# Supplementary Information (SI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_z1
_database_code_depnum_ccdc_archive 'CCDC 2523930'
loop_
_audit_author_name
_audit_author_address
'Jingfang Zhou'
;Tangshan Normal University
China
;
_audit_update_record             
;
2026-01-19 deposited with the CCDC.	2026-03-31 downloaded from the CCDC.
;
_audit_creation_date             2025-02-28
_audit_creation_method           
;
Olex2 1.3
(compiled 2020.11.12 svn.r5f609507 for OlexSys, GUI svn.r6408)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'Ga Li3 O11 Te4'
_chemical_formula_sum            'Ga Li3 O11 Te4'
_chemical_formula_weight         776.94
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   18.9217(17)
_cell_length_b                   5.1866(4)
_cell_length_c                   10.7568(9)
_cell_angle_alpha                90
_cell_angle_beta                 109.601(3)
_cell_angle_gamma                90
_cell_volume                     994.49(15)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    5234
_cell_measurement_temperature    301.0
_cell_measurement_theta_max      30.14
_cell_measurement_theta_min      2.29
_shelx_estimated_absorpt_T_max   ?
_shelx_estimated_absorpt_T_min   ?
_exptl_absorpt_coefficient_mu    14.321
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.6357
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0875 before and 0.0618 after correction.
The Ratio of minimum to maximum transmission is 0.8520.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    5.189
_exptl_crystal_density_meas      .
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1344
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0667
_diffrn_reflns_av_unetI/netI     0.0327
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -7
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            16792
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.562
_diffrn_reflns_theta_min         2.285
_diffrn_ambient_temperature      298.0
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                1401
_reflns_number_total             1515
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       ?
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.954
_refine_diff_density_min         -1.620
_refine_diff_density_rms         0.337
_refine_ls_extinction_coef       0.00195(10)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.147
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     94
_refine_ls_number_reflns         1515
_refine_ls_number_restraints     6
_refine_ls_R_factor_all          0.0251
_refine_ls_R_factor_gt           0.0229
_refine_ls_restrained_S_all      1.159
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0177P)²+2.1117P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0491
_refine_ls_wR_factor_ref         0.0508
_refine_special_details          ?
_olex2_refinement_description    
;
1. Uiso/Uaniso restraints and constraints
Uanis(O1) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.005
2. Others
 Fixed Sof: Li2(0.5)
;
_atom_sites_solution_hydrogens   .
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Te1 Te 0.83479(2) 0.33495(4) 0.32998(2) 0.01011(9) Uani 1 1 d . . . . .
Te2 Te 0.55607(2) 0.73783(5) 0.43787(3) 0.01616(9) Uani 1 1 d . . . . .
Ga1 Ga 0.750000 0.750000 0.500000 0.00792(12) Uani 1 2 d S . P . .
O5 O 0.76729(14) 0.4394(5) 0.1669(2) 0.0109(5) Uani 1 1 d . . . . .
O3 O 0.64616(14) 0.6073(5) 0.4288(3) 0.0130(5) Uani 1 1 d . . . . .
O4 O 0.77584(14) 0.4305(5) 0.4300(2) 0.0103(5) Uani 1 1 d . . . . .
O6 O 0.88892(17) 0.6460(5) 0.3473(3) 0.0190(6) Uani 1 1 d . . . . .
O2 O 0.56620(15) 1.0813(5) 0.4008(3) 0.0175(6) Uani 1 1 d . . . . .
O1 O 0.500000 0.6261(8) 0.250000 0.0298(11) Uani 1 2 d S TU P . .
Li1 Li 0.6717(5) 0.2439(14) 0.3832(8) 0.0229(16) Uani 1 1 d . . . . .
Li2 Li 0.4788(8) 1.232(3) 0.2709(14) 0.019(3) Uani 0.5 1 d . . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Te1 O5 1.870(2) . ?
Te1 O4 1.858(2) . ?
Te1 O6 1.886(3) . ?
