# Copyright The Royal Society of Chemistry, 1999
# CCDC Number: 186/1516

data_agbis 
  
_audit_creation_method            SHELXL-97 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common          [Ag(bisimpy)2](PF6) 
_chemical_melting_point           ? 
_chemical_formula_moiety          ? 
_chemical_formula_sum 
 'C38 H54 Ag2 F12 N10 O2 P2' 
_chemical_formula_weight          1188.59 
  
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'C'  'C'   0.0033   0.0016 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0061   0.0033 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'O'  'O'   0.0106   0.0060 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'F'  'F'   0.0171   0.0103 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'P'  'P'   0.1023   0.0942 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Ag'  'Ag'  -0.8971   1.1015 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
  
_symmetry_cell_setting            Monoclinic 
_symmetry_space_group_name_H-M    P2(1)/n 
  
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x+1/2, y+1/2, -z+1/2' 
 '-x, -y, -z' 
 'x-1/2, -y-1/2, z-1/2' 
  
_cell_length_a                    13.4333(7) 
_cell_length_b                    20.8362(11) 
_cell_length_c                    18.5916(10) 
_cell_angle_alpha                 90.00 
_cell_angle_beta                  99.7290(10) 
_cell_angle_gamma                 90.00 
_cell_volume                      5128.9(5) 
_cell_formula_units_Z             4 
_cell_measurement_temperature     -70 
_cell_measurement_reflns_used     ? 
_cell_measurement_theta_min       ? 
_cell_measurement_theta_max       ? 
  
_exptl_crystal_description        ? 
_exptl_crystal_colour             'dark red' 
_exptl_crystal_size_max           0.2 
_exptl_crystal_size_mid           0.1 
_exptl_crystal_size_min           0.1 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     1.539 
_exptl_crystal_density_method     'not measured' 
_exptl_crystal_F_000              2400 
_exptl_absorpt_coefficient_mu     0.912 
_exptl_absorpt_correction_type    integration 
_exptl_absorpt_correction_T_min   0.7397 
_exptl_absorpt_correction_T_max   0.9419 
_exptl_absorpt_process_details    ? 
  
_exptl_special_details 
; 
 ? 
; 
  
_diffrn_ambient_temperature       293(2) 
_diffrn_radiation_wavelength      0.71073 
_diffrn_radiation_type            MoK?a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device_type   'CCD area detector' 
_diffrn_measurement_method        'phi and omega scans' 
_diffrn_detector_area_resol_mean  ? 
_diffrn_standards_number          ? 
_diffrn_standards_interval_count  ? 
_diffrn_standards_interval_time   ? 
_diffrn_standards_decay_%         ? 
_diffrn_reflns_number             27089 
_diffrn_reflns_av_R_equivalents   0.0282 
_diffrn_reflns_av_sigmaI/netI     0.0350 
_diffrn_reflns_limit_h_min        -17 
_diffrn_reflns_limit_h_max        14 
_diffrn_reflns_limit_k_min        -27 
_diffrn_reflns_limit_k_max        25 
_diffrn_reflns_limit_l_min        -12 
_diffrn_reflns_limit_l_max        24 
_diffrn_reflns_theta_min          1.82 
_diffrn_reflns_theta_max          27.59 
_reflns_number_total              11712 
_reflns_number_gt                 8714 
_reflns_threshold_expression      >2sigma(I) 
  
_computing_data_collection        'Bruker SMART' 
_computing_cell_refinement        'Bruker SMART' 
_computing_data_reduction         'Bruker SHELXTL' 
_computing_structure_solution     'SHELXS-97 (Sheldrick, 1990)' 
_computing_structure_refinement   'SHELXL-97 (Sheldrick, 1997)' 
_computing_molecular_graphics     'Bruker SHELXTL' 
_computing_publication_material   'Bruker SHELXTL' 
  
_refine_special_details 
; 
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR 
and 
 goodness of fit S are based on F^2^, conventional R-factors R are based 
 on F, with F set to zero for negative F^2^. The threshold expression of 
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and 
is 
 not relevant to the choice of reflections for refinement.  R-factors 
based 
 on F^2^ are statistically about twice as large as those based on F, and 
R- 
 factors based on ALL data will be even larger. 
; 
  
_refine_ls_structure_factor_coef  Fsqd 
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme       calc 
_refine_ls_weighting_details 
 'calc w=1/[?s^2^(Fo^2^)+(0.0960P)^2^+5.1865P] where P=(Fo^2^+2Fc^2^)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     mixed 
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_number_reflns          11712 
_refine_ls_number_parameters      649 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.0733 
_refine_ls_R_factor_gt            0.0530 
_refine_ls_wR_factor_ref          0.1621 
_refine_ls_wR_factor_gt           0.1471 
_refine_ls_goodness_of_fit_ref    1.031 
_refine_ls_restrained_S_all       1.031 
_refine_ls_shift/su_max           0.098 
_refine_ls_shift/su_mean          0.004 
  
