# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_1_a
_database_code_depnum_ccdc_archive 'CCDC 2346401'
loop_
_audit_author_name
_audit_author_address
'Lei Zhu'
;Hunan University
China
;
_audit_update_record             
;
2024-04-08 deposited with the CCDC.	2026-02-23 downloaded from the CCDC.
;
_audit_creation_date             2024-04-08
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6403)
;
_shelx_SHELXL_version_number     2014/7
_chemical_name_common            ?
_chemical_name_systematic        'C26 H24 F N O2'
_chemical_formula_moiety         'C26 H24 F N O2'
_chemical_formula_sum            'C26 H24 F N O2'
_chemical_formula_weight         401.46
_chemical_absolute_configuration ad
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_H-M_alt        'P 21 21 21'
_space_group_name_Hall           'P 2ac 2ab'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'

_cell_length_a                   5.8725(2)
_cell_length_b                   17.5018(6)
_cell_length_c                   20.6518(7)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_volume                     2122.58(13)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    7295
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      66.40
_cell_measurement_theta_min      5.49
_shelx_estimated_absorpt_T_max   0.887
_shelx_estimated_absorpt_T_min   0.864
_exptl_absorpt_coefficient_mu    0.684
_exptl_absorpt_correction_T_max  0.7528
_exptl_absorpt_correction_T_min  0.5561
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1677 before and 0.0940 after correction.
The Ratio of minimum to maximum transmission is 0.7387.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'clear whiteish colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   whiteish
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.256
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             848
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.18
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0442
_diffrn_reflns_av_unetI/netI     0.0340
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            20585
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        66.576
_diffrn_reflns_theta_max         66.576
_diffrn_reflns_theta_min         3.310
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_source                   ?
_diffrn_source_current           1.1
_diffrn_source_power             0.055
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.713
_reflns_Friedel_fraction_full    0.994
_reflns_Friedel_fraction_max     0.994
_reflns_number_gt                3459
_reflns_number_total             3719
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.806
_refine_diff_density_min         -0.386
_refine_diff_density_rms         0.066
_refine_ls_abs_structure_details 
;
 Flack x determined using 1353 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   0.08(6)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     272
_refine_ls_number_reflns         3719
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0663
_refine_ls_R_factor_gt           0.0639
_refine_ls_restrained_S_all      1.089
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.1330P)²+0.3147P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1819
_refine_ls_wR_factor_ref         0.1857
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C17-C16
 1.54 with sigma of 0.01
3.a Secondary CH2 refined with riding coordinates:
 C12(H12A,H12B), C13(H13A,H13B), C16(H16A,H16B), C18(H18A,H18B)
3.b Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C3(H3), C4(H4), C7(H7), C8(H8), C10(H10), C20(H20), C22(H22),
 C23(H23), C24(H24), C25(H25), C26(H26)
3.c Idealised Me refined as rotating group:
 C17(H17A,H17B,H17C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.2304(9) 0.1947(2) 0.6238(2) 0.0718(11) Uani 1 1 d . . . . .
H1 H 0.0926 0.1842 0.6441 0.086 Uiso 1 1 calc R U . . .
C2 C 0.3685(11) 0.1364(2) 0.6052(2) 0.0798(14) Uani 1 1 d . . . . .
H2 H 0.3260 0.0862 0.6136 0.096 Uiso 1 1 calc R U . . .
C3 C 0.5743(11) 0.1515(2) 0.5735(2) 0.0809(14) Uani 1 1 d . . . . .
H3 H 0.6667 0.1110 0.5608 0.097 Uiso 1 1 calc R U . . .
C4 C 0.6406(8) 0.2238(2) 0.56126(19) 0.0658(10) Uani 1 1 d . . . . .
H4 H 0.7780 0.2327 0.5402 0.079 Uiso 1 1 calc R U . . .
C5 C 0.5029(7) 0.2867(2) 0.58011(16) 0.0523(8) Uani 1 1 d . . . . .
C6 C 0.2958(7) 0.2719(2) 0.61220(18) 0.0561(9) Uani 1 1 d . . . . .
C7 C 0.1584(7) 0.3353(2) 0.63103(19) 0.0629(10) Uani 1 1 d . . . . .
H7 H 0.0228 0.3267 0.6531 0.075 Uiso 1 1 calc R U . . .
C8 C 0.2229(6) 0.4082(2) 0.61711(17) 0.0559(8) Uani 1 1 d . . . . .
H8 H 0.1306 0.4487 0.6298 0.067 Uiso 1 1 calc R U . . .
C9 C 0.4302(6) 0.42324(19) 0.58336(15) 0.0486(8) Uani 1 1 d . . . . .
C10 C 0.5658(6) 0.36289(18) 0.56652(16) 0.0500(8) Uani 1 1 d . . . . .
