# Supplementary Information (SI) for ChemComm.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Cd6Eu4-polymer
_database_code_depnum_ccdc_archive 'CCDC 2529699'
loop_
_audit_author_name
_audit_author_address
'Xiaoping Yang'
;Wenzhou University
China
;
_audit_update_record             
;
2026-02-09 deposited with the CCDC.	2026-04-22 downloaded from the CCDC.
;

# start Validation Reply Form
_vrf_PLAT342_Cd6Eu4-polymer      
;
PROBLEM: Low Bond Precision on  C-C Bonds ...............     0.0445 Ang.  
RESPONSE: The positions of C atoms in the free methoxy groups of the ligands 
are poorly resolved because of conformational flexibility. They have higher
than usual su??s as a result.
;
_vrf_PLAT990_Cd6Eu4-polymer      
;
PROBLEM: Deprecated .res/.hkl Input Style SQUEEZE Job ...          ! Note  
RESPONSE: Some uncoordinated solvent molecules such as EtOH, EtOEt and H2O 
molecules were found to be badly disordered. The contributions to the 
scattering factors due to these solvent molecules were removed by use of 
the utility SQUEEZE.
;
# end Validation Reply Form

_audit_creation_method           SHELXL-97
_chemical_name_systematic        Cd6Eu4-polymer
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C39 H65 Cd3 Cl6 Eu2 N7 O19'
_chemical_formula_weight         1789.80

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   Pbcn

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z+1/2'
'-x, y, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y-1/2, -z-1/2'
'x, -y, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   12.5924(11)
_cell_length_b                   29.4736(18)
_cell_length_c                   36.5786(13)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     13575.9(15)
_cell_formula_units_Z            8
_cell_measurement_temperature    190(1)
_cell_measurement_reflns_used    9690
_cell_measurement_theta_min      1.2301
_cell_measurement_theta_max      31.1176

_exptl_crystal_description       Block
_exptl_crystal_colour            Yellow
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.751
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             6976
_exptl_absorpt_coefficient_mu    3.044
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.8320
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   
'DENZO and Scalepack (Otwinoski and Minor, 1997)'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      190(1)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Mercury2 (2x2 bin mode)'
_diffrn_measurement_method       dtprofit.ref
_diffrn_detector_area_resol_mean 13.6612
_diffrn_reflns_number            11814
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.1022
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_limit_l_max       43
_diffrn_reflns_theta_min         1.77
_diffrn_reflns_theta_max         25.00
_reflns_number_total             11814
_reflns_number_gt                6483
_reflns_threshold_expression     >2sigma(I)
_computing_data_collection       'Collect software, Nonius B.V. 1998'
_computing_cell_refinement       'Collect software, Nonius B.V. 1998'
_computing_data_reduction        
;
DENZO and Scalepack (Otwinoski and Minor, 1997)
;
_computing_structure_solution    
;

SIR97 - Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C., 
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R.
;
_computing_structure_refinement  'XL SHELXTL/PC, Siemens Analytical'
_computing_molecular_graphics    'XP SHELXTL/PC, Siemens Analytical'
_computing_publication_material  ?



_refine_special_details          
;Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 

 Restraints: ISOR was applied to all non-hydrogen atoms to allow their Uij 
 components approximate to isotropic behavior.
 
 Some uncoordinated solvent molecules such as EtOH, EtOEt and H2O molecules 
 were found to be badly disordered. Attempts to model the disorder were 
 unsatisfactory. The contributions to the scattering factors due to these 
 solvent molecules were removed by use of the utility SQUEEZE (Sluis and 
 Spek, 1990) in PLATON98 (Spek, 1998). PLATON98 was used as incorporated 
 in WinGX (Farrugia, 1999).,SQUEEZE
;
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.500 0.000 0.000 35 27 ' '
2 0.500 0.000 0.500 35 27 ' '
3 0.501 0.190 0.750 252 150 ' '
4 0.550 0.181 0.080 26 11 ' '
5 0.449 0.181 0.419 26 12 ' '
6 0.001 0.310 0.250 252 144 ' '
7 0.950 0.319 0.580 26 11 ' '
8 0.050 0.319 0.919 26 12 ' '
9 1.000 0.500 0.500 35 27 ' '
10 0.000 0.500 1.000 35 27 ' '
11 0.999 0.690 0.750 252 149 ' '
12 0.949 0.681 0.080 26 11 ' '
13 0.051 0.681 0.419 26 12 ' '
14 0.499 0.810 0.250 252 144 ' '
15 0.550 0.819 0.580 26 11 ' '
16 0.449 0.819 0.919 26 12 ' '

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.2000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11814
_refine_ls_number_parameters     687
_refine_ls_number_restraints     528
_refine_ls_R_factor_all          0.1778
_refine_ls_R_factor_gt           0.0903
_refine_ls_wR_factor_ref         0.2474
_refine_ls_wR_factor_gt          0.2220
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_restrained_S_all      1.071
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.59030(9) 0.51765(4) 0.29452(2) 0.0804(4) Uani 1 1 d U . .
Eu2 Eu 0.63196(10) 0.60820(4) 0.22102(3) 0.0950(5) Uani 1 1 d U . .
Cd1 Cd 0.72940(15) 0.60172(6) 0.36731(4) 0.1049(6) Uani 1 1 d U . .
Cd2 Cd 0.40974(16) 0.41910(5) 0.33618(4) 0.0996(6) Uani 1 1 d U . .
Cd3 Cd 0.43685(17) 0.52764(5) 0.45826(3) 0.1037(6) Uani 1 1 d U . .
