Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2004 data_global _journal_name_full 'Dalton Trans.' _journal_coden_Cambridge 0222 _publ_contact_author_name 'Roland A. Fischer' _publ_contact_author_address ; Lehrstuhl fuer Anorganische Chemie 2 Organometallics and Materials Ruhr-Universitaet Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; _publ_contact_author_email roland.fischer@ruhr-uni-bochum.de _publ_requested_coeditor_name ? _publ_section_title ; Insertion of group 13 carbenoids into transition metal halide bonds. Part 2: Novel RhCp*/GaCp* and RhCp*/InCp* cluster complexes. ; _publ_section_abstract ; The insertion of GaCp*, into the Rh-Cl bonds of (Cp*RhCl2)2 and (Cp*RhCl)2 is presented. The crystal structures of the insertion products are given. ; loop_ _publ_author_name _publ_author_address 'Tobias Steinke' ; Lehrstuhl fuer Anorganische Chemie 2 Organometallics and Materials Ruhr-Universitaet Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; 'Christian Gemel' ; Lehrstuhl fuer Anorganische Chemie 2 Organometallics and Materials Ruhr-Universitaet Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; 'Mirza Cokoja' ; Lehrstuhl fuer Anorganische Chemie 2 Organometallics and Materials Ruhr-Universitaet Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; 'Manuela Winter' ; Lehrstuhl fuer Anorganische Chemie 2 Organometallics and Materials Ruhr-Universitaet Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; 'Roland Fischer' ; Lehrstuhl fuer Anorganische Chemie 2 Organometallics and Materials Ruhr-Universitaet Bochum Universitaetsstrasse 150 44780 Bochum (Germany) ; data_1 _database_code_depnum_ccdc_archive 'CCDC 240968' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C40 H60 Cl2 Ga3 Rh' _chemical_formula_weight 923.85 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Orthorhombic _symmetry_space_group_name_H-M Pbca loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' '-x, -y, -z' 'x-1/2, y, -z-1/2' 'x, -y-1/2, z-1/2' '-x-1/2, y-1/2, z' _cell_length_a 10.707(4) _cell_length_b 21.664(9) _cell_length_c 34.608(14) _cell_angle_alpha 90.00 _cell_angle_beta 90.00 _cell_angle_gamma 90.00 _cell_volume 8028(6) _cell_formula_units_Z 8 _cell_measurement_temperature 213(2) _cell_measurement_reflns_used 60 _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description prism _exptl_crystal_colour red _exptl_crystal_size_max 0.45 _exptl_crystal_size_mid 0.25 _exptl_crystal_size_min 0.15 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.529 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 3776 _exptl_absorpt_coefficient_mu 2.555 _exptl_absorpt_correction_type empirical _exptl_absorpt_correction_T_min 0.463 _exptl_absorpt_correction_T_max 1 _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 213(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker CCD 1000' _diffrn_measurement_method 'omega scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 39347 _diffrn_reflns_av_R_equivalents 0.1259 _diffrn_reflns_av_sigmaI/netI 0.0888 _diffrn_reflns_limit_h_min -12 _diffrn_reflns_limit_h_max 12 _diffrn_reflns_limit_k_min -17 _diffrn_reflns_limit_k_max 25 _diffrn_reflns_limit_l_min -41 _diffrn_reflns_limit_l_max 35 _diffrn_reflns_theta_min 2.22 _diffrn_reflns_theta_max 25.09 _reflns_number_total 7124 _reflns_number_gt 5070 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0255P)^2^+30.4003P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 7123 _refine_ls_number_parameters 415 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0901 _refine_ls_R_factor_gt 0.0559 _refine_ls_wR_factor_ref 0.1182 _refine_ls_wR_factor_gt 0.1059 _refine_ls_goodness_of_fit_ref 1.078 _refine_ls_restrained_S_all 1.078 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group C1 C -0.1779(5) 0.0312(3) 0.14107(19) 0.0175(15) Uani 1 1 d . . . C2 C -0.1460(6) 0.0022(3) 0.17872(19) 0.0183(15) Uani 1 1 d . . . C3 C -0.0459(6) -0.0356(3) 0.1729(2) 0.0196(15) Uani 1 1 d . . . C4 C -0.0126(6) -0.0356(3) 0.1324(2) 0.0211(15) Uani 1 1 d . . . C5 C -0.0927(6) 0.0016(3) 0.11301(19) 0.0225(15) Uani 1 1 d . . . C6 C -0.3180(6) 0.0336(3) 0.1309(2) 0.0286(18) Uani 1 1 d . . . H6A H -0.3507 -0.0080 0.1292 0.043 Uiso 1 1 calc R . . H6B H -0.3289 0.0543 0.1063 0.043 Uiso 1 1 calc R . . H6C H -0.3625 0.0561 0.1509 0.043 Uiso 1 1 calc R . . C7 C -0.2206(6) 0.0088(3) 0.2149(2) 0.0314(18) Uani 1 1 d . . . H7A H -0.1810 -0.0145 0.2355 0.047 Uiso 1 1 calc R . . H7B H -0.3043 -0.0069 0.2107 0.047 Uiso 1 1 calc R . . H7C H -0.2249 0.0520 0.2221 0.047 Uiso 1 1 calc R . . C8 C 0.0213(6) -0.0746(3) 0.2030(2) 0.0303(18) Uani 1 1 d . . . H8A H -0.0162 -0.0678 0.2281 0.045 Uiso 1 1 calc R . . H8B H 0.1088 -0.0631 0.2038 0.045 Uiso 1 1 calc R . . H8C H 0.0141 -0.1179 0.1961 0.045 Uiso 1 1 calc R . . C9 C 0.0944(6) -0.0712(3) 0.1158(2) 0.0338(19) Uani 1 1 d . . . H9A H 0.0988 -0.0639 0.0882 0.051 Uiso 1 1 calc R . . H9B H 0.0820 -0.1149 0.1205 0.051 Uiso 1 1 calc R . . H9C H 0.1716 -0.0579 0.1278 0.051 Uiso 1 1 calc R . . C10 C -0.1064(8) 0.0100(4) 0.0703(2) 0.041(2) Uani 1 1 d . . . H10A H -0.0418 -0.0131 0.0571 0.061 Uiso 1 1 calc R . . H10B H -0.0985 0.0535 0.0640 0.061 Uiso 1 1 calc R . . H10C H -0.1878 -0.0047 0.0622 0.061 Uiso 1 1 calc R . . C11 C 0.2259(6) 0.1014(3) 0.0371(2) 0.0261(17) Uani 1 1 d . . . C12 C 0.3234(6) 0.1396(4) 0.0510(2) 0.0294(18) Uani 1 1 d . . . C13 C 0.2862(6) 0.2015(4) 0.0484(2) 0.0308(18) Uani 1 1 d . . . C14 C 0.1662(7) 0.2036(3) 0.0312(2) 0.0259(17) Uani 1 1 d . . . C15 C 0.1274(6) 0.1416(3) 0.02397(19) 0.0235(16) Uani 1 1 d . . . C16 C 0.2340(8) 0.0337(4) 0.0307(2) 0.041(2) Uani 1 1 d . . . H16A H 0.2785 0.0256 0.0068 0.061 Uiso 1 1 calc R . . H16B H 0.1505 0.0165 0.0290 0.061 Uiso 1 1 calc R . . H16C H 0.2783 0.0146 0.0520 0.061 Uiso 1 1 calc R . . C17 C 0.4511(7) 0.1152(5) 0.0631(3) 0.059(3) Uani 1 1 d . . . H17A H 0.5069 0.1157 0.0410 0.088 Uiso 1 1 calc R . . H17B H 0.4426 0.0732 0.0725 0.088 Uiso 1 1 calc R . . H17C H 0.4850 0.1411 0.0834 0.088 Uiso 1 1 calc R . . C18 C 0.3571(8) 0.2581(4) 0.0620(3) 0.052(2) Uani 1 1 d . . . H18A H 0.4149 0.2712 0.0421 0.079 Uiso 1 1 calc R . . H18B H 0.4032 0.2481 0.0854 0.079 Uiso 1 1 calc R . . H18C H 0.2986 0.2912 0.0675 0.079 Uiso 1 1 calc R . . C19 C 0.0951(8) 0.2610(4) 0.0204(2) 0.048(2) Uani 1 1 d . . . H19A H 0.1222 0.2752 -0.0048 0.073 Uiso 1 1 calc R . . H19B H 0.1107 0.2929 0.0395 0.073 Uiso 1 1 calc R . . H19C H 0.0064 0.2518 0.0197 0.073 Uiso 1 1 calc R . . C20 C 0.0134(6) 0.1226(4) 0.0014(2) 0.0331(18) Uani 1 1 d . . . H20A H 0.0339 0.1208 -0.0259 0.050 Uiso 1 1 calc R . . H20B H -0.0527 0.1525 0.0055 0.050 Uiso 1 1 calc R . . H20C H -0.0143 0.0823 0.0101 0.050 Uiso 1 1 calc R . . C21 C -0.2093(6) 0.3204(3) 0.1322(2) 0.0232(16) Uani 1 1 d . . . C22 C -0.1476(6) 0.3445(3) 0.1656(2) 0.0200(15) Uani 1 1 d . . . C23 C -0.0399(6) 0.3761(3) 0.1536(2) 0.0203(15) Uani 1 1 d . . . C24 C -0.0319(6) 0.3720(3) 0.1125(2) 0.0224(16) Uani 1 1 d . . . C25 C -0.1367(6) 0.3383(3) 0.0990(2) 0.0230(16) Uani 1 1 d . . . C26 C -0.3427(6) 0.2981(3) 0.1307(2) 0.034(2) Uani 1 1 d . . . H26A H -0.3987 0.3333 0.1306 0.051 Uiso 1 1 calc R . . H26B H -0.3598 0.2726 0.1531 0.051 Uiso 1 1 calc R . . H26C H -0.3554 0.2740 0.1074 0.051 Uiso 1 1 calc R . . C27 C -0.2006(6) 0.3428(3) 0.2056(2) 0.0286(17) Uani 1 1 d . . . H27A H -0.2326 0.3833 0.2124 0.043 Uiso 1 1 calc R . . H27B H -0.1357 0.3311 0.2238 0.043 Uiso 1 1 calc R . . H27C H -0.2679 0.3128 0.2067 0.043 Uiso 1 1 calc R . . C28 C 0.0481(6) 0.4125(3) 0.1787(2) 0.0331(19) Uani 1 1 d . . . H28A H 0.0237 0.4081 0.2055 0.050 Uiso 1 1 calc R . . H28B H 0.0449 0.4557 0.1714 0.050 Uiso 1 1 calc R . . H28C H 0.1324 0.3970 0.1753 0.050 Uiso 1 1 calc R . . C29 C 0.0658(7) 0.4028(4) 0.0878(3) 0.043(2) Uani 1 1 d . . . H29A H 0.0510 0.3928 0.0609 0.064 Uiso 1 1 calc R . . H29B H 0.1479 0.3882 0.0954 0.064 Uiso 1 1 calc R . . H29C H 0.0613 0.4472 0.0914 0.064 Uiso 1 1 calc R . . C30 C -0.1812(7) 0.3328(4) 0.0581(2) 0.037(2) Uani 1 1 d . . . H30A H -0.2126 0.3724 0.0494 0.056 Uiso 1 1 calc R . . H30B H -0.2476 0.3023 0.0567 0.056 Uiso 1 1 calc R . . H30C H -0.1124 0.3200 0.0417 0.056 Uiso 1 1 calc R . . C31 C 0.1111(5) 0.1394(3) 0.21189(18) 0.0139(14) Uani 1 1 d . . . C32 C 0.1168(5) 0.2055(3) 0.21254(18) 0.0155(14) Uani 1 1 d . . . C33 C 0.2249(5) 0.2255(3) 0.19125(19) 0.0175(15) Uani 1 1 d . . . C34 C 0.2828(5) 0.1724(3) 0.17659(19) 0.0166(14) Uani 1 1 d . . . C35 C 0.2118(5) 0.1195(3) 0.18758(18) 0.0154(14) Uani 1 1 d . . . C36 C 0.0287(6) 0.1011(3) 0.23736(19) 0.0219(16) Uani 1 1 d . . . H36A H 0.0710 0.0933 0.2617 0.033 Uiso 1 1 calc R . . H36B H 0.0105 0.0622 0.2247 0.033 Uiso 1 1 calc R . . H36C H -0.0486 0.1231 0.2422 0.033 Uiso 1 1 calc R . . C37 C 0.0371(6) 0.2446(3) 0.2389(2) 0.0254(17) Uani 1 1 d . . . H37A H 0.0778 0.2485 0.2639 0.038 Uiso 1 1 calc R . . H37B H -0.0438 0.2251 0.2423 0.038 Uiso 1 1 calc R . . H37C H 0.0260 0.2852 0.2277 0.038 Uiso 1 1 calc R . . C38 C 0.2759(6) 0.2897(3) 0.1890(2) 0.0304(18) Uani 1 1 d . . . H38A H 0.3340 0.2964 0.2101 0.046 Uiso 1 1 calc R . . H38B H 0.2078 0.3191 0.1909 0.046 Uiso 1 1 calc R . . H38C H 0.3188 0.2952 0.1646 0.046 Uiso 1 1 calc R . . C39 C 0.4074(6) 0.1703(4) 0.1567(2) 0.0339(19) Uani 1 1 d . . . H39A H 0.4733 0.1687 0.1759 0.051 Uiso 1 1 calc R . . H39B H 0.4176 0.2068 0.1409 0.051 Uiso 1 1 calc R . . H39C H 0.4118 0.1338 0.1405 0.051 Uiso 1 1 calc R . . C40 C 0.2496(6) 0.0539(3) 0.1804(2) 0.0291(18) Uani 1 1 d . . . H40A H 0.3062 0.0405 0.2006 0.044 Uiso 1 1 calc R . . H40B H 0.2910 0.0509 0.1556 0.044 Uiso 1 1 calc R . . H40C H 0.1760 0.0278 0.1805 0.044 Uiso 1 1 calc R . . Cl1 Cl -0.19811(15) 0.16732(8) 0.08589(5) 0.0274(4) Uani 1 1 d . . . Cl2 Cl -0.25095(14) 0.16772(7) 0.18770(5) 0.0245(4) Uani 1 1 d . . . Ga1 Ga -0.11210(6) 0.12167(3) 0.14454(2) 0.01844(19) Uani 1 1 d . . . Ga2 Ga 0.13370(7) 0.15327(4) 0.08775(2) 0.0237(2) Uani 1 1 d . . . Ga3 Ga -0.05354(8) 0.25712(4) 0.13284(3) 0.0382(3) Uani 1 1 d . . . Rh1 Rh 0.08579(4) 0.17698(2) 0.152585(14) 0.01255(13) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 C1 0.018(3) 0.013(3) 0.021(4) -0.001(3) -0.003(3) 0.001(3) C2 0.020(3) 0.013(3) 0.022(4) 0.002(3) -0.001(3) -0.002(3) C3 0.019(3) 0.011(3) 0.028(5) 0.003(3) -0.001(3) -0.003(3) C4 0.022(3) 0.012(3) 0.029(5) -0.003(3) 0.000(3) 0.004(3) C5 0.031(4) 0.019(4) 0.017(4) -0.004(3) 0.002(3) -0.003(3) C6 0.018(3) 0.020(4) 0.049(5) 0.000(3) -0.011(3) -0.009(3) C7 0.034(4) 0.024(4) 0.037(5) 0.008(3) 0.008(3) 0.000(3) C8 0.035(4) 0.025(4) 0.031(5) 0.002(3) -0.002(3) 0.006(3) C9 0.033(4) 0.031(4) 0.038(5) -0.004(4) 0.008(4) 0.009(3) C10 0.059(5) 0.035(5) 0.028(5) -0.003(4) -0.006(4) 0.013(4) C11 0.029(4) 0.037(5) 0.012(4) -0.002(3) 0.007(3) 0.008(3) C12 0.024(4) 0.049(5) 0.014(4) 0.000(3) 0.011(3) 0.005(3) C13 0.031(4) 0.047(5) 0.014(4) 0.001(3) 0.011(3) -0.017(4) C14 0.038(4) 0.033(4) 0.008(4) 0.001(3) 0.005(3) 0.002(3) C15 0.031(4) 0.029(4) 0.010(4) -0.001(3) 0.003(3) 0.008(3) C16 0.054(5) 0.034(5) 0.034(5) 0.000(4) 0.002(4) 0.014(4) C17 0.031(4) 0.105(8) 0.041(6) -0.018(5) 0.004(4) 0.018(5) C18 0.057(5) 0.062(6) 0.038(6) -0.001(4) 0.004(4) -0.032(5) C19 0.073(6) 0.040(5) 0.033(6) 0.004(4) -0.006(5) 0.009(5) C20 0.036(4) 0.043(5) 0.021(5) -0.001(4) -0.002(3) 0.011(4) C21 0.027(3) 0.018(4) 0.025(4) 0.000(3) -0.005(3) 0.002(3) C22 0.019(3) 0.014(4) 0.027(4) 0.004(3) -0.005(3) 0.004(3) C23 0.026(3) 0.013(3) 0.022(4) -0.003(3) -0.006(3) 0.004(3) C24 0.028(4) 0.010(3) 0.029(5) 0.003(3) -0.004(3) -0.001(3) C25 0.031(4) 0.012(4) 0.027(5) -0.002(3) -0.006(3) 0.008(3) C26 0.017(3) 0.029(4) 0.056(6) -0.006(4) -0.014(3) 0.007(3) C27 0.031(4) 0.026(4) 0.029(5) 0.000(3) 0.002(3) 0.006(3) C28 0.031(4) 0.028(4) 0.041(5) -0.007(4) -0.003(4) -0.002(3) C29 0.047(5) 0.033(5) 0.048(6) 0.004(4) 0.010(4) -0.008(4) C30 0.047(5) 0.033(5) 0.031(5) 0.005(4) -0.015(4) 0.012(4) C31 0.015(3) 0.015(4) 0.011(4) -0.001(3) -0.004(3) -0.001(3) C32 0.018(3) 0.022(4) 0.007(4) 0.002(3) -0.007(3) -0.001(3) C33 0.016(3) 0.021(4) 0.015(4) 0.001(3) -0.010(3) 0.000(3) C34 0.011(3) 0.020(4) 0.018(4) 0.000(3) -0.008(3) 0.000(3) C35 0.013(3) 0.016(4) 0.017(4) -0.003(3) -0.005(3) 0.006(3) C36 0.018(3) 0.027(4) 0.020(4) 0.010(3) 0.000(3) -0.006(3) C37 0.028(3) 0.022(4) 0.026(5) -0.010(3) -0.006(3) 0.006(3) C38 0.029(4) 0.021(4) 0.041(5) 0.002(3) -0.007(3) -0.010(3) C39 0.013(3) 0.059(5) 0.030(5) 0.006(4) 0.002(3) 0.001(3) C40 0.035(4) 0.023(4) 0.030(5) -0.001(3) -0.002(3) 0.008(3) Cl1 0.0288(9) 0.0246(10) 0.0287(11) 0.0011(8) -0.0123(7) 0.0015(7) Cl2 0.0172(7) 0.0216(9) 0.0346(12) -0.0021(8) 0.0082(7) 0.0022(7) Ga1 0.0122(3) 0.0212(4) 0.0219(5) -0.0045(3) -0.0001(3) -0.0033(3) Ga2 0.0249(4) 0.0333(5) 0.0131(5) -0.0010(3) 0.0019(3) -0.0016(3) Ga3 0.0326(4) 0.0507(6) 0.0312(6) 0.0115(4) 0.0002(4) 0.0264(4) Rh1 0.0100(2) 0.0161(3) 0.0115(3) 0.0005(2) -0.00091(19) 0.0006(2) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag C1 C5 1.479(9) . ? C1 C2 1.486(9) . ? C1 C6 1.541(8) . ? C1 Ga1 2.086(6) . ? C2 C3 1.364(9) . ? C2 C7 1.492(9) . ? C3 C4 1.444(10) . ? C3 C8 1.522(9) . ? C4 C5 1.356(9) . ? C4 C9 1.496(9) . ? C5 C10 1.496(10) . ? C11 C12 1.415(10) . ? C11 C15 1.442(9) . ? C11 C16 1.488(10) . ? C11 Ga2 2.304(7) . ? C12 C13 1.403(11) . ? C12 C17 1.524(10) . ? C12 Ga2 2.414(6) . ? C13 C14 1.416(10) . ? C13 C18 1.518(10) . ? C13 Ga2 2.370(7) . ? C14 C15 1.428(10) . ? C14 C19 1.504(10) . ? C14 Ga2 2.268(7) . ? C15 C20 1.506(9) . ? C15 Ga2 2.223(7) . ? C21 C22 1.431(9) . ? C21 C25 1.439(10) . ? C21 C26 1.509(9) . ? C21 Ga3 2.158(6) . ? C22 C23 1.404(9) . ? C22 C27 1.498(9) . ? C22 Ga3 2.426(7) . ? C23 C24 1.428(9) . ? C23 C28 1.503(9) . ? C24 C25 1.417(9) . ? C24 C29 1.506(10) . ? C25 C30 1.499(10) . ? C25 Ga3 2.293(6) . ? C31 C35 1.434(8) . ? C31 C32 1.434(9) . ? C31 C36 1.497(8) . ? C31 Rh1 2.225(6) . ? C32 C33 1.438(9) . ? C32 C37 1.509(9) . ? C32 Rh1 2.190(6) . ? C33 C34 1.400(9) . ? C33 C38 1.497(9) . ? C33 Rh1 2.261(6) . ? C34 C35 1.428(9) . ? C34 C39 1.502(8) . ? C34 Rh1 2.269(5) . ? C35 C40 1.498(9) . ? C35 Rh1 2.200(6) . ? Cl1 Ga1 2.438(2) . ? Cl2 Ga1 2.3316(18) . ? Ga1 Rh1 2.4500(11) . ? Ga2 Rh1 2.3583(12) . ? Ga3 Rh1 2.3888(11) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C5 C1 C2 104.5(5) . . ? C5 C1 C6 117.8(6) . . ? C2 C1 C6 116.0(5) . . ? C5 C1 Ga1 103.7(4) . . ? C2 C1 Ga1 105.6(4) . . ? C6 C1 Ga1 108.0(4) . . ? C3 C2 C1 107.7(6) . . ? C3 C2 C7 127.0(6) . . ? C1 C2 C7 125.0(6) . . ? C2 C3 C4 109.8(6) . . ? C2 C3 C8 127.1(6) . . ? C4 C3 C8 123.1(6) . . ? C5 C4 C3 108.9(6) . . ? C5 C4 C9 126.8(7) . . ? C3 C4 C9 124.3(6) . . ? C4 C5 C1 108.8(6) . . ? C4 C5 C10 128.7(6) . . ? C1 C5 C10 122.3(6) . . ? C12 C11 C15 107.1(6) . . ? C12 C11 C16 125.8(7) . . ? C15 C11 C16 126.2(7) . . ? C12 C11 Ga2 76.9(4) . . ? C15 C11 Ga2 68.4(4) . . ? C16 C11 Ga2 128.4(5) . . ? C13 C12 C11 109.0(6) . . ? C13 C12 C17 127.2(7) . . ? C11 C12 C17 123.5(7) . . ? C13 C12 Ga2 71.2(4) . . ? C11 C12 Ga2 68.3(4) . . ? C17 C12 Ga2 130.8(5) . . ? C12 C13 C14 108.4(6) . . ? C12 C13 C18 127.6(7) . . ? C14 C13 C18 124.0(7) . . ? C12 C13 Ga2 74.7(4) . . ? C14 C13 Ga2 68.4(4) . . ? C18 C13 Ga2 121.4(5) . . ? C13 C14 C15 107.9(6) . . ? C13 C14 C19 126.2(7) . . ? C15 C14 C19 125.9(7) . . ? C13 C14 Ga2 76.2(4) . . ? C15 C14 Ga2 69.7(4) . . ? C19 C14 Ga2 122.2(5) . . ? C14 C15 C11 107.4(6) . . ? C14 C15 C20 125.7(6) . . ? C11 C15 C20 126.3(6) . . ? C14 C15 Ga2 73.2(4) . . ? C11 C15 Ga2 74.5(4) . . ? C20 C15 Ga2 124.8(5) . . ? C22 C21 C25 107.2(6) . . ? C22 C21 C26 125.5(6) . . ? C25 C21 C26 124.8(6) . . ? C22 C21 Ga3 82.4(4) . . ? C25 C21 Ga3 76.3(4) . . ? C26 C21 Ga3 121.9(5) . . ? C23 C22 C21 108.6(6) . . ? C23 C22 C27 126.6(6) . . ? C21 C22 C27 124.3(6) . . ? C23 C22 Ga3 84.4(4) . . ? C21 C22 Ga3 61.8(3) . . ? C27 C22 Ga3 124.7(4) . . ? C22 C23 C24 108.2(6) . . ? C22 C23 C28 126.9(7) . . ? C24 C23 C28 124.8(6) . . ? C25 C24 C23 108.2(6) . . ? C25 C24 C29 126.2(7) . . ? C23 C24 C29 125.4(6) . . ? C24 C25 C21 107.7(6) . . ? C24 C25 C30 127.2(7) . . ? C21 C25 C30 124.0(6) . . ? C24 C25 Ga3 85.4(4) . . ? C21 C25 Ga3 66.1(4) . . ? C30 C25 Ga3 123.0(5) . . ? C35 C31 C32 106.1(5) . . ? C35 C31 C36 128.5(6) . . ? C32 C31 C36 124.7(6) . . ? C35 C31 Rh1 70.1(4) . . ? C32 C31 Rh1 69.8(3) . . ? C36 C31 Rh1 132.4(4) . . ? C31 C32 C33 109.0(5) . . ? C31 C32 C37 123.0(6) . . ? C33 C32 C37 126.7(6) . . ? C31 C32 Rh1 72.3(4) . . ? C33 C32 Rh1 73.8(4) . . ? C37 C32 Rh1 130.2(4) . . ? C34 C33 C32 107.2(5) . . ? C34 C33 C38 125.6(6) . . ? C32 C33 C38 126.8(6) . . ? C34 C33 Rh1 72.3(3) . . ? C32 C33 Rh1 68.5(3) . . ? C38 C33 Rh1 129.9(5) . . ? C33 C34 C35 109.1(5) . . ? C33 C34 C39 125.8(6) . . ? C35 C34 C39 124.7(6) . . ? C33 C34 Rh1 71.7(3) . . ? C35 C34 Rh1 68.7(3) . . ? C39 C34 Rh1 131.3(5) . . ? C34 C35 C31 108.4(5) . . ? C34 C35 C40 125.0(6) . . ? C31 C35 C40 125.8(6) . . ? C34 C35 Rh1 74.0(3) . . ? C31 C35 Rh1 72.0(3) . . ? C40 C35 Rh1 127.7(5) . . ? C1 Ga1 Cl2 102.90(18) . . ? C1 Ga1 Cl1 101.85(18) . . ? Cl2 Ga1 Cl1 96.83(7) . . ? C1 Ga1 Rh1 139.31(16) . . ? Cl2 Ga1 Rh1 105.63(5) . . ? Cl1 Ga1 Rh1 102.88(5) . . ? C15 Ga2 C14 37.1(3) . . ? C15 Ga2 C11 37.1(2) . . ? C14 Ga2 C11 60.8(3) . . ? C15 Ga2 Rh1 164.35(17) . . ? C14 Ga2 Rh1 138.57(18) . . ? C11 Ga2 Rh1 157.39(18) . . ? C15 Ga2 C13 60.0(3) . . ? C14 Ga2 C13 35.5(2) . . ? C11 Ga2 C13 58.8(3) . . ? Rh1 Ga2 C13 126.94(19) . . ? C15 Ga2 C12 59.3(2) . . ? C14 Ga2 C12 58.4(3) . . ? C11 Ga2 C12 34.8(2) . . ? Rh1 Ga2 C12 135.27(18) . . ? C13 Ga2 C12 34.1(3) . . ? C21 Ga3 C25 37.6(2) . . ? C21 Ga3 Rh1 161.25(19) . . ? C25 Ga3 Rh1 161.10(18) . . ? C21 Ga3 C22 35.8(2) . . ? C25 Ga3 C22 58.6(2) . . ? Rh1 Ga3 C22 133.87(16) . . ? C32 Rh1 C35 63.0(2) . . ? C32 Rh1 C31 37.9(2) . . ? C35 Rh1 C31 37.8(2) . . ? C32 Rh1 C33 37.7(2) . . ? C35 Rh1 C33 62.2(2) . . ? C31 Rh1 C33 62.9(2) . . ? C32 Rh1 C34 61.6(2) . . ? C35 Rh1 C34 37.2(2) . . ? C31 Rh1 C34 62.2(2) . . ? C33 Rh1 C34 36.0(2) . . ? C32 Rh1 Ga2 158.40(16) . . ? C35 Rh1 Ga2 105.49(16) . . ? C31 Rh1 Ga2 140.49(16) . . ? C33 Rh1 Ga2 121.39(17) . . ? C34 Rh1 Ga2 97.85(17) . . ? C32 Rh1 Ga3 99.23(16) . . ? C35 Rh1 Ga3 162.18(16) . . ? C31 Rh1 Ga3 127.30(15) . . ? C33 Rh1 Ga3 104.08(16) . . ? C34 Rh1 Ga3 135.79(16) . . ? Ga2 Rh1 Ga3 91.26(4) . . ? C32 Rh1 Ga1 112.14(16) . . ? C35 Rh1 Ga1 108.44(16) . . ? C31 Rh1 Ga1 91.79(15) . . ? C33 Rh1 Ga1 149.79(17) . . ? C34 Rh1 Ga1 145.52(16) . . ? Ga2 Rh1 Ga1 88.48(3) . . ? Ga3 Rh1 Ga1 77.46(4) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C5 C1 C2 C3 4.8(7) . . . . ? C6 C1 C2 C3 136.2(6) . . . . ? Ga1 C1 C2 C3 -104.2(5) . . . . ? C5 C1 C2 C7 -169.1(6) . . . . ? C6 C1 C2 C7 -37.7(9) . . . . ? Ga1 C1 C2 C7 81.9(7) . . . . ? C1 C2 C3 C4 -2.8(7) . . . . ? C7 C2 C3 C4 171.0(6) . . . . ? C1 C2 C3 C8 179.3(6) . . . . ? C7 C2 C3 C8 -6.9(11) . . . . ? C2 C3 C4 C5 -0.6(8) . . . . ? C8 C3 C4 C5 177.4(6) . . . . ? C2 C3 C4 C9 179.0(6) . . . . ? C8 C3 C4 C9 -3.0(10) . . . . ? C3 C4 C5 C1 3.8(7) . . . . ? C9 C4 C5 C1 -175.8(6) . . . . ? C3 C4 C5 C10 -171.3(7) . . . . ? C9 C4 C5 C10 9.1(12) . . . . ? C2 C1 C5 C4 -5.3(7) . . . . ? C6 C1 C5 C4 -135.6(6) . . . . ? Ga1 C1 C5 C4 105.1(5) . . . . ? C2 C1 C5 C10 170.2(6) . . . . ? C6 C1 C5 C10 39.9(9) . . . . ? Ga1 C1 C5 C10 -79.4(7) . . . . ? C15 C11 C12 C13 2.4(8) . . . . ? C16 C11 C12 C13 172.1(7) . . . . ? Ga2 C11 C12 C13 -59.8(5) . . . . ? C15 C11 C12 C17 -172.4(7) . . . . ? C16 C11 C12 C17 -2.6(11) . . . . ? Ga2 C11 C12 C17 125.5(7) . . . . ? C15 C11 C12 Ga2 62.1(4) . . . . ? C16 C11 C12 Ga2 -128.1(7) . . . . ? C11 C12 C13 C14 -2.4(8) . . . . ? C17 C12 C13 C14 172.2(7) . . . . ? Ga2 C12 C13 C14 -60.4(5) . . . . ? C11 C12 C13 C18 176.1(7) . . . . ? C17 C12 C13 C18 -9.3(12) . . . . ? Ga2 C12 C13 C18 118.1(8) . . . . ? C11 C12 C13 Ga2 58.0(5) . . . . ? C17 C12 C13 Ga2 -127.5(7) . . . . ? C12 C13 C14 C15 1.4(8) . . . . ? C18 C13 C14 C15 -177.2(7) . . . . ? Ga2 C13 C14 C15 -63.0(5) . . . . ? C12 C13 C14 C19 -175.6(7) . . . . ? C18 C13 C14 C19 5.8(12) . . . . ? Ga2 C13 C14 C19 120.0(7) . . . . ? C12 C13 C14 Ga2 64.4(5) . . . . ? C18 C13 C14 Ga2 -114.2(7) . . . . ? C13 C14 C15 C11 0.1(8) . . . . ? C19 C14 C15 C11 177.1(7) . . . . ? Ga2 C14 C15 C11 -67.2(5) . . . . ? C13 C14 C15 C20 -171.6(7) . . . . ? C19 C14 C15 C20 5.4(11) . . . . ? Ga2 C14 C15 C20 121.2(7) . . . . ? C13 C14 C15 Ga2 67.2(5) . . . . ? C19 C14 C15 Ga2 -115.7(7) . . . . ? C12 C11 C15 C14 -1.5(7) . . . . ? C16 C11 C15 C14 -171.2(7) . . . . ? Ga2 C11 C15 C14 66.3(5) . . . . ? C12 C11 C15 C20 170.1(7) . . . . ? C16 C11 C15 C20 0.4(11) . . . . ? Ga2 C11 C15 C20 -122.1(7) . . . . ? C12 C11 C15 Ga2 -67.8(5) . . . . ? C16 C11 C15 Ga2 122.5(7) . . . . ? C25 C21 C22 C23 -0.3(7) . . . . ? C26 C21 C22 C23 -163.3(6) . . . . ? Ga3 C21 C22 C23 72.7(5) . . . . ? C25 C21 C22 C27 172.3(6) . . . . ? C26 C21 C22 C27 9.4(10) . . . . ? Ga3 C21 C22 C27 -114.6(6) . . . . ? C25 C21 C22 Ga3 -73.0(4) . . . . ? C26 C21 C22 Ga3 124.1(7) . . . . ? C21 C22 C23 C24 -0.3(7) . . . . ? C27 C22 C23 C24 -172.8(6) . . . . ? Ga3 C22 C23 C24 57.4(5) . . . . ? C21 C22 C23 C28 175.4(6) . . . . ? C27 C22 C23 C28 3.0(11) . . . . ? Ga3 C22 C23 C28 -126.8(6) . . . . ? C22 C23 C24 C25 0.8(7) . . . . ? C28 C23 C24 C25 -175.0(6) . . . . ? C22 C23 C24 C29 176.3(6) . . . . ? C28 C23 C24 C29 0.4(10) . . . . ? C23 C24 C25 C21 -1.1(7) . . . . ? C29 C24 C25 C21 -176.4(6) . . . . ? C23 C24 C25 C30 167.2(6) . . . . ? C29 C24 C25 C30 -8.2(11) . . . . ? C23 C24 C25 Ga3 -64.2(5) . . . . ? C29 C24 C25 Ga3 120.4(7) . . . . ? C22 C21 C25 C24 0.9(7) . . . . ? C26 C21 C25 C24 163.9(6) . . . . ? Ga3 C21 C25 C24 -76.5(5) . . . . ? C22 C21 C25 C30 -167.8(6) . . . . ? C26 C21 C25 C30 -4.7(10) . . . . ? Ga3 C21 C25 C30 114.8(6) . . . . ? C22 C21 C25 Ga3 77.4(4) . . . . ? C26 C21 C25 Ga3 -119.5(7) . . . . ? C35 C31 C32 C33 -4.1(7) . . . . ? C36 C31 C32 C33 166.6(6) . . . . ? Rh1 C31 C32 C33 -65.2(4) . . . . ? C35 C31 C32 C37 -171.9(6) . . . . ? C36 C31 C32 C37 -1.2(9) . . . . ? Rh1 C31 C32 C37 127.0(6) . . . . ? C35 C31 C32 Rh1 61.1(4) . . . . ? C36 C31 C32 Rh1 -128.2(6) . . . . ? C31 C32 C33 C34 1.9(7) . . . . ? C37 C32 C33 C34 169.1(6) . . . . ? Rh1 C32 C33 C34 -62.4(4) . . . . ? C31 C32 C33 C38 -171.3(6) . . . . ? C37 C32 C33 C38 -4.1(10) . . . . ? Rh1 C32 C33 C38 124.5(6) . . . . ? C31 C32 C33 Rh1 64.3(4) . . . . ? C37 C32 C33 Rh1 -128.5(6) . . . . ? C32 C33 C34 C35 1.2(7) . . . . ? C38 C33 C34 C35 174.4(6) . . . . ? Rh1 C33 C34 C35 -58.8(4) . . . . ? C32 C33 C34 C39 -171.9(6) . . . . ? C38 C33 C34 C39 1.3(10) . . . . ? Rh1 C33 C34 C39 128.2(7) . . . . ? C32 C33 C34 Rh1 59.9(4) . . . . ? C38 C33 C34 Rh1 -126.8(7) . . . . ? C33 C34 C35 C31 -3.8(7) . . . . ? C39 C34 C35 C31 169.4(6) . . . . ? Rh1 C34 C35 C31 -64.3(4) . . . . ? C33 C34 C35 C40 -174.2(6) . . . . ? C39 C34 C35 C40 -1.1(10) . . . . ? Rh1 C34 C35 C40 125.2(6) . . . . ? C33 C34 C35 Rh1 60.6(4) . . . . ? C39 C34 C35 Rh1 -126.3(6) . . . . ? C32 C31 C35 C34 4.8(7) . . . . ? C36 C31 C35 C34 -165.4(6) . . . . ? Rh1 C31 C35 C34 65.7(4) . . . . ? C32 C31 C35 C40 175.2(6) . . . . ? C36 C31 C35 C40 4.9(10) . . . . ? Rh1 C31 C35 C40 -124.0(6) . . . . ? C32 C31 C35 Rh1 -60.8(4) . . . . ? C36 C31 C35 Rh1 128.9(6) . . . . ? C5 C1 Ga1 Cl2 178.7(4) . . . . ? C2 C1 Ga1 Cl2 -71.7(4) . . . . ? C6 C1 Ga1 Cl2 53.0(5) . . . . ? C5 C1 Ga1 Cl1 78.7(4) . . . . ? C2 C1 Ga1 Cl1 -171.7(4) . . . . ? C6 C1 Ga1 Cl1 -47.0(5) . . . . ? C5 C1 Ga1 Rh1 -47.7(6) . . . . ? C2 C1 Ga1 Rh1 61.9(5) . . . . ? C6 C1 Ga1 Rh1 -173.4(3) . . . . ? C11 C15 Ga2 C14 114.1(6) . . . . ? C20 C15 Ga2 C14 -122.2(7) . . . . ? C14 C15 Ga2 C11 -114.1(6) . . . . ? C20 C15 Ga2 C11 123.7(8) . . . . ? C14 C15 Ga2 Rh1 83.5(8) . . . . ? C11 C15 Ga2 Rh1 -162.4(5) . . . . ? C20 C15 Ga2 Rh1 -38.7(11) . . . . ? C14 C15 Ga2 C13 -37.3(4) . . . . ? C11 C15 Ga2 C13 76.8(4) . . . . ? C20 C15 Ga2 C13 -159.5(7) . . . . ? C14 C15 Ga2 C12 -77.0(4) . . . . ? C11 C15 Ga2 C12 37.1(4) . . . . ? C20 C15 Ga2 C12 160.8(7) . . . . ? C13 C14 Ga2 C15 -115.3(6) . . . . ? C19 C14 Ga2 C15 120.4(8) . . . . ? C13 C14 Ga2 C11 -76.2(5) . . . . ? C15 C14 Ga2 C11 39.1(4) . . . . ? C19 C14 Ga2 C11 159.5(7) . . . . ? C13 C14 Ga2 Rh1 88.6(5) . . . . ? C15 C14 Ga2 Rh1 -156.1(3) . . . . ? C19 C14 Ga2 Rh1 -35.7(7) . . . . ? C15 C14 Ga2 C13 115.3(6) . . . . ? C19 C14 Ga2 C13 -124.3(8) . . . . ? C13 C14 Ga2 C12 -35.7(4) . . . . ? C15 C14 Ga2 C12 79.6(4) . . . . ? C19 C14 Ga2 C12 -160.0(7) . . . . ? C12 C11 Ga2 C15 114.7(6) . . . . ? C16 C11 Ga2 C15 -119.8(8) . . . . ? C12 C11 Ga2 C14 75.6(5) . . . . ? C15 C11 Ga2 C14 -39.1(4) . . . . ? C16 C11 Ga2 C14 -158.9(7) . . . . ? C12 C11 Ga2 Rh1 -77.5(7) . . . . ? C15 C11 Ga2 Rh1 167.7(4) . . . . ? C16 C11 Ga2 Rh1 47.9(9) . . . . ? C12 C11 Ga2 C13 34.4(4) . . . . ? C15 C11 Ga2 C13 -80.3(4) . . . . ? C16 C11 Ga2 C13 159.9(8) . . . . ? C15 C11 Ga2 C12 -114.7(6) . . . . ? C16 C11 Ga2 C12 