# Supplementary Information (SI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_bbb
_audit_block_doi                 10.5517/ccdc.csd.cc2nfbp4
_database_code_depnum_ccdc_archive 'CCDC 2455686'
loop_
_audit_author_name
_audit_author_address
'Huidong Xie'
;Xian University of Architecture and Technology
China
;
_audit_update_record             
;
2025-06-01 deposited with the CCDC.	2026-01-15 downloaded from the CCDC.
;
_audit_creation_date             2025-06-01
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Cl5 Sb, 2(C21 H20 O P)'
_chemical_formula_sum            'C42 H40 Cl5 O2 P2 Sb'
_chemical_formula_weight         937.68
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           61
_space_group_name_H-M_alt        'P b c a'
_space_group_name_Hall           '-P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   15.7027(3)
_cell_length_b                   31.3672(8)
_cell_length_c                   17.4338(4)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     8587.0(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9481
_cell_measurement_temperature    297.00
_cell_measurement_theta_max      26.424
_cell_measurement_theta_min      2.175
_shelx_estimated_absorpt_T_max   0.800
_shelx_estimated_absorpt_T_min   0.800
_exptl_absorpt_coefficient_mu    1.062
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.6748
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0835 before and 0.0635 after correction.
The Ratio of minimum to maximum transmission is 0.9049.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.451
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             3792
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.22
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0676
_diffrn_reflns_av_unetI/netI     0.0266
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       41
_diffrn_reflns_limit_k_min       -41
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            152137
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.252
_diffrn_reflns_theta_min         2.176
_diffrn_ambient_temperature      297.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                8091
_reflns_number_total             10607
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.719
_refine_diff_density_min         -0.482
_refine_diff_density_rms         0.058
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     471
_refine_ls_number_reflns         10607
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0528
_refine_ls_R_factor_gt           0.0349
_refine_ls_restrained_S_all      1.056
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0298P)²+6.4168P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0765
_refine_ls_wR_factor_ref         0.0874
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C40(H40a,H40b), C19(H19a,H19b)
2.b Aromatic/amide H refined with riding coordinates:
 C23(H23), C24(H24), C25(H25), C26(H26), C27(H27), C29(H29), C30(H30),
 C31(H31), C32(H32), C33(H33), C35(H35), C36(H36), C37(H37), C38(H38), C39(H39),
  C2(H2), C3(H3), C4(H4), C5(H5), C6(H6), C8(H8), C9(H9), C10(H10), C11(H11),
 C12(H12), C14(H14), C15(H15), C16(H16), C17(H17), C18(H18)
2.c Idealised Me refined as rotating group:
 C42(H42a,H42b,H42c), C21(H21a,H21b,H21c)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.59771(2) 0.61917(2) 0.64216(2) 0.04538(6) Uani 1 1 d . . . . .
Cl1 Cl 0.63934(6) 0.54190(2) 0.67856(6) 0.0782(2) Uani 1 1 d . . . . .
Cl2 Cl 0.62356(7) 0.63886(3) 0.77160(5) 0.0815(3) Uani 1 1 d . . . . .
Cl3 Cl 0.75293(6) 0.63401(4) 0.60403(8) 0.1059(4) Uani 1 1 d . . . . .
Cl4 Cl 0.55013(6) 0.69906(2) 0.62137(5) 0.0686(2) Uani 1 1 d . . . . .
Cl5 Cl 0.43731(6) 0.60498(3) 0.67598(8) 0.0948(3) Uani 1 1 d . . . . .
P2 P 0.43449(4) 0.76966(2) 0.38336(4) 0.04130(14) Uani 1 1 d . . . . .
O2 O 0.37001(14) 0.73146(6) 0.23839(12) 0.0636(5) Uani 1 1 d . . . . .
C22 C 0.45127(16) 0.80866(7) 0.45755(13) 0.0429(5) Uani 1 1 d . . . . .
C23 C 0.4381(2) 0.79838(9) 0.53369(16) 0.0668(8) Uani 1 1 d . . . . .
H23 H 0.419228 0.771249 0.546896 0.080 Uiso 1 1 calc R U . . .
C24 C 0.4528(3) 0.82826(11) 0.59007(18) 0.0841(11) Uani 1 1 d . . . . .
H24 H 0.444293 0.821166 0.641298 0.101 Uiso 1 1 calc R U . . .
