?
Au3 P1 C91 C96 51.7(7) . . . . ?
Au3 P1 C91 C92 -129.9(7) . . . . ?
Au3 P1 C97 C102 32.9(6) . . . . ?
Au3 P1 C97 C98 -149.5(5) . . . . ?
Au3 P1 C88 Fe2 -60.6(5) . . . . ?
Au3 P1 C88 C87 30.5(6) . . . . ?
Au3 P1 C88 C89 -155.0(5) . . . . ?
Au8 P7 C35 C40 -108.9(6) . . . . ?
Au8 P7 C35 C36 69.9(6) . . . . ?
Au8 P7 C47 Fe4 -62.2(4) . . . . ?
Au8 P7 C47 C51 -154.2(5) . . . . ?
Au8 P7 C47 C48 28.1(6) . . . . ?
Au8 P7 C41 C42 -163.5(5) . . . . ?
Au8 P7 C41 C46 18.4(6) . . . . ?
Au7 P3 C7 C8 -26(2) . . . . ?
Au7 P3 C7 C12 164.7(16) . . . . ?
Au7 P3 C7 C138 144.8(9) . . . . ?
Au7 P3 C7 C97A -24.7(17) . . . . ?
Au7 P3 C1 C2 -58.5(6) . . . . ?
Au7 P3 C1 C6 117.7(6) . . . . ?
Au7 P3 C13 Fe3 54.9(5) . . . . ?
Au7 P3 C13 C17 -35.0(6) . . . . ?
Au7 P3 C13 C14 150.0(5) . . . . ?
Fe4 C56 C52 C53 -59.5(4) . . . . ?
Fe4 C56 C55 C54 59.6(5) . . . . ?
Fe4 C52 C53 C54 -58.6(5) . . . . ?
Fe4 C47 C51 C50 59.4(5) . . . . ?
Fe4 C47 C48 C49 -59.8(5) . . . . ?
Fe4 C55 C54 C53 60.1(5) . . . . ?
Fe4 C49 C50 C51 -59.4(5) . . . . ?
Fe4 C49 C48 C47 59.3(4) . . . . ?
Fe4 C53 C54 C55 -59.7(5) . . . . ?
Fe4 C50 C51 C47 -59.2(4) . . . . ?
Fe3 C17 C13 P3 124.5(5) . . . . ?
Fe3 C17 C13 C14 -59.6(4) . . . . ?
Fe3 C17 C16 C15 59.2(5) . . . . ?
Fe3 C21 C22 C18 59.6(5) . . . . ?
Fe3 C21 C20 C19 -58.3(5) . . . . ?
Fe3 C22 C18 C19 58.9(5) . . . . ?
Fe3 C13 C14 C15 -58.6(5) . . . . ?
Fe3 C20 C19 C18 -59.8(5) . . . . ?
Fe3 C18 C19 C20 60.1(5) . . . . ?
Fe3 C16 C15 C14 59.4(5) . . . . ?
Fe3 C14 C15 C16 -59.6(5) . . . . ?
Fe2 C82 C81 P2 -128.6(5) . . . . ?
Fe2 C82 C81 C85 59.1(4) . . . . ?
Fe2 C82 C83 C84 -59.2(5) . . . . ?
Fe2 C87 C88 P1 -124.9(5) . . . . ?
Fe2 C87 C88 C89 59.7(4) . . . . ?
Fe2 C87 C86 C90 -59.8(5) . . . . ?
Fe2 C81 C85 C84 59.6(5) . . . . ?
Fe2 C88 C89 C90 59.8(5) . . . . ?
Fe2 C86 C90 C89 -58.7(5) . . . . ?
Fe2 C89 C90 C86 58.7(5) . . . . ?
Fe2 C83 C84 C85 -59.2(5) . . . . ?
Fe2 C84 C85 C81 -59.7(5) . . . . ?
Fe1 C115 C119 C118 60.1(5) . . . . ?
Fe1 C115 C116 C117 -59.2(6) . . . . ?
Fe1 C119 C118 C117 58.7(6) . . . . ?
Fe1 C122 C121 C120 58.3(6) . . . . ?
Fe1 C122 C123 C124 -60.3(7) . . . . ?
Fe1 C121 C120 C124 59.3(7) . . . . ?
Fe1 C118 C117 C116 59.0(6) . . . . ?
Fe1 C116 C117 C118 -59.3(6) . . . . ?
Fe1 C123 C124 C120 -58.7(7) . . . . ?
Fe1 C120 C124 C123 58.4(7) . . . . ?
P8 C56 C52 Fe4 -120.7(5) . . . . ?
P8 C56 C52 C53 179.8(4) . . . . ?
P8 C56 C55 Fe4 120.3(5) . . . . ?
P8 C56 C55 C54 179.8(5) . . . . ?
P8 C63 C68 C67 179.5(5) . . . . ?
P8 C63 C64 C65 -179.3(5) . . . . ?
P8 C57 C58 C59 176.1(6) . . . . ?
P8 C57 C62 C61 -176.0(6) . . . . ?
P3 C7 C8 C9 -177(3) . . . . ?
P3 C7 C12 C11 172.2(16) . . . . ?
P3 C7 C138 C1C -178.2(11) . . . . ?
P3 C7 C97A C1E 176.3(15) . . . . ?
P3 C1 C2 C3 179.9(7) . . . . ?
P3 C1 C6 C5 -178.1(7) . . . . ?
P3 C13 C14 Fe3 -125.3(6) . . . . ?
P3 C13 C14 C15 176.2(5) . . . . ?
P1 C91 C96 C95 176.1(9) . . . . ?
P1 C91 C92 C93 -175.9(10) . . . . ?
P1 C97 C98 C99 -179.1(6) . . . . ?
P1 C88 C89 Fe2 125.3(5) . . . . ?
P1 C88 C89 C90 -174.9(5) . . . . ?
P7 C35 C40 C39 179.3(7) . . . . ?
P7 C35 C36 C37 -180.0(6) . . . . ?
P7 C47 C51 Fe4 122.6(5) . . . . ?
P7 C47 C51 C50 -177.9(5) . . . . ?
P7 C47 C48 Fe4 -122.8(5) . . . . ?
P7 C47 C48 C49 177.3(5) . . . . ?
P7 C41 C42 C43 -176.7(6) . . . . ?
P7 C41 C46 C45 177.0(5) . . . . ?
P2 C74 C69 C70 -178.1(5) . . . . ?
P2 C74 C73 C72 178.2(5) . . . . ?
P2 C75 C58A C84A 179.89(7) . . . . ?
P2 C75 C1B C1A -179.88(8) . . . . ?
P2 C75 C76 C77 -179.5(11) . . . . ?
P2 C75 C80 C79 172.3(10) . . . . ?
P2 C81 C85 Fe2 129.0(5) . . . . ?
P2 C81 C85 C84 -171.4(5) . . . . ?
P4 C23 C24 C25 177.2(7) . . . . ?
P4 C23 C28 C27 -177.8(9) . . . . ?
P4 C29 C34 C33 -178.9(6) . . . . ?
P4 C29 C30 C31 179.0(6) . . . . ?
P4 C21 C22 Fe3 118.4(5) . . . . ?
P4 C21 C22 C18 178.0(5) . . . . ?
P4 C21 C20 Fe3 -119.1(6) . . . . ?
P4 C21 C20 C19 -177.4(5) . . . . ?
P6 C109 C114 C113 176.8(7) . . . . ?
P6 C109 C110 C111 -175.4(6) . . . . ?
P6 C115 C119 Fe1 122.4(5) . . . . ?
P6 C115 C119 C118 -177.6(5) . . . . ?
P6 C115 C116 Fe1 -122.7(6) . . . . ?
P6 C115 C116 C117 178.0(6) . . . . ?
P6 C103 C104 C105 176.0(6) . . . . ?
P6 C103 C108 C107 -177.6(6) . . . . ?
P5 C125 C130 C129 177.7(6) . . . . ?
P5 C125 C126 C127 -179.5(7) . . . . ?
P5 C131 C132 C133 -177.3(7) . . . . ?
P5 C131 C136 C135 177.6(7) . . . . ?
P5 C122 C121 Fe1 121.8(6) . . . . ?
P5 C122 C121 C120 -179.9(6) . . . . ?
P5 C122 C123 Fe1 -120.6(6) . . . . ?
P5 C122 C123 C124 179.1(7) . . . . ?
C56 P8 C63 C68 146.4(5) . . . . ?
C56 P8 C63 C64 -34.0(6) . . . . ?
C56 P8 C57 C58 -107.9(6) . . . . ?
C56 P8 C57 C62 69.2(6) . . . . ?
C56 C52 C53 Fe4 58.9(4) . . . . ?
C56 C52 C53 C54 0.3(7) . . . . ?
C56 C55 C54 Fe4 -59.2(4) . . . . ?
C56 C55 C54 C53 0.9(7) . . . . ?
C52 C56 C55 Fe4 -60.3(4) . . . . ?
C52 C56 C55 C54 -0.7(7) . . . . ?
C52 C53 C54 Fe4 59.0(4) . . . . ?
C52 C53 C54 C55 -0.7(8) . . . . ?
C63 P8 C56 Fe4 172.1(3) . . . . ?
C63 P8 C56 C52 -98.9(5) . . . . ?
C63 P8 C56 C55 80.6(6) . . . . ?
C63 P8 C57 C58 140.8(5) . . . . ?
C63 P8 C57 C62 -42.1(6) . . . . ?
C63 C68 C67 C66 -1.0(10) . . . . ?
C63 C64 C65 C66 0.6(11) . . . . ?
C57 P8 C56 Fe4 59.5(4) . . . . ?
C57 P8 C56 C52 148.6(5) . . . . ?
C57 P8 C56 C55 -32.0(6) . . . . ?
C57 P8 C63 C68 -102.7(5) . . . . ?
C57 P8 C63 C64 76.8(6) . . . . ?
C57 C58 C59 C60 -1.9(12) . . . . ?
C57 C62 C61 C60 1.9(13) . . . . ?
C74 P2 C75 C58A 144.3(9) . . . . ?
C74 P2 C75 C1B -35.8(9) . . . . ?
C74 P2 C75 C76 153.7(11) . . . . ?
C74 P2 C75 C80 -2.4(8) . . . . ?
C74 P2 C81 Fe2 171.8(5) . . . . ?
C74 P2 C81 C82 -96.5(5) . . . . ?
C74 P2 C81 C85 74.1(7) . . . . ?
C74 C69 C70 C71 0.7(10) . . . . ?
C74 C73 C72 C71 -1.2(11) . . . . ?
C125 P5 C131 C132 -142.0(6) . . . . ?
C125 P5 C131 C136 39.0(8) . . . . ?
C125 P5 C122 Fe1 -171.6(5) . . . . ?
C125 P5 C122 C121 98.2(6) . . . . ?
C125 P5 C122 C123 -81.9(8) . . . . ?
C125 C130 C129 C128 0.6(12) . . . . ?
C125 C126 C127 C128 2.9(14) . . . . ?
C58 C57 C62 C61 1.1(11) . . . . ?
C58 C59 C60 C61 4.9(13) . . . . ?
C91 P1 C97 C102 155.0(5) . . . . ?
C91 P1 C97 C98 -27.3(6) . . . . ?
C91 P1 C88 Fe2 179.0(4) . . . . ?
C91 P1 C88 C87 -90.0(6) . . . . ?
C91 P1 C88 C89 84.5(6) . . . . ?
C91 C96 C95 C94 3.4(19) . . . . ?
C91 C92 C93 C94 -3(2) . . . . ?
C23 P4 C29 C34 -136.4(6) . . . . ?
C23 P4 C29 C30 45.9(6) . . . . ?
C23 P4 C21 Fe3 -176.2(4) . . . . ?
C23 P4 C21 C22 97.5(6) . . . . ?
C23 P4 C21 C20 -82.9(7) . . . . ?
C23 C24 C25 C26 1.2(16) . . . . ?
C23 C28 C27 C26 0.2(18) . . . . ?
C68 C63 C64 C65 0.3(10) . . . . ?
C68 C67 C66 C65 1.9(12) . . . . ?
C109 P6 C115 Fe1 -170.9(4) . . . . ?
C109 P6 C115 C119 99.1(6) . . . . ?
C109 P6 C115 C116 -77.5(7) . . . . ?
C109 P6 C103 C104 -132.8(5) . . . . ?
C109 P6 C103 C108 47.0(7) . . . . ?
C109 C114 C113 C112 0.3(14) . . . . ?
C109 C110 C111 C112 -3.2(14) . . . . ?
C35 P7 C47 Fe4 173.8(4) . . . . ?
C35 P7 C47 C51 81.7(6) . . . . ?
C35 P7 C47 C48 -95.9(6) . . . . ?
C35 P7 C41 C42 -35.7(7) . . . . ?
C35 P7 C41 C46 146.2(5) . . . . ?
C35 C40 C39 C38 -0.8(15) . . . . ?
C82 C81 C85 Fe2 -59.5(4) . . . . ?
C82 C81 C85 C84 0.1(7) . . . . ?
C82 C83 C84 Fe2 59.3(5) . . . . ?
C82 C83 C84 C85 0.1(8) . . . . ?
C115 P6 C109 C114 -59.8(6) . . . . ?
C115 P6 C109 C110 119.9(6) . . . . ?
C115 P6 C103 C104 116.3(6) . . . . ?
C115 P6 C103 C108 -63.9(7) . . . . ?
C115 C119 C118 Fe1 -59.2(5) . . . . ?
C115 C119 C118 C117 -0.4(9) . . . . ?
C115 C116 C117 Fe1 58.1(5) . . . . ?
C115 C116 C117 C118 -1.2(10) . . . . ?
C7 P3 C1 C2 67.7(7) . . . . ?
C7 P3 C1 C6 -116.1(7) . . . . ?
C7 P3 C13 Fe3 -71.6(5) . . . . ?
C7 P3 C13 C17 -161.5(6) . . . . ?
C7 P3 C13 C14 23.5(7) . . . . ?
C7 C8 C9 C10 3(5) . . . . ?
C7 C12 C11 C10 4(4) . . . . ?
C7 C138 C1C C1D 5(2) . . . . ?
C47 P7 C35 C40 12.5(7) . . . . ?
C47 P7 C35 C36 -168.7(6) . . . . ?
C47 P7 C41 C42 72.5(6) . . . . ?
C47 P7 C41 C46 -105.6(6) . . . . ?
C69 C74 C73 C72 1.3(10) . . . . ?
C17 C13 C14 Fe3 59.1(4) . . . . ?
C17 C13 C14 C15 0.5(7) . . . . ?
C17 C16 C15 Fe3 -59.4(5) . . . . ?
C17 C16 C15 C14 0.0(8) . . . . ?
C130 C125 C126 C127 -0.5(12) . . . . ?
C130 C129 C128 C127 1.9(14) . . . . ?
C59 C60 C61 C62 -5.0(14) . . . . ?
C41 P7 C35 C40 121.9(6) . . . . ?
C41 P7 C35 C36 -59.3(6) . . . . ?
C41 P7 C47 Fe4 65.8(5) . . . . ?
C41 P7 C47 C51 -26.3(6) . . . . ?
C41 P7 C47 C48 156.1(5) . . . . ?
C41 C42 C43 C44 -0.6(13) . . . . ?
C41 C46 C45 C44 0.0(11) . . . . ?
C75 P2 C74 C69 -112.0(5) . . . . ?
C75 P2 C74 C73 71.1(6) . . . . ?
C75 P2 C81 Fe2 60.6(5) . . . . ?
C75 P2 C81 C82 152.3(5) . . . . ?
C75 P2 C81 C85 -37.1(7) . . . . ?
C75 C58A C84A C137 0.0 . . . . ?
C75 C76 C77 C78 22(2) . . . . ?
C75 C80 C79 C78 -6(2) . . . . ?
C58A C75 C1B C1A 0.0 . . . . ?
C58A C84A C137 C1A 0.0 . . . . ?
C84A C137 C1A C1B 0.0 . . . . ?
C137 C1A C1B C75 0.0 . . . . ?
C1B C75 C58A C84A 0.0 . . . . ?
C64 C63 C68 C67 -0.1(9) . . . . ?
C103 P6 C109 C114 -173.2(6) . . . . ?
C103 P6 C109 C110 6.5(7) . . . . ?
C103 P6 C115 Fe1 -57.7(5) . . . . ?
C103 P6 C115 C119 -147.7(6) . . . . ?
C103 P6 C115 C116 35.6(7) . . . . ?
C103 C104 C105 C106 0.8(14) . . . . ?
C103 C108 C107 C106 2.5(14) . . . . ?
C29 P4 C23 C24 101.6(7) . . . . ?
C29 P4 C23 C28 -80.6(8) . . . . ?
C29 P4 C21 Fe3 -64.3(5) . . . . ?
C29 P4 C21 C22 -150.6(5) . . . . ?
C29 P4 C21 C20 29.0(7) . . . . ?
C29 C34 C33 C32 0.7(12) . . . . ?
C29 C30 C31 C32 -0.9(12) . . . . ?
C87 C88 C89 Fe2 -59.4(4) . . . . ?
C87 C88 C89 C90 0.4(7) . . . . ?
C87 C86 C90 Fe2 59.4(5) . . . . ?
C87 C86 C90 C89 0.7(8) . . . . ?
C73 C74 C69 C70 -1.1(10) . . . . ?
C131 P5 C125 C130 -83.5(6) . . . . ?
C131 P5 C125 C126 95.4(6) . . . . ?
C131 P5 C122 Fe1 -61.0(6) . . . . ?
C131 P5 C122 C121 -151.1(6) . . . . ?
C131 P5 C122 C123 28.7(8) . . . . ?
C131 C132 C133 C134 -0.6(14) . . . . ?
C131 C136 C135 C134 -0.1(16) . . . . ?
C55 C56 C52 Fe4 59.8(4) . . . . ?
C55 C56 C52 C53 0.3(7) . . . . ?
C102 C97 C98 C99 -1.4(11) . . . . ?
C102 C101 C100 C99 0.7(12) . . . . ?
C104 C103 C108 C107 2.2(12) . . . . ?
C104 C105 C106 C107 3.8(16) . . . . ?
C81 P2 C74 C69 139.5(5) . . . . ?
C81 P2 C74 C73 -37.4(6) . . . . ?
C81 P2 C75 C58A -107.4(9) . . . . ?
C81 P2 C75 C1B 72.5(9) . . . . ?
C81 P2 C75 C76 -98.0(11) . . . . ?
C81 P2 C75 C80 105.9(8) . . . . ?
C81 C82 C83 Fe2 59.2(4) . . . . ?
C81 C82 C83 C84 0.0(8) . . . . ?
C97 P1 C91 C96 -74.7(7) . . . . ?
C97 P1 C91 C92 103.7(8) . . . . ?
C97 P1 C88 Fe2 69.5(5) . . . . ?
C97 P1 C88 C87 160.5(5) . . . . ?
C97 P1 C88 C89 -24.9(6) . . . . ?
