# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_CNU-404
_database_code_depnum_ccdc_archive 'CCDC 2519391'
loop_
_audit_author_name
_audit_author_address
'Kunlin Huang'
;Chongqing Normal University
China
;
_audit_update_record             
;
2025-12-28 deposited with the CCDC.	2026-02-27 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C64 H40 N4 O9 Zn'
_chemical_formula_weight         1074.39

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 2/c'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'

_cell_length_a                   15.1823(7)
_cell_length_b                   6.5451(3)
_cell_length_c                   25.8783(13)
_cell_angle_alpha                90.00
_cell_angle_beta                 99.655(2)
_cell_angle_gamma                90.00
_cell_volume                     2535.1(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    9903
_cell_measurement_theta_min      2.92
_cell_measurement_theta_max      27.48

_exptl_crystal_description       Block
_exptl_crystal_colour            Yellow
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.17
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.408
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1108
_exptl_absorpt_coefficient_mu    0.552
_exptl_absorpt_correction_type   ?
_exptl_absorpt_correction_T_min  ?
_exptl_absorpt_correction_T_max  ?
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            42083
_diffrn_reflns_av_R_equivalents  0.0484
_diffrn_reflns_av_sigmaI/netI    0.0260
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_theta_min         1.92
_diffrn_reflns_theta_max         25.00
_reflns_number_total             4469
_reflns_number_gt                4194
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker APEX2'
_computing_cell_refinement       'Bruker SAINT'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0644P)²+1.4501P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4469
_refine_ls_number_parameters     354
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0327
_refine_ls_R_factor_gt           0.0281
_refine_ls_wR_factor_ref         0.1025
_refine_ls_wR_factor_gt          0.0823
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_restrained_S_all      1.004
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.5000 1.13393(4) 0.7500 0.02620(11) Uani 1 2 d S . .
O3 O 0.71773(11) 1.0401(3) 0.66101(7) 0.0544(4) Uani 1 1 d . . .
O5 O 1.0000 1.6050(3) 0.7500 0.0454(6) Uani 1 2 d S . .
O2 O 0.67388(10) 1.0328(2) 0.77069(6) 0.0442(4) Uani 1 1 d . . .
N2 N 0.85331(15) 0.6206(3) 0.61582(8) 0.0456(5) Uani 1 1 d . . .
N1 N 0.50412(11) 0.9567(3) 0.68636(6) 0.0307(3) Uani 1 1 d . . .
O1 O 0.60074(10) 1.3242(2) 0.75322(7) 0.0454(4) Uani 1 1 d . . .
O4 O 0.85714(12) 0.9305(3) 0.68557(7) 0.0555(5) Uani 1 1 d . . .
H4 H 0.8402 0.8362 0.6655 0.083 Uiso 1 1 calc R . .
C1 C 0.93147(19) 0.6400(3) 0.59972(10) 0.0508(6) Uani 1 1 d . . .
H1 H 0.9641 0.7589 0.6085 0.061 Uiso 1 1 calc R . .
C2 C 0.96716(17) 0.4947(3) 0.57080(10) 0.0463(5) Uani 1 1 d . . .
H2 H 1.0216 0.5179 0.5598 0.056 Uiso 1 1 calc R . .
C3 C 0.92124(14) 0.3130(3) 0.55815(8) 0.0342(4) Uani 1 1 d . . .
C9 C 0.96042(14) 0.1507(3) 0.52841(8) 0.0322(4) Uani 1 1 d . . .
C8 C 0.91891(13) 0.0952(3) 0.47760(8) 0.0316(4) Uani 1 1 d . . .
C10 C 1.04128(13) 0.0564(3) 0.55130(7) 0.0318(4) Uani 1 1 d . . .
C4 C 0.83986(14) 0.2916(3) 0.57520(8) 0.0381(5) Uani 1 1 d . . .
H4A H 0.8066 0.1727 0.5679 0.046 Uiso 1 1 calc R . .
C5 C 0.80844(15) 0.4475(3) 0.60313(9) 0.0421(5) Uani 1 1 d . . .
H5 H 0.7532 0.4311 0.6136 0.050 Uiso 1 1 calc R . .
C11 C 1.08409(15) 0.1010(3) 0.60384(8) 0.0397(5) Uani 1 1 d . . .
H11 H 1.0589 0.1981 0.6232 0.048 Uiso 1 1 calc R . .
C12 C 1.16013(15) 0.0053(4) 0.62584(8) 0.0443(5) Uani 1 1 d . . .
H12 H 1.1866 0.0373 0.6599 0.053 Uiso 1 1 calc R . .
