# Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2000
# CCDC Number: 186/2180

# 186/2180

data_99ab1 
 
_audit_creation_method            SHELXL 
_chemical_name_systematic 
; 
 ? 
; 
_chemical_name_common             ? 
_chemical_formula_moiety          ? 
_chemical_formula_structural      ? 
_chemical_formula_analytical      ? 
_chemical_formula_sum             'C34 H46 Cl4 Co N4 P2 Pt' 
_chemical_formula_weight          968.51 
_chemical_melting_point           ? 
_chemical_compound_source         ? 
 
loop_ 
 _atom_type_symbol 
 _atom_type_description 
 _atom_type_scat_dispersion_real 
 _atom_type_scat_dispersion_imag 
 _atom_type_scat_source 
 'C'  'C'   0.0033   0.0016 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'H'  'H'   0.0000   0.0000 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'N'  'N'   0.0061   0.0033 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'P'  'P'   0.1023   0.0942 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Cl'  'Cl'   0.1484   0.1585 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Co'  'Co'   0.3494   0.9721 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 'Pt'  'Pt'  -1.7033   8.3905 
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 
 
_symmetry_cell_setting            Monoclinic 
_symmetry_space_group_name_H-M    P21/c 
 
loop_ 
 _symmetry_equiv_pos_as_xyz 
 'x, y, z' 
 '-x, y+1/2, -z+1/2' 
 '-x, -y, -z' 
 'x, -y-1/2, z-1/2' 
 
_cell_length_a                    16.710(3) 
_cell_length_b                    12.160(2) 
_cell_length_c                    19.666(5) 
_cell_angle_alpha                 90.00 
_cell_angle_beta                  104.82(2) 
_cell_angle_gamma                 90.00 
_cell_volume                      3863.1(14) 
_cell_formula_units_Z             4 
_cell_measurement_temperature     293(2) 
_cell_measurement_reflns_used     ? 
_cell_measurement_theta_min       ? 
_cell_measurement_theta_max       ? 
 
_exptl_crystal_description        ? 
_exptl_crystal_colour             ? 
_exptl_crystal_size_max           0.15 
_exptl_crystal_size_mid           0.18 
_exptl_crystal_size_min           0.18
_exptl_crystal_density_meas       ? 
_exptl_crystal_density_diffrn     1.665 
_exptl_crystal_density_method     ? 
_exptl_crystal_F_000              1924 
_exptl_absorpt_coefficient_mu     4.436 
_exptl_absorpt_correction_type    ? 
_exptl_absorpt_correction_T_min   ? 
_exptl_absorpt_correction_T_max   ? 
 
_exptl_special_details 
; 
 ? 
; 
 
_diffrn_ambient_temperature       293(2) 
_diffrn_radiation_wavelength      0.71069 
_diffrn_radiation_type            MoK\a 
_diffrn_radiation_source          'fine-focus sealed tube' 
_diffrn_radiation_monochromator   graphite 
_diffrn_measurement_device        ? 
_diffrn_measurement_method        ? 
_diffrn_standards_number          ? 
_diffrn_standards_interval_count  ? 
_diffrn_standards_interval_time   ? 
_diffrn_standards_decay_%         ? 
_diffrn_reflns_number             7270 
_diffrn_reflns_av_R_equivalents   0.0127 
_diffrn_reflns_av_sigmaI/netI     0.0436 
_diffrn_reflns_limit_h_min        0 
_diffrn_reflns_limit_h_max        19 
_diffrn_reflns_limit_k_min        0 
_diffrn_reflns_limit_k_max        14 
_diffrn_reflns_limit_l_min        -23 
_diffrn_reflns_limit_l_max        22 
_diffrn_reflns_theta_min          2.10 
_diffrn_reflns_theta_max          24.99 
_reflns_number_total              6785 
_reflns_number_observed           5156 
_reflns_observed_criterion        >2sigma(I) 
 
_computing_data_collection        ? 
_computing_cell_refinement        ? 
_computing_data_reduction         ? 
_computing_structure_solution     'SHELXS-86 (Sheldrick, 1990)' 
_computing_structure_refinement   'SHELXL-93 (Sheldrick, 1993)' 
_computing_molecular_graphics     ? 
_computing_publication_material   ? 
 