125.5(9) . . . . ? C12 C13 Ga2 C15 -78.5(4) . . . . ? C14 C13 Ga2 C15 39.0(4) . . . . ? C18 C13 Ga2 C15 156.5(8) . . . . ? C12 C13 Ga2 C14 -117.5(6) . . . . ? C18 C13 Ga2 C14 117.5(8) . . . . ? C12 C13 Ga2 C11 -35.1(4) . . . . ? C14 C13 Ga2 C11 82.3(5) . . . . ? C18 C13 Ga2 C11 -160.1(8) . . . . ? C12 C13 Ga2 Rh1 118.4(4) . . . . ? C14 C13 Ga2 Rh1 -124.2(4) . . . . ? C18 C13 Ga2 Rh1 -6.6(8) . . . . ? C14 C13 Ga2 C12 117.5(6) . . . . ? C18 C13 Ga2 C12 -125.0(8) . . . . ? C13 C12 Ga2 C15 80.8(5) . . . . ? C11 C12 Ga2 C15 -39.6(4) . . . . ? C17 C12 Ga2 C15 -155.8(9) . . . . ? C13 C12 Ga2 C14 37.2(4) . . . . ? C11 C12 Ga2 C14 -83.2(5) . . . . ? C17 C12 Ga2 C14 160.6(9) . . . . ? C13 C12 Ga2 C11 120.4(6) . . . . ? C17 C12 Ga2 C11 -116.2(9) . . . . ? C13 C12 Ga2 Rh1 -91.8(4) . . . . ? C11 C12 Ga2 Rh1 147.8(4) . . . . ? C17 C12 Ga2 Rh1 31.5(9) . . . . ? C11 C12 Ga2 C13 -120.4(6) . . . . ? C17 C12 Ga2 C13 123.4(10) . . . . ? C22 C21 Ga3 C25 -109.9(5) . . . . ? C26 C21 Ga3 C25 122.7(8) . . . . ? C22 C21 Ga3 Rh1 66.4(7) . . . . ? C25 C21 Ga3 Rh1 176.3(4) . . . . ? C26 C21 Ga3 Rh1 -61.0(9) . . . . ? C25 C21 Ga3 C22 109.9(5) . . . . ? C26 C21 Ga3 C22 -127.4(8) . . . . ? C24 C25 Ga3 C21 111.7(6) . . . . ? C30 C25 Ga3 C21 -116.3(7) . . . . ? C24 C25 Ga3 Rh1 -64.7(7) . . . . ? C21 C25 Ga3 Rh1 -176.3(4) . . . . ? C30 C25 Ga3 Rh1 67.4(9) . . . . ? C24 C25 Ga3 C22 71.5(4) . . . . ? C21 C25 Ga3 C22 -40.1(4) . . . . ? C30 C25 Ga3 C22 -156.4(7) . . . . ? C23 C22 Ga3 C21 -114.6(6) . . . . ? C27 C22 Ga3 C21 114.0(7) . . . . ? C23 C22 Ga3 C25 -72.4(4) . . . . ? C21 C22 Ga3 C25 42.2(4) . . . . ? C27 C22 Ga3 C25 156.3(6) . . . . ? C23 C22 Ga3 Rh1 89.5(4) . . . . ? C21 C22 Ga3 Rh1 -155.9(3) . . . . ? C27 C22 Ga3 Rh1 -41.9(6) . . . . ? C31 C32 Rh1 C35 -38.0(3) . . . . ? C33 C32 Rh1 C35 78.6(4) . . . . ? C37 C32 Rh1 C35 -156.7(7) . . . . ? C33 C32 Rh1 C31 116.6(5) . . . . ? C37 C32 Rh1 C31 -118.7(7) . . . . ? C31 C32 Rh1 C33 -116.6(5) . . . . ? C37 C32 Rh1 C33 124.7(7) . . . . ? C31 C32 Rh1 C34 -80.2(4) . . . . ? C33 C32 Rh1 C34 36.4(3) . . . . ? C37 C32 Rh1 C34 161.1(7) . . . . ? C31 C32 Rh1 Ga2 -99.7(5) . . . . ? C33 C32 Rh1 Ga2 17.0(7) . . . . ? C37 C32 Rh1 Ga2 141.7(5) . . . . ? C31 C32 Rh1 Ga3 142.2(3) . . . . ? C33 C32 Rh1 Ga3 -101.1(3) . . . . ? C37 C32 Rh1 Ga3 23.6(6) . . . . ? C31 C32 Rh1 Ga1 62.1(3) . . . . ? C33 C32 Rh1 Ga1 178.8(3) . . . . ? C37 C32 Rh1 Ga1 -56.5(6) . . . . ? C34 C35 Rh1 C32 -77.9(4) . . . . ? C31 C35 Rh1 C32 38.1(3) . . . . ? C40 C35 Rh1 C32 159.9(6) . . . . ? C34 C35 Rh1 C31 -115.9(5) . . . . ? C40 C35 Rh1 C31 121.8(7) . . . . ? C34 C35 Rh1 C33 -35.2(4) . . . . ? C31 C35 Rh1 C33 80.7(4) . . . . ? C40 C35 Rh1 C33 -157.5(6) . . . . ? C31 C35 Rh1 C34 115.9(5) . . . . ? C40 C35 Rh1 C34 -122.3(7) . . . . ? C34 C35 Rh1 Ga2 82.5(4) . . . . ? C31 C35 Rh1 Ga2 -161.6(3) . . . . ? C40 C35 Rh1 Ga2 -39.8(6) . . . . ? C34 C35 Rh1 Ga3 -77.1(7) . . . . ? C31 C35 Rh1 Ga3 38.9(7) . . . . ? C40 C35 Rh1 Ga3 160.7(4) . . . . ? C34 C35 Rh1 Ga1 176.1(3) . . . . ? C31 C35 Rh1 Ga1 -67.9(3) . . . . ? C40 C35 Rh1 Ga1 53.9(6) . . . . ? C35 C31 Rh1 C32 -116.6(5) . . . . ? C36 C31 Rh1 C32 119.0(7) . . . . ? C32 C31 Rh1 C35 116.6(5) . . . . ? C36 C31 Rh1 C35 -124.5(7) . . . . ? C35 C31 Rh1 C33 -78.7(4) . . . . ? C32 C31 Rh1 C33 37.9(3) . . . . ? C36 C31 Rh1 C33 156.8(7) . . . . ? C35 C31 Rh1 C34 -37.9(3) . . . . ? C32 C31 Rh1 C34 78.6(4) . . . . ? C36 C31 Rh1 C34 -162.4(7) . . . . ? C35 C31 Rh1 Ga2 28.6(4) . . . . ? C32 C31 Rh1 Ga2 145.2(3) . . . . ? C36 C31 Rh1 Ga2 -95.8(6) . . . . ? C35 C31 Rh1 Ga3 -166.0(3) . . . . ? C32 C31 Rh1 Ga3 -49.4(4) . . . . ? C36 C31 Rh1 Ga3 69.5(6) . . . . ? C35 C31 Rh1 Ga1 118.4(3) . . . . ? C32 C31 Rh1 Ga1 -125.0(3) . . . . ? C36 C31 Rh1 Ga1 -6.0(6) . . . . ? C34 C33 Rh1 C32 117.3(5) . . . . ? C38 C33 Rh1 C32 -120.6(7) . . . . ? C34 C33 Rh1 C35 36.4(4) . . . . ? C32 C33 Rh1 C35 -81.0(4) . . . . ? C38 C33 Rh1 C35 158.4(7) . . . . ? C34 C33 Rh1 C31 79.2(4) . . . . ? C32 C33 Rh1 C31 -38.1(4) . . . . ? C38 C33 Rh1 C31 -158.8(7) . . . . ? C32 C33 Rh1 C34 -117.3(5) . . . . ? C38 C33 Rh1 C34 122.0(8) . . . . ? C34 C33 Rh1 Ga2 -55.4(4) . . . . ? C32 C33 Rh1 Ga2 -172.8(3) . . . . ? C38 C33 Rh1 Ga2 66.6(6) . . . . ? C34 C33 Rh1 Ga3 -155.8(3) . . . . ? C32 C33 Rh1 Ga3 86.9(3) . . . . ? C38 C33 Rh1 Ga3 -33.8(6) . . . . ? C34 C33 Rh1 Ga1 115.0(4) . . . . ? C32 C33 Rh1 Ga1 -2.3(5) . . . . ? C38 C33 Rh1 Ga1 -122.9(5) . . . . ? C33 C34 Rh1 C32 -38.1(4) . . . . ? C35 C34 Rh1 C32 81.8(4) . . . . ? C39 C34 Rh1 C32 -160.0(7) . . . . ? C33 C34 Rh1 C35 -119.9(5) . . . . ? C39 C34 Rh1 C35 118.2(8) . . . . ? C33 C34 Rh1 C31 -81.3(4) . . . . ? C35 C34 Rh1 C31 38.6(4) . . . . ? C39 C34 Rh1 C31 156.7(7) . . . . ? C35 C34 Rh1 C33 119.9(5) . . . . ? C39 C34 Rh1 C33 -122.0(8) . . . . ? C33 C34 Rh1 Ga2 134.8(4) . . . . ? C35 C34 Rh1 Ga2 -105.3(3) . . . . ? C39 C34 Rh1 Ga2 12.8(6) . . . . ? C33 C34 Rh1 Ga3 34.8(5) . . . . ? C35 C34 Rh1 Ga3 154.7(3) . . . . ? C39 C34 Rh1 Ga3 -87.2(7) . . . . ? C33 C34 Rh1 Ga1 -126.4(4) . . . . ? C35 C34 Rh1 Ga1 -6.5(5) . . . . ? C39 C34 Rh1 Ga1 111.7(6) . . . . ? C15 Ga2 Rh1 C32 -145.7(8) . . . . ? C14 Ga2 Rh1 C32 -80.9(5) . . . . ? C11 Ga2 Rh1 C32 62.6(7) . . . . ? C13 Ga2 Rh1 C32 -34.3(5) . . . . ? C12 Ga2 Rh1 C32 10.2(5) . . . . ? C15 Ga2 Rh1 C35 159.8(7) . . . . ? C14 Ga2 Rh1 C35 -135.3(3) . . . . ? C11 Ga2 Rh1 C35 8.2(5) . . . . ? C13 Ga2 Rh1 C35 -88.8(3) . . . . ? C12 Ga2 Rh1 C35 -44.2(3) . . . . ? C15 Ga2 Rh1 C31 142.1(7) . . . . ? C14 Ga2 Rh1 C31 -153.0(4) . . . . ? C11 Ga2 Rh1 C31 -9.6(5) . . . . ? C13 Ga2 Rh1 C31 -106.5(3) . . . . ? C12 Ga2 Rh1 C31 -62.0(4) . . . . ? C15 Ga2 Rh1 C33 -133.7(7) . . . . ? C14 Ga2 Rh1 C33 -68.8(3) . . . . ? C11 Ga2 Rh1 C33 74.7(5) . . . . ? C13 Ga2 Rh1 C33 -22.3(3) . . . . ? C12 Ga2 Rh1 C33 22.3(3) . . . . ? C15 Ga2 Rh1 C34 -162.9(7) . . . . ? C14 Ga2 Rh1 C34 -98.0(3) . . . . ? C11 Ga2 Rh1 C34 45.4(5) . . . . ? C13 Ga2 Rh1 C34 -51.5(3) . . . . ? C12 Ga2 Rh1 C34 -7.0(3) . . . . ? C15 Ga2 Rh1 Ga3 -26.3(7) . . . . ? C14 Ga2 Rh1 Ga3 38.6(3) . . . . ? C11 Ga2 Rh1 Ga3 -178.0(5) . . . . ? C13 Ga2 Rh1 Ga3 85.1(3) . . . . ? C12 Ga2 Rh1 Ga3 129.6(3) . . . . ? C15 Ga2 Rh1 Ga1 51.1(7) . . . . ? C14 Ga2 Rh1 Ga1 116.0(3) . . . . ? C11 Ga2 Rh1 Ga1 -100.5(5) . . . . ? C13 Ga2 Rh1 Ga1 162.5(2) . . . . ? C12 Ga2 Rh1 Ga1 -153.0(3) . . . . ? C21 Ga3 Rh1 C32 -50.0(6) . . . . ? C25 Ga3 Rh1 C32 123.0(6) . . . . ? C22 Ga3 Rh1 C32 -2.0(3) . . . . ? C21 Ga3 Rh1 C35 -50.7(8) . . . . ? C25 Ga3 Rh1 C35 122.3(7) . . . . ? C22 Ga3 Rh1 C35 -2.8(6) . . . . ? C21 Ga3 Rh1 C31 -21.8(6) . . . . ? C25 Ga3 Rh1 C31 151.2(6) . . . . ? C22 Ga3 Rh1 C31 26.2(3) . . . . ? C21 Ga3 Rh1 C33 -88.2(6) . . . . ? C25 Ga3 Rh1 C33 84.8(6) . . . . ? C22 Ga3 Rh1 C33 -40.2(3) . . . . ? C21 Ga3 Rh1 C34 -108.5(6) . . . . ? C25 Ga3 Rh1 C34 64.6(6) . . . . ? C22 Ga3 Rh1 C34 -60.5(3) . . . . ? C21 Ga3 Rh1 Ga2 148.9(6) . . . . ? C25 Ga3 Rh1 Ga2 -38.0(5) . . . . ? C22 Ga3 Rh1 Ga2 -163.1(2) . . . . ? C21 Ga3 Rh1 Ga1 60.8(6) . . . . ? C25 Ga3 Rh1 Ga1 -126.2(5) . . . . ? C22 Ga3 Rh1 Ga1 108.7(2) . . . . ? C1 Ga1 Rh1 C32 -98.1(3) . . . . ? Cl2 Ga1 Rh1 C32 34.79(18) . . . . ? Cl1 Ga1 Rh1 C32 135.78(18) . . . . ? C1 Ga1 Rh1 C35 -30.6(3) . . . . ? Cl2 Ga1 Rh1 C35 102.35(18) . . . . ? Cl1 Ga1 Rh1 C35 -156.66(18) . . . . ? C1 Ga1 Rh1 C31 -65.2(3) . . . . ? Cl2 Ga1 Rh1 C31 67.70(16) . . . . ? Cl1 Ga1 Rh1 C31 168.70(16) . . . . ? C1 Ga1 Rh1 C33 -96.6(4) . . . . ? Cl2 Ga1 Rh1 C33 36.3(3) . . . . ? Cl1 Ga1 Rh1 C33 137.3(3) . . . . ? C1 Ga1 Rh1 C34 -26.4(4) . . . . ? Cl2 Ga1 Rh1 C34 106.5(3) . . . . ? Cl1 Ga1 Rh1 C34 -152.5(3) . . . . ? C1 Ga1 Rh1 Ga2 75.3(3) . . . . ? Cl2 Ga1 Rh1 Ga2 -151.82(6) . . . . ? Cl1 Ga1 Rh1 Ga2 -50.83(6) . . . . ? C1 Ga1 Rh1 Ga3 166.9(3) . . . . ? Cl2 Ga1 Rh1 Ga3 -60.18(6) . . . . ? Cl1 Ga1 Rh1 Ga3 40.81(5) . . . . ? _diffrn_measured_fraction_theta_max 0.996 _diffrn_reflns_theta_full 25.09 _diffrn_measured_fraction_theta_full 0.996 _refine_diff_density_max 1.199 _refine_diff_density_min -0.961 _refine_diff_density_rms 0.140 #=================================================END data_2 _database_code_depnum_ccdc_archive 'CCDC 240969' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C30 H45 Cl3 Ga3 Rh' _chemical_formula_weight 824.08 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M P2(1)/n loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' _cell_length_a 11.652(2) _cell_length_b 18.467(4) _cell_length_c 15.991(3) _cell_angle_alpha 90.00 _cell_angle_beta 94.40(3) _cell_angle_gamma 90.00 _cell_volume 3430.8(12) _cell_formula_units_Z 4 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used 2944 _cell_measurement_theta_min 2.5446 _cell_measurement_theta_max 29.0468 _exptl_crystal_description block _exptl_crystal_colour red _exptl_crystal_size_max 0.22 _exptl_crystal_size_mid 0.13 _exptl_crystal_size_min 0.06 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.595 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1656 _exptl_absorpt_coefficient_mu 3.054 _exptl_absorpt_correction_type none _exptl_absorpt_correction_T_min ? _exptl_absorpt_correction_T_max ? _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 213(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'Enhance (Mo) X-ray Sourc' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Xcalibur2,Oxford Diffraction Ltd.' _diffrn_measurement_method 'omega scans' _diffrn_orient_matrix_UB_11 0.0577061007 _diffrn_orient_matrix_UB_12 -0.0125106677 _diffrn_orient_matrix_UB_13 0.0039304604 _diffrn_orient_matrix_UB_21 0.0196740495 _diffrn_orient_matrix_UB_22 0.0354783296 _diffrn_orient_matrix_UB_23 -0.0081243959 _diffrn_orient_matrix_UB_31 0.0032407821 _diffrn_orient_matrix_UB_32 0.0077634446 _diffrn_orient_matrix_UB_33 0.0435615600 _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 23283 _diffrn_reflns_av_R_equivalents 0.0863 _diffrn_reflns_av_sigmaI/netI 0.1113 _diffrn_reflns_limit_h_min -13 _diffrn_reflns_limit_h_max 13 _diffrn_reflns_limit_k_min -21 _diffrn_reflns_limit_k_max 22 _diffrn_reflns_limit_l_min -14 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_theta_min 3.15 _diffrn_reflns_theta_max 25.06 _reflns_number_total 6060 _reflns_number_gt 3495 _reflns_threshold_expression >2sigma(I) _computing_data_collection ; CrysAlis CCD, Oxford Diffraction Ltd., Version 1.170.32 (release 06.06.2003 CrysAlis170 VC++) (compiled Jun 6 2003,13:53:32) ; _computing_cell_refinement ; CrysAlis RED, Oxford Diffraction Ltd., Version 1.170.32 (release 06.06.2003 CrysAlis170 VC++) (compiled Jun 6 2003,13:53:32) ; _computing_data_reduction ; CrysAlis RED, Oxford Diffraction Ltd., Version 1.170.32 (release 06.06.2003 CrysAlis170 VC++) (compiled Jun 6 2003,13:53:32) ; _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics SHELXL-97 _computing_publication_material SHELXL-97 _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0344P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 6060 _refine_ls_number_parameters 390 _refine_ls_number_restraints 120 _refine_ls_R_factor_all 0.0845 _refine_ls_R_factor_gt 0.0453 _refine_ls_wR_factor_ref 0.0999 _refine_ls_wR_factor_gt 0.0919 _refine_ls_goodness_of_fit_ref 0.921 _refine_ls_restrained_S_all 0.942 _refine_ls_shift/su_max 0.155 _refine_ls_shift/su_mean 0.010 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.53862(4) 0.19422(3) 0.81501(3) 0.02622(15) Uani 1 1 d . A . Ga1 Ga 0.53373(7) 0.24253(4) 0.67435(5) 0.0433(2) Uani 1 1 d . . . Ga2 Ga 0.62553(6) 0.09660(4) 0.75069(5) 0.0362(2) Uani 1 1 d . . . Ga3 Ga 0.35075(6) 0.15655(4) 0.77313(5) 0.0389(2) Uani 1 1 d . . . Cl1 Cl 0.46174(19) 0.17101(12) 0.56835(12) 0.0705(7) Uani 1 1 d . . . Cl2 Cl 0.7082(2) 0.26942(14) 0.63283(14) 0.0857(8) Uani 1 1 d . . . Cl3 Cl 0.4322(2) 0.34372(13) 0.65017(16) 0.1067(10) Uani 1 1 d . . . C11 C 0.5181(6) 0.2174(4) 0.9504(4) 0.0397(18) Uani 1 1 d . . . C12 C 0.5092(7) 0.2829(4) 0.9021(4) 0.051(2) Uani 1 1 d . A . C13 C 0.6190(8) 0.2939(4) 0.8706(5) 0.057(2) Uani 1 1 d . . . C14 C 0.6889(6) 0.2337(6) 0.8938(5) 0.060(3) Uani 1 1 d . A . C15 C 0.6260(7) 0.1877(4) 0.9444(5) 0.049(2) Uani 1 1 d . A . C111 C 0.4242(7) 0.1903(6) 1.0044(5) 0.099(4) Uani 1 1 d . A . H11A H 0.4221 0.1383 1.0031 0.148 Uiso 1 1 calc R . . H11B H 0.3510 0.2090 0.9829 0.148 Uiso 1 1 calc R . . H11C H 0.4406 0.2064 1.0612 0.148 Uiso 1 1 calc R . . C121 C 0.4119(9) 0.3366(5) 0.9023(6) 0.121(5) Uani 1 1 d . . . H12A H 0.3496 0.3158 0.9301 0.182 Uiso 1 1 calc R A . H12B H 0.3859 0.3486 0.8456 0.182 Uiso 1 1 calc R . . H12C H 0.4383 0.3797 0.9314 0.182 Uiso 1 1 calc R . . C131 C 0.6547(12) 0.3624(5) 0.8306(6) 0.157(6) Uani 1 1 d . A . H13A H 0.6675 0.3992 0.8727 0.236 Uiso 1 1 calc R . . H13B H 0.5952 0.3778 0.7896 0.236 Uiso 1 1 calc R . . H13C H 0.7245 0.3542 0.8038 0.236 Uiso 1 1 calc R . . C141 C 0.8127(7) 0.2266(7) 0.8786(6) 0.147(6) Uani 1 1 d . . . H14A H 0.8588 0.2498 0.9231 0.220 Uiso 1 1 calc R A . H14B H 0.8264 0.2490 0.8261 0.220 Uiso 1 1 calc R . . H14C H 0.8328 0.1762 0.8766 0.220 Uiso 1 1 calc R . . C151 C 0.6690(11) 0.1221(6) 0.9937(6) 0.143(5) Uani 1 1 d . . . H15A H 0.7005 0.1370 1.0483 0.215 Uiso 1 1 calc R A . H15B H 0.7276 0.0984 0.9647 0.215 Uiso 1 1 calc R . . H15C H 0.6063 0.0892 0.9995 0.215 Uiso 1 1 calc R . . C21 C 0.7625(8) 0.0080(5) 0.7854(5) 0.058(2) Uani 1 1 d . . . C22 C 0.7970(6) 0.0473(5) 0.7189(6) 0.060(2) Uani 1 1 d . . . C23 C 0.7137(6) 0.0403(4) 0.6508(5) 0.046(2) Uani 1 1 d . . . C24 C 0.6268(6) -0.0048(4) 0.6762(5) 0.0444(19) Uani 1 1 d . . . C25 C 0.6570(7) -0.0244(4) 0.7608(5) 0.050(2) Uani 1 1 d . . . C211 C 0.8316(9) -0.0037(6) 0.8660(5) 0.127(5) Uani 1 1 d . . . H21A H 0.8893 -0.0398 0.8586 0.190 Uiso 1 1 calc R . . H21B H 0.7822 -0.0197 0.9076 0.190 Uiso 1 1 calc R . . H21C H 0.8682 0.0409 0.8839 0.190 Uiso 1 1 calc R . . C221 C 0.9083(7) 0.0900(5) 0.7112(7) 0.125(4) Uani 1 1 d . . . H22A H 0.8910 0.1348 0.6825 0.187 Uiso 1 1 calc R . . H22B H 0.9600 0.0620 0.6802 0.187 Uiso 1 1 calc R . . H22C H 0.9438 0.0999 0.7662 0.187 Uiso 1 1 calc R . . C231 C 0.7248(9) 0.0696(5) 0.5620(5) 0.101(4) Uani 1 1 d . . . H23A H 0.7707 0.0369 0.5319 0.152 Uiso 1 1 calc R . . H23B H 0.7610 0.1163 0.5654 0.152 Uiso 1 1 calc R . . H23C H 0.6497 0.0738 0.5333 0.152 Uiso 1 1 calc R . . C241 C 0.5234(7) -0.0336(5) 0.6222(6) 0.093(3) Uani 1 1 d . . . H24A H 0.4972 0.0026 0.5821 0.139 Uiso 1 1 calc R . . H24B H 0.4627 -0.0451 0.6573 0.139 Uiso 1 1 calc R . . H24C H 0.5453 -0.0763 0.5932 0.139 Uiso 1 1 calc R . . C251 C 0.5887(9) -0.0737(5) 0.8120(6) 0.113(4) Uani 1 1 d . . . H25A H 0.6401 -0.1036 0.8467 0.170 Uiso 1 1 calc R . . H25B H 0.5399 -0.1037 0.7754 0.170 Uiso 1 1 calc R . . H25C H 0.5423 -0.0454 0.8468 0.170 Uiso 1 1 calc R . . C31 C 0.1834(6) 0.1503(4) 0.6891(4) 0.034(5) Uani 0.481(9) 1 d PGU A 1 C32 C 0.1575(6) 0.1951(4) 0.7591(5) 0.042(5) Uani 0.481(9) 1 d PGU A 1 C33 C 0.1704(6) 0.1514(4) 0.8340(5) 0.040(5) Uani 0.481(9) 1 d PGU A 1 C34 C 0.2043(6) 0.0796(4) 0.8103(5) 0.035(5) Uani 0.481(9) 1 d PGU A 1 C35 C 0.2123(6) 0.0790(4) 0.7207(5) 0.034(5) Uani 0.481(9) 1 d PGU A 1 C311 C 0.1806(10) 0.1744(7) 0.5973(6) 0.086(7) Uani 0.481(9) 1 d PGU A 1 C321 C 0.1223(10) 0.2750(6) 0.7547(8) 0.100(7) Uani 0.481(9) 1 d PGU A 1 C331 C 0.1514(10) 0.1767(7) 0.9231(6) 0.086(7) Uani 0.481(9) 1 d PGU A 1 C341 C 0.2277(10) 0.0153(6) 0.8697(7) 0.087(7) Uani 0.481(9) 1 d PGU A 1 C351 C 0.2458(10) 0.0138(6) 0.6683(7) 0.090(7) Uani 0.481(9) 1 d PGU A 1 C31' C 0.1727(6) 0.1828(4) 0.7190(5) 0.040(5) Uani 0.519(9) 1 d PGU A 2 C32' C 0.1645(6) 0.1817(4) 0.8083(5) 0.048(5) Uani 0.519(9) 1 d PGU A 2 C33' C 0.1897(6) 0.1093(4) 0.8376(4) 0.039(5) Uani 0.519(9) 1 d PGU A 2 C34' C 0.2134(6) 0.0657(4) 0.7663(5) 0.049(5) Uani 0.519(9) 1 d PGU A 2 C35' C 0.2030(6) 0.1112(4) 0.6931(4) 0.044(5) Uani 0.519(9) 1 d PGU A 2 C312 C 0.1528(10) 0.2487(6) 0.6617(7) 0.103(7) Uani 0.519(9) 1 d PGU A 2 C322 C 0.1344(10) 0.2461(6) 0.8626(7) 0.100(7) Uani 0.519(9) 1 d PGU A 2 C332 C 0.1910(10) 0.0833(6) 0.9284(6) 0.079(6) Uani 0.519(9) 1 d PGU A 2 C342 C 0.2444(10) -0.0148(5) 0.7682(8) 0.091(6) Uani 0.519(9) 1 d PGU A 2 C352 C 0.2208(10) 0.0875(7) 0.6034(6) 0.114(8) Uani 0.519(9) 1 d PGU A 2 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.0273(3) 0.0267(3) 0.0248(3) -0.0015(2) 0.0037(2) -0.0026(3) Ga1 0.0579(6) 0.0395(5) 0.0331(5) 0.0099(4) 0.0068(4) -0.0036(4) Ga2 0.0406(5) 0.0349(4) 0.0331(5) -0.0067(4) 0.0027(4) 0.0069(4) Ga3 0.0305(4) 0.0445(5) 0.0409(5) 0.0020(4) -0.0025(4) -0.0056(4) Cl1 0.0853(16) 0.0847(17) 0.0386(12) -0.0009(11) -0.0139(11) -0.0060(13) Cl2 0.0944(18) 0.105(2) 0.0631(15) -0.0020(14) 0.0373(13) -0.0483(15) Cl3 0.150(3) 0.0611(16) 0.108(2) 0.0318(15) 0.0004(18) 0.0430(17) C11 0.044(5) 0.052(5) 0.022(4) -0.008(4) -0.001(3) -0.014(4) C12 0.072(6) 0.045(5) 0.034(5) -0.020(4) -0.002(4) 0.009(4) C13 0.090(7) 0.045(5) 0.040(5) -0.017(4) 0.022(5) -0.036(5) C14 0.025(4) 0.103(8) 0.053(6) -0.056(6) 0.002(4) -0.016(5) C15 0.056(5) 0.046(5) 0.040(5) -0.027(4) -0.020(4) 0.010(4) C111 0.091(7) 0.172(11) 0.037(5) -0.028(6) 0.036(5) -0.074(7) C121 0.136(9) 0.102(8) 0.117(9) -0.059(7) -0.046(7) 0.087(8) C131 0.307(17) 0.092(8) 0.078(8) -0.023(6) 0.048(9) -0.148(10) C141 0.030(5) 0.266(15) 0.146(10) -0.151(11) 0.019(6) -0.038(7) C151 0.236(14) 0.100(8) 0.078(8) -0.021(6) -0.093(8) 0.090(9) C21 0.067(6) 0.057(6) 0.047(6) -0.008(5) -0.013(5) 0.040(5) C22 0.023(4) 0.064(6) 0.092(7) -0.033(6) 0.002(5) 0.007(4) C23 0.047(5) 0.048(5) 0.046(5) -0.009(4) 0.017(4) 0.009(4) C24 0.049(5) 0.029(4) 0.055(5) -0.013(4) 0.002(4) 0.007(4) C25 0.068(6) 0.036(5) 0.048(5) 0.006(4) 0.026(5) 0.024(4) C211 0.165(11) 0.127(9) 0.077(7) -0.052(7) -0.063(7) 0.110(8) C221 0.039(6) 0.115(9) 0.222(13) -0.077(9) 0.017(7) -0.002(6) C231 0.153(10) 0.099(8) 0.060(6) -0.001(6) 0.061(7) 0.029(7) C241 0.082(7) 0.070(7) 0.121(9) -0.052(6) -0.027(6) 0.009(5) C251 0.162(10) 0.052(6) 0.137(10) 0.032(6) 0.086(8) 0.027(6) C31 0.034(8) 0.034(9) 0.032(8) -0.007(7) 0.000(7) 0.006(7) C32 0.024(8) 0.052(9) 0.050(10) -0.002(8) -0.006(7) 0.014(7) C33 0.032(8) 0.043(10) 0.046(9) 0.004(8) 0.005(7) -0.004(7) C34 0.027(8) 0.035(8) 0.041(9) -0.007(8) -0.006(7) -0.022(7) C35 0.027(8) 0.031(8) 0.043(9) 0.007(8) -0.003(7) -0.013(7) C311 0.071(10) 0.132(12) 0.052(9) 0.025(9) -0.013(8) -0.015(9) C321 0.087(11) 0.062(10) 0.148(13) 0.006(9) -0.015(10) 0.030(8) C331 0.076(10) 0.130(12) 0.058(10) -0.025(9) 0.028(8) -0.015(9) C341 0.078(10) 0.073(10) 0.104(11) 0.059(9) -0.019(9) -0.027(8) C351 0.073(10) 0.083(10) 0.115(12) -0.061(9) 0.000(9) -0.027(8) C31' 0.028(8) 0.051(9) 0.038(9) 0.001(8) -0.010(7) -0.006(7) C32' 0.023(7) 0.063(10) 0.055(10) 0.000(9) -0.015(7) -0.006(7) C33' 0.026(8) 0.043(9) 0.044(8) 0.002(8) -0.014(7) -0.017(7) C34' 0.042(8) 0.058(9) 0.046(10) 0.007(8) 0.003(8) -0.009(7) C35' 0.025(8) 0.058(10) 0.049(9) -0.007(8) 0.002(7) -0.007(7) C312 0.080(10) 0.114(11) 0.112(11) 0.072(9) -0.021(9) 0.022(9) C322 0.066(9) 0.113(11) 0.121(12) -0.058(9) 0.012(9) 0.027(8) C332 0.072(9) 0.114(11) 0.051(9) 0.032(8) 0.007(7) -0.044(8) C342 0.085(10) 0.049(9) 0.140(12) 0.002(9) 0.008(9) -0.008(8) C352 0.124(12) 0.148(13) 0.069(10) -0.041(9) 0.002(9) -0.038(10) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 C12 2.193(7) . ? Rh1 C14 2.202(7) . ? Rh1 C13 2.220(7) . ? Rh1 C11 2.238(6) . ? Rh1 C15 2.238(7) . ? Rh1 Ga2 2.3438(9) . ? Rh1 Ga3 2.3452(10) . ? Rh1 Ga1 2.4164(10) . ? Ga1 Cl3 2.230(2) . ? Ga1 Cl2 2.242(2) . ? Ga1 Cl1 2.259(2) . ? Ga2 C23 2.223(7) . ? Ga2 C24 2.221(7) . ? Ga2 C25 2.267(7) . ? Ga2 C22 2.288(7) . ? Ga2 C21 2.323(7) . ? Ga3 C35' 2.229(7) . ? Ga3 C31' 2.239(7) . ? Ga3 C35 2.269(7) . ? Ga3 C31 2.284(7) . ? Ga3 C34' 2.315(7) . ? Ga3 C32' 2.330(7) . ? Ga3 C34 2.332(7) . ? Ga3 C32 2.356(7) . ? Ga3 C33' 2.375(7) . ? Ga3 C33 2.385(7) . ? C11 C15 1.383(9) . ? C11 C12 1.435(9) . ? C11 C111 1.529(9) . ? C12 C13 1.425(10) . ? C12 C121 1.507(10) . ? C13 C14 1.410(11) . ? C13 C131 1.491(11) . ? C14 C15 1.417(10) . ? C14 C141 1.486(10) . ? C15 C151 1.509(11) . ? C21 C22 1.373(11) . ? C21 C25 1.396(11) . ? C21 C211 1.483(10) . ? C22 C23 1.407(10) . ? C22 C221 1.531(11) . ? C23 C24 1.395(9) . ? C23 C231 1.534(10) . ? C24 C25 1.419(10) . ? C24 C241 1.522(9) . ? C25 C251 1.494(10) . ? C31 C32 1.442(4) . ? C31 C35 1.442(4) . ? C31 C311 1.533(4) . ? C32 C33 1.442(4) . ? C32 C321 1.533(4) . ? C33 C34 1.442(4) . ? C33 C331 1.533(4) . ? C34 C35 1.442(4) . ? C34 C341 1.533(4) . ? C35 C351 1.533(4) . ? C31' C32' 1.439(4) . ? C31' C35' 1.439(4) . ? C31' C312 1.529(4) . ? C32' C33' 1.439(4) . ? C32' C322 1.529(4) . ? C33' C34' 1.439(4) . ? C33' C332 1.529(4) . ? C34' C35' 1.439(4) . ? C34' C342 1.529(4) . ? C35' C352 1.529(4) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C12 Rh1 C14 63.0(3) . . ? C12 Rh1 C13 37.7(3) . . ? C14 Rh1 C13 37.2(3) . . ? C12 Rh1 C11 37.8(2) . . ? C14 Rh1 C11 61.5(3) . . ? C13 Rh1 C11 61.8(2) . . ? C12 Rh1 C15 62.3(3) . . ? C14 Rh1 C15 37.2(3) . . ? C13 Rh1 C15 61.7(3) . . ? C11 Rh1 C15 36.0(2) . . ? C12 Rh1 Ga2 161.2(2) . . ? C14 Rh1 Ga2 98.9(2) . . ? C13 Rh1 Ga2 129.1(3) . . ? C11 Rh1 Ga2 130.8(2) . . ? C15 Rh1 Ga2 100.54(18) . . ? C12 Rh1 Ga3 102.4(2) . . ? C14 Rh1 Ga3 161.1(2) . . ? C13 Rh1 Ga3 135.8(3) . . ? C11 Rh1 Ga3 99.57(17) . . ? C15 Rh1 Ga3 126.6(2) . . ? Ga2 Rh1 Ga3 94.12(3) . . ? C12 Rh1 Ga1 108.8(2) . . ? C14 Rh1 Ga1 111.8(3) . . ? C13 Rh1 Ga1 92.6(2) . . ? C11 Rh1 Ga1 146.5(2) . . ? C15 Rh1 Ga1 149.0(2) . . ? Ga2 Rh1 Ga1 81.70(3) . . ? Ga3 Rh1 Ga1 83.62(4) . . ? Cl3 Ga1 Cl2 104.13(11) . . ? Cl3 Ga1 Cl1 101.44(10) . . ? Cl2 Ga1 Cl1 101.55(9) . . ? Cl3 Ga1 Rh1 116.43(8) . . ? Cl2 Ga1 Rh1 113.59(8) . . ? Cl1 Ga1 Rh1 117.61(7) . . ? C23 Ga2 C24 36.6(2) . . ? C23 Ga2 C25 60.6(3) . . ? C24 Ga2 C25 36.8(2) . . ? C23 Ga2 C22 36.3(3) . . ? C24 Ga2 C22 60.2(3) . . ? C25 Ga2 C22 59.0(3) . . ? C23 Ga2 C21 59.7(3) . . ? C24 Ga2 C21 60.1(3) . . ? C25 Ga2 C21 35.4(3) . . ? C22 Ga2 C21 34.6(3) . . ? C23 Ga2 Rh1 156.1(2) . . ? C24 Ga2 Rh1 154.83(19) . . ? C25 Ga2 Rh1 143.07(19) . . ? C22 Ga2 Rh1 144.9(2) . . ? C21 Ga2 Rh1 138.5(2) . . ? C35' Ga3 C31' 37.57(14) . . ? C35' Ga3 C35 19.0(2) . . ? C31' Ga3 C35 51.9(2) . . ? C35' Ga3 C31 19.3(2) . . ? C31' Ga3 C31 19.9(2) . . ? C35 Ga3 C31 36.92(13) . . ? C35' Ga3 C34' 36.86(13) . . ? C31' Ga3 C34' 61.5(2) . . ? C35 Ga3 C34' 19.3(2) . . ? C31 Ga3 C34' 51.7(2) . . ? C35' Ga3 C32' 61.4(2) . . ? C31' Ga3 C32' 36.64(13) . . ? C35 Ga3 C32' 64.3(2) . . ? C31 Ga3 C32' 51.9(2) . . ? C34' Ga3 C32' 60.16(19) . . ? C35' Ga3 C34 50.9(2) . . ? C31' Ga3 C34 63.7(2) . . ? C35 Ga3 C34 36.49(13) . . ? C31 Ga3 C34 60.7(2) . . ? C34' Ga3 C34 18.9(2) . . ? C32' Ga3 C34 49.2(2) . . ? C35' Ga3 Rh1 159.8(2) . . ? C31' Ga3 Rh1 149.7(2) . . ? C35 Ga3 Rh1 156.09(19) . . ? C31 Ga3 Rh1 156.78(19) . . ? C34' Ga3 Rh1 148.77(18) . . ? C32' Ga3 Rh1 137.58(18) . . ? C34 Ga3 Rh1 142.49(18) . . ? C35' Ga3 C32 50.8(2) . . ? C31' Ga3 C32 17.7(2) . . ? C35 Ga3 C32 60.6(2) . . ? C31 Ga3 C32 36.16(13) . . ? C34' Ga3 C32 64.0(2) . . ? C32' Ga3 C32 20.2(2) . . ? C34 Ga3 C32 59.7(2) . . ? Rh1 Ga3 C32 143.34(19) . . ? C35' Ga3 C33' 60.6(2) . . ? C31' Ga3 C33' 60.5(2) . . ? C35 Ga3 C33' 50.6(2) . . ? C31 Ga3 C33' 64.5(2) . . ? C34' Ga3 C33' 35.70(12) . . ? C32' Ga3 C33' 35.60(12) . . ? C34 Ga3 C33' 17.8(2) . . ? Rh1 Ga3 C33' 137.42(17) . . ? C32 Ga3 C33' 51.0(2) . . ? C35' Ga3 C33 63.5(2) . . ? C31' Ga3 C33 49.2(2) . . ? C35 Ga3 C33 60.1(2) . . ? C31 Ga3 C33 59.9(2) . . ? C34' Ga3 C33 50.4(2) . . ? C32' Ga3 C33 16.9(2) . . ? C34 Ga3 C33 35.58(13) . . ? Rh1 Ga3 C33 136.71(18) . . ? C32 Ga3 C33 35.41(13) . . ? C33' Ga3 C33 19.6(2) . . ? C15 C11 C12 109.0(7) . . ? C15 C11 C111 127.1(8) . . ? C12 C11 C111 123.8(8) . . ? C15 C11 Rh1 72.0(4) . . ? C12 C11 Rh1 69.4(4) . . ? C111 C11 Rh1 128.2(5) . . ? C13 C12 C11 106.3(7) . . ? C13 C12 C121 127.1(9) . . ? C11 C12 C121 125.2(8) . . ? C13 C12 Rh1 72.2(4) . . ? C11 C12 Rh1 72.8(4) . . ? C121 C12 Rh1 130.3(5) . . ? C14 C13 C12 108.1(7) . . ? C14 C13 C131 127.3(10) . . ? C12 C13 C131 124.1(10) . . ? C14 C13 Rh1 70.7(4) . . ? C12 C13 Rh1 70.1(4) . . ? C131 C13 Rh1 130.9(6) . . ? C15 C14 C13 108.0(6) . . ? C15 C14 C141 126.2(10) . . ? C13 C14 C141 125.1(10) . . ? C15 C14 Rh1 72.8(4) . . ? C13 C14 Rh1 72.1(4) . . ? C141 C14 Rh1 128.0(5) . . ? C11 C15 C14 108.4(7) . . ? C11 C15 C151 123.3(9) . . ? C14 C15 C151 127.9(9) . . ? C11 C15 Rh1 72.0(4) . . ? C14 C15 Rh1 70.0(4) . . ? C151 C15 Rh1 129.5(5) . . ? C22 C21 C25 108.2(7) . . ? C22 C21 C211 125.3(10) . . ? C25 C21 C211 126.2(10) . . ? C22 C21 Ga2 71.3(4) . . ? C25 C21 Ga2 70.1(4) . . ? C211 C21 Ga2 128.9(5) . . ? C21 C22 C23 108.9(7) . . ? C21 C22 C221 129.4(9) . . ? C23 C22 C221 121.6(9) . . ? C21 C22 Ga2 74.1(4) . . ? C23 C22 Ga2 69.3(4) . . ? C221 C22 Ga2 124.9(6) . . ? C24 C23 C22 107.7(7) . . ? C24 C23 C231 126.4(8) . . ? C22 C23 C231 125.5(8) . . ? C24 C23 Ga2 71.6(4) . . ? C22 C23 Ga2 74.4(4) . . ? C231 C23 Ga2 