# Supplementary Information (SI) for Chemical Science.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
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data_230830lu_lgpz264676_0m
_database_code_depnum_ccdc_archive 'CCDC 2366841'
loop_
_audit_author_name
_audit_author_address
'Kun Zhou'
;Zhejiang University of Technology
China
;
_audit_update_record             
;
2024-07-01 deposited with the CCDC.	2026-04-24 downloaded from the CCDC.
;
_audit_creation_date             2023-09-05
_audit_creation_method           
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number     2019/3
_chemical_name_common            ?
_chemical_name_systematic        ?
_chemical_formula_moiety         'C23 H19 Cl F N O2'
_chemical_formula_sum            'C23 H19 Cl F N O2'
_chemical_formula_weight         395.84
_chemical_melting_point          ?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0137 0.0067 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3281 0.5435 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0583 0.0400 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0241 0.0134 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0389 0.0241 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment       
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_H-M_alt        'C 1 2/c 1'
_space_group_name_Hall           '-C 2yc'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   33.0613(18)
_cell_length_b                   7.2094(4)
_cell_length_c                   15.6708(8)
_cell_angle_alpha                90
_cell_angle_beta                 91.011(2)
_cell_angle_gamma                90
_cell_volume                     3734.6(3)
_cell_formula_units_Z            8
_cell_measurement_reflns_used    9915
_cell_measurement_temperature    193.00
_cell_measurement_theta_max      60.18
_cell_measurement_theta_min      2.33
_shelx_estimated_absorpt_T_max   0.877
_shelx_estimated_absorpt_T_min   0.844
_exptl_absorpt_coefficient_mu    1.350
_exptl_absorpt_correction_T_max  0.7518
_exptl_absorpt_correction_T_min  0.6029
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1337 before and 0.0633 after correction.
The Ratio of minimum to maximum transmission is 0.8019.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details   ?
_exptl_crystal_colour            ?
_exptl_crystal_density_diffrn    1.408
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    ?
_exptl_crystal_description       block
_exptl_crystal_F_000             1648
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   ?
_exptl_transmission_factor_min   ?
_diffrn_reflns_av_R_equivalents  0.0355
_diffrn_reflns_av_unetI/netI     0.0237
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.966
_diffrn_reflns_limit_h_max       42
_diffrn_reflns_limit_h_min       -41
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            23529
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.966
_diffrn_reflns_theta_full        53.594
_diffrn_reflns_theta_max         60.286
_diffrn_reflns_theta_min         2.326
_diffrn_ambient_temperature      193.00
_diffrn_detector                 CPAD
_diffrn_detector_area_resol_mean 7.41
_diffrn_detector_type            'Bruker PHOTON II'
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.966
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Bruker D8 VENTURE Metaljet PHOTON II'
_diffrn_measurement_method       'ω and φ shutterless scans'
_diffrn_measurement_specimen_support 'nylon loop'
_diffrn_radiation_monochromator  'Helios Multi-layer Optic'
_diffrn_radiation_probe          X-ray
_diffrn_radiation_type           GaK\a
_diffrn_radiation_wavelength     1.34139
_diffrn_source                   MetalJet
_diffrn_source_current           2.86
_diffrn_source_power             0.19937059999999998
_diffrn_source_type              'Liquid Metal source'
_diffrn_source_voltage           69.71
_diffrn_standards_number         0
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                3541
_reflns_number_total             4123
_reflns_special_details          
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression     'I > 2σ(I)'
_computing_cell_refinement       'SAINT V8.40B (Bruker, 2019)'
_computing_data_collection       'APEX5 V2022.08-RC130 (Bruker, 2023)'
_computing_data_reduction        'SAINT V8.40B (Bruker, 2019)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.265
_refine_diff_density_min         -0.350
_refine_diff_density_rms         0.041
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     253
_refine_ls_number_reflns         4123
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0450
_refine_ls_R_factor_gt           0.0378
_refine_ls_restrained_S_all      1.045
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0443P)²+3.3297P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0957
_refine_ls_wR_factor_ref         0.1003
_refine_special_details          ?
