# Supplementary Information (SI) for Inorganic Chemistry Frontiers.
# This journal is © the Partner Organisations 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1
_database_code_depnum_ccdc_archive 'CCDC 2505634'
loop_
_audit_author_name
_audit_author_address
'shuangxue wu'
;Northeast Normal University Changchun
China
;
_audit_update_record             
;
2025-11-25 deposited with the CCDC.	2026-01-19 downloaded from the CCDC.
;
_audit_creation_date             2025-11-24
_audit_creation_method           
;
Olex2 1.5
(compiled 2025.07.13 svn.rb7424aed for OlexSys, GUI svn.r7314)
;
_shelx_SHELXL_version_number     2025/1
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C312 H276 Mo24 Na32 O276 P48 V30'
_chemical_formula_sum            'C312 H276 Mo24 Na32 O276 P48 V30'
_chemical_formula_weight         14494.31
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -0.0483 2.7339 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.1353 0.1239 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
V V 0.0687 2.1097 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      tetragonal
_space_group_IT_number           85
_space_group_name_H-M_alt        'P 4/n'
_space_group_name_Hall           '-P 4a'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'-y+1/2, x, z'
'y, -x+1/2, z'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'y-1/2, -x, -z'
'-y, x-1/2, -z'

_cell_length_a                   30.0146(14)
_cell_length_b                   30.0146(14)
_cell_length_c                   37.225(5)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     33535(6)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9749
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      57.000
_cell_measurement_theta_min      1.953
_shelx_estimated_absorpt_T_max   0.54
_shelx_estimated_absorpt_T_min   0.21
_exptl_absorpt_coefficient_mu    8.828
_exptl_absorpt_correction_T_max  0.86
_exptl_absorpt_correction_T_min  0.84
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Krause et al., 2015) was used for absorption correction.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.435
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             14252
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.13
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0813
_diffrn_reflns_av_unetI/netI     0.0678
_diffrn_reflns_Laue_measured_fraction_full 0.990
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            56621
_diffrn_reflns_point_group_measured_fraction_full 0.990
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        44.519
_diffrn_reflns_theta_max         44.519
_diffrn_reflns_theta_min         1.891
_diffrn_ambient_temperature      173.02
_diffrn_detector                 'charge-coupled device (CCD) area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'Bruker D8 VENTURE'
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 VENTURE'
_diffrn_measurement_method       '0.60\ % \ w and 0.6\ % \ f scans'
_diffrn_oxdiff_ac3_digest_hkl    013eb6badcc6709cee8d65a39da7a2c9c4453f
_diffrn_radiation_collimation    '0.5 mm double- pinhole'
_diffrn_radiation_detector       'Bruker D8 VENTURE'
_diffrn_radiation_monochromator  'equatorially mounted graphite'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_xray_symbol    K-L~3~
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           1.0
_diffrn_source_power             0.05
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                7483
_reflns_number_total             13119
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (Bruker-AXS, 2016)'
_computing_data_collection       'APEX4 Ver. 2016.5-0 (Bruker-AXS, 2016)'
_computing_data_reduction        'SAINT V8.40B (Bruker-AXS, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2025/1 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.124
_refine_diff_density_min         -1.117
_refine_diff_density_rms         0.157
_refine_ls_extinction_coef       0.000022(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2025/1 (Sheldrick 2025)'
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1490
_refine_ls_number_reflns         13119
_refine_ls_number_restraints     4155
_refine_ls_R_factor_all          0.2056
_refine_ls_R_factor_gt           0.1490
_refine_ls_restrained_S_all      0.973
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.2000P)²+600.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3701
_refine_ls_wR_factor_ref         0.4229
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 P6-C47 = P9-C18 = P8-C49 = P1-C26 = P10-C55 = P4-C66 = P12-C6 = P3-C37 = P2-
 C24 = P5-C35 = P11-C68 = P7-C7
 1.8 with sigma of 0.01
 P1-C27 = P8-C50 = P8-C54 = P1-C25 = P10-C60 = P10-C56 = P4-C61 = P4-C65 = P12-
 C5 = P12-C1 = P6-C48 = P6-C46 = P3-C38 = P3-C42 = P7-C8 = P7-C12 = P2-C19 = P2-
 C23 = P9-C17 = P9-C13 = P11-C67 = P11-C69 = P5-C34 = P5-C36
 2.75 with sigma of 0.01
 V7-O45
 2.093 with sigma of 0.02
 V3-O11 = V3-O37
 2 with sigma of 0.02
 V8-O3
 2.2 with sigma of 0.02
 O13-V2
 2.2 with sigma of 0.02
 V6-O228
 2.2 with sigma of 0.02
 O16-C73 = O6-C73 = O9-C75 = O58-C75 = O30-C77 = O40-C77
 1.25 with sigma of 0.01
 C74-C73 = C78-C75 = C76-C77
 1.5 with sigma of 0.01
 O16-C74 = O6-C74 = O9-C78 = O58-C78 = O30-C76 = O40-C76
 2.28 with sigma of 0.01
 O99-V2
 2.1 with sigma of 0.02
 V2-O13 = V2-O99
 2 with sigma of 0.02
 O17-V6
 2 with sigma of 0.02
 O5-V7
 2.08 with sigma of 0.01
3. Restrained planarity
 P9, C13, C14, C15, C16, C17, C18
 with sigma of 0.01
 P5, C31, C32, C33, C34, C35, C36
 with sigma of 0.01
 P11, C67, C68, C69, C70, C71, C72
 with sigma of 0.01
 P2, C24, C19, C23, C22, C20, C21
 with sigma of 0.01
 P7, C7, C12, C11, C10, C9, C8
 with sigma of 0.01
 C43, C44, C45, C46, C47, C48, P6
 with sigma of 0.01
 C37, C38, C39, C40, C41, C42, P3
 with sigma of 0.01
 C1, C2, C3, C4, C5, C6, P12
 with sigma of 0.01
 C62, C63, C64, C65, C66, C61, P4
 with sigma of 0.01
 P10, C55, C56, C57, C58, C59, C60
 with sigma of 0.01
 P1, C25, C26, C27, C28, C29, C30
 with sigma of 0.01
 P8, C49, C54, C53, C52, C51, C50
 with sigma of 0.01
 O58, O9, C75, C78
 with sigma of 0.01
4. Uiso/Uaniso restraints and constraints
C1 \\sim C2 \\sim C3 \\sim C4 \\sim C5 \\sim C6 \\sim C7 \\sim C8 \\sim C9
\\sim C10 \\sim C11 \\sim C12 \\sim C13 \\sim C14 \\sim C15 \\sim C16 \\sim C17
\\sim C18 \\sim C19 \\sim C20 \\sim C21 \\sim C22 \\sim C23 \\sim C24 \\sim C25
\\sim C26 \\sim C27 \\sim C28 \\sim C29 \\sim C30 \\sim C31 \\sim C32 \\sim C33
\\sim C34 \\sim C35 \\sim C36 \\sim C37 \\sim C38 \\sim C39 \\sim C40 \\sim C41
\\sim C42 \\sim C43 \\sim C44 \\sim C45 \\sim C46 \\sim C47 \\sim C48 \\sim C49
\\sim C50 \\sim C51 \\sim C52 \\sim C53 \\sim C54 \\sim C55 \\sim C56 \\sim C57
\\sim C58 \\sim C59 \\sim C60 \\sim C61 \\sim C62 \\sim C63 \\sim C64 \\sim C65
\\sim C66 \\sim C67 \\sim C68 \\sim C69 \\sim C70 \\sim C71 \\sim C72 \\sim C73
\\sim C74 \\sim C75 \\sim C76 \\sim C77 \\sim C78 \\sim O1 \\sim O2 \\sim O4
\\sim O6 \\sim O7 \\sim O8 \\sim O10 \\sim O12 \\sim O14 \\sim O15 \\sim O16
\\sim O18 \\sim O20 \\sim O21 \\sim O22 \\sim O24 \\sim O26 \\sim O28 \\sim O30
\\sim O32 \\sim O34 \\sim O36 \\sim O38 \\sim O40 \\sim O41 \\sim O42 \\sim O44
\\sim O48 \\sim O50 \\sim O52 \\sim O54 \\sim O56 \\sim O58 \\sim O59 \\sim O60
\\sim O61 \\sim O62 \\sim O63 \\sim O64 \\sim O66 \\sim O68 \\sim O70 \\sim O72
\\sim O74 \\sim O76 \\sim O78 \\sim O79 \\sim O80 \\sim O82 \\sim O84 \\sim O86
\\sim O88 \\sim O90 \\sim O92 \\sim O94 \\sim O96 \\sim O98 \\sim O100 \\sim
O102 \\sim O108 \\sim O110 \\sim O111 \\sim O9 \\sim O5 \\sim O3 \\sim O11
\\sim O37 \\sim O45 \\sim O13 \\sim O228 \\sim O99 \\sim O17 \\sim P1 \\sim P2
\\sim P3 \\sim P4 \\sim P5 \\sim P6 \\sim P7 \\sim P8 \\sim P9 \\sim P10 \\sim
P11 \\sim P12: within 3.8A with sigma of 0.04 and sigma for terminal atoms of
0.04 within 3.8A
5.a Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C5(H5), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12), C13(H13), C14(H14), C15(H15), C16(H16), C17(H17), C19(H19), C20(H20),
  C21(H21), C22(H22), C23(H23), C25(H25), C27(H27), C28(H28), C29(H29),
 C30(H30), C31(H31), C32(H32), C33(H33), C34(H34), C36(H36), C38(H38), C39(H39),
  C40(H40), C41(H41), C42(H42), C43(H43), C44(H44), C45(H45), C46(H46),
 C48(H48), C50(H50), C51(H51), C52(H52), C53(H53), C54(H54), C56(H56), C57(H57),
  C58(H58), C59(H59), C60(H60), C61(H61), C62(H62), C63(H63), C64(H64),
 C65(H65), C67(H67), C69(H69), C70(H70), C71(H71), C72(H72)
5.b Fitted hexagon refined as free rotating group:
 C1(C2,C3,C4,C5,C6), C7(C8,C9,C10,C11,C12), C13(C14,C15,C16,C17,C18), C19(C20,
 C21,C22,C23,C24), C25(C26,C27,C28,C29,C30), C31(C32,C33,C34,C35,C36), C37(C38,
 C39,C40,C41,C42), C43(C44,C45,C46,C47,C48), C49(C50,C51,C52,C53,C54), C55(C56,
 C57,C58,C59,C60), C61(C62,C63,C64,C65,C66), C67(C68,C69,C70,C71,C72)
5.c Idealised Me refined as rotating group:
 C74(H74A,H74B,H74C), C76(H76A,H76B,H76C), C78(H78A,H78B,H78C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Mo1 Mo 0.69646(8) 0.94206(8) 0.53855(7) 0.1141(9) Uani 1 1 d . . . . .
Mo2 Mo 0.50361(12) 0.67603(12) 0.90671(10) 0.1688(14) Uani 1 1 d . . . . .
Mo3 Mo 0.47023(9) 0.91742(9) 0.76017(9) 0.1420(12) Uani 1 1 d . . . . .
Mo4 Mo 0.64154(8) 0.97812(7) 0.58467(8) 0.1144(9) Uani 1 1 d . . . . .
Mo5 Mo 0.56943(13) 0.65995(13) 0.95058(10) 0.1795(15) Uani 1 1 d . . . . .
Mo6 Mo 0.43894(9) 0.84561(9) 0.72991(9) 0.1390(12) Uani 1 1 d . . . . .
V1 V 0.58846(16) 0.88200(19) 0.5403(2) 0.146(2) Uani 1 1 d . . . . .
V2 V 0.6467(3) 1.0163(3) 0.7455(3) 0.225(4) Uani 1 1 d D . . . .
V3 V 0.5492(3) 0.5621(3) 0.8924(2) 0.215(4) Uani 1 1 d D . . . .
V4 V 0.7575(2) 1.0189(3) 0.5986(2) 0.178(3) Uani 1 1 d . . . . .
V5 V 0.4511(3) 0.8307(3) 0.8291(2) 0.203(3) Uani 1 1 d . . . . .
V6 V 0.750000 0.750000 0.5074(5) 0.184(6) Uani 1 4 d DS T P . .
V7 V 0.750000 0.750000 0.9802(4) 0.216(7) Uani 1 4 d DS T P . .
V8 V 0.5432(3) 0.7826(3) 0.9460(2) 0.198(3) Uani 1 1 d D . . . .
V9 V 0.4878(3) 0.9196(3) 0.6624(2) 0.194(3) Uani 1 1 d . . . . .
P1 P 0.7968(3) 0.9765(3) 0.5264(3) 0.124(3) Uani 1 1 d D U . . .
P2 P 0.4531(4) 0.7701(4) 0.9022(4) 0.184(4) Uani 1 1 d D U . . .
P3 P 0.4708(4) 0.9335(4) 0.8465(3) 0.164(4) Uani 1 1 d D U . . .
P4 P 0.5380(3) 0.9547(2) 0.5893(3) 0.124(3) Uani 1 1 d D U . . .
P5 P 0.6121(5) 0.5622(5) 0.9621(3) 0.196(4) Uani 1 1 d D U . . .
P6 P 0.4289(2) 0.8339(3) 0.6442(3) 0.133(3) Uani 1 1 d D U . . .
P7 P 0.4292(4) 0.7494(4) 0.7757(4) 0.170(4) Uani 1 1 d D U . . .
P8 P 0.6747(3) 0.8432(4) 0.4995(3) 0.153(3) Uani 1 1 d D U . . .
P9 P 0.4802(4) 0.6074(5) 0.8373(4) 0.181(4) Uani 1 1 d D U . . .
P10 P 0.6782(3) 1.0395(3) 0.6540(3) 0.142(3) Uani 1 1 d D U . . .
P11 P 0.6301(6) 0.7433(6) 0.9874(3) 0.206(5) Uani 1 1 d D U . . .
P12 P 0.5346(4) 0.9903(3) 0.7157(4) 0.161(3) Uani 1 1 d D U . . .
O1 O 0.6353(6) 0.9260(5) 0.5535(6) 0.130(5) Uani 1 1 d . U . . .
O2 O 0.5668(9) 0.7949(9) 0.9037(7) 0.188(6) Uani 1 1 d . U . . .
C1 C 0.5327(7) 1.0780(5) 0.6935(7) 0.199(7) Uani 1 1 d DG U . . .
H1 H 0.561956 1.072879 0.684683 0.239 Uiso 1 1 calc R U . . .
C2 C 0.5131(9) 1.1196(5) 0.6894(8) 0.223(9) Uani 1 1 d G U . . .
H2 H 0.528901 1.142978 0.677860 0.268 Uiso 1 1 calc R U . . .
C3 C 0.4702(9) 1.1271(5) 0.7023(7) 0.221(10) Uani 1 1 d G U . . .
H3 H 0.456828 1.155594 0.699560 0.265 Uiso 1 1 calc R U . . .
C4 C 0.4471(7) 1.0930(7) 0.7193(8) 0.234(10) Uani 1 1 d G U . . .
H4 H 0.417809 1.098111 0.728083 0.281 Uiso 1 1 calc R U . . .
C5 C 0.4667(6) 1.0513(6) 0.7233(7) 0.196(7) Uani 1 1 d DG U . . .
H5 H 0.450864 1.028013 0.734906 0.235 Uiso 1 1 calc R U . . .
C6 C 0.5095(5) 1.0439(4) 0.7104(3) 0.194(7) Uani 1 1 d DG U . . .
O4 O 0.5836(6) 0.9600(5) 0.6082(6) 0.126(4) Uani 1 1 d . U . . .
C7 C 0.3747(4) 0.7257(5) 0.7752(4) 0.213(8) Uani 1 1 d DG U . . .
C8 C 0.3410(5) 0.7460(8) 0.7556(6) 0.218(8) Uani 1 1 d DG U . . .
H8 H 0.346911 0.772445 0.742429 0.262 Uiso 1 1 calc R U . . .
C9 C 0.2985(5) 0.7275(10) 0.7551(8) 0.246(11) Uani 1 1 d G U . . .
H9 H 0.275413 0.741375 0.741714 0.295 Uiso 1 1 calc R U . . .
C10 C 0.2898(6) 0.6888(10) 0.7744(8) 0.245(11) Uani 1 1 d G U . . .
H10 H 0.260747 0.676168 0.774076 0.294 Uiso 1 1 calc R U . . .
C11 C 0.3235(8) 0.6685(8) 0.7940(8) 0.254(11) Uani 1 1 d G U . . .