125.2(5) . . ? C23 C24 C25 107.2(7) . . ? C23 C24 C241 127.1(8) . . ? C25 C24 C241 125.5(8) . . ? C23 C24 Ga2 71.8(4) . . ? C25 C24 Ga2 73.4(4) . . ? C241 C24 Ga2 124.1(5) . . ? C21 C25 C24 108.0(7) . . ? C21 C25 C251 126.9(9) . . ? C24 C25 C251 125.0(9) . . ? C21 C25 Ga2 74.5(4) . . ? C24 C25 Ga2 69.8(4) . . ? C251 C25 Ga2 123.3(5) . . ? C32 C31 C35 108.0 . . ? C32 C31 C311 126.0 . . ? C35 C31 C311 126.0 . . ? C32 C31 Ga3 74.6(2) . . ? C35 C31 Ga3 71.0(2) . . ? C311 C31 Ga3 120.2(2) . . ? C31 C32 C33 108.0 . . ? C31 C32 C321 126.0 . . ? C33 C32 C321 126.0 . . ? C31 C32 Ga3 69.2(2) . . ? C33 C32 Ga3 73.4(2) . . ? C321 C32 Ga3 123.0(2) . . ? C34 C33 C32 108.0 . . ? C34 C33 C331 126.0 . . ? C32 C33 C331 126.0 . . ? C34 C33 Ga3 70.2(2) . . ? C32 C33 Ga3 71.2(2) . . ? C331 C33 Ga3 124.2(2) . . ? C35 C34 C33 108.0 . . ? C35 C34 C341 126.0 . . ? C33 C34 C341 126.0 . . ? C35 C34 Ga3 69.4(2) . . ? C33 C34 Ga3 74.2(2) . . ? C341 C34 Ga3 122.1(2) . . ? C34 C35 C31 108.0 . . ? C34 C35 C351 126.0 . . ? C31 C35 C351 126.0 . . ? C34 C35 Ga3 74.1(2) . . ? C31 C35 Ga3 72.1(2) . . ? C351 C35 Ga3 119.6(2) . . ? C32' C31' C35' 108.0 . . ? C32' C31' C312 126.0 . . ? C35' C31' C312 126.0 . . ? C32' C31' Ga3 75.1(2) . . ? C35' C31' Ga3 70.8(2) . . ? C312 C31' Ga3 119.8(2) . . ? C31' C32' C33' 108.0 . . ? C31' C32' C322 126.0 . . ? C33' C32' C322 126.0 . . ? C31' C32' Ga3 68.2(2) . . ? C33' C32' Ga3 73.9(2) . . ? C322 C32' Ga3 123.4(2) . . ? C34' C33' C32' 108.0 . . ? C34' C33' C332 126.0 . . ? C32' C33' C332 126.0 . . ? C34' C33' Ga3 69.9(2) . . ? C32' C33' Ga3 70.5(2) . . ? C332 C33' Ga3 125.3(2) . . ? C35' C34' C33' 108.0 . . ? C35' C34' C342 126.0 . . ? C33' C34' C342 126.0 . . ? C35' C34' Ga3 68.3(2) . . ? C33' C34' Ga3 74.4(2) . . ? C342 C34' Ga3 122.8(2) . . ? C34' C35' C31' 108.0 . . ? C34' C35' C352 126.0 . . ? C31' C35' C352 126.0 . . ? C34' C35' Ga3 74.8(2) . . ? C31' C35' Ga3 71.6(2) . . ? C352 C35' Ga3 119.4(2) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C12 Rh1 Ga1 Cl3 -25.5(2) . . . . ? C14 Rh1 Ga1 Cl3 -93.1(3) . . . . ? C13 Rh1 Ga1 Cl3 -60.3(3) . . . . ? C11 Rh1 Ga1 Cl3 -22.2(3) . . . . ? C15 Rh1 Ga1 Cl3 -92.7(4) . . . . ? Ga2 Rh1 Ga1 Cl3 170.63(10) . . . . ? Ga3 Rh1 Ga1 Cl3 75.50(10) . . . . ? C12 Rh1 Ga1 Cl2 95.5(2) . . . . ? C14 Rh1 Ga1 Cl2 27.9(3) . . . . ? C13 Rh1 Ga1 Cl2 60.7(3) . . . . ? C11 Rh1 Ga1 Cl2 98.8(3) . . . . ? C15 Rh1 Ga1 Cl2 28.3(4) . . . . ? Ga2 Rh1 Ga1 Cl2 -68.40(8) . . . . ? Ga3 Rh1 Ga1 Cl2 -163.52(8) . . . . ? C12 Rh1 Ga1 Cl1 -146.1(2) . . . . ? C14 Rh1 Ga1 Cl1 146.3(3) . . . . ? C13 Rh1 Ga1 Cl1 179.1(3) . . . . ? C11 Rh1 Ga1 Cl1 -142.9(3) . . . . ? C15 Rh1 Ga1 Cl1 146.6(4) . . . . ? Ga2 Rh1 Ga1 Cl1 49.96(8) . . . . ? Ga3 Rh1 Ga1 Cl1 -45.16(8) . . . . ? C12 Rh1 Ga2 C23 -109.4(9) . . . . ? C14 Rh1 Ga2 C23 -94.8(6) . . . . ? C13 Rh1 Ga2 C23 -70.6(6) . . . . ? C11 Rh1 Ga2 C23 -154.6(6) . . . . ? C15 Rh1 Ga2 C23 -132.6(6) . . . . ? Ga3 Rh1 Ga2 C23 99.0(5) . . . . ? Ga1 Rh1 Ga2 C23 16.1(5) . . . . ? C12 Rh1 Ga2 C24 152.3(8) . . . . ? C14 Rh1 Ga2 C24 166.9(6) . . . . ? C13 Rh1 Ga2 C24 -168.9(6) . . . . ? C11 Rh1 Ga2 C24 107.1(5) . . . . ? C15 Rh1 Ga2 C24 129.1(6) . . . . ? Ga3 Rh1 Ga2 C24 0.7(5) . . . . ? Ga1 Rh1 Ga2 C24 -82.2(5) . . . . ? C12 Rh1 Ga2 C25 79.8(8) . . . . ? C14 Rh1 Ga2 C25 94.4(5) . . . . ? C13 Rh1 Ga2 C25 118.6(5) . . . . ? C11 Rh1 Ga2 C25 34.6(5) . . . . ? C15 Rh1 Ga2 C25 56.6(5) . . . . ? Ga3 Rh1 Ga2 C25 -71.8(4) . . . . ? Ga1 Rh1 Ga2 C25 -154.7(4) . . . . ? C12 Rh1 Ga2 C22 -33.8(8) . . . . ? C14 Rh1 Ga2 C22 -19.2(5) . . . . ? C13 Rh1 Ga2 C22 5.0(5) . . . . ? C11 Rh1 Ga2 C22 -79.0(5) . . . . ? C15 Rh1 Ga2 C22 -57.0(5) . . . . ? Ga3 Rh1 Ga2 C22 174.6(5) . . . . ? Ga1 Rh1 Ga2 C22 91.7(5) . . . . ? C12 Rh1 Ga2 C21 22.7(8) . . . . ? C14 Rh1 Ga2 C21 37.3(5) . . . . ? C13 Rh1 Ga2 C21 61.6(5) . . . . ? C11 Rh1 Ga2 C21 -22.5(5) . . . . ? C15 Rh1 Ga2 C21 -0.4(5) . . . . ? Ga3 Rh1 Ga2 C21 -128.9(4) . . . . ? Ga1 Rh1 Ga2 C21 148.2(4) . . . . ? C12 Rh1 Ga3 C35' 150.2(7) . . . . ? C14 Rh1 Ga3 C35' -172.2(11) . . . . ? C13 Rh1 Ga3 C35' 129.5(7) . . . . ? C11 Rh1 Ga3 C35' -171.5(6) . . . . ? C15 Rh1 Ga3 C35' -145.3(7) . . . . ? Ga2 Rh1 Ga3 C35' -38.9(6) . . . . ? Ga1 Rh1 Ga3 C35' 42.3(6) . . . . ? C12 Rh1 Ga3 C31' 54.4(5) . . . . ? C14 Rh1 Ga3 C31' 92.0(10) . . . . ? C13 Rh1 Ga3 C31' 33.7(5) . . . . ? C11 Rh1 Ga3 C31' 92.8(5) . . . . ? C15 Rh1 Ga3 C31' 119.0(5) . . . . ? Ga2 Rh1 Ga3 C31' -134.6(4) . . . . ? Ga1 Rh1 Ga3 C31' -53.5(4) . . . . ? C12 Rh1 Ga3 C35 -158.5(5) . . . . ? C14 Rh1 Ga3 C35 -120.9(10) . . . . ? C13 Rh1 Ga3 C35 -179.1(6) . . . . ? C11 Rh1 Ga3 C35 -120.1(5) . . . . ? C15 Rh1 Ga3 C35 -93.9(5) . . . . ? Ga2 Rh1 Ga3 C35 12.5(5) . . . . ? Ga1 Rh1 Ga3 C35 93.7(5) . . . . ? C12 Rh1 Ga3 C31 96.8(6) . . . . ? C14 Rh1 Ga3 C31 134.4(10) . . . . ? C13 Rh1 Ga3 C31 76.1(6) . . . . ? C11 Rh1 Ga3 C31 135.2(5) . . . . ? C15 Rh1 Ga3 C31 161.4(6) . . . . ? Ga2 Rh1 Ga3 C31 -92.2(5) . . . . ? Ga1 Rh1 Ga3 C31 -11.1(5) . . . . ? C12 Rh1 Ga3 C34' -119.0(4) . . . . ? C14 Rh1 Ga3 C34' -81.4(9) . . . . ? C13 Rh1 Ga3 C34' -139.7(5) . . . . ? C11 Rh1 Ga3 C34' -80.7(4) . . . . ? C15 Rh1 Ga3 C34' -54.4(4) . . . . ? Ga2 Rh1 Ga3 C34' 51.9(4) . . . . ? Ga1 Rh1 Ga3 C34' 133.1(4) . . . . ? C12 Rh1 Ga3 C32' -6.6(4) . . . . ? C14 Rh1 Ga3 C32' 31.0(9) . . . . ? C13 Rh1 Ga3 C32' -27.2(4) . . . . ? C11 Rh1 Ga3 C32' 31.8(3) . . . . ? C15 Rh1 Ga3 C32' 58.0(4) . . . . ? Ga2 Rh1 Ga3 C32' 164.4(3) . . . . ? Ga1 Rh1 Ga3 C32' -114.5(3) . . . . ? C12 Rh1 Ga3 C34 -87.1(4) . . . . ? C14 Rh1 Ga3 C34 -49.5(9) . . . . ? C13 Rh1 Ga3 C34 -107.7(4) . . . . ? C11 Rh1 Ga3 C34 -48.7(4) . . . . ? C15 Rh1 Ga3 C34 -22.5(4) . . . . ? Ga2 Rh1 Ga3 C34 83.9(3) . . . . ? Ga1 Rh1 Ga3 C34 165.0(3) . . . . ? C12 Rh1 Ga3 C32 24.1(4) . . . . ? C14 Rh1 Ga3 C32 61.8(9) . . . . ? C13 Rh1 Ga3 C32 3.5(4) . . . . ? C11 Rh1 Ga3 C32 62.5(4) . . . . ? C15 Rh1 Ga3 C32 88.7(4) . . . . ? Ga2 Rh1 Ga3 C32 -164.9(3) . . . . ? Ga1 Rh1 Ga3 C32 -83.7(3) . . . . ? C12 Rh1 Ga3 C33' -60.4(4) . . . . ? C14 Rh1 Ga3 C33' -22.8(9) . . . . ? C13 Rh1 Ga3 C33' -81.0(4) . . . . ? C11 Rh1 Ga3 C33' -22.0(3) . . . . ? C15 Rh1 Ga3 C33' 4.2(4) . . . . ? Ga2 Rh1 Ga3 C33' 110.6(3) . . . . ? Ga1 Rh1 Ga3 C33' -168.2(3) . . . . ? C12 Rh1 Ga3 C33 -31.5(4) . . . . ? C14 Rh1 Ga3 C33 6.1(9) . . . . ? C13 Rh1 Ga3 C33 -52.1(4) . . . . ? C11 Rh1 Ga3 C33 6.9(3) . . . . ? C15 Rh1 Ga3 C33 33.1(4) . . . . ? Ga2 Rh1 Ga3 C33 139.5(3) . . . . ? Ga1 Rh1 Ga3 C33 -139.4(3) . . . . ? C12 Rh1 C11 C15 -119.2(6) . . . . ? C14 Rh1 C11 C15 -37.4(5) . . . . ? C13 Rh1 C11 C15 -79.9(5) . . . . ? Ga2 Rh1 C11 C15 38.9(5) . . . . ? Ga3 Rh1 C11 C15 142.9(4) . . . . ? Ga1 Rh1 C11 C15 -124.2(5) . . . . ? C14 Rh1 C11 C12 81.8(5) . . . . ? C13 Rh1 C11 C12 39.3(5) . . . . ? C15 Rh1 C11 C12 119.2(6) . . . . ? Ga2 Rh1 C11 C12 158.1(4) . . . . ? Ga3 Rh1 C11 C12 -97.9(4) . . . . ? Ga1 Rh1 C11 C12 -5.1(6) . . . . ? C12 Rh1 C11 C111 117.4(9) . . . . ? C14 Rh1 C11 C111 -160.9(9) . . . . ? C13 Rh1 C11 C111 156.6(9) . . . . ? C15 Rh1 C11 C111 -123.5(10) . . . . ? Ga2 Rh1 C11 C111 -84.6(8) . . . . ? Ga3 Rh1 C11 C111 19.4(8) . . . . ? Ga1 Rh1 C11 C111 112.3(7) . . . . ? C15 C11 C12 C13 -3.4(8) . . . . ? C111 C11 C12 C13 172.2(6) . . . . ? Rh1 C11 C12 C13 -64.9(5) . . . . ? C15 C11 C12 C121 -170.9(7) . . . . ? C111 C11 C12 C121 4.8(11) . . . . ? Rh1 C11 C12 C121 127.7(8) . . . . ? C15 C11 C12 Rh1 61.4(5) . . . . ? C111 C11 C12 Rh1 -122.9(6) . . . . ? C14 Rh1 C12 C13 36.6(5) . . . . ? C11 Rh1 C12 C13 114.1(6) . . . . ? C15 Rh1 C12 C13 78.7(5) . . . . ? Ga2 Rh1 C12 C13 52.8(9) . . . . ? Ga3 Rh1 C12 C13 -156.2(5) . . . . ? Ga1 Rh1 C12 C13 -68.8(5) . . . . ? C14 Rh1 C12 C11 -77.5(5) . . . . ? C13 Rh1 C12 C11 -114.1(6) . . . . ? C15 Rh1 C12 C11 -35.4(4) . . . . ? Ga2 Rh1 C12 C11 -61.3(9) . . . . ? Ga3 Rh1 C12 C11 89.6(4) . . . . ? Ga1 Rh1 C12 C11 177.0(3) . . . . ? C14 Rh1 C12 C121 160.5(10) . . . . ? C13 Rh1 C12 C121 123.9(11) . . . . ? C11 Rh1 C12 C121 -122.0(11) . . . . ? C15 Rh1 C12 C121 -157.4(10) . . . . ? Ga2 Rh1 C12 C121 176.7(6) . . . . ? Ga3 Rh1 C12 C121 -32.3(9) . . . . ? Ga1 Rh1 C12 C121 55.1(9) . . . . ? C11 C12 C13 C14 4.5(8) . . . . ? C121 C12 C13 C14 171.7(7) . . . . ? Rh1 C12 C13 C14 -60.8(5) . . . . ? C11 C12 C13 C131 -168.1(7) . . . . ? C121 C12 C13 C131 -0.9(12) . . . . ? Rh1 C12 C13 C131 126.6(8) . . . . ? C11 C12 C13 Rh1 65.3(5) . . . . ? C121 C12 C13 Rh1 -127.5(8) . . . . ? C12 Rh1 C13 C14 118.5(7) . . . . ? C11 Rh1 C13 C14 79.1(5) . . . . ? C15 Rh1 C13 C14 38.1(4) . . . . ? Ga2 Rh1 C13 C14 -42.2(5) . . . . ? Ga3 Rh1 C13 C14 152.8(4) . . . . ? Ga1 Rh1 C13 C14 -123.6(5) . . . . ? C14 Rh1 C13 C12 -118.5(7) . . . . ? C11 Rh1 C13 C12 -39.4(4) . . . . ? C15 Rh1 C13 C12 -80.4(5) . . . . ? Ga2 Rh1 C13 C12 -160.7(4) . . . . ? Ga3 Rh1 C13 C12 34.3(6) . . . . ? Ga1 Rh1 C13 C12 117.9(5) . . . . ? C12 Rh1 C13 C131 -118.4(13) . . . . ? C14 Rh1 C13 C131 123.1(13) . . . . ? C11 Rh1 C13 C131 -157.8(12) . . . . ? C15 Rh1 C13 C131 161.2(12) . . . . ? Ga2 Rh1 C13 C131 80.9(11) . . . . ? Ga3 Rh1 C13 C131 -84.1(11) . . . . ? Ga1 Rh1 C13 C131 -0.5(11) . . . . ? C12 C13 C14 C15 -4.0(8) . . . . ? C131 C13 C14 C15 168.3(7) . . . . ? Rh1 C13 C14 C15 -64.4(5) . . . . ? C12 C13 C14 C141 -175.2(7) . . . . ? C131 C13 C14 C141 -2.9(12) . . . . ? Rh1 C13 C14 C141 124.4(7) . . . . ? C12 C13 C14 Rh1 60.4(5) . . . . ? C131 C13 C14 Rh1 -127.2(8) . . . . ? C12 Rh1 C14 C15 79.0(5) . . . . ? C13 Rh1 C14 C15 116.1(6) . . . . ? C11 Rh1 C14 C15 36.1(4) . . . . ? Ga2 Rh1 C14 C15 -95.8(4) . . . . ? Ga3 Rh1 C14 C15 37.0(12) . . . . ? Ga1 Rh1 C14 C15 179.7(4) . . . . ? C12 Rh1 C14 C13 -37.1(4) . . . . ? C11 Rh1 C14 C13 -79.9(5) . . . . ? C15 Rh1 C14 C13 -116.1(6) . . . . ? Ga2 Rh1 C14 C13 148.1(4) . . . . ? Ga3 Rh1 C14 C13 -79.1(11) . . . . ? Ga1 Rh1 C14 C13 63.6(5) . . . . ? C12 Rh1 C14 C141 -158.1(12) . . . . ? C13 Rh1 C14 C141 -121.0(13) . . . . ? C11 Rh1 C14 C141 159.0(12) . . . . ? C15 Rh1 C14 C141 122.9(13) . . . . ? Ga2 Rh1 C14 C141 27.1(11) . . . . ? Ga3 Rh1 C14 C141 159.9(7) . . . . ? Ga1 Rh1 C14 C141 -57.4(11) . . . . ? C12 C11 C15 C14 1.0(8) . . . . ? C111 C11 C15 C14 -174.4(6) . . . . ? Rh1 C11 C15 C14 60.9(5) . . . . ? C12 C11 C15 C151 174.3(7) . . . . ? C111 C11 C15 C151 -1.2(11) . . . . ? Rh1 C11 C15 C151 -125.9(7) . . . . ? C12 C11 C15 Rh1 -59.8(5) . . . . ? C111 C11 C15 Rh1 124.7(7) . . . . ? C13 C14 C15 C11 1.8(8) . . . . ? C141 C14 C15 C11 172.9(7) . . . . ? Rh1 C14 C15 C11 -62.1(5) . . . . ? C13 C14 C15 C151 -171.0(7) . . . . ? C141 C14 C15 C151 0.1(12) . . . . ? Rh1 C14 C15 C151 125.0(7) . . . . ? C13 C14 C15 Rh1 64.0(5) . . . . ? C141 C14 C15 Rh1 -124.9(7) . . . . ? C12 Rh1 C15 C11 37.1(4) . . . . ? C14 Rh1 C15 C11 118.1(6) . . . . ? C13 Rh1 C15 C11 80.0(5) . . . . ? Ga2 Rh1 C15 C11 -151.1(4) . . . . ? Ga3 Rh1 C15 C11 -47.8(5) . . . . ? Ga1 Rh1 C15 C11 117.5(5) . . . . ? C12 Rh1 C15 C14 -80.9(5) . . . . ? C13 Rh1 C15 C14 -38.0(4) . . . . ? C11 Rh1 C15 C14 -118.1(6) . . . . ? Ga2 Rh1 C15 C14 90.8(5) . . . . ? Ga3 Rh1 C15 C14 -165.9(4) . . . . ? Ga1 Rh1 C15 C14 -0.6(7) . . . . ? C12 Rh1 C15 C151 155.9(10) . . . . ? C14 Rh1 C15 C151 -123.2(11) . . . . ? C13 Rh1 C15 C151 -161.2(11) . . . . ? C11 Rh1 C15 C151 118.7(11) . . . . ? Ga2 Rh1 C15 C151 -32.3(9) . . . . ? Ga3 Rh1 C15 C151 70.9(10) . . . . ? Ga1 Rh1 C15 C151 -123.7(9) . . . . ? C23 Ga2 C21 C22 37.3(4) . . . . ? C24 Ga2 C21 C22 79.9(5) . . . . ? C25 Ga2 C21 C22 118.2(7) . . . . ? Rh1 Ga2 C21 C22 -122.3(4) . . . . ? C23 Ga2 C21 C25 -80.9(5) . . . . ? C24 Ga2 C21 C25 -38.3(4) . . . . ? C22 Ga2 C21 C25 -118.2(7) . . . . ? Rh1 Ga2 C21 C25 119.5(4) . . . . ? C23 Ga2 C21 C211 158.1(11) . . . . ? C24 Ga2 C21 C211 -159.3(11) . . . . ? C25 Ga2 C21 C211 -121.0(12) . . . . ? C22 Ga2 C21 C211 120.8(13) . . . . ? Rh1 Ga2 C21 C211 -1.6(12) . . . . ? C25 C21 C22 C23 -0.2(9) . . . . ? C211 C21 C22 C23 174.2(7) . . . . ? Ga2 C21 C22 C23 -60.9(5) . . . . ? C25 C21 C22 C221 -176.8(7) . . . . ? C211 C21 C22 C221 -2.5(13) . . . . ? Ga2 C21 C22 C221 122.4(8) . . . . ? C25 C21 C22 Ga2 60.7(5) . . . . ? C211 C21 C22 Ga2 -124.9(8) . . . . ? C23 Ga2 C22 C21 -117.9(7) . . . . ? C24 Ga2 C22 C21 -79.5(5) . . . . ? C25 Ga2 C22 C21 -36.5(5) . . . . ? Rh1 Ga2 C22 C21 103.5(5) . . . . ? C24 Ga2 C22 C23 38.5(4) . . . . ? C25 Ga2 C22 C23 81.4(5) . . . . ? C21 Ga2 C22 C23 117.9(7) . . . . ? Rh1 Ga2 C22 C23 -138.6(4) . . . . ? C23 Ga2 C22 C221 114.8(11) . . . . ? C24 Ga2 C22 C221 153.3(10) . . . . ? C25 Ga2 C22 C221 -163.8(10) . . . . ? C21 Ga2 C22 C221 -127.3(11) . . . . ? Rh1 Ga2 C22 C221 -23.8(12) . . . . ? C21 C22 C23 C24 -0.4(8) . . . . ? C221 C22 C23 C24 176.5(7) . . . . ? Ga2 C22 C23 C24 -64.4(5) . . . . ? C21 C22 C23 C231 -173.7(7) . . . . ? C221 C22 C23 C231 3.3(11) . . . . ? Ga2 C22 C23 C231 122.4(7) . . . . ? C21 C22 C23 Ga2 63.9(5) . . . . ? C221 C22 C23 Ga2 -119.1(7) . . . . ? C25 Ga2 C23 C24 38.6(4) . . . . ? C22 Ga2 C23 C24 115.2(7) . . . . ? C21 Ga2 C23 C24 79.6(5) . . . . ? Rh1 Ga2 C23 C24 -135.1(5) . . . . ? C24 Ga2 C23 C22 -115.2(7) . . . . ? C25 Ga2 C23 C22 -76.6(5) . . . . ? C21 Ga2 C23 C22 -35.6(5) . . . . ? Rh1 Ga2 C23 C22 109.7(6) . . . . ? C24 Ga2 C23 C231 122.1(9) . . . . ? C25 Ga2 C23 C231 160.7(8) . . . . ? C22 Ga2 C23 C231 -122.7(10) . . . . ? C21 Ga2 C23 C231 -158.3(9) . . . . ? Rh1 Ga2 C23 C231 -13.0(11) . . . . ? C22 C23 C24 C25 0.9(8) . . . . ? C231 C23 C24 C25 174.1(7) . . . . ? Ga2 C23 C24 C25 -65.3(5) . . . . ? C22 C23 C24 C241 -174.4(7) . . . . ? C231 C23 C24 C241 -1.2(12) . . . . ? Ga2 C23 C24 C241 119.4(7) . . . . ? C22 C23 C24 Ga2 66.2(5) . . . . ? C231 C23 C24 Ga2 -120.6(7) . . . . ? C25 Ga2 C24 C23 -115.1(6) . . . . ? C22 Ga2 C24 C23 -38.1(5) . . . . ? C21 Ga2 C24 C23 -78.3(5) . . . . ? Rh1 Ga2 C24 C23 137.8(5) . . . . ? C23 Ga2 C24 C25 115.1(6) . . . . ? C22 Ga2 C24 C25 76.9(5) . . . . ? C21 Ga2 C24 C25 36.8(4) . . . . ? Rh1 Ga2 C24 C25 -107.1(5) . . . . ? C23 Ga2 C24 C241 -123.0(9) . . . . ? C25 Ga2 C24 C241 121.9(9) . . . . ? C22 Ga2 C24 C241 -161.2(9) . . . . ? C21 Ga2 C24 C241 158.7(9) . . . . ? Rh1 Ga2 C24 C241 14.8(11) . . . . ? C22 C21 C25 C24 0.7(8) . . . . ? C211 C21 C25 C24 -173.6(7) . . . . ? Ga2 C21 C25 C24 62.2(5) . . . . ? C22 C21 C25 C251 178.2(7) . . . . ? C211 C21 C25 C251 3.9(12) . . . . ? Ga2 C21 C25 C251 -120.3(8) . . . . ? C22 C21 C25 Ga2 -61.5(5) . . . . ? C211 C21 C25 Ga2 124.2(8) . . . . ? C23 C24 C25 C21 -1.0(8) . . . . ? C241 C24 C25 C21 174.4(7) . . . . ? Ga2 C24 C25 C21 -65.2(5) . . . . ? C23 C24 C25 C251 -178.5(7) . . . . ? C241 C24 C25 C251 -3.2(11) . . . . ? Ga2 C24 C25 C251 117.2(7) . . . . ? C23 C24 C25 Ga2 64.2(5) . . . . ? C241 C24 C25 Ga2 -120.4(7) . . . . ? C23 Ga2 C25 C21 78.0(5) . . . . ? C24 Ga2 C25 C21 116.3(7) . . . . ? C22 Ga2 C25 C21 35.8(4) . . . . ? Rh1 Ga2 C25 C21 -106.2(5) . . . . ? C23 Ga2 C25 C24 -38.3(4) . . . . ? C22 Ga2 C25 C24 -80.6(5) . . . . ? C21 Ga2 C25 C24 -116.3(7) . . . . ? Rh1 Ga2 C25 C24 137.4(4) . . . . ? C23 Ga2 C25 C251 -157.7(9) . . . . ? C24 Ga2 C25 C251 -119.3(10) . . . . ? C22 Ga2 C25 C251 160.1(10) . . . . ? C21 Ga2 C25 C251 124.3(11) . . . . ? Rh1 Ga2 C25 C251 18.1(10) . . . . ? C35' Ga3 C31 C32 131.8(8) . . . . ? C31' Ga3 C31 C32 -15.4(8) . . . . ? C35 Ga3 C31 C32 115.72(12) . . . . ? C34' Ga3 C31 C32 97.8(3) . . . . ? C32' Ga3 C31 C32 18.5(3) . . . . ? C34 Ga3 C31 C32 77.70(13) . . . . ? Rh1 Ga3 C31 C32 -105.0(4) . . . . ? C33' Ga3 C31 C32 58.1(2) . . . . ? C33 Ga3 C31 C32 36.53(8) . . . . ? C35' Ga3 C31 C35 16.1(8) . . . . ? C31' Ga3 C31 C35 -131.2(8) . . . . ? C34' Ga3 C31 C35 -18.0(3) . . . . ? C32' Ga3 C31 C35 -97.2(3) . . . . ? C34 Ga3 C31 C35 -38.02(8) . . . . ? Rh1 Ga3 C31 C35 139.3(4) . . . . ? C32 Ga3 C31 C35 -115.72(12) . . . . ? C33' Ga3 C31 C35 -57.6(2) . . . . ? C33 Ga3 C31 C35 -79.19(13) . . . . ? C35' Ga3 C31 C311 -105.2(8) . . . . ? C31' Ga3 C31 C311 107.6(8) . . . . ? C35 Ga3 C31 C311 -121.24(11) . . . . ? C34' Ga3 C31 C311 -139.2(3) . . . . ? C32' Ga3 C31 C311 141.5(3) . . . . ? C34 Ga3 C31 C311 -159.3 . . . . ? Rh1 Ga3 C31 C311 18.0(5) . . . . ? C32 Ga3 C31 C311 123.04(12) . . . . ? C33' Ga3 C31 C311 -178.9(2) . . . . ? C33 Ga3 C31 C311 159.6 . . . . ? C35 C31 C32 C33 0.0 . . . . ? C311 C31 C32 C33 180.0 . . . . ? Ga3 C31 C32 C33 -63.6(2) . . . . ? C35 C31 C32 C321 180.0 . . . . ? C311 C31 C32 C321 0.0 . . . . ? Ga3 C31 C32 C321 116.4(2) . . . . ? C35 C31 C32 Ga3 63.6(2) . . . . ? C311 C31 C32 Ga3 -116.4(2) . . . . ? C35' Ga3 C32 C31 -18.5(3) . . . . ? C31' Ga3 C32 C31 17.4(9) . . . . ? C35 Ga3 C32 C31 -38.42(9) . . . . ? C34' Ga3 C32 C31 -59.9(2) . . . . ? C32' Ga3 C32 C31 -133.7(7) . . . . ? C34 Ga3 C32 C31 -80.74(14) . . . . ? Rh1 Ga3 C32 C31 140.4(3) . . . . ? C33' Ga3 C32 C31 -99.7(3) . . . . ? C33 Ga3 C32 C31 -117.27(13) . . . . ? C35' Ga3 C32 C33 98.7(3) . . . . ? C31' Ga3 C32 C33 134.7(8) . . . . ? C35 Ga3 C32 C33 78.85(14) . . . . ? C31 Ga3 C32 C33 117.27(13) . . . . ? C34' Ga3 C32 C33 57.4(2) . . . . ? C32' Ga3 C32 C33 -16.4(7) . . . . ? C34 Ga3 C32 C33 36.52(9) . . . . ? Rh1 Ga3 C32 C33 -102.4(3) . . . . ? C33' Ga3 C32 C33 17.6(3) . . . . ? C35' Ga3 C32 C321 -138.7(3) . . . . ? C31' Ga3 C32 C321 -102.8(9) . . . . ? C35 Ga3 C32 C321 -158.63(5) . . . . ? C31 Ga3 C32 C321 -120.21(13) . . . . ? C34' Ga3 C32 C321 179.9(2) . . . . ? C32' Ga3 C32 C321 106.1(7) . . . . ? C34 Ga3 C32 C321 159.05(5) . . . . ? Rh1 Ga3 C32 C321 20.2(3) . . . . ? C33' Ga3 C32 C321 140.1(3) . . . . ? C33 Ga3 C32 C321 122.52(13) . . . . ? C31 C32 C33 C34 0.0 . . . . ? C321 C32 C33 C34 180.0 . . . . ? Ga3 C32 C33 C34 -60.9(2) . . . . ? C31 C32 C33 C331 180.0 . . . . ? C321 C32 C33 C331 0.0 . . . . ? Ga3 C32 C33 C331 119.1(2) . . . . ? C31 C32 C33 Ga3 60.9(2) . . . . ? C321 C32 C33 Ga3 -119.1(2) . . . . ? C35' Ga3 C33 C34 59.1(2) . . . . ? C31' Ga3 C33 C34 101.4(3) . . . . ? C35 Ga3 C33 C34 37.78(9) . . . . ? C31 Ga3 C33 C34 80.67(14) . . . . ? C34' Ga3 C33 C34 17.4(3) . . . . ? C32' Ga3 C33 C34 137.6(8) . . . . ? Rh1 Ga3 C33 C34 -120.3(2) . . . . ? C32 Ga3 C33 C34 117.98(13) . . . . ? C33' Ga3 C33 C34 -17.6(7) . . . . ? C35' Ga3 C33 C32 -58.9(2) . . . . ? C31' Ga3 C33 C32 -16.6(3) . . . . ? C35 Ga3 C33 C32 -80.20(15) . . . . ? C31 Ga3 C33 C32 -37.31(9) . . . . ? C34' Ga3 C33 C32 -100.5(3) . . . . ? C32' Ga3 C33 C32 19.7(9) . . . . ? C34 Ga3 C33 C32 -117.98(13) . . . . ? Rh1 Ga3 C33 C32 121.7(2) . . . . ? C33' Ga3 C33 C32 -135.6(7) . . . . ? C35' Ga3 C33 C331 179.8(2) . . . . ? C31' Ga3 C33 C331 -137.9(3) . . . . ? C35 Ga3 C33 C331 158.51(5) . . . . ? C31 Ga3 C33 C331 -158.61(5) . . . . ? C34' Ga3 C33 C331 138.2(3) . . . . ? C32' Ga3 C33 C331 -101.6(8) . . . . ? C34 Ga3 C33 C331 120.73(13) . . . . ? Rh1 Ga3 C33 C331 0.4(3) . . . . ? C32 Ga3 C33 C331 -121.29(13) . . . . ? C33' Ga3 C33 C331 103.1(7) . . . . ? C32 C33 C34 C35 0.0 . . . . ? C331 C33 C34 C35 180.0 . . . . ? Ga3 C33 C34 C35 -61.5(2) . . . . ? C32 C33 C34 C341 180.0 . . . . ? C331 C33 C34 C341 0.0 . . . . ? Ga3 C33 C34 C341 118.5(2) . . . . ? C32 C33 C34 Ga3 61.5(2) . . . . ? C331 C33 C34 Ga3 -118.5(2) . . . . ? C35' Ga3 C34 C35 18.3(3) . . . . ? C31' Ga3 C34 C35 60.8(2) . . . . ? C31 Ga3 C34 C35 38.47(9) . . . . ? C34' Ga3 C34 C35 -17.8(8) . . . . ? C32' Ga3 C34 C35 101.7(3) . . . . ? Rh1 Ga3 C34 C35 -139.8(3) . . . . ? C32 Ga3 C34 C35 80.37(14) . . . . ? C33' Ga3 C34 C35 136.1(8) . . . . ? C33 Ga3 C34 C35 116.72(13) . . . . ? C35' Ga3 C34 C33 -98.4(3) . . . . ? C31' Ga3 C34 C33 -55.9(2) . . . . ? C35 Ga3 C34 C33 -116.72(13) . . . . ? C31 Ga3 C34 C33 -78.25(14) . . . . ? C34' Ga3 C34 C33 -134.5(7) . . . . ? C32' Ga3 C34 C33 -15.0(3) . . . . ? Rh1 Ga3 C34 C33 103.5(3) . . . . ? C32 Ga3 C34 C33 -36.35(9) . . . . ? C33' Ga3 C34 C33 19.3(8) . . . . ? C35' Ga3 C34 C341 138.6(3) . . . . ? C31' Ga3 C34 C341 -178.9(2) . . . . ? C35 Ga3 C34 C341 120.36(12) . . . . ? C31 Ga3 C34 C341 158.82(5) . . . . ? C34' Ga3 C34 C341 102.6(8) . . . . ? C32' Ga3 C34 C341 -137.9(3) . . . . ? Rh1 Ga3 C34 C341 -19.4(3) . . . . ? C32 Ga3 C34 C341 -159.3 . . . . ? C33' Ga3 C34 C341 -103.6(8) . . . . ? C33 Ga3 C34 C341 -122.92(12) . . . . ? C33 C34 C35 C31 0.0 . . . . ? C341 C34 C35 C31 180.0 . . . . ? Ga3 C34 C35 C31 -64.7(2) . . . . ? C33 C34 C35 C351 180.0 . . . . ? C341 C34 C35 C351 0.0 . . . . ? Ga3 C34 C35 C351 115.4(2) . . . . ? C33 C34 C35 Ga3 64.6(2) . . . . ? C341 C34 C35 Ga3 -115.3(2) . . . . ? C32 C31 C35 C34 0.0 . . . . ? C311 C31 C35 C34 180.0 . . . . ? Ga3 C31 C35 C34 66.0(2) . . . . ? C32 C31 C35 C351 180.0 . . . . ? C311 C31 C35 C351 0.0 . . . . ? Ga3 C31 C35 C351 -114.0(2) . . . . ? C32 C31 C35 Ga3 -66.0(2) . . . . ? C311 C31 C35 Ga3 114.0(2) . . . . ? C35' Ga3 C35 C34 -131.7(8) . . . . ? C31' Ga3 C35 C34 -96.4(3) . . . . ? C31 Ga3 C35 C34 -115.42(12) . . . . ? C34' Ga3 C35 C34 17.4(8) . . . . ? C32' Ga3 C35 C34 -55.4(2) . . . . ? Rh1 Ga3 C35 C34 104.0(4) . . . . ? C32 Ga3 C35 C34 -77.80(13) . . . . ? C33' Ga3 C35 C34 -15.9(3) . . . . ? C33 Ga3 C35 C34 -36.83(8) . . . . ? C35' Ga3 C35 C31 -16.3(8) . . . . ? C31' Ga3 C35 C31 19.0(3) . . . . ? C34' Ga3 C35 C31 132.8(7) . . . . ? C32' Ga3 C35 C31 60.1(2) . . . . ? C34 Ga3 C35 C31 115.42(12) . . . . ? Rh1 Ga3 C35 C31 -140.6(4) . . . . ? C32 Ga3 C35 C31 37.63(8) . . . . ? C33' Ga3 C35 C31 99.5(3) . . . . ? C33 Ga3 C35 C31 78.60(13) . . . . ? C35' Ga3 C35 C351 105.5(8) . . . . ? C31' Ga3 C35 C351 140.8(3) . . . . ? C31 Ga3 C35 C351 121.80(11) . . . . ? C34' Ga3 C35 C351 -105.4(8) . . . . ? C32' Ga3 C35 C351 -178.1(2) . . . . ? C34 Ga3 C35 C351 -122.77(11) . . . . ? Rh1 Ga3 C35 C351 -18.8(5) . . . . ? C32 Ga3 C35 C351 159.4 . . . . ? C33' Ga3 C35 C351 -138.7(3) . . . . ? C33 Ga3 C35 C351 -159.6 . . . . ? C35' Ga3 C31' C32' 115.52(11) . . . . ? C35 Ga3 C31' C32' 97.5(3) . . . . ? C31 Ga3 C31' C32' 132.6(7) . . . . ? C34' Ga3 C31' C32' 77.41(13) . . . . ? C34 Ga3 C31' C32' 56.2(2) . . . . ? Rh1 Ga3 C31' C32' -98.7(3) . . . . ? C32 Ga3 C31' C32' -16.2(9) . . . . ? C33' Ga3 C31' C32' 36.39(8) . . . . ? C33 Ga3 C31' C32' 16.7(3) . . . . ? C35 Ga3 C31' C35' -18.0(3) . . . . ? C31 Ga3 C31' C35' 17.1(8) . . . . ? C34' Ga3 C31' C35' -38.11(9) . . . . ? C32' Ga3 C31' C35' -115.52(11) . . . . ? C34 Ga3 C31' C35' -59.3(2) . . . . ? Rh1 Ga3 C31' C35' 145.8(3) . . . . ? C32 Ga3 C31' C35' -131.8(8) . . . . ? C33' Ga3 C31' C35' -79.13(13) . . . . ? C33 Ga3 C31' C35' -98.8(3) . . . . ? C35' Ga3 C31' C312 -121.20(12) . . . . ? C35 Ga3 C31' C312 -139.2(3) . . . . ? C31 Ga3 C31' C312 -104.1(8) . . . . ? C34' Ga3 C31' C312 -159.3 . . . . ? C32' Ga3 C31' C312 123.28(12) . . . . ? C34 Ga3 C31' C312 179.5(2) . . . . ? Rh1 Ga3 C31' C312 24.6(4) . . . . ? C32 Ga3 C31' C312 107.0(8) . . . . ? C33' Ga3 C31' C312 159.7 . . . . ? C33 Ga3 C31' C312 140.0(3) . . . . ? C35' C31' C32' C33' 0.0 . . . . ? C312 C31' C32' C33' 180.0 . . . . ? Ga3 C31' C32' C33' -63.7(2) . . . . ? C35' C31' C32' C322 180.0 . . . . ? C312 C31' C32' C322 0.0 . . . . ? Ga3 C31' C32' C322 116.3(2) . . . . ? C35' C31' C32' Ga3 63.7(2) . . . . ? C312 C31' C32' Ga3 -116.3(2) . . . . ? C35' Ga3 C32' C31' -38.83(10) . . . . ? C35 Ga3 C32' C31' -60.0(2) . . . . ? C31 Ga3 C32' C31' -18.6(3) . . . . ? C34' Ga3 C32' C31' -81.29(15) . . . . ? C34 Ga3 C32' C31' -100.2(3) . . . . ? Rh1 Ga3 C32' C31' 132.2(3) . . . . ? C32 Ga3 C32' C31' 14.2(7) . . . . ? C33' Ga3 C32' C31' -117.47(13) . . . . ? C33 Ga3 C32' C31' -131.4(8) . . . . ? C35' Ga3 C32' C33' 78.65(14) . . . . ? C31' Ga3 C32' C33' 117.47(13) . . . . ? C35 Ga3 C32' C33' 57.5(2) . . . . ? C31 Ga3 C32' C33' 98.9(3) . . . . ? C34' Ga3 C32' C33' 36.19(9) . . . . ? C34 Ga3 C32' C33' 17.2(3) . . . . ? Rh1 Ga3 C32' C33' -110.3(2) . . . . ? C32 Ga3 C32' C33' 131.7(7) . . . . ? C33 Ga3 C32' C33' -14.0(8) . . . . ? C35' Ga3 C32' C322 -158.48(5) . . . . ? C31' Ga3 C32' C322 -119.65(13) . . . . ? C35 Ga3 C32' C322 -179.6(2) . . . . ? C31 Ga3 C32' C322 -138.2(3) . . . . ? C34' Ga3 C32' C322 159.06(5) . . . . ? C34 Ga3 C32' C322 140.1(3) . . . . ? Rh1 Ga3 C32' C322 12.6(3) . . . . ? C32 Ga3 C32' C322 -105.4(7) . . . . ? C33' Ga3 C32' C322 122.87(12) . . . . ? C33 Ga3 C32' C322 108.9(8) . . . . ? C31' C32' C33' C34' 0.0 . . . . ? C322 C32' C33' C34' 180.0 . . . . ? Ga3 C32' C33' C34' -60.0(2) . . . . ? C31' C32' C33' C332 180.0 . . . . ? C322 C32' C33' C332 0.0 . . . . ? Ga3 C32' C33' C332 120.0(2) . . . . ? C31' C32' C33' Ga3 60.0(2) . . . . ? C322 C32' C33' Ga3 -120.0(2) . . . . ? C35' Ga3 C33' C34' 37.78(10) . . . . ? C31' Ga3 C33' C34' 81.17(16) . . . . ? C35 Ga3 C33' C34' 18.1(3) . . . . ? C31 Ga3 C33' C34' 59.1(2) . . . . ? C32' Ga3 C33' C34' 118.64(14) . . . . ? C34 Ga3 C33' C34' -14.2(8) . . . . ? Rh1 Ga3 C33' C34' -130.6(3) . . . . ? C32 Ga3 C33' C34' 99.3(3) . . . . ? C33 Ga3 C33' C34' 130.7(7) . . . . ? C35' Ga3 C33' C32' -80.86(15) . . . . ? C31' Ga3 C33' C32' -37.47(10) . . . . ? C35 Ga3 C33' C32' -100.5(3) . . . . ? C31 Ga3 C33' C32' -59.5(2) . . . . ? C34' Ga3 C33' C32' -118.64(14) . . . . ? C34 Ga3 C33' C32' -132.8(8) . . . . ? Rh1 