C97 C102 C101 C100 0.0(12) . . . . ?
C97 C98 C99 C100 2.0(12) . . . . ?
C1 P3 C7 C8 -151(2) . . . . ?
C1 P3 C7 C12 39.7(17) . . . . ?
C1 P3 C7 C138 19.9(10) . . . . ?
C1 P3 C7 C97A -149.6(16) . . . . ?
C1 P3 C13 Fe3 177.8(4) . . . . ?
C1 P3 C13 C17 87.9(6) . . . . ?
C1 P3 C13 C14 -87.1(7) . . . . ?
C1 C2 C3 C4 -2.7(15) . . . . ?
C1 C6 C5 C4 -0.4(13) . . . . ?
C21 P4 C23 C24 -145.6(6) . . . . ?
C21 P4 C23 C28 32.1(9) . . . . ?
C21 P4 C29 C34 111.4(6) . . . . ?
C21 P4 C29 C30 -66.4(6) . . . . ?
C21 C22 C18 Fe3 -58.5(4) . . . . ?
C21 C22 C18 C19 0.4(8) . . . . ?
C21 C20 C19 Fe3 57.7(5) . . . . ?
C21 C20 C19 C18 -2.0(8) . . . . ?
C67 C66 C65 C64 -1.7(12) . . . . ?
C108 C103 C104 C105 -3.8(11) . . . . ?
C108 C107 C106 C105 -5.5(16) . . . . ?
C132 C131 C136 C135 -1.4(13) . . . . ?
C132 C133 C134 C135 -0.9(16) . . . . ?
C119 C115 C116 Fe1 60.2(5) . . . . ?
C119 C115 C116 C117 0.9(8) . . . . ?
C119 C118 C117 Fe1 -58.0(5) . . . . ?
C119 C118 C117 C116 1.0(10) . . . . ?
C49 C50 C51 Fe4 59.9(5) . . . . ?
C49 C50 C51 C47 0.7(8) . . . . ?
C122 P5 C125 C130 27.5(7) . . . . ?
C122 P5 C125 C126 -153.6(6) . . . . ?
C122 P5 C131 C132 107.7(6) . . . . ?
C122 P5 C131 C136 -71.2(7) . . . . ?
C122 C121 C120 Fe1 -58.7(5) . . . . ?
C122 C121 C120 C124 0.6(10) . . . . ?
C122 C123 C124 Fe1 60.1(6) . . . . ?
C122 C123 C124 C120 1.4(11) . . . . ?
C22 C21 C20 Fe3 60.6(4) . . . . ?
C22 C21 C20 C19 2.2(8) . . . . ?
C22 C18 C19 Fe3 -59.1(5) . . . . ?
C22 C18 C19 C20 1.0(8) . . . . ?
C101 C102 C97 P1 178.1(6) . . . . ?
C101 C102 C97 C98 0.4(10) . . . . ?
C101 C100 C99 C98 -1.7(13) . . . . ?
C13 P3 C7 C8 100(2) . . . . ?
C13 P3 C7 C12 -68.9(17) . . . . ?
C13 P3 C7 C138 -88.8(10) . . . . ?
C13 P3 C7 C97A 101.7(16) . . . . ?
C13 P3 C1 C2 177.4(6) . . . . ?
C13 P3 C1 C6 -6.4(7) . . . . ?
C13 C17 C16 Fe3 -58.9(4) . . . . ?
C13 C17 C16 C15 0.3(8) . . . . ?
C13 C14 C15 Fe3 59.3(5) . . . . ?
C13 C14 C15 C16 -0.4(8) . . . . ?
C88 P1 C91 C96 174.3(7) . . . . ?
C88 P1 C91 C92 -7.3(8) . . . . ?
C88 P1 C97 C102 -95.2(6) . . . . ?
C88 P1 C97 C98 82.4(6) . . . . ?
C88 C87 C86 Fe2 59.3(5) . . . . ?
C88 C87 C86 C90 -0.5(8) . . . . ?
C88 C89 C90 Fe2 -59.4(4) . . . . ?
C88 C89 C90 C86 -0.7(8) . . . . ?
C34 C29 C30 C31 1.1(10) . . . . ?
C34 C33 C32 C31 -0.4(13) . . . . ?
C70 C71 C72 C73 0.8(11) . . . . ?
C42 C41 C46 C45 -1.1(10) . . . . ?
C42 C43 C44 C45 -0.6(13) . . . . ?
C24 C23 C28 C27 0.0(15) . . . . ?
C24 C25 C26 C27 -1.0(18) . . . . ?
C50 C49 C48 Fe4 -58.1(5) . . . . ?
C50 C49 C48 C47 1.1(8) . . . . ?
C72 C71 C70 C69 -0.5(11) . . . . ?
C20 C21 C22 Fe3 -61.2(4) . . . . ?
C20 C21 C22 C18 -1.6(7) . . . . ?
C51 C47 C48 Fe4 59.2(4) . . . . ?
C51 C47 C48 C49 -0.7(7) . . . . ?
C86 C87 C88 Fe2 -59.6(5) . . . . ?
C86 C87 C88 P1 175.5(5) . . . . ?
C86 C87 C88 C89 0.1(7) . . . . ?
C76 C75 C80 C79 14.7(18) . . . . ?
C76 C77 C78 C79 -12(2) . . . . ?
C62 C57 C58 C59 -1.1(11) . . . . ?
C46 C41 C42 C43 1.4(11) . . . . ?
C46 C45 C44 C43 0.9(12) . . . . ?
C16 C17 C13 Fe3 59.1(4) . . . . ?
C16 C17 C13 P3 -176.4(5) . . . . ?
C16 C17 C13 C14 -0.5(7) . . . . ?
C121 C122 C123 Fe1 59.3(5) . . . . ?
C121 C122 C123 C124 -1.0(10) . . . . ?
C121 C120 C124 Fe1 -59.7(6) . . . . ?
C121 C120 C124 C123 -1.3(12) . . . . ?
C48 C47 C51 Fe4 -59.4(4) . . . . ?
C48 C47 C51 C50 0.0(7) . . . . ?
C48 C49 C50 Fe4 58.2(5) . . . . ?
C48 C49 C50 C51 -1.2(8) . . . . ?
C83 C82 C81 Fe2 -59.2(4) . . . . ?
C83 C82 C81 P2 172.2(5) . . . . ?
C83 C82 C81 C85 -0.1(7) . . . . ?
C83 C84 C85 Fe2 59.5(5) . . . . ?
C83 C84 C85 C81 -0.1(8) . . . . ?
C2 C1 C6 C5 -1.9(12) . . . . ?
C2 C3 C4 C5 0.3(15) . . . . ?
C126 C125 C130 C129 -1.3(11) . . . . ?
C126 C127 C128 C129 -3.6(15) . . . . ?
C30 C29 C34 C33 -1.0(10) . . . . ?
C30 C31 C32 C33 0.6(13) . . . . ?
C40 C35 C36 C37 -1.1(11) . . . . ?
C40 C39 C38 C37 1.7(16) . . . . ?
C6 C1 C2 C3 3.5(12) . . . . ?
C6 C5 C4 C3 1.3(15) . . . . ?
C114 C109 C110 C111 4.4(12) . . . . ?
C77 C78 C79 C80 4(2) . . . . ?
C116 C115 C119 Fe1 -60.4(5) . . . . ?
C116 C115 C119 C118 -0.3(8) . . . . ?
C36 C35 C40 C39 0.5(12) . . . . ?
C36 C37 C38 C39 -2.3(15) . . . . ?
C28 C23 C24 C25 -0.7(14) . . . . ?
C110 C109 C114 C113 -3.0(12) . . . . ?
C8 C7 C12 C11 3(4) . . . . ?
C8 C9 C10 C11 4(4) . . . . ?
C25 C26 C27 C28 0.3(19) . . . . ?
C136 C131 C132 C133 1.7(12) . . . . ?
C136 C135 C134 C133 1.2(17) . . . . ?
C123 C122 C121 Fe1 -58.1(6) . . . . ?
C123 C122 C121 C120 0.3(9) . . . . ?
C80 C75 C76 C77 -22.5(18) . . . . ?
C38 C37 C36 C35 2.0(13) . . . . ?
C96 C91 C92 C93 2.5(16) . . . . ?
C92 C91 C96 C95 -2.4(15) . . . . ?
C111 C112 C113 C114 0.9(15) . . . . ?
C12 C7 C8 C9 -7(5) . . . . ?
C12 C11 C10 C9 -8(4) . . . . ?
C113 C112 C111 C110 0.5(14) . . . . ?
C95 C94 C93 C92 4(2) . . . . ?
C93 C94 C95 C96 -4(2) . . . . ?
C138 C7 C97A C1E 7(3) . . . . ?
C138 C1C C1D C1E -2(3) . . . . ?
C1C C1D C1E C97A 0(3) . . . . ?
C1D C1E C97A C7 -3(3) . . . . ?
C97A C7 C138 C1C -8(2) . . . . ?

_smtbx_masks_special_details     
;
A solvent mask was calculated and 1546 electrons were 
found in a volume of 4557Å³ in 1 void per unit cell. 
This is consistent with the presence of 
8.38[CH2Cl2], 2[Cl-] per Asymmetric Unit 
which account for 1544 electrons 
per unit cell.
;
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 0.000 -0.637 -0.201 4557.1 1546.0 '33.52 DCM,8 Cl-'

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cu_lwm1_0m
_database_code_depnum_ccdc_archive 'CCDC 2471149'
loop_
_audit_author_name
_audit_author_address
'Fuling Liu'
;Linyi university
China
;
_audit_update_record             
;
2025-07-09 deposited with the CCDC.	2025-11-14 downloaded from the CCDC.
;
_audit_creation_date             2024-07-17
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C136 H112 Au8 Fe4 P8, 2(Cl), 3(C H2 Cl2)'
_chemical_formula_sum            'C139 H118 Au8 Cl8 Fe4 P8'
_chemical_formula_weight         4118.82
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe -1.1336 3.1974 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   16.1119(12)
_cell_length_b                   20.0589(14)
_cell_length_c                   23.1015(16)
_cell_angle_alpha                76.658(4)
_cell_angle_beta                 73.657(4)
_cell_angle_gamma                81.061(4)
_cell_volume                     6938.3(9)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9326
_cell_measurement_temperature    228.00
_cell_measurement_theta_max      68.697
_cell_measurement_theta_min      3.066
_shelx_estimated_absorpt_T_max   0.100
_shelx_estimated_absorpt_T_min   0.100
_exptl_absorpt_coefficient_mu    21.352
_exptl_absorpt_correction_T_max  0.7531
_exptl_absorpt_correction_T_min  0.2819
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1486 before and 0.0786 after correction.
The Ratio of minimum to maximum transmission is 0.3743.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            black
_exptl_crystal_colour_primary    black
_exptl_crystal_density_diffrn    1.972
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3888
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0599
_diffrn_reflns_av_unetI/netI     0.0603
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.984
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            77049
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.984
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.797
_diffrn_reflns_theta_min         2.274
_diffrn_ambient_temperature      228.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_source_current           0.0
_diffrn_source_power             0.0
_diffrn_source_voltage           0.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                21475
_reflns_number_total             25278
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         3.255
_refine_diff_density_min         -4.024
_refine_diff_density_rms         0.301
_refine_ls_extinction_coef       0.000332(15)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1493
_refine_ls_number_reflns         25278
_refine_ls_number_restraints     60
_refine_ls_R_factor_all          0.0646
_refine_ls_R_factor_gt           0.0578
_refine_ls_restrained_S_all      1.036
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1154P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1534
_refine_ls_wR_factor_ref         0.1593
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2. Restrained distances
 Cl4-C137
 1.73 with sigma of 0.02
 Cl3-C137
 1.73 with sigma of 0.02
 Cl4-C137 \\sim Cl3-C137
 with sigma of 0.002
 Cl6-C138 \\sim Cl5-C138
 with sigma of 0.002
 Cl7-C139 \\sim Cl8-C139
 with sigma of 0.002
3. Uiso/Uaniso restraints and constraints
Uanis(C5) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
4. Rigid body (RIGU) restrains
 Cl3, Cl4, C137
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 C1, C2, C3, C4, C5, C6, P6
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
5.a Secondary CH2 refined with riding coordinates:
 C137(H13A,H13B), C138(H13C,H13D), C139(H13E,H13F)
5.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12), C13(H13), C14(H14), C15(H15), C16(H16), C18(H18), C19(H19), C20(H20),
  C22(H22), C24(H24), C25(H25), C26(H26), C27(H27), C28(H28), C30(H30),
 C31(H31), C32(H32), C33(H33), C34(H34), C36(H36), C37(H37), C38(H38), C39(H39),
  C40(H40), C42(H42), C43(H43), C44(H44), C46(H46), C47(H47), C48(H48),
 C49(H49), C50(H50), C52(H52), C53(H53), C54(H54), C55(H55), C56(H56), C58(H58),
  C59(H59), C60(H60), C61(H61), C62(H62), C64(H64), C65(H65), C66(H66),
 C67(H67), C68(H68), C69(H69), C71(H71), C72(H72), C73(H73), C74(H74), C75(H75),
  C76(H76), C77(H77), C80(H80), C81(H81), C82(H82), C83(H83), C84(H84),
 C86(H86), C87(H87), C88(H88), C89(H89), C90(H90), C92(H92), C93(H93), C94(H94),
  C95(H95), C96(H96), C98(H98), C99(H99), C100(H100), C101(H101), C102(H102),
 C104(H104), C105(H105), C106(H106), C107(H107), C108(H108), C110(H110),
 C111(H111), C112(H112), C113(H113), C114(H114), C116(H116), C117(H117),
 C118(H118), C119(H119), C120(H120), C122(H122), C123(H123), C124(H124),
 C125(H125), C127(H127), C128(H128), C129(H129), C130(H130), C132(H132),
 C133(H133), C134(H134), C135(H135), C136(H136)
5.c Fitted hexagon refined as free rotating group:
 C1(C2,C3,C4,C5,C6)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.34304(2) 0.25196(2) 0.70619(2) 0.02348(9) Uani 1 1 d . . . . .
Au2 Au 0.33232(2) 0.12013(2) 0.77537(2) 0.02807(10) Uani 1 1 d . . . . .
Au3 Au 0.47739(2) 0.18858(2) 0.75630(2) 0.02973(10) Uani 1 1 d . . . . .
Au4 Au 0.34431(2) 0.27663(2) 0.81613(2) 0.03146(10) Uani 1 1 d . . . . .
Au5 Au 0.24928(2) 0.37296(2) 0.74390(2) 0.03184(10) Uani 1 1 d . . . . .
Au6 Au 0.19927(2) 0.30416(2) 0.66468(2) 0.02988(10) Uani 1 1 d . . . . .
Au7 Au 0.19689(2) 0.23199(2) 0.78946(2) 0.02925(10) Uani 1 1 d . . . . .
Au8 Au 0.26512(2) 0.16475(2) 0.66894(2) 0.03259(10) Uani 1 1 d . . . . .
Fe1 Fe 0.24786(9) -0.05360(7) 0.72250(6) 0.0352(3) Uani 1 1 d . . . . .
Fe2 Fe 0.66146(8) 0.28545(7) 0.63227(6) 0.0324(3) Uani 1 1 d . . . . .
Fe3 Fe 0.16167(10) 0.24803(8) 0.98645(6) 0.0366(3) Uani 1 1 d . . . . .
Fe4 Fe 0.08989(9) 0.52678(7) 0.63905(6) 0.0344(3) Uani 1 1 d . . . . .
P1 P 0.08987(14) 0.20216(12) 0.87645(10) 0.0321(4) Uani 1 1 d . . . . .
P2 P 0.35241(15) 0.30696(12) 0.90413(10) 0.0332(5) Uani 1 1 d . . . . .
P3 P 0.32617(14) 0.00540(11) 0.82117(9) 0.0297(4) Uani 1 1 d . . . . .
P4 P 0.24110(14) 0.09157(11) 0.61330(10) 0.0314(4) Uani 1 1 d . . . . .
P5 P 0.45157(13) 0.27824(10) 0.61461(9) 0.0275(4) Uani 1 1 d . . . . .
P6 P 0.20232(14) 0.48725(11) 0.75209(10) 0.0305(4) Uani 1 1 d . . . . .
P7 P 0.09957(15) 0.36497(11) 0.61254(10) 0.0320(4) Uani 1 1 d . . . . .
P8 P 0.61862(13) 0.16591(11) 0.76332(10) 0.0326(5) Uani 1 1 d . . . . .
C1 C 0.2871(4) 0.5418(3) 0.7082(3) 0.043(2) Uani 1 1 d G . . . .
C2 C 0.3555(5) 0.5142(4) 0.6659(4) 0.081(4) Uani 1 1 d G . . . .
H2 H 0.357423 0.468349 0.662081 0.097 Uiso 1 1 calc R U . . .
C3 C 0.4211(5) 0.5545(6) 0.6293(4) 0.118(7) Uani 1 1 d G . . . .
H3 H 0.467435 0.535807 0.600696 0.141 Uiso 1 1 calc R U . . .
C4 C 0.4183(6) 0.6223(5) 0.6350(5) 0.107(5) Uani 1 1 d G . . . .
H4 H 0.462703 0.649552 0.610244 0.128 Uiso 1 1 calc R U . . .
C5 C 0.3499(6) 0.6499(4) 0.6773(5) 0.099(5) Uani 1 1 d G U . . .
H5 H 0.347961 0.695838 0.681176 0.119 Uiso 1 1 calc R U . . .
C6 C 0.2842(5) 0.6097(4) 0.7139(4) 0.072(4) Uani 1 1 d G . . . .
H6 H 0.237949 0.628381 0.742562 0.086 Uiso 1 1 calc R U . . .
C7 C 0.1708(6) 0.5089(5) 0.8271(4) 0.0357(19) Uani 1 1 d . . . . .
C8 C 0.2321(8) 0.5074(5) 0.8590(5) 0.048(2) Uani 1 1 d . . . . .
H8 H 0.291268 0.496662 0.840820 0.058 Uiso 1 1 calc R U . . .
C9 C 0.2064(8) 0.5220(7) 0.9184(5) 0.060(3) Uani 1 1 d . . . . .
H9 H 0.248756 0.521244 0.939525 0.072 Uiso 1 1 calc R U . . .
C10 C 0.1203(9) 0.5373(7) 0.9462(5) 0.064(3) Uani 1 1 d . . . . .
H10 H 0.104375 0.546718 0.986151 0.076 Uiso 1 1 calc R U . . .
C11 C 0.0568(8) 0.5391(6) 0.9159(5) 0.057(3) Uani 1 1 d . . . . .
H11 H -0.002154 0.549886 0.934588 0.069 Uiso 1 1 calc R U . . .
C12 C 0.0825(6) 0.5245(6) 0.8570(4) 0.045(2) Uani 1 1 d . . . . .
H12 H 0.039780 0.525087 0.836251 0.054 Uiso 1 1 calc R U . . .
C13 C 0.1992(6) 0.4799(5) 0.5874(4) 0.039(2) Uani 1 1 d . . . . .
