# Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 1999
# CCDC Number: 186/1582 
data_nabs 
 
_audit_creation_method            SHELXL 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_formula_moiety          ? 
_chemical_formula_structural      ? 
_chemical_formula_analytical      ? 
_chemical_formula_sum             'C140 H156 Cl52 Mn4 N4 O20 P12 Sb8' 
_chemical_formula_weight          5623.49 
_chemical_melting_point           ? 
_chemical_compound_source         ? 
 
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'C'  'C'   0.0033   0.0016 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0061   0.0033 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'O'  'O'   0.0106   0.0060 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'P'  'P'   0.1023   0.0942 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Cl'  'Cl'   0.1484   0.1585 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Mn'  'Mn'   0.3368   0.7283 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Sb'  'Sb'  -0.5866   1.5461 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 
_symmetry_cell_setting            monoclinic
_symmetry_space_group_name_H-M    'P2(1)/n' 
 
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x+1/2, y+1/2, -z+1/2' 
 '-x, -y, -z' 
 'x-1/2, -y-1/2, z-1/2' 
 
_cell_length_a                    16.267(3) 
_cell_length_b                    13.822(3) 
_cell_length_c                    24.993(5) 
_cell_angle_alpha                 90.00 
_cell_angle_beta                  97.95(3) 
_cell_angle_gamma                 90.00 
_cell_volume                      5565.7(19) 
_cell_formula_units_Z             1 
_cell_measurement_temperature     293(2) 
_cell_measurement_reflns_used     ? 
_cell_measurement_theta_min       ? 
_cell_measurement_theta_max       ? 
 
_exptl_crystal_description        ? 
_exptl_crystal_colour             ? 
_exptl_crystal_size_max           .3 
_exptl_crystal_size_mid           .2 
_exptl_crystal_size_min           .2 
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     1.678 
_exptl_crystal_density_method     ? 
_exptl_crystal_F_000              2756 
_exptl_absorpt_coefficient_mu     1.934 
_exptl_absorpt_correction_type    empirical  
_exptl_absorpt_correction_T_min   .419 
_exptl_absorpt_correction_T_max   .679 
 
_exptl_special_details 
; 
 ? 
; 
 
_diffrn_ambient_temperature       293(2) 
_diffrn_radiation_wavelength      0.71073 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device        ? 
_diffrn_measurement_method        ? 
_diffrn_standards_number          ? 
_diffrn_standards_interval_count  ? 
_diffrn_standards_interval_time   ? 
_diffrn_standards_decay_%         ? 
_diffrn_reflns_number             21246 
_diffrn_reflns_av_R_equivalents   0.0321 
_diffrn_reflns_av_sigmaI/netI     0.0272 
_diffrn_reflns_limit_h_min        -18 
_diffrn_reflns_limit_h_max        16 
_diffrn_reflns_limit_k_min        -9 
_diffrn_reflns_limit_k_max        15 
_diffrn_reflns_limit_l_min        -27 
_diffrn_reflns_limit_l_max        26 
_diffrn_reflns_theta_min          1.41 
_diffrn_reflns_theta_max          23.29 
_reflns_number_total              7948 
_reflns_number_observed           6754 
_reflns_observed_criterion        >2sigma(I) 
 
_computing_data_collection        ? 
_computing_cell_refinement        ? 
_computing_data_reduction         ? 
_computing_structure_solution     'SHELXS-86 (Sheldrick, 1990)' 
_computing_structure_refinement   'SHELXL-93 (Sheldrick, 1993)' 
_computing_molecular_graphics     ? 
_computing_publication_material   ? 
 
