# Supplementary Information (SI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_231201lu_lgpz271048_0m
_database_code_depnum_ccdc_archive 'CCDC 2427309'
loop_
_audit_author_name
_audit_author_address
'Lu Zhao'
;Qingdao University of Science and Technology
China
;
_audit_update_record             
;
2025-02-27 deposited with the CCDC.	2025-06-02 downloaded from the CCDC.
;
_audit_creation_date             2023-12-02
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2019/3
_chemical_name_common            ?
_chemical_name_systematic        '[Eu2(Phen)4(CO3)3(H2O)2]n'
_chemical_formula_moiety         'C51 H33 Eu2 N8 O11, 11(H2 O), H5 O2, O'
_chemical_formula_sum            'C51 H60 Eu2 N8 O25'
_chemical_formula_weight         1488.99
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   23.988(6)
_cell_length_b                   12.672(3)
_cell_length_c                   19.276(5)
_cell_angle_alpha                90
_cell_angle_beta                 101.714(9)
_cell_angle_gamma                90
_cell_volume                     5737(2)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9854
_cell_measurement_temperature    293.30
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      2.69
_shelx_estimated_absorpt_T_max   0.823
_shelx_estimated_absorpt_T_min   0.758
_exptl_absorpt_coefficient_mu    2.258
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5728
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1479 before and 0.0571 after correction.
The Ratio of minimum to maximum transmission is 0.7682.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.724
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2992
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.09
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0471
_diffrn_reflns_av_unetI/netI     0.0406
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            26781
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.541
_diffrn_reflns_theta_min         1.826
_diffrn_ambient_temperature      293.30
_diffrn_detector                 CPAD
_diffrn_detector_area_resol_mean 7.41
_diffrn_detector_type            'Bruker PHOTON II'
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 VENTURE TXS PHOTON II'
_diffrn_measurement_method       'ω and φ shutterless scans'
_diffrn_measurement_specimen_support 'nylon loop'
_diffrn_radiation_monochromator  'Helios Multi-layer Optic'
_diffrn_radiation_probe          X-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   TXS
_diffrn_source_current           40.0
_diffrn_source_power             1.8
_diffrn_source_type              'Rotaing Anode'
_diffrn_source_voltage           45.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                5483
_reflns_number_total             6590
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (Bruker, 2019)'
_computing_data_collection       'APEX5 V2023.9-2 (Bruker, 2023)'
_computing_data_reduction        'SAINT V8.40B (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.654
_refine_diff_density_min         -0.466
_refine_diff_density_rms         0.095
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     413
_refine_ls_number_reflns         6590
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0408
_refine_ls_R_factor_gt           0.0290
_refine_ls_restrained_S_all      1.033
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0233P)²+13.5951P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0629
_refine_ls_wR_factor_ref         0.0685
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Shared sites
{O12, O12A}
{O6, O6A}
3. Restrained distances
 Eu1-H13A \\sim Eu1-H13B
 with sigma of 0.02
4. Uiso/Uaniso restraints and constraints
Uanis(O12) = Uanis(O12A)
Uanis(O6) = Uanis(O6A)
5. Others
 Fixed Sof: O6(0.5) H6A(0.5) H6B(0.5) O12(0.5) H12A(0.5) H12B(0.5) O12A(0.5)
 H12C(0.5) H12D(0.5) O6A(0.5) H(0.5) HA(0.5)
6.a Riding coordinates:
 O12(H12A,H12B), O12A(H12C,H12D)
6.b Free rotating group:
 O8(H8A,H8B), O13(H13A,H13B), O6(H6A,H6B), O7(H7A,H7B), O9(H9A,H9B), O10(H10A,
 H10B), O11(H11A,H11B), O6A(H,HA)
6.c Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C8(H8), C9(H9), C10(H10), C11(H11), C14(H14),
 C15(H15), C20(H20), C21(H21), C22(H22), C23(H23), C24(H24)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.42776(2) 0.27464(2) 0.64135(2) 0.02064(5) Uani 1 1 d D . . . .
