# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_2HF
_database_code_depnum_ccdc_archive 'CCDC 2494566'
loop_
_audit_author_name
_audit_author_address
'Marcus Drover'
;Western University
Canada
;
_audit_update_record             
;
2025-10-10 deposited with the CCDC.	2026-02-03 downloaded from the CCDC.
;
_audit_creation_date             2024-11-27
_audit_creation_method           
;
Olex2 1.5
(compiled 2024.01.12 svn.r2f8d729c for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C29 H23.4 B F8.6 Rh'
_chemical_formula_sum            'C29 H23.40 B F8.60 Rh'
_chemical_formula_weight         649.00
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   8.2646(9)
_cell_length_b                   9.3254(11)
_cell_length_c                   17.716(2)
_cell_angle_alpha                88.548(5)
_cell_angle_beta                 77.438(6)
_cell_angle_gamma                69.538(4)
_cell_volume                     1246.7(2)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    9723
_cell_measurement_temperature    110.00
_cell_measurement_theta_max      35.49
_cell_measurement_theta_min      2.93
_shelx_estimated_absorpt_T_max   0.945
_shelx_estimated_absorpt_T_min   0.832
_exptl_absorpt_coefficient_mu    0.768
_exptl_absorpt_correction_T_max  0.944
_exptl_absorpt_correction_T_min  0.888
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
 TWINABS-2012/1 (Bruker,2012) was used for absorption correction.

Final HKLF 4 output contains 144040 reflections, Rint = 0.1090
 (58922 with I > 3sig(I), Rint = 0.0841)
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            orange
_exptl_crystal_colour_primary    orange
_exptl_crystal_density_diffrn    1.729
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             650
_exptl_crystal_size_max          0.249
_exptl_crystal_size_mid          0.128
_exptl_crystal_size_min          0.075
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0383
_diffrn_reflns_av_unetI/netI     0.0580
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.977
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            11526
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.977
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         35.965
_diffrn_reflns_theta_min         3.165
_diffrn_ambient_temperature      110.00
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           30.0
_diffrn_source_power             1.5
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                9588
_reflns_number_total             11526
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.176
_refine_diff_density_min         -0.558
_refine_diff_density_rms         0.108
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.957
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         11526
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0446
_refine_ls_R_factor_gt           0.0333
_refine_ls_restrained_S_all      0.957
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0293P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0652
_refine_ls_wR_factor_ref         0.0678
_refine_special_details          ?
_olex2_refinement_description    
;
1. Restrained distances
 F6-C5 \\sim H5-C5
 with sigma of 0.02
2. Others
 Fixed Sof: F6(0.6) H5(0.4)
3.a Ternary CH refined with riding coordinates:
 C15(H15), C17(H17)
3.b Secondary CH2 refined with riding coordinates:
 C19(H19A,H19B), C18(H18A,H18B), C16(H16A,H16B)
3.c Idealised Me refined as rotating group:
 C28(H28A,H28B,H28C), C29(H29A,H29B,H29C), C27(H27A,H27B,H27C), C25(H25A,H25B,
 H25C), C26(H26A,H26B,H26C)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.24070(2) 0.78870(2) 0.22040(2) 0.01080(3) Uani 1 1 d . . . . .
F2 F 0.08863(13) 0.52578(11) 0.54930(5) 0.02203(18) Uani 1 1 d . . . . .
F1 F 0.09198(12) 0.71400(10) 0.43396(5) 0.01953(17) Uani 1 1 d . . . . .
F3 F 0.37455(14) 0.26956(11) 0.55079(5) 0.02284(19) Uani 1 1 d . . . . .
F4 F 0.67560(14) 0.21459(11) 0.43787(6) 0.0250(2) Uani 1 1 d . . . . .
F5 F 0.69233(13) 0.41361(11) 0.32915(6) 0.0253(2) Uani 1 1 d . . . . .
F8 F 0.80528(16) 0.76584(13) 0.01707(6) 0.0348(3) Uani 1 1 d . . . . .
F7 F 0.86051(16) 0.47886(13) 0.06135(6) 0.0363(3) Uani 1 1 d . . . . .
