# Supplementary Information (SI) for Journal of Materials Chemistry C.
# This journal is © The Royal Society of Chemistry 2026

####################################################################### 
# 
# This file contains crystal structure data downloaded from the 
# Cambridge Structural Database (CSD) hosted by the Cambridge 
# Crystallographic Data Centre (CCDC).
# 
# Full information about CCDC data access policies and citation 
# guidelines are available at http://www.ccdc.cam.ac.uk/access/V1 
# 
# Audit and citation data items may have been added by the CCDC. 
# Please retain this information to preserve the provenance of 
# this file and to allow appropriate attribution of the data. 
# 
#######################################################################

data_[Eu2(bpm)(nta)6]
_database_code_depnum_ccdc_archive 'CCDC 2534491'
loop_
_audit_author_name
_audit_author_address
'Joao Honorato de Araujo Neto'
;Institute of Chemistry, University of Sao Paulo
Brazil
;
_audit_update_record             
;
2026-03-02 deposited with the CCDC.	2026-05-13 downloaded from the CCDC.
;
_audit_creation_date             2026-03-02
_audit_creation_method           
;
Olex2 1.5
(compiled 2025.07.13 svn.rb7424aed for OlexSys, GUI svn.r7314)
;
_chemical_formula_moiety         'C92 H54 Eu2 F18 N4 O12'
_chemical_formula_sum            'C92 H54 Eu2 F18 N4 O12'
_chemical_formula_weight         2053.373
_chemical_oxdiff_formula         'Eu C H N O F S'
_chemical_oxdiff_usercomment     'CSD: QARRUX'
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
_atom_type_scat_dispersion_source
C 0.01788 0.00908 2.31000 1.02000 1.58860 0.86500 20.84390 10.20750 0.56870
51.65120 0.21560 'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'
Eu -8.40252 11.10833 24.62740 19.08860 13.76030 2.92270 2.38790 0.19420
13.75460 123.17400 2.57450
'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'
F 0.07327 0.05351 3.53920 2.64120 1.51700 1.02430 10.28250 4.29440 0.26150
26.14760 0.27760 'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'
H 0.00000 0.00000 0.49300 0.32291 0.14019 0.04081 10.51090 26.12570 3.14236
57.79970 0.00304 'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'
N 0.03110 0.01806 12.21260 3.13220 2.01250 1.16630 0.00570 9.89330 28.99750
0.58260 -11.52900 'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'
O 0.04960 0.03234 3.04850 2.28680 1.54630 0.86700 13.27710 5.70110 0.32390
32.90890 0.25080 'International Tables Volume C Table 6.1.1.4 (pp. 500-502)'
'Brennan, Cowan, Rev. Sci. Instrum., 1992, 63, 850'

_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_H-M_alt        'P -1'
_space_group_name_Hall           '-P 1'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z

_symmetry_Int_Tables_number      2
_cell_length_a                   9.9805(2)
_cell_length_b                   12.6721(2)
_cell_length_c                   17.2729(3)
_cell_angle_alpha                106.234(2)
_cell_angle_beta                 97.168(2)
_cell_angle_gamma                101.980(2)
_cell_volume                     2012.54(7)
_cell_formula_units_Z            1
_cell_measurement_reflns_used    29428
_cell_measurement_temperature    100.00(11)
_cell_measurement_theta_max      79.1960
_cell_measurement_theta_min      2.6990
_cell_oxdiff_angle_alpha         106.2342(17)
_cell_oxdiff_angle_beta          97.1677(16)
_cell_oxdiff_angle_gamma         101.9796(16)
_cell_oxdiff_length_a            9.98047(19)
_cell_oxdiff_length_b            12.6721(2)
_cell_oxdiff_length_c            17.2729(3)
_cell_oxdiff_measurement_reflns_used 29428
_cell_oxdiff_volume              2012.55(6)
_exptl_absorpt_coefficient_mu    11.959
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.33693
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   
;
CrysAlisPro 1.171.43.90 (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.694
_exptl_crystal_description       block
_exptl_crystal_F_000             1006.614
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-1 0 1 0.0372
1 0 -1 0.0372
-2 8 -6 0.0748
2 -8 6 0.0748
3 -7 -3 0.0773
-3 7 3 0.0773
4 0 7 0.0956
-4 0 -7 0.0956
0 -7 7 0.0637
0 7 -7 0.0637

_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.07
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.9993 -0.0000 1.0000 -0.1378 0.0417 0.0903
0.9993 0.0000 -1.0000 0.1378 -0.0417 -0.0903
-1.9516 7.8382 -5.7666 0.5234 -0.1266 0.8426
1.9516 -7.8382 5.7666 -0.5234 0.1266 -0.8426
2.5674 -6.8704 -3.1436 0.1394 0.5780 -0.8041
-2.5674 6.8704 3.1436 -0.1394 -0.5780 0.8041
3.6681 0.0043 7.3953 -0.2175 -0.9115 -0.3490
-3.6681 -0.0043 -7.3953 0.2175 0.9115 0.3490
-0.0611 -7.3404 7.4911 -0.7638 0.1837 -0.6188
0.0611 7.3404 -7.4911 0.7638 -0.1837 0.6188

_diffrn_reflns_av_R_equivalents  0.0392
_diffrn_reflns_av_unetI/netI     0.0316
_diffrn_reflns_Laue_measured_fraction_full 0.9981
_diffrn_reflns_Laue_measured_fraction_max 0.9976
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            45131
_diffrn_reflns_point_group_measured_fraction_full 0.9981
_diffrn_reflns_point_group_measured_fraction_max 0.9976
_diffrn_reflns_theta_full        67.6840
_diffrn_reflns_theta_max         70.08
_diffrn_reflns_theta_min         4.62
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(11)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            HyPix
_diffrn_measured_fraction_theta_full 0.9981