H11 H 0.317577 0.642030 0.807153 0.305 Uiso 1 1 calc R U . . .
C12 C 0.3660(7) 0.6870(7) 0.7944(7) 0.226(8) Uani 1 1 d DG U . . .
H12 H 0.389075 0.673100 0.807869 0.271 Uiso 1 1 calc R U . . .
O6 O 0.6650(5) 0.9231(5) 0.6224(5) 0.117(5) Uani 1 1 d D U . . .
O7 O 0.4607(9) 0.7110(9) 0.7706(8) 0.193(7) Uani 1 1 d . U . . .
O8 O 0.7064(6) 0.9855(6) 0.5766(6) 0.135(5) Uani 1 1 d . U . . .
O10 O 0.7024(6) 0.8832(6) 0.5118(6) 0.136(5) Uani 1 1 d . U . . .
O12 O 0.7643(6) 0.9365(6) 0.5336(5) 0.126(5) Uani 1 1 d . U . . .
O14 O 0.6870(6) 0.9769(6) 0.5032(5) 0.130(5) Uani 1 1 d . U . . .
O15 O 0.7301(8) 1.0783(8) 0.5727(8) 0.188(7) Uani 1 1 d . U . . .
O16 O 0.7151(6) 0.8953(5) 0.5828(5) 0.118(5) Uani 1 1 d D U . . .
O18 O 0.7889(6) 1.0130(7) 0.5510(6) 0.135(5) Uani 1 1 d . U . . .
C13 C 0.3956(6) 0.5946(8) 0.8644(6) 0.235(9) Uani 1 1 d DG U . . .
H13 H 0.402629 0.617940 0.880664 0.282 Uiso 1 1 calc R U . . .
C14 C 0.3542(6) 0.5741(10) 0.8658(8) 0.263(11) Uani 1 1 d G U . . .
H14 H 0.332799 0.583403 0.883083 0.316 Uiso 1 1 calc R U . . .
C15 C 0.3439(6) 0.5400(9) 0.8420(9) 0.261(11) Uani 1 1 d G U . . .
H15 H 0.315566 0.525929 0.842947 0.313 Uiso 1 1 calc R U . . .
C16 C 0.3752(8) 0.5263(9) 0.8167(8) 0.259(11) Uani 1 1 d G U . . .
H16 H 0.368164 0.502992 0.800393 0.310 Uiso 1 1 calc R U . . .
C17 C 0.4166(7) 0.5468(7) 0.8153(6) 0.239(9) Uani 1 1 d DG U . . .
H17 H 0.437994 0.537528 0.797974 0.287 Uiso 1 1 calc R U . . .
C18 C 0.4269(4) 0.5810(5) 0.8391(4) 0.222(8) Uani 1 1 d DG U . . .
O20 O 0.6438(6) 1.0116(6) 0.6321(6) 0.137(5) Uani 1 1 d . U . . .
O21 O 0.3786(10) 0.8350(9) 0.8276(8) 0.214(8) Uani 1 1 d . U . . .
O22 O 0.5029(6) 0.9360(6) 0.6119(6) 0.136(5) Uani 1 1 d . U . . .
C19 C 0.3753(6) 0.7227(7) 0.8920(6) 0.218(8) Uani 1 1 d DG U . . .
H19 H 0.387436 0.714601 0.869349 0.262 Uiso 1 1 calc R U . . .
C20 C 0.3335(6) 0.7071(8) 0.9021(8) 0.242(11) Uani 1 1 d G U . . .
H20 H 0.317071 0.688431 0.886300 0.291 Uiso 1 1 calc R U . . .
C21 C 0.3157(5) 0.7190(8) 0.9352(8) 0.237(11) Uani 1 1 d G U . . .
H21 H 0.287138 0.708357 0.942075 0.284 Uiso 1 1 calc R U . . .
C22 C 0.3397(7) 0.7464(10) 0.9583(7) 0.243(11) Uani 1 1 d G U . . .
H22 H 0.327570 0.754452 0.980899 0.291 Uiso 1 1 calc R U . . .
C23 C 0.3815(6) 0.7619(8) 0.9482(5) 0.217(8) Uani 1 1 d DG U . . .
H23 H 0.397936 0.780622 0.963949 0.260 Uiso 1 1 calc R U . . .
C24 C 0.3993(4) 0.7501(4) 0.9151(4) 0.206(8) Uani 1 1 d DG U . . .
O24 O 0.4677(6) 0.8972(6) 0.7081(7) 0.147(5) Uani 1 1 d . U . . .
C25 C 0.7756(6) 1.0387(5) 0.4745(4) 0.169(7) Uani 1 1 d DG U . . .
H25 H 0.775046 1.059688 0.493570 0.203 Uiso 1 1 calc R U . . .
C26 C 0.7853(3) 0.9942(4) 0.4815(3) 0.145(7) Uani 1 1 d DG U . . .
C27 C 0.7861(6) 0.9635(6) 0.4536(3) 0.165(7) Uani 1 1 d DG U . . .
H27 H 0.792746 0.933097 0.458465 0.198 Uiso 1 1 calc R U . . .
C28 C 0.7772(7) 0.9771(8) 0.4187(3) 0.185(10) Uani 1 1 d G U . . .
H28 H 0.777745 0.956094 0.399632 0.222 Uiso 1 1 calc R U . . .
C29 C 0.7675(6) 1.0216(9) 0.4117(4) 0.182(10) Uani 1 1 d G U . . .
H29 H 0.761396 1.030889 0.387767 0.218 Uiso 1 1 calc R U . . .
C30 C 0.7667(7) 1.0523(7) 0.4396(5) 0.185(10) Uani 1 1 d G U . . .
H30 H 0.760046 1.082686 0.434736 0.222 Uiso 1 1 calc R U . . .
O26 O 0.4525(7) 0.8609(7) 0.7820(7) 0.158(5) Uani 1 1 d . U . . .
O28 O 0.4446(6) 0.8161(7) 0.6802(7) 0.144(5) Uani 1 1 d . U . . .
O30 O 0.5587(6) 0.6937(8) 0.8658(6) 0.169(6) Uani 1 1 d D U . . .
O32 O 0.4313(7) 0.7796(7) 0.7427(7) 0.159(6) Uani 1 1 d . U . . .
C31 C 0.6030(10) 0.5547(9) 1.0705(3) 0.255(11) Uani 1 1 d G U . . .
H31 H 0.622390 0.557785 1.090480 0.306 Uiso 1 1 calc R U . . .
C32 C 0.5582(11) 0.5449(8) 1.0759(4) 0.244(11) Uani 1 1 d G U . . .
H32 H 0.547028 0.541361 1.099630 0.293 Uiso 1 1 calc R U . . .
C33 C 0.5298(8) 0.5404(10) 1.0467(6) 0.249(11) Uani 1 1 d G U . . .
H33 H 0.499169 0.533734 1.050390 0.299 Uiso 1 1 calc R U . . .
C34 C 0.5461(6) 0.5456(9) 1.0120(5) 0.221(8) Uani 1 1 d DG U . . .
H34 H 0.526671 0.542531 0.992001 0.265 Uiso 1 1 calc R U . . .
C35 C 0.5909(5) 0.5554(4) 1.0066(3) 0.209(8) Uani 1 1 d DG U . . .
C36 C 0.6193(7) 0.5599(8) 1.0358(4) 0.232(9) Uani 1 1 d DG U . . .
H36 H 0.649894 0.566582 1.032089 0.278 Uiso 1 1 calc R U . . .
O34 O 0.4751(8) 0.7336(9) 0.8831(7) 0.177(6) Uani 1 1 d . U . . .
C37 C 0.4319(4) 0.9782(4) 0.8419(3) 0.181(7) Uani 1 1 d DG U . . .
C38 C 0.4457(6) 1.0189(5) 0.8280(6) 0.188(8) Uani 1 1 d DG U . . .
H38 H 0.475872 1.022995 0.820966 0.225 Uiso 1 1 calc R U . . .
C39 C 0.4154(8) 1.0536(5) 0.8244(7) 0.220(10) Uani 1 1 d G U . . .
H39 H 0.424841 1.081459 0.814939 0.264 Uiso 1 1 calc R U . . .
C40 C 0.3713(8) 1.0476(7) 0.8347(6) 0.209(10) Uani 1 1 d G U . . .
H40 H 0.350584 1.071373 0.832275 0.251 Uiso 1 1 calc R U . . .
C41 C 0.3575(5) 1.0069(8) 0.8486(7) 0.212(10) Uani 1 1 d G U . . .
H41 H 0.327358 1.002824 0.855638 0.255 Uiso 1 1 calc R U . . .
C42 C 0.3878(4) 0.9722(6) 0.8522(6) 0.190(8) Uani 1 1 d DG U . . .
H42 H 0.378389 0.944360 0.861666 0.228 Uiso 1 1 calc R U . . .
O36 O 0.8456(6) 0.9617(6) 0.5255(6) 0.128(5) Uani 1 1 d . U . . .
O38 O 0.4452(6) 0.8077(7) 0.6141(7) 0.143(6) Uani 1 1 d . U . . .
O40 O 0.6164(7) 0.6792(8) 0.9046(5) 0.169(6) Uani 1 1 d D U . . .
O41 O 0.4339(8) 0.9708(8) 0.6640(8) 0.187(6) Uani 1 1 d . U . . .
O42 O 0.5025(8) 0.9427(8) 0.8780(7) 0.166(7) Uani 1 1 d . U . . .
O44 O 0.6294(9) 0.8423(8) 0.5148(7) 0.177(6) Uani 1 1 d . U . . .
O48 O 0.5379(8) 0.7170(9) 0.9356(7) 0.180(5) Uani 1 1 d . U . . .
O50 O 0.5425(6) 0.9244(6) 0.5568(6) 0.137(5) Uani 1 1 d . U . . .
O52 O 0.4402(6) 0.8834(6) 0.6418(6) 0.143(5) Uani 1 1 d . U . . .
O54 O 0.6972(8) 0.7995(8) 0.5112(7) 0.180(7) Uani 1 1 d . U . . .
O56 O 0.3849(6) 0.8613(7) 0.7269(7) 0.152(5) Uani 1 1 d . U . . .
O58 O 0.5089(6) 0.8205(6) 0.7317(6) 0.150(5) Uani 1 1 d D U . . .
O59 O 0.5149(11) 0.5761(10) 0.8515(9) 0.215(7) Uani 1 1 d . U . . .
O60 O 0.6190(9) 0.6968(10) 0.9758(7) 0.194(6) Uani 1 1 d . U . . .
O61 O 0.5984(11) 0.7773(11) 0.9694(8) 0.206(7) Uani 1 1 d . U . . .
O62 O 0.6211(6) 1.0189(6) 0.5582(6) 0.143(5) Uani 1 1 d . U . . .
O63 O 0.5157(8) 0.8266(8) 0.8318(7) 0.179(6) Uani 1 1 d . U . . .
O64 O 0.5237(7) 0.9640(7) 0.6796(7) 0.157(5) Uani 1 1 d . U . . .
O66 O 0.5117(8) 0.9683(7) 0.7475(7) 0.161(6) Uani 1 1 d . U . . .
O68 O 0.4214(6) 0.9470(7) 0.7635(7) 0.158(5) Uani 1 1 d . U . . .
O70 O 0.7253(8) 1.0376(6) 0.6392(7) 0.159(6) Uani 1 1 d . U . . .
O72 O 0.4971(7) 0.9339(7) 0.8092(7) 0.158(5) Uani 1 1 d . U . . .
C43 C 0.3041(5) 0.7835(8) 0.6537(8) 0.219(10) Uani 1 1 d G U . . .
H43 H 0.290363 0.758167 0.664305 0.263 Uiso 1 1 calc R U . . .
C44 C 0.2784(3) 0.8147(9) 0.6356(7) 0.223(10) Uani 1 1 d G U . . .
H44 H 0.247058 0.810780 0.633765 0.268 Uiso 1 1 calc R U . . .
C45 C 0.2985(4) 0.8518(9) 0.6201(8) 0.235(10) Uani 1 1 d G U . . .
H45 H 0.280905 0.873125 0.607695 0.282 Uiso 1 1 calc R U . . .
C46 C 0.3443(4) 0.8575(7) 0.6227(6) 0.201(8) Uani 1 1 d DG U . . .
H46 H 0.358058 0.882859 0.612164 0.242 Uiso 1 1 calc R U . . .
C47 C 0.3700(3) 0.8263(4) 0.6409(3) 0.175(7) Uani 1 1 d DG U . . .
C48 C 0.3499(5) 0.7893(6) 0.6564(6) 0.190(8) Uani 1 1 d DG U . . .
H48 H 0.367517 0.767901 0.668775 0.228 Uiso 1 1 calc R U . . .
O74 O 0.6562(9) 0.5372(9) 0.9601(6) 0.185(7) Uani 1 1 d . U . . .
C49 C 0.6718(4) 0.8471(5) 0.4517(3) 0.203(8) Uani 1 1 d DG U . . .
C50 C 0.6488(8) 0.8148(7) 0.4323(4) 0.225(8) Uani 1 1 d DG U . . .
H50 H 0.634780 0.790845 0.444439 0.270 Uiso 1 1 calc R U . . .
C51 C 0.6465(10) 0.8177(10) 0.3950(4) 0.253(11) Uani 1 1 d G U . . .
H51 H 0.630834 0.795668 0.381780 0.304 Uiso 1 1 calc R U . . .
C52 C 0.6671(9) 0.8528(10) 0.3772(3) 0.241(11) Uani 1 1 d G U . . .
H52 H 0.665489 0.854772 0.351787 0.289 Uiso 1 1 calc R U . . .
C53 C 0.6900(10) 0.8851(9) 0.3966(4) 0.253(11) Uani 1 1 d G U . . .
H53 H 0.704091 0.909055 0.384454 0.304 Uiso 1 1 calc R U . . .
C54 C 0.6924(8) 0.8822(7) 0.4339(4) 0.209(8) Uani 1 1 d DG U . . .
H54 H 0.708037 0.904233 0.447113 0.250 Uiso 1 1 calc R U . . .
O76 O 0.5952(7) 0.8504(7) 0.5853(6) 0.155(6) Uani 1 1 d . U . . .
O78 O 0.5402(9) 0.6198(9) 0.9129(7) 0.186(6) Uani 1 1 d . U . . .
O79 O 0.5854(9) 0.9149(9) 0.4898(8) 0.197(7) Uani 1 1 d . U . . .
O80 O 0.4409(8) 0.8070(9) 0.8768(8) 0.184(6) Uani 1 1 d . U . . .
O82 O 0.4775(9) 0.6474(10) 0.8588(8) 0.192(6) Uani 1 1 d . U . . .
O84 O 0.6215(9) 0.6137(10) 0.9558(6) 0.187(6) Uani 1 1 d . U . . .
O86 O 0.4952(9) 0.6178(9) 0.8003(8) 0.190(7) Uani 1 1 d . U . . .
O88 O 0.7806(7) 0.9651(7) 0.6208(6) 0.156(6) Uani 1 1 d . U . . .
O90 O 0.4590(8) 0.6636(8) 0.9341(7) 0.185(6) Uani 1 1 d . U . . .
O92 O 0.5800(10) 0.5423(9) 0.9370(8) 0.189(7) Uani 1 1 d . U . . .
O94 O 0.5380(9) 0.6460(9) 0.9885(6) 0.195(6) Uani 1 1 d . U . . .
O96 O 0.6771(9) 1.0242(8) 0.6933(9) 0.190(7) Uani 1 1 d . U . . .
O98 O 0.4459(8) 0.8914(8) 0.8512(7) 0.169(6) Uani 1 1 d . U . . .
O100 O 0.5839(9) 0.9928(8) 0.7169(8) 0.182(6) Uani 1 1 d . U . . .
O102 O 0.5383(7) 0.8727(7) 0.6614(6) 0.155(5) Uani 1 1 d . U . . .
O108 O 0.4796(9) 0.7851(9) 0.9352(8) 0.186(6) Uani 1 1 d . U . . .
O110 O 0.4422(9) 0.7744(9) 0.8105(8) 0.190(6) Uani 1 1 d . U . . .
O111 O 0.6759(12) 0.7532(11) 0.9778(8) 0.224(8) Uani 1 1 d . U . . .
C55 C 0.6535(4) 1.0937(3) 0.6529(4) 0.197(7) Uani 1 1 d DG U . . .
C56 C 0.6242(7) 1.1048(6) 0.6254(6) 0.191(8) Uani 1 1 d DG U . . .
H56 H 0.617317 1.083533 0.607314 0.230 Uiso 1 1 calc R U . . .