_refine_special_details 
; 
 Refinement on F^2^ for ALL reflections except for 8 with very negative F^2^ 
 or flagged by the user for potential systematic errors.  Weighted R-factors 
 wR and all goodnesses of fit S are based on F^2^, conventional R-factors R 
 are based on F, with F set to zero for negative F^2^. The observed criterion 
 of F^2^ > 2sigma(F^2^) is used only for calculating _R_factor_obs etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F^2^ are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
; 
 
_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme 
 'calc w=1/[\s^2^(Fo^2^)+(0.0550P)^2^+16.3736P] where P=(Fo^2^+2Fc^2^)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     ? 
_refine_ls_extinction_method      none 
_refine_ls_extinction_coef        ? 
_refine_ls_number_reflns          7940 
_refine_ls_number_parameters      539 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.0585 
_refine_ls_R_factor_obs           0.0476 
_refine_ls_wR_factor_all          0.1334 
_refine_ls_wR_factor_obs          0.1205 
_refine_ls_goodness_of_fit_all    1.111 
_refine_ls_goodness_of_fit_obs    1.099 
_refine_ls_restrained_S_all       1.116 
_refine_ls_restrained_S_obs       1.099 
_refine_ls_shift/esd_max          0.005 
_refine_ls_shift/esd_mean         0.000 
 