Cl1 Cl 0.7050(7) 0.6711(2) 0.33104(18) 0.141(2) Uani 1 1 d U . .
Cl2 Cl 0.2450(8) 0.4172(4) 0.3018(2) 0.175(3) Uani 1 1 d U . .
Cl3 Cl 0.4833(9) 0.3476(3) 0.3517(3) 0.174(3) Uani 1 1 d U . .
Cl4 Cl 0.2764(9) 0.5669(4) 0.4709(3) 0.191(4) Uani 1 1 d U . .
Cl5 Cl 0.5706(9) 0.5487(3) 0.5086(2) 0.177(3) Uani 1 1 d U . .
Cl6 Cl 0.8809(11) 0.5830(5) 0.4003(4) 0.238(5) Uani 1 1 d U . .
N1 N 0.6039(13) 0.6035(5) 0.4161(4) 0.085(4) Uani 1 1 d U . .
N2 N 0.5285(13) 0.5667(5) 0.4145(4) 0.085(4) Uani 1 1 d U . .
N3 N 0.4034(13) 0.4922(5) 0.4026(5) 0.083(4) Uani 1 1 d U . .
N4 N 0.3457(15) 0.4524(6) 0.3919(5) 0.101(5) Uani 1 1 d U . .
N5 N 0.765(3) 0.4431(16) 0.4018(14) 0.282(18) Uani 1 1 d DU . .
N6 N 0.864(3) 0.5216(12) 0.1471(11) 0.200(13) Uani 1 1 d DU . .
N7 N 0.621(3) 0.6796(11) 0.1161(11) 0.211(10) Uani 1 1 d DU . .
O1 O 0.6895(15) 0.7294(6) 0.5413(5) 0.126(5) Uani 1 1 d U . .
O2 O 0.8181(18) 0.7755(7) 0.4985(6) 0.156(7) Uani 1 1 d U . .
O3 O 0.843(2) 0.7540(10) 0.4264(8) 0.209(10) Uani 1 1 d U . .
O4 O 0.5847(10) 0.5589(4) 0.3536(3) 0.082(3) Uani 1 1 d U . .
O5 O 0.4535(11) 0.4917(4) 0.3410(3) 0.082(3) Uani 1 1 d U . .
O6 O -0.002(3) 0.3661(13) 0.4806(12) 0.267(14) Uani 1 1 d DU . .
O7 O -0.011(3) 0.3054(14) 0.4262(10) 0.265(13) Uani 1 1 d DU . .
O8 O 0.097(3) 0.3081(12) 0.3712(10) 0.250(14) Uani 1 1 d DU . .
O9 O 0.6710(16) 0.4696(5) 0.3422(5) 0.126(5) Uani 1 1 d U . .
O10 O 0.5123(10) 0.4420(4) 0.2803(3) 0.081(3) Uani 1 1 d U . .
O11 O 0.7584(13) 0.5568(5) 0.3109(4) 0.107(4) Uani 1 1 d U . .
O12 O 0.7831(13) 0.5834(5) 0.2549(5) 0.118(5) Uani 1 1 d U . .
O13 O 0.5870(9) 0.5286(4) 0.2299(3) 0.071(3) Uani 1 1 d U . .
H13B H 0.6383 0.5088 0.2177 0.085 Uiso 1 1 calc R . .
O14 O 0.5567(10) 0.5963(4) 0.2813(3) 0.071(3) Uani 1 1 d U . .
H14A H 0.5902 0.6161 0.2994 0.085 Uiso 1 1 calc R . .
O15 O 0.5794(17) 0.6836(6) 0.2354(5) 0.144(6) Uani 1 1 d U . .
O16 O 0.7370(15) 0.5663(6) 0.1763(5) 0.127(5) Uani 1 1 d DU . .
O17 O 0.582(2) 0.6376(9) 0.1637(7) 0.184(8) Uani 1 1 d DU . .
O18 O 0.7851(18) 0.6615(8) 0.2032(6) 0.175(7) Uani 1 1 d DU . .
H18A H 0.7686 0.6607 0.1815 0.211 Uiso 1 1 calc R . .
O19 O 0.7401(16) 0.4715(6) 0.2700(5) 0.146(6) Uani 1 1 d DU . .
H19B H 0.7680 0.4953 0.2634 0.176 Uiso 1 1 calc R . .
C1 C 0.627(3) 0.7059(13) 0.5675(12) 0.199(15) Uani 1 1 d U . .
H1A H 0.6309 0.7215 0.5905 0.299 Uiso 1 1 calc R . .
H1B H 0.6541 0.6756 0.5703 0.299 Uiso 1 1 calc R . .
H1C H 0.5549 0.7047 0.5594 0.299 Uiso 1 1 calc R . .
C2 C 0.697(2) 0.7123(8) 0.5074(7) 0.115(7) Uani 1 1 d U . .
C3 C 0.642(2) 0.6774(8) 0.4939(7) 0.118(8) Uani 1 1 d U . .
H3A H 0.5964 0.6611 0.5090 0.141 Uiso 1 1 calc R . .
C4 C 0.6529(18) 0.6656(7) 0.4570(5) 0.093(6) Uani 1 1 d U . .
C5 C 0.716(3) 0.6857(11) 0.4341(10) 0.163(11) Uani 1 1 d U . .
H5A H 0.7179 0.6762 0.4098 0.195 Uiso 1 1 calc R . .
C6 C 0.783(3) 0.7226(11) 0.4457(9) 0.152(10) Uani 1 1 d U . .
C7 C 0.761(2) 0.7338(9) 0.4839(8) 0.125(8) Uani 1 1 d U . .