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_adp_type 
 _atom_site_occupancy 
 _atom_site_symmetry_multiplicity 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_assembly 
 _atom_site_disorder_group 
Ag1 Ag 0.81378(3) 0.238111(18) 0.766901(18) 0.04554(12) Uani 1 1 d . . . 
Ag2 Ag 0.79363(2) 0.108785(17) 0.709470(19) 0.04313(11) Uani 1 1 d . . . 
P1 P 0.78358(9) -0.04715(6) 0.85188(7) 0.0478(3) Uani 1 1 d . . . 
P2 P 0.77671(10) 0.06942(7) 0.45857(7) 0.0540(3) Uani 1 1 d . . . 
F1 F 0.7812(5) -0.0400(2) 0.7666(2) 0.1198(17) Uani 1 1 d . . . 
F2 F 0.8096(3) -0.12095(15) 0.8505(3) 0.1021(15) Uani 1 1 d . . . 
F3 F 0.7874(4) -0.0519(2) 0.9352(2) 0.1040(14) Uani 1 1 d . . . 
F4 F 0.7588(3) 0.02758(15) 0.8511(2) 0.0833(11) Uani 1 1 d . . . 
F5 F 0.9004(3) -0.03082(18) 0.8620(3) 0.1025(15) Uani 1 1 d . . . 
F6 F 0.6678(3) -0.0623(2) 0.8388(3) 0.1063(15) Uani 1 1 d . . . 
F7 F 0.8358(4) 0.1153(3) 0.5197(3) 0.1280(19) Uani 1 1 d . . . 
F8 F 0.7078(4) 0.0283(2) 0.3985(2) 0.1161(16) Uani 1 1 d . . . 
F9 F 0.8143(14) 0.0992(9) 0.3892(9) 0.128(6) Uani 0.50 1 d P . . 
F10 F 0.8797(14) 0.0491(9) 0.4542(18) 0.141(8) Uani 0.50 1 d P . . 
F11 F 0.7463(19) 0.0296(14) 0.5237(12) 0.112(8) Uani 0.50 1 d P . . 
F12 F 0.6687(13) 0.0986(11) 0.4652(12) 0.135(8) Uani 0.50 1 d P . . 
F9' F 0.7812(12) 0.1270(6) 0.4046(9) 0.094(4) Uani 0.50 1 d P . . 
F10' F 0.8639(18) 0.0198(11) 0.4576(15) 0.164(11) Uani 0.50 1 d P . . 
F11' F 0.7644(17) 0.0146(12) 0.5132(11) 0.117(8) Uani 0.50 1 d P . . 
F12' F 0.6868(16) 0.1139(9) 0.4636(14) 0.149(11) Uani 0.50 1 d P . . 
O1 O 0.4782(3) 0.2267(2) 0.5403(4) 0.104(2) Uani 1 1 d . . . 
O2 O 1.0309(3) 0.3558(3) 0.5863(2) 0.0993(19) Uani 1 1 d . . . 
O3 O 0.7002(4) 0.2340(3) 1.0316(2) 0.1010(18) Uani 1 1 d . . . 
O4 O 1.1609(3) 0.0904(2) 0.8832(2) 0.0645(10) Uani 1 1 d . . . 
N1 N 0.7805(2) 0.24212(13) 0.63031(16) 0.0276(6) Uani 1 1 d . . . 
N2 N 0.9438(2) 0.28457(15) 0.72997(17) 0.0325(7) Uani 1 1 d . . . 
N3 N 1.0159(3) 0.3357(2) 0.6478(2) 0.0492(9) Uani 1 1 d . . . 
N4 N 0.6497(2) 0.13435(16) 0.65224(19) 0.0350(7) Uani 1 1 d . . . 
N5 N 0.5236(3) 0.18358(19) 0.5814(2) 0.0524(10) Uani 1 1 d . . . 
N6 N 0.8703(2) 0.15865(14) 0.87287(17) 0.0319(6) Uani 1 1 d . . . 
N7 N 0.7191(3) 0.25040(16) 0.8504(2) 0.0377(7) Uani 1 1 d . . . 
N8 N 0.6876(4) 0.2454(2) 0.9634(2) 0.0637(12) Uani 1 1 d . . . 
N9 N 0.9447(2) 0.08794(15) 0.75598(17) 0.0302(6) Uani 1 1 d . . . 
N10 N 1.0937(2) 0.08012(16) 0.8282(2) 0.0392(8) Uani 1 1 d . . . 
C1 C 0.6969(3) 0.22800(16) 0.5833(2) 0.0306(7) Uani 1 1 d . . . 
C2 C 0.6755(4) 0.2529(2) 0.5133(2) 0.0457(10) Uani 1 1 d . . . 
H2A H 0.6158 0.2423 0.4826 0.055 Uiso 1 1 calc R . . 