H13 H 0.246114 0.454397 0.601616 0.047 Uiso 1 1 calc R U . . .
C14 C 0.1904(7) 0.5518(5) 0.5632(4) 0.047(2) Uani 1 1 d . . . . .
H14 H 0.231862 0.582133 0.558558 0.056 Uiso 1 1 calc R U . . .
C15 C 0.1140(7) 0.5704(5) 0.5477(4) 0.047(2) Uani 1 1 d . . . . .
H15 H 0.094418 0.615356 0.530860 0.057 Uiso 1 1 calc R U . . .
C16 C 0.0670(7) 0.5106(5) 0.5611(4) 0.043(2) Uani 1 1 d . . . . .
H16 H 0.012145 0.509713 0.554686 0.052 Uiso 1 1 calc R U . . .
C17 C 0.1192(6) 0.4535(5) 0.5856(4) 0.037(2) Uani 1 1 d . . . . .
C18 C -0.0256(7) 0.5260(6) 0.7059(5) 0.051(3) Uani 1 1 d . . . . .
H18 H -0.078192 0.513026 0.703979 0.061 Uiso 1 1 calc R U . . .
C19 C -0.0019(7) 0.5922(6) 0.6880(5) 0.050(2) Uani 1 1 d . . . . .
H19 H -0.034612 0.631452 0.671765 0.060 Uiso 1 1 calc R U . . .
C20 C 0.0814(7) 0.5900(5) 0.6986(4) 0.044(2) Uani 1 1 d . . . . .
H20 H 0.113506 0.628039 0.689914 0.053 Uiso 1 1 calc R U . . .
C21 C 0.1082(6) 0.5219(4) 0.7242(4) 0.0343(19) Uani 1 1 d . . . . .
C22 C 0.0400(6) 0.4803(5) 0.7278(4) 0.038(2) Uani 1 1 d . . . . .
H22 H 0.039668 0.432403 0.741784 0.046 Uiso 1 1 calc R U . . .
C23 C 0.4031(6) 0.3870(5) 0.8853(5) 0.041(2) Uani 1 1 d . . . . .
C24 C 0.4375(7) 0.4139(6) 0.8244(6) 0.058(3) Uani 1 1 d . . . . .
H24 H 0.432787 0.392078 0.793721 0.070 Uiso 1 1 calc R U . . .
C25 C 0.4812(9) 0.4759(7) 0.8076(8) 0.080(4) Uani 1 1 d . . . . .
H25 H 0.504675 0.495031 0.766055 0.096 Uiso 1 1 calc R U . . .
C26 C 0.4876(10) 0.5052(7) 0.8516(10) 0.090(5) Uani 1 1 d . . . . .
H26 H 0.518626 0.544170 0.840753 0.108 Uiso 1 1 calc R U . . .
C27 C 0.4496(11) 0.4802(7) 0.9142(8) 0.082(4) Uani 1 1 d . . . . .
H27 H 0.452639 0.503374 0.944441 0.098 Uiso 1 1 calc R U . . .
C28 C 0.4082(9) 0.4214(6) 0.9301(7) 0.067(3) Uani 1 1 d . . . . .
H28 H 0.382906 0.404018 0.971816 0.080 Uiso 1 1 calc R U . . .
C29 C 0.4141(6) 0.2438(5) 0.9508(4) 0.0352(19) Uani 1 1 d . . . . .
C30 C 0.4483(6) 0.1823(5) 0.9316(4) 0.041(2) Uani 1 1 d . . . . .
H30 H 0.436472 0.172661 0.896925 0.050 Uiso 1 1 calc R U . . .
C31 C 0.4996(7) 0.1355(5) 0.9636(5) 0.048(2) Uani 1 1 d . . . . .
H31 H 0.522888 0.093855 0.950671 0.057 Uiso 1 1 calc R U . . .
C32 C 0.5174(8) 0.1495(6) 1.0152(5) 0.057(3) Uani 1 1 d . . . . .
H32 H 0.552401 0.117535 1.037089 0.069 Uiso 1 1 calc R U . . .
C33 C 0.4838(9) 0.2093(7) 1.0332(6) 0.066(3) Uani 1 1 d . . . . .
H33 H 0.496671 0.219330 1.067338 0.079 Uiso 1 1 calc R U . . .
C34 C 0.4306(9) 0.2565(6) 1.0026(5) 0.061(3) Uani 1 1 d . . . . .
H34 H 0.405684 0.297068 1.016951 0.073 Uiso 1 1 calc R U . . .
C35 C 0.1260(6) 0.1818(5) 0.9460(4) 0.041(2) Uani 1 1 d . . . . .
C36 C 0.2141(6) 0.1621(5) 0.9495(5) 0.042(2) Uani 1 1 d . . . . .
H36 H 0.262519 0.158258 0.915951 0.050 Uiso 1 1 calc R U . . .
C37 C 0.2160(9) 0.1496(5) 1.0118(5) 0.054(3) Uani 1 1 d . . . . .
H37 H 0.265719 0.136499 1.026944 0.065 Uiso 1 1 calc R U . . .
C38 C 0.1274(8) 0.1607(6) 1.0482(4) 0.052(3) Uani 1 1 d . . . . .
H38 H 0.109959 0.156820 1.091165 0.062 Uiso 1 1 calc R U . . .
C39 C 0.0719(8) 0.1784(6) 1.0081(4) 0.051(3) Uani 1 1 d . . . . .
H39 H 0.011034 0.186533 1.019700 0.061 Uiso 1 1 calc R U . . .
C40 C 0.1700(6) 0.3428(4) 0.9314(4) 0.038(2) Uani 1 1 d . . . . .
H40 H 0.168358 0.352683 0.889961 0.046 Uiso 1 1 calc R U . . .
C41 C 0.2475(7) 0.3213(5) 0.9537(4) 0.040(2) Uani 1 1 d . . . . .
C42 C 0.2193(7) 0.3087(6) 1.0206(4) 0.048(2) Uani 1 1 d . . . . .
H42 H 0.255121 0.292779 1.047811 0.057 Uiso 1 1 calc R U . . .
C43 C 0.1280(7) 0.3248(6) 1.0372(5) 0.052(3) Uani 1 1 d . . . . .
H43 H 0.092700 0.321945 1.077540 0.063 Uiso 1 1 calc R U . . .
C44 C 0.0980(6) 0.3464(5) 0.9819(5) 0.042(2) Uani 1 1 d . . . . .
H44 H 0.040251 0.360489 0.980002 0.051 Uiso 1 1 calc R U . . .
C45 C -0.0011(6) 0.2655(5) 0.8928(4) 0.040(2) Uani 1 1 d . . . . .
C46 C -0.0784(7) 0.2484(7) 0.9378(5) 0.053(3) Uani 1 1 d . . . . .
H46 H -0.086131 0.202193 0.956762 0.063 Uiso 1 1 calc R U . . .
C47 C -0.1425(7) 0.2997(7) 0.9539(6) 0.063(3) Uani 1 1 d . . . . .
H47 H -0.193421 0.287974 0.984386 0.075 Uiso 1 1 calc R U . . .
C48 C -0.1336(7) 0.3688(8) 0.9260(7) 0.070(4) Uani 1 1 d . . . . .
H48 H -0.178201 0.402995 0.937704 0.084 Uiso 1 1 calc R U . . .
C49 C -0.0594(8) 0.3864(6) 0.8813(6) 0.059(3) Uani 1 1 d . . . . .
H49 H -0.053584 0.432700 0.861858 0.071 Uiso 1 1 calc R U . . .
C50 C 0.0070(6) 0.3359(6) 0.8649(5) 0.047(2) Uani 1 1 d . . . . .
H50 H 0.058068 0.348429 0.834853 0.057 Uiso 1 1 calc R U . . .
C51 C 0.0373(6) 0.1281(5) 0.8778(4) 0.037(2) Uani 1 1 d . . . . .
C52 C 0.0504(7) 0.0649(5) 0.9162(4) 0.043(2) Uani 1 1 d . . . . .
H52 H 0.086545 0.059881 0.942834 0.051 Uiso 1 1 calc R U . . .
C53 C 0.0095(8) 0.0092(6) 0.9149(5) 0.060(3) Uani 1 1 d . . . . .
H53 H 0.018691 -0.033308 0.940850 0.072 Uiso 1 1 calc R U . . .
C54 C -0.0453(7) 0.0149(6) 0.8757(5) 0.056(3) Uani 1 1 d . . . . .
H54 H -0.073375 -0.022835 0.875585 0.068 Uiso 1 1 calc R U . . .
C55 C -0.0564(6) 0.0773(6) 0.8376(5) 0.047(2) Uani 1 1 d . . . . .
H55 H -0.092929 0.082274 0.811223 0.057 Uiso 1 1 calc R U . . .
C56 C -0.0148(7) 0.1337(6) 0.8370(5) 0.048(2) Uani 1 1 d . . . . .
H56 H -0.021700 0.175293 0.809347 0.058 Uiso 1 1 calc R U . . .
C57 C 0.3048(6) -0.0119(4) 0.9049(4) 0.0342(19) Uani 1 1 d . . . . .
C58 C 0.3549(6) 0.0162(5) 0.9309(4) 0.039(2) Uani 1 1 d . . . . .
H58 H 0.399522 0.042731 0.905432 0.047 Uiso 1 1 calc R U . . .
C59 C 0.3399(7) 0.0055(6) 0.9948(4) 0.049(3) Uani 1 1 d . . . . .
H59 H 0.373401 0.025332 1.012537 0.059 Uiso 1 1 calc R U . . .
C60 C 0.2748(8) -0.0347(6) 1.0315(4) 0.056(3) Uani 1 1 d . . . . .
H60 H 0.264577 -0.042822 1.074549 0.067 Uiso 1 1 calc R U . . .
C61 C 0.2259(8) -0.0622(6) 1.0061(4) 0.056(3) Uani 1 1 d . . . . .
H61 H 0.181952 -0.089309 1.031846 0.067 Uiso 1 1 calc R U . . .
C62 C 0.2389(8) -0.0514(6) 0.9428(5) 0.050(3) Uani 1 1 d . . . . .
H62 H 0.203717 -0.070393 0.925732 0.060 Uiso 1 1 calc R U . . .
C63 C 0.4278(6) -0.0469(4) 0.7966(4) 0.0341(19) Uani 1 1 d . . . . .
C64 C 0.4383(7) -0.1178(5) 0.8254(5) 0.048(2) Uani 1 1 d . . . . .
H64 H 0.394773 -0.137342 0.858877 0.057 Uiso 1 1 calc R U . . .
C65 C 0.5135(8) -0.1566(6) 0.8027(6) 0.058(3) Uani 1 1 d . . . . .
H65 H 0.521636 -0.202986 0.821810 0.070 Uiso 1 1 calc R U . . .
C66 C 0.5777(8) -0.1296(7) 0.7528(5) 0.067(4) Uani 1 1 d . . . . .
H66 H 0.627186 -0.157877 0.736791 0.080 Uiso 1 1 calc R U . . .
C67 C 0.5682(7) -0.0592(7) 0.7261(5) 0.059(3) Uani 1 1 d . . . . .
H67 H 0.613017 -0.039056 0.694086 0.071 Uiso 1 1 calc R U . . .
C68 C 0.4910(6) -0.0199(5) 0.7480(4) 0.039(2) Uani 1 1 d . . . . .
H68 H 0.482698 0.026343 0.728557 0.047 Uiso 1 1 calc R U . . .
C69 C 0.3574(6) -0.0184(5) 0.6590(4) 0.040(2) Uani 1 1 d . . . . .
H69 H 0.394266 0.010732 0.663990 0.048 Uiso 1 1 calc R U . . .
C70 C 0.2798(6) 0.0034(5) 0.6347(4) 0.0366(19) Uani 1 1 d . . . . .
C71 C 0.2463(7) -0.0594(5) 0.6362(5) 0.045(2) Uani 1 1 d . . . . .
H71 H 0.196374 -0.062199 0.623783 0.055 Uiso 1 1 calc R U . . .
C72 C 0.2974(8) -0.1143(6) 0.6584(5) 0.055(3) Uani 1 1 d . . . . .
H72 H 0.288553 -0.160673 0.663109 0.066 Uiso 1 1 calc R U . . .
C73 C 0.3661(8) -0.0910(6) 0.6735(5) 0.052(3) Uani 1 1 d . . . . .
H73 H 0.409562 -0.118936 0.690138 0.062 Uiso 1 1 calc R U . . .
C74 C 0.2332(7) -0.1033(5) 0.8119(4) 0.046(2) Uani 1 1 d . . . . .
H74 H 0.269643 -0.140786 0.826600 0.055 Uiso 1 1 calc R U . . .
C75 C 0.1577(7) -0.1067(6) 0.7920(5) 0.056(3) Uani 1 1 d . . . . .
H75 H 0.135057 -0.147279 0.792170 0.067 Uiso 1 1 calc R U . . .
C76 C 0.1225(7) -0.0378(6) 0.7716(5) 0.051(3) Uani 1 1 d . . . . .
H76 H 0.073919 -0.025067 0.755167 0.061 Uiso 1 1 calc R U . . .
C77 C 0.1749(6) 0.0075(5) 0.7811(4) 0.038(2) Uani 1 1 d . . . . .
H77 H 0.165567 0.055765 0.772536 0.045 Uiso 1 1 calc R U . . .
C78 C 0.2427(6) -0.0308(5) 0.8051(4) 0.037(2) Uani 1 1 d . . . . .
C79 C 0.1291(6) 0.0916(5) 0.6162(4) 0.0367(19) Uani 1 1 d . . . . .
C80 C 0.1031(7) 0.0647(6) 0.5740(5) 0.055(3) Uani 1 1 d . . . . .
H80 H 0.144910 0.046533 0.542617 0.066 Uiso 1 1 calc R U . . .
C81 C 0.0134(9) 0.0650(7) 0.5788(7) 0.073(4) Uani 1 1 d . . . . .
H81 H -0.004300 0.046177 0.551036 0.087 Uiso 1 1 calc R U . . .
C82 C -0.0483(7) 0.0928(7) 0.6244(7) 0.069(4) Uani 1 1 d . . . . .
H82 H -0.107702 0.091974 0.627941 0.082 Uiso 1 1 calc R U . . .
C83 C -0.0233(7) 0.1211(8) 0.6636(6) 0.066(3) Uani 1 1 d . . . . .
H83 H -0.065589 0.141083 0.693672 0.079 Uiso 1 1 calc R U . . .
C84 C 0.0640(7) 0.1209(6) 0.6601(5) 0.051(3) Uani 1 1 d . . . . .
H84 H 0.079862 0.140925 0.687912 0.061 Uiso 1 1 calc R U . . .
C85 C 0.0909(6) 0.3363(5) 0.5446(4) 0.038(2) Uani 1 1 d . . . . .
C86 C 0.1303(7) 0.3688(6) 0.4865(5) 0.049(2) Uani 1 1 d . . . . .
H86 H 0.159580 0.407919 0.480402 0.059 Uiso 1 1 calc R U . . .
C87 C 0.1260(7) 0.3422(6) 0.4356(5) 0.055(3) Uani 1 1 d . . . . .
H87 H 0.154049 0.362817 0.395377 0.066 Uiso 1 1 calc R U . . .
C88 C 0.0812(8) 0.2869(6) 0.4454(6) 0.058(3) Uani 1 1 d . . . . .
H88 H 0.077440 0.270410 0.411340 0.069 Uiso 1 1 calc R U . . .
C89 C 0.0420(8) 0.2549(6) 0.5026(6) 0.062(3) Uani 1 1 d . . . . .
H89 H 0.011721 0.216453 0.508384 0.074 Uiso 1 1 calc R U . . .
C90 C 0.0471(7) 0.2803(5) 0.5535(5) 0.046(2) Uani 1 1 d . . . . .
H90 H 0.020199 0.258554 0.593688 0.056 Uiso 1 1 calc R U . . .
C91 C 0.2969(6) 0.1146(5) 0.5318(4) 0.037(2) Uani 1 1 d . . . . .
C92 C 0.2620(8) 0.1684(6) 0.4941(5) 0.055(3) Uani 1 1 d . . . . .
H92 H 0.207008 0.190786 0.509206 0.066 Uiso 1 1 calc R U . . .
C93 C 0.3075(8) 0.1889(7) 0.4347(5) 0.063(3) Uani 1 1 d . . . . .
H93 H 0.283077 0.225955 0.409564 0.075 Uiso 1 1 calc R U . . .
C94 C 0.3883(8) 0.1574(7) 0.4100(5) 0.060(3) Uani 1 1 d . . . . .
H94 H 0.418560 0.171919 0.368844 0.073 Uiso 1 1 calc R U . . .
C95 C 0.4222(8) 0.1042(6) 0.4483(5) 0.060(3) Uani 1 1 d . . . . .
H95 H 0.477447 0.082186 0.433071 0.073 Uiso 1 1 calc R U . . .
C96 C 0.3778(7) 0.0820(6) 0.5083(5) 0.047(2) Uani 1 1 d . . . . .
H96 H 0.402228 0.044801 0.533379 0.056 Uiso 1 1 calc R U . . .
C97 C 0.4134(5) 0.3372(5) 0.5525(4) 0.0324(19) Uani 1 1 d . . . . .
C98 C 0.4210(6) 0.4085(5) 0.5416(4) 0.038(2) Uani 1 1 d . . . . .
H98 H 0.446109 0.426181 0.566293 0.045 Uiso 1 1 calc R U . . .
C99 C 0.3911(6) 0.4519(6) 0.4944(5) 0.048(2) Uani 1 1 d . . . . .
H99 H 0.395780 0.499388 0.487357 0.057 Uiso 1 1 calc R U . . .
C100 C 0.3548(7) 0.4270(6) 0.4577(5) 0.053(3) Uani 1 1 d . . . . .
H100 H 0.335594 0.457229 0.425433 0.064 Uiso 1 1 calc R U . . .
C101 C 0.3465(7) 0.3573(6) 0.4683(5) 0.055(3) Uani 1 1 d . . . . .
H101 H 0.322068 0.339848 0.443004 0.065 Uiso 1 1 calc R U . . .
C102 C 0.3747(7) 0.3131(6) 0.5167(5) 0.049(2) Uani 1 1 d . . . . .
H102 H 0.367031 0.266001 0.524878 0.059 Uiso 1 1 calc R U . . .
C103 C 0.5059(6) 0.2069(5) 0.5766(4) 0.0338(18) Uani 1 1 d . . . . .
C104 C 0.5595(7) 0.2188(5) 0.5172(4) 0.042(2) Uani 1 1 d . . . . .
H104 H 0.563717 0.264316 0.495113 0.051 Uiso 1 1 calc R U . . .
C105 C 0.6067(7) 0.1655(6) 0.4898(5) 0.056(3) Uani 1 1 d . . . . .
H105 H 0.641588 0.174572 0.449251 0.067 Uiso 1 1 calc R U . . .
