# Copyright The Royal Society of Chemistry, 1998.

data_ipds114 
 
_audit_creation_method            SHELXL 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_formula_moiety          ? 
_chemical_formula_structural      ? 
_chemical_formula_analytical      ? 
_chemical_formula_sum             'C29 H34 N4 O4 P Rh' 
_chemical_formula_weight          636.48 
_chemical_melting_point           '170-172 \% C decomp.' 
_chemical_compound_source         'see text' 
 
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'Rh'  'Rh'  -1.1178   0.9187 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'C'  'C'   0.0033   0.0016 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0061   0.0033 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'O'  'O'   0.0106   0.0060 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'P'  'P'   0.1023   0.0942 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 
_symmetry_cell_setting            monoclinic
_symmetry_space_group_name_H-M    'I 2/a' 
 
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x+1/2, y, -z' 
 'x+1/2, y+1/2, z+1/2' 
 '-x+1, y+1/2, -z+1/2' 
 '-x, -y, -z' 
 'x-1/2, -y, z' 
 '-x+1/2, -y+1/2, -z+1/2' 
 'x, -y+1/2, z+1/2' 
 
_cell_length_a                    15.298(2) 
_cell_length_b                    11.928(2) 
_cell_length_c                    33.903(5) 
_cell_angle_alpha                 90.00 
_cell_angle_beta                  100.232(12) 
_cell_angle_gamma                 90.00 
_cell_volume                      6088.0(15) 
_cell_formula_units_Z             8 
_cell_measurement_temperature     293(2) 
_cell_measurement_reflns_used     2000 
_cell_measurement_theta_min       ? 
_cell_measurement_theta_max       ? 
 
_exptl_crystal_description        plate 
_exptl_crystal_colour             orange 
_exptl_crystal_size_max           0.2 
_exptl_crystal_size_mid           0.2 
_exptl_crystal_size_min           0.05 
_exptl_crystal_density_meas       none 
_exptl_crystal_density_diffrn     1.389 
_exptl_crystal_density_method     none 
_exptl_crystal_F_000              2624 
_exptl_absorpt_coefficient_mu     0.652 
_exptl_absorpt_correction_type    numerical 
_exptl_absorpt_correction_T_min   ? 
_exptl_absorpt_correction_T_max   ? 
 
_exptl_special_details 
; 
 ? 
; 
 
_diffrn_ambient_temperature       293(2) 
_diffrn_radiation_wavelength      0.71073 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device        'STOE Image Plate Detection System' 
_diffrn_measurement_method        
;
 The reciprocical space was scanned with 133 images each of which
 with an exposure time of 5 min and a rotation angle of 1.5
degrees.
;
_diffrn_standards_number          'max. 50 per image' 
_diffrn_standards_interval_count  none 
_diffrn_standards_interval_time   none 
_diffrn_standards_decay_%         <1 
_diffrn_reflns_number             25709 
_diffrn_reflns_av_R_equivalents   0.1032 
_diffrn_reflns_av_sigmaI/netI     0.0595 
_diffrn_reflns_limit_h_min        -17 
_diffrn_reflns_limit_h_max        17 
_diffrn_reflns_limit_k_min        -13 
_diffrn_reflns_limit_k_max        13 
_diffrn_reflns_limit_l_min        -38 
_diffrn_reflns_limit_l_max        38 
_diffrn_reflns_theta_min          1.81 
_diffrn_reflns_theta_max          23.97 
_reflns_number_total              4725 
_reflns_number_observed           3410 
_reflns_observed_criterion        >2sigma(I) 
 
_computing_data_collection
;
 Stoe IPDS-software (STOE publication 4805-010, 1996)
;
_computing_cell_refinement
;
 Stoe IPDS-software (STOE publication 4805-010, 1996)
;
_computing_data_reduction
;
 Stoe IPDS-software (STOE publication 4805-010, 1996)
;
_computing_structure_solution     'SHELXS-86 (Sheldrick, 1990)' 
_computing_structure_refinement   'SHELXL-93 (Sheldrick, 1993)' 
_computing_molecular_graphics     'ORTEPIII (Johnson, C. K., 1997)' 
_computing_publication_material   'SHELXL-93 (Sheldrick, 1993)' 
 
