# Supplementary Information (SI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2025

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1-dy
_database_code_depnum_ccdc_archive 'CCDC 2355400'
loop_
_audit_author_name
_audit_author_address
'Wen-Bin Sun'
;Heilongjiang University
China
;
_audit_update_record             
;
2024-12-21 deposited with the CCDC.	2025-03-24 downloaded from the CCDC.
;
_audit_creation_date             2024-12-14
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C24 H22 Dy N2 O9, 2(H2 O), N O3'
_chemical_formula_sum            'C24 H26 Dy N3 O14'
_chemical_formula_weight         742.98
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x+1/2, -y, z+1/2'
'-x, -y, -z'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'
'x-1/2, y, -z-1/2'

_cell_length_a                   14.666(2)
_cell_length_b                   18.530(3)
_cell_length_c                   19.784(3)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     5376.4(15)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9970
_cell_measurement_temperature    293
_cell_measurement_theta_max      25.66
_cell_measurement_theta_min      2.43
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    2.858
_exptl_absorpt_correction_T_max  0.7453
_exptl_absorpt_correction_T_min  0.5878
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0968 before and 0.0626 after correction.
The Ratio of minimum to maximum transmission is 0.7887.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            colourless
_exptl_crystal_colour_lustre     .
_exptl_crystal_colour_modifier   .
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.836
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             2952
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0338
_diffrn_reflns_av_unetI/netI     0.0295
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            32555
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.676
_diffrn_reflns_theta_min         2.048
_diffrn_ambient_temperature      293.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3999
_reflns_number_total             5068
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max         0.925
_refine_diff_density_min         -0.492
_refine_diff_density_rms         0.116
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         5068
_refine_ls_number_restraints     83
_refine_ls_R_factor_all          0.0429
_refine_ls_R_factor_gt           0.0294
_refine_ls_restrained_S_all      1.084
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0252P)²+11.7739P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0655
_refine_ls_wR_factor_ref         0.0706
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Restrained distances
 N3-O10 = N3-O11 = N3-O12 = N3'-O10' = N3'-O11' = N3'-O12'
 1.21 with sigma of 0.01
 O10-O11 \\sim O11-O12 \\sim O12-O10 \\sim O10'-O11' \\sim O11'-O12' \\sim
O12'-O10'
 with sigma of 0.01
3. Restrained planarity
 N3, O10, O11, O12
 with sigma of 0.01
 N3', O10', O11', O12'
 with sigma of 0.01
4. Rigid bond restraints
 N3, O10, O11, O12
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
 N3', O10', O11', O12'
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01
5. Uiso/Uaniso restraints and constraints
N3 \\sim O10 \\sim O11 \\sim O12: within 2A with sigma of 0.01 and sigma for
terminal atoms of 0.02 within 2A
N3' \\sim O10' \\sim O11' \\sim O12': within 2A with sigma of 0.01 and sigma
for terminal atoms of 0.02 within 2A
Uanis(O13) \\sim Ueq, Uanis(O01) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
Uanis(O01) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
6. Others
 Fixed Sof: O01(0.5) H01A(0.5) H01B(0.5) O02(0.5) H02A(0.5) H02B(0.5) N3(0.5)
 O10(0.5) O11(0.5) O12(0.5) N3'(0.5) O10'(0.5) O11'(0.5) O12'(0.5) O13(0.5)
 H13A(0.5) H13B(0.5) O14(0.5) H14C(0.5) H14D(0.5)
7.a Riding coordinates:
 O9(H9A,H9B), O01(H01A,H01B), O02(H02A,H02B), O13(H13A,H13B), O14(H14C,H14D)
7.b Secondary CH2 refined with riding coordinates:
 C14(H14A,H14B), C15(H15A,H15B), C3(H3A,H3B), C2(H2A,H2B)
7.c Aromatic/amide H refined with riding coordinates:
 C22(H22), C20(H20), C19(H19), C21(H21), C4(H4), C6(H6), C7(H7), C5(H5),
 C10(H10), C12(H12), C13(H13), C11(H11)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.41821(2) 0.53461(2) 0.39948(2) 0.02762(7) Uani 1 1 d . . . . .
O7 O 0.5075(2) 0.96623(15) 0.19323(15) 0.0428(7) Uani 1 1 d . . . . .
O8 O 0.5173(2) 0.91469(15) 0.09311(14) 0.0441(7) Uani 1 1 d . . . . .
O6 O 0.3259(2) 0.59906(16) 0.23154(16) 0.0541(9) Uani 1 1 d . . . . .
O5 O 0.4154(2) 0.62115(15) 0.32009(15) 0.0459(8) Uani 1 1 d . . . . .
O1 O 0.3730(2) 0.49556(17) 0.50307(15) 0.0472(8) Uani 1 1 d . . . . .
O2 O 0.4269(2) 0.43723(18) 0.59092(16) 0.0469(8) Uani 1 1 d . . . . .
O3 O 0.2563(2) 0.93020(16) 0.89715(13) 0.0406(7) Uani 1 1 d . . . . .
O4 O 0.2965(2) 1.03385(15) 0.85169(15) 0.0450(7) Uani 1 1 d . . . . .
O9 O 0.4215(2) 0.63653(18) 0.47229(17) 0.0615(10) Uani 1 1 d . . . . .
H9A H 0.381594 0.666729 0.459204 0.092 Uiso 1 1 d R U . . .
H9B H 0.467514 0.664269 0.474964 0.092 Uiso 1 1 d R U . . .
O01 O 0.0912(10) 0.7820(8) 0.5124(8) 0.150(5) Uani 0.5 1 d . U P A 1
H01A H 0.062478 0.742873 0.505664 0.225 Uiso 0.5 1 d R U P A 1
H01B H 0.119258 0.799663 0.478644 0.225 Uiso 0.5 1 d R U P A 1
O02 O 0.3124(7) 0.7576(4) 0.4676(6) 0.118(4) Uani 0.5 1 d . . P B 2
H02A H 0.263732 0.772956 0.449209 0.177 Uiso 0.5 1 d R U P B 2
H02B H 0.355412 0.779216 0.447009 0.177 Uiso 0.5 1 d R U P B 2
N2 N 0.1211(2) 0.8636(2) 0.79450(18) 0.0420(9) Uani 1 1 d . . . . .
N1 N 0.1997(2) 0.5565(2) 0.59973(19) 0.0450(9) Uani 1 1 d . . . . .
C24 C 0.4960(3) 0.9121(2) 0.1557(2) 0.0348(9) Uani 1 1 d . . . . .
C23 C 0.4597(3) 0.8430(2) 0.18396(19) 0.0309(9) Uani 1 1 d . . . . .
C22 C 0.4385(3) 0.7862(2) 0.1411(2) 0.0390(10) Uani 1 1 d . . . . .
H22 H 0.443859 0.791947 0.094580 0.047 Uiso 1 1 calc R U . . .
C20 C 0.4095(3) 0.7210(2) 0.1673(2) 0.0371(10) Uani 1 1 d . . . . .
H20 H 0.393323 0.683720 0.138238 0.044 Uiso 1 1 calc R U . . .
C18 C 0.4042(2) 0.7106(2) 0.23653(19) 0.0297(9) Uani 1 1 d . . . . .
C19 C 0.4255(3) 0.7676(2) 0.2792(2) 0.0353(9) Uani 1 1 d . . . . .
H19 H 0.422327 0.761277 0.325741 0.042 Uiso 1 1 calc R U . . .