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_thermal_displace_type 
 _atom_site_occupancy 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_group 
Sb1 Sb 0.12734(3) 0.33643(3) 0.12599(2) 0.0647(2) Uani 1 d . . 
Sb2 Sb 0.77377(3) 0.97119(3) 0.14394(2) 0.0625(2) Uani 1 d . . 
Mn1 Mn 0.32429(5) 0.62199(6) 0.08629(3) 0.0444(2) Uani 1 d . . 
P1 P 0.22348(9) 0.66935(11) 0.01418(6) 0.0459(4) Uani 1 d . . 
P2 P 0.37188(9) 0.76613(11) 0.05082(6) 0.0452(4) Uani 1 d . . 
P3 P 0.43373(11) 0.58305(14) 0.15242(7) 0.0604(4) Uani 1 d . . 
Cl1 Cl 0.2306(2) 0.2667(2) 0.18818(12) 0.1235(10) Uani 1 d . . 
Cl2 Cl 0.0302(2) 0.2169(2) 0.13785(11) 0.1175(9) Uani 1 d . . 
Cl3 Cl 0.17921(14) 0.2534(2) 0.05642(11) 0.0986(7) Uani 1 d . . 
Cl4 Cl 0.0899(2) 0.4354(3) 0.19339(13) 0.1420(12) Uani 1 d . . 
Cl5 Cl 0.03786(12) 0.4196(2) 0.06105(10) 0.0947(7) Uani 1 d . . 
Cl6 Cl 0.7794(2) 0.8019(2) 0.13931(12) 0.1169(9) Uani 1 d . . 
Cl7 Cl 0.7609(2) 0.9647(2) 0.23620(9) 0.1164(9) Uani 1 d . . 
Cl8 Cl 0.7712(2) 1.1420(2) 0.14760(11) 0.1252(10) Uani 1 d . . 
Cl9 Cl 0.7867(2) 0.9782(2) 0.05092(9) 0.1024(7) Uani 1 d . . 
Cl10 Cl 0.62978(14) 0.9688(2) 0.12191(12) 0.1134(8) Uani 1 d . . 
Cl11 Cl 0.9197(2) 0.9759(3) 0.16555(15) 0.1420(12) Uani 1 d . . 
Cl12 Cl 1.0607(5) 0.7060(7) 0.2359(4) 0.348(5) Uani 1 d . . 
Cl13 Cl 0.9156(4) 0.6714(5) 0.2726(3) 0.248(3) Uani 1 d . . 
O1 O 0.2503(3) 0.7424(4) 0.1672(2) 0.083(2) Uani 1 d . . 
O2 O 0.4063(3) 0.5062(4) 0.0081(2) 0.0780(14) Uani 1 d . . 
O3 O 0.4994(3) 0.5165(5) 0.1299(2) 0.093(2) Uani 1 d . . 
O4 O 0.4805(3) 0.6754(4) 0.1734(2) 0.093(2) Uani 1 d . . 
O5 O 0.4143(4) 0.5219(5) 0.2014(2) 0.092(2) Uani 1 d . . 
N1 N 0.2185(4) 0.4475(4) 0.1147(2) 0.0653(15) Uani 1 d . . 
C1 C 0.2774(4) 0.6970(5) 0.1363(3) 0.056(2) Uani 1 d . . 
C2 C 0.3752(4) 0.5499(5) 0.0377(3) 0.0533(15) Uani 1 d . . 
C3 C 0.2600(4) 0.5102(5) 0.1051(3) 0.0519(14) Uani 1 d . . 
C4 C 0.2913(4) 0.7622(4) -0.0084(2) 0.0513(14) Uani 1 d . . 
H4A H 0.2630(4) 0.8238(4) -0.0146(2) 0.062 Uiso 1 calc R . 
H4B H 0.3136(4) 0.7426(4) -0.0408(2) 0.062 Uiso 1 calc R . 