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C17(H17A,H17B), C14(H14A,H14B), C16(H16A,H16B), C15(H15A,H15B)
2.b Aromatic/amide H refined with riding coordinates:
 C10(H10), C7(H7), C9(H9), C8(H8), C1(H1), C19(H19), C21(H21), C3(H3),
 C23(H23), C2(H2), C22(H22)
;
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   ?
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cl1 Cl 0.60110(2) 0.46530(5) 0.21194(3) 0.04358(13) Uani 1 1 d . . . . .
O2 O 0.61803(3) 0.55728(13) 0.42983(6) 0.0258(2) Uani 1 1 d . . . . .
O1 O 0.59544(3) 0.79178(16) 0.51068(7) 0.0365(3) Uani 1 1 d . . . . .
F1 F 0.73653(4) 0.24127(17) 0.60546(8) 0.0715(4) Uani 1 1 d . . . . .
N1 N 0.59018(4) 0.81451(18) 0.18210(7) 0.0316(3) Uani 1 1 d . . . . .
C11 C 0.57904(4) 0.47940(18) 0.42789(8) 0.0230(3) Uani 1 1 d . . . . .
C6 C 0.55028(4) 0.54627(18) 0.36969(8) 0.0227(3) Uani 1 1 d . . . . .
C4 C 0.55933(4) 0.70245(19) 0.31108(8) 0.0239(3) Uani 1 1 d . . . . .
C10 C 0.57132(4) 0.3350(2) 0.48273(8) 0.0280(3) Uani 1 1 d . . . . .
H10 H 0.591675 0.291589 0.521328 0.034 Uiso 1 1 calc R U . . .
C5 C 0.58177(4) 0.68185(19) 0.23706(8) 0.0257(3) Uani 1 1 d . . . . .
C12 C 0.62283(4) 0.71558(19) 0.47624(8) 0.0255(3) Uani 1 1 d . . . . .
C7 C 0.51207(4) 0.4645(2) 0.37006(9) 0.0276(3) Uani 1 1 d . . . . .
H7 H 0.491558 0.508718 0.332029 0.033 Uiso 1 1 calc R U . . .
C13 C 0.66716(4) 0.7774(2) 0.48059(9) 0.0278(3) Uani 1 1 d . . . . .
C18 C 0.68625(4) 0.6747(2) 0.55629(9) 0.0285(3) Uani 1 1 d . . . . .
C9 C 0.53329(5) 0.2542(2) 0.48058(9) 0.0316(3) Uani 1 1 d . . . . .
H9 H 0.527605 0.153222 0.517422 0.038 Uiso 1 1 calc R U . . .
C8 C 0.50356(4) 0.3195(2) 0.42518(9) 0.0315(3) Uani 1 1 d . . . . .
H8 H 0.477364 0.265325 0.424833 0.038 Uiso 1 1 calc R U . . .
C17 C 0.68852(4) 0.7451(2) 0.39520(9) 0.0330(3) Uani 1 1 d . . . . .
H17A H 0.718280 0.750165 0.403009 0.040 Uiso 1 1 calc R U . . .
H17B H 0.680968 0.623231 0.370548 0.040 Uiso 1 1 calc R U . . .
C1 C 0.57603(5) 0.9841(2) 0.19914(10) 0.0348(3) Uani 1 1 d . . . . .
H1 H 0.581601 1.081770 0.160401 0.042 Uiso 1 1 calc R U . . .
C19 C 0.70304(5) 0.4996(2) 0.54607(10) 0.0377(4) Uani 1 1 d . . . . .
H19 H 0.703335 0.442691 0.491413 0.045 Uiso 1 1 calc R U . . .
C14 C 0.66843(5) 0.9902(2) 0.48805(11) 0.0376(4) Uani 1 1 d . . . . .
H14A H 0.647414 1.035398 0.527194 0.045 Uiso 1 1 calc R U . . .