F9 F 0.54937(15) 1.00962(11) 0.10600(6) 0.0278(2) Uani 1 1 d . . . . .
C12 C 0.3799(2) 0.36534(16) 0.49363(8) 0.0162(2) Uani 1 1 d . . . . .
C11 C 0.2338(2) 0.49464(16) 0.49201(7) 0.0156(2) Uani 1 1 d . . . . .
C14 C 0.53555(19) 0.44231(15) 0.37910(8) 0.0146(2) Uani 1 1 d . . . . .
F6 F 0.6628(3) 0.41959(17) 0.19088(11) 0.0242(4) Uani 0.6 1 d D . P A 1
C13 C 0.5322(2) 0.33840(15) 0.43661(8) 0.0161(2) Uani 1 1 d . . . . .
C19 C 0.3473(2) 1.16151(16) 0.33479(9) 0.0196(3) Uani 1 1 d . . . . .
H19A H 0.305611 1.271547 0.345289 0.023 Uiso 1 1 calc R U . . .
H19B H 0.475062 1.123760 0.316563 0.023 Uiso 1 1 calc R U . . .
C10 C 0.24062(19) 0.59259(15) 0.43224(7) 0.0140(2) Uani 1 1 d . . . . .
C18 C 0.2907(2) 1.07959(17) 0.40813(9) 0.0207(3) Uani 1 1 d . . . . .
H18A H 0.226750 1.152676 0.451865 0.025 Uiso 1 1 calc R U . . .
H18B H 0.392959 1.003132 0.421856 0.025 Uiso 1 1 calc R U . . .
C16 C 0.0808(2) 1.12494(16) 0.32925(9) 0.0181(3) Uani 1 1 d . . . . .
H16A H 0.006790 1.092827 0.302928 0.022 Uiso 1 1 calc R U . . .
H16B H 0.014223 1.224607 0.355874 0.022 Uiso 1 1 calc R U . . .
C15 C 0.25657(19) 1.11967(15) 0.27485(8) 0.0160(2) Uani 1 1 d . . . . .
H15 H 0.246998 1.182301 0.229642 0.019 Uiso 1 1 calc R U . . .
C2 C 0.34642(18) 0.94868(14) 0.25870(7) 0.0130(2) Uani 1 1 d . . . . .
C9 C 0.39173(18) 0.57231(15) 0.37356(7) 0.0126(2) Uani 1 1 d . . . . .
C17 C 0.1686(2) 1.00338(15) 0.38326(8) 0.0163(2) Uani 1 1 d . . . . .
H17 H 0.087611 0.976297 0.425395 0.020 Uiso 1 1 calc R U . . .
C6 C 0.7379(2) 0.59394(18) 0.10954(9) 0.0229(3) Uani 1 1 d . . . . .
C5 C 0.6450(2) 0.56516(16) 0.17771(9) 0.0190(3) Uani 1 1 d D . . . .
C7 C 0.7084(2) 0.74583(19) 0.08510(9) 0.0229(3) Uani 1 1 d . . . . .
C8 C 0.5821(2) 0.86621(17) 0.12962(8) 0.0186(3) Uani 1 1 d . . . . .
C20 C -0.0374(2) 0.81928(17) 0.23268(9) 0.0174(2) Uani 1 1 d . . . . .
C23 C 0.1841(2) 0.63869(17) 0.14514(8) 0.0183(3) Uani 1 1 d . . . . .
C24 C 0.06440(19) 0.65928(16) 0.21872(8) 0.0146(2) Uani 1 1 d . . . . .
C1 C 0.29479(18) 0.87279(15) 0.32587(7) 0.0126(2) Uani 1 1 d . . . . .
C3 C 0.48558(18) 0.84170(15) 0.20270(7) 0.0135(2) Uani 1 1 d . . . . .
C4 C 0.52112(18) 0.68701(15) 0.23055(7) 0.0133(2) Uani 1 1 d . . . . .
C28 C 0.3127(3) 0.4888(2) 0.10632(11) 0.0301(4) Uani 1 1 d . . . . .
H28A H 0.413603 0.504934 0.073947 0.045 Uiso 1 1 calc R U . . .
