# Supplementary Information (SI) for RSC Advances.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_cyn-1-68
_database_code_depnum_ccdc_archive 'CCDC 2422929'
loop_
_audit_author_name
_audit_author_address
'Wei Ding'
;Zhengzhou University
China
;
_audit_update_record             
;
2025-02-11 deposited with the CCDC.	2025-07-04 downloaded from the CCDC.
;
_audit_creation_date             2024-06-17
_audit_creation_method           
;
Olex2 1.5-beta
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6439)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C24 H22 N O2 P'
_chemical_formula_sum            'C24 H22 N O2 P'
_chemical_formula_weight         387.39
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C H O N P'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/n 1'
_space_group_name_Hall           '-P 2yn'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   11.53630(10)
_cell_length_b                   12.06750(10)
_cell_length_c                   14.55360(10)
_cell_angle_alpha                90
_cell_angle_beta                 102.1150(10)
_cell_angle_gamma                90
_cell_volume                     1980.94(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    10423
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      73.0330
_cell_measurement_theta_min      4.4570
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    1.380
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.69864
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.43.92a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_density_diffrn    1.299
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             816
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.12
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0264
_diffrn_reflns_av_unetI/netI     0.0236
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.974
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            13272
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.974
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         73.237
_diffrn_reflns_theta_min         4.462
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -111.00 -42.00   0.50    0.10    --  -99.00 125.00   0.00  138
  2  ω   -106.00 -59.00   0.50    0.10    --  -99.00 106.00 -89.98   94
  3  ω    -23.00  29.00   0.50    0.05    --  -45.87  19.00-120.00  104
  4  ω     -8.00  17.00   0.50    0.05    --  -45.87   4.00-154.00   50
  5  ω   -102.00   4.00   0.50    0.05    --  -45.87  -4.00  25.00  212
  6  ω     43.00 145.00   0.50    0.10    --   99.00   4.00-154.00  204
  7  ω     38.00  75.00   0.50    0.05    --   45.87   4.00-154.00   74
  8  ω   -163.00 -46.00   0.50    0.10    --  -99.00  -4.00  25.00  234
  9  ω    -15.00  10.00   0.50    0.05    --   45.87  -4.00  25.00   50
 10  ω     28.00  71.00   0.50    0.10    --   99.00 -61.00 -90.00   86
 11  ω     27.00  52.00   0.50    0.10    --   99.00 -45.00-150.00   50
 12  ω     31.00  73.00   0.50    0.10    --   99.00 -61.00-180.00   84
 13  ω     39.00  72.00   0.50    0.10    --   99.00 -61.00 -60.00   66
 14  ω     28.00  72.00   0.50    0.10    --   99.00 -61.00 -30.00   88
 15  ω     36.00  86.00   0.50    0.10    --   99.00 -94.00 -90.00  100
 16  ω     80.00 112.00   0.50    0.10    --   99.00-125.00-150.00   64
 17  ω     41.00  92.00   0.50    0.05    --   45.87-125.00 -60.00  102
 18  ω     62.00 110.00   0.50    0.10    --   99.00-125.00  30.00   96
 19  ω     48.00  94.00   0.50    0.10    --   99.00 -94.00  90.00   92
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.1221757000
_diffrn_orient_matrix_UB_12      -0.0028745000
_diffrn_orient_matrix_UB_13      -0.0676932000
_diffrn_orient_matrix_UB_21      0.0608984000
_diffrn_orient_matrix_UB_22      0.0059435000
_diffrn_orient_matrix_UB_23      -0.0845363000
_diffrn_orient_matrix_UB_31      0.0058338000
_diffrn_orient_matrix_UB_32      -0.1273734000
_diffrn_orient_matrix_UB_33      -0.0023877000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3623
_reflns_number_total             3870
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.43.92a (Rigaku OD, 2023)'
_computing_data_collection       'CrysAlisPro 1.171.43.92a (Rigaku OD, 2023)'
_computing_data_reduction        'CrysAlisPro 1.171.43.92a (Rigaku OD, 2023)'
_computing_molecular_graphics    'Olex2 1.5-beta (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5-beta (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXS  (Sheldrick, 2008)'
_refine_diff_density_max         0.413
_refine_diff_density_min         -0.340
_refine_diff_density_rms         0.043
_refine_ls_extinction_coef       0.0021(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     255
_refine_ls_number_reflns         3870
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0351
_refine_ls_R_factor_gt           0.0330
_refine_ls_restrained_S_all      1.036
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0443P)²+0.8992P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0857
_refine_ls_wR_factor_ref         0.0874
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C13(H13)
2.b Secondary CH2 refined with riding coordinates:
 C14(H14A,H14B)
2.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12), C15(H15), C20(H20), C21(H21), C22(H22), C23(H23), C24(H24)
2.d Idealised Me refined as rotating group:
 C18(H18A,H18B,H18C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.59330(3) 0.25720(2) 0.41361(2) 0.01459(11) Uani 1 1 d . . . . .