C25 C 0.4799(2) 0.86851(10) 0.57082(18) 0.0722(9) Uani 1 1 d . . . . .
H25 H 0.489504 0.888687 0.608939 0.087 Uiso 1 1 calc R U . . .
C26 C 0.4928(2) 0.87881(9) 0.49575(18) 0.0629(8) Uani 1 1 d . . . . .
H26 H 0.511175 0.906088 0.483001 0.075 Uiso 1 1 calc R U . . .
C27 C 0.47883(18) 0.84933(8) 0.43850(16) 0.0535(6) Uani 1 1 d . . . . .
H27 H 0.487843 0.856642 0.387445 0.064 Uiso 1 1 calc R U . . .
C28 C 0.53263(16) 0.74167(8) 0.36773(14) 0.0438(5) Uani 1 1 d . . . . .
C29 C 0.57993(17) 0.72854(9) 0.43016(16) 0.0532(6) Uani 1 1 d . . . . .
H29 H 0.560866 0.734554 0.479487 0.064 Uiso 1 1 calc R U . . .
C30 C 0.65523(18) 0.70657(9) 0.42007(18) 0.0596(7) Uani 1 1 d . . . . .
H30 H 0.686018 0.697317 0.462489 0.072 Uiso 1 1 calc R U . . .
C31 C 0.68462(19) 0.69838(10) 0.34763(19) 0.0625(8) Uani 1 1 d . . . . .
H31 H 0.735422 0.683640 0.340622 0.075 Uiso 1 1 calc R U . . .
C32 C 0.6388(2) 0.71201(12) 0.28572(19) 0.0770(10) Uani 1 1 d . . . . .
H32 H 0.659274 0.706640 0.236595 0.092 Uiso 1 1 calc R U . . .
C33 C 0.5631(2) 0.73348(10) 0.29444(17) 0.0653(8) Uani 1 1 d . . . . .
H33 H 0.532653 0.742444 0.251643 0.078 Uiso 1 1 calc R U . . .
C34 C 0.35141(15) 0.73421(7) 0.41583(14) 0.0417(5) Uani 1 1 d . . . . .
C35 C 0.37073(17) 0.69773(8) 0.45704(16) 0.0501(6) Uani 1 1 d . . . . .
H35 H 0.427270 0.690115 0.465106 0.060 Uiso 1 1 calc R U . . .
C36 C 0.30614(19) 0.67266(9) 0.48614(17) 0.0565(7) Uani 1 1 d . . . . .
H36 H 0.319105 0.648488 0.514746 0.068 Uiso 1 1 calc R U . . .
C37 C 0.22260(19) 0.68346(9) 0.47280(17) 0.0567(7) Uani 1 1 d . . . . .
H37 H 0.179178 0.666349 0.491984 0.068 Uiso 1 1 calc R U . . .
C38 C 0.20275(18) 0.71949(9) 0.43116(17) 0.0551(7) Uani 1 1 d . . . . .
H38 H 0.146143 0.726461 0.421723 0.066 Uiso 1 1 calc R U . . .
C39 C 0.26720(17) 0.74516(8) 0.40355(15) 0.0518(6) Uani 1 1 d . . . . .
H39 H 0.253972 0.769879 0.376619 0.062 Uiso 1 1 calc R U . . .
C40 C 0.40129(17) 0.79763(8) 0.29846(14) 0.0473(6) Uani 1 1 d . . . . .
H40A H 0.360170 0.819234 0.313066 0.057 Uiso 1 1 calc R U . . .
H40B H 0.450293 0.812169 0.276937 0.057 Uiso 1 1 calc R U . . .
C41 C 0.36209(17) 0.76986(9) 0.23672(14) 0.0478(6) Uani 1 1 d . . . . .
C42 C 0.3164(2) 0.79279(11) 0.17536(19) 0.0729(9) Uani 1 1 d . . . . .
H42A H 0.265586 0.805345 0.195934 0.109 Uiso 1 1 calc R U . . .
H42B H 0.301613 0.773166 0.135264 0.109 Uiso 1 1 calc R U . . .
H42C H 0.352421 0.814775 0.154936 0.109 Uiso 1 1 calc R U . . .
P1 P 0.31302(4) 0.47684(2) 0.68077(4) 0.04220(14) Uani 1 1 d . . . . .
O1 O 0.42729(15) 0.46125(7) 0.81692(13) 0.0713(6) Uani 1 1 d . . . . .