Te1 Li1 3.096(8) 4_655 ?
Te1 Li1 3.356(8) . ?
Te1 Li1 3.155(8) 7_656 ?
Te2 O3 1.867(3) . ?
Te2 O6 2.274(3) 7_666 ?
Te2 O2 1.850(3) . ?
Te2 O1 2.0265(13) . ?
Te2 Li2 3.190(14) . ?
Te2 Li2 3.326(15) 2_655 ?
Te2 Li2 3.237(14) 1_545 ?
Te2 Li2 3.370(14) 2_645 ?
Ga1 O5 1.975(2) 6_566 ?
Ga1 O5 1.975(2) 4_655 ?
Ga1 O3 1.996(2) . ?
Ga1 O3 1.996(2) 7_666 ?
Ga1 O4 1.949(2) 7_666 ?
Ga1 O4 1.949(2) . ?
Ga1 Li1 3.068(8) . ?
Ga1 Li1 3.014(8) 7_656 ?
Ga1 Li1 3.014(8) 1_565 ?
Ga1 Li1 3.068(8) 7_666 ?
O5 Li1 2.130(8) 4_655 ?
O3 Li1 2.046(8) . ?
O4 Li1 2.099(8) . ?
O4 Li1 2.121(8) 7_656 ?
O6 Li1 2.412(9) 4_655 ?
O6 Li2 2.170(15) 3_545 ?
O2 Li1 2.233(9) 1_565 ?
O2 Li2 1.936(14) . ?
O2 Li2 1.922(15) 2_655 ?
O1 Li2 2.108(14) 1_545 ?
O1 Li2 2.108(14) 2_645 ?
Li1 Li1 3.178(17) 7_656 ?
Li1 Li2 2.774(17) 2_645 ?
Li2 Li2 1.04(3) 2_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Te1 O6 91.29(12) . . ?
O5 Te1 Li1 135.74(17) . 7_656 ?
O5 Te1 Li1 79.80(16) . . ?
O5 Te1 Li1 42.44(18) . 4_655 ?
O4 Te1 O5 96.44(11) . . ?
O4 Te1 O6 97.25(12) . . ?
O4 Te1 Li1 111.35(16) . 4_655 ?
O4 Te1 Li1 34.27(15) . . ?
O4 Te1 Li1 40.57(17) . 7_656 ?
O6 Te1 Li1 102.24(17) . 7_656 ?
O6 Te1 Li1 51.15(18) . 4_655 ?
O6 Te1 Li1 127.11(16) . . ?
Li1 Te1 Li1 114.37(17) 4_655 . ?
Li1 Te1 Li1 143.93(13) 4_655 7_656 ?
Li1 Te1 Li1 58.3(3) 7_656 . ?
O3 Te2 O6 91.96(11) . 7_666 ?
O3 Te2 O1 91.50(9) . . ?
O3 Te2 Li2 102.8(3) . 2_655 ?
O3 Te2 Li2 70.2(3) . 2_645 ?
O3 Te2 Li2 85.9(3) . 1_545 ?
O3 Te2 Li2 121.1(3) . . ?
O6 Te2 Li2 138.3(3) 7_666 1_545 ?
O6 Te2 Li2 113.6(3) 7_666 2_655 ?
O6 Te2 Li2 143.5(3) 7_666 2_645 ?
O6 Te2 Li2 109.0(3) 7_666 . ?
O2 Te2 O3 100.11(12) . . ?
O2 Te2 O6 85.34(12) . 7_666 ?
O2 Te2 O1 96.76(14) . . ?
O2 Te2 Li2 28.7(3) . 2_655 ?
O2 Te2 Li2 33.4(3) . . ?
O2 Te2 Li2 136.1(3) . 1_545 ?
O2 Te2 Li2 128.1(3) . 2_645 ?
O1 Te2 O6 175.58(8) . 7_666 ?
O1 Te2 Li2 36.2(3) . 2_645 ?
O1 Te2 Li2 68.2(3) . 2_655 ?