C5 C 0.1293(4) 0.7275(5) 0.0276(3) 0.058(2) Uani 1 d . . 
C6 C 0.0891(4) 0.6943(7) 0.0683(3) 0.084(2) Uani 1 d . . 
H6A H 0.1094(4) 0.6410(7) 0.0887(3) 0.101 Uiso 1 calc R . 
C7 C 0.0168(5) 0.7416(10) 0.0791(4) 0.120(4) Uani 1 d . . 
H7A H -0.0107(5) 0.7206(10) 0.1072(4) 0.143 Uiso 1 calc R . 
C8 C -0.0129(6) 0.8185(10) 0.0481(5) 0.124(4) Uani 1 d . . 
H8A H -0.0608(6) 0.8493(10) 0.0555(5) 0.148 Uiso 1 calc R . 
C9 C 0.0249(6) 0.8508(7) 0.0073(5) 0.105(3) Uani 1 d . . 
H9A H 0.0031(6) 0.9029(7) -0.0137(5) 0.125 Uiso 1 calc R . 
C10 C 0.0974(4) 0.8051(5) -0.0034(3) 0.074(2) Uani 1 d . . 
H10A H 0.1245(4) 0.8271(5) -0.0315(3) 0.089 Uiso 1 calc R . 
C11 C 0.1967(4) 0.5865(5) -0.0420(3) 0.0531(15) Uani 1 d . . 
C12 C 0.1931(5) 0.4900(5) -0.0342(3) 0.070(2) Uani 1 d . . 
H12A H 0.2029(5) 0.4652(5) 0.0007(3) 0.084 Uiso 1 calc R . 
C13 C 0.1751(6) 0.4279(6) -0.0773(4) 0.094(3) Uani 1 d . . 
H13A H 0.1736(6) 0.3615(6) -0.0714(4) 0.113 Uiso 1 calc R . 
C14 C 0.1597(6) 0.4632(7) -0.1280(4) 0.096(3) Uani 1 d . . 
H14A H 0.1495(6) 0.4208(7) -0.1570(4) 0.116 Uiso 1 calc R . 
C15 C 0.1591(6) 0.5599(7) -0.1370(3) 0.094(3) Uani 1 d . . 
H15A H 0.1454(6) 0.5840(7) -0.1719(3) 0.113 Uiso 1 calc R . 
C16 C 0.1789(5) 0.6226(6) -0.0939(3) 0.075(2) Uani 1 d . . 
H16A H 0.1801(5) 0.6890(6) -0.0998(3) 0.090 Uiso 1 calc R . 
C17 C 0.3595(4) 0.8762(4) 0.0880(2) 0.0512(14) Uani 1 d . . 
C18 C 0.2864(4) 0.9290(5) 0.0808(3) 0.066(2) Uani 1 d . . 
H18A H 0.2422(4) 0.9096(5) 0.0555(3) 0.080 Uiso 1 calc R . 
C19 C 0.2801(6) 1.0114(6) 0.1119(4) 0.085(2) Uani 1 d . . 
H19A H 0.2322(6) 1.0488(6) 0.1063(4) 0.102 Uiso 1 calc R . 
C20 C 0.3433(7) 1.0373(6) 0.1502(4) 0.091(3) Uani 1 d . . 
H20A H 0.3382(7) 1.0923(6) 0.1710(4) 0.109 Uiso 1 calc R . 
C21 C 0.4149(6) 0.9833(6) 0.1589(3) 0.090(3) Uani 1 d . . 
H21A H 0.4578(6) 1.0007(6) 0.1858(3) 0.108 Uiso 1 calc R . 
C22 C 0.4224(5) 0.9029(5) 0.1272(3) 0.075(2) Uani 1 d . . 
H22A H 0.4708(5) 0.8664(5) 0.1325(3) 0.090 Uiso 1 calc R . 
C23 C 0.4695(4) 0.7802(4) 0.0249(3) 0.0521(15) Uani 1 d . . 
