# Supplementary Information (SI) for Materials Chemistry Frontiers.
# This journal is © the Partner Organisations 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_Am-MIL-103
_database_code_depnum_ccdc_archive 'CCDC 2503007'
loop_
_audit_author_name
_audit_author_address
'Mikhail Grigoriev'
;IPCE RAS
Russia
;
_audit_update_record             
;
2025-11-14 deposited with the CCDC.	2026-03-23 downloaded from the CCDC.
;
_audit_creation_date             2025-10-29
_audit_creation_method           
;
Olex2 1.5
(compiled 2025.03.04 svn.red2d20d0 for OlexSys, GUI svn.r7188)
;
_shelx_SHELXL_version_number     2018/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C27 H17 Am O7, 0.111[], 0.111[], 0.111[]'
_chemical_formula_sum            'C27 H17 Am O7'
_chemical_formula_weight         696.41
_chemical_absolute_configuration ?
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Am Am -7.8986 4.5125 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      trigonal
_space_group_IT_number           155
_space_group_name_H-M_alt        'R 3 2'
_space_group_name_Hall           'R 3 2"'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+1/3'
'x-y+2/3, -y+1/3, -z+1/3'
'-x+2/3, -x+y+1/3, -z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+2/3'
'x-y+1/3, -y+2/3, -z+2/3'
'-x+1/3, -x+y+2/3, -z+2/3'

_cell_length_a                   28.767(2)
_cell_length_b                   28.767(2)
_cell_length_c                   12.2277(16)
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_volume                     8763.4(17)
_cell_formula_units_Z            9
_cell_measurement_reflns_used    2144
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      18.611
_cell_measurement_theta_min      2.833
_shelx_estimated_absorpt_T_max   0.890
_shelx_estimated_absorpt_T_min   0.533
_exptl_absorpt_coefficient_mu    1.997
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7387
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1023 before and 0.0873 after correction.
The Ratio of minimum to maximum transmission is 0.7387.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.188
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       needle
_exptl_crystal_F_000             2970
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.1458
_diffrn_reflns_av_unetI/netI     0.0973
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       34
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -34
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            26642
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        24.997
_diffrn_reflns_theta_max         24.997
_diffrn_reflns_theta_min         4.251
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean ?
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  
'Bruker KAPPA APEX II area-detector diffractometer'
_diffrn_measurement_method       ?
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_source                   ?
_reflns_Friedel_coverage         0.882
_reflns_Friedel_fraction_full    0.995
_reflns_Friedel_fraction_max     0.995
_reflns_number_gt                3046
_reflns_number_total             3429
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       ?
_computing_data_collection       ?
_computing_data_reduction        ?
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    ?
_refine_diff_density_max         2.392
_refine_diff_density_min         -1.859
_refine_diff_density_rms         0.170
_refine_ls_abs_structure_details 
;
 Flack x determined using 1130 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons, Flack and Wagner, Acta Cryst. B69 (2013) 249-259).
;
_refine_ls_abs_structure_Flack   -0.09(2)
_refine_ls_extinction_coef       0.00050(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2018/3 (Sheldrick 2018)'
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     76
_refine_ls_number_reflns         3429
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0631
_refine_ls_R_factor_gt           0.0545
_refine_ls_restrained_S_all      1.016
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0592P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1140
_refine_ls_wR_factor_ref         0.1176
_refine_special_details          SQUEEZE
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
: with sigma of 0.001 and sigma for terminal atoms of 0.002
3. Others
 Fixed Sof: H2A(0.5) H2B(0.5)
4.a Rotating group:
 O2(H2A,H2B)
4.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C9(H9), C11(H11), C4(H4), C12(H12), C8(H8), C16(H16), C14(H14)
;
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     ?
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Am1 Am 0.666667 0.65682(2) 0.333333 0.0193(3) Uani 1 2 d S T P . .
O4 O 0.6103(3) 0.6980(3) 0.2794(6) 0.0009(17) Uiso 1 1 d . . . . .
O3 O 0.6799(3) 0.7252(3) 0.1686(5) 0.0001(17) Uiso 1 1 d . . . . .
O1 O 0.5803(4) 0.5983(4) 0.4172(7) 0.012(2) Uiso 1 1 d . . . . .
C3 C 0.4729(5) 0.5108(5) 0.4395(10) 0.005(3) Uiso 1 1 d . . . . .
H3 H 0.476330 0.540138 0.397503 0.006 Uiso 1 1 calc R U . . .
C9 C 0.6879(5) 0.8740(5) 0.1323(9) 0.003(3) Uiso 1 1 d . . . . .
H9 H 0.716913 0.902258 0.093661 0.004 Uiso 1 1 calc R U . . .