Ga3 C33' C32' 110.7(2) . . . . ? C32 Ga3 C33' C32' -19.4(3) . . . . ? C33 Ga3 C33' C32' 12.1(7) . . . . ? C35' Ga3 C33' C332 158.27(6) . . . . ? C31' Ga3 C33' C332 -158.34(6) . . . . ? C35 Ga3 C33' C332 138.6(3) . . . . ? C31 Ga3 C33' C332 179.6(2) . . . . ? C34' Ga3 C33' C332 120.49(14) . . . . ? C32' Ga3 C33' C332 -120.87(13) . . . . ? C34 Ga3 C33' C332 106.3(8) . . . . ? Rh1 Ga3 C33' C332 -10.1(3) . . . . ? C32 Ga3 C33' C332 -140.3(3) . . . . ? C33 Ga3 C33' C332 -108.8(7) . . . . ? C32' C33' C34' C35' 0.0 . . . . ? C332 C33' C34' C35' 180.0 . . . . ? Ga3 C33' C34' C35' -60.4(2) . . . . ? C32' C33' C34' C342 180.0 . . . . ? C332 C33' C34' C342 0.0 . . . . ? Ga3 C33' C34' C342 119.6(2) . . . . ? C32' C33' C34' Ga3 60.4(2) . . . . ? C332 C33' C34' Ga3 -119.6(2) . . . . ? C31' Ga3 C34' C35' 38.85(10) . . . . ? C35 Ga3 C34' C35' -16.2(8) . . . . ? C31 Ga3 C34' C35' 18.0(3) . . . . ? C32' Ga3 C34' C35' 81.03(14) . . . . ? C34 Ga3 C34' C35' 130.5(7) . . . . ? Rh1 Ga3 C34' C35' -144.9(3) . . . . ? C32 Ga3 C34' C35' 58.5(2) . . . . ? C33' Ga3 C34' C35' 117.11(13) . . . . ? C33 Ga3 C34' C35' 97.9(3) . . . . ? C35' Ga3 C34' C33' -117.11(13) . . . . ? C31' Ga3 C34' C33' -78.26(15) . . . . ? C35 Ga3 C34' C33' -133.3(7) . . . . ? C31 Ga3 C34' C33' -99.1(3) . . . . ? C32' Ga3 C34' C33' -36.08(9) . . . . ? C34 Ga3 C34' C33' 13.4(8) . . . . ? Rh1 Ga3 C34' C33' 98.0(3) . . . . ? C32 Ga3 C34' C33' -58.6(2) . . . . ? C33 Ga3 C34' C33' -19.2(3) . . . . ? C35' Ga3 C34' C342 119.76(13) . . . . ? C31' Ga3 C34' C342 158.61(5) . . . . ? C35 Ga3 C34' C342 103.6(8) . . . . ? C31 Ga3 C34' C342 137.7(3) . . . . ? C32' Ga3 C34' C342 -159.21(5) . . . . ? C34 Ga3 C34' C342 -109.8(8) . . . . ? Rh1 Ga3 C34' C342 -25.2(4) . . . . ? C32 Ga3 C34' C342 178.3(2) . . . . ? C33' Ga3 C34' C342 -123.13(13) . . . . ? C33 Ga3 C34' C342 -142.4(3) . . . . ? C33' C34' C35' C31' 0.0 . . . . ? C342 C34' C35' C31' 180.0 . . . . ? Ga3 C34' C35' C31' -64.4(2) . . . . ? C33' C34' C35' C352 180.0 . . . . ? C342 C34' C35' C352 0.0 . . . . ? Ga3 C34' C35' C352 115.6(2) . . . . ? C33' C34' C35' Ga3 64.4(2) . . . . ? C342 C34' C35' Ga3 -115.6(2) . . . . ? C32' C31' C35' C34' 0.0 . . . . ? C312 C31' C35' C34' 180.0 . . . . ? Ga3 C31' C35' C34' 66.5(2) . . . . ? C32' C31' C35' C352 180.0 . . . . ? C312 C31' C35' C352 0.0 . . . . ? Ga3 C31' C35' C352 -113.5(2) . . . . ? C32' C31' C35' Ga3 -66.5(2) . . . . ? C312 C31' C35' Ga3 113.5(2) . . . . ? C31' Ga3 C35' C34' -115.33(12) . . . . ? C35 Ga3 C35' C34' 16.4(8) . . . . ? C31 Ga3 C35' C34' -132.9(8) . . . . ? C32' Ga3 C35' C34' -77.48(13) . . . . ? C34 Ga3 C35' C34' -18.5(3) . . . . ? Rh1 Ga3 C35' C34' 120.2(5) . . . . ? C32 Ga3 C35' C34' -98.3(3) . . . . ? C33' Ga3 C35' C34' -36.58(8) . . . . ? C33 Ga3 C35' C34' -58.5(2) . . . . ? C35 Ga3 C35' C31' 131.7(8) . . . . ? C31 Ga3 C35' C31' -17.6(8) . . . . ? C34' Ga3 C35' C31' 115.33(12) . . . . ? C32' Ga3 C35' C31' 37.85(8) . . . . ? C34 Ga3 C35' C31' 96.8(3) . . . . ? Rh1 Ga3 C35' C31' -124.5(5) . . . . ? C32 Ga3 C35' C31' 17.0(3) . . . . ? C33' Ga3 C35' C31' 78.75(13) . . . . ? C33 Ga3 C35' C31' 56.8(2) . . . . ? C31' Ga3 C35' C352 121.56(11) . . . . ? C35 Ga3 C35' C352 -106.7(8) . . . . ? C31 Ga3 C35' C352 104.0(8) . . . . ? C34' Ga3 C35' C352 -123.10(11) . . . . ? C32' Ga3 C35' C352 159.4 . . . . ? C34 Ga3 C35' C352 -141.6(3) . . . . ? Rh1 Ga3 C35' C352 -2.9(6) . . . . ? C32 Ga3 C35' C352 138.5(3) . . . . ? C33' Ga3 C35' C352 -159.7 . . . . ? C33 Ga3 C35' C352 178.4(2) . . . . ? _diffrn_measured_fraction_theta_max 0.998 _diffrn_reflns_theta_full 25.06 _diffrn_measured_fraction_theta_full 0.998 _refine_diff_density_max 0.584 _refine_diff_density_min -0.573 _refine_diff_density_rms 0.114 #=================================================END data_3 _database_code_depnum_ccdc_archive 'CCDC 240970' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C50 H79 Cl4 In3 O2 Rh2' _chemical_formula_weight 1404.21 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M P-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 10.004(2) _cell_length_b 15.458(3) _cell_length_c 19.400(4) _cell_angle_alpha 101.842(5) _cell_angle_beta 98.540(5) _cell_angle_gamma 95.925(5) _cell_volume 2876.0(11) _cell_formula_units_Z 2 _cell_measurement_temperature 100(2) _cell_measurement_reflns_used 7869 _cell_measurement_theta_min 2.59 _cell_measurement_theta_max 25.12 _exptl_crystal_description plate _exptl_crystal_colour 'red, clear' _exptl_crystal_size_max 0.40 _exptl_crystal_size_mid 0.30 _exptl_crystal_size_min 0.03 _exptl_crystal_density_meas 0 _exptl_crystal_density_diffrn 1.622 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1400 _exptl_absorpt_coefficient_mu 1.966 _exptl_absorpt_correction_type multi-scans _exptl_absorpt_correction_T_min 0.5060 _exptl_absorpt_correction_T_max 0.9432 _exptl_absorpt_process_details SADABS _exptl_special_details ; ? ; _diffrn_ambient_temperature 100(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'SMART APEX CCD area detector' _diffrn_measurement_method 'phi and omega scans' _diffrn_detector_area_resol_mean 8.366 _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 20950 _diffrn_reflns_av_R_equivalents 0.0248 _diffrn_reflns_av_sigmaI/netI 0.0304 _diffrn_reflns_limit_h_min -11 _diffrn_reflns_limit_h_max 11 _diffrn_reflns_limit_k_min -18 _diffrn_reflns_limit_k_max 17 _diffrn_reflns_limit_l_min -21 _diffrn_reflns_limit_l_max 23 _diffrn_reflns_theta_min 2.32 _diffrn_reflns_theta_max 25.12 _reflns_number_total 9907 _reflns_number_gt 8942 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker APEX2' _computing_cell_refinement 'Bruker APEX2' _computing_data_reduction 'Bruker SAINT' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0334P)^2^+9.4658P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 9907 _refine_ls_number_parameters 575 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0322 _refine_ls_R_factor_gt 0.0281 _refine_ls_wR_factor_ref 0.0810 _refine_ls_wR_factor_gt 0.0781 _refine_ls_goodness_of_fit_ref 1.085 _refine_ls_restrained_S_all 1.085 _refine_ls_shift/su_max 0.102 _refine_ls_shift/su_mean 0.001 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group In1 In 1.07876(3) 0.708216(18) 0.359828(15) 0.01630(8) Uani 1 1 d . . . In2 In 0.91069(3) 0.550902(17) 0.226039(14) 0.01343(7) Uani 1 1 d . . . In3 In 0.92662(3) 0.757225(17) 0.208986(14) 0.01406(7) Uani 1 1 d . . . Rh1 Rh 0.83009(3) 0.684744(19) 0.300900(15) 0.01178(8) Uani 1 1 d . . . Rh2 Rh 0.32763(3) 0.159240(19) 0.249921(16) 0.01460(8) Uani 1 1 d . . . Cl1 Cl 1.16585(9) 0.55847(6) 0.27581(5) 0.01715(19) Uani 1 1 d . . . Cl2 Cl 0.83596(11) 0.39531(6) 0.22680(6) 0.0244(2) Uani 1 1 d . . . Cl3 Cl 0.85198(10) 0.89402(6) 0.17849(6) 0.0229(2) Uani 1 1 d . . . Cl4 Cl 1.18436(9) 0.80585(6) 0.25707(5) 0.01763(19) Uani 1 1 d . . . C11' C 1.2397(4) 0.8201(3) 0.4771(2) 0.0171(8) Uani 1 1 d . . . C12' C 1.1663(4) 0.8043(3) 0.5291(2) 0.0172(8) Uani 1 1 d . . . C13' C 1.1534(4) 0.7107(3) 0.5285(2) 0.0185(8) Uani 1 1 d . . . C14' C 1.2214(4) 0.6690(3) 0.4766(2) 0.0165(8) Uani 1 1 d . . . C15 C 1.2743(4) 0.7357(3) 0.4405(2) 0.0156(8) Uani 1 1 d . . . C111 C 1.2829(4) 0.9094(3) 0.4617(2) 0.0229(9) Uani 1 1 d . . . H11A H 1.2160 0.9495 0.4739 0.034 Uiso 1 1 calc R . . H11B H 1.2881 0.9019 0.4109 0.034 Uiso 1 1 calc R . . H11C H 1.3726 0.9349 0.4905 0.034 Uiso 1 1 calc R . . C121 C 1.1075(5) 0.8730(3) 0.5784(2) 0.0281(10) Uani 1 1 d . . . H12A H 1.1760 0.8998 0.6211 0.042 Uiso 1 1 calc R . . H12B H 1.0270 0.8443 0.5925 0.042 Uiso 1 1 calc R . . H12C H 1.0811 0.9195 0.5536 0.042 Uiso 1 1 calc R . . C131 C 1.0806(5) 0.6656(3) 0.5766(2) 0.0270(10) Uani 1 1 d . . . H13A H 1.0488 0.6030 0.5526 0.041 Uiso 1 1 calc R . . H13B H 1.0022 0.6958 0.5873 0.041 Uiso 1 1 calc R . . H13C H 1.1432 0.6685 0.6212 0.041 Uiso 1 1 calc R . . C141 C 1.2446(5) 0.5729(3) 0.4620(2) 0.0236(9) Uani 1 1 d . . . H14A H 1.3089 0.5628 0.5019 0.035 Uiso 1 1 calc R . . H14B H 1.2823 0.5587 0.4178 0.035 Uiso 1 1 calc R . . H14C H 1.1577 0.5345 0.4567 0.035 Uiso 1 1 calc R . . C151 C 1.3992(4) 0.7290(3) 0.4051(2) 0.0232(9) Uani 1 1 d . . . H15A H 1.4813 0.7399 0.4420 0.035 Uiso 1 1 calc R . . H15B H 1.4048 0.7735 0.3759 0.035 Uiso 1 1 calc R . . H15C H 1.3924 0.6692 0.3747 0.035 Uiso 1 1 calc R . . C21 C 0.8030(4) 0.5479(3) 0.0770(2) 0.0201(9) Uani 1 1 d . . . C22 C 0.8064(4) 0.6342(3) 0.0689(2) 0.0190(8) Uani 1 1 d . . . C23 C 0.9471(4) 0.6776(3) 0.0879(2) 0.0182(8) Uani 1 1 d . . . C24 C 1.0281(4) 0.6123(3) 0.1054(2) 0.0169(8) Uani 1 1 d . . . C25 C 0.9417(4) 0.5324(3) 0.1019(2) 0.0185(8) Uani 1 1 d . . . C211 C 0.6773(4) 0.4790(3) 0.0624(2) 0.0267(10) Uani 1 1 d . . . H21A H 0.5964 0.5091 0.0665 0.040 Uiso 1 1 calc R . . H21B H 0.6864 0.4412 0.0972 0.040 Uiso 1 1 calc R . . H21C H 0.6678 0.4419 0.0140 0.040 Uiso 1 1 calc R . . C221 C 0.6880(4) 0.6782(3) 0.0414(2) 0.0263(10) Uani 1 1 d . . . H22A H 0.6844 0.6751 -0.0098 0.040 Uiso 1 1 calc R . . H22B H 0.7000 0.7408 0.0671 0.040 Uiso 1 1 calc R . . H22C H 0.6027 0.6473 0.0490 0.040 Uiso 1 1 calc R . . C231 C 1.0023(5) 0.7547(3) 0.0583(2) 0.0242(9) Uani 1 1 d . . . H23A H 1.0920 0.7817 0.0864 0.036 Uiso 1 1 calc R . . H23B H 0.9395 0.7994 0.0612 0.036 Uiso 1 1 calc R . . H23C H 1.0111 0.7328 0.0083 0.036 Uiso 1 1 calc R . . C241 C 1.1805(4) 0.6205(3) 0.1132(2) 0.0216(9) Uani 1 1 d . . . H24A H 1.2054 0.5850 0.0701 0.032 Uiso 1 1 calc R . . H24B H 1.2175 0.5985 0.1550 0.032 Uiso 1 1 calc R . . H24C H 1.2182 0.6832 0.1194 0.032 Uiso 1 1 calc R . . C251 C 0.9914(5) 0.4420(3) 0.0886(2) 0.0251(9) Uani 1 1 d . . . H25A H 1.0167 0.4290 0.0410 0.038 Uiso 1 1 calc R . . H25B H 0.9186 0.3959 0.0912 0.038 Uiso 1 1 calc R . . H25C H 1.0712 0.4427 0.1248 0.038 Uiso 1 1 calc R . . C31 C 0.6913(4) 0.7765(3) 0.3438(2) 0.0190(8) Uani 1 1 d . . . C32 C 0.7330(4) 0.7254(3) 0.3946(2) 0.0218(9) Uani 1 1 d . . . C33 C 0.6857(4) 0.6329(3) 0.3628(2) 0.0250(10) Uani 1 1 d . . . C34 C 0.6150(4) 0.6271(3) 0.2922(2) 0.0214(9) Uani 1 1 d . . . C35 C 0.6184(4) 0.7157(3) 0.2800(2) 0.0170(8) Uani 1 1 d . . . C311 C 0.7042(5) 0.8767(3) 0.3565(3) 0.0352(12) Uani 1 1 d . . . H31A H 0.6218 0.8969 0.3723 0.053 Uiso 1 1 calc R . . H31B H 0.7154 0.8950 0.3121 0.053 Uiso 1 1 calc R . . H31C H 0.7839 0.9032 0.3935 0.053 Uiso 1 1 calc R . . C321 C 0.7973(5) 0.7638(4) 0.4711(2) 0.0441(14) Uani 1 1 d . . . H32A H 0.8519 0.8215 0.4749 0.066 Uiso 1 1 calc R . . H32B H 0.8563 0.7229 0.4881 0.066 Uiso 1 1 calc R . . H32C H 0.7258 0.7721 0.5004 0.066 Uiso 1 1 calc R . . C331 C 0.6945(6) 0.5587(4) 0.4016(3) 0.0490(15) Uani 1 1 d . . . H33A H 0.6166 0.5541 0.4265 0.073 Uiso 1 1 calc R . . H33B H 0.7795 0.5710 0.4365 0.073 Uiso 1 1 calc R . . H33C H 0.6932 0.5024 0.3672 0.073 Uiso 1 1 calc R . . C341 C 0.5346(5) 0.5442(3) 0.2420(3) 0.0412(14) Uani 1 1 d . . . H34A H 0.5820 0.4927 0.2465 0.062 Uiso 1 1 calc R . . H34B H 0.5260 0.5518 0.1927 0.062 Uiso 1 1 calc R . . H34C H 0.4435 0.5343 0.2543 0.062 Uiso 1 1 calc R . . C351 C 0.5426(5) 0.7411(4) 0.2161(2) 0.0320(11) Uani 1 1 d . . . H35A H 0.5295 0.6908 0.1746 0.048 Uiso 1 1 calc R . . H35B H 0.5953 0.7927 0.2060 0.048 Uiso 1 1 calc R . . H35C H 0.4536 0.7563 0.2258 0.048 Uiso 1 1 calc R . . C41 C 0.3370(4) 0.1580(3) 0.3627(2) 0.0208(9) Uani 1 1 d . . . C42 C 0.2035(4) 0.1203(3) 0.3244(2) 0.0176(8) Uani 1 1 d . . . C43 C 0.1457(4) 0.1878(3) 0.2941(2) 0.0196(8) Uani 1 1 d . . . C44 C 0.2418(5) 0.2670(3) 0.3138(2) 0.0232(9) Uani 1 1 d . . . C45 C 0.3606(5) 0.2482(3) 0.3559(2) 0.0242(9) Uani 1 1 d . . . C411 C 0.4335(5) 0.1107(3) 0.4039(2) 0.0297(10) Uani 1 1 d . . . H41A H 0.5273 0.1394 0.4082 0.045 Uiso 1 1 calc R . . H41B H 0.4252 0.0481 0.3786 0.045 Uiso 1 1 calc R . . H41C H 0.4109 0.1138 0.4517 0.045 Uiso 1 1 calc R . . C421 C 0.1368(5) 0.0284(3) 0.3201(2) 0.0251(9) Uani 1 1 d . . . H42A H 0.1019 0.0262 0.3644 0.038 Uiso 1 1 calc R . . H42B H 0.2034 -0.0135 0.3135 0.038 Uiso 1 1 calc R . . H42C H 0.0610 0.0119 0.2794 0.038 Uiso 1 1 calc R . . C431 C 0.0052(4) 0.1773(3) 0.2507(2) 0.0278(10) Uani 1 1 d . . . H43A H -0.0231 0.1146 0.2262 0.042 Uiso 1 1 calc R . . H43B H 0.0061 0.2142 0.2152 0.042 Uiso 1 1 calc R . . H43C H -0.0591 0.1964 0.2824 0.042 Uiso 1 1 calc R . . C441 C 0.2195(6) 0.3540(3) 0.2961(3) 0.0361(12) Uani 1 1 d . . . H44A H 0.1556 0.3437 0.2508 0.054 Uiso 1 1 calc R . . H44B H 0.3067 0.3856 0.2916 0.054 Uiso 1 1 calc R . . H44C H 0.1814 0.3900 0.3342 0.054 Uiso 1 1 calc R . . C451 C 0.4834(5) 0.3147(3) 0.3906(3) 0.0413(13) Uani 1 1 d . . . H45A H 0.4668 0.3495 0.4360 0.062 Uiso 1 1 calc R . . H45B H 0.5016 0.3548 0.3590 0.062 Uiso 1 1 calc R . . H45C H 0.5623 0.2835 0.3996 0.062 Uiso 1 1 calc R . . C51 C 0.4416(5) 0.0620(3) 0.1951(2) 0.0251(10) Uani 1 1 d . . . C52 C 0.3110(4) 0.0563(3) 0.1526(2) 0.0220(9) Uani 1 1 d . . . C53 C 0.3000(4) 0.1403(3) 0.1338(2) 0.0224(9) Uani 1 1 d . . . C54 C 0.4235(4) 0.1989(3) 0.1660(2) 0.0229(9) Uani 1 1 d . . . C55 C 0.5115(4) 0.1501(3) 0.2037(2) 0.0253(10) Uani 1 1 d . . . C511 C 0.4997(6) -0.0119(3) 0.2242(3) 0.0389(13) Uani 1 1 d . . . H51A H 0.4252 -0.0532 0.2320 0.058 Uiso 1 1 calc R . . H51B H 0.5614 0.0135 0.2697 0.058 Uiso 1 1 calc R . . H51C H 0.5501 -0.0441 0.1900 0.058 Uiso 1 1 calc R . . C521 C 0.2045(6) -0.0248(3) 0.1288(3) 0.0372(12) Uani 1 1 d . . . H52A H 0.2181 -0.0598 0.0828 0.056 Uiso 1 1 calc R . . H52B H 0.1136 -0.0062 0.1235 0.056 Uiso 1 1 calc R . . H52C H 0.2125 -0.0614 0.1645 0.056 Uiso 1 1 calc R . . C531 C 0.1820(5) 0.1626(4) 0.0863(3) 0.0328(11) Uani 1 1 d . . . H53A H 0.1752 0.2264 0.1008 0.049 Uiso 1 1 calc R . . H53B H 0.0974 0.1276 0.0905 0.049 Uiso 1 1 calc R . . H53C H 0.1964 0.1485 0.0365 0.049 Uiso 1 1 calc R . . C541 C 0.4569(5) 0.2932(3) 0.1584(3) 0.0346(11) Uani 1 1 d . . . H54A H 0.5287 0.3255 0.1980 0.052 Uiso 1 1 calc R . . H54B H 0.3751 0.3230 0.1592 0.052 Uiso 1 1 calc R . . H54C H 0.4888 0.2927 0.1129 0.052 Uiso 1 1 calc R . . C551 C 0.6525(5) 0.1841(4) 0.2440(3) 0.0437(14) Uani 1 1 d . . . H55A H 0.7189 0.1584 0.2163 0.066 Uiso 1 1 calc R . . H55B H 0.6630 0.1668 0.2901 0.066 Uiso 1 1 calc R . . H55C H 0.6682 0.2493 0.2520 0.066 Uiso 1 1 calc R . . O1 O 0.7631(14) 0.1668(10) 0.0667(7) 0.061(5) Uiso 0.325(11) 1 d P A 1 O1' O 0.7780(5) 0.0967(3) 0.0783(2) 0.0273(16) Uiso 0.675(11) 1 d P A 2 O2 O 0.3778(7) -0.2007(3) -0.0009(3) 0.093(2) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 In1 0.00946(14) 0.01756(14) 0.02036(15) 0.00253(11) 0.00004(11) 0.00205(11) In2 0.01235(14) 0.01119(13) 0.01695(14) 0.00343(10) 0.00316(10) 0.00118(10) In3 0.01307(14) 0.01267(14) 0.01755(14) 0.00566(11) 0.00351(10) 0.00109(10) Rh1 0.00799(14) 0.01213(15) 0.01592(15) 0.00429(11) 0.00251(11) 0.00167(11) Rh2 0.01114(15) 0.01198(15) 0.02066(16) 0.00616(12) -0.00018(12) 0.00064(11) Cl1 0.0139(4) 0.0168(4) 0.0205(5) 0.0030(4) 0.0019(4) 0.0051(4) Cl2 0.0247(5) 0.0143(5) 0.0342(6) 0.0085(4) 0.0048(4) -0.0027(4) Cl3 0.0212(5) 0.0175(5) 0.0324(6) 0.0113(4) 0.0034(4) 0.0049(4) Cl4 0.0129(4) 0.0171(5) 0.0216(5) 0.0035(4) 0.0018(4) -0.0006(4) C11 0.0144(19) 0.019(2) 0.0158(19) 0.0036(16) -0.0016(15) -0.0003(16) C12 0.0164(19) 0.019(2) 0.0145(19) 0.0021(16) 0.0009(15) 0.0031(16) C13 0.0154(19) 0.023(2) 0.0159(19) 0.0055(16) -0.0009(15) -0.0009(16) C14 0.0157(19) 0.018(2) 0.0133(18) 0.0025(15) -0.0048(15) 0.0022(15) C15 0.0121(18) 0.022(2) 0.0122(18) 0.0033(15) 0.0005(15) 0.0010(15) C111 0.026(2) 0.018(2) 0.023(2) 0.0089(17) -0.0007(17) -0.0016(17) C121 0.027(2) 0.030(2) 0.025(2) 0.0005(19) 0.0054(19) 0.0065(19) C131 0.029(2) 0.030(2) 0.025(2) 0.0129(19) 0.0081(19) 0.0012(19) C141 0.031(2) 0.017(2) 0.021(2) 0.0062(17) -0.0030(18) 0.0038(18) C151 0.0107(19) 0.034(2) 0.022(2) 0.0028(18) -0.0005(16) 0.0024(17) C21 0.023(2) 0.019(2) 0.0140(19) 0.0009(16) -0.0006(16) -0.0034(17) C22 0.019(2) 0.023(2) 0.0142(19) 0.0041(16) 0.0001(16) 0.0003(17) C23 0.019(2) 0.018(2) 0.0164(19) 0.0051(16) 0.0003(16) -0.0017(16) C24 0.020(2) 0.019(2) 0.0107(18) 0.0015(15) 0.0024(15) 0.0017(16) C25 0.023(2) 0.018(2) 0.0132(19) 0.0003(15) 0.0037(16) 0.0021(17) C211 0.023(2) 0.029(2) 0.023(2) 0.0033(18) -0.0007(18) -0.0062(19) C221 0.021(2) 0.031(2) 0.025(2) 0.0091(19) -0.0033(18) 0.0019(19) C231 0.031(2) 0.021(2) 0.021(2) 0.0070(17) 0.0044(18) 0.0008(18) C241 0.019(2) 0.022(2) 0.023(2) 0.0019(17) 0.0056(17) 0.0022(17) C251 0.035(3) 0.017(2) 0.023(2) 0.0012(17) 0.0080(19) 0.0014(18) C31 0.0101(18) 0.017(2) 0.029(2) 0.0003(17) 0.0063(16) 0.0029(15) C32 0.0117(19) 0.037(2) 0.018(2) 0.0050(18) 0.0057(16) 0.0076(18) C33 0.016(2) 0.031(2) 0.038(3) 0.020(2) 0.0143(18) 0.0103(18) C34 0.0098(19) 0.017(2) 0.036(2) 0.0021(18) 0.0095(17) -0.0003(16) C35 0.0086(18) 0.022(2) 0.023(2) 0.0062(17) 0.0063(15) 0.0057(15) C311 0.029(3) 0.019(2) 0.057(3) 0.000(2) 0.017(2) 0.0050(19) C321 0.025(3) 0.083(4) 0.023(2) 0.002(3) 0.007(2) 0.017(3) C331 0.044(3) 0.056(4) 0.074(4) 0.052(3) 0.035(3) 0.024(3) C341 0.015(2) 0.026(3) 0.072(4) -0.014(2) 0.016(2) -0.0072(19) C351 0.018(2) 0.054(3) 0.030(2) 0.017(2) 0.0055(18) 0.015(2) C41 0.023(2) 0.023(2) 0.016(2) 0.0047(17) 0.0009(16) 0.0052(17) C42 0.019(2) 0.0167(19) 0.018(2) 0.0022(16) 0.0048(16) 0.0058(16) C43 0.020(2) 0.021(2) 0.019(2) 0.0035(16) 0.0056(16) 0.0081(17) C44 0.029(2) 0.017(2) 0.024(2) 0.0016(17) 0.0067(18) 0.0072(18) C45 0.028(2) 0.018(2) 0.021(2) -0.0013(17) -0.0026(18) -0.0004(18) C411 0.029(2) 0.037(3) 0.025(2) 0.013(2) -0.0016(19) 0.011(2) C421 0.029(2) 0.020(2) 0.028(2) 0.0073(18) 0.0124(19) 0.0012(18) C431 0.018(2) 0.040(3) 0.028(2) 0.009(2) 0.0033(18) 0.0110(19) C441 0.046(3) 0.020(2) 0.046(3) 0.010(2) 0.012(2) 0.012(2) C451 0.037(3) 0.033(3) 0.042(3) -0.004(2) -0.004(2) -0.010(2) C51 0.029(2) 0.027(2) 0.029(2) 0.0139(19) 0.0199(19) 0.0128(19) C52 0.027(2) 0.020(2) 0.021(2) 0.0043(17) 0.0126(17) 0.0029(18) C53 0.019(2) 0.023(2) 0.027(2) 0.0096(18) 0.0055(17) 0.0015(17) C54 0.017(2) 0.025(2) 0.028(2) 0.0110(18) 0.0037(17) -0.0015(17) C55 0.015(2) 0.034(2) 0.032(2) 0.016(2) 0.0082(18) 0.0053(18) C511 0.047(3) 0.037(3) 0.052(3) 0.026(2) 0.030(3) 0.029(2) C521 0.052(3) 0.025(2) 0.031(3) -0.002(2) 0.014(2) -0.011(2) C531 0.023(2) 0.047(3) 0.027(2) 0.014(2) -0.0032(19) 0.001(2) C541 0.037(3) 0.028(2) 0.040(3) 0.020(2) 0.002(2) -0.007(2) C551 0.013(2) 0.072(4) 0.054(3) 0.034(3) 0.004(2) 0.001(2) O2 0.152(5) 0.047(3) 0.104(4) 0.009(3) 0.099(4) 0.035(3) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag In1 C15 2.259(4) . ? In1 Rh1 2.5351(6) . ? In1 C14 2.705(4) . ? In1 Cl1 2.8396(10) . ? In1 In2 3.2782(6) . ? In1 In3 3.3584(7) . ? In2 C25 2.436(4) . ? In2 Cl2 2.4476(11) . ? In2 Rh1 2.5493(5) . ? In2 Cl1 2.5734(11) . ? In2 In3 3.2636(8) . ? In3 C23 2.466(4) . ? In3 Cl3 2.4672(11) . ? In3 Rh1 2.5447(5) . ? In3 Cl4 2.5849(11) . ? Rh1 C32 2.197(4) . ? Rh1 C33 2.201(4) . ? Rh1 C34 2.211(4) . ? Rh1 C31 2.214(4) . ? Rh1 C35 2.217(4) . ? Rh2 C55 2.167(4) . ? Rh2 C54 2.168(4) . ? Rh2 C43 2.171(4) . ? Rh2 C42 2.175(4) . ? Rh2 C52 2.178(4) . ? Rh2 C51 2.179(4) . ? Rh2 C41 2.181(4) . ? Rh2 C53 2.183(4) . ? Rh2 C45 2.185(4) . ? Rh2 C44 2.194(4) . ? C11 C12 1.380(6) . ? C11 C15 1.453(5) . ? C11 C111 1.504(6) . ? C12 C13 1.436(6) . ? C12 C121 1.505(6) . ? C13 C14 1.385(6) . ? C13 C131 1.501(6) . ? C14 C15 1.458(6) . ? C14 C141 1.504(5) . ? C15 C151 1.515(6) . ? C21 C22 1.373(6) . ? C21 C25 1.461(6) . ? C21 C211 1.513(6) . ? C22 C23 1.454(6) . ? C22 C221 1.510(6) . ? C23 C24 1.420(6) . ? C23 C231 1.515(6) . ? C24 C25 1.416(6) . ? C24 C241 1.499(6) . ? C25 C251 1.516(6) . ? C31 C32 1.427(6) . ? C31 C35 1.435(6) . ? C31 C311 1.506(6) . ? C32 C33 1.435(6) . ? C32 C321 1.498(6) . ? C33 C34 1.427(6) . ? C33 C331 1.499(6) . ? C34 C35 1.435(6) . ? C34 C341 1.510(6) . ? C35 C351 1.498(6) . ? C41 C45 1.428(6) . ? C41 C42 1.429(6) . ? C41 C411 1.503(6) . ? C42 C43 1.430(6) . ? C42 C421 1.487(6) . ? C43 C44 1.423(6) . ? C43 C431 1.502(6) . ? C44 C45 1.430(6) . ? C44 C441 1.484(6) . ? C45 C451 1.493(6) . ? C51 C52 1.421(6) . ? C51 C55 1.431(6) . ? C51 C511 1.506(6) . ? C52 C53 1.430(6) . ? C52 C521 1.504(6) . ? C53 C54 1.431(6) . ? C53 C531 1.501(6) . ? C54 C55 1.432(6) . ? C54 C541 1.504(6) . ? C55 C551 1.492(6) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C15 In1 Rh1 163.86(10) . . ? C15 In1 C14 32.62(13) . . ? Rh1 In1 C14 135.80(9) . . ? C15 In1 Cl1 92.19(10) . . ? Rh1 In1 Cl1 99.15(2) . . ? C14 In1 Cl1 87.95(9) . . ? C15 In1 In2 139.95(10) . . ? Rh1 In1 In2 50.043(11) . . ? C14 In1 In2 121.47(8) . . ? Cl1 In1 In2 49.11(2) . . ? C15 In1 In3 143.60(10) . . ? Rh1 In1 In3 48.737(10) . . ? C14 In1 In3 175.07(9) . . ? Cl1 In1 In3 89.21(2) . . ? In2 In1 In3 58.898(16) . . ? C25 In2 Cl2 99.45(10) . . ? C25 In2 Rh1 126.31(9) . . ? Cl2 In2 Rh1 124.33(3) . . ? C25 In2 Cl1 94.69(10) . . ? Cl2 In2 Cl1 98.72(3) . . ? Rh1 In2 Cl1 106.19(2) . . ? C25 In2 In3 79.39(9) . . ? Cl2 In2 In3 165.11(3) . . ? Rh1 In2 In3 50.096(14) . . ? Cl1 In2 In3 96.17(2) . . ? C25 In2 In1 125.32(10) . . ? Cl2 In2 In1 127.68(3) . . ? Rh1 In2 In1 49.662(15) . . ? Cl1 In2 In1 56.53(2) . . ? In3 In2 In1 61.777(15) . . ? C23 In3 Cl3 98.32(10) . . ? C23 In3 Rh1 124.84(9) . . ? Cl3 In3 Rh1 122.52(3) . . ? C23 In3 Cl4 97.27(10) . . ? Cl3 In3 Cl4 102.46(3) . . ? Rh1 In3 Cl4 106.84(3) . . ? C23 In3 In2 78.19(9) . . ? Cl3 In3 In2 159.46(3) . . ? Rh1 In3 In2 50.220(10) . . ? Cl4 In3 In2 98.06(2) . . ? C23 In3 In1 123.74(9) . . ? Cl3 In3 In1 134.08(3) . . ? Rh1 In3 In1 48.491(15) . . ? Cl4 In3 In1 58.54(2) . . ? In2 In3 In1 59.325(9) . . ? C32 Rh1 C33 38.09(17) . . ? C32 Rh1 C34 63.27(16) . . ? C33 Rh1 C34 37.74(16) . . ? C32 Rh1 C31 37.74(16) . . ? C33 Rh1 C31 63.40(16) . . ? C34 Rh1 C31 63.22(15) . . ? C32 Rh1 C35 63.23(15) . . ? C33 Rh1 C35 63.32(15) . . ? C34 Rh1 C35 37.82(15) . . ? C31 Rh1 C35 37.81(14) . . ? C32 Rh1 In1 100.61(10) . . ? C33 Rh1 In1 114.93(12) . . ? C34 Rh1 In1 151.22(12) . . ? C31 Rh1 In1 119.55(10) . . ? C35 Rh1 In1 157.07(10) . . ? C32 Rh1 In3 137.66(12) . . ? C33 Rh1 In3 161.53(11) . . ? C34 Rh1 In3 125.53(12) . . ? C31 Rh1 In3 104.15(11) . . ? C35 Rh1 In3 98.37(11) . . ? In1 Rh1 In3 82.772(17) . . ? C32 Rh1 In2 142.65(12) . . ? C33 Rh1 In2 107.41(12) . . ? C34 Rh1 In2 98.30(10) . . ? C31 Rh1 In2 159.97(10) . . ? C35 Rh1 In2 122.54(10) . . ? In1 Rh1 In2 80.295(16) . . ? In3 Rh1 In2 79.684(19) . . ? C55 Rh2 C54 38.57(16) . . ? C55 Rh2 C43 171.80(16) . . ? C54 Rh2 C43 134.87(15) . . ? C55 Rh2 C42 148.72(15) . . ? C54 Rh2 C42 171.68(15) . . ? C43 Rh2 C42 38.41(15) . . ? C55 Rh2 C52 64.17(17) . . ? C54 Rh2 C52 64.39(16) . . ? C43 Rh2 C52 119.75(16) . . ? C42 Rh2 C52 113.05(15) . . ? C55 Rh2 C51 38.43(17) . . ? C54 Rh2 C51 64.42(16) . . ? C43 Rh2 C51 149.01(17) . . ? C42 Rh2 C51 119.02(15) . . ? C52 Rh2 C51 38.08(17) . . ? C55 Rh2 C41 119.21(16) . . ? C54 Rh2 C41 149.17(16) . . ? C43 Rh2 C41 64.06(15) . . ? C42 Rh2 C41 38.30(15) . . ? C52 Rh2 C41 134.24(16) . . ? C51 Rh2 C41 113.04(16) . . ? C55 Rh2 C53 64.14(16) . . ? C54 Rh2 C53 38.39(15) . . ? C43 Rh2 C53 113.84(15) . . ? C42 Rh2 C53 134.71(15) . . ? C52 Rh2 C53 38.27(15) . . ? C51 Rh2 C53 63.90(16) . . ? C41 Rh2 C53 171.22(16) . . ? C55 Rh2 C45 113.55(17) . . ? C54 Rh2 C45 119.83(17) . . ? C43 Rh2 C45 63.77(16) . . ? C42 Rh2 C45 63.95(16) . . ? C52 Rh2 C45 171.07(16) . . ? C51 Rh2 C45 134.75(17) . . ? C41 Rh2 C45 38.17(16) . . ? C53 Rh2 C45 149.82(16) . . ? C55 Rh2 C44 135.04(17) . . ? C54 Rh2 C44 113.73(16) . . ? C43 Rh2 C44 38.05(16) . . ? C42 Rh2 C44 64.04(15) . . ? C52 Rh2 C44 149.58(16) . . ? C51 Rh2 C44 171.69(17) . . ? C41 Rh2 C44 63.97(16) . . ? C53 Rh2 C44 120.25(16) . . ? C45 Rh2 C44 38.12(16) . . ? In2 Cl1 In1 74.36(3) . . ? C12 C11 C15 108.5(3) . . ? C12 C11 C111 126.6(4) . . ? C15 C11 C111 124.9(4) . . ? C11 C12 C13 108.8(3) . . ? C11 C12 C121 126.0(4) . . ? C13 C12 C121 125.1(4) . . ? C14 C13 C12 108.6(4) . . ? C14 C13 C131 125.6(4) . . ? C12 C13 C131 125.9(4) . . ? C13 C14 C15 108.3(3) . . ? C13 C14 C141 126.5(4) . . ? C15 C14 C141 125.1(4) . . ? C13 C14 In1 99.6(2) . . ? C15 C14 In1 56.64(19) . . ? C141 C14 In1 111.0(2) . . ? C11 C15 C14 105.8(3) . . ? C11 C15 C151 122.9(4) . . ? C14 C15 C151 123.6(4) . . ? C11 C15 In1 92.3(2) . . ? C14 C15 In1 90.7(2) . . ? C151 C15 In1 112.2(2) . . ? C22 C21 C25 108.9(4) . . ? C22 C21 C211 126.3(4) . . ? C25 C21 C211 124.9(4) . . ? C21 C22 C23 108.7(4) . . ? C21 C22 C221 127.2(4) . . ? C23 C22 C221 124.0(4) . . ? C24 C23 C22 106.7(3) . . ? C24 C23 C231 122.4(4) . . ? C22 C23 C231 124.0(4) . . ? C24 C23 In3 100.0(2) . . ? C22 C23 In3 95.5(2) . . ? C231 C23 In3 100.4(2) . . ? C25 C24 C23 109.1(3) . . ? C25 C24 C241 124.6(4) . . ? C23 C24 C241 125.4(4) . . ? C24 C25 C21 106.5(3) . . ? C24 C25 C251 122.0(4) . . ? C21 C25 C251 124.6(4) . . ? C24 C25 In2 101.0(2) . . ? C21 C25 In2 93.7(2) . . ? C251 C25 In2 101.3(3) . . ? C32 C31 C35 107.9(4) . . ? C32 C31 C311 126.9(4) . . ? C35 C31 C311 124.8(4) . . ? C32 C31 Rh1 70.5(2) . . ? C35 C31 Rh1 