C57 C 0.6049(8) 1.1468(7) 0.6244(8) 0.228(10) Uani 1 1 d G U . . .
H57 H 0.584820 1.154368 0.605634 0.273 Uiso 1 1 calc R U . . .
C58 C 0.6149(8) 1.1779(4) 0.6509(8) 0.221(10) Uani 1 1 d G U . . .
H58 H 0.601700 1.206643 0.650239 0.266 Uiso 1 1 calc R U . . .
C59 C 0.6442(9) 1.1669(5) 0.6784(8) 0.227(10) Uani 1 1 d G U . . .
H59 H 0.651075 1.188083 0.696526 0.272 Uiso 1 1 calc R U . . .
C60 C 0.6635(7) 1.1248(5) 0.6794(6) 0.211(8) Uani 1 1 d DG U . . .
H60 H 0.683573 1.117248 0.698208 0.253 Uiso 1 1 calc R U . . .
C61 C 0.5206(6) 1.0238(5) 0.5426(4) 0.168(7) Uani 1 1 d DG U . . .
H61 H 0.528759 1.003565 0.524084 0.202 Uiso 1 1 calc R U . . .
C62 C 0.5077(7) 1.0669(6) 0.5340(6) 0.175(9) Uani 1 1 d G U . . .
H62 H 0.507043 1.076260 0.509617 0.211 Uiso 1 1 calc R U . . .
C63 C 0.4957(6) 1.0965(4) 0.5611(7) 0.187(9) Uani 1 1 d G U . . .
H63 H 0.486856 1.125991 0.555209 0.224 Uiso 1 1 calc R U . . .
C64 C 0.4966(8) 1.0828(4) 0.5968(7) 0.198(9) Uani 1 1 d G U . . .
H64 H 0.488384 1.103027 0.615268 0.238 Uiso 1 1 calc R U . . .
C65 C 0.5095(7) 1.0397(4) 0.6054(5) 0.166(7) Uani 1 1 d DG U . . .
H65 H 0.510099 1.030332 0.629735 0.199 Uiso 1 1 calc R U . . .
C66 C 0.5215(3) 1.0101(3) 0.5783(4) 0.153(7) Uani 1 1 d DG U . . .
C67 C 0.6091(8) 0.7097(7) 1.0543(5) 0.235(8) Uani 1 1 d DG U . . .
H67 H 0.600771 0.683278 1.041945 0.282 Uiso 1 1 calc R U . . .
C68 C 0.6251(4) 0.7461(6) 1.0352(4) 0.233(8) Uani 1 1 d DG U . . .
C69 C 0.6373(9) 0.7848(7) 1.0533(5) 0.246(9) Uani 1 1 d DG U . . .
H69 H 0.648257 0.809669 1.040198 0.295 Uiso 1 1 calc R U . . .
C70 C 0.6334(11) 0.7870(10) 1.0904(5) 0.262(11) Uani 1 1 d G U . . .
H70 H 0.641752 0.813444 1.102765 0.314 Uiso 1 1 calc R U . . .
C71 C 0.6174(9) 0.7506(12) 1.1095(4) 0.257(11) Uani 1 1 d G U . . .
H71 H 0.614756 0.752137 1.134923 0.308 Uiso 1 1 calc R U . . .
C72 C 0.6052(10) 0.7119(10) 1.0915(5) 0.259(11) Uani 1 1 d G U . . .
H72 H 0.594265 0.687054 1.104513 0.310 Uiso 1 1 calc R U . . .
O9 O 0.5374(6) 0.8825(6) 0.7595(6) 0.148(5) Uani 1 1 d D U . . .
C73 C 0.6927(8) 0.8962(8) 0.6109(5) 0.134(6) Uani 1 1 d D U . . .
C74 C 0.7070(9) 0.8624(8) 0.6378(6) 0.161(9) Uani 1 1 d D U . . .
H74A H 0.693248 0.833630 0.632209 0.241 Uiso 1 1 calc R U . . .
H74B H 0.697776 0.871964 0.661866 0.241 Uiso 1 1 calc R U . . .
H74C H 0.739539 0.859369 0.637144 0.241 Uiso 1 1 calc R U . . .
O5 O 0.750000 0.750000 1.0362(5) 0.257(14) Uani 1 4 d DS TU P . .
O3 O 0.5146(10) 0.7617(10) 0.9992(6) 0.219(7) Uani 1 1 d D U . . .
O11 O 0.6033(7) 0.5818(9) 0.8650(7) 0.191(6) Uani 1 1 d D U . . .
O37 O 0.4898(8) 0.5534(11) 0.9168(8) 0.230(7) Uani 1 1 d D U . . .
O45 O 0.750000 0.750000 0.9234(7) 0.28(2) Uani 1 4 d DS TU P . .
O13 O 0.6675(13) 0.9482(7) 0.7502(10) 0.286(12) Uani 1 1 d D U . . .
O228 O 0.750000 0.750000 0.4481(7) 0.225(13) Uani 1 4 d DS TU P . .
C75 C 0.5379(6) 0.8447(6) 0.7457(4) 0.149(7) Uani 1 1 d D U . . .
C76 C 0.6309(8) 0.6998(13) 0.8468(6) 0.190(10) Uani 1 1 d D U . . .
H76A H 0.650517 0.673815 0.844728 0.285 Uiso 1 1 calc R U . . .
H76B H 0.648699 0.726319 0.852068 0.285 Uiso 1 1 calc R U . . .
H76C H 0.614883 0.704095 0.824073 0.285 Uiso 1 1 calc R U . . .
C77 C 0.5981(7) 0.6923(14) 0.8764(6) 0.180(8) Uani 1 1 d D U . . .
C78 C 0.5828(6) 0.8237(9) 0.7461(9) 0.179(9) Uani 1 1 d D U . . .
H78A H 0.599990 0.834027 0.725340 0.269 Uiso 1 1 calc R U . . .
H78B H 0.579706 0.791227 0.745084 0.269 Uiso 1 1 calc R U . . .
H78C H 0.598418 0.832031 0.768282 0.269 Uiso 1 1 calc R U . . .
O99 O 0.6256(11) 1.0817(6) 0.7482(9) 0.257(9) Uani 1 1 d D U . . .
O17 O 0.750000 0.750000 0.5619(7) 0.27(2) Uani 1 4 d DS TU P . .
Na1 Na 0.6441(4) 0.7670(4) 0.5476(4) 0.152(4) Uani 1 1 d . . . . .
Na2 Na 0.4779(4) 0.8710(4) 0.5736(4) 0.144(4) Uani 1 1 d . . . . .
Na3 Na 0.6814(5) 0.6661(6) 0.9404(4) 0.205(7) Uani 1 1 d . . . . .
Na4 Na 0.4931(4) 0.7511(4) 0.7041(4) 0.169(5) Uani 1 1 d . . . . .
Na5 Na 0.5577(5) 0.5751(5) 0.7882(5) 0.190(6) Uani 1 1 d . . . . .
Na6 Na 0.6126(4) 0.9514(4) 0.6706(4) 0.143(4) Uani 1 1 d . . . . .
Na7 Na 0.5062(5) 0.7135(6) 0.8212(5) 0.196(7) Uani 1 1 d . . . . .
Na8 Na 0.6269(6) 0.4743(6) 0.9134(5) 0.219(8) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Mo1 Mo4 2.614(4) . ?
Mo1 O1 1.977(19) . ?
Mo1 O8 1.95(2) . ?
Mo1 O10 2.03(2) . ?
Mo1 O12 2.050(18) . ?
Mo1 O14 1.704(18) . ?
Mo1 O16 2.235(16) . ?
Mo1 Na1 3.359(12) 4_565 ?
Mo2 Mo5 2.608(6) . ?
Mo2 O30 2.309(18) . ?
Mo2 O34 2.12(3) . ?
Mo2 O48 1.93(3) . ?
Mo2 O78 2.03(3) . ?
Mo2 O82 2.13(3) . ?
Mo2 O90 1.72(2) . ?
Mo2 Na7 3.376(16) . ?
Mo3 Mo6 2.607(4) . ?
Mo3 O24 2.03(2) . ?
Mo3 O26 1.95(2) . ?
Mo3 O66 2.03(2) . ?
Mo3 O68 1.717(19) . ?
Mo3 O72 2.06(2) . ?
Mo3 O9 2.272(18) . ?
Mo3 Na5 3.399(15) 4_565 ?
Mo4 O1 1.956(18) . ?
Mo4 O4 2.021(19) . ?
Mo4 O6 2.279(15) . ?
Mo4 O8 1.981(19) . ?
Mo4 O20 2.03(2) . ?
Mo4 O62 1.687(19) . ?
Mo4 Na6 3.411(13) . ?
Mo5 O40 2.291(18) . ?
Mo5 O48 2.03(3) . ?
Mo5 O60 2.08(3) . ?
Mo5 O78 2.05(3) . ?
Mo5 O84 2.10(3) . ?
Mo5 O94 1.75(2) . ?
Mo5 Na3 3.388(17) . ?
Mo6 O24 1.95(2) . ?
Mo6 O26 2.03(2) . ?
Mo6 O28 2.06(2) . ?
Mo6 O32 2.05(2) . ?
Mo6 O56 1.693(18) . ?
Mo6 O58 2.232(18) . ?
Mo6 Na4 3.406(12) . ?
V1 O1 1.991(19) . ?
V1 O36 1.939(18) 3_655 ?
V1 O44 1.96(3) . ?
V1 O50 1.97(2) . ?
V1 O76 1.93(2) . ?
V1 O79 2.13(3) . ?
V1 Na2 3.556(13) . ?
V2 O7 2.25(3) 4_565 ?
V2 O86 2.24(3) 4_565 ?
V2 O96 2.16(3) . ?
V2 O100 2.28(3) . ?
V2 O13 2.145(14) . ?
V2 O99 2.063(14) . ?
V2 Na4 3.505(16) 4_565 ?
V2 Na5 3.47(2) 4_565 ?
V2 Na6 3.553(17) . ?
V2 Na7 3.53(2) 4_565 ?
V3 O42 1.88(3) 3_655 ?
V3 O59 1.89(3) . ?
V3 O78 1.91(3) . ?
V3 O92 1.99(3) . ?
V3 O11 2.005(16) . ?
V3 O37 2.019(17) . ?
V3 Na8 3.60(2) . ?
V4 O8 2.01(2) . ?
V4 O15 2.19(3) . ?
V4 O18 2.02(2) . ?
V4 O38 1.94(2) 4_565 ?
V4 O70 1.88(2) . ?
V4 O88 1.94(2) . ?
V4 Na2 3.532(13) 4_565 ?
V5 O21 2.18(3) . ?
V5 O26 1.97(3) . ?
V5 O63 1.94(2) . ?
V5 O80 1.94(3) . ?
V5 O98 2.00(2) . ?
V5 O110 1.85(3) . ?
V5 Na8 3.46(2) 4_565 ?
V6 O54 2.18(3) . ?
V6 O54 2.18(3) 4_565 ?
V6 O54 2.18(3) 3_655 ?
V6 O54 2.18(3) 2_665 ?
V6 O228 2.21(2) . ?
V6 O17 2.03(2) . ?
V6 Na1 3.551(16) . ?
V6 Na1 3.551(16) 3_655 ?
V6 Na1 3.551(16) 4_565 ?
V6 Na1 3.551(16) 2_665 ?
V7 O111 2.23(4) 3_655 ?
V7 O111 2.23(4) 4_565 ?
V7 O111 2.23(4) . ?
V7 O111 2.23(4) 2_665 ?
V7 O5 2.084(10) . ?
V7 O45 2.11(2) . ?
V7 Na3 3.57(2) . ?
V7 Na3 3.57(2) 3_655 ?
V7 Na3 3.57(2) 4_565 ?
V7 Na3 3.57(2) 2_665 ?
V8 O2 1.77(2) . ?
V8 O48 2.01(3) . ?
V8 O61 1.88(4) . ?
V8 O74 1.92(3) 4_565 ?
V8 O108 1.95(3) . ?
V8 O3 2.246(17) . ?
V8 Na8 3.62(2) 4_565 ?
V9 O22 1.99(2) . ?
V9 O24 1.93(2) . ?
V9 O41 2.23(2) . ?
V9 O52 1.95(2) . ?
V9 O64 1.83(2) . ?
V9 O102 2.07(2) . ?
V9 Na2 3.625(16) . ?
P1 O12 1.570(19) . ?
P1 O18 1.45(2) . ?
P1 C26 1.786(6) . ?
P1 O36 1.532(18) . ?
P1 Na2 3.149(16) 4_565 ?
P2 C24 1.789(6) . ?
P2 O34 1.46(3) . ?
P2 O80 1.50(3) . ?
P2 O108 1.53(3) . ?
P2 Na8 3.18(2) 4_565 ?
P3 C37 1.786(6) . ?
P3 O42 1.53(3) . ?
P3 O72 1.60(2) . ?
P3 O98 1.48(2) . ?
P3 Na8 3.08(2) 4_565 ?
P4 O4 1.547(19) . ?
P4 O22 1.46(2) . ?
P4 O50 1.52(2) . ?
P4 C66 1.785(6) . ?
P4 Na2 3.147(14) . ?
P5 C35 1.787(6) . ?
P5 O74 1.52(3) . ?
P5 O84 1.59(3) . ?
P5 O92 1.47(3) . ?
P5 Na8 3.23(3) . ?
P6 O28 1.52(2) . ?
P6 O38 1.46(2) . ?
P6 O52 1.53(2) . ?
P6 C47 1.785(6) . ?
P6 Na2 3.210(18) . ?
P7 C7 1.783(6) . ?
P7 O7 1.50(3) . ?
P7 O32 1.53(3) . ?
P7 O110 1.55(3) . ?
P7 Na4 3.283(19) . ?
P7 Na7 3.06(2) . ?
P8 O10 1.53(2) . ?
P8 O44 1.47(3) . ?
P8 O54 1.54(3) . ?
P8 C49 1.786(6) . ?
P8 Na1 3.047(17) . ?
P8 Na1 3.322(17) 4_565 ?
P9 C18 1.786(6) . ?
P9 O59 1.50(3) . ?
P9 O82 1.45(3) . ?
P9 O86 1.48(3) . ?
P9 Na5 3.11(2) . ?
P9 Na7 3.34(2) . ?
P10 O20 1.56(2) . ?
P10 O70 1.52(2) . ?
P10 O96 1.53(3) . ?
P10 C55 1.788(6) . ?
P10 Na4 3.039(18) 4_565 ?
P10 Na6 3.355(15) . ?
P11 O60 1.50(3) . ?
P11 O61 1.55(3) . ?
P11 O111 1.45(3) . ?
P11 C68 1.788(6) . ?
P11 Na3 3.29(2) . ?
P11 Na3 3.05(2) 4_565 ?
P12 C6 1.787(6) . ?
P12 O64 1.59(3) . ?
P12 O66 1.52(2) . ?
P12 O100 1.48(3) . ?
P12 Na5 3.29(2) 4_565 ?
P12 Na6 3.107(16) . ?
C1 H1 0.9500 . ?
C1 C2 1.3900 . ?
C1 C6 1.3900 . ?
C2 H2 0.9500 . ?
C2 C3 1.3900 . ?
C3 H3 0.9500 . ?
C3 C4 1.3900 . ?
C4 H4 0.9500 . ?
C4 C5 1.3900 . ?
C5 H5 0.9500 . ?
C5 C6 1.3900 . ?
O4 Na6 2.49(2) . ?
C7 C8 1.3900 . ?
C7 C12 1.3900 . ?
C8 H8 0.9500 . ?
C8 C9 1.3900 . ?
C9 H9 0.9500 . ?
C9 C10 1.3900 . ?
C10 H10 0.9500 . ?
C10 C11 1.3900 . ?
C11 H11 0.9500 . ?
C11 C12 1.3900 . ?
C12 H12 0.9500 . ?
O6 C73 1.236(10) . ?
O6 Na6 2.53(2) . ?
O7 Na4 2.92(3) . ?
O7 Na7 2.33(3) . ?
O10 Na1 2.49(2) 4_565 ?
O12 Na1 2.47(2) 4_565 ?
O16 C73 1.244(9) . ?
O16 Na1 2.35(2) 4_565 ?
O18 Na2 2.62(2) 4_565 ?
C13 H13 0.9500 . ?
C13 C14 1.3900 . ?
C13 C18 1.3900 . ?
C14 H14 0.9500 . ?
C14 C15 1.3900 . ?
C15 H15 0.9500 . ?
C15 C16 1.3900 . ?