_diffrn_measured_fraction_theta_max 0.9976
_diffrn_measurement_details      
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -13.00  24.00   0.50    0.16    --   48.85 -19.00   0.00   74
  2  ω    -10.00  16.00   0.50    0.16    --   48.85 -19.00 -30.00   52
  3  ω    -23.00  23.00   0.50    0.16    --   48.85 -19.00 -90.00   92
  4  ω     44.00  94.00   0.50    0.16    --   48.85-132.00-168.00  100
  5  ω     72.00 117.00   0.50    0.63    --  111.50-132.00-168.00   90
  6  ω     67.00  97.00   0.50    0.63    --  111.50-125.00-150.00   60
  7  ω     41.00 102.00   0.50    0.16    --   48.85-137.00  14.00  122
  8  ω     49.00  92.00   0.50    0.63    --  111.50-125.00 150.00   86
  9  ω     45.00  73.00   0.50    0.63    --  111.50-125.00 120.00   56
 10  ω     94.00 120.00   0.50    0.63    --  111.50-137.00  14.00   52
 11  ω     69.00 111.00   0.50    0.63    --  111.50-125.00 -30.00   84
 12  ω     86.00 111.00   0.50    0.63    --  111.50-125.00 -90.00   50
 13  ω     86.00 111.00   0.50    0.63    --  111.50-125.00-120.00   50
 14  ω     70.00 103.00   0.50    0.63    --  111.50 -94.00-180.00   66
 15  ω     43.00  82.00   0.50    0.63    --  111.50 -94.00 -90.00   78
 16  ω     70.00  96.00   0.50    0.63    --  111.50 -94.00 -60.00   52
 17  ω     59.00 104.00   0.50    0.63    --  111.50 -94.00 -30.00   90
 18  ω     42.00  68.00   0.50    0.63    --  111.50 -94.00-150.00   52
 19  ω     72.00 105.00   0.50    0.63    --  111.50 -94.00-120.00   66
 20  ω     80.00 105.00   0.50    0.63    --  111.50 -94.00-150.00   50
 21  ω     42.00 104.00   0.50    0.63    --  111.50 -94.00   0.00  124
 22  ω     61.00 105.00   0.50    0.63    --  111.50 -94.00  30.00   88
 23  ω     80.00 105.00   0.50    0.63    --  111.50 -94.00  60.00   50
 24  ω     70.00 104.00   0.50    0.63    --  111.50 -94.00 120.00   68
 25  ω     79.00 105.00   0.50    0.63    --  111.50 -94.00 150.00   52
 26  ω     41.00 105.00   0.50    0.63    --  111.50 -94.00  90.00  128
 27  ω     46.00  72.00   0.50    0.63    --  111.50 -94.00  60.00   52
 28  ω     83.00 109.00   0.50    0.63    --  111.50 -82.00  75.75   52
 29  ω     92.00 118.00   0.50    0.63    --  111.50 -88.00  -1.74   52
 30  ω     99.00 125.00   0.50    0.63    --  111.50 -87.00 -16.78   52
 31  ω     42.00  84.00   0.50    0.63    --  111.50 -87.00 -16.78   84
 32  ω    106.00 132.00   0.50    0.63    --  111.50 -81.00-136.61   52
 33  ω     42.00  70.00   0.50    0.63    --  111.50 -61.00-150.00   56
 34  ω     52.00  96.00   0.50    0.63    --  111.50 -77.00-120.00   88
 35  ω     75.00 104.00   0.50    0.63    --  111.50 -77.00-180.00   58
 36  ω     41.00  70.00   0.50    0.63    --  111.50 -77.00-150.00   58
 37  ω     59.00 104.00   0.50    0.63    --  111.50 -77.00 -90.00   90
 38  ω     40.00  69.00   0.50    0.63    --  111.50 -77.00-180.00   58
 39  ω    108.00 134.00   0.50    0.63    --  111.50 -79.00 115.47   52
 40  ω     41.00  71.00   0.50    0.63    --  111.50 -77.00 150.00   60
 41  ω     40.00  76.00   0.50    0.63    --  111.50 -79.00 115.47   72
 42  ω     40.00  66.00   0.50    0.63    --  111.50 -61.00 120.00   52
 43  ω     57.00  83.00   0.50    0.63    --  111.50 -77.00  90.00   52
 44  ω     40.00  92.00   0.50    0.63    --  111.50 -77.00  30.00  104
 45  ω     43.00  69.00   0.50    0.63    --  111.50 -61.00   0.00   52
 46  ω     44.00  70.00   0.50    0.63    --  111.50 -61.00 -60.00   52
 47  ω     43.00  70.00   0.50    0.63    --  111.50 -61.00 -90.00   54
 48  ω    107.00 135.00   0.50    0.63    --  111.50  15.00 -90.00   56
 49  ω    150.00 176.00   0.50    0.63    --  111.50  77.00-150.00   52
 50  ω    111.00 137.00   0.50    0.63    --  111.50  77.00-150.00   52
 51  ω    117.00 154.00   0.50    0.63    --  111.50  61.00-180.00   74
 52  ω    107.00 143.00   0.50    0.63    --  111.50  61.00   0.00   72
 53  ω    144.00 173.00   0.50    0.63    --  111.50  61.00 -90.00   58
 54  ω    148.00 173.00   0.50    0.63    --  111.50  61.00   0.00   50
 55  ω    106.00 135.00   0.50    0.63    --  111.50  61.00 -90.00   58
 56  ω    110.00 176.00   0.50    0.63    --  111.50  77.00  30.00  132
 57  ω    101.00 138.00   0.50    0.63    --  111.50  45.00 -30.00   74
 58  ω    123.00 149.00   0.50    0.63    --  111.50  61.00  90.00   52
 59  ω    109.00 137.00   0.50    0.63    --  111.50  45.00 120.00   56
 60  ω    107.00 165.00   0.50    0.63    --  111.50  61.00 150.00  116
 61  ω    148.00 175.00   0.50    0.63    --  111.50  45.00 120.00   54
 62  ω    150.00 176.00   0.50    0.63    --  111.50  77.00 120.00   52
 63  ω    114.00 140.00   0.50    0.63    --  111.50  77.00 120.00   52
 64  ω    143.00 178.00   0.50    0.63    --  111.50  45.00 -30.00   70
 65  ω    144.00 178.00   0.50    0.63    --  111.50  15.00 -90.00   68
 66  ω    127.00 177.00   0.50    0.63    --  111.50  30.00-180.00  100
 67  ω    103.00 137.00   0.50    0.63    --  111.50  30.00 -30.00   68
 68  ω    101.00 139.00   0.50    0.63    --  111.50  15.00  90.00   76
 69  ω    102.00 138.00   0.50    0.63    --  111.50  15.00 150.00   72
 70  ω    128.00 154.00   0.50    0.63    --  111.50 125.00 120.00   52
 71  ω    122.00 162.00   0.50    0.63    --  111.50 125.00 150.00   80
 72  ω    108.00 133.00   0.50    0.63    --  111.50 137.00  77.00   50