C6 C 0.80072(16) 0.1425(4) 0.40266(9) 0.0453(5) Uani 1 1 d . . .
H6 H 0.7482 0.2067 0.3873 0.054 Uiso 1 1 calc R . .
C7 C 0.83859(14) 0.1925(3) 0.45221(9) 0.0397(5) Uani 1 1 d . . .
H7 H 0.8120 0.2919 0.4701 0.048 Uiso 1 1 calc R . .
C25 C 0.67162(12) 1.2155(3) 0.75867(8) 0.0332(4) Uani 1 1 d . . .
C26 C 0.75627(12) 1.3213(3) 0.75222(8) 0.0320(4) Uani 1 1 d . . .
C31 C 0.77937(14) 1.5044(4) 0.77818(9) 0.0431(5) Uani 1 1 d . . .
H31 H 0.7384 1.5684 0.7958 0.052 Uiso 1 1 calc R . .
C30 C 0.86167(14) 1.5927(3) 0.77831(10) 0.0432(5) Uani 1 1 d . . .
H30 H 0.8765 1.7142 0.7963 0.052 Uiso 1 1 calc R . .
C29 C 0.92177(12) 1.4999(3) 0.75157(8) 0.0336(4) Uani 1 1 d . . .
C28 C 0.89991(13) 1.3204(3) 0.72433(8) 0.0326(4) Uani 1 1 d . . .
H28 H 0.9408 1.2590 0.7062 0.039 Uiso 1 1 calc R . .
C27 C 0.81684(12) 1.2317(3) 0.72403(7) 0.0295(4) Uani 1 1 d . . .
C32 C 0.79021(13) 1.0556(3) 0.68777(8) 0.0346(4) Uani 1 1 d . . .
C13 C 0.54580(14) 0.7775(3) 0.68821(8) 0.0375(5) Uani 1 1 d . . .
H13 H 0.5751 0.7300 0.7204 0.045 Uiso 1 1 calc R . .
C14 C 0.54726(15) 0.6593(3) 0.64429(8) 0.0385(5) Uani 1 1 d . . .
H14 H 0.5762 0.5336 0.6471 0.046 Uiso 1 1 calc R . .
C15 C 0.50528(13) 0.7295(3) 0.59604(7) 0.0331(4) Uani 1 1 d . . .
C16 C 0.46313(18) 0.9173(4) 0.59429(8) 0.0504(6) Uani 1 1 d . . .
H16 H 0.4349 0.9706 0.5625 0.060 Uiso 1 1 calc R . .
C17 C 0.46325(17) 1.0241(4) 0.63981(8) 0.0465(6) Uani 1 1 d . . .
H17 H 0.4336 1.1489 0.6382 0.056 Uiso 1 1 calc R . .
C21 C 0.50363(13) 0.6093(3) 0.54704(7) 0.0324(4) Uani 1 1 d . . .
C22 C 0.43155(13) 0.4777(3) 0.53042(7) 0.0318(4) Uani 1 1 d . . .
C23 C 0.36092(14) 0.4492(3) 0.55994(8) 0.0380(5) Uani 1 1 d . . .
H23 H 0.3626 0.5191 0.5914 0.046 Uiso 1 1 calc R . .
C24 C 0.29187(15) 0.3230(4) 0.54305(10) 0.0450(5) Uani 1 1 d . . .
H24 H 0.2466 0.3067 0.5629 0.054 Uiso 1 1 calc R . .
C18 C 0.71195(16) 0.7847(4) 0.50452(10) 0.0470(5) Uani 1 1 d . . .
H18 H 0.7602 0.8703 0.5159 0.056 Uiso 1 1 calc R . .
C20 C 0.57222(13) 0.6337(3) 0.51754(8) 0.0322(4) Uani 1 1 d . . .
C19 C 0.64696(15) 0.7655(3) 0.53368(8) 0.0403(5) Uani 1 1 d . . .
H19 H 0.6507 0.8388 0.5648 0.048 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 O1 1.9632(15) . ?
Zn1 O1 1.9632(15) 2_656 ?
Zn1 N1 2.0239(16) . ?
Zn1 N1 2.0239(16) 2_656 ?
O3 C32 1.202(3) . ?
O5 C29 1.379(2) . ?
O5 C29 1.379(2) 2_756 ?
O2 C25 1.234(3) . ?
N2 C1 1.328(3) . ?
N2 C5 1.334(3) . ?
N1 C13 1.330(3) . ?
N1 C17 1.334(3) . ?
O1 C25 1.278(3) . ?
O4 C32 1.314(3) . ?
O4 H4 0.8200 . ?
