# Supplementary Information (SI) for Nanoscale.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
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data_231018_sf_tus9_purple_90k_0m_a
_database_code_depnum_ccdc_archive 'CCDC 2523357'
loop_
_audit_author_name
_audit_author_address
'Saikat Das'
;Tohoku University
Japan
;
_audit_update_record             
;
2026-01-16 deposited with the CCDC.	2026-03-16 downloaded from the CCDC.
;
_audit_creation_date             2023-10-18
_audit_creation_method           
; 
Olex2 1.5 
(compiled 2023.08.24 svn.re1ec1418 for OlexSys, GUI svn.r6817) 
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C58 H98 Ag13 F9 N6 O6 S10, 2(C2 H3 N)'
_chemical_formula_sum            'C62 H104 Ag13 F9 N8 O6 S10'
_chemical_formula_weight         2951.44
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   17.536(2)
_cell_length_b                   20.071(2)
_cell_length_c                   26.605(3)
_cell_angle_alpha                90
_cell_angle_beta                 102.569(3)
_cell_angle_gamma                90
_cell_volume                     9139.2(17)
_cell_formula_units_Z            4
_cell_measurement_reflns_used    4270
_cell_measurement_temperature    273.15
_cell_measurement_theta_max      25.67
_cell_measurement_theta_min      2.38
_shelx_estimated_absorpt_T_max   0.584
_shelx_estimated_absorpt_T_min   0.532
_exptl_absorpt_coefficient_mu    3.011
_exptl_absorpt_correction_T_max  0.7458
_exptl_absorpt_correction_T_min  0.4695
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
; 
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. 
wR2(int) was 0.1295 before and 0.0643 after correction. 
The Ratio of minimum to maximum transmission is 0.6295. 
The λ/2 correction factor is Not present. 
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            brown
_exptl_crystal_colour_primary    brown
_exptl_crystal_density_diffrn    2.145
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             5728
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0840
_diffrn_reflns_av_unetI/netI     0.1139
_diffrn_reflns_Laue_measured_fraction_full 0.960
_diffrn_reflns_Laue_measured_fraction_max 0.960
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            20652
_diffrn_reflns_point_group_measured_fraction_full 0.960
_diffrn_reflns_point_group_measured_fraction_max 0.960
_diffrn_reflns_theta_full        24.713
_diffrn_reflns_theta_max         24.713
_diffrn_reflns_theta_min         1.862
_diffrn_ambient_temperature      273.15
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.960
_diffrn_measured_fraction_theta_max 0.960
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_diffrn_source_current           1.4
_diffrn_source_power             0.07
_diffrn_source_voltage           50.0
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4650
_reflns_number_total             7485
_reflns_special_details          
; 
 Reflections were merged by SHELXL according to the crystal 
 class for the calculation of statistics and refinement. 
  
 _reflns_Friedel_fraction is defined as the number of unique 
 Friedel pairs measured divided by the number that would be 
 possible theoretically, ignoring centric projections and 
 systematic absences. 
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL  (Sheldrick, 2008)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         1.456
_refine_diff_density_min         -1.100
_refine_diff_density_rms         0.199
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     559
_refine_ls_number_reflns         7485
_refine_ls_number_restraints     540
_refine_ls_R_factor_all          0.1025
_refine_ls_R_factor_gt           0.0525
_refine_ls_restrained_S_all      0.983
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0100P)²+50.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0996
_refine_ls_wR_factor_ref         0.1172
_refine_special_details          ?
_olex2_refinement_description    
; 
1. Fixed Uiso 
 At 1.2 times of: 
  All C(H) groups 
 At 1.5 times of: 
  All C(H,H,H) groups 
2. Restrained distances 
 F1-C31 = F13-C31 = F00M-C31 
 1.33 with sigma of 0.02 
 F01K-F01E = F01E-F00E 
 2 with sigma of 0.02 
 F01K-F00E 
 2 with sigma of 0.02 
 F01K-C29 = F01E-C29 = F00E-C29 
 1.33 with sigma of 0.02 
 F00E-C29 \\sim F00F-C28 
 with sigma of 0.02 
 C27-C29 \\sim C27-C28 
 with sigma of 0.02 
 F01E-C29 \\sim F01F-C28 
 with sigma of 0.02 
 C29-F01K \\sim C28-F01L 
 with sigma of 0.02 
 F00E-C27 \\sim F00F-C27 
 with sigma of 0.04 
 F00E-F01E \\sim F00F-F01F 
 with sigma of 0.04 
 F00E-F01K \\sim F00F-F01L 
 with sigma of 0.04 
 C27-F01E \\sim C27-F01F 
 with sigma of 0.04 
 C27-F01K \\sim C27-F01L 
 with sigma of 0.04 
 F01E-F01K \\sim F01F-F01L 
 with sigma of 0.04 
3. Rigid bond restraints 
 All non-hydrogen atoms 
 with sigma for 1-2 distances of 0.01 and sigma for 1-3 distances of 0.01 
4. Uiso/Uaniso restraints and constraints 
All non-hydrogen atoms have similar U: within 2A with sigma of 0.01 and sigma 
for terminal atoms of 0.02 within 2A 
5. Others 
 Sof(F00F)=Sof(F01F)=Sof(F01L)=Sof(C28)=1-FVAR(1) 
 Sof(F00E)=Sof(F01E)=Sof(F01K)=Sof(C29)=FVAR(1) 
 Fixed Sof: F00M(0.5) F1(0.5) F13(0.5) C31(0.5) 
6.a Aromatic/amide H refined with riding coordinates: 
 C3(H3), C4(H4), C5(H5), C6(H6) 
6.b Idealised Me refined as rotating group: 
 C8(H8A,H8B,H8C), C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), 
 C13(H13A,H13B,H13C), C14(H14A,H14B,H14C), C16(H16A,H16B,H16C), C17(H17A,H17B, 
 H17C), C18(H18A,H18B,H18C), C20(H20A,H20B,H20C), C21(H21A,H21B,H21C), C22(H22A, 
 H22B,H22C), C24(H24A,H24B,H24C), C25(H25A,H25B,H25C), C26(H26A,H26B,H26C), 
 C33(H33B,H33A,H33C) 
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.500000 0.15229(6) 0.750000 0.0261(3) Uani 1 2 d S TU P . .