C1 C 0.40108(16) 0.45215(8) 0.63341(14) 0.0458(6) Uani 1 1 d . . . . .
C2 C 0.47162(18) 0.47696(9) 0.61638(17) 0.0568(7) Uani 1 1 d . . . . .
H2 H 0.475803 0.504501 0.635786 0.068 Uiso 1 1 calc R U . . .
C3 C 0.5352(2) 0.46090(11) 0.5709(2) 0.0707(9) Uani 1 1 d . . . . .
H3 H 0.582708 0.477489 0.559812 0.085 Uiso 1 1 calc R U . . .
C4 C 0.5288(2) 0.42012(12) 0.54164(18) 0.0715(9) Uani 1 1 d . . . . .
H4 H 0.571814 0.409482 0.510326 0.086 Uiso 1 1 calc R U . . .
C5 C 0.4599(2) 0.39532(10) 0.55834(18) 0.0652(8) Uani 1 1 d . . . . .
H5 H 0.456233 0.367836 0.538605 0.078 Uiso 1 1 calc R U . . .
C6 C 0.39553(19) 0.41086(9) 0.60437(17) 0.0565(7) Uani 1 1 d . . . . .
H6 H 0.348710 0.393883 0.615946 0.068 Uiso 1 1 calc R U . . .
C7 C 0.24299(16) 0.43789(7) 0.72176(14) 0.0443(5) Uani 1 1 d . . . . .
C8 C 0.2750(2) 0.40295(9) 0.76212(17) 0.0602(7) Uani 1 1 d . . . . .
H8 H 0.333519 0.399384 0.767596 0.072 Uiso 1 1 calc R U . . .
C9 C 0.2198(2) 0.37385(10) 0.79375(18) 0.0683(9) Uani 1 1 d . . . . .
H9 H 0.241149 0.350491 0.820378 0.082 Uiso 1 1 calc R U . . .
C10 C 0.1336(2) 0.37892(10) 0.78642(18) 0.0645(8) Uani 1 1 d . . . . .
H10 H 0.096849 0.358849 0.807563 0.077 Uiso 1 1 calc R U . . .
C11 C 0.10130(19) 0.41326(10) 0.74827(19) 0.0617(7) Uani 1 1 d . . . . .
H11 H 0.042664 0.416835 0.744371 0.074 Uiso 1 1 calc R U . . .
C12 C 0.15544(17) 0.44272(8) 0.71545(16) 0.0522(6) Uani 1 1 d . . . . .
H12 H 0.133150 0.465920 0.688978 0.063 Uiso 1 1 calc R U . . .
C13 C 0.25914(16) 0.50720(8) 0.60764(14) 0.0458(5) Uani 1 1 d . . . . .
C14 C 0.2249(2) 0.54686(9) 0.62296(16) 0.0591(7) Uani 1 1 d . . . . .
H14 H 0.225554 0.557556 0.672707 0.071 Uiso 1 1 calc R U . . .
C15 C 0.1897(2) 0.57053(11) 0.56448(19) 0.0733(9) Uani 1 1 d . . . . .
H15 H 0.165681 0.596979 0.575108 0.088 Uiso 1 1 calc R U . . .
C16 C 0.1899(2) 0.55556(12) 0.49141(19) 0.0799(10) Uani 1 1 d . . . . .
H16 H 0.166515 0.571883 0.452162 0.096 Uiso 1 1 calc R U . . .
C17 C 0.2240(2) 0.51688(14) 0.47556(19) 0.0911(13) Uani 1 1 d . . . . .
H17 H 0.224456 0.506920 0.425314 0.109 Uiso 1 1 calc R U . . .
C18 C 0.2581(2) 0.49211(11) 0.53349(18) 0.0741(9) Uani 1 1 d . . . . .
H18 H 0.280290 0.465322 0.522404 0.089 Uiso 1 1 calc R U . . .
C19 C 0.34898(17) 0.51473(8) 0.75122(16) 0.0501(6) Uani 1 1 d . . . . .
H19A H 0.373727 0.538854 0.724482 0.060 Uiso 1 1 calc R U . . .
H19B H 0.299686 0.525109 0.779073 0.060 Uiso 1 1 calc R U . . .
C20 C 0.41302(18) 0.49868(11) 0.80860(16) 0.0571(7) Uani 1 1 d . . . . .