71.2(2) . . ? C311 C31 Rh1 129.6(3) . . ? C31 C32 C33 108.3(4) . . ? C31 C32 C321 124.9(4) . . ? C33 C32 C321 126.3(4) . . ? C31 C32 Rh1 71.7(2) . . ? C33 C32 Rh1 71.1(2) . . ? C321 C32 Rh1 129.4(3) . . ? C34 C33 C32 107.8(4) . . ? C34 C33 C331 126.9(5) . . ? C32 C33 C331 124.8(5) . . ? C34 C33 Rh1 71.5(2) . . ? C32 C33 Rh1 70.8(2) . . ? C331 C33 Rh1 129.2(3) . . ? C33 C34 C35 108.2(4) . . ? C33 C34 C341 126.2(4) . . ? C35 C34 C341 125.1(4) . . ? C33 C34 Rh1 70.7(2) . . ? C35 C34 Rh1 71.3(2) . . ? C341 C34 Rh1 129.5(3) . . ? C34 C35 C31 107.8(4) . . ? C34 C35 C351 125.7(4) . . ? C31 C35 C351 126.0(4) . . ? C34 C35 Rh1 70.9(2) . . ? C31 C35 Rh1 71.0(2) . . ? C351 C35 Rh1 130.1(3) . . ? C45 C41 C42 107.8(3) . . ? C45 C41 C411 126.5(4) . . ? C42 C41 C411 125.6(4) . . ? C45 C41 Rh2 71.1(2) . . ? C42 C41 Rh2 70.6(2) . . ? C411 C41 Rh2 124.7(3) . . ? C41 C42 C43 107.7(4) . . ? C41 C42 C421 125.3(4) . . ? C43 C42 C421 126.9(4) . . ? C41 C42 Rh2 71.1(2) . . ? C43 C42 Rh2 70.7(2) . . ? C421 C42 Rh2 125.5(3) . . ? C44 C43 C42 108.6(4) . . ? C44 C43 C431 125.9(4) . . ? C42 C43 C431 125.5(4) . . ? C44 C43 Rh2 71.8(2) . . ? C42 C43 Rh2 70.9(2) . . ? C431 C43 Rh2 124.7(3) . . ? C43 C44 C45 107.5(4) . . ? C43 C44 C441 125.9(4) . . ? C45 C44 C441 126.6(4) . . ? C43 C44 Rh2 70.1(2) . . ? C45 C44 Rh2 70.6(2) . . ? C441 C44 Rh2 126.5(3) . . ? C41 C45 C44 108.4(4) . . ? C41 C45 C451 126.5(4) . . ? C44 C45 C451 124.9(4) . . ? C41 C45 Rh2 70.8(2) . . ? C44 C45 Rh2 71.3(2) . . ? C451 C45 Rh2 127.0(4) . . ? C52 C51 C55 108.1(4) . . ? C52 C51 C511 126.6(4) . . ? C55 C51 C511 125.3(4) . . ? C52 C51 Rh2 70.9(2) . . ? C55 C51 Rh2 70.4(2) . . ? C511 C51 Rh2 125.9(3) . . ? C51 C52 C53 108.1(4) . . ? C51 C52 C521 126.3(4) . . ? C53 C52 C521 125.6(4) . . ? C51 C52 Rh2 71.0(2) . . ? C53 C52 Rh2 71.0(2) . . ? C521 C52 Rh2 125.5(3) . . ? C52 C53 C54 108.1(4) . . ? C52 C53 C531 126.2(4) . . ? C54 C53 C531 125.6(4) . . ? C52 C53 Rh2 70.7(2) . . ? C54 C53 Rh2 70.2(2) . . ? C531 C53 Rh2 126.5(3) . . ? C53 C54 C55 107.6(4) . . ? C53 C54 C541 125.9(4) . . ? C55 C54 C541 126.4(4) . . ? C53 C54 Rh2 71.4(2) . . ? C55 C54 Rh2 70.7(2) . . ? C541 C54 Rh2 125.6(3) . . ? C51 C55 C54 108.1(4) . . ? C51 C55 C551 125.6(4) . . ? C54 C55 C551 126.3(4) . . ? C51 C55 Rh2 71.2(2) . . ? C54 C55 Rh2 70.7(2) . . ? C551 C55 Rh2 124.6(4) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C15 In1 In2 C25 -87.53(19) . . . . ? Rh1 In1 In2 C25 110.51(12) . . . . ? C14 In1 In2 C25 -123.78(15) . . . . ? Cl1 In1 In2 C25 -69.61(12) . . . . ? In3 In1 In2 C25 50.47(12) . . . . ? C15 In1 In2 Cl2 55.76(16) . . . . ? Rh1 In1 In2 Cl2 -106.20(4) . . . . ? C14 In1 In2 Cl2 19.51(11) . . . . ? Cl1 In1 In2 Cl2 73.68(4) . . . . ? In3 In1 In2 Cl2 -166.24(4) . . . . ? C15 In1 In2 Rh1 161.96(16) . . . . ? C14 In1 In2 Rh1 125.72(10) . . . . ? Cl1 In1 In2 Rh1 179.88(3) . . . . ? In3 In1 In2 Rh1 -60.041(13) . . . . ? C15 In1 In2 Cl1 -17.92(16) . . . . ? Rh1 In1 In2 Cl1 -179.88(3) . . . . ? C14 In1 In2 Cl1 -54.17(11) . . . . ? In3 In1 In2 Cl1 120.08(3) . . . . ? C15 In1 In2 In3 -138.00(16) . . . . ? Rh1 In1 In2 In3 60.041(13) . . . . ? C14 In1 In2 In3 -174.24(10) . . . . ? Cl1 In1 In2 In3 -120.08(3) . . . . ? C25 In2 In3 C23 1.42(14) . . . . ? Cl2 In2 In3 C23 -85.47(15) . . . . ? Rh1 In2 In3 C23 -158.98(10) . . . . ? Cl1 In2 In3 C23 95.05(10) . . . . ? In1 In2 In3 C23 141.61(10) . . . . ? C25 In2 In3 Cl3 83.58(13) . . . . ? Cl2 In2 In3 Cl3 -3.31(14) . . . . ? Rh1 In2 In3 Cl3 -76.81(8) . . . . ? Cl1 In2 In3 Cl3 177.22(8) . . . . ? In1 In2 In3 Cl3 -136.23(8) . . . . ? C25 In2 In3 Rh1 160.39(10) . . . . ? Cl2 In2 In3 Rh1 73.51(11) . . . . ? Cl1 In2 In3 Rh1 -105.97(3) . . . . ? In1 In2 In3 Rh1 -59.415(19) . . . . ? C25 In2 In3 Cl4 -94.38(10) . . . . ? Cl2 In2 In3 Cl4 178.74(11) . . . . ? Rh1 In2 In3 Cl4 105.23(3) . . . . ? Cl1 In2 In3 Cl4 -0.74(3) . . . . ? In1 In2 In3 Cl4 45.82(2) . . . . ? C25 In2 In3 In1 -140.19(10) . . . . ? Cl2 In2 In3 In1 132.92(11) . . . . ? Rh1 In2 In3 In1 59.415(19) . . . . ? Cl1 In2 In3 In1 -46.55(2) . . . . ? C15 In1 In3 C23 86.5(2) . . . . ? Rh1 In1 In3 C23 -109.04(11) . . . . ? C14 In1 In3 C23 48.8(10) . . . . ? Cl1 In1 In3 C23 -6.12(11) . . . . ? In2 In1 In3 C23 -46.98(11) . . . . ? C15 In1 In3 Cl3 -66.26(17) . . . . ? Rh1 In1 In3 Cl3 98.19(4) . . . . ? C14 In1 In3 Cl3 -104.0(10) . . . . ? Cl1 In1 In3 Cl3 -158.89(4) . . . . ? In2 In1 In3 Cl3 160.25(4) . . . . ? C15 In1 In3 Rh1 -164.45(17) . . . . ? C14 In1 In3 Rh1 157.8(10) . . . . ? Cl1 In1 In3 Rh1 102.92(3) . . . . ? In2 In1 In3 Rh1 62.064(13) . . . . ? C15 In1 In3 Cl4 9.83(17) . . . . ? Rh1 In1 In3 Cl4 174.28(3) . . . . ? C14 In1 In3 Cl4 -27.9(10) . . . . ? Cl1 In1 In3 Cl4 -82.79(3) . . . . ? In2 In1 In3 Cl4 -123.65(3) . . . . ? C15 In1 In3 In2 133.49(16) . . . . ? Rh1 In1 In3 In2 -62.064(13) . . . . ? C14 In1 In3 In2 95.7(10) . . . . ? Cl1 In1 In3 In2 40.86(2) . . . . ? C15 In1 Rh1 C32 7.8(4) . . . . ? C14 In1 Rh1 C32 45.42(17) . . . . ? Cl1 In1 Rh1 C32 141.95(12) . . . . ? In2 In1 Rh1 C32 142.04(12) . . . . ? In3 In1 Rh1 C32 -137.25(12) . . . . ? C15 In1 Rh1 C33 -29.4(4) . . . . ? C14 In1 Rh1 C33 8.17(18) . . . . ? Cl1 In1 Rh1 C33 104.70(13) . . . . ? In2 In1 Rh1 C33 104.79(13) . . . . ? In3 In1 Rh1 C33 -174.50(13) . . . . ? C15 In1 Rh1 C34 -44.6(4) . . . . ? C14 In1 Rh1 C34 -7.0(2) . . . . ? Cl1 In1 Rh1 C34 89.5(2) . . . . ? In2 In1 Rh1 C34 89.6(2) . . . . ? In3 In1 Rh1 C34 170.3(2) . . . . ? C15 In1 Rh1 C31 42.9(4) . . . . ? C14 In1 Rh1 C31 80.47(18) . . . . ? Cl1 In1 Rh1 C31 177.00(13) . . . . ? In2 In1 Rh1 C31 177.09(13) . . . . ? In3 In1 Rh1 C31 -102.20(13) . . . . ? C15 In1 Rh1 C35 50.7(5) . . . . ? C14 In1 Rh1 C35 88.3(3) . . . . ? Cl1 In1 Rh1 C35 -175.2(3) . . . . ? In2 In1 Rh1 C35 -175.1(3) . . . . ? In3 In1 Rh1 C35 -94.4(3) . . . . ? C15 In1 Rh1 In3 145.1(4) . . . . ? C14 In1 Rh1 In3 -177.33(12) . . . . ? Cl1 In1 Rh1 In3 -80.80(3) . . . . ? In2 In1 Rh1 In3 -80.709(19) . . . . ? C15 In1 Rh1 In2 -134.2(4) . . . . ? C14 In1 Rh1 In2 -96.62(12) . . . . ? Cl1 In1 Rh1 In2 -0.09(2) . . . . ? In3 In1 Rh1 In2 80.709(19) . . . . ? C23 In3 Rh1 C32 -155.44(19) . . . . ? Cl3 In3 Rh1 C32 -24.68(16) . . . . ? Cl4 In3 Rh1 C32 92.74(16) . . . . ? In2 In3 Rh1 C32 179.23(15) . . . . ? In1 In3 Rh1 C32 97.83(15) . . . . ? C23 In3 Rh1 C33 -89.2(4) . . . . ? Cl3 In3 Rh1 C33 41.6(4) . . . . ? Cl4 In3 Rh1 C33 159.0(4) . . . . ? In2 In3 Rh1 C33 -114.5(4) . . . . ? In1 In3 Rh1 C33 164.1(4) . . . . ? C23 In3 Rh1 C34 -67.55(17) . . . . ? Cl3 In3 Rh1 C34 63.22(13) . . . . ? Cl4 In3 Rh1 C34 -179.37(13) . . . . ? In2 In3 Rh1 C34 -92.88(13) . . . . ? In1 In3 Rh1 C34 -174.28(13) . . . . ? C23 In3 Rh1 C31 -134.54(15) . . . . ? Cl3 In3 Rh1 C31 -3.77(11) . . . . ? Cl4 In3 Rh1 C31 113.64(11) . . . . ? In2 In3 Rh1 C31 -159.87(11) . . . . ? In1 In3 Rh1 C31 118.73(11) . . . . ? C23 In3 Rh1 C35 -96.40(15) . . . . ? Cl3 In3 Rh1 C35 34.37(11) . . . . ? Cl4 In3 Rh1 C35 151.79(11) . . . . ? In2 In3 Rh1 C35 -121.73(11) . . . . ? In1 In3 Rh1 C35 156.88(11) . . . . ? C23 In3 Rh1 In1 106.72(11) . . . . ? Cl3 In3 Rh1 In1 -122.51(3) . . . . ? Cl4 In3 Rh1 In1 -5.09(2) . . . . ? In2 In3 Rh1 In1 81.394(14) . . . . ? C23 In3 Rh1 In2 25.33(11) . . . . ? Cl3 In3 Rh1 In2 156.10(3) . . . . ? Cl4 In3 Rh1 In2 -86.49(3) . . . . ? In1 In3 Rh1 In2 -81.394(14) . . . . ? C25 In2 Rh1 C32 156.7(2) . . . . ? Cl2 In2 Rh1 C32 18.22(18) . . . . ? Cl1 In2 Rh1 C32 -94.70(17) . . . . ? In3 In2 Rh1 C32 -179.14(17) . . . . ? In1 In2 Rh1 C32 -94.80(17) . . . . ? C25 In2 Rh1 C33 138.26(17) . . . . ? Cl2 In2 Rh1 C33 -0.21(13) . . . . ? Cl1 In2 Rh1 C33 -113.13(12) . . . . ? In3 In2 Rh1 C33 162.42(12) . . . . ? In1 In2 Rh1 C33 -113.24(12) . . . . ? C25 In2 Rh1 C34 100.61(17) . . . . ? Cl2 In2 Rh1 C34 -37.86(12) . . . . ? Cl1 In2 Rh1 C34 -150.78(12) . . . . ? In3 In2 Rh1 C34 124.77(12) . . . . ? In1 In2 Rh1 C34 -150.88(12) . . . . ? C25 In2 Rh1 C31 78.9(4) . . . . ? Cl2 In2 Rh1 C31 -59.6(3) . . . . ? Cl1 In2 Rh1 C31 -172.5(3) . . . . ? In3 In2 Rh1 C31 103.1(3) . . . . ? In1 In2 Rh1 C31 -172.6(3) . . . . ? C25 In2 Rh1 C35 69.25(17) . . . . ? Cl2 In2 Rh1 C35 -69.23(13) . . . . ? Cl1 In2 Rh1 C35 177.85(13) . . . . ? In3 In2 Rh1 C35 93.41(13) . . . . ? In1 In2 Rh1 C35 177.75(13) . . . . ? C25 In2 Rh1 In1 -108.50(12) . . . . ? Cl2 In2 Rh1 In1 113.02(4) . . . . ? Cl1 In2 Rh1 In1 0.10(2) . . . . ? In3 In2 Rh1 In1 -84.341(17) . . . . ? C25 In2 Rh1 In3 -24.16(12) . . . . ? Cl2 In2 Rh1 In3 -162.64(3) . . . . ? Cl1 In2 Rh1 In3 84.44(3) . . . . ? In1 In2 Rh1 In3 84.341(17) . . . . ? C25 In2 Cl1 In1 129.88(10) . . . . ? Cl2 In2 Cl1 In1 -129.79(3) . . . . ? Rh1 In2 Cl1 In1 -0.09(2) . . . . ? In3 In2 Cl1 In1 50.08(2) . . . . ? C15 In1 Cl1 In2 168.57(10) . . . . ? Rh1 In1 Cl1 In2 0.09(2) . . . . ? C14 In1 Cl1 In2 136.22(9) . . . . ? In3 In1 Cl1 In2 -47.818(19) . . . . ? C15 C11 C12 C13 0.9(4) . . . . ? C111 C11 C12 C13 -176.7(4) . . . . ? C15 C11 C12 C121 -178.5(4) . . . . ? C111 C11 C12 C121 3.9(6) . . . . ? C11 C12 C13 C14 1.1(4) . . . . ? C121 C12 C13 C14 -179.5(4) . . . . ? C11 C12 C13 C131 -179.8(4) . . . . ? C121 C12 C13 C131 -0.4(6) . . . . ? C12 C13 C14 C15 -2.6(4) . . . . ? C131 C13 C14 C15 178.3(4) . . . . ? C12 C13 C14 C141 174.2(4) . . . . ? C131 C13 C14 C141 -4.9(6) . . . . ? C12 C13 C14 In1 -60.5(3) . . . . ? C131 C13 C14 In1 120.4(4) . . . . ? C15 In1 C14 C13 105.6(3) . . . . ? Rh1 In1 C14 C13 -56.0(3) . . . . ? Cl1 In1 C14 C13 -157.1(3) . . . . ? In2 In1 C14 C13 -119.3(2) . . . . ? In3 In1 C14 C13 148.0(8) . . . . ? Rh1 In1 C14 C15 -161.67(19) . . . . ? Cl1 In1 C14 C15 97.3(2) . . . . ? In2 In1 C14 C15 135.1(2) . . . . ? In3 In1 C14 C15 42.4(11) . . . . ? C15 In1 C14 C141 -119.0(4) . . . . ? Rh1 In1 C14 C141 79.3(3) . . . . ? Cl1 In1 C14 C141 -21.7(3) . . . . ? In2 In1 C14 C141 16.1(3) . . . . ? In3 In1 C14 C141 -76.6(10) . . . . ? C12 C11 C15 C14 -2.4(4) . . . . ? C111 C11 C15 C14 175.3(4) . . . . ? C12 C11 C15 C151 -152.5(4) . . . . ? C111 C11 C15 C151 25.2(6) . . . . ? C12 C11 C15 In1 89.1(3) . . . . ? C111 C11 C15 In1 -93.3(4) . . . . ? C13 C14 C15 C11 3.0(4) . . . . ? C141 C14 C15 C11 -173.8(3) . . . . ? In1 C14 C15 C11 92.6(3) . . . . ? C13 C14 C15 C151 152.9(4) . . . . ? C141 C14 C15 C151 -24.0(6) . . . . ? In1 C14 C15 C151 -117.5(4) . . . . ? C13 C14 C15 In1 -89.6(3) . . . . ? C141 C14 C15 In1 93.6(4) . . . . ? Rh1 In1 C15 C11 -53.8(5) . . . . ? C14 In1 C15 C11 -105.9(3) . . . . ? Cl1 In1 C15 C11 171.4(2) . . . . ? In2 In1 C15 C11 -175.15(17) . . . . ? In3 In1 C15 C11 79.7(3) . . . . ? Rh1 In1 C15 C14 52.1(5) . . . . ? Cl1 In1 C15 C14 -82.7(2) . . . . ? In2 In1 C15 C14 -69.3(3) . . . . ? In3 In1 C15 C14 -174.40(16) . . . . ? Rh1 In1 C15 C151 179.1(2) . . . . ? C14 In1 C15 C151 127.0(4) . . . . ? Cl1 In1 C15 C151 44.3(3) . . . . ? In2 In1 C15 C151 57.8(3) . . . . ? In3 In1 C15 C151 -47.3(4) . . . . ? C25 C21 C22 C23 0.2(5) . . . . ? C211 C21 C22 C23 -179.4(4) . . . . ? C25 C21 C22 C221 177.2(4) . . . . ? C211 C21 C22 C221 -2.4(7) . . . . ? C21 C22 C23 C24 1.9(5) . . . . ? C221 C22 C23 C24 -175.2(4) . . . . ? C21 C22 C23 C231 153.3(4) . . . . ? C221 C22 C23 C231 -23.8(6) . . . . ? C21 C22 C23 In3 -100.2(3) . . . . ? C221 C22 C23 In3 82.7(4) . . . . ? Cl3 In3 C23 C24 163.1(2) . . . . ? Rh1 In3 C23 C24 -57.1(3) . . . . ? Cl4 In3 C23 C24 59.3(3) . . . . ? In2 In3 C23 C24 -37.5(2) . . . . ? In1 In3 C23 C24 2.5(3) . . . . ? Cl3 In3 C23 C22 -88.8(2) . . . . ? Rh1 In3 C23 C22 51.0(3) . . . . ? Cl4 In3 C23 C22 167.4(2) . . . . ? In2 In3 C23 C22 70.6(2) . . . . ? In1 In3 C23 C22 110.6(2) . . . . ? Cl3 In3 C23 C231 37.2(3) . . . . ? Rh1 In3 C23 C231 177.0(2) . . . . ? Cl4 In3 C23 C231 -66.6(2) . . . . ? In2 In3 C23 C231 -163.4(3) . . . . ? In1 In3 C23 C231 -123.4(2) . . . . ? C22 C23 C24 C25 -3.4(4) . . . . ? C231 C23 C24 C25 -155.3(4) . . . . ? In3 C23 C24 C25 95.5(3) . . . . ? C22 C23 C24 C241 166.3(4) . . . . ? C231 C23 C24 C241 14.4(6) . . . . ? In3 C23 C24 C241 -94.8(4) . . . . ? C23 C24 C25 C21 3.5(4) . . . . ? C241 C24 C25 C21 -166.3(4) . . . . ? C23 C24 C25 C251 155.4(4) . . . . ? C241 C24 C25 C251 -14.4(6) . . . . ? C23 C24 C25 In2 -93.7(3) . . . . ? C241 C24 C25 In2 96.4(4) . . . . ? C22 C21 C25 C24 -2.3(4) . . . . ? C211 C21 C25 C24 177.3(4) . . . . ? C22 C21 C25 C251 -153.3(4) . . . . ? C211 C21 C25 C251 26.3(6) . . . . ? C22 C21 C25 In2 100.3(3) . . . . ? C211 C21 C25 In2 -80.1(4) . . . . ? Cl2 In2 C25 C24 -160.4(2) . . . . ? Rh1 In2 C25 C24 53.3(3) . . . . ? Cl1 In2 C25 C24 -60.7(2) . . . . ? In3 In2 C25 C24 34.7(2) . . . . ? In1 In2 C25 C24 -9.1(3) . . . . ? Cl2 In2 C25 C21 92.0(2) . . . . ? Rh1 In2 C25 C21 -54.3(3) . . . . ? Cl1 In2 C25 C21 -168.3(2) . . . . ? In3 In2 C25 C21 -72.9(2) . . . . ? In1 In2 C25 C21 -116.6(2) . . . . ? Cl2 In2 C25 C251 -34.3(3) . . . . ? Rh1 In2 C25 C251 179.4(2) . . . . ? Cl1 In2 C25 C251 65.3(3) . . . . ? In3 In2 C25 C251 160.8(3) . . . . ? In1 In2 C25 C251 117.0(2) . . . . ? C33 Rh1 C31 C32 37.7(2) . . . . ? C34 Rh1 C31 C32 80.2(3) . . . . ? C35 Rh1 C31 C32 117.7(3) . . . . ? In1 Rh1 C31 C32 -67.2(3) . . . . ? In3 Rh1 C31 C32 -156.9(2) . . . . ? In2 Rh1 C31 C32 104.4(4) . . . . ? C32 Rh1 C31 C35 -117.7(3) . . . . ? C33 Rh1 C31 C35 -80.0(3) . . . . ? C34 Rh1 C31 C35 -37.5(2) . . . . ? In1 Rh1 C31 C35 175.06(19) . . . . ? In3 Rh1 C31 C35 85.4(2) . . . . ? In2 Rh1 C31 C35 -13.3(5) . . . . ? C32 Rh1 C31 C311 122.2(5) . . . . ? C33 Rh1 C31 C311 159.9(5) . . . . ? C34 Rh1 C31 C311 -157.6(5) . . . . ? C35 Rh1 C31 C311 -120.1(5) . . . . ? In1 Rh1 C31 C311 55.0(4) . . . . ? In3 Rh1 C31 C311 -34.7(4) . . . . ? In2 Rh1 C31 C311 -133.4(4) . . . . ? C35 C31 C32 C33 -0.3(4) . . . . ? C311 C31 C32 C33 172.5(4) . . . . ? Rh1 C31 C32 C33 -62.1(3) . . . . ? C35 C31 C32 C321 -172.4(4) . . . . ? C311 C31 C32 C321 0.4(7) . . . . ? Rh1 C31 C32 C321 125.8(4) . . . . ? C35 C31 C32 Rh1 61.8(3) . . . . ? C311 C31 C32 Rh1 -125.4(4) . . . . ? C33 Rh1 C32 C31 -117.6(3) . . . . ? C34 Rh1 C32 C31 -80.0(2) . . . . ? C35 Rh1 C32 C31 -37.4(2) . . . . ? In1 Rh1 C32 C31 125.3(2) . . . . ? In3 Rh1 C32 C31 34.4(3) . . . . ? In2 Rh1 C32 C31 -146.84(19) . . . . ? C34 Rh1 C32 C33 37.6(2) . . . . ? C31 Rh1 C32 C33 117.6(3) . . . . ? C35 Rh1 C32 C33 80.1(3) . . . . ? In1 Rh1 C32 C33 -117.1(2) . . . . ? In3 Rh1 C32 C33 151.97(19) . . . . ? In2 Rh1 C32 C33 -29.3(3) . . . . ? C33 Rh1 C32 C321 121.8(6) . . . . ? C34 Rh1 C32 C321 159.4(5) . . . . ? C31 Rh1 C32 C321 -120.6(6) . . . . ? C35 Rh1 C32 C321 -158.0(5) . . . . ? In1 Rh1 C32 C321 4.7(5) . . . . ? In3 Rh1 C32 C321 -86.2(5) . . . . ? In2 Rh1 C32 C321 92.6(5) . . . . ? C31 C32 C33 C34 0.1(5) . . . . ? C321 C32 C33 C34 172.1(4) . . . . ? Rh1 C32 C33 C34 -62.3(3) . . . . ? C31 C32 C33 C331 -172.6(4) . . . . ? C321 C32 C33 C331 -0.6(7) . . . . ? Rh1 C32 C33 C331 124.9(4) . . . . ? C31 C32 C33 Rh1 62.5(3) . . . . ? C321 C32 C33 Rh1 -125.5(4) . . . . ? C32 Rh1 C33 C34 117.2(3) . . . . ? C31 Rh1 C33 C34 79.8(2) . . . . ? C35 Rh1 C33 C34 37.3(2) . . . . ? In1 Rh1 C33 C34 -168.09(19) . . . . ? In3 Rh1 C33 C34 29.4(5) . . . . ? In2 Rh1 C33 C34 -80.9(2) . . . . ? C34 Rh1 C33 C32 -117.2(3) . . . . ? C31 Rh1 C33 C32 -37.4(2) . . . . ? C35 Rh1 C33 C32 -79.9(2) . . . . ? In1 Rh1 C33 C32 74.7(2) . . . . ? In3 Rh1 C33 C32 -87.8(5) . . . . ? In2 Rh1 C33 C32 161.9(2) . . . . ? C32 Rh1 C33 C331 -119.8(6) . . . . ? C34 Rh1 C33 C331 123.0(6) . . . . ? C31 Rh1 C33 C331 -157.1(5) . . . . ? C35 Rh1 C33 C331 160.4(5) . . . . ? In1 Rh1 C33 C331 -45.1(5) . . . . ? In3 Rh1 C33 C331 152.4(4) . . . . ? In2 Rh1 C33 C331 42.1(5) . . . . ? C32 C33 C34 C35 0.1(4) . . . . ? C331 C33 C34 C35 172.6(4) . . . . ? Rh1 C33 C34 C35 -61.8(3) . . . . ? C32 C33 C34 C341 -172.7(4) . . . . ? C331 C33 C34 C341 -0.2(7) . . . . ? Rh1 C33 C34 C341 125.4(4) . . . . ? C32 C33 C34 Rh1 61.9(3) . . . . ? C331 C33 C34 Rh1 -125.6(4) . . . . ? C32 Rh1 C34 C33 -37.9(2) . . . . ? C31 Rh1 C34 C33 -80.4(3) . . . . ? C35 Rh1 C34 C33 -117.9(3) . . . . ? In1 Rh1 C34 C33 22.9(4) . . . . ? In3 Rh1 C34 C33 -169.0(2) . . . . ? In2 Rh1 C34 C33 107.8(2) . . . . ? C32 Rh1 C34 C35 80.0(3) . . . . ? C33 Rh1 C34 C35 117.9(3) . . . . ? C31 Rh1 C34 C35 37.5(2) . . . . ? In1 Rh1 C34 C35 140.8(2) . . . . ? In3 Rh1 C34 C35 -51.1(3) . . . . ? In2 Rh1 C34 C35 -134.3(2) . . . . ? C32 Rh1 C34 C341 -159.4(5) . . . . ? C33 Rh1 C34 C341 -121.5(5) . . . . ? C31 Rh1 C34 C341 158.1(5) . . . . ? C35 Rh1 C34 C341 120.6(6) . . . . ? In1 Rh1 C34 C341 -98.7(5) . . . . ? In3 Rh1 C34 C341 69.5(5) . . . . ? In2 Rh1 C34 C341 -13.7(5) . . . . ? C33 C34 C35 C31 -0.3(4) . . . . ? C341 C34 C35 C31 172.6(4) . . . . ? Rh1 C34 C35 C31 -61.7(3) . . . . ? C33 C34 C35 C351 -172.4(4) . . . . ? C341 C34 C35 C351 0.4(6) . . . . ? Rh1 C34 C35 C351 126.1(4) . . . . ? C33 C34 C35 Rh1 61.5(3) . . . . ? C341 C34 C35 Rh1 -125.7(4) . . . . ? C32 C31 C35 C34 0.4(4) . . . . ? C311 C31 C35 C34 -172.7(4) . . . . ? Rh1 C31 C35 C34 61.7(3) . . . . ? C32 C31 C35 C351 172.5(4) . . . . ? C311 C31 C35 C351 -0.6(7) . . . . ? Rh1 C31 C35 C351 -126.2(4) . . . . ? C32 C31 C35 Rh1 -61.3(3) . . . . ? C311 C31 C35 Rh1 125.7(4) . . . . ? C32 Rh1 C35 C34 -80.1(3) . . . . ? C33 Rh1 C35 C34 -37.3(3) . . . . ? C31 Rh1 C35 C34 -117.5(3) . . . . ? In1 Rh1 C35 C34 -128.6(3) . . . . ? In3 Rh1 C35 C34 140.2(2) . . . . ? In2 Rh1 C35 C34 57.1(3) . . . . ? C32 Rh1 C35 C31 37.4(2) . . . . ? C33 Rh1 C35 C31 80.2(3) . . . . ? C34 Rh1 C35 C31 117.5(3) . . . . ? In1 Rh1 C35 C31 -11.1(4) . . . . ? In3 Rh1 C35 C31 -102.3(2) . . . . ? In2 Rh1 C35 C31 174.6(2) . . . . ? C32 Rh1 C35 C351 158.8(5) . . . . ? C33 Rh1 C35 C351 -158.3(5) . . . . ? C34 Rh1 C35 C351 -121.1(5) . . . . ? C31 Rh1 C35 C351 121.4(5) . . . . ? In1 Rh1 C35 C351 110.3(4) . . . . ? In3 Rh1 C35 C351 19.1(4) . . . . ? In2 Rh1 C35 C351 -63.9(4) . . . . ? C55 Rh2 C41 C45 91.7(3) . . . . ? C54 Rh2 C41 C45 55.9(4) . . . . ? C43 Rh2 C41 C45 -79.8(3) . . . . ? C42 Rh2 C41 C45 -117.6(3) . . . . ? C52 Rh2 C41 C45 172.9(3) . . . . ? C51 Rh2 C41 C45 134.2(3) . . . . ? C53 Rh2 C41 C45 -158.0(9) . . . . ? C44 Rh2 C41 C45 -37.3(3) . . . . ? C55 Rh2 C41 C42 -150.7(2) . . . . ? C54 Rh2 C41 C42 173.5(3) . . . . ? C43 Rh2 C41 C42 37.8(2) . . . . ? C52 Rh2 C41 C42 -69.4(3) . . . . ? C51 Rh2 C41 C42 -108.2(2) . . . . ? C53 Rh2 C41 C42 -40.4(11) . . . . ? C45 Rh2 C41 C42 117.6(3) . . . . ? C44 Rh2 C41 C42 80.3(2) . . . . ? C55 Rh2 C41 C411 -30.1(4) . . . . ? C54 Rh2 C41 C411 -65.9(5) . . . . ? C43 Rh2 C41 C411 158.3(4) . . . . ? C42 Rh2 C41 C411 120.5(5) . . . . ? C52 Rh2 C41 C411 51.1(5) . . . . ? C51 Rh2 C41 C411 12.3(4) . . . . ? C53 Rh2 C41 C411 80.1(11) . . . . ? C45 Rh2 C41 C411 -121.8(5) . . . . ? C44 Rh2 C41 C411 -159.1(4) . . . . ? C45 C41 C42 C43 0.1(5) . . . . ? C411 C41 C42 C43 179.1(4) . . . . ? Rh2 C41 C42 C43 -61.5(3) . . . . ? C45 C41 C42 C421 -177.8(4) . . . . ? C411 C41 C42 C421 1.2(7) . . . . ? Rh2 C41 C42 C421 120.6(4) . . . . ? C45 C41 C42 Rh2 61.7(3) . . . . ? C411 C41 C42 Rh2 -119.4(4) . . . . ? C55 Rh2 C42 C41 55.4(4) . . . . ? C54 Rh2 C42 C41 -156.5(10) . . . . ? C43 Rh2 C42 C41 -117.4(3) . . . . ? C52 Rh2 C42 C41 133.2(2) . . . . ? C51 Rh2 C42 C41 91.1(3) . . . . ? C53 Rh2 C42 C41 172.0(2) . . . . ? C45 Rh2 C42 C41 -37.5(2) . . . . ? C44 Rh2 C42 C41 -80.2(3) . . . . ? C55 Rh2 C42 C43 172.9(3) . . . . ? C54 Rh2 C42 C43 -39.0(11) . . . . ? C52 Rh2 C42 C43 -109.3(2) . . . . ? C51 Rh2 C42 C43 -151.4(2) . . . . ? C41 Rh2 C42 C43 117.4(3) . . . . ? C53 Rh2 C42 C43 -70.6(3) . . . . ? C45 Rh2 C42 C43 79.9(3) . . . . ? C44 Rh2 C42 C43 37.3(2) . . . . ? C55 Rh2 C42 C421 -65.0(5) . . . . ? C54 Rh2 C42 C421 83.1(11) . . . . ? C43 Rh2 C42 C421 122.1(4) . . . . ? C52 Rh2 C42 C421 12.8(4) . . . . ? C51 Rh2 C42 C421 -29.3(4) . . . . ? C41 Rh2 C42 C421 -120.4(4) . . . . ? C53 Rh2 C42 C421 51.6(4) . . . . ? C45 Rh2 C42 C421 -158.0(4) . . . . ? C44 Rh2 C42 C421 159.4(4) . . . . ? C41 C42 C43 C44 -0.6(5) . . . . ? C421 C42 C43 C44 177.3(4) . . . . ? Rh2 C42 C43 C44 -62.3(3) . . . . ? C41 C42 C43 C431 -178.7(4) . . . . ? C421 C42 C43 C431 -0.8(7) . . . . ? Rh2 C42 C43 C431 119.6(4) . . . . ? C41 C42 C43 Rh2 61.8(3) . . . . ? C421 C42 C43 Rh2 -120.4(4) . . . . ? C55 Rh2 C43 C44 -35.2(12) . . . . ? C54 Rh2 C43 C44 -69.5(3) . . . . ? C42 Rh2 C43 C44 117.9(3) . . . . ? C52 Rh2 C43 C44 -151.8(2) . . . . ? C51 Rh2 C43 C44 172.2(3) . . . . ? C41 Rh2 C43 C44 80.2(3) . . . . ? C53 Rh2 C43 C44 -109.2(3) . . . . ? C45 Rh2 C43 C44 37.5(2) . . . . ? C55 Rh2 C43 C42 -153.2(11) . . . . ? C54 Rh2 C43 C42 172.6(2) . . . . ? C52 Rh2 C43 C42 90.3(3) . . . . ? C51 Rh2 C43 C42 54.3(4) . . . . ? C41 Rh2 C43 C42 -37.7(2) . . . . ? C53 Rh2 C43 C42 132.9(2) . . . . ? C45 Rh2 C43 C42 -80.4(3) . . . . ? C44 Rh2 C43 C42 -117.9(3) . . . . ? C55 Rh2 C43 C431 86.3(12) . . . . ? C54 Rh2 C43 C431 52.1(5) . . . . ? C42 Rh2 C43 C431 -120.5(5) . . . . ? C52 Rh2 C43 C431 -30.2(4) . . . . ? C51 Rh2 C43 C431 -66.2(5) . . . . ? C41 Rh2 C43 C431 -158.2(4) . . . . ? C53 Rh2 C43 C431 12.4(4) . . . . ? C45 Rh2 C43 C431 159.1(4) . . . . ? C44 Rh2 C43 C431 121.6(5) . . . . ? C42 C43 C44 C45 0.7(5) . . . . ? C431 C43 C44 C45 178.8(4) . . . . ? Rh2 C43 C44 C45 -61.0(3) . . . . ? C42 C43 C44 C441 -177.0(4) . . . . ? C431 C43 C44 C441 1.1(7) . . . . ? Rh2 C43 C44 C441 121.2(5) . . . . ? C42 C43 C44 Rh2 61.8(3) . . . . ? C431 C43 C44 Rh2 -120.1(4) . . . . ? C55 Rh2 C44 C43 173.3(2) . . . . ? C54 Rh2 C44 C43 133.5(2) . . . . ? C42 Rh2 C44 C43 -37.6(2) . . . . ? C52 Rh2 C44 C43 54.1(4) . . . . ? C51 Rh2 C44 C43 -151.2(10) . . . . ? C41 Rh2 C44 C43 -80.4(3) . . . . ? C53 Rh2 C44 C43 90.8(3) . . . . ? C45 Rh2 C44 C43 -117.8(4) . . . . ? C55 Rh2 C44 C45 -68.9(3) . . . . ? C54 Rh2 C44 C45 -108.7(3) . . . . ? C43 Rh2 C44 C45 117.8(4) . . . . ? C42 Rh2 C44 C45 80.2(3) . . . . ? C52 Rh2 C44 C45 171.9(3) . . . . ? C51 Rh2 C44 C45 -33.4(12) . . . . ? C41 Rh2 C44 C45 37.4(3) . . . . ? C53 Rh2 C44 C45 -151.4(3) . . . . ? C55 Rh2 C44 C441 52.8(5) . . . . ? C54 Rh2 C44 C441 13.0(5) . . . . ? C43 Rh2 C44 C441 -120.5(5) . . . . ? C42 Rh2 C44 C441 -158.1(5) . . . . ? C52 Rh2 C44 C441 -66.4(5) . . . . ? C51 Rh2 C44 C441 88.3(12) . . . . ? C41 Rh2 C44 C441 159.1(5) . . . . ? C53 Rh2 C44 C441 -29.7(5) . . . . ? C45 Rh2 C44 C441 121.7(5) . . . . ? C42 C41 C45 C44 0.3(5) . . . . ? C411 C41 C45 C44 -178.6(4) . . . . ? Rh2 C41 C45 C44 61.7(3) . . . . ? C42 C41 C45 C451 176.3(4) . . . . ? C411 C41 C45 C451 -2.6(8) . . . . ? Rh2 C41 C45 C451 -122.3(5) . . . . ? C42 C41 C45 Rh2 -61.4(3) . . . . ? C411 C41 C45 Rh2 119.7(4) . . . . ? C43 C44 C45 C41 -0.7(5) . . . . ? C441 C44 C45 C41 177.1(4) . . . . ? Rh2 C44 C45 C41 -61.4(3) . . . . ? C43 C44 C45 C451 -176.7(4) . . . . ? C441 C44 C45 C451 1.0(8) . . . . ? Rh2 C44 C45 C451 122.5(5) . . . . ? C43 C44 C45 Rh2 60.7(3) . . . . ? C441 C44 C45 Rh2 -121.5(5) . . . . ? C55 Rh2 C45 C41 -107.9(3) . . . . ? C54 Rh2 C45 C41 -150.7(2) . . . . ? C43 Rh2 C45 C41 80.7(3) . . . . ? C42 Rh2 C45 C41 37.7(2) . . . . ? C52 Rh2 C45 C41 -34.6(12) . . . . ? C51 Rh2 C45 C41 -68.3(3) . . . . ? C53 Rh2 C45 C41 173.5(3) . . . . ? C44 Rh2 C45 C41 118.1(4) . . . . ? C55 Rh2 C45 C44 134.0(3) . . . . ? C54 Rh2 C45 C44 91.2(3) . . . . ? C43 Rh2 C45 C44 -37.4(3) . . . . ? C42 Rh2 C45 C44 -80.4(3) . . . . ? C52 Rh2 C45 C44 -152.7(10) . . . . ? C51 Rh2 C45 C44 173.6(3) . . . . ? C41 Rh2 C45 C44 -118.1(4) . . . . ? C53 Rh2 C45 C44 55.4(4) . . . . ? C55 Rh2 C45 C451 13.9(5) . . . . ? C54 Rh2 C45 C451 -29.0(5) . . . . ? C43 Rh2 C45 C451 -157.6(5) . . . . ? C42 Rh2 C45 C451 159.4(5) . . . . ? C52 Rh2 C45 C451 87.1(11) . . . . ? C51 Rh2 C45 C451 53.4(5) . . . . ? C41 Rh2 C45 C451 121.8(5) . . . . ? C53 Rh2 C45 C451 -64.8(5) . . . . ? C44 Rh2 C45 C451 -120.1(5) . . . . ? C55 Rh2 C51 C52 -118.2(4) . . . . ? C54 Rh2 C51 C52 -80.4(3) . . . . ? C43 Rh2 C51 C52 55.8(4) . . . . ? C42 Rh2 C51 C52 91.0(3) . . . . ? C41 Rh2 C51 C52 133.4(2) . . . . ? C53 Rh2 C51 C52 -37.6(2) . . . . ? C45 Rh2 C51 C52 172.0(2) . . . . ? C44 Rh2 C51 C52 -159.4(10) . . . . ? C54 Rh2 C51 C55 37.7(2) . . . . ? C43 Rh2 C51 C55 173.9(3) . . . . ? C42 Rh2 C51 C55 -150.8(2) . . . . ? C52 Rh2 C51 C55 118.2(4) . . . . ? C41 Rh2 C51 C55 -108.5(3) . . . . ? C53 Rh2 C51 C55 80.6(3) . . . . ? C45 Rh2 C51 C55 -69.9(3) . . . . ? C44 Rh2 C51 C55 -41.3(12) . . . . ? C55 Rh2 C51 C511 120.0(5) . . . . ? C54 Rh2 C51 C511 157.7(5) . . . . ? C43 Rh2 C51 C511 -66.1(6) . . . . ? C42 Rh2 C51 C511 -30.8(5) . . . . ? C52 Rh2 C51 C511 -121.9(5) . . . . ? C41 Rh2 C51 C511 11.5(5) . . . . ? C53 Rh2 C51 C511 -159.4(5) . . . . ? C45 Rh2 C51 C511 50.1(5) . . . . ? C44 Rh2 C51 C511 78.7(12) . . . . ? C55 C51 C52 C53 0.8(5) . . . . ? C511 C51 C52 C53 -177.3(4) . . . . ? Rh2 C51 C52 C53 61.7(3) . . . . ? C55 C51 C52 C521 178.6(4) . . . . ? C511 C51 C52 C521 0.5(7) . . . . ? Rh2 C51 C52 C521 -120.6(4) . . . . ? C55 C51 C52 Rh2 -60.9(3) . . . . ? C511 C51 C52 Rh2 121.0(4) . . . . ? C55 Rh2 C52 C51 37.5(2) . . . . ? C54 Rh2 C52 C51 80.5(3) . . . . ? C43 Rh2 C52 C51 -150.6(2) . . . . ? C42 