Ag2 Ag 0.44598(5) 0.35458(4) 0.69926(3) 0.0322(2) Uani 1 1 d . U . . .
Ag3 Ag 0.32061(5) 0.26064(5) 0.70105(3) 0.0361(2) Uani 1 1 d . U . . .
Ag4 Ag 0.23164(5) 0.25265(4) 0.59365(3) 0.0276(2) Uani 1 1 d . U . . .
Ag5 Ag 0.18519(5) 0.38472(4) 0.39251(3) 0.0335(2) Uani 1 1 d . U . . .
Ag6 Ag 0.00358(5) 0.26530(4) 0.34786(3) 0.0278(2) Uani 1 1 d . U . . .
Ag7 Ag 0.14198(5) 0.22482(4) 0.46847(3) 0.0325(2) Uani 1 1 d . U . . .
S1 S 0.17207(15) 0.15663(13) 0.54654(9) 0.0268(6) Uani 1 1 d . U . . .
S2 S 0.36789(16) 0.14261(15) 0.70325(9) 0.0308(6) Uani 1 1 d . U . . .
S3 S 0.07498(15) 0.32286(13) 0.42177(9) 0.0271(6) Uani 1 1 d . U . . .
S4 S 0.33924(15) 0.33460(13) 0.61870(8) 0.0241(6) Uani 1 1 d . U . . .
S5 S -0.08545(15) 0.19592(14) 0.28917(9) 0.0273(6) Uani 1 1 d . U . . .
O1 O 0.1381(4) 0.3050(4) 0.6365(3) 0.0430(19) Uani 1 1 d . U . . .
O2 O 0.1987(5) 0.2846(5) 0.7177(3) 0.054(2) Uani 1 1 d . U . . .
O3 O 0.4644(5) 0.4695(4) 0.7094(3) 0.0439(19) Uani 1 1 d . U . . .
N1 N 0.3246(5) 0.7672(4) 0.5226(3) 0.0279(19) Uani 1 1 d . U . . .
N2 N 0.3125(5) 0.7077(4) 0.5019(3) 0.0315(19) Uani 1 1 d . U . . .
N4 N 0.2008(5) 0.4978(4) 0.4146(3) 0.0316(18) Uani 1 1 d . U . . .
C1 C 0.2375(6) 0.6918(5) 0.4798(3) 0.027(2) Uani 1 1 d . U . . .
C2 C 0.2238(6) 0.6244(5) 0.4571(3) 0.0271(19) Uani 1 1 d . U . . .
C3 C 0.1566(6) 0.6100(5) 0.4195(4) 0.031(2) Uani 1 1 d . U . . .
H3 H 0.118193 0.641961 0.408557 0.037 Uiso 1 1 calc R U . . .
C4 C 0.1497(7) 0.5461(6) 0.3992(4) 0.036(2) Uani 1 1 d . U . . .
H4 H 0.106412 0.536616 0.373122 0.043 Uiso 1 1 calc R U . . .
C5 C 0.2647(7) 0.5135(6) 0.4512(4) 0.035(2) Uani 1 1 d . U . . .
H5 H 0.301888 0.480403 0.461832 0.042 Uiso 1 1 calc R U . . .
C6 C 0.2780(7) 0.5746(5) 0.4732(4) 0.033(2) Uani 1 1 d . U . . .
H6 H 0.322622 0.582740 0.498644 0.040 Uiso 1 1 calc R U . . .
C7 C -0.0002(6) 0.3718(5) 0.4465(4) 0.030(2) Uani 1 1 d . U . . .
C8 C -0.0138(7) 0.4377(6) 0.4140(5) 0.049(3) Uani 1 1 d . U . . .
H8A H -0.027229 0.426917 0.378032 0.073 Uiso 1 1 calc R U . . .
H8B H 0.033147 0.463914 0.421108 0.073 Uiso 1 1 calc R U . . .
H8C H -0.055532 0.462647 0.423106 0.073 Uiso 1 1 calc R U . . .
C9 C -0.0757(6) 0.3327(6) 0.4389(4) 0.033(2) Uani 1 1 d . U . . .
H9A H -0.114479 0.358964 0.450237 0.050 Uiso 1 1 calc R U . . .
H9B H -0.066878 0.292260 0.458485 0.050 Uiso 1 1 calc R U . . .
H9C H -0.093482 0.322251 0.403024 0.050 Uiso 1 1 calc R U . . .
C10 C 0.0324(7) 0.3894(7) 0.5021(4) 0.052(3) Uani 1 1 d . U . . .
H10A H -0.007316 0.410841 0.516095 0.078 Uiso 1 1 calc R U . . .