C8 C 0.792(3) 0.8176(12) 0.4786(10) 0.188(14) Uani 1 1 d U . .
H8A H 0.8313 0.8424 0.4891 0.282 Uiso 1 1 calc R . .
H8B H 0.7176 0.8235 0.4805 0.282 Uiso 1 1 calc R . .
H8C H 0.8116 0.8143 0.4534 0.282 Uiso 1 1 calc R . .
C9 C 0.860(4) 0.7356(15) 0.3872(14) 0.243(15) Uani 1 1 d U . .
H9A H 0.9084 0.7550 0.3743 0.364 Uiso 1 1 calc R . .
H9B H 0.7933 0.7348 0.3746 0.364 Uiso 1 1 calc R . .
H9C H 0.8891 0.7055 0.3884 0.364 Uiso 1 1 calc R . .
C10 C 0.5830(17) 0.6272(6) 0.4447(5) 0.085(5) Uani 1 1 d U . .
H10A H 0.5225 0.6204 0.4582 0.102 Uiso 1 1 calc R . .
C11 C 0.5291(15) 0.5472(6) 0.3806(5) 0.079(5) Uani 1 1 d DU . .
C12 C 0.4601(14) 0.5070(5) 0.3738(5) 0.072(5) Uani 1 1 d DU . .
C13 C 0.282(2) 0.4388(9) 0.4178(7) 0.124(8) Uani 1 1 d U . .
H13A H 0.2848 0.4565 0.4388 0.148 Uiso 1 1 calc R . .
C14 C 0.214(2) 0.4033(10) 0.4197(8) 0.134(8) Uani 1 1 d DU . .
C15 C 0.147(3) 0.4033(10) 0.4528(9) 0.145(10) Uani 1 1 d DU . .
H15A H 0.1576 0.4225 0.4725 0.174 Uiso 1 1 calc R . .
C16 C 0.067(3) 0.3720(14) 0.4513(13) 0.199(15) Uani 1 1 d DU . .
C17 C 0.065(3) 0.3375(14) 0.4258(11) 0.173(13) Uani 1 1 d DU . .
C18 C 0.114(3) 0.3396(14) 0.3962(12) 0.175(13) Uani 1 1 d U . .
C19 C 0.190(3) 0.3744(12) 0.3927(10) 0.179(11) Uani 1 1 d DU . .
H19A H 0.2248 0.3775 0.3705 0.215 Uiso 1 1 calc R . .
C20 C 0.029(4) 0.3827(17) 0.5203(13) 0.274(17) Uani 1 1 d DU . .
H20A H -0.0248 0.3735 0.5373 0.410 Uiso 1 1 calc R . .
H20B H 0.0352 0.4151 0.5205 0.410 Uiso 1 1 calc R . .
H20C H 0.0958 0.3695 0.5273 0.410 Uiso 1 1 calc R . .
C21 C -0.007(4) 0.2734(19) 0.4607(14) 0.279(18) Uani 1 1 d DU . .
H21A H -0.0653 0.2525 0.4598 0.418 Uiso 1 1 calc R . .
H21B H -0.0120 0.2914 0.4826 0.418 Uiso 1 1 calc R . .
H21C H 0.0587 0.2568 0.4609 0.418 Uiso 1 1 calc R . .
C22 C 0.192(4) 0.3062(18) 0.3424(13) 0.28(2) Uani 1 1 d DU . .
H22A H 0.1772 0.2834 0.3243 0.413 Uiso 1 1 calc R . .
H22B H 0.2569 0.2988 0.3548 0.413 Uiso 1 1 calc R . .
H22C H 0.1993 0.3351 0.3307 0.413 Uiso 1 1 calc R . .
C23 C 0.672(4) 0.4166(15) 0.4115(13) 0.27(2) Uani 1 1 d DU . .
H23A H 0.6183 0.4204 0.3932 0.410 Uiso 1 1 calc R . .
H23B H 0.6454 0.4267 0.4347 0.410 Uiso 1 1 calc R . .
H23C H 0.6914 0.3851 0.4131 0.410 Uiso 1 1 calc R . .
C24 C 0.838(5) 0.4684(19) 0.4271(15) 0.31(2) Uani 1 1 d DU . .
H24A H 0.8388 0.4537 0.4505 0.459 Uiso 1 1 calc R . .
H24B H 0.8134 0.4990 0.4299 0.459 Uiso 1 1 calc R . .
H24C H 0.9084 0.4685 0.4171 0.459 Uiso 1 1 calc R . .
C25 C 0.743(3) 0.4749(11) 0.3678(9) 0.163(10) Uani 1 1 d DU . .
H25A H 0.7797 0.5022 0.3660 0.196 Uiso 1 1 d R . .
C26 C 0.958(4) 0.5013(18) 0.1565(15) 0.30(3) Uani 1 1 d DU . .
H26A H 0.9878 0.5163 0.1774 0.443 Uiso 1 1 calc R . .
H26B H 1.0070 0.5035 0.1364 0.443 Uiso 1 1 calc R . .
H26C H 0.9460 0.4699 0.1621 0.443 Uiso 1 1 calc R . .
C27 C 0.846(3) 0.5518(14) 0.1193(12) 0.231(18) Uani 1 1 d DU . .
H27A H 0.7771 0.5650 0.1221 0.346 Uiso 1 1 calc R . .
H27B H 0.8504 0.5362 0.0963 0.346 Uiso 1 1 calc R . .
H27C H 0.8991 0.5753 0.1202 0.346 Uiso 1 1 calc R . .
C28 C 0.823(3) 0.5389(11) 0.1740(11) 0.169(12) Uani 1 1 d DU . .
