# Supplementary Information (SI) for Organic Chemistry Frontiers.
# This journal is © the Partner Organisations 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cu_20250614_LYX_3_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2466831'
loop_
_audit_author_name
_audit_author_address
'Yankai Liu'
;Ocean University of China
China
;
_audit_update_record             
;
2025-06-24 deposited with the CCDC.	2025-10-07 downloaded from the CCDC.
;
_audit_creation_date             2025-06-16
_audit_creation_method           
;
Olex2 1.5
(compiled 2025.05.31 svn.r86d253d1 for OlexSys, GUI svn.r7254)
;
_chemical_name_systematic        ?
_chemical_formula_moiety         'C24 H24 N O2'
_chemical_formula_sum            'C24 H24 N O2'
_chemical_formula_weight         358.464
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
_atom_type_scat_dispersion_source
C 0.01788 0.00908 2.31000 1.02000 1.58860 0.86500 20.84390 10.20750 0.56870
51.65120 0.21560 'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'
H 0.00000 0.00000 0.49300 0.32291 0.14019 0.04081 10.51090 26.12570 3.14236
57.79970 0.00304 'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'
N 0.03110 0.01806 12.21260 3.13220 2.01250 1.16630 0.00570 9.89330 28.99750
0.58260 -11.52900 'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'
O 0.04960 0.03234 3.04850 2.28680 1.54630 0.86700 13.27710 5.70110 0.32390
32.90890 0.25080 'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z

_symmetry_Int_Tables_number      2
_cell_length_a                   8.6745(4)
_cell_length_b                   11.0198(6)
_cell_length_c                   11.3400(7)
_cell_angle_alpha                106.866(4)
_cell_angle_beta                 93.785(3)
_cell_angle_gamma                111.247(3)
_cell_volume                     948.9(1)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    6731
_cell_measurement_temperature    269.0
_cell_measurement_theta_max      72.381
_cell_measurement_theta_min      4.151
_exptl_absorpt_coefficient_mu    0.624
_exptl_absorpt_correction_T_max  0.7535
_exptl_absorpt_correction_T_min  0.5692
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1077 before and 0.0642 after correction.
The Ratio of minimum to maximum transmission is 0.7554.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.255
_exptl_crystal_description       block
_exptl_crystal_F_000             383.196
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.08
_diffrn_reflns_av_R_equivalents  0.0658
_diffrn_reflns_av_unetI/netI     0.0766
_diffrn_reflns_Laue_measured_fraction_full 0.9785
_diffrn_reflns_Laue_measured_fraction_max 0.9571
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            11922
_diffrn_reflns_point_group_measured_fraction_full 0.9785
_diffrn_reflns_point_group_measured_fraction_max 0.9571
_diffrn_reflns_theta_full        67.6840
_diffrn_reflns_theta_max         72.40
_diffrn_reflns_theta_min         4.15
_diffrn_ambient_temperature      269.0
_diffrn_measured_fraction_theta_full 0.9785
_diffrn_measured_fraction_theta_max 0.9571
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source_current           1.1
_diffrn_source_power             0.05500000000000001
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.0
_reflns_limit_h_max              10
_reflns_limit_h_min              -10
_reflns_limit_k_max              12