C11 C 0.6078(5) 0.8413(5) 0.2446(9) 0.006(3) Uiso 1 1 d . . . . .
H11 H 0.581068 0.846126 0.280102 0.007 Uiso 1 1 calc R U . . .
C4 C 0.4244(5) 0.4634(5) 0.4386(10) 0.003(3) Uiso 1 1 d . . . . .
H4 H 0.394950 0.460374 0.397627 0.004 Uiso 1 1 calc R U . . .
C12 C 0.6069(5) 0.7927(5) 0.2520(9) 0.003(3) Uiso 1 1 d . . . . .
H12 H 0.579867 0.764480 0.294537 0.004 Uiso 1 1 calc R U . . .
C8 C 0.6845(5) 0.8261(5) 0.1375(10) 0.006(3) Uiso 1 1 d . . . . .
H8 H 0.709681 0.820258 0.098679 0.008 Uiso 1 1 calc R U . . .
C6 C 0.6438(5) 0.7322(4) 0.2139(8) -0.001(2) Uiso 1 1 d . . . . .
C16 C 0.6029(6) 0.9362(6) 0.166667 0.002(4) Uiso 1 2 d S . P . .
H16 H 0.569892 0.903224 0.166667 0.003 Uiso 1 2 calc R U P . .
C7 C 0.6447(5) 0.7847(5) 0.1986(9) 0.003(3) Uiso 1 1 d . . . . .
O2 O 0.666667 0.5710(5) 0.333333 0.025(4) Uiso 1 2 d S . P . .
H2A H 0.641843 0.537340 0.373384 0.038 Uiso 0.5 1 d R U P . .
H2B H 0.691491 0.562162 0.293283 0.038 Uiso 0.5 1 d R U P . .
C2 C 0.5175(6) 0.5175(6) 0.500000 0.000(3) Uiso 1 2 d S . P . .
C5 C 0.4192(6) 0.4192(6) 0.500000 0.001(4) Uiso 1 2 d S . P . .
C10 C 0.6491(5) 0.8839(5) 0.1830(9) 0.004(3) Uiso 1 1 d . . . . .
C14 C 0.6989(5) 0.9851(5) 0.1743(9) 0.004(3) Uiso 1 1 d . . . . .
H14 H 0.731809 0.984967 0.179345 0.004 Uiso 1 1 calc R U . . .
C13 C 0.6505(5) 0.9361(5) 0.1748(10) 0.006(3) Uiso 1 1 d . . . . .
C1 C 0.5693(6) 0.5693(6) 0.500000 0.007(4) Uiso 1 2 d S . P . .
C15 C 0.7000(6) 1.0333(6) 0.166667 0.001(4) Uiso 1 2 d S . P . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Am1 O4 2.528(7) . ?
Am1 O4 2.528(7) 18_655 ?
Am1 O3 2.467(7) 9_565 ?
Am1 O3 2.706(7) 18_655 ?
Am1 O3 2.706(7) . ?
Am1 O3 2.467(7) 11_565 ?
Am1 O1 2.424(9) . ?
Am1 O1 2.424(9) 18_655 ?
Am1 O2 2.469(15) . ?
O4 C6 1.261(13) . ?
O3 C6 1.278(14) . ?
O1 C1 1.248(12) . ?
C3 H3 0.9500 . ?
C3 C4 1.380(17) . ?
C3 C2 1.408(14) . ?
C9 H9 0.9500 . ?
C9 C8 1.333(17) . ?
C9 C10 1.423(17) . ?
C11 H11 0.9500 . ?
C11 C12 1.390(17) . ?
C11 C10 1.423(17) . ?
C4 H4 0.9500 . ?
C4 C5 1.418(14) . ?
C12 H12 0.9500 . ?
C12 C7 1.383(17) . ?
C8 H8 0.9500 . ?
C8 C7 1.388(17) . ?
C6 C7 1.509(16) . ?
C16 H16 0.9500 . ?
C16 C13 1.373(15) . ?
C16 C13 1.373(15) 10_455 ?
O2 H2A 0.9981 . ?
O2 H2B 0.9981 . ?
C2 C1 1.49(2) . ?
C5 C15 1.51(2) 7_445 ?
C10 C13 1.487(17) . ?
C14 H14 0.9500 . ?
C14 C13 1.402(18) . ?
C14 C15 1.376(15) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O4 Am1 O4 75.7(4) 18_655 . ?
O4 Am1 O3 49.8(2) . . ?
O4 Am1 O3 66.9(2) 18_655 . ?
O4 Am1 O3 66.9(2) . 18_655 ?
O4 Am1 O3 49.8(2) 18_655 18_655 ?
O3 Am1 O4 76.6(2) 11_565 . ?