C3 C 0.7437(4) 0.2933(2) 0.4903(2) 0.0483(11) Uani 1 1 d . . . 
H3A H 0.7310 0.3102 0.4434 0.058 Uiso 1 1 calc R . . 
C4 C 0.8321(3) 0.30914(19) 0.5373(2) 0.0375(8) Uani 1 1 d . . . 
H4A H 0.8796 0.3366 0.5228 0.045 Uiso 1 1 calc R . . 
C5 C 0.8471(3) 0.28244(16) 0.60688(19) 0.0278(7) Uani 1 1 d . . . 
C6 C 0.9360(3) 0.29963(17) 0.6623(2) 0.0295(7) Uani 1 1 d . . . 
C7 C 1.0888(3) 0.3489(2) 0.7161(2) 0.0402(9) Uani 1 1 d . . . 
C8 C 1.0348(3) 0.31440(18) 0.7737(2) 0.0335(8) Uani 1 1 d . . . 
C9 C 1.1904(4) 0.3214(4) 0.7058(4) 0.083(2) Uani 1 1 d . . . 
H9A H 1.2166 0.3458 0.6694 0.125 Uiso 1 1 calc R . . 
H9B H 1.1820 0.2775 0.6904 0.125 Uiso 1 1 calc R . . 
H9C H 1.2367 0.3236 0.7511 0.125 Uiso 1 1 calc R . . 
C10 C 1.0972(5) 0.4220(3) 0.7237(4) 0.0754(18) Uani 1 1 d . . . 
H10A H 1.1311 0.4389 0.6863 0.113 Uiso 1 1 calc R . . 
H10B H 1.1349 0.4327 0.7708 0.113 Uiso 1 1 calc R . . 
H10C H 1.0308 0.4403 0.7189 0.113 Uiso 1 1 calc R . . 
C11 C 1.0964(4) 0.2619(2) 0.8171(3) 0.0534(12) Uani 1 1 d . . . 
H11A H 1.0582 0.2435 0.8511 0.080 Uiso 1 1 calc R . . 
H11B H 1.1579 0.2798 0.8432 0.080 Uiso 1 1 calc R . . 
H11C H 1.1122 0.2292 0.7844 0.080 Uiso 1 1 calc R . . 
C12 C 0.9943(4) 0.3593(3) 0.8267(3) 0.0564(13) Uani 1 1 d . . . 
H12A H 0.9626 0.3346 0.8601 0.085 Uiso 1 1 calc R . . 
H12B H 0.9458 0.3881 0.8000 0.085 Uiso 1 1 calc R . . 
H12C H 1.0491 0.3836 0.8535 0.085 Uiso 1 1 calc R . . 
C13 C 0.6267(3) 0.18197(17) 0.6083(2) 0.0328(8) Uani 1 1 d . . . 
C14 C 0.4730(3) 0.1260(3) 0.6025(3) 0.0589(14) Uani 1 1 d . . . 
C15 C 0.5569(3) 0.0972(2) 0.6611(3) 0.0422(10) Uani 1 1 d . . . 
C16 C 0.4590(6) 0.0847(4) 0.5291(4) 0.094(2) Uani 1 1 d . . . 
H16A H 0.4068 0.1034 0.4937 0.141 Uiso 1 1 calc R . . 
H16B H 0.4406 0.0415 0.5393 0.141 Uiso 1 1 calc R . . 
H16C H 0.5212 0.0843 0.5102 0.141 Uiso 1 1 calc R . . 
C17 C 0.3735(5) 0.1386(5) 0.6207(6) 0.127(4) Uani 1 1 d . . . 
H17A H 0.3805 0.1637 0.6646 0.191 Uiso 1 1 calc R . . 
H17B H 0.3411 0.0986 0.6281 0.191 Uiso 1 1 calc R . . 
H17C H 0.3334 0.1617 0.5815 0.191 Uiso 1 1 calc R . . 
C18 C 0.5417(5) 0.1074(4) 0.7395(3) 0.0751(18) Uani 1 1 d . . . 
H18A H 0.5965 0.0880 0.7721 0.113 Uiso 1 1 calc R . . 
H18B H 0.4792 0.0880 0.7465 0.113 Uiso 1 1 calc R . . 
H18C H 0.5398 0.1526 0.7494 0.113 Uiso 1 1 calc R . . 
C19 C 0.5775(5) 0.0266(3) 0.6494(4) 0.0772(19) Uani 1 1 d . . . 
H19A H 0.6300 0.0118 0.6874 0.116 Uiso 1 1 calc R . . 
H19B H 0.5983 0.0210 0.6029 0.116 Uiso 1 1 calc R . . 
H19C H 0.5171 0.0022 0.6506 0.116 Uiso 1 1 calc R . . 
C20 C 0.9485(3) 0.11819(17) 0.8851(2) 0.0333(8) Uani 1 1 d . . . 
