# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_ET_ag_c
_database_code_depnum_ccdc_archive 'CCDC 2465037'
loop_
_audit_author_name
_audit_author_address
'Emma J. Jordan'
;University of Birmingham
United Kingdom
;
_audit_update_record             
;
2025-06-17 deposited with the CCDC.	2026-03-25 downloaded from the CCDC.
;
_audit_creation_date             2023-03-21
_audit_creation_method           
;
Olex2 1.5
(compiled 2023.03.06 svn.rbb2c1857 for OlexSys, GUI svn.r6748)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C30 H50 Au2 N4 O2 P2, 2(F6 Sb)'
_chemical_formula_sum            'C30 H50 Au2 F12 N4 O2 P2 Sb2'
_chemical_formula_weight         1426.11
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C11 H10 N O'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.0562 5.8946 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.4548(6)
_cell_length_b                   12.6126(5)
_cell_length_c                   14.7731(6)
_cell_angle_alpha                90
_cell_angle_beta                 112.161(5)
_cell_angle_gamma                90
_cell_volume                     2149.23(17)
_cell_formula_units_Z            2
_cell_measurement_reflns_used    6002
_cell_measurement_temperature    99.97(12)
_cell_measurement_theta_max      73.0130
_cell_measurement_theta_min      4.6800
_shelx_estimated_absorpt_T_max   0.456
_shelx_estimated_absorpt_T_min   0.159
_exptl_absorpt_coefficient_mu    23.875
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.918
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.73a (Rigaku Oxford Diffraction, 2022)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            'dark orange'
_exptl_crystal_colour_modifier   dark
_exptl_crystal_colour_primary    orange
_exptl_crystal_density_diffrn    2.204
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1344
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
3 1 -10 0.0469
2 -8 -3 0.0306
-2 -4 8 0.0590
-3 6 6 0.0545
0 7 -5 0.0535
7 1 2 0.0100
-5 0 -5 0.0309
-7 -2 0 0.0263
2 3 -9 0.0447
-8 1 2 0.0377

_exptl_crystal_size_max          0.122
_exptl_crystal_size_mid          0.095
_exptl_crystal_size_min          0.039
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
2.5989 0.8153 -9.5288 0.3499 -0.2155 -0.9117
1.9322 -7.7964 -2.5528 0.8240 -0.5039 0.2590
-1.7167 -4.1061 8.2182 0.0083 -0.0036 1.0000
-2.6707 6.4064 5.8854 -0.8457 0.5177 0.1292
0.3845 6.8406 -5.0335 -0.3992 0.2430 -0.8841
6.7872 1.3406 1.5575 0.4236 0.8891 0.1734
-5.1316 0.4304 -4.5474 -0.3631 -0.7610 -0.5377
-7.2813 -2.2879 0.3122 -0.4293 -0.9016 0.0533
2.1683 3.0669 -8.8548 0.1238 -0.0604 -0.9905
-7.9081 0.8375 1.9383 -0.7600 -0.6499 0.0089

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0511
_diffrn_reflns_av_unetI/netI     0.0485
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.976
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            12151
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.976
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         73.106
_diffrn_reflns_theta_min         3.832
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      99.97(12)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.3537
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -112.00 -15.00   1.00    1.68    --  -41.69 -57.00-120.00   97
  2  ω    -64.00  31.00   1.00    1.68    --  -41.69  38.00  60.00   95
  3  ω      6.00  81.00   1.00    1.68    --   41.69 -99.00 -90.00   75
  4  ω     27.00  95.00   1.00    1.68    --   41.69-125.00-180.00   68
  5  ω     33.00 112.00   1.00    6.71    --  102.88-125.00  60.00   79
  6  ω     33.00 130.00   1.00    6.71    --  102.88 -61.00  90.00   97
  7  ω     97.00 172.00   1.00    6.71    --  102.88 125.00-150.00   75
  8  ω     79.00 178.00   1.00    6.71    --  102.88  30.00-180.00   99
  9  ω    103.00 177.00   1.00    6.71    --  102.88  77.00-180.00   74
 10  ω     97.00 172.00   1.00    6.71    --  102.88 125.00-120.00   75
 11  ω     33.00 130.00   1.00    6.71    --  102.88 -61.00-120.00   97
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0826860000
_diffrn_orient_matrix_UB_12      -0.0783643000
_diffrn_orient_matrix_UB_13      -0.0208765000
_diffrn_orient_matrix_UB_21      0.1037510000
_diffrn_orient_matrix_UB_22      0.0716640000
_diffrn_orient_matrix_UB_23      0.0570433000
_diffrn_orient_matrix_UB_31      0.0157126000
_diffrn_orient_matrix_UB_32      -0.0603721000
_diffrn_orient_matrix_UB_33      0.0947941000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3586
_reflns_number_total             4194
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.73a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.73a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.73a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         2.253
_refine_diff_density_min         -1.469
_refine_diff_density_rms         0.203
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     251
_refine_ls_number_reflns         4194
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0438
_refine_ls_R_factor_gt           0.0356
_refine_ls_restrained_S_all      1.042
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0538P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0897
_refine_ls_wR_factor_ref         0.0958
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C10(H10), C11(H11), C13(H13), C14(H14)
2.b Idealised Me refined as rotating group:
 C2(H2A,H2B,H2C), C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C6(H6A,H6B,H6C), C7(H7A,
 H7B,H7C), C8(H8A,H8B,H8C), C15(H15A,H15B,H15C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.04859(2) 0.55387(2) 0.44274(2) 0.01736(10) Uani 1 1 d . . . . .