H10B H 0.075958 0.419099 0.504303 0.078 Uiso 1 1 calc R U . . .
H10C H 0.049374 0.349616 0.521274 0.078 Uiso 1 1 calc R U . . .
C11 C -0.1988(7) 0.1857(6) 0.3446(4) 0.043(3) Uani 1 1 d . U . . .
H11A H -0.175125 0.224326 0.362856 0.064 Uiso 1 1 calc R U . . .
H11B H -0.226013 0.160928 0.366179 0.064 Uiso 1 1 calc R U . . .
H11C H -0.234995 0.199267 0.313879 0.064 Uiso 1 1 calc R U . . .
C12 C -0.1368(6) 0.1427(6) 0.3307(4) 0.035(2) Uani 1 1 d . U . . .
C13 C -0.1713(7) 0.0835(6) 0.2977(4) 0.051(3) Uani 1 1 d . U . . .
H13A H -0.209891 0.098918 0.268713 0.076 Uiso 1 1 calc R U . . .
H13B H -0.195291 0.053645 0.317896 0.076 Uiso 1 1 calc R U . . .
H13C H -0.130598 0.060559 0.285789 0.076 Uiso 1 1 calc R U . . .
C14 C -0.0783(6) 0.1206(6) 0.3782(4) 0.039(3) Uani 1 1 d . U . . .
H14A H -0.037097 0.095959 0.368110 0.059 Uiso 1 1 calc R U . . .
H14B H -0.103798 0.092861 0.398858 0.059 Uiso 1 1 calc R U . . .
H14C H -0.056678 0.159015 0.397714 0.059 Uiso 1 1 calc R U . . .
C15 C 0.0739(6) 0.1395(5) 0.5609(4) 0.029(2) Uani 1 1 d . U . . .
C16 C 0.0234(7) 0.2036(6) 0.5536(4) 0.045(3) Uani 1 1 d . U . . .
H16A H 0.046627 0.236180 0.578693 0.067 Uiso 1 1 calc R U . . .
H16B H -0.028245 0.193176 0.557977 0.067 Uiso 1 1 calc R U . . .
H16C H 0.020377 0.221017 0.519646 0.067 Uiso 1 1 calc R U . . .
C17 C 0.0359(7) 0.0872(7) 0.5237(4) 0.052(3) Uani 1 1 d . U . . .
H17A H 0.043762 0.097567 0.489973 0.079 Uiso 1 1 calc R U . . .
H17B H -0.019022 0.085919 0.522962 0.079 Uiso 1 1 calc R U . . .
H17C H 0.058715 0.044612 0.534351 0.079 Uiso 1 1 calc R U . . .
C18 C 0.0838(7) 0.1160(7) 0.6150(4) 0.060(4) Uani 1 1 d . U . . .
H18A H 0.115299 0.076449 0.619815 0.090 Uiso 1 1 calc R U . . .
H18B H 0.033559 0.106432 0.622064 0.090 Uiso 1 1 calc R U . . .
H18C H 0.109059 0.150114 0.638093 0.090 Uiso 1 1 calc R U . . .
C19 C 0.3212(7) 0.0933(6) 0.7471(4) 0.037(2) Uani 1 1 d . U . . .
C20 C 0.2343(6) 0.0907(6) 0.7232(4) 0.044(3) Uani 1 1 d . U . . .
H20A H 0.207727 0.067550 0.745924 0.066 Uiso 1 1 calc R U . . .
H20B H 0.226000 0.067810 0.690805 0.066 Uiso 1 1 calc R U . . .
H20C H 0.214205 0.135285 0.717808 0.066 Uiso 1 1 calc R U . . .
C21 C 0.3318(7) 0.1274(6) 0.7989(4) 0.047(3) Uani 1 1 d . U . . .
H21A H 0.308191 0.170732 0.794448 0.071 Uiso 1 1 calc R U . . .
H21B H 0.386585 0.131819 0.813868 0.071 Uiso 1 1 calc R U . . .
H21C H 0.307482 0.101226 0.821224 0.071 Uiso 1 1 calc R U . . .
C22 C 0.3558(7) 0.0235(6) 0.7517(4) 0.043(3) Uani 1 1 d . U . . .
H22A H 0.329272 -0.003544 0.772242 0.065 Uiso 1 1 calc R U . . .
H22B H 0.410335 0.025771 0.767641 0.065 Uiso 1 1 calc R U . . .
H22C H 0.349482 0.004261 0.717971 0.065 Uiso 1 1 calc R U . . .
C23 C 0.2937(6) 0.4198(5) 0.6053(4) 0.0284(19) Uani 1 1 d . U . . .
C24 C 0.3551(6) 0.4629(5) 0.5895(4) 0.033(2) Uani 1 1 d . U . . .
H24A H 0.332448 0.504925 0.576957 0.049 Uiso 1 1 calc R U . . .
H24B H 0.374532 0.440966 0.562720 0.049 Uiso 1 1 calc R U . . .
H24C H 0.397348 0.470277 0.618602 0.049 Uiso 1 1 calc R U . . .
C25 C 0.2217(6) 0.4156(6) 0.5613(4) 0.038(3) Uani 1 1 d . U . . .
H25A H 0.182238 0.389334 0.571914 0.057 Uiso 1 1 calc R U . . .
H25B H 0.235633 0.395323 0.531910 0.057 Uiso 1 1 calc R U . . .
H25C H 0.201863 0.459671 0.552435 0.057 Uiso 1 1 calc R U . . .