H14B H 0.695247 1.032664 0.509287 0.045 Uiso 1 1 calc R U . . .
C21 C 0.71949(5) 0.4839(3) 0.69671(10) 0.0402(4) Uani 1 1 d . . . . .
H21 H 0.730651 0.417913 0.744022 0.048 Uiso 1 1 calc R U . . .
C3 C 0.54535(5) 0.8807(2) 0.32618(10) 0.0365(3) Uani 1 1 d . . . . .
H3 H 0.529838 0.905036 0.375397 0.044 Uiso 1 1 calc R U . . .
C23 C 0.68640(4) 0.7530(2) 0.63731(9) 0.0362(3) Uani 1 1 d . . . . .
H23 H 0.675096 0.872735 0.645448 0.043 Uiso 1 1 calc R U . . .
C2 C 0.55380(6) 1.0232(2) 0.27013(11) 0.0423(4) Uani 1 1 d . . . . .
H2 H 0.544438 1.145592 0.280538 0.051 Uiso 1 1 calc R U . . .
C20 C 0.71928(5) 0.4097(2) 0.61632(11) 0.0413(4) Uani 1 1 d . . . . .
C22 C 0.70298(5) 0.6573(3) 0.70651(10) 0.0423(4) Uani 1 1 d . . . . .
H22 H 0.702893 0.712772 0.761504 0.051 Uiso 1 1 calc R U . . .
C16 C 0.67349(5) 0.9037(3) 0.33786(10) 0.0422(4) Uani 1 1 d . . . . .
H16A H 0.695415 0.947146 0.300573 0.051 Uiso 1 1 calc R U . . .
H16B H 0.650476 0.861861 0.301432 0.051 Uiso 1 1 calc R U . . .
C15 C 0.66023(7) 1.0589(3) 0.39714(12) 0.0558(5) Uani 1 1 d . . . . .
H15A H 0.631097 1.085875 0.388367 0.067 Uiso 1 1 calc R U . . .
H15B H 0.675814 1.173374 0.386065 0.067 Uiso 1 1 calc R U . . .


_geom_special_details            
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cl1 C5 1.7348(14) . ?
O2 C11 1.4058(15) . ?
O2 C12 1.3610(16) . ?
O1 C12 1.1960(17) . ?
F1 C20 1.354(2) . ?
N1 C5 1.3200(18) . ?
N1 C1 1.337(2) . ?
C11 C6 1.3921(18) . ?
C11 C10 1.3767(19) . ?
C6 C4 1.4868(18) . ?
C6 C7 1.3939(18) . ?
C4 C5 1.3958(18) . ?
C4 C3 1.387(2) . ?
C10 H10 0.9500 . ?
C10 C9 1.385(2) . ?
C12 C13 1.5323(18) . ?
C7 H7 0.9500 . ?
C7 C8 1.388(2) . ?
C13 C18 1.526(2) . ?
C13 C17 1.5417(19) . ?
C13 C14 1.539(2) . ?
C18 C19 1.389(2) . ?
C18 C23 1.390(2) . ?
C9 H9 0.9500 . ?
C9 C8 1.383(2) . ?
C8 H8 0.9500 . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C17 C16 1.532(2) . ?
C1 H1 0.9500 . ?
C1 C2 1.373(2) . ?
C19 H19 0.9500 . ?
C19 C20 1.378(2) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C14 C15 1.528(2) . ?
C21 H21 0.9500 . ?
C21 C20 1.369(2) . ?
C21 C22 1.374(3) . ?
C3 H3 0.9500 . ?
C3 C2 1.384(2) . ?
C23 H23 0.9500 . ?
C23 C22 1.390(2) . ?
C2 H2 0.9500 . ?
C22 H22 0.9500 . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C16 C15 1.523(3) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C12 O2 C11 116.41(10) . . ?
C5 N1 C1 116.97(12) . . ?
C6 C11 O2 119.43(12) . . ?
C10 C11 O2 117.94(11) . . ?
