# Supplementary Information (SI) for New Journal of Chemistry.
# This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_Complex_2
_database_code_depnum_ccdc_archive 'CCDC 1566059'
loop_
_audit_author_name
_audit_author_address
'MANOJ TRIVEDI'
;Department of Chemistry Daulat Ram College University of Delhi
India
;
_audit_update_record             
;
2026-02-28 deposited with the CCDC.	2026-03-04 downloaded from the CCDC.
;

_audit_creation_method           SHELXL-2018/3
_shelx_SHELXL_version_number     2018/3
_chemical_name_systematic        ?
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C41 H37 F6 N2 O P3 Ru'
_chemical_formula_sum            'C41 H37 F6 N2 O P3 Ru'
_chemical_formula_weight         881.71

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system      monoclinic
_space_group_IT_number           11
_space_group_name_H-M_alt        'P 21/m'
_space_group_name_Hall           '-P 2yb'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;

loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'

_cell_length_a                   9.2610(11)
_cell_length_b                   22.228(2)
_cell_length_c                   10.4259(13)
_cell_angle_alpha                90
_cell_angle_beta                 110.918(14)
_cell_angle_gamma                90
_cell_volume                     2004.8(4)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    813
_cell_measurement_theta_min      3.3184
_cell_measurement_theta_max      32.6223

_exptl_crystal_description       Block
_exptl_crystal_colour            Yellow
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_density_diffrn    1.461
_exptl_crystal_F_000             896
_exptl_transmission_factor_min   ?
_exptl_transmission_factor_max   ?
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_absorpt_coefficient_mu    0.573
_shelx_estimated_absorpt_T_min   ?
_shelx_estimated_absorpt_T_max   ?
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.7317
_exptl_absorpt_correction_T_max  0.8013
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details   
;
 ?
;
_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_source                   'fine-focus sealed tube'
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       ω/2θ
_diffrn_detector_area_resol_mean 15.9948
_diffrn_reflns_number            29409
_diffrn_reflns_av_unetI/netI     0.0482
_diffrn_reflns_av_R_equivalents  0.0976
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_theta_min         2.984
_diffrn_reflns_theta_max         27.498
_diffrn_reflns_theta_full        25.242
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measured_fraction_theta_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_point_group_measured_fraction_full 0.996
_reflns_number_total             4711
_reflns_number_gt                4439
_reflns_threshold_expression     'I > 2σ(I)'
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_max     .
_reflns_Friedel_fraction_full    .

_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;

_computing_data_collection       
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.44 (release 25-10-2010 CrysAlis171 .NET)
(compiled Oct 25 2010,18:11:34)
;
_computing_cell_refinement       
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.44 (release 25-10-2010 CrysAlis171 .NET)
(compiled Oct 25 2010,18:11:34)
;
_computing_data_reduction        
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.44 (release 25-10-2010 CrysAlis171 .NET)
(compiled Oct 25 2010,18:11:34)
;
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_molecular_graphics    ?
_computing_publication_material  ?
_refine_special_details          ?
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0734P)²+5.2565P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
_atom_sites_solution_hydrogens   mixed
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       .
_refine_ls_number_reflns         4711
_refine_ls_number_parameters     264
_refine_ls_number_restraints     94
_refine_ls_R_factor_all          0.0774
_refine_ls_R_factor_gt           0.0736
_refine_ls_wR_factor_ref         0.1882
_refine_ls_wR_factor_gt          0.1855
_refine_ls_goodness_of_fit_ref   1.228
_refine_ls_restrained_S_all      1.255
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.65323(6) 0.750000 0.53613(5) 0.02804(18) Uani 1 2 d S T P . .
H1 H 0.467258 0.750000 0.469472 0.042 Uiso 1 2 d R U P . .
P1 P 0.61943(13) 0.64465(5) 0.52603(12) 0.0303(3) Uani 1 1 d . . . . .