_reflns_limit_k_min              -13
_reflns_limit_l_max              13
_reflns_limit_l_min              0
_reflns_number_gt                2834
_reflns_number_total             3594
_reflns_threshold_expression     I>=2u(I)
_computing_cell_refinement       'SAINT V8.41 (?, 2016)'
_computing_data_reduction        'SAINT V8.41 (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'olex2.refine 1.5 (Bourhis et al., 2015)'
_computing_structure_solution    'olex2.solve 1.5 (Bourhis et al., 2015)'
_refine_diff_density_max         0.6082
_refine_diff_density_min         -0.4715
_refine_diff_density_rms         0.1149
_refine_ls_d_res_high            0.8088
_refine_ls_d_res_low             10.6505
_refine_ls_goodness_of_fit_ref   1.0521
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_constraints    40
_refine_ls_number_parameters     250
_refine_ls_number_reflns         3594
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0903
_refine_ls_R_factor_gt           0.0532
_refine_ls_restrained_S_all      1.0521
_refine_ls_shift/su_max          0.0009
_refine_ls_shift/su_mean         0.0001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0734P)²+0.3220P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1442
_refine_ls_wR_factor_ref         0.1577
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, {H1a,H1b} of C1, {H2a,H2b} of C2, {H5a,H5b} of C5, {H6a,
  H6b} of C6, {H4a,H4b} of C4, {H12a,H12b} of C12
 At 1.5 times of:
  {H11a,H11b} of C11
2.a Ternary CH refined with riding coordinates:
 C7(H7)
2.b Secondary CH2 refined with riding coordinates:
 C1(H1a,H1b), C2(H2a,H2b), C4(H4a,H4b), C5(H5a,H5b), C6(H6a,H6b), C12(H12a,H12b)
2.c Aromatic/amide H refined with riding coordinates:
 C14(H14), C15(H15), C16(H16), C17(H17), C18(H18), C20(H20), C21(H21),
 C22(H22), C23(H23)
;
_atom_sites_solution_primary     iterative
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_refinement_flags_posn
O1 O 0.73600(14) 0.71709(13) 0.63685(11) 0.0409(3) Uani 1.000000 .
O2 O 0.83494(15) 0.62731(14) 0.83513(13) 0.0451(3) Uani 1.000000 .
N1 N 0.40288(18) 0.65877(16) 0.79335(15) 0.0418(4) Uani 1.000000 .
C1 C 1.1486(3) 0.8820(3) 0.5584(4) 0.0830(9) Uani 1.000000 .
H1a H 1.1722(3) 0.9046(3) 0.4832(4) 0.0996(11) Uiso 1.000000 R
H1b H 1.2367(3) 0.9502(3) 0.6288(4) 0.0996(11) Uiso 1.000000 R
C2 C 0.9781(3) 0.8802(2) 0.5821(2) 0.0543(5) Uani 1.000000 .
H2a H 0.9883(3) 0.9702(2) 0.6359(2) 0.0651(6) Uiso 1.000000 R
H2b H 0.9015(3) 0.8531(2) 0.5040(2) 0.0651(6) Uiso 1.000000 R
C3 C 0.9178(2) 0.7720(2) 0.64740(19) 0.0436(4) Uani 1.000000 .
C4 C 0.9723(3) 0.6592(2) 0.5734(2) 0.0577(5) Uani 1.000000 .
H4a H 0.9859(3) 0.6047(2) 0.6237(2) 0.0692(7) Uiso 1.000000 R
H4b H 0.8901(3) 0.5982(2) 0.4973(2) 0.0692(7) Uiso 1.000000 R
C5 C 1.1403(3) 0.7379(3) 0.5425(3) 0.0787(8) Uani 1.000000 .
H5a H 1.1465(3) 0.6921(3) 0.4570(3) 0.0945(10) Uiso 1.000000 R
H5b H 1.2332(3) 0.7430(3) 0.5990(3) 0.0945(10) Uiso 1.000000 R
C6 C 0.9886(2) 0.8292(2) 0.7891(2) 0.0476(5) Uani 1.000000 .
H6a H 1.0822(2) 0.8049(2) 0.8074(2) 0.0571(6) Uiso 1.000000 R
H6b H 1.0267(2) 0.9290(2) 0.8212(2) 0.0571(6) Uiso 1.000000 R
C7 C 0.8425(2) 0.76153(19) 0.84614(18) 0.0406(4) Uani 1.000000 .
H7 H 0.8528(2) 0.81717(19) 0.93343(18) 0.0487(5) Uiso 1.000000 R
C8 C 0.69251(19) 0.75526(18) 0.75767(16) 0.0356(4) Uani 1.000000 .
C9 C 0.5337(2) 0.63962(17) 0.75974(16) 0.0352(4) Uani 1.000000 .