C1 C 0.1708(6) 0.2707(5) 0.6528(5) 0.0250(13) Uani 1 1 d . . . . .
C2 C 0.1473(6) 0.2485(6) 0.5450(5) 0.0305(15) Uani 1 1 d . . . . .
H2A H 0.069749 0.274132 0.504392 0.046 Uiso 1 1 calc R U . . .
H2B H 0.151979 0.172083 0.535217 0.046 Uiso 1 1 calc R U . . .
H2C H 0.205288 0.285272 0.526408 0.046 Uiso 1 1 calc R U . . .
C3 C 0.2934(7) 0.2431(6) 0.7177(5) 0.0376(18) Uani 1 1 d . . . . .
H3A H 0.347164 0.290903 0.703616 0.056 Uiso 1 1 calc R U . . .
H3B H 0.309902 0.169717 0.705325 0.056 Uiso 1 1 calc R U . . .
H3C H 0.302889 0.250717 0.786297 0.056 Uiso 1 1 calc R U . . .
C4 C 0.0834(9) 0.2055(7) 0.6814(8) 0.046(2) Uani 1 1 d . . . . .
H4A H 0.094638 0.220704 0.749409 0.069 Uiso 1 1 calc R U . . .
H4B H 0.095904 0.129730 0.674305 0.069 Uiso 1 1 calc R U . . .
H4C H 0.004251 0.224670 0.638550 0.069 Uiso 1 1 calc R U . . .
C5 C 0.1751(6) 0.4772(6) 0.7776(5) 0.0239(13) Uani 1 1 d . . . . .
C6 C 0.3030(8) 0.4653(8) 0.8421(6) 0.055(3) Uani 1 1 d . . . . .
H6A H 0.322918 0.389884 0.851471 0.082 Uiso 1 1 calc R U . . .
H6B H 0.317946 0.498601 0.905609 0.082 Uiso 1 1 calc R U . . .
H6C H 0.350276 0.499863 0.810550 0.082 Uiso 1 1 calc R U . . .
C7 C 0.0970(12) 0.4327(9) 0.8266(7) 0.066(4) Uani 1 1 d . . . . .
H7A H 0.016772 0.430414 0.779295 0.099 Uiso 1 1 calc R U . . .
H7B H 0.101399 0.478266 0.881704 0.099 Uiso 1 1 calc R U . . .
H7C H 0.122401 0.360951 0.850514 0.099 Uiso 1 1 calc R U . . .
C8 C 0.1501(7) 0.5958(6) 0.7567(6) 0.0355(17) Uani 1 1 d . . . . .
H8A H 0.191786 0.621749 0.716590 0.053 Uiso 1 1 calc R U . . .
H8B H 0.175788 0.634927 0.818518 0.053 Uiso 1 1 calc R U . . .
H8C H 0.066596 0.606339 0.721579 0.053 Uiso 1 1 calc R U . . .
C9 C 0.3130(5) 0.5647(5) 0.5267(5) 0.0187(12) Uani 1 1 d . . . . .
C10 C 0.4294(6) 0.5513(5) 0.5915(4) 0.0183(12) Uani 1 1 d . . . . .
H10 H 0.446949 0.504300 0.645494 0.022 Uiso 1 1 calc R U . . .
C11 C 0.5167(5) 0.6051(5) 0.5773(4) 0.0182(12) Uani 1 1 d . . . . .
H11 H 0.595022 0.593902 0.619673 0.022 Uiso 1 1 calc R U . . .
C12 C 0.4898(6) 0.6773(5) 0.4993(5) 0.0224(13) Uani 1 1 d . . . . .
C13 C 0.3768(6) 0.6870(5) 0.4310(5) 0.0229(13) Uani 1 1 d . . . . .
H13 H 0.359772 0.731797 0.375670 0.027 Uiso 1 1 calc R U . . .
C14 C 0.2901(5) 0.6297(5) 0.4458(5) 0.0228(13) Uani 1 1 d . . . . .
H14 H 0.212859 0.635073 0.399306 0.027 Uiso 1 1 calc R U . . .
C15 C 0.5507(6) 0.8249(6) 0.4307(5) 0.0280(14) Uani 1 1 d . . . . .