_refine_special_details 
; 
 Refinement on F^2^ for ALL reflections except for 0 with very negative F^2^ 
 or flagged by the user for potential systematic errors.  Weighted R-factors 
 wR and all goodnesses of fit S are based on F^2^, conventional R-factors R 
 are based on F, with F set to zero for negative F^2^. The observed criterion 
 of F^2^ > 2sigma(F^2^) is used only for calculating _R_factor_obs etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F^2^ are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
; 
 
_refine_ls_structure_factor_coef  Fsqd  
_refine_ls_matrix_type            full 
_refine_ls_weighting_scheme 
 'calc w=1/[\s^2^(Fo^2^)+(0.0534P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' 
_atom_sites_solution_primary      direct 
_atom_sites_solution_secondary    difmap 
_atom_sites_solution_hydrogens    geom 
_refine_ls_hydrogen_treatment     ? 
_refine_ls_extinction_method      SHELXL 
_refine_ls_extinction_coef        0.00013(5) 
_refine_ls_extinction_expression 
 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^' 
_refine_ls_number_reflns          6785 
_refine_ls_number_parameters      422 
_refine_ls_number_restraints      0 
_refine_ls_R_factor_all           0.0570 
_refine_ls_R_factor_obs           0.0367 
_refine_ls_wR_factor_all          0.0886 
_refine_ls_wR_factor_obs          0.0838 
_refine_ls_goodness_of_fit_all    1.017 
_refine_ls_goodness_of_fit_obs    1.114 
_refine_ls_restrained_S_all       1.017 
_refine_ls_restrained_S_obs       1.114 
_refine_ls_shift/esd_max          0.000 
_refine_ls_shift/esd_mean         0.000 
 