O1 O 0.40259(10) 0.2511(2) 0.51559(13) 0.0347(6) Uani 1 1 d . . . . .
O2 O 0.34408(10) 0.1912(2) 0.58022(13) 0.0351(6) Uani 1 1 d . . . . .
O3 O 0.32283(11) 0.1678(2) 0.46297(14) 0.0445(7) Uani 1 1 d . . . . .
O4 O 0.500000 0.2873(2) 0.750000 0.0255(7) Uani 1 2 d S T P . .
O5 O 0.53614(9) 0.43741(17) 0.79718(12) 0.0282(5) Uani 1 1 d . . . . .
O8 O 0.23955(14) 0.1782(3) 0.6190(2) 0.0707(10) Uani 1 1 d G . . . .
H8A H 0.219475 0.225995 0.594980 0.106 Uiso 1 1 d G U . . .
H8B H 0.272647 0.186884 0.610464 0.106 Uiso 1 1 d G U . . .
O13 O 0.36517(11) 0.4238(2) 0.60160(15) 0.0404(6) Uani 1 1 d G . . . .
H13A H 0.334068 0.421901 0.571207 0.061 Uiso 1 1 d DG U . . .
H13B H 0.363977 0.481975 0.623215 0.061 Uiso 1 1 d DG U . . .
N1 N 0.51619(11) 0.3265(2) 0.58987(15) 0.0275(6) Uani 1 1 d . . . . .
N2 N 0.49270(11) 0.1220(2) 0.61866(14) 0.0251(6) Uani 1 1 d . . . . .
N3 N 0.41551(11) 0.0952(2) 0.69924(14) 0.0242(6) Uani 1 1 d . . . . .
N4 N 0.36843(12) 0.2747(2) 0.73966(15) 0.0282(6) Uani 1 1 d . . . . .
C1 C 0.52974(15) 0.4251(3) 0.5775(2) 0.0352(8) Uani 1 1 d . . . . .
H1 H 0.510468 0.479255 0.595109 0.042 Uiso 1 1 calc R U . . .
C2 C 0.57136(17) 0.4523(3) 0.5394(2) 0.0407(9) Uani 1 1 d . . . . .
H2 H 0.579689 0.522739 0.532631 0.049 Uiso 1 1 calc R U . . .
C3 C 0.59928(16) 0.3749(3) 0.5125(2) 0.0401(9) Uani 1 1 d . . . . .
H3 H 0.626320 0.391666 0.485844 0.048 Uiso 1 1 calc R U . . .
C4 C 0.58732(14) 0.2689(3) 0.52490(19) 0.0306(7) Uani 1 1 d . . . . .
C5 C 0.54543(14) 0.2483(3) 0.56465(18) 0.0264(7) Uani 1 1 d . . . . .
C6 C 0.53393(13) 0.1408(2) 0.58109(17) 0.0248(7) Uani 1 1 d . . . . .
C7 C 0.56567(14) 0.0587(3) 0.55851(19) 0.0305(7) Uani 1 1 d . . . . .
C8 C 0.60765(15) 0.0832(3) 0.5177(2) 0.0397(9) Uani 1 1 d . . . . .
H8 H 0.628275 0.028705 0.502569 0.048 Uiso 1 1 calc R U . . .
C9 C 0.61778(16) 0.1826(3) 0.5009(2) 0.0411(9) Uani 1 1 d . . . . .
H9 H 0.644679 0.196297 0.473415 0.049 Uiso 1 1 calc R U . . .
C10 C 0.55528(16) -0.0433(3) 0.5785(2) 0.0383(9) Uani 1 1 d . . . . .
H10 H 0.576199 -0.099090 0.565587 0.046 Uiso 1 1 calc R U . . .
C11 C 0.51424(16) -0.0624(3) 0.6174(2) 0.0371(9) Uani 1 1 d . . . . .
