# Supplementary Information (SI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_250620ha_z1899367_0m
_database_code_depnum_ccdc_archive 'CCDC 2499388'
loop_
_audit_author_name
_audit_author_address
'Bo Yang'
;Zhengzhou University
China
;
_audit_update_record             
;
2025-10-31 deposited with the CCDC.	2026-04-20 downloaded from the CCDC.
;
_audit_creation_date             2025-09-18
_audit_creation_method           
;
Olex2 1.5
(compiled 2025.07.13 svn.rb7424aed for OlexSys, GUI svn.r7314)
;
_shelx_SHELXL_version_number     2019/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C226 H207 Eu3 K2 N2 O36'
_chemical_formula_sum            'C226 H207 Eu3 K2 N2 O36'
_chemical_formula_weight         4061.00
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -8.9294 11.1857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.3868 1.0657 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        P-1
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.2417(15)
_cell_length_b                   23.613(2)
_cell_length_c                   24.022(2)
_cell_angle_alpha                79.559(6)
_cell_angle_beta                 87.183(6)
_cell_angle_gamma                86.107(7)
_cell_volume                     7920.7(13)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    9512
_cell_measurement_temperature    200.00
_cell_measurement_theta_max      61.84
_cell_measurement_theta_min      3.11
_shelx_estimated_absorpt_T_max   0.700
_shelx_estimated_absorpt_T_min   0.574
_exptl_absorpt_coefficient_mu    4.804
_exptl_absorpt_correction_T_max  0.7531
_exptl_absorpt_correction_T_min  0.5107
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1151 before and 0.0806 after correction.
The Ratio of minimum to maximum transmission is 0.6781.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    0.851
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2092
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.11
_exptl_crystal_size_min          0.08
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1208
_diffrn_reflns_av_unetI/netI     0.1177
_diffrn_reflns_Laue_measured_fraction_full 0.962
_diffrn_reflns_Laue_measured_fraction_max 0.953
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            86484
_diffrn_reflns_point_group_measured_fraction_full 0.962
_diffrn_reflns_point_group_measured_fraction_max 0.953
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         68.814
_diffrn_reflns_theta_min         3.551
_diffrn_ambient_temperature      200.00
_diffrn_detector                 CPAD
_diffrn_detector_area_resol_mean 7.41
_diffrn_detector_type            'Bruker PHOTON III'
_diffrn_measured_fraction_theta_full 0.962
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 VENTURE dual wavelength Mo/Cu'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'Helios Multi-layer Optic'
_diffrn_radiation_probe          X-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           1.1
_diffrn_source_power             0.05500000000000001
_diffrn_source_type              'Incoatec I\ms DIAMOND'
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                11856
_reflns_number_total             27990
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.41 (Bruker, 2024)'
_computing_data_collection       'APEX6 V2024.9-1 (Bruker, 2024)'
_computing_data_reduction        'SAINT V8.41 (Bruker, 2024)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2025/1 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         1.332
_refine_diff_density_min         -0.752
_refine_diff_density_rms         0.094
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1136
_refine_ls_number_reflns         27990
_refine_ls_number_restraints     926
_refine_ls_R_factor_all          0.1926
_refine_ls_R_factor_gt           0.1284
_refine_ls_restrained_S_all      1.140
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0800P)²+20.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3088
_refine_ls_wR_factor_ref         0.3456
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Restrained distances
 O3-C92 = O4-C92 = O1-C1 = O2-C1 = O17-C75 = O8-C75 = O5-C49 = O6-C49
 1.25 with sigma of 0.01
 C92-C89 = C1-C2 = C49-C46 = C75-C72
 1.5 with sigma of 0.01
 C99-C98 = C97-C96 = C111-C110 = C109-C108 = C107-C106 = C105-C104 = C101-C100
 = C103-C102
 1.5 with sigma of 0.01
 O11-C102 = O11-C61 = O12-C58 = O12-C100 = O9-C64 = O9-C106 = O10-C53 = O10-
 C104 = O16-C108 = O16-C25 = O15-C28 = O15-C110 = O14-C79 = O14-C98 = O13-C21 =
 O13-C96
 1.4 with sigma of 0.01
 O22-C112
 1.25 with sigma of 0.01
 N2-C112
 1.35 with sigma of 0.01
 N2-C114 = N2-C113
 1.45 with sigma of 0.01
 O3-O4 = O17-O8 = O5-O6 = O1-O2
 2.2 with sigma of 0.01
 C113-C112
 2.3 with sigma of 0.01
 C114-C112
 2.3 with sigma of 0.01
 C113-C114
 2.5 with sigma of 0.01
3. Restrained planarity
 C89, O4, C92, O3
 with sigma of 0.1
 O22, N2, C112, C114, C113
 with sigma of 0.1
4. Uiso/Uaniso restraints and constraints
All non-hydrogen atoms have similar U: within 2A with sigma of 0.01 and sigma
for terminal atoms of 0.02 within 2A
Uanis(O7) \\sim Ueq, Uanis(O19) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
5. Others
 Fixed Sof: O19(0.5) H19A(0.25) H19B(0.25) O7(0.5)
6.a Riding coordinates:
 O19(H19A,H19B)
6.b Secondary CH2 refined with riding coordinates:
 C30(H30A,H30B), C50(H50A,H50B), C18(H18A,H18B), C23(H23A,H23B), C55(H55A,
 H55B), C93(H93A,H93B), C108(H10A,H10B), C106(H10C,H10D), C110(H11A,H11B),
 C96(H96A,H96B), C104(H10E,H10F), C98(H98A,H98B), C100(H10P,H10Q), C102(H10R,
 H10S)
6.c Aromatic/amide H refined with riding coordinates:
 C33(H33), C36(H36), C52(H52), C38(H38), C39(H39), C41(H41), C42(H42),
 C26(H26), C67(H67), C66(H66), C77(H77), C76(H76), C70(H70), C74(H74), C73(H73),
  C71(H71), C63(H63), C29(H29), C57(H57), C20(H20), C16(H16), C44(H44),
 C45(H45), C47(H47), C48(H48), C81(H81), C82(H82), C84(H84), C85(H85), C78(H78),
  C13(H13), C60(H60), C9(H9), C95(H95), C94(H94), C10(H10), C87(H87), C91(H91),
 C90(H90), C88(H88), C6(H6), C7(H7), C3(H3), C4(H4), C112(H112)
6.d Fitted hexagon refined as free rotating group:
 C37(C38,C39,C40,C41,C42), C67(C66,C65,C77,C76,C68), C70(C69,C74,C73,C72,C71),
 C43(C44,C45,C46,C47,C48), C80(C81,C82,C83,C84,C85), C9(C8,C95,C94,C11,C10),
 C87(C86,C91,C90,C89,C88), C5(C6,C7,C2,C3,C4)
6.e Idealised Me refined as rotating group:
 C107(H10G,H10H,H10I), C105(H10J,H10K,H10L), C97(H97A,H97B,H97C), C111(H11C,
 H11D,H11E), C109(H10M,H10N,H10O), C101(H10T,H10U,H10V), C114(H11F,H11G,H11H),
 C103(H10W,H10X,H10Y), C99(H99A,H99B,H99C), C113(H11I,H11J,H11K)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu2 Eu 1.000000 1.000000 0.000000 0.1637(6) Uani 1 2 d S . P . .
Eu1 Eu -0.18220(7) 0.83501(4) -0.01977(3) 0.1450(4) Uani 1 1 d . . . . .
K1 K -0.3679(3) 0.72039(15) -0.04355(9) 0.1730(16) Uani 1 1 d . . . . .
O9 O 0.6063(4) 0.8505(2) 0.5681(2) 0.0834(15) Uani 1 1 d D U . . .
O15 O 0.1093(4) 0.9516(3) 0.3770(2) 0.0819(15) Uani 1 1 d D U . . .
O16 O -0.0634(4) 0.8705(2) 0.5846(2) 0.0839(15) Uani 1 1 d D U . . .
O10 O 0.6044(4) 0.7459(2) 0.3808(2) 0.0855(15) Uani 1 1 d D U . . .
O13 O -0.1351(4) 0.8017(3) 0.3904(3) 0.0960(17) Uani 1 1 d D U . . .
C34 C 0.4649(4) 0.9401(3) 0.4640(3) 0.0533(15) Uani 1 1 d . U . . .
C51 C 0.5895(4) 0.8586(3) 0.4704(3) 0.0564(15) Uani 1 1 d . U . . .
C35 C 0.4184(4) 0.9594(3) 0.4144(3) 0.0529(14) Uani 1 1 d . U . . .
C33 C 0.4159(4) 0.9367(3) 0.5150(3) 0.0524(15) Uani 1 1 d . U . . .
H33 H 0.448884 0.923385 0.548743 0.063 Uiso 1 1 calc R U . . .
O12 O 0.4386(5) 0.5551(3) 0.3999(3) 0.1076(19) Uani 1 1 d D U . . .
O14 O -0.0654(5) 0.6411(3) 0.5834(3) 0.110(2) Uani 1 1 d D U . . .
C31 C 0.2722(4) 0.9732(3) 0.4698(3) 0.0532(15) Uani 1 1 d . U . . .
C32 C 0.3184(4) 0.9522(3) 0.5194(3) 0.0547(15) Uani 1 1 d . U . . .
C30 C 0.1673(4) 0.9938(3) 0.4692(3) 0.0583(16) Uani 1 1 d . U . . .
H30A H 0.154278 1.015970 0.500249 0.070 Uiso 1 1 calc R U . . .
H30B H 0.156354 1.020850 0.433131 0.070 Uiso 1 1 calc R U . . .
C27 C 0.0977(5) 0.9487(3) 0.4751(3) 0.0617(16) Uani 1 1 d . U . . .
C50 C 0.5715(4) 0.9224(3) 0.4653(3) 0.0584(16) Uani 1 1 d . U . . .
H50A H 0.603282 0.942018 0.430234 0.070 Uiso 1 1 calc R U . . .
H50B H 0.598529 0.935192 0.497847 0.070 Uiso 1 1 calc R U . . .
C36 C 0.3204(4) 0.9748(3) 0.4176(3) 0.0560(15) Uani 1 1 d . U . . .
H36 H 0.287171 0.986463 0.383715 0.067 Uiso 1 1 calc R U . . .
C52 C 0.5892(5) 0.8330(3) 0.4232(3) 0.0669(18) Uani 1 1 d . U . . .
H52 H 0.578321 0.856256 0.387179 0.080 Uiso 1 1 calc R U . . .
C37 C 0.4651(3) 0.9641(2) 0.35559(15) 0.0630(16) Uani 1 1 d G U . . .
C38 C 0.5384(3) 1.0003(2) 0.33933(18) 0.0742(19) Uani 1 1 d G U . . .
H38 H 0.555830 1.025052 0.363632 0.089 Uiso 1 1 calc R U . . .
C39 C 0.5863(3) 1.0001(2) 0.2875(2) 0.081(2) Uani 1 1 d G U . . .
H39 H 0.636432 1.024840 0.276399 0.097 Uiso 1 1 calc R U . . .
C40 C 0.5608(4) 0.9639(3) 0.25195(15) 0.082(2) Uani 1 1 d G U . . .