loop_ 
 _atom_site_label 
 _atom_site_type_symbol 
 _atom_site_fract_x 
 _atom_site_fract_y 
 _atom_site_fract_z 
 _atom_site_U_iso_or_equiv 
 _atom_site_thermal_displace_type 
 _atom_site_occupancy 
 _atom_site_calc_flag 
 _atom_site_refinement_flags 
 _atom_site_disorder_group 
Pt1 Pt 0.201691(13) 0.22419(2) 0.243566(11) 0.03107(9) Uani 1 d . . 
Co1 Co 0.25171(6) -0.26253(7) 0.26988(5) 0.0500(2) Uani 1 d . . 
Cl1 Cl 0.25419(10) 0.18267(14) 0.36428(7) 0.0463(4) Uani 1 d . . 
Cl3 Cl 0.34959(13) -0.3093(2) 0.21787(13) 0.0798(6) Uani 1 d . . 
Cl4 Cl 0.14101(11) -0.1771(2) 0.20131(11) 0.0685(5) Uani 1 d . . 
Cl5 Cl 0.20260(12) -0.4042(2) 0.32073(11) 0.0710(5) Uani 1 d . . 
P1 P 0.14481(9) 0.23045(14) 0.12698(8) 0.0362(3) Uani 1 d . . 
P2 P 0.33589(9) 0.21066(12) 0.23940(7) 0.0316(3) Uani 1 d . . 
N1 N 0.0477(3) 0.1834(5) 0.1109(3) 0.0515(14) Uani 1 d . . 
N2 N 0.0819(3) 0.2514(4) 0.2641(2) 0.0379(12) Uani 1 d . . 
N3 N 0.3694(3) 0.0819(4) 0.2455(2) 0.0348(11) Uani 1 d . . 
N4 N 0.3108(4) -0.1542(4) 0.3517(3) 0.0539(14) Uani 1 d . . 
C1 C 0.1885(4) 0.1332(5) 0.0768(3) 0.0395(14) Uani 1 d . . 
C2 C 0.2106(4) 0.1569(6) 0.0158(3) 0.049(2) Uani 1 d . . 
H2 H 0.2065(4) 0.2285(6) -0.0013(3) 0.059 Uiso 1 calc R . 
C3 C 0.2390(5) 0.0740(6) -0.0204(3) 0.064(2) Uani 1 d . . 
H3 H 0.2527(5) 0.0898(6) -0.0623(3) 0.077 Uiso 1 calc R . 
C4 C 0.2470(5) -0.0311(7) 0.0054(4) 0.071(2) Uani 1 d . . 
H4 H 0.2670(5) -0.0862(7) -0.0187(4) 0.085 Uiso 1 calc R . 
C5 C 0.2259(5) -0.0556(6) 0.0665(4) 0.066(2) Uani 1 d . . 
H5 H 0.2313(5) -0.1272(6) 0.0837(4) 0.079 Uiso 1 calc R . 
C6 C 0.1968(4) 0.0256(5) 0.1022(3) 0.051(2) Uani 1 d . . 
H6 H 0.1825(4) 0.0088(5) 0.1437(3) 0.062 Uiso 1 calc R . 
C7 C 0.1418(4) 0.3642(5) 0.0861(3) 0.0429(15) Uani 1 d . . 
C8 C 0.1730(4) 0.4550(6) 0.1261(4) 0.059(2) Uani 1 d . . 
H8 H 0.1980(4) 0.4466(6) 0.1738(4) 0.071 Uiso 1 calc R . 
C9 C 0.1675(5) 0.5594(7) 0.0959(4) 0.077(2) Uani 1 d . . 
H9 H 0.1871(5) 0.6204(7) 0.1236(4) 0.092 Uiso 1 calc R . 
C10 C 0.1337(5) 0.5716(7) 0.0266(4) 0.075(2) Uani 1 d . . 
H10 H 0.1338(5) 0.6405(7) 0.0061(4) 0.090 Uiso 1 calc R . 
C11 C 0.0991(6) 0.4840(7) -0.0145(4) 0.080(3) Uani 1 d . . 
H11 H 0.0732(6) 0.4944(7) -0.0618(4) 0.096 Uiso 1 calc R . 
C12 C 0.1028(5) 0.3809(6) 0.0149(3) 0.062(2) Uani 1 d . . 
H12 H 0.0792(5) 0.3215(6) -0.0129(3) 0.075 Uiso 1 calc R . 
C13 C 0.3648(3) 0.2716(5) 0.1638(3) 0.0381(13) Uani 1 d . . 
C14 C 0.3681(4) 0.3854(6) 0.1583(3) 0.050(2) Uani 1 d . . 
H14 H 0.3585(4) 0.4298(6) 0.1939(3) 0.060 Uiso 1 calc R . 
C15 C 0.3857(5) 0.4323(7) 0.0995(4) 0.069(2) Uani 1 d . . 
H15 H 0.3863(5) 0.5085(7) 0.0952(4) 0.083 Uiso 1 calc R . 
C16 C 0.4022(5) 0.3686(9) 0.0482(4) 0.077(3) Uani 1 d . . 
H16 H 0.4162(5) 0.4010(9) 0.0100(4) 0.092 Uiso 1 calc R . 
C17 C 0.3980(5) 0.2568(8) 0.0526(4) 0.070(2) Uani 1 d . . 
H17 H 0.4077(5) 0.2133(8) 0.0166(4) 0.084 Uiso 1 calc R . 
C18 C 0.3797(4) 0.2079(6) 0.1098(3) 0.053(2) Uani 1 d . . 