C21 C 0.4514(3) 0.8339(2) 0.2531(2) 0.0354(9) Uani 1 1 d . . . . .
H21 H 0.463255 0.872282 0.282130 0.042 Uiso 1 1 calc R U . . .
C17 C 0.3785(3) 0.6377(2) 0.2640(2) 0.0352(9) Uani 1 1 d . . . . .
C4 C 0.1812(3) 0.5517(3) 0.6662(2) 0.0499(12) Uani 1 1 d . . . . .
H4 H 0.171678 0.506525 0.685390 0.060 Uiso 1 1 calc R U . . .
C6 C 0.1762(3) 0.6113(3) 0.7059(2) 0.0503(12) Uani 1 1 d . . . . .
H6 H 0.164523 0.606496 0.751863 0.060 Uiso 1 1 calc R U . . .
C8 C 0.1883(3) 0.6795(2) 0.6781(2) 0.0423(11) Uani 1 1 d . . . . .
C7 C 0.2117(3) 0.6828(3) 0.6097(2) 0.0514(12) Uani 1 1 d . . . . .
H7 H 0.223901 0.727171 0.589697 0.062 Uiso 1 1 calc R U . . .
C5 C 0.2166(3) 0.6207(3) 0.5720(2) 0.0514(12) Uani 1 1 d . . . . .
H5 H 0.231996 0.623526 0.526436 0.062 Uiso 1 1 calc R U . . .
C9 C 0.1710(3) 0.7450(2) 0.7184(2) 0.0420(10) Uani 1 1 d . . . . .
C10 C 0.1813(3) 0.7464(3) 0.7885(2) 0.0484(12) Uani 1 1 d . . . . .
H10 H 0.205981 0.706569 0.810504 0.058 Uiso 1 1 calc R U . . .
C12 C 0.1558(3) 0.8048(3) 0.8249(2) 0.0503(12) Uani 1 1 d . . . . .
H12 H 0.162462 0.804266 0.871614 0.060 Uiso 1 1 calc R U . C 2
C13 C 0.1131(3) 0.8652(2) 0.7269(2) 0.0418(11) Uani 1 1 d . . . . .
H13 H 0.090875 0.906549 0.705921 0.050 Uiso 1 1 calc R U . . .
C11 C 0.1372(3) 0.8072(2) 0.6887(2) 0.0450(11) Uani 1 1 d . . . . .
H11 H 0.130852 0.809348 0.641954 0.054 Uiso 1 1 calc R U . . .
C14 C 0.0864(3) 0.9257(3) 0.8340(3) 0.0530(12) Uani 1 1 d . . . . .
H14A H 0.081900 0.911761 0.881165 0.064 Uiso 1 1 calc R U . . .
H14B H 0.025456 0.937533 0.818415 0.064 Uiso 1 1 calc R U . . .
C15 C 0.1459(3) 0.9924(3) 0.8286(2) 0.0498(12) Uani 1 1 d . . . . .
H15A H 0.153933 1.004189 0.781246 0.060 Uiso 1 1 calc R U . . .
H15B H 0.114417 1.032569 0.849802 0.060 Uiso 1 1 calc R U . . .
C16 C 0.2387(3) 0.9844(2) 0.8610(2) 0.0391(10) Uani 1 1 d . . . . .
C3 C 0.1946(3) 0.4906(3) 0.5567(3) 0.0494(12) Uani 1 1 d . . . . .
H3A H 0.201075 0.504371 0.509609 0.059 Uiso 1 1 calc R U . . .
H3B H 0.135156 0.468439 0.562151 0.059 Uiso 1 1 calc R U . . .
C2 C 0.2677(3) 0.4358(2) 0.5742(2) 0.0446(11) Uani 1 1 d . . . . .
H2A H 0.266141 0.427130 0.622512 0.054 Uiso 1 1 calc R U . . .
H2B H 0.253411 0.390671 0.551747 0.054 Uiso 1 1 calc R U . . .
C1 C 0.3631(3) 0.4584(2) 0.55457(19) 0.0312(9) Uani 1 1 d . . . . .
N3 N -0.0090(8) 0.6630(8) 0.5317(6) 0.206(6) Uani 0.5 1 d D U P D 2
O10 O -0.0007(15) 0.7263(7) 0.5463(7) 0.218(7) Uani 0.5 1 d D U P D 2
O11 O 0.0114(17) 0.6438(9) 0.4764(6) 0.217(8) Uani 0.5 1 d D U P D 2
O12 O -0.0372(17) 0.6220(8) 0.5732(8) 0.204(7) Uani 0.5 1 d D U P D 2
N3' N -0.0142(8) 0.6139(9) 0.5255(6) 0.238(9) Uani 0.5 1 d D U P E 1
O10' O 0.0465(10) 0.6426(12) 0.4942(7) 0.242(9) Uani 0.5 1 d D U P E 1
O11' O -0.0892(9) 0.6392(12) 0.5252(11) 0.281(10) Uani 0.5 1 d D U P E 1
O12' O 0.0014(9) 0.5601(11) 0.5569(11) 0.287(10) Uani 0.5 1 d D U P E 1
O13 O 0.2246(14) 0.8303(8) 0.4277(7) 0.196(6) Uani 0.5 1 d . U P F 1
H13A H 0.201424 0.861120 0.400974 0.294 Uiso 0.5 1 d R U P F 1
H13B H 0.280094 0.840910 0.435054 0.294 Uiso 0.5 1 d R U P F 1
O14 O 0.1379(7) 0.8001(5) 0.4677(6) 0.098(3) Uani 0.5 1 d . . P G 2
H14C H 0.093813 0.774874 0.482625 0.147 Uiso 0.5 1 d R U P G 2
H14D H 0.112443 0.835054 0.447315 0.147 Uiso 0.5 1 d R U P G 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 O7 2.481(3) 3_645 ?
Dy1 O8 2.420(3) 3_645 ?
Dy1 O5 2.245(3) . ?
Dy1 O1 2.272(3) . ?
Dy1 O2 2.338(3) 5_666 ?
Dy1 O3 2.464(3) 7_575 ?
Dy1 O4 2.385(3) 7_575 ?
Dy1 O9 2.376(3) . ?
Dy1 C24 2.816(4) 3_645 ?
Dy1 C16 2.763(4) 7_575 ?
O7 C24 1.259(5) . ?
O8 C24 1.279(5) . ?
O6 C17 1.232(5) . ?
O5 C17 1.273(5) . ?
O1 C1 1.239(5) . ?
O2 C1 1.244(5) . ?
O3 C16 1.260(5) . ?
O4 C16 1.262(5) . ?
O9 H9A 0.8501 . ?
O9 H9B 0.8500 . ?
O01 H01A 0.8500 . ?
O01 H01B 0.8501 . ?
O02 H02A 0.8498 . ?
O02 H02B 0.8500 . ?
N2 C12 1.345(6) . ?
N2 C13 1.343(5) . ?
N2 C14 1.481(6) . ?
N1 C4 1.346(6) . ?
N1 C5 1.334(6) . ?
N1 C3 1.491(6) . ?
C24 C23 1.495(5) . ?
C23 C22 1.387(6) . ?
C23 C21 1.384(6) . ?
C22 H22 0.9300 . ?
C22 C20 1.382(6) . ?
C20 H20 0.9300 . ?
C20 C18 1.384(6) . ?
C18 C19 1.387(5) . ?
C18 C17 1.504(5) . ?
C19 H19 0.9300 . ?
C19 C21 1.385(5) . ?