C41 C 0.4875(4) 0.9278(2) 0.26821(18) 0.077(2) Uani 1 1 d G U . . .
H41 H 0.470037 0.902979 0.243902 0.092 Uiso 1 1 calc R U . . .
C42 C 0.4396(3) 0.9279(2) 0.32002(19) 0.0720(19) Uani 1 1 d G U . . .
H42 H 0.389435 0.903190 0.331135 0.086 Uiso 1 1 calc R U . . .
C26 C 0.0546(5) 0.9275(3) 0.5276(3) 0.0626(17) Uani 1 1 d . U . . .
H26 H 0.077186 0.938179 0.560576 0.075 Uiso 1 1 calc R U . . .
C64 C 0.6080(5) 0.8225(3) 0.5221(3) 0.0662(17) Uani 1 1 d D U . . .
C28 C 0.0641(5) 0.9304(4) 0.4280(3) 0.0712(18) Uani 1 1 d D U . . .
C67 C 0.1864(3) 0.99189(18) 0.64931(18) 0.0707(18) Uani 1 1 d G U . . .
H67 H 0.155759 1.024812 0.661373 0.085 Uiso 1 1 calc R U . . .
C66 C 0.2297(3) 0.99693(15) 0.59565(17) 0.0590(16) Uani 1 1 d G U . . .
H66 H 0.228632 1.033297 0.571039 0.071 Uiso 1 1 calc R U . . .
C65 C 0.2746(3) 0.94875(18) 0.57801(14) 0.0547(15) Uani 1 1 d G U . . .
C77 C 0.2763(3) 0.89553(16) 0.61402(18) 0.0661(18) Uani 1 1 d G U . . .
H77 H 0.306946 0.862604 0.601963 0.079 Uiso 1 1 calc R U . . .
C76 C 0.2330(4) 0.89049(17) 0.66768(17) 0.0733(19) Uani 1 1 d G U . . .
H76 H 0.234074 0.854118 0.692297 0.088 Uiso 1 1 calc R U . . .
C68 C 0.1881(3) 0.9387(2) 0.68533(14) 0.0727(18) Uani 1 1 d G U . . .
C24 C -0.0562(5) 0.8765(3) 0.4862(4) 0.0723(18) Uani 1 1 d . U . . .
C25 C -0.0188(5) 0.8920(3) 0.5336(3) 0.0709(18) Uani 1 1 d D U . . .
C70 C 0.1238(4) 0.9803(2) 0.7710(2) 0.092(2) Uani 1 1 d G U . . .
H70 H 0.149939 1.015988 0.755626 0.110 Uiso 1 1 calc R U . . .
C69 C 0.1371(4) 0.9340(3) 0.74245(18) 0.086(2) Uani 1 1 d G U . . .
C74 C 0.0989(5) 0.8818(2) 0.7650(2) 0.107(3) Uani 1 1 d G U . . .
H74 H 0.107992 0.850163 0.745464 0.128 Uiso 1 1 calc R U . . .
C73 C 0.0474(5) 0.8758(3) 0.8162(2) 0.119(3) Uani 1 1 d G U . . .
H73 H 0.021227 0.840076 0.831604 0.142 Uiso 1 1 calc R U . . .
C72 C 0.0340(4) 0.9220(3) 0.84478(19) 0.113(3) Uani 1 1 d DG U . . .
C71 C 0.0723(4) 0.9743(3) 0.8222(2) 0.102(3) Uani 1 1 d G U . . .
H71 H 0.063173 1.005901 0.841768 0.123 Uiso 1 1 calc R U . . .
C63 C 0.6283(5) 0.7644(3) 0.5262(3) 0.0696(19) Uani 1 1 d . U . . .
H63 H 0.643583 0.741467 0.561696 0.084 Uiso 1 1 calc R U . . .
C29 C -0.0125(5) 0.8961(4) 0.4330(3) 0.0725(19) Uani 1 1 d . U . . .
H29 H -0.035810 0.885806 0.400057 0.087 Uiso 1 1 calc R U . . .
C17 C 0.0506(6) 0.5808(4) 0.4873(4) 0.0798(19) Uani 1 1 d . U . . .
C53 C 0.6046(5) 0.7739(3) 0.4277(3) 0.0706(18) Uani 1 1 d D U . . .
C57 C 0.5398(6) 0.6163(3) 0.4419(4) 0.076(2) Uani 1 1 d . U . . .
H57 H 0.573458 0.625790 0.406704 0.091 Uiso 1 1 calc R U . . .
C56 C 0.5666(6) 0.6390(3) 0.4867(4) 0.0762(19) Uani 1 1 d . U . . .
C22 C -0.1220(5) 0.7791(4) 0.4874(4) 0.083(2) Uani 1 1 d . U . . .
C21 C -0.1189(6) 0.7600(4) 0.4388(4) 0.085(2) Uani 1 1 d D U . . .
C20 C -0.0959(5) 0.7011(4) 0.4374(4) 0.083(2) Uani 1 1 d . U . . .
H20 H -0.091774 0.688406 0.402038 0.100 Uiso 1 1 calc R U . . .
C15 C 0.1771(6) 0.5270(3) 0.5446(4) 0.0765(19) Uani 1 1 d . U . . .
O17 O -0.0292(6) 0.9552(4) 0.9274(3) 0.155(3) Uani 1 1 d D U . . .
C16 C 0.0798(6) 0.5484(3) 0.5369(4) 0.082(2) Uani 1 1 d . U . . .
H16 H 0.035094 0.539432 0.567430 0.098 Uiso 1 1 calc R U . . .
C58 C 0.4649(6) 0.5795(4) 0.4451(4) 0.085(2) Uani 1 1 d D U . . .
C19 C -0.0797(5) 0.6626(4) 0.4851(4) 0.083(2) Uani 1 1 d . U . . .
C54 C 0.6268(5) 0.7386(3) 0.4783(4) 0.0704(18) Uani 1 1 d . U . . .
C43 C 0.6166(4) 0.9612(3) 0.1969(2) 0.101(2) Uani 1 1 d G U . . .
C44 C 0.6287(5) 0.9096(3) 0.1766(3) 0.112(3) Uani 1 1 d G U . . .
H44 H 0.599344 0.876349 0.196066 0.135 Uiso 1 1 calc R U . . .
C45 C 0.6836(5) 0.9067(3) 0.1276(3) 0.128(3) Uani 1 1 d G U . . .
H45 H 0.691898 0.871449 0.113659 0.153 Uiso 1 1 calc R U . . .
C46 C 0.7265(5) 0.9554(4) 0.0990(2) 0.132(3) Uani 1 1 d DG U . . .
C47 C 0.7144(5) 1.0069(3) 0.1194(3) 0.127(3) Uani 1 1 d G U . . .
H47 H 0.743723 1.040182 0.099925 0.153 Uiso 1 1 calc R U . . .
C48 C 0.6594(5) 1.0098(3) 0.1684(3) 0.116(3) Uani 1 1 d G U . . .
H48 H 0.651169 1.045084 0.182333 0.139 Uiso 1 1 calc R U . . .
C59 C 0.4143(6) 0.5634(3) 0.4958(4) 0.078(2) Uani 1 1 d . U . . .
C18 C -0.0541(6) 0.5983(4) 0.4827(4) 0.087(2) Uani 1 1 d . U . . .
H18A H -0.089086 0.574179 0.513899 0.104 Uiso 1 1 calc R U . . .
H18B H -0.075423 0.589956 0.446566 0.104 Uiso 1 1 calc R U . . .
C23 C -0.1436(5) 0.8425(4) 0.4914(4) 0.082(2) Uani 1 1 d . U . . .
H23A H -0.186446 0.860259 0.460930 0.099 Uiso 1 1 calc R U . . .
H23B H -0.176773 0.844955 0.528122 0.099 Uiso 1 1 calc R U . . .
O8 O -0.0613(6) 0.8695(4) 0.9140(3) 0.157(3) Uani 1 1 d D U . . .
C80 C 0.2005(5) 0.4886(2) 0.6012(2) 0.093(2) Uani 1 1 d G U . . .
C81 C 0.1879(6) 0.5108(2) 0.6510(3) 0.134(3) Uani 1 1 d G U . . .
H81 H 0.169143 0.550359 0.649661 0.161 Uiso 1 1 calc R U . . .
C82 C 0.2029(7) 0.4750(3) 0.7029(2) 0.146(3) Uani 1 1 d G U . . .
H82 H 0.194305 0.490114 0.736985 0.175 Uiso 1 1 calc R U . . .
C83 C 0.2304(6) 0.4170(3) 0.7050(2) 0.130(3) Uani 1 1 d G U . . .
C84 C 0.2430(5) 0.3949(2) 0.6551(3) 0.099(3) Uani 1 1 d G U . . .
H84 H 0.261753 0.355301 0.656503 0.119 Uiso 1 1 calc R U . . .
C85 C 0.2280(5) 0.4307(2) 0.6032(2) 0.086(2) Uani 1 1 d G U . . .
H85 H 0.236591 0.415546 0.569179 0.103 Uiso 1 1 calc R U . . .
C55 C 0.6495(6) 0.6744(3) 0.4831(4) 0.082(2) Uani 1 1 d . U . . .
H55A H 0.689615 0.667804 0.449739 0.099 Uiso 1 1 calc R U . . .
H55B H 0.686856 0.660821 0.517161 0.099 Uiso 1 1 calc R U . . .
C78 C -0.1077(5) 0.7393(4) 0.5386(4) 0.087(2) Uani 1 1 d . U . . .
H78 H -0.113159 0.751528 0.574261 0.104 Uiso 1 1 calc R U . . .
C93 C 0.3462(5) 0.5175(3) 0.5037(4) 0.085(2) Uani 1 1 d . U . . .
H93A H 0.355867 0.492295 0.540898 0.102 Uiso 1 1 calc R U . . .
H93B H 0.359528 0.493581 0.474080 0.102 Uiso 1 1 calc R U . . .
C79 C -0.0852(6) 0.6814(4) 0.5349(4) 0.093(2) Uani 1 1 d D U . . .
C14 C 0.2396(6) 0.5411(3) 0.5010(4) 0.0777(19) Uani 1 1 d . U . . .
C12 C 0.1178(6) 0.5960(4) 0.4443(4) 0.087(2) Uani 1 1 d . U . . .
C108 C -0.0348(6) 0.8864(4) 0.6342(3) 0.093(2) Uani 1 1 d D U . . .
H10A H -0.039518 0.928919 0.630499 0.112 Uiso 1 1 calc R U . . .
H10B H 0.031631 0.872645 0.641038 0.112 Uiso 1 1 calc R U . . .
O6 O 0.7739(7) 0.9163(4) 0.0200(3) 0.173(4) Uani 1 1 d D U . . .
C13 C 0.2119(6) 0.5763(4) 0.4522(4) 0.088(2) Uani 1 1 d . U . . .
H13 H 0.257766 0.587628 0.422962 0.105 Uiso 1 1 calc R U . . .
C106 C 0.6423(8) 0.8213(4) 0.6194(3) 0.104(3) Uani 1 1 d D U . . .
H10C H 0.709518 0.809033 0.614051 0.125 Uiso 1 1 calc R U . . .