C26 C 0.2734(6) 0.4484(5) 0.6537(3) 0.032(3) Uani 1 1 d . U . . .
H26A H 0.319429 0.449436 0.680942 0.049 Uiso 1 1 calc R U . . .
H26B H 0.234475 0.420968 0.663863 0.049 Uiso 1 1 calc R U . . .
H26C H 0.253492 0.492790 0.646927 0.049 Uiso 1 1 calc R U . . .
C27 C 0.1459(7) 0.3055(7) 0.6836(4) 0.048(2) Uani 1 1 d D U . . .
C30 C 0.500000 0.4945(8) 0.750000 0.036(3) Uani 1 2 d S TU P . .
F00E F 0.0786(11) 0.3607(11) 0.7418(5) 0.055(4) Uani 0.500(10) 1 d D U P A 1
F01E F 0.0086(7) 0.3132(8) 0.6789(6) 0.057(4) Uani 0.500(10) 1 d D U P A 1
F01K F 0.0582(8) 0.4022(7) 0.6699(5) 0.060(3) Uani 0.500(10) 1 d D U P A 1
C29 C 0.0765(9) 0.3449(9) 0.6937(7) 0.050(3) Uani 0.500(10) 1 d D U P A 1
F00F F 0.1002(11) 0.3589(11) 0.7512(6) 0.054(4) Uani 0.500(10) 1 d D U P A 2
F01F F 0.0404(8) 0.2693(7) 0.7215(5) 0.056(3) Uani 0.500(10) 1 d D U P A 2
F01L F 0.0257(8) 0.3565(10) 0.6761(6) 0.058(3) Uani 0.500(10) 1 d D U P A 2
C28 C 0.0780(10) 0.3225(10) 0.7090(7) 0.049(3) Uani 0.500(10) 1 d D U P A 2
F00M F 0.4754(10) 0.5994(9) 0.7848(6) 0.047(4) Uani 0.5 1 d D U P B -1
F1 F 0.4382(10) 0.5931(7) 0.7040(6) 0.075(4) Uani 0.5 1 d D U P B -1
F13 F 0.5617(10) 0.5966(9) 0.7402(7) 0.057(4) Uani 0.5 1 d D U P B -1
C31 C 0.4935(12) 0.5706(8) 0.7436(7) 0.042(3) Uani 0.5 1 d D U P B -1
N3 N 0.2796(6) 0.6398(6) 0.5982(4) 0.059(3) Uani 1 1 d . U . . .
C32 C 0.3180(8) 0.6712(8) 0.6276(4) 0.050(3) Uani 1 1 d . U . . .
C33 C 0.3688(7) 0.7144(8) 0.6653(5) 0.070(4) Uani 1 1 d . U . . .
H33B H 0.369719 0.698485 0.699494 0.105 Uiso 1 1 calc R U . . .
H33A H 0.349143 0.759128 0.661845 0.105 Uiso 1 1 calc R U . . .
H33C H 0.420841 0.713603 0.659282 0.105 Uiso 1 1 calc R U . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Ag6 3.0736(10) 7_556 ?
Ag1 Ag6 3.0736(10) 8_556 ?
Ag1 S2 2.387(3) 2_656 ?
Ag1 S2 2.387(3) . ?
Ag2 Ag2 2.9413(16) 2_656 ?
Ag2 Ag3 2.9044(12) . ?
Ag2 Ag6 2.9369(12) 7_556 ?
Ag2 S4 2.552(3) . ?
Ag2 S5 2.603(3) 7_556 ?
Ag2 S5 2.761(2) 8_556 ?
Ag2 O3 2.338(8) . ?
Ag3 Ag4 2.9469(11) . ?
Ag3 S2 2.506(3) . ?
Ag3 S4 2.724(3) . ?
Ag3 S5 2.700(3) 8_556 ?
Ag3 O2 2.326(8) . ?
Ag4 Ag5 3.1033(12) 7_556 ?
Ag4 Ag7 3.0726(11) 7_556 ?
Ag4 S1 2.410(3) . ?
Ag4 S4 2.482(3) . ?
Ag4 O1 2.432(6) . ?
Ag5 S1 2.796(3) 7_556 ?
Ag5 S2 2.574(2) 7_556 ?
Ag5 S3 2.557(3) . ?
Ag5 N4 2.345(9) . ?
Ag6 S3 2.387(3) . ?
Ag6 S5 2.399(3) . ?
Ag7 S1 2.447(3) . ?
Ag7 S3 2.482(3) . ?
Ag7 S4 2.691(2) 7_556 ?
S1 C15 1.874(10) . ?
S2 C19 1.850(10) . ?
S3 C7 1.875(10) . ?
S4 C23 1.888(11) . ?
S5 C12 1.898(10) . ?
O1 C27 1.230(12) . ?
O2 C27 1.220(14) . ?
O3 C30 1.229(9) . ?
N1 N2 1.313(11) . ?
N1 C1 1.356(13) 7_566 ?
N2 C1 1.356(13) . ?
N4 C4 1.323(14) . ?
N4 C5 1.352(13) . ?
C1 C2 1.480(14) . ?
C2 C3 1.399(14) . ?
C2 C6 1.383(15) . ?
C3 H3 0.9300 . ?
C3 C4 1.386(14) . ?
C4 H4 0.9300 . ?
C5 H5 0.9300 . ?
C5 C6 1.358(15) . ?
C6 H6 0.9300 . ?
C7 C8 1.570(15) . ?