H10 H 0.7031 0.3723 0.5455 0.060 Uiso 1 1 calc R U . . .
C11 C 0.4915(6) 0.50233(19) 0.56673(15) 0.0476(7) Uani 1 1 d . . . . .
C12 C 0.7184(6) 0.5237(2) 0.5372(2) 0.0569(9) Uani 1 1 d . . . . .
H12A H 0.8439 0.5043 0.5630 0.068 Uiso 1 1 calc R U . . .
H12B H 0.7318 0.5045 0.4934 0.068 Uiso 1 1 calc R U . . .
C13 C 0.7122(6) 0.6101(2) 0.53822(18) 0.0532(8) Uani 1 1 d . . . . .
H13A H 0.7639 0.6310 0.4973 0.064 Uiso 1 1 calc R U . . .
H13B H 0.8065 0.6302 0.5728 0.064 Uiso 1 1 calc R U . . .
C14 C 0.4571(6) 0.62867(18) 0.54999(16) 0.0480(8) Uani 1 1 d . . . . .
C15 C 0.4293(8) 0.6921(2) 0.60072(18) 0.0617(10) Uani 1 1 d . . . . .
C16 C 0.488(2) 0.7253(4) 0.7115(3) 0.142(4) Uani 1 1 d D . . . .
H16A H 0.3527 0.7563 0.7064 0.170 Uiso 1 1 calc R U . . .
H16B H 0.4801 0.6987 0.7526 0.170 Uiso 1 1 calc R U . . .
C17 C 0.688(3) 0.7712(6) 0.7082(6) 0.192(5) Uani 1 1 d D . . . .
H17A H 0.8199 0.7391 0.7101 0.289 Uiso 1 1 calc R U . . .
H17B H 0.6894 0.8062 0.7441 0.289 Uiso 1 1 calc R U . . .
H17C H 0.6880 0.7994 0.6684 0.289 Uiso 1 1 calc R U . . .
C18 C 0.3330(6) 0.65473(19) 0.48805(17) 0.0524(8) Uani 1 1 d . . . . .
H18A H 0.1740 0.6634 0.4984 0.063 Uiso 1 1 calc R U . . .
H18B H 0.3971 0.7031 0.4743 0.063 Uiso 1 1 calc R U . . .
C19 C 0.3458(6) 0.60024(19) 0.43336(16) 0.0498(7) Uani 1 1 d . . . . .
C20 C 0.4948(7) 0.6003(2) 0.38476(17) 0.0573(8) Uani 1 1 d . . . . .
H20 H 0.6000 0.6400 0.3858 0.069 Uiso 1 1 calc R U . . .
C21 C 0.5196(7) 0.5479(2) 0.32996(17) 0.0577(9) Uani 1 1 d . . . . .
C22 C 0.3529(10) 0.4965(3) 0.3096(2) 0.0772(12) Uani 1 1 d . . . . .
H22 H 0.2159 0.4929 0.3319 0.093 Uiso 1 1 calc R U . . .
C23 C 0.3920(13) 0.4510(3) 0.2560(3) 0.0988(18) Uani 1 1 d . . . . .
H23 H 0.2799 0.4170 0.2425 0.119 Uiso 1 1 calc R U . . .
C24 C 0.5923(14) 0.4550(4) 0.2226(2) 0.102(2) Uani 1 1 d . . . . .
H24 H 0.6157 0.4239 0.1867 0.122 Uiso 1 1 calc R U . . .
C25 C 0.7556(13) 0.5039(4) 0.2414(3) 0.1026(19) Uani 1 1 d . . . . .
H25 H 0.8920 0.5069 0.2187 0.123 Uiso 1 1 calc R U . . .
C26 C 0.7191(9) 0.5494(3) 0.2946(2) 0.0869(14) Uani 1 1 d . . . . .
H26 H 0.8339 0.5828 0.3074 0.104 Uiso 1 1 calc R U . . .
F1 F 0.1831(5) 0.54501(15) 0.43626(12) 0.0804(8) Uani 1 1 d . . . . .
N1 N 0.3533(5) 0.55766(16) 0.57462(14) 0.0524(7) Uani 1 1 d . . . . .
O1 O 0.3535(9) 0.75311(18) 0.59007(15) 0.1000(14) Uani 1 1 d . . . . .
O2 O 0.5114(8) 0.67108(19) 0.65791(14) 0.0939(12) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 H1 0.9300 . ?
C1 C2 1.359(7) . ?
C1 C6 1.425(5) . ?
C2 H2 0.9300 . ?
C2 C3 1.399(8) . ?
C3 H3 0.9300 . ?
C3 C4 1.349(6) . ?
C4 H4 0.9300 . ?
C4 C5 1.419(5) . ?
C5 C6 1.409(6) . ?
C5 C10 1.412(5) . ?
C6 C7 1.425(6) . ?