H18 H 0.3773(4) 0.1316(6) 0.1124(3) 0.063 Uiso 1 calc R . 
C19 C 0.3995(4) 0.2925(5) 0.3114(3) 0.0401(14) Uani 1 d . . 
C20 C 0.3722(4) 0.3912(5) 0.3312(3) 0.049(2) Uani 1 d . . 
H20 H 0.3194(4) 0.4159(5) 0.3088(3) 0.059 Uiso 1 calc R . 
C21 C 0.4215(5) 0.4540(6) 0.3835(4) 0.059(2) Uani 1 d . . 
H21 H 0.4022(5) 0.5212(6) 0.3953(4) 0.071 Uiso 1 calc R . 
C22 C 0.4990(5) 0.4184(7) 0.4185(4) 0.061(2) Uani 1 d . . 
H22 H 0.5322(5) 0.4609(7) 0.4540(4) 0.074 Uiso 1 calc R . 
C23 C 0.5263(4) 0.3212(7) 0.4006(3) 0.062(2) Uani 1 d . . 
H23 H 0.5788(4) 0.2970(7) 0.4243(3) 0.075 Uiso 1 calc R . 
C24 C 0.4775(4) 0.2557(6) 0.3472(3) 0.051(2) Uani 1 d . . 
H24 H 0.4971(4) 0.1883(6) 0.3360(3) 0.062 Uiso 1 calc R . 
C25 C 0.0042(5) 0.1233(8) 0.0487(4) 0.093(3) Uani 1 d . . 
H25A H -0.0459(21) 0.0928(47) 0.0562(14) 0.140 Uiso 1 calc R . 
H25B H 0.0388(17) 0.0651(35) 0.0396(21) 0.140 Uiso 1 calc R . 
H25C H -0.0092(36) 0.1724(15) 0.0092(8) 0.140 Uiso 1 calc R . 
C26 C -0.0122(4) 0.2424(7) 0.1404(4) 0.065(2) Uani 1 d . . 
H26A H -0.0499(4) 0.1889(7) 0.1516(4) 0.078 Uiso 1 calc R . 
H26B H -0.0445(4) 0.2903(7) 0.1042(4) 0.078 Uiso 1 calc R . 
C27 C 0.0227(4) 0.3109(6) 0.2054(4) 0.057(2) Uani 1 d . . 
H27A H 0.0510(4) 0.3740(6) 0.1921(4) 0.069 Uiso 1 calc R . 
H27B H -0.0229(4) 0.3384(6) 0.2227(4) 0.069 Uiso 1 calc R . 
C28 C 0.0460(4) 0.1457(6) 0.2796(4) 0.059(2) Uani 1 d . . 
H28A H 0.0341(27) 0.1001(16) 0.2384(8) 0.088 Uiso 1 calc R . 
H28B H -0.0042(16) 0.1597(6) 0.2933(24) 0.088 Uiso 1 calc R . 
H28C H 0.0848(12) 0.1089(19) 0.3172(17) 0.088 Uiso 1 calc R . 
C29 C 0.0915(4) 0.3257(7) 0.3258(4) 0.063(2) Uani 1 d . . 
H29A H 0.1093(31) 0.3969(14) 0.3145(10) 0.094 Uiso 1 calc R . 
H29B H 0.1321(24) 0.2957(22) 0.3651(8) 0.094 Uiso 1 calc R . 
H29C H 0.0395(9) 0.3323(34) 0.3377(17) 0.094 Uiso 1 calc R . 
C30 C 0.4508(4) 0.0481(6) 0.2367(4) 0.055(2) Uani 1 d . . 
H30A H 0.4842(11) 0.0207(34) 0.2806(7) 0.083 Uiso 1 calc R . 
H30B H 0.4778(12) 0.1102(10) 0.2220(22) 0.083 Uiso 1 calc R . 
H30C H 0.4436(5) -0.0087(26) 0.2017(17) 0.083 Uiso 1 calc R . 
C31 C 0.3207(3) -0.0112(5) 0.2618(3) 0.0384(14) Uani 1 d . . 
H31A H 0.3129(3) -0.0651(5) 0.2243(3) 0.046 Uiso 1 calc R . 
H31B H 0.2666(3) 0.0150(5) 0.2638(3) 0.046 Uiso 1 calc R . 
C32 C 0.3627(4) -0.0660(6) 0.3311(3) 0.054(2) Uani 1 d . . 
H32A H 0.4147(4) -0.0978(6) 0.3275(3) 0.065 Uiso 1 calc R . 
H32B H 0.3752(4) -0.0105(6) 0.3678(3) 0.065 Uiso 1 calc R . 
C33 C 0.2455(6) -0.1069(7) 0.3802(4) 0.081(3) Uani 1 d . . 
H33A H 0.2697(7) -0.0579(37) 0.4182(20) 0.121 Uiso 1 calc R . 
H33B H 0.2167(24) -0.1648(8) 0.3971(28) 0.121 Uiso 1 calc R . 
H33C H 0.2073(21) -0.0668(40) 0.3438(9) 0.121 Uiso 1 calc R . 
C34 C 0.3664(6) -0.2221(7) 0.4066(4) 0.082(3) Uani 1 d . . 
H34A H 0.4124(20) -0.2470(41) 0.3899(13) 0.123 Uiso 1 calc R . 
H34B H 0.3365(11) -0.2844(28) 0.4172(23) 0.123 Uiso 1 calc R . 
H34C H 0.3863(30) -0.1788(16) 0.4484(11) 0.123 Uiso 1 calc R . 
 