C16 H16 0.9500 . ?
C16 C17 1.3900 . ?
C17 H17 0.9500 . ?
C17 C18 1.3900 . ?
O20 Na6 2.49(2) . ?
O22 Na2 2.53(2) . ?
C19 H19 0.9500 . ?
C19 C20 1.3900 . ?
C19 C24 1.3900 . ?
C20 H20 0.9500 . ?
C20 C21 1.3900 . ?
C21 H21 0.9500 . ?
C21 C22 1.3900 . ?
C22 H22 0.9500 . ?
C22 C23 1.3900 . ?
C23 H23 0.9500 . ?
C23 C24 1.3900 . ?
C25 H25 0.9500 . ?
C25 C26 1.3900 . ?
C25 C30 1.3900 . ?
C26 C27 1.3900 . ?
C27 H27 0.9500 . ?
C27 C28 1.3900 . ?
C28 H28 0.9500 . ?
C28 C29 1.3900 . ?
C29 H29 0.9500 . ?
C29 C30 1.3900 . ?
C30 H30 0.9500 . ?
O28 Na4 2.59(3) . ?
O30 C77 1.247(10) . ?
O30 Na7 2.36(3) . ?
O32 Na4 2.49(2) . ?
C31 H31 0.9500 . ?
C31 C32 1.3900 . ?
C31 C36 1.3900 . ?
C32 H32 0.9500 . ?
C32 C33 1.3900 . ?
C33 H33 0.9500 . ?
C33 C34 1.3900 . ?
C34 H34 0.9500 . ?
C34 C35 1.3900 . ?
C35 C36 1.3900 . ?
C36 H36 0.9500 . ?
O34 Na7 2.56(3) . ?
C37 C38 1.3900 . ?
C37 C42 1.3900 . ?
C38 H38 0.9500 . ?
C38 C39 1.3900 . ?
C39 H39 0.9500 . ?
C39 C40 1.3900 . ?
C40 H40 0.9500 . ?
C40 C41 1.3900 . ?
C41 H41 0.9500 . ?
C41 C42 1.3900 . ?
C42 H42 0.9500 . ?
O36 Na2 2.66(2) 4_565 ?
O38 Na2 2.62(2) . ?
O40 C77 1.248(10) . ?
O40 Na3 2.40(3) . ?
O42 Na8 2.61(3) 4_565 ?
O44 Na1 2.60(3) . ?
O50 Na2 2.59(2) . ?
O52 Na2 2.81(3) . ?
O54 Na1 2.31(3) . ?
O54 Na1 3.02(3) 4_565 ?
O58 C75 1.247(10) . ?
O58 Na4 2.37(2) . ?
O59 Na5 2.69(3) . ?
O60 Na3 2.47(3) . ?
O61 Na3 2.61(3) 4_565 ?
O64 Na6 2.72(2) . ?
O66 Na5 2.56(3) 4_565 ?
O70 Na4 2.70(3) 4_565 ?
O72 Na5 2.48(3) 4_565 ?
C43 H43 0.9500 . ?
C43 C44 1.3900 . ?
C43 C48 1.3900 . ?
C44 H44 0.9500 . ?
C44 C45 1.3900 . ?
C45 H45 0.9500 . ?
C45 C46 1.3900 . ?
C46 H46 0.9500 . ?
C46 C47 1.3900 . ?
C47 C48 1.3900 . ?
C48 H48 0.9500 . ?
O74 Na8 2.71(3) . ?
C49 C50 1.3900 . ?
C49 C54 1.3900 . ?
C50 H50 0.9500 . ?
C50 C51 1.3900 . ?
C51 H51 0.9500 . ?
C51 C52 1.3900 . ?
C52 H52 0.9500 . ?
C52 C53 1.3900 . ?
C53 H53 0.9500 . ?
C53 C54 1.3900 . ?
C54 H54 0.9500 . ?
O80 Na8 2.61(3) 4_565 ?
O82 Na7 2.58(3) . ?
O84 Na3 2.46(3) . ?
O86 Na5 2.32(3) . ?
O86 Na7 3.00(3) . ?
O92 Na8 2.63(3) . ?
O96 Na4 2.32(3) 4_565 ?
O98 Na8 2.53(3) 4_565 ?
O100 Na6 2.29(3) . ?
O108 Na8 2.77(3) 4_565 ?
O110 Na7 2.68(3) . ?
O111 Na3 2.42(4) 4_565 ?
O111 Na3 2.97(4) . ?
C55 C56 1.3900 . ?
C55 C60 1.3900 . ?
C56 H56 0.9500 . ?
C56 C57 1.3900 . ?
C57 H57 0.9500 . ?
C57 C58 1.3900 . ?
C58 H58 0.9500 . ?
C58 C59 1.3900 . ?
C59 H59 0.9500 . ?
C59 C60 1.3900 . ?
C60 H60 0.9500 . ?
C61 H61 0.9500 . ?
C61 C62 1.3900 . ?
C61 C66 1.3900 . ?
C62 H62 0.9500 . ?
C62 C63 1.3900 . ?
C63 H63 0.9500 . ?
C63 C64 1.3900 . ?
C64 H64 0.9500 . ?
C64 C65 1.3900 . ?
C65 H65 0.9500 . ?
C65 C66 1.3900 . ?
C67 H67 0.9500 . ?
C67 C68 1.3900 . ?
C67 C72 1.3900 . ?
C68 C69 1.3900 . ?
C69 H69 0.9500 . ?
C69 C70 1.3900 . ?
C70 H70 0.9500 . ?
C70 C71 1.3900 . ?
C71 H71 0.9500 . ?
C71 C72 1.3900 . ?
C72 H72 0.9500 . ?
O9 C75 1.246(10) . ?
O9 Na5 2.37(2) 4_565 ?
C73 C74 1.491(10) . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C75 C78 1.490(10) . ?
C76 H76A 0.9800 . ?
C76 H76B 0.9800 . ?
C76 H76C 0.9800 . ?
C76 C77 1.496(10) . ?
C78 H78A 0.9800 . ?
C78 H78B 0.9800 . ?
C78 H78C 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Mo4 Mo1 Na1 130.6(3) . 4_565 ?
O1 Mo1 Mo4 48.0(5) . . ?
O1 Mo1 O10 90.4(8) . . ?
O1 Mo1 O12 157.9(7) . . ?
O1 Mo1 O16 82.7(7) . . ?
O1 Mo1 Na1 111.7(5) . 4_565 ?
O8 Mo1 Mo4 48.8(6) . . ?
O8 Mo1 O1 95.7(8) . . ?
O8 Mo1 O10 157.4(8) . . ?
O8 Mo1 O12 88.2(8) . . ?
O8 Mo1 O16 81.2(7) . . ?
O8 Mo1 Na1 110.3(6) . 4_565 ?
O10 Mo1 Mo4 137.3(6) . . ?
O10 Mo1 O12 78.4(8) . . ?
O10 Mo1 O16 78.1(7) . . ?
O10 Mo1 Na1 47.6(6) . 4_565 ?
O12 Mo1 Mo4 135.9(6) . . ?
O12 Mo1 O16 76.4(7) . . ?
O12 Mo1 Na1 47.2(5) . 4_565 ?
O14 Mo1 Mo4 98.6(7) . . ?
O14 Mo1 O1 102.3(8) . . ?
O14 Mo1 O8 100.1(9) . . ?
O14 Mo1 O10 99.8(9) . . ?
O14 Mo1 O12 98.4(8) . . ?
O14 Mo1 O16 174.7(8) . . ?
O14 Mo1 Na1 130.8(7) . 4_565 ?
O16 Mo1 Mo4 86.2(4) . . ?
O16 Mo1 Na1 44.3(5) . 4_565 ?
Mo5 Mo2 Na7 129.4(3) . . ?
O30 Mo2 Mo5 85.0(6) . . ?
O30 Mo2 Na7 44.4(6) . . ?
O34 Mo2 Mo5 135.8(7) . . ?
O34 Mo2 O30 80.1(8) . . ?
O34 Mo2 O82 80.3(11) . . ?
O34 Mo2 Na7 49.2(7) . . ?
O48 Mo2 Mo5 50.6(8) . . ?
O48 Mo2 O30 80.8(9) . . ?
O48 Mo2 O34 85.8(11) . . ?
O48 Mo2 O78 100.2(11) . . ?
O48 Mo2 O82 156.9(10) . . ?
O48 Mo2 Na7 107.5(8) . . ?
O78 Mo2 Mo5 50.5(8) . . ?
O78 Mo2 O30 83.0(9) . . ?
O78 Mo2 O34 160.9(9) . . ?
O78 Mo2 O82 87.7(11) . . ?
O78 Mo2 Na7 111.9(7) . . ?
O82 Mo2 Mo5 136.8(8) . . ?
O82 Mo2 O30 78.7(9) . . ?
O82 Mo2 Na7 49.7(8) . . ?
O90 Mo2 Mo5 100.2(10) . . ?
O90 Mo2 O30 174.7(11) . . ?
O90 Mo2 O34 96.2(11) . . ?
O90 Mo2 O48 102.8(11) . . ?
O90 Mo2 O78 100.0(11) . . ?
O90 Mo2 O82 97.1(11) . . ?
O90 Mo2 Na7 130.4(10) . . ?
Mo6 Mo3 Na5 130.4(3) . 4_565 ?
O24 Mo3 Mo6 47.8(6) . . ?
O24 Mo3 O72 158.9(8) . . ?
O24 Mo3 O9 83.4(8) . . ?
O24 Mo3 Na5 113.1(6) . 4_565 ?
O26 Mo3 Mo6 50.5(7) . . ?
O26 Mo3 O24 97.3(9) . . ?
O26 Mo3 O66 156.8(10) . . ?
O26 Mo3 O72 86.9(10) . . ?
O26 Mo3 O9 81.2(8) . . ?
O26 Mo3 Na5 108.4(7) . 4_565 ?
O66 Mo3 Mo6 138.1(7) . . ?
O66 Mo3 O24 91.5(9) . . ?
O66 Mo3 O72 77.6(10) . . ?
O66 Mo3 O9 78.5(8) . . ?
O66 Mo3 Na5 48.5(8) . 4_565 ?
O68 Mo3 Mo6 98.7(7) . . ?
O68 Mo3 O24 101.0(10) . . ?
O68 Mo3 O26 100.7(10) . . ?
O68 Mo3 O66 98.7(10) . . ?
O68 Mo3 O72 98.4(10) . . ?
O68 Mo3 O9 174.9(9) . . ?
O68 Mo3 Na5 130.9(8) . 4_565 ?
O72 Mo3 Mo6 136.4(7) . . ?
O72 Mo3 O9 76.9(8) . . ?
O72 Mo3 Na5 46.5(7) . 4_565 ?
O9 Mo3 Mo6 86.2(5) . . ?
O9 Mo3 Na5 44.2(5) . 4_565 ?
Mo1 Mo4 Na6 132.8(2) . . ?
O1 Mo4 Mo1 48.7(6) . . ?
O1 Mo4 O4 87.7(8) . . ?
O1 Mo4 O6 79.4(7) . . ?
O1 Mo4 O8 95.4(8) . . ?
O1 Mo4 O20 156.0(8) . . ?
O1 Mo4 Na6 110.1(6) . . ?
O4 Mo4 Mo1 135.7(5) . . ?
O4 Mo4 O6 78.7(6) . . ?
O4 Mo4 O20 77.7(8) . . ?
O4 Mo4 Na6 46.5(6) . . ?
O6 Mo4 Mo1 84.8(4) . . ?
O6 Mo4 Na6 48.0(5) . . ?
O8 Mo4 Mo1 47.8(6) . . ?
O8 Mo4 O4 160.1(8) . . ?
O8 Mo4 O6 82.6(7) . . ?
O8 Mo4 O20 92.5(8) . . ?
O8 Mo4 Na6 114.8(6) . . ?
O20 Mo4 Mo1 138.9(6) . . ?
O20 Mo4 O6 79.2(7) . . ?
O20 Mo4 Na6 46.4(6) . . ?
O62 Mo4 Mo1 98.4(7) . . ?
O62 Mo4 O1 101.5(9) . . ?
O62 Mo4 O4 97.7(8) . . ?
O62 Mo4 O6 176.3(8) . . ?
O62 Mo4 O8 100.8(9) . . ?
O62 Mo4 O20 99.3(9) . . ?
O62 Mo4 Na6 128.7(8) . . ?
Mo2 Mo5 Na3 132.2(3) . . ?
O40 Mo5 Mo2 87.2(6) . . ?
O40 Mo5 Na3 45.0(6) . . ?
O48 Mo5 Mo2 47.2(8) . . ?
O48 Mo5 O40 82.5(8) . . ?
O48 Mo5 O60 90.5(12) . . ?
O48 Mo5 O78 96.2(11) . . ?
O48 Mo5 O84 158.2(9) . . ?
O48 Mo5 Na3 112.7(7) . . ?
O60 Mo5 Mo2 136.6(8) . . ?
O60 Mo5 O40 76.3(9) . . ?
O60 Mo5 O84 77.1(12) . . ?
O60 Mo5 Na3 46.5(8) . . ?
O78 Mo5 Mo2 49.8(8) . . ?
O78 Mo5 O40 84.3(9) . . ?
O78 Mo5 O60 158.5(10) . . ?
O78 Mo5 O84 89.7(11) . . ?
O78 Mo5 Na3 112.4(8) . . ?
O84 Mo5 Mo2 138.1(8) . . ?
O84 Mo5 O40 77.2(8) . . ?
O84 Mo5 Na3 46.2(8) . . ?
O94 Mo5 Mo2 98.1(10) . . ?
O94 Mo5 O40 174.4(11) . . ?
O94 Mo5 O48 99.9(11) . . ?
O94 Mo5 O60 98.6(12) . . ?
O94 Mo5 O78 100.4(12) . . ?
O94 Mo5 O84 99.6(11) . . ?
O94 Mo5 Na3 129.7(10) . . ?
Mo3 Mo6 Na4 129.6(3) . . ?
O24 Mo6 Mo3 50.5(7) . . ?
O24 Mo6 O26 97.5(9) . . ?
O24 Mo6 O28 86.0(9) . . ?
O24 Mo6 O32 155.9(8) . . ?
O24 Mo6 O58 82.1(8) . . ?
O24 Mo6 Na4 109.4(6) . . ?
O26 Mo6 Mo3 47.9(6) . . ?
O26 Mo6 O28 159.7(8) . . ?
O26 Mo6 O32 91.1(10) . . ?
O26 Mo6 O58 82.0(8) . . ?
O26 Mo6 Na4 111.2(6) . . ?
O28 Mo6 Mo3 135.6(6) . . ?
O28 Mo6 O58 78.7(8) . . ?
O28 Mo6 Na4 49.4(7) . . ?
O32 Mo6 Mo3 137.6(7) . . ?
O32 Mo6 O28 78.6(9) . . ?
O32 Mo6 O58 76.8(8) . . ?
O32 Mo6 Na4 46.7(6) . . ?
O56 Mo6 Mo3 98.3(7) . . ?
O56 Mo6 O24 100.1(9) . . ?
O56 Mo6 O26 101.1(10) . . ?
O56 Mo6 O28 97.9(10) . . ?
O56 Mo6 O32 100.2(9) . . ?
O56 Mo6 O58 175.8(9) . . ?
O56 Mo6 Na4 132.0(8) . . ?
O58 Mo6 Mo3 85.8(5) . . ?
O58 Mo6 Na4 43.8(5) . . ?
O1 V1 O79 86.5(9) . . ?
O1 V1 Na2 129.4(6) . . ?
O36 V1 O1 172.6(8) 3_655 . ?
O36 V1 O44 90.4(9) 3_655 . ?
O36 V1 O50 84.7(8) 3_655 . ?
O36 V1 O79 88.7(10) 3_655 . ?
O36 V1 Na2 47.4(6) 3_655 . ?
O44 V1 O1 94.6(9) . . ?
O44 V1 O50 169.0(11) . . ?
O44 V1 O79 83.2(11) . . ?
O44 V1 Na2 134.2(8) . . ?
O50 V1 O1 89.4(8) . . ?
O50 V1 O79 86.8(10) . . ?
O50 V1 Na2 45.6(6) . . ?
O76 V1 O1 92.2(9) . . ?
O76 V1 O36 92.9(9) . 3_655 ?
O76 V1 O44 93.2(11) . . ?
O76 V1 O50 96.9(10) . . ?
O76 V1 O79 176.1(10) . . ?
O76 V1 Na2 75.5(7) . . ?
O79 V1 Na2 108.1(8) . . ?