O1 Te2 Li2 71.4(3) . . ?
O1 Te2 Li2 39.4(3) . 1_545 ?
Li2 Te2 Li2 18.3(5) . 2_655 ?
Li2 Te2 Li2 18.0(5) 1_545 2_645 ?
Li2 Te2 Li2 101.5(4) 2_655 2_645 ?
Li2 Te2 Li2 107.43(6) 1_545 2_655 ?
Li2 Te2 Li2 107.6(4) . 1_545 ?
Li2 Te2 Li2 107.45(6) . 2_645 ?
O5 Ga1 O5 180.0 6_566 4_655 ?
O5 Ga1 O3 90.33(11) 6_566 . ?
O5 Ga1 O3 89.67(11) 6_566 7_666 ?
O5 Ga1 O3 89.67(11) 4_655 . ?
O5 Ga1 O3 90.33(11) 4_655 7_666 ?
O5 Ga1 Li1 44.79(17) 6_566 7_656 ?
O5 Ga1 Li1 81.76(17) 6_566 . ?
O5 Ga1 Li1 98.24(17) 6_566 7_666 ?
O5 Ga1 Li1 135.21(17) 4_655 7_656 ?
O5 Ga1 Li1 98.24(17) 4_655 . ?
O5 Ga1 Li1 135.21(17) 6_566 1_565 ?
O5 Ga1 Li1 81.76(17) 4_655 7_666 ?
O5 Ga1 Li1 44.79(17) 4_655 1_565 ?
O3 Ga1 O3 180.0 7_666 . ?
O3 Ga1 Li1 138.77(17) 7_666 . ?
O3 Ga1 Li1 97.34(17) 7_666 1_565 ?
O3 Ga1 Li1 82.66(17) . 1_565 ?
O3 Ga1 Li1 41.23(17) . . ?
O3 Ga1 Li1 41.23(17) 7_666 7_666 ?
O3 Ga1 Li1 138.77(17) . 7_666 ?
O3 Ga1 Li1 97.34(17) . 7_656 ?
O3 Ga1 Li1 82.66(17) 7_666 7_656 ?
O4 Ga1 O5 86.66(10) . 6_566 ?
O4 Ga1 O5 93.34(10) . 4_655 ?
O4 Ga1 O5 93.35(11) 7_666 6_566 ?
O4 Ga1 O5 86.65(11) 7_666 4_655 ?
O4 Ga1 O3 83.04(11) . . ?
O4 Ga1 O3 83.04(11) 7_666 7_666 ?
O4 Ga1 O3 96.96(11) . 7_666 ?
O4 Ga1 O3 96.96(11) 7_666 . ?
O4 Ga1 O4 180.0 7_666 . ?
O4 Ga1 Li1 44.47(17) . 7_656 ?
O4 Ga1 Li1 137.42(17) 7_666 . ?
O4 Ga1 Li1 135.53(17) . 1_565 ?
O4 Ga1 Li1 42.58(17) 7_666 7_666 ?
O4 Ga1 Li1 42.58(17) . . ?
O4 Ga1 Li1 137.42(17) . 7_666 ?
O4 Ga1 Li1 135.53(17) 7_666 7_656 ?
O4 Ga1 Li1 44.47(17) 7_666 1_565 ?
Li1 Ga1 Li1 63.0(3) 7_656 . ?
Li1 Ga1 Li1 180.0 . 7_666 ?
Li1 Ga1 Li1 63.0(3) 1_565 7_666 ?
Li1 Ga1 Li1 117.0(3) 1_565 . ?
Li1 Ga1 Li1 117.0(3) 7_656 7_666 ?
Li1 Ga1 Li1 180.0 7_656 1_565 ?
Te1 O5 Ga1 124.14(13) . 4_645 ?
Te1 O5 Li1 101.2(3) . 4_655 ?
Ga1 O5 Li1 94.4(2) 4_645 4_655 ?
Te2 O3 Ga1 130.11(14) . . ?