C24 C 0.4761(5) 0.8565(6) -0.0100(4) 0.083(2) Uani 1 d . . 
H24A H 0.4312(5) 0.8978(6) -0.0191(4) 0.100 Uiso 1 calc R . 
C25 C 0.5484(6) 0.8717(7) -0.0314(4) 0.100(3) Uani 1 d . . 
H25A H 0.5529(6) 0.9240(7) -0.0542(4) 0.120 Uiso 1 calc R . 
C26 C 0.6122(6) 0.8110(7) -0.0192(4) 0.100(3) Uani 1 d . . 
H26A H 0.6601(6) 0.8200(7) -0.0350(4) 0.120 Uiso 1 calc R . 
C27 C 0.6085(5) 0.7357(7) 0.0161(4) 0.092(3) Uani 1 d . . 
H27A H 0.6542(5) 0.6956(7) 0.0251(4) 0.111 Uiso 1 calc R . 
C28 C 0.5352(4) 0.7197(5) 0.0385(3) 0.066(2) Uani 1 d . . 
H28A H 0.5316(4) 0.6686(5) 0.0623(3) 0.079 Uiso 1 calc R . 
C29 C 0.5483(12) 0.4409(15) 0.1530(7) 0.257(12) Uani 1 d . . 
H29A H 0.5917(12) 0.4684(15) 0.1791(7) 0.309 Uiso 1 calc R . 
H29B H 0.5141(12) 0.4008(15) 0.1728(7) 0.309 Uiso 1 calc R . 
C30 C 0.5857(13) 0.3815(16) 0.1191(6) 0.280(14) Uani 1 d . . 
H30A H 0.5956(148) 0.3191(59) 0.1356(48) 0.420 Uiso 1 calc R . 
H30B H 0.6376(78) 0.4094(93) 0.1128(84) 0.420 Uiso 1 calc R . 
H30C H 0.5501(72) 0.3747(154) 0.0853(40) 0.420 Uiso 1 calc R . 
C31 C 0.5570(9) 0.6759(10) 0.2133(6) 0.196(8) Uani 1 d . . 
H31A H 0.5456(9) 0.6417(10) 0.2453(6) 0.235 Uiso 1 calc R . 
H31B H 0.5996(9) 0.6399(10) 0.1982(6) 0.235 Uiso 1 calc R . 
C32 C 0.5865(9) 0.7602(11) 0.2277(6) 0.193(8) Uani 1 d . . 
H32A H 0.6288(64) 0.7535(15) 0.2583(38) 0.290 Uiso 1 calc R . 
H32B H 0.5427(20) 0.8005(35) 0.2372(56) 0.290 Uiso 1 calc R . 
H32C H 0.6099(81) 0.7891(46) 0.1983(21) 0.290 Uiso 1 calc R . 
C33 C 0.3626(9) 0.5470(10) 0.2384(5) 0.147(5) Uani 1 d . . 
H33A H 0.3079(9) 0.5607(10) 0.2192(5) 0.176 Uiso 1 calc R . 
H33B H 0.3833(9) 0.6059(10) 0.2566(5) 0.176 Uiso 1 calc R . 
C34 C 0.3551(8) 0.4748(9) 0.2782(5) 0.129(4) Uiso 1 d . . 
H34A H 0.3024(25) 0.4811(43) 0.2909(27) 0.194 Uiso 1 calc R . 
H34B H 0.3988(35) 0.4826(42) 0.3079(18) 0.194 Uiso 1 calc R . 
H34C H 0.3591(58) 0.4118(9) 0.2625(11) 0.194 Uiso 1 calc R . 
C35 C 0.9719(10) 0.7125(21) 0.2345(7) 0.288(15) Uani 1 d . . 
H35B H 0.9492(10) 0.6878(21) 0.1992(7) 0.345 Uiso 1 calc R . 
H35A H 0.9602(10) 0.7814(21) 0.2334(7) 0.345 Uiso 1 calc R . 
 