O7 V2 O100 176.5(11) 4_565 . ?
O7 V2 Na4 56.0(8) 4_565 4_565 ?
O7 V2 Na5 122.4(9) 4_565 4_565 ?
O7 V2 Na6 137.8(8) 4_565 . ?
O7 V2 Na7 40.5(8) 4_565 4_565 ?
O86 V2 O7 90.1(10) 4_565 4_565 ?
O86 V2 O100 93.3(10) 4_565 . ?
O86 V2 Na4 137.1(8) 4_565 4_565 ?
O86 V2 Na5 41.1(7) 4_565 4_565 ?
O86 V2 Na6 121.2(8) 4_565 . ?
O86 V2 Na7 57.6(7) 4_565 4_565 ?
O96 V2 O7 88.7(11) . 4_565 ?
O96 V2 O86 176.6(12) . 4_565 ?
O96 V2 O100 87.9(11) . . ?
O96 V2 Na4 40.1(8) . 4_565 ?
O96 V2 Na5 138.0(8) . 4_565 ?
O96 V2 Na6 58.4(8) . . ?
O96 V2 Na7 120.0(9) . 4_565 ?
O100 V2 Na4 120.7(8) . 4_565 ?
O100 V2 Na5 60.3(8) . 4_565 ?
O100 V2 Na6 39.1(7) . . ?
O100 V2 Na7 141.8(8) . 4_565 ?
O13 V2 O7 90.5(14) . 4_565 ?
O13 V2 O86 83.8(13) . 4_565 ?
O13 V2 O96 93.1(13) . . ?
O13 V2 O100 89.1(13) . . ?
O13 V2 Na4 72.4(11) . 4_565 ?
O13 V2 Na5 62.2(11) . 4_565 ?
O13 V2 Na6 67.9(11) . . ?
O13 V2 Na7 65.6(12) . 4_565 ?
O99 V2 O7 87.2(13) . 4_565 ?
O99 V2 O86 89.1(13) . 4_565 ?
O99 V2 O96 93.9(13) . . ?
O99 V2 O100 93.7(12) . . ?
O99 V2 O13 172.6(15) . . ?
O99 V2 Na4 111.8(11) . 4_565 ?
O99 V2 Na5 113.4(11) . 4_565 ?
O99 V2 Na6 118.1(11) . . ?
O99 V2 Na7 108.5(11) . 4_565 ?
Na4 V2 Na6 82.4(4) 4_565 . ?
Na4 V2 Na7 80.0(4) 4_565 4_565 ?
Na5 V2 Na4 134.6(5) 4_565 4_565 ?
Na5 V2 Na6 80.2(4) 4_565 . ?
Na5 V2 Na7 82.2(4) 4_565 4_565 ?
Na7 V2 Na6 133.3(4) 4_565 . ?
O42 V3 O59 92.9(13) 3_655 . ?
O42 V3 O78 172.9(11) 3_655 . ?
O42 V3 O92 83.9(12) 3_655 . ?
O42 V3 O11 91.8(11) 3_655 . ?
O42 V3 O37 96.8(12) 3_655 . ?
O42 V3 Na8 44.3(9) 3_655 . ?
O59 V3 O78 92.5(13) . . ?
O59 V3 O92 173.3(13) . . ?
O59 V3 O11 88.0(13) . . ?
O59 V3 O37 84.7(14) . . ?
O59 V3 Na8 133.7(10) . . ?
O78 V3 O92 90.2(13) . . ?
O78 V3 O11 92.9(11) . . ?
O78 V3 O37 79.2(12) . . ?
O78 V3 Na8 131.9(10) . . ?
O92 V3 O11 97.9(11) . . ?
O92 V3 O37 89.8(12) . . ?
O92 V3 Na8 45.6(9) . . ?
O11 V3 O37 169.0(13) . . ?
O11 V3 Na8 78.6(9) . . ?
O37 V3 Na8 112.3(10) . . ?
O8 V4 O15 86.6(9) . . ?
O8 V4 O18 87.4(9) . . ?
O8 V4 Na2 130.0(7) . 4_565 ?
O15 V4 Na2 102.9(7) . 4_565 ?
O18 V4 O15 81.9(10) . . ?
O18 V4 Na2 47.1(6) . 4_565 ?
O38 V4 O8 172.7(10) 4_565 . ?
O38 V4 O15 88.2(9) 4_565 . ?
O38 V4 O18 86.9(9) 4_565 . ?
O38 V4 O88 93.3(9) 4_565 . ?
O38 V4 Na2 46.7(7) 4_565 4_565 ?
O70 V4 O8 94.9(9) . . ?
O70 V4 O15 85.3(10) . . ?
O70 V4 O18 166.8(10) . . ?
O70 V4 O38 89.7(10) . 4_565 ?
O70 V4 O88 95.2(11) . . ?
O70 V4 Na2 134.4(8) . 4_565 ?
O88 V4 O8 91.9(9) . . ?
O88 V4 O15 178.4(10) . . ?
O88 V4 O18 97.7(10) . . ?
O88 V4 Na2 77.9(7) . 4_565 ?
O21 V5 Na8 101.7(9) . 4_565 ?
O26 V5 O21 88.3(11) . . ?
O26 V5 O98 87.1(10) . . ?
O26 V5 Na8 129.3(8) . 4_565 ?
O63 V5 O21 178.6(12) . . ?
O63 V5 O26 93.1(10) . . ?
O63 V5 O98 96.6(11) . . ?
O63 V5 Na8 77.1(9) . 4_565 ?
O80 V5 O21 83.5(12) . . ?
O80 V5 O26 170.3(11) . . ?
O80 V5 O63 95.1(12) . . ?
O80 V5 O98 86.9(11) . . ?
O80 V5 Na8 48.3(9) . 4_565 ?
O98 V5 O21 83.0(10) . . ?
O98 V5 Na8 46.3(9) . 4_565 ?
O110 V5 O21 84.2(11) . . ?
O110 V5 O26 95.1(12) . . ?
O110 V5 O63 96.0(12) . . ?
O110 V5 O80 89.2(12) . . ?
O110 V5 O98 167.0(12) . . ?
O110 V5 Na8 135.0(11) . 4_565 ?
O54 V6 O54 89.75(12) 4_565 . ?
O54 V6 O54 172.5(17) 4_565 3_655 ?
O54 V6 O54 89.76(11) 3_655 2_665 ?
O54 V6 O54 89.76(12) 3_655 . ?
O54 V6 O54 89.76(12) 4_565 2_665 ?
O54 V6 O54 172.5(17) 2_665 . ?
O54 V6 O228 93.7(9) 3_655 . ?
O54 V6 O228 93.7(9) 2_665 . ?
O54 V6 O228 93.7(9) 4_565 . ?
O54 V6 O228 93.7(9) . . ?
O54 V6 Na1 118.6(8) 4_565 . ?
O54 V6 Na1 136.3(8) 4_565 3_655 ?
O54 V6 Na1 57.7(7) 2_665 3_655 ?
O54 V6 Na1 57.7(7) 3_655 . ?
O54 V6 Na1 136.3(8) . 2_665 ?
O54 V6 Na1 39.0(7) 4_565 4_565 ?
O54 V6 Na1 57.7(7) . 4_565 ?
O54 V6 Na1 39.0(7) . . ?
O54 V6 Na1 57.7(7) 4_565 2_665 ?
O54 V6 Na1 118.6(8) . 3_655 ?
O54 V6 Na1 118.6(8) 3_655 2_665 ?
O54 V6 Na1 136.3(8) 3_655 4_565 ?
O54 V6 Na1 39.0(7) 2_665 2_665 ?
O54 V6 Na1 39.0(7) 3_655 3_655 ?
O54 V6 Na1 118.6(8) 2_665 4_565 ?
O54 V6 Na1 136.3(8) 2_665 . ?
O228 V6 Na1 114.9(3) . 3_655 ?
O228 V6 Na1 114.9(3) . 2_665 ?
O228 V6 Na1 114.9(3) . 4_565 ?
O228 V6 Na1 114.9(3) . . ?
O17 V6 O54 86.3(9) . 4_565 ?
O17 V6 O54 86.3(9) . 2_665 ?
O17 V6 O54 86.3(9) . . ?
O17 V6 O54 86.3(9) . 3_655 ?
O17 V6 O228 180.0 . . ?
O17 V6 Na1 65.1(3) . 2_665 ?
O17 V6 Na1 65.1(3) . 4_565 ?
O17 V6 Na1 65.1(3) . 3_655 ?
O17 V6 Na1 65.1(3) . . ?
Na1 V6 Na1 79.8(3) 4_565 2_665 ?
Na1 V6 Na1 79.8(3) 3_655 . ?
Na1 V6 Na1 130.2(7) 2_665 . ?
Na1 V6 Na1 130.2(7) 4_565 3_655 ?
Na1 V6 Na1 79.8(3) 2_665 3_655 ?
Na1 V6 Na1 79.8(3) 4_565 . ?
O111 V7 O111 89.91(8) 3_655 2_665 ?
O111 V7 O111 175.5(18) 2_665 . ?
O111 V7 O111 89.91(8) 4_565 2_665 ?
O111 V7 O111 175.5(18) 3_655 4_565 ?
O111 V7 O111 89.91(8) 4_565 . ?
O111 V7 O111 89.91(8) 3_655 . ?
O111 V7 Na3 135.4(9) 3_655 2_665 ?
O111 V7 Na3 55.9(9) 3_655 3_655 ?
O111 V7 Na3 55.9(9) . . ?
O111 V7 Na3 41.8(9) 2_665 3_655 ?
O111 V7 Na3 121.9(9) . 2_665 ?
O111 V7 Na3 135.4(9) 4_565 . ?
O111 V7 Na3 121.9(9) 3_655 4_565 ?
O111 V7 Na3 41.8(9) 4_565 2_665 ?
O111 V7 Na3 55.9(9) 4_565 4_565 ?
O111 V7 Na3 121.9(9) 4_565 3_655 ?
O111 V7 Na3 135.4(9) 2_665 4_565 ?
O111 V7 Na3 121.9(9) 2_665 . ?
O111 V7 Na3 41.8(9) . 4_565 ?
O111 V7 Na3 55.9(9) 2_665 2_665 ?
O111 V7 Na3 41.8(9) 3_655 . ?
O111 V7 Na3 135.4(9) . 3_655 ?
O5 V7 O111 92.3(9) . . ?
O5 V7 O111 92.3(9) . 4_565 ?
O5 V7 O111 92.3(9) . 2_665 ?
O5 V7 O111 92.3(9) . 3_655 ?
O5 V7 O45 180.000(11) . . ?
O5 V7 Na3 114.5(4) . 2_665 ?
O5 V7 Na3 114.5(3) . 3_655 ?
O5 V7 Na3 114.5(3) . 4_565 ?
O5 V7 Na3 114.5(3) . . ?
O45 V7 O111 87.7(9) . 4_565 ?
O45 V7 O111 87.7(9) . 2_665 ?
O45 V7 O111 87.7(9) . . ?
O45 V7 O111 87.7(9) . 3_655 ?
O45 V7 Na3 65.5(3) . . ?
O45 V7 Na3 65.5(3) . 3_655 ?
O45 V7 Na3 65.5(3) . 2_665 ?
O45 V7 Na3 65.5(3) . 4_565 ?
Na3 V7 Na3 131.0(7) 4_565 3_655 ?
Na3 V7 Na3 131.1(7) 2_665 . ?
Na3 V7 Na3 80.1(3) 2_665 4_565 ?
Na3 V7 Na3 80.1(3) 4_565 . ?
Na3 V7 Na3 80.1(3) 3_655 . ?
Na3 V7 Na3 80.1(3) 2_665 3_655 ?
O2 V8 O48 93.6(11) . . ?
O2 V8 O61 94.4(13) . . ?
O2 V8 O74 94.8(12) . 4_565 ?
O2 V8 O108 101.5(13) . . ?
O2 V8 O3 175.7(13) . . ?
O2 V8 Na8 76.9(10) . 4_565 ?
O48 V8 O3 82.3(11) . . ?
O48 V8 Na8 128.6(10) . 4_565 ?
O61 V8 O48 94.3(13) . . ?
O61 V8 O74 92.2(13) . 4_565 ?
O61 V8 O108 164.0(13) . . ?
O61 V8 O3 84.6(12) . . ?
O61 V8 Na8 136.3(11) . 4_565 ?
O74 V8 O48 169.0(12) 4_565 . ?
O74 V8 O108 85.9(13) 4_565 . ?
O74 V8 O3 89.5(11) 4_565 . ?
O74 V8 Na8 47.2(9) 4_565 4_565 ?
O108 V8 O48 85.4(12) . . ?
O108 V8 O3 79.5(12) . . ?
O108 V8 Na8 49.0(9) . 4_565 ?
O3 V8 Na8 106.6(9) . 4_565 ?
O22 V9 O41 91.2(10) . . ?
O22 V9 O102 89.1(9) . . ?
O22 V9 Na2 42.2(6) . . ?
O24 V9 O22 171.6(9) . . ?
O24 V9 O41 89.3(10) . . ?
O24 V9 O52 85.5(9) . . ?
O24 V9 O102 90.4(9) . . ?
O24 V9 Na2 129.7(7) . . ?
O41 V9 Na2 104.1(8) . . ?
O52 V9 O22 86.2(9) . . ?
O52 V9 O41 82.1(9) . . ?
O52 V9 O102 98.7(9) . . ?
O52 V9 Na2 50.1(7) . . ?
O64 V9 O22 91.0(10) . . ?
O64 V9 O24 97.4(10) . . ?
O64 V9 O41 85.1(10) . . ?
O64 V9 O52 166.9(10) . . ?
O64 V9 O102 94.1(10) . . ?
O64 V9 Na2 131.4(9) . . ?
O102 V9 O41 179.2(11) . . ?
O102 V9 Na2 76.7(7) . . ?
O12 P1 C26 105.6(9) . . ?
O12 P1 Na2 132.5(9) . 4_565 ?
O18 P1 O12 111.6(12) . . ?
O18 P1 C26 109.5(10) . . ?
O18 P1 O36 112.9(12) . . ?
O18 P1 Na2 55.5(8) . 4_565 ?
C26 P1 Na2 121.9(4) . 4_565 ?
O36 P1 O12 112.1(10) . . ?
O36 P1 C26 104.5(9) . . ?
O36 P1 Na2 57.4(8) . 4_565 ?
C24 P2 Na8 118.2(6) . 4_565 ?
O34 P2 C24 106.6(12) . . ?
O34 P2 O80 110.9(17) . . ?
O34 P2 O108 112.0(18) . . ?
O34 P2 Na8 134.5(11) . 4_565 ?
O80 P2 C24 101.3(12) . . ?
O80 P2 O108 114.6(18) . . ?
O80 P2 Na8 54.2(12) . 4_565 ?
O108 P2 C24 110.6(12) . . ?
O108 P2 Na8 60.4(12) . 4_565 ?
C37 P3 Na8 122.9(6) . 4_565 ?
O42 P3 C37 110.0(10) . . ?
O42 P3 O72 110.9(14) . . ?
O42 P3 Na8 57.9(11) . 4_565 ?
O72 P3 C37 103.4(10) . . ?
O72 P3 Na8 133.7(10) . 4_565 ?
O98 P3 C37 108.9(11) . . ?
O98 P3 O42 112.2(17) . . ?
O98 P3 O72 111.0(14) . . ?
O98 P3 Na8 54.5(12) . 4_565 ?
O4 P4 C66 104.7(8) . . ?
O4 P4 Na2 132.4(7) . . ?
O22 P4 O4 114.6(13) . . ?
O22 P4 O50 107.1(12) . . ?
O22 P4 C66 106.8(8) . . ?
O22 P4 Na2 52.3(9) . . ?
O50 P4 O4 110.2(11) . . ?
O50 P4 C66 113.5(9) . . ?
O50 P4 Na2 54.9(8) . . ?
C66 P4 Na2 122.8(4) . . ?
C35 P5 Na8 118.4(6) . . ?
O74 P5 C35 107.4(11) . . ?
O74 P5 O84 108.6(17) . . ?
O74 P5 Na8 56.8(13) . . ?
O84 P5 C35 108.0(11) . . ?
O84 P5 Na8 133.5(10) . . ?
O92 P5 C35 107.9(12) . . ?
O92 P5 O74 109.9(19) . . ?
O92 P5 O84 114.8(18) . . ?
O92 P5 Na8 53.3(13) . . ?
O28 P6 O52 108.9(13) . . ?
O28 P6 C47 108.8(10) . . ?