O1 O 0.54234(8) 0.17194(7) 0.34260(6) 0.0193(2) Uani 1 1 d . . . . .
O2 O 0.39733(8) 0.49389(8) 0.35220(7) 0.0235(2) Uani 1 1 d . . . . .
N1 N 0.21089(10) 0.42390(9) 0.30980(8) 0.0197(2) Uani 1 1 d . . . . .
C1 C 0.66176(11) 0.36883(10) 0.36150(9) 0.0165(3) Uani 1 1 d . . . . .
C2 C 0.69596(12) 0.34481(11) 0.27737(9) 0.0219(3) Uani 1 1 d . . . . .
H2 H 0.674427 0.275965 0.246881 0.026 Uiso 1 1 calc R U . . .
C3 C 0.76148(13) 0.42116(12) 0.23783(10) 0.0262(3) Uani 1 1 d . . . . .
H3 H 0.784840 0.404111 0.180613 0.031 Uiso 1 1 calc R U . . .
C4 C 0.79280(13) 0.52193(12) 0.28153(10) 0.0254(3) Uani 1 1 d . . . . .
H4 H 0.838843 0.573427 0.255057 0.030 Uiso 1 1 calc R U . . .
C5 C 0.75663(13) 0.54734(11) 0.36415(10) 0.0247(3) Uani 1 1 d . . . . .
H5 H 0.776596 0.617071 0.393516 0.030 Uiso 1 1 calc R U . . .
C6 C 0.69127(12) 0.47130(11) 0.40429(9) 0.0215(3) Uani 1 1 d . . . . .
H6 H 0.666745 0.489215 0.460862 0.026 Uiso 1 1 calc R U . . .
C7 C 0.71262(11) 0.20086(10) 0.50260(9) 0.0163(3) Uani 1 1 d . . . . .
C8 C 0.77204(12) 0.26241(11) 0.57964(9) 0.0192(3) Uani 1 1 d . . . . .
H8 H 0.747702 0.336122 0.588607 0.023 Uiso 1 1 calc R U . . .
C9 C 0.86659(12) 0.21612(12) 0.64316(9) 0.0227(3) Uani 1 1 d . . . . .
H9 H 0.906354 0.257774 0.695798 0.027 Uiso 1 1 calc R U . . .
C10 C 0.90270(12) 0.10857(12) 0.62928(10) 0.0257(3) Uani 1 1 d . . . . .
H10 H 0.967785 0.077093 0.672285 0.031 Uiso 1 1 calc R U . . .
C11 C 0.84435(13) 0.04703(12) 0.55312(11) 0.0267(3) Uani 1 1 d . . . . .
H11 H 0.869769 -0.026222 0.543788 0.032 Uiso 1 1 calc R U . . .
C12 C 0.74847(12) 0.09258(11) 0.49029(9) 0.0212(3) Uani 1 1 d . . . . .
H12 H 0.707376 0.049745 0.438901 0.025 Uiso 1 1 calc R U . . .
C13 C 0.48852(11) 0.30853(10) 0.48035(9) 0.0170(3) Uani 1 1 d . . . . .
H13 H 0.520385 0.368759 0.525864 0.020 Uiso 1 1 calc R U . . .
C14 C 0.43298(12) 0.20750(11) 0.52543(9) 0.0211(3) Uani 1 1 d . . . . .