H28B H 0.256400 0.447005 0.075226 0.045 Uiso 1 1 calc R U . . .
H28C H 0.350578 0.418583 0.144915 0.045 Uiso 1 1 calc R U . . .
C22 C 0.1514(2) 0.7872(2) 0.11211(8) 0.0232(3) Uani 1 1 d . . . . .
C29 C 0.0401(2) 0.53512(18) 0.26990(9) 0.0225(3) Uani 1 1 d . . . . .
H29A H 0.153231 0.457026 0.268732 0.034 Uiso 1 1 calc R U . . .
H29B H -0.034849 0.491357 0.251848 0.034 Uiso 1 1 calc R U . . .
H29C H -0.013805 0.577219 0.321995 0.034 Uiso 1 1 calc R U . . .
C21 C 0.0137(2) 0.89803(18) 0.16545(9) 0.0220(3) Uani 1 1 d . . . . .
C27 C 0.2460(4) 0.8134(3) 0.03347(10) 0.0424(6) Uani 1 1 d . . . . .
H27A H 0.226702 0.920664 0.029384 0.064 Uiso 1 1 calc R U . . .
H27B H 0.201195 0.779355 -0.005603 0.064 Uiso 1 1 calc R U . . .
H27C H 0.370600 0.756820 0.026343 0.064 Uiso 1 1 calc R U . . .
C25 C -0.1840(2) 0.8868(2) 0.30265(11) 0.0277(3) Uani 1 1 d . . . . .
H25A H -0.144316 0.846751 0.348498 0.041 Uiso 1 1 calc R U . . .
H25B H -0.284642 0.860500 0.299139 0.041 Uiso 1 1 calc R U . . .
H25C H -0.216794 0.996285 0.305063 0.041 Uiso 1 1 calc R U . . .
C26 C -0.0725(3) 1.0649(2) 0.15276(13) 0.0386(5) Uani 1 1 d . . . . .
H26A H -0.117326 1.122172 0.201757 0.058 Uiso 1 1 calc R U . . .
H26B H -0.168300 1.077835 0.127738 0.058 Uiso 1 1 calc R U . . .
H26C H 0.013162 1.101190 0.120675 0.058 Uiso 1 1 calc R U . . .
B1 B 0.3992(2) 0.70027(16) 0.31341(8) 0.0125(2) Uani 1 1 d . . . . .
H5 H 0.708(14) 0.422(5) 0.196(7) 0.09(4) Uiso 0.4 1 d D . P B 2


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C2 2.1610(13) . ?
Rh1 C20 2.1769(15) . ?
Rh1 C23 2.1857(14) . ?
Rh1 C24 2.1979(13) . ?
Rh1 C1 2.2336(13) . ?
Rh1 C3 2.2032(13) . ?
Rh1 C4 2.2223(14) . ?
Rh1 C22 2.2024(15) . ?
Rh1 C21 2.2165(16) . ?
Rh1 B1 2.2862(15) . ?
F2 C11 1.3403(16) . ?
F1 C10 1.3434(17) . ?
F3 C12 1.3369(15) . ?
F4 C13 1.3385(17) . ?
F5 C14 1.3433(16) . ?
F8 C7 1.3422(17) . ?
F7 C6 1.3481(18) . ?
F9 C8 1.3434(17) . ?
C12 C11 1.381(2) . ?
C12 C13 1.381(2) . ?
C11 C10 1.3855(18) . ?
C14 C13 1.3907(18) . ?
C14 C9 1.389(2) . ?
F6 C5 1.334(2) . ?
C19 H19A 0.9700 . ?
C19 H19B 0.9700 . ?
C19 C18 1.557(2) . ?
C19 C15 1.554(2) . ?
C10 C9 1.3987(19) . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C18 C17 1.558(2) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 C15 1.544(2) . ?
C16 C17 1.549(2) . ?
C15 H15 0.9800 . ?
C15 C2 1.5095(19) . ?
C2 C1 1.4306(18) . ?
C2 C3 1.4331(19) . ?
C9 B1 1.5880(18) . ?
C17 H17 0.9800 . ?
C17 C1 1.5225(19) . ?
C6 C5 1.358(2) . ?