 73  ω    128.00 154.00   0.50    0.63    --  111.50 125.00  60.00   52
 74  ω    119.00 157.00   0.50    0.63    --  111.50 125.00 -30.00   76
 75  ω    121.00 147.00   0.50    0.63    --  111.50 132.00 -99.00   52
 76  ω     98.00 165.00   0.50    0.63    --  111.50 125.00-150.00  134
 77  ω     95.00 165.00   0.50    0.63    --  111.50 125.00-180.00  140
 78  ω    -27.00  -2.00   0.50    0.16    --  -48.85  19.00-150.00   50
 79  ω    -27.00  21.00   0.50    0.16    --  -48.85  19.00-180.00   96
 80  ω    -27.00  25.00   0.50    0.16    --  -48.85  19.00-120.00  104
 81  ω    -79.00 -54.00   0.50    0.16    --  -48.85 137.00  77.00   50
 82  ω    -81.00 -56.00   0.50    0.63    --  -90.00 137.00  77.00   50
 83  ω    -66.00 -41.00   0.50    0.16    --  -48.85 132.00 -99.00   50
 84  ω    -80.00 -55.00   0.50    0.63    --  -90.00 132.00 -99.00   50
 85  ω   -121.00 -54.00   0.50    0.16    --  -48.85 -46.00-117.87  134
 86  ω   -137.00-112.00   0.50    0.63    --  -90.00-137.00  14.00   50
 87  ω   -103.00 -66.00   0.50    0.16    --  -48.85-137.00  14.00   74
 88  ω   -152.00-108.00   0.50    0.63    --  -90.00 -61.00 -60.00   88
 89  ω   -139.00-114.00   0.50    0.63    --  -90.00-132.00-168.00   50
 90  ω   -107.00 -69.00   0.50    0.16    --  -48.85-132.00-168.00   76
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type       
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0724886000
_diffrn_orient_matrix_UB_12      0.0367190000
_diffrn_orient_matrix_UB_13      -0.0653830000
_diffrn_orient_matrix_UB_21      -0.1103063000
_diffrn_orient_matrix_UB_22      -0.0940070000
_diffrn_orient_matrix_UB_23      -0.0684934000
_diffrn_orient_matrix_UB_31      -0.0919633000
_diffrn_orient_matrix_UB_32      0.0834105000
_diffrn_orient_matrix_UB_33      -0.0016256000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'PhotonJet (Cu) X-ray Source'
_reflns_Friedel_coverage         0.0
_reflns_limit_h_max              12
_reflns_limit_h_min              -12
_reflns_limit_k_max              14
_reflns_limit_k_min              -15
_reflns_limit_l_max              21
_reflns_limit_l_min              0
_reflns_number_gt                7429
_reflns_number_total             7641
_reflns_threshold_expression     I>=2u(I)
_computing_cell_refinement       'CrysAlisPro 1.171.43.90 (Rigaku OD, 2023)'
_computing_data_collection       
'CrysAlisPro system (CCD 44.91a 64-bit (release 23-01-2025))'
_computing_data_reduction        'CrysAlisPro 1.171.43.90 (Rigaku OD, 2023)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'olex2.refine 1.5 (Bourhis et al., 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max         0.5387
_refine_diff_density_min         -0.4889
_refine_diff_density_rms         0.0682
_refine_ls_d_res_high            0.8200
_refine_ls_d_res_low             9.5764
_refine_ls_goodness_of_fit_ref   1.0464
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    54
_refine_ls_number_parameters     602
_refine_ls_number_reflns         7641
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0243
_refine_ls_R_factor_gt           0.0235
_refine_ls_restrained_S_all      1.0464
_refine_ls_shift/su_max          0.0004
_refine_ls_shift/su_mean         0.0001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     
'w=1/[σ²(Fo²)+(0.0275P)²+1.0251P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0570
_refine_ls_wR_factor_ref         0.0574
_olex2_refinement_description    
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C3A(H3A), C3B(H3B), C3C(H3C), C4(H4), C6A(H6A), C6B(H6B),
 C6C(H6C), C8A(H8A), C8B(H8B), C8C(H8C), C9A(H9A), C9B(H9B), C9C(H9C),
 C10A(H10A), C10B(H10B), C10C(H10C), C11A(H11A), C11B(H11B), C11C(H11C),
 C12B(H12B), C13A(H13A), C13C(H13C), C14A(H14A), C14B(H14B), C14C(H14C)
;
_atom_sites_solution_primary     dual
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_refinement_flags_posn
Eu1 Eu 0.70751(4) 0.53653(3) 0.18295(2) 0.02580(19) Uani 1.000000 .
F1A F 0.57982(16) 0.51254(15) 0.43109(9) 0.0476(4) Uani 1.000000 .
F1B F 1.15591(15) 0.84338(14) 0.19410(9) 0.0468(4) Uani 1.000000 .
F1C F 1.18506(18) 0.35291(19) 0.20554(11) 0.0723(7) Uani 1.000000 .
F2A F 0.3768(2) 0.5081(2) 0.37694(11) 0.0703(6) Uani 1.000000 .
F2B F 1.03153(18) 0.94109(12) 0.14884(10) 0.0452(4) Uani 1.000000 .
F2C F 1.1153(2) 0.39793(14) 0.09870(12) 0.0612(5) Uani 1.000000 .
F3A F 0.4231(3) 0.36019(14) 0.39878(12) 0.0777(7) Uani 1.000000 .
F3B F 1.03298(15) 0.77601(11) 0.07239(8) 0.0371(3) Uani 1.000000 .
F3C F 0.99330(14) 0.25782(11) 0.12414(9) 0.0375(3) Uani 1.000000 .
O1A O 0.54330(17) 0.50161(12) 0.26503(9) 0.0288(3) Uani 1.000000 .
O1B O 0.85805(17) 0.67627(12) 0.14520(9) 0.0304(3) Uani 1.000000 .
O1C O 0.89347(17) 0.45157(13) 0.16002(9) 0.0322(3) Uani 1.000000 .
O2A O 0.60415(17) 0.33972(12) 0.14106(9) 0.0291(3) Uani 1.000000 .
O2B O 0.68060(16) 0.71527(12) 0.25436(9) 0.0277(3) Uani 1.000000 .
O2C O 0.85167(17) 0.57579(14) 0.30813(9) 0.0337(4) Uani 1.000000 .
N1 N 0.48059(19) 0.55819(14) 0.10441(11) 0.0251(4) Uani 1.000000 .
N2 N 0.3367(2) 0.53567(14) -0.02253(11) 0.0261(4) Uani 1.000000 .
C1 C 0.4494(2) 0.52565(16) 0.02259(13) 0.0238(4) Uani 1.000000 .
C1A C 0.4697(2) 0.44803(18) 0.37468(13) 0.0277(4) Uani 1.000000 .
C1B C 1.0321(2) 0.83608(19) 0.14890(14) 0.0314(5) Uani 1.000000 .
C1C C 1.0742(2) 0.3623(2) 0.15996(15) 0.0340(5) Uani 1.000000 .