C21 H21 0.9300 . ?
C4 H4 0.9300 . ?
C4 C6 1.357(6) . ?
C6 H6 0.9300 . ?
C6 C8 1.390(6) . ?
C8 C7 1.396(6) . ?
C8 C9 1.474(6) . ?
C7 H7 0.9300 . ?
C7 C5 1.373(7) . ?
C5 H5 0.9300 . ?
C9 C10 1.395(6) . ?
C9 C11 1.386(6) . ?
C10 H10 0.9300 . ?
C10 C12 1.352(7) . ?
C12 H12 0.9300 . ?
C13 H13 0.9300 . ?
C13 C11 1.361(6) . ?
C11 H11 0.9300 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C14 C15 1.517(7) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C15 C16 1.512(6) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C3 C2 1.515(6) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C2 C1 1.511(6) . ?
N3 O10 1.214(9) . ?
N3 O11 1.190(9) . ?
N3 O12 1.191(9) . ?
N3' O10' 1.207(9) . ?
N3' O11' 1.196(9) . ?
N3' O12' 1.196(9) . ?
O13 H13A 0.8498 . ?
O13 H13B 0.8501 . ?
O14 H14C 0.8499 . ?
O14 H14D 0.8501 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 Dy1 C24 26.54(10) 3_645 3_645 ?
O7 Dy1 C16 98.60(12) 3_645 7_575 ?
O8 Dy1 O7 53.42(9) 3_645 3_645 ?
O8 Dy1 O3 128.41(10) 3_645 7_575 ?
O8 Dy1 C24 26.93(10) 3_645 3_645 ?
O8 Dy1 C16 105.79(12) 3_645 7_575 ?
O5 Dy1 O7 81.70(11) . 3_645 ?
O5 Dy1 O8 134.88(10) . 3_645 ?
O5 Dy1 O1 148.55(11) . . ?
O5 Dy1 O2 85.14(10) . 5_666 ?
O5 Dy1 O3 77.29(10) . 7_575 ?
O5 Dy1 O4 95.09(11) . 7_575 ?
O5 Dy1 O9 81.77(13) . . ?
O5 Dy1 C24 108.22(12) . 3_645 ?
O5 Dy1 C16 83.14(11) . 7_575 ?
O1 Dy1 O7 129.21(10) . 3_645 ?
O1 Dy1 O8 76.53(10) . 3_645 ?
O1 Dy1 O2 106.34(11) . 5_666 ?
O1 Dy1 O3 79.62(10) . 7_575 ?
O1 Dy1 O4 88.27(11) . 7_575 ?
O1 Dy1 O9 73.27(12) . . ?
O1 Dy1 C24 102.92(12) . 3_645 ?
O1 Dy1 C16 85.99(11) . 7_575 ?
O2 Dy1 O7 75.37(11) 5_666 3_645 ?
O2 Dy1 O8 79.64(11) 5_666 3_645 ?
O2 Dy1 O3 151.52(11) 5_666 7_575 ?
O2 Dy1 O4 151.37(11) 5_666 7_575 ?
O2 Dy1 O9 75.74(12) 5_666 . ?
O2 Dy1 C24 77.14(12) 5_666 3_645 ?
O2 Dy1 C16 167.51(11) 5_666 7_575 ?
O3 Dy1 O7 123.00(9) 7_575 3_645 ?
O3 Dy1 C24 129.56(10) 7_575 3_645 ?
O3 Dy1 C16 27.12(11) 7_575 7_575 ?
O4 Dy1 O7 76.34(10) 7_575 3_645 ?
O4 Dy1 O8 80.10(11) 7_575 3_645 ?
O4 Dy1 O3 53.98(10) 7_575 7_575 ?
O4 Dy1 C24 75.62(11) 7_575 3_645 ?
O4 Dy1 C16 27.12(11) 7_575 7_575 ?
O9 Dy1 O7 147.70(11) . 3_645 ?
O9 Dy1 O8 133.27(11) . 3_645 ?
O9 Dy1 O3 79.66(11) . 7_575 ?
O9 Dy1 O4 132.72(11) . 7_575 ?
O9 Dy1 C24 150.12(12) . 3_645 ?
O9 Dy1 C16 106.73(13) . 7_575 ?
C16 Dy1 C24 102.47(12) 7_575 3_645 ?
C24 O7 Dy1 91.7(2) . 3_655 ?
C24 O8 Dy1 94.1(2) . 3_655 ?
C17 O5 Dy1 142.2(3) . . ?
C1 O1 Dy1 162.4(3) . . ?
C1 O2 Dy1 135.1(3) . 5_666 ?
C16 O3 Dy1 89.8(3) . 7_576 ?
C16 O4 Dy1 93.4(2) . 7_576 ?
Dy1 O9 H9A 108.9 . . ?
Dy1 O9 H9B 122.3 . . ?
H9A O9 H9B 99.6 . . ?
H01A O01 H01B 116.3 . . ?
H02A O02 H02B 105.2 . . ?
C12 N2 C14 121.6(4) . . ?
C13 N2 C12 119.7(4) . . ?
C13 N2 C14 118.6(4) . . ?
C4 N1 C3 119.6(4) . . ?
C5 N1 C4 119.9(4) . . ?
C5 N1 C3 120.3(4) . . ?
O7 C24 Dy1 61.7(2) . 3_655 ?
O7 C24 O8 120.6(4) . . ?
O7 C24 C23 120.7(4) . . ?
O8 C24 Dy1 59.0(2) . 3_655 ?
O8 C24 C23 118.7(4) . . ?
C23 C24 Dy1 174.0(3) . 3_655 ?
C22 C23 C24 120.1(3) . . ?
C21 C23 C24 120.3(4) . . ?
C21 C23 C22 119.5(4) . . ?
C23 C22 H22 119.9 . . ?
C20 C22 C23 120.2(4) . . ?
C20 C22 H22 119.9 . . ?
C22 C20 H20 119.7 . . ?
C22 C20 C18 120.7(4) . . ?
C18 C20 H20 119.7 . . ?
C20 C18 C19 118.9(4) . . ?
C20 C18 C17 119.7(4) . . ?
C19 C18 C17 121.4(3) . . ?
C18 C19 H19 119.6 . . ?
C21 C19 C18 120.7(4) . . ?
C21 C19 H19 119.6 . . ?
C23 C21 C19 120.0(4) . . ?
C23 C21 H21 120.0 . . ?
C19 C21 H21 120.0 . . ?
O6 C17 O5 125.5(4) . . ?
O6 C17 C18 119.4(4) . . ?
O5 C17 C18 115.1(4) . . ?
N1 C4 H4 119.2 . . ?
N1 C4 C6 121.5(4) . . ?
C6 C4 H4 119.2 . . ?
C4 C6 H6 119.9 . . ?
C4 C6 C8 120.3(4) . . ?
C8 C6 H6 119.9 . . ?
C6 C8 C7 117.1(4) . . ?
C6 C8 C9 120.8(4) . . ?
C7 C8 C9 122.0(4) . . ?
C8 C7 H7 119.9 . . ?
C5 C7 C8 120.2(4) . . ?
C5 C7 H7 119.9 . . ?
N1 C5 C7 120.9(4) . . ?
N1 C5 H5 119.5 . . ?
C7 C5 H5 119.5 . . ?
C10 C9 C8 122.3(4) . . ?
C11 C9 C8 121.1(4) . . ?
C11 C9 C10 116.4(4) . . ?
C9 C10 H10 119.5 . . ?