H10D H 0.606930 0.786703 0.633973 0.125 Uiso 1 1 calc R U . . .
O11 O 0.5324(7) 0.6504(4) 0.5815(3) 0.158(3) Uani 1 1 d D U . . .
O2 O -0.0641(7) 0.8428(4) 0.0324(4) 0.180(4) Uani 1 1 d D U . . .
C110 C 0.0804(6) 0.9342(5) 0.3278(3) 0.102(3) Uani 1 1 d D U . . .
H11A H 0.013325 0.946381 0.321544 0.122 Uiso 1 1 calc R U . . .
H11B H 0.088035 0.891738 0.331760 0.122 Uiso 1 1 calc R U . . .
O5 O 0.8447(7) 0.9935(5) 0.0327(4) 0.184(4) Uani 1 1 d D U . . .
C60 C 0.4385(7) 0.5881(4) 0.5405(4) 0.099(3) Uani 1 1 d . U . . .
H60 H 0.402641 0.580304 0.575110 0.119 Uiso 1 1 calc R U . . .
C96 C -0.1558(8) 0.7855(4) 0.3391(4) 0.111(3) Uani 1 1 d D U . . .
H96A H -0.207613 0.758866 0.345502 0.133 Uiso 1 1 calc R U . . .
H96B H -0.099717 0.765235 0.323995 0.133 Uiso 1 1 calc R U . . .
C104 C 0.5677(7) 0.7772(4) 0.3312(3) 0.100(3) Uani 1 1 d D U . . .
H10E H 0.608729 0.808823 0.315204 0.120 Uiso 1 1 calc R U . . .
H10F H 0.504234 0.794397 0.339244 0.120 Uiso 1 1 calc R U . . .
C75 C -0.0236(9) 0.9161(5) 0.8991(4) 0.140(3) Uani 1 1 d D U . . .
C107 C 0.6315(9) 0.8630(5) 0.6601(4) 0.133(4) Uani 1 1 d D U . . .
H10G H 0.663802 0.897985 0.644082 0.200 Uiso 1 1 calc R U . . .
H10H H 0.659191 0.845115 0.696082 0.200 Uiso 1 1 calc R U . . .
H10I H 0.564481 0.873097 0.666591 0.200 Uiso 1 1 calc R U . . .
C61 C 0.5111(8) 0.6232(4) 0.5372(4) 0.105(2) Uani 1 1 d D U . . .
C49 C 0.7867(10) 0.9557(6) 0.0467(5) 0.164(4) Uani 1 1 d D U . . .
C9 C 0.0200(5) 0.6519(4) 0.2974(3) 0.123(3) Uani 1 1 d G U . . .
H9 H -0.019259 0.640034 0.271264 0.147 Uiso 1 1 calc R U . . .
C8 C 0.0587(6) 0.7053(3) 0.2844(2) 0.127(3) Uani 1 1 d G U . . .
C95 C 0.1161(5) 0.7227(3) 0.3226(3) 0.129(3) Uani 1 1 d G U . . .
H95 H 0.142603 0.759216 0.313728 0.155 Uiso 1 1 calc R U . . .
C94 C 0.1347(5) 0.6865(3) 0.3738(3) 0.119(3) Uani 1 1 d G U . . .
H94 H 0.173933 0.698319 0.399887 0.143 Uiso 1 1 calc R U . . .
C11 C 0.0959(5) 0.6330(3) 0.3868(3) 0.110(3) Uani 1 1 d G U . . .
C10 C 0.0386(5) 0.6157(3) 0.3486(3) 0.119(3) Uani 1 1 d G U . . .
H10 H 0.012071 0.579136 0.357425 0.142 Uiso 1 1 calc R U . . .
C87 C 0.2127(8) 0.3206(4) 0.7688(3) 0.157(4) Uani 1 1 d G U . . .
H87 H 0.184190 0.307607 0.738794 0.189 Uiso 1 1 calc R U . . .
C86 C 0.2472(8) 0.3753(4) 0.7600(3) 0.159(3) Uani 1 1 d G U . . .
C91 C 0.2889(9) 0.3943(4) 0.8038(4) 0.194(4) Uani 1 1 d G U . . .
H91 H 0.312567 0.431704 0.797808 0.233 Uiso 1 1 calc R U . . .
C90 C 0.2961(9) 0.3586(5) 0.8564(3) 0.220(4) Uani 1 1 d G U . . .
H90 H 0.324588 0.371648 0.886368 0.263 Uiso 1 1 calc R U . . .
C89 C 0.2615(9) 0.3040(4) 0.8652(3) 0.211(4) Uani 1 1 d DG U . . .
C88 C 0.2198(9) 0.2849(3) 0.8214(4) 0.177(4) Uani 1 1 d G U . . .
H88 H 0.196211 0.247550 0.827356 0.213 Uiso 1 1 calc R U . . .
O22 O -0.2539(9) 0.9016(6) -0.1005(5) 0.233(6) Uani 1 1 d D U . . .
O4 O 0.2334(11) 0.2129(5) 0.9310(4) 0.230(5) Uani 1 1 d D U . . .
C105 C 0.5618(10) 0.7377(5) 0.2900(5) 0.142(4) Uani 1 1 d D U . . .
H10J H 0.532544 0.758741 0.255659 0.213 Uiso 1 1 calc R U . . .
H10K H 0.523809 0.705442 0.306938 0.213 Uiso 1 1 calc R U . . .
H10L H 0.625340 0.722827 0.280393 0.213 Uiso 1 1 calc R U . . .
C5 C 0.0357(7) 0.7483(4) 0.2302(3) 0.145(3) Uani 1 1 d G U . . .
C6 C 0.0117(7) 0.7266(3) 0.1831(4) 0.159(4) Uani 1 1 d G U . . .
H6 H 0.007154 0.686259 0.185514 0.191 Uiso 1 1 calc R U . . .
C7 C -0.0055(7) 0.7639(5) 0.1324(3) 0.171(4) Uani 1 1 d G U . . .
H7 H -0.021822 0.749130 0.100154 0.205 Uiso 1 1 calc R U . . .
C2 C 0.0012(8) 0.8229(4) 0.1288(3) 0.184(4) Uani 1 1 d DG U . . .
C3 C 0.0252(8) 0.8446(3) 0.1760(4) 0.178(4) Uani 1 1 d G U . . .
H3 H 0.029740 0.884942 0.173535 0.214 Uiso 1 1 calc R U . . .
C4 C 0.0424(7) 0.8073(4) 0.2267(3) 0.166(4) Uani 1 1 d G U . . .
H4 H 0.058717 0.822072 0.258896 0.199 Uiso 1 1 calc R U . . .
C97 C -0.1839(9) 0.8381(5) 0.2979(5) 0.132(4) Uani 1 1 d D U . . .
H97A H -0.197130 0.827233 0.261689 0.198 Uiso 1 1 calc R U . . .
H97B H -0.132670 0.864461 0.292182 0.198 Uiso 1 1 calc R U . . .
H97C H -0.240546 0.857257 0.312601 0.198 Uiso 1 1 calc R U . . .
C111 C 0.1402(7) 0.9619(6) 0.2795(4) 0.132(4) Uani 1 1 d D U . . .
H11C H 0.131081 0.944588 0.246257 0.197 Uiso 1 1 calc R U . . .
H11D H 0.206534 0.956177 0.289494 0.197 Uiso 1 1 calc R U . . .
H11E H 0.122543 1.003346 0.270978 0.197 Uiso 1 1 calc R U . . .
C109 C -0.0969(8) 0.8600(6) 0.6827(4) 0.150(5) Uani 1 1 d D U . . .
H10M H -0.163014 0.870016 0.673679 0.224 Uiso 1 1 calc R U . . .
H10N H -0.082998 0.874789 0.716818 0.224 Uiso 1 1 calc R U . . .
H10O H -0.085459 0.817984 0.689445 0.224 Uiso 1 1 calc R U . . .
C98 C -0.0713(10) 0.6581(5) 0.6374(4) 0.147(4) Uani 1 1 d D U . . .
H98A H -0.135451 0.674825 0.644615 0.176 Uiso 1 1 calc R U . . .
H98B H -0.025958 0.687903 0.638325 0.176 Uiso 1 1 calc R U . . .
O1 O -0.0079(10) 0.9126(5) 0.0695(5) 0.229(5) Uani 1 1 d D U . . .
N2 N -0.3185(12) 0.9824(6) -0.1444(6) 0.275(7) Uani 1 1 d D U . . .
O19 O -0.3644(12) 0.8296(7) -0.0208(7) 0.146(6) Uani 0.5 1 d . U P . .
H19A H -0.391974 0.842817 0.007741 0.219 Uiso 0.25 1 d R U P A 1
H19B H -0.380833 0.851746 -0.052252 0.219 Uiso 0.25 1 d R U P A 1
C100 C 0.5000(10) 0.5612(6) 0.3522(5) 0.152(4) Uani 1 1 d D U . . .
H10P H 0.565718 0.553994 0.364431 0.182 Uiso 1 1 calc R U . . .
H10Q H 0.492876 0.601316 0.331138 0.182 Uiso 1 1 calc R U . . .
C1 C -0.0245(15) 0.8599(6) 0.0721(5) 0.201(4) Uani 1 1 d D U . . .
C112 C -0.2657(12) 0.9549(7) -0.1043(6) 0.252(6) Uani 1 1 d D U . . .
H112 H -0.237351 0.974596 -0.078969 0.302 Uiso 1 1 calc R U . . .
C92 C 0.2558(12) 0.2642(6) 0.9220(4) 0.242(5) Uani 1 1 d D U . . .
C102 C 0.4555(11) 0.6543(7) 0.6224(6) 0.198(5) Uani 1 1 d D U . . .
H10R H 0.458163 0.618364 0.651076 0.237 Uiso 1 1 calc R U . . .
H10S H 0.395678 0.655768 0.602740 0.237 Uiso 1 1 calc R U . . .
C101 C 0.4809(13) 0.5207(8) 0.3141(7) 0.204(6) Uani 1 1 d D U . . .
H10T H 0.524187 0.526538 0.280898 0.307 Uiso 1 1 calc R U . . .
H10U H 0.415814 0.527745 0.301941 0.307 Uiso 1 1 calc R U . . .
H10V H 0.490043 0.480894 0.334468 0.307 Uiso 1 1 calc R U . . .
C114 C -0.3487(17) 0.9505(8) -0.1845(8) 0.304(11) Uani 1 1 d D U . . .
H11F H -0.328794 0.968917 -0.222787 0.456 Uiso 1 1 calc R U . . .
H11G H -0.417461 0.949696 -0.181864 0.456 Uiso 1 1 calc R U . . .
H11H H -0.320524 0.910996 -0.176488 0.456 Uiso 1 1 calc R U . . .
O3 O 0.2664(14) 0.2897(6) 0.9630(6) 0.291(6) Uani 1 1 d D U . . .
C103 C 0.4522(16) 0.7048(8) 0.6532(8) 0.249(8) Uani 1 1 d D U . . .
H10W H 0.439800 0.740728 0.626275 0.373 Uiso 1 1 calc R U . . .