H28A H 0.8560 0.5324 0.1961 0.203 Uiso 1 1 calc R . .
C29 C 0.920(4) 0.7037(16) 0.1765(12) 0.23(2) Uani 1 1 d DU . .
H29A H 0.9607 0.7310 0.1736 0.352 Uiso 1 1 calc R . .
H29B H 0.8745 0.6996 0.1558 0.352 Uiso 1 1 calc R . .
H29C H 0.9674 0.6782 0.1785 0.352 Uiso 1 1 calc R . .
C30 C 0.853(4) 0.7072(13) 0.2112(12) 0.227(14) Uani 1 1 d DU . .
H30A H 0.8089 0.7342 0.2117 0.273 Uiso 1 1 calc R . .
H30B H 0.8947 0.7051 0.2334 0.273 Uiso 1 1 calc R . .
C31 C 0.682(4) 0.6783(13) 0.0771(10) 0.233(13) Uani 1 1 d DU . .
H31A H 0.6647 0.7049 0.0633 0.350 Uiso 1 1 calc R . .
H31B H 0.6607 0.6518 0.0638 0.350 Uiso 1 1 calc R . .
H31C H 0.7575 0.6773 0.0812 0.350 Uiso 1 1 calc R . .
C32 C 0.528(3) 0.7074(14) 0.1274(12) 0.227(13) Uani 1 1 d DU . .
H32A H 0.5213 0.7331 0.1113 0.341 Uiso 1 1 calc R . .
H32B H 0.5380 0.7178 0.1520 0.341 Uiso 1 1 calc R . .
H32C H 0.4648 0.6893 0.1261 0.341 Uiso 1 1 calc R . .
C33 C 0.5000 0.7479(17) 0.2500 0.216(18) Uani 1 2 d SDU . .
H33A H 0.4368 0.7587 0.2618 0.324 Uiso 0.50 1 calc PR . .
H33B H 0.5020 0.7587 0.2253 0.324 Uiso 0.50 1 calc PR . .
H33C H 0.5612 0.7587 0.2630 0.324 Uiso 0.50 1 calc PR . .
C34 C 0.5000 0.6978(18) 0.2500 0.186(17) Uani 1 2 d SDU . .
C35 C 0.9320(19) 0.5866(11) 0.2967(9) 0.152(9) Uani 1 1 d DU . .
H35A H 0.9457 0.5793 0.3219 0.228 Uiso 1 1 calc R . .
H35B H 0.9442 0.6184 0.2928 0.228 Uiso 1 1 calc R . .
H35C H 0.9786 0.5693 0.2813 0.228 Uiso 1 1 calc R . .
C36 C 0.8217(18) 0.5757(8) 0.2879(7) 0.112(7) Uani 1 1 d DU . .
C37 C 0.5000 0.3700(11) 0.2500 0.125(10) Uani 1 2 d SU . .
H37A H 0.4912 0.3592 0.2254 0.187 Uiso 0.50 1 calc PR . .
H37B H 0.4426 0.3592 0.2649 0.187 Uiso 0.50 1 calc PR . .
H37C H 0.5662 0.3592 0.2597 0.187 Uiso 0.50 1 calc PR . .
C38 C 0.5000 0.4229(11) 0.2500 0.099(8) Uani 1 2 d SU . .
C39 C 0.637(3) 0.6334(12) 0.1313(10) 0.224(14) Uani 1 1 d DU . .
H39A H 0.6729 0.6086 0.1217 0.268 Uiso 1 1 calc R . .
C40 C 0.816(3) 0.4371(11) 0.2709(9) 0.175(7) Uani 1 1 d DU . .
H40A H 0.8835 0.4520 0.2663 0.210 Uiso 1 1 calc R . .
H40B H 0.8019 0.4184 0.2497 0.210 Uiso 1 1 calc R . .
C41 C 0.837(3) 0.4038(11) 0.3023(10) 0.208(11) Uani 1 1 d DU . .
H41A H 0.8664 0.3762 0.2926 0.313 Uiso 1 1 calc R . .
H41B H 0.7721 0.3973 0.3148 0.313 Uiso 1 1 calc R . .
H41C H 0.8871 0.4170 0.3191 0.313 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O13 2.385(10) . ?
Eu1 O14 2.405(11) . ?
Eu1 O13 2.426(11) 3_655 ?
Eu1 O9 2.467(17) . ?
Eu1 O4 2.480(11) . ?
Eu1 O11 2.485(16) . ?
Eu1 O19 2.491(19) . ?
Eu1 O10 2.492(12) . ?
Eu1 O5 2.539(11) . ?
Eu1 Eu2 3.8245(14) . ?
Eu1 Eu2 3.9089(15) 3_655 ?
Eu1 Eu1 3.9724(18) 3_655 ?
Eu2 O17 2.36(2) . ?
Eu2 O12 2.385(17) . ?
Eu2 O15 2.378(19) . ?
Eu2 O14 2.403(12) 3_655 ?
Eu2 O14 2.424(10) . ?
Eu2 O13 2.434(11) . ?
Eu2 O16 2.440(18) . ?
Eu2 O18 2.57(2) . ?
Eu2 Eu1 3.9089(15) 3_655 ?
Eu2 Eu2 3.942(2) 3_655 ?
Cd1 O4 2.272(13) . ?
Cd1 Cl6 2.324(13) . ?
Cd1 N1 2.383(16) . ?
Cd1 Cl1 2.456(7) . ?
Cd1 O11 2.477(14) . ?
Cd2 O5 2.216(12) . ?