O3 Am1 O4 76.6(2) 9_565 18_655 ?
O3 Am1 O4 135.4(2) 11_565 18_655 ?
O3 Am1 O4 135.4(2) 9_565 . ?
O3 Am1 O3 97.9(3) 18_655 . ?
O3 Am1 O3 68.5(3) 11_565 . ?
O3 Am1 O3 139.97(12) 9_565 . ?
O3 Am1 O3 68.5(3) 9_565 18_655 ?
O3 Am1 O3 144.7(3) 9_565 11_565 ?
O3 Am1 O3 139.97(12) 11_565 18_655 ?
O3 Am1 O2 72.33(17) 11_565 . ?
O3 Am1 O2 72.33(17) 9_565 . ?
O1 Am1 O4 121.8(3) 18_655 . ?
O1 Am1 O4 76.2(3) . . ?
O1 Am1 O4 121.8(3) . 18_655 ?
O1 Am1 O4 76.2(3) 18_655 18_655 ?
O1 Am1 O3 83.8(3) . 11_565 ?
O1 Am1 O3 83.8(3) 18_655 9_565 ?
O1 Am1 O3 89.9(3) . 9_565 ?
O1 Am1 O3 89.9(3) 18_655 11_565 ?
O1 Am1 O3 122.8(3) 18_655 18_655 ?
O1 Am1 O3 72.3(3) 18_655 . ?
O1 Am1 O3 122.8(3) . . ?
O1 Am1 O3 72.3(3) . 18_655 ?
O1 Am1 O1 159.0(4) . 18_655 ?
O1 Am1 O2 79.5(2) 18_655 . ?
O1 Am1 O2 79.5(2) . . ?
O2 Am1 O4 142.14(18) . 18_655 ?
O2 Am1 O4 142.15(18) . . ?
O2 Am1 O3 131.04(16) . 18_655 ?
O2 Am1 O3 131.04(16) . . ?
C6 O4 Am1 96.4(6) . . ?
Am1 O3 Am1 104.9(3) 14_654 . ?
C6 O3 Am1 130.3(7) . 14_654 ?
C6 O3 Am1 87.8(6) . . ?
C1 O1 Am1 129.5(8) . . ?
C4 C3 H3 118.6 . . ?
C4 C3 C2 122.7(12) . . ?
C2 C3 H3 118.6 . . ?
C8 C9 H9 119.2 . . ?
C8 C9 C10 121.7(12) . . ?
C10 C9 H9 119.2 . . ?
C12 C11 H11 120.4 . . ?
C12 C11 C10 119.1(11) . . ?
C10 C11 H11 120.4 . . ?
C3 C4 H4 120.6 . . ?
C3 C4 C5 118.9(11) . . ?
C5 C4 H4 120.6 . . ?
C11 C12 H12 119.4 . . ?
C7 C12 C11 121.2(11) . . ?
C7 C12 H12 119.4 . . ?
C9 C8 H8 119.4 . . ?
C9 C8 C7 121.1(12) . . ?
C7 C8 H8 119.4 . . ?
O4 C6 O3 121.2(10) . . ?
O4 C6 C7 118.8(10) . . ?
O3 C6 C7 119.7(10) . . ?
C13 C16 H16 119.8 10_455 . ?
C13 C16 H16 119.8 . . ?
C13 C16 C13 120.4(16) . 10_455 ?
C12 C7 C8 119.3(11) . . ?
C12 C7 C6 119.2(11) . . ?
C8 C7 C6 121.4(11) . . ?
Am1 O2 H2A 127.8 . . ?
Am1 O2 H2B 127.8 . . ?
H2A O2 H2B 104.4 . . ?
C3 C2 C3 116.8(15) . 4_556 ?
C3 C2 C1 121.6(8) 4_556 . ?
C3 C2 C1 121.6(8) . . ?
C4 C5 C4 120.0(15) . 4_556 ?
C4 C5 C15 120.0(8) 4_556 7_445 ?
C4 C5 C15 120.0(8) . 7_445 ?
C9 C10 C13 123.1(11) . . ?
C11 C10 C9 117.4(11) . . ?
C11 C10 C13 119.5(11) . . ?
C13 C14 H14 119.2 . . ?
C15 C14 H14 119.2 . . ?
C15 C14 C13 121.6(12) . . ?
C16 C13 C10 119.0(12) . . ?
C16 C13 C14 119.3(12) . . ?
C14 C13 C10 121.7(11) . . ?
O1 C1 O1 125.1(17) . 4_556 ?
O1 C1 C2 117.4(8) 4_556 . ?
O1 C1 C2 117.4(8) . . ?
C14 C15 C5 121.1(8) 10_455 13_554 ?