C7 H7 0.9300 . ?
C7 C8 1.362(6) . ?
C8 H8 0.9300 . ?
C8 C9 1.427(5) . ?
C9 C10 1.368(5) . ?
C9 C11 1.471(5) . ?
C10 H10 0.9300 . ?
C11 C12 1.512(5) . ?
C11 N1 1.274(4) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 C13 1.511(5) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C13 C14 1.553(5) . ?
C14 C15 1.535(5) . ?
C14 C18 1.541(5) . ?
C14 N1 1.475(4) . ?
C15 O1 1.178(5) . ?
C15 O2 1.328(5) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C16 C17 1.421(11) . ?
C16 O2 1.464(8) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C18 C19 1.480(5) . ?
C19 C20 1.332(5) . ?
C19 F1 1.361(4) . ?
C20 H20 0.9300 . ?
C20 C21 1.464(5) . ?
C21 C22 1.394(6) . ?
C21 C26 1.381(7) . ?
C22 H22 0.9300 . ?
C22 C23 1.383(7) . ?
C23 H23 0.9300 . ?
C23 C24 1.366(10) . ?
C24 H24 0.9300 . ?
C24 C25 1.343(10) . ?
C25 H25 0.9300 . ?
C25 C26 1.373(8) . ?
C26 H26 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C2 C1 H1 119.9 . . ?
C2 C1 C6 120.3(5) . . ?
C6 C1 H1 119.9 . . ?
C1 C2 H2 119.8 . . ?
C1 C2 C3 120.4(4) . . ?
C3 C2 H2 119.8 . . ?
C2 C3 H3 119.5 . . ?
C4 C3 C2 120.9(5) . . ?
C4 C3 H3 119.5 . . ?
C3 C4 H4 119.6 . . ?
C3 C4 C5 120.8(5) . . ?
C5 C4 H4 119.6 . . ?
C6 C5 C4 118.6(3) . . ?
C6 C5 C10 119.5(3) . . ?
C10 C5 C4 121.9(4) . . ?
C1 C6 C7 122.6(4) . . ?
C5 C6 C1 119.0(4) . . ?
C5 C6 C7 118.4(3) . . ?
C6 C7 H7 119.6 . . ?
C8 C7 C6 120.9(4) . . ?
C8 C7 H7 119.6 . . ?
C7 C8 H8 119.6 . . ?
C7 C8 C9 120.9(3) . . ?
C9 C8 H8 119.6 . . ?
C8 C9 C11 119.8(3) . . ?
C10 C9 C8 118.6(3) . . ?
C10 C9 C11 121.7(3) . . ?
C5 C10 H10 119.1 . . ?
C9 C10 C5 121.8(3) . . ?
C9 C10 H10 119.1 . . ?
C9 C11 C12 122.9(3) . . ?
N1 C11 C9 122.0(3) . . ?
N1 C11 C12 115.1(3) . . ?
C11 C12 H12A 111.2 . . ?
C11 C12 H12B 111.2 . . ?
H12A C12 H12B 109.1 . . ?
C13 C12 C11 102.8(3) . . ?
C13 C12 H12A 111.2 . . ?
C13 C12 H12B 111.2 . . ?
C12 C13 H13A 111.0 . . ?
C12 C13 H13B 111.0 . . ?
C12 C13 C14 103.6(3) . . ?
H13A C13 H13B 109.0 . . ?
C14 C13 H13A 111.0 . . ?
C14 C13 H13B 111.0 . . ?
C15 C14 C13 111.2(3) . . ?
C15 C14 C18 107.6(3) . . ?
C18 C14 C13 112.9(3) . . ?
N1 C14 C13 106.0(3) . . ?
N1 C14 C15 109.3(3) . . ?
N1 C14 C18 109.9(3) . . ?
O1 C15 C14 124.6(3) . . ?
O1 C15 O2 123.7(4) . . ?
O2 C15 C14 111.6(3) . . ?
H16A C16 H16B 108.9 . . ?
C17 C16 H16A 110.8 . . ?
C17 C16 H16B 110.8 . . ?
C17 C16 O2 104.8(9) . . ?
O2 C16 H16A 110.8 . . ?
O2 C16 H16B 110.8 . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C14 C18 H18A 108.6 . . ?
C14 C18 H18B 108.6 . . ?
H18A C18 H18B 107.6 . . ?
C19 C18 C14 114.7(3) . . ?
C19 C18 H18A 108.6 . . ?
C19 C18 H18B 108.6 . . ?
C20 C19 C18 127.5(3) . . ?
C20 C19 F1 119.7(3) . . ?
F1 C19 C18 112.8(3) . . ?
C19 C20 H20 114.8 . . ?
C19 C20 C21 130.3(3) . . ?
C21 C20 H20 114.8 . . ?
C22 C21 C20 124.6(4) . . ?