C106 C 0.6020(7) 0.0995(6) 0.5223(5) 0.056(3) Uani 1 1 d . . . . .
H106 H 0.636768 0.063625 0.504514 0.067 Uiso 1 1 calc R U . . .
C107 C 0.5472(7) 0.0839(5) 0.5812(5) 0.048(2) Uani 1 1 d . . . . .
H107 H 0.543354 0.038096 0.602585 0.058 Uiso 1 1 calc R U . . .
C108 C 0.4969(5) 0.1395(4) 0.6079(4) 0.0328(18) Uani 1 1 d . . . . .
H108 H 0.457693 0.130404 0.646926 0.039 Uiso 1 1 calc R U . . .
C109 C 0.6453(5) 0.2134(5) 0.8140(4) 0.0345(19) Uani 1 1 d . . . . .
C110 C 0.7160(7) 0.1860(6) 0.8400(6) 0.056(3) Uani 1 1 d . . . . .
H110 H 0.747173 0.143571 0.833310 0.067 Uiso 1 1 calc R U . . .
C111 C 0.7378(8) 0.2244(6) 0.8763(6) 0.059(3) Uani 1 1 d . . . . .
H111 H 0.785897 0.208989 0.892929 0.071 Uiso 1 1 calc R U . . .
C112 C 0.6876(7) 0.2858(6) 0.8876(5) 0.056(3) Uani 1 1 d . . . . .
H112 H 0.700166 0.310012 0.913873 0.067 Uiso 1 1 calc R U . . .
C113 C 0.6200(7) 0.3111(6) 0.8606(6) 0.056(3) Uani 1 1 d . . . . .
H113 H 0.587703 0.353140 0.867213 0.067 Uiso 1 1 calc R U . . .
C114 C 0.6007(6) 0.2737(6) 0.8238(5) 0.044(2) Uani 1 1 d . . . . .
H114 H 0.554859 0.291003 0.805037 0.053 Uiso 1 1 calc R U . . .
C115 C 0.6583(6) 0.0773(5) 0.7863(4) 0.038(2) Uani 1 1 d . . . . .
C116 C 0.7451(7) 0.0512(6) 0.7624(6) 0.064(3) Uani 1 1 d . . . . .
H116 H 0.783410 0.080191 0.732369 0.077 Uiso 1 1 calc R U . . .
C117 C 0.7739(9) -0.0154(6) 0.7823(7) 0.070(4) Uani 1 1 d . . . . .
H117 H 0.831490 -0.032301 0.765839 0.084 Uiso 1 1 calc R U . . .
C118 C 0.7183(10) -0.0580(6) 0.8265(6) 0.071(4) Uani 1 1 d . . . . .
H118 H 0.737718 -0.104182 0.839960 0.085 Uiso 1 1 calc R U . . .
C119 C 0.6348(9) -0.0330(6) 0.8508(6) 0.062(3) Uani 1 1 d . . . . .
H119 H 0.597205 -0.062000 0.881416 0.074 Uiso 1 1 calc R U . . .
C120 C 0.6057(7) 0.0337(5) 0.8310(5) 0.047(2) Uani 1 1 d . . . . .
H120 H 0.548311 0.050030 0.848558 0.056 Uiso 1 1 calc R U . . .
C121 C 0.6886(6) 0.1960(5) 0.6901(4) 0.037(2) Uani 1 1 d . . . . .
C122 C 0.7570(6) 0.2413(5) 0.6766(5) 0.040(2) Uani 1 1 d . . . . .
H122 H 0.774547 0.258920 0.705174 0.048 Uiso 1 1 calc R U . . .
C123 C 0.7917(6) 0.2537(5) 0.6119(5) 0.048(2) Uani 1 1 d . . . . .
H123 H 0.836651 0.281668 0.590014 0.058 Uiso 1 1 calc R U . . .
C124 C 0.7482(7) 0.2172(5) 0.5851(5) 0.050(2) Uani 1 1 d . . . . .
H124 H 0.759319 0.216802 0.542999 0.060 Uiso 1 1 calc R U . . .
C125 C 0.6854(6) 0.1819(5) 0.6331(4) 0.042(2) Uani 1 1 d . . . . .
H125 H 0.647439 0.153553 0.628371 0.051 Uiso 1 1 calc R U . . .
C126 C 0.5410(6) 0.3218(4) 0.6173(4) 0.0327(18) Uani 1 1 d . . . . .
C127 C 0.6098(6) 0.3514(4) 0.5679(4) 0.0367(19) Uani 1 1 d . . . . .
H127 H 0.621379 0.347494 0.526479 0.044 Uiso 1 1 calc R U . . .
C128 C 0.6571(6) 0.3873(5) 0.5919(5) 0.041(2) Uani 1 1 d . . . . .
H128 H 0.705599 0.411170 0.569509 0.049 Uiso 1 1 calc R U . . .
C129 C 0.6187(6) 0.3808(5) 0.6552(5) 0.041(2) Uani 1 1 d . . . . .
H129 H 0.637574 0.399576 0.682427 0.049 Uiso 1 1 calc R U . . .
C130 C 0.5469(6) 0.3415(4) 0.6714(4) 0.0328(18) Uani 1 1 d . . . . .
H130 H 0.509589 0.330373 0.710883 0.039 Uiso 1 1 calc R U . . .
C131 C -0.0129(6) 0.3655(5) 0.6594(5) 0.041(2) Uani 1 1 d . . . . .
C132 C -0.0808(6) 0.3994(5) 0.6336(6) 0.049(2) Uani 1 1 d . . . . .
H132 H -0.069833 0.418328 0.591262 0.059 Uiso 1 1 calc R U . . .
C133 C -0.1645(7) 0.4046(7) 0.6713(7) 0.066(3) Uani 1 1 d . . . . .
H133 H -0.210107 0.429355 0.655059 0.079 Uiso 1 1 calc R U . . .
C134 C -0.1805(8) 0.3736(8) 0.7323(7) 0.074(4) Uani 1 1 d . . . . .
H134 H -0.237387 0.377147 0.757465 0.088 Uiso 1 1 calc R U . . .
C135 C -0.1158(8) 0.3380(7) 0.7569(6) 0.066(3) Uani 1 1 d . . . . .
H135 H -0.128248 0.316838 0.798763 0.079 Uiso 1 1 calc R U . . .
C136 C -0.0300(7) 0.3326(6) 0.7200(5) 0.046(2) Uani 1 1 d . . . . .
H136 H 0.014879 0.306988 0.736649 0.056 Uiso 1 1 calc R U . . .
Cl1 Cl 0.4170(6) 0.3434(4) 1.1239(5) 0.212(5) Uani 1 1 d . . . . .
Cl2 Cl 0.1946(6) 0.2538(3) 0.2990(2) 0.164(3) Uani 1 1 d . . . . .
Cl3 Cl -0.0417(6) 0.2834(4) 1.1961(5) 0.207(4) Uani 1 1 d D . . . .
Cl4 Cl 0.0413(4) 0.1470(3) 1.2375(4) 0.153(3) Uani 1 1 d D . . . .
C137 C 0.0518(15) 0.2370(5) 1.2179(15) 0.193(14) Uani 1 1 d D . . . .
H13A H 0.103500 0.246281 1.183805 0.232 Uiso 1 1 calc R U . . .
H13B H 0.059260 0.252400 1.253249 0.232 Uiso 1 1 calc R U . . .
Cl5 Cl 0.9095(4) -0.0975(4) 0.5878(4) 0.171(3) Uani 1 1 d D . . . .
Cl6 Cl 0.7648(3) 0.0001(3) 0.5990(3) 0.148(3) Uani 1 1 d D . . . .
C138 C 0.8065(8) -0.0791(8) 0.6278(10) 0.122(8) Uani 1 1 d D . . . .
H13C H 0.805424 -0.081784 0.670853 0.147 Uiso 1 1 calc R U . . .
H13D H 0.770253 -0.113480 0.626537 0.147 Uiso 1 1 calc R U . . .
Cl7 Cl 0.8681(3) 0.1231(2) 0.4613(2) 0.0922(11) Uani 1 1 d D . . . .
Cl8 Cl 0.8182(6) 0.2542(4) 0.3974(5) 0.229(5) Uani 1 1 d D . . . .
C139 C 0.8993(13) 0.1893(7) 0.4016(11) 0.146(10) Uani 1 1 d D . . . .
H13E H 0.949601 0.207296 0.406408 0.175 Uiso 1 1 calc R U . . .
H13F H 0.917054 0.172212 0.363019 0.175 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Au2 2.7589(5) . ?
Au1 Au3 2.7417(5) . ?
Au1 Au4 2.7032(5) . ?
Au1 Au5 2.8334(5) . ?
Au1 Au6 2.7231(5) . ?
Au1 Au7 2.6066(5) . ?
Au1 Au8 2.7133(5) . ?
Au1 P5 2.3456(19) . ?
Au2 Au3 2.7714(5) . ?
Au2 Au7 2.8840(5) . ?
Au2 Au8 2.8636(5) . ?
Au2 P3 2.305(2) . ?
Au3 Au4 2.8122(5) . ?
Au3 P8 2.294(2) . ?
Au4 Au5 2.8093(5) . ?
Au4 Au7 2.9260(5) . ?
Au4 P2 2.295(2) . ?
Au5 Au6 2.8712(5) . ?
Au5 Au7 2.9470(5) . ?
Au5 P6 2.333(2) . ?
Au6 Au7 2.9043(5) . ?
Au6 Au8 2.8222(5) . ?
Au6 P7 2.307(2) . ?
Au7 Au8 3.2139(5) . ?
Au7 P1 2.277(2) . ?
Au8 P4 2.299(2) . ?
Fe1 C69 2.054(9) . ?
Fe1 C70 2.053(9) . ?
Fe1 C71 2.030(9) . ?
Fe1 C72 2.043(11) . ?
Fe1 C73 2.051(11) . ?
Fe1 C74 2.041(10) . ?
Fe1 C75 2.050(10) . ?
Fe1 C76 2.036(11) . ?
Fe1 C77 2.034(9) . ?
Fe1 C78 2.040(9) . ?
Fe2 C121 2.043(9) . ?
Fe2 C122 2.061(9) . ?
Fe2 C123 2.049(9) . ?
Fe2 C124 2.061(11) . ?
Fe2 C125 2.050(10) . ?
Fe2 C126 2.058(9) . ?
Fe2 C127 2.026(9) . ?
Fe2 C128 2.039(9) . ?
Fe2 C129 2.066(10) . ?
Fe2 C130 2.091(9) . ?
Fe3 C35 2.020(10) . ?
Fe3 C36 2.057(10) . ?
Fe3 C37 2.055(11) . ?
Fe3 C38 2.027(10) . ?
Fe3 C39 2.046(11) . ?
Fe3 C40 2.028(9) . ?
Fe3 C41 2.043(10) . ?
Fe3 C42 2.043(11) . ?
Fe3 C43 2.063(11) . ?
Fe3 C44 2.072(10) . ?
Fe4 C13 2.057(9) . ?
Fe4 C14 2.049(10) . ?
Fe4 C15 2.040(9) . ?
Fe4 C16 2.041(9) . ?
Fe4 C17 2.051(9) . ?
Fe4 C18 2.057(10) . ?
Fe4 C19 2.081(11) . ?
Fe4 C20 2.041(10) . ?
Fe4 C21 2.048(9) . ?
Fe4 C22 2.035(9) . ?
P1 C35 1.800(10) . ?
P1 C45 1.799(10) . ?
P1 C51 1.810(9) . ?
P2 C23 1.822(10) . ?
P2 C29 1.826(9) . ?
P2 C41 1.778(10) . ?
P3 C57 1.827(9) . ?
P3 C63 1.823(9) . ?
P3 C78 1.783(9) . ?
P4 C70 1.786(10) . ?
P4 C79 1.787(9) . ?
P4 C91 1.829(9) . ?
P5 C97 1.823(8) . ?
P5 C103 1.829(9) . ?
P5 C126 1.820(9) . ?
P6 C1 1.807(6) . ?
P6 C7 1.798(9) . ?
P6 C21 1.792(10) . ?
P7 C17 1.788(10) . ?
P7 C85 1.837(9) . ?
P7 C131 1.830(10) . ?
P8 C109 1.840(10) . ?
P8 C115 1.803(9) . ?
P8 C121 1.779(9) . ?
C1 C2 1.3900 . ?
C1 C6 1.3900 . ?
C2 H2 0.9400 . ?
C2 C3 1.3900 . ?
C3 H3 0.9400 . ?
C3 C4 1.3900 . ?
C4 H4 0.9400 . ?
C4 C5 1.3900 . ?
C5 H5 0.9400 . ?
C5 C6 1.3900 . ?
C6 H6 0.9400 . ?
C7 C8 1.382(14) . ?
C7 C12 1.417(13) . ?
C8 H8 0.9400 . ?
C8 C9 1.403(14) . ?
C9 H9 0.9400 . ?
C9 C10 1.375(17) . ?
C10 H10 0.9400 . ?
C10 C11 1.386(17) . ?
C11 H11 0.9400 . ?
C11 C12 1.392(14) . ?
C12 H12 0.9400 . ?
C13 H13 0.9400 . ?
C13 C14 1.422(14) . ?
C13 C17 1.482(14) . ?
C14 H14 0.9400 . ?
C14 C15 1.350(15) . ?
C15 H15 0.9400 . ?
C15 C16 1.445(15) . ?
C16 H16 0.9400 . ?
C16 C17 1.417(13) . ?
C18 H18 0.9400 . ?
C18 C19 1.376(16) . ?
C18 C22 1.414(14) . ?
C19 H19 0.9400 . ?
C19 C20 1.423(14) . ?
C20 H20 0.9400 . ?
C20 C21 1.411(12) . ?
C21 C22 1.453(13) . ?
C22 H22 0.9400 . ?
C23 C24 1.371(16) . ?
C23 C28 1.398(15) . ?
C24 H24 0.9400 . ?
C24 C25 1.445(18) . ?
C25 H25 0.9400 . ?
C25 C26 1.32(2) . ?
C26 H26 0.9400 . ?
C26 C27 1.41(2) . ?
C27 H27 0.9400 . ?
C27 C28 1.370(18) . ?
C28 H28 0.9400 . ?
C29 C30 1.387(13) . ?
C29 C34 1.381(13) . ?
C30 H30 0.9400 . ?
C30 C31 1.376(13) . ?
C31 H31 0.9400 . ?
C31 C32 1.398(16) . ?
C32 H32 0.9400 . ?
C32 C33 1.344(17) . ?
C33 H33 0.9400 . ?
C33 C34 1.381(15) . ?
C34 H34 0.9400 . ?
C35 C36 1.433(14) . ?
C35 C39 1.446(13) . ?
C36 H36 0.9400 . ?
C36 C37 1.410(14) . ?
C37 H37 0.9400 . ?
C37 C38 1.451(17) . ?
C38 H38 0.9400 . ?
C38 C39 1.414(16) . ?
C39 H39 0.9400 . ?
C40 H40 0.9400 . ?
C40 C41 1.449(14) . ?
C40 C44 1.400(13) . ?
C41 C42 1.457(12) . ?
C42 H42 0.9400 . ?
C42 C43 1.418(15) . ?
C43 H43 0.9400 . ?
C43 C44 1.441(15) . ?
C44 H44 0.9400 . ?
C45 C46 1.411(13) . ?
C45 C50 1.420(15) . ?
C46 H46 0.9400 . ?
C46 C47 1.375(16) . ?
C47 H47 0.9400 . ?
C47 C48 1.398(19) . ?
C48 H48 0.9400 . ?
C48 C49 1.374(19) . ?
C49 H49 0.9400 . ?
C49 C50 1.389(15) . ?
C50 H50 0.9400 . ?
C51 C52 1.393(13) . ?
C51 C56 1.406(15) . ?
C52 H52 0.9400 . ?
C52 C53 1.392(15) . ?
C53 H53 0.9400 . ?
C53 C54 1.409(18) . ?
C54 H54 0.9400 . ?
C54 C55 1.373(16) . ?
C55 H55 0.9400 . ?
C55 C56 1.396(14) . ?
C56 H56 0.9400 . ?
C57 C58 1.378(13) . ?
C57 C62 1.392(14) . ?
C58 H58 0.9400 . ?
C58 C59 1.397(12) . ?
C59 H59 0.9400 . ?
C59 C60 1.385(16) . ?
C60 H60 0.9400 . ?
C60 C61 1.347(17) . ?
C61 H61 0.9400 . ?
C61 C62 1.388(14) . ?
C62 H62 0.9400 . ?
C63 C64 1.430(12) . ?
C63 C68 1.356(13) . ?
C64 H64 0.9400 . ?
C64 C65 1.374(15) . ?
C65 H65 0.9400 . ?
C65 C66 1.381(18) . ?
C66 H66 0.9400 . ?
C66 C67 1.407(18) . ?
C67 H67 0.9400 . ?
C67 C68 1.396(14) . ?
C68 H68 0.9400 . ?
C69 H69 0.9400 . ?
C69 C70 1.479(14) . ?
C69 C73 1.410(15) . ?
C70 C71 1.435(13) . ?
C71 H71 0.9400 . ?
C71 C72 1.359(15) . ?
C72 H72 0.9400 . ?
C72 C73 1.421(17) . ?
C73 H73 0.9400 . ?
C74 H74 0.9400 . ?
C74 C75 1.433(15) . ?
C74 C78 1.453(12) . ?
C75 H75 0.9400 . ?
C75 C76 1.435(17) . ?
C76 H76 0.9400 . ?
C76 C77 1.421(14) . ?
C77 H77 0.9400 . ?
C77 C78 1.406(13) . ?
C79 C80 1.400(14) . ?
C79 C84 1.400(14) . ?
C80 H80 0.9400 . ?
C80 C81 1.417(16) . ?
C81 H81 0.9400 . ?
C81 C82 1.38(2) . ?
C82 H82 0.9400 . ?
C82 C83 1.35(2) . ?
C83 H83 0.9400 . ?
C83 C84 1.385(16) . ?
C84 H84 0.9400 . ?
C85 C86 1.369(14) . ?
C85 C90 1.365(14) . ?
C86 H86 0.9400 . ?
C86 C87 1.421(15) . ?
C87 H87 0.9400 . ?
C87 C88 1.359(17) . ?
C88 H88 0.9400 . ?
C88 C89 1.349(18) . ?
C89 H89 0.9400 . ?
C89 C90 1.413(15) . ?
C90 H90 0.9400 . ?
C91 C92 1.375(14) . ?
C91 C96 1.387(13) . ?
C92 H92 0.9400 . ?
C92 C93 1.362(15) . ?
C93 H93 0.9400 . ?
C93 C94 1.382(17) . ?
C94 H94 0.9400 . ?
C94 C95 1.370(17) . ?
C95 H95 0.9400 . ?
C95 C96 1.374(15) . ?
C96 H96 0.9400 . ?
C97 C98 1.412(13) . ?
C97 C102 1.369(14) . ?
C98 H98 0.9400 . ?
C98 C99 1.380(13) . ?