Cd2 Cl3 2.370(8) . ?
Cd2 N4 2.401(17) . ?
Cd2 Cl2 2.426(10) . ?
Cd2 O10 2.511(12) . ?
Cd3 N2 2.283(15) . ?
Cd3 N3 2.327(16) . ?
Cd3 Cl4 2.373(10) . ?
Cd3 Cl5 2.557(8) 5_666 ?
Cd3 Cl5 2.571(9) . ?
Cl5 Cd3 2.557(8) 5_666 ?
N1 C10 1.29(2) . ?
N1 N2 1.44(2) . ?
N2 C11 1.37(2) . ?
N3 C12 1.34(2) . ?
N3 N4 1.43(2) . ?
N4 C13 1.30(3) . ?
N5 C23 1.45(3) . ?
N5 C24 1.51(3) . ?
N5 C25 1.58(5) . ?
N6 C28 1.22(4) . ?
N6 C26 1.37(3) . ?
N6 C27 1.37(4) . ?
N7 C39 1.49(3) . ?
N7 C32 1.49(3) . ?
N7 C31 1.62(4) . ?
O1 C2 1.34(3) . ?
O1 C1 1.42(4) . ?
O2 C8 1.47(4) . ?
O2 C7 1.52(3) . ?
O3 C6 1.39(4) . ?
O3 C9 1.55(5) . ?
O4 C11 1.260(19) . ?
O5 C12 1.285(19) . ?
O6 C16 1.38(5) . ?
O6 C20 1.58(3) . ?
O7 C17 1.34(4) . ?
O7 C21 1.58(3) . ?
O8 C18 1.32(4) . ?
O8 C22 1.60(3) . ?
O9 C25 1.31(3) . ?
O10 C38 1.251(17) . ?
O11 C36 1.29(3) . ?
O12 C36 1.32(3) . ?
O13 Eu1 2.426(11) 3_655 ?
O13 H13B 0.9800 . ?
O14 Eu2 2.403(12) 3_655 ?
O14 H14A 0.9800 . ?
O15 C34 1.21(2) . ?
O16 C28 1.35(2) . ?
O17 C39 1.38(2) . ?
O18 C30 1.62(3) . ?
O18 H18A 0.8200 . ?
O19 C40 1.40(2) . ?
O19 H19B 0.8200 . ?
C1 H1A 0.9600 . ?
C1 H1B 0.9600 . ?
C1 H1C 0.9600 . ?
C2 C7 1.33(3) . ?
C2 C3 1.34(3) . ?
C3 C4 1.40(3) . ?
C3 H3A 0.9300 . ?
C4 C5 1.30(3) . ?
C4 C10 1.50(3) . ?
C5 C6 1.44(4) . ?
C5 H5A 0.9300 . ?
C6 C7 1.46(4) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 H10A 0.9300 . ?
C11 C12 1.49(2) . ?
C13 C14 1.36(3) . ?
C13 H13A 0.9300 . ?
C14 C19 1.34(2) . ?
C14 C15 1.47(4) . ?
C15 C16 1.37(3) . ?
C15 H15A 0.9300 . ?
C16 C17 1.38(3) . ?
C17 C18 1.25(4) . ?
C18 C19 1.41(5) . ?
C19 H19A 0.9300 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 H25A 0.9300 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 H28A 0.9300 . ?
C29 C30 1.53(3) . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C31 H31A 0.9600 . ?
C31 H31B 0.9600 . ?
C31 H31C 0.9600 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 C34 1.48(3) . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
C34 O15 1.21(2) 3_655 ?
C35 C36 1.463(10) . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
C37 C38 1.56(5) . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C38 O10 1.251(17) 3_655 ?
C39 H39A 0.9300 . ?
C40 C41 1.53(2) . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C41 H41A 0.9600 . ?
C41 H41B 0.9600 . ?
C41 H41C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O13 Eu1 O14 70.5(4) . . ?
O13 Eu1 O13 66.5(5) . 3_655 ?
O14 Eu1 O13 68.6(4) . 3_655 ?
O13 Eu1 O9 141.8(5) . . ?
O14 Eu1 O9 140.2(5) . . ?
O13 Eu1 O9 135.7(5) 3_655 . ?
O13 Eu1 O4 142.7(4) . . ?
O14 Eu1 O4 72.4(4) . . ?
O13 Eu1 O4 103.3(4) 3_655 . ?
O9 Eu1 O4 71.2(5) . . ?
O13 Eu1 O11 101.0(4) . . ?
O14 Eu1 O11 75.6(5) . . ?
O13 Eu1 O11 144.2(4) 3_655 . ?
O9 Eu1 O11 75.2(5) . . ?
O4 Eu1 O11 65.5(4) . . ?
O13 Eu1 O19 74.4(5) . . ?
O14 Eu1 O19 125.9(5) . . ?
O13 Eu1 O19 129.5(5) 3_655 . ?
O9 Eu1 O19 68.3(6) . . ?
O4 Eu1 O19 127.0(5) . . ?
O11 Eu1 O19 72.3(6) . . ?
O13 Eu1 O10 84.7(4) . . ?
O14 Eu1 O10 138.6(4) . . ?
O13 Eu1 O10 71.3(4) 3_655 . ?
O9 Eu1 O10 78.3(5) . . ?
O4 Eu1 O10 127.6(4) . . ?
O11 Eu1 O10 143.3(5) . . ?
O19 Eu1 O10 74.6(6) . . ?
O13 Eu1 O5 133.8(4) . . ?
O14 Eu1 O5 107.8(4) . . ?
O13 Eu1 O5 70.3(4) 3_655 . ?