H15A H 0.521316 0.801242 0.362476 0.042 Uiso 1 1 calc R U . . .
H15B H 0.620568 0.867868 0.443978 0.042 Uiso 1 1 calc R U . . .
H15C H 0.491335 0.867538 0.442290 0.042 Uiso 1 1 calc R U . . .
N1 N 0.2438(4) 0.4680(4) 0.6217(4) 0.0196(10) Uani 1 1 d . . . . .
N2 N 0.2193(4) 0.5213(4) 0.5430(4) 0.0174(10) Uani 1 1 d . . . . .
O1 O 0.5785(4) 0.7337(4) 0.4946(3) 0.0247(9) Uani 1 1 d . . . . .
P1 P 0.13635(13) 0.41395(12) 0.65627(10) 0.0172(3) Uani 1 1 d . . . . .
F1 F 0.1634(4) 0.7743(4) 0.5433(4) 0.0496(13) Uani 1 1 d . . . . .
F2 F 0.3614(6) 0.9652(5) 0.7240(4) 0.0592(15) Uani 1 1 d . . . . .
F3 F 0.3493(7) 0.8862(5) 0.5552(4) 0.0637(17) Uani 1 1 d . . . . .
F4 F 0.1767(4) 0.8540(4) 0.7123(3) 0.0425(11) Uani 1 1 d . . . . .
F5 F 0.3568(4) 0.7578(4) 0.6989(3) 0.0433(11) Uani 1 1 d . . . . .
F6 F 0.1678(7) 0.9824(5) 0.5684(4) 0.072(2) Uani 1 1 d . . . . .
Sb1 Sb 0.26272(4) 0.87022(3) 0.63334(3) 0.02618(13) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Au1 2.7782(5) 3_566 ?
Au1 N2 2.123(5) . ?
Au1 P1 2.2513(15) 3_566 ?
C1 C2 1.533(9) . ?
C1 C3 1.506(10) . ?
C1 C4 1.544(10) . ?
C1 P1 1.863(7) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 C6 1.524(11) . ?
C5 C7 1.523(11) . ?
C5 C8 1.535(11) . ?
C5 P1 1.851(7) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 C10 1.414(9) . ?
C9 C14 1.388(9) . ?
C9 N2 1.389(8) . ?
C10 H10 0.9500 . ?
C10 C11 1.364(9) . ?
C11 H11 0.9500 . ?
C11 C12 1.406(9) . ?
C12 C13 1.393(10) . ?
C12 O1 1.338(8) . ?
C13 H13 0.9500 . ?
C13 C14 1.383(9) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C15 O1 1.445(8) . ?
N1 N2 1.276(7) . ?
N1 P1 1.741(5) . ?
F1 Sb1 1.876(4) . ?
F2 Sb1 1.871(5) . ?
F3 Sb1 1.864(6) . ?
F4 Sb1 1.869(5) . ?
F5 Sb1 1.862(4) . ?
F6 Sb1 1.861(5) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Au1 Au1 91.85(14) . 3_566 ?
N2 Au1 P1 176.50(14) . 3_566 ?
P1 Au1 Au1 84.83(4) 3_566 3_566 ?
C2 C1 C4 108.0(6) . . ?
C2 C1 P1 104.4(5) . . ?
C3 C1 C2 111.7(6) . . ?
C3 C1 C4 110.7(7) . . ?
C3 C1 P1 113.3(5) . . ?
C4 C1 P1 108.4(5) . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C1 C3 H3A 109.5 . . ?
C1 C3 H3B 109.5 . . ?
C1 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C1 C4 H4A 109.5 . . ?
C1 C4 H4B 109.5 . . ?
C1 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C6 C5 C8 107.8(7) . . ?
C6 C5 P1 113.1(5) . . ?
C7 C5 C6 111.8(8) . . ?
C7 C5 C8 109.7(7) . . ?
C7 C5 P1 108.8(5) . . ?
C8 C5 P1 105.4(5) . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C5 C7 H7A 109.5 . . ?
C5 C7 H7B 109.5 . . ?
C5 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C5 C8 H8A 109.5 . . ?
C5 C8 H8B 109.5 . . ?
C5 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C14 C9 C10 118.6(6) . . ?
C14 C9 N2 118.0(5) . . ?
N2 C9 C10 123.3(6) . . ?
C9 C10 H10 119.7 . . ?
C11 C10 C9 120.6(6) . . ?
C11 C10 H10 119.7 . . ?
C10 C11 H11 120.3 . . ?
C10 C11 C12 119.4(6) . . ?
C12 C11 H11 120.3 . . ?
C13 C12 C11 120.9(6) . . ?
O1 C12 C11 116.2(6) . . ?
O1 C12 C13 122.9(6) . . ?
C12 C13 H13 120.8 . . ?