Rh2 C52 C51 -108.2(3) . . . . ? C41 Rh2 C52 C51 -69.1(3) . . . . ? C53 Rh2 C52 C51 117.8(4) . . . . ? C45 Rh2 C52 C51 -39.7(12) . . . . ? C44 Rh2 C52 C51 174.2(3) . . . . ? C55 Rh2 C52 C53 -80.3(3) . . . . ? C54 Rh2 C52 C53 -37.3(2) . . . . ? C43 Rh2 C52 C53 91.6(3) . . . . ? C42 Rh2 C52 C53 134.0(2) . . . . ? C51 Rh2 C52 C53 -117.8(4) . . . . ? C41 Rh2 C52 C53 173.1(2) . . . . ? C45 Rh2 C52 C53 -157.5(10) . . . . ? C44 Rh2 C52 C53 56.4(4) . . . . ? C55 Rh2 C52 C521 159.0(4) . . . . ? C54 Rh2 C52 C521 -158.0(4) . . . . ? C43 Rh2 C52 C521 -29.1(5) . . . . ? C42 Rh2 C52 C521 13.3(4) . . . . ? C51 Rh2 C52 C521 121.5(5) . . . . ? C41 Rh2 C52 C521 52.4(5) . . . . ? C53 Rh2 C52 C521 -120.7(5) . . . . ? C45 Rh2 C52 C521 81.8(12) . . . . ? C44 Rh2 C52 C521 -64.2(5) . . . . ? C51 C52 C53 C54 -1.1(5) . . . . ? C521 C52 C53 C54 -178.9(4) . . . . ? Rh2 C52 C53 C54 60.5(3) . . . . ? C51 C52 C53 C531 176.8(4) . . . . ? C521 C52 C53 C531 -1.0(7) . . . . ? Rh2 C52 C53 C531 -121.6(5) . . . . ? C51 C52 C53 Rh2 -61.6(3) . . . . ? C521 C52 C53 Rh2 120.6(4) . . . . ? C55 Rh2 C53 C52 80.4(3) . . . . ? C54 Rh2 C53 C52 118.4(4) . . . . ? C43 Rh2 C53 C52 -108.4(3) . . . . ? C42 Rh2 C53 C52 -68.6(3) . . . . ? C51 Rh2 C53 C52 37.4(3) . . . . ? C41 Rh2 C53 C52 -34.2(11) . . . . ? C45 Rh2 C53 C52 173.2(3) . . . . ? C44 Rh2 C53 C52 -150.8(2) . . . . ? C55 Rh2 C53 C54 -38.1(3) . . . . ? C43 Rh2 C53 C54 133.2(2) . . . . ? C42 Rh2 C53 C54 173.0(2) . . . . ? C52 Rh2 C53 C54 -118.4(4) . . . . ? C51 Rh2 C53 C54 -81.0(3) . . . . ? C41 Rh2 C53 C54 -152.6(9) . . . . ? C45 Rh2 C53 C54 54.8(4) . . . . ? C44 Rh2 C53 C54 90.8(3) . . . . ? C55 Rh2 C53 C531 -158.3(4) . . . . ? C54 Rh2 C53 C531 -120.2(5) . . . . ? C43 Rh2 C53 C531 12.9(4) . . . . ? C42 Rh2 C53 C531 52.8(5) . . . . ? C52 Rh2 C53 C531 121.3(5) . . . . ? C51 Rh2 C53 C531 158.7(4) . . . . ? C41 Rh2 C53 C531 87.2(11) . . . . ? C45 Rh2 C53 C531 -65.4(5) . . . . ? C44 Rh2 C53 C531 -29.4(4) . . . . ? C52 C53 C54 C55 1.0(5) . . . . ? C531 C53 C54 C55 -176.9(4) . . . . ? Rh2 C53 C54 C55 61.8(3) . . . . ? C52 C53 C54 C541 178.2(4) . . . . ? C531 C53 C54 C541 0.3(7) . . . . ? Rh2 C53 C54 C541 -121.0(5) . . . . ? C52 C53 C54 Rh2 -60.8(3) . . . . ? C531 C53 C54 Rh2 121.3(4) . . . . ? C55 Rh2 C54 C53 117.1(4) . . . . ? C43 Rh2 C54 C53 -70.3(3) . . . . ? C42 Rh2 C54 C53 -36.7(12) . . . . ? C52 Rh2 C54 C53 37.2(2) . . . . ? C51 Rh2 C54 C53 79.6(3) . . . . ? C41 Rh2 C54 C53 172.1(3) . . . . ? C45 Rh2 C54 C53 -151.7(2) . . . . ? C44 Rh2 C54 C53 -109.3(3) . . . . ? C43 Rh2 C54 C55 172.6(3) . . . . ? C42 Rh2 C54 C55 -153.9(10) . . . . ? C52 Rh2 C54 C55 -80.0(3) . . . . ? C51 Rh2 C54 C55 -37.6(3) . . . . ? C41 Rh2 C54 C55 55.0(4) . . . . ? C53 Rh2 C54 C55 -117.1(4) . . . . ? C45 Rh2 C54 C55 91.1(3) . . . . ? C44 Rh2 C54 C55 133.5(3) . . . . ? C55 Rh2 C54 C541 -121.6(5) . . . . ? C43 Rh2 C54 C541 51.0(5) . . . . ? C42 Rh2 C54 C541 84.6(11) . . . . ? C52 Rh2 C54 C541 158.4(4) . . . . ? C51 Rh2 C54 C541 -159.1(4) . . . . ? C41 Rh2 C54 C541 -66.6(5) . . . . ? C53 Rh2 C54 C541 121.3(5) . . . . ? C45 Rh2 C54 C541 -30.4(4) . . . . ? C44 Rh2 C54 C541 11.9(4) . . . . ? C52 C51 C55 C54 -0.2(5) . . . . ? C511 C51 C55 C54 177.9(4) . . . . ? Rh2 C51 C55 C54 -61.5(3) . . . . ? C52 C51 C55 C551 -179.2(4) . . . . ? C511 C51 C55 C551 -1.1(7) . . . . ? Rh2 C51 C55 C551 119.6(5) . . . . ? C52 C51 C55 Rh2 61.2(3) . . . . ? C511 C51 C55 Rh2 -120.6(4) . . . . ? C53 C54 C55 C51 -0.4(5) . . . . ? C541 C54 C55 C51 -177.7(4) . . . . ? Rh2 C54 C55 C51 61.8(3) . . . . ? C53 C54 C55 C551 178.5(5) . . . . ? C541 C54 C55 C551 1.3(8) . . . . ? Rh2 C54 C55 C551 -119.3(5) . . . . ? C53 C54 C55 Rh2 -62.2(3) . . . . ? C541 C54 C55 Rh2 120.6(5) . . . . ? C54 Rh2 C55 C51 -117.8(4) . . . . ? C43 Rh2 C55 C51 -157.5(10) . . . . ? C42 Rh2 C55 C51 55.2(4) . . . . ? C52 Rh2 C55 C51 -37.2(3) . . . . ? C41 Rh2 C55 C51 91.0(3) . . . . ? C53 Rh2 C55 C51 -79.9(3) . . . . ? C45 Rh2 C55 C51 133.3(3) . . . . ? C44 Rh2 C55 C51 172.2(2) . . . . ? C43 Rh2 C55 C54 -39.7(12) . . . . ? C42 Rh2 C55 C54 173.0(3) . . . . ? C52 Rh2 C55 C54 80.6(3) . . . . ? C51 Rh2 C55 C54 117.8(4) . . . . ? C41 Rh2 C55 C54 -151.3(2) . . . . ? C53 Rh2 C55 C54 37.9(2) . . . . ? C45 Rh2 C55 C54 -108.9(3) . . . . ? C44 Rh2 C55 C54 -70.0(3) . . . . ? C54 Rh2 C55 C551 121.4(5) . . . . ? C43 Rh2 C55 C551 81.7(12) . . . . ? C42 Rh2 C55 C551 -65.6(5) . . . . ? C52 Rh2 C55 C551 -158.0(5) . . . . ? C51 Rh2 C55 C551 -120.8(5) . . . . ? C41 Rh2 C55 C551 -29.9(5) . . . . ? C53 Rh2 C55 C551 159.3(5) . . . . ? C45 Rh2 C55 C551 12.5(5) . . . . ? C44 Rh2 C55 C551 51.4(5) . . . . ? _diffrn_measured_fraction_theta_max 0.967 _diffrn_reflns_theta_full 25.12 _diffrn_measured_fraction_theta_full 0.967 _refine_diff_density_max 2.146 _refine_diff_density_min -0.739 _refine_diff_density_rms 0.119 #=================================================END data_6 _database_code_depnum_ccdc_archive 'CCDC 240971' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C54 H79 Ga3 Rh2' _chemical_formula_weight 1143.15 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M P-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 11.819(7) _cell_length_b 13.990(9) _cell_length_c 17.931(10) _cell_angle_alpha 74.978(16) _cell_angle_beta 71.020(14) _cell_angle_gamma 67.023(14) _cell_volume 2551(3) _cell_formula_units_Z 2 _cell_measurement_temperature 203(2) _cell_measurement_reflns_used 60 _cell_measurement_theta_min 10.0 _cell_measurement_theta_max 15.0 _exptl_crystal_description prism _exptl_crystal_colour 'dark red' _exptl_crystal_size_max 0.30 _exptl_crystal_size_mid 0.25 _exptl_crystal_size_min 0.20 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.488 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1172 _exptl_absorpt_coefficient_mu 2.230 _exptl_absorpt_correction_type empirical _exptl_absorpt_correction_T_min 0.343 _exptl_absorpt_correction_T_max 1.000 _exptl_absorpt_process_details ? _exptl_special_details ; ? ; _diffrn_ambient_temperature 203(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker axs CCD 1000' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 15132 _diffrn_reflns_av_R_equivalents 0.0802 _diffrn_reflns_av_sigmaI/netI 0.1637 _diffrn_reflns_limit_h_min -14 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 16 _diffrn_reflns_limit_l_min -15 _diffrn_reflns_limit_l_max 21 _diffrn_reflns_theta_min 2.15 _diffrn_reflns_theta_max 25.41 _reflns_number_total 9154 _reflns_number_gt 5034 _reflns_threshold_expression >2sigma(I) _computing_data_collection SMART _computing_cell_refinement SMART _computing_data_reduction SAINT _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker axs SHELXTL-PLUS' _computing_publication_material SHELXL-97 _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0424P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 9154 _refine_ls_number_parameters 534 _refine_ls_number_restraints 1 _refine_ls_R_factor_all 0.1197 _refine_ls_R_factor_gt 0.0593 _refine_ls_wR_factor_ref 0.1388 _refine_ls_wR_factor_gt 0.1170 _refine_ls_goodness_of_fit_ref 0.906 _refine_ls_restrained_S_all 0.907 _refine_ls_shift/su_max 0.003 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.14455(6) 0.65943(6) 0.22008(4) 0.02428(19) Uani 1 1 d . . . Rh2 Rh 0.20744(6) 0.74879(6) 0.33134(4) 0.02446(19) Uani 1 1 d . . . Ga1 Ga 0.29575(8) 0.57487(8) 0.29862(5) 0.0277(3) Uani 1 1 d . . . Ga2 Ga 0.02486(8) 0.81761(8) 0.27712(5) 0.0283(3) Uani 1 1 d . . . Ga3 Ga 0.28177(8) 0.76093(8) 0.18941(5) 0.0252(2) Uani 1 1 d . . . C11 C 0.1894(8) 0.5156(8) 0.1671(5) 0.031(2) Uani 1 1 d . . . C12 C 0.0803(8) 0.5177(8) 0.2347(5) 0.033(2) Uani 1 1 d . . . C13 C -0.0198(7) 0.6080(7) 0.2178(5) 0.027(2) Uani 1 1 d . . . C14 C 0.0273(7) 0.6622(7) 0.1418(5) 0.028(2) Uani 1 1 d . . . C15 C 0.1548(8) 0.6037(7) 0.1116(5) 0.032(2) Uani 1 1 d . . . C111 C 0.3069(8) 0.4210(8) 0.1505(6) 0.049(3) Uani 1 1 d . . . H11A H 0.2979 0.3834 0.1154 0.074 Uiso 1 1 calc R . . H11B H 0.3182 0.3751 0.2003 0.074 Uiso 1 1 calc R . . H11C H 0.3803 0.4435 0.1251 0.074 Uiso 1 1 calc R . . C121 C 0.0730(9) 0.4313(8) 0.3037(5) 0.051(3) Uani 1 1 d . . . H12A H 0.0148 0.4609 0.3509 0.076 Uiso 1 1 calc R . . H12B H 0.1567 0.3939 0.3133 0.076 Uiso 1 1 calc R . . H12C H 0.0429 0.3831 0.2917 0.076 Uiso 1 1 calc R . . C131 C -0.1542(8) 0.6314(8) 0.2680(5) 0.044(3) Uani 1 1 d . . . H13A H -0.1918 0.5857 0.2597 0.066 Uiso 1 1 calc R . . H13B H -0.2030 0.7041 0.2529 0.066 Uiso 1 1 calc R . . H13C H -0.1547 0.6195 0.3239 0.066 Uiso 1 1 calc R . . C141 C -0.0499(8) 0.7478(8) 0.0893(5) 0.043(3) Uani 1 1 d . . . H14A H -0.0144 0.8042 0.0694 0.065 Uiso 1 1 calc R . . H14B H -0.1370 0.7748 0.1200 0.065 Uiso 1 1 calc R . . H14C H -0.0480 0.7195 0.0447 0.065 Uiso 1 1 calc R . . C151 C 0.2289(9) 0.6223(9) 0.0266(5) 0.048(3) Uani 1 1 d . . . H15A H 0.3185 0.5842 0.0225 0.072 Uiso 1 1 calc R . . H15B H 0.2155 0.6968 0.0101 0.072 Uiso 1 1 calc R . . H15C H 0.2004 0.5978 -0.0077 0.072 Uiso 1 1 calc R . . C21 C 0.2173(8) 0.7108(7) 0.4653(5) 0.031(2) Uani 1 1 d . . . C22 C 0.1034(8) 0.7940(8) 0.4587(5) 0.034(2) Uani 1 1 d . . . C23 C 0.1357(7) 0.8768(7) 0.4048(5) 0.028(2) Uani 1 1 d . . . C24 C 0.2687(7) 0.8469(7) 0.3770(5) 0.029(2) Uani 1 1 d . . . C25 C 0.3211(7) 0.7441(7) 0.4134(5) 0.030(2) Uani 1 1 d . . . C211 C 0.2237(8) 0.6134(8) 0.5262(5) 0.039(2) Uani 1 1 d . . . H21A H 0.3102 0.5647 0.5168 0.058 Uiso 1 1 calc R . . H21B H 0.1677 0.5808 0.5218 0.058 Uiso 1 1 calc R . . H21C H 0.1975 0.6319 0.5792 0.058 Uiso 1 1 calc R . . C221 C -0.0265(8) 0.7925(8) 0.5063(5) 0.044(3) Uani 1 1 d . . . H22A H -0.0399 0.8021 0.5605 0.065 Uiso 1 1 calc R . . H22B H -0.0337 0.7255 0.5068 0.065 Uiso 1 1 calc R . . H22C H -0.0900 0.8487 0.4823 0.065 Uiso 1 1 calc R . . C231 C 0.0510(8) 0.9895(8) 0.3933(6) 0.046(3) Uani 1 1 d . . . H23A H -0.0371 0.9931 0.4119 0.069 Uiso 1 1 calc R . . H23B H 0.0692 1.0185 0.3371 0.069 Uiso 1 1 calc R . . H23C H 0.0665 1.0296 0.4234 0.069 Uiso 1 1 calc R . . C241 C 0.3437(9) 0.9191(8) 0.3304(5) 0.046(3) Uani 1 1 d . . . H24A H 0.2946 0.9758 0.2972 0.068 Uiso 1 1 calc R . . H24B H 0.4228 0.8799 0.2969 0.068 Uiso 1 1 calc R . . H24C H 0.3619 0.9480 0.3671 0.068 Uiso 1 1 calc R . . C251 C 0.4592(8) 0.6949(8) 0.4163(5) 0.047(3) Uani 1 1 d . . . H25A H 0.4775 0.7344 0.4454 0.070 Uiso 1 1 calc R . . H25B H 0.5133 0.6959 0.3625 0.070 Uiso 1 1 calc R . . H25C H 0.4750 0.6229 0.4431 0.070 Uiso 1 1 calc R . . C31 C 0.4330(8) 0.4387(7) 0.3256(5) 0.030(2) Uani 1 1 d . . . C32 C 0.5211(8) 0.3982(8) 0.2515(5) 0.034(2) Uani 1 1 d . . . C33 C 0.5164(8) 0.3033(9) 0.2511(6) 0.044(3) Uani 1 1 d . . . C34 C 0.4244(9) 0.2794(8) 0.3214(6) 0.039(2) Uani 1 1 d . . . C35 C 0.3744(8) 0.3556(7) 0.3662(5) 0.032(2) Uani 1 1 d . . . C311 C 0.5037(8) 0.4562(8) 0.3765(5) 0.041(2) Uani 1 1 d . . . H31A H 0.5694 0.3909 0.3891 0.062 Uiso 1 1 calc R . . H31B H 0.4442 0.4793 0.4256 0.062 Uiso 1 1 calc R . . H31C H 0.5420 0.5093 0.3471 0.062 Uiso 1 1 calc R . . C321 C 0.6054(9) 0.4532(9) 0.1924(6) 0.058(3) Uani 1 1 d . . . H32A H 0.6719 0.4491 0.2149 0.087 Uiso 1 1 calc R . . H32B H 0.5562 0.5263 0.1790 0.087 Uiso 1 1 calc R . . H32C H 0.6433 0.4203 0.1446 0.087 Uiso 1 1 calc R . . C331 C 0.5903(10) 0.2354(9) 0.1865(7) 0.061(3) Uani 1 1 d . . . H33A H 0.6391 0.2721 0.1426 0.092 Uiso 1 1 calc R . . H33B H 0.5319 0.2203 0.1675 0.092 Uiso 1 1 calc R . . H33C H 0.6474 0.1701 0.2078 0.092 Uiso 1 1 calc R . . C341 C 0.3944(11) 0.1804(9) 0.3378(7) 0.068(3) Uani 1 1 d . . . H34A H 0.4722 0.1205 0.3361 0.102 Uiso 1 1 calc R . . H34B H 0.3550 0.1812 0.2978 0.102 Uiso 1 1 calc R . . H34C H 0.3367 0.1751 0.3903 0.102 Uiso 1 1 calc R . . C351 C 0.2782(9) 0.3651(8) 0.4454(5) 0.050(3) Uani 1 1 d . . . H35A H 0.2023 0.4243 0.4392 0.076 Uiso 1 1 calc R . . H35B H 0.3134 0.3758 0.4833 0.076 Uiso 1 1 calc R . . H35C H 0.2568 0.3012 0.4649 0.076 Uiso 1 1 calc R . . C41 C -0.1391(8) 0.9419(7) 0.2711(5) 0.033(2) Uani 1 1 d . . . C42 C -0.2300(8) 0.9496(8) 0.3519(5) 0.038(2) Uani 1 1 d . . . C43 C -0.2534(8) 1.0407(9) 0.3739(6) 0.042(3) Uani 1 1 d . . . C44 C -0.1774(9) 1.0967(9) 0.3111(6) 0.046(3) Uani 1 1 d . . . C45 C -0.1127(9) 1.0420(8) 0.2522(6) 0.041(3) Uani 1 1 d . . . C411 C -0.1935(9) 0.9293(8) 0.2103(6) 0.051(3) Uani 1 1 d . . . H41A H -0.2731 0.9861 0.2083 0.076 Uiso 1 1 calc R . . H41B H -0.2084 0.8627 0.2253 0.076 Uiso 1 1 calc R . . H41C H -0.1340 0.9312 0.1583 0.076 Uiso 1 1 calc R . . C421 C -0.2907(9) 0.8683(9) 0.3933(6) 0.067(4) Uani 1 1 d . . . H42A H -0.3382 0.8824 0.4470 0.101 Uiso 1 1 calc R . . H42B H -0.2257 0.7996 0.3958 0.101 Uiso 1 1 calc R . . H42C H -0.3478 0.8699 0.3641 0.101 Uiso 1 1 calc R . . C431 C -0.3399(10) 1.0819(10) 0.4502(6) 0.067(4) Uani 1 1 d . . . H43A H -0.3703 1.0271 0.4863 0.101 Uiso 1 1 calc R . . H43B H -0.4117 1.1419 0.4381 0.101 Uiso 1 1 calc R . . H43C H -0.2933 1.1028 0.4750 0.101 Uiso 1 1 calc R . . C441 C -0.1789(10) 1.2028(9) 0.3165(7) 0.068(4) Uani 1 1 d . . . H44A H -0.1163 1.2235 0.2714 0.102 Uiso 1 1 calc R . . H44B H -0.1587 1.1992 0.3657 0.102 Uiso 1 1 calc R . . H44C H -0.2625 1.2541 0.3160 0.102 Uiso 1 1 calc R . . C451 C -0.0276(9) 1.0715(9) 0.1750(6) 0.063(3) Uani 1 1 d . . . H45A H -0.0715 1.0936 0.1330 0.095 Uiso 1 1 calc R . . H45B H 0.0484 1.0114 0.1625 0.095 Uiso 1 1 calc R . . H45C H -0.0043 1.1287 0.1793 0.095 Uiso 1 1 calc R . . C51 C 0.4029(7) 0.8091(7) 0.0911(5) 0.026(2) Uani 1 1 d . . . C52 C 0.4783(7) 0.8441(8) 0.1233(5) 0.030(2) Uani 1 1 d . . . C53 C 0.4348(7) 0.9495(8) 0.1151(5) 0.029(2) Uani 1 1 d . . . C54 C 0.3327(8) 0.9908(8) 0.0739(5) 0.036(2) Uani 1 1 d . . . C55 C 0.3144(7) 0.9077(8) 0.0593(5) 0.031(2) Uani 1 1 d . . . C511 C 0.4742(8) 0.7253(7) 0.0390(5) 0.036(2) Uani 1 1 d . . . H51A H 0.4145 0.7071 0.0237 0.054 Uiso 1 1 calc R . . H51B H 0.5248 0.6635 0.0681 0.054 Uiso 1 1 calc R . . H51C H 0.5295 0.7508 -0.0084 0.054 Uiso 1 1 calc R . . C521 C 0.5815(8) 0.7712(8) 0.1610(5) 0.046(3) Uani 1 1 d . . . H52A H 0.6487 0.7297 0.1223 0.068 Uiso 1 1 calc R . . H52B H 0.5483 0.7251 0.2058 0.068 Uiso 1 1 calc R . . H52C H 0.6152 0.8113 0.1797 0.068 Uiso 1 1 calc R . . C531 C 0.4812(9) 1.0208(9) 0.1375(6) 0.052(3) Uani 1 1 d . . . H53A H 0.4107 1.0682 0.1707 0.078 Uiso 1 1 calc R . . H53B H 0.5178 1.0611 0.0896 0.078 Uiso 1 1 calc R . . H53C H 0.5452 0.9792 0.1667 0.078 Uiso 1 1 calc R . . C541 C 0.2630(9) 1.1043(8) 0.0538(6) 0.051(3) Uani 1 1 d . . . H54A H 0.3182 1.1361 0.0108 0.076 Uiso 1 1 calc R . . H54B H 0.2364 1.1384 0.1004 0.076 Uiso 1 1 calc R . . H54C H 0.1889 1.1125 0.0373 0.076 Uiso 1 1 calc R . . C551 C 0.2251(8) 0.9107(8) 0.0130(5) 0.044(3) Uani 1 1 d . . . H55A H 0.2744 0.8789 -0.0347 0.065 Uiso 1 1 calc R . . H55B H 0.1751 0.9831 -0.0018 0.065 Uiso 1 1 calc R . . H55C H 0.1690 0.8722 0.0462 0.065 Uiso 1 1 calc R . . C94 C -0.0038 0.3822 0.1355 0.071(7) Uiso 0.50 1 d PD . . C91 C -0.0056(17) 0.4558(13) 0.0562(7) 0.093(9) Uiso 0.50 1 d PGD . . C92 C 0.0955(13) 0.4393(12) -0.0112(10) 0.054(6) Uiso 0.50 1 d PG . . C93 C 0.0847(15) 0.5066(15) -0.0827(7) 0.096(9) Uiso 0.50 1 d PG . . C91A C -0.0271(19) 0.5903(13) -0.0867(7) 0.074(7) Uiso 0.50 1 d PG . . C92A C -0.1281(13) 0.6067(11) -0.0193(11) 0.069(7) Uiso 0.50 1 d PG . . C93A C -0.1174(13) 0.5394(14) 0.0522(7) 0.044(5) Uiso 0.50 1 d PG . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.0236(3) 0.0277(5) 0.0295(4) -0.0027(3) -0.0098(3) -0.0154(3) Rh2 0.0240(3) 0.0284(5) 0.0275(4) -0.0028(3) -0.0080(3) -0.0153(3) Ga1 0.0269(5) 0.0286(7) 0.0333(5) 0.0004(5) -0.0120(4) -0.0149(5) Ga2 0.0244(5) 0.0299(7) 0.0347(6) -0.0037(5) -0.0097(4) -0.0124(5) Ga3 0.0252(5) 0.0296(7) 0.0275(5) -0.0020(4) -0.0071(4) -0.0172(5) C11 0.029(5) 0.035(7) 0.038(5) -0.017(5) -0.012(4) -0.009(5) C12 0.044(5) 0.038(7) 0.031(5) 0.002(4) -0.015(4) -0.028(5) C13 0.026(4) 0.023(6) 0.038(5) -0.003(4) -0.010(4) -0.017(4) C14 0.034(5) 0.021(6) 0.042(5) -0.002(4) -0.020(4) -0.017(5) C15 0.027(5) 0.030(6) 0.049(6) -0.012(5) -0.016(4) -0.012(5) C111 0.044(6) 0.039(8) 0.076(7) -0.029(6) -0.030(6) -0.002(5) C121 0.052(6) 0.055(8) 0.058(7) 0.005(6) -0.019(5) -0.035(6) C131 0.036(5) 0.054(8) 0.054(6) -0.007(5) -0.014(5) -0.025(5) C141 0.047(6) 0.048(8) 0.049(6) -0.004(5) -0.028(5) -0.020(5) C151 0.049(6) 0.071(9) 0.042(6) -0.016(5) -0.004(5) -0.040(6) C21 0.035(5) 0.035(7) 0.032(5) 0.002(4) -0.014(4) -0.023(5) C22 0.027(5) 0.034(7) 0.044(5) -0.013(5) -0.006(4) -0.013(5) C23 0.027(4) 0.035(7) 0.027(5) -0.008(4) -0.016(4) -0.007(5) C24 0.031(5) 0.027(6) 0.035(5) 0.000(4) -0.020(4) -0.010(4) C25 0.030(5) 0.036(7) 0.032(5) -0.010(4) -0.010(4) -0.016(5) C211 0.047(5) 0.047(7) 0.028(5) 0.000(5) -0.012(4) -0.023(5) C221 0.035(5) 0.058(8) 0.042(6) -0.010(5) 0.001(4) -0.027(5) C231 0.046(6) 0.048(8) 0.052(6) -0.020(5) -0.023(5) -0.008(6) C241 0.063(6) 0.062(8) 0.033(5) -0.001(5) -0.010(5) -0.048(6) C251 0.036(5) 0.060(8) 0.055(6) 0.003(6) -0.024(5) -0.026(6) C31 0.036(5) 0.014(6) 0.045(6) 0.006(4) -0.025(4) -0.008(4) C32 0.027(5) 0.038(7) 0.041(6) -0.007(5) -0.013(4) -0.010(5) C33 0.036(5) 0.048(8) 0.050(6) -0.004(6) -0.025(5) -0.006(5) C34 0.048(6) 0.017(6) 0.060(7) 0.003(5) -0.029(5) -0.012(5) C35 0.035(5) 0.026(6) 0.040(6) 0.010(5) -0.019(4) -0.016(5) C311 0.047(6) 0.034(7) 0.051(6) -0.015(5) -0.021(5) -0.009(5) C321 0.040(6) 0.076(10) 0.049(6) -0.004(6) -0.003(5) -0.022(6) C331 0.053(7) 0.042(8) 0.087(9) -0.023(7) -0.031(6) 0.006(6) C341 0.090(9) 0.041(8) 0.087(9) 0.003(7) -0.040(7) -0.032(7) C351 0.050(6) 0.040(8) 0.062(7) 0.008(5) -0.013(5) -0.026(6) C41 0.032(5) 0.027(6) 0.046(6) -0.011(5) -0.019(4) -0.003(5) C42 0.027(5) 0.036(7) 0.043(6) -0.003(5) -0.008(4) -0.005(5) C43 0.032(5) 0.039(8) 0.043(6) -0.011(5) -0.015(5) 0.008(5) C44 0.033(5) 0.048(8) 0.061(7) -0.009(6) -0.020(5) -0.011(5) C45 0.038(5) 0.044(7) 0.046(6) 0.004(5) -0.020(5) -0.018(5) C411 0.049(6) 0.049(8) 0.068(7) -0.016(6) -0.037(6) -0.008(6) C421 0.041(6) 0.069(10) 0.075(8) 0.009(7) -0.004(6) -0.024(6) C431 0.052(7) 0.078(11) 0.062(7) -0.036(7) -0.008(6) -0.001(7) C441 0.060(7) 0.058(9) 0.102(9) -0.024(7) -0.046(7) -0.008(7) C451 0.044(6) 0.056(9) 0.068(8) 0.002(6) 0.003(5) -0.015(6) C51 0.023(4) 0.027(6) 0.036(5) -0.001(4) -0.011(4) -0.015(4) C52 0.028(5) 0.042(7) 0.024(5) 0.001(4) -0.007(4) -0.020(5) C53 0.029(5) 0.043(7) 0.023(5) -0.006(4) 0.002(4) -0.024(5) C54 0.036(5) 0.042(7) 0.029(5) 0.007(5) -0.009(4) -0.020(5) C55 0.029(5) 0.039(7) 0.032(5) 0.001(4) -0.009(4) -0.021(5) C511 0.036(5) 0.032(7) 0.040(5) -0.006(5) -0.003(4) -0.017(5) C521 0.035(5) 0.059(8) 0.050(6) 0.000(5) -0.016(5) -0.024(6) C531 0.052(6) 0.063(9) 0.053(6) -0.001(6) -0.009(5) -0.040(6) C541 0.050(6) 0.029(7) 0.063(7) 0.008(5) -0.007(5) -0.017(6) C551 0.045(6) 0.047(8) 0.042(6) 0.013(5) -0.020(5) -0.025(6) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 C15 2.229(8) . ? Rh1 C11 2.250(9) . ? Rh1 C14 2.256(7) . ? Rh1 C12 2.314(8) . ? Rh1 C13 2.335(7) . ? Rh1 Ga1 2.3873(15) . ? Rh1 Ga2 2.3942(18) . ? Rh1 Ga3 2.4004(15) . ? Rh1 Rh2 3.0131(15) . ? Rh2 C24 2.196(8) . ? Rh2 C23 2.229(9) . ? Rh2 C25 2.267(8) . ? Rh2 C22 2.332(9) . ? Rh2 C21 2.353(8) . ? Rh2 Ga1 2.3902(19) . ? Rh2 Ga3 2.3908(17) . ? Rh2 Ga2 2.4054(16) . ? Ga1 C31 2.029(8) . ? Ga1 Ga3 2.8055(19) . ? Ga2 C41 2.049(9) . ? Ga2 Ga3 2.8253(19) . ? Ga3 C51 2.026(8) . ? C11 C15 1.382(12) . ? C11 C12 1.451(11) . ? C11 C111 1.507(12) . ? C12 C13 1.398(12) . ? C12 C121 1.496(12) . ? C13 C14 1.430(11) . ? C13 C131 1.502(11) . ? C14 C15 1.403(11) . ? C14 C141 1.508(11) . ? C15 C151 1.504(12) . ? C21 C22 1.411(12) . ? C21 C25 1.438(10) . ? C21 C211 1.502(12) . ? C22 C23 1.395(12) . ? C22 C221 1.500(10) . ? C23 C24 1.407(11) . ? C23 C231 1.505(13) . ? C24 C25 1.400(12) . ? C24 C241 1.512(11) . ? C25 C251 1.516(11) . ? C31 C32 1.483(12) . ? C31 C35 1.492(11) . ? C31 C311 1.536(10) . ? C32 C33 1.353(13) . ? C32 C321 1.482(12) . ? C33 C34 1.434(13) . ? C33 C331 1.507(14) . ? C34 C35 1.333(13) . ? C34 C341 1.495(13) . ? C35 C351 1.501(12) . ? C41 C45 1.482(13) . ? C41 C42 1.497(12) . ? C41 C411 1.509(11) . ? C42 C43 1.331(13) . ? C42 C421 1.487(13) . ? C43 C44 1.457(13) . ? C43 C431 1.512(13) . ? C44 C45 1.313(13) . ? C44 C441 1.506(14) . ? C45 C451 1.490(12) . ? C51 C55 1.476(12) . ? C51 C52 1.480(10) . ? C51 C511 1.497(12) . ? C52 C53 1.343(12) . ? C52 C521 1.481(11) . ? C53 C54 1.466(11) . ? C53 C531 1.495(11) . ? C54 C55 1.364(12) . ? C54 C541 1.484(13) . ? C55 C551 1.523(10) . ? C94 C91A 0.880(13) 2_565 ? C94 C91 1.525(5) . ? C94 C93 1.702(18) 2_565 ? C91 C91A 0.789(17) 2_565 ? C91 C93 0.91(4) 2_565 ? C91 C92 1.3900 . ? C91 C93A 1.3900 . ? C91 C92A 1.50(4) 2_565 ? C91 C92 1.63(2) 2_565 ? C91 C93A 2.02(3) 2_565 ? C92 C93A 0.72(3) 2_565 ? C92 C92A 0.79(2) 2_565 ? C92 C93 1.3900 . ? C92 C91 1.631(17) 2_565 ? C92 C91A 1.69(3) 2_565 ? C93 C93A 0.79(3) 2_565 ? C93 C91 0.91(3) 2_565 ? C93 C91A 1.3900 . ? C93 C94 1.702(17) 2_565 ? C91A C91 0.789(13) 2_565 ? C91A C94 0.880(10) 2_565 ? C91A C92A 1.3900 . ? C91A C92 1.69(2) 2_565 ? C92A C92 0.79(2) 2_565 ? C92A C93A 1.3900 . ? C92A C91 1.50(3) 2_565 ? C93A C92 0.72(2) 2_565 ? C93A C93 0.79(3) 2_565 ? C93A C91 2.02(2) 2_565 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C15 Rh1 C11 36.0(3) . . ? C15 Rh1 C14 36.5(3) . . ? C11 Rh1 C14 60.1(3) . . ? C15 Rh1 C12 60.7(3) . . ? C11 Rh1 C12 37.0(3) . . ? C14 Rh1 C12 59.8(3) . . ? C15 Rh1 C13 60.5(3) . . ? C11 Rh1 C13 60.0(3) . . ? C14 Rh1 C13 36.2(3) . . ? C12 Rh1 C13 35.0(3) . . ? C15 Rh1 Ga1 123.9(2) . . ? C11 Rh1 Ga1 94.4(2) . . ? C14 Rh1 Ga1 153.9(2) . . ? C12 Rh1 Ga1 97.0(2) . . ? C13 Rh1 Ga1 128.2(2) . . ? C15 Rh1 Ga2 134.5(2) . . ? C11 Rh1 Ga2 160.3(2) . . ? C14 Rh1 Ga2 103.1(2) . . ? C12 Rh1 Ga2 127.3(2) . . ? C13 Rh1 Ga2 100.4(2) . . ? Ga1 Rh1 Ga2 100.77(5) . . ? C15 Rh1 Ga3 111.0(2) . . ? C11 Rh1 Ga3 125.2(2) . . ? C14 Rh1 Ga3 126.0(2) . . ? C12 Rh1 Ga3 159.8(2) . . ? C13 Rh1 Ga3 160.1(2) . . ? Ga1 Rh1 Ga3 71.74(5) . . ? Ga2 Rh1 Ga3 72.21(6) . . ? C15 Rh1 Rh2 161.3(2) . . ? C11 Rh1 Rh2 145.3(2) . . ? C14 Rh1 Rh2 154.3(2) . . ? C12 Rh1 Rh2 133.9(2) . . ? C13 Rh1 Rh2 138.1(2) . . ? Ga1 Rh1 Rh2 50.94(4) . . ? Ga2 Rh1 Rh2 51.28(4) . . ? Ga3 Rh1 Rh2 50.89(4) . . ? C24 Rh2 C23 37.1(3) . . ? C24 Rh2 C25 36.5(3) . . ? C23 Rh2 C25 60.7(3) . . ? C24 Rh2 C22 60.5(3) . . ? C23 Rh2 C22 35.5(3) . . ? C25 Rh2 C22 60.1(3) . . ? C24 Rh2 C21 60.2(3) . . ? C23 Rh2 C21 59.2(3) . . ? C25 Rh2 C21 36.2(3) . . ? C22 Rh2 C21 35.1(3) . . ? C24 Rh2 Ga1 136.0(2) . . ? C23 Rh2 Ga1 159.0(2) . . ? C25 Rh2 Ga1 103.6(2) . . ? C22 Rh2 Ga1 125.8(2) . . ? C21 Rh2 Ga1 99.9(2) . . ? C24 Rh2 Ga3 111.6(2) . . ? C23 Rh2 Ga3 128.0(2) . . ? C25 Rh2 Ga3 124.8(2) . . ? C22 Rh2 Ga3 161.7(2) . . ? C21 Rh2 Ga3 158.4(2) . . ? Ga1 Rh2 Ga3 71.86(4) . . ? C24 Rh2 Ga2 122.9(2) . . ? C23 Rh2 Ga2 93.55(19) . . ? C25 Rh2 Ga2 154.1(2) . . ? C22 Rh2 Ga2 97.7(2) . . ? C21 Rh2 Ga2 129.5(2) . . ? Ga1 Rh2 Ga2 100.36(4) . . ? Ga3 Rh2 Ga2 72.18(5) . . ? C24 Rh2 Rh1 161.7(2) . . ? C23 Rh2 Rh1 144.40(19) . . ? C25 Rh2 Rh1 154.3(2) . . ? C22 Rh2 Rh1 133.48(19) . . ? C21 Rh2 Rh1 138.1(2) . . ? Ga1 Rh2 Rh1 50.86(4) . . ? Ga3 Rh2 Rh1 51.17(4) . . ? Ga2 Rh2 Rh1 50.95(4) . . ? C31 Ga1 Rh1 144.4(2) . . ? C31 Ga1 Rh2 137.3(2) . . ? Rh1 Ga1 Rh2 78.20(4) . . ? C31 Ga1 Ga3 137.1(2) . . ? Rh1 Ga1 Ga3 54.34(4) . . ? Rh2 Ga1 Ga3 54.08(5) . . ? C41 Ga2 Rh1 138.1(2) . . ? C41 Ga2 Rh2 144.1(2) . . ? Rh1 Ga2 Rh2 77.77(5) . . ? C41 Ga2 Ga3 137.0(3) . . ? Rh1 Ga2 Ga3 54.00(3) . . ? Rh2 Ga2 Ga3 53.67(5) . . ? C51 Ga3 Rh2 145.1(2) . . ? C51 Ga3 Rh1 136.6(2) . . ? Rh2 Ga3 Rh1 77.93(4) . . ? C51 Ga3 Ga1 135.2(3) . . ? Rh2 Ga3 Ga1 54.06(4) . . ? Rh1 Ga3 Ga1 53.91(4) . . ? C51 Ga3 Ga2 142.7(2) . . ? Rh2 Ga3 Ga2 54.15(3) . . ? Rh1 Ga3 Ga2 53.79(5) . . ? Ga1 Ga3 Ga2 81.71(4) . . ? C15 C11 C12 108.4(8) . . ? C15 C11 C111 124.8(8) . . ? C12 C11 C111 125.0(9) . . ? C15 C11 Rh1 71.2(5) . . ? C12 C11 Rh1 73.9(5) . . ? C111 C11 Rh1 133.2(5) . . ? C13 C12 C11 107.3(7) . . ? C13 C12 C121 126.7(8) . . ? C11 C12 C121 125.5(9) . . ? C13 C12 Rh1 73.3(5) . . ? C11 C12 Rh1 69.1(5) . . ? C121 C12 Rh1 129.0(6) . . ? C12 C13 C14 107.4(7) . . ? C12 C13 C131 123.7(7) . . ? C14 C13 C131 128.4(8) . . ? C12 C13 Rh1 71.7(4) . . ? C14 C13 Rh1 68.9(4) . . ? C131 C13 Rh1 130.8(6) . . ? C15 C14 C13 108.7(8) . . ? C15 C14 C141 121.9(8) . . ? C13 C14 C141 127.1(7) . . ? C15 C14 Rh1 70.7(4) . . ? C13 C14 Rh1 74.9(4) . . ? C141 C14 Rh1 134.0(6) . . ? C11 C15 C14 108.3(8) . . ? C11 C15 C151 126.1(8) . . ? C14 C15 C151 124.4(8) . . ? C11 C15 Rh1 72.8(5) . . ? C14 C15 Rh1 72.8(5) . . ? C151 C15 Rh1 130.5(6) . . ? C22 C21 C25 107.9(8) . . ? C22 C21 C211 123.7(7) . . ? C25 C21 C211 127.8(8) . . ? C22 C21 Rh2 71.7(5) . . ? C25 C21 Rh2 68.6(4) . . ? C211 C21 Rh2 132.3(6) . . ? C23 C22 C21 107.6(7) . . ? C23 C22 C221 127.8(9) . . ? C21 C22 C221 124.5(8) . . ? C23 C22 Rh2 68.2(5) . . ? C21 C22 Rh2 73.3(5) . . ? C221 C22 Rh2 126.9(6) . . ? C22 C23 C24 109.2(8) . . ? C22 C23 C231 126.8(8) . . ? C24 C23 C231 122.0(8) . . ? C22 C23 Rh2 76.3(5) . . ? C24 C23 Rh2 70.2(5) . . ? C231 C23 Rh2 132.1(6) . . ? C25 C24 C23 108.2(7) . . ? C25 C24 C241 124.6(7) . . ? C23 C24 C241 126.1(8) . . ? C25 C24 Rh2 74.5(5) . . ? C23 C24 Rh2 72.7(5) . . ? C241 C24 Rh2 128.4(6) . . ? C24 C25 C21 107.2(7) . . ? C24 C25 C251 123.5(7) . . ? C21 C25 C251 126.6(8) . . ? C24 C25 Rh2 69.0(4) . . ? C21 C25 Rh2 75.2(4) . . ? C251 C25 Rh2 135.6(6) . . ? C32 C31 C35 103.3(8) . . ? C32 C31 C311 111.6(7) . . ? C35 C31 C311 112.6(7) . . ? C32 C31 Ga1 110.2(6) . . ? C35 C31 Ga1 109.1(5) . . ? C311 C31 Ga1 109.8(6) . . ? C33 C32 C321 127.6(10) . . ? C33 C32 C31 109.1(8) . . ? C321 C32 C31 123.2(9) . . ? C32 C33 C34 108.4(9) . . ? C32 C33 C331 126.4(9) . . ? C34 C33 C331 125.2(10) . . ? C35 C34 C33 110.7(9) . . ? C35 C34 C341 127.6(9) . . ? C33 C34 C341 121.7(10) . . ? C34 C35 C31 108.4(8) . . ? C34 C35 C351 130.5(9) . . ? C31 C35 C351 121.1(9) . . ? C45 C41 C42 102.2(8) . . ? C45 C41 C411 112.8(7) . . ? C42 C41 C411 112.9(7) . . ? C45 C41 Ga2 109.8(6) . . ? C42 C41 Ga2 110.5(6) . . ? C411 C41 Ga2 108.4(6) . . ? C43 C42 C421 128.2(10) . . ? C43 C42 C41 110.0(9) . . ? C421 C42 C41 121.6(9) . . ? C42 C43 C44 107.8(9) . . ? C42 C43 C431 128.1(10) . . ? C44 C43 C431 124.1(10) . . ? C45 C44 C43 110.2(10) . . ? C45 C44 C441 127.4(10) . . ? C43 C44 C441 122.3(10) . . ? C44 C45 C41 109.8(8) . . ? C44 C45 C451 128.1(10) . . ? C41 C45 C451 122.1(10) . . ? C55 C51 C52 104.1(7) . . ? C55 C51 C511 117.9(7) . . ? C52 C51 C511 117.3(7) . . ? C55 C51 Ga3 100.4(5) . . ? C52 C51 Ga3 104.1(5) . . ? C511 C51 Ga3 110.9(6) . . ? C53 C52 C51 109.3(7) . . ? C53 C52 C521 127.0(8) . . ? C51 C52 C521 123.6(9) . . ? C52 C53 C54 109.3(8) . . ? C52 C53 C531 129.1(8) . . ? C54 C53 C531 121.6(9) . . ? C55 C54 C53 108.0(9) . . ? C55 C54 C541 127.7(8) . . ? C53 C54 C541 124.3(9) . . ? C54 C55 C51 109.2(7) . . ? C54 C55 C551 127.6(9) . . ? C51 C55 C551 123.1(8) . . ? C91A C94 C91 23(2) 2_565 . ? C91A C94 C93 54.5(11) 2_565 2_565 ? C91 C94 C93 32.3(12) . 