_refine_special_details 
; 
 Refinement on F^2^ for ALL reflections except for 0 with very
negative F^2^ 
 or flagged by the user for potential systematic errors. 
Weighted R-factors 
 wR and all goodnesses of fit S are based on F^2^, conventional
R-factors R 
 are based on F, with F set to zero for negative F^2^. The
observed criterion 
 of F^2^ > 2sigma(F^2^) is used only for calculating
_R_factor_obs etc. and is 
 not relevant to the choice of reflections for refinement. 
R-factors based 
 on F^2^ are statistically about twice as large as those based on
F, and R- 
 factors based on ALL data will be even larger. 
; 
 
_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme 
 'calc w=1/[\s^2^(Fo^2^)+(0.1260P)^2^+46.1524P] where P=(Fo^2^+2Fc^2^)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     'riding model' 
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        none 
_refine_ls_number_reflns          4725 
_refine_ls_number_parameters      352 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.0956 
_refine_ls_R_factor_obs           0.0649 
_refine_ls_wR_factor_all          0.2269 
_refine_ls_wR_factor_obs          0.2063 
_refine_ls_goodness_of_fit_all    1.116 
_refine_ls_goodness_of_fit_obs    1.206 
_refine_ls_restrained_S_all       1.116 
_refine_ls_restrained_S_obs       1.206 
_refine_ls_shift/esd_max          -0.001 
_refine_ls_shift/esd_mean         0.000 
 