H11 H 0.507266 -0.130770 0.630970 0.044 Uiso 1 1 calc R U . . .
C12 C 0.48296(14) 0.0230(2) 0.63621(18) 0.0274(7) Uani 1 1 d . . . . .
C13 C 0.43790(14) 0.0076(3) 0.67807(18) 0.0279(7) Uani 1 1 d . . . . .
C14 C 0.42039(17) -0.0932(3) 0.6944(2) 0.0415(9) Uani 1 1 d . . . . .
H14 H 0.436380 -0.152887 0.678298 0.050 Uiso 1 1 calc R U . . .
C15 C 0.37961(18) -0.1031(3) 0.7343(2) 0.0451(10) Uani 1 1 d . . . . .
H15 H 0.367499 -0.169696 0.745075 0.054 Uiso 1 1 calc R U . . .
C16 C 0.35618(15) -0.0130(3) 0.7588(2) 0.0343(8) Uani 1 1 d . . . . .
C17 C 0.37503(14) 0.0854(3) 0.73882(17) 0.0267(7) Uani 1 1 d . . . . .
C18 C 0.35161(13) 0.1804(3) 0.76251(17) 0.0264(7) Uani 1 1 d . . . . .
C19 C 0.31189(15) 0.1728(3) 0.8068(2) 0.0349(8) Uani 1 1 d . . . . .
C20 C 0.29478(17) 0.0715(3) 0.8266(2) 0.0433(10) Uani 1 1 d . . . . .
H20 H 0.268874 0.066788 0.856453 0.052 Uiso 1 1 calc R U . . .
C21 C 0.31522(17) -0.0173(3) 0.8033(2) 0.0447(10) Uani 1 1 d . . . . .
H21 H 0.302618 -0.082429 0.816151 0.054 Uiso 1 1 calc R U . . .
C22 C 0.29180(18) 0.2671(3) 0.8308(2) 0.0442(10) Uani 1 1 d . . . . .
H22 H 0.265994 0.265305 0.860819 0.053 Uiso 1 1 calc R U . . .
C23 C 0.31014(17) 0.3613(3) 0.8100(2) 0.0437(10) Uani 1 1 d . . . . .
H23 H 0.297502 0.424328 0.826110 0.052 Uiso 1 1 calc R U . . .
C24 C 0.34827(16) 0.3618(3) 0.7640(2) 0.0375(9) Uani 1 1 d . . . . .
H24 H 0.360168 0.426611 0.749596 0.045 Uiso 1 1 calc R U . . .
C25 C 0.500000 0.3898(3) 0.750000 0.0227(9) Uani 1 2 d S T P . .
C26 C 0.35501(14) 0.2029(3) 0.5177(2) 0.0308(8) Uani 1 1 d . . . . .
O6 O 0.22810(13) -0.1599(2) 0.46308(16) 0.0496(7) Uani 0.5 1 d G . P A 1
H6A H 0.241432 -0.202824 0.496220 0.074 Uiso 0.5 1 d G U P A 1
H6B H 0.235446 -0.099245 0.481492 0.074 Uiso 0.5 1 d G U P A 1
O7 O 0.23593(14) 0.0542(2) 0.49304(18) 0.0570(8) Uani 1 1 d G . . . .
H7A H 0.231239 0.078451 0.532558 0.085 Uiso 1 1 d G U . . .
H7B H 0.262950 0.090787 0.483109 0.085 Uiso 1 1 d G U . . .
O9 O 0.43163(15) 0.3048(3) 0.3880(2) 0.0646(9) Uani 1 1 d G . . . .
H9A H 0.420707 0.282705 0.424743 0.097 Uiso 1 1 d G U . . .
H9B H 0.400999 0.320498 0.359205 0.097 Uiso 1 1 d G U . . .
O10 O 0.33577(15) 0.6355(4) 0.7927(2) 0.0805(12) Uani 1 1 d G . . . .
H10A H 0.327009 0.642633 0.747995 0.121 Uiso 1 1 d G U . . .