C21 C 0.9849(4) 0.0930(2) 0.9543(2) 0.0487(11) Uani 1 1 d . . . 
H21A H 1.0404 0.0656 0.9614 0.058 Uiso 1 1 calc R . . 
C22 C 0.9376(4) 0.1091(2) 1.0107(3) 0.0581(13) Uani 1 1 d . . . 
H22A H 0.9603 0.0928 1.0572 0.070 Uiso 1 1 calc R . . 
C23 C 0.8552(4) 0.1502(2) 0.9986(2) 0.0520(12) Uani 1 1 d . . . 
H23A H 0.8211 0.1614 1.0364 0.062 Uiso 1 1 calc R . . 
C24 C 0.8250(3) 0.17416(19) 0.9291(2) 0.0379(9) Uani 1 1 d . . . 
C25 C 0.7442(3) 0.2224(2) 0.9126(2) 0.0421(9) Uani 1 1 d . . . 
C26 C 0.6010(5) 0.2844(3) 0.9244(3) 0.0714(17) Uani 1 1 d . . . 
C27 C 0.6470(4) 0.3041(2) 0.8570(3) 0.0485(11) Uani 1 1 d . . . 
C28 C 0.5769(7) 0.3388(5) 0.9734(4) 0.129(4) Uani 1 1 d . . . 
H28A H 0.5490 0.3213 1.0134 0.193 Uiso 1 1 calc R . . 
H28B H 0.5289 0.3674 0.9458 0.193 Uiso 1 1 calc R . . 
H28C H 0.6377 0.3619 0.9918 0.193 Uiso 1 1 calc R . . 
C29 C 0.5117(5) 0.2399(5) 0.9083(5) 0.102(3) Uani 1 1 d . . . 
H29A H 0.4876 0.2300 0.9528 0.153 Uiso 1 1 calc R . . 
H29B H 0.5317 0.2010 0.8871 0.153 Uiso 1 1 calc R . . 
H29C H 0.4588 0.2602 0.8748 0.153 Uiso 1 1 calc R . . 
C30 C 0.7151(5) 0.3645(3) 0.8694(4) 0.0773(19) Uani 1 1 d . . . 
H30A H 0.7411 0.3741 0.8256 0.116 Uiso 1 1 calc R . . 
H30B H 0.7702 0.3566 0.9085 0.116 Uiso 1 1 calc R . . 
H30C H 0.6761 0.4002 0.8817 0.116 Uiso 1 1 calc R . . 
C31 C 0.5714(4) 0.3119(3) 0.7861(3) 0.0571(12) Uani 1 1 d . . . 
H31A H 0.5287 0.2748 0.7785 0.086 Uiso 1 1 calc R . . 
H31B H 0.6074 0.3166 0.7460 0.086 Uiso 1 1 calc R . . 
H31C H 0.5309 0.3494 0.7894 0.086 Uiso 1 1 calc R . . 
C32 C 0.9921(3) 0.09710(16) 0.8214(2) 0.0299(7) Uani 1 1 d . . . 
C33 C 1.1122(3) 0.04476(19) 0.7622(2) 0.0375(8) Uani 1 1 d . . . 
C34 C 1.0152(3) 0.06463(19) 0.7071(2) 0.0356(8) Uani 1 1 d . . . 
C35 C 1.2121(4) 0.0644(3) 0.7424(3) 0.0620(14) Uani 1 1 d . . . 
H35A H 1.2659 0.0499 0.7795 0.093 Uiso 1 1 calc R . . 
H35B H 1.2147 0.1102 0.7386 0.093 Uiso 1 1 calc R . . 
H35C H 1.2193 0.0454 0.6965 0.093 Uiso 1 1 calc R . . 
C36 C 1.1159(4) -0.0267(2) 0.7824(3) 0.0525(11) Uani 1 1 d . . . 
H36A H 1.1769 -0.0355 0.8160 0.079 Uiso 1 1 calc R . . 
H36B H 1.1144 -0.0520 0.7392 0.079 Uiso 1 1 calc R . . 
H36C H 1.0586 -0.0372 0.8049 0.079 Uiso 1 1 calc R . . 
C37 C 1.0327(4) 0.1213(2) 0.6581(3) 0.0501(11) Uani 1 1 d . . . 
H37A H 0.9710 0.1311 0.6259 0.075 Uiso 1 1 calc R . . 
H37B H 1.0839 0.1101 0.6300 0.075 Uiso 1 1 calc R . . 
H37C H 1.0542 0.1580 0.6879 0.075 Uiso 1 1 calc R . . 
C38 C 0.9650(4) 0.0094(2) 0.6612(3) 0.0499(11) Uani 1 1 d . . . 
H38A H 0.9064 0.0249 0.6291 0.075 Uiso 1 1 calc R . . 
H38B H 0.9452 -0.0231 0.6927 0.075 Uiso 1 1 calc R . . 
H38C H 1.0117 -0.0086 0.6329 0.075 Uiso 1 1 calc R . . 
  