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_thermal_displace_type 
 _atom_site_occupancy 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_group 
Rh Rh 0.27740(4) 0.12161(6) 0.36746(2) 0.0326(3) Uani 1 d . . 
C1 C 0.1620(8) -0.1336(10) 0.4321(4) 0.067(3) Uani 1 d . . 
H1A H 0.2042(8) -0.1938(10) 0.4372(4) 0.080 Uiso 1 calc R . 
H1B H 0.1044(8) -0.1634(10) 0.4214(4) 0.080 Uiso 1 calc R . 
H1C H 0.1597(8) -0.0945(10) 0.4566(4) 0.080 Uiso 1 calc R . 
C2 C 0.1896(6) -0.0551(8) 0.4028(3) 0.039(2) Uani 1 d . . 
C3 C 0.1633(6) -0.0719(9) 0.3607(3) 0.046(2) Uani 1 d . . 
C4 C 0.0994(7) -0.1598(10) 0.3411(4) 0.062(3) Uani 1 d . . 
H4A H 0.0756(7) -0.2001(10) 0.3613(4) 0.075 Uiso 1 calc R . 
H4B H 0.1300(7) -0.2109(10) 0.3264(4) 0.075 Uiso 1 calc R . 
H4C H 0.0519(7) -0.1244(10) 0.3231(4) 0.075 Uiso 1 calc R . 
C5 C 0.4155(7) 0.3191(10) 0.2918(3) 0.056(3) Uani 1 d . . 
H5A H 0.4792(7) 0.3218(10) 0.2985(3) 0.067 Uiso 1 calc R . 
H5B H 0.3926(7) 0.3938(10) 0.2872(3) 0.067 Uiso 1 calc R . 
H5C H 0.3984(7) 0.2751(10) 0.2679(3) 0.067 Uiso 1 calc R . 
C6 C 0.3786(6) 0.2666(8) 0.3258(3) 0.039(2) Uani 1 d . . 
C7 C 0.3987(6) 0.3042(8) 0.3671(3) 0.038(2) Uani 1 d . . 
C8 C 0.4582(7) 0.4015(9) 0.3816(4) 0.061(3) Uani 1 d . . 
H8A H 0.4497(7) 0.4598(9) 0.3617(4) 0.074 Uiso 1 calc R . 
H8B H 0.5191(7) 0.3774(9) 0.3860(4) 0.074 Uiso 1 calc R . 
H8C H 0.4439(7) 0.4295(9) 0.4062(4) 0.074 Uiso 1 calc R . 
C9 C 0.0552(5) 0.2451(8) 0.3189(2) 0.037(2) Uani 1 d . . 
C10 C 0.0148(6) 0.1425(9) 0.3126(3) 0.050(3) Uani 1 d . . 
H10 H 0.0407(6) 0.0802(9) 0.3266(3) 0.060 Uiso 1 calc R . 
C11 C -0.0653(7) 0.1302(10) 0.2853(3) 0.064(3) Uani 1 d . . 
H11 H -0.0915(7) 0.0599(10) 0.2810(3) 0.077 Uiso 1 calc R . 
C12 C -0.1046(6) 0.2209(11) 0.2653(3) 0.057(3) Uani 1 d . . 
H12 H -0.1576(6) 0.2130(11) 0.2472(3) 0.069 Uiso 1 calc R . 
C13 C -0.0646(7) 0.3257(11) 0.2721(3) 0.056(3) Uani 1 d . . 
H13 H -0.0912(7) 0.3883(11) 0.2586(3) 0.067 Uiso 1 calc R . 
C14 C 0.0141(6) 0.3368(10) 0.2986(3) 0.051(3) Uani 1 d . . 
H14 H 0.0401(6) 0.4072(10) 0.3030(3) 0.061 Uiso 1 calc R . 
C15 C 0.1924(6) 0.3985(8) 0.3523(3) 0.041(2) Uani 1 d . . 
C16 C 0.2153(6) 0.4266(9) 0.3146(3) 0.048(2) Uani 1 d . . 
H16 H 0.2067(6) 0.3745(9) 0.2939(3) 0.058 Uiso 1 calc R . 
C17 C 0.2505(7) 0.5320(10) 0.3086(3) 0.058(3) Uani 1 d . . 
H17 H 0.2641(7) 0.5500(10) 0.2837(3) 0.069 Uiso 1 calc R . 
C18 C 0.2653(7) 0.6099(10) 0.3393(4) 0.065(3) Uani 1 d . . 
H18 H 0.2890(7) 0.6800(10) 0.3354(4) 0.078 Uiso 1 calc R . 
C19 C 0.2442(8) 0.5814(11) 0.3759(4) 0.069(3) Uani 1 d . . 
H19 H 0.2544(8) 0.6332(11) 0.3967(4) 0.082 Uiso 1 calc R . 
C20 C 0.2080(7) 0.4767(9) 0.3828(3) 0.051(3) Uani 1 d . . 
H20 H 0.1946(7) 0.4600(9) 0.4078(3) 0.061 Uiso 1 calc R . 
C21 C 0.1012(6) 0.2664(8) 0.4044(2) 0.037(2) Uani 1 d . . 
C22 C 0.1530(6) 0.2419(9) 0.4410(2) 0.045(2) Uani 1 d . . 
H22 H 0.2129(6) 0.2253(9) 0.4425(2) 0.054 Uiso 1 calc R . 
C23 C 0.1161(7) 0.2417(10) 0.4759(3) 0.056(3) Uani 1 d . . 
H23 H 0.1511(7) 0.2232(10) 0.5004(3) 0.068 Uiso 1 calc R . 
C24 C 0.0287(7) 0.2689(10) 0.4740(3) 0.061(3) Uani 1 d . . 
H24 H 0.0041(7) 0.2692(10) 0.4972(3) 0.074 Uiso 1 calc R . 
C25 C -0.0232(7) 0.2958(10) 0.4376(3) 0.060(3) Uani 1 d . . 
H25 H -0.0824(7) 0.3155(10) 0.4363(3) 0.072 Uiso 1 calc R . 
C26 C 0.0132(7) 0.2935(10) 0.4025(3) 0.053(3) Uani 1 d . . 
H26 H -0.0222(7) 0.3103(10) 0.3779(3) 0.064 Uiso 1 calc R . 
C27 C 0.3887(6) 0.0138(9) 0.3817(3) 0.047(2) Uani 1 d . . 
H27A H 0.3708(6) -0.0625(9) 0.3743(3) 0.056 Uiso 1 calc R . 
H27B H 0.4337(6) 0.0356(9) 0.3663(3) 0.056 Uiso 1 calc R . 
C28 C 0.4286(7) 0.0189(10) 0.4274(3) 0.058(3) Uani 1 d . . 
H28A H 0.4833(7) -0.0241(10) 0.4319(3) 0.070 Uiso 1 calc R . 
H28B H 0.4442(7) 0.0962(10) 0.4342(3) 0.070 Uiso 1 calc R . 
C29 C 0.3703(7) -0.0234(10) 0.4558(3) 0.057(3) Uani 1 d . . 
H29A H 0.3579(7) -0.1023(10) 0.4505(3) 0.068 Uiso 1 calc R . 
H29B H 0.4026(7) -0.0170(10) 0.4831(3) 0.068 Uiso 1 calc R . 
N1 N 0.2410(4) 0.0307(6) 0.4122(2) 0.037(2) Uani 1 d . . 
N2 N 0.2028(5) -0.0034(7) 0.3390(2) 0.044(2) Uani 1 d . . 
N3 N 0.3223(5) 0.1839(7) 0.3204(2) 0.039(2) Uani 1 d . . 
N4 N 0.3573(4) 0.2502(6) 0.3920(2) 0.035(2) Uani 1 d . . 
O1 O 0.2854(4) 0.0372(6) 0.4528(2) 0.050(2) Uani 1 d . . 
O2 O 0.1909(4) -0.0114(6) 0.2990(2) 0.057(2) Uani 1 d . . 
O3 O 0.2976(5) 0.1412(6) 0.2822(2) 0.055(2) Uani 1 d . . 
H3 H 0.2622(5) 0.0897(6) 0.2826(2) 0.066 Uiso 1 calc R . 
O4 O 0.3676(4) 0.2796(6) 0.4295(2) 0.052(2) Uani 1 d . . 
P P 0.15276(15) 0.2576(2) 0.35906(6) 0.0351(6) Uani 1 d . . 
 