O28 P6 Na2 134.6(8) . . ?
O38 P6 O28 112.6(12) . . ?
O38 P6 O52 114.1(14) . . ?
O38 P6 C47 102.2(9) . . ?
O38 P6 Na2 53.3(9) . . ?
O52 P6 C47 110.0(9) . . ?
O52 P6 Na2 60.9(10) . . ?
C47 P6 Na2 116.2(6) . . ?
C7 P7 Na4 122.2(6) . . ?
C7 P7 Na7 123.8(7) . . ?
O7 P7 C7 105.5(12) . . ?
O7 P7 O32 109.1(16) . . ?
O7 P7 O110 108.6(18) . . ?
O7 P7 Na4 62.8(12) . . ?
O7 P7 Na7 47.5(12) . . ?
O32 P7 C7 105.5(11) . . ?
O32 P7 O110 112.0(15) . . ?
O32 P7 Na4 46.6(9) . . ?
O32 P7 Na7 128.4(10) . . ?
O110 P7 C7 115.8(11) . . ?
O110 P7 Na4 121.6(11) . . ?
O110 P7 Na7 61.1(12) . . ?
Na7 P7 Na4 90.8(5) . . ?
O10 P8 O54 110.2(14) . . ?
O10 P8 C49 106.0(11) . . ?
O10 P8 Na1 45.2(8) . 4_565 ?
O10 P8 Na1 125.1(10) . . ?
O44 P8 O10 113.5(14) . . ?
O44 P8 O54 106.1(15) . . ?
O44 P8 C49 110.0(12) . . ?
O44 P8 Na1 124.2(12) . 4_565 ?
O44 P8 Na1 58.6(11) . . ?
O54 P8 C49 111.1(11) . . ?
O54 P8 Na1 47.6(10) . . ?
O54 P8 Na1 65.1(10) . 4_565 ?
C49 P8 Na1 124.8(6) . 4_565 ?
C49 P8 Na1 128.3(6) . . ?
Na1 P8 Na1 91.2(5) . 4_565 ?
C18 P9 Na5 123.7(7) . . ?
C18 P9 Na7 129.8(6) . . ?
O59 P9 C18 109.3(14) . . ?
O59 P9 Na5 59.6(13) . . ?
O59 P9 Na7 120.0(14) . . ?
O82 P9 C18 107.3(13) . . ?
O82 P9 O59 111(2) . . ?
O82 P9 O86 110.8(18) . . ?
O82 P9 Na5 128.7(12) . . ?
O82 P9 Na7 47.0(12) . . ?
O86 P9 C18 113.7(14) . . ?
O86 P9 O59 104.4(18) . . ?
O86 P9 Na5 45.0(12) . . ?
O86 P9 Na7 64.0(12) . . ?
Na5 P9 Na7 91.0(5) . . ?
O20 P10 C55 101.7(9) . . ?
O20 P10 Na4 128.7(9) . 4_565 ?
O20 P10 Na6 44.3(8) . . ?
O70 P10 O20 113.9(14) . . ?
O70 P10 O96 110.8(15) . . ?
O70 P10 C55 114.3(9) . . ?
O70 P10 Na4 62.6(10) . 4_565 ?
O70 P10 Na6 125.7(9) . . ?
O96 P10 O20 108.9(14) . . ?
O96 P10 C55 106.6(11) . . ?
O96 P10 Na4 48.2(11) . 4_565 ?
O96 P10 Na6 64.9(11) . . ?
C55 P10 Na4 127.3(6) . 4_565 ?
C55 P10 Na6 118.6(5) . . ?
Na4 P10 Na6 93.2(4) 4_565 . ?
O60 P11 O61 111(2) . . ?
O60 P11 C68 108.0(13) . . ?
O60 P11 Na3 45.1(12) . . ?
O60 P11 Na3 127.2(12) . 4_565 ?
O61 P11 C68 110.4(13) . . ?
O61 P11 Na3 58.9(13) . 4_565 ?
O61 P11 Na3 121.5(13) . . ?
O111 P11 O60 109(2) . . ?
O111 P11 O61 110(2) . . ?
O111 P11 C68 108.3(15) . . ?
O111 P11 Na3 51.2(15) . 4_565 ?
O111 P11 Na3 64.5(15) . . ?
C68 P11 Na3 127.0(7) . . ?
C68 P11 Na3 124.4(8) . 4_565 ?
Na3 P11 Na3 93.0(7) 4_565 . ?
C6 P12 Na5 129.7(6) . 4_565 ?
C6 P12 Na6 126.6(6) . . ?
O64 P12 C6 105.4(10) . . ?
O64 P12 Na5 123.5(9) . 4_565 ?
O64 P12 Na6 60.9(9) . . ?
O66 P12 C6 106.5(10) . . ?
O66 P12 O64 110.4(13) . . ?
O66 P12 Na5 48.7(10) . 4_565 ?
O66 P12 Na6 126.8(10) . . ?
O100 P12 C6 112.2(11) . . ?
O100 P12 O64 104.9(15) . . ?
O100 P12 O66 116.9(17) . . ?
O100 P12 Na5 68.3(12) . 4_565 ?
O100 P12 Na6 44.3(11) . . ?
Na6 P12 Na5 90.0(4) . 4_565 ?
Mo1 O1 V1 138.4(11) . . ?
Mo4 O1 Mo1 83.3(7) . . ?
Mo4 O1 V1 138.1(10) . . ?
C2 C1 H1 120.0 . . ?
C2 C1 C6 120.0 . . ?
C6 C1 H1 120.0 . . ?
C1 C2 H2 120.0 . . ?
C3 C2 C1 120.0 . . ?
C3 C2 H2 120.0 . . ?
C2 C3 H3 120.0 . . ?
C2 C3 C4 120.0 . . ?
C4 C3 H3 120.0 . . ?
C3 C4 H4 120.0 . . ?
C5 C4 C3 120.0 . . ?
C5 C4 H4 120.0 . . ?
C4 C5 H5 120.0 . . ?
C6 C5 C4 120.0 . . ?
C6 C5 H5 120.0 . . ?
C1 C6 P12 120.1(5) . . ?
C5 C6 P12 119.9(5) . . ?
C5 C6 C1 120.0 . . ?
Mo4 O4 Na6 97.6(8) . . ?
P4 O4 Mo4 126.3(13) . . ?
P4 O4 Na6 136.1(12) . . ?
C8 C7 P7 119.9(5) . . ?
C8 C7 C12 120.0 . . ?
C12 C7 P7 120.1(5) . . ?
C7 C8 H8 120.0 . . ?
C9 C8 C7 120.0 . . ?
C9 C8 H8 120.0 . . ?
C8 C9 H9 120.0 . . ?
C10 C9 C8 120.0 . . ?
C10 C9 H9 120.0 . . ?
C9 C10 H10 120.0 . . ?
C9 C10 C11 120.0 . . ?
C11 C10 H10 120.0 . . ?
C10 C11 H11 120.0 . . ?
C12 C11 C10 120.0 . . ?
C12 C11 H11 120.0 . . ?
C7 C12 H12 120.0 . . ?
C11 C12 C7 120.0 . . ?
C11 C12 H12 120.0 . . ?
Mo4 O6 Na6 90.1(6) . . ?
C73 O6 Mo4 117.9(12) . . ?
C73 O6 Na6 151.9(12) . . ?
V2 O7 Na4 84.2(9) 3_655 . ?
V2 O7 Na7 100.6(12) 3_655 . ?
P7 O7 V2 154.4(19) . 3_655 ?
P7 O7 Na4 90.0(13) . . ?
P7 O7 Na7 104.0(16) . . ?
Na7 O7 Na4 118.5(11) . . ?
Mo1 O8 Mo4 83.4(8) . . ?
Mo1 O8 V4 138.4(11) . . ?
Mo4 O8 V4 138.1(11) . . ?
Mo1 O10 Na1 95.3(8) . 4_565 ?
P8 O10 Mo1 141.3(12) . . ?
P8 O10 Na1 109.0(11) . 4_565 ?
Mo1 O12 Na1 95.4(7) . 4_565 ?
P1 O12 Mo1 124.7(10) . . ?
P1 O12 Na1 139.6(11) . 4_565 ?
Mo1 O16 Na1 94.1(7) . 4_565 ?
C73 O16 Mo1 118.0(12) . . ?
C73 O16 Na1 146.8(12) . 4_565 ?
V4 O18 Na2 98.5(9) . 4_565 ?
P1 O18 V4 134.3(12) . . ?
P1 O18 Na2 97.4(11) . 4_565 ?
C14 C13 H13 120.0 . . ?
C14 C13 C18 120.0 . . ?
C18 C13 H13 120.0 . . ?
C13 C14 H14 120.0 . . ?
C13 C14 C15 120.0 . . ?
C15 C14 H14 120.0 . . ?
C14 C15 H15 120.0 . . ?
C14 C15 C16 120.0 . . ?
C16 C15 H15 120.0 . . ?
C15 C16 H16 120.0 . . ?
C17 C16 C15 120.0 . . ?
C17 C16 H16 120.0 . . ?
C16 C17 H17 120.0 . . ?
C16 C17 C18 120.0 . . ?
C18 C17 H17 120.0 . . ?
C13 C18 P9 120.0(5) . . ?
C17 C18 P9 120.0(5) . . ?
C17 C18 C13 120.0 . . ?
Mo4 O20 Na6 97.4(7) . . ?
P10 O20 Mo4 138.0(13) . . ?
P10 O20 Na6 109.7(12) . . ?
V9 O22 Na2 105.9(9) . . ?
P4 O22 V9 143.3(13) . . ?
P4 O22 Na2 100.6(12) . . ?
C20 C19 H19 120.0 . . ?
C20 C19 C24 120.0 . . ?
C24 C19 H19 120.0 . . ?
C19 C20 H20 120.0 . . ?
C21 C20 C19 120.0 . . ?
C21 C20 H20 120.0 . . ?
C20 C21 H21 120.0 . . ?
C20 C21 C22 120.0 . . ?
C22 C21 H21 120.0 . . ?
C21 C22 H22 120.0 . . ?
C23 C22 C21 120.0 . . ?
C23 C22 H22 120.0 . . ?
C22 C23 H23 120.0 . . ?
C22 C23 C24 120.0 . . ?
C24 C23 H23 120.0 . . ?
C19 C24 P2 120.1(5) . . ?
C23 C24 P2 119.9(5) . . ?
C23 C24 C19 120.0 . . ?
Mo6 O24 Mo3 81.7(9) . . ?
V9 O24 Mo3 136.6(10) . . ?
V9 O24 Mo6 141.7(12) . . ?
C26 C25 H25 120.0 . . ?
C26 C25 C30 120.0 . . ?
C30 C25 H25 120.0 . . ?
C25 C26 P1 120.2(5) . . ?
C25 C26 C27 120.0 . . ?
C27 C26 P1 119.8(5) . . ?
C26 C27 H27 120.0 . . ?
C28 C27 C26 120.0 . . ?
C28 C27 H27 120.0 . . ?
C27 C28 H28 120.0 . . ?
C29 C28 C27 120.0 . . ?
C29 C28 H28 120.0 . . ?
C28 C29 H29 120.0 . . ?
C30 C29 C28 120.0 . . ?
C30 C29 H29 120.0 . . ?
C25 C30 H30 120.0 . . ?
C29 C30 C25 120.0 . . ?
C29 C30 H30 120.0 . . ?
Mo3 O26 Mo6 81.6(10) . . ?
Mo3 O26 V5 140.7(12) . . ?
V5 O26 Mo6 137.6(11) . . ?
Mo6 O28 Na4 93.4(10) . . ?
P6 O28 Mo6 128.1(12) . . ?
P6 O28 Na4 138.0(13) . . ?
Mo2 O30 Na7 92.5(8) . . ?
C77 O30 Mo2 117.5(14) . . ?
C77 O30 Na7 149.6(15) . . ?
Mo6 O32 Na4 96.6(10) . . ?
P7 O32 Mo6 139.8(15) . . ?
P7 O32 Na4 107.0(12) . . ?
C32 C31 H31 120.0 . . ?
C32 C31 C36 120.0 . . ?
C36 C31 H31 120.0 . . ?
C31 C32 H32 120.0 . . ?
C31 C32 C33 120.0 . . ?
C33 C32 H32 120.0 . . ?
C32 C33 H33 120.0 . . ?
C32 C33 C34 120.0 . . ?
C34 C33 H33 120.0 . . ?
C33 C34 H34 120.0 . . ?
C35 C34 C33 120.0 . . ?
C35 C34 H34 120.0 . . ?
C34 C35 P5 120.3(5) . . ?
C34 C35 C36 120.0 . . ?
C36 C35 P5 119.7(5) . . ?
C31 C36 H36 120.0 . . ?
C35 C36 C31 120.0 . . ?
C35 C36 H36 120.0 . . ?
Mo2 O34 Na7 92.0(10) . . ?
P2 O34 Mo2 126.2(16) . . ?
P2 O34 Na7 141.1(16) . . ?
C38 C37 P3 120.2(5) . . ?
C38 C37 C42 120.0 . . ?
C42 C37 P3 119.8(5) . . ?
C37 C38 H38 120.0 . . ?
C39 C38 C37 120.0 . . ?
C39 C38 H38 120.0 . . ?
C38 C39 H39 120.0 . . ?
C38 C39 C40 120.0 . . ?
C40 C39 H39 120.0 . . ?
C39 C40 H40 120.0 . . ?
C41 C40 C39 120.0 . . ?
C41 C40 H40 120.0 . . ?
C40 C41 H41 120.0 . . ?
C40 C41 C42 120.0 . . ?
C42 C41 H41 120.0 . . ?
C37 C42 H42 120.0 . . ?
C41 C42 C37 120.0 . . ?
C41 C42 H42 120.0 . . ?
V1 O36 Na2 100.2(8) 4_565 4_565 ?
P1 O36 V1 139.2(11) . 4_565 ?
P1 O36 Na2 93.5(10) . 4_565 ?
V4 O38 Na2 100.6(10) 3_655 . ?
P6 O38 V4 146.8(15) . 3_655 ?
P6 O38 Na2 100.2(11) . . ?
Mo5 O40 Na3 92.5(8) . . ?
C77 O40 Mo5 115.9(15) . . ?
C77 O40 Na3 151.4(15) . . ?
V3 O42 Na8 105.5(13) 4_565 4_565 ?
P3 O42 V3 146.0(15) . 4_565 ?
P3 O42 Na8 92.3(13) . 4_565 ?
V1 O44 Na1 114.0(13) . . ?
P8 O44 V1 138.9(16) . . ?
P8 O44 Na1 92.5(13) . . ?
Mo2 O48 Mo5 82.2(10) . . ?
Mo2 O48 V8 140.6(16) . . ?
V8 O48 Mo5 137.2(15) . . ?
V1 O50 Na2 101.5(8) . . ?
P4 O50 V1 134.0(12) . . ?
P4 O50 Na2 96.4(11) . . ?
V9 O52 Na2 97.7(8) . . ?
P6 O52 V9 133.0(13) . . ?
P6 O52 Na2 90.7(11) . . ?
V6 O54 Na1 104.7(12) . . ?
V6 O54 Na1 84.6(9) . 4_565 ?
P8 O54 V6 152.0(16) . . ?
P8 O54 Na1 102.9(13) . . ?
P8 O54 Na1 87.3(10) . 4_565 ?
Na1 O54 Na1 117.0(11) . 4_565 ?
Mo6 O58 Na4 95.5(7) . . ?
C75 O58 Mo6 118.1(13) . . ?
C75 O58 Na4 146.4(13) . . ?
V3 O59 Na5 116.4(15) . . ?
P9 O59 V3 144(2) . . ?
P9 O59 Na5 91.6(16) . . ?
Mo5 O60 Na3 95.9(12) . . ?
P11 O60 Mo5 142(2) . . ?
P11 O60 Na3 109.4(16) . . ?
V8 O61 Na3 117.0(15) . 4_565 ?
P11 O61 V8 143(2) . . ?
P11 O61 Na3 90.6(16) . 4_565 ?
V9 O64 Na6 115.6(11) . . ?
P12 O64 V9 141.1(15) . . ?
P12 O64 Na6 88.4(11) . . ?
Mo3 O66 Na5 95.1(10) . 4_565 ?
P12 O66 Mo3 141.9(15) . . ?
P12 O66 Na5 104.8(13) . 4_565 ?
V4 O70 Na4 118.0(11) . 4_565 ?
P10 O70 V4 141.4(16) . . ?
P10 O70 Na4 87.4(12) . 4_565 ?