C12 C10 C9 120.9(4) . . ?
C12 C10 H10 119.5 . . ?
N2 C12 C10 121.0(4) . . ?
N2 C12 H12 119.5 . . ?
C10 C12 H12 119.5 . . ?
N2 C13 H13 119.6 . . ?
N2 C13 C11 120.9(4) . . ?
C11 C13 H13 119.6 . . ?
C9 C11 H11 119.5 . . ?
C13 C11 C9 121.0(4) . . ?
C13 C11 H11 119.5 . . ?
N2 C14 H14A 108.9 . . ?
N2 C14 H14B 108.9 . . ?
N2 C14 C15 113.5(4) . . ?
H14A C14 H14B 107.7 . . ?
C15 C14 H14A 108.9 . . ?
C15 C14 H14B 108.9 . . ?
C14 C15 H15A 108.7 . . ?
C14 C15 H15B 108.7 . . ?
H15A C15 H15B 107.6 . . ?
C16 C15 C14 114.1(4) . . ?
C16 C15 H15A 108.7 . . ?
C16 C15 H15B 108.7 . . ?
O3 C16 Dy1 63.1(2) . 7_576 ?
O3 C16 O4 121.6(4) . . ?
O3 C16 C15 120.2(4) . . ?
O4 C16 Dy1 59.5(2) . 7_576 ?
O4 C16 C15 118.2(4) . . ?
C15 C16 Dy1 170.9(3) . 7_576 ?
N1 C3 H3A 109.1 . . ?
N1 C3 H3B 109.1 . . ?
N1 C3 C2 112.5(4) . . ?
H3A C3 H3B 107.8 . . ?
C2 C3 H3A 109.1 . . ?
C2 C3 H3B 109.1 . . ?
C3 C2 H2A 108.7 . . ?
C3 C2 H2B 108.7 . . ?
H2A C2 H2B 107.6 . . ?
C1 C2 C3 114.3(4) . . ?
C1 C2 H2A 108.7 . . ?
C1 C2 H2B 108.7 . . ?
O1 C1 O2 124.2(4) . . ?
O1 C1 C2 118.3(4) . . ?
O2 C1 C2 117.5(4) . . ?
O11 N3 O10 118.8(9) . . ?
O11 N3 O12 122.1(9) . . ?
O12 N3 O10 119.1(9) . . ?
O11' N3' O10' 120.2(9) . . ?
O11' N3' O12' 120.4(9) . . ?
O12' N3' O10' 119.4(9) . . ?
H13A O13 H13B 109.5 . . ?
H14C O14 H14D 104.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy1 O7 C24 O8 -4.6(4) 3_655 . . . ?
Dy1 O7 C24 C23 173.7(3) 3_655 . . . ?
Dy1 O8 C24 O7 4.7(4) 3_655 . . . ?
Dy1 O8 C24 C23 -173.6(3) 3_655 . . . ?
Dy1 O5 C17 O6 -4.0(7) . . . . ?
Dy1 O5 C17 C18 176.8(3) . . . . ?
Dy1 O1 C1 O2 57.6(11) . . . . ?
Dy1 O1 C1 C2 -121.3(9) . . . . ?
Dy1 O2 C1 O1 12.8(6) 5_666 . . . ?
Dy1 O2 C1 C2 -168.3(3) 5_666 . . . ?
Dy1 O3 C16 O4 -11.1(4) 7_576 . . . ?
Dy1 O3 C16 C15 170.3(4) 7_576 . . . ?
Dy1 O4 C16 O3 11.5(4) 7_576 . . . ?
Dy1 O4 C16 C15 -169.9(3) 7_576 . . . ?
O7 C24 C23 C22 173.4(4) . . . . ?
O7 C24 C23 C21 -9.9(6) . . . . ?
O8 C24 C23 C22 -8.3(6) . . . . ?
O8 C24 C23 C21 168.4(4) . . . . ?
N2 C13 C11 C9 -0.3(7) . . . . ?
N2 C14 C15 C16 -67.1(5) . . . . ?
N1 C4 C6 C8 1.3(8) . . . . ?
N1 C3 C2 C1 -70.4(5) . . . . ?
C24 C23 C22 C20 176.6(4) . . . . ?
C24 C23 C21 C19 -174.3(4) . . . . ?
C23 C22 C20 C18 -2.3(6) . . . . ?
C22 C23 C21 C19 2.5(6) . . . . ?
C22 C20 C18 C19 2.3(6) . . . . ?
C22 C20 C18 C17 -175.9(4) . . . . ?
C20 C18 C19 C21 0.1(6) . . . . ?
C20 C18 C17 O6 -31.9(6) . . . . ?
C20 C18 C17 O5 147.3(4) . . . . ?
C18 C19 C21 C23 -2.5(6) . . . . ?
C19 C18 C17 O6 150.0(4) . . . . ?
C19 C18 C17 O5 -30.8(5) . . . . ?
C21 C23 C22 C20 -0.1(6) . . . . ?
C17 C18 C19 C21 178.3(4) . . . . ?
C4 N1 C5 C7 -2.8(7) . . . . ?
C4 N1 C3 C2 -67.0(5) . . . . ?
C4 C6 C8 C7 -4.2(7) . . . . ?
C4 C6 C8 C9 171.8(4) . . . . ?
C6 C8 C7 C5 3.7(7) . . . . ?
C6 C8 C9 C10 28.8(7) . . . . ?
C6 C8 C9 C11 -146.6(4) . . . . ?
C8 C7 C5 N1 -0.3(7) . . . . ?
C8 C9 C10 C12 -173.0(4) . . . . ?
C8 C9 C11 C13 173.7(4) . . . . ?
C7 C8 C9 C10 -155.4(4) . . . . ?
C7 C8 C9 C11 29.2(6) . . . . ?
C5 N1 C4 C6 2.3(7) . . . . ?
C5 N1 C3 C2 117.4(5) . . . . ?
C9 C8 C7 C5 -172.2(4) . . . . ?
C9 C10 C12 N2 -1.0(7) . . . . ?
C10 C9 C11 C13 -1.9(6) . . . . ?
C12 N2 C13 C11 2.0(6) . . . . ?
C12 N2 C14 C15 109.8(5) . . . . ?
C13 N2 C12 C10 -1.4(7) . . . . ?
C13 N2 C14 C15 -73.5(5) . . . . ?
C11 C9 C10 C12 2.6(7) . . . . ?
C14 N2 C12 C10 175.2(4) . . . . ?
C14 N2 C13 C11 -174.7(4) . . . . ?
C14 C15 C16 O3 -9.9(6) . . . . ?
C14 C15 C16 O4 171.5(4) . . . . ?
C3 N1 C4 C6 -173.3(4) . . . . ?
C3 N1 C5 C7 172.8(4) . . . . ?
C3 C2 C1 O1 -33.1(6) . . . . ?
C3 C2 C1 O2 147.9(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_2-dy
_database_code_depnum_ccdc_archive 'CCDC 2412117'
loop_
_audit_author_name
_audit_author_address
'Wen-Bin Sun'
;Heilongjiang University
China
;
_audit_update_record             
;
2024-12-21 deposited with the CCDC.	2025-03-24 downloaded from the CCDC.