loop_ 
 _atom_site_aniso_label 
 _atom_site_aniso_U_11 
 _atom_site_aniso_U_22 
 _atom_site_aniso_U_33 
 _atom_site_aniso_U_23 
 _atom_site_aniso_U_13 
 _atom_site_aniso_U_12 
Rh 0.0346(4) 0.0432(5) 0.0192(4) -0.0018(3) 0.0026(3) 0.0002(3) 
C1 0.069(7) 0.053(7) 0.084(9) 0.014(6) 0.028(6) -0.001(6) 
C2 0.038(5) 0.046(6) 0.036(5) -0.001(4) 0.012(4) 0.005(4) 
C3 0.036(5) 0.048(6) 0.052(6) -0.006(5) 0.005(4) 0.002(5) 
C4 0.049(6) 0.058(7) 0.080(8) -0.013(6) 0.012(6) -0.009(5) 
C5 0.052(6) 0.073(8) 0.048(6) 0.013(6) 0.023(5) 0.010(6) 
C6 0.040(5) 0.042(6) 0.035(5) 0.009(4) 0.009(4) 0.010(4) 
C7 0.039(5) 0.047(6) 0.029(5) 0.004(4) 0.005(4) -0.001(4) 
C8 0.056(6) 0.063(8) 0.068(7) -0.001(6) 0.017(5) -0.017(5) 
C9 0.034(5) 0.057(6) 0.020(4) 0.005(4) 0.000(3) 0.005(4) 
C10 0.039(5) 0.063(7) 0.044(6) 0.006(5) -0.005(4) -0.006(5) 
C11 0.056(7) 0.071(8) 0.059(7) 0.000(6) -0.005(5) -0.014(6) 
C12 0.035(5) 0.093(10) 0.038(6) -0.002(6) -0.009(4) 0.005(6) 
C13 0.051(6) 0.087(9) 0.026(5) 0.006(5) -0.005(4) 0.019(6) 
C14 0.048(6) 0.073(8) 0.032(5) 0.003(5) 0.008(4) 0.007(5) 
C15 0.033(5) 0.053(7) 0.035(5) 0.005(4) 0.000(4) 0.008(4) 
C16 0.050(6) 0.057(7) 0.039(5) 0.002(5) 0.011(4) 0.007(5) 
C17 0.055(6) 0.056(7) 0.064(7) 0.017(6) 0.017(5) 0.014(5) 
C18 0.055(7) 0.054(8) 0.086(9) 0.016(7) 0.012(6) 0.006(5) 
C19 0.062(7) 0.065(8) 0.076(9) -0.023(7) 0.004(6) -0.005(6) 
C20 0.054(6) 0.056(7) 0.043(6) -0.010(5) 0.009(4) -0.003(5) 
C21 0.040(5) 0.047(6) 0.024(4) 0.002(4) 0.004(4) 0.000(4) 
C22 0.048(5) 0.062(7) 0.025(5) -0.001(4) 0.004(4) 0.010(5) 
C23 0.062(7) 0.079(8) 0.025(5) -0.002(5) 0.001(4) 0.013(6) 
C24 0.072(7) 0.080(9) 0.037(6) -0.001(6) 0.024(5) 0.003(6) 
C25 0.046(6) 0.092(9) 0.046(6) -0.002(6) 0.017(5) 0.010(6) 
C26 0.053(6) 0.075(8) 0.033(5) 0.010(5) 0.013(4) 0.016(5) 
C27 0.048(5) 0.047(6) 0.045(5) 0.001(5) 0.006(4) 0.008(5) 
C28 0.048(6) 0.065(8) 0.058(7) 0.011(6) 0.001(5) 0.006(5) 
C29 0.057(6) 0.070(8) 0.037(5) 0.009(5) -0.007(4) 0.009(6) 
N1 0.038(4) 0.047(5) 0.024(4) -0.002(3) 0.002(3) 0.003(4) 
N2 0.038(4) 0.054(5) 0.038(4) -0.013(4) 0.002(3) -0.002(4) 
N3 0.045(4) 0.053(5) 0.017(4) -0.003(3) 0.006(3) 0.010(4) 
N4 0.040(4) 0.043(5) 0.021(4) -0.004(3) 0.001(3) 0.001(3) 
O1 0.061(4) 0.060(5) 0.028(3) 0.004(3) 0.004(3) 0.007(3) 
O2 0.064(4) 0.077(5) 0.027(3) -0.019(3) -0.001(3) -0.009(4) 
O3 0.066(4) 0.079(5) 0.020(3) -0.008(3) 0.004(3) -0.002(4) 
O4 0.061(4) 0.063(5) 0.030(4) -0.007(3) 0.002(3) -0.007(4) 
P 0.0368(12) 0.048(2) 0.0191(10) 0.0005(10) 0.0013(8) 0.0035(10) 
 