H14A H 0.462304 0.133980 0.510460 0.025 Uiso 1 1 calc R U . . .
H14B H 0.435488 0.215328 0.593539 0.025 Uiso 1 1 calc R U . . .
C15 C 0.31706(12) 0.24144(11) 0.46314(10) 0.0211(3) Uani 1 1 d . . . . .
H15 H 0.239249 0.211633 0.453812 0.025 Uiso 1 1 calc R U . . .
C16 C 0.36232(11) 0.32847(11) 0.42551(9) 0.0174(3) Uani 1 1 d . . . . .
C17 C 0.32395(11) 0.42156(10) 0.35948(9) 0.0180(3) Uani 1 1 d . . . . .
C18 C 0.17220(13) 0.50752(12) 0.23673(11) 0.0271(3) Uani 1 1 d . . . . .
H18A H 0.237127 0.559646 0.235934 0.041 Uiso 1 1 calc R U . . .
H18B H 0.103787 0.547780 0.250017 0.041 Uiso 1 1 calc R U . . .
H18C H 0.149833 0.471044 0.175400 0.041 Uiso 1 1 calc R U . . .
C19 C 0.12281(11) 0.34589(11) 0.32509(9) 0.0188(3) Uani 1 1 d . . . . .
C20 C 0.06201(12) 0.36514(12) 0.39627(10) 0.0249(3) Uani 1 1 d . . . . .
H20 H 0.076912 0.430329 0.433473 0.030 Uiso 1 1 calc R U . . .
C21 C -0.02103(12) 0.28803(14) 0.41265(10) 0.0290(3) Uani 1 1 d . . . . .
H21 H -0.061571 0.299529 0.462324 0.035 Uiso 1 1 calc R U . . .
C22 C -0.04466(12) 0.19452(13) 0.35664(10) 0.0271(3) Uani 1 1 d . . . . .
H22 H -0.101503 0.142092 0.367931 0.033 Uiso 1 1 calc R U . . .
C23 C 0.01443(12) 0.17718(11) 0.28407(10) 0.0234(3) Uani 1 1 d . . . . .
H23 H -0.002747 0.113561 0.245144 0.028 Uiso 1 1 calc R U . . .
C24 C 0.09866(12) 0.25303(11) 0.26851(9) 0.0201(3) Uani 1 1 d . . . . .
H24 H 0.139635 0.241238 0.219139 0.024 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1 1.4891(9) . ?
P1 C1 1.8070(13) . ?
P1 C7 1.8127(13) . ?
P1 C13 1.8114(13) . ?
O2 C17 1.2358(16) . ?
N1 C17 1.3523(17) . ?
N1 C18 1.4660(17) . ?
N1 C19 1.4363(17) . ?
C1 C2 1.3934(18) . ?
C1 C6 1.3942(18) . ?
C2 H2 0.9500 . ?
C2 C3 1.391(2) . ?
C3 H3 0.9500 . ?
C3 C4 1.385(2) . ?
C4 H4 0.9500 . ?
C4 C5 1.387(2) . ?
C5 H5 0.9500 . ?
C5 C6 1.3916(19) . ?
C6 H6 0.9500 . ?
C7 C8 1.3986(18) . ?
C7 C12 1.3935(18) . ?
C8 H8 0.9500 . ?
C8 C9 1.3903(19) . ?
C9 H9 0.9500 . ?
C9 C10 1.391(2) . ?
C10 H10 0.9500 . ?
C10 C11 1.386(2) . ?
C11 H11 0.9500 . ?
C11 C12 1.3917(19) . ?
C12 H12 0.9500 . ?
C13 H13 1.0000 . ?
C13 C14 1.5824(18) . ?
C13 C16 1.5253(17) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C14 C15 1.5063(18) . ?
C15 H15 0.9500 . ?
C15 C16 1.3399(19) . ?
C16 C17 1.4843(18) . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 C20 1.3871(19) . ?
C19 C24 1.3839(18) . ?
C20 H20 0.9500 . ?
C20 C21 1.391(2) . ?
C21 H21 0.9500 . ?
C21 C22 1.385(2) . ?
C22 H22 0.9500 . ?
C22 C23 1.388(2) . ?