H10X H 0.512808 0.705974 0.670524 0.373 Uiso 1 1 calc R U . . .
H10Y H 0.402000 0.700603 0.682776 0.373 Uiso 1 1 calc R U . . .
C99 C -0.0491(13) 0.6060(7) 0.6825(6) 0.219(7) Uani 1 1 d D U . . .
H99A H -0.055628 0.570798 0.667183 0.328 Uiso 1 1 calc R U . . .
H99B H -0.092942 0.606663 0.715173 0.328 Uiso 1 1 calc R U . . .
H99C H 0.015548 0.606814 0.694379 0.328 Uiso 1 1 calc R U . . .
C113 C -0.3306(17) 1.0434(6) -0.1492(8) 0.314(10) Uani 1 1 d D U . . .
H11I H -0.373437 1.052838 -0.118532 0.471 Uiso 1 1 calc R U . . .
H11J H -0.357240 1.060137 -0.185788 0.471 Uiso 1 1 calc R U . . .
H11K H -0.269467 1.059223 -0.146451 0.471 Uiso 1 1 calc R U . . .
O7 O -0.2250(13) 0.7702(8) -0.0846(8) 0.153(6) Uani 0.5 1 d . U P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu2 O17 2.267(8) 2_676 ?
Eu2 O17 2.267(8) 1_654 ?
Eu2 O5 2.316(9) . ?
Eu2 O5 2.316(9) 2_775 ?
Eu2 O1 2.412(11) 2_675 ?
Eu2 O1 2.412(11) 1_655 ?
Eu1 K1 4.040(3) . ?
Eu1 O8 2.369(7) 1_554 ?
Eu1 O6 2.330(10) 1_455 ?
Eu1 O2 2.183(10) . ?
Eu1 O22 2.479(10) . ?
Eu1 O4 2.333(9) 2_566 ?
Eu1 O19 2.608(17) . ?
Eu1 C92 3.194(10) 2_566 ?
Eu1 O7 2.494(19) . ?
K1 O19 2.735(18) . ?
K1 H19B 3.0641 . ?
K1 C92 3.483(14) 2_566 ?
K1 O3 2.440(15) 2_566 ?
K1 O7 2.490(18) . ?
O9 C64 1.385(7) . ?
O9 C106 1.402(7) . ?
O15 C28 1.381(7) . ?
O15 C110 1.406(7) . ?
O16 C25 1.380(7) . ?
O16 C108 1.400(7) . ?
O10 C53 1.407(7) . ?
O10 C104 1.388(7) . ?
O13 C21 1.399(7) . ?
O13 C96 1.404(8) . ?
C34 C35 1.380(9) . ?
C34 C33 1.371(8) . ?
C34 C50 1.547(9) . ?
C51 C50 1.496(10) . ?
C51 C52 1.378(10) . ?
C51 C64 1.398(10) . ?
C35 C36 1.420(9) . ?
C35 C37 1.521(7) . ?
C33 H33 0.9500 . ?
C33 C32 1.416(9) . ?
O12 C58 1.395(8) . ?
O12 C100 1.400(8) . ?
O14 C79 1.391(8) . ?
O14 C98 1.425(8) . ?
C31 C32 1.386(9) . ?
C31 C30 1.539(9) . ?
C31 C36 1.394(8) . ?
C32 C65 1.501(7) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C30 C27 1.488(10) . ?
C27 C26 1.398(10) . ?
C27 C28 1.400(10) . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C36 H36 0.9500 . ?
C52 H52 0.9500 . ?
C52 C53 1.385(10) . ?
C37 C38 1.3900 . ?
C37 C42 1.3900 . ?
C38 H38 0.9500 . ?
C38 C39 1.3900 . ?
C39 H39 0.9500 . ?
C39 C40 1.3900 . ?
C40 C41 1.3900 . ?
C40 C43 1.517(5) . ?
C41 H41 0.9500 . ?
C41 C42 1.3900 . ?
C42 H42 0.9500 . ?
C26 H26 0.9500 . ?
C26 C25 1.371(10) . ?
C64 C63 1.371(10) . ?
C28 C29 1.389(11) . ?
C67 H67 0.9500 . ?
C67 C66 1.3900 . ?
C67 C68 1.3900 . ?
C66 H66 0.9500 . ?
C66 C65 1.3900 . ?
C65 C77 1.3900 . ?
C77 H77 0.9500 . ?
C77 C76 1.3900 . ?
C76 H76 0.9500 . ?
C76 C68 1.3900 . ?
C68 C69 1.510(4) . ?
C24 C25 1.396(11) . ?
C24 C29 1.408(11) . ?
C24 C23 1.513(11) . ?
C70 H70 0.9500 . ?
C70 C69 1.3900 . ?
C70 C71 1.3900 . ?
C69 C74 1.3900 . ?
C74 H74 0.9500 . ?
C74 C73 1.3900 . ?
C73 H73 0.9500 . ?
C73 C72 1.3900 . ?
C72 C71 1.3900 . ?
C72 C75 1.496(7) . ?
C71 H71 0.9500 . ?
C63 H63 0.9500 . ?
C63 C54 1.395(11) . ?
C29 H29 0.9500 . ?
C17 C16 1.362(12) . ?
C17 C18 1.525(11) . ?
C17 C12 1.388(12) . ?
C53 C54 1.380(10) . ?
C57 H57 0.9500 . ?
C57 C56 1.367(12) . ?
C57 C58 1.412(11) . ?
C56 C55 1.483(12) . ?
C56 C61 1.419(12) . ?
C22 C21 1.322(12) . ?
C22 C23 1.527(12) . ?
C22 C78 1.422(12) . ?
C21 C20 1.413(12) . ?
C20 H20 0.9500 . ?
C20 C19 1.346(12) . ?
C15 C16 1.451(11) . ?
C15 C80 1.530(9) . ?
C15 C14 1.350(11) . ?
O17 C75 1.236(8) . ?
C16 H16 0.9500 . ?
C58 C59 1.389(11) . ?
C19 C18 1.549(12) . ?
C19 C79 1.347(12) . ?
C54 C55 1.514(11) . ?
C43 C44 1.3900 . ?
C43 C48 1.3900 . ?
C44 H44 0.9500 . ?
C44 C45 1.3900 . ?
C45 H45 0.9500 . ?
C45 C46 1.3900 . ?
C46 C47 1.3900 . ?
C46 C49 1.487(8) . ?
C47 H47 0.9500 . ?
C47 C48 1.3900 . ?
C48 H48 0.9500 . ?
C59 C93 1.484(11) . ?
C59 C60 1.378(13) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
O8 C75 1.244(8) . ?
C80 C81 1.3900 . ?
C80 C85 1.3900 . ?
C81 H81 0.9500 . ?
C81 C82 1.3900 . ?
C82 H82 0.9500 . ?
C82 C83 1.3900 . ?
C83 C84 1.3900 . ?
C83 C86 1.518(7) . ?
C84 H84 0.9500 . ?
C84 C85 1.3900 . ?
C85 H85 0.9500 . ?
C55 H55A 0.9900 . ?
C55 H55B 0.9900 . ?
C78 H78 0.9500 . ?
C78 C79 1.399(12) . ?
C93 H93A 0.9900 . ?
C93 H93B 0.9900 . ?
C93 C14 1.581(11) . ?
C14 C13 1.365(11) . ?
C12 C13 1.400(11) . ?
C12 C11 1.529(10) . ?
C108 H10A 0.9900 . ?
C108 H10B 0.9900 . ?
C108 C109 1.496(8) . ?
O6 C49 1.250(8) . ?
C13 H13 0.9500 . ?
C106 H10C 0.9900 . ?
C106 H10D 0.9900 . ?
C106 C107 1.504(8) . ?
O11 C61 1.393(8) . ?
O11 C102 1.446(9) . ?
O2 C1 1.271(8) . ?
C110 H11A 0.9900 . ?
C110 H11B 0.9900 . ?
C110 C111 1.484(8) . ?
O5 C49 1.247(8) . ?
C60 H60 0.9500 . ?
C60 C61 1.360(13) . ?
C96 H96A 0.9900 . ?
C96 H96B 0.9900 . ?
C96 C97 1.487(8) . ?
C104 H10E 0.9900 . ?
C104 H10F 0.9900 . ?
C104 C105 1.486(8) . ?
C107 H10G 0.9800 . ?
C107 H10H 0.9800 . ?
C107 H10I 0.9800 . ?
C9 H9 0.9500 . ?
C9 C8 1.3900 . ?
C9 C10 1.3900 . ?
C8 C95 1.3900 . ?
C8 C5 1.532(8) . ?
C95 H95 0.9500 . ?
C95 C94 1.3900 . ?
C94 H94 0.9500 . ?
C94 C11 1.3900 . ?
C11 C10 1.3900 . ?
C10 H10 0.9500 . ?
C87 H87 0.9500 . ?
C87 C86 1.3900 . ?
C87 C88 1.3900 . ?
C86 C91 1.3900 . ?
C91 H91 0.9500 . ?
C91 C90 1.3900 . ?
C90 H90 0.9500 . ?
C90 C89 1.3900 . ?
C89 C88 1.3900 . ?
C89 C92 1.511(8) . ?
C88 H88 0.9500 . ?
O22 C112 1.245(9) . ?
O4 C92 1.251(8) . ?
C105 H10J 0.9800 . ?
C105 H10K 0.9800 . ?
C105 H10L 0.9800 . ?
C5 C6 1.3900 . ?
C5 C4 1.3900 . ?
C6 H6 0.9500 . ?
C6 C7 1.3900 . ?
C7 H7 0.9500 . ?
C7 C2 1.3900 . ?
C2 C3 1.3900 . ?
C2 C1 1.526(8) . ?
C3 H3 0.9500 . ?
C3 C4 1.3900 . ?
C4 H4 0.9500 . ?
C97 H97A 0.9800 . ?
C97 H97B 0.9800 . ?
C97 H97C 0.9800 . ?
C111 H11C 0.9800 . ?
C111 H11D 0.9800 . ?
C111 H11E 0.9800 . ?
C109 H10M 0.9800 . ?
C109 H10N 0.9800 . ?
C109 H10O 0.9800 . ?
C98 H98A 0.9900 . ?
C98 H98B 0.9900 . ?
C98 C99 1.512(9) . ?
O1 C1 1.272(9) . ?
N2 C112 1.302(8) . ?
N2 C114 1.424(8) . ?
N2 C113 1.423(8) . ?
O19 H19A 0.8700 . ?
O19 H19B 0.8700 . ?
C100 H10P 0.9900 . ?
C100 H10Q 0.9900 . ?
C100 C101 1.485(9) . ?
C112 H112 0.9500 . ?
C92 O3 1.263(9) . ?
C102 H10R 0.9900 . ?
C102 H10S 0.9900 . ?
C102 C103 1.511(9) . ?
C101 H10T 0.9800 . ?
C101 H10U 0.9800 . ?
C101 H10V 0.9800 . ?
C114 H11F 0.9800 . ?
C114 H11G 0.9800 . ?
C114 H11H 0.9800 . ?
C103 H10W 0.9800 . ?
C103 H10X 0.9800 . ?
C103 H10Y 0.9800 . ?
