# Copyright The Royal Society of Chemistry, 1999 # CCDC Number: 186/1446 #============================================================================ data_global #============================================================================ _audit_creation_method 'form.cif (version 2.0)' # PROCESSING SUMMARY (IUCr Office Use Only) _journal_data_validation_number ? _journal_date_recd_electronic ? _journal_date_to_coeditor ? _journal_date_from_coeditor ? _journal_date_accepted ? _journal_date_printers_first ? _journal_date_printers_final ? _journal_date_proofs_out ? _journal_date_proofs_in ? _journal_coeditor_name ? _journal_coeditor_code ? _journal_coeditor_notes ; ? ; _journal_techeditor_code ? _journal_techeditor_notes ; ? ; _journal_coden_ASTM ? _journal_name_full ? _journal_year ? _journal_volume ? _journal_issue ? _journal_page_first ? _journal_page_last ? _journal_paper_category ? _journal_suppl_publ_number ? _journal_suppl_publ_pages ? #============================================================================== # SUBMISSION DETAILS _publ_contact_author_name 'Prof.Fun Hoong Kun' _publ_contact_author_address ; X-ray Crystallography Unit School of Physics Universiti Sains Malaysia 11800 USM, Penang MALAYSIA ; _publ_contact_author_email 'hkfun@usm.my' _publ_contact_author_fax '6 04 6579150' _publ_contact_author_phone '6 04 6577888 Ext. 3690' _publ_requested_journal 'Dalton Transactions' _publ_requested_category ? _publ_requested_coeditor_name ? #============================================================================ # TITLE AND AUTHOR LIST _publ_section_title ; A Three-dimensional Network Coordination Polymer: (Terephthalato) (pyridine) Cadmium with Blue Flourescent Emission ; loop_ _publ_author_name _publ_author_address 'Hoong-Kun Fun' ; X-ray Crystallography Unit School of Physics Universiti Sains Malaysia 11800 USM, Penang Malaysia ; 'S.Shanmuga Sundara Raj' ; X-ray Crystallography Unit School of Physics Universiti Sains Malaysia 11800 USM, Penang Malaysia ; 'Ren-Gen Xiong' ; Coordination Chemistry Institute State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210093 P.R.China ; 'Jing-Lin Zuo' ; Coordination Chemistry Institute State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210093 P.R.China ; 'Zhi Yu' ; Coordination Chemistry Institute State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210093 P.R.China ; 'Xiao-Lei Zhu' ; Coordination Chemistry Institute State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210093 P.R.China ; 'Xiao-Zeng You' ; Coordination Chemistry Institute State Key Laboratory of Coordination Chemistry Nanjing University Nanjing 210093 P.R.China ; #============================================================================ _publ_section_references ; Nardelli, M. (1995). J. Appl. Cryst. 