C6 C7 1.424(2) . ?
C5 C4 1.4280(19) . ?
C5 H5 1.32(2) . ?
C7 C8 1.356(2) . ?
C8 C3 1.4243(18) . ?
C20 C24 1.430(2) . ?
C20 C21 1.446(2) . ?
C20 C25 1.501(2) . ?
C23 C24 1.426(2) . ?
C23 C28 1.500(2) . ?
C23 C22 1.449(2) . ?
C24 C29 1.4945(18) . ?
C1 B1 1.532(2) . ?
C3 C4 1.4634(18) . ?
C4 B1 1.5696(19) . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C22 C21 1.420(3) . ?
C22 C27 1.502(2) . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C21 C26 1.502(2) . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 Rh1 C20 127.01(5) . . ?
C2 Rh1 C23 161.11(5) . . ?
C2 Rh1 C24 160.06(5) . . ?
C2 Rh1 C1 37.95(5) . . ?
C2 Rh1 C3 38.33(5) . . ?
C2 Rh1 C4 65.16(5) . . ?
C2 Rh1 C22 127.59(5) . . ?
C2 Rh1 C21 113.71(5) . . ?
C2 Rh1 B1 65.88(5) . . ?
C20 Rh1 C23 63.92(6) . . ?
C20 Rh1 C24 38.16(5) . . ?
C20 Rh1 C1 112.72(5) . . ?
C20 Rh1 C3 160.51(5) . . ?
C20 Rh1 C4 160.11(5) . . ?
C20 Rh1 C22 63.71(6) . . ?
C20 Rh1 C21 38.41(6) . . ?
C20 Rh1 B1 124.93(5) . . ?
C23 Rh1 C24 37.96(5) . . ?
C23 Rh1 C1 158.98(5) . . ?
C23 Rh1 C3 126.32(5) . . ?
C23 Rh1 C4 109.74(6) . . ?
C23 Rh1 C22 38.56(6) . . ?
C23 Rh1 C21 63.74(6) . . ?
C23 Rh1 B1 123.26(5) . . ?
C24 Rh1 C1 126.13(5) . . ?
C24 Rh1 C3 159.86(5) . . ?
C24 Rh1 C4 125.11(5) . . ?
C24 Rh1 C22 63.76(5) . . ?
C24 Rh1 C21 63.76(5) . . ?
C24 Rh1 B1 109.49(5) . . ?
C1 Rh1 B1 39.60(5) . . ?
C3 Rh1 C1 64.12(5) . . ?
C3 Rh1 C4 38.62(5) . . ?
C3 Rh1 C21 126.59(5) . . ?
C3 Rh1 B1 66.19(5) . . ?
C4 Rh1 C1 65.82(5) . . ?
C4 Rh1 B1 40.72(5) . . ?
C22 Rh1 C1 161.16(6) . . ?
C22 Rh1 C3 112.48(5) . . ?
C22 Rh1 C4 124.32(6) . . ?
C22 Rh1 C21 37.48(7) . . ?
C22 Rh1 B1 158.43(6) . . ?
C21 Rh1 C1 127.90(6) . . ?
C21 Rh1 C4 158.32(6) . . ?
C21 Rh1 B1 160.67(6) . . ?
F3 C12 C11 120.20(13) . . ?
F3 C12 C13 120.60(13) . . ?
C13 C12 C11 119.18(12) . . ?
F2 C11 C12 119.55(12) . . ?
F2 C11 C10 120.76(13) . . ?
C12 C11 C10 119.67(13) . . ?
F5 C14 C13 115.60(13) . . ?
F5 C14 C9 120.34(11) . . ?
C9 C14 C13 123.99(13) . . ?
F4 C13 C12 119.94(12) . . ?
F4 C13 C14 120.70(13) . . ?
C12 C13 C14 119.35(13) . . ?
H19A C19 H19B 109.0 . . ?
C18 C19 H19A 111.1 . . ?
C18 C19 H19B 111.1 . . ?
C15 C19 H19A 111.1 . . ?
C15 C19 H19B 111.1 . . ?
C15 C19 C18 103.46(11) . . ?
F1 C10 C11 116.02(12) . . ?