C1 C2 1.376(3) . ?
C1 H1 0.9300 . ?
C2 C3 1.389(3) . ?
C2 H2 0.9300 . ?
C3 C4 1.387(3) . ?
C3 C9 1.493(3) . ?
C9 C8 1.407(3) . ?
C9 C10 1.412(3) . ?
C8 C7 1.433(3) . ?
C8 C10 1.436(3) 3_756 ?
C10 C11 1.435(3) . ?
C10 C8 1.436(3) 3_756 ?
C4 C5 1.381(3) . ?
C4 H4A 0.9300 . ?
C5 H5 0.9300 . ?
C11 C12 1.352(3) . ?
C11 H11 0.9300 . ?
C12 C6 1.407(3) 3_756 ?
C12 H12 0.9300 . ?
C6 C7 1.354(3) . ?
C6 C12 1.407(3) 3_756 ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C25 C26 1.494(3) . ?
C26 C31 1.390(3) . ?
C26 C27 1.395(3) . ?
C31 C30 1.376(3) . ?
C31 H31 0.9300 . ?
C30 C29 1.375(3) . ?
C30 H30 0.9300 . ?
C29 C28 1.382(3) . ?
C28 C27 1.387(3) . ?
C28 H28 0.9300 . ?
C27 C32 1.498(3) . ?
C13 C14 1.378(3) . ?
C13 H13 0.9300 . ?
C14 C15 1.382(3) . ?
C14 H14 0.9300 . ?
C15 C16 1.383(3) . ?
C15 C21 1.489(3) . ?
C16 C17 1.370(3) . ?
C16 H16 0.9300 . ?
C17 H17 0.9300 . ?
C21 C20 1.400(3) . ?
C21 C22 1.403(3) . ?
C22 C23 1.429(3) . ?
C22 C20 1.432(3) 3_666 ?
C23 C24 1.349(3) . ?
C23 H23 0.9300 . ?
C24 C18 1.411(4) 3_666 ?
C24 H24 0.9300 . ?
C18 C19 1.345(3) . ?
C18 C24 1.411(4) 3_666 ?
C18 H18 0.9300 . ?
C20 C19 1.431(3) . ?
C20 C22 1.432(3) 3_666 ?
C19 H19 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Zn1 O1 101.26(9) . 2_656 ?
O1 Zn1 N1 105.54(7) . . ?
O1 Zn1 N1 117.34(7) 2_656 . ?
O1 Zn1 N1 117.34(7) . 2_656 ?
O1 Zn1 N1 105.54(7) 2_656 2_656 ?
N1 Zn1 N1 110.06(10) . 2_656 ?
C29 O5 C29 120.2(2) . 2_756 ?
C1 N2 C5 116.74(19) . . ?
C13 N1 C17 118.07(17) . . ?
C13 N1 Zn1 123.77(13) . . ?
C17 N1 Zn1 118.17(14) . . ?
C25 O1 Zn1 106.68(13) . . ?
C32 O4 H4 109.5 . . ?
N2 C1 C2 124.0(2) . . ?
N2 C1 H1 118.0 . . ?
C2 C1 H1 118.0 . . ?
C1 C2 C3 119.5(2) . . ?
C1 C2 H2 120.3 . . ?
C3 C2 H2 120.3 . . ?
C4 C3 C2 116.7(2) . . ?
C4 C3 C9 123.05(18) . . ?
C2 C3 C9 120.20(19) . . ?
C8 C9 C10 120.06(18) . . ?
C8 C9 C3 120.70(18) . . ?
C10 C9 C3 119.22(18) . . ?
C9 C8 C7 121.81(19) . . ?
C9 C8 C10 120.22(19) . 3_756 ?
C7 C8 C10 117.92(19) . 3_756 ?
C9 C10 C11 122.15(19) . . ?
C9 C10 C8 119.72(18) . 3_756 ?
C11 C10 C8 118.08(19) . 3_756 ?
C5 C4 C3 119.8(2) . . ?
C5 C4 H4A 120.1 . . ?
C3 C4 H4A 120.1 . . ?
N2 C5 C4 123.3(2) . . ?
N2 C5 H5 118.3 . . ?
C4 C5 H5 118.3 . . ?
C12 C11 C10 121.6(2) . . ?
C12 C11 H11 119.2 . . ?
C10 C11 H11 119.2 . . ?
C11 C12 C6 120.2(2) . 3_756 ?
C11 C12 H12 119.9 . . ?
C6 C12 H12 119.9 3_756 . ?
C7 C6 C12 120.8(2) . 3_756 ?
C7 C6 H6 119.6 . . ?