C14 C13 C12 118.4(6) . . ?
C14 C13 H13 120.8 . . ?
C9 C14 H14 119.2 . . ?
C13 C14 C9 121.7(6) . . ?
C13 C14 H14 119.2 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
O1 C15 H15A 109.5 . . ?
O1 C15 H15B 109.5 . . ?
O1 C15 H15C 109.5 . . ?
N2 N1 P1 121.8(4) . . ?
C9 N2 Au1 119.2(4) . . ?
N1 N2 Au1 124.7(4) . . ?
N1 N2 C9 116.0(5) . . ?
C12 O1 C15 117.3(5) . . ?
C1 P1 Au1 110.3(2) . 3_566 ?
C5 P1 Au1 112.4(2) . 3_566 ?
C5 P1 C1 117.8(3) . . ?
N1 P1 Au1 116.74(18) . 3_566 ?
N1 P1 C1 99.3(3) . . ?
N1 P1 C5 99.6(3) . . ?
F2 Sb1 F1 179.5(3) . . ?
F3 Sb1 F1 90.7(3) . . ?
F3 Sb1 F2 89.8(3) . . ?
F3 Sb1 F4 179.7(3) . . ?
F4 Sb1 F1 89.5(2) . . ?
F4 Sb1 F2 90.0(3) . . ?
F5 Sb1 F1 89.7(2) . . ?
F5 Sb1 F2 90.0(3) . . ?
F5 Sb1 F3 90.4(3) . . ?
F5 Sb1 F4 89.3(2) . . ?
F6 Sb1 F1 90.2(3) . . ?
F6 Sb1 F2 90.0(3) . . ?
F6 Sb1 F3 90.1(3) . . ?
F6 Sb1 F4 90.1(3) . . ?
F6 Sb1 F5 179.5(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 C1 P1 Au1 58.4(5) . . . 3_566 ?
C2 C1 P1 C5 -170.8(4) . . . . ?
C2 C1 P1 N1 -64.7(5) . . . . ?
C3 C1 P1 Au1 -179.9(5) . . . 3_566 ?
C3 C1 P1 C5 -49.1(6) . . . . ?
C3 C1 P1 N1 57.0(6) . . . . ?
C4 C1 P1 Au1 -56.6(6) . . . 3_566 ?
C4 C1 P1 C5 74.2(6) . . . . ?
C4 C1 P1 N1 -179.7(5) . . . . ?
C6 C5 P1 Au1 -174.4(6) . . . 3_566 ?
C6 C5 P1 C1 55.8(7) . . . . ?
C6 C5 P1 N1 -50.2(7) . . . . ?
C7 C5 P1 Au1 60.7(7) . . . 3_566 ?
C7 C5 P1 C1 -69.1(8) . . . . ?
C7 C5 P1 N1 -175.0(7) . . . . ?
C8 C5 P1 Au1 -56.8(5) . . . 3_566 ?
C8 C5 P1 C1 173.4(4) . . . . ?
C8 C5 P1 N1 67.4(5) . . . . ?
C9 C10 C11 C12 2.2(9) . . . . ?
C10 C9 C14 C13 -4.6(10) . . . . ?
C10 C9 N2 Au1 177.2(4) . . . . ?
C10 C9 N2 N1 0.6(9) . . . . ?
C10 C11 C12 C13 -6.3(9) . . . . ?
C10 C11 C12 O1 174.6(5) . . . . ?
C11 C12 C13 C14 4.8(10) . . . . ?
C11 C12 O1 C15 -165.7(6) . . . . ?
C12 C13 C14 C9 0.7(10) . . . . ?
C13 C12 O1 C15 15.2(9) . . . . ?
C14 C9 C10 C11 3.1(9) . . . . ?
C14 C9 N2 Au1 1.3(8) . . . . ?
C14 C9 N2 N1 -175.4(6) . . . . ?
N2 C9 C10 C11 -172.8(6) . . . . ?
N2 C9 C14 C13 171.5(6) . . . . ?
N2 N1 P1 Au1 -1.5(6) . . . 3_566 ?
N2 N1 P1 C1 116.9(5) . . . . ?
N2 N1 P1 C5 -122.7(5) . . . . ?
O1 C12 C13 C14 -176.2(6) . . . . ?
P1 N1 N2 Au1 0.3(7) . . . . ?
P1 N1 N2 C9 176.7(4) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.483
_oxdiff_exptl_absorpt_empirical_full_min 0.596
####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_et16
_database_code_depnum_ccdc_archive 'CCDC 2465038'
loop_
_audit_author_name
_audit_author_address
'Emma J. Jordan'
;University of Birmingham
United Kingdom
;
_audit_update_record             
;
2025-06-17 deposited with the CCDC.	2026-03-25 downloaded from the CCDC.