C2 C 0.3911(3) 0.60606(18) 0.14500(13) 0.0300(5) Uani 1.000000 .
H2 H 0.4092(3) 0.62948(18) 0.20338(13) 0.0360(5) Uiso 1.000000 R
C2A C 0.5102(2) 0.41695(18) 0.28974(12) 0.0233(4) Uani 1.000000 .
C2B C 0.9110(2) 0.78042(18) 0.18360(13) 0.0273(4) Uani 1.000000 .
C2C C 0.9923(2) 0.44045(18) 0.20728(14) 0.0279(4) Uani 1.000000 .
C3 C 0.2733(3) 0.6219(2) 0.10355(14) 0.0328(5) Uani 1.000000 .
H3 H 0.2111(3) 0.6573(2) 0.13237(14) 0.0394(6) Uiso 1.000000 R
C3A C 0.5117(2) 0.30545(17) 0.25310(13) 0.0244(4) Uani 1.000000 .
H3A H 0.4802(2) 0.25022(17) 0.27878(13) 0.0293(5) Uiso 1.000000 R
C3B C 0.8808(2) 0.84904(18) 0.25316(14) 0.0295(4) Uani 1.000000 .
H3B H 0.9373(2) 0.92455(18) 0.27773(14) 0.0353(5) Uiso 1.000000 R
C3C C 1.0341(2) 0.4866(2) 0.29155(14) 0.0314(5) Uani 1.000000 .
H3C H 1.1139(2) 0.4713(2) 0.31807(14) 0.0377(6) Uiso 1.000000 R
C4 C 0.2491(2) 0.58456(19) 0.01870(14) 0.0307(5) Uani 1.000000 .
H4 H 0.1681(2) 0.59382(19) -0.01117(14) 0.0369(6) Uiso 1.000000 R
C4A C 0.5593(2) 0.27112(17) 0.17772(12) 0.0225(4) Uani 1.000000 .
C4B C 0.7676(2) 0.80990(17) 0.28907(13) 0.0255(4) Uani 1.000000 .
C4C C 0.9604(2) 0.55657(18) 0.33959(14) 0.0269(4) Uani 1.000000 .
C5A C 0.5667(2) 0.15095(17) 0.14301(12) 0.0226(4) Uani 1.000000 .
C5B C 0.7488(2) 0.87927(17) 0.37052(13) 0.0257(4) Uani 1.000000 .
C5C C 1.0083(2) 0.61021(17) 0.42998(13) 0.0255(4) Uani 1.000000 .
C6A C 0.6531(2) 0.12939(16) 0.08797(12) 0.0222(4) Uani 1.000000 .
H6A H 0.6984(2) 0.18914(16) 0.06980(12) 0.0267(5) Uiso 1.000000 R
C6B C 0.6450(2) 0.83269(18) 0.40554(13) 0.0267(4) Uani 1.000000 .
H6B H 0.5846(2) 0.75998(18) 0.37601(13) 0.0320(5) Uiso 1.000000 R
C6C C 0.9237(2) 0.66775(17) 0.47283(13) 0.0236(4) Uani 1.000000 .
H6C H 0.8372(2) 0.66992(17) 0.44414(13) 0.0283(5) Uiso 1.000000 R
C7A C 0.6763(2) 0.02012(17) 0.05760(12) 0.0238(4) Uani 1.000000 .
C7B C 0.6261(2) 0.89095(18) 0.48490(13) 0.0267(4) Uani 1.000000 .
C7C C 0.9628(2) 0.72343(17) 0.55828(13) 0.0235(4) Uani 1.000000 .
C8A C 0.7676(2) -0.00244(19) 0.00176(14) 0.0298(4) Uani 1.000000 .
H8A H 0.8144(2) 0.05670(19) -0.01649(14) 0.0358(5) Uiso 1.000000 R
C8B C 0.5188(2) 0.8446(2) 0.52151(15) 0.0331(5) Uani 1.000000 .
H8B H 0.4567(2) 0.7725(2) 0.49253(15) 0.0398(6) Uiso 1.000000 R
C8C C 0.8764(2) 0.78334(18) 0.60299(13) 0.0267(4) Uani 1.000000 .
H8C H 0.7885(2) 0.78456(18) 0.57536(13) 0.0320(5) Uiso 1.000000 R
C9A C 0.7886(3) -0.1088(2) -0.02596(16) 0.0355(5) Uani 1.000000 .
H9A H 0.8491(3) -0.1232(2) -0.06377(16) 0.0426(6) Uiso 1.000000 R
C9B C 0.5039(3) 0.9030(2) 0.59832(15) 0.0357(5) Uani 1.000000 .
H9B H 0.4308(3) 0.8717(2) 0.62197(15) 0.0428(6) Uiso 1.000000 R
C9C C 0.9190(2) 0.83916(19) 0.68546(14) 0.0307(5) Uani 1.000000 .
H9C H 0.8600(2) 0.87811(19) 0.71480(14) 0.0368(5) Uiso 1.000000 R
C10A C 0.7212(3) -0.1967(2) 0.00114(16) 0.0363(5) Uani 1.000000 .
H10A H 0.7365(3) -0.2703(2) -0.01847(16) 0.0436(6) Uiso 1.000000 R
C10B C 0.5966(3) 1.0092(2) 0.64234(14) 0.0353(5) Uani 1.000000 .
H10B H 0.5863(3) 1.0487(2) 0.69588(14) 0.0424(6) Uiso 1.000000 R
C10C C 1.0501(3) 0.83934(19) 0.72737(14) 0.0324(5) Uani 1.000000 .
H10C H 1.0798(3) 0.87989(19) 0.78438(14) 0.0389(6) Uiso 1.000000 R
C11A C 0.6338(3) -0.17727(19) 0.05550(15) 0.0328(5) Uani 1.000000 .
H11A H 0.5897(3) -0.23730(19) 0.07380(15) 0.0394(6) Uiso 1.000000 R
C11B C 0.7015(3) 1.0562(2) 0.60871(14) 0.0342(5) Uani 1.000000 .
H11B H 0.7633(3) 1.1279(2) 0.63923(14) 0.0411(6) Uiso 1.000000 R
C11C C 1.1343(2) 0.78117(19) 0.68596(14) 0.0321(5) Uani 1.000000 .
H11C H 1.2217(2) 0.78096(19) 0.71479(14) 0.0386(6) Uiso 1.000000 R
C12A C 0.6082(2) -0.06852(17) 0.08491(13) 0.0263(4) Uani 1.000000 .
C12B C 0.8236(3) 1.04573(19) 0.49140(15) 0.0341(5) Uani 1.000000 .