O1 O 0.5716(8) 0.750000 0.7876(7) 0.0666(18) Uani 1 2 d S T P . .
N1 N 0.9032(7) 0.750000 0.6187(7) 0.0395(13) Uani 1 2 d S T P . .
N2 N 0.6534(9) 0.750000 0.3362(7) 0.0497(16) Uani 1 2 d S T P . .
C1 C 0.6125(9) 0.750000 0.6971(7) 0.0399(15) Uani 1 2 d S T P . .
C6 C 0.7668(5) 0.5981(2) 0.6465(5) 0.0355(10) Uani 1 1 d . . . . .
C13 C 0.4423(7) 0.5826(2) 0.6567(6) 0.0470(12) Uani 1 1 d . . . . .
H13 H 0.533338 0.563298 0.709317 0.056 Uiso 1 1 calc R U . . .
C11 C 0.7885(6) 0.5380(2) 0.6186(6) 0.0465(12) Uani 1 1 d . . . . .
H11 H 0.728019 0.521243 0.534923 0.056 Uiso 1 1 calc R U . . .
C7 C 0.8579(6) 0.6217(2) 0.7729(5) 0.0436(11) Uani 1 1 d . . . . .
H7 H 0.844730 0.661535 0.793923 0.052 Uiso 1 1 calc R U . . .
C19 C 0.4634(7) 0.5902(3) 0.2667(7) 0.0598(16) Uani 1 1 d . . . . .
H19 H 0.375810 0.588018 0.290482 0.072 Uiso 1 1 calc R U . . .
C10 C 0.8992(7) 0.5034(3) 0.7142(7) 0.0561(15) Uani 1 1 d . . . . .
H10 H 0.913073 0.463398 0.694991 0.067 Uiso 1 1 calc R U . . .
C17 C 0.3060(6) 0.6510(3) 0.4771(6) 0.0475(12) Uani 1 1 d . . . . .
H17 H 0.304618 0.678154 0.408787 0.057 Uiso 1 1 calc R U . . .
C2 C 1.0308(9) 0.750000 0.6752(9) 0.0508(19) Uani 1 2 d S T P . .
C22 C 0.7178(8) 0.5957(3) 0.1906(7) 0.0608(16) Uani 1 1 d . . . . .
H22 H 0.804584 0.597361 0.165617 0.073 Uiso 1 1 calc R U . . .
C21 C 0.5823(10) 0.5754(3) 0.0999(7) 0.072(2) Uani 1 1 d . . . . .
H21 H 0.574561 0.563931 0.011932 0.087 Uiso 1 1 calc R U . . .
C4 C 0.6247(14) 0.750000 0.2217(9) 0.066(3) Uani 1 2 d S T P . .
C8 C 0.9673(7) 0.5867(3) 0.8670(6) 0.0558(14) Uani 1 1 d . . . . .
H8 H 1.027566 0.602897 0.951450 0.067 Uiso 1 1 calc R U . . .
C20 C 0.4562(9) 0.5720(4) 0.1395(8) 0.081(2) Uani 1 1 d . . . . .
H20 H 0.363666 0.556791 0.078221 0.097 Uiso 1 1 calc R U . . .
C16 C 0.1710(7) 0.6378(3) 0.5005(8) 0.0611(17) Uani 1 1 d . . . . .
H16 H 0.078604 0.656098 0.447368 0.073 Uiso 1 1 calc R U . . .
C3 C 1.1973(11) 0.750000 0.7547(15) 0.087(4) Uani 1 2 d S T P . .
H3A H 1.252703 0.738747 0.696222 0.131 Uiso 0.5 1 calc R U P A -1
H3B H 1.219299 0.721737 0.828897 0.131 Uiso 0.5 1 calc R U P A -1
H3C H 1.228812 0.789517 0.791114 0.131 Uiso 0.5 1 calc R U P A -1
C9 C 0.9882(8) 0.5280(3) 0.8370(7) 0.0579(15) Uani 1 1 d . . . . .