O9 Eu1 O5 68.4(6) . . ?
O4 Eu1 O5 62.9(4) . . ?
O11 Eu1 O5 123.8(4) . . ?
O19 Eu1 O5 126.2(5) . . ?
O10 Eu1 O5 66.6(4) . . ?
O13 Eu1 Eu2 37.9(3) . . ?
O14 Eu1 Eu2 37.8(2) . . ?
O13 Eu1 Eu2 76.9(3) 3_655 . ?
O9 Eu1 Eu2 147.3(4) . . ?
O4 Eu1 Eu2 105.9(3) . . ?
O11 Eu1 Eu2 74.3(4) . . ?
O19 Eu1 Eu2 91.4(4) . . ?
O10 Eu1 Eu2 122.1(2) . . ?
O5 Eu1 Eu2 140.7(3) . . ?
O13 Eu1 Eu2 75.6(3) . 3_655 ?
O14 Eu1 Eu2 35.6(3) . 3_655 ?
O13 Eu1 Eu2 36.5(3) 3_655 3_655 ?
O9 Eu1 Eu2 142.2(4) . 3_655 ?
O4 Eu1 Eu2 76.8(3) . 3_655 ?
O11 Eu1 Eu2 109.1(3) . 3_655 ?
O19 Eu1 Eu2 149.6(4) . 3_655 ?
O10 Eu1 Eu2 107.4(3) . 3_655 ?
O5 Eu1 Eu2 79.5(3) . 3_655 ?
Eu2 Eu1 Eu2 61.28(4) . 3_655 ?
O13 Eu1 Eu1 34.7(3) . 3_655 ?
O14 Eu1 Eu1 74.6(3) . 3_655 ?
O13 Eu1 Eu1 34.0(2) 3_655 3_655 ?
O9 Eu1 Eu1 144.7(4) . 3_655 ?
O4 Eu1 Eu1 134.2(3) . 3_655 ?
O11 Eu1 Eu1 133.3(3) . 3_655 ?
O19 Eu1 Eu1 98.0(4) . 3_655 ?
O10 Eu1 Eu1 66.6(3) . 3_655 ?
O5 Eu1 Eu1 99.3(3) . 3_655 ?
Eu2 Eu1 Eu1 60.14(2) . 3_655 ?
Eu2 Eu1 Eu1 58.05(2) 3_655 3_655 ?
O17 Eu2 O12 142.1(7) . . ?
O17 Eu2 O15 77.2(8) . . ?
O12 Eu2 O15 113.2(6) . . ?
O17 Eu2 O14 76.0(7) . 3_655 ?
O12 Eu2 O14 139.6(4) . 3_655 ?
O15 Eu2 O14 82.5(6) . 3_655 ?
O17 Eu2 O14 139.3(7) . . ?
O12 Eu2 O14 78.2(5) . . ?
O15 Eu2 O14 80.0(5) . . ?
O14 Eu2 O14 67.9(4) 3_655 . ?
O17 Eu2 O13 114.3(7) . . ?
O12 Eu2 O13 79.7(5) . . ?
O15 Eu2 O13 143.7(6) . . ?
O14 Eu2 O13 68.5(4) 3_655 . ?
O14 Eu2 O13 69.4(4) . . ?
O17 Eu2 O16 74.6(8) . . ?
O12 Eu2 O16 76.2(6) . . ?
O15 Eu2 O16 140.6(6) . . ?
O14 Eu2 O16 116.0(5) 3_655 . ?
O14 Eu2 O16 138.4(5) . . ?
O13 Eu2 O16 74.2(5) . . ?
O17 Eu2 O18 75.5(8) . . ?
O12 Eu2 O18 73.8(6) . . ?
O15 Eu2 O18 72.2(7) . . ?
O14 Eu2 O18 145.2(5) 3_655 . ?
O14 Eu2 O18 127.8(6) . . ?
O13 Eu2 O18 142.9(6) . . ?
O16 Eu2 O18 74.5(7) . . ?
O17 Eu2 Eu1 147.8(6) . . ?
O12 Eu2 Eu1 62.0(4) . . ?
O15 Eu2 Eu1 117.3(5) . . ?
O14 Eu2 Eu1 77.7(2) 3_655 . ?
O14 Eu2 Eu1 37.5(3) . . ?
O13 Eu2 Eu1 37.0(2) . . ?
O16 Eu2 Eu1 101.1(4) . . ?
O18 Eu2 Eu1 135.1(5) . . ?
O17 Eu2 Eu1 86.0(6) . 3_655 ?
O12 Eu2 Eu1 116.0(4) . 3_655 ?
O15 Eu2 Eu1 118.1(5) . 3_655 ?
O14 Eu2 Eu1 35.6(3) 3_655 3_655 ?
O14 Eu2 Eu1 75.7(3) . 3_655 ?
O13 Eu2 Eu1 36.4(3) . 3_655 ?
O16 Eu2 Eu1 86.8(4) . 3_655 ?
O18 Eu2 Eu1 156.5(5) . 3_655 ?
Eu1 Eu2 Eu1 61.81(3) . 3_655 ?
O17 Eu2 Eu2 104.7(6) . 3_655 ?
O12 Eu2 Eu2 113.1(4) . 3_655 ?
O15 Eu2 Eu2 69.3(5) . 3_655 ?
O14 Eu2 Eu2 35.4(2) 3_655 3_655 ?
O14 Eu2 Eu2 35.1(3) . 3_655 ?
O13 Eu2 Eu2 74.4(3) . 3_655 ?
O16 Eu2 Eu2 144.9(4) . 3_655 ?