H12B H 0.8849(3) 1.11833(19) 0.52013(15) 0.0409(6) Uiso 1.000000 R
C12C C 1.0931(2) 0.72137(17) 0.60084(13) 0.0265(4) Uani 1.000000 .
C13A C 0.5167(3) -0.04505(19) 0.14012(14) 0.0314(5) Uani 1.000000 .
H13A H 0.4687(3) -0.10444(19) 0.15768(14) 0.0377(6) Uiso 1.000000 R
C13B C 0.7189(2) 0.99898(18) 0.52873(13) 0.0279(4) Uani 1.000000 .
C13C C 1.1771(2) 0.6597(2) 0.55565(14) 0.0319(5) Uani 1.000000 .
H13C H 1.2636(2) 0.6561(2) 0.58345(14) 0.0383(6) Uiso 1.000000 R
C14A C 0.4959(2) 0.06119(18) 0.16873(13) 0.0280(4) Uani 1.000000 .
H14A H 0.4341(2) 0.07498(18) 0.20584(13) 0.0336(5) Uiso 1.000000 R
C14B C 0.8384(3) 0.98835(19) 0.41449(14) 0.0319(5) Uani 1.000000 .
H14B H 0.9092(3) 1.02172(19) 0.39025(14) 0.0382(6) Uiso 1.000000 R
C14C C 1.1362(2) 0.60552(19) 0.47340(15) 0.0314(5) Uani 1.000000 .
H14C H 1.1939(2) 0.56414(19) 0.44473(15) 0.0376(6) Uiso 1.000000 R

loop_
_atom_site_anharm_GC_C_label
_atom_site_anharm_GC_C_111
_atom_site_anharm_GC_C_112
_atom_site_anharm_GC_C_113
_atom_site_anharm_GC_C_122
_atom_site_anharm_GC_C_123
_atom_site_anharm_GC_C_133
_atom_site_anharm_GC_C_222
_atom_site_anharm_GC_C_223
_atom_site_anharm_GC_C_233
_atom_site_anharm_GC_C_333
Eu1 0.00000018(7) -0.00000005(3) 0.00000004(2) -0.00000014(2) 0.000000028(11)
-0.000000020(12) -0.00000013(4) -0.000000003(14) -0.000000025(10)
-0.000000020(13)

loop_
_atom_site_anharm_GC_D_label
_atom_site_anharm_GC_D_1111
_atom_site_anharm_GC_D_1112
_atom_site_anharm_GC_D_1113
_atom_site_anharm_GC_D_1122
_atom_site_anharm_GC_D_1123
_atom_site_anharm_GC_D_1133
_atom_site_anharm_GC_D_1222
_atom_site_anharm_GC_D_1223
_atom_site_anharm_GC_D_1233
_atom_site_anharm_GC_D_1333
_atom_site_anharm_GC_D_2222
_atom_site_anharm_GC_D_2223
_atom_site_anharm_GC_D_2233
_atom_site_anharm_GC_D_2333
_atom_site_anharm_GC_D_3333
Eu1 -0.000000026(8) -0.000000040(3) 0.000000014(2) 0.000000017(2)
-0.0000000048(9) 0.0000000089(10) -0.000000012(2) -0.0000000063(8)
-0.0000000012(5) 0.0000000026(7) 0.000000068(4) -0.0000000019(13)
0.0000000062(7) 0.0000000008(6) 0.0000000065(10)


loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1A 2.3498(16) . ?
Eu1 O1B 2.3673(16) . ?
Eu1 O1C 2.3527(15) . ?
Eu1 O2A 2.3547(15) . ?
Eu1 O2B 2.3446(14) . ?
Eu1 O2C 2.3062(16) . ?
Eu1 N1 2.5969(18) . ?
Eu1 N2 2.6114(18) 2_665 ?
F1A C1A 1.319(3) . ?
F1B C1B 1.348(3) . ?
F1C C1C 1.322(3) . ?
F2A C1A 1.314(3) . ?
F2B C1B 1.332(3) . ?
F2C C1C 1.338(3) . ?
F3A C1A 1.312(3) . ?
F3B C1B 1.330(3) . ?
F3C C1C 1.327(3) . ?
O1A C2A 1.259(3) . ?
O1B C2B 1.263(3) . ?
O1C C2C 1.257(3) . ?
O2A C4A 1.255(3) . ?
O2B C4B 1.260(3) . ?
O2C C4C 1.253(3) . ?
N1 C1 1.332(3) . ?
N1 C2 1.342(3) . ?
N2 C1 1.336(3) . ?
N2 C4 1.338(3) . ?
C1 C1 1.496(4) 2_665 ?
C1A C2A 1.537(3) . ?
C1B C2B 1.543(3) . ?
C1C C2C 1.538(3) . ?
C2 H2 0.9500 . ?
C2 C3 1.380(3) . ?
C2A C3A 1.381(3) . ?
C2B C3B 1.380(3) . ?
C2C C3C 1.381(3) . ?
C3 H3 0.9500 . ?
C3 C4 1.381(3) . ?
C3A H3A 0.9500 . ?
C3A C4A 1.426(3) . ?
C3B H3B 0.9500 . ?
C3B C4B 1.421(3) . ?
C3C H3C 0.9500 . ?
C3C C4C 1.424(3) . ?
C4 H4 0.9500 . ?
C4A C5A 1.494(3) . ?
C4B C5B 1.493(3) . ?
C4C C5C 1.488(3) . ?
C5A C6A 1.371(3) . ?
C5A C14A 1.420(3) . ?
C5B C6B 1.375(3) . ?
C5B C14B 1.420(3) . ?
C5C C6C 1.379(3) . ?
C5C C14C 1.419(3) . ?
C6A H6A 0.9500 . ?
C6A C7A 1.416(3) . ?
C6B H6B 0.9500 . ?
C6B C7B 1.420(3) . ?
C6C H6C 0.9500 . ?
C6C C7C 1.410(3) . ?
C7A C8A 1.419(3) . ?
C7A C12A 1.416(3) . ?
C7B C8B 1.417(3) . ?
C7B C13B 1.423(3) . ?
C7C C8C 1.423(3) . ?
C7C C12C 1.421(3) . ?
C8A H8A 0.9500 . ?
C8A C9A 1.368(3) . ?
C8B H8B 0.9500 . ?
C8B C9B 1.369(3) . ?
C8C H8C 0.9500 . ?
C8C C9C 1.368(3) . ?
C9A H9A 0.9500 . ?
C9A C10A 1.405(4) . ?
C9B H9B 0.9500 . ?
C9B C10B 1.407(4) . ?
C9C H9C 0.9500 . ?