C99 H99A 0.9800 . ?
C99 H99B 0.9800 . ?
C99 H99C 0.9800 . ?
C113 H11I 0.9800 . ?
C113 H11J 0.9800 . ?
C113 H11K 0.9800 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O17 Eu2 O17 180.0(4) 2_676 1_654 ?
O17 Eu2 O5 89.4(3) 1_654 2_775 ?
O17 Eu2 O5 90.6(3) 2_676 2_775 ?
O17 Eu2 O5 90.6(3) 1_654 . ?
O17 Eu2 O5 89.4(3) 2_676 . ?
O17 Eu2 O1 86.8(3) 1_654 2_675 ?
O17 Eu2 O1 93.2(3) 2_676 2_675 ?
O17 Eu2 O1 93.2(3) 1_654 1_655 ?
O17 Eu2 O1 86.8(3) 2_676 1_655 ?
O5 Eu2 O5 180.0 . 2_775 ?
O5 Eu2 O1 107.3(5) 2_775 1_655 ?
O5 Eu2 O1 72.7(5) . 1_655 ?
O5 Eu2 O1 72.7(5) 2_775 2_675 ?
O5 Eu2 O1 107.3(5) . 2_675 ?
O1 Eu2 O1 180.0(6) 2_675 1_655 ?
O8 Eu1 K1 124.8(2) 1_554 . ?
O8 Eu1 O22 71.0(4) 1_554 . ?
O8 Eu1 O19 136.2(4) 1_554 . ?
O8 Eu1 C92 148.9(4) 1_554 2_566 ?
O8 Eu1 O7 89.1(5) 1_554 . ?
O6 Eu1 K1 122.7(2) 1_455 . ?
O6 Eu1 O8 101.8(3) 1_455 1_554 ?
O6 Eu1 O22 77.9(4) 1_455 . ?
O6 Eu1 O4 82.4(4) 1_455 2_566 ?
O6 Eu1 O19 81.8(5) 1_455 . ?
O6 Eu1 C92 100.4(3) 1_455 2_566 ?
O6 Eu1 O7 146.5(5) 1_455 . ?
O2 Eu1 K1 140.9(3) . . ?
O2 Eu1 O8 75.8(3) . 1_554 ?
O2 Eu1 O6 76.1(4) . 1_455 ?
O2 Eu1 O22 132.0(4) . . ?
O2 Eu1 O4 78.1(4) . 2_566 ?
O2 Eu1 O19 144.9(5) . . ?
O2 Eu1 C92 88.8(4) . 2_566 ?
O2 Eu1 O7 137.4(5) . . ?
O22 Eu1 K1 87.0(3) . . ?
O22 Eu1 O19 67.1(5) . . ?
O22 Eu1 C92 135.4(4) . 2_566 ?
O22 Eu1 O7 75.9(5) . . ?
O4 Eu1 K1 71.9(3) 2_566 . ?
O4 Eu1 O8 151.6(4) 2_566 1_554 ?
O4 Eu1 O22 136.6(5) 2_566 . ?
O4 Eu1 O19 72.1(5) 2_566 . ?
O4 Eu1 C92 19.1(2) 2_566 2_566 ?
O4 Eu1 O7 102.9(5) 2_566 . ?
O19 Eu1 K1 42.1(4) . . ?
O19 Eu1 C92 68.6(5) . 2_566 ?
C92 Eu1 K1 56.1(3) 2_566 . ?
O7 Eu1 K1 35.8(4) . . ?
O7 Eu1 O19 69.0(6) . . ?
O7 Eu1 C92 84.3(5) . 2_566 ?
Eu1 K1 H19B 46.7 . . ?
O19 K1 Eu1 39.7(4) . . ?
O19 K1 H19B 16.0 . . ?
O19 K1 C92 62.9(4) . 2_566 ?
C92 K1 Eu1 49.6(2) 2_566 . ?
C92 K1 H19B 78.4 2_566 . ?
O3 K1 Eu1 54.5(3) 2_566 . ?
O3 K1 O19 75.3(5) 2_566 . ?
O3 K1 H19B 90.3 2_566 . ?
O3 K1 C92 14.0(4) 2_566 2_566 ?
O3 K1 O7 76.6(6) 2_566 . ?
O7 K1 Eu1 35.9(4) . . ?
O7 K1 O19 67.0(5) . . ?
O7 K1 H19B 64.5 . . ?
O7 K1 C92 78.4(5) . 2_566 ?
C64 O9 C106 119.4(6) . . ?
C28 O15 C110 118.1(7) . . ?
C25 O16 C108 119.3(6) . . ?
C104 O10 C53 117.4(6) . . ?
C21 O13 C96 120.7(7) . . ?
C35 C34 C50 123.1(5) . . ?
C33 C34 C35 119.4(6) . . ?
C33 C34 C50 117.4(6) . . ?
C52 C51 C50 120.4(6) . . ?
C52 C51 C64 117.3(7) . . ?
C64 C51 C50 122.3(6) . . ?
C34 C35 C36 118.9(5) . . ?
C34 C35 C37 124.0(5) . . ?
C36 C35 C37 117.1(5) . . ?
C34 C33 H33 118.6 . . ?
C34 C33 C32 122.9(6) . . ?
C32 C33 H33 118.6 . . ?
C58 O12 C100 116.2(8) . . ?
C79 O14 C98 120.0(8) . . ?
C32 C31 C30 122.7(5) . . ?
C32 C31 C36 119.9(6) . . ?
C36 C31 C30 117.5(6) . . ?
C33 C32 C65 117.2(5) . . ?
C31 C32 C33 117.7(6) . . ?
C31 C32 C65 124.9(5) . . ?
C31 C30 H30A 108.1 . . ?
C31 C30 H30B 108.1 . . ?
H30A C30 H30B 107.3 . . ?
C27 C30 C31 117.0(6) . . ?
C27 C30 H30A 108.1 . . ?
C27 C30 H30B 108.1 . . ?
C26 C27 C30 121.2(7) . . ?
C26 C27 C28 116.6(7) . . ?
C28 C27 C30 121.8(6) . . ?
C34 C50 H50A 109.3 . . ?
C34 C50 H50B 109.3 . . ?
C51 C50 C34 111.6(5) . . ?
C51 C50 H50A 109.3 . . ?
C51 C50 H50B 109.3 . . ?
H50A C50 H50B 108.0 . . ?
C35 C36 H36 119.5 . . ?
C31 C36 C35 121.1(6) . . ?
C31 C36 H36 119.5 . . ?
C51 C52 H52 119.7 . . ?
C51 C52 C53 120.6(7) . . ?
C53 C52 H52 119.7 . . ?
C38 C37 C35 120.6(4) . . ?
C38 C37 C42 120.0 . . ?
C42 C37 C35 119.1(4) . . ?
C37 C38 H38 120.0 . . ?
C39 C38 C37 120.0 . . ?
C39 C38 H38 120.0 . . ?
C38 C39 H39 120.0 . . ?
C38 C39 C40 120.0 . . ?
C40 C39 H39 120.0 . . ?
C39 C40 C43 120.1(4) . . ?
C41 C40 C39 120.0 . . ?
C41 C40 C43 119.8(4) . . ?
C40 C41 H41 120.0 . . ?
C40 C41 C42 120.0 . . ?
C42 C41 H41 120.0 . . ?
C37 C42 H42 120.0 . . ?
C41 C42 C37 120.0 . . ?
C41 C42 H42 120.0 . . ?
C27 C26 H26 118.6 . . ?
C25 C26 C27 122.8(7) . . ?
C25 C26 H26 118.6 . . ?
O9 C64 C51 114.6(6) . . ?
C63 C64 O9 123.2(7) . . ?
C63 C64 C51 122.1(7) . . ?
O15 C28 C27 114.9(7) . . ?
O15 C28 C29 123.9(7) . . ?
C29 C28 C27 121.2(7) . . ?
C66 C67 H67 120.0 . . ?
C66 C67 C68 120.0 . . ?
C68 C67 H67 120.0 . . ?
C67 C66 H66 120.0 . . ?
C65 C66 C67 120.0 . . ?
C65 C66 H66 120.0 . . ?
C66 C65 C32 121.3(4) . . ?
C66 C65 C77 120.0 . . ?
C77 C65 C32 118.6(4) . . ?
C65 C77 H77 120.0 . . ?
C76 C77 C65 120.0 . . ?
C76 C77 H77 120.0 . . ?
C77 C76 H76 120.0 . . ?
C77 C76 C68 120.0 . . ?
C68 C76 H76 120.0 . . ?
C67 C68 C69 118.8(4) . . ?
C76 C68 C67 120.0 . . ?
C76 C68 C69 121.2(4) . . ?
C25 C24 C29 117.5(7) . . ?
C25 C24 C23 121.4(8) . . ?
C29 C24 C23 121.1(8) . . ?
O16 C25 C24 114.9(7) . . ?
C26 C25 O16 124.4(8) . . ?
C26 C25 C24 120.7(7) . . ?
C69 C70 H70 120.0 . . ?
C69 C70 C71 120.0 . . ?
C71 C70 H70 120.0 . . ?
C70 C69 C68 122.5(4) . . ?
C74 C69 C68 117.4(4) . . ?
C74 C69 C70 120.0 . . ?
C69 C74 H74 120.0 . . ?
C69 C74 C73 120.0 . . ?
C73 C74 H74 120.0 . . ?
C74 C73 H73 120.0 . . ?
C72 C73 C74 120.0 . . ?
C72 C73 H73 120.0 . . ?
C73 C72 C71 120.0 . . ?
C73 C72 C75 120.0(6) . . ?
C71 C72 C75 119.9(6) . . ?
C70 C71 H71 120.0 . . ?
C72 C71 C70 120.0 . . ?
C72 C71 H71 120.0 . . ?
C64 C63 H63 119.9 . . ?
C64 C63 C54 120.2(7) . . ?
C54 C63 H63 119.9 . . ?
C28 C29 C24 121.0(8) . . ?
C28 C29 H29 119.5 . . ?
C24 C29 H29 119.5 . . ?
C16 C17 C18 117.7(8) . . ?
C16 C17 C12 118.2(8) . . ?
C12 C17 C18 124.1(8) . . ?
C52 C53 O10 122.6(7) . . ?
C54 C53 O10 115.3(7) . . ?
C54 C53 C52 122.0(7) . . ?
C56 C57 H57 118.2 . . ?
C56 C57 C58 123.6(8) . . ?
C58 C57 H57 118.2 . . ?
C57 C56 C55 122.4(8) . . ?
C57 C56 C61 114.1(8) . . ?
C61 C56 C55 123.5(9) . . ?
C21 C22 C23 122.7(9) . . ?
C21 C22 C78 119.4(9) . . ?
C78 C22 C23 117.8(9) . . ?
O13 C21 C20 123.5(9) . . ?
C22 C21 O13 116.1(8) . . ?
C22 C21 C20 120.4(8) . . ?
C21 C20 H20 119.2 . . ?
C19 C20 C21 121.5(9) . . ?
C19 C20 H20 119.2 . . ?
C16 C15 C80 117.2(7) . . ?
C14 C15 C16 118.0(8) . . ?