H10B H 0.305431 0.650813 0.806891 0.121 Uiso 1 1 d G U . . .
O11 O 0.35381(12) 0.6282(2) 0.65800(17) 0.0509(7) Uani 1 1 d G . . . .
H11A H 0.330689 0.662513 0.626821 0.076 Uiso 1 1 d G U . . .
H11B H 0.386160 0.655070 0.657278 0.076 Uiso 1 1 d G U . . .
O12 O 0.47267(12) 0.6498(2) 0.67590(16) 0.0493(7) Uani 0.5 1 d . . P B 1
H12A H 0.461642 0.605249 0.703190 0.074 Uiso 0.5 1 d R U P B 1
H12B H 0.496182 0.688809 0.703460 0.074 Uiso 0.5 1 d R U P B 1
O12A O 0.47267(12) 0.6498(2) 0.67590(16) 0.0493(7) Uani 0.5 1 d . . P C 2
H12C H 0.465972 0.603589 0.712430 0.074 Uiso 0.5 1 d R U P C 2
H12D H 0.500523 0.687149 0.712710 0.074 Uiso 0.5 1 d R U P C 2
O6A O 0.22810(13) -0.1599(2) 0.46308(16) 0.0496(7) Uani 0.5 1 d G . P D 2
H H -0.073081 -0.074905 -1.564524 0.074 Uiso 0.5 1 d G U P D 2
HA H -0.037980 -0.156356 -1.542722 0.074 Uiso 0.5 1 d G U P D 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.395(3) . ?
Eu1 O2 2.361(2) . ?
Eu1 O4 2.4375(6) . ?
Eu1 O5 2.448(2) 2_656 ?
Eu1 O13 2.439(2) . ?
Eu1 N1 2.602(3) . ?
Eu1 N2 2.576(3) . ?
Eu1 N3 2.576(3) . ?
Eu1 N4 2.591(3) . ?
Eu1 C25 2.836(2) . ?
Eu1 C26 2.804(4) . ?
O1 C26 1.302(4) . ?
O2 C26 1.293(4) . ?
O3 C26 1.255(4) . ?
O4 C25 1.298(5) . ?
O5 C25 1.274(3) . ?
O8 H8A 0.8500 . ?
O8 H8B 0.8499 . ?
O13 H13A 0.8502 . ?
O13 H13B 0.8501 . ?
N1 C1 1.324(4) . ?
N1 C5 1.360(4) . ?
N2 C6 1.360(4) . ?
N2 C12 1.332(4) . ?
N3 C13 1.333(4) . ?
N3 C17 1.357(4) . ?
N4 C18 1.363(4) . ?
N4 C24 1.327(4) . ?
C1 H1 0.9300 . ?
C1 C2 1.397(5) . ?
C2 H2 0.9300 . ?
C2 C3 1.349(5) . ?
C3 H3 0.9300 . ?
C3 C4 1.404(5) . ?
C4 C5 1.406(4) . ?
C4 C9 1.443(5) . ?
C5 C6 1.439(4) . ?
C6 C7 1.409(4) . ?
C7 C8 1.432(5) . ?
C7 C10 1.386(5) . ?
C8 H8 0.9300 . ?
C8 C9 1.335(5) . ?
C9 H9 0.9300 . ?
C10 H10 0.9300 . ?
C10 C11 1.374(5) . ?
C11 H11 0.9300 . ?
C11 C12 1.406(4) . ?
C12 C13 1.487(4) . ?
C13 C14 1.399(5) . ?
C14 H14 0.9300 . ?
C14 C15 1.367(5) . ?
C15 H15 0.9300 . ?
C15 C16 1.396(5) . ?
C16 C17 1.406(5) . ?
C16 C21 1.431(5) . ?
C17 C18 1.441(5) . ?
C18 C19 1.406(4) . ?
C19 C20 1.424(5) . ?
C19 C22 1.401(5) . ?
C20 H20 0.9300 . ?