loop_ 
 _atom_site_aniso_label 
 _atom_site_aniso_U_11 
 _atom_site_aniso_U_22 
 _atom_site_aniso_U_33 
 _atom_site_aniso_U_23 
 _atom_site_aniso_U_13 
 _atom_site_aniso_U_12 
Sb1 0.0639(3) 0.0614(3) 0.0693(3) 0.0118(2) 0.0112(2) -0.0138(2) 
Sb2 0.0630(3) 0.0601(3) 0.0636(3) 0.0031(2) 0.0053(2) -0.0037(2) 
Mn1 0.0430(5) 0.0416(5) 0.0487(5) 0.0014(4) 0.0062(4) -0.0017(4) 
P1 0.0419(8) 0.0449(8) 0.0508(9) -0.0014(7) 0.0063(6) 0.0008(7) 
P2 0.0430(8) 0.0403(8) 0.0527(9) 0.0000(7) 0.0088(7) -0.0013(6) 
P3 0.0572(10) 0.0643(11) 0.0574(10) 0.0072(8) -0.0006(8) -0.0012(8) 
Cl1 0.129(2) 0.104(2) 0.123(2) 0.048(2) -0.035(2) -0.017(2) 
Cl2 0.119(2) 0.122(2) 0.111(2) 0.028(2) 0.0141(15) -0.063(2) 
Cl3 0.0934(15) 0.0884(15) 0.118(2) -0.0182(13) 0.0272(13) 0.0029(12) 
Cl4 0.150(3) 0.166(3) 0.125(2) -0.056(2) 0.068(2) -0.038(2) 
Cl5 0.0621(11) 0.0935(15) 0.124(2) 0.0234(13) -0.0038(11) 0.0040(10) 
Cl6 0.152(2) 0.0605(13) 0.133(2) 0.0038(13) -0.002(2) 0.0104(14) 
Cl7 0.159(2) 0.125(2) 0.0653(14) 0.0052(13) 0.0173(14) -0.024(2) 
Cl8 0.206(3) 0.0617(13) 0.110(2) -0.0014(12) 0.029(2) -0.018(2) 
Cl9 0.135(2) 0.105(2) 0.0717(13) 0.0018(12) 0.0293(13) -0.0014(15) 
Cl10 0.0657(13) 0.138(2) 0.134(2) -0.003(2) 0.0044(13) 0.0042(13) 
Cl11 0.0698(14) 0.179(3) 0.170(3) -0.025(2) -0.006(2) -0.012(2) 
Cl12 0.231(7) 0.399(11) 0.402(11) 0.228(10) -0.001(7) 0.019(7) 
Cl13 0.256(6) 0.276(7) 0.222(6) 0.064(5) 0.067(5) -0.008(5) 
O1 0.099(4) 0.087(4) 0.069(3) -0.012(3) 0.029(3) 0.011(3) 
O2 0.074(3) 0.076(3) 0.087(4) -0.018(3) 0.021(3) 0.014(3) 
O3 0.069(3) 0.115(5) 0.091(4) 0.014(3) 0.001(3) 0.035(3) 
O4 0.089(4) 0.083(4) 0.095(4) 0.013(3) -0.030(3) -0.025(3) 
O5 0.096(4) 0.117(5) 0.066(3) 0.019(3) 0.015(3) 0.000(3) 
N1 0.062(3) 0.062(4) 0.071(4) 0.012(3) 0.006(3) -0.013(3) 
C1 0.055(4) 0.059(4) 0.054(4) 0.003(3) 0.007(3) -0.007(3) 
C2 0.044(3) 0.051(4) 0.063(4) 0.007(3) 0.004(3) -0.001(3) 
C3 0.046(3) 0.048(4) 0.060(4) 0.003(3) 0.003(3) 0.004(3) 
C4 0.052(3) 0.051(4) 0.051(3) 0.002(3) 0.009(3) 0.000(3) 
C5 0.045(3) 0.060(4) 0.067(4) -0.014(3) 0.001(3) 0.004(3) 
C6 0.056(4) 0.122(7) 0.075(5) -0.005(5) 0.014(4) 0.003(4) 
C7 0.060(5) 0.204(13) 0.099(7) -0.027(8) 0.025(5) 0.013(7) 
C8 0.076(6) 0.161(11) 0.129(9) -0.054(9) 0.001(7) 0.050(7) 
C9 0.080(6) 0.089(7) 0.138(9) -0.026(6) -0.007(6) 0.027(5) 
C10 0.052(4) 0.062(4) 0.108(6) -0.004(4) 0.009(4) 0.011(3) 
C11 0.046(3) 0.055(4) 0.058(4) -0.004(3) 0.010(3) 0.004(3) 
C12 0.084(5) 0.055(4) 0.068(5) -0.005(3) -0.001(4) -0.011(4) 
C13 0.124(7) 0.063(5) 0.092(7) -0.016(5) 0.000(5) -0.008(5) 
C14 0.123(8) 0.085(7) 0.078(6) -0.035(5) 0.003(5) -0.001(5) 
C15 0.128(8) 0.099(7) 0.053(5) -0.010(4) 0.002(4) -0.012(6) 
C16 0.092(5) 0.066(5) 0.064(5) -0.004(4) 0.001(4) -0.005(4) 
C17 0.055(4) 0.044(3) 0.057(4) 0.003(3) 0.014(3) -0.002(3) 
C18 0.070(4) 0.058(4) 0.073(5) 0.000(4) 0.017(4) 0.007(4) 
C19 0.105(6) 0.063(5) 0.092(6) 0.001(4) 0.034(5) 0.024(5) 
C20 0.124(8) 0.056(5) 0.098(7) -0.021(4) 0.038(6) 0.000(5) 
C21 0.108(7) 0.081(6) 0.079(6) -0.022(5) 0.011(5) -0.020(5) 
C22 0.072(5) 0.066(5) 0.087(5) -0.019(4) 0.010(4) -0.009(4) 
C23 0.047(3) 0.046(3) 0.066(4) 0.001(3) 0.017(3) -0.009(3) 
C24 0.078(5) 0.066(5) 0.114(7) 0.022(5) 0.042(5) 0.007(4) 
C25 0.104(7) 0.080(6) 0.130(8) 0.026(5) 0.064(6) 0.003(5) 
C26 0.090(6) 0.084(6) 0.138(8) -0.004(6) 0.062(6) -0.018(5) 
C27 0.051(4) 0.087(6) 0.141(8) -0.014(6) 0.026(5) 0.008(4) 
C28 0.050(4) 0.063(4) 0.088(5) 0.005(4) 0.017(3) -0.006(3) 
C29 0.300(23) 0.311(24) 0.176(15) 0.092(15) 0.083(15) 0.242(21) 
C30 0.357(27) 0.351(28) 0.146(13) 0.044(15) 0.084(15) 0.282(25) 
C31 0.196(14) 0.137(11) 0.211(16) 0.033(10) -0.131(13) -0.057(11) 
C32 0.201(15) 0.171(14) 0.178(14) 0.052(11) -0.085(12) -0.098(12) 
C33 0.203(14) 0.150(11) 0.088(7) 0.011(7) 0.025(8) 0.050(10) 
C35 0.124(12) 0.562(46) 0.170(16) 0.101(22) -0.004(11) -0.121(20) 
 