2_565 ? C91A C91 C93 109(3) 2_565 2_565 ? C91A C91 C92 98(4) 2_565 . ? C93 C91 C92 152.3(15) 2_565 . ? C91A C91 C93A 142(4) 2_565 . ? C93 C91 C93A 32.4(15) 2_565 . ? C92 C91 C93A 120.0 . . ? C91A C91 C92A 67(3) 2_565 2_565 ? C93 C91 C92A 175(3) 2_565 2_565 ? C92 C91 C92A 31.5(13) . 2_565 ? C93A C91 C92A 151.4(13) . 2_565 ? C91A C91 C94 25(2) 2_565 . ? C93 C91 C94 84.6(7) 2_565 . ? C92 C91 C94 123.1(12) . . ? C93A C91 C94 116.8(12) . . ? C92A C91 C94 91.8(6) 2_565 . ? C91A C91 C92 167(4) 2_565 2_565 ? C93 C91 C92 58.4(13) 2_565 2_565 ? C92 C91 C92 94.0(9) . 2_565 ? C93A C91 C92 26.0(9) . 2_565 ? C92A C91 C92 125.4(12) 2_565 2_565 ? C94 C91 C92 142.9(14) . 2_565 ? C91A C91 C93A 110(3) 2_565 2_565 ? C93 C91 C93A 140.1(12) 2_565 2_565 ? C92 C91 C93A 12.2(9) . 2_565 ? C93A C91 C93A 107.9(9) . 2_565 ? C92A C91 C93A 43.5(7) 2_565 2_565 ? C94 C91 C93A 135.2(11) . 2_565 ? C92 C91 C93A 81.8(5) 2_565 2_565 ? C93A C92 C92A 134(4) 2_565 2_565 ? C93A C92 C93 24(2) 2_565 . ? C92A C92 C93 158(3) 2_565 . ? C93A C92 C91 144(2) 2_565 . ? C92A C92 C91 82(3) 2_565 . ? C93 C92 C91 120.0 . . ? C93A C92 C91 57.9(19) 2_565 2_565 ? C92A C92 C91 167(4) 2_565 2_565 ? C93 C92 C91 34.0(8) . 2_565 ? C91 C92 C91 86.0(8) . 2_565 ? C93A C92 C91A 171(3) 2_565 2_565 ? C92A C92 C91A 54(2) 2_565 2_565 ? C93 C92 C91A 147.4(14) . 2_565 ? C91 C92 C91A 27.5(14) . 2_565 ? C91 C92 C91A 113(2) 2_565 2_565 ? C93A C93 C91 109(2) 2_565 2_565 ? C93A C93 C92 21.9(18) 2_565 . ? C91 C93 C92 87.6(6) 2_565 . ? C93A C93 C91A 141.7(19) 2_565 . ? C91 C93 C91A 32.4(6) 2_565 . ? C92 C93 C91A 120.0 . . ? C93A C93 C94 170(3) 2_565 2_565 ? C91 C93 C94 63.1(11) 2_565 2_565 ? C92 C93 C94 150.6(8) . 2_565 ? C91A C93 C94 31.0(8) . 2_565 ? C91 C91A C94 132(3) 2_565 2_565 ? C91 C91A C92A 81.8(18) 2_565 . ? C94 C91A C92A 144.8(18) 2_565 . ? C91 C91A C93 38.3(18) 2_565 . ? C94 C91A C93 94.5(18) 2_565 . ? C92A C91A C93 120.0 . . ? C91 C91A C92 54.3(11) 2_565 2_565 ? C94 C91A C92 169(2) 2_565 2_565 ? C92A C91A C92 27.5(8) . 2_565 ? C93 C91A C92 92.6(8) . 2_565 ? C92 C92A C93A 21.9(18) 2_565 . ? C92 C92A C91A 98.2(19) 2_565 . ? C93A C92A C91A 120.0 . . ? C92 C92A C91 66.8(19) 2_565 2_565 ? C93A C92A C91 88.6(4) . 2_565 ? C91A C92A C91 31.5(4) . 2_565 ? C92 C93A C93 134(4) 2_565 2_565 ? C92 C93A C92A 24.1(19) 2_565 . ? C93 C93A C92A 158(2) 2_565 . ? C92 C93A C91 96(2) 2_565 . ? C93 C93A C91 38(2) 2_565 . ? C92A C93A C91 120.0 . . ? C92 C93A C91 24.0(15) 2_565 2_565 ? C93 C93A C91 110(3) 2_565 2_565 ? C92A C93A C91 47.9(5) . 2_565 ? C91 C93A C91 72.1(5) . 2_565 ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C15 Rh1 Rh2 C24 38.7(10) . . . . ? C11 Rh1 Rh2 C24 119.1(8) . . . . ? C14 Rh1 Rh2 C24 -71.6(9) . . . . ? C12 Rh1 Rh2 C24 175.3(8) . . . . ? C13 Rh1 Rh2 C24 -133.7(8) . . . . ? Ga1 Rh1 Rh2 C24 119.6(7) . . . . ? Ga2 Rh1 Rh2 C24 -76.9(7) . . . . ? Ga3 Rh1 Rh2 C24 21.6(7) . . . . ? C15 Rh1 Rh2 C23 120.6(8) . . . . ? C11 Rh1 Rh2 C23 -159.1(5) . . . . ? C14 Rh1 Rh2 C23 10.2(6) . . . . ? C12 Rh1 Rh2 C23 -102.8(5) . . . . ? C13 Rh1 Rh2 C23 -51.8(5) . . . . ? Ga1 Rh1 Rh2 C23 -158.5(4) . . . . ? Ga2 Rh1 Rh2 C23 5.0(4) . . . . ? Ga3 Rh1 Rh2 C23 103.4(4) . . . . ? C15 Rh1 Rh2 C25 -73.8(9) . . . . ? C11 Rh1 Rh2 C25 6.6(6) . . . . ? C14 Rh1 Rh2 C25 175.9(7) . . . . ? C12 Rh1 Rh2 C25 62.9(6) . . . . ? C13 Rh1 Rh2 C25 113.8(6) . . . . ? Ga1 Rh1 Rh2 C25 7.1(5) . . . . ? Ga2 Rh1 Rh2 C25 170.7(5) . . . . ? Ga3 Rh1 Rh2 C25 -90.9(5) . . . . ? C15 Rh1 Rh2 C22 173.6(8) . . . . ? C11 Rh1 Rh2 C22 -106.1(5) . . . . ? C14 Rh1 Rh2 C22 63.2(6) . . . . ? C12 Rh1 Rh2 C22 -49.8(5) . . . . ? C13 Rh1 Rh2 C22 1.2(5) . . . . ? Ga1 Rh1 Rh2 C22 -105.6(3) . . . . ? Ga2 Rh1 Rh2 C22 58.0(3) . . . . ? Ga3 Rh1 Rh2 C22 156.4(3) . . . . ? C15 Rh1 Rh2 C21 -135.7(8) . . . . ? C11 Rh1 Rh2 C21 -55.3(5) . . . . ? C14 Rh1 Rh2 C21 113.9(6) . . . . ? C12 Rh1 Rh2 C21 0.9(5) . . . . ? C13 Rh1 Rh2 C21 51.9(5) . . . . ? Ga1 Rh1 Rh2 C21 -54.8(3) . . . . ? Ga2 Rh1 Rh2 C21 108.7(3) . . . . ? Ga3 Rh1 Rh2 C21 -152.8(3) . . . . ? C15 Rh1 Rh2 Ga1 -80.9(7) . . . . ? C11 Rh1 Rh2 Ga1 -0.6(4) . . . . ? C14 Rh1 Rh2 Ga1 168.7(5) . . . . ? C12 Rh1 Rh2 Ga1 55.7(3) . . . . ? C13 Rh1 Rh2 Ga1 106.7(3) . . . . ? Ga2 Rh1 Rh2 Ga1 163.51(5) . . . . ? Ga3 Rh1 Rh2 Ga1 -98.03(6) . . . . ? C15 Rh1 Rh2 Ga3 17.1(7) . . . . ? C11 Rh1 Rh2 Ga3 97.5(4) . . . . ? C14 Rh1 Rh2 Ga3 -93.2(5) . . . . ? C12 Rh1 Rh2 Ga3 153.7(3) . . . . ? C13 Rh1 Rh2 Ga3 -155.3(3) . . . . ? Ga1 Rh1 Rh2 Ga3 98.03(6) . . . . ? Ga2 Rh1 Rh2 Ga3 -98.46(6) . . . . ? C15 Rh1 Rh2 Ga2 115.6(7) . . . . ? C11 Rh1 Rh2 Ga2 -164.1(4) . . . . ? C14 Rh1 Rh2 Ga2 5.2(5) . . . . ? C12 Rh1 Rh2 Ga2 -107.8(3) . . . . ? C13 Rh1 Rh2 Ga2 -56.8(3) . . . . ? Ga1 Rh1 Rh2 Ga2 -163.51(5) . . . . ? Ga3 Rh1 Rh2 Ga2 98.46(6) . . . . ? C15 Rh1 Ga1 C31 -19.6(5) . . . . ? C11 Rh1 Ga1 C31 2.5(5) . . . . ? C14 Rh1 Ga1 C31 14.0(6) . . . . ? C12 Rh1 Ga1 C31 39.7(5) . . . . ? C13 Rh1 Ga1 C31 57.3(5) . . . . ? Ga2 Rh1 Ga1 C31 169.8(4) . . . . ? Ga3 Rh1 Ga1 C31 -123.1(4) . . . . ? Rh2 Rh1 Ga1 C31 -177.1(4) . . . . ? C15 Rh1 Ga1 Rh2 157.5(3) . . . . ? C11 Rh1 Ga1 Rh2 179.7(2) . . . . ? C14 Rh1 Ga1 Rh2 -168.9(5) . . . . ? C12 Rh1 Ga1 Rh2 -143.2(2) . . . . ? C13 Rh1 Ga1 Rh2 -125.6(3) . . . . ? Ga2 Rh1 Ga1 Rh2 -13.03(4) . . . . ? Ga3 Rh1 Ga1 Rh2 54.01(5) . . . . ? C15 Rh1 Ga1 Ga3 103.5(3) . . . . ? C11 Rh1 Ga1 Ga3 125.7(2) . . . . ? C14 Rh1 Ga1 Ga3 137.1(5) . . . . ? C12 Rh1 Ga1 Ga3 162.8(2) . . . . ? C13 Rh1 Ga1 Ga3 -179.6(3) . . . . ? Ga2 Rh1 Ga1 Ga3 -67.03(6) . . . . ? Rh2 Rh1 Ga1 Ga3 -54.01(5) . . . . ? C24 Rh2 Ga1 C31 20.7(5) . . . . ? C23 Rh2 Ga1 C31 -38.9(6) . . . . ? C25 Rh2 Ga1 C31 0.7(4) . . . . ? C22 Rh2 Ga1 C31 -62.0(4) . . . . ? C21 Rh2 Ga1 C31 -36.1(4) . . . . ? Ga3 Rh2 Ga1 C31 123.3(4) . . . . ? Ga2 Rh2 Ga1 C31 -169.5(4) . . . . ? Rh1 Rh2 Ga1 C31 177.5(4) . . . . ? C24 Rh2 Ga1 Rh1 -156.8(3) . . . . ? C23 Rh2 Ga1 Rh1 143.6(5) . . . . ? C25 Rh2 Ga1 Rh1 -176.8(2) . . . . ? C22 Rh2 Ga1 Rh1 120.4(2) . . . . ? C21 Rh2 Ga1 Rh1 146.37(19) . . . . ? Ga3 Rh2 Ga1 Rh1 -54.27(4) . . . . ? Ga2 Rh2 Ga1 Rh1 12.95(4) . . . . ? C24 Rh2 Ga1 Ga3 -102.6(3) . . . . ? C23 Rh2 Ga1 Ga3 -162.2(5) . . . . ? C25 Rh2 Ga1 Ga3 -122.6(2) . . . . ? C22 Rh2 Ga1 Ga3 174.7(2) . . . . ? C21 Rh2 Ga1 Ga3 -159.36(19) . . . . ? Ga2 Rh2 Ga1 Ga3 67.22(5) . . . . ? Rh1 Rh2 Ga1 Ga3 54.27(4) . . . . ? C15 Rh1 Ga2 C41 20.7(5) . . . . ? C11 Rh1 Ga2 C41 -30.8(8) . . . . ? C14 Rh1 Ga2 C41 -1.0(4) . . . . ? C12 Rh1 Ga2 C41 -62.8(5) . . . . ? C13 Rh1 Ga2 C41 -37.9(4) . . . . ? Ga1 Rh1 Ga2 C41 -170.3(4) . . . . ? Ga3 Rh1 Ga2 C41 123.0(4) . . . . ? Rh2 Rh1 Ga2 C41 176.7(4) . . . . ? C15 Rh1 Ga2 Rh2 -156.0(3) . . . . ? C11 Rh1 Ga2 Rh2 152.5(7) . . . . ? C14 Rh1 Ga2 Rh2 -177.7(2) . . . . ? C12 Rh1 Ga2 Rh2 120.5(3) . . . . ? C13 Rh1 Ga2 Rh2 145.4(2) . . . . ? Ga1 Rh1 Ga2 Rh2 12.96(4) . . . . ? Ga3 Rh1 Ga2 Rh2 -53.71(5) . . . . ? C15 Rh1 Ga2 Ga3 -102.3(3) . . . . ? C11 Rh1 Ga2 Ga3 -153.8(7) . . . . ? C14 Rh1 Ga2 Ga3 -124.0(2) . . . . ? C12 Rh1 Ga2 Ga3 174.2(3) . . . . ? C13 Rh1 Ga2 Ga3 -160.9(2) . . . . ? Ga1 Rh1 Ga2 Ga3 66.68(5) . . . . ? Rh2 Rh1 Ga2 Ga3 53.71(5) . . . . ? C24 Rh2 Ga2 C41 -17.6(5) . . . . ? C23 Rh2 Ga2 C41 6.7(5) . . . . ? C25 Rh2 Ga2 C41 13.0(7) . . . . ? C22 Rh2 Ga2 C41 42.1(5) . . . . ? C21 Rh2 Ga2 C41 58.8(5) . . . . ? Ga1 Rh2 Ga2 C41 170.8(4) . . . . ? Ga3 Rh2 Ga2 C41 -122.2(4) . . . . ? Rh1 Rh2 Ga2 C41 -176.2(4) . . . . ? C24 Rh2 Ga2 Rh1 158.6(3) . . . . ? C23 Rh2 Ga2 Rh1 -177.1(2) . . . . ? C25 Rh2 Ga2 Rh1 -170.7(5) . . . . ? C22 Rh2 Ga2 Rh1 -141.6(2) . . . . ? C21 Rh2 Ga2 Rh1 -125.0(3) . . . . ? Ga1 Rh2 Ga2 Rh1 -12.93(4) . . . . ? Ga3 Rh2 Ga2 Rh1 54.04(4) . . . . ? C24 Rh2 Ga2 Ga3 104.6(3) . . . . ? C23 Rh2 Ga2 Ga3 128.9(2) . . . . ? C25 Rh2 Ga2 Ga3 135.2(5) . . . . ? C22 Rh2 Ga2 Ga3 164.3(2) . . . . ? C21 Rh2 Ga2 Ga3 -179.0(3) . . . . ? Ga1 Rh2 Ga2 Ga3 -66.97(4) . . . . ? Rh1 Rh2 Ga2 Ga3 -54.04(4) . . . . ? C24 Rh2 Ga3 C51 13.8(5) . . . . ? C23 Rh2 Ga3 C51 52.5(5) . . . . ? C25 Rh2 Ga3 C51 -25.2(5) . . . . ? C22 Rh2 Ga3 C51 74.3(7) . . . . ? C21 Rh2 Ga3 C51 -49.2(8) . . . . ? Ga1 Rh2 Ga3 C51 -119.5(4) . . . . ? Ga2 Rh2 Ga3 C51 132.8(4) . . . . ? Rh1 Rh2 Ga3 C51 -173.4(4) . . . . ? C24 Rh2 Ga3 Rh1 -172.9(2) . . . . ? C23 Rh2 Ga3 Rh1 -134.1(2) . . . . ? C25 Rh2 Ga3 Rh1 148.2(3) . . . . ? C22 Rh2 Ga3 Rh1 -112.3(6) . . . . ? C21 Rh2 Ga3 Rh1 124.2(6) . . . . ? Ga1 Rh2 Ga3 Rh1 53.91(5) . . . . ? Ga2 Rh2 Ga3 Rh1 -53.79(5) . . . . ? C24 Rh2 Ga3 Ga1 133.2(2) . . . . ? C23 Rh2 Ga3 Ga1 172.0(2) . . . . ? C25 Rh2 Ga3 Ga1 94.3(3) . . . . ? C22 Rh2 Ga3 Ga1 -166.2(6) . . . . ? C21 Rh2 Ga3 Ga1 70.3(6) . . . . ? Ga2 Rh2 Ga3 Ga1 -107.70(4) . . . . ? Rh1 Rh2 Ga3 Ga1 -53.91(5) . . . . ? C24 Rh2 Ga3 Ga2 -119.1(2) . . . . ? C23 Rh2 Ga3 Ga2 -80.3(2) . . . . ? C25 Rh2 Ga3 Ga2 -158.0(3) . . . . ? C22 Rh2 Ga3 Ga2 -58.5(6) . . . . ? C21 Rh2 Ga3 Ga2 178.0(6) . . . . ? Ga1 Rh2 Ga3 Ga2 107.70(4) . . . . ? Rh1 Rh2 Ga3 Ga2 53.79(5) . . . . ? C15 Rh1 Ga3 C51 0.3(4) . . . . ? C11 Rh1 Ga3 C51 38.1(4) . . . . ? C14 Rh1 Ga3 C51 -37.9(5) . . . . ? C12 Rh1 Ga3 C51 62.1(7) . . . . ? C13 Rh1 Ga3 C51 -60.6(7) . . . . ? Ga1 Rh1 Ga3 C51 120.4(4) . . . . ? Ga2 Rh1 Ga3 C51 -131.4(4) . . . . ? Rh2 Rh1 Ga3 C51 174.5(4) . . . . ? C15 Rh1 Ga3 Rh2 -174.2(2) . . . . ? C11 Rh1 Ga3 Rh2 -136.4(3) . . . . ? C14 Rh1 Ga3 Rh2 147.6(3) . . . . ? C12 Rh1 Ga3 Rh2 -112.3(6) . . . . ? C13 Rh1 Ga3 Rh2 124.9(6) . . . . ? Ga1 Rh1 Ga3 Rh2 -54.06(5) . . . . ? Ga2 Rh1 Ga3 Rh2 54.14(4) . . . . ? C15 Rh1 Ga3 Ga1 -120.1(3) . . . . ? C11 Rh1 Ga3 Ga1 -82.3(3) . . . . ? C14 Rh1 Ga3 Ga1 -158.3(3) . . . . ? C12 Rh1 Ga3 Ga1 -58.3(6) . . . . ? C13 Rh1 Ga3 Ga1 179.0(6) . . . . ? Ga2 Rh1 Ga3 Ga1 108.21(6) . . . . ? Rh2 Rh1 Ga3 Ga1 54.06(5) . . . . ? C15 Rh1 Ga3 Ga2 131.7(3) . . . . ? C11 Rh1 Ga3 Ga2 169.5(3) . . . . ? C14 Rh1 Ga3 Ga2 93.5(3) . . . . ? C12 Rh1 Ga3 Ga2 -166.5(6) . . . . ? C13 Rh1 Ga3 Ga2 70.8(6) . . . . ? Ga1 Rh1 Ga3 Ga2 -108.21(6) . . . . ? Rh2 Rh1 Ga3 Ga2 -54.14(4) . . . . ? C31 Ga1 Ga3 C51 11.4(5) . . . . ? Rh1 Ga1 Ga3 C51 -122.9(3) . . . . ? Rh2 Ga1 Ga3 C51 135.0(3) . . . . ? C31 Ga1 Ga3 Rh2 -123.7(4) . . . . ? Rh1 Ga1 Ga3 Rh2 102.06(5) . . . . ? C31 Ga1 Ga3 Rh1 134.3(4) . . . . ? Rh2 Ga1 Ga3 Rh1 -102.06(5) . . . . ? C31 Ga1 Ga3 Ga2 -175.0(4) . . . . ? Rh1 Ga1 Ga3 Ga2 50.77(5) . . . . ? Rh2 Ga1 Ga3 Ga2 -51.29(3) . . . . ? C41 Ga2 Ga3 C51 -2.9(5) . . . . ? Rh1 Ga2 Ga3 C51 121.7(4) . . . . ? Rh2 Ga2 Ga3 C51 -136.2(4) . . . . ? C41 Ga2 Ga3 Rh2 133.2(3) . . . . ? Rh1 Ga2 Ga3 Rh2 -102.08(5) . . . . ? C41 Ga2 Ga3 Rh1 -124.7(3) . . . . ? Rh2 Ga2 Ga3 Rh1 102.08(5) . . . . ? C41 Ga2 Ga3 Ga1 -175.6(3) . . . . ? Rh1 Ga2 Ga3 Ga1 -50.88(5) . . . . ? Rh2 Ga2 Ga3 Ga1 51.21(4) . . . . ? C14 Rh1 C11 C15 38.0(4) . . . . ? C12 Rh1 C11 C15 116.4(7) . . . . ? C13 Rh1 C11 C15 80.1(5) . . . . ? Ga1 Rh1 C11 C15 -147.8(4) . . . . ? Ga2 Rh1 C11 C15 72.0(9) . . . . ? Ga3 Rh1 C11 C15 -77.0(5) . . . . ? Rh2 Rh1 C11 C15 -147.3(4) . . . . ? C15 Rh1 C11 C12 -116.4(7) . . . . ? C14 Rh1 C11 C12 -78.4(5) . . . . ? C13 Rh1 C11 C12 -36.4(4) . . . . ? Ga1 Rh1 C11 C12 95.8(4) . . . . ? Ga2 Rh1 C11 C12 -44.4(9) . . . . ? Ga3 Rh1 C11 C12 166.5(4) . . . . ? Rh2 Rh1 C11 C12 96.2(5) . . . . ? C15 Rh1 C11 C111 120.5(11) . . . . ? C14 Rh1 C11 C111 158.5(10) . . . . ? C12 Rh1 C11 C111 -123.1(11) . . . . ? C13 Rh1 C11 C111 -159.5(10) . . . . ? Ga1 Rh1 C11 C111 -27.3(9) . . . . ? Ga2 Rh1 C11 C111 -167.5(6) . . . . ? Ga3 Rh1 C11 C111 43.4(10) . . . . ? Rh2 Rh1 C11 C111 -26.9(12) . . . . ? C15 C11 C12 C13 0.6(9) . . . . ? C111 C11 C12 C13 -164.3(7) . . . . ? Rh1 C11 C12 C13 63.9(6) . . . . ? C15 C11 C12 C121 173.0(8) . . . . ? C111 C11 C12 C121 8.1(13) . . . . ? Rh1 C11 C12 C121 -123.7(8) . . . . ? C15 C11 C12 Rh1 -63.3(6) . . . . ? C111 C11 C12 Rh1 131.8(8) . . . . ? C15 Rh1 C12 C13 -79.4(5) . . . . ? C11 Rh1 C12 C13 -116.5(7) . . . . ? C14 Rh1 C12 C13 -37.2(5) . . . . ? Ga1 Rh1 C12 C13 155.5(4) . . . . ? Ga2 Rh1 C12 C13 46.2(5) . . . . ? Ga3 Rh1 C12 C13 -150.0(5) . . . . ? Rh2 Rh1 C12 C13 115.2(4) . . . . ? C15 Rh1 C12 C11 37.1(4) . . . . ? C14 Rh1 C12 C11 79.3(5) . . . . ? C13 Rh1 C12 C11 116.5(7) . . . . ? Ga1 Rh1 C12 C11 -88.0(4) . . . . ? Ga2 Rh1 C12 C11 162.7(4) . . . . ? Ga3 Rh1 C12 C11 -33.5(8) . . . . ? Rh2 Rh1 C12 C11 -128.3(4) . . . . ? C15 Rh1 C12 C121 156.5(10) . . . . ? C11 Rh1 C12 C121 119.4(11) . . . . ? C14 Rh1 C12 C121 -161.3(10) . . . . ? C13 Rh1 C12 C121 -124.1(11) . . . . ? Ga1 Rh1 C12 C121 31.4(9) . . . . ? Ga2 Rh1 C12 C121 -77.9(9) . . . . ? Ga3 Rh1 C12 C121 85.9(10) . . . . ? Rh2 Rh1 C12 C121 -8.9(10) . . . . ? C11 C12 C13 C14 -1.2(9) . . . . ? C121 C12 C13 C14 -173.5(8) . . . . ? Rh1 C12 C13 C14 59.9(5) . . . . ? C11 C12 C13 C131 171.6(7) . . . . ? C121 C12 C13 C131 -0.6(14) . . . . ? Rh1 C12 C13 C131 -127.3(8) . . . . ? C11 C12 C13 Rh1 -61.1(5) . . . . ? C121 C12 C13 Rh1 126.6(9) . . . . ? C15 Rh1 C13 C12 80.1(5) . . . . ? C11 Rh1 C13 C12 38.5(5) . . . . ? C14 Rh1 C13 C12 117.8(7) . . . . ? Ga1 Rh1 C13 C12 -31.6(6) . . . . ? Ga2 Rh1 C13 C12 -144.3(4) . . . . ? Ga3 Rh1 C13 C12 149.6(5) . . . . ? Rh2 Rh1 C13 C12 -102.7(5) . . . . ? C15 Rh1 C13 C14 -37.7(5) . . . . ? C11 Rh1 C13 C14 -79.3(6) . . . . ? C12 Rh1 C13 C14 -117.8(7) . . . . ? Ga1 Rh1 C13 C14 -149.4(4) . . . . ? Ga2 Rh1 C13 C14 97.9(5) . . . . ? Ga3 Rh1 C13 C14 31.8(10) . . . . ? Rh2 Rh1 C13 C14 139.5(4) . . . . ? C15 Rh1 C13 C131 -160.8(9) . . . . ? C11 Rh1 C13 C131 157.6(9) . . . . ? C14 Rh1 C13 C131 -123.1(11) . . . . ? C12 Rh1 C13 C131 119.1(10) . . . . ? Ga1 Rh1 C13 C131 87.5(8) . . . . ? Ga2 Rh1 C13 C131 -25.2(8) . . . . ? Ga3 Rh1 C13 C131 -91.3(9) . . . . ? Rh2 Rh1 C13 C131 16.4(10) . . . . ? C12 C13 C14 C15 1.5(9) . . . . ? C131 C13 C14 C15 -170.9(8) . . . . ? Rh1 C13 C14 C15 63.1(5) . . . . ? C12 C13 C14 C141 164.1(8) . . . . ? C131 C13 C14 C141 -8.4(14) . . . . ? Rh1 C13 C14 C141 -134.3(9) . . . . ? C12 C13 C14 Rh1 -61.6(6) . . . . ? C131 C13 C14 Rh1 125.9(9) . . . . ? C11 Rh1 C14 C15 -37.5(5) . . . . ? C12 Rh1 C14 C15 -80.5(6) . . . . ? C13 Rh1 C14 C15 -116.5(8) . . . . ? Ga1 Rh1 C14 C15 -50.7(7) . . . . ? Ga2 Rh1 C14 C15 153.7(5) . . . . ? Ga3 Rh1 C14 C15 76.4(5) . . . . ? Rh2 Rh1 C14 C15 149.5(5) . . . . ? C15 Rh1 C14 C13 116.5(8) . . . . ? C11 Rh1 C14 C13 79.0(6) . . . . ? C12 Rh1 C14 C13 35.9(5) . . . . ? Ga1 Rh1 C14 C13 65.8(8) . . . . ? Ga2 Rh1 C14 C13 -89.8(5) . . . . ? Ga3 Rh1 C14 C13 -167.2(4) . . . . ? Rh2 Rh1 C14 C13 -94.0(6) . . . . ? C15 Rh1 C14 C141 -116.1(10) . . . . ? C11 Rh1 C14 C141 -153.6(9) . . . . ? C12 Rh1 C14 C141 163.3(9) . . . . ? C13 Rh1 C14 C141 127.4(11) . . . . ? Ga1 Rh1 C14 C141 -166.8(6) . . . . ? Ga2 Rh1 C14 C141 37.6(8) . . . . ? Ga3 Rh1 C14 C141 -39.8(9) . . . . ? Rh2 Rh1 C14 C141 33.4(11) . . . . ? C12 C11 C15 C14 0.3(9) . . . . ? C111 C11 C15 C14 165.3(7) . . . . ? Rh1 C11 C15 C14 -64.7(6) . . . . ? C12 C11 C15 C151 -166.9(7) . . . . ? C111 C11 C15 C151 -2.0(13) . . . . ? Rh1 C11 C15 C151 128.0(8) . . . . ? C12 C11 C15 Rh1 65.0(6) . . . . ? C111 C11 C15 Rh1 -130.0(8) . . . . ? C13 C14 C15 C11 -1.1(9) . . . . ? C141 C14 C15 C11 -164.8(8) . . . . ? Rh1 C14 C15 C11 64.7(6) . . . . ? C13 C14 C15 C151 166.4(8) . . . . ? C141 C14 C15 C151 2.8(12) . . . . ? Rh1 C14 C15 C151 -127.8(8) . . . . ? C13 C14 C15 Rh1 -65.8(6) . . . . ? C141 C14 C15 Rh1 130.5(7) . . . . ? C14 Rh1 C15 C11 -116.0(7) . . . . ? C12 Rh1 C15 C11 -38.2(5) . . . . ? C13 Rh1 C15 C11 -78.6(5) . . . . ? Ga1 Rh1 C15 C11 39.8(5) . . . . ? Ga2 Rh1 C15 C11 -153.2(4) . . . . ? Ga3 Rh1 C15 C11 121.4(4) . . . . ? Rh2 Rh1 C15 C11 107.2(8) . . . . ? C11 Rh1 C15 C14 116.0(7) . . . . ? C12 Rh1 C15 C14 77.8(5) . . . . ? C13 Rh1 C15 C14 37.4(5) . . . . ? Ga1 Rh1 C15 C14 155.8(4) . . . . ? Ga2 Rh1 C15 C14 -37.2(6) . . . . ? Ga3 Rh1 C15 C14 -122.6(4) . . . . ? Rh2 Rh1 C15 C14 -136.7(6) . . . . ? C11 Rh1 C15 C151 -123.1(10) . . . . ? C14 Rh1 C15 C151 120.9(11) . . . . ? C12 Rh1 C15 C151 -161.3(10) . . . . ? C13 Rh1 C15 C151 158.3(10) . . . . ? Ga1 Rh1 C15 C151 -83.3(9) . . . . ? Ga2 Rh1 C15 C151 83.6(9) . . . . ? Ga3 Rh1 C15 C151 -1.7(9) . . . . ? Rh2 Rh1 C15 C151 -15.9(15) . . . . ? C24 Rh2 C21 C22 80.2(5) . . . . ? C23 Rh2 C21 C22 36.9(5) . . . . ? C25 Rh2 C21 C22 118.4(8) . . . . ? Ga1 Rh2 C21 C22 -141.9(4) . . . . ? Ga3 Rh2 C21 C22 152.9(5) . . . . ? Ga2 Rh2 C21 C22 -29.6(6) . . . . ? Rh1 Rh2 C21 C22 -101.9(5) . . . . ? C24 Rh2 C21 C25 -38.3(5) . . . . ? C23 Rh2 C21 C25 -81.5(6) . . . . ? C22 Rh2 C21 C25 -118.4(8) . . . . ? Ga1 Rh2 C21 C25 99.7(5) . . . . ? Ga3 Rh2 C21 C25 34.5(10) . . . . ? Ga2 Rh2 C21 C25 -148.0(5) . . . . ? Rh1 Rh2 C21 C25 139.7(5) . . . . ? C24 Rh2 C21 C211 -160.5(9) . . . . ? C23 Rh2 C21 C211 156.3(9) . . . . ? C25 Rh2 C21 C211 -122.2(11) . . . . ? C22 Rh2 C21 C211 119.3(9) . . . . ? Ga1 Rh2 C21 C211 -22.6(8) . . . . ? Ga3 Rh2 C21 C211 -87.8(9) . . . . ? Ga2 Rh2 C21 C211 89.7(8) . . . . ? Rh1 Rh2 C21 C211 17.5(10) . . . . ? C25 C21 C22 C23 -0.5(10) . . . . ? C211 C21 C22 C23 171.0(8) . . . . ? Rh2 C21 C22 C23 -59.9(6) . . . . ? C25 C21 C22 C221 -177.0(8) . . . . ? C211 C21 C22 C221 -5.5(14) . . . . ? Rh2 C21 C22 C221 123.7(8) . . . . ? C25 C21 C22 Rh2 59.4(6) . . . . ? C211 C21 C22 Rh2 -129.2(8) . . . . ? C24 Rh2 C22 C23 38.3(5) . . . . ? C25 Rh2 C22 C23 80.6(5) . . . . ? C21 Rh2 C22 C23 117.4(7) . . . . ? Ga1 Rh2 C22 C23 166.0(4) . . . . ? Ga3 Rh2 C22 C23 -30.2(9) . . . . ? Ga2 Rh2 C22 C23 -85.3(4) . . . . ? Rh1 Rh2 C22 C23 -126.9(4) . . . . ? C24 Rh2 C22 C21 -79.1(5) . . . . ? C23 Rh2 C22 C21 -117.4(7) . . . . ? C25 Rh2 C22 C21 -36.8(5) . . . . ? Ga1 Rh2 C22 C21 48.6(5) . . . . ? Ga3 Rh2 C22 C21 -147.6(5) . . . . ? Ga2 Rh2 C22 C21 157.4(4) . . . . ? Rh1 Rh2 C22 C21 115.7(4) . . . . ? C24 Rh2 C22 C221 160.0(9) . . . . ? C23 Rh2 C22 C221 121.7(10) . . . . ? C25 Rh2 C22 C221 -157.7(9) . . . . ? C21 Rh2 C22 C221 -120.9(10) . . . . ? Ga1 Rh2 C22 C221 -72.3(8) . . . . ? Ga3 Rh2 C22 C221 91.5(10) . . . . ? Ga2 Rh2 C22 C221 36.5(8) . . . . ? Rh1 Rh2 C22 C221 -5.2(10) . . . . ? C21 C22 C23 C24 0.1(10) . . . . ? C221 C22 C23 C24 176.5(8) . . . . ? Rh2 C22 C23 C24 -63.0(6) . . . . ? C21 C22 C23 C231 -164.0(8) . . . . ? C221 C22 C23 C231 12.3(14) . . . . ? Rh2 C22 C23 C231 132.9(8) . . . . ? C21 C22 C23 Rh2 63.1(6) . . . . ? C221 C22 C23 Rh2 -120.6(9) . . . . ? C24 Rh2 C23 C22 -116.6(7) . . . . ? C25 Rh2 C23 C22 -78.5(5) . . . . ? C21 Rh2 C23 C22 -36.4(4) . . . . ? Ga1 Rh2 C23 C22 -33.2(8) . . . . ? Ga3 Rh2 C23 C22 168.4(4) . . . . ? Ga2 Rh2 C23 C22 98.4(4) . . . . ? Rh1 Rh2 C23 C22 94.5(5) . . . . ? C25 Rh2 C23 C24 38.1(5) . . . . ? C22 Rh2 C23 C24 116.6(7) . . . . ? C21 Rh2 C23 C24 80.1(5) . . . . ? Ga1 Rh2 C23 C24 83.4(7) . . . . ? Ga3 Rh2 C23 C24 -75.0(5) . . . . ? Ga2 Rh2 C23 C24 -145.1(4) . . . . ? Rh1 Rh2 C23 C24 -148.9(4) . . . . ? C24 Rh2 C23 C231 115.7(10) . . . . ? C25 Rh2 C23 C231 153.9(9) . . . . ? C22 Rh2 C23 C231 -127.7(10) . . . . ? C21 Rh2 C23 C231 -164.1(9) . . . . ? Ga1 Rh2 C23 C231 -160.9(5) . . . . ? Ga3 Rh2 C23 C231 40.8(9) . . . . ? Ga2 Rh2 C23 C231 -29.3(8) . . . . ? Rh1 Rh2 C23 C231 -33.2(10) . . . . ? C22 C23 C24 C25 0.3(10) . . . . ? C231 C23 C24 C25 165.4(8) . . . . ? Rh2 C23 C24 C25 -66.6(6) . . . . ? C22 C23 C24 C241 -167.8(8) . . . . ? C231 C23 C24 C241 -2.7(12) . . . . ? Rh2 C23 C24 C241 125.3(8) . . . . ? C22 C23 C24 Rh2 66.9(6) . . . . ? C231 C23 C24 Rh2 -128.0(7) . . . . ? C23 Rh2 C24 C25 115.2(7) . . . . ? C22 Rh2 C24 C25 78.5(5) . . . . ? C21 Rh2 C24 C25 38.0(5) . . . . ? Ga1 Rh2 C24 C25 -33.9(6) . . . . ? Ga3 Rh2 C24 C25 -119.8(4) . . . . ? Ga2 Rh2 C24 C25 158.1(4) . . . . ? Rh1 Rh2 C24 C25 -137.7(6) . . . . ? C25 Rh2 C24 C23 -115.2(7) . . . . ? C22 Rh2 C24 C23 -36.7(5) . . . . ? C21 Rh2 C24 C23 -77.2(5) . . . . ? Ga1 Rh2 C24 C23 -149.1(4) . . . . ? Ga3 Rh2 C24 C23 125.0(4) . . . . ? Ga2 Rh2 C24 C23 42.9(5) . . . . ? Rh1 Rh2 C24 C23 107.1(7) . . . . ? C23 Rh2 C24 C241 -122.7(10) . . . . ? C25 Rh2 C24 C241 122.1(10) . . . . ? C22 Rh2 C24 C241 -159.4(9) . . . . ? C21 Rh2 C24 C241 160.1(9) . . . . ? Ga1 Rh2 C24 C241 88.2(8) . . . . ? Ga3 Rh2 C24 C241 2.3(9) . . . . ? Ga2 Rh2 C24 C241 -79.8(8) . . . . ? Rh1 Rh2 C24 C241 -15.6(14) . . . . ? C23 C24 C25 C21 -0.6(9) . . . . ? C241 C24 C25 C21 167.7(8) . . . . ? Rh2 C24 C25 C21 -66.0(6) . . . . ? C23 C24 C25 C251 -163.0(8) . . . . ? C241 C24 C25 C251 5.3(13) . . . . ? Rh2 C24 C25 C251 131.5(8) . . . . ? C23 C24 C25 Rh2 65.4(5) . . . . ? C241 C24 C25 Rh2 -126.2(8) . . . . ? C22 C21 C25 C24 0.7(9) . . . . ? C211 C21 C25 C24 -170.3(8) . . . . ? Rh2 C21 C25 C24 62.0(6) . . . . ? C22 C21 C25 C251 162.4(8) . . . . ? C211 C21 C25 C251 -8.6(15) . . . . ? Rh2 C21 C25 C251 -136.3(9) . . . . ? C22 C21 C25 Rh2 -61.3(6) . . . . ? C211 C21 C25 Rh2 127.7(9) . . . . ? C23 Rh2 C25 C24 -38.7(5) . . . . ? C22 Rh2 C25 C24 -79.8(5) . . . . ? C21 Rh2 C25 C24 -115.4(7) . . . . ? Ga1 Rh2 C25 C24 156.5(4) . . . . ? Ga3 Rh2 C25 C24 79.3(5) . . . . ? Ga2 Rh2 C25 C24 -46.0(7) . . . . ? Rh1 Rh2 C25 C24 150.8(4) . . . . ? C24 Rh2 C25 C21 115.4(7) . . . . ? C23 Rh2 C25 C21 76.7(6) . . . . ? C22 Rh2 C25 C21 35.6(5) . . . . ? Ga1 Rh2 C25 C21 -88.1(5) . . . . ? Ga3 Rh2 C25 C21 -165.3(4) . . . . ? Ga2 Rh2 C25 C21 69.4(8) . . . . ? Rh1 Rh2 C25 C21 -93.8(6) . . . . ? C24 Rh2 C25 C251 -117.0(11) . . . . ? C23 Rh2 C25 C251 -155.7(10) . . . . ? C22 Rh2 C25 C251 163.2(10) . . . . ? C21 Rh2 C25 C251 127.6(12) . . . . ? Ga1 Rh2 C25 C251 39.5(9) . . . . ? Ga3 Rh2 C25 C251 -37.7(10) . . . . ? Ga2 Rh2 C25 C251 -163.0(6) . . . . ? Rh1 Rh2 C25 C251 33.8(12) . . . . ? Rh1 Ga1 C31 C32 47.5(8) . . . . ? Rh2 Ga1 C31 C32 -128.3(5) . . . . ? Ga3 Ga1 C31 C32 -44.3(7) . . . . ? Rh1 Ga1 C31 C35 -65.3(8) . . . . ? Rh2 Ga1 C31 C35 118.9(5) . . . . ? Ga3 Ga1 C31 C35 -157.1(4) . . . . ? Rh1 Ga1 C31 C311 170.8(4) . . . . ? Rh2 Ga1 C31 C311 -5.0(8) . . . . ? Ga3 Ga1 C31 C311 79.0(7) . . . . ? C35 C31 C32 C33 -1.7(9) . . . . ? C311 C31 C32 C33 119.5(8) . . . . ? Ga1 C31 C32 C33 -118.2(7) . . . . ? C35 C31 C32 C321 -177.7(8) . . . . ? C311 C31 C32 C321 -56.5(11) . . . . ? Ga1 C31 C32 C321 65.8(9) . . . . ? C321 C32 C33 C34 177.8(8) . . . . ? C31 C32 C33 C34 2.0(10) . . . . ? C321 C32 C33 C331 -4.7(15) . . . . ? C31 C32 C33 C331 179.5(8) . . . . ? C32 C33 C34 C35 -1.6(11) . . . . ? C331 C33 C34 C35 -179.1(8) . . . . ? C32 C33 C34 C341 178.7(8) . . . . ? C331 C33 C34 C341 1.1(14) . . . . ? C33 C34 C35 C31 0.4(10) . . . . ? C341 C34 C35 C31 -179.8(8) . . . . ? C33 C34 C35 C351 -178.2(8) . . . . ? C341 C34 C35 C351 1.6(16) . . . . ? C32 C31 C35 C34 0.7(9) . . . . ? C311 C31 C35 C34 -119.8(8) . . . . ? Ga1 C31 C35 C34 118.0(7) . . . . ? C32 C31 C35 C351 179.5(7) . . . . ? C311 C31 C35 C351 59.0(11) . . . . ? Ga1 C31 C35 C351 -63.3(9) . . . . ? Rh1 Ga2 C41 C45 -127.1(5) . . . . ? Rh2 Ga2 C41 C45 47.4(8) . . . . ? Ga3 Ga2 C41 C45 -42.6(8) . . . . ? Rh1 Ga2 C41 C42 120.9(6) . . . . ? Rh2 Ga2 C41 C42 -64.6(8) . . . . ? Ga3 Ga2 C41 C42 -154.6(5) . . . . ? Rh1 Ga2 C41 C411 -3.4(8) . . . . ? Rh2 Ga2 C41 C411 171.1(4) . . . . ? Ga3 Ga2 C41 C411 81.1(7) . . . . ? C45 C41 C42 C43 1.4(9) . . . . ? C411 C41 C42 C43 -120.1(9) . . . . ? Ga2 C41 C42 C43 118.3(7) . . . . ? C45 C41 C42 C421 175.7(8) . . . . ? C411 C41 C42 C421 54.2(11) . . . . ? Ga2 C41 C42 C421 -67.5(9) . . . . ? C421 C42 C43 C44 -175.6(9) . . . . ? C41 C42 C43 C44 -1.8(10) . . . . ? C421 C42 C43 C431 5.7(17) . . . . ? C41 C42 C43 C431 179.5(8) . . . . ? C42 C43 C44 C45 1.6(11) . . . . ? C431 C43 C44 C45 -179.6(9) . . . . ? C42 C43 C44 C441 -179.1(9) . . . . ? C431 C43 C44 C441 -0.4(14) . . . . ? C43 C44 C45 C41 -0.7(11) . . . . ? C441 C44 C45 C41 -179.9(8) . . . . ? C43 C44 C45 C451 177.2(9) . . . . ? C441 C44 C45 C451 -2.0(17) . . . . ? C42 C41 C45 C44 -0.4(9) . . . . ? C411 C41 C45 C44 121.2(9) . . . . ? Ga2 C41 C45 C44 -117.8(8) . . . . ? C42 C41 C45 C451 -178.4(8) . . . . ? C411 C41 C45 C451 -56.9(11) . . . . ? Ga2 C41 C45 C451 64.2(9) . . . . ? Rh2 Ga3 C51 C55 -102.2(5) . . . . ? Rh1 Ga3 C51 C55 87.3(6) . . . . ? Ga1 Ga3 C51 C55 168.5(4) . . . . ? Ga2 Ga3 C51 C55 -1.1(7) . . . . ? Rh2 Ga3 C51 C52 5.4(9) . . . . ? Rh1 Ga3 C51 C52 -165.1(4) . . . . ? Ga1 Ga3 C51 C52 -83.9(7) . . . . ? Ga2 Ga3 C51 C52 106.5(6) . . . . ? Rh2 Ga3 C51 C511 132.4(5) . . . . ? Rh1 Ga3 C51 C511 -38.1(7) . . . . ? Ga1 Ga3 C51 C511 43.2(7) . . . . ? Ga2 Ga3 C51 C511 -126.4(5) . . . . ? C55 C51 C52 C53 2.9(9) . . . . ? C511 C51 C52 C53 135.2(8) . . . . ? Ga3 C51 C52 C53 -101.9(7) . . . . ? C55 C51 C52 C521 -179.3(7) . . . . ? C511 C51 C52 C521 -47.1(11) . . . . ? Ga3 C51 C52 C521 75.9(8) . . . . ? C51 C52 C53 C54 -2.6(9) . . . . ? C521 C52 C53 C54 179.7(7) . . . . ? C51 C52 C53 C531 -179.1(8) . . . . ? C521 C52 C53 C531 3.2(14) . . . . ? C52 C53 C54 C55 1.3(9) . . . . ? C531 C53 C54 C55 178.0(8) . . . . ? C52 C53 C54 C541 -179.4(8) . . . . ? C531 C53 C54 C541 -2.7(12) . . . . ? C53 C54 C55 C51 0.6(9) . . . . ? C541 C54 C55 C51 -178.7(8) . . . . ? C53 C54 C55 C551 -175.5(7) . . . . ? C541 C54 C55 C551 5.2(15) . . . . ? C52 C51 C55 C54 -2.1(9) . . . . ? C511 C51 C55 C54 -134.0(8) . . . . ? Ga3 C51 C55 C54 105.5(7) . . . . ? C52 C51 C55 C551 174.3(7) . . . . ? C511 C51 C55 C551 42.4(10) . . . . ? Ga3 C51 C55 C551 -78.1(8) . . . . ? C93 C94 C91 C91A 166(9) 2_565 . . 