;
_audit_creation_date             2024-12-14
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C32 H20 Dy2 N O14'
_chemical_formula_sum            'C32 H20 Dy2 N O14'
_chemical_formula_weight         967.49
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   10.7786(6)
_cell_length_b                   13.8101(7)
_cell_length_c                   22.0003(9)
_cell_angle_alpha                90
_cell_angle_beta                 102.801(5)
_cell_angle_gamma                90
_cell_volume                     3193.4(3)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    9087
_cell_measurement_temperature    293
_cell_measurement_theta_max      28.8390
_cell_measurement_theta_min      3.7840
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    4.717
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.31422
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.81a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   .
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.012
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1852
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1091
_diffrn_reflns_av_unetI/netI     0.1376
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.858
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            22059
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.858
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.297
_diffrn_reflns_theta_min         3.406
_diffrn_ambient_temperature      293.0
_diffrn_detector_area_resol_mean 16.1954
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.858
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -37.00  52.00   1.00    6.82    --  -16.60  33.00 -41.00   89
  2  ω    -41.00 -13.00   1.00    6.82    --  -16.60 -33.00 160.00   28
  3  ω    -46.00 -20.00   1.00    6.82    --   16.91 -33.00 160.00   26
  4  ω    -25.00  15.00   1.00    6.82    --  -16.60 -99.00 -90.00   40
  5  ω    -22.00  14.00   1.00    6.82    --  -16.60 -99.00 120.00   36
  6  ω    -89.00 -33.00   1.00    6.82    --  -16.60 178.00  90.00   56
  7  ω    -24.00  34.00   1.00    6.82    --   16.91 -99.00 150.00   58
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4983
_reflns_number_total             7481
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.81a (Rigaku OD, 2023)'
_computing_data_collection       'CrysAlisPro 1.171.42.81a (Rigaku OD, 2023)'
_computing_data_reduction        'CrysAlisPro 1.171.42.81a (Rigaku OD, 2023)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'olex2.solve 1.3 (Bourhis et al., 2015)'
_refine_diff_density_max         0.313
_refine_diff_density_min         -0.243
_refine_diff_density_rms         0.031
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     444
_refine_ls_number_reflns         7481
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1398
_refine_ls_R_factor_gt           0.0904
_refine_ls_restrained_S_all      1.049
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0430P)²+1.1175P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1748
_refine_ls_wR_factor_ref         0.1980
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C3(H3A,H3B), C2(H2A,H2B)
2.b Aromatic/amide H refined with riding coordinates:
 C15(H15), C31(H31), C23(H23), C13(H13), C5(H5), C21(H21), C27(H27), C4(H4),
 C19(H19), C12(H12), C11(H11), C8(H8), C7(H7), C29(H29), C20(H20), C28(H28)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy01 Dy 0.95669(6) 0.51746(5) 0.15990(3) 0.0338(10) Uani 1 1 d . . . . .
Dy02 Dy 0.78312(7) 0.27597(5) 0.23006(3) 0.0358(10) Uani 1 1 d . . . . .
O11 O 0.7804(10) 0.1897(8) 0.3153(5) 0.043(3) Uani 1 1 d . . . . .
O8 O 0.8338(10) 0.4966(8) 0.2318(5) 0.044(3) Uani 1 1 d . . . . .
O9 O 1.0346(10) 0.8261(8) 0.3066(5) 0.042(2) Uani 1 1 d . . . . .
O10 O 0.9307(10) 0.8870(7) 0.3737(5) 0.042(3) Uani 1 1 d . . . . .
O14 O 0.8034(10) 0.0649(8) 0.5915(4) 0.043(3) Uani 1 1 d . . . . .
O12 O 0.8900(10) 0.0896(7) 0.3851(4) 0.040(2) Uani 1 1 d . . . . .
O4 O 0.8896(10) 0.0171(8) 0.2523(5) 0.045(3) Uani 1 1 d . . . . .
O7 O 0.8653(10) 0.3851(7) 0.3076(5) 0.043(3) Uani 1 1 d . . . . .
O6 O 0.9419(11) -0.3111(8) 0.1844(5) 0.048(3) Uani 1 1 d . . . . .
O13 O 0.6984(11) 0.1819(8) 0.6282(5) 0.044(3) Uani 1 1 d . . . . .
O3 O 0.7991(10) 0.1314(7) 0.1857(5) 0.041(2) Uani 1 1 d . . . . .
O5 O 0.8257(11) -0.3643(8) 0.0967(6) 0.052(3) Uani 1 1 d . . . . .
O1 O 0.6073(11) 0.3717(9) 0.2450(5) 0.055(3) Uani 1 1 d . . . . .
C17 C 0.8594(13) 0.4709(13) 0.2887(7) 0.044(4) Uani 1 1 d . . . . .
O2 O 0.5559(11) 0.2244(10) 0.2117(6) 0.057(3) Uani 1 1 d . . . . .
C22 C 0.9389(14) 0.7164(10) 0.3662(7) 0.039(3) Uani 1 1 d . . . . .
C18 C 0.8857(15) 0.5487(10) 0.3378(6) 0.037(3) Uani 1 1 d . . . . .
C9 C 0.8300(13) 0.0441(11) 0.1998(6) 0.037(3) Uani 1 1 d . . . . .
C32 C 0.7398(13) 0.1419(11) 0.5854(6) 0.036(3) Uani 1 1 d . . . . .
C25 C 0.8136(14) 0.1561(10) 0.3704(7) 0.037(3) Uani 1 1 d . . . . .
C14 C 0.8114(14) -0.1961(11) 0.1187(7) 0.038(3) Uani 1 1 d . . . . .
C24 C 0.9687(14) 0.8142(11) 0.3483(7) 0.038(3) Uani 1 1 d . . . . .
C16 C 0.8631(16) -0.2960(11) 0.1352(7) 0.046(4) Uani 1 1 d . . . . .
N1 N 0.4035(12) 0.4633(11) 0.1397(6) 0.050(3) Uani 1 1 d . . . . .
C15 C 0.8364(14) -0.1269(10) 0.1645(7) 0.037(3) Uani 1 1 d . . . . .
H15 H 0.880762 -0.143161 0.204477 0.044 Uiso 1 1 calc R U . . .
C30 C 0.7143(14) 0.1879(11) 0.5226(7) 0.039(3) Uani 1 1 d . . . . .
C31 C 0.7741(13) 0.1540(11) 0.4777(6) 0.035(3) Uani 1 1 d . . . . .
H31 H 0.830963 0.102633 0.486677 0.042 Uiso 1 1 calc R U . . .
C26 C 0.7500(15) 0.1963(11) 0.4188(6) 0.041(3) Uani 1 1 d . . . . .
C1 C 0.5243(15) 0.3095(15) 0.2256(8) 0.052(4) Uani 1 1 d . . . . .
C23 C 0.9099(14) 0.6428(11) 0.3213(7) 0.040(3) Uani 1 1 d . . . . .
H23 H 0.906898 0.657332 0.279708 0.049 Uiso 1 1 calc R U . . .
C10 C 0.7949(14) -0.0315(11) 0.1510(7) 0.040(3) Uani 1 1 d . . . . .
C13 C 0.7415(16) -0.1732(12) 0.0596(8) 0.050(4) Uani 1 1 d . . . . .
H13 H 0.722763 -0.221029 0.029175 0.060 Uiso 1 1 calc R U . . .
C5 C 0.5424(15) 0.5322(14) 0.0850(8) 0.054(4) Uani 1 1 d . . . . .
H5 H 0.612741 0.571560 0.085551 0.065 Uiso 1 1 calc R U . . .
C21 C 0.9401(18) 0.6951(11) 0.4276(7) 0.050(4) Uani 1 1 d . . . . .
H21 H 0.954086 0.743767 0.457583 0.060 Uiso 1 1 calc R U . . .