C9C C10C 1.413(3) . ?
C10A H10A 0.9500 . ?
C10A C11A 1.366(4) . ?
C10B H10B 0.9500 . ?
C10B C11B 1.369(4) . ?
C10C H10C 0.9500 . ?
C10C C11C 1.369(3) . ?
C11A H11A 0.9500 . ?
C11A C12A 1.418(3) . ?
C11B H11B 0.9500 . ?
C11B C13B 1.420(3) . ?
C11C H11C 0.9500 . ?
C11C C12C 1.415(3) . ?
C12A C13A 1.415(3) . ?
C12B H12B 0.9500 . ?
C12B C13B 1.408(3) . ?
C12B C14B 1.367(3) . ?
C12C C13C 1.421(3) . ?
C13A H13A 0.9500 . ?
C13A C14A 1.367(3) . ?
C13C H13C 0.9500 . ?
C13C C14C 1.360(3) . ?
C14A H14A 0.9500 . ?
C14B H14B 0.9500 . ?
C14C H14C 0.9500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1B Eu1 O1A 146.00(5) . . ?
O1C Eu1 O1A 127.35(5) . . ?
O1C Eu1 O1B 79.46(6) . . ?
O2A Eu1 O1A 71.47(5) . . ?
O2A Eu1 O1B 141.83(5) . . ?
O2A Eu1 O1C 75.25(6) . . ?
O2B Eu1 O1A 74.34(5) . . ?
O2B Eu1 O1B 71.68(5) . . ?
O2B Eu1 O1C 137.01(6) . . ?
O2B Eu1 O2A 143.99(6) . . ?
O2C Eu1 O1A 78.86(6) . . ?
O2C Eu1 O1B 93.35(6) . . ?
O2C Eu1 O1C 71.91(5) . . ?
O2C Eu1 O2A 105.18(6) . . ?
O2C Eu1 O2B 78.59(5) . . ?
N1 Eu1 O1A 76.75(5) . . ?
N1 Eu1 O1B 94.61(6) . . ?
N1 Eu1 O1C 141.01(6) . . ?
N1 Eu1 O2A 87.66(5) . . ?
N1 Eu1 O2B 73.75(5) . . ?
N1 Eu1 O2C 147.06(5) . . ?
N2 Eu1 O1A 126.17(6) 2_665 . ?
N2 Eu1 O1B 74.42(6) 2_665 . ?
N2 Eu1 O1C 78.72(5) 2_665 . ?
N2 Eu1 O2A 72.94(5) 2_665 . ?
N2 Eu1 O2B 121.19(5) 2_665 . ?
N2 Eu1 O2C 149.85(6) 2_665 . ?
N2 Eu1 N1 62.71(6) 2_665 . ?
C2A O1A Eu1 128.69(13) . . ?
C2B O1B Eu1 130.05(14) . . ?
C2C O1C Eu1 133.18(14) . . ?
C4A O2A Eu1 134.23(13) . . ?
C4B O2B Eu1 131.93(13) . . ?
C4C O2C Eu1 141.39(14) . . ?
C1 N1 Eu1 121.98(14) . . ?
C2 N1 Eu1 121.05(14) . . ?
C2 N1 C1 116.94(18) . . ?
C1 N2 Eu1 121.15(13) . 2_665 ?
C4 N2 Eu1 122.27(14) . 2_665 ?
C4 N2 C1 116.58(18) . . ?
N2 C1 N1 125.86(19) . . ?
C1 C1 N1 116.9(2) 2_665 . ?
C1 C1 N2 117.2(2) 2_665 . ?
F2A C1A F1A 106.22(19) . . ?
F3A C1A F1A 105.9(2) . . ?
F3A C1A F2A 109.2(2) . . ?
C2A C1A F1A 109.94(17) . . ?
C2A C1A F2A 111.10(19) . . ?
C2A C1A F3A 114.06(18) . . ?
F2B C1B F1B 106.70(19) . . ?
F3B C1B F1B 105.98(18) . . ?
F3B C1B F2B 107.22(19) . . ?
C2B C1B F1B 110.36(19) . . ?
C2B C1B F2B 113.55(18) . . ?
C2B C1B F3B 112.59(19) . . ?
F2C C1C F1C 108.3(2) . . ?
F3C C1C F1C 106.7(2) . . ?
F3C C1C F2C 105.49(19) . . ?
C2C C1C F1C 114.69(19) . . ?
C2C C1C F2C 110.5(2) . . ?
C2C C1C F3C 110.75(18) . . ?
H2 C2 N1 119.37(12) . . ?
C3 C2 N1 121.3(2) . . ?
C3 C2 H2 119.37(13) . . ?
C1A C2A O1A 112.77(17) . . ?
C3A C2A O1A 129.18(19) . . ?
C3A C2A C1A 117.98(19) . . ?
C1B C2B O1B 114.01(18) . . ?
C3B C2B O1B 129.7(2) . . ?
C3B C2B C1B 116.19(19) . . ?
C1C C2C O1C 111.75(19) . . ?
C3C C2C O1C 129.86(19) . . ?
C3C C2C C1C 118.4(2) . . ?
H3 C3 C2 121.18(13) . . ?
C4 C3 C2 117.6(2) . . ?
C4 C3 H3 121.18(13) . . ?
H3A C3A C2A 119.15(12) . . ?
C4A C3A C2A 121.70(19) . . ?
C4A C3A H3A 119.15(12) . . ?
H3B C3B C2B 119.08(13) . . ?
C4B C3B C2B 121.8(2) . . ?
C4B C3B H3B 119.08(12) . . ?
H3C C3C C2C 119.28(12) . . ?
C4C C3C C2C 121.4(2) . . ?
C4C C3C H3C 119.28(13) . . ?
C3 C4 N2 121.7(2) . . ?
H4 C4 N2 119.15(12) . . ?
H4 C4 C3 119.15(13) . . ?
C3A C4A O2A 122.58(18) . . ?
C5A C4A O2A 117.57(18) . . ?
C5A C4A C3A 119.71(18) . . ?
C3B C4B O2B 121.70(19) . . ?
C5B C4B O2B 117.37(19) . . ?
C5B C4B C3B 120.93(19) . . ?
C3C C4C O2C 121.8(2) . . ?
C5C C4C O2C 116.52(18) . . ?
C5C C4C C3C 121.63(19) . . ?
C6A C5A C4A 117.63(18) . . ?
C14A C5A C4A 122.79(18) . . ?
C14A C5A C6A 119.45(18) . . ?
C6B C5B C4B 118.27(19) . . ?
C14B C5B C4B 122.4(2) . . ?
C14B C5B C6B 119.2(2) . . ?