;
_audit_creation_date             2023-02-27
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C15 H25 Au Cl N2 O P'
_chemical_formula_sum            'C15 H25 Au Cl N2 O P'
_chemical_formula_weight         512.76
_chemical_melting_point          ?
_chemical_oxdiff_formula         'C30 H50 Au2 Cl2 N4 O2 P2'
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -4.4197 7.2980 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_H-M_alt        'P 1 21/c 1'
_space_group_name_Hall           '-P 2ybc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   12.2138(3)
_cell_length_b                   11.6076(3)
_cell_length_c                   14.2495(4)
_cell_angle_alpha                90
_cell_angle_beta                 114.331(3)
_cell_angle_gamma                90
_cell_volume                     1840.76(9)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    16238
_cell_measurement_temperature    99.95(15)
_cell_measurement_theta_max      72.6280
_cell_measurement_theta_min      3.9470
_shelx_estimated_absorpt_T_max   0.379
_shelx_estimated_absorpt_T_min   0.214
_exptl_absorpt_coefficient_mu    17.174
_exptl_absorpt_correction_T_max  0.458
_exptl_absorpt_correction_T_min  0.226
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.42.73a (Rigaku Oxford Diffraction, 2022)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.850
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             992
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-6 5 1 0.0447
8 -2 -3 0.0223
6 5 -4 0.0478
-6 -5 4 0.0478
-2 4 8 0.0518
2 -4 -8 0.0586
-3 7 0 0.0464
-2 5 -5 0.0535
1 -4 6 0.0410
2 -7 2 0.0312
3 -7 -3 0.0355
5 5 1 0.0421
-5 -5 -1 0.0518
-6 2 -2 0.0441
8 1 -4 0.0270

_exptl_crystal_size_max          0.129
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.075
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-5.7320 4.9088 0.7750 0.2453 0.3989 0.8836
7.5329 -2.1912 -2.6112 -0.4199 -0.6849 -0.5955
6.0710 4.6256 -4.4942 -0.4848 -0.7930 0.3689
-6.0710 -4.6256 4.4942 0.4848 0.7930 -0.3689
-1.7207 4.2135 7.5702 -0.7505 0.5756 0.3247
1.7024 -4.1628 -7.6058 0.7527 -0.5774 -0.3163
-2.6142 6.9918 -0.2423 -0.1045 0.0816 0.9912
-1.7709 4.9884 -5.1802 0.3716 -0.2834 0.8841
1.4125 -4.0849 6.2418 -0.4825 0.3685 -0.7946
2.4458 -6.6252 1.8968 -0.0495 0.0364 -0.9981
2.6245 -6.8317 -3.4854 0.4337 -0.3337 -0.8370
5.2009 4.7964 0.9112 -0.8963 -0.3715 0.2420
-5.3679 -4.5351 -0.9830 0.9053 0.3754 -0.1988
-6.1445 2.0480 -1.8672 0.6917 0.2880 0.6623
7.8998 0.6424 -3.8432 -0.5072 -0.8295 -0.2338

_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0448
_diffrn_reflns_av_unetI/netI     0.0208
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            33476
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         72.754
_diffrn_reflns_theta_min         3.972
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      99.95(15)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.3537
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω   -121.00   0.00   1.00    1.00    --  -41.27 -19.00 120.00  121
  2  ω    -87.00  -6.00   1.00    1.00    --  -41.27 125.00 -90.00   81
  3  ω     17.00 116.00   1.00    1.00    --   41.27  38.00 -60.00   99
  4  ω     13.00 114.00   1.00    1.00    --   41.27  57.00-150.00  101
  5  ω     17.00 116.00   1.00    1.00    --   41.27  38.00 -90.00   99
  6  ω    -21.00  74.00   1.00    1.00    --   41.27 -77.00  90.00   95
  7  ω     27.00  95.00   1.00    1.00    --   41.27-125.00 120.00   68
  8  ω      8.00  42.00   1.00    1.00    --   41.27  80.00-124.09   34
  9  ω     72.00 176.00   1.00    2.00    --  102.80  69.00 131.67  104
 10  ω    104.00 176.00   1.00    2.00    --  102.80 111.00-150.00   72
 11  ω    104.00 176.00   1.00    2.00    --  102.80 111.00 -60.00   72
 12  ω    103.00 178.00   1.00    2.00    --  102.80  77.00   0.00   75
 13  ω     74.00 175.00   1.00    2.00    --  102.80  61.00-180.00  101
 14  ω     73.00 175.00   1.00    2.00    --  102.80  63.00-161.02  102
 15  ω     75.00 176.00   1.00    2.00    --  102.80  57.00 167.57  101