Mo3 O72 Na5 96.6(10) . 4_565 ?
P3 O72 Mo3 125.2(13) . . ?
P3 O72 Na5 137.8(14) . 4_565 ?
C44 C43 H43 120.0 . . ?
C44 C43 C48 120.0 . . ?
C48 C43 H43 120.0 . . ?
C43 C44 H44 120.0 . . ?
C45 C44 C43 120.0 . . ?
C45 C44 H44 120.0 . . ?
C44 C45 H45 120.0 . . ?
C44 C45 C46 120.0 . . ?
C46 C45 H45 120.0 . . ?
C45 C46 H46 120.0 . . ?
C47 C46 C45 120.0 . . ?
C47 C46 H46 120.0 . . ?
C46 C47 P6 119.7(5) . . ?
C46 C47 C48 120.0 . . ?
C48 C47 P6 120.3(5) . . ?
C43 C48 H48 120.0 . . ?
C47 C48 C43 120.0 . . ?
C47 C48 H48 120.0 . . ?
V8 O74 Na8 101.6(12) 3_655 . ?
P5 O74 V8 143.0(17) . 3_655 ?
P5 O74 Na8 95.2(15) . . ?
C50 C49 P8 119.8(5) . . ?
C50 C49 C54 120.0 . . ?
C54 C49 P8 120.2(5) . . ?
C49 C50 H50 120.0 . . ?
C51 C50 C49 120.0 . . ?
C51 C50 H50 120.0 . . ?
C50 C51 H51 120.0 . . ?
C50 C51 C52 120.0 . . ?
C52 C51 H51 120.0 . . ?
C51 C52 H52 120.0 . . ?
C51 C52 C53 120.0 . . ?
C53 C52 H52 120.0 . . ?
C52 C53 H53 120.0 . . ?
C54 C53 C52 120.0 . . ?
C54 C53 H53 120.0 . . ?
C49 C54 H54 120.0 . . ?
C53 C54 C49 120.0 . . ?
C53 C54 H54 120.0 . . ?
Mo2 O78 Mo5 79.7(10) . . ?
V3 O78 Mo2 141.8(16) . . ?
V3 O78 Mo5 138.2(16) . . ?
V5 O80 Na8 98.0(11) . 4_565 ?
P2 O80 V5 144.0(16) . . ?
P2 O80 Na8 97.9(16) . 4_565 ?
Mo2 O82 Na7 91.2(11) . . ?
P9 O82 Mo2 141.1(19) . . ?
P9 O82 Na7 108.7(15) . . ?
Mo5 O84 Na3 95.8(11) . . ?
P5 O84 Mo5 121.7(15) . . ?
P5 O84 Na3 141.8(17) . . ?
V2 O86 Na5 99.3(12) 3_655 . ?
V2 O86 Na7 83.3(9) 3_655 . ?
P9 O86 V2 151.5(18) . 3_655 ?
P9 O86 Na5 108.1(17) . . ?
P9 O86 Na7 89.7(13) . . ?
Na5 O86 Na7 119.5(12) . . ?
V3 O92 Na8 101.6(13) . . ?
P5 O92 V3 135.5(18) . . ?
P5 O92 Na8 100.1(16) . . ?
V2 O96 Na4 103.0(14) . 4_565 ?
P10 O96 V2 154.1(17) . . ?
P10 O96 Na4 102.3(15) . 4_565 ?
V5 O98 Na8 98.7(11) . 4_565 ?
P3 O98 V5 133.5(14) . . ?
P3 O98 Na8 97.0(14) . 4_565 ?
V2 O100 Na6 102.0(11) . . ?
P12 O100 V2 148.9(17) . . ?
P12 O100 Na6 109.0(15) . . ?
V8 O108 Na8 98.8(11) . 4_565 ?
P2 O108 V8 131.5(16) . . ?
P2 O108 Na8 90.8(15) . 4_565 ?
V5 O110 Na7 117.6(14) . . ?
P7 O110 V5 142.7(19) . . ?
P7 O110 Na7 88.6(13) . . ?
V7 O111 Na3 85.7(11) . . ?
V7 O111 Na3 100.3(14) . 4_565 ?
P11 O111 V7 158(2) . . ?
P11 O111 Na3 101.0(19) . 4_565 ?
P11 O111 Na3 89.3(16) . . ?
Na3 O111 Na3 116.8(13) 4_565 . ?
C56 C55 P10 119.7(5) . . ?
C56 C55 C60 120.0 . . ?
C60 C55 P10 120.3(5) . . ?
C55 C56 H56 120.0 . . ?
C57 C56 C55 120.0 . . ?
C57 C56 H56 120.0 . . ?
C56 C57 H57 120.0 . . ?
C56 C57 C58 120.0 . . ?
C58 C57 H57 120.0 . . ?
C57 C58 H58 120.0 . . ?
C59 C58 C57 120.0 . . ?
C59 C58 H58 120.0 . . ?
C58 C59 H59 120.0 . . ?
C58 C59 C60 120.0 . . ?
C60 C59 H59 120.0 . . ?
C55 C60 H60 120.0 . . ?
C59 C60 C55 120.0 . . ?
C59 C60 H60 120.0 . . ?
C62 C61 H61 120.0 . . ?
C62 C61 C66 120.0 . . ?
C66 C61 H61 120.0 . . ?
C61 C62 H62 120.0 . . ?
C61 C62 C63 120.0 . . ?
C63 C62 H62 120.0 . . ?
C62 C63 H63 120.0 . . ?
C62 C63 C64 120.0 . . ?
C64 C63 H63 120.0 . . ?
C63 C64 H64 120.0 . . ?
C63 C64 C65 120.0 . . ?
C65 C64 H64 120.0 . . ?
C64 C65 H65 120.0 . . ?
C66 C65 C64 120.0 . . ?
C66 C65 H65 120.0 . . ?
C61 C66 P4 120.0(5) . . ?
C65 C66 P4 120.0(5) . . ?
C65 C66 C61 120.0 . . ?
C68 C67 H67 120.0 . . ?
C68 C67 C72 120.0 . . ?
C72 C67 H67 120.0 . . ?
C67 C68 P11 120.1(5) . . ?
C67 C68 C69 120.0 . . ?
C69 C68 P11 119.9(5) . . ?
C68 C69 H69 120.0 . . ?
C70 C69 C68 120.0 . . ?
C70 C69 H69 120.0 . . ?
C69 C70 H70 120.0 . . ?
C69 C70 C71 120.0 . . ?
C71 C70 H70 120.0 . . ?
C70 C71 H71 120.0 . . ?
C72 C71 C70 120.0 . . ?
C72 C71 H71 120.0 . . ?
C67 C72 H72 120.0 . . ?
C71 C72 C67 120.0 . . ?
C71 C72 H72 120.0 . . ?
Mo3 O9 Na5 94.0(7) . 4_565 ?
C75 O9 Mo3 115.8(13) . . ?
C75 O9 Na5 150.2(13) . 4_565 ?
O6 C73 O16 132.0(17) . . ?
O6 C73 C74 113.9(11) . . ?
O16 C73 C74 113.2(10) . . ?
C73 C74 H74A 109.5 . . ?
C73 C74 H74B 109.5 . . ?
C73 C74 H74C 109.5 . . ?
H74A C74 H74B 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
O58 C75 C78 112.9(11) . . ?
O9 C75 O58 134.0(16) . . ?
O9 C75 C78 113.0(11) . . ?
H76A C76 H76B 109.5 . . ?
H76A C76 H76C 109.5 . . ?
H76B C76 H76C 109.5 . . ?
C77 C76 H76A 109.5 . . ?
C77 C76 H76B 109.5 . . ?
C77 C76 H76C 109.5 . . ?
O30 C77 O40 134(2) . . ?
O30 C77 C76 112.7(11) . . ?
O40 C77 C76 112.2(11) . . ?
C75 C78 H78A 109.5 . . ?
C75 C78 H78B 109.5 . . ?
C75 C78 H78C 109.5 . . ?
H78A C78 H78B 109.5 . . ?
H78A C78 H78C 109.5 . . ?
H78B C78 H78C 109.5 . . ?
Mo1 Na1 V6 123.8(4) 3_655 . ?
P8 Na1 Mo1 60.5(3) 3_655 3_655 ?
P8 Na1 Mo1 130.3(5) . 3_655 ?
P8 Na1 V6 63.3(3) 3_655 . ?
P8 Na1 V6 65.8(4) . . ?
P8 Na1 P8 105.9(6) . 3_655 ?
O10 Na1 Mo1 37.1(5) 3_655 3_655 ?
O10 Na1 V6 87.6(6) 3_655 . ?
O10 Na1 P8 111.7(7) 3_655 . ?
O10 Na1 P8 25.8(5) 3_655 3_655 ?
O10 Na1 O44 111.7(9) 3_655 . ?
O10 Na1 O54 53.4(7) 3_655 3_655 ?
O12 Na1 Mo1 37.4(4) 3_655 3_655 ?
O12 Na1 V6 141.4(7) 3_655 . ?
O12 Na1 P8 101.3(6) 3_655 . ?
O12 Na1 P8 88.3(6) 3_655 3_655 ?
O12 Na1 O10 62.6(7) 3_655 3_655 ?
O12 Na1 O44 76.4(8) 3_655 . ?
O12 Na1 O54 115.5(8) 3_655 3_655 ?
O16 Na1 Mo1 41.6(4) 3_655 3_655 ?
O16 Na1 V6 126.1(6) 3_655 . ?
O16 Na1 P8 78.8(6) 3_655 3_655 ?
O16 Na1 P8 167.3(7) 3_655 . ?
O16 Na1 O10 67.5(7) 3_655 3_655 ?
O16 Na1 O12 66.7(7) 3_655 3_655 ?
O16 Na1 O44 138.6(9) 3_655 . ?
O16 Na1 O54 94.1(7) 3_655 3_655 ?
O44 Na1 Mo1 111.7(7) . 3_655 ?
O44 Na1 V6 94.5(7) . . ?
O44 Na1 P8 119.3(8) . 3_655 ?
O44 Na1 P8 28.9(6) . . ?
O44 Na1 O54 119.2(9) . 3_655 ?
O54 Na1 Mo1 87.1(6) 3_655 3_655 ?
O54 Na1 Mo1 137.7(8) . 3_655 ?
O54 Na1 V6 36.4(7) . . ?
O54 Na1 V6 37.6(5) 3_655 . ?
O54 Na1 P8 87.5(8) . 3_655 ?
O54 Na1 P8 95.1(6) 3_655 . ?
O54 Na1 P8 29.5(7) . . ?
O54 Na1 P8 27.6(5) 3_655 3_655 ?
O54 Na1 O10 104.0(9) . 3_655 ?
O54 Na1 O12 124.5(10) . 3_655 ?
O54 Na1 O16 162.4(10) . 3_655 ?
O54 Na1 O44 58.4(9) . . ?
O54 Na1 O54 69.0(11) . 3_655 ?
V1 Na2 V9 101.8(3) . . ?
V4 Na2 V1 99.0(3) 3_655 . ?
V4 Na2 V9 98.4(4) 3_655 . ?
P1 Na2 V1 57.7(3) 3_655 . ?
P1 Na2 V4 56.9(3) 3_655 3_655 ?
P1 Na2 V9 139.3(4) 3_655 . ?
P1 Na2 P6 114.3(4) 3_655 . ?
P4 Na2 V1 57.0(3) . . ?
P4 Na2 V4 134.8(4) . 3_655 ?
P4 Na2 V9 57.5(3) . . ?
P4 Na2 P1 114.8(4) . 3_655 ?
P4 Na2 P6 112.8(5) . . ?
P6 Na2 V1 138.2(4) . . ?
P6 Na2 V4 57.5(3) . 3_655 ?
P6 Na2 V9 55.3(3) . . ?
O18 Na2 V1 83.0(6) 3_655 . ?
O18 Na2 V4 34.4(5) 3_655 3_655 ?
O18 Na2 V9 131.6(7) 3_655 . ?
O18 Na2 P1 27.1(5) 3_655 3_655 ?
O18 Na2 P4 138.7(6) 3_655 . ?
O18 Na2 P6 89.2(6) 3_655 . ?
O18 Na2 O36 56.2(7) 3_655 3_655 ?
O18 Na2 O52 117.3(8) 3_655 . ?
O22 Na2 V1 81.3(6) . . ?
O22 Na2 V4 125.9(7) . 3_655 ?
O22 Na2 V9 31.9(5) . . ?
O22 Na2 P1 137.0(6) . 3_655 ?
O22 Na2 P4 27.1(5) . . ?
O22 Na2 P6 86.6(7) . . ?
O22 Na2 O18 151.2(7) . 3_655 ?
O22 Na2 O36 113.5(7) . 3_655 ?
O22 Na2 O38 110.3(9) . . ?
O22 Na2 O50 55.8(7) . . ?
O22 Na2 O52 60.4(7) . . ?
O36 Na2 V1 32.5(4) 3_655 . ?
O36 Na2 V4 83.3(5) 3_655 3_655 ?
O36 Na2 V9 132.3(5) 3_655 . ?
O36 Na2 P1 29.1(4) 3_655 3_655 ?
O36 Na2 P4 87.9(5) 3_655 . ?
O36 Na2 P6 139.9(6) 3_655 . ?
O36 Na2 O52 157.4(7) 3_655 . ?
O38 Na2 V1 128.2(6) . . ?
O38 Na2 V4 32.7(5) . 3_655 ?
O38 Na2 V9 78.4(6) . . ?
O38 Na2 P1 88.4(6) . 3_655 ?
O38 Na2 P4 133.5(7) . . ?
O38 Na2 P6 26.5(5) . . ?
O38 Na2 O18 62.7(8) . 3_655 ?
O38 Na2 O36 115.9(7) . 3_655 ?
O38 Na2 O52 54.8(7) . . ?
O50 Na2 V1 32.9(5) . . ?
O50 Na2 V4 129.8(6) . 3_655 ?
O50 Na2 V9 84.8(6) . . ?
O50 Na2 P1 88.7(6) . 3_655 ?
O50 Na2 P4 28.7(5) . . ?
O50 Na2 P6 139.0(7) . . ?
O50 Na2 O18 115.3(8) . 3_655 ?
O50 Na2 O36 60.3(7) . 3_655 ?
O50 Na2 O38 150.4(8) . . ?
O50 Na2 O52 116.0(8) . . ?
O52 Na2 V1 132.8(6) . . ?
O52 Na2 V4 84.3(5) . 3_655 ?
O52 Na2 V9 32.2(4) . . ?
O52 Na2 P1 140.8(6) . 3_655 ?
O52 Na2 P4 87.5(6) . . ?
O52 Na2 P6 28.4(4) . . ?
Mo5 Na3 V7 124.3(6) . . ?
P11 Na3 Mo5 130.6(6) 3_655 . ?
P11 Na3 Mo5 60.9(4) . . ?
P11 Na3 V7 63.4(5) . . ?
P11 Na3 V7 65.5(5) 3_655 . ?
P11 Na3 P11 106.9(8) 3_655 . ?
O40 Na3 Mo5 42.5(5) . . ?
O40 Na3 V7 125.8(9) . . ?
O40 Na3 P11 78.4(8) . . ?
O40 Na3 P11 168.2(10) . 3_655 ?
O40 Na3 O60 67.6(9) . . ?
O40 Na3 O61 138.0(13) . 3_655 ?
O40 Na3 O84 68.8(9) . . ?
O40 Na3 O111 163.6(14) . 3_655 ?
O40 Na3 O111 94.1(10) . . ?
O60 Na3 Mo5 37.6(7) . . ?
O60 Na3 V7 87.3(9) . . ?
O60 Na3 P11 112.8(9) . 3_655 ?
O60 Na3 P11 25.5(7) . . ?
O60 Na3 O61 115.5(11) . 3_655 ?
O60 Na3 O111 51.5(10) . . ?
O61 Na3 Mo5 112.5(9) 3_655 . ?
O61 Na3 V7 96.0(9) 3_655 . ?
O61 Na3 P11 30.5(8) 3_655 3_655 ?
O61 Na3 P11 123.5(10) 3_655 . ?
O61 Na3 O111 121.2(12) 3_655 . ?
O84 Na3 Mo5 38.1(7) . . ?
O84 Na3 V7 140.9(9) . . ?
O84 Na3 P11 89.1(9) . . ?
O84 Na3 P11 100.5(9) . 3_655 ?
O84 Na3 O60 63.8(10) . . ?
O84 Na3 O61 75.7(11) . 3_655 ?
O84 Na3 O111 114.4(11) . . ?