H9 H 1.063519 0.504777 0.900821 0.069 Uiso 1 1 calc R U . . .
C14 C 0.3064(8) 0.5704(3) 0.6792(7) 0.0621(17) Uani 1 1 d . . . . .
H14 H 0.307165 0.543325 0.747415 0.075 Uiso 1 1 calc R U . . .
C15 C 0.1733(7) 0.5975(3) 0.6030(9) 0.0682(19) Uani 1 1 d . . . . .
H15 H 0.082762 0.589259 0.619126 0.082 Uiso 1 1 calc R U . . .
C5 C 0.582(2) 0.750000 0.0751(11) 0.115(6) Uani 1 2 d S T P . .
H5A H 0.563361 0.790552 0.041516 0.172 Uiso 0.5 1 calc R U P B -1
H5B H 0.489858 0.726538 0.034437 0.172 Uiso 0.5 1 calc R U P B -1
H5C H 0.664265 0.732909 0.051233 0.172 Uiso 0.5 1 calc R U P B -1
C18 C 0.5997(5) 0.6120(2) 0.3598(5) 0.0340(9) Uani 1 1 d . . . . .
C12 C 0.4434(5) 0.6231(2) 0.5567(5) 0.0363(10) Uani 1 1 d . . . . .
C23 C 0.7281(7) 0.6141(3) 0.3202(6) 0.0496(13) Uani 1 1 d . . . . .
H23 H 0.821966 0.628131 0.381620 0.059 Uiso 1 1 calc R U . . .
P2 P 0.9430(5) 0.250000 0.8867(4) 0.1059(13) Uani 1 2 d DS TU P . .
F1 F 1.000(2) 0.250000 1.0335(9) 0.229(7) Uani 1 2 d DS TU P . .
F2 F 0.913(3) 0.250000 0.7378(11) 0.283(9) Uani 1 2 d DS TU P . .
F3 F 1.0388(18) 0.3033(5) 0.8905(13) 0.268(6) Uani 1 1 d D U . . .
F4 F 0.8214(16) 0.2933(6) 0.8758(18) 0.337(8) Uani 1 1 d D U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C1 1.847(7) . ?
Ru1 N2 2.085(6) . ?
Ru1 N1 2.163(6) . ?
Ru1 P1 2.3599(12) . ?
Ru1 P1 2.3600(12) 4_575 ?
Ru1 H1 1.6108 . ?
P1 C6 1.813(5) . ?
P1 C18 1.827(5) . ?
P1 C12 1.833(5) . ?
O1 C1 1.135(9) . ?
N1 C2 1.116(10) . ?
N2 C4 1.126(11) . ?
C6 C7 1.389(7) . ?
C6 C11 1.396(7) . ?
C13 C12 1.381(7) . ?
C13 C14 1.387(8) . ?
C13 H13 0.9300 . ?
C11 C10 1.382(8) . ?
C11 H11 0.9300 . ?
C7 C8 1.373(8) . ?
C7 H7 0.9300 . ?
C19 C20 1.366(9) . ?
C19 C18 1.377(7) . ?
C19 H19 0.9300 . ?
C10 C9 1.365(9) . ?
C10 H10 0.9300 . ?
C17 C16 1.388(7) . ?
C17 C12 1.392(7) . ?
C17 H17 0.9300 . ?
C2 C3 1.467(12) . ?
C22 C21 1.351(10) . ?
C22 C23 1.382(8) . ?
C22 H22 0.9300 . ?
C21 C20 1.372(11) . ?
C21 H21 0.9300 . ?
C4 C5 1.436(12) . ?
C8 C9 1.372(9) . ?
C8 H8 0.9300 . ?
C20 H20 0.9300 . ?
C16 C15 1.389(10) . ?
C16 H16 0.9300 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C9 H9 0.9300 . ?
C14 C15 1.347(10) . ?
C14 H14 0.9300 . ?
C15 H15 0.9300 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C18 C23 1.392(7) . ?