C20 C21 1.341(6) . ?
C21 H21 0.9300 . ?
C22 H22 0.9300 . ?
C22 C23 1.360(5) . ?
C23 H23 0.9300 . ?
C23 C24 1.397(5) . ?
C24 H24 0.9300 . ?
O6 H6A 0.8501 . ?
O6 H6B 0.8504 . ?
O7 H7A 0.8499 . ?
O7 H7B 0.8498 . ?
O9 H9A 0.8499 . ?
O9 H9B 0.8502 . ?
O10 H10A 0.8499 . ?
O10 H10B 0.8498 . ?
O11 H11A 0.8499 . ?
O11 H11B 0.8501 . ?
O12 H12A 0.8501 . ?
O12 H12B 0.8499 . ?
O12A H12C 0.9546 . ?
O12A H12D 0.9903 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O4 150.12(6) . . ?
O1 Eu1 O5 125.92(8) . 2_656 ?
O1 Eu1 O13 76.47(9) . . ?
O1 Eu1 N1 72.72(9) . . ?
O1 Eu1 N2 76.79(9) . . ?
O1 Eu1 N3 107.52(9) . . ?
O1 Eu1 N4 132.64(9) . . ?
O1 Eu1 C25 143.34(7) . . ?
O1 Eu1 C26 27.60(9) . . ?
O2 Eu1 O1 54.90(8) . . ?
O2 Eu1 O4 147.39(8) . . ?
O2 Eu1 O5 143.15(8) . 2_656 ?
O2 Eu1 O13 77.49(9) . . ?
O2 Eu1 N1 126.80(9) . . ?
O2 Eu1 N2 93.52(9) . . ?
O2 Eu1 N3 70.17(9) . . ?
O2 Eu1 N4 80.08(9) . . ?
O2 Eu1 C25 158.27(6) . . ?
O2 Eu1 C26 27.30(9) . . ?
O4 Eu1 O5 53.75(8) . 2_656 ?
O4 Eu1 O13 120.26(9) . . ?
O4 Eu1 N1 79.55(7) . . ?
O4 Eu1 N2 81.16(8) . . ?
O4 Eu1 N3 79.02(9) . . ?
O4 Eu1 N4 76.80(7) . . ?
O4 Eu1 C25 27.18(10) . . ?
O4 Eu1 C26 164.33(9) . . ?
O5 Eu1 N1 74.69(8) 2_656 . ?
O5 Eu1 N2 123.24(8) 2_656 . ?
O5 Eu1 N3 126.47(8) 2_656 . ?
O5 Eu1 N4 80.70(8) 2_656 . ?
O5 Eu1 C25 26.62(9) 2_656 . ?
O5 Eu1 C26 141.50(9) 2_656 . ?
O13 Eu1 O5 68.51(8) . 2_656 ?
O13 Eu1 N1 100.48(9) . . ?
O13 Eu1 N2 152.08(9) . . ?
O13 Eu1 N3 134.69(9) . . ?
O13 Eu1 N4 80.49(9) . . ?
O13 Eu1 C25 94.49(9) . . ?
O13 Eu1 C26 75.35(9) . . ?
N1 Eu1 C25 74.24(7) . . ?
N1 Eu1 C26 99.94(10) . . ?
N2 Eu1 N1 63.71(9) . . ?
N2 Eu1 N3 62.41(8) . . ?
N2 Eu1 N4 124.44(8) . . ?
N2 Eu1 C25 102.22(9) . . ?
N2 Eu1 C26 84.59(9) . . ?
N3 Eu1 N1 124.18(8) . . ?
N3 Eu1 N4 63.62(8) . . ?
N3 Eu1 C25 103.92(9) . . ?
N3 Eu1 C26 88.62(10) . . ?
N4 Eu1 N1 152.90(9) . . ?
N4 Eu1 C25 78.67(7) . . ?
N4 Eu1 C26 106.40(10) . . ?
C26 Eu1 C25 167.39(10) . . ?