C12 C6 H6 119.6 3_756 . ?
C6 C7 C8 121.3(2) . . ?
C6 C7 H7 119.3 . . ?
C8 C7 H7 119.3 . . ?
O2 C25 O1 123.67(18) . . ?
O2 C25 C26 119.28(18) . . ?
O1 C25 C26 116.99(18) . . ?
C31 C26 C27 118.68(18) . . ?
C31 C26 C25 119.86(18) . . ?
C27 C26 C25 121.24(18) . . ?
C30 C31 C26 121.25(19) . . ?
C30 C31 H31 119.4 . . ?
C26 C31 H31 119.4 . . ?
C29 C30 C31 119.5(2) . . ?
C29 C30 H30 120.3 . . ?
C31 C30 H30 120.3 . . ?
C30 C29 O5 116.23(18) . . ?
C30 C29 C28 120.62(18) . . ?
O5 C29 C28 122.92(18) . . ?
C29 C28 C27 119.92(18) . . ?
C29 C28 H28 120.0 . . ?
C27 C28 H28 120.0 . . ?
C28 C27 C26 119.99(18) . . ?
C28 C27 C32 118.34(17) . . ?
C26 C27 C32 121.22(17) . . ?
O3 C32 O4 124.2(2) . . ?
O3 C32 C27 123.42(19) . . ?
O4 C32 C27 112.16(17) . . ?
N1 C13 C14 122.61(18) . . ?
N1 C13 H13 118.7 . . ?
C14 C13 H13 118.7 . . ?
C13 C14 C15 119.33(19) . . ?
C13 C14 H14 120.3 . . ?
C15 C14 H14 120.3 . . ?
C14 C15 C16 117.76(18) . . ?
C14 C15 C21 122.22(18) . . ?
C16 C15 C21 120.01(18) . . ?
C17 C16 C15 119.46(19) . . ?
C17 C16 H16 120.3 . . ?
C15 C16 H16 120.3 . . ?
N1 C17 C16 122.8(2) . . ?
N1 C17 H17 118.6 . . ?
C16 C17 H17 118.6 . . ?
C20 C21 C22 121.09(18) . . ?
C20 C21 C15 119.76(18) . . ?
C22 C21 C15 119.12(18) . . ?
C21 C22 C23 122.19(18) . . ?
C21 C22 C20 119.62(18) . 3_666 ?
C23 C22 C20 118.18(18) . 3_666 ?
C24 C23 C22 121.2(2) . . ?
C24 C23 H23 119.4 . . ?
C22 C23 H23 119.4 . . ?
C23 C24 C18 120.3(2) . 3_666 ?
C23 C24 H24 119.8 . . ?
C18 C24 H24 119.8 3_666 . ?
C19 C18 C24 121.1(2) . 3_666 ?
C19 C18 H18 119.5 . . ?
C24 C18 H18 119.5 3_666 . ?
C21 C20 C19 122.40(19) . . ?
C21 C20 C22 119.28(18) . 3_666 ?
C19 C20 C22 118.32(19) . 3_666 ?
C18 C19 C20 120.9(2) . . ?
C18 C19 H19 119.6 . . ?
C20 C19 H19 119.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 Zn1 N1 C13 93.33(18) . . . . ?
O1 Zn1 N1 C13 -154.84(16) 2_656 . . . ?
N1 Zn1 N1 C13 -34.18(15) 2_656 . . . ?
O1 Zn1 N1 C17 -86.16(18) . . . . ?
O1 Zn1 N1 C17 25.67(19) 2_656 . . . ?
N1 Zn1 N1 C17 146.32(19) 2_656 . . . ?
O1 Zn1 O1 C25 176.15(17) 2_656 . . . ?
N1 Zn1 O1 C25 -61.07(15) . . . . ?
N1 Zn1 O1 C25 61.92(15) 2_656 . . . ?
C5 N2 C1 C2 0.7(4) . . . . ?
N2 C1 C2 C3 -1.6(4) . . . . ?
C1 C2 C3 C4 1.1(3) . . . . ?
C1 C2 C3 C9 -177.9(2) . . . . ?
C4 C3 C9 C8 66.2(3) . . . . ?
C2 C3 C9 C8 -114.9(2) . . . . ?
C4 C3 C9 C10 -115.5(2) . . . . ?
C2 C3 C9 C10 63.5(3) . . . . ?
C10 C9 C8 C7 -177.65(18) . . . . ?
C3 C9 C8 C7 0.7(3) . . . . ?
C10 C9 C8 C10 -0.3(3) . . . 3_756 ?