loop_ 
 _atom_site_aniso_label 
 _atom_site_aniso_U_11 
 _atom_site_aniso_U_22 
 _atom_site_aniso_U_33 
 _atom_site_aniso_U_23 
 _atom_site_aniso_U_13 
 _atom_site_aniso_U_12 
Ag1 0.0487(2) 0.0561(2) 0.03439(18) 0.01004(14) 0.01445(14) -0.00605(14) 
Ag2 0.03317(17) 0.0512(2) 0.04128(19) 0.00716(14) -0.00451(13) 
0.00369(13) 
P1 0.0511(6) 0.0377(6) 0.0534(7) 0.0093(5) 0.0053(5) -0.0056(5) 
P2 0.0442(6) 0.0691(8) 0.0471(7) 0.0020(6) 0.0030(5) 0.0033(6) 
F1 0.188(5) 0.113(4) 0.063(3) 0.010(2) 0.036(3) 0.006(3) 
F2 0.119(3) 0.0387(17) 0.164(4) 0.008(2) 0.068(3) 0.0023(18) 
F3 0.139(4) 0.115(3) 0.057(2) 0.013(2) 0.016(2) 0.017(3) 
F4 0.078(2) 0.0448(17) 0.126(3) 0.0162(19) 0.012(2) 0.0057(15) 
F5 0.0554(19) 0.071(2) 0.181(5) 0.046(3) 0.018(2) 0.0021(17) 
F6 0.060(2) 0.086(3) 0.166(5) 0.008(3) -0.002(2) -0.0242(19) 
F7 0.121(4) 0.128(4) 0.111(4) -0.012(3) -0.051(3) -0.022(3) 
F8 0.175(5) 0.083(3) 0.078(3) -0.020(2) -0.016(3) -0.013(3) 
F9 0.131(13) 0.184(18) 0.071(7) 0.042(11) 0.018(7) -0.024(11) 
F10 0.062(6) 0.129(13) 0.25(2) 0.048(12) 0.068(9) 0.039(8) 
F11 0.085(8) 0.20(2) 0.057(6) 0.016(9) 0.029(6) -0.033(10) 
F12 0.045(5) 0.25(2) 0.100(11) -0.010(11) -0.008(5) 0.039(8) 
F9' 0.110(10) 0.077(7) 0.095(10) 0.041(6) 0.012(7) -0.010(6) 
F10' 0.154(19) 0.21(2) 0.152(14) 0.081(17) 0.082(14) 0.136(17) 
F11' 0.111(14) 0.119(10) 0.100(14) 0.064(10) -0.041(10) -0.049(9) 
F12' 0.140(16) 0.116(9) 0.165(17) -0.099(11) -0.050(12) 0.072(10) 
O1 0.044(2) 0.090(3) 0.168(5) 0.077(3) -0.011(3) 0.006(2) 
O2 0.082(3) 0.170(5) 0.043(2) 0.025(3) 0.002(2) -0.074(3) 
O3 0.119(4) 0.146(5) 0.047(2) 0.019(3) 0.039(3) 0.049(3) 
O4 0.0405(18) 0.085(3) 0.060(2) -0.0178(19) -0.0153(16) 0.0092(17) 
N1 0.0316(15) 0.0235(14) 0.0275(15) -0.0008(11) 0.0043(12) 0.0002(11) 
N2 0.0355(16) 0.0330(16) 0.0278(15) 0.0001(12) 0.0015(13) -0.0106(13) 
N3 0.044(2) 0.069(3) 0.0335(18) 0.0052(17) 0.0043(15) -0.0251(18) 
N4 0.0297(15) 0.0341(16) 0.0388(18) 0.0042(14) -0.0015(13) -0.0052(12) 
N5 0.0303(17) 0.048(2) 0.074(3) 0.023(2) -0.0053(17) -0.0019(15) 
N6 0.0411(17) 0.0281(15) 0.0265(15) 0.0035(12) 0.0055(13) 0.0029(12) 
N7 0.0445(19) 0.0347(17) 0.0363(18) 0.0042(14) 0.0136(15) 0.0070(14) 
N8 0.073(3) 0.086(3) 0.038(2) 0.007(2) 0.027(2) 0.029(2) 
N9 0.0313(15) 0.0302(15) 0.0287(15) 0.0021(12) 0.0040(12) 0.0032(12) 
N10 0.0337(17) 0.0386(18) 0.0425(19) -0.0055(15) -0.0021(14) 0.0050(13) 
C1 0.0313(18) 0.0254(17) 0.0335(19) 0.0010(14) 0.0008(15) 0.0004(13) 
C2 0.046(2) 0.050(2) 0.034(2) 0.0037(18) -0.0109(19) -0.0092(19) 
C3 0.058(3) 0.052(3) 0.030(2) 0.0103(19) -0.0070(19) -0.008(2) 
C4 0.048(2) 0.037(2) 0.0281(19) 0.0028(15) 0.0079(16) -0.0078(17) 
C5 0.0330(17) 0.0250(16) 0.0256(17) -0.0016(13) 0.0054(14) -0.0027(13) 
C6 0.0328(18) 0.0273(17) 0.0287(18) -0.0004(13) 0.0059(14) -0.0022(13) 
C7 0.034(2) 0.048(2) 0.038(2) 0.0002(17) 0.0024(16) -0.0132(17) 
C8 0.0336(19) 0.0337(19) 0.0311(19) -0.0039(15) -0.0005(15) -0.0055(15) 
C9 0.045(3) 0.128(6) 0.080(4) 0.013(4) 0.022(3) 0.014(3) 
C10 0.106(5) 0.048(3) 0.074(4) 0.001(3) 0.019(4) -0.033(3) 
C11 0.052(3) 0.052(3) 0.049(3) 0.010(2) -0.011(2) -0.005(2) 
C12 0.060(3) 0.058(3) 0.053(3) -0.024(2) 0.013(2) -0.015(2) 
C13 0.0293(18) 0.0292(18) 0.037(2) 0.0013(15) -0.0025(15) -0.0029(14) 
C14 0.031(2) 0.066(3) 0.075(4) 0.029(3) -0.004(2) -0.014(2) 
C15 0.036(2) 0.042(2) 0.047(2) 0.0091(18) 0.0019(18) -0.0092(16) 
C16 0.105(5) 0.094(5) 0.068(4) 0.009(4) -0.027(4) -0.040(4) 
C17 0.047(4) 0.145(8) 0.197(10) 0.089(7) 0.042(5) 0.024(4) 
C18 0.060(3) 0.115(5) 0.055(3) 0.004(3) 0.022(3) -0.021(3) 
C19 0.070(4) 0.044(3) 0.109(5) 0.004(3) -0.009(3) -0.014(3) 
C20 0.042(2) 0.0269(17) 0.0297(19) 0.0025(14) 0.0012(15) 0.0041(14) 
C21 0.061(3) 0.047(2) 0.035(2) 0.0038(18) -0.002(2) 0.020(2) 
C22 0.085(4) 0.059(3) 0.028(2) 0.013(2) 0.005(2) 0.021(3) 
C23 0.084(3) 0.044(2) 0.031(2) 0.0044(18) 0.020(2) 0.013(2) 
C24 0.051(2) 0.0320(19) 0.032(2) 0.0052(16) 0.0118(17) 0.0053(16) 
C25 0.053(2) 0.045(2) 0.032(2) 0.0045(17) 0.0172(18) 0.0107(19) 
C26 0.067(4) 0.098(4) 0.051(3) -0.001(3) 0.018(3) 0.038(3) 
C27 0.047(2) 0.048(2) 0.050(3) -0.002(2) 0.008(2) 0.020(2) 
C28 0.138(7) 0.180(9) 0.069(5) -0.030(5) 0.020(5) 0.103(7) 
C29 0.066(4) 0.154(8) 0.095(6) 0.038(5) 0.041(4) 0.013(4) 
C30 0.072(4) 0.042(3) 0.108(5) -0.008(3) -0.015(3) 0.021(3) 
C31 0.050(3) 0.061(3) 0.059(3) 0.005(2) 0.004(2) 0.020(2) 
C32 0.0322(18) 0.0225(16) 0.0337(19) 0.0026(13) 0.0021(15) 0.0035(13) 
C33 0.0334(19) 0.0343(19) 0.045(2) -0.0035(17) 0.0071(17) 0.0041(15) 
C34 0.038(2) 0.0342(19) 0.034(2) -0.0008(16) 0.0064(16) 0.0012(15) 
C35 0.043(3) 0.069(3) 0.077(4) -0.003(3) 0.019(3) -0.002(2) 
C36 0.054(3) 0.039(2) 0.063(3) 0.002(2) 0.005(2) 0.0117(19) 
C37 0.060(3) 0.052(3) 0.041(2) 0.007(2) 0.017(2) 0.002(2) 
C38 0.053(3) 0.048(2) 0.047(3) -0.017(2) 0.004(2) 0.000(2) 
  