C99 H99 0.9400 . ?
C99 C100 1.369(16) . ?
C100 H100 0.9400 . ?
C100 C101 1.384(17) . ?
C101 H101 0.9400 . ?
C101 C102 1.396(14) . ?
C102 H102 0.9400 . ?
C103 C104 1.388(12) . ?
C103 C108 1.387(12) . ?
C104 H104 0.9400 . ?
C104 C105 1.383(14) . ?
C105 H105 0.9400 . ?
C105 C106 1.364(16) . ?
C106 H106 0.9400 . ?
C106 C107 1.393(15) . ?
C107 H107 0.9400 . ?
C107 C108 1.427(12) . ?
C108 H108 0.9400 . ?
C109 C110 1.415(13) . ?
C109 C114 1.340(14) . ?
C110 H110 0.9400 . ?
C110 C111 1.402(17) . ?
C111 H111 0.9400 . ?
C111 C112 1.399(17) . ?
C112 H112 0.9400 . ?
C112 C113 1.376(16) . ?
C113 H113 0.9400 . ?
C113 C114 1.379(15) . ?
C114 H114 0.9400 . ?
C115 C116 1.417(14) . ?
C115 C120 1.369(14) . ?
C116 H116 0.9400 . ?
C116 C117 1.362(15) . ?
C117 H117 0.9400 . ?
C117 C118 1.38(2) . ?
C118 H118 0.9400 . ?
C118 C119 1.368(19) . ?
C119 H119 0.9400 . ?
C119 C120 1.364(15) . ?
C120 H120 0.9400 . ?
C121 C122 1.457(13) . ?
C121 C125 1.425(13) . ?
C122 H122 0.9400 . ?
C122 C123 1.419(14) . ?
C123 H123 0.9400 . ?
C123 C124 1.421(16) . ?
C124 H124 0.9400 . ?
C124 C125 1.410(15) . ?
C125 H125 0.9400 . ?
C126 C127 1.436(12) . ?
C126 C130 1.424(12) . ?
C127 H127 0.9400 . ?
C127 C128 1.415(14) . ?
C128 H128 0.9400 . ?
C128 C129 1.400(14) . ?
C129 H129 0.9400 . ?
C129 C130 1.415(13) . ?
C130 H130 0.9400 . ?
C131 C132 1.402(14) . ?
C131 C136 1.373(14) . ?
C132 H132 0.9400 . ?
C132 C133 1.387(16) . ?
C133 H133 0.9400 . ?
C133 C134 1.37(2) . ?
C134 H134 0.9400 . ?
C134 C135 1.354(19) . ?
C135 H135 0.9400 . ?
C135 C136 1.408(16) . ?
C136 H136 0.9400 . ?
Cl3 C137 1.780(11) . ?
Cl4 C137 1.779(11) . ?
C137 H13A 0.9800 . ?
C137 H13B 0.9800 . ?
Cl5 C138 1.687(10) . ?
Cl6 C138 1.688(10) . ?
C138 H13C 0.9800 . ?
C138 H13D 0.9800 . ?
Cl7 C139 1.701(13) . ?
Cl8 C139 1.701(12) . ?
C139 H13E 0.9800 . ?
C139 H13F 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Au2 Au1 Au5 125.754(15) . . ?
Au3 Au1 Au2 60.508(12) . . ?
Au3 Au1 Au5 119.296(15) . . ?
Au4 Au1 Au2 80.402(14) . . ?
Au4 Au1 Au3 62.190(13) . . ?
Au4 Au1 Au5 60.930(12) . . ?
Au4 Au1 Au6 116.599(15) . . ?
Au4 Au1 Au8 135.199(16) . . ?
Au6 Au1 Au2 113.546(15) . . ?
Au6 Au1 Au3 173.869(16) . . ?
Au6 Au1 Au5 62.190(12) . . ?
Au7 Au1 Au2 64.956(13) . . ?
Au7 Au1 Au3 108.757(16) . . ?
Au7 Au1 Au4 66.853(13) . . ?
Au7 Au1 Au5 65.448(14) . . ?
Au7 Au1 Au6 65.999(14) . . ?
Au7 Au1 Au8 74.301(14) . . ?
Au8 Au1 Au2 63.099(13) . . ?
Au8 Au1 Au3 113.602(15) . . ?
Au8 Au1 Au5 120.805(16) . . ?
Au8 Au1 Au6 62.548(13) . . ?
P5 Au1 Au2 122.07(5) . . ?
P5 Au1 Au3 85.18(5) . . ?
P5 Au1 Au4 124.99(5) . . ?
P5 Au1 Au5 111.35(5) . . ?
P5 Au1 Au6 99.87(5) . . ?
P5 Au1 Au7 165.62(5) . . ?
P5 Au1 Au8 97.24(5) . . ?
Au1 Au2 Au3 59.437(12) . . ?
Au1 Au2 Au7 54.967(11) . . ?
Au1 Au2 Au8 57.673(12) . . ?
Au3 Au2 Au7 100.482(15) . . ?
Au3 Au2 Au8 108.190(15) . . ?
Au8 Au2 Au7 67.995(13) . . ?
P3 Au2 Au1 172.50(5) . . ?
P3 Au2 Au3 122.55(6) . . ?
P3 Au2 Au7 128.53(6) . . ?
P3 Au2 Au8 116.15(5) . . ?
Au1 Au3 Au2 60.055(12) . . ?
Au1 Au3 Au4 58.233(12) . . ?
Au2 Au3 Au4 78.313(14) . . ?
P8 Au3 Au1 156.31(6) . . ?
P8 Au3 Au2 139.92(6) . . ?
P8 Au3 Au4 128.03(6) . . ?
Au1 Au4 Au3 59.577(12) . . ?
Au1 Au4 Au5 61.824(12) . . ?
Au1 Au4 Au7 54.995(11) . . ?
Au3 Au4 Au7 98.513(16) . . ?
Au5 Au4 Au3 117.704(15) . . ?
Au5 Au4 Au7 61.797(13) . . ?
P2 Au4 Au1 174.33(6) . . ?
P2 Au4 Au3 120.59(6) . . ?
P2 Au4 Au5 115.62(6) . . ?
P2 Au4 Au7 129.14(6) . . ?
Au1 Au5 Au6 57.021(12) . . ?
Au1 Au5 Au7 53.564(12) . . ?
Au4 Au5 Au1 57.245(12) . . ?
Au4 Au5 Au6 108.721(16) . . ?
Au4 Au5 Au7 61.048(13) . . ?
Au6 Au5 Au7 59.875(12) . . ?
P6 Au5 Au1 163.83(6) . . ?
P6 Au5 Au4 127.34(6) . . ?
P6 Au5 Au6 123.59(6) . . ?
P6 Au5 Au7 142.41(5) . . ?
Au1 Au6 Au5 60.790(12) . . ?
Au1 Au6 Au7 55.072(11) . . ?
Au1 Au6 Au8 58.557(12) . . ?
Au5 Au6 Au7 61.357(13) . . ?
Au8 Au6 Au5 115.808(15) . . ?
Au8 Au6 Au7 68.263(13) . . ?
P7 Au6 Au1 166.61(6) . . ?
P7 Au6 Au5 116.70(6) . . ?
P7 Au6 Au7 136.98(6) . . ?
P7 Au6 Au8 127.17(6) . . ?
Au1 Au7 Au2 60.077(12) . . ?
Au1 Au7 Au4 58.153(12) . . ?
Au1 Au7 Au5 60.989(12) . . ?
Au1 Au7 Au6 58.930(12) . . ?
Au1 Au7 Au8 54.367(12) . . ?
Au2 Au7 Au4 74.722(13) . . ?
Au2 Au7 Au5 117.212(15) . . ?
Au2 Au7 Au6 104.792(15) . . ?
Au2 Au7 Au8 55.700(12) . . ?
Au4 Au7 Au5 57.154(12) . . ?
Au4 Au7 Au8 109.207(14) . . ?
Au5 Au7 Au8 102.969(14) . . ?
Au6 Au7 Au4 104.715(15) . . ?
Au6 Au7 Au5 58.768(12) . . ?
Au6 Au7 Au8 54.657(12) . . ?
P1 Au7 Au1 166.68(6) . . ?
P1 Au7 Au2 110.31(6) . . ?
P1 Au7 Au4 111.85(6) . . ?
P1 Au7 Au5 122.99(6) . . ?
P1 Au7 Au6 134.40(6) . . ?
P1 Au7 Au8 129.89(6) . . ?
Au1 Au8 Au2 59.228(12) . . ?
Au1 Au8 Au6 58.896(12) . . ?
Au1 Au8 Au7 51.332(11) . . ?
Au2 Au8 Au7 56.304(12) . . ?
Au6 Au8 Au2 107.516(15) . . ?
Au6 Au8 Au7 57.080(12) . . ?
P4 Au8 Au1 161.35(6) . . ?
P4 Au8 Au2 124.05(6) . . ?
P4 Au8 Au6 126.90(6) . . ?
P4 Au8 Au7 147.23(6) . . ?
C70 Fe1 C69 42.2(4) . . ?
C71 Fe1 C69 69.0(4) . . ?
C71 Fe1 C70 41.1(4) . . ?
C71 Fe1 C72 39.0(4) . . ?
C71 Fe1 C73 67.7(4) . . ?
C71 Fe1 C74 146.8(4) . . ?
C71 Fe1 C75 114.9(4) . . ?
C71 Fe1 C76 107.8(4) . . ?
C71 Fe1 C77 131.6(4) . . ?
C71 Fe1 C78 170.4(4) . . ?
C72 Fe1 C69 67.9(4) . . ?
C72 Fe1 C70 67.9(4) . . ?
C72 Fe1 C73 40.6(5) . . ?
C72 Fe1 C75 106.9(5) . . ?
C73 Fe1 C69 40.2(4) . . ?
C73 Fe1 C70 69.1(4) . . ?
C74 Fe1 C69 129.2(4) . . ?
C74 Fe1 C70 170.3(4) . . ?
C74 Fe1 C72 115.4(4) . . ?
C74 Fe1 C73 107.0(4) . . ?
C74 Fe1 C75 41.0(4) . . ?
C75 Fe1 C69 167.1(5) . . ?
C75 Fe1 C70 148.3(4) . . ?
C75 Fe1 C73 128.3(5) . . ?
C76 Fe1 C69 151.3(4) . . ?
C76 Fe1 C70 116.2(4) . . ?
C76 Fe1 C72 128.4(5) . . ?
C76 Fe1 C73 167.0(5) . . ?
C76 Fe1 C74 69.6(5) . . ?
C76 Fe1 C75 41.1(5) . . ?
C76 Fe1 C78 69.1(4) . . ?
C77 Fe1 C69 119.0(4) . . ?
C77 Fe1 C70 109.8(4) . . ?
C77 Fe1 C72 167.9(4) . . ?
C77 Fe1 C73 150.9(4) . . ?
C77 Fe1 C74 69.0(4) . . ?
C77 Fe1 C75 68.5(4) . . ?
C77 Fe1 C76 40.9(4) . . ?
C77 Fe1 C78 40.4(4) . . ?
C78 Fe1 C69 109.0(4) . . ?
C78 Fe1 C70 131.2(3) . . ?
C78 Fe1 C72 149.9(4) . . ?
C78 Fe1 C73 117.3(4) . . ?
C78 Fe1 C74 41.7(4) . . ?
C78 Fe1 C75 69.1(4) . . ?
C121 Fe2 C122 41.6(4) . . ?
C121 Fe2 C123 68.5(4) . . ?
C121 Fe2 C124 68.4(4) . . ?
C121 Fe2 C125 40.7(4) . . ?
C121 Fe2 C126 125.3(3) . . ?
C121 Fe2 C129 126.8(4) . . ?
C121 Fe2 C130 112.5(4) . . ?
C122 Fe2 C124 68.5(4) . . ?
C122 Fe2 C129 107.6(4) . . ?
C122 Fe2 C130 124.6(4) . . ?
C123 Fe2 C122 40.4(4) . . ?
C123 Fe2 C124 40.4(5) . . ?
C123 Fe2 C125 67.7(4) . . ?
C123 Fe2 C126 158.3(4) . . ?
C123 Fe2 C129 119.8(4) . . ?
C123 Fe2 C130 157.0(4) . . ?
C124 Fe2 C129 153.9(4) . . ?
C124 Fe2 C130 162.6(4) . . ?
C125 Fe2 C122 68.8(4) . . ?
C125 Fe2 C124 40.1(4) . . ?
C125 Fe2 C126 110.5(4) . . ?
C125 Fe2 C129 164.7(4) . . ?
C125 Fe2 C130 129.2(4) . . ?
C126 Fe2 C122 161.0(4) . . ?
C126 Fe2 C124 124.1(4) . . ?
C126 Fe2 C129 67.7(4) . . ?
C126 Fe2 C130 40.1(3) . . ?
C127 Fe2 C121 159.4(4) . . ?
C127 Fe2 C122 156.0(4) . . ?
C127 Fe2 C123 119.9(4) . . ?
C127 Fe2 C124 105.0(4) . . ?
C127 Fe2 C125 121.9(4) . . ?
C127 Fe2 C126 41.2(3) . . ?
C127 Fe2 C128 40.8(4) . . ?
C127 Fe2 C129 67.6(4) . . ?
C127 Fe2 C130 67.7(3) . . ?
C128 Fe2 C121 159.7(4) . . ?
C128 Fe2 C122 120.4(4) . . ?
C128 Fe2 C123 103.3(4) . . ?
C128 Fe2 C124 118.2(4) . . ?
C128 Fe2 C125 155.0(4) . . ?
C128 Fe2 C126 68.8(3) . . ?
C128 Fe2 C129 39.9(4) . . ?
C128 Fe2 C130 67.4(4) . . ?
C129 Fe2 C130 39.8(4) . . ?
C35 Fe3 C36 41.1(4) . . ?
C35 Fe3 C37 69.0(4) . . ?
C35 Fe3 C38 69.5(4) . . ?
C35 Fe3 C39 41.7(4) . . ?
C35 Fe3 C40 110.9(4) . . ?
C35 Fe3 C41 132.4(3) . . ?
C35 Fe3 C42 170.0(4) . . ?
C35 Fe3 C43 149.6(4) . . ?
C35 Fe3 C44 118.6(4) . . ?
C36 Fe3 C43 166.5(4) . . ?
C36 Fe3 C44 152.1(4) . . ?
C37 Fe3 C36 40.1(4) . . ?
C37 Fe3 C43 127.5(4) . . ?
C37 Fe3 C44 167.2(4) . . ?
C38 Fe3 C36 68.9(4) . . ?
C38 Fe3 C37 41.6(5) . . ?
C38 Fe3 C39 40.6(4) . . ?
C38 Fe3 C40 168.2(4) . . ?
C38 Fe3 C41 146.6(4) . . ?
C38 Fe3 C42 111.9(4) . . ?
C38 Fe3 C43 104.9(5) . . ?
C38 Fe3 C44 128.8(4) . . ?
C39 Fe3 C36 69.1(4) . . ?
C39 Fe3 C37 69.0(5) . . ?
C39 Fe3 C43 114.6(4) . . ?
C39 Fe3 C44 109.1(4) . . ?
C40 Fe3 C36 119.7(4) . . ?
C40 Fe3 C37 150.1(4) . . ?
C40 Fe3 C39 132.0(4) . . ?
C40 Fe3 C41 41.7(4) . . ?
C40 Fe3 C42 69.9(4) . . ?
C40 Fe3 C43 68.4(4) . . ?
C40 Fe3 C44 39.9(4) . . ?
C41 Fe3 C36 109.4(4) . . ?
C41 Fe3 C37 115.0(5) . . ?
C41 Fe3 C39 172.3(4) . . ?
C41 Fe3 C43 68.7(4) . . ?
C41 Fe3 C44 68.5(4) . . ?
C42 Fe3 C36 129.3(4) . . ?
C42 Fe3 C37 105.1(5) . . ?
C42 Fe3 C39 145.0(4) . . ?
C42 Fe3 C41 41.8(3) . . ?
C42 Fe3 C43 40.4(4) . . ?
C42 Fe3 C44 68.8(4) . . ?
C43 Fe3 C44 40.8(4) . . ?
C13 Fe4 C19 166.6(4) . . ?
C14 Fe4 C13 40.5(4) . . ?
C14 Fe4 C17 68.8(4) . . ?
C14 Fe4 C18 165.1(5) . . ?
C14 Fe4 C19 128.6(4) . . ?
C15 Fe4 C13 67.5(4) . . ?
C15 Fe4 C14 38.6(4) . . ?
C15 Fe4 C16 41.5(4) . . ?
C15 Fe4 C17 68.5(4) . . ?
C15 Fe4 C18 129.3(4) . . ?
C15 Fe4 C19 108.5(4) . . ?
C15 Fe4 C20 117.1(4) . . ?
C15 Fe4 C21 149.6(4) . . ?
C16 Fe4 C13 69.3(4) . . ?
C16 Fe4 C14 67.9(4) . . ?
C16 Fe4 C17 40.5(4) . . ?
C16 Fe4 C18 108.4(4) . . ?
C16 Fe4 C19 116.8(4) . . ?
C16 Fe4 C21 168.0(4) . . ?
C17 Fe4 C13 42.3(4) . . ?
C17 Fe4 C18 118.5(4) . . ?
C17 Fe4 C19 149.7(4) . . ?
C18 Fe4 C13 153.3(4) . . ?
C18 Fe4 C19 38.9(4) . . ?
C20 Fe4 C13 128.8(4) . . ?
C20 Fe4 C14 108.8(4) . . ?
C20 Fe4 C16 150.0(4) . . ?
C20 Fe4 C17 168.6(4) . . ?
C20 Fe4 C18 66.7(5) . . ?
C20 Fe4 C19 40.4(4) . . ?
C20 Fe4 C21 40.4(3) . . ?
C21 Fe4 C13 108.4(4) . . ?
C21 Fe4 C14 118.5(4) . . ?
C21 Fe4 C17 130.0(3) . . ?
C21 Fe4 C18 68.0(4) . . ?
C21 Fe4 C19 68.1(4) . . ?
C22 Fe4 C13 118.9(4) . . ?
C22 Fe4 C14 153.0(4) . . ?
C22 Fe4 C15 167.3(4) . . ?
C22 Fe4 C16 128.2(4) . . ?
C22 Fe4 C17 108.2(4) . . ?
C22 Fe4 C18 40.4(4) . . ?
C22 Fe4 C19 67.8(4) . . ?
C22 Fe4 C20 68.5(4) . . ?
C22 Fe4 C21 41.7(4) . . ?
C35 P1 Au7 114.0(3) . . ?
C35 P1 C45 102.9(4) . . ?
C35 P1 C51 105.0(4) . . ?
C45 P1 Au7 116.8(3) . . ?
C45 P1 C51 102.2(4) . . ?
C51 P1 Au7 114.4(3) . . ?
C23 P2 Au4 110.3(3) . . ?
C23 P2 C29 106.6(4) . . ?
C29 P2 Au4 115.2(3) . . ?