C6C C5C C4C 117.75(18) . . ?
C14C C5C C4C 123.24(19) . . ?
C14C C5C C6C 119.0(2) . . ?
H6A C6A C5A 119.25(12) . . ?
C7A C6A C5A 121.50(19) . . ?
C7A C6A H6A 119.25(12) . . ?
H6B C6B C5B 119.30(12) . . ?
C7B C6B C5B 121.4(2) . . ?
C7B C6B H6B 119.30(13) . . ?
H6C C6C C5C 119.27(12) . . ?
C7C C6C C5C 121.46(18) . . ?
C7C C6C H6C 119.27(11) . . ?
C8A C7A C6A 121.9(2) . . ?
C12A C7A C6A 118.88(19) . . ?
C12A C7A C8A 119.24(19) . . ?
C8B C7B C6B 122.1(2) . . ?
C13B C7B C6B 118.5(2) . . ?
C13B C7B C8B 119.4(2) . . ?
C8C C7C C6C 121.87(19) . . ?
C12C C7C C6C 119.15(18) . . ?
C12C C7C C8C 118.96(19) . . ?
H8A C8A C7A 119.79(12) . . ?
C9A C8A C7A 120.4(2) . . ?
C9A C8A H8A 119.79(14) . . ?
H8B C8B C7B 119.72(14) . . ?
C9B C8B C7B 120.6(2) . . ?
C9B C8B H8B 119.72(15) . . ?
H8C C8C C7C 119.77(12) . . ?
C9C C8C C7C 120.5(2) . . ?
C9C C8C H8C 119.77(13) . . ?
H9A C9A C8A 119.80(14) . . ?
C10A C9A C8A 120.4(2) . . ?
C10A C9A H9A 119.80(13) . . ?
H9B C9B C8B 119.88(15) . . ?
C10B C9B C8B 120.2(2) . . ?
C10B C9B H9B 119.88(14) . . ?
H9C C9C C8C 119.73(13) . . ?
C10C C9C C8C 120.5(2) . . ?
C10C C9C H9C 119.73(13) . . ?
H10A C10A C9A 119.76(13) . . ?
C11A C10A C9A 120.5(2) . . ?
C11A C10A H10A 119.76(13) . . ?
H10B C10B C9B 119.70(14) . . ?
C11B C10B C9B 120.6(2) . . ?
C11B C10B H10B 119.70(14) . . ?
H10C C10C C9C 119.95(13) . . ?
C11C C10C C9C 120.1(2) . . ?
C11C C10C H10C 119.95(13) . . ?
H11A C11A C10A 119.62(13) . . ?
C12A C11A C10A 120.8(2) . . ?
C12A C11A H11A 119.62(14) . . ?
H11B C11B C10B 119.62(14) . . ?
C13B C11B C10B 120.8(2) . . ?
C13B C11B H11B 119.62(14) . . ?
H11C C11C C10C 119.52(13) . . ?
C12C C11C C10C 121.0(2) . . ?
C12C C11C H11C 119.52(12) . . ?
C11A C12A C7A 118.7(2) . . ?
C13A C12A C7A 118.64(18) . . ?
C13A C12A C11A 122.7(2) . . ?
C13B C12B H12B 119.46(13) . . ?
C14B C12B H12B 119.46(14) . . ?
C14B C12B C13B 121.1(2) . . ?
C11C C12C C7C 118.94(19) . . ?
C13C C12C C7C 118.32(19) . . ?
C13C C12C C11C 122.74(19) . . ?
H13A C13A C12A 119.26(12) . . ?
C14A C13A C12A 121.5(2) . . ?
C14A C13A H13A 119.26(13) . . ?
C11B C13B C7B 118.4(2) . . ?
C12B C13B C7B 119.2(2) . . ?
C12B C13B C11B 122.4(2) . . ?
H13C C13C C12C 119.33(12) . . ?
C14C C13C C12C 121.33(19) . . ?
C14C C13C H13C 119.33(12) . . ?
C13A C14A C5A 120.0(2) . . ?
H14A C14A C5A 119.99(12) . . ?
H14A C14A C13A 119.99(13) . . ?
C12B C14B C5B 120.6(2) . . ?
H14B C14B C5B 119.71(13) . . ?
H14B C14B C12B 119.71(14) . . ?
C13C C14C C5C 120.68(19) . . ?
H14C C14C C5C 119.66(12) . . ?
H14C C14C C13C 119.66(12) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Eu1 O1A C2A C1A 147.34(16) . . . . ?
Eu1 O1A C2A C3A -29.6(2) . . . . ?
Eu1 O1B C2B C1B 165.32(18) . . . . ?
Eu1 O1B C2B C3B -11.4(2) . . . . ?
Eu1 O1C C2C C1C 171.9(2) . . . . ?
Eu1 O1C C2C C3C -7.8(2) . . . . ?
Eu1 O2A C4A C3A 25.5(2) . . . . ?
Eu1 O2A C4A C5A -150.03(17) . . . . ?
Eu1 O2B C4B C3B 41.03(19) . . . . ?
Eu1 O2B C4B C5B -138.06(17) . . . . ?
Eu1 O2C C4C C3C -1.5(3) . . . . ?
Eu1 O2C C4C C5C 178.8(2) . . . . ?
Eu1 N1 C1 N2 -178.64(14) . . . . ?
Eu1 N1 C1 C1 0.72(15) . . . 2_665 ?
Eu1 N1 C2 C3 177.35(17) . . . . ?
Eu1 N2 C1 N1 -179.04(13) 2_665 . . . ?
Eu1 N2 C1 C1 -1.60(15) . 2_665 2_665 . ?
Eu1 N2 C4 C3 179.70(17) 2_665 . . . ?
F1A C1A C2A O1A -66.8(2) . . . . ?
F1A C1A C2A C3A 110.48(19) . . . . ?
F1B C1B C2B O1B -99.64(18) . . . . ?
F1B C1B C2B C3B 77.5(2) . . . . ?
F1C C1C C2C O1C 175.9(2) . . . . ?
F1C C1C C2C C3C -4.3(3) . . . . ?
F2A C1A C2A O1A 50.5(2) . . . . ?
F2A C1A C2A C3A -132.2(2) . . . . ?
F2B C1B C2B O1B 140.62(19) . . . . ?
F2B C1B C2B C3B -42.2(2) . . . . ?
F2C C1C C2C O1C 53.2(2) . . . . ?
F2C C1C C2C C3C -127.0(2) . . . . ?
F3A C1A C2A O1A 174.4(2) . . . . ?
F3A C1A C2A C3A -8.3(2) . . . . ?