28, 659. Siemens (1996a). SMART Software Reference Manual, Siemens Analytical X-Ray Systems, Inc., Siemens (1996b). SAINT v4 Software Reference Manual, Siemens Analytical X-Ray Systems, Inc., Madison, Wisconsin, USA. Sheldrick, G. M. (1996). SADABS. Program for Empirical Absorption Correction of Area Detector Data, University of G\"ottingen, Germany. Sheldrick, G.M. (1997). SHELXTL V5.1 Software Reference Manual, Bruker AXS, Inc., Madison, Wisconsin, USA. ; _publ_section_exptl_refinement ; The data collection was covered over a hemisphere of reciprocal space by a combination of three sets of exposures; each set had a different \f angle (0, 88 and 180\%) for the crystal and each exposure of 10s covered 0.3\% in \w. The crystal-to-detector distance was 4 cm and the detector swing angle was -35\%. Coverage of the unique set is over 99% complete. Crystal decay was monitored by repeating thirty initial frames at the end of data collection and analysing the duplicate reflections, and was found to be negligible. ; #============================================================================ data_xrgt1m _audit_creation_method SHELXL-97 _chemical_name_systematic ; A Three-dimensional Network Coordination Polymer: (Terephthalato) (pyridine) Cadmium with Blue Flourescent Emission ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C13 H9 Cd N O4' _chemical_formula_weight 355.61 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Cd' 'Cd' -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M 'C 2/c' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' _cell_length_a 16.9875(4) _cell_length_b 9.9995(2) _cell_length_c 7.84760(10) _cell_angle_alpha 90.00 _cell_angle_beta 104.5840(10) _cell_angle_gamma 90.00 _cell_volume 1290.09(4) _cell_formula_units_Z 4 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 4297 _cell_measurement_theta_min 1.37 _cell_measurement_theta_max 33.22 _exptl_crystal_description plate _exptl_crystal_colour transparent _exptl_crystal_size_max 0.52 _exptl_crystal_size_mid 0.30 _exptl_crystal_size_min 0.08 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.831 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 696 _exptl_absorpt_coefficient_mu 1.701 _exptl_absorpt_correction_type empirical _exptl_absorpt_correction_T_min 0.4717 _exptl_absorpt_correction_T_max 0.8760 _exptl_absorpt_process_details 'SADABS (Sheldrick, 1996)' _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type ; Siemens SMART CCD area detector diffractometer ; _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean 8.33 _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 5753 _diffrn_reflns_av_R_equivalents 0.0209 _diffrn_reflns_av_sigmaI/netI 0.0285 _diffrn_reflns_limit_h_min -23 _diffrn_reflns_limit_h_max 