F1 C10 C9 120.31(11) . . ?
C11 C10 C9 123.65(13) . . ?
C19 C18 H18A 111.0 . . ?
C19 C18 H18B 111.0 . . ?
C19 C18 C17 103.65(12) . . ?
H18A C18 H18B 109.0 . . ?
C17 C18 H18A 111.0 . . ?
C17 C18 H18B 111.0 . . ?
H16A C16 H16B 110.2 . . ?
C15 C16 H16A 112.7 . . ?
C15 C16 H16B 112.7 . . ?
C15 C16 C17 95.38(11) . . ?
C17 C16 H16A 112.7 . . ?
C17 C16 H16B 112.7 . . ?
C19 C15 H15 116.6 . . ?
C16 C15 C19 99.57(12) . . ?
C16 C15 H15 116.6 . . ?
C2 C15 C19 104.99(12) . . ?
C2 C15 C16 99.97(10) . . ?
C2 C15 H15 116.6 . . ?
C15 C2 Rh1 127.97(10) . . ?
C1 C2 Rh1 73.78(7) . . ?
C1 C2 C15 108.94(11) . . ?
C1 C2 C3 110.67(11) . . ?
C3 C2 Rh1 72.43(7) . . ?
C3 C2 C15 139.46(12) . . ?
C14 C9 C10 114.09(11) . . ?
C14 C9 B1 124.41(12) . . ?
C10 C9 B1 121.08(12) . . ?
C18 C17 H17 116.1 . . ?
C16 C17 C18 99.84(11) . . ?
C16 C17 H17 116.1 . . ?
C1 C17 C18 104.32(12) . . ?
C1 C17 C16 102.20(11) . . ?
C1 C17 H17 116.1 . . ?
F7 C6 C5 121.13(14) . . ?
F7 C6 C7 117.06(13) . . ?
C5 C6 C7 121.80(14) . . ?
F6 C5 C6 117.64(14) . . ?
F6 C5 C4 120.89(14) . . ?
C6 C5 C4 121.25(13) . . ?
C6 C5 H5 113(5) . . ?
C4 C5 H5 124(5) . . ?
F8 C7 C6 118.61(14) . . ?
F8 C7 C8 121.47(14) . . ?
C8 C7 C6 119.91(13) . . ?
F9 C8 C7 120.44(12) . . ?
F9 C8 C3 119.43(13) . . ?
C7 C8 C3 120.12(13) . . ?
C24 C20 Rh1 71.71(8) . . ?
C24 C20 C21 108.33(13) . . ?
C24 C20 C25 124.20(13) . . ?
C21 C20 Rh1 72.28(9) . . ?
C21 C20 C25 127.20(15) . . ?
C25 C20 Rh1 126.47(11) . . ?
C24 C23 Rh1 71.48(8) . . ?
C24 C23 C28 126.18(13) . . ?
C24 C23 C22 107.88(13) . . ?
C28 C23 Rh1 125.78(12) . . ?
C22 C23 Rh1 71.34(8) . . ?
C22 C23 C28 125.82(14) . . ?
C20 C24 Rh1 70.13(8) . . ?
C20 C24 C29 125.73(13) . . ?
C23 C24 Rh1 70.56(8) . . ?
C23 C24 C20 107.92(12) . . ?
C23 C24 C29 126.23(13) . . ?
C29 C24 Rh1 128.06(10) . . ?
C2 C1 Rh1 68.27(7) . . ?
C2 C1 C17 103.91(11) . . ?
C2 C1 B1 109.55(11) . . ?
C17 C1 Rh1 126.99(10) . . ?
C17 C1 B1 146.17(12) . . ?
B1 C1 Rh1 72.05(7) . . ?
C2 C3 Rh1 69.24(7) . . ?
C2 C3 C4 109.18(11) . . ?
C8 C3 Rh1 124.80(10) . . ?
C8 C3 C2 130.25(12) . . ?
C8 C3 C4 120.57(12) . . ?
C4 C3 Rh1 71.40(7) . . ?
C5 C4 Rh1 120.43(10) . . ?
C5 C4 C3 115.97(11) . . ?
C5 C4 B1 136.10(12) . . ?