C23 H23 0.9300 . ?
P2 F1 1.429(9) . ?
P2 F4 1.455(9) 4_565 ?
P2 F4 1.455(9) . ?
P2 F3 1.472(8) 4_565 ?
P2 F3 1.472(8) . ?
P2 F2 1.476(11) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ru1 N2 169.0(3) . . ?
C1 Ru1 N1 100.1(3) . . ?
N2 Ru1 N1 90.9(3) . . ?
C1 Ru1 P1 88.49(4) . . ?
N2 Ru1 P1 90.16(4) . . ?
N1 Ru1 P1 97.12(3) . . ?
C1 Ru1 P1 88.49(4) . 4_575 ?
N2 Ru1 P1 90.16(4) . 4_575 ?
N1 Ru1 P1 97.11(3) . 4_575 ?
P1 Ru1 P1 165.76(6) . 4_575 ?
C1 Ru1 H1 81.9 . . ?
N2 Ru1 H1 87.2 . . ?
N1 Ru1 H1 178.0 . . ?
P1 Ru1 H1 82.9 . . ?
P1 Ru1 H1 82.9 4_575 . ?
C6 P1 C18 103.0(2) . . ?
C6 P1 C12 103.1(2) . . ?
C18 P1 C12 105.5(2) . . ?
C6 P1 Ru1 118.69(16) . . ?
C18 P1 Ru1 113.80(15) . . ?
C12 P1 Ru1 111.29(16) . . ?
C2 N1 Ru1 172.2(7) . . ?
C4 N2 Ru1 167.2(9) . . ?
O1 C1 Ru1 172.8(8) . . ?
C7 C6 C11 118.4(5) . . ?
C7 C6 P1 119.6(4) . . ?
C11 C6 P1 122.0(4) . . ?
C12 C13 C14 120.4(6) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 H13 119.8 . . ?
C10 C11 C6 120.5(6) . . ?
C10 C11 H11 119.7 . . ?
C6 C11 H11 119.7 . . ?
C8 C7 C6 120.5(5) . . ?
C8 C7 H7 119.8 . . ?
C6 C7 H7 119.8 . . ?
C20 C19 C18 120.2(6) . . ?
C20 C19 H19 119.9 . . ?
C18 C19 H19 119.9 . . ?
C9 C10 C11 119.8(6) . . ?
C9 C10 H10 120.1 . . ?
C11 C10 H10 120.1 . . ?
C16 C17 C12 119.4(6) . . ?
C16 C17 H17 120.3 . . ?
C12 C17 H17 120.3 . . ?
N1 C2 C3 177.7(11) . . ?
C21 C22 C23 120.4(6) . . ?
C21 C22 H22 119.8 . . ?
C23 C22 H22 119.8 . . ?
C22 C21 C20 119.1(6) . . ?
C22 C21 H21 120.5 . . ?
C20 C21 H21 120.5 . . ?
N2 C4 C5 177.8(15) . . ?
C9 C8 C7 120.3(6) . . ?
C9 C8 H8 119.9 . . ?
C7 C8 H8 119.9 . . ?
C19 C20 C21 121.6(7) . . ?
C19 C20 H20 119.2 . . ?
C21 C20 H20 119.2 . . ?
C17 C16 C15 120.3(6) . . ?
C17 C16 H16 119.9 . . ?
C15 C16 H16 119.9 . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C10 C9 C8 120.6(5) . . ?
C10 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
C15 C14 C13 120.5(6) . . ?
C15 C14 H14 119.7 . . ?
C13 C14 H14 119.7 . . ?
C14 C15 C16 120.1(5) . . ?
C14 C15 H15 120.0 . . ?
C16 C15 H15 120.0 . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C19 C18 C23 117.9(5) . . ?
C19 C18 P1 124.3(4) . . ?
C23 C18 P1 117.5(4) . . ?
C13 C12 C17 119.3(5) . . ?
C13 C12 P1 123.2(4) . . ?