C10 C 0.5348(2) 0.49956(18) 0.75212(17) 0.0381(4) Uani 1.000000 .
C11 C 0.5572(3) 0.4124(2) 0.6273(2) 0.0510(5) Uani 1.000000 .
H11a H 0.661(4) 0.452(3) 0.610(3) 0.0766(7) Uiso 1.000000 .
H11b H 0.544(3) 0.325(3) 0.628(3) 0.0766(7) Uiso 1.000000 .
C12 C 0.6829(2) 0.5394(2) 0.85925(19) 0.0447(4) Uani 1.000000 .
H12a H 0.6938(2) 0.4566(2) 0.86481(19) 0.0536(5) Uiso 1.000000 R
H12b H 0.6611(2) 0.5868(2) 0.93867(19) 0.0536(5) Uiso 1.000000 R
C13 C 0.6735(2) 0.89261(18) 0.78973(18) 0.0401(4) Uani 1.000000 .
C14 C 0.6373(3) 0.9390(2) 0.6938(2) 0.0532(5) Uani 1.000000 .
H14 H 0.6304(3) 0.8881(2) 0.6109(2) 0.0638(6) Uiso 1.000000 R
C15 C 0.6116(3) 1.0601(3) 0.7207(3) 0.0695(7) Uani 1.000000 .
H15 H 0.5870(3) 1.0897(3) 0.6557(3) 0.0835(9) Uiso 1.000000 R
C16 C 0.6221(3) 1.1372(2) 0.8430(3) 0.0711(8) Uani 1.000000 .
H16 H 0.6048(3) 1.2186(2) 0.8605(3) 0.0854(9) Uiso 1.000000 R
C17 C 0.6581(3) 1.0934(2) 0.9387(3) 0.0682(7) Uani 1.000000 .
H17 H 0.6657(3) 1.1452(2) 1.0215(3) 0.0819(8) Uiso 1.000000 R
C18 C 0.6834(3) 0.9714(2) 0.9119(2) 0.0554(5) Uani 1.000000 .
H18 H 0.7074(3) 0.9422(2) 0.9774(2) 0.0665(6) Uiso 1.000000 R
C19 C 0.2940(2) 0.53211(19) 0.80604(18) 0.0424(4) Uani 1.000000 .
C20 C 0.1368(2) 0.5049(2) 0.8372(2) 0.0537(5) Uani 1.000000 .
H20 H 0.0915(2) 0.5713(2) 0.8534(2) 0.0645(6) Uiso 1.000000 R
C21 C 0.0490(2) 0.3742(2) 0.8432(2) 0.0586(6) Uani 1.000000 .
H21 H -0.0570(2) 0.3530(2) 0.8646(2) 0.0703(7) Uiso 1.000000 R
C22 C 0.1154(3) 0.2752(2) 0.8183(2) 0.0559(5) Uani 1.000000 .
H22 H 0.0530(3) 0.1881(2) 0.8220(2) 0.0671(6) Uiso 1.000000 R
C23 C 0.2748(3) 0.3038(2) 0.7876(2) 0.0494(5) Uani 1.000000 .
H23 H 0.3193(3) 0.2368(2) 0.7702(2) 0.0593(6) Uiso 1.000000 R
C24 C 0.3655(2) 0.43498(18) 0.78380(17) 0.0397(4) Uani 1.000000 .


loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O1 C3 1.452(2) . ?
O1 C8 1.430(2) . ?
O2 C7 1.424(2) . ?
O2 C12 1.424(2) . ?
N1 C9 1.289(2) . ?
N1 C19 1.428(2) . ?
C1 H1a 0.9700 . ?
C1 H1b 0.9700 . ?
C1 C2 1.515(3) . ?
C1 C5 1.519(4) . ?
C2 H2a 0.9700 . ?
C2 H2b 0.9700 . ?
C2 C3 1.535(3) . ?
C3 C4 1.532(3) . ?
C3 C6 1.536(3) . ?