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are 
only 
 used when they are defined by crystal symmetry.  An approximate 
(isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. 
planes. 
; 
  
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Ag1 N7 2.182(3) . ? 
Ag1 N2 2.206(3) . ? 
Ag1 N1 2.504(3) . ? 
Ag1 N6 2.587(3) . ? 
Ag1 Ag2 2.8943(5) . ? 
Ag2 N4 2.112(3) . ? 
Ag2 N9 2.112(3) . ? 
P1 F3 1.544(4) . ? 
P1 F6 1.566(4) . ? 
P1 F2 1.578(3) . ? 
P1 F5 1.586(4) . ? 
P1 F1 1.588(4) . ? 
P1 F4 1.592(3) . ? 
P2 F10 1.462(18) . ? 
P2 F12' 1.537(15) . ? 
P2 F11' 1.555(17) . ? 
P2 F10' 1.564(19) . ? 
P2 F9' 1.571(13) . ? 
P2 F8 1.578(4) . ? 
P2 F11 1.58(2) . ? 
P2 F9 1.589(16) . ? 
P2 F7 1.591(5) . ? 
P2 F12 1.598(16) . ? 
F9 F9' 0.810(18) . ? 
F9 F10 1.72(3) . ? 
F10 F10' 0.65(3) . ? 
O1 N5 1.267(5) . ? 
O2 N3 1.265(5) . ? 
O3 N8 1.272(6) . ? 
O4 N10 1.262(5) . ? 
N1 C1 1.334(5) . ? 
N1 C5 1.352(5) . ? 
N2 C6 1.284(5) . ? 
N2 C8 1.485(4) . ? 
N3 C6 1.374(5) . ? 
N3 C7 1.493(5) . ? 
N4 C13 1.289(5) . ? 
N4 C15 1.500(5) . ? 
N5 C13 1.391(5) . ? 
N5 C14 1.464(6) . ? 
N6 C24 1.335(5) . ? 
N6 C20 1.336(5) . ? 
N7 C25 1.289(5) . ? 
N7 C27 1.498(5) . ? 
N8 C25 1.393(5) . ? 
N8 C26 1.503(7) . ? 
N9 C32 1.289(5) . ? 
N9 C34 1.501(5) . ? 
N10 C32 1.395(5) . ? 
N10 C33 1.488(5) . ? 
C1 C2 1.384(6) . ? 
C1 C13 1.475(5) . ? 
C2 C3 1.365(7) . ? 
C3 C4 1.390(6) . ? 
C4 C5 1.391(5) . ? 
C5 C6 1.482(5) . ? 
C7 C9 1.521(7) . ? 
C7 C10 1.533(7) . ? 
C7 C8 1.566(6) . ? 
C8 C11 1.519(6) . ? 
C8 C12 1.524(6) . ? 
C14 C17 1.457(8) . ? 
C14 C15 1.550(6) . ? 
C14 C16 1.599(10) . ? 
C15 C19 1.519(7) . ? 
C15 C18 1.521(7) . ? 
C20 C21 1.398(6) . ? 
C20 C32 1.474(5) . ? 
C21 C22 1.358(7) . ? 
C22 C23 1.388(7) . ? 
C23 C24 1.380(6) . ? 
C24 C25 1.473(6) . ? 
C26 C29 1.506(10) . ? 
C26 C28 1.521(9) . ? 
C26 C27 1.542(8) . ? 
C27 C31 1.531(7) . ? 
C27 C30 1.550(8) . ? 
C33 C35 1.506(6) . ? 
C33 C36 1.534(6) . ? 
C33 C34 1.571(6) . ? 
C34 C38 1.522(6) . ? 
C34 C37 1.532(6) . ? 
  