C27 C 0.6648(18) 0.2722(13) 0.4048(7) 0.057(5) Uani 1 1 d . . . . .
H27 H 0.646203 0.298697 0.364944 0.069 Uiso 1 1 calc R U . . .
C4 C 0.5056(17) 0.5151(14) 0.1388(8) 0.056(4) Uani 1 1 d . . . . .
H4 H 0.553302 0.540323 0.175827 0.067 Uiso 1 1 calc R U . . .
C19 C 0.8941(17) 0.5292(12) 0.4002(7) 0.049(4) Uani 1 1 d . . . . .
H19 H 0.881499 0.465903 0.412027 0.059 Uiso 1 1 calc R U . . .
C12 C 0.700(2) -0.0808(14) 0.0459(8) 0.062(5) Uani 1 1 d . . . . .
H12 H 0.653813 -0.065556 0.006180 0.075 Uiso 1 1 calc R U . . .
C11 C 0.7271(17) -0.0090(13) 0.0918(8) 0.055(4) Uani 1 1 d . . . . .
H11 H 0.699406 0.054156 0.082393 0.066 Uiso 1 1 calc R U . . .
C8 C 0.3362(17) 0.4261(13) 0.0872(8) 0.054(4) Uani 1 1 d . . . . .
H8 H 0.263949 0.389823 0.088150 0.065 Uiso 1 1 calc R U . . .
C6 C 0.4785(15) 0.4930(12) 0.0292(8) 0.046(4) Uani 1 1 d . . . . .
C3 C 0.3636(18) 0.4434(15) 0.1997(8) 0.061(5) Uani 1 1 d . . . . .
H3A H 0.411710 0.484074 0.232522 0.074 Uiso 1 1 calc R U . . .
H3B H 0.274003 0.458164 0.194923 0.074 Uiso 1 1 calc R U . . .
C7 C 0.3705(16) 0.4399(14) 0.0316(8) 0.054(4) Uani 1 1 d . . . . .
H7 H 0.321264 0.413551 -0.004775 0.064 Uiso 1 1 calc R U . . .
C29 C 0.6272(17) 0.2659(12) 0.5080(7) 0.051(4) Uani 1 1 d . . . . .
H29 H 0.583752 0.288304 0.537293 0.061 Uiso 1 1 calc R U . . .
C2 C 0.3871(16) 0.3389(16) 0.2167(9) 0.063(5) Uani 1 1 d . . . . .
H2A H 0.336225 0.299250 0.184085 0.076 Uiso 1 1 calc R U . . .
H2B H 0.359147 0.326202 0.254866 0.076 Uiso 1 1 calc R U . . .
C20 C 0.920(2) 0.5983(14) 0.4448(8) 0.061(5) Uani 1 1 d . . . . .
H20 H 0.924130 0.582537 0.486280 0.073 Uiso 1 1 calc R U . . .
C28 C 0.6076(19) 0.3083(14) 0.4500(8) 0.061(5) Uani 1 1 d . . . . .
H28 H 0.554930 0.362160 0.441242 0.073 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy01 O8 2.295(9) . ?
Dy01 O9 2.739(11) 2_745 ?
Dy01 O10 2.379(10) 2_745 ?
Dy01 O14 2.278(10) 4_565 ?
Dy01 O12 2.330(9) 2_755 ?
Dy01 O4 2.249(11) 2_755 ?
Dy01 O6 2.441(11) 1_565 ?
Dy01 O5 2.393(11) 1_565 ?
Dy02 O11 2.228(9) . ?
Dy02 O9 2.386(10) 2_745 ?
Dy02 O7 2.302(10) . ?
Dy02 O13 2.299(10) 4_565 ?
Dy02 O3 2.245(9) . ?
Dy02 O1 2.392(11) . ?
Dy02 O2 2.496(12) . ?
O11 C25 1.272(16) . ?
O8 C17 1.271(18) . ?
O9 C24 1.289(16) . ?
O10 C24 1.262(17) . ?
O14 C32 1.256(17) . ?
O12 C25 1.228(17) . ?
O4 C9 1.248(17) . ?
O7 C17 1.254(19) . ?
O6 C16 1.237(19) . ?
O13 C32 1.257(16) . ?
O3 C9 1.271(17) . ?
O5 C16 1.272(18) . ?
O1 C1 1.24(2) . ?
C17 C18 1.51(2) . ?
O2 C1 1.28(2) . ?
C22 C24 1.46(2) . ?
C22 C23 1.40(2) . ?
C22 C21 1.38(2) . ?
C18 C23 1.391(19) . ?
C18 C19 1.38(2) . ?
C9 C10 1.48(2) . ?
C32 C30 1.49(2) . ?
C25 C26 1.495(18) . ?
C14 C16 1.50(2) . ?
C14 C15 1.37(2) . ?
C14 C13 1.39(2) . ?
N1 C4 1.32(2) . ?
N1 C8 1.32(2) . ?
N1 C3 1.50(2) . ?
C15 H15 0.9300 . ?
C15 C10 1.40(2) . ?
C30 C31 1.377(18) . ?
C30 C29 1.42(2) . ?
C31 H31 0.9300 . ?
C31 C26 1.391(18) . ?
C26 C27 1.38(2) . ?
C1 C2 1.50(2) . ?
C23 H23 0.9300 . ?
C10 C11 1.38(2) . ?
C13 H13 0.9300 . ?
C13 C12 1.36(2) . ?
C5 H5 0.9300 . ?
C5 C4 1.35(2) . ?
C5 C6 1.38(2) . ?
C21 H21 0.9300 . ?
C21 C20 1.42(2) . ?
C27 H27 0.9300 . ?
C27 C28 1.37(2) . ?
C4 H4 0.9300 . ?
C19 H19 0.9300 . ?
C19 C20 1.35(2) . ?
C12 H12 0.9300 . ?
C12 C11 1.40(2) . ?
C11 H11 0.9300 . ?
C8 H8 0.9300 . ?
C8 C7 1.37(2) . ?
C6 C6 1.47(3) 3_665 ?
C6 C7 1.39(2) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C3 C2 1.50(3) . ?
C7 H7 0.9300 . ?
C29 H29 0.9300 . ?
C29 C28 1.38(2) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C20 H20 0.9300 . ?
C28 H28 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O8 Dy01 O9 71.6(3) . 2_745 ?
O8 Dy01 O10 122.1(4) . 2_745 ?
O8 Dy01 O12 156.7(3) . 2_755 ?
O8 Dy01 O6 83.9(4) . 1_565 ?
O8 Dy01 O5 97.5(4) . 1_565 ?
O10 Dy01 O9 50.5(3) 2_745 2_745 ?
O10 Dy01 O6 149.9(4) 2_745 1_565 ?
O10 Dy01 O5 127.7(4) 2_745 1_565 ?
O14 Dy01 O8 87.0(4) 4_565 . ?
O14 Dy01 O9 70.9(4) 4_565 2_745 ?
O14 Dy01 O10 76.2(4) 4_565 2_745 ?
O14 Dy01 O12 114.3(3) 4_565 2_755 ?
O14 Dy01 O6 123.8(4) 4_565 1_565 ?
O14 Dy01 O5 73.0(4) 4_565 1_565 ?
O12 Dy01 O9 122.8(3) 2_755 2_745 ?
O12 Dy01 O10 74.5(3) 2_755 2_745 ?
O12 Dy01 O6 76.5(4) 2_755 1_565 ?