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s.
planes) 
 are estimated using the full covariance matrix.  The cell esds
are taken 
 into account individually in the estimation of esds in
distances, angles 
 and torsion angles; correlations between esds in cell parameters
are only 
 used when they are defined by crystal symmetry.  An approximate
(isotropic) 
 treatment of cell esds is used for estimating esds involving
l.s. planes. 
; 
 
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Rh N3 1.989(7) . ? 
Rh N2 2.016(8) . ? 
Rh N1 2.022(7) . ? 
Rh N4 2.044(7) . ? 
Rh C27 2.120(9) . ? 
Rh P 2.481(2) . ? 
C1 C2 1.480(14) . ? 
C2 N1 1.295(12) . ? 
C2 C3 1.426(13) . ? 
C3 N2 1.314(13) . ? 
C3 C4 1.505(14) . ? 
C5 C6 1.510(13) . ? 
C6 N3 1.300(12) . ? 
C6 C7 1.451(12) . ? 
C7 N4 1.309(11) . ? 
C7 C8 1.502(13) . ? 
C9 C10 1.371(13) . ? 
C9 C14 1.382(13) . ? 
C9 P 1.838(8) . ? 
C10 C11 1.406(13) . ? 
C11 C12 1.36(2) . ? 
C12 C13 1.39(2) . ? 
C13 C14 1.376(13) . ? 
C15 C20 1.382(13) . ? 
C15 C16 1.424(13) . ? 
C15 P 1.816(10) . ? 
C16 C17 1.397(15) . ? 
C17 C18 1.39(2) . ? 
C18 C19 1.38(2) . ? 
C19 C20 1.40(2) . ? 
C21 C26 1.375(13) . ? 
C21 C22 1.381(12) . ? 
C21 P 1.850(8) . ? 
C22 C23 1.398(13) . ? 
C23 C24 1.367(14) . ? 
C24 C25 1.384(14) . ? 
C25 C26 1.399(13) . ? 
C27 C28 1.563(13) . ? 
C28 C29 1.514(14) . ? 
C29 O1 1.474(12) . ? 
N1 O1 1.424(9) . ? 
N2 O2 1.339(9) . ? 
N3 O3 1.380(9) . ? 
N4 O4 1.303(9) . ? 
 