C7 C9 1.512(14) . ?
C7 C10 1.507(13) . ?
C8 H8A 0.9600 . ?
C8 H8B 0.9600 . ?
C8 H8C 0.9600 . ?
C9 H9A 0.9600 . ?
C9 H9B 0.9600 . ?
C9 H9C 0.9600 . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C11 C12 1.496(15) . ?
C12 C13 1.522(16) . ?
C12 C14 1.511(14) . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 C16 1.550(15) . ?
C15 C17 1.496(15) . ?
C15 C18 1.488(13) . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 C20 1.520(15) . ?
C19 C21 1.514(14) . ?
C19 C22 1.520(16) . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 C24 1.512(14) . ?
C23 C25 1.527(14) . ?
C23 C26 1.521(12) . ?
C24 H24A 0.9600 . ?
C24 H24B 0.9600 . ?
C24 H24C 0.9600 . ?
C25 H25A 0.9600 . ?
C25 H25B 0.9600 . ?
C25 H25C 0.9600 . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 C29 1.523(18) . ?
C27 C28 1.530(19) . ?
C30 C31 1.54(2) . ?
F00E C29 1.312(13) . ?
F01E C29 1.332(15) . ?
F01K C29 1.317(15) . ?
F00F C28 1.324(17) . ?
F01F C28 1.334(19) . ?
F01L C28 1.31(2) . ?
F00M C31 1.336(18) . ?
F1 C31 1.346(17) . ?
F13 C31 1.326(18) . ?
N3 C32 1.111(16) . ?
C32 C33 1.471(19) . ?
C33 H33B 0.9600 . ?
C33 H33A 0.9600 . ?
C33 H33C 0.9600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ag6 Ag1 Ag6 114.88(5) 8_556 7_556 ?
S2 Ag1 Ag6 76.34(6) . 7_556 ?
S2 Ag1 Ag6 108.89(7) . 8_556 ?
S2 Ag1 Ag6 76.34(6) 2_656 8_556 ?
S2 Ag1 Ag6 108.89(7) 2_656 7_556 ?
S2 Ag1 S2 170.67(15) . 2_656 ?
Ag3 Ag2 Ag2 108.88(3) . 2_656 ?
Ag3 Ag2 Ag6 76.97(3) . 7_556 ?
Ag6 Ag2 Ag2 101.43(3) 7_556 2_656 ?
S4 Ag2 Ag2 168.27(7) . 2_656 ?
S4 Ag2 Ag3 59.49(6) . . ?
S4 Ag2 Ag6 75.33(6) . 7_556 ?
S4 Ag2 S5 122.46(8) . 7_556 ?
S4 Ag2 S5 114.94(8) . 8_556 ?
S5 Ag2 Ag2 59.37(6) 7_556 2_656 ?
S5 Ag2 Ag2 54.20(6) 8_556 2_656 ?
S5 Ag2 Ag3 56.84(6) 8_556 . ?
S5 Ag2 Ag3 116.13(7) 7_556 . ?
S5 Ag2 Ag6 50.88(6) 7_556 7_556 ?
S5 Ag2 Ag6 101.80(6) 8_556 7_556 ?
S5 Ag2 S5 96.55(9) 7_556 8_556 ?
O3 Ag2 Ag2 81.28(17) . 2_656 ?
O3 Ag2 Ag3 136.5(2) . . ?
O3 Ag2 Ag6 144.2(2) . 7_556 ?
O3 Ag2 S4 108.07(18) . . ?
O3 Ag2 S5 105.5(2) . 7_556 ?
O3 Ag2 S5 108.10(19) . 8_556 ?
Ag2 Ag3 Ag4 105.21(3) . . ?
S2 Ag3 Ag2 111.48(7) . . ?
S2 Ag3 Ag4 94.23(6) . . ?
S2 Ag3 S4 115.90(8) . . ?
S2 Ag3 S5 98.55(9) . 8_556 ?
S4 Ag3 Ag2 53.81(6) . . ?
S4 Ag3 Ag4 51.74(6) . . ?
S5 Ag3 Ag2 58.91(6) 8_556 . ?
S5 Ag3 Ag4 162.52(7) 8_556 . ?
S5 Ag3 S4 111.41(8) 8_556 . ?
O2 Ag3 Ag2 126.8(2) . . ?
O2 Ag3 Ag4 83.18(19) . . ?
O2 Ag3 S2 120.3(2) . . ?
O2 Ag3 S4 108.4(2) . . ?
O2 Ag3 S5 100.4(2) . 8_556 ?
Ag3 Ag4 Ag5 78.31(3) . 7_556 ?
Ag3 Ag4 Ag7 102.82(3) . 7_556 ?
Ag7 Ag4 Ag5 79.59(3) 7_556 7_556 ?
S1 Ag4 Ag3 128.76(7) . . ?
S1 Ag4 Ag5 59.37(7) . 7_556 ?
S1 Ag4 Ag7 96.87(6) . 7_556 ?
S1 Ag4 S4 152.58(9) . . ?
S1 Ag4 O1 109.2(2) . . ?
S4 Ag4 Ag3 59.50(6) . . ?
S4 Ag4 Ag5 104.28(7) . 7_556 ?
S4 Ag4 Ag7 56.75(6) . 7_556 ?
O1 Ag4 Ag3 77.90(17) . . ?
O1 Ag4 Ag5 132.5(2) . 7_556 ?
O1 Ag4 Ag7 145.9(2) . 7_556 ?