25 _diffrn_reflns_limit_k_min -11 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_l_min -11 _diffrn_reflns_limit_l_max 12 _diffrn_reflns_theta_min 3.35 _diffrn_reflns_theta_max 33.17 _reflns_number_total 2389 _reflns_number_gt 2075 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'SMART (Siemens, 1996a)' _computing_cell_refinement 'SAINT (Siemens, 1996b)' _computing_data_reduction 'SAINT (Siemens, 1996b)' _computing_structure_solution 'SHELXTL (Sheldrick, 1997)' _computing_structure_refinement SHELXTL _computing_molecular_graphics SHELXTL _computing_publication_material ; SHELXTL (Sheldrick, 1997) PARST (Nardelli, 1995) ; _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0229P)^2^+0.5981P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 2389 _refine_ls_number_parameters 88 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0345 _refine_ls_R_factor_gt 0.0263 _refine_ls_wR_factor_ref 0.0596 _refine_ls_wR_factor_gt 0.0565 _refine_ls_goodness_of_fit_ref 1.084 _refine_ls_restrained_S_all 1.084 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Cd1 Cd -0.5000 -0.017007(17) -0.2500 0.03689(7) Uani 1 2 d S . . O1 O -0.40613(11) -0.18098(19) -0.2628(3) 0.0622(5) Uani 1 1 d . . . O2 O -0.40964(10) -0.01616(15) -0.4486(2) 0.0494(4) Uani 1 1 d . . . N1 N -0.5000 0.2111(2) -0.2500 0.0518(6) Uani 1 2 d S . . C1 C -0.38022(11) -0.1258(2) -0.3793(3) 0.0443(4) Uani 1 1 d . . . C2 C -0.31158(11) -0.18893(19) -0.4404(3) 0.0390(4) Uani 1 1 d . . . C3 C -0.28463(12) -0.3163(2) -0.3814(3) 0.0467(5) Uani 1 1 d . . . H3A H -0.3086 -0.3620 -0.2993 0.056 Uiso 1 1 d R . . C4 C -0.22337(12) -0.3769(2) -0.4420(3) 0.0458(4) Uani 1 1 d . . . H4A H -0.2049 -0.4649 -0.4018 0.055 Uiso 1 1 d R . . C9 C -0.44989(19) 0.2787(3) -0.3235(4) 0.0698(8) Uani 1 1 d . . . H9A H -0.4144 0.2291 -0.3779 0.084 Uiso 1 1 d R . . C10 C -0.4476(3) 0.4171(3) -0.3229(5) 0.1112(18) Uani 1 1 d . . . H10A H -0.4093 0.4639 -0.3724 0.133 Uiso 1 1 d R . . C11 C -0.5000 0.4866(5) -0.2500 0.138(4) Uani 1 2 d S . . H11A H -0.5000 0.5826 -0.2500 0.166 Uiso 1 2 d SR . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Cd1 0.03735(10) 0.03086(9) 0.05167(12) 0.000 0.02834(8) 0.000 O1 0.0566(10) 0.0688(11) 0.0757(12) 0.0028(9) 0.0437(9) 0.0153(8) O2 0.0371(7) 0.0500(8) 0.0639(10) -0.0069(7) 0.0181(7) 0.0124(6) N1 0.0578(16) 0.0346(12) 0.0564(16) 0.000 0.0020(12) 0.000 C1 0.0302(8) 0.0500(11) 0.0552(12) -0.0122(9) 0.0152(8) 0.0041(7) C2 0.0292(8) 0.0443(10) 0.0464(11) -0.0059(7) 0.0151(7) 0.0064(7) C3 0.0406(10) 0.0494(11) 0.0569(13) 0.0071(9) 0.0249(9) 0.0090(8) C4 0.0371(9) 0.0445(10) 0.0603(13) 0.0066(8) 0.0205(9) 0.0121(7) C9 0.086(2) 0.0495(13) 0.0621(16) 0.0137(11) -0.0042(14) -0.0182(12) C10 0.176(4) 0.0538(18) 0.074(2) 0.0217(15) -0.023(3) -0.047(2) C11 