C14 C15 C80 124.8(7) . . ?
C75 O17 Eu2 156.8(9) . 1_456 ?
C17 C16 C15 121.9(8) . . ?
C17 C16 H16 119.0 . . ?
C15 C16 H16 119.0 . . ?
O12 C58 C57 123.9(8) . . ?
C59 C58 O12 115.4(8) . . ?
C59 C58 C57 120.6(8) . . ?
C20 C19 C18 120.8(9) . . ?
C20 C19 C79 118.5(9) . . ?
C79 C19 C18 120.8(9) . . ?
C63 C54 C55 120.0(7) . . ?
C53 C54 C63 117.5(7) . . ?
C53 C54 C55 122.5(8) . . ?
C44 C43 C40 120.3(5) . . ?
C44 C43 C48 120.0 . . ?
C48 C43 C40 119.7(5) . . ?
C43 C44 H44 120.0 . . ?
C43 C44 C45 120.0 . . ?
C45 C44 H44 120.0 . . ?
C44 C45 H45 120.0 . . ?
C44 C45 C46 120.0 . . ?
C46 C45 H45 120.0 . . ?
C45 C46 C49 123.3(7) . . ?
C47 C46 C45 120.0 . . ?
C47 C46 C49 116.7(7) . . ?
C46 C47 H47 120.0 . . ?
C48 C47 C46 120.0 . . ?
C48 C47 H47 120.0 . . ?
C43 C48 H48 120.0 . . ?
C47 C48 C43 120.0 . . ?
C47 C48 H48 120.0 . . ?
C58 C59 C93 122.3(9) . . ?
C60 C59 C58 115.9(8) . . ?
C60 C59 C93 121.4(8) . . ?
C17 C18 C19 114.3(7) . . ?
C17 C18 H18A 108.7 . . ?
C17 C18 H18B 108.7 . . ?
C19 C18 H18A 108.7 . . ?
C19 C18 H18B 108.7 . . ?
H18A C18 H18B 107.6 . . ?
C24 C23 C22 113.0(6) . . ?
C24 C23 H23A 109.0 . . ?
C24 C23 H23B 109.0 . . ?
C22 C23 H23A 109.0 . . ?
C22 C23 H23B 109.0 . . ?
H23A C23 H23B 107.8 . . ?
C75 O8 Eu1 135.7(7) . 1_556 ?
C81 C80 C15 119.8(5) . . ?
C81 C80 C85 120.0 . . ?
C85 C80 C15 120.0(5) . . ?
C80 C81 H81 120.0 . . ?
C80 C81 C82 120.0 . . ?
C82 C81 H81 120.0 . . ?
C81 C82 H82 120.0 . . ?
C83 C82 C81 120.0 . . ?
C83 C82 H82 120.0 . . ?
C82 C83 C86 123.0(6) . . ?
C84 C83 C82 120.0 . . ?
C84 C83 C86 117.0(6) . . ?
C83 C84 H84 120.0 . . ?
C85 C84 C83 120.0 . . ?
C85 C84 H84 120.0 . . ?
C80 C85 H85 120.0 . . ?
C84 C85 C80 120.0 . . ?
C84 C85 H85 120.0 . . ?
C56 C55 C54 115.1(7) . . ?
C56 C55 H55A 108.5 . . ?
C56 C55 H55B 108.5 . . ?
C54 C55 H55A 108.5 . . ?
C54 C55 H55B 108.5 . . ?
H55A C55 H55B 107.5 . . ?
C22 C78 H78 121.0 . . ?
C79 C78 C22 117.9(9) . . ?
C79 C78 H78 121.0 . . ?
C59 C93 H93A 108.8 . . ?
C59 C93 H93B 108.8 . . ?
C59 C93 C14 114.0(7) . . ?
H93A C93 H93B 107.6 . . ?
C14 C93 H93A 108.8 . . ?
C14 C93 H93B 108.8 . . ?
O14 C79 C78 120.5(9) . . ?
C19 C79 O14 117.3(9) . . ?
C19 C79 C78 122.3(8) . . ?
C15 C14 C93 122.1(7) . . ?
C15 C14 C13 120.4(8) . . ?
C13 C14 C93 117.5(7) . . ?
C17 C12 C13 119.6(8) . . ?
C17 C12 C11 124.1(8) . . ?
C13 C12 C11 116.2(8) . . ?
O16 C108 H10A 110.0 . . ?
O16 C108 H10B 110.0 . . ?
O16 C108 C109 108.7(8) . . ?
H10A C108 H10B 108.3 . . ?
C109 C108 H10A 110.0 . . ?
C109 C108 H10B 110.0 . . ?
C49 O6 Eu1 155.1(11) . 1_655 ?
C14 C13 C12 121.7(8) . . ?
C14 C13 H13 119.2 . . ?
C12 C13 H13 119.2 . . ?
O9 C106 H10C 110.4 . . ?
O9 C106 H10D 110.4 . . ?
O9 C106 C107 106.6(7) . . ?
H10C C106 H10D 108.6 . . ?
C107 C106 H10C 110.4 . . ?
C107 C106 H10D 110.4 . . ?
C61 O11 C102 114.0(11) . . ?
C1 O2 Eu1 154.7(13) . . ?
O15 C110 H11A 110.2 . . ?
O15 C110 H11B 110.2 . . ?
O15 C110 C111 107.6(7) . . ?
H11A C110 H11B 108.5 . . ?
C111 C110 H11A 110.2 . . ?
C111 C110 H11B 110.2 . . ?
C49 O5 Eu2 138.5(10) . . ?
C59 C60 H60 118.5 . . ?
C61 C60 C59 123.1(9) . . ?
C61 C60 H60 118.5 . . ?
O13 C96 H96A 109.9 . . ?
O13 C96 H96B 109.9 . . ?
O13 C96 C97 108.9(8) . . ?
H96A C96 H96B 108.3 . . ?
C97 C96 H96A 109.9 . . ?
C97 C96 H96B 109.9 . . ?
O10 C104 H10E 110.0 . . ?
O10 C104 H10F 110.0 . . ?
O10 C104 C105 108.6(8) . . ?
H10E C104 H10F 108.3 . . ?
C105 C104 H10E 110.0 . . ?
C105 C104 H10F 110.0 . . ?
O17 C75 C72 120.5(8) . . ?
O17 C75 O8 123.6(7) . . ?
O8 C75 C72 115.8(8) . . ?
C106 C107 H10G 109.5 . . ?
C106 C107 H10H 109.5 . . ?
C106 C107 H10I 109.5 . . ?
H10G C107 H10H 109.5 . . ?
H10G C107 H10I 109.5 . . ?
H10H C107 H10I 109.5 . . ?
O11 C61 C56 114.4(9) . . ?
C60 C61 C56 122.6(9) . . ?
C60 C61 O11 122.8(9) . . ?
O6 C49 C46 114.8(9) . . ?
O5 C49 C46 119.8(9) . . ?
O5 C49 O6 125.4(8) . . ?
C8 C9 H9 120.0 . . ?
C8 C9 C10 120.0 . . ?
C10 C9 H9 120.0 . . ?
C9 C8 C5 122.0(7) . . ?
C95 C8 C9 120.0 . . ?
C95 C8 C5 117.9(7) . . ?
C8 C95 H95 120.0 . . ?
C8 C95 C94 120.0 . . ?
C94 C95 H95 120.0 . . ?
C95 C94 H94 120.0 . . ?
C11 C94 C95 120.0 . . ?
C11 C94 H94 120.0 . . ?
C94 C11 C12 117.2(6) . . ?
C10 C11 C12 122.8(6) . . ?
C10 C11 C94 120.0 . . ?
C9 C10 H10 120.0 . . ?
C11 C10 C9 120.0 . . ?
C11 C10 H10 120.0 . . ?
C86 C87 H87 120.0 . . ?
C86 C87 C88 120.0 . . ?
C88 C87 H87 120.0 . . ?
C87 C86 C83 120.4(7) . . ?
C87 C86 C91 120.0 . . ?
C91 C86 C83 119.2(7) . . ?
C86 C91 H91 120.0 . . ?
C90 C91 C86 120.0 . . ?
C90 C91 H91 120.0 . . ?
C91 C90 H90 120.0 . . ?
C91 C90 C89 120.0 . . ?
C89 C90 H90 120.0 . . ?
C90 C89 C88 120.0 . . ?
C90 C89 C92 124.5(9) . . ?
C88 C89 C92 115.2(9) . . ?
C87 C88 H88 120.0 . . ?
C89 C88 C87 120.0 . . ?
C89 C88 H88 120.0 . . ?
C112 O22 Eu1 125.1(10) . . ?
C92 O4 Eu1 123.2(7) . 2_566 ?
C104 C105 H10J 109.5 . . ?
C104 C105 H10K 109.5 . . ?
C104 C105 H10L 109.5 . . ?
H10J C105 H10K 109.5 . . ?
H10J C105 H10L 109.5 . . ?
H10K C105 H10L 109.5 . . ?
C6 C5 C8 118.3(7) . . ?
C6 C5 C4 120.0 . . ?
C4 C5 C8 121.7(7) . . ?
C5 C6 H6 120.0 . . ?
C7 C6 C5 120.0 . . ?
C7 C6 H6 120.0 . . ?
C6 C7 H7 120.0 . . ?
C6 C7 C2 120.0 . . ?
C2 C7 H7 120.0 . . ?
C7 C2 C1 115.3(9) . . ?
C3 C2 C7 120.0 . . ?
C3 C2 C1 124.6(9) . . ?
C2 C3 H3 120.0 . . ?
C2 C3 C4 120.0 . . ?
C4 C3 H3 120.0 . . ?
C5 C4 H4 120.0 . . ?
C3 C4 C5 120.0 . . ?
C3 C4 H4 120.0 . . ?
C96 C97 H97A 109.5 . . ?
C96 C97 H97B 109.5 . . ?
C96 C97 H97C 109.5 . . ?
H97A C97 H97B 109.5 . . ?
H97A C97 H97C 109.5 . . ?
H97B C97 H97C 109.5 . . ?
C110 C111 H11C 109.5 . . ?
C110 C111 H11D 109.5 . . ?
C110 C111 H11E 109.5 . . ?
H11C C111 H11D 109.5 . . ?
H11C C111 H11E 109.5 . . ?
H11D C111 H11E 109.5 . . ?
C108 C109 H10M 109.5 . . ?
C108 C109 H10N 109.5 . . ?
C108 C109 H10O 109.5 . . ?
H10M C109 H10N 109.5 . . ?
H10M C109 H10O 109.5 . . ?
H10N C109 H10O 109.5 . . ?
O14 C98 H98A 109.9 . . ?
O14 C98 H98B 109.9 . . ?
O14 C98 C99 109.1(11) . . ?
H98A C98 H98B 108.3 . . ?
C99 C98 H98A 109.9 . . ?
C99 C98 H98B 109.9 . . ?
C1 O1 Eu2 139.2(8) . 1_455 ?
C112 N2 C114 117.5(9) . . ?
C112 N2 C113 117.0(9) . . ?
C114 N2 C113 124.9(8) . . ?
Eu1 O19 K1 98.2(6) . . ?