C26 O1 Eu1 94.0(2) . . ?
C26 O2 Eu1 95.8(2) . . ?
Eu1 O4 Eu1 172.45(13) . 2_656 ?
C25 O4 Eu1 93.77(7) . . ?
C25 O4 Eu1 93.77(7) . 2_656 ?
C25 O5 Eu1 93.9(2) . 2_656 ?
H8A O8 H8B 104.5 . . ?
Eu1 O13 H13A 126.3 . . ?
Eu1 O13 H13B 126.7 . . ?
H13A O13 H13B 104.5 . . ?
C1 N1 Eu1 123.8(2) . . ?
C1 N1 C5 117.3(3) . . ?
C5 N1 Eu1 118.2(2) . . ?
C6 N2 Eu1 119.3(2) . . ?
C12 N2 Eu1 121.4(2) . . ?
C12 N2 C6 118.9(3) . . ?
C13 N3 Eu1 121.0(2) . . ?
C13 N3 C17 118.3(3) . . ?
C17 N3 Eu1 118.8(2) . . ?
C18 N4 Eu1 118.6(2) . . ?
C24 N4 Eu1 123.5(2) . . ?
C24 N4 C18 117.5(3) . . ?
N1 C1 H1 118.1 . . ?
N1 C1 C2 123.7(3) . . ?
C2 C1 H1 118.1 . . ?
C1 C2 H2 120.5 . . ?
C3 C2 C1 119.1(3) . . ?
C3 C2 H2 120.5 . . ?
C2 C3 H3 120.2 . . ?
C2 C3 C4 119.7(3) . . ?
C4 C3 H3 120.2 . . ?
C3 C4 C5 117.6(3) . . ?
C3 C4 C9 122.4(3) . . ?
C5 C4 C9 119.9(3) . . ?
N1 C5 C4 122.5(3) . . ?
N1 C5 C6 118.4(3) . . ?
C4 C5 C6 119.1(3) . . ?
N2 C6 C5 118.4(3) . . ?
N2 C6 C7 122.2(3) . . ?
C7 C6 C5 119.4(3) . . ?
C6 C7 C8 119.6(3) . . ?
C10 C7 C6 117.6(3) . . ?
C10 C7 C8 122.8(3) . . ?
C7 C8 H8 119.3 . . ?
C9 C8 C7 121.4(3) . . ?
C9 C8 H8 119.3 . . ?
C4 C9 H9 119.7 . . ?
C8 C9 C4 120.5(3) . . ?
C8 C9 H9 119.7 . . ?
C7 C10 H10 119.8 . . ?
C11 C10 C7 120.4(3) . . ?
C11 C10 H10 119.8 . . ?
C10 C11 H11 120.5 . . ?
C10 C11 C12 118.9(3) . . ?
C12 C11 H11 120.5 . . ?
N2 C12 C11 121.9(3) . . ?
N2 C12 C13 116.5(3) . . ?
C11 C12 C13 121.6(3) . . ?
N3 C13 C12 116.0(3) . . ?
N3 C13 C14 122.2(3) . . ?
C14 C13 C12 121.8(3) . . ?
C13 C14 H14 120.3 . . ?
C15 C14 C13 119.5(3) . . ?
C15 C14 H14 120.3 . . ?
C14 C15 H15 120.1 . . ?
C14 C15 C16 119.9(3) . . ?
C16 C15 H15 120.1 . . ?
C15 C16 C17 117.3(3) . . ?
C15 C16 C21 123.0(3) . . ?
C17 C16 C21 119.7(3) . . ?
N3 C17 C16 122.8(3) . . ?
N3 C17 C18 118.1(3) . . ?
C16 C17 C18 119.1(3) . . ?
N4 C18 C17 118.0(3) . . ?
N4 C18 C19 122.5(3) . . ?
C19 C18 C17 119.4(3) . . ?
C18 C19 C20 119.5(3) . . ?
C22 C19 C18 117.6(3) . . ?