C17 C12 P1 117.4(4) . . ?
C22 C23 C18 120.8(6) . . ?
C22 C23 H23 119.6 . . ?
C18 C23 H23 119.6 . . ?
F1 P2 F4 93.8(9) . 4_565 ?
F1 P2 F4 93.8(9) . . ?
F4 P2 F4 82.9(14) 4_565 . ?
F1 P2 F3 88.9(7) . 4_565 ?
F4 P2 F3 84.9(8) 4_565 4_565 ?
F4 P2 F3 167.7(11) . 4_565 ?
F1 P2 F3 88.9(7) . . ?
F4 P2 F3 167.7(11) 4_565 . ?
F4 P2 F3 84.9(8) . . ?
F3 P2 F3 107.2(13) 4_565 . ?
F1 P2 F2 169.9(12) . . ?
F4 P2 F2 93.8(8) 4_565 . ?
F4 P2 F2 93.8(8) . . ?
F3 P2 F2 85.1(7) 4_565 . ?
F3 P2 F2 85.1(7) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C18 P1 C6 C7 153.7(4) . . . . ?
C12 P1 C6 C7 -96.6(4) . . . . ?
Ru1 P1 C6 C7 26.9(5) . . . . ?
C18 P1 C6 C11 -28.7(5) . . . . ?
C12 P1 C6 C11 80.9(5) . . . . ?
Ru1 P1 C6 C11 -155.5(4) . . . . ?
C7 C6 C11 C10 -0.7(8) . . . . ?
P1 C6 C11 C10 -178.3(4) . . . . ?
C11 C6 C7 C8 0.6(8) . . . . ?
P1 C6 C7 C8 178.2(4) . . . . ?
C6 C11 C10 C9 0.0(9) . . . . ?
C23 C22 C21 C20 -1.5(11) . . . . ?
C6 C7 C8 C9 0.2(9) . . . . ?
C18 C19 C20 C21 -1.0(13) . . . . ?
C22 C21 C20 C19 2.0(13) . . . . ?
C12 C17 C16 C15 0.4(10) . . . . ?
C11 C10 C9 C8 0.8(10) . . . . ?
C7 C8 C9 C10 -0.9(10) . . . . ?
C12 C13 C14 C15 0.6(10) . . . . ?
C13 C14 C15 C16 0.3(12) . . . . ?
C17 C16 C15 C14 -0.8(12) . . . . ?
C20 C19 C18 C23 -0.4(10) . . . . ?
C20 C19 C18 P1 173.6(6) . . . . ?
C6 P1 C18 C19 122.8(5) . . . . ?
C12 P1 C18 C19 14.9(5) . . . . ?
Ru1 P1 C18 C19 -107.4(5) . . . . ?
C6 P1 C18 C23 -63.1(4) . . . . ?
C12 P1 C18 C23 -171.0(4) . . . . ?
Ru1 P1 C18 C23 66.7(4) . . . . ?
C14 C13 C12 C17 -1.0(9) . . . . ?
C14 C13 C12 P1 176.8(5) . . . . ?
C16 C17 C12 C13 0.5(9) . . . . ?
C16 C17 C12 P1 -177.5(5) . . . . ?
C6 P1 C12 C13 2.9(5) . . . . ?
C18 P1 C12 C13 110.7(5) . . . . ?
Ru1 P1 C12 C13 -125.4(4) . . . . ?
C6 P1 C12 C17 -179.2(4) . . . . ?
C18 P1 C12 C17 -71.4(4) . . . . ?
Ru1 P1 C12 C17 52.5(4) . . . . ?
C21 C22 C23 C18 0.1(10) . . . . ?
C19 C18 C23 C22 0.8(9) . . . . ?
P1 C18 C23 C22 -173.6(5) . . . . ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C17 H17 F2 0.93 2.60 3.274(13) 130.2 3_666 yes

_refine_diff_density_max         1.754
_refine_diff_density_min         -1.106
_refine_diff_density_rms         0.118