C3 C4 Rh1 69.98(8) . . ?
C3 C4 B1 107.85(11) . . ?
B1 C4 Rh1 71.83(8) . . ?
C23 C28 H28A 109.5 . . ?
C23 C28 H28B 109.5 . . ?
C23 C28 H28C 109.5 . . ?
H28A C28 H28B 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C23 C22 Rh1 70.10(8) . . ?
C23 C22 C27 124.35(18) . . ?
C21 C22 Rh1 71.80(9) . . ?
C21 C22 C23 108.26(12) . . ?
C21 C22 C27 127.37(17) . . ?
C27 C22 Rh1 125.31(13) . . ?
C24 C29 H29A 109.5 . . ?
C24 C29 H29B 109.5 . . ?
C24 C29 H29C 109.5 . . ?
H29A C29 H29B 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C20 C21 Rh1 69.31(8) . . ?
C20 C21 C26 125.77(17) . . ?
C22 C21 Rh1 70.72(9) . . ?
C22 C21 C20 107.54(13) . . ?
C22 C21 C26 126.57(16) . . ?
C26 C21 Rh1 128.35(12) . . ?
C22 C27 H27A 109.5 . . ?
C22 C27 H27B 109.5 . . ?
C22 C27 H27C 109.5 . . ?
H27A C27 H27B 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C20 C25 H25A 109.5 . . ?
C20 C25 H25B 109.5 . . ?
C20 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C21 C26 H26A 109.5 . . ?
C21 C26 H26B 109.5 . . ?
C21 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C9 B1 Rh1 130.12(10) . . ?
C1 B1 Rh1 68.35(7) . . ?
C1 B1 C9 127.24(12) . . ?
C1 B1 C4 102.62(10) . . ?
C4 B1 Rh1 67.46(7) . . ?
C4 B1 C9 130.00(12) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Rh1 C2 C1 C17 -124.65(10) . . . . ?
Rh1 C2 C1 B1 60.42(10) . . . . ?
Rh1 C2 C3 C8 118.61(16) . . . . ?
Rh1 C2 C3 C4 -60.46(10) . . . . ?
Rh1 C20 C24 C23 -60.73(10) . . . . ?
Rh1 C20 C24 C29 123.20(15) . . . . ?
Rh1 C20 C21 C22 60.69(11) . . . . ?
Rh1 C20 C21 C26 -123.06(16) . . . . ?
Rh1 C23 C24 C20 60.46(10) . . . . ?
Rh1 C23 C24 C29 -123.49(15) . . . . ?
Rh1 C23 C22 C21 -62.02(11) . . . . ?
Rh1 C23 C22 C27 119.81(17) . . . . ?
Rh1 C1 B1 C9 -124.69(14) . . . . ?
Rh1 C1 B1 C4 59.23(9) . . . . ?
Rh1 C3 C4 C5 114.98(13) . . . . ?
Rh1 C3 C4 B1 -62.22(9) . . . . ?
Rh1 C4 B1 C9 124.22(15) . . . . ?
Rh1 C4 B1 C1 -59.85(9) . . . . ?
Rh1 C22 C21 C20 -59.80(10) . . . . ?
Rh1 C22 C21 C26 123.99(17) . . . . ?
F2 C11 C10 F1 -2.95(19) . . . . ?
F2 C11 C10 C9 175.61(12) . . . . ?
F1 C10 C9 C14 179.84(12) . . . . ?
F1 C10 C9 B1 6.94(19) . . . . ?
F3 C12 C11 F2 1.9(2) . . . . ?
F3 C12 C11 C10 -179.64(12) . . . . ?
F3 C12 C13 F4 0.7(2) . . . . ?
F3 C12 C13 C14 -178.17(12) . . . . ?
F5 C14 C13 F4 -3.5(2) . . . . ?
F5 C14 C13 C12 175.39(13) . . . . ?
F5 C14 C9 C10 -176.11(12) . . . . ?
F5 C14 C9 B1 -3.5(2) . . . . ?
F8 C7 C8 F9 0.8(3) . . . . ?
F8 C7 C8 C3 -177.92(15) . . . . ?
F7 C6 C5 F6 -8.3(3) . . . . ?