O1 Ag4 S4 98.0(2) . . ?
S1 Ag5 Ag4 47.87(6) 7_556 7_556 ?
S2 Ag5 Ag4 89.28(7) 7_556 7_556 ?
S2 Ag5 S1 126.59(9) 7_556 7_556 ?
S3 Ag5 Ag4 84.22(7) . 7_556 ?
S3 Ag5 S1 108.65(8) . 7_556 ?
S3 Ag5 S2 93.63(8) . 7_556 ?
N4 Ag5 Ag4 143.5(2) . 7_556 ?
N4 Ag5 S1 95.8(2) . 7_556 ?
N4 Ag5 S2 116.8(2) . 7_556 ?
N4 Ag5 S3 116.6(2) . . ?
Ag2 Ag6 Ag1 91.83(3) 7_556 7_556 ?
S3 Ag6 Ag1 110.35(7) . 7_556 ?
S3 Ag6 Ag2 126.54(7) . 7_556 ?
S3 Ag6 S5 165.39(9) . . ?
S5 Ag6 Ag1 82.57(6) . 7_556 ?
S5 Ag6 Ag2 57.34(7) . 7_556 ?
S1 Ag7 Ag4 119.43(7) . 7_556 ?
S1 Ag7 S3 149.24(9) . . ?
S1 Ag7 S4 116.07(9) . 7_556 ?
S3 Ag7 Ag4 86.12(6) . 7_556 ?
S3 Ag7 S4 93.06(8) . 7_556 ?
S4 Ag7 Ag4 50.50(6) 7_556 7_556 ?
Ag4 S1 Ag5 72.76(7) . 7_556 ?
Ag4 S1 Ag7 89.04(9) . . ?
Ag7 S1 Ag5 131.21(10) . 7_556 ?
C15 S1 Ag4 110.7(3) . . ?
C15 S1 Ag5 125.0(3) . 7_556 ?
C15 S1 Ag7 103.8(3) . . ?
Ag1 S2 Ag3 102.35(10) . . ?
Ag1 S2 Ag5 129.34(11) . 7_556 ?
Ag3 S2 Ag5 97.57(9) . 7_556 ?
C19 S2 Ag1 103.1(4) . . ?
C19 S2 Ag3 109.3(4) . . ?
C19 S2 Ag5 113.3(4) . 7_556 ?
Ag6 S3 Ag5 106.26(9) . . ?
Ag6 S3 Ag7 97.76(10) . . ?
Ag7 S3 Ag5 103.33(10) . . ?
C7 S3 Ag5 119.3(4) . . ?
C7 S3 Ag6 105.0(3) . . ?
C7 S3 Ag7 122.1(3) . . ?
Ag2 S4 Ag3 66.70(6) . . ?
Ag2 S4 Ag7 126.05(10) . 7_556 ?
Ag4 S4 Ag2 134.85(11) . . ?
Ag4 S4 Ag3 68.76(7) . . ?
Ag4 S4 Ag7 72.75(7) . 7_556 ?
Ag7 S4 Ag3 120.68(10) 7_556 . ?
C23 S4 Ag2 102.6(3) . . ?
C23 S4 Ag3 121.7(3) . . ?
C23 S4 Ag4 106.5(3) . . ?
C23 S4 Ag7 111.4(3) . 7_556 ?
Ag2 S5 Ag2 66.43(7) 7_556 8_455 ?
Ag2 S5 Ag3 127.48(9) 7_556 8_455 ?
Ag3 S5 Ag2 64.25(6) 8_455 8_455 ?
Ag6 S5 Ag2 123.54(10) . 8_455 ?
Ag6 S5 Ag2 71.78(8) . 7_556 ?
Ag6 S5 Ag3 124.44(11) . 8_455 ?
C12 S5 Ag2 120.5(4) . 8_455 ?
C12 S5 Ag2 105.3(4) . 7_556 ?
C12 S5 Ag3 114.2(4) . 8_455 ?
C12 S5 Ag6 105.8(3) . . ?
C27 O1 Ag4 123.0(7) . . ?
C27 O2 Ag3 120.6(7) . . ?
C30 O3 Ag2 122.3(8) . . ?
N2 N1 C1 118.5(9) . 7_566 ?
N1 N2 C1 116.6(9) . . ?
C4 N4 Ag5 126.7(7) . . ?
C4 N4 C5 116.9(10) . . ?
C5 N4 Ag5 116.0(7) . . ?
N1 C1 N2 124.8(9) 7_566 . ?
N1 C1 C2 118.6(9) 7_566 . ?
N2 C1 C2 116.6(9) . . ?
C3 C2 C1 121.2(10) . . ?
C6 C2 C1 119.6(10) . . ?
C6 C2 C3 119.2(10) . . ?
C2 C3 H3 121.4 . . ?
C4 C3 C2 117.3(10) . . ?
C4 C3 H3 121.4 . . ?
N4 C4 C3 124.2(11) . . ?
N4 C4 H4 117.9 . . ?
C3 C4 H4 117.9 . . ?
N4 C5 H5 118.0 . . ?
N4 C5 C6 124.0(11) . . ?
C6 C5 H5 118.0 . . ?
C2 C6 H6 120.8 . . ?
C5 C6 C2 118.5(11) . . ?
C5 C6 H6 120.8 . . ?
C8 C7 S3 106.4(7) . . ?
C9 C7 S3 110.1(7) . . ?
C9 C7 C8 109.9(9) . . ?
C10 C7 S3 108.8(8) . . ?