Te2 O3 Li1 129.8(3) . . ?
Ga1 O3 Li1 98.8(3) . . ?
Te1 O4 Ga1 136.66(14) . . ?
Te1 O4 Li1 104.7(2) . 7_656 ?
Te1 O4 Li1 115.8(2) . . ?
Ga1 O4 Li1 95.5(2) . 7_656 ?
Ga1 O4 Li1 98.5(2) . . ?
Li1 O4 Li1 97.7(3) . 7_656 ?
Te1 O6 Te2 112.06(13) . 7_666 ?
Te1 O6 Li1 91.3(2) . 4_655 ?
Te1 O6 Li2 127.4(4) . 3_545 ?
Te2 O6 Li1 152.5(2) 7_666 4_655 ?
Li2 O6 Te2 100.4(4) 3_545 7_666 ?
Li2 O6 Li1 74.3(4) 3_545 4_655 ?
Te2 O2 Li1 122.8(2) . 1_565 ?
Te2 O2 Li2 114.8(4) . . ?
Te2 O2 Li2 123.7(4) . 2_655 ?
Li2 O2 Li1 83.4(5) 2_655 1_565 ?
Li2 O2 Li1 110.9(5) . 1_565 ?
Li2 O2 Li2 31.3(9) 2_655 . ?
Te2 O1 Te2 146.8(2) 2_655 . ?
Te2 O1 Li2 103.0(4) 2_655 2_645 ?
Te2 O1 Li2 109.2(4) . 2_645 ?
Te2 O1 Li2 109.2(4) 2_655 1_545 ?
Te2 O1 Li2 103.0(4) . 1_545 ?
Li2 O1 Li2 28.6(8) 1_545 2_645 ?
Te1 Li1 Te1 129.1(2) 4_645 7_656 ?
Te1 Li1 Li1 64.0(3) 7_656 7_656 ?
Te1 Li1 Li1 113.2(4) 4_645 7_656 ?
Ga1 Li1 Te1 69.96(17) 1_545 7_656 ?
Ga1 Li1 Te1 141.5(3) . 4_645 ?
Ga1 Li1 Te1 83.25(19) . 7_656 ?
Ga1 Li1 Te1 67.56(15) 1_545 4_645 ?
Ga1 Li1 Ga1 117.0(3) 1_545 . ?
Ga1 Li1 Li1 57.7(2) . 7_656 ?
Ga1 Li1 Li1 59.3(2) 1_545 7_656 ?
O5 Li1 Te1 110.7(3) 4_645 7_656 ?
O5 Li1 Te1 36.34(14) 4_645 4_645 ?
O5 Li1 Ga1 120.7(3) 4_645 . ?
O5 Li1 Ga1 40.80(15) 4_645 1_545 ?
O5 Li1 O6 72.2(2) 4_645 4_645 ?
O5 Li1 O2 108.5(3) 4_645 1_545 ?
O5 Li1 Li1 76.9(3) 4_645 7_656 ?
O5 Li1 Li2 111.6(4) 4_645 2_645 ?
O3 Li1 Te1 78.2(2) . 7_656 ?
O3 Li1 Te1 148.8(4) . 4_645 ?
O3 Li1 Ga1 143.7(4) . 1_545 ?
O3 Li1 Ga1 40.02(16) . . ?
O3 Li1 O5 159.3(4) . 4_645 ?
O3 Li1 O4 78.2(3) . . ?
O3 Li1 O4 103.8(4) . 7_656 ?
O3 Li1 O6 111.8(4) . 4_645 ?
O3 Li1 O2 92.2(3) . 1_545 ?
O3 Li1 Li1 91.4(4) . 7_656 ?
O3 Li1 Li2 83.4(4) . 2_645 ?
O4 Li1 Te1 107.4(3) 7_656 4_645 ?
O4 Li1 Te1 107.1(3) . 4_645 ?
O4 Li1 Te1 34.74(14) 7_656 7_656 ?
O4 Li1 Te1 99.6(3) . 7_656 ?