loop_ 
 _atom_site_aniso_label 
 _atom_site_aniso_U_11 
 _atom_site_aniso_U_22 
 _atom_site_aniso_U_33 
 _atom_site_aniso_U_23 
 _atom_site_aniso_U_13 
 _atom_site_aniso_U_12 
Pt1 0.03222(13) 0.03161(13) 0.03156(12) -0.00010(10) 0.01213(8) 0.00165(11) 
Co1 0.0472(5) 0.0426(5) 0.0637(6) 0.0026(4) 0.0208(4) -0.0005(4) 
Cl1 0.0534(9) 0.0538(9) 0.0336(7) 0.0023(7) 0.0147(7) 0.0055(8) 
Cl3 0.0661(13) 0.0741(14) 0.113(2) -0.0153(12) 0.0479(12) 0.0016(10) 
Cl4 0.0437(10) 0.0716(12) 0.0909(14) 0.0250(11) 0.0187(9) 0.0014(9) 
Cl5 0.0729(13) 0.0511(11) 0.0949(14) 0.0209(10) 0.0322(11) -0.0018(10) 
P1 0.0375(8) 0.0390(8) 0.0323(7) -0.0018(7) 0.0095(6) 0.0016(7) 
P2 0.0319(8) 0.0304(8) 0.0341(7) -0.0020(6) 0.0112(6) 0.0013(6) 
N1 0.043(3) 0.057(3) 0.053(3) -0.007(3) 0.010(3) -0.007(3) 
N2 0.035(3) 0.042(3) 0.039(3) 0.001(2) 0.014(2) 0.000(2) 
N3 0.031(3) 0.029(3) 0.048(3) -0.001(2) 0.015(2) 0.006(2) 
N4 0.064(4) 0.039(3) 0.060(3) 0.012(3) 0.019(3) 0.003(3) 
C1 0.041(4) 0.041(4) 0.035(3) -0.001(3) 0.006(3) 0.003(3) 
C2 0.060(4) 0.050(4) 0.038(3) 0.003(3) 0.013(3) 0.009(3) 
C3 0.083(6) 0.072(5) 0.038(4) -0.009(4) 0.018(4) 0.020(4) 
C4 0.099(6) 0.066(5) 0.047(4) -0.015(4) 0.017(4) 0.027(5) 
C5 0.096(6) 0.044(4) 0.055(4) -0.001(3) 0.015(4) 0.012(4) 
C6 0.067(5) 0.045(4) 0.042(4) -0.004(3) 0.015(3) -0.001(3) 
C7 0.045(4) 0.044(4) 0.038(3) 0.002(3) 0.008(3) 0.009(3) 
C8 0.058(5) 0.059(5) 0.052(4) 0.009(4) 0.000(3) 0.003(4) 
C9 0.099(7) 0.050(5) 0.069(5) 0.002(4) -0.001(5) -0.009(4) 
C10 0.106(7) 0.052(5) 0.066(5) 0.017(4) 0.020(5) 0.005(5) 
C11 0.115(7) 0.070(6) 0.050(4) 0.023(4) 0.015(5) 0.038(5) 
C12 0.081(5) 0.053(4) 0.048(4) -0.004(3) 0.006(4) 0.022(4) 
C13 0.033(3) 0.046(3) 0.036(3) 0.004(3) 0.011(2) -0.004(3) 
C14 0.054(4) 0.045(4) 0.051(4) 0.001(3) 0.015(3) -0.012(3) 
C15 0.071(5) 0.067(5) 0.068(5) 0.021(4) 0.015(4) -0.019(4) 
C16 0.080(6) 0.106(8) 0.048(4) 0.012(5) 0.025(4) -0.022(5) 
C17 0.073(5) 0.100(7) 0.046(4) -0.002(4) 0.032(4) 0.002(5) 
C18 0.053(4) 0.062(5) 0.049(4) -0.005(3) 0.024(3) -0.004(3) 
C19 0.046(4) 0.036(4) 0.042(3) -0.001(3) 0.018(3) -0.004(3) 
C20 0.054(4) 0.042(4) 0.054(4) -0.004(3) 0.017(3) 0.005(3) 
C21 0.084(6) 0.042(4) 0.057(4) -0.019(3) 0.028(4) -0.014(4) 
C22 0.065(5) 0.078(6) 0.044(4) -0.020(4) 0.019(4) -0.033(4) 
C23 0.047(4) 0.089(6) 0.045(4) -0.006(4) 0.003(3) -0.008(4) 
C24 0.043(4) 0.055(5) 0.050(4) -0.002(3) 0.001(3) 0.008(3) 
C25 0.057(5) 0.120(8) 0.091(6) -0.046(6) -0.003(5) -0.022(5) 
C26 0.043(4) 0.104(7) 0.050(4) 0.005(4) 0.014(3) 0.007(4) 
C27 0.046(4) 0.069(5) 0.062(4) 0.012(4) 0.023(3) 0.019(4) 
C28 0.052(4) 0.059(5) 0.070(5) 0.007(4) 0.025(4) -0.009(4) 
C29 0.053(4) 0.078(5) 0.063(4) -0.019(4) 0.027(4) 0.009(4) 
C30 0.054(4) 0.046(4) 0.072(5) -0.002(3) 0.027(4) 0.013(3) 
C31 0.039(3) 0.029(3) 0.048(3) -0.004(3) 0.014(3) 0.001(3) 
C32 0.050(4) 0.054(4) 0.058(4) 0.008(3) 0.011(3) -0.004(3) 
C33 0.112(7) 0.068(5) 0.083(6) -0.008(5) 0.064(5) -0.014(5) 
C34 0.099(7) 0.065(5) 0.063(5) 0.025(4) -0.014(5) -0.009(5) 
 