 16  ω     73.00 175.00   1.00    2.00    --  102.80  64.00-112.40  102
 17  ω     29.00 108.00   1.00    2.00    --  102.80-111.00   0.00   79
 18  ω     72.00 176.00   1.00    2.00    --  102.80  70.00 164.27  104
 19  ω     74.00 175.00   1.00    2.00    --  102.80  61.00-150.00  101
 20  ω     31.00 132.00   1.00    2.00    --  102.80 -61.00-180.00  101
 21  ω     77.00 176.00   1.00    2.00    --  102.80  45.00-110.57   99
 22  ω     74.00 175.00   1.00    2.00    --  102.80  61.00-120.00  101
 23  ω     77.00 176.00   1.00    2.00    --  102.80  45.00 150.00   99
 24  ω     74.00 175.00   1.00    2.00    --  102.80  61.00 150.00  101
 25  ω     77.00 176.00   1.00    2.00    --  102.80  45.00-120.00   99
 26  ω     77.00 176.00   1.00    2.00    --  102.80  45.00-150.00   99
 27  ω    103.00 178.00   1.00    2.00    --  102.80  77.00 -90.00   75
 28  ω    104.00 176.00   1.00    2.00    --  102.80 111.00 120.00   72
 29  ω     72.00 176.00   1.00    2.00    --  102.80  68.00 176.96  104
 30  ω     72.00 177.00   1.00    2.00    --  102.80  71.00 121.91  105
 31  ω   -113.00 -48.00   1.00    1.00    --  -41.27 -57.00  30.00   65
 32  ω      6.00  32.00   1.00    1.00    --   41.27  85.00  33.88   26
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.1038746000
_diffrn_orient_matrix_UB_12      -0.0569392000
_diffrn_orient_matrix_UB_13      -0.0910558000
_diffrn_orient_matrix_UB_21      -0.0714304000
_diffrn_orient_matrix_UB_22      -0.0127148000
_diffrn_orient_matrix_UB_23      0.0668813000
_diffrn_orient_matrix_UB_31      -0.0570037000
_diffrn_orient_matrix_UB_32      0.1191867000
_diffrn_orient_matrix_UB_33      -0.0364062000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3210
_reflns_number_total             3631
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'CrysAlisPro 1.171.42.73a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.73a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.73a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max         0.856
_refine_diff_density_min         -1.160
_refine_diff_density_rms         0.111
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     197
_refine_ls_number_reflns         3631
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0293
_refine_ls_R_factor_gt           0.0227
_refine_ls_restrained_S_all      1.059
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0274P)²+3.5729P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0519
_refine_ls_wR_factor_ref         0.0559
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C10(H10), C11(H11), C13(H13), C14(H14)
2.b Idealised Me refined as rotating group:
 C2(H2A,H2B,H2C), C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C6(H6A,H6B,H6C), C7(H7A,
 H7B,H7C), C8(H8A,H8B,H8C), C15(H15A,H15B,H15C)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.73077(2) 0.18573(2) 0.40227(2) 0.01971(6) Uani 1 1 d . . . . .
C1 C 0.4965(3) 0.3766(3) 0.3115(3) 0.0209(7) Uani 1 1 d . . . . .
C2 C 0.4839(4) 0.3222(4) 0.4048(3) 0.0255(8) Uani 1 1 d . . . . .
H2A H 0.501899 0.239656 0.407418 0.038 Uiso 1 1 calc R U . . .
H2B H 0.401488 0.332849 0.398416 0.038 Uiso 1 1 calc R U . . .
H2C H 0.540102 0.359292 0.468083 0.038 Uiso 1 1 calc R U . . .
C3 C 0.4597(3) 0.5038(3) 0.3056(3) 0.0260(8) Uani 1 1 d . . . . .
H3A H 0.512072 0.543186 0.369101 0.039 Uiso 1 1 calc R U . . .
H3B H 0.376122 0.509003 0.297344 0.039 Uiso 1 1 calc R U . . .
H3C H 0.467366 0.540320 0.246596 0.039 Uiso 1 1 calc R U . . .
C4 C 0.4153(3) 0.3132(4) 0.2125(3) 0.0257(8) Uani 1 1 d . . . . .
H4A H 0.414494 0.355116 0.152497 0.039 Uiso 1 1 calc R U . . .
H4B H 0.333488 0.308793 0.208664 0.039 Uiso 1 1 calc R U . . .
H4C H 0.446289 0.235122 0.213141 0.039 Uiso 1 1 calc R U . . .
C5 C 0.6948(4) 0.3971(4) 0.2259(3) 0.0240(8) Uani 1 1 d . . . . .
C6 C 0.8325(4) 0.4068(4) 0.2718(4) 0.0313(9) Uani 1 1 d . . . . .
H6A H 0.858315 0.471030 0.320705 0.047 Uiso 1 1 calc R U . . .
H6B H 0.858827 0.420403 0.216424 0.047 Uiso 1 1 calc R U . . .
H6C H 0.868149 0.335000 0.307581 0.047 Uiso 1 1 calc R U . . .
C7 C 0.6571(4) 0.2977(4) 0.1476(3) 0.0299(9) Uani 1 1 d . . . . .