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
N7 Ag1 N2 139.25(13) . . ? 
N7 Ag1 N1 133.77(12) . . ? 
N2 Ag1 N1 71.63(10) . . ? 
N7 Ag1 N6 70.42(11) . . ? 
N2 Ag1 N6 111.82(11) . . ? 
N1 Ag1 N6 140.59(9) . . ? 
N7 Ag1 Ag2 110.02(9) . . ? 
N2 Ag1 Ag2 108.87(9) . . ? 
N1 Ag1 Ag2 70.58(7) . . ? 
N6 Ag1 Ag2 71.48(7) . . ? 
N4 Ag2 N9 173.09(13) . . ? 
N4 Ag2 Ag1 88.38(9) . . ? 
N9 Ag2 Ag1 90.97(8) . . ? 
F3 P1 F6 90.3(3) . . ? 
F3 P1 F2 89.0(3) . . ? 
F6 P1 F2 91.0(2) . . ? 
F3 P1 F5 91.8(3) . . ? 
F6 P1 F5 177.8(3) . . ? 
F2 P1 F5 89.6(2) . . ? 
F3 P1 F1 178.2(3) . . ? 
F6 P1 F1 90.7(3) . . ? 
F2 P1 F1 92.4(3) . . ? 
F5 P1 F1 87.2(3) . . ? 
F3 P1 F4 92.5(2) . . ? 
F6 P1 F4 89.7(2) . . ? 
F2 P1 F4 178.3(3) . . ? 
F5 P1 F4 89.6(2) . . ? 
F1 P1 F4 86.0(3) . . ? 
F10 P2 F12' 159.7(12) . . ? 
F10 P2 F11' 91.8(12) . . ? 
F12' P2 F11' 103.3(15) . . ? 
F10 P2 F10' 24.6(12) . . ? 
F12' P2 F10' 174.9(14) . . ? 
F11' P2 F10' 71.7(12) . . ? 
F10 P2 F9' 92.7(9) . . ? 
F12' P2 F9' 72.2(12) . . ? 
F11' P2 F9' 175.5(11) . . ? 
F10' P2 F9' 112.8(9) . . ? 
F10 P2 F8 104.5(13) . . ? 
F12' P2 F8 89.9(7) . . ? 
F11' P2 F8 87.1(9) . . ? 
F10' P2 F8 89.0(11) . . ? 
F9' P2 F8 92.5(7) . . ? 
F10 P2 F11 105.2(13) . . ? 
F12' P2 F11 87.8(15) . . ? 
F11' P2 F11 16.8(18) . . ? 
F10' P2 F11 87.3(12) . . ? 
F9' P2 F11 159.1(11) . . ? 
F8 P2 F11 93.5(11) . . ? 
F10 P2 F9 68.6(12) . . ? 
F12' P2 F9 100.1(13) . . ? 
F11' P2 F9 154.3(12) . . ? 
F10' P2 F9 84.7(10) . . ? 
F9' P2 F9 29.7(6) . . ? 
F8 P2 F9 82.3(8) . . ? 
F11 P2 F9 171.0(12) . . ? 
F10 P2 F7 81.4(13) . . ? 
F12' P2 F7 84.1(7) . . ? 
F11' P2 F7 94.0(9) . . ? 
F10' P2 F7 97.0(11) . . ? 
F9' P2 F7 86.0(7) . . ? 
F8 P2 F7 173.9(3) . . ? 
F11 P2 F7 86.0(11) . . ? 
F9 P2 F7 99.0(8) . . ? 
F10 P2 F12 174.2(12) . . ? 
F12' P2 F12 14.6(16) . . ? 
F11' P2 F12 91.8(13) . . ? 
F10' P2 F12 160.8(13) . . ? 
F9' P2 F12 83.8(10) . . ? 
F8 P2 F12 80.2(7) . . ? 
F11 P2 F12 77.5(13) . . ? 
F9 P2 F12 109.3(11) . . ? 
F7 P2 F12 93.8(8) . . ? 
F9' F9 P2 74.0(18) . . ? 
F9' F9 F10 116(3) . . ? 
P2 F9 F10 52.2(8) . . ? 
F10' F10 P2 86(3) . . ? 
F10' F10 F9 120(5) . . ? 
P2 F10 F9 59.2(9) . . ? 
F9 F9' P2 76.3(18) . . ? 
F10 F10' P2 69(3) . . ? 
C1 N1 C5 117.1(3) . . ? 
C1 N1 Ag1 130.1(2) . . ? 
C5 N1 Ag1 109.4(2) . . ? 
C6 N2 C8 111.0(3) . . ? 
C6 N2 Ag1 118.3(2) . . ? 
C8 N2 Ag1 129.4(2) . . ? 
O2 N3 C6 127.4(4) . . ? 
O2 N3 C7 121.7(3) . . ? 
C6 N3 C7 110.8(3) . . ? 
C13 N4 C15 110.6(3) . . ? 
C13 N4 Ag2 127.9(3) . . ? 
C15 N4 Ag2 121.4(2) . . ? 
O1 N5 C13 125.6(4) . . ? 
O1 N5 C14 123.0(4) . . ? 
C13 N5 C14 111.2(3) . . ? 
C24 N6 C20 117.9(3) . . ? 
C24 N6 Ag1 109.1(2) . . ? 
C20 N6 Ag1 130.9(3) . . ? 