Eu1 O19 H19A 110.8 . . ?
Eu1 O19 H19B 104.8 . . ?
K1 O19 H19A 127.1 . . ?
K1 O19 H19B 104.0 . . ?
H19A O19 H19B 109.5 . . ?
O12 C100 H10P 109.3 . . ?
O12 C100 H10Q 109.3 . . ?
O12 C100 C101 111.6(10) . . ?
H10P C100 H10Q 108.0 . . ?
C101 C100 H10P 109.3 . . ?
C101 C100 H10Q 109.3 . . ?
O2 C1 C2 125.7(11) . . ?
O2 C1 O1 121.8(9) . . ?
O1 C1 C2 112.3(10) . . ?
O22 C112 N2 117.2(12) . . ?
O22 C112 H112 121.4 . . ?
N2 C112 H112 121.4 . . ?
Eu1 C92 K1 74.3(2) 2_566 2_566 ?
C89 C92 Eu1 159.1(10) . 2_566 ?
C89 C92 K1 126.0(8) . 2_566 ?
O4 C92 Eu1 37.7(5) . 2_566 ?
O4 C92 K1 104.8(7) . 2_566 ?
O4 C92 C89 126.6(11) . . ?
O4 C92 O3 120.2(9) . . ?
O3 C92 Eu1 83.1(7) . 2_566 ?
O3 C92 K1 28.0(9) . 2_566 ?
O3 C92 C89 112.8(11) . . ?
O11 C102 H10R 108.1 . . ?
O11 C102 H10S 108.1 . . ?
O11 C102 C103 116.7(13) . . ?
H10R C102 H10S 107.3 . . ?
C103 C102 H10R 108.1 . . ?
C103 C102 H10S 108.1 . . ?
C100 C101 H10T 109.5 . . ?
C100 C101 H10U 109.5 . . ?
C100 C101 H10V 109.5 . . ?
H10T C101 H10U 109.5 . . ?
H10T C101 H10V 109.5 . . ?
H10U C101 H10V 109.5 . . ?
N2 C114 H11F 109.5 . . ?
N2 C114 H11G 109.5 . . ?
N2 C114 H11H 109.5 . . ?
H11F C114 H11G 109.5 . . ?
H11F C114 H11H 109.5 . . ?
H11G C114 H11H 109.5 . . ?
C92 O3 K1 138.0(13) . 2_566 ?
C102 C103 H10W 109.5 . . ?
C102 C103 H10X 109.5 . . ?
C102 C103 H10Y 109.5 . . ?
H10W C103 H10X 109.5 . . ?
H10W C103 H10Y 109.5 . . ?
H10X C103 H10Y 109.5 . . ?
C98 C99 H99A 109.5 . . ?
C98 C99 H99B 109.5 . . ?
C98 C99 H99C 109.5 . . ?
H99A C99 H99B 109.5 . . ?
H99A C99 H99C 109.5 . . ?
H99B C99 H99C 109.5 . . ?
N2 C113 H11I 109.5 . . ?
N2 C113 H11J 109.5 . . ?
N2 C113 H11K 109.5 . . ?
H11I C113 H11J 109.5 . . ?
H11I C113 H11K 109.5 . . ?
H11J C113 H11K 109.5 . . ?
K1 O7 Eu1 108.3(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu2 O17 C75 C72 -105.2(16) 1_456 . . . ?
Eu2 O17 C75 O8 72(2) 1_456 . . . ?
Eu2 O5 C49 C46 135.4(9) . . . . ?
Eu2 O5 C49 O6 -44(3) . . . . ?
Eu2 O1 C1 O2 -16(4) 1_455 . . . ?
Eu2 O1 C1 C2 168.4(11) 1_455 . . . ?
Eu1 O8 C75 C72 -164.8(6) 1_556 . . . ?
Eu1 O8 C75 O17 18(2) 1_556 . . . ?
Eu1 O6 C49 C46 -119.4(13) 1_655 . . . ?
Eu1 O6 C49 O5 60(3) 1_655 . . . ?
Eu1 O2 C1 C2 105(2) . . . . ?
Eu1 O2 C1 O1 -70(4) . . . . ?
Eu1 O22 C112 N2 -168.6(11) . . . . ?
Eu1 O4 C92 K1 37.1(14) 2_566 . . 2_566 ?
Eu1 O4 C92 C89 -160.5(12) 2_566 . . . ?
Eu1 O4 C92 O3 12(2) 2_566 . . . ?
Eu1 C92 O3 K1 69.3(14) 2_566 . . 2_566 ?
O9 C64 C63 C54 178.6(7) . . . . ?
O15 C28 C29 C24 -179.2(7) . . . . ?
O10 C53 C54 C63 179.7(6) . . . . ?
O10 C53 C54 C55 0.1(11) . . . . ?
O13 C21 C20 C19 179.1(8) . . . . ?
C34 C35 C36 C31 2.9(10) . . . . ?
C34 C35 C37 C38 -61.4(8) . . . . ?
C34 C35 C37 C42 112.6(6) . . . . ?
C34 C33 C32 C31 -1.9(10) . . . . ?
C34 C33 C32 C65 -177.5(6) . . . . ?
C51 C52 C53 O10 179.7(6) . . . . ?
C51 C52 C53 C54 -4.3(11) . . . . ?
C51 C64 C63 C54 -3.1(11) . . . . ?
C35 C34 C33 C32 0.1(10) . . . . ?
C35 C34 C50 C51 -97.0(8) . . . . ?
C35 C37 C38 C39 173.9(5) . . . . ?
C35 C37 C42 C41 -174.0(5) . . . . ?
C33 C34 C35 C36 -0.6(10) . . . . ?
C33 C34 C35 C37 -179.1(6) . . . . ?
C33 C34 C50 C51 83.8(8) . . . . ?
C33 C32 C65 C66 121.3(5) . . . . ?
C33 C32 C65 C77 -61.4(7) . . . . ?
O12 C58 C59 C93 8.1(12) . . . . ?
O12 C58 C59 C60 -178.7(8) . . . . ?
C31 C32 C65 C66 -53.9(8) . . . . ?
C31 C32 C65 C77 123.4(6) . . . . ?
C31 C30 C27 C26 97.0(8) . . . . ?
C31 C30 C27 C28 -90.6(8) . . . . ?
C32 C31 C30 C27 -81.1(9) . . . . ?
C32 C31 C36 C35 -4.8(10) . . . . ?
C32 C65 C77 C76 -177.4(5) . . . . ?
C30 C31 C32 C33 -177.4(6) . . . . ?
C30 C31 C32 C65 -2.2(10) . . . . ?
C30 C31 C36 C35 176.7(6) . . . . ?
C30 C27 C26 C25 170.8(6) . . . . ?
C30 C27 C28 O15 8.1(10) . . . . ?
C30 C27 C28 C29 -168.4(7) . . . . ?
C27 C26 C25 O16 -179.6(6) . . . . ?
C27 C26 C25 C24 -1.9(11) . . . . ?
C27 C28 C29 C24 -3.0(11) . . . . ?
C50 C34 C35 C36 -179.8(6) . . . . ?
C50 C34 C35 C37 1.7(10) . . . . ?
C50 C34 C33 C32 179.4(6) . . . . ?
C50 C51 C52 C53 -179.1(6) . . . . ?
C50 C51 C64 O9 1.2(9) . . . . ?
C50 C51 C64 C63 -177.2(6) . . . . ?
C36 C35 C37 C38 120.1(6) . . . . ?
C36 C35 C37 C42 -65.9(7) . . . . ?
C36 C31 C32 C33 4.2(10) . . . . ?
C36 C31 C32 C65 179.3(6) . . . . ?
C36 C31 C30 C27 97.4(8) . . . . ?
C52 C51 C50 C34 81.5(7) . . . . ?
C52 C51 C64 O9 -179.3(6) . . . . ?
C52 C51 C64 C63 2.3(10) . . . . ?
C52 C53 C54 C63 3.4(11) . . . . ?
C52 C53 C54 C55 -176.2(7) . . . . ?
C37 C35 C36 C31 -178.5(6) . . . . ?
C37 C38 C39 C40 0.0 . . . . ?
C38 C37 C42 C41 0.0 . . . . ?
C38 C39 C40 C41 0.0 . . . . ?
C38 C39 C40 C43 -176.5(5) . . . . ?
C39 C40 C41 C42 0.0 . . . . ?
C39 C40 C43 C44 146.0(4) . . . . ?
C39 C40 C43 C48 -30.9(6) . . . . ?
C40 C41 C42 C37 0.0 . . . . ?
C40 C43 C44 C45 -176.9(6) . . . . ?
C40 C43 C48 C47 176.9(6) . . . . ?
C41 C40 C43 C44 -30.5(6) . . . . ?
C41 C40 C43 C48 152.6(4) . . . . ?
C42 C37 C38 C39 0.0 . . . . ?
C26 C27 C28 O15 -179.2(6) . . . . ?
C26 C27 C28 C29 4.3(10) . . . . ?
C64 O9 C106 C107 179.4(8) . . . . ?
C64 C51 C50 C34 -99.0(8) . . . . ?
C64 C51 C52 C53 1.4(10) . . . . ?
C64 C63 C54 C53 0.3(11) . . . . ?
C64 C63 C54 C55 179.9(7) . . . . ?
C28 O15 C110 C111 -179.1(8) . . . . ?
C28 C27 C26 C25 -2.0(10) . . . . ?
C67 C66 C65 C32 177.3(5) . . . . ?
C67 C66 C65 C77 0.0 . . . . ?
C67 C68 C69 C70 -28.2(6) . . . . ?
C67 C68 C69 C74 148.6(3) . . . . ?
C66 C67 C68 C76 0.0 . . . . ?
C66 C67 C68 C69 -177.6(5) . . . . ?
C66 C65 C77 C76 0.0 . . . . ?
C65 C77 C76 C68 0.0 . . . . ?
C77 C76 C68 C67 0.0 . . . . ?
C77 C76 C68 C69 177.5(5) . . . . ?
C76 C68 C69 C70 154.2(3) . . . . ?
C76 C68 C69 C74 -28.9(5) . . . . ?
C68 C67 C66 C65 0.0 . . . . ?
C68 C69 C74 C73 -176.9(5) . . . . ?
C25 O16 C108 C109 177.1(8) . . . . ?
C25 C24 C29 C28 -0.9(11) . . . . ?
C25 C24 C23 C22 -104.0(9) . . . . ?
C70 C69 C74 C73 0.0 . . . . ?
C69 C70 C71 C72 0.0 . . . . ?
C69 C74 C73 C72 0.0 . . . . ?
C74 C73 C72 C71 0.0 . . . . ?
C74 C73 C72 C75 178.4(8) . . . . ?
C73 C72 C71 C70 0.0 . . . . ?
C73 C72 C75 O17 173.7(10) . . . . ?
C73 C72 C75 O8 -3.8(15) . . . . ?
C71 C70 C69 C68 176.8(6) . . . . ?
C71 C70 C69 C74 0.0 . . . . ?
C71 C72 C75 O17 -7.9(15) . . . . ?
C71 C72 C75 O8 174.5(9) . . . . ?
C63 C54 C55 C56 99.8(9) . . . . ?