H7A H 0.688948 0.225010 0.183335 0.045 Uiso 1 1 calc R U . . .
H7B H 0.689015 0.311273 0.095750 0.045 Uiso 1 1 calc R U . . .
H7C H 0.569183 0.293613 0.113823 0.045 Uiso 1 1 calc R U . . .
C8 C 0.6386(4) 0.5099(4) 0.1730(3) 0.0298(9) Uani 1 1 d . . . . .
H8A H 0.551044 0.501465 0.139417 0.045 Uiso 1 1 calc R U . . .
H8B H 0.669173 0.529068 0.121170 0.045 Uiso 1 1 calc R U . . .
H8C H 0.659474 0.571692 0.224282 0.045 Uiso 1 1 calc R U . . .
C9 C 0.8083(3) 0.5401(3) 0.5820(3) 0.0211(7) Uani 1 1 d . . . . .
C10 C 0.8004(3) 0.6552(3) 0.5528(3) 0.0214(8) Uani 1 1 d . . . . .
H10 H 0.768092 0.675656 0.481985 0.026 Uiso 1 1 calc R U . . .
C11 C 0.8399(3) 0.7394(4) 0.6276(3) 0.0243(8) Uani 1 1 d . . . . .
H11 H 0.835142 0.818191 0.608187 0.029 Uiso 1 1 calc R U . . .
C12 C 0.8871(3) 0.7093(3) 0.7319(3) 0.0231(8) Uani 1 1 d . . . . .
C13 C 0.8968(3) 0.5941(4) 0.7622(3) 0.0230(8) Uani 1 1 d . . . . .
H13 H 0.929432 0.573435 0.832986 0.028 Uiso 1 1 calc R U . . .
C14 C 0.8572(3) 0.5104(4) 0.6858(3) 0.0233(8) Uani 1 1 d . . . . .
H14 H 0.863730 0.431401 0.704749 0.028 Uiso 1 1 calc R U . . .
C15 C 0.9723(4) 0.7730(4) 0.9066(3) 0.0330(9) Uani 1 1 d . . . . .
H15A H 1.046560 0.729064 0.923897 0.050 Uiso 1 1 calc R U . . .
H15B H 0.915443 0.727458 0.923690 0.050 Uiso 1 1 calc R U . . .
H15C H 0.990304 0.845058 0.945918 0.050 Uiso 1 1 calc R U . . .
Cl1 Cl 0.80873(9) 0.01161(8) 0.47628(7) 0.0283(2) Uani 1 1 d . . . . .
N1 N 0.7221(3) 0.4723(3) 0.4176(2) 0.0212(7) Uani 1 1 d . . . . .
N2 N 0.7653(3) 0.4458(3) 0.5118(2) 0.0228(7) Uani 1 1 d . . . . .
O1 O 0.9203(3) 0.7986(3) 0.7987(2) 0.0289(6) Uani 1 1 d . . . . .
P1 P 0.65789(8) 0.35800(8) 0.33557(7) 0.01862(18) Uani 1 1 d . . . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Cl1 2.2970(9) . ?
Au1 P1 2.2354(10) . ?
C1 C2 1.537(5) . ?
C1 C3 1.536(5) . ?
C1 C4 1.537(5) . ?
C1 P1 1.868(4) . ?
C2 H2A 0.9800 . ?
C2 H2B 0.9800 . ?
C2 H2C 0.9800 . ?
C3 H3A 0.9800 . ?
C3 H3B 0.9800 . ?
C3 H3C 0.9800 . ?
C4 H4A 0.9800 . ?
C4 H4B 0.9800 . ?
C4 H4C 0.9800 . ?
C5 C6 1.537(5) . ?
C5 C7 1.537(6) . ?
C5 C8 1.526(6) . ?
C5 P1 1.853(4) . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 C10 1.391(6) . ?
C9 C14 1.391(5) . ?
C9 N2 1.428(5) . ?
C10 H10 0.9500 . ?
C10 C11 1.378(6) . ?
C11 H11 0.9500 . ?
C11 C12 1.400(6) . ?
C12 C13 1.395(6) . ?
C12 O1 1.351(5) . ?
C13 H13 0.9500 . ?
C13 C14 1.389(6) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C15 O1 1.431(5) . ?
N1 N2 1.261(4) . ?
N1 P1 1.728(3) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Cl1 178.03(3) . . ?
C2 C1 C4 109.9(3) . . ?
C2 C1 P1 105.6(2) . . ?
C3 C1 C2 108.1(3) . . ?
C3 C1 C4 110.3(3) . . ?
C3 C1 P1 112.6(3) . . ?
C4 C1 P1 110.3(3) . . ?
C1 C2 H2A 109.5 . . ?
C1 C2 H2B 109.5 . . ?
C1 C2 H2C 109.5 . . ?