C25 N7 C27 109.8(4) . . ? 
C25 N7 Ag1 119.3(3) . . ? 
C27 N7 Ag1 127.5(3) . . ? 
O3 N8 C25 127.9(4) . . ? 
O3 N8 C26 123.0(4) . . ? 
C25 N8 C26 109.0(4) . . ? 
C32 N9 C34 111.0(3) . . ? 
C32 N9 Ag2 130.1(3) . . ? 
C34 N9 Ag2 118.7(2) . . ? 
O4 N10 C32 125.8(4) . . ? 
O4 N10 C33 123.8(3) . . ? 
C32 N10 C33 110.3(3) . . ? 
N1 C1 C2 123.5(4) . . ? 
N1 C1 C13 116.7(3) . . ? 
C2 C1 C13 119.9(3) . . ? 
C3 C2 C1 118.8(4) . . ? 
C2 C3 C4 119.8(4) . . ? 
C5 C4 C3 117.6(4) . . ? 
N1 C5 C4 123.2(3) . . ? 
N1 C5 C6 115.2(3) . . ? 
C4 C5 C6 121.5(3) . . ? 
N2 C6 N3 112.9(3) . . ? 
N2 C6 C5 123.1(3) . . ? 
N3 C6 C5 124.0(3) . . ? 
N3 C7 C9 107.2(4) . . ? 
N3 C7 C10 106.8(4) . . ? 
C9 C7 C10 109.4(5) . . ? 
N3 C7 C8 100.6(3) . . ? 
C9 C7 C8 116.3(4) . . ? 
C10 C7 C8 115.4(4) . . ? 
N2 C8 C11 108.3(3) . . ? 
N2 C8 C12 105.1(3) . . ? 
C11 C8 C12 108.7(4) . . ? 
N2 C8 C7 104.5(3) . . ? 
C11 C8 C7 114.8(4) . . ? 
C12 C8 C7 114.7(4) . . ? 
N4 C13 N5 111.4(3) . . ? 
N4 C13 C1 127.1(3) . . ? 
N5 C13 C1 121.4(3) . . ? 
C17 C14 N5 113.6(5) . . ? 
C17 C14 C15 119.5(6) . . ? 
N5 C14 C15 101.0(3) . . ? 
C17 C14 C16 108.4(6) . . ? 
N5 C14 C16 101.9(5) . . ? 
C15 C14 C16 111.0(5) . . ? 
N4 C15 C19 108.0(4) . . ? 
N4 C15 C18 106.4(4) . . ? 
C19 C15 C18 109.3(5) . . ? 
N4 C15 C14 104.0(3) . . ? 
C19 C15 C14 113.8(4) . . ? 
C18 C15 C14 114.8(5) . . ? 
N6 C20 C21 122.5(4) . . ? 
N6 C20 C32 117.3(3) . . ? 
C21 C20 C32 120.1(4) . . ? 
C22 C21 C20 118.8(4) . . ? 
C21 C22 C23 119.5(4) . . ? 
C24 C23 C22 118.3(4) . . ? 
N6 C24 C23 123.0(4) . . ? 
N6 C24 C25 114.8(3) . . ? 
C23 C24 C25 122.0(4) . . ? 
N7 C25 N8 111.3(4) . . ? 
N7 C25 C24 124.6(4) . . ? 
N8 C25 C24 124.1(4) . . ? 
C29 C26 N8 106.7(6) . . ? 
C29 C26 C28 109.6(6) . . ? 
N8 C26 C28 109.8(5) . . ? 
C29 C26 C27 114.7(5) . . ? 
N8 C26 C27 98.7(4) . . ? 
C28 C26 C27 116.3(7) . . ? 
N7 C27 C31 110.7(4) . . ? 
N7 C27 C26 102.8(4) . . ? 
C31 C27 C26 115.4(4) . . ? 
N7 C27 C30 104.2(4) . . ? 
C31 C27 C30 109.2(4) . . ? 
C26 C27 C30 113.8(5) . . ? 
N9 C32 N10 111.6(3) . . ? 
N9 C32 C20 127.0(3) . . ? 
N10 C32 C20 121.2(3) . . ? 
N10 C33 C35 110.3(4) . . ? 
N10 C33 C36 106.3(4) . . ? 
C35 C33 C36 109.3(4) . . ? 
N10 C33 C34 99.9(3) . . ? 
C35 C33 C34 116.3(4) . . ? 
C36 C33 C34 113.9(3) . . ? 
N9 C34 C38 108.6(3) . . ? 
N9 C34 C37 106.6(3) . . ? 
C38 C34 C37 110.4(4) . . ? 
N9 C34 C33 103.2(3) . . ? 
C38 C34 C33 114.0(3) . . ? 
C37 C34 C33 113.4(3) . . ? 
  
_diffrn_measured_fraction_theta_max    0.984 
_diffrn_reflns_theta_full              27.59 
_diffrn_measured_fraction_theta_full   0.984 
_refine_diff_density_max    3.302 
_refine_diff_density_min   -1.489 
_refine_diff_density_rms    0.106