O12 Dy01 O5 81.0(4) 2_755 1_565 ?
O4 Dy01 O8 80.5(4) 2_755 . ?
O4 Dy01 O9 78.0(3) 2_755 2_745 ?
O4 Dy01 O10 86.3(4) 2_755 2_745 ?
O4 Dy01 O14 148.7(4) 2_755 4_565 ?
O4 Dy01 O12 84.8(4) 2_755 2_755 ?
O4 Dy01 O6 83.4(4) 2_755 1_565 ?
O4 Dy01 O5 136.8(4) 2_755 1_565 ?
O6 Dy01 O9 151.2(3) 1_565 2_745 ?
O5 Dy01 O9 142.7(4) 1_565 2_745 ?
O5 Dy01 O6 53.7(4) 1_565 1_565 ?
O11 Dy02 O9 127.2(4) . 2_745 ?
O11 Dy02 O7 78.5(4) . . ?
O11 Dy02 O13 151.6(4) . 4_565 ?
O11 Dy02 O3 84.7(4) . . ?
O11 Dy02 O1 91.2(4) . . ?
O11 Dy02 O2 77.8(4) . . ?
O9 Dy02 O1 128.5(4) 2_745 . ?
O9 Dy02 O2 151.6(4) 2_745 . ?
O7 Dy02 O9 81.4(4) . 2_745 ?
O7 Dy02 O1 73.9(4) . . ?
O7 Dy02 O2 120.6(4) . . ?
O13 Dy02 O9 77.0(4) 4_565 2_745 ?
O13 Dy02 O7 124.2(4) 4_565 . ?
O13 Dy02 O1 80.7(4) 4_565 . ?
O13 Dy02 O2 75.6(4) 4_565 . ?
O3 Dy02 O9 87.9(4) . 2_745 ?
O3 Dy02 O7 148.2(4) . . ?
O3 Dy02 O13 81.6(4) . 4_565 ?
O3 Dy02 O1 133.7(4) . . ?
O3 Dy02 O2 81.0(4) . . ?
O1 Dy02 O2 53.2(4) . . ?
C25 O11 Dy02 160.7(10) . . ?
C17 O8 Dy01 132.9(10) . . ?
Dy02 O9 Dy01 112.9(4) 2_755 2_755 ?
C24 O9 Dy01 85.6(8) . 2_755 ?
C24 O9 Dy02 145.9(10) . 2_755 ?
C24 O10 Dy01 103.2(8) . 2_755 ?
C32 O14 Dy01 142.4(9) . 4_566 ?
C25 O12 Dy01 134.8(9) . 2_745 ?
C9 O4 Dy01 157.6(10) . 2_745 ?
C17 O7 Dy02 112.9(10) . . ?
C16 O6 Dy01 92.1(9) . 1_545 ?
C32 O13 Dy02 135.4(10) . 4_566 ?
C9 O3 Dy02 141.2(9) . . ?
C16 O5 Dy01 93.4(10) . 1_545 ?
C1 O1 Dy02 95.9(11) . . ?
O8 C17 C18 118.2(15) . . ?
O7 C17 O8 125.1(14) . . ?
O7 C17 C18 116.6(14) . . ?
C1 O2 Dy02 90.2(10) . . ?
C23 C22 C24 120.5(13) . . ?
C21 C22 C24 120.4(13) . . ?
C21 C22 C23 119.1(13) . . ?
C23 C18 C17 119.7(13) . . ?
C19 C18 C17 122.3(14) . . ?
C19 C18 C23 117.9(13) . . ?
O4 C9 O3 124.2(14) . . ?
O4 C9 C10 117.1(13) . . ?
O3 C9 C10 118.8(13) . . ?
O14 C32 O13 124.6(13) . . ?
O14 C32 C30 116.4(12) . . ?
O13 C32 C30 119.0(13) . . ?
O11 C25 C26 117.8(13) . . ?
O12 C25 O11 123.8(13) . . ?
O12 C25 C26 118.4(12) . . ?
C15 C14 C16 117.5(13) . . ?
C15 C14 C13 120.5(14) . . ?
C13 C14 C16 122.1(14) . . ?
O9 C24 Dy01 68.4(8) . 2_755 ?
O9 C24 C22 119.9(13) . . ?
O10 C24 Dy01 52.1(7) . 2_755 ?
O10 C24 O9 119.8(13) . . ?
O10 C24 C22 120.3(12) . . ?
C22 C24 Dy01 168.2(10) . 2_755 ?
O6 C16 Dy01 61.5(9) . 1_545 ?
O6 C16 O5 120.8(16) . . ?
O6 C16 C14 120.8(14) . . ?
O5 C16 Dy01 59.4(9) . 1_545 ?
O5 C16 C14 118.3(15) . . ?
C14 C16 Dy01 177.4(11) . 1_545 ?
C4 N1 C8 119.6(15) . . ?
C4 N1 C3 121.1(15) . . ?
C8 N1 C3 119.2(15) . . ?
C14 C15 H15 120.1 . . ?
C14 C15 C10 119.8(14) . . ?
C10 C15 H15 120.1 . . ?
C31 C30 C32 120.1(13) . . ?
C31 C30 C29 119.1(13) . . ?
C29 C30 C32 120.8(12) . . ?
C30 C31 H31 119.8 . . ?
C30 C31 C26 120.4(13) . . ?
C26 C31 H31 119.8 . . ?
C31 C26 C25 119.1(13) . . ?
C27 C26 C25 120.6(13) . . ?
C27 C26 C31 120.2(13) . . ?
O1 C1 O2 120.4(15) . . ?
O1 C1 C2 118.0(18) . . ?
O2 C1 C2 121.5(17) . . ?
C22 C23 H23 119.4 . . ?
C18 C23 C22 121.2(13) . . ?
C18 C23 H23 119.4 . . ?
C15 C10 C9 119.3(13) . . ?
C11 C10 C9 121.3(15) . . ?
C11 C10 C15 119.4(14) . . ?
C14 C13 H13 119.9 . . ?
C12 C13 C14 120.2(15) . . ?
C12 C13 H13 119.9 . . ?
C4 C5 H5 119.2 . . ?
C4 C5 C6 121.7(17) . . ?
C6 C5 H5 119.2 . . ?
C22 C21 H21 120.2 . . ?
C22 C21 C20 119.5(14) . . ?
C20 C21 H21 120.2 . . ?
C26 C27 H27 120.1 . . ?
C28 C27 C26 119.8(14) . . ?
C28 C27 H27 120.1 . . ?
N1 C4 C5 121.2(18) . . ?
N1 C4 H4 119.4 . . ?
C5 C4 H4 119.4 . . ?
C18 C19 H19 118.7 . . ?
C20 C19 C18 122.7(15) . . ?
C20 C19 H19 118.7 . . ?
C13 C12 H12 120.0 . . ?
C13 C12 C11 119.9(16) . . ?
C11 C12 H12 120.0 . . ?
C10 C11 C12 120.2(16) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
N1 C8 H8 119.3 . . ?
N1 C8 C7 121.5(17) . . ?
C7 C8 H8 119.3 . . ?
C5 C6 C6 122.3(19) . 3_665 ?
C5 C6 C7 115.7(15) . . ?
C7 C6 C6 122(2) . 3_665 ?
N1 C3 H3A 109.8 . . ?
N1 C3 H3B 109.8 . . ?
H3A C3 H3B 108.3 . . ?
C2 C3 N1 109.3(15) . . ?
C2 C3 H3A 109.8 . . ?