C21 C 0.4561(3) 0.53252(14) 0.8542(2) 0.1020(14) Uani 1 1 d . . . . .
H21A H 0.490287 0.519568 0.893527 0.153 Uiso 1 1 calc R U . . .
H21B H 0.414075 0.550593 0.877473 0.153 Uiso 1 1 calc R U . . .
H21C H 0.491855 0.549219 0.821155 0.153 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 Cl1 2.5891(8) . ?
Sb1 Cl2 2.3745(8) . ?
Sb1 Cl3 2.5689(9) . ?
Sb1 Cl4 2.6398(8) . ?
Sb1 Cl5 2.6248(8) . ?
P2 C22 1.800(2) . ?
P2 C28 1.794(3) . ?
P2 C34 1.805(2) . ?
P2 C40 1.798(2) . ?
O2 C41 1.211(3) . ?
C22 C23 1.382(4) . ?
C22 C27 1.387(3) . ?
C23 H23 0.9300 . ?
C23 C24 1.377(4) . ?
C24 H24 0.9300 . ?
C24 C25 1.374(5) . ?
C25 H25 0.9300 . ?
C25 C26 1.363(4) . ?
C26 H26 0.9300 . ?
C26 C27 1.378(4) . ?
C27 H27 0.9300 . ?
C28 C29 1.381(4) . ?
C28 C33 1.389(4) . ?
C29 H29 0.9300 . ?
C29 C30 1.380(4) . ?
C30 H30 0.9300 . ?
C30 C31 1.369(4) . ?
C31 H31 0.9300 . ?
C31 C32 1.366(5) . ?
C32 H32 0.9300 . ?
C32 C33 1.374(4) . ?
C33 H33 0.9300 . ?
C34 C35 1.385(3) . ?
C34 C39 1.383(4) . ?
C35 H35 0.9300 . ?
C35 C36 1.380(4) . ?
C36 H36 0.9300 . ?
C36 C37 1.375(4) . ?
C37 H37 0.9300 . ?
C37 C38 1.379(4) . ?
C38 H38 0.9300 . ?
C38 C39 1.380(4) . ?
C39 H39 0.9300 . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C40 C41 1.515(3) . ?
C41 C42 1.475(4) . ?
C42 H42A 0.9600 . ?
C42 H42B 0.9600 . ?
C42 H42C 0.9600 . ?
P1 C1 1.787(3) . ?
P1 C7 1.792(3) . ?
P1 C13 1.802(2) . ?
P1 C19 1.800(3) . ?
O1 C20 1.204(4) . ?
C1 C2 1.386(4) . ?
C1 C6 1.393(4) . ?
C2 H2 0.9300 . ?
C2 C3 1.371(4) . ?
C3 H3 0.9300 . ?
C3 C4 1.381(5) . ?
C4 H4 0.9300 . ?
C4 C5 1.365(5) . ?
C5 H5 0.9300 . ?
C5 C6 1.379(4) . ?
C6 H6 0.9300 . ?
C7 C8 1.396(4) . ?
C7 C12 1.387(4) . ?
C8 H8 0.9300 . ?
C8 C9 1.375(4) . ?
C9 H9 0.9300 . ?
C9 C10 1.369(5) . ?
C10 H10 0.9300 . ?
C10 C11 1.364(4) . ?
C11 H11 0.9300 . ?
C11 C12 1.380(4) . ?
C12 H12 0.9300 . ?
C13 C14 1.382(4) . ?
C13 C18 1.377(4) . ?
C14 H14 0.9300 . ?
C14 C15 1.377(4) . ?
C15 H15 0.9300 . ?
C15 C16 1.358(5) . ?
C16 H16 0.9300 . ?
C16 C17 1.355(5) . ?
C17 H17 0.9300 . ?
C17 C18 1.382(4) . ?
C18 H18 0.9300 . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 C20 1.505(4) . ?
C20 C21 1.489(5) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1 Sb1 Cl4 173.54(3) . . ?
Cl1 Sb1 Cl5 91.64(3) . . ?
Cl2 Sb1 Cl1 88.13(3) . . ?
Cl2 Sb1 Cl3 92.10(4) . . ?
Cl2 Sb1 Cl4 86.10(3) . . ?
Cl2 Sb1 Cl5 89.70(4) . . ?
Cl3 Sb1 Cl1 89.63(4) . . ?
Cl3 Sb1 Cl4 93.49(3) . . ?