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
 
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Sb1 N1 2.180(6) . ? 
Sb1 Cl4 2.316(3) . ? 
Sb1 Cl5 2.328(2) . ? 
Sb1 Cl1 2.333(2) . ? 
Sb1 Cl2 2.333(2) . ? 
Sb1 Cl3 2.336(2) . ? 
Sb2 Cl10 2.331(2) . ? 
Sb2 Cl6 2.345(2) . ? 
Sb2 Cl7 2.346(2) . ? 
Sb2 Cl11 2.361(3) . ? 
Sb2 Cl8 2.364(2) . ? 
Sb2 Cl9 2.365(2) . ? 
Mn1 C2 1.854(7) . ? 
Mn1 C1 1.866(7) . ? 
Mn1 C3 1.959(7) . ? 
Mn1 P3 2.319(2) . ? 
Mn1 P2 2.355(2) . ? 
Mn1 P1 2.356(2) . ? 
P1 C5 1.803(6) . ? 
P1 C11 1.817(6) . ? 
P1 C4 1.832(6) . ? 
P2 C23 1.807(6) . ? 
P2 C17 1.808(6) . ? 
P2 C4 1.837(6) . ? 
P3 O4 1.541(6) . ? 
P3 O5 1.556(6) . ? 
P3 O3 1.572(6) . ? 
Cl12 C35 1.44(2) . ? 
Cl13 C35 1.52(2) . ? 
O1 C1 1.130(8) . ? 
O2 C2 1.127(8) . ? 
O3 C29 1.389(13) . ? 
O4 C31 1.482(11) . ? 
O5 C33 1.378(13) . ? 
N1 C3 1.144(8) . ? 
C5 C6 1.363(10) . ? 
C5 C10 1.381(10) . ? 
C6 C7 1.404(12) . ? 
C7 C8 1.36(2) . ? 
C8 C9 1.34(2) . ? 
C9 C10 1.396(11) . ? 
C11 C12 1.350(10) . ? 
C11 C16 1.382(9) . ? 
C12 C13 1.376(11) . ? 
C13 C14 1.349(12) . ? 
C14 C15 1.356(12) . ? 
C15 C16 1.387(11) . ? 
C17 C22 1.365(9) . ? 
C17 C18 1.386(9) . ? 
C18 C19 1.390(11) . ? 
C19 C20 1.352(12) . ? 
C20 C21 1.377(12) . ? 
C21 C22 1.381(11) . ? 
C23 C28 1.363(9) . ? 
C23 C24 1.382(9) . ? 
C24 C25 1.372(11) . ? 
C25 C26 1.337(13) . ? 
C26 C27 1.370(13) . ? 
C27 C28 1.403(10) . ? 
C29 C30 1.38(2) . ? 
C31 C32 1.29(2) . ? 
C33 C34 1.425(15) . ? 
 