_geom_special_details 
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
; 
 
loop_ 
 _geom_bond_atom_site_label_1 
 _geom_bond_atom_site_label_2 
 _geom_bond_distance 
 _geom_bond_site_symmetry_2 
 _geom_bond_publ_flag 
Pt1 N2 2.167(5) . ? 
Pt1 P1 2.247(2) . ? 
Pt1 P2 2.2709(15) . ? 
Pt1 Cl1 2.365(2) . ? 
Co1 N4 2.118(6) . ? 
Co1 Cl3 2.214(2) . ? 
Co1 Cl4 2.246(2) . ? 
Co1 Cl5 2.249(2) . ? 
P1 N1 1.673(5) . ? 
P1 C1 1.809(6) . ? 
P1 C7 1.810(6) . ? 
P2 N3 1.657(5) . ? 
P2 C19 1.832(6) . ? 
P2 C13 1.832(6) . ? 
N1 C25 1.450(8) . ? 
N1 C26 1.465(9) . ? 
N2 C28 1.483(8) . ? 
N2 C29 1.488(8) . ? 
N2 C27 1.500(8) . ? 
N3 C30 1.473(7) . ? 
N3 C31 1.477(7) . ? 
N4 C33 1.466(9) . ? 
N4 C34 1.483(8) . ? 
N4 C32 1.499(8) . ? 
C1 C2 1.374(8) . ? 
C1 C6 1.395(9) . ? 
C2 C3 1.385(9) . ? 
C3 C4 1.369(10) . ? 
C4 C5 1.368(10) . ? 
C5 C6 1.372(9) . ? 
C7 C8 1.378(9) . ? 
C7 C12 1.400(8) . ? 
C8 C9 1.394(10) . ? 
C9 C10 1.343(10) . ? 
C10 C11 1.371(11) . ? 
C11 C12 1.376(10) . ? 
C13 C18 1.388(8) . ? 
C13 C14 1.390(8) . ? 
C14 C15 1.388(9) . ? 
C15 C16 1.354(11) . ? 
C16 C17 1.366(11) . ? 
C17 C18 1.375(10) . ? 
C19 C20 1.376(8) . ? 
C19 C24 1.387(9) . ? 
C20 C21 1.373(9) . ? 
C21 C22 1.372(10) . ? 
C22 C23 1.345(11) . ? 
C23 C24 1.402(9) . ? 
C26 C27 1.511(10) . ? 
C31 C32 1.518(8) . ? 
 