C26 C21 C20 118.8(4) . . ?
C26 C21 C22 116.6(4) . . ?
C21 C22 H22 120.1 . . ?
C23 C22 C21 119.8(5) . . ?
C23 C22 H22 120.1 . . ?
C22 C23 H23 119.4 . . ?
C24 C23 C22 121.1(6) . . ?
C24 C23 H23 119.4 . . ?
C23 C24 H24 119.9 . . ?
C25 C24 C23 120.1(5) . . ?
C25 C24 H24 119.9 . . ?
C24 C25 H25 120.3 . . ?
C24 C25 C26 119.3(6) . . ?
C26 C25 H25 120.3 . . ?
C21 C26 H26 118.5 . . ?
C25 C26 C21 123.0(6) . . ?
C25 C26 H26 118.5 . . ?
C11 N1 C14 109.5(3) . . ?
C15 O2 C16 117.4(4) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 C2 C3 C4 0.5(7) . . . . ?
C1 C6 C7 C8 -177.7(4) . . . . ?
C2 C1 C6 C5 1.3(6) . . . . ?
C2 C1 C6 C7 -179.6(4) . . . . ?
C2 C3 C4 C5 -0.1(7) . . . . ?
C3 C4 C5 C6 0.3(6) . . . . ?
C3 C4 C5 C10 -178.5(4) . . . . ?
C4 C5 C6 C1 -0.9(5) . . . . ?
C4 C5 C6 C7 180.0(3) . . . . ?
C4 C5 C10 C9 178.4(3) . . . . ?
C5 C6 C7 C8 1.5(6) . . . . ?
C6 C1 C2 C3 -1.1(7) . . . . ?
C6 C5 C10 C9 -0.4(5) . . . . ?
C6 C7 C8 C9 -0.1(6) . . . . ?
C7 C8 C9 C10 -1.5(6) . . . . ?
C7 C8 C9 C11 177.6(4) . . . . ?
C8 C9 C10 C5 1.7(5) . . . . ?
C8 C9 C11 C12 173.6(3) . . . . ?
C8 C9 C11 N1 -8.4(5) . . . . ?
C9 C11 C12 C13 -172.3(3) . . . . ?
C9 C11 N1 C14 -176.5(3) . . . . ?
C10 C5 C6 C1 177.9(3) . . . . ?
C10 C5 C6 C7 -1.2(5) . . . . ?
C10 C9 C11 C12 -7.3(5) . . . . ?
C10 C9 C11 N1 170.7(3) . . . . ?
C11 C9 C10 C5 -177.4(3) . . . . ?
C11 C12 C13 C14 -15.5(4) . . . . ?
C12 C11 N1 C14 1.7(4) . . . . ?
C12 C13 C14 C15 135.8(3) . . . . ?
C12 C13 C14 C18 -103.2(3) . . . . ?
C12 C13 C14 N1 17.1(4) . . . . ?
C13 C14 C15 O1 114.7(5) . . . . ?
C13 C14 C15 O2 -62.3(5) . . . . ?
C13 C14 C18 C19 56.1(4) . . . . ?
C13 C14 N1 C11 -12.0(4) . . . . ?
C14 C15 O2 C16 -177.8(7) . . . . ?
C14 C18 C19 C20 -94.8(4) . . . . ?
C14 C18 C19 F1 84.7(4) . . . . ?
C15 C14 C18 C19 179.1(3) . . . . ?
C15 C14 N1 C11 -131.9(3) . . . . ?
C17 C16 O2 C15 -88.9(8) . . . . ?
C18 C14 C15 O1 -9.4(6) . . . . ?
C18 C14 C15 O2 173.6(4) . . . . ?
C18 C14 N1 C11 110.2(3) . . . . ?
C18 C19 C20 C21 179.0(4) . . . . ?
C19 C20 C21 C22 16.4(7) . . . . ?
C19 C20 C21 C26 -164.8(4) . . . . ?
C20 C21 C22 C23 178.3(4) . . . . ?
C20 C21 C26 C25 -178.2(5) . . . . ?
C21 C22 C23 C24 0.3(8) . . . . ?
C22 C21 C26 C25 0.7(7) . . . . ?
C22 C23 C24 C25 -0.1(9) . . . . ?
C23 C24 C25 C26 0.2(9) . . . . ?
C24 C25 C26 C21 -0.5(9) . . . . ?
C26 C21 C22 C23 -0.6(7) . . . . ?
F1 C19 C20 C21 -0.6(6) . . . . ?
N1 C11 C12 C13 9.6(4) . . . . ?
N1 C14 C15 O1 -128.6(5) . . . . ?
N1 C14 C15 O2 54.3(5) . . . . ?
N1 C14 C18 C19 -62.0(4) . . . . ?
O1 C15 O2 C16 5.1(10) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: CH2Cl2 and methanol'