Cl3 Sb1 Cl5 177.84(4) . . ?
Cl5 Sb1 Cl4 85.42(3) . . ?
C22 P2 C34 107.41(11) . . ?
C28 P2 C22 108.42(12) . . ?
C28 P2 C34 111.53(11) . . ?
C28 P2 C40 111.27(12) . . ?
C40 P2 C22 107.59(12) . . ?
C40 P2 C34 110.44(12) . . ?
C23 C22 P2 120.6(2) . . ?
C23 C22 C27 119.4(2) . . ?
C27 C22 P2 119.91(19) . . ?
C22 C23 H23 119.9 . . ?
C24 C23 C22 120.1(3) . . ?
C24 C23 H23 119.9 . . ?
C23 C24 H24 119.9 . . ?
C25 C24 C23 120.2(3) . . ?
C25 C24 H24 119.9 . . ?
C24 C25 H25 120.1 . . ?
C26 C25 C24 119.9(3) . . ?
C26 C25 H25 120.1 . . ?
C25 C26 H26 119.6 . . ?
C25 C26 C27 120.8(3) . . ?
C27 C26 H26 119.6 . . ?
C22 C27 H27 120.2 . . ?
C26 C27 C22 119.5(3) . . ?
C26 C27 H27 120.2 . . ?
C29 C28 P2 119.23(19) . . ?
C29 C28 C33 119.0(3) . . ?
C33 C28 P2 121.8(2) . . ?
C28 C29 H29 119.7 . . ?
C30 C29 C28 120.6(3) . . ?
C30 C29 H29 119.7 . . ?
C29 C30 H30 120.0 . . ?
C31 C30 C29 120.0(3) . . ?
C31 C30 H30 120.0 . . ?
C30 C31 H31 120.2 . . ?
C32 C31 C30 119.5(3) . . ?
C32 C31 H31 120.2 . . ?
C31 C32 H32 119.3 . . ?
C31 C32 C33 121.4(3) . . ?
C33 C32 H32 119.3 . . ?
C28 C33 H33 120.3 . . ?
C32 C33 C28 119.4(3) . . ?
C32 C33 H33 120.3 . . ?
C35 C34 P2 120.88(19) . . ?
C39 C34 P2 119.31(19) . . ?
C39 C34 C35 119.7(2) . . ?
C34 C35 H35 120.0 . . ?
C36 C35 C34 120.0(3) . . ?
C36 C35 H35 120.0 . . ?
C35 C36 H36 120.0 . . ?
C37 C36 C35 119.9(3) . . ?
C37 C36 H36 120.0 . . ?
C36 C37 H37 119.8 . . ?
C36 C37 C38 120.5(3) . . ?
C38 C37 H37 119.8 . . ?
C37 C38 H38 120.1 . . ?
C37 C38 C39 119.7(3) . . ?
C39 C38 H38 120.1 . . ?
C34 C39 H39 119.9 . . ?
C38 C39 C34 120.2(2) . . ?
C38 C39 H39 119.9 . . ?
P2 C40 H40A 108.5 . . ?
P2 C40 H40B 108.5 . . ?
H40A C40 H40B 107.5 . . ?
C41 C40 P2 114.96(18) . . ?
C41 C40 H40A 108.5 . . ?
C41 C40 H40B 108.5 . . ?
O2 C41 C40 120.9(2) . . ?
O2 C41 C42 123.5(3) . . ?
C42 C41 C40 115.6(2) . . ?
C41 C42 H42A 109.5 . . ?
C41 C42 H42B 109.5 . . ?
C41 C42 H42C 109.5 . . ?
H42A C42 H42B 109.5 . . ?
H42A C42 H42C 109.5 . . ?
H42B C42 H42C 109.5 . . ?
C1 P1 C7 111.31(12) . . ?
C1 P1 C13 105.39(12) . . ?
C1 P1 C19 111.01(13) . . ?
C7 P1 C13 110.74(12) . . ?
C7 P1 C19 111.75(12) . . ?
C19 P1 C13 106.33(12) . . ?
C2 C1 P1 118.3(2) . . ?
C2 C1 C6 119.6(3) . . ?
C6 C1 P1 121.5(2) . . ?
C1 C2 H2 120.0 . . ?
C3 C2 C1 120.0(3) . . ?
C3 C2 H2 120.0 . . ?
C2 C3 H3 119.9 . . ?
C2 C3 C4 120.1(3) . . ?