C23 H23 0.9500 . ?
C23 C24 1.3876(19) . ?
C24 H24 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 P1 C1 111.56(6) . . ?
O1 P1 C7 111.51(6) . . ?
O1 P1 C13 113.44(6) . . ?
C1 P1 C7 104.25(6) . . ?
C1 P1 C13 111.70(6) . . ?
C13 P1 C7 103.73(6) . . ?
C17 N1 C18 120.98(11) . . ?
C17 N1 C19 122.53(11) . . ?
C19 N1 C18 116.49(10) . . ?
C2 C1 P1 116.30(10) . . ?
C2 C1 C6 119.30(12) . . ?
C6 C1 P1 124.12(10) . . ?
C1 C2 H2 119.9 . . ?
C3 C2 C1 120.30(13) . . ?
C3 C2 H2 119.9 . . ?
C2 C3 H3 119.9 . . ?
C4 C3 C2 120.26(13) . . ?
C4 C3 H3 119.9 . . ?
C3 C4 H4 120.2 . . ?
C3 C4 C5 119.68(13) . . ?
C5 C4 H4 120.2 . . ?
C4 C5 H5 119.8 . . ?
C4 C5 C6 120.41(13) . . ?
C6 C5 H5 119.8 . . ?
C1 C6 H6 120.0 . . ?
C5 C6 C1 120.02(12) . . ?
C5 C6 H6 120.0 . . ?
C8 C7 P1 122.99(10) . . ?
C12 C7 P1 117.47(10) . . ?
C12 C7 C8 119.49(12) . . ?
C7 C8 H8 119.9 . . ?
C9 C8 C7 120.25(12) . . ?
C9 C8 H8 119.9 . . ?
C8 C9 H9 120.1 . . ?
C8 C9 C10 119.70(13) . . ?
C10 C9 H9 120.1 . . ?
C9 C10 H10 119.8 . . ?
C11 C10 C9 120.42(13) . . ?
C11 C10 H10 119.8 . . ?
C10 C11 H11 120.0 . . ?
C10 C11 C12 119.97(13) . . ?
C12 C11 H11 120.0 . . ?
C7 C12 H12 119.9 . . ?
C11 C12 C7 120.16(13) . . ?
C11 C12 H12 119.9 . . ?
P1 C13 H13 114.2 . . ?
C14 C13 P1 109.43(9) . . ?
C14 C13 H13 114.2 . . ?
C16 C13 P1 116.39(9) . . ?
C16 C13 H13 114.2 . . ?
C16 C13 C14 85.03(9) . . ?
C13 C14 H14A 114.4 . . ?
C13 C14 H14B 114.4 . . ?
H14A C14 H14B 111.5 . . ?
C15 C14 C13 85.78(10) . . ?
C15 C14 H14A 114.4 . . ?
C15 C14 H14B 114.4 . . ?
C14 C15 H15 132.5 . . ?
C16 C15 C14 94.95(11) . . ?
C16 C15 H15 132.5 . . ?
C15 C16 C13 94.22(11) . . ?
C15 C16 C17 140.26(12) . . ?
C17 C16 C13 125.48(11) . . ?
O2 C17 N1 122.73(12) . . ?
O2 C17 C16 118.25(11) . . ?
N1 C17 C16 119.02(11) . . ?
N1 C18 H18A 109.5 . . ?
N1 C18 H18B 109.5 . . ?
N1 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 N1 119.41(12) . . ?
C24 C19 N1 119.94(12) . . ?
C24 C19 C20 120.65(13) . . ?
C19 C20 H20 120.3 . . ?
C19 C20 C21 119.35(13) . . ?
C21 C20 H20 120.3 . . ?
C20 C21 H21 120.0 . . ?
C22 C21 C20 120.10(13) . . ?
C22 C21 H21 120.0 . . ?
C21 C22 H22 119.9 . . ?
C21 C22 C23 120.21(13) . . ?
C23 C22 H22 119.9 . . ?
C22 C23 H23 120.1 . . ?
C24 C23 C22 119.83(13) . . ?
C24 C23 H23 120.1 . . ?
C19 C24 C23 119.83(13) . . ?