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
N1 Sb1 Cl4 86.0(2) . . ? 
N1 Sb1 Cl5 86.2(2) . . ? 
Cl4 Sb1 Cl5 90.77(13) . . ? 
N1 Sb1 Cl1 86.4(2) . . ? 
Cl4 Sb1 Cl1 89.83(14) . . ? 
Cl5 Sb1 Cl1 172.46(9) . . ? 
N1 Sb1 Cl2 179.7(2) . . ? 
Cl4 Sb1 Cl2 94.32(11) . . ? 
Cl5 Sb1 Cl2 93.97(9) . . ? 
Cl1 Sb1 Cl2 93.48(10) . . ? 
N1 Sb1 Cl3 85.9(2) . . ? 
Cl4 Sb1 Cl3 171.83(10) . . ? 
Cl5 Sb1 Cl3 88.80(9) . . ? 
Cl1 Sb1 Cl3 89.55(11) . . ? 
Cl2 Sb1 Cl3 93.86(10) . . ? 
Cl10 Sb2 Cl6 91.11(11) . . ? 
Cl10 Sb2 Cl7 90.46(11) . . ? 
Cl6 Sb2 Cl7 91.12(10) . . ? 
Cl10 Sb2 Cl11 179.09(12) . . ? 
Cl6 Sb2 Cl11 89.66(12) . . ? 
Cl7 Sb2 Cl11 90.01(13) . . ? 
Cl10 Sb2 Cl8 90.02(12) . . ? 
Cl6 Sb2 Cl8 178.56(11) . . ? 
Cl7 Sb2 Cl8 89.76(10) . . ? 
Cl11 Sb2 Cl8 89.20(13) . . ? 
Cl10 Sb2 Cl9 89.49(11) . . ? 
Cl6 Sb2 Cl9 89.04(10) . . ? 
Cl7 Sb2 Cl9 179.83(9) . . ? 
Cl11 Sb2 Cl9 90.04(12) . . ? 
Cl8 Sb2 Cl9 90.07(9) . . ? 
C2 Mn1 C1 177.6(3) . . ? 
C2 Mn1 C3 92.0(3) . . ? 
C1 Mn1 C3 89.8(3) . . ? 
C2 Mn1 P3 88.5(2) . . ? 
C1 Mn1 P3 89.8(2) . . ? 
C3 Mn1 P3 91.6(2) . . ? 
C2 Mn1 P2 90.5(2) . . ? 
C1 Mn1 P2 88.2(2) . . ? 
C3 Mn1 P2 166.4(2) . . ? 
P3 Mn1 P2 101.81(7) . . ? 
C2 Mn1 P1 88.6(2) . . ? 
C1 Mn1 P1 93.0(2) . . ? 
C3 Mn1 P1 93.7(2) . . ? 
P3 Mn1 P1 173.98(7) . . ? 
P2 Mn1 P1 72.97(6) . . ? 
C5 P1 C11 107.8(3) . . ? 
C5 P1 C4 108.0(3) . . ? 
C11 P1 C4 107.1(3) . . ? 
C5 P1 Mn1 120.1(2) . . ? 
C11 P1 Mn1 118.9(2) . . ? 
C4 P1 Mn1 92.6(2) . . ? 
C23 P2 C17 105.0(3) . . ? 
C23 P2 C4 106.2(3) . . ? 
C17 P2 C4 108.7(3) . . ? 
C23 P2 Mn1 125.3(2) . . ? 
C17 P2 Mn1 116.9(2) . . ? 
C4 P2 Mn1 92.5(2) . . ? 
O4 P3 O5 109.0(3) . . ? 
O4 P3 O3 106.1(4) . . ? 
O5 P3 O3 100.7(3) . . ? 
O4 P3 Mn1 110.2(2) . . ? 
O5 P3 Mn1 117.9(2) . . ? 
O3 P3 Mn1 112.0(2) . . ? 
C29 O3 P3 132.1(8) . . ? 
C31 O4 P3 124.2(7) . . ? 
C33 O5 P3 127.0(7) . . ? 
C3 N1 Sb1 172.8(5) . . ? 
O1 C1 Mn1 178.7(6) . . ? 
O2 C2 Mn1 179.9(5) . . ? 
N1 C3 Mn1 176.1(5) . . ? 
P1 C4 P2 99.5(3) . . ? 
C6 C5 C10 119.9(7) . . ? 
C6 C5 P1 119.7(6) . . ? 
C10 C5 P1 120.3(6) . . ? 
C5 C6 C7 119.1(9) . . ? 
C8 C7 C6 119.6(10) . . ? 
C9 C8 C7 122.0(9) . . ? 
C8 C9 C10 118.9(10) . . ? 
C5 C10 C9 120.4(9) . . ? 
C12 C11 C16 118.9(6) . . ? 
C12 C11 P1 121.5(5) . . ? 
C16 C11 P1 119.6(5) . . ? 
C11 C12 C13 120.9(7) . . ? 
C14 C13 C12 120.0(8) . . ? 
C13 C14 C15 120.7(8) . . ? 
C14 C15 C16 119.4(8) . . ? 
C11 C16 C15 120.0(8) . . ? 
C22 C17 C18 119.6(6) . . ? 
C22 C17 P2 118.1(5) . . ? 
C18 C17 P2 122.1(5) . . ? 
C17 C18 C19 119.2(7) . . ? 
C20 C19 C18 120.4(8) . . ? 
C19 C20 C21 120.8(8) . . ? 
C20 C21 C22 119.1(8) . . ? 
C17 C22 C21 120.9(8) . . ? 
C28 C23 C24 119.9(6) . . ? 
C28 C23 P2 122.8(5) . . ? 
C24 C23 P2 117.2(5) . . ? 
C25 C24 C23 120.5(8) . . ? 
C26 C25 C24 119.7(8) . . ? 
C25 C26 C27 121.5(8) . . ? 
C26 C27 C28 119.4(8) . . ? 
C23 C28 C27 118.9(7) . . ? 
C30 C29 O3 118.0(14) . . ? 
C32 C31 O4 115.8(12) . . ? 
O5 C33 C34 114.2(10) . . ? 
Cl12 C35 Cl13 130.5(15) . . ? 
 
_refine_diff_density_max    0.924 
_refine_diff_density_min   -0.753 
_refine_diff_density_rms    0.081