C4 H4a 0.9700 . ?
C4 H4b 0.9700 . ?
C4 C5 1.525(3) . ?
C5 H5a 0.9700 . ?
C5 H5b 0.9700 . ?
C6 H6a 0.9700 . ?
C6 H6b 0.9700 . ?
C6 C7 1.511(3) . ?
C7 H7 0.9800 . ?
C7 C8 1.558(2) . ?
C8 C9 1.507(2) . ?
C8 C13 1.523(2) . ?
C9 C10 1.524(2) . ?
C10 C11 1.532(3) . ?
C10 C12 1.547(2) . ?
C10 C24 1.500(2) . ?
C11 H11a 0.91(3) . ?
C11 H11b 0.93(3) . ?
C12 H12a 0.9700 . ?
C12 H12b 0.9700 . ?
C13 C14 1.392(3) . ?
C13 C18 1.383(3) . ?
C14 H14 0.9300 . ?
C14 C15 1.383(3) . ?
C15 H15 0.9300 . ?
C15 C16 1.377(4) . ?
C16 H16 0.9300 . ?
C16 C17 1.370(4) . ?
C17 H17 0.9300 . ?
C17 C18 1.391(3) . ?
C18 H18 0.9300 . ?
C19 C20 1.380(3) . ?
C19 C24 1.393(3) . ?
C20 H20 0.9300 . ?
C20 C21 1.389(3) . ?
C21 H21 0.9300 . ?
C21 C22 1.378(3) . ?
C22 H22 0.9300 . ?
C22 C23 1.394(3) . ?
C23 H23 0.9300 . ?
C23 C24 1.388(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C8 O1 C3 110.55(13) . . ?
C12 O2 C7 114.06(14) . . ?
C19 N1 C9 106.09(15) . . ?
H1b C1 H1a 108.6 . . ?
C2 C1 H1a 110.41(15) . . ?
C2 C1 H1b 110.41(17) . . ?
C5 C1 H1a 110.41(17) . . ?
C5 C1 H1b 110.41(18) . . ?
C5 C1 C2 106.6(2) . . ?
H2a C2 C1 111.12(16) . . ?
H2b C2 C1 111.12(17) . . ?
H2b C2 H2a 109.1 . . ?
C3 C2 C1 103.21(18) . . ?
C3 C2 H2a 111.12(12) . . ?
C3 C2 H2b 111.12(11) . . ?
C2 C3 O1 111.70(15) . . ?
C4 C3 O1 110.37(15) . . ?
C4 C3 C2 102.45(17) . . ?
C6 C3 O1 104.85(15) . . ?
C6 C3 C2 113.73(17) . . ?
C6 C3 C4 113.94(17) . . ?
H4a C4 C3 110.83(12) . . ?
H4b C4 C3 110.83(11) . . ?
H4b C4 H4a 108.9 . . ?
C5 C4 C3 104.63(19) . . ?
C5 C4 H4a 110.83(14) . . ?
C5 C4 H4b 110.83(16) . . ?
C4 C5 C1 106.48(19) . . ?
H5a C5 C1 110.43(18) . . ?
H5a C5 C4 110.43(15) . . ?
H5b C5 C1 110.43(18) . . ?
H5b C5 C4 110.43(15) . . ?
H5b C5 H5a 108.6 . . ?
H6a C6 C3 110.84(10) . . ?
H6b C6 C3 110.84(11) . . ?
H6b C6 H6a 108.9 . . ?
C7 C6 C3 104.56(14) . . ?
C7 C6 H6a 110.84(10) . . ?
C7 C6 H6b 110.84(11) . . ?
C6 C7 O2 107.59(15) . . ?
H7 C7 O2 111.96(10) . . ?
H7 C7 C6 111.96(10) . . ?
C8 C7 O2 112.09(13) . . ?
C8 C7 C6 100.69(14) . . ?
C8 C7 H7 111.96(10) . . ?
C7 C8 O1 102.48(13) . . ?
C9 C8 O1 108.40(13) . . ?