O4 Li1 Ga1 38.92(15) . . ?
O4 Li1 Ga1 90.1(3) . 1_545 ?
O4 Li1 Ga1 88.2(3) 7_656 . ?
O4 Li1 Ga1 40.06(15) 7_656 1_545 ?
O4 Li1 O5 78.6(3) 7_656 4_645 ?
O4 Li1 O5 81.8(3) . 4_645 ?
O4 Li1 O4 82.3(3) . 7_656 ?
O4 Li1 O6 142.6(4) 7_656 4_645 ?
O4 Li1 O6 115.3(4) . 4_645 ?
O4 Li1 O2 84.6(3) 7_656 1_545 ?
O4 Li1 O2 161.4(4) . 1_545 ?
O4 Li1 Li1 40.9(2) 7_656 7_656 ?
O4 Li1 Li1 41.4(2) . 7_656 ?
O4 Li1 Li2 128.1(5) 7_656 2_645 ?
O4 Li1 Li2 147.8(5) . 2_645 ?
O6 Li1 Te1 144.8(3) 4_645 7_656 ?
O6 Li1 Te1 37.52(13) 4_645 4_645 ?
O6 Li1 Ga1 126.8(3) 4_645 . ?
O6 Li1 Ga1 104.3(3) 4_645 1_545 ?
O6 Li1 Li1 144.4(5) 4_645 7_656 ?
O6 Li1 Li2 48.9(3) 4_645 2_645 ?
O2 Li1 Te1 89.4(3) 1_545 4_645 ?
O2 Li1 Te1 62.6(2) 1_545 7_656 ?
O2 Li1 Ga1 127.7(3) 1_545 . ?
O2 Li1 Ga1 88.4(2) 1_545 1_545 ?
O2 Li1 O6 82.9(3) 1_545 4_645 ?
O2 Li1 Li1 124.3(4) 1_545 7_656 ?
O2 Li1 Li2 43.5(4) 1_545 2_645 ?
Li2 Li1 Te1 76.4(3) 2_645 4_645 ?
Li2 Li1 Te1 102.3(4) 2_645 7_656 ?
Li2 Li1 Ga1 121.4(4) 2_645 . ?
Li2 Li1 Ga1 119.5(4) 2_645 1_545 ?
Li2 Li1 Li1 166.1(5) 2_645 7_656 ?
Te2 Li2 Te2 72.0(3) 1_565 2_665 ?
Te2 Li2 Te2 162.0(5) . 2_665 ?
Te2 Li2 Te2 161.8(5) 1_565 2_655 ?
Te2 Li2 Te2 107.6(4) . 1_565 ?
Te2 Li2 Te2 73.1(3) . 2_655 ?
Te2 Li2 Te2 101.5(4) 2_655 2_665 ?
Te2 Li2 Li1 65.4(3) . 1_565 ?
Te2 Li2 Li1 101.4(4) 2_655 1_565 ?
Te2 Li2 Li1 99.7(4) 2_665 1_565 ?
Te2 Li2 Li1 64.0(3) 1_565 1_565 ?
O6 Li2 Te2 95.4(5) 3_455 2_655 ?
O6 Li2 Te2 102.8(5) 3_455 1_565 ?
O6 Li2 Te2 83.7(4) 3_455 . ?
O6 Li2 Te2 114.2(5) 3_455 2_665 ?
O6 Li2 Li1 138.1(6) 3_455 1_565 ?
O6 Li2 Li1 56.8(4) 3_455 2_665 ?
O2 Li2 Te2 95.9(5) . 2_655 ?
O2 Li2 Te2 75.7(4) 2_655 2_665 ?
O2 Li2 Te2 79.0(4) . 1_565 ?
O2 Li2 Te2 100.7(5) 2_655 . ?
O2 Li2 Te2 31.7(2) . . ?
O2 Li2 Te2 136.4(6) . 2_665 ?
O2 Li2 Te2 146.7(6) 2_655 1_565 ?