C10 C7 C8 108.7(10) . . ?
C10 C7 C9 112.8(8) . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9B 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C7 C10 H10A 109.5 . . ?
C7 C10 H10B 109.5 . . ?
C7 C10 H10C 109.5 . . ?
H10A C10 H10B 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
H11A C11 H11B 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C12 C11 H11A 109.5 . . ?
C12 C11 H11B 109.5 . . ?
C12 C11 H11C 109.5 . . ?
C11 C12 S5 106.4(8) . . ?
C11 C12 C13 111.9(10) . . ?
C11 C12 C14 111.0(9) . . ?
C13 C12 S5 106.5(7) . . ?
C14 C12 S5 109.3(7) . . ?
C14 C12 C13 111.4(10) . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13B 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14B 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C16 C15 S1 110.4(8) . . ?
C17 C15 S1 106.8(7) . . ?
C17 C15 C16 109.8(10) . . ?
C18 C15 S1 109.7(8) . . ?
C18 C15 C16 109.1(9) . . ?
C18 C15 C17 111.0(10) . . ?
C15 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
C15 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C15 C17 H17A 109.5 . . ?
C15 C17 H17B 109.5 . . ?
C15 C17 H17C 109.5 . . ?
H17A C17 H17B 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
C15 C18 H18A 109.5 . . ?
C15 C18 H18B 109.5 . . ?
C15 C18 H18C 109.5 . . ?
H18A C18 H18B 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C20 C19 S2 107.2(7) . . ?
C20 C19 C22 110.4(10) . . ?
C21 C19 S2 110.4(8) . . ?
C21 C19 C20 108.0(9) . . ?
C21 C19 C22 112.1(10) . . ?
C22 C19 S2 108.7(7) . . ?
C19 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
C19 C20 H20C 109.5 . . ?
H20A C20 H20B 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C19 C21 H21A 109.5 . . ?
C19 C21 H21B 109.5 . . ?
C19 C21 H21C 109.5 . . ?
H21A C21 H21B 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C19 C22 H22A 109.5 . . ?
C19 C22 H22B 109.5 . . ?
C19 C22 H22C 109.5 . . ?
H22A C22 H22B 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
C24 C23 S4 105.9(7) . . ?
C24 C23 C25 109.7(8) . . ?
C24 C23 C26 109.4(9) . . ?
C25 C23 S4 109.9(7) . . ?
C26 C23 S4 110.5(7) . . ?
C26 C23 C25 111.3(8) . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C23 C25 H25A 109.5 . . ?
C23 C25 H25B 109.5 . . ?
C23 C25 H25C 109.5 . . ?
H25A C25 H25B 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C23 C26 H26A 109.5 . . ?
C23 C26 H26B 109.5 . . ?
C23 C26 H26C 109.5 . . ?
H26A C26 H26B 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
O1 C27 C29 105.4(12) . . ?
O1 C27 C28 121.7(13) . . ?
O2 C27 O1 130.7(11) . . ?
O2 C27 C29 123.6(11) . . ?
O2 C27 C28 106.6(12) . . ?
O3 C30 O3 132.0(16) 2_656 . ?
O3 C30 C31 107.2(10) . . ?
O3 C30 C31 120.8(11) 2_656 . ?
F00E C29 C27 116.3(15) . . ?
F00E C29 F01E 103.7(13) . . ?
F00E C29 F01K 102.1(13) . . ?
F01E C29 C27 113.4(13) . . ?
F01K C29 C27 119.3(14) . . ?
F01K C29 F01E 99.6(13) . . ?
F00F C28 C27 112.6(16) . . ?
F00F C28 F01F 107.5(17) . . ?
F01F C28 C27 113.9(15) . . ?
F01L C28 C27 108.7(15) . . ?
F01L C28 F00F 108.2(18) . . ?
F01L C28 F01F 105.7(16) . . ?
F00M C31 C30 111.4(16) . . ?
F00M C31 F1 103.6(17) . . ?
F1 C31 C30 116.3(13) . . ?
F13 C31 C30 110.7(16) . . ?
F13 C31 F00M 105.3(14) . . ?
F13 C31 F1 108.7(18) . . ?
N3 C32 C33 178.3(16) . . ?
C32 C33 H33B 109.5 . . ?
C32 C33 H33A 109.5 . . ?
C32 C33 H33C 109.5 . . ?
H33B C33 H33A 109.5 . . ?
H33B C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Ag1 S2 C19 C20 173.9(7) . . . . ?
Ag1 S2 C19 C21 56.5(9) . . . . ?
Ag1 S2 C19 C22 -66.8(8) . . . . ?
Ag2 S4 C23 C24 68.0(6) . . . . ?
Ag2 S4 C23 C25 -173.6(6) . . . . ?
Ag2 S4 C23 C26 -50.4(7) . . . . ?
Ag2 S5 C12 C11 154.5(6) 7_556 . . . ?
Ag2 S5 C12 C11 -134.2(6) 8_455 . . . ?
Ag2 S5 C12 C13 -14.6(10) 8_455 . . . ?
Ag2 S5 C12 C13 -86.0(8) 7_556 . . . ?
Ag2 S5 C12 C14 105.8(8) 8_455 . . . ?
Ag2 S5 C12 C14 34.5(8) 7_556 . . . ?
Ag2 O3 C30 O3 4.5(3) . . . 2_656 ?
Ag2 O3 C30 C31 -174.9(9) . . . . ?
Ag3 S2 C19 C20 65.6(8) . . . . ?