C10 C11 C6 122.60(12) . . ?
C11 C6 C4 121.63(11) . . ?
C11 C6 C7 117.35(12) . . ?
C7 C6 C4 121.00(12) . . ?
C5 C4 C6 123.27(12) . . ?
C3 C4 C6 121.64(12) . . ?
C3 C4 C5 115.09(12) . . ?
C11 C10 H10 120.6 . . ?
C11 C10 C9 118.75(13) . . ?
C9 C10 H10 120.6 . . ?
N1 C5 Cl1 114.92(10) . . ?
N1 C5 C4 125.90(13) . . ?
C4 C5 Cl1 119.19(11) . . ?
O2 C12 C13 111.72(11) . . ?
O1 C12 O2 122.96(12) . . ?
O1 C12 C13 125.29(13) . . ?
C6 C7 H7 119.5 . . ?
C8 C7 C6 120.99(13) . . ?
C8 C7 H7 119.5 . . ?
C12 C13 C17 111.70(11) . . ?
C12 C13 C14 108.54(12) . . ?
C18 C13 C12 105.99(11) . . ?
C18 C13 C17 114.34(12) . . ?
C18 C13 C14 114.49(12) . . ?
C14 C13 C17 101.78(12) . . ?
C19 C18 C13 120.80(13) . . ?
C19 C18 C23 118.66(14) . . ?
C23 C18 C13 120.53(14) . . ?
C10 C9 H9 119.8 . . ?
C8 C9 C10 120.45(13) . . ?
C8 C9 H9 119.8 . . ?
C7 C8 H8 120.1 . . ?
C9 C8 C7 119.83(13) . . ?
C9 C8 H8 120.1 . . ?
C13 C17 H17A 110.9 . . ?
C13 C17 H17B 110.9 . . ?
H17A C17 H17B 108.9 . . ?
C16 C17 C13 104.34(13) . . ?
C16 C17 H17A 110.9 . . ?
C16 C17 H17B 110.9 . . ?
N1 C1 H1 118.5 . . ?
N1 C1 C2 122.93(14) . . ?
C2 C1 H1 118.5 . . ?
C18 C19 H19 120.5 . . ?
C20 C19 C18 119.08(15) . . ?
C20 C19 H19 120.5 . . ?
C13 C14 H14A 110.9 . . ?
C13 C14 H14B 110.9 . . ?
H14A C14 H14B 108.9 . . ?
C15 C14 C13 104.35(14) . . ?
C15 C14 H14A 110.9 . . ?
C15 C14 H14B 110.9 . . ?
C20 C21 H21 121.2 . . ?
C20 C21 C22 117.58(15) . . ?
C22 C21 H21 121.2 . . ?
C4 C3 H3 119.7 . . ?
C2 C3 C4 120.52(14) . . ?
C2 C3 H3 119.7 . . ?
C18 C23 H23 119.8 . . ?
C18 C23 C22 120.41(15) . . ?
C22 C23 H23 119.8 . . ?
C1 C2 C3 118.59(15) . . ?
C1 C2 H2 120.7 . . ?
C3 C2 H2 120.7 . . ?
F1 C20 C19 118.72(15) . . ?
F1 C20 C21 118.11(15) . . ?
C21 C20 C19 123.17(16) . . ?
C21 C22 C23 121.10(15) . . ?
C21 C22 H22 119.5 . . ?
C23 C22 H22 119.5 . . ?
C17 C16 H16A 110.4 . . ?
C17 C16 H16B 110.4 . . ?
H16A C16 H16B 108.6 . . ?
C15 C16 C17 106.51(13) . . ?
C15 C16 H16A 110.4 . . ?
C15 C16 H16B 110.4 . . ?
C14 C15 H15A 110.4 . . ?
C14 C15 H15B 110.4 . . ?
C16 C15 C14 106.42(15) . . ?
C16 C15 H15A 110.4 . . ?
C16 C15 H15B 110.4 . . ?
H15A C15 H15B 108.6 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O2 C11 C6 C4 -1.91(19) . . . . ?