O2 Li2 Te2 27.6(2) 2_655 2_655 ?
O2 Li2 O6 103.4(6) . 3_455 ?
O2 Li2 O6 97.4(6) 2_655 3_455 ?
O2 Li2 O2 121.6(8) 2_655 . ?
O2 Li2 O1 108.8(6) . 1_565 ?
O2 Li2 O1 109.3(7) 2_655 1_565 ?
O2 Li2 Li1 114.9(6) 2_655 1_565 ?
O2 Li2 Li1 53.1(4) 2_655 2_665 ?
O2 Li2 Li1 37.3(3) . 1_565 ?
O2 Li2 Li1 153.8(7) . 2_665 ?
O1 Li2 Te2 34.6(2) 1_565 2_665 ?
O1 Li2 Te2 37.6(2) 1_565 1_565 ?
O1 Li2 Te2 140.5(6) 1_565 . ?
O1 Li2 Te2 132.6(6) 1_565 2_655 ?
O1 Li2 O6 116.2(7) 1_565 3_455 ?
O1 Li2 Li1 96.3(5) 1_565 2_665 ?
O1 Li2 Li1 78.6(4) 1_565 1_565 ?
Li1 Li2 Te2 69.7(3) 2_665 2_665 ?
Li1 Li2 Te2 119.7(5) 2_665 1_565 ?
Li1 Li2 Te2 71.5(4) 2_665 2_655 ?
Li1 Li2 Te2 122.6(5) 2_665 . ?
Li1 Li2 Li1 164.9(5) 2_665 1_565 ?
Li2 Li2 Te2 88.3(9) 2_655 1_565 ?
Li2 Li2 Te2 88.2(9) 2_655 . ?
Li2 Li2 Te2 73.7(9) 2_655 2_665 ?
Li2 Li2 Te2 73.5(9) 2_655 2_655 ?
Li2 Li2 O6 167.8(6) 2_655 3_455 ?
Li2 Li2 O2 73.5(14) 2_655 . ?
Li2 Li2 O2 75.1(14) 2_655 2_655 ?
Li2 Li2 O1 75.7(4) 2_655 1_565 ?
Li2 Li2 Li1 43.3(14) 2_655 1_565 ?
Li2 Li2 Li1 121.8(17) 2_655 2_665 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O5 Te1 O4 Ga1 -77.6(2) . . . . ?
O5 Te1 O4 Li1 61.2(3) . . . . ?
O5 Te1 O4 Li1 167.5(2) . . . 7_656 ?
O5 Te1 O6 Te2 150.12(14) . . . 7_666 ?
O5 Te1 O6 Li1 -15.0(2) . . . 4_655 ?
O5 Te1 O6 Li2 -86.2(5) . . . 3_545 ?
O3 Te2 O2 Li1 -7.2(3) . . . 1_565 ?
O3 Te2 O2 Li2 98.3(6) . . . 2_655 ?
O3 Te2 O2 Li2 133.0(5) . . . . ?
O4 Te1 O5 Ga1 -141.94(16) . . . 4_645 ?
O4 Te1 O5 Li1 114.8(2) . . . 4_655 ?
O4 Te1 O6 Te2 53.46(15) . . . 7_666 ?
O4 Te1 O6 Li1 -111.6(2) . . . 4_655 ?
O4 Te1 O6 Li2 177.2(5) . . . 3_545 ?
O6 Te1 O5 Ga1 120.62(17) . . . 4_645 ?
O6 Te1 O5 Li1 17.4(2) . . . 4_655 ?
O6 Te1 O4 Ga1 14.5(2) . . . . ?
O6 Te1 O4 Li1 153.3(3) . . . . ?
O6 Te1 O4 Li1 -100.4(3) . . . 7_656 ?
O6 Te2 O3 Ga1 -42.23(19) 7_666 . . . ?
O6 Te2 O3 Li1 121.5(3) 7_666 . . . ?
O6 Te2 O2 Li1 84.0(3) 7_666 . . 1_565 ?