C4 C3 H3 119.9 . . ?
C3 C4 H4 119.8 . . ?
C5 C4 C3 120.4(3) . . ?
C5 C4 H4 119.8 . . ?
C4 C5 H5 119.9 . . ?
C4 C5 C6 120.3(3) . . ?
C6 C5 H5 119.9 . . ?
C1 C6 H6 120.2 . . ?
C5 C6 C1 119.6(3) . . ?
C5 C6 H6 120.2 . . ?
C8 C7 P1 121.0(2) . . ?
C12 C7 P1 120.1(2) . . ?
C12 C7 C8 118.9(2) . . ?
C7 C8 H8 120.1 . . ?
C9 C8 C7 119.7(3) . . ?
C9 C8 H8 120.1 . . ?
C8 C9 H9 119.7 . . ?
C10 C9 C8 120.6(3) . . ?
C10 C9 H9 119.7 . . ?
C9 C10 H10 119.8 . . ?
C11 C10 C9 120.3(3) . . ?
C11 C10 H10 119.8 . . ?
C10 C11 H11 119.9 . . ?
C10 C11 C12 120.1(3) . . ?
C12 C11 H11 119.9 . . ?
C7 C12 H12 119.9 . . ?
C11 C12 C7 120.3(3) . . ?
C11 C12 H12 119.9 . . ?
C14 C13 P1 121.5(2) . . ?
C18 C13 P1 119.2(2) . . ?
C18 C13 C14 119.1(3) . . ?
C13 C14 H14 120.0 . . ?
C15 C14 C13 119.9(3) . . ?
C15 C14 H14 120.0 . . ?
C14 C15 H15 119.8 . . ?
C16 C15 C14 120.5(3) . . ?
C16 C15 H15 119.8 . . ?
C15 C16 H16 119.9 . . ?
C17 C16 C15 120.1(3) . . ?
C17 C16 H16 119.9 . . ?
C16 C17 H17 119.7 . . ?
C16 C17 C18 120.5(3) . . ?
C18 C17 H17 119.7 . . ?
C13 C18 C17 119.8(3) . . ?
C13 C18 H18 120.1 . . ?
C17 C18 H18 120.1 . . ?
P1 C19 H19A 108.2 . . ?
P1 C19 H19B 108.2 . . ?
H19A C19 H19B 107.4 . . ?
C20 C19 P1 116.25(19) . . ?
C20 C19 H19A 108.2 . . ?
C20 C19 H19B 108.2 . . ?
O1 C20 C19 122.0(3) . . ?
O1 C20 C21 123.1(3) . . ?
C21 C20 C19 114.9(3) . . ?
C20 C21 H21A 109.5 . . ?
C20 C21 H21B 109.5 . . ?
C20 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 C22 C23 C24 178.7(3) . . . . ?
P2 C22 C27 C26 -179.0(2) . . . . ?
P2 C28 C29 C30 179.3(2) . . . . ?
P2 C28 C33 C32 179.8(3) . . . . ?
P2 C34 C35 C36 175.3(2) . . . . ?
P2 C34 C39 C38 -176.9(2) . . . . ?
P2 C40 C41 O2 -15.1(3) . . . . ?
P2 C40 C41 C42 166.1(2) . . . . ?
C22 P2 C28 C29 43.9(2) . . . . ?
C22 P2 C28 C33 -135.0(2) . . . . ?
C22 P2 C34 C35 -90.2(2) . . . . ?
C22 P2 C34 C39 85.6(2) . . . . ?
C22 P2 C40 C41 -164.60(19) . . . . ?
C22 C23 C24 C25 0.6(6) . . . . ?
C23 C22 C27 C26 0.1(4) . . . . ?
C23 C24 C25 C26 -0.4(6) . . . . ?
C24 C25 C26 C27 0.0(6) . . . . ?
C25 C26 C27 C22 0.1(5) . . . . ?
C27 C22 C23 C24 -0.4(5) . . . . ?
C28 P2 C22 C23 -90.0(3) . . . . ?
C28 P2 C22 C27 89.2(2) . . . . ?
C28 P2 C34 C35 28.4(2) . . . . ?
C28 P2 C34 C39 -155.7(2) . . . . ?
C28 P2 C40 C41 76.8(2) . . . . ?
C28 C29 C30 C31 1.4(4) . . . . ?
C29 C28 C33 C32 1.0(5) . . . . ?