F7 C6 C5 C4 176.99(15) . . . . ?
F7 C6 C7 F8 -1.2(3) . . . . ?
F7 C6 C7 C8 177.53(16) . . . . ?
F9 C8 C3 Rh1 93.58(15) . . . . ?
F9 C8 C3 C2 2.3(2) . . . . ?
F9 C8 C3 C4 -178.75(13) . . . . ?
C12 C11 C10 F1 178.65(12) . . . . ?
C12 C11 C10 C9 -2.8(2) . . . . ?
C11 C12 C13 F4 179.20(13) . . . . ?
C11 C12 C13 C14 0.3(2) . . . . ?
C11 C10 C9 C14 1.3(2) . . . . ?
C11 C10 C9 B1 -171.55(13) . . . . ?
C14 C9 B1 Rh1 122.14(14) . . . . ?
C14 C9 B1 C1 -145.87(15) . . . . ?
C14 C9 B1 C4 29.1(2) . . . . ?
F6 C5 C4 Rh1 -86.4(2) . . . . ?
F6 C5 C4 C3 -167.47(18) . . . . ?
F6 C5 C4 B1 8.7(3) . . . . ?
C13 C12 C11 F2 -176.58(12) . . . . ?
C13 C12 C11 C10 1.8(2) . . . . ?
C13 C14 C9 C10 1.0(2) . . . . ?
C13 C14 C9 B1 173.61(13) . . . . ?
C19 C18 C17 C16 -34.18(13) . . . . ?
C19 C18 C17 C1 71.23(13) . . . . ?
C19 C15 C2 Rh1 153.73(10) . . . . ?
C19 C15 C2 C1 69.87(14) . . . . ?
C19 C15 C2 C3 -97.4(2) . . . . ?
C10 C9 B1 Rh1 -65.72(17) . . . . ?
C10 C9 B1 C1 26.3(2) . . . . ?
C10 C9 B1 C4 -158.73(14) . . . . ?
C18 C19 C15 C16 37.02(13) . . . . ?
C18 C19 C15 C2 -66.09(14) . . . . ?
C18 C17 C1 Rh1 -144.64(10) . . . . ?
C18 C17 C1 C2 -71.56(13) . . . . ?
C18 C17 C1 B1 99.8(2) . . . . ?
C16 C15 C2 Rh1 50.91(14) . . . . ?
C16 C15 C2 C1 -32.95(14) . . . . ?
C16 C15 C2 C3 159.78(18) . . . . ?
C16 C17 C1 Rh1 -41.01(14) . . . . ?
C16 C17 C1 C2 32.08(14) . . . . ?
C16 C17 C1 B1 -156.5(2) . . . . ?
C15 C19 C18 C17 -1.66(15) . . . . ?
C15 C16 C17 C18 56.64(12) . . . . ?
C15 C16 C17 C1 -50.47(12) . . . . ?
C15 C2 C1 Rh1 125.28(11) . . . . ?
C15 C2 C1 C17 0.64(15) . . . . ?
C15 C2 C1 B1 -174.29(12) . . . . ?
C15 C2 C3 Rh1 -128.51(19) . . . . ?
C15 C2 C3 C8 -9.9(3) . . . . ?
C15 C2 C3 C4 171.02(16) . . . . ?
C2 C1 B1 Rh1 -58.13(10) . . . . ?
C2 C1 B1 C9 177.18(13) . . . . ?
C2 C1 B1 C4 1.10(15) . . . . ?
C2 C3 C4 Rh1 59.14(10) . . . . ?
C2 C3 C4 C5 174.12(13) . . . . ?
C2 C3 C4 B1 -3.08(16) . . . . ?
C9 C14 C13 F4 179.32(13) . . . . ?
C9 C14 C13 C12 -1.8(2) . . . . ?
C17 C16 C15 C19 -57.78(12) . . . . ?
C17 C16 C15 C2 49.44(12) . . . . ?
C17 C1 B1 Rh1 130.7(2) . . . . ?
C17 C1 B1 C9 6.0(3) . . . . ?
C17 C1 B1 C4 -170.04(19) . . . . ?