C9 C8 C7 108.93(14) . . ?
C13 C8 O1 111.74(14) . . ?
C13 C8 C7 112.89(14) . . ?
C13 C8 C9 111.90(13) . . ?
C8 C9 N1 123.08(16) . . ?
C10 C9 N1 115.16(15) . . ?
C10 C9 C8 120.24(14) . . ?
C11 C10 C9 117.06(16) . . ?
C12 C10 C9 102.41(13) . . ?
C12 C10 C11 111.07(15) . . ?
C24 C10 C9 99.30(13) . . ?
C24 C10 C11 113.20(15) . . ?
C24 C10 C12 112.94(15) . . ?
H11a C11 C10 112.1(18) . . ?
H11b C11 C10 111.3(18) . . ?
H11b C11 H11a 107(2) . . ?
C10 C12 O2 109.57(14) . . ?
H12a C12 O2 109.76(9) . . ?
H12a C12 C10 109.76(10) . . ?
H12b C12 O2 109.76(10) . . ?
H12b C12 C10 109.76(10) . . ?
H12b C12 H12a 108.2 . . ?
C14 C13 C8 119.76(18) . . ?
C18 C13 C8 122.15(17) . . ?
C18 C13 C14 118.01(19) . . ?
H14 C14 C13 119.70(13) . . ?
C15 C14 C13 120.6(2) . . ?
C15 C14 H14 119.70(16) . . ?
H15 C15 C14 119.73(16) . . ?
C16 C15 C14 120.5(2) . . ?
C16 C15 H15 119.73(14) . . ?
H16 C16 C15 120.14(14) . . ?
C17 C16 C15 119.7(2) . . ?
C17 C16 H16 120.14(15) . . ?
H17 C17 C16 120.06(15) . . ?
C18 C17 C16 119.9(3) . . ?
C18 C17 H17 120.06(17) . . ?
C17 C18 C13 121.3(2) . . ?
H18 C18 C13 119.37(12) . . ?
H18 C18 C17 119.37(17) . . ?
C20 C19 N1 125.91(18) . . ?
C24 C19 N1 111.85(16) . . ?
C24 C19 C20 122.24(18) . . ?
H20 C20 C19 121.36(12) . . ?
C21 C20 C19 117.3(2) . . ?
C21 C20 H20 121.36(13) . . ?
H21 C21 C20 119.26(13) . . ?
C22 C21 C20 121.5(2) . . ?
C22 C21 H21 119.26(12) . . ?
H22 C22 C21 119.56(12) . . ?
C23 C22 C21 120.9(2) . . ?
C23 C22 H22 119.56(13) . . ?
H23 C23 C22 120.87(13) . . ?
C24 C23 C22 118.3(2) . . ?
C24 C23 H23 120.87(12) . . ?
C19 C24 C10 107.51(15) . . ?
C23 C24 C10 132.60(18) . . ?
C23 C24 C19 119.80(18) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 C3 C2 C1 -158.6(2) . . . . ?
O1 C3 C4 C5 155.5(2) . . . . ?
O1 C3 C6 C7 17.75(15) . . . . ?
O1 C8 C7 O2 -73.61(14) . . . . ?
O1 C8 C7 C6 40.51(14) . . . . ?
O1 C8 C9 N1 -128.12(14) . . . . ?
O1 C8 C9 C10 66.62(15) . . . . ?
O1 C8 C13 C14 23.27(16) . . . . ?
O1 C8 C13 C18 -159.74(14) . . . . ?
O2 C7 C6 C3 82.32(15) . . . . ?
O2 C7 C8 C9 41.08(16) . . . . ?
O2 C7 C8 C13 166.04(15) . . . . ?
O2 C12 C10 C9 -60.91(16) . . . . ?
O2 C12 C10 C11 64.83(18) . . . . ?
O2 C12 C10 C24 -166.74(14) . . . . ?
N1 C9 C8 C7 121.09(18) . . . . ?
N1 C9 C8 C13 -4.44(19) . . . . ?