F3B C1B C2B O1B 18.5(2) . . . . ?
F3B C1B C2B C3B -164.30(19) . . . . ?
F3C C1C C2C O1C -63.3(2) . . . . ?
F3C C1C C2C C3C 116.5(2) . . . . ?
O1A C2A C3A C4A 2.2(3) . . . . ?
O1B C2B C3B C4B -6.4(3) . . . . ?
O1C C2C C3C C4C 1.9(3) . . . . ?
O2A C4A C3A C2A 1.0(2) . . . . ?
O2A C4A C5A C6A 16.8(2) . . . . ?
O2A C4A C5A C14A -167.51(19) . . . . ?
O2B C4B C3B C2B -7.7(2) . . . . ?
O2B C4B C5B C6B 4.8(2) . . . . ?
O2B C4B C5B C14B -178.51(19) . . . . ?
O2C C4C C3C C2C 2.8(3) . . . . ?
O2C C4C C5C C6C 5.7(2) . . . . ?
O2C C4C C5C C14C -173.8(2) . . . . ?
N1 C1 N2 C4 1.2(2) . . . . ?
N1 C1 C1 N1 -180.0(2) . . 2_665 2_665 ?
N1 C1 C1 N2 0.58(19) . . 2_665 2_665 ?
N1 C2 C3 C4 1.4(3) . . . . ?
N2 C1 N1 C2 -0.5(2) . . . . ?
N2 C1 C1 N1 -0.58(19) . . 2_665 2_665 ?
N2 C1 C1 N2 -180.0(2) . . 2_665 2_665 ?
N2 C4 C3 C2 -0.7(3) . . . . ?
C1 N1 C2 C3 -0.8(2) . . . . ?
C1 N2 C4 C3 -0.5(2) . . . . ?
C1 C1 N1 C2 178.8(2) 2_665 . . . ?
C1 C1 N2 C4 -178.2(2) 2_665 . . . ?
C1A C2A C3A C4A -174.59(17) . . . . ?
C1B C2B C3B C4B 177.01(18) . . . . ?
C1C C2C C3C C4C -177.9(2) . . . . ?
C2A C3A C4A C5A 176.46(18) . . . . ?
C2B C3B C4B C5B 171.3(2) . . . . ?
C2C C3C C4C C5C -177.5(2) . . . . ?
C3A C4A C5A C6A -158.88(19) . . . . ?
C3A C4A C5A C14A 16.8(2) . . . . ?
C3B C4B C5B C6B -174.3(2) . . . . ?
C3B C4B C5B C14B 2.4(2) . . . . ?
C3C C4C C5C C6C -174.0(2) . . . . ?
C3C C4C C5C C14C 6.5(3) . . . . ?
C4A C5A C6A C7A 174.26(17) . . . . ?
C4A C5A C14A C13A -174.1(2) . . . . ?
C4B C5B C6B C7B 176.34(18) . . . . ?
C4B C5B C14B C12B -175.4(2) . . . . ?
C4C C5C C6C C7C -178.41(18) . . . . ?
C4C C5C C14C C13C 177.6(2) . . . . ?
C5A C6A C7A C8A -178.8(2) . . . . ?
C5A C6A C7A C12A 0.1(2) . . . . ?
C5A C14A C13A C12A 0.1(3) . . . . ?
C5B C6B C7B C8B 179.4(2) . . . . ?
C5B C6B C7B C13B -1.0(2) . . . . ?
C5B C14B C12B C13B -0.5(3) . . . . ?
C5C C6C C7C C8C 179.8(2) . . . . ?
C5C C6C C7C C12C 0.9(2) . . . . ?
C5C C14C C13C C12C 0.7(3) . . . . ?
C6A C5A C14A C13A 1.5(2) . . . . ?
C6A C7A C8A C9A 179.5(2) . . . . ?
C6A C7A C12A C11A -178.8(2) . . . . ?
C6A C7A C12A C13A 1.5(2) . . . . ?
C6B C5B C14B C12B 1.2(2) . . . . ?
C6B C7B C8B C9B 179.8(2) . . . . ?
C6B C7B C13B C11B -178.9(2) . . . . ?
C6B C7B C13B C12B 1.6(2) . . . . ?
C6C C5C C14C C13C -1.9(3) . . . . ?
C6C C7C C8C C9C -178.2(2) . . . . ?
C6C C7C C12C C11C 177.5(2) . . . . ?
C6C C7C C12C C13C -2.1(2) . . . . ?
C7A C6A C5A C14A -1.6(2) . . . . ?
C7A C8A C9A C10A -0.6(3) . . . . ?
C7A C12A C11A C10A -0.8(2) . . . . ?
C7A C12A C13A C14A -1.6(2) . . . . ?
C7B C6B C5B C14B -0.4(2) . . . . ?
C7B C8B C9B C10B -0.9(3) . . . . ?
C7B C13B C11B C10B -0.9(2) . . . . ?
C7B C13B C12B C14B -0.9(2) . . . . ?
C7C C6C C5C C14C 1.1(2) . . . . ?
C7C C8C C9C C10C 0.7(3) . . . . ?
C7C C12C C11C C10C 0.7(2) . . . . ?
C7C C12C C13C C14C 1.3(2) . . . . ?
C8A C7A C12A C11A 0.1(2) . . . . ?
C8A C7A C12A C13A -179.5(2) . . . . ?
C8A C9A C10A C11A 0.0(3) . . . . ?
C8B C7B C13B C11B 0.8(2) . . . . ?
C8B C7B C13B C12B -178.7(2) . . . . ?
C8B C9B C10B C11B 0.8(3) . . . . ?
C8C C7C C12C C11C -1.5(2) . . . . ?
C8C C7C C12C C13C 179.0(2) . . . . ?
C8C C9C C10C C11C -1.5(3) . . . . ?
C9A C8A C7A C12A 0.6(3) . . . . ?
C9A C10A C11A C12A 0.7(3) . . . . ?
C9B C8B C7B C13B 0.1(3) . . . . ?
C9B C10B C11B C13B 0.1(3) . . . . ?
C9C C8C C7C C12C 0.8(3) . . . . ?
C9C C10C C11C C12C 0.8(3) . . . . ?
C10A C11A C12A C13A 178.9(2) . . . . ?
C10B C11B C13B C12B 178.6(2) . . . . ?
C10C C11C C12C C13C -179.8(2) . . . . ?
C11A C12A C13A C14A 178.7(2) . . . . ?
C11B C13B C12B C14B 179.6(2) . . . . ?
C11C C12C C13C C14C -178.2(2) . . . . ?


_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details 
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.440
_oxdiff_exptl_absorpt_empirical_full_min 0.660