C3 C9 C8 C10 177.97(17) . . . 3_756 ?
C8 C9 C10 C11 -177.16(18) . . . . ?
C3 C9 C10 C11 4.5(3) . . . . ?
C8 C9 C10 C8 0.3(3) . . . 3_756 ?
C3 C9 C10 C8 -178.00(17) . . . 3_756 ?
C2 C3 C4 C5 0.2(3) . . . . ?
C9 C3 C4 C5 179.1(2) . . . . ?
C1 N2 C5 C4 0.7(3) . . . . ?
C3 C4 C5 N2 -1.2(3) . . . . ?
C9 C10 C11 C12 178.0(2) . . . . ?
C8 C10 C11 C12 0.5(3) 3_756 . . . ?
C10 C11 C12 C6 -0.2(3) . . . 3_756 ?
C12 C6 C7 C8 -0.8(3) 3_756 . . . ?
C9 C8 C7 C6 177.9(2) . . . . ?
C10 C8 C7 C6 0.5(3) 3_756 . . . ?
Zn1 O1 C25 O2 -13.8(2) . . . . ?
Zn1 O1 C25 C26 168.99(14) . . . . ?
O2 C25 C26 C31 -129.0(2) . . . . ?
O1 C25 C26 C31 48.4(3) . . . . ?
O2 C25 C26 C27 45.6(3) . . . . ?
O1 C25 C26 C27 -137.0(2) . . . . ?
C27 C26 C31 C30 -2.8(3) . . . . ?
C25 C26 C31 C30 171.9(2) . . . . ?
C26 C31 C30 C29 1.0(4) . . . . ?
C31 C30 C29 O5 175.1(2) . . . . ?
C31 C30 C29 C28 0.6(4) . . . . ?
C29 O5 C29 C30 148.4(2) 2_756 . . . ?
C29 O5 C29 C28 -37.22(16) 2_756 . . . ?
C30 C29 C28 C27 -0.3(3) . . . . ?
O5 C29 C28 C27 -174.50(17) . . . . ?
C29 C28 C27 C26 -1.5(3) . . . . ?
C29 C28 C27 C32 170.94(19) . . . . ?
C31 C26 C27 C28 3.0(3) . . . . ?
C25 C26 C27 C28 -171.62(18) . . . . ?
C31 C26 C27 C32 -169.2(2) . . . . ?
C25 C26 C27 C32 16.1(3) . . . . ?
C28 C27 C32 O3 -135.1(2) . . . . ?
C26 C27 C32 O3 37.2(3) . . . . ?
C28 C27 C32 O4 39.7(3) . . . . ?
C26 C27 C32 O4 -148.0(2) . . . . ?
C17 N1 C13 C14 -0.8(3) . . . . ?
Zn1 N1 C13 C14 179.70(17) . . . . ?
N1 C13 C14 C15 1.1(4) . . . . ?
C13 C14 C15 C16 -0.2(3) . . . . ?
C13 C14 C15 C21 -179.5(2) . . . . ?
C14 C15 C16 C17 -1.0(4) . . . . ?
C21 C15 C16 C17 178.4(2) . . . . ?
C13 N1 C17 C16 -0.4(4) . . . . ?
Zn1 N1 C17 C16 179.1(2) . . . . ?
C15 C16 C17 N1 1.3(4) . . . . ?
C14 C15 C21 C20 -89.5(3) . . . . ?
C16 C15 C21 C20 91.2(3) . . . . ?
C14 C15 C21 C22 92.4(3) . . . . ?
C16 C15 C21 C22 -86.9(3) . . . . ?
C20 C21 C22 C23 179.68(19) . . . . ?
C15 C21 C22 C23 -2.3(3) . . . . ?
C20 C21 C22 C20 -0.1(3) . . . 3_666 ?
C15 C21 C22 C20 177.99(17) . . . 3_666 ?
C21 C22 C23 C24 179.5(2) . . . . ?
C20 C22 C23 C24 -0.7(3) 3_666 . . . ?
C22 C23 C24 C18 0.0(3) . . . 3_666 ?
C22 C21 C20 C19 -179.46(19) . . . . ?
C15 C21 C20 C19 2.5(3) . . . . ?
C22 C21 C20 C22 0.1(3) . . . 3_666 ?
C15 C21 C20 C22 -177.98(17) . . . 3_666 ?
C24 C18 C19 C20 0.5(4) 3_666 . . . ?
C21 C20 C19 C18 179.7(2) . . . . ?
C22 C20 C19 C18 0.2(3) 3_666 . . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         0.277
_refine_diff_density_min         -0.516
_refine_diff_density_rms         0.100