C6 C5 C4 Rh1 88.16(17) . . . . ?
C6 C5 C4 C3 7.1(2) . . . . ?
C6 C5 C4 B1 -176.74(16) . . . . ?
C6 C7 C8 F9 -177.93(15) . . . . ?
C6 C7 C8 C3 3.4(3) . . . . ?
C5 C6 C7 F8 179.88(16) . . . . ?
C5 C6 C7 C8 -1.4(3) . . . . ?
C5 C4 B1 Rh1 -115.32(18) . . . . ?
C5 C4 B1 C9 8.9(3) . . . . ?
C5 C4 B1 C1 -175.17(17) . . . . ?
C7 C6 C5 F6 170.60(19) . . . . ?
C7 C6 C5 C4 -4.1(3) . . . . ?
C7 C8 C3 Rh1 -87.72(18) . . . . ?
C7 C8 C3 C2 -179.04(16) . . . . ?
C7 C8 C3 C4 0.0(2) . . . . ?
C8 C3 C4 Rh1 -120.04(14) . . . . ?
C8 C3 C4 C5 -5.1(2) . . . . ?
C8 C3 C4 B1 177.74(13) . . . . ?
C23 C22 C21 Rh1 60.94(11) . . . . ?
C23 C22 C21 C20 1.14(18) . . . . ?
C23 C22 C21 C26 -175.07(16) . . . . ?
C24 C20 C21 Rh1 -63.07(10) . . . . ?
C24 C20 C21 C22 -2.37(17) . . . . ?
C24 C20 C21 C26 173.88(15) . . . . ?
C24 C23 C22 Rh1 62.53(10) . . . . ?
C24 C23 C22 C21 0.52(18) . . . . ?
C24 C23 C22 C27 -177.66(16) . . . . ?
C1 C2 C3 Rh1 64.36(10) . . . . ?
C1 C2 C3 C8 -177.02(15) . . . . ?
C1 C2 C3 C4 3.90(16) . . . . ?
C3 C2 C1 Rh1 -63.53(10) . . . . ?
C3 C2 C1 C17 171.83(12) . . . . ?
C3 C2 C1 B1 -3.10(16) . . . . ?
C3 C4 B1 Rh1 61.04(9) . . . . ?
C3 C4 B1 C9 -174.74(14) . . . . ?
C3 C4 B1 C1 1.19(15) . . . . ?
C28 C23 C24 Rh1 121.26(17) . . . . ?
C28 C23 C24 C20 -178.28(15) . . . . ?
C28 C23 C24 C29 -2.2(3) . . . . ?
C28 C23 C22 Rh1 -121.15(17) . . . . ?
C28 C23 C22 C21 176.83(16) . . . . ?
C28 C23 C22 C27 -1.3(3) . . . . ?
C22 C23 C24 Rh1 -62.45(10) . . . . ?
C22 C23 C24 C20 -1.98(17) . . . . ?
C22 C23 C24 C29 174.06(14) . . . . ?
C21 C20 C24 Rh1 63.43(10) . . . . ?
C21 C20 C24 C23 2.70(17) . . . . ?
C21 C20 C24 C29 -173.37(14) . . . . ?
C27 C22 C21 Rh1 -120.96(18) . . . . ?
C27 C22 C21 C20 179.24(16) . . . . ?
C27 C22 C21 C26 3.0(3) . . . . ?
C25 C20 C24 Rh1 -122.16(15) . . . . ?
C25 C20 C24 C23 177.11(14) . . . . ?
C25 C20 C24 C29 1.0(2) . . . . ?
C25 C20 C21 Rh1 122.74(16) . . . . ?
C25 C20 C21 C22 -176.57(15) . . . . ?
C25 C20 C21 C26 -0.3(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
# start Validation Reply Form
_vrf_PLAT770_2HF                 
;
PROBLEM: Suspect C-H Bond in CIF:  C5       --H5        .       1.32 Ang.  
RESPONSE: F6 and H5 are substitutionally disordered with occupencies of 
0.6 and 0.4, respectively. Both atoms were refined freely, leading to the
short C5-H5 bond. Attempts to model other atoms (besides H5) at this position
led to worse R1 values.  
;