H2A C2 H2B 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
C1 C3 H3A 109.5 . . ?
C1 C3 H3B 109.5 . . ?
C1 C3 H3C 109.5 . . ?
H3A C3 H3B 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C1 C4 H4A 109.5 . . ?
C1 C4 H4B 109.5 . . ?
C1 C4 H4C 109.5 . . ?
H4A C4 H4B 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C6 C5 C7 108.2(3) . . ?
C6 C5 P1 105.2(3) . . ?
C7 C5 P1 108.9(3) . . ?
C8 C5 C6 109.8(3) . . ?
C8 C5 C7 110.2(3) . . ?
C8 C5 P1 114.3(3) . . ?
C5 C6 H6A 109.5 . . ?
C5 C6 H6B 109.5 . . ?
C5 C6 H6C 109.5 . . ?
H6A C6 H6B 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C5 C7 H7A 109.5 . . ?
C5 C7 H7B 109.5 . . ?
C5 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C5 C8 H8A 109.5 . . ?
C5 C8 H8B 109.5 . . ?
C5 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C10 C9 N2 124.5(3) . . ?
C14 C9 C10 120.1(4) . . ?
C14 C9 N2 115.3(4) . . ?
C9 C10 H10 120.3 . . ?
C11 C10 C9 119.4(4) . . ?
C11 C10 H10 120.3 . . ?
C10 C11 H11 119.9 . . ?
C10 C11 C12 120.3(4) . . ?
C12 C11 H11 119.9 . . ?
C13 C12 C11 120.9(4) . . ?
O1 C12 C11 115.4(4) . . ?
O1 C12 C13 123.7(4) . . ?
C12 C13 H13 121.0 . . ?
C14 C13 C12 118.0(4) . . ?
C14 C13 H13 121.0 . . ?
C9 C14 H14 119.4 . . ?
C13 C14 C9 121.3(4) . . ?
C13 C14 H14 119.4 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
O1 C15 H15A 109.5 . . ?
O1 C15 H15B 109.5 . . ?
O1 C15 H15C 109.5 . . ?
N2 N1 P1 114.1(3) . . ?
N1 N2 C9 115.5(3) . . ?
C12 O1 C15 118.0(3) . . ?
C1 P1 Au1 112.74(13) . . ?
C5 P1 Au1 112.66(13) . . ?
C5 P1 C1 114.92(18) . . ?
N1 P1 Au1 114.12(11) . . ?
N1 P1 C1 100.73(17) . . ?
N1 P1 C5 100.51(17) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C2 C1 P1 Au1 40.6(3) . . . . ?
C2 C1 P1 C5 171.5(3) . . . . ?
C2 C1 P1 N1 -81.5(3) . . . . ?
C3 C1 P1 Au1 158.3(2) . . . . ?
C3 C1 P1 C5 -70.8(3) . . . . ?
C3 C1 P1 N1 36.2(3) . . . . ?
C4 C1 P1 Au1 -78.1(3) . . . . ?
C4 C1 P1 C5 52.9(3) . . . . ?
C4 C1 P1 N1 159.9(3) . . . . ?
C6 C5 P1 Au1 -63.9(3) . . . . ?
C6 C5 P1 C1 165.1(3) . . . . ?
C6 C5 P1 N1 57.9(3) . . . . ?
C7 C5 P1 Au1 51.8(3) . . . . ?
C7 C5 P1 C1 -79.2(3) . . . . ?
C7 C5 P1 N1 173.7(3) . . . . ?
C8 C5 P1 Au1 175.6(3) . . . . ?
C8 C5 P1 C1 44.6(4) . . . . ?
C8 C5 P1 N1 -62.6(3) . . . . ?
C9 C10 C11 C12 -0.3(6) . . . . ?
C10 C9 C14 C13 1.3(6) . . . . ?
C10 C9 N2 N1 2.9(5) . . . . ?
C10 C11 C12 C13 1.0(6) . . . . ?
C10 C11 C12 O1 -178.3(3) . . . . ?
C11 C12 C13 C14 -0.6(5) . . . . ?
C11 C12 O1 C15 -178.3(4) . . . . ?
C12 C13 C14 C9 -0.6(5) . . . . ?
C13 C12 O1 C15 2.3(5) . . . . ?
C14 C9 C10 C11 -0.9(6) . . . . ?
C14 C9 N2 N1 -179.2(3) . . . . ?
N2 C9 C10 C11 176.9(3) . . . . ?
N2 C9 C14 C13 -176.7(3) . . . . ?
N2 N1 P1 Au1 -25.0(3) . . . . ?
N2 N1 P1 C1 96.1(3) . . . . ?
N2 N1 P1 C5 -145.8(3) . . . . ?
O1 C12 C13 C14 178.7(3) . . . . ?
P1 N1 N2 C9 -174.0(2) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.262
_oxdiff_exptl_absorpt_empirical_full_min 0.722