loop_ 
 _geom_angle_atom_site_label_1 
 _geom_angle_atom_site_label_2 
 _geom_angle_atom_site_label_3 
 _geom_angle 
 _geom_angle_site_symmetry_1 
 _geom_angle_site_symmetry_3 
 _geom_angle_publ_flag 
N2 Pt1 P1 90.85(13) . . ? 
N2 Pt1 P2 170.38(13) . . ? 
P1 Pt1 P2 97.44(6) . . ? 
N2 Pt1 Cl1 88.23(13) . . ? 
P1 Pt1 Cl1 169.30(6) . . ? 
P2 Pt1 Cl1 84.53(6) . . ? 
N4 Co1 Cl3 104.8(2) . . ? 
N4 Co1 Cl4 108.7(2) . . ? 
Cl3 Co1 Cl4 115.71(10) . . ? 
N4 Co1 Cl5 106.9(2) . . ? 
Cl3 Co1 Cl5 113.91(9) . . ? 
Cl4 Co1 Cl5 106.44(8) . . ? 
N1 P1 C1 100.4(3) . . ? 
N1 P1 C7 107.9(3) . . ? 
C1 P1 C7 108.3(3) . . ? 
N1 P1 Pt1 108.5(2) . . ? 
C1 P1 Pt1 114.2(2) . . ? 
C7 P1 Pt1 116.1(2) . . ? 
N3 P2 C19 109.8(3) . . ? 
N3 P2 C13 106.6(3) . . ? 
C19 P2 C13 100.7(3) . . ? 
N3 P2 Pt1 112.6(2) . . ? 
C19 P2 Pt1 108.4(2) . . ? 
C13 P2 Pt1 117.9(2) . . ? 
C25 N1 C26 109.6(6) . . ? 
C25 N1 P1 125.7(5) . . ? 
C26 N1 P1 119.1(5) . . ? 
C28 N2 C29 108.9(5) . . ? 
C28 N2 C27 110.8(5) . . ? 
C29 N2 C27 104.4(5) . . ? 
C28 N2 Pt1 110.3(4) . . ? 
C29 N2 Pt1 109.4(4) . . ? 
C27 N2 Pt1 112.9(4) . . ? 
C30 N3 C31 112.8(5) . . ? 
C30 N3 P2 124.1(4) . . ? 
C31 N3 P2 123.1(4) . . ? 
C33 N4 C34 109.2(6) . . ? 
C33 N4 C32 111.2(5) . . ? 
C34 N4 C32 107.3(6) . . ? 
C33 N4 Co1 106.7(5) . . ? 
C34 N4 Co1 106.9(4) . . ? 
C32 N4 Co1 115.5(4) . . ? 
C2 C1 C6 119.0(6) . . ? 
C2 C1 P1 125.2(5) . . ? 
C6 C1 P1 115.8(5) . . ? 
C1 C2 C3 120.0(6) . . ? 
C4 C3 C2 120.2(7) . . ? 
C5 C4 C3 120.4(7) . . ? 
C4 C5 C6 119.9(7) . . ? 
C5 C6 C1 120.5(6) . . ? 
C8 C7 C12 117.8(6) . . ? 
C8 C7 P1 120.2(5) . . ? 
C12 C7 P1 121.8(5) . . ? 
C7 C8 C9 120.8(7) . . ? 
C10 C9 C8 119.9(8) . . ? 
C9 C10 C11 121.1(8) . . ? 
C10 C11 C12 119.6(7) . . ? 
C11 C12 C7 120.7(7) . . ? 
C18 C13 C14 118.5(6) . . ? 
C18 C13 P2 122.1(5) . . ? 
C14 C13 P2 119.3(5) . . ? 
C15 C14 C13 119.7(7) . . ? 
C16 C15 C14 120.8(8) . . ? 
C15 C16 C17 120.0(7) . . ? 
C16 C17 C18 120.5(7) . . ? 
C17 C18 C13 120.4(7) . . ? 
C20 C19 C24 118.3(6) . . ? 
C20 C19 P2 121.6(5) . . ? 
C24 C19 P2 120.1(5) . . ? 
C21 C20 C19 121.2(7) . . ? 
C22 C21 C20 120.6(7) . . ? 
C23 C22 C21 119.0(6) . . ? 
C22 C23 C24 121.6(7) . . ? 
C19 C24 C23 119.2(7) . . ? 
N1 C26 C27 116.7(6) . . ? 
N2 C27 C26 114.9(6) . . ? 
N3 C31 C32 112.2(5) . . ? 
N4 C32 C31 112.9(5) . . ? 
 
_refine_diff_density_max    1.707 
_refine_diff_density_min   -1.186 
_refine_diff_density_rms    0.118