C41 P2 Au4 111.5(3) . . ?
C41 P2 C23 106.8(4) . . ?
C41 P2 C29 105.9(4) . . ?
C57 P3 Au2 114.4(3) . . ?
C63 P3 Au2 112.8(3) . . ?
C63 P3 C57 104.0(4) . . ?
C78 P3 Au2 111.9(3) . . ?
C78 P3 C57 105.7(4) . . ?
C78 P3 C63 107.3(4) . . ?
C70 P4 Au8 115.4(3) . . ?
C70 P4 C79 105.7(4) . . ?
C70 P4 C91 103.7(4) . . ?
C79 P4 Au8 113.6(3) . . ?
C79 P4 C91 105.9(4) . . ?
C91 P4 Au8 111.5(3) . . ?
C97 P5 Au1 114.4(2) . . ?
C97 P5 C103 101.1(4) . . ?
C103 P5 Au1 117.1(3) . . ?
C126 P5 Au1 117.3(3) . . ?
C126 P5 C97 100.9(4) . . ?
C126 P5 C103 103.6(4) . . ?
C1 P6 Au5 110.0(2) . . ?
C7 P6 Au5 118.7(3) . . ?
C7 P6 C1 104.6(4) . . ?
C21 P6 Au5 114.6(3) . . ?
C21 P6 C1 106.3(4) . . ?
C21 P6 C7 101.4(4) . . ?
C17 P7 Au6 111.8(3) . . ?
C17 P7 C85 104.6(4) . . ?
C17 P7 C131 105.5(4) . . ?
C85 P7 Au6 118.2(3) . . ?
C131 P7 Au6 113.7(3) . . ?
C131 P7 C85 101.7(4) . . ?
C109 P8 Au3 114.1(3) . . ?
C115 P8 Au3 117.7(3) . . ?
C115 P8 C109 105.9(4) . . ?
C121 P8 Au3 108.9(3) . . ?
C121 P8 C109 103.3(4) . . ?
C121 P8 C115 105.7(4) . . ?
C2 C1 P6 117.3(4) . . ?
C2 C1 C6 120.0 . . ?
C6 C1 P6 122.7(4) . . ?
C1 C2 H2 120.0 . . ?
C1 C2 C3 120.0 . . ?
C3 C2 H2 120.0 . . ?
C2 C3 H3 120.0 . . ?
C4 C3 C2 120.0 . . ?
C4 C3 H3 120.0 . . ?
C3 C4 H4 120.0 . . ?
C3 C4 C5 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 120.0 . . ?
C4 C5 C6 120.0 . . ?
C6 C5 H5 120.0 . . ?
C1 C6 H6 120.0 . . ?
C5 C6 C1 120.0 . . ?
C5 C6 H6 120.0 . . ?
C8 C7 P6 120.8(8) . . ?
C8 C7 C12 117.5(9) . . ?
C12 C7 P6 121.6(7) . . ?
C7 C8 H8 119.9 . . ?
C7 C8 C9 120.3(10) . . ?
C9 C8 H8 119.9 . . ?
C8 C9 H9 119.5 . . ?
C10 C9 C8 121.0(11) . . ?
C10 C9 H9 119.5 . . ?
C9 C10 H10 119.7 . . ?
C9 C10 C11 120.5(10) . . ?
C11 C10 H10 119.7 . . ?
C10 C11 H11 120.9 . . ?
C10 C11 C12 118.3(10) . . ?
C12 C11 H11 120.9 . . ?
C7 C12 H12 118.8 . . ?
C11 C12 C7 122.4(10) . . ?
C11 C12 H12 118.8 . . ?
Fe4 C13 H13 126.4 . . ?
C14 C13 Fe4 69.4(5) . . ?
C14 C13 H13 127.1 . . ?
C14 C13 C17 105.9(8) . . ?
C17 C13 Fe4 68.6(5) . . ?
C17 C13 H13 127.1 . . ?
Fe4 C14 H14 126.4 . . ?
C13 C14 Fe4 70.0(5) . . ?
C13 C14 H14 124.8 . . ?
C15 C14 Fe4 70.4(6) . . ?
C15 C14 C13 110.4(10) . . ?
C15 C14 H14 124.8 . . ?
Fe4 C15 H15 126.0 . . ?
C14 C15 Fe4 71.1(6) . . ?
C14 C15 H15 125.2 . . ?
C14 C15 C16 109.6(9) . . ?
C16 C15 Fe4 69.3(5) . . ?
C16 C15 H15 125.2 . . ?
Fe4 C16 H16 125.9 . . ?
C15 C16 Fe4 69.2(5) . . ?
C15 C16 H16 126.4 . . ?
C17 C16 Fe4 70.1(5) . . ?
C17 C16 C15 107.1(9) . . ?
C17 C16 H16 126.4 . . ?
P7 C17 Fe4 125.3(5) . . ?
C13 C17 Fe4 69.1(5) . . ?
C13 C17 P7 122.5(7) . . ?
C16 C17 Fe4 69.4(5) . . ?
C16 C17 P7 130.5(8) . . ?
C16 C17 C13 107.0(8) . . ?
Fe4 C18 H18 126.5 . . ?
C19 C18 Fe4 71.5(7) . . ?
C19 C18 H18 124.7 . . ?
C19 C18 C22 110.7(10) . . ?
C22 C18 Fe4 68.9(5) . . ?
C22 C18 H18 124.7 . . ?
Fe4 C19 H19 127.1 . . ?
C18 C19 Fe4 69.6(6) . . ?
C18 C19 H19 126.5 . . ?
C18 C19 C20 107.1(9) . . ?
C20 C19 Fe4 68.3(6) . . ?
C20 C19 H19 126.5 . . ?
Fe4 C20 H20 124.9 . . ?
C19 C20 Fe4 71.3(6) . . ?
C19 C20 H20 125.3 . . ?
C21 C20 Fe4 70.1(5) . . ?
C21 C20 C19 109.4(9) . . ?
C21 C20 H20 125.3 . . ?
P6 C21 Fe4 128.6(5) . . ?
C20 C21 Fe4 69.5(5) . . ?
C20 C21 P6 130.7(7) . . ?
C20 C21 C22 106.4(8) . . ?
C22 C21 Fe4 68.7(5) . . ?
C22 C21 P6 122.8(7) . . ?
Fe4 C22 H22 124.6 . . ?
C18 C22 Fe4 70.6(6) . . ?
C18 C22 C21 106.4(9) . . ?
C18 C22 H22 126.8 . . ?
C21 C22 Fe4 69.6(5) . . ?
C21 C22 H22 126.8 . . ?
C24 C23 P2 118.0(8) . . ?
C24 C23 C28 119.3(11) . . ?
C28 C23 P2 122.7(9) . . ?
C23 C24 H24 120.2 . . ?
C23 C24 C25 119.7(13) . . ?
C25 C24 H24 120.2 . . ?
C24 C25 H25 120.5 . . ?
C26 C25 C24 119.0(15) . . ?
C26 C25 H25 120.5 . . ?
C25 C26 H26 118.9 . . ?
C25 C26 C27 122.3(14) . . ?
C27 C26 H26 118.9 . . ?
C26 C27 H27 120.6 . . ?
C28 C27 C26 118.7(14) . . ?
C28 C27 H27 120.6 . . ?
C23 C28 H28 119.6 . . ?
C27 C28 C23 120.9(14) . . ?
C27 C28 H28 119.6 . . ?
C30 C29 P2 118.3(7) . . ?
C34 C29 P2 122.3(8) . . ?
C34 C29 C30 119.4(9) . . ?
C29 C30 H30 120.2 . . ?
C31 C30 C29 119.6(9) . . ?
C31 C30 H30 120.2 . . ?
C30 C31 H31 119.8 . . ?
C30 C31 C32 120.5(10) . . ?
C32 C31 H31 119.8 . . ?
C31 C32 H32 120.4 . . ?
C33 C32 C31 119.2(10) . . ?
C33 C32 H32 120.4 . . ?
C32 C33 H33 119.3 . . ?
C32 C33 C34 121.4(11) . . ?
C34 C33 H33 119.3 . . ?
C29 C34 C33 119.9(11) . . ?
C29 C34 H34 120.0 . . ?
C33 C34 H34 120.0 . . ?
P1 C35 Fe3 127.1(5) . . ?
C36 C35 Fe3 70.8(6) . . ?
C36 C35 P1 125.4(7) . . ?
C36 C35 C39 107.8(9) . . ?
C39 C35 Fe3 70.1(6) . . ?
C39 C35 P1 126.7(8) . . ?
Fe3 C36 H36 127.9 . . ?
C35 C36 Fe3 68.1(6) . . ?
C35 C36 H36 125.8 . . ?
C37 C36 Fe3 69.9(6) . . ?
C37 C36 C35 108.5(9) . . ?
C37 C36 H36 125.8 . . ?
Fe3 C37 H37 127.2 . . ?
C36 C37 Fe3 70.0(6) . . ?
C36 C37 H37 126.1 . . ?
C36 C37 C38 107.7(10) . . ?
C38 C37 Fe3 68.2(6) . . ?
C38 C37 H37 126.1 . . ?
Fe3 C38 H38 125.2 . . ?
C37 C38 Fe3 70.2(6) . . ?
C37 C38 H38 125.8 . . ?
C39 C38 Fe3 70.4(6) . . ?
C39 C38 C37 108.4(9) . . ?
C39 C38 H38 125.8 . . ?
Fe3 C39 H39 128.1 . . ?
C35 C39 Fe3 68.2(6) . . ?
C35 C39 H39 126.3 . . ?
C38 C39 Fe3 69.0(6) . . ?
C38 C39 C35 107.5(10) . . ?
C38 C39 H39 126.3 . . ?
Fe3 C40 H40 124.6 . . ?
C41 C40 Fe3 69.7(5) . . ?
C41 C40 H40 125.6 . . ?
C44 C40 Fe3 71.7(6) . . ?
C44 C40 H40 125.6 . . ?
C44 C40 C41 108.9(8) . . ?
P2 C41 Fe3 122.7(5) . . ?
C40 C41 Fe3 68.6(5) . . ?
C40 C41 P2 122.9(7) . . ?
C40 C41 C42 106.8(9) . . ?
C42 C41 Fe3 69.1(6) . . ?
C42 C41 P2 130.0(8) . . ?
Fe3 C42 H42 125.6 . . ?
C41 C42 Fe3 69.1(6) . . ?
C41 C42 H42 126.3 . . ?
C43 C42 Fe3 70.6(6) . . ?
C43 C42 C41 107.4(9) . . ?
C43 C42 H42 126.3 . . ?
Fe3 C43 H43 127.0 . . ?
C42 C43 Fe3 69.0(6) . . ?
C42 C43 H43 125.6 . . ?
C42 C43 C44 108.8(9) . . ?
C44 C43 Fe3 69.9(6) . . ?
C44 C43 H43 125.6 . . ?
Fe3 C44 H44 128.0 . . ?
C40 C44 Fe3 68.4(5) . . ?
C40 C44 C43 108.1(8) . . ?
C40 C44 H44 126.0 . . ?
C43 C44 Fe3 69.3(6) . . ?
C43 C44 H44 126.0 . . ?
C46 C45 P1 121.6(9) . . ?
C46 C45 C50 118.1(9) . . ?
C50 C45 P1 119.9(7) . . ?
C45 C46 H46 120.2 . . ?
C47 C46 C45 119.6(11) . . ?
C47 C46 H46 120.2 . . ?
C46 C47 H47 119.2 . . ?
C46 C47 C48 121.6(11) . . ?
C48 C47 H47 119.2 . . ?
C47 C48 H48 120.2 . . ?
C49 C48 C47 119.6(11) . . ?
C49 C48 H48 120.2 . . ?
C48 C49 H49 120.0 . . ?
C48 C49 C50 120.0(12) . . ?
C50 C49 H49 120.0 . . ?
C45 C50 H50 119.6 . . ?
C49 C50 C45 120.9(10) . . ?
C49 C50 H50 119.6 . . ?
C52 C51 P1 121.9(8) . . ?
C52 C51 C56 119.0(9) . . ?
C56 C51 P1 119.1(7) . . ?
C51 C52 H52 120.2 . . ?
C53 C52 C51 119.6(10) . . ?
C53 C52 H52 120.2 . . ?
C52 C53 H53 119.1 . . ?
C52 C53 C54 121.7(11) . . ?
C54 C53 H53 119.1 . . ?
C53 C54 H54 121.1 . . ?
C55 C54 C53 117.7(10) . . ?
C55 C54 H54 121.1 . . ?
C54 C55 H55 119.1 . . ?
C54 C55 C56 121.7(10) . . ?
C56 C55 H55 119.1 . . ?
C51 C56 H56 120.0 . . ?
C55 C56 C51 120.0(10) . . ?
C55 C56 H56 120.0 . . ?
C58 C57 P3 118.4(7) . . ?
C58 C57 C62 119.6(8) . . ?
C62 C57 P3 121.9(7) . . ?
C57 C58 H58 119.7 . . ?
C57 C58 C59 120.6(9) . . ?
C59 C58 H58 119.7 . . ?
C58 C59 H59 120.6 . . ?
C60 C59 C58 118.8(10) . . ?
C60 C59 H59 120.6 . . ?
C59 C60 H60 119.7 . . ?
C61 C60 C59 120.6(9) . . ?
C61 C60 H60 119.7 . . ?
C60 C61 H61 119.3 . . ?
C60 C61 C62 121.5(10) . . ?
C62 C61 H61 119.3 . . ?
C57 C62 H62 120.5 . . ?
C61 C62 C57 118.9(10) . . ?
C61 C62 H62 120.5 . . ?
C64 C63 P3 120.0(7) . . ?
C68 C63 P3 119.9(7) . . ?
C68 C63 C64 119.9(8) . . ?
C63 C64 H64 120.9 . . ?
C65 C64 C63 118.2(10) . . ?
C65 C64 H64 120.9 . . ?
C64 C65 H65 118.9 . . ?
C64 C65 C66 122.2(10) . . ?
C66 C65 H65 118.9 . . ?
C65 C66 H66 120.4 . . ?
C65 C66 C67 119.2(10) . . ?
C67 C66 H66 120.4 . . ?
C66 C67 H67 120.6 . . ?
C68 C67 C66 118.8(11) . . ?
C68 C67 H67 120.6 . . ?
C63 C68 C67 121.6(9) . . ?
C63 C68 H68 119.2 . . ?
C67 C68 H68 119.2 . . ?
Fe1 C69 H69 126.6 . . ?
C70 C69 Fe1 68.9(5) . . ?
C70 C69 H69 126.3 . . ?
C73 C69 Fe1 69.8(6) . . ?
C73 C69 H69 126.3 . . ?
C73 C69 C70 107.4(9) . . ?
P4 C70 Fe1 124.2(5) . . ?
C69 C70 Fe1 68.9(5) . . ?
C69 C70 P4 123.0(7) . . ?
C71 C70 Fe1 68.6(5) . . ?
C71 C70 P4 131.8(8) . . ?
C71 C70 C69 105.1(8) . . ?
Fe1 C71 H71 125.3 . . ?
C70 C71 Fe1 70.3(5) . . ?
C70 C71 H71 125.1 . . ?
C72 C71 Fe1 71.0(6) . . ?
C72 C71 C70 109.9(9) . . ?
C72 C71 H71 125.1 . . ?
Fe1 C72 H72 126.5 . . ?
C71 C72 Fe1 70.0(6) . . ?
C71 C72 H72 125.1 . . ?
C71 C72 C73 109.8(10) . . ?
C73 C72 Fe1 70.0(6) . . ?
C73 C72 H72 125.1 . . ?
Fe1 C73 H73 126.1 . . ?
C69 C73 Fe1 70.0(6) . . ?
C69 C73 C72 107.9(9) . . ?
C69 C73 H73 126.1 . . ?
C72 C73 Fe1 69.4(6) . . ?
C72 C73 H73 126.1 . . ?
Fe1 C74 H74 126.1 . . ?
C75 C74 Fe1 69.9(6) . . ?
C75 C74 H74 126.5 . . ?
C75 C74 C78 107.1(10) . . ?
C78 C74 Fe1 69.1(5) . . ?
C78 C74 H74 126.5 . . ?
Fe1 C75 H75 127.7 . . ?
C74 C75 Fe1 69.1(5) . . ?
C74 C75 H75 125.8 . . ?
C74 C75 C76 108.4(9) . . ?
C76 C75 Fe1 68.9(6) . . ?
C76 C75 H75 125.8 . . ?
Fe1 C76 H76 125.7 . . ?
C75 C76 Fe1 70.0(6) . . ?
C75 C76 H76 126.4 . . ?
C77 C76 Fe1 69.5(6) . . ?
C77 C76 C75 107.1(10) . . ?
C77 C76 H76 126.4 . . ?
Fe1 C77 H77 126.8 . . ?
C76 C77 Fe1 69.6(6) . . ?
C76 C77 H77 125.1 . . ?
C78 C77 Fe1 70.1(5) . . ?
C78 C77 C76 109.8(9) . . ?
C78 C77 H77 125.1 . . ?
P3 C78 Fe1 125.0(5) . . ?
C74 C78 Fe1 69.1(5) . . ?
C74 C78 P3 127.6(8) . . ?
C77 C78 Fe1 69.6(5) . . ?
C77 C78 P3 124.9(7) . . ?
C77 C78 C74 107.5(8) . . ?
C80 C79 P4 121.9(8) . . ?
C80 C79 C84 117.5(9) . . ?
C84 C79 P4 120.5(8) . . ?
C79 C80 H80 120.1 . . ?
C79 C80 C81 119.7(11) . . ?
C81 C80 H80 120.1 . . ?
C80 C81 H81 119.9 . . ?
C82 C81 C80 120.2(12) . . ?
C82 C81 H81 119.9 . . ?
C81 C82 H82 119.9 . . ?
C83 C82 C81 120.2(11) . . ?
C83 C82 H82 119.9 . . ?
C82 C83 H83 119.7 . . ?
C82 C83 C84 120.6(12) . . ?
C84 C83 H83 119.7 . . ?
C79 C84 H84 119.2 . . ?
C83 C84 C79 121.7(11) . . ?
C83 C84 H84 119.2 . . ?
C86 C85 P7 120.8(8) . . ?
C90 C85 P7 118.3(7) . . ?
C90 C85 C86 120.8(9) . . ?
C85 C86 H86 120.7 . . ?
C85 C86 C87 118.6(11) . . ?
C87 C86 H86 120.7 . . ?
C86 C87 H87 120.1 . . ?
C88 C87 C86 119.7(11) . . ?
C88 C87 H87 120.1 . . ?
C87 C88 H88 119.1 . . ?
C89 C88 C87 121.8(11) . . ?
C89 C88 H88 119.1 . . ?
C88 C89 H89 120.5 . . ?
C88 C89 C90 118.9(12) . . ?
C90 C89 H89 120.5 . . ?
C85 C90 C89 120.1(11) . . ?
C85 C90 H90 119.9 . . ?