C2 C3 H3B 109.8 . . ?
C8 C7 C6 120.2(17) . . ?
C8 C7 H7 119.9 . . ?
C6 C7 H7 119.9 . . ?
C30 C29 H29 120.3 . . ?
C28 C29 C30 119.4(13) . . ?
C28 C29 H29 120.3 . . ?
C1 C2 H2A 108.8 . . ?
C1 C2 H2B 108.8 . . ?
C3 C2 C1 113.6(16) . . ?
C3 C2 H2A 108.8 . . ?
C3 C2 H2B 108.8 . . ?
H2A C2 H2B 107.7 . . ?
C21 C20 H20 120.3 . . ?
C19 C20 C21 119.4(15) . . ?
C19 C20 H20 120.3 . . ?
C27 C28 C29 121.0(15) . . ?
C27 C28 H28 119.5 . . ?
C29 C28 H28 119.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Dy01 O8 C17 O7 -86.3(18) . . . . ?
Dy01 O8 C17 C18 93.4(15) . . . . ?
Dy01 O9 C24 O10 9.0(13) 2_755 . . . ?
Dy01 O9 C24 C22 -170.7(13) 2_755 . . . ?
Dy01 O10 C24 O9 -10.6(16) 2_755 . . . ?
Dy01 O10 C24 C22 169.1(12) 2_755 . . . ?
Dy01 O14 C32 O13 -37(2) 4_566 . . . ?
Dy01 O14 C32 C30 142.1(12) 4_566 . . . ?
Dy01 O12 C25 O11 17(2) 2_745 . . . ?
Dy01 O12 C25 C26 -166.4(10) 2_745 . . . ?
Dy01 O4 C9 O3 -48(3) 2_745 . . . ?
Dy01 O4 C9 C10 131(2) 2_745 . . . ?
Dy01 O6 C16 O5 -0.1(15) 1_545 . . . ?
Dy01 O6 C16 C14 -178.6(12) 1_545 . . . ?
Dy01 O5 C16 O6 0.1(15) 1_545 . . . ?
Dy01 O5 C16 C14 178.7(11) 1_545 . . . ?
Dy02 O11 C25 O12 -83(3) . . . . ?
Dy02 O11 C25 C26 101(3) . . . . ?
Dy02 O9 C24 Dy01 125.7(16) 2_755 . . 2_755 ?
Dy02 O9 C24 O10 134.6(14) 2_755 . . . ?
Dy02 O9 C24 C22 -45(2) 2_755 . . . ?
Dy02 O7 C17 O8 -12.4(18) . . . . ?
Dy02 O7 C17 C18 167.9(9) . . . . ?
Dy02 O13 C32 O14 48(2) 4_566 . . . ?
Dy02 O13 C32 C30 -130.9(12) 4_566 . . . ?
Dy02 O3 C9 O4 -15(2) . . . . ?
Dy02 O3 C9 C10 165.9(10) . . . . ?
Dy02 O1 C1 O2 5.8(17) . . . . ?
Dy02 O1 C1 C2 -171.7(13) . . . . ?
Dy02 O2 C1 O1 -5.5(16) . . . . ?
Dy02 O2 C1 C2 171.8(15) . . . . ?
O11 C25 C26 C31 173.2(14) . . . . ?
O11 C25 C26 C27 -4(2) . . . . ?
O8 C17 C18 C23 -15(2) . . . . ?
O8 C17 C18 C19 169.3(15) . . . . ?
O14 C32 C30 C31 -9(2) . . . . ?
O14 C32 C30 C29 170.0(15) . . . . ?
O12 C25 C26 C31 -3(2) . . . . ?
O12 C25 C26 C27 178.9(17) . . . . ?
O4 C9 C10 C15 -4(2) . . . . ?
O4 C9 C10 C11 178.9(14) . . . . ?
O7 C17 C18 C23 165.2(13) . . . . ?
O7 C17 C18 C19 -11(2) . . . . ?
O13 C32 C30 C31 170.2(14) . . . . ?
O13 C32 C30 C29 -11(2) . . . . ?
O3 C9 C10 C15 175.4(13) . . . . ?
O3 C9 C10 C11 -2(2) . . . . ?
O1 C1 C2 C3 30(2) . . . . ?
C17 C18 C23 C22 -177.9(14) . . . . ?
C17 C18 C19 C20 178.8(17) . . . . ?
O2 C1 C2 C3 -147.0(17) . . . . ?
C22 C21 C20 C19 -3(3) . . . . ?
C18 C19 C20 C21 0(3) . . . . ?
C9 C10 C11 C12 177.2(16) . . . . ?
C32 C30 C31 C26 179.5(14) . . . . ?
C32 C30 C29 C28 178.7(17) . . . . ?
C25 C26 C27 C28 -179.8(18) . . . . ?
C14 C15 C10 C9 -175.9(13) . . . . ?
C14 C15 C10 C11 1(2) . . . . ?
C14 C13 C12 C11 -1(3) . . . . ?
C24 C22 C23 C18 177.7(14) . . . . ?
C24 C22 C21 C20 -175.5(16) . . . . ?
C16 C14 C15 C10 177.4(13) . . . . ?
C16 C14 C13 C12 -177.7(16) . . . . ?
N1 C8 C7 C6 1(3) . . . . ?
N1 C3 C2 C1 60(2) . . . . ?
C15 C14 C16 O6 -12(2) . . . . ?
C15 C14 C16 O5 169.8(14) . . . . ?
C15 C14 C13 C12 2(2) . . . . ?
C15 C10 C11 C12 0(3) . . . . ?
C30 C31 C26 C25 -178.3(14) . . . . ?
C30 C31 C26 C27 -1(2) . . . . ?
C30 C29 C28 C27 4(3) . . . . ?
C31 C30 C29 C28 -2(3) . . . . ?
C31 C26 C27 C28 3(3) . . . . ?
C26 C27 C28 C29 -4(3) . . . . ?
C23 C22 C24 Dy01 -171(4) . . . 2_755 ?
C23 C22 C24 O9 -38(2) . . . . ?
C23 C22 C24 O10 142.4(15) . . . . ?
C23 C22 C21 C20 4(3) . . . . ?
C23 C18 C19 C20 3(3) . . . . ?
C13 C14 C16 O6 168.1(14) . . . . ?
C13 C14 C16 O5 -11(2) . . . . ?
C13 C14 C15 C10 -2(2) . . . . ?
C13 C12 C11 C10 0(3) . . . . ?
C5 C6 C7 C8 -2(2) . . . . ?
C21 C22 C24 Dy01 9(6) . . . 2_755 ?
C21 C22 C24 O9 141.4(16) . . . . ?
C21 C22 C24 O10 -38(2) . . . . ?
C21 C22 C23 C18 -2(2) . . . . ?
C4 N1 C8 C7 0(3) . . . . ?
C4 N1 C3 C2 -108.8(19) . . . . ?
C4 C5 C6 C6 -176.8(19) . . . 3_665 ?
C4 C5 C6 C7 4(3) . . . . ?
C19 C18 C23 C22 -2(2) . . . . ?
C8 N1 C4 C5 1(3) . . . . ?
C8 N1 C3 C2 70(2) . . . . ?
C6 C5 C4 N1 -3(3) . . . . ?
C6 C6 C7 C8 178.0(19) 3_665 . . . ?
C3 N1 C4 C5 179.3(17) . . . . ?
C3 N1 C8 C7 -178.2(16) . . . . ?
C29 C30 C31 C26 0(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