O2 C11 C6 C7 179.90(11) . . . . ?
O2 C11 C10 C9 -178.79(12) . . . . ?
O2 C12 C13 C18 -86.74(13) . . . . ?
O2 C12 C13 C17 38.41(16) . . . . ?
O2 C12 C13 C14 149.83(12) . . . . ?
O1 C12 C13 C18 91.38(17) . . . . ?
O1 C12 C13 C17 -143.47(15) . . . . ?
O1 C12 C13 C14 -32.05(19) . . . . ?
N1 C1 C2 C3 -0.6(3) . . . . ?
C11 O2 C12 O1 -3.49(19) . . . . ?
C11 O2 C12 C13 174.68(11) . . . . ?
C11 C6 C4 C5 78.08(17) . . . . ?
C11 C6 C4 C3 -102.73(16) . . . . ?
C11 C6 C7 C8 -1.38(19) . . . . ?
C11 C10 C9 C8 -0.9(2) . . . . ?
C6 C11 C10 C9 -0.7(2) . . . . ?
C6 C4 C5 Cl1 -1.16(18) . . . . ?
C6 C4 C5 N1 178.86(12) . . . . ?
C6 C4 C3 C2 -179.27(15) . . . . ?
C6 C7 C8 C9 -0.1(2) . . . . ?
C4 C6 C7 C8 -179.58(12) . . . . ?
C4 C3 C2 C1 0.5(3) . . . . ?
C10 C11 C6 C4 180.00(12) . . . . ?
C10 C11 C6 C7 1.8(2) . . . . ?
C10 C9 C8 C7 1.3(2) . . . . ?
C5 N1 C1 C2 0.2(2) . . . . ?
C5 C4 C3 C2 0.0(2) . . . . ?
C12 O2 C11 C6 83.60(14) . . . . ?
C12 O2 C11 C10 -98.23(14) . . . . ?
C12 C13 C18 C19 88.17(15) . . . . ?
C12 C13 C18 C23 -90.48(15) . . . . ?
C12 C13 C17 C16 77.10(15) . . . . ?
C12 C13 C14 C15 -78.71(15) . . . . ?
C7 C6 C4 C5 -103.81(16) . . . . ?
C7 C6 C4 C3 75.39(18) . . . . ?
C13 C18 C19 C20 -178.73(14) . . . . ?
C13 C18 C23 C22 178.53(13) . . . . ?
C13 C17 C16 C15 23.53(16) . . . . ?
C13 C14 C15 C16 -25.23(19) . . . . ?
C18 C13 C17 C16 -162.52(12) . . . . ?
C18 C13 C14 C15 163.12(13) . . . . ?
C18 C19 C20 F1 -178.32(14) . . . . ?
C18 C19 C20 C21 0.5(3) . . . . ?
C18 C23 C22 C21 -0.1(2) . . . . ?
C17 C13 C18 C19 -35.33(18) . . . . ?
C17 C13 C18 C23 146.02(13) . . . . ?
C17 C13 C14 C15 39.22(16) . . . . ?
C17 C16 C15 C14 1.02(19) . . . . ?
C1 N1 C5 Cl1 -179.70(11) . . . . ?
C1 N1 C5 C4 0.3(2) . . . . ?
C19 C18 C23 C22 -0.1(2) . . . . ?
C14 C13 C18 C19 -152.22(14) . . . . ?
C14 C13 C18 C23 29.12(18) . . . . ?
C14 C13 C17 C16 -38.52(14) . . . . ?
C3 C4 C5 Cl1 179.60(11) . . . . ?
C3 C4 C5 N1 -0.4(2) . . . . ?
C23 C18 C19 C20 0.0(2) . . . . ?
C20 C21 C22 C23 0.5(2) . . . . ?
C22 C21 C20 F1 178.11(15) . . . . ?
C22 C21 C20 C19 -0.7(3) . . . . ?

_olex2_submission_special_instructions 'No special instructions were received'
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