C89 C90 H90 119.9 . . ?
C92 C91 P4 120.0(8) . . ?
C92 C91 C96 119.2(9) . . ?
C96 C91 P4 120.6(7) . . ?
C91 C92 H92 120.2 . . ?
C93 C92 C91 119.6(11) . . ?
C93 C92 H92 120.2 . . ?
C92 C93 H93 118.7 . . ?
C92 C93 C94 122.6(11) . . ?
C94 C93 H93 118.7 . . ?
C93 C94 H94 121.5 . . ?
C95 C94 C93 117.0(10) . . ?
C95 C94 H94 121.5 . . ?
C94 C95 H95 119.1 . . ?
C94 C95 C96 121.9(10) . . ?
C96 C95 H95 119.1 . . ?
C91 C96 H96 120.1 . . ?
C95 C96 C91 119.7(10) . . ?
C95 C96 H96 120.1 . . ?
C98 C97 P5 120.7(7) . . ?
C102 C97 P5 120.3(7) . . ?
C102 C97 C98 119.0(8) . . ?
C97 C98 H98 120.3 . . ?
C99 C98 C97 119.4(10) . . ?
C99 C98 H98 120.3 . . ?
C98 C99 H99 119.4 . . ?
C100 C99 C98 121.2(10) . . ?
C100 C99 H99 119.4 . . ?
C99 C100 H100 120.0 . . ?
C99 C100 C101 119.9(9) . . ?
C101 C100 H100 120.0 . . ?
C100 C101 H101 120.3 . . ?
C100 C101 C102 119.4(11) . . ?
C102 C101 H101 120.3 . . ?
C97 C102 C101 121.1(10) . . ?
C97 C102 H102 119.5 . . ?
C101 C102 H102 119.5 . . ?
C104 C103 P5 121.1(7) . . ?
C108 C103 P5 120.0(6) . . ?
C108 C103 C104 118.9(8) . . ?
C103 C104 H104 119.1 . . ?
C105 C104 C103 121.7(9) . . ?
C105 C104 H104 119.1 . . ?
C104 C105 H105 120.4 . . ?
C106 C105 C104 119.2(9) . . ?
C106 C105 H105 120.4 . . ?
C105 C106 H106 119.1 . . ?
C105 C106 C107 121.9(10) . . ?
C107 C106 H106 119.1 . . ?
C106 C107 H107 121.0 . . ?
C106 C107 C108 118.0(9) . . ?
C108 C107 H107 121.0 . . ?
C103 C108 C107 120.1(8) . . ?
C103 C108 H108 119.9 . . ?
C107 C108 H108 119.9 . . ?
C110 C109 P8 118.3(8) . . ?
C114 C109 P8 120.5(7) . . ?
C114 C109 C110 121.2(10) . . ?
C109 C110 H110 121.3 . . ?
C111 C110 C109 117.4(11) . . ?
C111 C110 H110 121.3 . . ?
C110 C111 H111 120.1 . . ?
C112 C111 C110 119.8(10) . . ?
C112 C111 H111 120.1 . . ?
C111 C112 H112 119.6 . . ?
C113 C112 C111 120.8(10) . . ?
C113 C112 H112 119.6 . . ?
C112 C113 H113 120.6 . . ?
C112 C113 C114 118.8(10) . . ?
C114 C113 H113 120.6 . . ?
C109 C114 C113 121.9(9) . . ?
C109 C114 H114 119.1 . . ?
C113 C114 H114 119.1 . . ?
C116 C115 P8 122.4(8) . . ?
C120 C115 P8 120.1(7) . . ?
C120 C115 C116 117.4(10) . . ?
C115 C116 H116 119.6 . . ?
C117 C116 C115 120.8(12) . . ?
C117 C116 H116 119.6 . . ?
C116 C117 H117 120.1 . . ?
C116 C117 C118 119.8(12) . . ?
C118 C117 H117 120.1 . . ?
C117 C118 H118 120.1 . . ?
C119 C118 C117 119.9(11) . . ?
C119 C118 H118 120.1 . . ?
C118 C119 H119 119.7 . . ?
C120 C119 C118 120.5(12) . . ?
C120 C119 H119 119.7 . . ?
C115 C120 H120 119.3 . . ?
C119 C120 C115 121.5(11) . . ?
C119 C120 H120 119.3 . . ?
P8 C121 Fe2 123.8(5) . . ?
C122 C121 Fe2 69.8(5) . . ?
C122 C121 P8 127.0(7) . . ?
C125 C121 Fe2 69.9(5) . . ?
C125 C121 P8 125.6(7) . . ?
C125 C121 C122 107.4(8) . . ?
Fe2 C122 H122 126.8 . . ?
C121 C122 Fe2 68.6(5) . . ?
C121 C122 H122 126.8 . . ?
C123 C122 Fe2 69.4(5) . . ?
C123 C122 C121 106.4(9) . . ?
C123 C122 H122 126.8 . . ?
Fe2 C123 H123 125.9 . . ?
C122 C123 Fe2 70.2(5) . . ?
C122 C123 H123 125.2 . . ?
C122 C123 C124 109.6(9) . . ?
C124 C123 Fe2 70.2(6) . . ?
C124 C123 H123 125.2 . . ?
Fe2 C124 H124 126.6 . . ?
C123 C124 Fe2 69.3(6) . . ?
C123 C124 H124 126.2 . . ?
C125 C124 Fe2 69.5(6) . . ?
C125 C124 C123 107.6(10) . . ?
C125 C124 H124 126.2 . . ?
Fe2 C125 H125 126.3 . . ?
C121 C125 Fe2 69.4(6) . . ?
C121 C125 H125 125.5 . . ?
C124 C125 Fe2 70.4(6) . . ?
C124 C125 C121 109.0(9) . . ?
C124 C125 H125 125.5 . . ?
P5 C126 Fe2 132.1(5) . . ?
C127 C126 Fe2 68.2(5) . . ?
C127 C126 P5 129.4(7) . . ?
C130 C126 Fe2 71.2(5) . . ?
C130 C126 P5 123.4(7) . . ?
C130 C126 C127 106.7(8) . . ?
Fe2 C127 H127 125.0 . . ?
C126 C127 Fe2 70.6(5) . . ?
C126 C127 H127 125.8 . . ?
C128 C127 Fe2 70.1(5) . . ?
C128 C127 C126 108.4(8) . . ?
C128 C127 H127 125.8 . . ?
Fe2 C128 H128 125.3 . . ?
C127 C128 Fe2 69.1(5) . . ?
C127 C128 H128 126.1 . . ?
C129 C128 Fe2 71.1(5) . . ?
C129 C128 C127 107.8(8) . . ?
C129 C128 H128 126.1 . . ?
Fe2 C129 H129 126.0 . . ?
C128 C129 Fe2 69.0(6) . . ?
C128 C129 H129 125.5 . . ?
C128 C129 C130 109.0(9) . . ?
C130 C129 Fe2 71.1(5) . . ?
C130 C129 H129 125.5 . . ?
Fe2 C130 H130 127.8 . . ?
C126 C130 Fe2 68.7(5) . . ?
C126 C130 H130 126.0 . . ?
C129 C130 Fe2 69.1(5) . . ?
C129 C130 C126 108.1(8) . . ?
C129 C130 H130 126.0 . . ?
C132 C131 P7 120.2(8) . . ?
C136 C131 P7 119.4(7) . . ?
C136 C131 C132 120.4(10) . . ?
C131 C132 H132 120.4 . . ?
C133 C132 C131 119.1(11) . . ?
C133 C132 H132 120.4 . . ?
C132 C133 H133 120.1 . . ?
C134 C133 C132 119.9(12) . . ?
C134 C133 H133 120.1 . . ?
C133 C134 H134 119.4 . . ?
C135 C134 C133 121.3(12) . . ?
C135 C134 H134 119.4 . . ?
C134 C135 H135 119.9 . . ?
C134 C135 C136 120.2(12) . . ?
C136 C135 H135 119.9 . . ?
C131 C136 C135 118.9(10) . . ?
C131 C136 H136 120.5 . . ?
C135 C136 H136 120.5 . . ?
Cl3 C137 H13A 109.5 . . ?
Cl3 C137 H13B 109.5 . . ?
Cl4 C137 Cl3 110.6(12) . . ?
Cl4 C137 H13A 109.5 . . ?
Cl4 C137 H13B 109.5 . . ?
H13A C137 H13B 108.1 . . ?
Cl5 C138 Cl6 111.8(10) . . ?
Cl5 C138 H13C 109.3 . . ?
Cl5 C138 H13D 109.3 . . ?
Cl6 C138 H13C 109.3 . . ?
Cl6 C138 H13D 109.3 . . ?
H13C C138 H13D 107.9 . . ?
Cl7 C139 H13E 109.2 . . ?
Cl7 C139 H13F 109.2 . . ?
Cl8 C139 Cl7 112.1(12) . . ?
Cl8 C139 H13E 109.2 . . ?
Cl8 C139 H13F 109.2 . . ?
H13E C139 H13F 107.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P5 C97 C98 96.0(6) . . . . ?
Au1 P5 C97 C102 -82.1(8) . . . . ?
Au1 P5 C103 C104 168.5(7) . . . . ?
Au1 P5 C103 C108 -14.2(9) . . . . ?
Au1 P5 C126 Fe2 93.0(6) . . . . ?
Au1 P5 C126 C127 -171.6(7) . . . . ?
Au1 P5 C126 C130 -1.3(8) . . . . ?
Au2 P3 C57 C58 -50.4(8) . . . . ?
Au2 P3 C57 C62 128.5(8) . . . . ?
Au2 P3 C63 C64 173.4(7) . . . . ?
Au2 P3 C63 C68 -11.6(9) . . . . ?
Au2 P3 C78 Fe1 73.3(6) . . . . ?
Au2 P3 C78 C74 162.8(7) . . . . ?
Au2 P3 C78 C77 -14.8(9) . . . . ?
Au3 P8 C109 C110 156.4(7) . . . . ?
Au3 P8 C109 C114 -26.1(8) . . . . ?
Au3 P8 C115 C116 144.8(9) . . . . ?
Au3 P8 C115 C120 -39.3(9) . . . . ?
Au3 P8 C121 Fe2 38.8(6) . . . . ?
Au3 P8 C121 C122 127.9(7) . . . . ?
Au3 P8 C121 C125 -49.5(9) . . . . ?
Au4 P2 C23 C24 -7.1(9) . . . . ?
Au4 P2 C23 C28 173.1(8) . . . . ?
Au4 P2 C29 C30 -2.3(9) . . . . ?
Au4 P2 C29 C34 175.0(9) . . . . ?
Au4 P2 C41 Fe3 57.5(6) . . . . ?
Au4 P2 C41 C40 -26.7(9) . . . . ?
Au4 P2 C41 C42 146.7(8) . . . . ?
Au5 P6 C1 C2 15.0(6) . . . . ?
Au5 P6 C1 C6 -167.3(5) . . . . ?
Au5 P6 C7 C8 70.1(9) . . . . ?
Au5 P6 C7 C12 -106.7(8) . . . . ?
Au5 P6 C21 Fe4 -55.6(6) . . . . ?
Au5 P6 C21 C20 -151.2(8) . . . . ?
Au5 P6 C21 C22 32.1(8) . . . . ?
Au6 P7 C17 Fe4 -76.0(6) . . . . ?
Au6 P7 C17 C13 10.1(8) . . . . ?
Au6 P7 C17 C16 -168.2(8) . . . . ?
Au6 P7 C85 C86 -100.1(8) . . . . ?
Au6 P7 C85 C90 77.5(8) . . . . ?
Au6 P7 C131 C132 -178.9(7) . . . . ?
Au6 P7 C131 C136 1.4(9) . . . . ?
Au7 P1 C35 Fe3 71.1(6) . . . . ?
Au7 P1 C35 C36 -20.7(10) . . . . ?
Au7 P1 C35 C39 163.0(8) . . . . ?
Au7 P1 C45 C46 167.1(7) . . . . ?
Au7 P1 C45 C50 -19.7(9) . . . . ?
Au7 P1 C51 C52 108.7(7) . . . . ?
Au7 P1 C51 C56 -68.3(8) . . . . ?
Au8 P4 C70 Fe1 54.1(6) . . . . ?
Au8 P4 C70 C69 -31.5(8) . . . . ?
Au8 P4 C70 C71 145.0(8) . . . . ?
Au8 P4 C79 C80 163.6(8) . . . . ?
Au8 P4 C79 C84 -14.3(9) . . . . ?
Au8 P4 C91 C92 -78.9(9) . . . . ?
Au8 P4 C91 C96 95.9(8) . . . . ?
Fe1 C69 C70 P4 117.9(6) . . . . ?
Fe1 C69 C70 C71 -59.4(6) . . . . ?
Fe1 C69 C73 C72 59.3(7) . . . . ?
Fe1 C70 C71 C72 -60.2(8) . . . . ?
Fe1 C71 C72 C73 -58.8(8) . . . . ?
Fe1 C72 C73 C69 -59.7(7) . . . . ?
Fe1 C74 C75 C76 -57.8(7) . . . . ?
Fe1 C74 C78 P3 -118.7(8) . . . . ?
Fe1 C74 C78 C77 59.2(6) . . . . ?
Fe1 C75 C76 C77 -59.8(7) . . . . ?
Fe1 C76 C77 C78 -58.7(7) . . . . ?
Fe1 C77 C78 P3 119.1(7) . . . . ?
Fe1 C77 C78 C74 -58.9(6) . . . . ?
Fe2 C121 C122 C123 -59.3(6) . . . . ?
Fe2 C121 C125 C124 59.4(7) . . . . ?
Fe2 C122 C123 C124 -59.4(7) . . . . ?
Fe2 C123 C124 C125 -59.2(7) . . . . ?
Fe2 C124 C125 C121 -58.8(7) . . . . ?
Fe2 C126 C127 C128 -60.2(6) . . . . ?
Fe2 C126 C130 C129 58.0(6) . . . . ?
Fe2 C127 C128 C129 -60.8(7) . . . . ?
Fe2 C128 C129 C130 -60.0(6) . . . . ?
Fe2 C129 C130 C126 -57.7(6) . . . . ?
Fe3 C35 C36 C37 58.3(7) . . . . ?
Fe3 C35 C39 C38 -57.9(7) . . . . ?
Fe3 C36 C37 C38 57.9(7) . . . . ?
Fe3 C37 C38 C39 60.3(7) . . . . ?
Fe3 C38 C39 C35 57.4(7) . . . . ?
Fe3 C40 C41 P2 116.0(7) . . . . ?
Fe3 C40 C41 C42 -58.8(7) . . . . ?
Fe3 C40 C44 C43 58.0(7) . . . . ?
Fe3 C41 C42 C43 -60.5(7) . . . . ?
Fe3 C42 C43 C44 -58.8(8) . . . . ?
Fe3 C43 C44 C40 -57.4(7) . . . . ?
Fe4 C13 C14 C15 -58.9(7) . . . . ?
Fe4 C13 C17 P7 -119.4(7) . . . . ?
Fe4 C13 C17 C16 59.3(6) . . . . ?
Fe4 C14 C15 C16 -58.8(7) . . . . ?
Fe4 C15 C16 C17 -60.1(6) . . . . ?
Fe4 C16 C17 P7 119.4(8) . . . . ?
Fe4 C16 C17 C13 -59.1(6) . . . . ?
Fe4 C18 C19 C20 -58.2(7) . . . . ?
Fe4 C18 C22 C21 60.8(6) . . . . ?
Fe4 C19 C20 C21 -60.0(7) . . . . ?
Fe4 C20 C21 P6 123.9(8) . . . . ?
Fe4 C20 C21 C22 -59.0(6) . . . . ?
Fe4 C21 C22 C18 -61.4(6) . . . . ?
P1 C35 C36 Fe3 122.4(8) . . . . ?
P1 C35 C36 C37 -179.3(7) . . . . ?
P1 C35 C39 Fe3 -122.0(8) . . . . ?
P1 C35 C39 C38 -180.0(8) . . . . ?
P1 C45 C46 C47 172.5(9) . . . . ?
P1 C45 C50 C49 -173.7(8) . . . . ?
P1 C51 C52 C53 -179.0(8) . . . . ?
P1 C51 C56 C55 -179.6(7) . . . . ?
P2 C23 C24 C25 -177.7(9) . . . . ?
P2 C23 C28 C27 177.6(11) . . . . ?
P2 C29 C30 C31 176.0(8) . . . . ?
P2 C29 C34 C33 -174.5(10) . . . . ?
P2 C41 C42 Fe3 -115.8(9) . . . . ?
P2 C41 C42 C43 -176.3(8) . . . . ?
P3 C57 C58 C59 178.7(8) . . . . ?
P3 C57 C62 C61 -179.6(9) . . . . ?
P3 C63 C64 C65 175.6(8) . . . . ?
P3 C63 C68 C67 -177.1(8) . . . . ?
P4 C70 C71 Fe1 -117.3(8) . . . . ?
P4 C70 C71 C72 -177.5(8) . . . . ?
P4 C79 C80 C81 179.0(9) . . . . ?
P4 C79 C84 C83 -179.5(9) . . . . ?
P4 C91 C92 C93 174.4(10) . . . . ?
P4 C91 C96 C95 -174.1(9) . . . . ?
P5 C97 C98 C99 -179.7(7) . . . . ?
P5 C97 C102 C101 -178.9(8) . . . . ?
P5 C103 C104 C105 174.5(9) . . . . ?
P5 C103 C108 C107 -172.6(7) . . . . ?
P5 C126 C127 Fe2 -127.3(7) . . . . ?
P5 C126 C127 C128 172.5(7) . . . . ?
P5 C126 C130 Fe2 128.6(7) . . . . ?
P5 C126 C130 C129 -173.4(6) . . . . ?
P6 C1 C2 C3 177.8(6) . . . . ?
P6 C1 C6 C5 -177.7(7) . . . . ?
P6 C7 C8 C9 -177.7(9) . . . . ?
P6 C7 C12 C11 177.8(9) . . . . ?
P6 C21 C22 Fe4 -123.0(6) . . . . ?
P6 C21 C22 C18 175.5(6) . . . . ?
P7 C85 C86 C87 176.3(7) . . . . ?
P7 C85 C90 C89 -177.4(8) . . . . ?
P7 C131 C132 C133 -174.0(9) . . . . ?
P7 C131 C136 C135 175.0(8) . . . . ?
P8 C109 C110 C111 177.2(9) . . . . ?
P8 C109 C114 C113 -178.8(9) . . . . ?
P8 C115 C116 C117 177.7(11) . . . . ?
P8 C115 C120 C119 -177.8(8) . . . . ?
P8 C121 C122 Fe2 -117.7(8) . . . . ?
P8 C121 C122 C123 -177.0(7) . . . . ?
P8 C121 C125 Fe2 117.8(7) . . . . ?
P8 C121 C125 C124 177.2(7) . . . . ?
C1 P6 C7 C8 -53.0(9) . . . . ?
C1 P6 C7 C12 130.2(8) . . . . ?