O18 Eu2 Eu2 140.2(5) . 3_655 ?
Eu1 Eu2 Eu2 60.41(2) . 3_655 ?
Eu1 Eu2 Eu2 58.30(3) 3_655 3_655 ?
O4 Cd1 Cl6 129.9(5) . . ?
O4 Cd1 N1 69.3(5) . . ?
Cl6 Cd1 N1 99.3(5) . . ?
O4 Cd1 Cl1 104.0(4) . . ?
Cl6 Cd1 Cl1 125.5(4) . . ?
N1 Cd1 Cl1 107.6(4) . . ?
O4 Cd1 O11 68.7(5) . . ?
Cl6 Cd1 O11 100.6(5) . . ?
N1 Cd1 O11 137.1(5) . . ?
Cl1 Cd1 O11 90.8(4) . . ?
O5 Cd2 Cl3 137.9(5) . . ?
O5 Cd2 N4 67.7(5) . . ?
Cl3 Cd2 N4 106.9(5) . . ?
O5 Cd2 Cl2 106.0(4) . . ?
Cl3 Cd2 Cl2 116.0(4) . . ?
N4 Cd2 Cl2 99.3(5) . . ?
O5 Cd2 O10 71.2(4) . . ?
Cl3 Cd2 O10 103.5(4) . . ?
N4 Cd2 O10 138.9(5) . . ?
Cl2 Cd2 O10 91.4(4) . . ?
N2 Cd3 N3 72.8(5) . . ?
N2 Cd3 Cl4 108.8(5) . . ?
N3 Cd3 Cl4 103.5(5) . . ?
N2 Cd3 Cl5 142.5(5) . 5_666 ?
N3 Cd3 Cl5 90.8(4) . 5_666 ?
Cl4 Cd3 Cl5 107.8(4) . 5_666 ?
N2 Cd3 Cl5 92.8(5) . . ?
N3 Cd3 Cl5 148.6(5) . . ?
Cl4 Cd3 Cl5 107.5(4) . . ?
Cl5 Cd3 Cl5 84.1(3) 5_666 . ?
Cd3 Cl5 Cd3 95.9(3) 5_666 . ?
C10 N1 N2 107.8(16) . . ?
C10 N1 Cd1 139.2(14) . . ?
N2 N1 Cd1 113.0(10) . . ?
C11 N2 N1 110.3(14) . . ?
C11 N2 Cd3 115.3(12) . . ?
N1 N2 Cd3 133.2(11) . . ?
C12 N3 N4 108.7(15) . . ?
C12 N3 Cd3 116.3(11) . . ?
N4 N3 Cd3 134.2(12) . . ?
C13 N4 N3 111.3(19) . . ?
C13 N4 Cd2 134.2(17) . . ?
N3 N4 Cd2 113.3(11) . . ?
C23 N5 C24 127(5) . . ?
C23 N5 C25 112(3) . . ?
C24 N5 C25 107(4) . . ?
C28 N6 C26 110(4) . . ?
C28 N6 C27 105(4) . . ?
C26 N6 C27 127(4) . . ?
C39 N7 C32 120(3) . . ?
C39 N7 C31 104(2) . . ?
C32 N7 C31 129(3) . . ?
C2 O1 C1 119(2) . . ?
C8 O2 C7 114(2) . . ?
C6 O3 C9 108(3) . . ?
C11 O4 Cd1 115.1(11) . . ?
C11 O4 Eu1 124.4(11) . . ?
Cd1 O4 Eu1 116.3(5) . . ?
C12 O5 Cd2 115.4(10) . . ?
C12 O5 Eu1 118.4(11) . . ?
Cd2 O5 Eu1 114.0(5) . . ?
C16 O6 C20 121(4) . . ?
C17 O7 C21 114(4) . . ?
C18 O8 C22 111(4) . . ?
C25 O9 Eu1 136.1(18) . . ?
C38 O10 Eu1 129.5(14) . . ?
C38 O10 Cd2 122.4(12) . . ?
Eu1 O10 Cd2 105.8(4) . . ?
C36 O11 Cd1 114.0(15) . . ?
C36 O11 Eu1 124.7(14) . . ?
Cd1 O11 Eu1 108.9(6) . . ?
C36 O12 Eu2 145.3(15) . . ?
Eu1 O13 Eu1 111.3(4) . 3_655 ?
Eu1 O13 Eu2 105.0(4) . . ?
Eu1 O13 Eu2 107.1(4) 3_655 . ?
Eu1 O13 H13B 111.1 . . ?
Eu1 O13 H13B 111.1 3_655 . ?
Eu2 O13 H13B 111.1 . . ?
Eu2 O14 Eu1 108.8(5) 3_655 . ?
Eu2 O14 Eu2 109.5(4) 3_655 . ?
Eu1 O14 Eu2 104.7(4) . . ?
Eu2 O14 H14A 111.2 3_655 . ?
Eu1 O14 H14A 111.2 . . ?
Eu2 O14 H14A 111.2 . . ?
C34 O15 Eu2 131(3) . . ?
C28 O16 Eu2 141(2) . . ?
C39 O17 Eu2 127(2) . . ?
C30 O18 Eu2 149(2) . . ?
C30 O18 H18A 109.5 . . ?
Eu2 O18 H18A 92.2 . . ?
C40 O19 Eu1 155.2(18) . . ?
C40 O19 H19B 109.5 . . ?
Eu1 O19 H19B 88.1 . . ?
O1 C1 H1A 109.5 . . ?
O1 C1 H1B 109.5 . . ?
H1A C1 H1B 109.5 . . ?
O1 C1 H1C 109.5 . . ?