C22 C19 C20 122.9(3) . . ?
C19 C20 H20 119.3 . . ?
C21 C20 C19 121.4(3) . . ?
C21 C20 H20 119.3 . . ?
C16 C21 H21 119.6 . . ?
C20 C21 C16 120.8(4) . . ?
C20 C21 H21 119.6 . . ?
C19 C22 H22 120.1 . . ?
C23 C22 C19 119.8(3) . . ?
C23 C22 H22 120.1 . . ?
C22 C23 H23 120.5 . . ?
C22 C23 C24 118.9(3) . . ?
C24 C23 H23 120.5 . . ?
N4 C24 C23 123.5(3) . . ?
N4 C24 H24 118.2 . . ?
C23 C24 H24 118.2 . . ?
Eu1 C25 Eu1 118.09(15) . 2_656 ?
O4 C25 Eu1 59.05(7) . 2_656 ?
O4 C25 Eu1 59.04(7) . . ?
O5 C25 Eu1 59.43(14) 2_656 . ?
O5 C25 Eu1 59.43(14) . 2_656 ?
O5 C25 Eu1 174.95(17) . . ?
O5 C25 Eu1 174.95(17) 2_656 2_656 ?
O5 C25 O4 118.3(2) 2_656 . ?
O5 C25 O4 118.3(2) . . ?
O5 C25 O5 123.4(4) . 2_656 ?
O1 C26 Eu1 58.43(17) . . ?
O2 C26 Eu1 56.89(17) . . ?
O2 C26 O1 115.3(3) . . ?
O3 C26 Eu1 178.2(3) . . ?
O3 C26 O1 122.2(3) . . ?
O3 C26 O2 122.4(3) . . ?
H6A O6 H6B 104.5 . . ?
H7A O7 H7B 104.5 . . ?
H9A O9 H9B 104.5 . . ?
H10A O10 H10B 104.5 . . ?
H11A O11 H11B 104.5 . . ?
H12A O12 H12B 104.5 . . ?
H12C O12A H12D 87.4 . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O8 H8A O3 0.85 1.91 2.754(4) 176.6 7_556 yes
O8 H8B O2 0.85 1.92 2.763(4) 171.4 . yes
O13 H13A O7 0.85 1.90 2.737(4) 169.0 7_556 yes
O13 H13B O11 0.85 2.00 2.843(4) 170.1 . yes
O6 H6A O6 0.85 1.99 2.781(6) 155.4 7_546 yes
O6 H6B O7 0.85 1.96 2.773(4) 160.4 . yes
O7 H7A O8 0.85 2.07 2.878(6) 159.1 . yes
O7 H7B O3 0.85 1.84 2.691(4) 178.5 . yes
O9 H9A O1 0.85 1.93 2.773(4) 171.0 . yes
O9 H9B O10 0.85 1.89 2.742(5) 175.6 6_565 yes
O10 H10A O11 0.85 1.98 2.720(5) 145.4 . yes
O10 H10B O8 0.85 1.99 2.775(5) 153.6 4_556 yes
O11 H11A O6 0.85 2.00 2.758(4) 148.0 7_556 yes
O11 H11A O6A 0.85 2.00 2.758(4) 148.0 7_556 yes
O11 H11B O12 0.85 2.03 2.815(4) 152.4 . yes
O11 H11B O12A 0.85 2.03 2.815(4) 152.4 . yes
O12 H12A O5 0.85 2.13 2.758(3) 130.6 2_656 yes
O12 H12B O12 0.85 2.35 2.891(6) 122.3 2_656 yes
O12A H12C O5 0.95 2.11 2.758(3) 123.5 2_656 yes
O12A H12D O12A 0.99 2.16 2.891(6) 128.9 2_656 yes

_olex2_submission_special_instructions 'No special instructions were received'
_site                            XU
_exptl_crystal_recrystallization_method Sublimation
_chemical_properties_physical    Light-sensitive
_exptl_crystal_preparation       Luminescent