C14 C15 C5 121.1(8) . 13_554 ?
C14 C15 C14 117.9(16) . 10_455 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Am1 O4 C6 O3 23.4(11) . . . . ?
Am1 O4 C6 C7 -150.0(9) . . . . ?
Am1 O3 C6 O4 -21.6(10) . . . . ?
Am1 O3 C6 O4 86.2(12) 14_654 . . . ?
Am1 O3 C6 C7 151.7(9) . . . . ?
Am1 O3 C6 C7 -100.5(11) 14_654 . . . ?
Am1 O1 C1 O1 34.2(6) . . . 4_556 ?
Am1 O1 C1 C2 -145.8(6) . . . . ?
O4 C6 C7 C12 -3.6(16) . . . . ?
O4 C6 C7 C8 172.5(11) . . . . ?
O3 C6 C7 C12 -177.1(10) . . . . ?
O3 C6 C7 C8 -0.9(17) . . . . ?
C3 C4 C5 C4 0.4(8) . . . 4_556 ?
C3 C4 C5 C15 -179.6(8) . . . 7_445 ?
C3 C2 C1 O1 152.0(7) 4_556 . . . ?
C3 C2 C1 O1 -28.0(7) 4_556 . . 4_556 ?
C3 C2 C1 O1 -28.0(7) . . . . ?
C3 C2 C1 O1 152.0(7) . . . 4_556 ?
C9 C8 C7 C12 2.2(18) . . . . ?
C9 C8 C7 C6 -174.0(11) . . . . ?
C9 C10 C13 C16 143.0(11) . . . . ?
C9 C10 C13 C14 -36.5(17) . . . . ?
C11 C12 C7 C8 0.7(18) . . . . ?
C11 C12 C7 C6 176.9(10) . . . . ?
C11 C10 C13 C16 -37.4(15) . . . . ?
C11 C10 C13 C14 143.1(12) . . . . ?
C4 C3 C2 C3 0.4(8) . . . 4_556 ?
C4 C3 C2 C1 -179.6(8) . . . . ?
C12 C11 C10 C9 -0.2(17) . . . . ?
C12 C11 C10 C13 -179.8(11) . . . . ?
C8 C9 C10 C11 3.0(17) . . . . ?
C8 C9 C10 C13 -177.3(11) . . . . ?
C2 C3 C4 C5 -0.8(16) . . . . ?
C10 C9 C8 C7 -4.1(19) . . . . ?
C10 C11 C12 C7 -1.6(18) . . . . ?
C13 C16 C13 C10 -179.7(12) 10_455 . . . ?
C13 C16 C13 C14 -0.2(8) 10_455 . . . ?
C13 C14 C15 C5 179.8(8) . . . 13_554 ?
C13 C14 C15 C14 -0.2(8) . . . 10_455 ?
C15 C14 C13 C16 0.5(16) . . . . ?
C15 C14 C13 C10 180.0(9) . . . . ?

_platon_squeeze_details          ?
_platon_squeeze_special_details  ?
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.000 0.000 -0.006 1435 579 ' '
2 0.333 0.667 0.647 1438 578 ' '
3 0.667 0.333 0.313 1437 578 ' '

_platon_squeeze_void_probe_radius 1.20
_olex2_submission_special_instructions 'No special instructions were received'

# start Validation Reply Form
_vrf_PLAT201_Am-MIL-103          
;
PROBLEM: Isotropic non-H Atoms in Main Residue(s) ....... 20 Report
RESPONSE: Anisotropic refinement of light atoms does not improve the model; 
these atoms were refined isotropically.
;
_vrf_PLAT203_Am-MIL-103          
;
PROBLEM: Negative Isotropic ADP for C6 ........... -0.001 Report
RESPONSE: The negative isotropic ADP is due to numerical instability
in the anisotropic refinement of a poorly defined site (weak data).
C6 has been modelled isotropically; this does not alter the chemical
interpretation.
.
;
_vrf_PLAT220_Am-MIL-103          
;
PROBLEM: NonSolvent Resd 1 C Ueq(max)/Ueq(min) Range 10.0 Ratio
RESPONSE: The anomalous Ueq is attributed to limited data quality (weak 
diffraction, bad crystal) and does not affect the chemical conclusions.
;
_vrf_PLAT420_Am-MIL-103          
;
PROBLEM: D-H Bond Without Acceptor O2 --H2A . Please Check
RESPONSE: The electron density of the solvent with which the water molecule
could interact was removed by squeezing.
;
_vrf_PLAT910_Am-MIL-103          
;
PROBLEM: Missing FCF Reflection(s) Below Theta(Min)[Deg]= 4.25 Note
RESPONSE: Closed by beamstop.
;
# end Validation Reply Form