O6 Te2 O2 Li2 -135.9(5) 7_666 . . . ?
O6 Te2 O2 Li2 -170.5(6) 7_666 . . 2_655 ?
O2 Te2 O3 Ga1 43.4(2) . . . . ?
O2 Te2 O3 Li1 -152.9(3) . . . . ?
O1 Te2 O3 Ga1 140.5(2) . . . . ?
O1 Te2 O3 Li1 -55.7(4) . . . . ?
O1 Te2 O2 Li1 -99.9(3) . . . 1_565 ?
O1 Te2 O2 Li2 5.6(6) . . . 2_655 ?
O1 Te2 O2 Li2 40.2(5) . . . . ?
Li1 Te1 O5 Ga1 -130.3(2) 7_656 . . 4_645 ?
Li1 Te1 O5 Ga1 -111.9(2) . . . 4_645 ?
Li1 Te1 O5 Ga1 103.3(3) 4_655 . . 4_645 ?
Li1 Te1 O5 Li1 126.44(19) 7_656 . . 4_655 ?
Li1 Te1 O5 Li1 144.9(3) . . . 4_655 ?
Li1 Te1 O4 Ga1 -36.5(3) 4_655 . . . ?
Li1 Te1 O4 Ga1 114.9(3) 7_656 . . . ?
Li1 Te1 O4 Ga1 -138.8(4) . . . . ?
Li1 Te1 O4 Li1 -106.3(3) 7_656 . . . ?
Li1 Te1 O4 Li1 106.3(3) . . . 7_656 ?
Li1 Te1 O4 Li1 102.30(16) 4_655 . . . ?
Li1 Te1 O4 Li1 -151.4(3) 4_655 . . 7_656 ?
Li1 Te1 O6 Te2 165.1(3) 4_655 . . 7_666 ?
Li1 Te1 O6 Te2 12.6(2) 7_656 . . 7_666 ?
Li1 Te1 O6 Te2 72.0(2) . . . 7_666 ?
Li1 Te1 O6 Li1 -93.2(3) . . . 4_655 ?
Li1 Te1 O6 Li1 -152.5(3) 7_656 . . 4_655 ?
Li1 Te1 O6 Li2 -71.2(5) 4_655 . . 3_545 ?
Li1 Te1 O6 Li2 136.3(5) 7_656 . . 3_545 ?
Li1 Te1 O6 Li2 -164.3(5) . . . 3_545 ?
Li2 Te2 O3 Ga1 71.5(4) . . . . ?
Li2 Te2 O3 Ga1 72.6(3) 2_655 . . . ?
Li2 Te2 O3 Ga1 170.4(3) 2_645 . . . ?
Li2 Te2 O3 Ga1 179.5(3) 1_545 . . . ?
Li2 Te2 O3 Li1 -123.7(4) 2_655 . . . ?
Li2 Te2 O3 Li1 -25.9(4) 2_645 . . . ?
Li2 Te2 O3 Li1 -16.7(4) 1_545 . . . ?
Li2 Te2 O3 Li1 -124.8(4) . . . . ?
Li2 Te2 O2 Li1 -140.2(6) . . . 1_565 ?
Li2 Te2 O2 Li1 -105.5(6) 2_655 . . 1_565 ?
Li2 Te2 O2 Li1 -79.9(4) 2_645 . . 1_565 ?
Li2 Te2 O2 Li1 -101.7(5) 1_545 . . 1_565 ?
Li2 Te2 O2 Li2 34.7(10) 2_655 . . . ?
Li2 Te2 O2 Li2 38.4(4) 1_545 . . . ?
Li2 Te2 O2 Li2 3.8(9) 1_545 . . 2_655 ?
Li2 Te2 O2 Li2 25.6(4) 2_645 . . 2_655 ?
Li2 Te2 O2 Li2 -34.7(10) . . . 2_655 ?
Li2 Te2 O2 Li2 60.3(7) 2_645 . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