H1A C1 H1C 109.5 . . ?
H1B C1 H1C 109.5 . . ?
C7 C2 C3 116(2) . . ?
C7 C2 O1 117(2) . . ?
C3 C2 O1 126(2) . . ?
C2 C3 C4 120(2) . . ?
C2 C3 H3A 120.2 . . ?
C4 C3 H3A 120.2 . . ?
C5 C4 C3 125(3) . . ?
C5 C4 C10 121(2) . . ?
C3 C4 C10 115(2) . . ?
C4 C5 C6 121(3) . . ?
C4 C5 H5A 119.6 . . ?
C6 C5 H5A 119.6 . . ?
O3 C6 C5 132(3) . . ?
O3 C6 C7 116(3) . . ?
C5 C6 C7 110(3) . . ?
C2 C7 C6 129(3) . . ?
C2 C7 O2 116(2) . . ?
C6 C7 O2 115(3) . . ?
O2 C8 H8A 109.5 . . ?
O2 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
O2 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
O3 C9 H9A 109.5 . . ?
O3 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
O3 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
N1 C10 C4 122.2(19) . . ?
N1 C10 H10A 118.9 . . ?
C4 C10 H10A 118.9 . . ?
O4 C11 N2 126.9(16) . . ?
O4 C11 C12 114.3(16) . . ?
N2 C11 C12 118.7(15) . . ?
O5 C12 N3 125.6(15) . . ?
O5 C12 C11 118.1(16) . . ?
N3 C12 C11 116.0(15) . . ?
N4 C13 C14 132(3) . . ?
N4 C13 H13A 114.2 . . ?
C14 C13 H13A 114.2 . . ?
C13 C14 C19 127(3) . . ?
C13 C14 C15 114(3) . . ?
C19 C14 C15 118(3) . . ?
C16 C15 C14 113(3) . . ?
C16 C15 H15A 123.5 . . ?
C14 C15 H15A 123.5 . . ?
C15 C16 C17 122(4) . . ?
C15 C16 O6 121(4) . . ?
C17 C16 O6 115(4) . . ?
C18 C17 O7 113(4) . . ?
C18 C17 C16 123(5) . . ?
O7 C17 C16 122(4) . . ?
C17 C18 O8 119(4) . . ?
C17 C18 C19 117(5) . . ?
O8 C18 C19 124(4) . . ?
C14 C19 C18 123(4) . . ?
C14 C19 H19A 118.4 . . ?
C18 C19 H19A 118.4 . . ?
O6 C20 H20A 109.5 . . ?
O6 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
O6 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
O7 C21 H21A 109.5 . . ?
O7 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
O7 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
O8 C22 H22A 109.5 . . ?
O8 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
O8 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N5 C23 H23A 109.5 . . ?
N5 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
N5 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
N5 C24 H24A 109.5 . . ?
N5 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
N5 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
O9 C25 N5 127(3) . . ?
O9 C25 H25A 113.2 . . ?
N5 C25 H25A 119.0 . . ?
N6 C26 H26A 109.5 . . ?
N6 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
N6 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
N6 C27 H27A 109.5 . . ?
N6 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
N6 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
N6 C28 O16 130(4) . . ?
N6 C28 H28A 115.2 . . ?
O16 C28 H28A 115.2 . . ?
C30 C29 H29A 109.5 . . ?
C30 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C30 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C29 C30 O18 95(3) . . ?
C29 C30 H30A 112.8 . . ?
O18 C30 H30A 112.8 . . ?
C29 C30 H30B 112.8 . . ?
O18 C30 H30B 112.8 . . ?
H30A C30 H30B 110.2 . . ?
N7 C31 H31A 109.5 . . ?
N7 C31 H31B 109.5 . . ?
H31A C31 H31B 109.5 . . ?
N7 C31 H31C 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
N7 C32 H32A 109.5 . . ?
N7 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
N7 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C34 C33 H33A 109.5 . . ?
C34 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C34 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
O15 C34 O15 140(5) . 3_655 ?
O15 C34 C33 110(3) . . ?
O15 C34 C33 110(3) 3_655 . ?
C36 C35 H35A 109.5 . . ?
C36 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C36 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
O11 C36 O12 116(2) . . ?
O11 C36 C35 123(2) . . ?
O12 C36 C35 121(2) . . ?
C38 C37 H37A 109.5 . . ?
C38 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
C38 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
O10 C38 O10 127(3) 3_655 . ?
O10 C38 C37 116.7(14) 3_655 . ?
O10 C38 C37 116.7(14) . . ?
O17 C39 N7 100(3) . . ?
O17 C39 H39A 130.0 . . ?
N7 C39 H39A 130.0 . . ?
O19 C40 C41 127(3) . . ?
O19 C40 H40A 105.5 . . ?
C41 C40 H40A 105.5 . . ?
O19 C40 H40B 105.5 . . ?
C41 C40 H40B 105.5 . . ?
H40A C40 H40B 106.1 . . ?
C40 C41 H41A 109.5 . . ?
C40 C41 H41B 109.5 . . ?
H41A C41 H41B 109.5 . . ?
C40 C41 H41C 109.5 . . ?
H41A C41 H41C 109.5 . . ?
H41B C41 H41C 109.5 . . ?

_diffrn_measured_fraction_theta_max 0.989
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.989
_refine_diff_density_max         2.108
_refine_diff_density_min         -1.210
_refine_diff_density_rms         0.225
_exptl_crystal_recrystallization_method 'Vapour deposition'
_chemical_properties_physical    Heat-sensitive
_exptl_crystal_preparation       Luminescent