C19 C24 H24 120.1 . . ?
C23 C24 H24 120.1 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 C1 C2 C3 -172.54(11) . . . . ?
P1 C1 C6 C5 172.20(10) . . . . ?
P1 C7 C8 C9 -176.96(10) . . . . ?
P1 C7 C12 C11 176.07(11) . . . . ?
P1 C13 C14 C15 -115.36(9) . . . . ?
P1 C13 C16 C15 108.24(10) . . . . ?
P1 C13 C16 C17 -73.73(14) . . . . ?
O1 P1 C1 C2 -22.00(12) . . . . ?
O1 P1 C1 C6 164.12(10) . . . . ?
O1 P1 C7 C8 -177.15(10) . . . . ?
O1 P1 C7 C12 5.47(12) . . . . ?
O1 P1 C13 C14 53.71(10) . . . . ?
O1 P1 C13 C16 -40.45(11) . . . . ?
N1 C19 C20 C21 -178.29(12) . . . . ?
N1 C19 C24 C23 179.32(12) . . . . ?
C1 P1 C7 C8 62.35(12) . . . . ?
C1 P1 C7 C12 -115.03(10) . . . . ?
C1 P1 C13 C14 -179.16(8) . . . . ?
C1 P1 C13 C16 86.67(10) . . . . ?
C1 C2 C3 C4 -0.3(2) . . . . ?
C2 C1 C6 C5 -1.51(19) . . . . ?
C2 C3 C4 C5 -1.2(2) . . . . ?
C3 C4 C5 C6 1.3(2) . . . . ?
C4 C5 C6 C1 0.0(2) . . . . ?
C6 C1 C2 C3 1.65(19) . . . . ?
C7 P1 C1 C2 98.47(10) . . . . ?
C7 P1 C1 C6 -75.40(12) . . . . ?
C7 P1 C13 C14 -67.45(9) . . . . ?
C7 P1 C13 C16 -161.61(9) . . . . ?
C7 C8 C9 C10 0.6(2) . . . . ?
C8 C7 C12 C11 -1.4(2) . . . . ?
C8 C9 C10 C11 -0.6(2) . . . . ?
C9 C10 C11 C12 -0.4(2) . . . . ?
C10 C11 C12 C7 1.4(2) . . . . ?
C12 C7 C8 C9 0.37(19) . . . . ?
C13 P1 C1 C2 -150.14(10) . . . . ?
C13 P1 C1 C6 35.98(13) . . . . ?
C13 P1 C7 C8 -54.71(12) . . . . ?
C13 P1 C7 C12 127.91(10) . . . . ?
C13 C14 C15 C16 -1.03(10) . . . . ?
C13 C16 C17 O2 -5.24(19) . . . . ?
C13 C16 C17 N1 174.64(12) . . . . ?
C14 C13 C16 C15 -1.01(10) . . . . ?
C14 C13 C16 C17 177.02(12) . . . . ?
C14 C15 C16 C13 1.07(11) . . . . ?
C14 C15 C16 C17 -176.43(16) . . . . ?
C15 C16 C17 O2 171.68(16) . . . . ?
C15 C16 C17 N1 -8.4(2) . . . . ?
C16 C13 C14 C15 0.90(9) . . . . ?
C17 N1 C19 C20 83.93(16) . . . . ?
C17 N1 C19 C24 -96.61(15) . . . . ?
C18 N1 C17 O2 6.3(2) . . . . ?
C18 N1 C17 C16 -173.57(11) . . . . ?
C18 N1 C19 C20 -96.09(15) . . . . ?
C18 N1 C19 C24 83.38(15) . . . . ?
C19 N1 C17 O2 -173.71(12) . . . . ?
C19 N1 C17 C16 6.41(18) . . . . ?
C19 C20 C21 C22 -1.7(2) . . . . ?
C20 C19 C24 C23 -1.23(19) . . . . ?
C20 C21 C22 C23 0.1(2) . . . . ?
C21 C22 C23 C24 0.9(2) . . . . ?
C22 C23 C24 C19 -0.4(2) . . . . ?
C24 C19 C20 C21 2.2(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.479
_oxdiff_exptl_absorpt_empirical_full_min 0.586