0.264(11) 0.0295(19) 0.079(4) 0.000 -0.038(5) 0.000 _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Cd1 N1 2.281(2) . ? Cd1 O1 2.3069(16) 2_454 ? Cd1 O1 2.3069(16) . ? Cd1 O2 2.4474(17) . ? Cd1 O2 2.4474(17) 2_454 ? Cd1 O2 2.4966(18) 6_556 ? Cd1 O2 2.4966(18) 5_454 ? Cd1 C1 2.7191(18) 2_454 ? Cd1 C1 2.7191(18) . ? O1 C1 1.240(3) . ? O2 C1 1.269(3) . ? O2 Cd1 2.4966(18) 5_454 ? N1 C9 1.327(3) . ? N1 C9 1.327(3) 2_454 ? C1 C2 1.506(2) . ? C2 C4 1.384(3) 7_444 ? C2 C3 1.392(3) . ? C3 C4 1.388(3) . ? C4 C2 1.384(3) 7_444 ? C9 C10 1.385(4) . ? C10 C11 1.363(5) . ? C11 C10 1.363(5) 2_454 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N1 Cd1 O1 135.30(5) . 2_454 ? N1 Cd1 O1 135.30(5) . . ? O1 Cd1 O1 89.41(9) 2_454 . ? N1 Cd1 O2 89.80(3) . . ? O1 Cd1 O2 125.55(6) 2_454 . ? O1 Cd1 O2 54.80(6) . . ? N1 Cd1 O2 89.80(3) . 2_454 ? O1 Cd1 O2 54.80(6) 2_454 2_454 ? O1 Cd1 O2 125.55(6) . 2_454 ? O2 Cd1 O2 179.60(7) . 2_454 ? N1 Cd1 O2 82.37(3) . 6_556 ? O1 Cd1 O2 108.67(6) 2_454 6_556 ? O1 Cd1 O2 82.46(7) . 6_556 ? O2 Cd1 O2 105.56(6) . 6_556 ? O2 Cd1 O2 74.39(6) 2_454 6_556 ? N1 Cd1 O2 82.37(3) . 5_454 ? O1 Cd1 O2 82.46(7) 2_454 5_454 ? O1 Cd1 O2 108.67(6) . 5_454 ? O2 Cd1 O2 74.39(6) . 5_454 ? O2 Cd1 O2 105.56(6) 2_454 5_454 ? O2 Cd1 O2 164.73(7) 6_556 5_454 ? N1 Cd1 C1 113.59(5) . 2_454 ? O1 Cd1 C1 26.99(6) 2_454 2_454 ? O1 Cd1 C1 108.80(7) . 2_454 ? O2 Cd1 C1 152.53(6) . 2_454 ? O2 Cd1 C1 27.81(6) 2_454 2_454 ? O2 Cd1 C1 92.24(6) 6_556 2_454 ? O2 Cd1 C1 93.86(6) 5_454 2_454 ? N1 Cd1 C1 113.59(5) . . ? O1 Cd1 C1 108.80(7) 2_454 . ? O1 Cd1 C1 26.99(6) . . ? O2 Cd1 C1 27.81(6) . . ? O2 Cd1 C1 152.53(6) 2_454 . ? O2 Cd1 C1 93.86(6) 6_556 . ? O2 Cd1 C1 92.24(6) 5_454 . ? C1 Cd1 C1 132.82(10) 2_454 . ? C1 O1 Cd1 95.37(13) . . ? C1 O2 Cd1 88.09(13) . . ? C1 O2 Cd1 127.05(14) . 5_454 ? Cd1 O2 Cd1 105.61(6) . 5_454 ? C9 N1 C9 118.7(3) . 2_454 ? C9 N1 Cd1 120.63(17) . . ? C9 N1 Cd1 120.63(17) 2_454 . ? O1 C1 O2 121.72(18) . . ? O1 C1 C2 119.7(2) . . ? O2 C1 C2 118.6(2) . . ? O1 C1 Cd1 57.64(10) . . ? O2 C1 Cd1 64.10(11) . . ? C2 C1 Cd1 176.70(16) . . ? C4 C2 C3 119.77(16) 7_444 . ? C4 C2 C1 120.64(18) 7_444 . ? C3 C2 C1 119.57(19) . . ? C4 C3 C2 119.85(19) . . ? C2 C4 C3 120.38(19) 7_444 . ? N1 C9 C10 121.9(4) . . ? C11 C10 C9 119.4(4) . . ? C10 C11 C10 118.7(4) 2_454 . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N1 Cd1 O1 C1 -43.10(18) . . . . ? O1 Cd1 O1 C1 136.90(18) 2_454 . . . ? O2 Cd1 O1 C1 0.95(13) . . . . ? O2 Cd1 O1 C1 -178.81(13) 2_454 . . . ? O2 Cd1 O1 C1 -114.17(15) 6_556 . . . ? O2 Cd1 O1 C1 55.07(16) 5_454 . . . ? C1 Cd1 O1 C1 156.03(12) 2_454 . . . ? N1 Cd1 O2 C1 149.80(12) . . . . ? O1 Cd1 O2 C1 -59.62(15) 2_454 . . . ? O1 Cd1 O2 C1 -0.92(12) . . . . ? O2 Cd1 O2 C1 149.80(13) 2_454 . . . ? O2 Cd1 O2 C1 67.78(11) 6_556 . . . ? O2 Cd1 O2 C1 -128.07(15) 5_454 . . . ? C1 Cd1 O2 C1 -60.8(2) 2_454 . . . ? N1 Cd1 O2 Cd1 -82.13(5) . . . 