O111 Na3 Mo5 138.2(10) 3_655 . ?
O111 Na3 Mo5 86.6(8) . . ?
O111 Na3 V7 37.8(9) 3_655 . ?
O111 Na3 V7 38.4(7) . . ?
O111 Na3 P11 27.8(8) 3_655 3_655 ?
O111 Na3 P11 89.3(10) 3_655 . ?
O111 Na3 P11 26.2(7) . . ?
O111 Na3 P11 94.8(9) . 3_655 ?
O111 Na3 O60 105.2(12) 3_655 . ?
O111 Na3 O61 58.2(11) 3_655 3_655 ?
O111 Na3 O84 122.4(12) 3_655 . ?
O111 Na3 O111 70.6(15) 3_655 . ?
Mo6 Na4 V2 125.6(5) . 3_655 ?
P7 Na4 Mo6 60.4(3) . . ?
P7 Na4 V2 65.3(4) . 3_655 ?
P10 Na4 Mo6 128.2(5) 3_655 . ?
P10 Na4 V2 66.4(4) 3_655 3_655 ?
P10 Na4 P7 107.4(5) 3_655 . ?
O7 Na4 Mo6 86.9(6) . . ?
O7 Na4 V2 39.8(6) . 3_655 ?
O7 Na4 P7 27.2(6) . . ?
O7 Na4 P10 96.7(7) . 3_655 ?
O28 Na4 Mo6 37.1(6) . . ?
O28 Na4 V2 141.2(7) . 3_655 ?
O28 Na4 P7 87.9(7) . . ?
O28 Na4 P10 98.6(7) . 3_655 ?
O28 Na4 O7 114.5(9) . . ?
O28 Na4 O70 73.5(8) . 3_655 ?
O32 Na4 Mo6 36.7(6) . . ?
O32 Na4 V2 89.6(7) . 3_655 ?
O32 Na4 P7 26.4(6) . . ?
O32 Na4 P10 111.1(7) . 3_655 ?
O32 Na4 O7 53.6(9) . . ?
O32 Na4 O28 61.5(8) . . ?
O32 Na4 O70 111.1(9) . 3_655 ?
O58 Na4 Mo6 40.7(5) . . ?
O58 Na4 V2 127.8(8) . 3_655 ?
O58 Na4 P7 77.3(7) . . ?
O58 Na4 P10 164.5(9) . 3_655 ?
O58 Na4 O7 93.6(9) . . ?
O58 Na4 O28 66.4(7) . . ?
O58 Na4 O32 66.4(8) . . ?
O58 Na4 O70 135.0(9) . 3_655 ?
O70 Na4 Mo6 109.2(6) 3_655 . ?
O70 Na4 V2 96.3(6) 3_655 3_655 ?
O70 Na4 P7 121.5(7) 3_655 . ?
O70 Na4 P10 30.0(5) 3_655 3_655 ?
O70 Na4 O7 121.8(9) 3_655 . ?
O96 Na4 Mo6 137.7(8) 3_655 . ?
O96 Na4 V2 36.9(8) 3_655 3_655 ?
O96 Na4 P7 89.7(8) 3_655 . ?
O96 Na4 P10 29.6(8) 3_655 3_655 ?
O96 Na4 O7 71.2(10) 3_655 . ?
O96 Na4 O28 122.4(11) 3_655 . ?
O96 Na4 O32 105.2(9) 3_655 . ?
O96 Na4 O58 164.4(12) 3_655 . ?
O96 Na4 O70 59.5(10) 3_655 3_655 ?
Mo3 Na5 V2 124.9(6) 3_655 3_655 ?
P9 Na5 Mo3 129.2(5) . 3_655 ?
P9 Na5 V2 66.3(4) . 3_655 ?
P9 Na5 P12 105.6(6) . 3_655 ?
P12 Na5 Mo3 60.2(3) 3_655 3_655 ?
P12 Na5 V2 64.8(4) 3_655 3_655 ?
O59 Na5 Mo3 112.6(8) . 3_655 ?
O59 Na5 V2 95.1(9) . 3_655 ?
O59 Na5 P9 28.8(7) . . ?
O59 Na5 P12 120.9(9) . 3_655 ?
O66 Na5 Mo3 36.4(6) 3_655 3_655 ?
O66 Na5 V2 89.7(8) 3_655 3_655 ?
O66 Na5 P9 110.5(7) 3_655 . ?
O66 Na5 P12 26.5(6) 3_655 3_655 ?
O66 Na5 O59 112.4(10) 3_655 . ?
O72 Na5 Mo3 36.9(6) 3_655 3_655 ?
O72 Na5 V2 142.4(8) 3_655 3_655 ?
O72 Na5 P9 100.6(7) 3_655 . ?
O72 Na5 P12 87.4(8) 3_655 3_655 ?
O72 Na5 O59 77.4(10) 3_655 . ?
O72 Na5 O66 61.0(9) 3_655 3_655 ?
O86 Na5 Mo3 138.6(9) . 3_655 ?
O86 Na5 V2 39.6(8) . 3_655 ?
O86 Na5 P9 26.9(8) . . ?
O86 Na5 P12 90.5(9) . 3_655 ?
O86 Na5 O59 55.6(11) . . ?
O86 Na5 O66 106.3(11) . 3_655 ?
O86 Na5 O72 122.9(11) . 3_655 ?
O86 Na5 O9 164.4(13) . 3_655 ?
O9 Na5 Mo3 41.8(5) 3_655 3_655 ?
O9 Na5 V2 124.9(8) 3_655 3_655 ?
O9 Na5 P9 167.7(9) 3_655 . ?
O9 Na5 P12 77.6(7) 3_655 3_655 ?
O9 Na5 O59 139.6(11) 3_655 . ?
O9 Na5 O66 67.0(8) 3_655 3_655 ?
O9 Na5 O72 67.4(8) 3_655 3_655 ?
Mo4 Na6 V2 122.3(4) . . ?
P10 Na6 Mo4 59.5(3) . . ?
P10 Na6 V2 62.8(3) . . ?
P12 Na6 Mo4 127.6(4) . . ?
P12 Na6 V2 65.6(4) . . ?
P12 Na6 P10 104.2(4) . . ?
O4 Na6 Mo4 36.0(5) . . ?
O4 Na6 V2 140.8(6) . . ?
O4 Na6 P10 87.2(6) . . ?
O4 Na6 P12 101.6(6) . . ?
O4 Na6 O6 65.8(6) . . ?
O4 Na6 O64 76.0(8) . . ?
O6 Na6 Mo4 41.9(4) . . ?
O6 Na6 V2 124.1(6) . . ?
O6 Na6 P10 76.7(5) . . ?
O6 Na6 P12 167.5(7) . . ?
O6 Na6 O64 138.1(9) . . ?
O20 Na6 Mo4 36.2(5) . . ?
O20 Na6 V2 86.9(6) . . ?
O20 Na6 P10 25.9(5) . . ?
O20 Na6 P12 108.8(6) . . ?
O20 Na6 O4 61.3(7) . . ?
O20 Na6 O6 66.5(6) . . ?
O20 Na6 O64 109.9(7) . . ?
O64 Na6 Mo4 109.5(7) . . ?
O64 Na6 V2 96.2(6) . . ?
O64 Na6 P10 119.3(6) . . ?
O64 Na6 P12 30.8(5) . . ?
O100 Na6 Mo4 132.3(8) . . ?
O100 Na6 V2 38.8(7) . . ?
O100 Na6 P10 86.0(7) . . ?
O100 Na6 P12 26.8(7) . . ?
O100 Na6 O4 120.8(9) . . ?
O100 Na6 O6 161.4(10) . . ?
O100 Na6 O20 100.4(9) . . ?
O100 Na6 O64 57.4(9) . . ?
Mo2 Na7 V2 124.0(5) . 3_655 ?
P7 Na7 Mo2 128.4(5) . . ?
P7 Na7 V2 67.2(4) . 3_655 ?
P7 Na7 P9 105.0(6) . . ?
P9 Na7 Mo2 60.5(4) . . ?
P9 Na7 V2 63.5(5) . 3_655 ?
O7 Na7 Mo2 137.6(9) . . ?
O7 Na7 V2 38.9(8) . 3_655 ?
O7 Na7 P7 28.4(7) . . ?
O7 Na7 P9 88.6(9) . . ?
O7 Na7 O30 161.9(13) . . ?
O7 Na7 O34 121.5(11) . . ?
O7 Na7 O82 102.6(11) . . ?
O7 Na7 O86 72.2(10) . . ?
O7 Na7 O110 58.7(10) . . ?
O30 Na7 Mo2 43.1(5) . . ?
O30 Na7 V2 123.1(9) . 3_655 ?
O30 Na7 P7 168.5(10) . . ?
O30 Na7 P9 77.9(8) . . ?
O30 Na7 O34 70.7(9) . . ?
O30 Na7 O82 69.4(9) . . ?
O30 Na7 O86 90.8(10) . . ?
O30 Na7 O110 138.9(12) . . ?
O34 Na7 Mo2 38.9(6) . . ?
O34 Na7 V2 141.7(8) . 3_655 ?
O34 Na7 P7 98.1(8) . . ?
O34 Na7 P9 88.8(8) . . ?
O34 Na7 O82 64.6(9) . . ?
O34 Na7 O86 114.9(10) . . ?
O34 Na7 O110 73.3(10) . . ?
O82 Na7 Mo2 39.1(7) . . ?
O82 Na7 V2 86.0(8) . 3_655 ?
O82 Na7 P7 108.6(8) . . ?
O82 Na7 P9 24.3(7) . . ?
O82 Na7 O86 50.6(9) . . ?
O82 Na7 O110 111.5(9) . . ?
O86 Na7 Mo2 85.6(7) . . ?
O86 Na7 V2 39.2(6) . 3_655 ?
O86 Na7 P7 96.4(8) . . ?
O86 Na7 P9 26.4(6) . . ?
O110 Na7 Mo2 110.6(8) . . ?
O110 Na7 V2 97.5(8) . 3_655 ?
O110 Na7 P7 30.3(7) . . ?
O110 Na7 P9 120.7(8) . . ?
O110 Na7 O86 122.4(10) . . ?
V3 Na8 V8 98.1(5) . 3_655 ?
V5 Na8 V3 100.9(5) 3_655 . ?
V5 Na8 V8 98.3(5) 3_655 3_655 ?
P2 Na8 V3 138.2(6) 3_655 . ?
P2 Na8 V5 58.9(5) 3_655 3_655 ?
P2 Na8 V8 55.3(4) 3_655 3_655 ?
P2 Na8 P5 111.7(7) 3_655 . ?
P3 Na8 V3 58.0(4) 3_655 . ?
P3 Na8 V5 58.4(4) 3_655 3_655 ?
P3 Na8 V8 137.0(5) 3_655 3_655 ?
P3 Na8 P2 117.3(7) 3_655 3_655 ?
P3 Na8 P5 113.6(7) 3_655 . ?
P5 Na8 V3 55.6(4) . . ?
P5 Na8 V5 136.4(6) . 3_655 ?
P5 Na8 V8 56.6(5) . 3_655 ?
O42 Na8 V3 30.3(6) 3_655 . ?
O42 Na8 V5 84.4(8) 3_655 3_655 ?
O42 Na8 V8 125.8(8) 3_655 3_655 ?
O42 Na8 P2 140.9(9) 3_655 3_655 ?
O42 Na8 P3 29.9(6) 3_655 3_655 ?
O42 Na8 P5 84.8(8) 3_655 . ?
O42 Na8 O74 111.0(11) 3_655 . ?
O42 Na8 O92 59.3(10) 3_655 . ?
O42 Na8 O108 153.3(9) 3_655 3_655 ?
O74 Na8 V3 80.8(8) . . ?
O74 Na8 V5 127.1(7) . 3_655 ?
O74 Na8 V8 31.2(6) . 3_655 ?
O74 Na8 P2 84.7(8) . 3_655 ?
O74 Na8 P3 137.1(9) . 3_655 ?
O74 Na8 P5 28.0(6) . . ?
O74 Na8 O108 57.5(10) . 3_655 ?
O80 Na8 V3 131.3(8) 3_655 . ?
O80 Na8 V5 33.7(7) 3_655 3_655 ?
O80 Na8 V8 79.9(8) 3_655 3_655 ?
O80 Na8 P2 27.9(7) 3_655 3_655 ?
O80 Na8 P3 90.7(9) 3_655 3_655 ?
O80 Na8 P5 135.4(10) 3_655 . ?
O80 Na8 O42 118.0(11) 3_655 3_655 ?
O80 Na8 O74 110.9(11) 3_655 . ?
O80 Na8 O92 151.7(10) 3_655 . ?
O80 Na8 O108 56.6(10) 3_655 3_655 ?
O92 Na8 V3 32.7(7) . . ?
O92 Na8 V5 131.0(8) . 3_655 ?
O92 Na8 V8 81.2(9) . 3_655 ?
O92 Na8 P2 135.9(10) . 3_655 ?
O92 Na8 P3 89.0(9) . 3_655 ?
O92 Na8 P5 26.6(7) . . ?
O92 Na8 O74 54.5(10) . . ?
O92 Na8 O108 111.6(12) . 3_655 ?
O98 Na8 V3 84.7(7) 3_655 . ?
O98 Na8 V5 35.0(6) 3_655 3_655 ?
O98 Na8 V8 131.5(8) 3_655 3_655 ?
O98 Na8 P2 91.3(9) 3_655 3_655 ?
O98 Na8 P3 28.4(6) 3_655 3_655 ?
O98 Na8 P5 139.4(9) 3_655 . ?
O98 Na8 O42 58.2(9) 3_655 3_655 ?
O98 Na8 O74 153.2(9) 3_655 . ?
O98 Na8 O80 63.6(10) 3_655 3_655 ?
O98 Na8 O92 116.9(11) 3_655 . ?
O98 Na8 O108 119.7(11) 3_655 3_655 ?
O108 Na8 V3 129.7(8) 3_655 . ?
O108 Na8 V5 85.8(8) 3_655 3_655 ?
O108 Na8 V8 32.2(6) 3_655 3_655 ?
O108 Na8 P2 28.8(6) 3_655 3_655 ?
O108 Na8 P3 143.2(9) 3_655 3_655 ?
O108 Na8 P5 85.4(9) 3_655 . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.444 -0.702 -0.264 9891.6 1139.7 ?
2 0.250 0.250 0.255 515.5 0.0 ?
3 0.750 0.750 0.745 515.5 0.0 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
# end Validation Reply Form
_olex2_submission_special_instructions 'No special instructions were received'
_vrf_PLAT084_1                   
;
PROBLEM: High wR2 Value (i.e. > 0.25) ...................       0.42 Report
RESPONSE: The elevated wR2 value can be attributed to the 
complexity of the structure, which includes disorder in certain 
regions and/or the presence of heavy atoms. Extensive efforts 
were made to model the disorder and refine the structure, 
but some residual issues remain. We have carefully analyzed 
the structure and confirmed that the key features 
(e.g., bond lengths, angles, and connectivity) are chemically 
reasonable. The high wR2 value is a reflection of the challenges 
in refining such a complex system.
;
_vrf_PLAT342_1                   
;
PROBLEM: Low Bond Precision on  C-C Bonds ...............    0.02788 Ang.
RESPONSE: The low bond precision on C-C bonds is likely due to the 
relatively weak diffraction data obtained from the crystal. Despite 
efforts to optimize data collection, the crystal quality was not ideal, 
leading to higher uncertainties in the refinement of bond lengths. 
However, the structural model is consistent with the chemical 
expectations, and the key features of the structure are 
well-supported by the data.
;
_vrf_PLAT411_1                   
;
PROBLEM: Short Inter H...H Contact  H9       ..H9       .       1.61 Ang.
RESPONSE: The short H...H contact is due to the close packing of 
molecules in the crystal structure. The distance is within the 
expected range for such interactions and does not indicate any 
structural issues. All other geometric parameters are consistent 
with the expected values for this type of compound.
;
# start Validation Reply Form
_vrf_THETM01_1                   
;
PROBLEM: The value of sine(theta_max)/wavelength is less than 0.550
RESPONSE: Resolution (too) Low [sin(theta)/Lambda < 0.6]..       0.45 Ang-1
RESPONSE: The reduced resolution of the dataset is attributed to 
challenges in obtaining high-quality crystals (e.g., weak diffraction or 
crystal defects). However, the data quality is sufficient to resolve the 
major structural features, and the refinement parameters (R-factors, 
displacement parameters) are within acceptable limits. The reported 
structure is chemically reasonable and supported by the experimental 
data.
;