Ag3 S2 C19 C21 -51.8(9) . . . . ?
Ag3 S2 C19 C22 -175.1(7) . . . . ?
Ag3 S4 C23 C24 138.2(5) . . . . ?
Ag3 S4 C23 C25 -103.3(6) . . . . ?
Ag3 S4 C23 C26 19.8(9) . . . . ?
Ag3 S5 C12 C11 -60.9(8) 8_455 . . . ?
Ag3 S5 C12 C13 58.6(9) 8_455 . . . ?
Ag3 S5 C12 C14 179.1(7) 8_455 . . . ?
Ag3 O2 C27 O1 17(2) . . . . ?
Ag3 O2 C27 C29 -157.4(11) . . . . ?
Ag3 O2 C27 C28 -174.3(9) . . . . ?
Ag4 S1 C15 C16 51.2(7) . . . . ?
Ag4 S1 C15 C17 170.5(7) . . . . ?
Ag4 S1 C15 C18 -69.1(9) . . . . ?
Ag4 S4 C23 C24 -146.9(6) . . . . ?
Ag4 S4 C23 C25 -28.5(7) . . . . ?
Ag4 S4 C23 C26 94.7(7) . . . . ?
Ag4 O1 C27 O2 3(2) . . . . ?
Ag4 O1 C27 C29 178.2(9) . . . . ?
Ag4 O1 C27 C28 -164.3(11) . . . . ?
Ag5 S1 C15 C16 134.2(6) 7_556 . . . ?
Ag5 S1 C15 C17 -106.5(8) 7_556 . . . ?
Ag5 S1 C15 C18 13.9(10) 7_556 . . . ?
Ag5 S2 C19 C20 -42.1(9) 7_556 . . . ?
Ag5 S2 C19 C21 -159.4(7) 7_556 . . . ?
Ag5 S2 C19 C22 77.3(8) 7_556 . . . ?
Ag5 S3 C7 C8 35.5(8) . . . . ?
Ag5 S3 C7 C9 154.5(6) . . . . ?
Ag5 S3 C7 C10 -81.4(8) . . . . ?
Ag5 N4 C4 C3 169.6(7) . . . . ?
Ag5 N4 C5 C6 -171.4(8) . . . . ?
Ag6 S3 C7 C8 -83.3(7) . . . . ?
Ag6 S3 C7 C9 35.7(7) . . . . ?
Ag6 S3 C7 C10 159.7(7) . . . . ?
Ag6 S5 C12 C11 79.5(7) . . . . ?
Ag6 S5 C12 C13 -160.9(7) . . . . ?
Ag6 S5 C12 C14 -40.5(8) . . . . ?
Ag7 S1 C15 C16 -43.1(7) . . . . ?
Ag7 S1 C15 C17 76.3(8) . . . . ?
Ag7 S1 C15 C18 -163.3(8) . . . . ?
Ag7 S3 C7 C8 167.2(6) . . . . ?
Ag7 S3 C7 C9 -73.9(7) . . . . ?
Ag7 S3 C7 C10 50.2(9) . . . . ?
Ag7 S4 C23 C24 -69.4(7) 7_556 . . . ?
Ag7 S4 C23 C25 49.0(7) 7_556 . . . ?
Ag7 S4 C23 C26 172.2(6) 7_556 . . . ?
O1 C27 C29 F00E -170.0(15) . . . . ?
O1 C27 C29 F01E 69.9(17) . . . . ?
O1 C27 C29 F01K -46.9(18) . . . . ?
O1 C27 C28 F00F -141.3(18) . . . . ?
O1 C27 C28 F01F 96.1(19) . . . . ?
O1 C27 C28 F01L -21(2) . . . . ?
O2 C27 C29 F00E 5(2) . . . . ?
O2 C27 C29 F01E -114.7(17) . . . . ?
O2 C27 C29 F01K 128.4(16) . . . . ?
O2 C27 C28 F00F 49(2) . . . . ?
O2 C27 C28 F01F -74.1(18) . . . . ?
O2 C27 C28 F01L 168.4(15) . . . . ?
O3 C30 C31 F00M 134.4(14) . . . . ?
O3 C30 C31 F00M -45.1(19) 2_656 . . . ?
O3 C30 C31 F1 -163.6(14) 2_656 . . . ?
O3 C30 C31 F1 15.9(19) . . . . ?
O3 C30 C31 F13 -108.8(15) . . . . ?
O3 C30 C31 F13 71.6(18) 2_656 . . . ?
N1 N2 C1 N1 0.6(14) . . . 7_566 ?
N1 N2 C1 C2 -179.3(8) . . . . ?
N1 C1 C2 C3 21.7(13) 7_566 . . . ?
N1 C1 C2 C6 -158.2(8) 7_566 . . . ?
N2 C1 C2 C3 -158.5(9) . . . . ?
N2 C1 C2 C6 21.7(12) . . . . ?
N4 C5 C6 C2 -1.0(15) . . . . ?
C1 N1 N2 C1 -0.5(13) 7_566 . . . ?
C1 C2 C3 C4 178.1(8) . . . . ?
C1 C2 C6 C5 -178.9(9) . . . . ?
C2 C3 C4 N4 2.8(15) . . . . ?
C3 C2 C6 C5 1.2(14) . . . . ?
C4 N4 C5 C6 1.5(14) . . . . ?
C5 N4 C4 C3 -2.5(15) . . . . ?
C6 C2 C3 C4 -2.1(13) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