N1 C9 C10 C11 124.82(16) . . . . ?
N1 C9 C10 C12 -113.45(17) . . . . ?
N1 C9 C10 C24 2.68(16) . . . . ?
N1 C19 C20 C21 179.1(2) . . . . ?
N1 C19 C24 C10 -0.71(17) . . . . ?
N1 C19 C24 C23 -177.72(16) . . . . ?
C1 C2 C3 C4 -40.5(2) . . . . ?
C1 C2 C3 C6 82.9(2) . . . . ?
C1 C5 C4 C3 -18.5(3) . . . . ?
C2 C1 C5 C4 -6.9(3) . . . . ?
C2 C3 O1 C8 -114.49(17) . . . . ?
C2 C3 C4 C5 36.40(19) . . . . ?
C2 C3 C6 C7 140.05(17) . . . . ?
C3 O1 C8 C7 -31.31(14) . . . . ?
C3 O1 C8 C9 -146.39(14) . . . . ?
C3 O1 C8 C13 89.83(14) . . . . ?
C3 C2 C1 C5 29.5(2) . . . . ?
C3 C6 C7 C8 -35.15(16) . . . . ?
C4 C3 O1 C8 132.23(16) . . . . ?
C4 C3 C6 C7 -103.03(17) . . . . ?
C5 C4 C3 C6 -86.9(2) . . . . ?
C6 C3 O1 C8 9.12(17) . . . . ?
C6 C7 O2 C12 -166.92(14) . . . . ?
C6 C7 C8 C9 155.20(14) . . . . ?
C6 C7 C8 C13 -79.84(15) . . . . ?
C7 O2 C12 C10 69.40(15) . . . . ?
C7 C8 C9 C10 -44.16(16) . . . . ?
C7 C8 C13 C14 138.16(16) . . . . ?
C7 C8 C13 C18 -44.85(18) . . . . ?
C8 C7 O2 C12 -57.12(17) . . . . ?
C8 C9 N1 C19 -169.11(17) . . . . ?
C8 C9 C10 C11 -68.81(17) . . . . ?
C8 C9 C10 C12 52.92(16) . . . . ?
C8 C9 C10 C24 169.05(17) . . . . ?
C8 C13 C14 C15 176.87(18) . . . . ?
C8 C13 C18 C17 -177.06(19) . . . . ?
C9 N1 C19 C20 -178.02(16) . . . . ?
C9 N1 C19 C24 2.40(16) . . . . ?
C9 C8 C13 C14 -98.51(16) . . . . ?
C9 C8 C13 C18 78.48(17) . . . . ?
C9 C10 C24 C19 -0.98(15) . . . . ?
C9 C10 C24 C23 175.50(14) . . . . ?
C10 C9 N1 C19 -3.17(16) . . . . ?
C10 C9 C8 C13 -169.70(16) . . . . ?
C10 C24 C19 C20 179.69(16) . . . . ?
C10 C24 C23 C22 -178.3(2) . . . . ?
C11 C10 C24 C19 -125.85(17) . . . . ?
C11 C10 C24 C23 50.6(2) . . . . ?
C12 C10 C24 C19 106.83(16) . . . . ?
C12 C10 C24 C23 -76.69(19) . . . . ?
C13 C14 C15 C16 0.3(2) . . . . ?
C13 C18 C17 C16 0.2(2) . . . . ?
C14 C13 C18 C17 -0.0(2) . . . . ?
C14 C15 C16 C17 -0.1(3) . . . . ?
C15 C14 C13 C18 -0.2(2) . . . . ?
C15 C16 C17 C18 -0.2(3) . . . . ?
C19 C20 C21 C22 -0.5(3) . . . . ?
C19 C24 C23 C22 -2.2(2) . . . . ?
C20 C19 C24 C23 2.7(2) . . . . ?
C20 C21 C22 C23 0.9(3) . . . . ?
C21 C20 C19 C24 -1.3(3) . . . . ?
C21 C22 C23 C24 0.5(3) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