5_454 ? O1 Cd1 O2 Cd1 68.46(9) 2_454 . . 5_454 ? O1 Cd1 O2 Cd1 127.15(9) . . . 5_454 ? O2 Cd1 O2 Cd1 -82.13(7) 2_454 . . 5_454 ? O2 Cd1 O2 Cd1 -164.14(7) 6_556 . . 5_454 ? O2 Cd1 O2 Cd1 0.0 5_454 . . 5_454 ? C1 Cd1 O2 Cd1 67.29(13) 2_454 . . 5_454 ? C1 Cd1 O2 Cd1 128.07(15) . . . 5_454 ? O1 Cd1 N1 C9 -154.17(15) 2_454 . . . ? O1 Cd1 N1 C9 25.83(15) . . . . ? O2 Cd1 N1 C9 -8.79(14) . . . . ? O2 Cd1 N1 C9 171.21(14) 2_454 . . . ? O2 Cd1 N1 C9 96.94(14) 6_556 . . . ? O2 Cd1 N1 C9 -83.06(14) 5_454 . . . ? C1 Cd1 N1 C9 -173.95(15) 2_454 . . . ? C1 Cd1 N1 C9 6.05(15) . . . . ? O1 Cd1 N1 C9 25.83(15) 2_454 . . 2_454 ? O1 Cd1 N1 C9 -154.17(15) . . . 2_454 ? O2 Cd1 N1 C9 171.21(14) . . . 2_454 ? O2 Cd1 N1 C9 -8.79(14) 2_454 . . 2_454 ? O2 Cd1 N1 C9 -83.06(14) 6_556 . . 2_454 ? O2 Cd1 N1 C9 96.94(14) 5_454 . . 2_454 ? C1 Cd1 N1 C9 6.05(15) 2_454 . . 2_454 ? C1 Cd1 N1 C9 -173.95(15) . . . 2_454 ? Cd1 O1 C1 O2 -1.8(2) . . . . ? Cd1 O1 C1 C2 177.73(16) . . . . ? Cd1 O2 C1 O1 1.6(2) . . . . ? Cd1 O2 C1 O1 -106.5(2) 5_454 . . . ? Cd1 O2 C1 C2 -177.84(17) . . . . ? Cd1 O2 C1 C2 74.0(2) 5_454 . . . ? Cd1 O2 C1 Cd1 -108.19(14) 5_454 . . . ? N1 Cd1 C1 O1 148.37(14) . . . . ? O1 Cd1 C1 O1 -46.2(2) 2_454 . . . ? O2 Cd1 C1 O1 -178.3(2) . . . . ? O2 Cd1 C1 O1 2.1(2) 2_454 . . . ? O2 Cd1 C1 O1 65.02(15) 6_556 . . . ? O2 Cd1 C1 O1 -128.99(15) 5_454 . . . ? C1 Cd1 C1 O1 -31.63(14) 2_454 . . . ? N1 Cd1 C1 O2 -33.29(13) . . . . ? O1 Cd1 C1 O2 132.15(13) 2_454 . . . ? O1 Cd1 C1 O2 178.3(2) . . . . ? O2 Cd1 C1 O2 -179.57(8) 2_454 . . . ? O2 Cd1 C1 O2 -116.64(11) 6_556 . . . ? O2 Cd1 C1 O2 49.35(14) 5_454 . . . ? C1 Cd1 C1 O2 146.71(13) 2_454 . . . ? N1 Cd1 C1 C2 112(3) . . . . ? O1 Cd1 C1 C2 -83(3) 2_454 . . . ? O1 Cd1 C1 C2 -37(3) . . . . ? O2 Cd1 C1 C2 145(3) . . . . ? O2 Cd1 C1 C2 -35(3) 2_454 . . . ? O2 Cd1 C1 C2 28(3) 6_556 . . . ? O2 Cd1 C1 C2 -166(3) 5_454 . . . ? C1 Cd1 C1 C2 -68(3) 2_454 . . . ? O1 C1 C2 C4 -173.9(2) . . . 7_444 ? O2 C1 C2 C4 5.6(3) . . . 7_444 ? Cd1 C1 C2 C4 -138(2) . . . 7_444 ? O1 C1 C2 C3 7.9(3) . . . . ? O2 C1 C2 C3 -172.6(2) . . . . ? Cd1 C1 C2 C3 43(3) . . . . ? C4 C2 C3 C4 -0.5(4) 7_444 . . . ? C1 C2 C3 C4 177.73(19) . . . . ? C2 C3 C4 C2 0.5(4) . . . 7_444 ? C9 N1 C9 C10 1.1(2) 2_454 . . . ? Cd1 N1 C9 C10 -178.9(2) . . . . ? N1 C9 C10 C11 -2.2(4) . . . . ? C9 C10 C11 C10 1.03(19) . . . 2_454 ? _diffrn_measured_fraction_theta_max 0.968 _diffrn_reflns_theta_full 33.17 _diffrn_measured_fraction_theta_full 0.968 _refine_diff_density_max 0.451 _refine_diff_density_min -0.324 _refine_diff_density_rms 0.070 #============================================================================ # END OF CIF