C29 C24 C25 O16 -178.8(6) . . . . ?
C29 C24 C25 C26 3.3(10) . . . . ?
C29 C24 C23 C22 79.3(10) . . . . ?
C17 C12 C13 C14 1.6(15) . . . . ?
C17 C12 C11 C94 115.1(9) . . . . ?
C17 C12 C11 C10 -63.6(11) . . . . ?
C53 O10 C104 C105 -172.2(8) . . . . ?
C53 C54 C55 C56 -80.6(10) . . . . ?
C57 C56 C55 C54 104.2(9) . . . . ?
C57 C56 C61 O11 -174.4(9) . . . . ?
C57 C56 C61 C60 0.7(14) . . . . ?
C57 C58 C59 C93 -169.6(7) . . . . ?
C57 C58 C59 C60 3.6(12) . . . . ?
C56 C57 C58 O12 -178.5(8) . . . . ?
C56 C57 C58 C59 -1.0(12) . . . . ?
C22 C21 C20 C19 2.2(13) . . . . ?
C22 C78 C79 O14 176.5(7) . . . . ?
C22 C78 C79 C19 -2.0(13) . . . . ?
C21 O13 C96 C97 171.4(8) . . . . ?
C21 C22 C23 C24 -90.2(10) . . . . ?
C21 C22 C78 C79 3.7(12) . . . . ?
C21 C20 C19 C18 -179.7(7) . . . . ?
C21 C20 C19 C79 -0.5(13) . . . . ?
C20 C19 C18 C17 100.7(10) . . . . ?
C20 C19 C79 O14 -178.1(7) . . . . ?
C20 C19 C79 C78 0.4(13) . . . . ?
C15 C80 C81 C82 175.6(7) . . . . ?
C15 C80 C85 C84 -175.6(7) . . . . ?
C15 C14 C13 C12 -4.0(15) . . . . ?
C16 C17 C18 C19 106.5(10) . . . . ?
C16 C17 C12 C13 2.0(14) . . . . ?
C16 C17 C12 C11 -179.0(8) . . . . ?
C16 C15 C80 C81 -63.0(9) . . . . ?
C16 C15 C80 C85 112.5(7) . . . . ?
C16 C15 C14 C93 -176.9(8) . . . . ?
C16 C15 C14 C13 2.7(13) . . . . ?
C58 O12 C100 C101 163.8(12) . . . . ?
C58 C57 C56 C55 175.9(7) . . . . ?
C58 C57 C56 C61 -1.2(12) . . . . ?
C58 C59 C93 C14 -102.8(10) . . . . ?
C58 C59 C60 C61 -4.2(14) . . . . ?
C43 C40 C41 C42 176.5(5) . . . . ?
C43 C44 C45 C46 0.0 . . . . ?
C44 C43 C48 C47 0.0 . . . . ?
C44 C45 C46 C47 0.0 . . . . ?
C44 C45 C46 C49 179.7(10) . . . . ?
C45 C46 C47 C48 0.0 . . . . ?
C45 C46 C49 O6 21.2(18) . . . . ?
C45 C46 C49 O5 -158.5(12) . . . . ?
C46 C47 C48 C43 0.0 . . . . ?
C47 C46 C49 O6 -159.1(11) . . . . ?
C47 C46 C49 O5 21.2(18) . . . . ?
C48 C43 C44 C45 0.0 . . . . ?
C59 C93 C14 C15 -121.1(9) . . . . ?
C59 C93 C14 C13 59.4(12) . . . . ?
C59 C60 C61 C56 2.2(16) . . . . ?
C59 C60 C61 O11 176.8(10) . . . . ?
C18 C17 C16 C15 176.7(7) . . . . ?
C18 C17 C12 C13 -178.0(8) . . . . ?
C18 C17 C12 C11 1.0(14) . . . . ?
C18 C19 C79 O14 1.1(12) . . . . ?
C18 C19 C79 C78 179.7(7) . . . . ?
C23 C24 C25 O16 4.4(10) . . . . ?
C23 C24 C25 C26 -173.5(7) . . . . ?
C23 C24 C29 C28 175.9(7) . . . . ?
C23 C22 C21 O13 1.0(12) . . . . ?
C23 C22 C21 C20 178.2(7) . . . . ?
C23 C22 C78 C79 -178.2(7) . . . . ?
C80 C15 C16 C17 -177.2(8) . . . . ?
C80 C15 C14 C93 1.2(13) . . . . ?
C80 C15 C14 C13 -179.3(8) . . . . ?
C80 C81 C82 C83 0.0 . . . . ?
C81 C80 C85 C84 0.0 . . . . ?
C81 C82 C83 C84 0.0 . . . . ?
C81 C82 C83 C86 -179.5(8) . . . . ?
C82 C83 C84 C85 0.0 . . . . ?
C82 C83 C86 C87 135.8(7) . . . . ?
C82 C83 C86 C91 -37.5(10) . . . . ?
C83 C84 C85 C80 0.0 . . . . ?
C83 C86 C91 C90 173.4(10) . . . . ?
C84 C83 C86 C87 -43.7(10) . . . . ?
C84 C83 C86 C91 143.0(6) . . . . ?
C85 C80 C81 C82 0.0 . . . . ?
C55 C56 C61 O11 8.6(14) . . . . ?
C55 C56 C61 C60 -176.4(9) . . . . ?
C78 C22 C21 O13 179.1(7) . . . . ?
C78 C22 C21 C20 -3.8(13) . . . . ?
C78 C22 C23 C24 91.7(9) . . . . ?
C93 C59 C60 C61 169.1(9) . . . . ?
C93 C14 C13 C12 175.5(9) . . . . ?
C79 O14 C98 C99 178.4(11) . . . . ?
C79 C19 C18 C17 -78.6(11) . . . . ?
C14 C15 C16 C17 1.0(13) . . . . ?
C14 C15 C80 C81 118.9(8) . . . . ?
C14 C15 C80 C85 -65.5(10) . . . . ?
C12 C17 C16 C15 -3.3(13) . . . . ?
C12 C17 C18 C19 -73.5(12) . . . . ?
C12 C11 C10 C9 178.7(7) . . . . ?
C108 O16 C25 C26 1.6(11) . . . . ?
C108 O16 C25 C24 -176.2(7) . . . . ?
C13 C12 C11 C94 -65.8(10) . . . . ?
C13 C12 C11 C10 115.4(8) . . . . ?
C106 O9 C64 C51 -167.0(7) . . . . ?
C106 O9 C64 C63 11.4(11) . . . . ?
C110 O15 C28 C27 178.9(7) . . . . ?
C110 O15 C28 C29 -4.7(11) . . . . ?
C60 C59 C93 C14 84.4(10) . . . . ?
C96 O13 C21 C22 -164.7(8) . . . . ?
C96 O13 C21 C20 18.3(13) . . . . ?
C104 O10 C53 C52 -14.1(11) . . . . ?
C104 O10 C53 C54 169.6(8) . . . . ?
C75 C72 C71 C70 -178.4(8) . . . . ?
C61 C56 C55 C54 -79.0(11) . . . . ?
C61 O11 C102 C103 -150.9(16) . . . . ?
C49 C46 C47 C48 -179.7(9) . . . . ?
C9 C8 C95 C94 0.0 . . . . ?
C9 C8 C5 C6 -28.4(9) . . . . ?
C9 C8 C5 C4 154.6(5) . . . . ?
C8 C9 C10 C11 0.0 . . . . ?
C8 C95 C94 C11 0.0 . . . . ?
C8 C5 C6 C7 -177.1(9) . . . . ?
C8 C5 C4 C3 177.0(9) . . . . ?
C95 C8 C5 C6 155.3(5) . . . . ?
C95 C8 C5 C4 -21.7(9) . . . . ?
C95 C94 C11 C12 -178.8(7) . . . . ?
C95 C94 C11 C10 0.0 . . . . ?
C94 C11 C10 C9 0.0 . . . . ?
C11 C12 C13 C14 -177.5(9) . . . . ?
C10 C9 C8 C95 0.0 . . . . ?
C10 C9 C8 C5 -176.3(8) . . . . ?
C87 C86 C91 C90 0.0 . . . . ?
C86 C83 C84 C85 179.5(8) . . . . ?
C86 C87 C88 C89 0.0 . . . . ?
C86 C91 C90 C89 0.0 . . . . ?
C91 C90 C89 C88 0.0 . . . . ?
C91 C90 C89 C92 -173.0(13) . . . . ?
C90 C89 C88 C87 0.0 . . . . ?
C90 C89 C92 Eu1 152(2) . . . 2_566 ?
C90 C89 C92 K1 -14.2(16) . . . 2_566 ?
C90 C89 C92 O4 -173.0(15) . . . . ?
C90 C89 C92 O3 14.3(19) . . . . ?
C89 C92 O3 K1 -124.7(14) . . . 2_566 ?
C88 C87 C86 C83 -173.3(10) . . . . ?
C88 C87 C86 C91 0.0 . . . . ?
C88 C89 C92 Eu1 -21(3) . . . 2_566 ?
C88 C89 C92 K1 172.5(7) . . . 2_566 ?
C88 C89 C92 O4 14(2) . . . . ?
C88 C89 C92 O3 -159.0(13) . . . . ?
O4 C92 O3 K1 62(2) . . . 2_566 ?
C5 C8 C95 C94 176.4(7) . . . . ?
C5 C6 C7 C2 0.0 . . . . ?
C6 C5 C4 C3 0.0 . . . . ?
C6 C7 C2 C3 0.0 . . . . ?
C6 C7 C2 C1 -176.7(12) . . . . ?
C7 C2 C3 C4 0.0 . . . . ?
C7 C2 C1 O2 11(3) . . . . ?
C7 C2 C1 O1 -173.3(15) . . . . ?
C2 C3 C4 C5 0.0 . . . . ?
C3 C2 C1 O2 -165.2(16) . . . . ?
C3 C2 C1 O1 10(2) . . . . ?
C4 C5 C6 C7 0.0 . . . . ?
C98 O14 C79 C19 -179.1(9) . . . . ?
C98 O14 C79 C78 2.3(13) . . . . ?
C100 O12 C58 C57 9.9(13) . . . . ?
C100 O12 C58 C59 -167.6(10) . . . . ?
C1 C2 C3 C4 176.4(13) . . . . ?
C92 C89 C88 C87 173.6(12) . . . . ?
C102 O11 C61 C56 155.5(11) . . . . ?
C102 O11 C61 C60 -19.6(17) . . . . ?
C114 N2 C112 O22 -7(2) . . . . ?
C113 N2 C112 O22 -179.1(18) . . . . ?

_smtbx_masks_special_details     ?
loop_
_smtbx_masks_void_nr
_smtbx_masks_void_average_x
_smtbx_masks_void_average_y
_smtbx_masks_void_average_z
_smtbx_masks_void_volume
_smtbx_masks_void_count_electrons
_smtbx_masks_void_content
1 -0.305 -0.872 -0.777 3784.6 484.7 ?

_smtbx_masks_void_probe_radius   1.2
_smtbx_masks_void_truncation_radius 1.2
_olex2_submission_special_instructions 'No special instructions were received'
_site                            XU