C29 C30 C31 C32 -0.2(5) . . . . ?
C30 C31 C32 C33 -0.6(5) . . . . ?
C31 C32 C33 C28 0.2(5) . . . . ?
C33 C28 C29 C30 -1.8(4) . . . . ?
C34 P2 C22 C23 30.7(3) . . . . ?
C34 P2 C22 C27 -150.2(2) . . . . ?
C34 P2 C28 C29 -74.2(2) . . . . ?
C34 P2 C28 C33 107.0(2) . . . . ?
C34 P2 C40 C41 -47.7(2) . . . . ?
C34 C35 C36 C37 1.4(4) . . . . ?
C35 C34 C39 C38 -1.0(4) . . . . ?
C35 C36 C37 C38 -0.7(4) . . . . ?
C36 C37 C38 C39 -0.8(4) . . . . ?
C37 C38 C39 C34 1.7(4) . . . . ?
C39 C34 C35 C36 -0.5(4) . . . . ?
C40 P2 C22 C23 149.6(3) . . . . ?
C40 P2 C22 C27 -31.3(3) . . . . ?
C40 P2 C28 C29 162.0(2) . . . . ?
C40 P2 C28 C33 -16.8(3) . . . . ?
C40 P2 C34 C35 152.7(2) . . . . ?
C40 P2 C34 C39 -31.5(2) . . . . ?
P1 C1 C2 C3 -170.9(2) . . . . ?
P1 C1 C6 C5 170.3(2) . . . . ?
P1 C7 C8 C9 179.2(2) . . . . ?
P1 C7 C12 C11 -178.7(2) . . . . ?
P1 C13 C14 C15 175.2(3) . . . . ?
P1 C13 C18 C17 -174.0(3) . . . . ?
P1 C19 C20 O1 -13.9(4) . . . . ?
P1 C19 C20 C21 166.7(3) . . . . ?
C1 P1 C7 C8 44.1(3) . . . . ?
C1 P1 C7 C12 -137.6(2) . . . . ?
C1 P1 C13 C14 -141.4(2) . . . . ?
C1 P1 C13 C18 33.3(3) . . . . ?
C1 P1 C19 C20 -52.2(2) . . . . ?
C1 C2 C3 C4 0.4(5) . . . . ?
C2 C1 C6 C5 -0.7(4) . . . . ?
C2 C3 C4 C5 -0.8(5) . . . . ?
C3 C4 C5 C6 0.4(5) . . . . ?
C4 C5 C6 C1 0.4(5) . . . . ?
C6 C1 C2 C3 0.3(4) . . . . ?
C7 P1 C1 C2 -163.4(2) . . . . ?
C7 P1 C1 C6 25.5(3) . . . . ?
C7 P1 C13 C14 98.1(2) . . . . ?
C7 P1 C13 C18 -87.2(3) . . . . ?
C7 P1 C19 C20 72.8(2) . . . . ?
C7 C8 C9 C10 -0.4(5) . . . . ?
C8 C7 C12 C11 -0.4(4) . . . . ?
C8 C9 C10 C11 -0.7(5) . . . . ?
C9 C10 C11 C12 1.3(5) . . . . ?
C10 C11 C12 C7 -0.7(5) . . . . ?
C12 C7 C8 C9 0.9(4) . . . . ?
C13 P1 C1 C2 76.5(2) . . . . ?
C13 P1 C1 C6 -94.6(2) . . . . ?
C13 P1 C7 C8 161.0(2) . . . . ?
C13 P1 C7 C12 -20.7(3) . . . . ?
C13 P1 C19 C20 -166.3(2) . . . . ?
C13 C14 C15 C16 -1.3(5) . . . . ?
C14 C13 C18 C17 0.8(5) . . . . ?
C14 C15 C16 C17 0.7(6) . . . . ?
C15 C16 C17 C18 0.7(6) . . . . ?
C16 C17 C18 C13 -1.4(6) . . . . ?
C18 C13 C14 C15 0.5(5) . . . . ?
C19 P1 C1 C2 -38.3(3) . . . . ?
C19 P1 C1 C6 150.7(2) . . . . ?
C19 P1 C7 C8 -80.6(2) . . . . ?
C19 P1 C7 C12 97.6(2) . . . . ?
C19 P1 C13 C14 -23.4(3) . . . . ?
C19 P1 C13 C18 151.2(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