C1 P6 C21 Fe4 66.1(6) . . . . ?
C1 P6 C21 C20 -29.4(10) . . . . ?
C1 P6 C21 C22 153.9(7) . . . . ?
C1 C2 C3 C4 0.0 . . . . ?
C2 C1 C6 C5 0.0 . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C3 C4 C5 C6 0.0 . . . . ?
C4 C5 C6 C1 0.0 . . . . ?
C6 C1 C2 C3 0.0 . . . . ?
C7 P6 C1 C2 143.5(6) . . . . ?
C7 P6 C1 C6 -38.7(7) . . . . ?
C7 P6 C21 Fe4 175.2(6) . . . . ?
C7 P6 C21 C20 79.7(9) . . . . ?
C7 P6 C21 C22 -97.0(8) . . . . ?
C7 C8 C9 C10 0.5(19) . . . . ?
C8 C7 C12 C11 0.9(16) . . . . ?
C8 C9 C10 C11 0(2) . . . . ?
C9 C10 C11 C12 0(2) . . . . ?
C10 C11 C12 C7 -0.7(18) . . . . ?
C12 C7 C8 C9 -0.8(15) . . . . ?
C13 C14 C15 Fe4 58.7(7) . . . . ?
C13 C14 C15 C16 -0.1(11) . . . . ?
C14 C13 C17 Fe4 -59.8(6) . . . . ?
C14 C13 C17 P7 -179.1(7) . . . . ?
C14 C13 C17 C16 -0.5(10) . . . . ?
C14 C15 C16 Fe4 59.8(7) . . . . ?
C14 C15 C16 C17 -0.3(11) . . . . ?
C15 C16 C17 Fe4 59.5(6) . . . . ?
C15 C16 C17 P7 179.0(7) . . . . ?
C15 C16 C17 C13 0.5(10) . . . . ?
C17 P7 C85 C86 25.0(9) . . . . ?
C17 P7 C85 C90 -157.4(8) . . . . ?
C17 P7 C131 C132 58.3(9) . . . . ?
C17 P7 C131 C136 -121.4(8) . . . . ?
C17 C13 C14 Fe4 59.2(6) . . . . ?
C17 C13 C14 C15 0.3(11) . . . . ?
C18 C19 C20 Fe4 59.1(8) . . . . ?
C18 C19 C20 C21 -0.9(12) . . . . ?
C19 C18 C22 Fe4 -59.4(8) . . . . ?
C19 C18 C22 C21 1.4(11) . . . . ?
C19 C20 C21 Fe4 60.7(7) . . . . ?
C19 C20 C21 P6 -175.4(7) . . . . ?
C19 C20 C21 C22 1.7(11) . . . . ?
C20 C21 C22 Fe4 59.6(6) . . . . ?
C20 C21 C22 C18 -1.9(10) . . . . ?
C21 P6 C1 C2 -109.6(6) . . . . ?
C21 P6 C1 C6 68.1(6) . . . . ?
C21 P6 C7 C8 -163.4(8) . . . . ?
C21 P6 C7 C12 19.8(9) . . . . ?
C22 C18 C19 Fe4 57.9(7) . . . . ?
C22 C18 C19 C20 -0.3(12) . . . . ?
C23 P2 C29 C30 -125.0(8) . . . . ?
C23 P2 C29 C34 52.3(11) . . . . ?
C23 P2 C41 Fe3 178.1(5) . . . . ?
C23 P2 C41 C40 93.8(8) . . . . ?
C23 P2 C41 C42 -92.7(10) . . . . ?
C23 C24 C25 C26 1(2) . . . . ?
C24 C23 C28 C27 -2.2(18) . . . . ?
C24 C25 C26 C27 -3(2) . . . . ?
C25 C26 C27 C28 3(3) . . . . ?
C26 C27 C28 C23 0(2) . . . . ?
C28 C23 C24 C25 2.1(17) . . . . ?
C29 P2 C23 C24 118.6(8) . . . . ?
C29 P2 C23 C28 -61.2(10) . . . . ?
C29 P2 C41 Fe3 -68.5(6) . . . . ?
C29 P2 C41 C40 -152.8(8) . . . . ?
C29 P2 C41 C42 20.7(10) . . . . ?
C29 C30 C31 C32 0.1(16) . . . . ?
C30 C29 C34 C33 2.7(19) . . . . ?
C30 C31 C32 C33 -0.1(18) . . . . ?
C31 C32 C33 C34 1(2) . . . . ?
C32 C33 C34 C29 -3(2) . . . . ?
C34 C29 C30 C31 -1.4(16) . . . . ?
C35 P1 C45 C46 -67.3(9) . . . . ?
C35 P1 C45 C50 106.0(8) . . . . ?
C35 P1 C51 C52 -17.0(9) . . . . ?
C35 P1 C51 C56 166.0(7) . . . . ?
C35 C36 C37 Fe3 -57.2(7) . . . . ?
C35 C36 C37 C38 0.7(12) . . . . ?
C36 C35 C39 Fe3 61.1(7) . . . . ?
C36 C35 C39 C38 3.2(12) . . . . ?
C36 C37 C38 Fe3 -59.0(7) . . . . ?
C36 C37 C38 C39 1.3(12) . . . . ?
C37 C38 C39 Fe3 -60.2(7) . . . . ?
C37 C38 C39 C35 -2.7(12) . . . . ?
C39 C35 C36 Fe3 -60.7(7) . . . . ?
C39 C35 C36 C37 -2.4(12) . . . . ?
C40 C41 C42 Fe3 58.5(6) . . . . ?
C40 C41 C42 C43 -2.0(11) . . . . ?
C41 P2 C23 C24 -128.5(8) . . . . ?
C41 P2 C23 C28 51.7(10) . . . . ?
C41 P2 C29 C30 121.5(8) . . . . ?
C41 P2 C29 C34 -61.2(11) . . . . ?
C41 C40 C44 Fe3 -60.1(6) . . . . ?
C41 C40 C44 C43 -2.1(11) . . . . ?
C41 C42 C43 Fe3 59.6(7) . . . . ?
C41 C42 C43 C44 0.8(12) . . . . ?
C42 C43 C44 Fe3 58.2(8) . . . . ?
C42 C43 C44 C40 0.8(12) . . . . ?
C44 C40 C41 Fe3 61.3(7) . . . . ?
C44 C40 C41 P2 177.3(7) . . . . ?
C44 C40 C41 C42 2.6(11) . . . . ?
C45 P1 C35 Fe3 -56.4(7) . . . . ?
C45 P1 C35 C36 -148.2(9) . . . . ?
C45 P1 C35 C39 35.5(10) . . . . ?
C45 P1 C51 C52 -124.2(8) . . . . ?
C45 P1 C51 C56 58.9(8) . . . . ?
C45 C46 C47 C48 1.0(18) . . . . ?
C46 C45 C50 C49 -0.2(15) . . . . ?
C46 C47 C48 C49 0(2) . . . . ?
C47 C48 C49 C50 -1.2(19) . . . . ?
C48 C49 C50 C45 1.3(18) . . . . ?
C50 C45 C46 C47 -0.9(15) . . . . ?
C51 P1 C35 Fe3 -162.9(6) . . . . ?
C51 P1 C35 C36 105.3(9) . . . . ?
C51 P1 C35 C39 -71.1(10) . . . . ?
C51 P1 C45 C46 41.5(9) . . . . ?
C51 P1 C45 C50 -145.2(8) . . . . ?
C51 C52 C53 C54 -0.1(16) . . . . ?
C52 C51 C56 C55 3.4(14) . . . . ?
C52 C53 C54 C55 1.0(17) . . . . ?
C53 C54 C55 C56 0.3(16) . . . . ?
C54 C55 C56 C51 -2.5(15) . . . . ?
C56 C51 C52 C53 -2.1(14) . . . . ?
C57 P3 C63 C64 48.9(9) . . . . ?
C57 P3 C63 C68 -136.2(8) . . . . ?
C57 P3 C78 Fe1 -161.5(5) . . . . ?
C57 P3 C78 C74 -72.1(9) . . . . ?
C57 P3 C78 C77 110.3(8) . . . . ?
C57 C58 C59 C60 1.1(15) . . . . ?
C58 C57 C62 C61 -0.8(16) . . . . ?
C58 C59 C60 C61 -1.0(17) . . . . ?
C59 C60 C61 C62 0.0(19) . . . . ?
C60 C61 C62 C57 0.9(18) . . . . ?
C62 C57 C58 C59 -0.2(15) . . . . ?
C63 P3 C57 C58 73.2(8) . . . . ?
C63 P3 C57 C62 -108.0(9) . . . . ?
C63 P3 C78 Fe1 -51.0(7) . . . . ?
C63 P3 C78 C74 38.5(9) . . . . ?
C63 P3 C78 C77 -139.1(8) . . . . ?
C63 C64 C65 C66 -1.4(18) . . . . ?
C64 C63 C68 C67 -2.1(15) . . . . ?
C64 C65 C66 C67 3.5(19) . . . . ?
C65 C66 C67 C68 -4.8(18) . . . . ?
C66 C67 C68 C63 4.2(16) . . . . ?
C68 C63 C64 C65 0.6(15) . . . . ?
C69 C70 C71 Fe1 59.6(6) . . . . ?
C69 C70 C71 C72 -0.6(11) . . . . ?
C70 P4 C79 C80 -68.8(10) . . . . ?
C70 P4 C79 C84 113.3(8) . . . . ?
C70 P4 C91 C92 156.3(9) . . . . ?
C70 P4 C91 C96 -28.9(9) . . . . ?
C70 C69 C73 Fe1 -58.8(6) . . . . ?
C70 C69 C73 C72 0.5(11) . . . . ?
C70 C71 C72 Fe1 59.7(7) . . . . ?
C70 C71 C72 C73 0.9(13) . . . . ?
C71 C72 C73 Fe1 58.8(8) . . . . ?
C71 C72 C73 C69 -0.9(12) . . . . ?
C73 C69 C70 Fe1 59.4(6) . . . . ?
C73 C69 C70 P4 177.3(7) . . . . ?
C73 C69 C70 C71 0.0(10) . . . . ?
C74 C75 C76 Fe1 58.0(7) . . . . ?
C74 C75 C76 C77 -1.9(12) . . . . ?
C75 C74 C78 Fe1 -59.8(7) . . . . ?
C75 C74 C78 P3 -178.6(7) . . . . ?
C75 C74 C78 C77 -0.7(11) . . . . ?
C75 C76 C77 Fe1 60.1(7) . . . . ?
C75 C76 C77 C78 1.5(11) . . . . ?
C76 C77 C78 Fe1 58.4(7) . . . . ?
C76 C77 C78 P3 177.5(7) . . . . ?
C76 C77 C78 C74 -0.5(11) . . . . ?
C78 P3 C57 C58 -173.9(7) . . . . ?
C78 P3 C57 C62 4.9(9) . . . . ?
C78 P3 C63 C64 -62.8(9) . . . . ?
C78 P3 C63 C68 112.1(8) . . . . ?
C78 C74 C75 Fe1 59.4(7) . . . . ?
C78 C74 C75 C76 1.5(12) . . . . ?
C79 P4 C70 Fe1 -72.4(6) . . . . ?
C79 P4 C70 C69 -158.0(7) . . . . ?
C79 P4 C70 C71 18.5(10) . . . . ?
C79 P4 C91 C92 45.2(10) . . . . ?
C79 P4 C91 C96 -139.9(8) . . . . ?
C79 C80 C81 C82 1.2(19) . . . . ?
C80 C79 C84 C83 2.5(16) . . . . ?
C80 C81 C82 C83 1(2) . . . . ?
C81 C82 C83 C84 -2(2) . . . . ?
C82 C83 C84 C79 -0.1(19) . . . . ?
C84 C79 C80 C81 -3.0(17) . . . . ?
C85 P7 C17 Fe4 154.9(5) . . . . ?
C85 P7 C17 C13 -118.9(8) . . . . ?
C85 P7 C17 C16 62.7(10) . . . . ?
C85 P7 C131 C132 -50.6(9) . . . . ?
C85 P7 C131 C136 129.6(8) . . . . ?
C85 C86 C87 C88 1.9(15) . . . . ?
C86 C85 C90 C89 0.1(15) . . . . ?
C86 C87 C88 C89 -1.7(17) . . . . ?
C87 C88 C89 C90 0.6(17) . . . . ?
C88 C89 C90 C85 0.2(16) . . . . ?
C90 C85 C86 C87 -1.2(14) . . . . ?
C91 P4 C70 Fe1 176.4(5) . . . . ?
C91 P4 C70 C69 90.8(8) . . . . ?
C91 P4 C70 C71 -92.7(10) . . . . ?
C91 P4 C79 C80 40.8(10) . . . . ?
C91 P4 C79 C84 -137.1(8) . . . . ?
C91 C92 C93 C94 0(2) . . . . ?
C92 C91 C96 C95 0.7(16) . . . . ?
C92 C93 C94 C95 -1(2) . . . . ?
C93 C94 C95 C96 1.0(19) . . . . ?
C94 C95 C96 C91 -1.0(19) . . . . ?
C96 C91 C92 C93 -0.5(17) . . . . ?
C97 P5 C103 C104 43.5(9) . . . . ?
C97 P5 C103 C108 -139.2(7) . . . . ?
C97 P5 C126 Fe2 -142.1(6) . . . . ?
C97 P5 C126 C127 -46.7(9) . . . . ?
C97 P5 C126 C130 123.6(7) . . . . ?
C97 C98 C99 C100 -0.4(14) . . . . ?
C98 C97 C102 C101 2.9(15) . . . . ?
C98 C99 C100 C101 0.9(16) . . . . ?
C99 C100 C101 C102 0.5(17) . . . . ?
C100 C101 C102 C97 -2.5(17) . . . . ?
C102 C97 C98 C99 -1.5(13) . . . . ?
C103 P5 C97 C98 -137.2(7) . . . . ?
C103 P5 C97 C102 44.7(8) . . . . ?
C103 P5 C126 Fe2 -37.8(7) . . . . ?
C103 P5 C126 C127 57.7(9) . . . . ?
C103 P5 C126 C130 -132.1(7) . . . . ?
C103 C104 C105 C106 -1.4(18) . . . . ?
C104 C103 C108 C107 4.7(14) . . . . ?
C104 C105 C106 C107 3.7(19) . . . . ?
C105 C106 C107 C108 -1.8(18) . . . . ?
C106 C107 C108 C103 -2.5(15) . . . . ?
C108 C103 C104 C105 -2.8(15) . . . . ?
C109 P8 C115 C116 -86.2(10) . . . . ?
C109 P8 C115 C120 89.7(8) . . . . ?
C109 P8 C121 Fe2 -82.8(6) . . . . ?
C109 P8 C121 C122 6.3(9) . . . . ?
C109 P8 C121 C125 -171.1(8) . . . . ?
C109 C110 C111 C112 2.8(18) . . . . ?
C110 C109 C114 C113 -1.4(16) . . . . ?
C110 C111 C112 C113 -3.8(19) . . . . ?
C111 C112 C113 C114 2.1(18) . . . . ?
C112 C113 C114 C109 0.5(18) . . . . ?
C114 C109 C110 C111 -0.3(16) . . . . ?
C115 P8 C109 C110 25.4(9) . . . . ?
C115 P8 C109 C114 -157.2(8) . . . . ?
C115 P8 C121 Fe2 166.1(5) . . . . ?
C115 P8 C121 C122 -104.8(8) . . . . ?
C115 P8 C121 C125 77.8(9) . . . . ?
C115 C116 C117 C118 0(2) . . . . ?
C116 C115 C120 C119 -1.8(16) . . . . ?
C116 C117 C118 C119 -1(2) . . . . ?
C117 C118 C119 C120 0.8(19) . . . . ?
C118 C119 C120 C115 0.5(17) . . . . ?
C120 C115 C116 C117 1.8(19) . . . . ?
C121 P8 C109 C110 -85.5(8) . . . . ?
C121 P8 C109 C114 91.9(8) . . . . ?
C121 P8 C115 C116 23.0(11) . . . . ?
C121 P8 C115 C120 -161.1(8) . . . . ?
C121 C122 C123 Fe2 58.8(6) . . . . ?
C121 C122 C123 C124 -0.6(11) . . . . ?
C122 C121 C125 Fe2 -60.0(6) . . . . ?
C122 C121 C125 C124 -0.6(10) . . . . ?
C122 C123 C124 Fe2 59.4(7) . . . . ?
C122 C123 C124 C125 0.2(11) . . . . ?
C123 C124 C125 Fe2 59.1(7) . . . . ?
C123 C124 C125 C121 0.3(11) . . . . ?
C125 C121 C122 Fe2 60.1(6) . . . . ?
C125 C121 C122 C123 0.8(10) . . . . ?
C126 P5 C97 C98 -30.8(7) . . . . ?
C126 P5 C97 C102 151.1(8) . . . . ?
C126 P5 C103 C104 -60.7(9) . . . . ?
C126 P5 C103 C108 116.6(8) . . . . ?
C126 C127 C128 Fe2 60.5(6) . . . . ?
C126 C127 C128 C129 -0.3(10) . . . . ?
C127 C126 C130 Fe2 -59.2(6) . . . . ?
C127 C126 C130 C129 -1.2(10) . . . . ?
C127 C128 C129 Fe2 59.6(7) . . . . ?
C127 C128 C129 C130 -0.5(11) . . . . ?
C128 C129 C130 Fe2 58.8(7) . . . . ?
C128 C129 C130 C126 1.1(10) . . . . ?
C130 C126 C127 Fe2 61.1(6) . . . . ?
C130 C126 C127 C128 0.9(10) . . . . ?
C131 P7 C17 Fe4 48.1(7) . . . . ?
C131 P7 C17 C13 134.2(8) . . . . ?
C131 P7 C17 C16 -44.1(10) . . . . ?
C131 P7 C85 C86 134.7(8) . . . . ?
C131 P7 C85 C90 -47.8(9) . . . . ?
C131 C132 C133 C134 -3.5(18) . . . . ?
C132 C131 C136 C135 -4.8(16) . . . . ?
C132 C133 C134 C135 0(2) . . . . ?
C133 C134 C135 C136 1(2) . . . . ?
C134 C135 C136 C131 1.7(17) . . . . ?
C136 C131 C132 C133 5.7(16) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.500 0.500 0.000 929.8 320.6 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
_vrf_PLAT971_cu_lwm1_0m          
;
PROBLEM:  Check  Check Calcd Positive Resid. Density on Au
RESPONSE: Possibly related to Fourier Truncation near the heavy Au atom.
;
_vrf_PLAT972_cu_lwm1_0m          
;
PROBLEM:  Check Calcd Resid. Dens. 1.11Ang From Au
RESPONSE: Possibly related to Fourier Truncation near the heavy Au atom.
;
_vrf_PLAT973_cu_lwm1_0m          
;
PROBLEM:  Check  Check Calcd Positive Resid. Density on Au
RESPONSE: Possibly related to Fourier Truncation near the heavy Au atom.
;