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
N3 Rh N2 98.1(3) . . ? 
N3 Rh N1 169.2(3) . . ? 
N2 Rh N1 75.7(3) . . ? 
N3 Rh N4 77.2(3) . . ? 
N2 Rh N4 175.2(3) . . ? 
N1 Rh N4 108.8(3) . . ? 
N3 Rh C27 91.7(3) . . ? 
N2 Rh C27 91.3(4) . . ? 
N1 Rh C27 79.7(3) . . ? 
N4 Rh C27 88.0(3) . . ? 
N3 Rh P 91.8(2) . . ? 
N2 Rh P 94.0(2) . . ? 
N1 Rh P 97.4(2) . . ? 
N4 Rh P 87.0(2) . . ? 
C27 Rh P 173.1(3) . . ? 
N1 C2 C3 114.2(8) . . ? 
N1 C2 C1 124.5(9) . . ? 
C3 C2 C1 121.3(10) . . ? 
N2 C3 C2 113.3(8) . . ? 
N2 C3 C4 120.9(9) . . ? 
C2 C3 C4 125.8(10) . . ? 
N3 C6 C7 113.1(8) . . ? 
N3 C6 C5 122.4(9) . . ? 
C7 C6 C5 124.5(9) . . ? 
N4 C7 C6 115.1(8) . . ? 
N4 C7 C8 120.4(8) . . ? 
C6 C7 C8 124.4(8) . . ? 
C10 C9 C14 118.4(8) . . ? 
C10 C9 P 118.1(7) . . ? 
C14 C9 P 122.9(8) . . ? 
C9 C10 C11 120.8(10) . . ? 
C12 C11 C10 120.2(11) . . ? 
C11 C12 C13 119.3(9) . . ? 
C14 C13 C12 120.2(10) . . ? 
C13 C14 C9 121.2(11) . . ? 
C20 C15 C16 118.4(10) . . ? 
C20 C15 P 123.2(8) . . ? 
C16 C15 P 118.2(8) . . ? 
C17 C16 C15 120.4(10) . . ? 
C18 C17 C16 120.6(11) . . ? 
C19 C18 C17 118.6(11) . . ? 
C18 C19 C20 122.1(11) . . ? 
C15 C20 C19 119.8(10) . . ? 
C26 C21 C22 119.5(8) . . ? 
C26 C21 P 122.2(6) . . ? 
C22 C21 P 118.3(7) . . ? 
C21 C22 C23 120.5(9) . . ? 
C24 C23 C22 120.0(9) . . ? 
C23 C24 C25 119.8(9) . . ? 
C24 C25 C26 120.3(10) . . ? 
C21 C26 C25 119.9(9) . . ? 
C28 C27 Rh 111.0(7) . . ? 
C29 C28 C27 116.6(8) . . ? 
O1 C29 C28 113.8(8) . . ? 
C2 N1 O1 116.5(7) . . ? 
C2 N1 Rh 118.3(6) . . ? 
O1 N1 Rh 123.2(5) . . ? 
C3 N2 O2 121.9(8) . . ? 
C3 N2 Rh 118.1(6) . . ? 
O2 N2 Rh 120.0(6) . . ? 
C6 N3 O3 118.5(7) . . ? 
C6 N3 Rh 119.0(6) . . ? 
O3 N3 Rh 122.5(6) . . ? 
O4 N4 C7 120.5(7) . . ? 
O4 N4 Rh 124.0(5) . . ? 
C7 N4 Rh 115.5(6) . . ? 
N1 O1 C29 107.7(6) . . ? 
C15 P C9 103.1(4) . . ? 
C15 P C21 104.7(4) . . ? 
C9 P C21 102.1(4) . . ? 
C15 P Rh 110.7(3) . . ? 
C9 P Rh 122.6(3) . . ? 
C21 P Rh 112.0(3) . . ? 
 
_refine_diff_density_max    2.199 
_refine_diff_density_min   -0.509 
_refine_diff_density_rms    0.174 

#=================================END