2_565 ? C91A C94 C91 C93 -166(9) 2_565 . . 2_565 ? C91A C94 C91 C92 14(6) 2_565 . . . ? C93 C94 C91 C92 179(3) 2_565 . . . ? C91A C94 C91 C93A -170(7) 2_565 . . . ? C93 C94 C91 C93A -3.9(19) 2_565 . . . ? C91A C94 C91 C92A 11(5) 2_565 . . 2_565 ? C93 C94 C91 C92A 176(4) 2_565 . . 2_565 ? C91A C94 C91 C92 -170(9) 2_565 . . 2_565 ? C93 C94 C91 C92 -4.2(7) 2_565 . . 2_565 ? C91A C94 C91 C93A 13(4) 2_565 . . 2_565 ? C93 C94 C91 C93A 179(5) 2_565 . . 2_565 ? C91A C91 C92 C93A -173(8) 2_565 . . 2_565 ? C93 C91 C92 C93A 0(5) 2_565 . . 2_565 ? C93A C91 C92 C93A 5(5) . . . 2_565 ? C92A C91 C92 C93A -173(9) 2_565 . . 2_565 ? C94 C91 C92 C93A -179(6) . . . 2_565 ? C92 C91 C92 C93A 3(5) 2_565 . . 2_565 ? C91A C91 C92 C92A 0.0(15) 2_565 . . 2_565 ? C93 C91 C92 C92A 173(8) 2_565 . . 2_565 ? C93A C91 C92 C92A 177(4) . . . 2_565 ? C94 C91 C92 C92A -6(3) . . . 2_565 ? C92 C91 C92 C92A 176(4) 2_565 . . 2_565 ? C93A C91 C92 C92A 173(9) 2_565 . . 2_565 ? C91A C91 C92 C93 -177(4) 2_565 . . . ? C93 C91 C92 C93 -5(5) 2_565 . . . ? C93A C91 C92 C93 0.0 . . . . ? C92A C91 C92 C93 -177(4) 2_565 . . . ? C94 C91 C92 C93 176.6(13) . . . . ? C92 C91 C92 C93 -1.2(11) 2_565 . . . ? C93A C91 C92 C93 -5(5) 2_565 . . . ? C91A C91 C92 C91 -176(5) 2_565 . . 2_565 ? C93 C91 C92 C91 -3(5) 2_565 . . 2_565 ? C93A C91 C92 C91 1.2(11) . . . 2_565 ? C92A C91 C92 C91 -176(5) 2_565 . . 2_565 ? C94 C91 C92 C91 178(2) . . . 2_565 ? C92 C91 C92 C91 0.0(6) 2_565 . . 2_565 ? C93A C91 C92 C91 -3(4) 2_565 . . 2_565 ? C93 C91 C92 C91A 173(9) 2_565 . . 2_565 ? C93A C91 C92 C91A 177(4) . . . 2_565 ? C92A C91 C92 C91A 0.0(15) 2_565 . . 2_565 ? C94 C91 C92 C91A -6(2) . . . 2_565 ? C92 C91 C92 C91A 176(4) 2_565 . . 2_565 ? C93A C91 C92 C91A 173(8) 2_565 . . 2_565 ? C92A C92 C93 C93A 0(4) 2_565 . . 2_565 ? C91 C92 C93 C93A 173(8) . . . 2_565 ? C91 C92 C93 C93A 171(10) 2_565 . . 2_565 ? C91A C92 C93 C93A 171(10) 2_565 . . 2_565 ? C93A C92 C93 C91 -171(10) 2_565 . . 2_565 ? C92A C92 C93 C91 -171(11) 2_565 . . 2_565 ? C91 C92 C93 C91 2(2) . . . 2_565 ? C91A C92 C93 C91 0.0(18) 2_565 . . 2_565 ? C93A C92 C93 C91A -173(8) 2_565 . . . ? C92A C92 C93 C91A -173(10) 2_565 . . . ? C91 C92 C93 C91A 0.0 . . . . ? C91 C92 C93 C91A -2(2) 2_565 . . . ? C91A C92 C93 C91A -2(3) 2_565 . . . ? C93A C92 C93 C94 -166(9) 2_565 . . 2_565 ? C92A C92 C93 C94 -166(10) 2_565 . . 2_565 ? C91 C92 C93 C94 7.6(15) . . . 2_565 ? C91 C92 C93 C94 5.4(19) 2_565 . . 2_565 ? C91A C92 C93 C94 5(4) 2_565 . . 2_565 ? C93A C93 C91A C91 0(2) 2_565 . . 2_565 ? C92 C93 C91A C91 4(4) . . . 2_565 ? C94 C93 C91A C91 -169(4) 2_565 . . 2_565 ? C93A C93 C91A C94 169(5) 2_565 . . 2_565 ? C91 C93 C91A C94 169(4) 2_565 . . 2_565 ? C92 C93 C91A C94 172.8(14) . . . 2_565 ? C93A C93 C91A C92A -4(5) 2_565 . . . ? C91 C93 C91A C92A -4(4) 2_565 . . . ? C92 C93 C91A C92A 0.0 . . . . ? C94 C93 C91A C92A -172.8(14) 2_565 . . . ? C93A C93 C91A C92 -3(4) 2_565 . . 2_565 ? C91 C93 C91A C92 -3(3) 2_565 . . 2_565 ? C92 C93 C91A C92 1.2(10) . . . 2_565 ? C94 C93 C91A C92 -172(2) 2_565 . . 2_565 ? C91 C91A C92A C92 0.0(12) 2_565 . . 2_565 ? C94 C91A C92A C92 -165(4) 2_565 . . 2_565 ? C93 C91A C92A C92 3(2) . . . 2_565 ? C91 C91A C92A C93A -3(2) 2_565 . . . ? C94 C91A C92A C93A -167(2) 2_565 . . . ? C93 C91A C92A C93A 0.0 . . . . ? C92 C91A C92A C93A -3(2) 2_565 . . . ? C94 C91A C92A C91 -165(4) 2_565 . . 2_565 ? C93 C91A C92A C91 3(2) . . . 2_565 ? C92 C91A C92A C91 0.0(12) 2_565 . . 2_565 ? C91A C92A C93A C92 7(6) . . . 2_565 ? C91 C92A C93A C92 5(5) 2_565 . . 2_565 ? C92 C92A C93A C93 0(4) 2_565 . . 2_565 ? C91A C92A C93A C93 7(8) . . . 2_565 ? C91 C92A C93A C93 5(7) 2_565 . . 2_565 ? C92 C92A C93A C91 -7(6) 2_565 . . . ? C91A C92A C93A C91 0.0 . . . . ? C91 C92A C93A C91 -1.3(12) 2_565 . . . ? C92 C92A C93A C91 -5(5) 2_565 . . 2_565 ? C91A C92A C93A C91 1.3(12) . . . 2_565 ? C91A C91 C93A C92 173(8) 2_565 . . 2_565 ? C93 C91 C93A C92 173(7) 2_565 . . 2_565 ? C92 C91 C93A C92 -3(2) . . . 2_565 ? C92A C91 C93A C92 0(3) 2_565 . . 2_565 ? C94 C91 C93A C92 -180(3) . . . 2_565 ? C93A C91 C93A C92 -2(2) 2_565 . . 2_565 ? C91A C91 C93A C93 0(2) 2_565 . . 2_565 ? C92 C91 C93A C93 -176(5) . . . 2_565 ? C92A C91 C93A C93 -173(8) 2_565 . . 2_565 ? C94 C91 C93A C93 7(4) . . . 2_565 ? C92 C91 C93A C93 -173(7) 2_565 . . 2_565 ? C93A C91 C93A C93 -175(5) 2_565 . . 2_565 ? C91A C91 C93A C92A 176(6) 2_565 . . . ? C93 C91 C93A C92A 176(5) 2_565 . . . ? C92 C91 C93A C92A 0.0 . . . . ? C92A C91 C93A C92A 3(4) 2_565 . . . ? C94 C91 C93A C92A -176.8(13) . . . . ? C92 C91 C93A C92A 3(2) 2_565 . . . ? C93A C91 C93A C92A 1.0(12) 2_565 . . . ? C91A C91 C93A C91 175(7) 2_565 . . 2_565 ? C93 C91 C93A C91 175(6) 2_565 . . 2_565 ? C92 C91 C93A C91 -1.0(9) . . . 2_565 ? C92A C91 C93A C91 2(3) 2_565 . . 2_565 ? C94 C91 C93A C91 -178(2) . . . 2_565 ? C92 C91 C93A C91 1.7(17) 2_565 . . 2_565 ? C93A C91 C93A C91 0.0(6) 2_565 . . 2_565 ? _diffrn_measured_fraction_theta_max 0.972 _diffrn_reflns_theta_full 25.41 _diffrn_measured_fraction_theta_full 0.972 _refine_diff_density_max 1.318 _refine_diff_density_min -1.833 _refine_diff_density_rms 0.162 #=================================================END data_7 _database_code_depnum_ccdc_archive 'CCDC 240972' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C34 H48 Ga2 Rh2' _chemical_formula_weight 801.98 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Orthorhombic _symmetry_space_group_name_H-M Pbca loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' '-x, -y, -z' 'x-1/2, y, -z-1/2' 'x, -y-1/2, z-1/2' '-x-1/2, y-1/2, z' _cell_length_a 15.283(3) _cell_length_b 11.742(2) _cell_length_c 17.902(4) _cell_angle_alpha 90.00 _cell_angle_beta 90.00 _cell_angle_gamma 90.00 _cell_volume 3212.8(12) _cell_formula_units_Z 4 _cell_measurement_temperature 213(2) _cell_measurement_reflns_used 60 _cell_measurement_theta_min 10.5 _cell_measurement_theta_max 15.0 _exptl_crystal_description prism _exptl_crystal_colour 'dark red' _exptl_crystal_size_max 0.28 _exptl_crystal_size_mid 0.25 _exptl_crystal_size_min 0.20 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.658 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1616 _exptl_absorpt_coefficient_mu 2.689 _exptl_absorpt_correction_type empirical _exptl_absorpt_correction_T_min 0.746 _exptl_absorpt_correction_T_max 1.000 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 213(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker axs CCD 1000' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 17290 _diffrn_reflns_av_R_equivalents 0.0787 _diffrn_reflns_av_sigmaI/netI 0.0450 _diffrn_reflns_limit_h_min -18 _diffrn_reflns_limit_h_max 17 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 13 _diffrn_reflns_limit_l_min -21 _diffrn_reflns_limit_l_max 18 _diffrn_reflns_theta_min 2.47 _diffrn_reflns_theta_max 25.05 _reflns_number_total 2832 _reflns_number_gt 2171 _reflns_threshold_expression >2sigma(I) _computing_data_collection SMART _computing_cell_refinement SMART _computing_data_reduction SMART _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker axs SHELXTL-PLUS' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0462P)^2^+6.0076P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 2832 _refine_ls_number_parameters 241 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0561 _refine_ls_R_factor_gt 0.0371 _refine_ls_wR_factor_ref 0.1002 _refine_ls_wR_factor_gt 0.0906 _refine_ls_goodness_of_fit_ref 1.025 _refine_ls_restrained_S_all 1.025 _refine_ls_shift/su_max 0.106 _refine_ls_shift/su_mean 0.007 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.07649(3) 0.39164(3) 0.44629(2) 0.04428(16) Uani 1 1 d . . . C11 C 0.0283(10) 0.2203(9) 0.4435(6) 0.062(3) Uani 0.583(9) 1 d P A 1 H11 H -0.0009 0.1892 0.4850 0.074 Uiso 0.583(9) 1 calc PR A 1 C12 C -0.0088(11) 0.2882(15) 0.3878(9) 0.066(5) Uani 0.583(9) 1 d P A 1 H12 H -0.0678 0.3104 0.3855 0.080 Uiso 0.583(9) 1 calc PR A 1 C13 C 0.0546(9) 0.3175(9) 0.3367(5) 0.066(4) Uani 0.583(9) 1 d P A 1 H13 H 0.0468 0.3635 0.2942 0.079 Uiso 0.583(9) 1 calc PR A 1 C14 C 0.1321(11) 0.2669(14) 0.3593(9) 0.078(5) Uani 0.583(9) 1 d P A 1 H14 H 0.1860 0.2715 0.3342 0.094 Uiso 0.583(9) 1 calc PR A 1 C15 C 0.1164(11) 0.2074(9) 0.4262(7) 0.085(5) Uani 0.583(9) 1 d P A 1 H15 H 0.1580 0.1664 0.4541 0.102 Uiso 0.583(9) 1 calc PR A 1 C161 C 0.1825(8) 0.5232(13) 0.4539(7) 0.059(4) Uani 0.583(9) 1 d P A 1 C162 C 0.1934(10) 0.4525(13) 0.5160(8) 0.060(4) Uani 0.583(9) 1 d P A 1 C11' C 0.1933(9) 0.2941(17) 0.4662(9) 0.072(6) Uani 0.417(9) 1 d P A 2 H11A H 0.1971 0.2324 0.4995 0.086 Uiso 0.417(9) 1 calc PR A 2 C12' C 0.2009(12) 0.4076(18) 0.4875(12) 0.059(5) Uani 0.417(9) 1 d P A 2 H12A H 0.2074 0.4353 0.5365 0.070 Uiso 0.417(9) 1 calc PR A 2 C13' C 0.1969(11) 0.478(2) 0.4166(17) 0.087(8) Uani 0.417(9) 1 d P A 2 H13A H 0.2016 0.5575 0.4119 0.105 Uiso 0.417(9) 1 calc PR A 2 C14' C 0.1846(11) 0.399(2) 0.3604(11) 0.096(8) Uani 0.417(9) 1 d P A 2 H14A H 0.1804 0.4185 0.3096 0.115 Uiso 0.417(9) 1 calc PR A 2 C15' C 0.1787(16) 0.282(2) 0.3871(12) 0.081(6) Uani 0.417(9) 1 d P A 2 H15A H 0.1680 0.2156 0.3595 0.098 Uiso 0.417(9) 1 calc PR A 2 C161' C -0.0378(17) 0.2639(16) 0.4308(15) 0.079(7) Uani 0.417(9) 1 d P A 2 C162' C -0.0456(15) 0.3426(17) 0.3712(11) 0.071(5) Uani 0.417(9) 1 d P A 2 Ga1 Ga -0.00511(4) 0.56970(5) 0.43648(3) 0.04370(19) Uani 1 1 d . . . C21 C -0.0020(5) 0.6634(5) 0.3370(3) 0.0665(19) Uani 1 1 d . . . C22 C 0.0081(4) 0.7784(5) 0.3648(3) 0.0600(16) Uani 1 1 d . . . C23 C -0.0713(4) 0.8288(4) 0.3705(3) 0.0555(15) Uani 1 1 d . . . C24 C -0.1354(4) 0.7513(6) 0.3436(3) 0.0611(16) Uani 1 1 d . . . C25 C -0.0944(5) 0.6550(5) 0.3212(3) 0.069(2) Uani 1 1 d . . . C211 C 0.0658(8) 0.6155(8) 0.2829(5) 0.160(6) Uani 1 1 d . . . H21A H 0.0500 0.5380 0.2696 0.239 Uiso 1 1 calc R . . H21B H 0.1229 0.6158 0.3064 0.239 Uiso 1 1 calc R . . H21C H 0.0674 0.6621 0.2382 0.239 Uiso 1 1 calc R . . C221 C 0.0958(5) 0.8356(9) 0.3837(6) 0.136(4) Uani 1 1 d . . . H22A H 0.1338 0.8331 0.3404 0.204 Uiso 1 1 calc R . . H22B H 0.1233 0.7955 0.4249 0.204 Uiso 1 1 calc R . . H22C H 0.0856 0.9142 0.3979 0.204 Uiso 1 1 calc R . . C231 C -0.0908(7) 0.9468(6) 0.3986(4) 0.115(4) Uani 1 1 d . . . H23A H -0.1353 0.9430 0.4371 0.173 Uiso 1 1 calc R . . H23B H -0.1116 0.9936 0.3576 0.173 Uiso 1 1 calc R . . H23C H -0.0379 0.9801 0.4192 0.173 Uiso 1 1 calc R . . C241 C -0.2314(5) 0.7745(9) 0.3412(5) 0.127(4) Uani 1 1 d . . . H24A H -0.2430 0.8359 0.3063 0.190 Uiso 1 1 calc R . . H24B H -0.2516 0.7962 0.3906 0.190 Uiso 1 1 calc R . . H24C H -0.2621 0.7065 0.3251 0.190 Uiso 1 1 calc R . . C251 C -0.1356(9) 0.5546(7) 0.2802(5) 0.164(6) Uani 1 1 d . . . H25A H -0.1967 0.5708 0.2703 0.247 Uiso 1 1 calc R . . H25B H -0.1310 0.4867 0.3108 0.247 Uiso 1 1 calc R . . H25C H -0.1051 0.5424 0.2333 0.247 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.0526(3) 0.0359(2) 0.0444(3) 0.00333(17) 0.01883(19) 0.01234(19) C11 0.087(9) 0.045(6) 0.053(6) -0.012(5) -0.002(6) -0.026(6) C12 0.052(9) 0.076(13) 0.071(11) -0.031(9) -0.017(8) 0.006(8) C13 0.120(11) 0.049(6) 0.030(5) -0.009(4) -0.007(6) -0.014(6) C14 0.065(10) 0.090(10) 0.081(11) -0.053(9) 0.008(8) 0.000(8) C15 0.139(14) 0.039(6) 0.076(9) -0.021(6) -0.043(9) 0.032(7) C161 0.039(7) 0.087(10) 0.053(8) 0.010(6) 0.004(5) -0.025(7) C162 0.051(8) 0.064(10) 0.064(9) -0.007(6) -0.016(7) -0.024(7) C11 0.035(8) 0.118(16) 0.063(10) 0.032(10) 0.019(7) 0.039(9) C12 0.040(9) 0.065(15) 0.071(14) -0.008(9) 0.005(9) -0.007(9) C13 0.032(9) 0.12(2) 0.11(2) 0.037(16) 0.022(13) 0.012(11) C14 0.045(10) 0.17(2) 0.077(13) 0.068(14) 0.037(9) 0.047(12) C15 0.091(17) 0.084(15) 0.069(14) -0.015(11) 0.035(12) 0.045(13) C161 0.091(18) 0.032(8) 0.11(2) 0.001(11) -0.058(15) -0.015(10) C162 0.079(15) 0.061(12) 0.071(12) -0.005(10) -0.015(11) -0.044(10) Ga1 0.0545(4) 0.0337(3) 0.0429(3) 0.0069(2) 0.0192(3) 0.0111(3) C21 0.096(5) 0.051(4) 0.053(3) 0.019(3) 0.025(3) 0.034(4) C22 0.058(4) 0.064(4) 0.058(4) 0.031(3) 0.006(3) -0.010(3) C23 0.083(5) 0.036(3) 0.047(3) 0.009(2) 0.010(3) 0.010(3) C24 0.056(4) 0.074(4) 0.053(3) 0.023(3) 0.002(3) 0.002(3) C25 0.124(7) 0.043(3) 0.041(3) 0.006(3) -0.001(4) -0.011(4) C211 0.261(13) 0.134(8) 0.084(6) 0.071(5) 0.110(7) 0.129(9) C221 0.077(6) 0.176(10) 0.155(9) 0.094(8) -0.018(6) -0.054(6) C231 0.229(11) 0.049(4) 0.068(5) 0.004(4) 0.020(6) 0.035(5) C241 0.050(5) 0.218(11) 0.113(7) 0.064(7) -0.009(4) 0.012(6) C251 0.330(17) 0.091(6) 0.073(6) 0.006(5) -0.039(8) -0.092(9) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 C12 2.05(2) . ? Rh1 C12 2.066(15) . ? Rh1 C11 2.143(10) . ? Rh1 C11 2.151(13) . ? Rh1 C13 2.17(2) . ? Rh1 C13 2.172(9) . ? Rh1 C161 2.243(12) . ? Rh1 C14 2.258(15) . ? Rh1 C15 2.276(10) . ? Rh1 C162 2.294(13) . ? Rh1 C15 2.283(16) . ? Rh1 C161 2.32(2) . ? C11 C15 1.39(2) . ? C11 C12 1.40(2) . ? C11 H11 0.9400 . ? C12 C13 1.38(2) . ? C12 H12 0.9400 . ? C13 C14 1.38(2) . ? C13 H13 0.9400 . ? C14 C15 1.41(2) . ? C14 H14 0.9400 . ? C15 H15 0.9400 . ? C161 C162 1.40(2) . ? C11 C12 1.39(3) . ? C11 C15 1.44(3) . ? C11 H11A 0.9400 . ? C12 C13 1.52(3) . ? C12 H12A 0.9400 . ? C13 C14 1.38(3) . ? C13 H13A 0.9400 . ? C14 C15 1.45(3) . ? C14 H14A 0.9400 . ? C15 H15A 0.9400 . ? C161 C162 1.42(3) . ? Ga1 C21 2.094(6) . ? Ga1 Rh1 2.4085(8) 5_566 ? Ga1 Ga1 2.8065(12) 5_566 ? C21 C22 1.447(9) . ? C21 C25 1.445(9) . ? C21 C211 1.526(9) . ? C22 C23 1.354(8) . ? C22 C221 1.536(9) . ? C23 C24 1.421(9) . ? C23 C231 1.504(8) . ? C24 C25 1.353(9) . ? C24 C241 1.494(9) . ? C25 C251 1.525(10) . ? C211 H21A 0.9700 . ? C211 H21B 0.9700 . ? C211 H21C 0.9700 . ? C221 H22A 0.9700 . ? C221 H22B 0.9700 . ? C221 H22C 0.9700 . ? C231 H23A 0.9700 . ? C231 H23B 0.9700 . ? C231 H23C 0.9700 . ? C241 H24A 0.9700 . ? C241 H24B 0.9700 . ? C241 H24C 0.9700 . ? C251 H25A 0.9700 . ? C251 H25B 0.9700 . ? C251 H25C 0.9700 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C12 Rh1 C12 145.3(7) . . ? C12 Rh1 C11 114.4(7) . . ? C12 Rh1 C11 38.7(6) . . ? C12 Rh1 C11 38.6(7) . . ? C12 Rh1 C11 107.1(7) . . ? C11 Rh1 C11 77.8(7) . . ? C12 Rh1 C13 42.1(9) . . ? C12 Rh1 C13 133.3(10) . . ? C11 Rh1 C13 136.5(8) . . ? C11 Rh1 C13 65.5(8) . . ? C12 Rh1 C13 120.3(7) . . ? C12 Rh1 C13 37.8(6) . . ? C11 Rh1 C13 63.3(4) . . ? C11 Rh1 C13 93.7(6) . . ? C13 Rh1 C13 95.5(9) . . ? C12 Rh1 C161 40.9(7) . . ? C12 Rh1 C161 153.0(6) . . ? C11 Rh1 C161 153.7(6) . . ? C11 Rh1 C161 76.0(7) . . ? C13 Rh1 C161 23.0(7) . . ? C13 Rh1 C161 116.2(5) . . ? C12 Rh1 C14 64.1(8) . . ? C12 Rh1 C14 97.9(9) . . ? C11 Rh1 C14 105.7(8) . . ? C11 Rh1 C14 61.7(6) . . ? C13 Rh1 C14 36.4(9) . . ? C13 Rh1 C14 60.8(7) . . ? C161 Rh1 C14 59.2(7) . . ? C12 Rh1 C15 84.0(7) . . ? C12 Rh1 C15 62.0(6) . . ? C11 Rh1 C15 36.5(5) . . ? C11 Rh1 C15 45.4(7) . . ? C13 Rh1 C15 100.3(9) . . ? C13 Rh1 C15 61.2(4) . . ? C161 Rh1 C15 118.1(6) . . ? C14 Rh1 C15 74.4(7) . . ? C12 Rh1 C162 18.6(6) . . ? C12 Rh1 C162 161.8(6) . . ? C11 Rh1 C162 125.0(5) . . ? C11 Rh1 C162 55.2(6) . . ? C13 Rh1 C162 47.7(8) . . ? C13 Rh1 C162 137.4(5) . . ? C161 Rh1 C162 35.9(5) . . ? C14 Rh1 C162 77.8(7) . . ? C15 Rh1 C162 100.0(6) . . ? C12 Rh1 C15 65.4(10) . . ? C12 Rh1 C15 82.3(9) . . ? C11 Rh1 C15 72.3(8) . . ? C11 Rh1 C15 37.8(7) . . ? C13 Rh1 C15 64.4(11) . . ? C13 Rh1 C15 57.4(7) . . ? C161 Rh1 C15 85.5(9) . . ? C14 Rh1 C15 37.3(8) . . ? C15 Rh1 C15 37.7(7) . . ? C162 Rh1 C15 84.0(9) . . ? C12 Rh1 C161 143.3(8) . . ? C12 Rh1 C161 23.7(6) . . ? C11 Rh1 C161 29.7(6) . . ? C11 Rh1 C161 107.5(8) . . ? C13 Rh1 C161 155.9(11) . . ? C13 Rh1 C161 61.1(8) . . ? C161 Rh1 C161 175.5(7) . . ? C14 Rh1 C161 119.6(10) . . ? C15 Rh1 C161 64.4(8) . . ? C162 Rh1 C161 148.6(7) . . ? C15 Rh1 C161 95.5(11) . . ? C15 C11 C12 107.2(12) . . ? C15 C11 Rh1 77.0(6) . . ? C12 C11 Rh1 67.7(8) . . ? C15 C11 H11 126.4 . . ? C12 C11 H11 126.4 . . ? Rh1 C11 H11 120.7 . . ? C13 C12 C11 109.4(13) . . ? C13 C12 Rh1 75.3(8) . . ? C11 C12 Rh1 73.6(7) . . ? C13 C12 H12 125.3 . . ? C11 C12 H12 125.3 . . ? Rh1 C12 H12 117.7 . . ? C14 C13 C12 107.5(13) . . ? C14 C13 Rh1 77.1(7) . . ? C12 C13 Rh1 66.9(7) . . ? C14 C13 H13 126.3 . . ? C12 C13 H13 126.3 . . ? Rh1 C13 H13 121.3 . . ? C13 C14 C15 108.5(14) . . ? C13 C14 Rh1 67.0(7) . . ? C15 C14 Rh1 71.2(7) . . ? C13 C14 H14 125.8 . . ? C15 C14 H14 125.8 . . ? Rh1 C14 H14 127.7 . . ? C11 C15 C14 107.5(12) . . ? C11 C15 Rh1 66.5(6) . . ? C14 C15 Rh1 73.0(7) . . ? C11 C15 H15 126.3 . . ? C14 C15 H15 126.3 . . ? Rh1 C15 H15 125.7 . . ? C162 C161 Rh1 74.1(7) . . ? C161 C162 Rh1 70.1(7) . . ? C12 C11 C15 112.0(18) . . ? C12 C11 Rh1 66.7(10) . . ? C15 C11 Rh1 76.1(9) . . ? C12 C11 H11A 124.0 . . ? C15 C11 H11A 124.0 . . ? Rh1 C11 H11A 124.6 . . ? C11 C12 C13 106.8(19) . . ? C11 C12 Rh1 74.6(10) . . ? C13 C12 Rh1 73.2(11) . . ? C11 C12 H12A 126.6 . . ? C13 C12 H12A 126.6 . . ? Rh1 C12 H12A 117.7 . . ? C14 C13 C12 104(2) . . ? C14 C13 Rh1 75.4(12) . . ? C12 C13 Rh1 64.8(10) . . ? C14 C13 H13A 127.8 . . ? C12 C13 H13A 127.9 . . ? Rh1 C13 H13A 123.5 . . ? C13 C14 C15 113.8(17) . . ? C13 C14 Rh1 68.2(10) . . ? C15 C14 Rh1 72.3(9) . . ? C13 C14 H14A 123.1 . . ? C15 C14 H14A 123.1 . . ? Rh1 C14 H14A 128.2 . . ? C11 C15 C14 102.9(19) . . ? C11 C15 Rh1 66.1(8) . . ? C14 C15 Rh1 70.4(9) . . ? C11 C15 H15A 128.5 . . ? C14 C15 H15A 128.5 . . ? Rh1 C15 H15A 126.4 . . ? C162 C161 Rh1 74.4(11) . . ? C161 C162 Rh1 70.4(11) . . ? C21 Ga1 Rh1 130.72(16) . 5_566 ? C21 Ga1 Rh1 119.98(16) . . ? Rh1 Ga1 Rh1 109.28(2) 5_566 . ? C21 Ga1 Ga1 173.96(16) . 5_566 ? Rh1 Ga1 Ga1 55.18(2) 5_566 5_566 ? Rh1 Ga1 Ga1 54.10(2) . 5_566 ? C22 C21 C25 103.6(5) . . ? C22 C21 C211 119.4(7) . . ? C25 C21 C211 120.9(8) . . ? C22 C21 Ga1 101.6(4) . . ? C25 C21 Ga1 96.2(4) . . ? C211 C21 Ga1 111.2(4) . . ? C23 C22 C21 109.8(6) . . ? C23 C22 C221 125.1(7) . . ? C21 C22 C221 125.2(7) . . ? C22 C23 C24 108.2(5) . . ? C22 C23 C231 127.2(7) . . ? C24 C23 C231 124.6(7) . . ? C25 C24 C23 108.5(6) . . ? C25 C24 C241 126.8(8) . . ? C23 C24 C241 124.7(7) . . ? C24 C25 C21 109.7(6) . . ? C24 C25 C251 126.7(9) . . ? C21 C25 C251 123.4(8) . . ? C21 C211 H21A 109.5 . . ? C21 C211 H21B 109.5 . . ? H21A C211 H21B 109.5 . . ? C21 C211 H21C 109.5 . . ? H21A C211 H21C 109.5 . . ? H21B C211 H21C 109.5 . . ? C22 C221 H22A 109.5 . . ? C22 C221 H22B 109.5 . . ? H22A C221 H22B 109.5 . . ? C22 C221 H22C 109.5 . . ? H22A C221 H22C 109.5 . . ? H22B C221 H22C 109.5 . . ? C23 C231 H23A 109.5 . . ? C23 C231 H23B 109.5 . . ? H23A C231 H23B 109.5 . . ? C23 C231 H23C 109.5 . . ? H23A C231 H23C 109.5 . . ? H23B C231 H23C 109.5 . . ? C24 C241 H24A 109.5 . . ? C24 C241 H24B 109.5 . . ? H24A C241 H24B 109.5 . . ? C24 C241 H24C 109.5 . . ? H24A C241 H24C 109.5 . . ? H24B C241 H24C 109.5 . . ? C25 C251 H25A 109.5 . . ? C25 C251 H25B 109.5 . . ? H25A C251 H25B 109.5 . . ? C25 C251 H25C 109.5 . . ? H25A C251 H25C 109.5 . . ? H25B C251 H25C 109.5 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C12 Rh1 C11 C15 -36.2(10) . . . . ? C12 Rh1 C11 C15 115.0(11) . . . . ? C11 Rh1 C11 C15 -23.6(8) . . . . ? C13 Rh1 C11 C15 8.9(14) . . . . ? C13 Rh1 C11 C15 76.9(8) . . . . ? C161 Rh1 C11 C15 -18.8(14) . . . . ? C14 Rh1 C11 C15 32.0(9) . . . . ? C162 Rh1 C11 C15 -53.9(9) . . . . ? C15 Rh1 C11 C15 15.1(9) . . . . ? C161 Rh1 C11 C15 154.9(18) . . . . ? C12 Rh1 C11 C12 -151.2(11) . . . . ? C11 Rh1 C11 C12 -138.6(10) . . . . ? C13 Rh1 C11 C12 -106.2(15) . . . . ? C13 Rh1 C11 C12 -38.1(9) . . . . ? C161 Rh1 C11 C12 -133.8(12) . . . . ? C14 Rh1 C11 C12 -83.0(11) . . . . ? C15 Rh1 C11 C12 -115.0(11) . . . . ? C162 Rh1 C11 C12 -169.0(9) . . . . ? C15 Rh1 C11 C12 -99.9(11) . . . . ? C161 Rh1 C11 C12 39.8(15) . . . . ? C15 C11 C12 C13 -0.1(14) . . . . ? Rh1 C11 C12 C13 67.4(10) . . . . ? C15 C11 C12 Rh1 -67.5(8) . . . . ? C12 Rh1 C12 C13 -65.5(18) . . . . ? C11 Rh1 C12 C13 -115.8(12) . . . . ? C11 Rh1 C12 C13 -73.3(10) . . . . ? C13 Rh1 C12 C13 -1.1(15) . . . . ? C161 Rh1 C12 C13 19.3(18) . . . . ? C14 Rh1 C12 C13 -10.6(10) . . . . ? C15 Rh1 C12 C13 -78.2(9) . . . . ? C162 Rh1 C12 C13 -86(2) . . . . ? C15 Rh1 C12 C13 -44.5(10) . . . . ? C161 Rh1 C12 C13 -168(3) . . . . ? C12 Rh1 C12 C11 50.3(18) . . . . ? C11 Rh1 C12 C11 42.5(11) . . . . ? C13 Rh1 C12 C11 114.8(13) . . . . ? C13 Rh1 C12 C11 115.8(12) . . . . ? C161 Rh1 C12 C11 135.2(13) . . . . ? C14 Rh1 C12 C11 105.3(10) . . . . ? C15 Rh1 C12 C11 37.7(8) . . . . ? C162 Rh1 C12 C11 30(3) . . . . ? C15 Rh1 C12 C11 71.3(10) . . . . ? C161 Rh1 C12 C11 -52(2) . . . . ? C11 C12 C13 C14 0.8(14) . . . . ? Rh1 C12 C13 C14 67.2(9) . . . . ? C11 C12 C13 Rh1 -66.3(9) . . . . ? C12 Rh1 C13 C14 27.5(12) . . . . ? C12 Rh1 C13 C14 -115.6(13) . . . . ? C11 Rh1 C13 C14 -76.5(10) . . . . ? C11 Rh1 C13 C14 -2.1(10) . . . . ? C13 Rh1 C13 C14 63.6(11) . . . . ? C161 Rh1 C13 C14 74.0(10) . . . . ? C14 Rh1 C13 C14 52.4(10) . . . . ? C15 Rh1 C13 C14 -35.1(10) . . . . ? C162 Rh1 C13 C14 37.1(12) . . . . ? C15 Rh1 C13 C14 8.9(13) . . . . ? C161 Rh1 C13 C14 -110.1(11) . . . . ? C12 Rh1 C13 C12 143.1(11) . . . . ? C11 Rh1 C13 C12 39.1(9) . . . . ? C11 Rh1 C13 C12 113.5(10) . . . . ? C13 Rh1 C13 C12 179.2(11) . . . . ? C161 Rh1 C13 C12 -170.4(10) . . . . ? C14 Rh1 C13 C12 168.0(12) . . . . ? C15 Rh1 C13 C12 80.5(10) . . . . ? C162 Rh1 C13 C12 152.7(10) . . . . ? C15 Rh1 C13 C12 124.5(13) . . . . ? C161 Rh1 C13 C12 5.5(12) . . . . ? C12 C13 C14 C15 -1.2(14) . . . . ? Rh1 C13 C14 C15 59.2(9) . . . . ? C12 C13 C14 Rh1 -60.4(8) . . . . ? C12 Rh1 C14 C13 -156.5(10) . . . . ? C12 Rh1 C14 C13 39.2(9) . . . . ? C11 Rh1 C14 C13 83.7(9) . . . . ? C11 Rh1 C14 C13 177.5(12) . . . . ? C13 Rh1 C14 C13 -114.9(11) . . . . ? C161 Rh1 C14 C13 -118.0(9) . . . . ? C14 Rh1 C14 C13 -101.8(13) . . . . ? C15 Rh1 C14 C13 120.6(13) . . . . ? C162 Rh1 C14 C13 -154.9(8) . . . . ? C15 Rh1 C14 C13 -160(3) . . . . ? C161 Rh1 C14 C13 57.4(10) . . . . ? C12 Rh1 C14 C15 82.9(11) . . . . ? C12 Rh1 C14 C15 -81.4(11) . . . . ? C11 Rh1 C14 C15 -36.8(9) . . . . ? C11 Rh1 C14 C15 56.9(10) . . . . ? C13 Rh1 C14 C15 124.5(12) . . . . ? C13 Rh1 C14 C15 -120.6(13) . . . . ? C161 Rh1 C14 C15 121.4(10) . . . . ? C14 Rh1 C14 C15 137.6(14) . . . . ? C162 Rh1 C14 C15 84.6(10) . . . . ? C15 Rh1 C14 C15 79(2) . . . . ? C161 Rh1 C14 C15 -63.2(10) . . . . ? C12 C11 C15 C14 -0.6(13) . . . . ? Rh1 C11 C15 C14 -61.9(8) . . . . ? C12 C11 C15 Rh1 61.3(8) . . . . ? C13 C14 C15 C11 1.2(13) . . . . ? Rh1 C14 C15 C11 57.8(7) . . . . ? C13 C14 C15 Rh1 -56.7(9) . . . . ? C12 Rh1 C15 C11 147.3(9) . . . . ? C12 Rh1 C15 C11 -39.9(8) . . . . ? C11 Rh1 C15 C11 146.6(11) . . . . ? C13 Rh1 C15 C11 -173.8(10) . . . . ? C13 Rh1 C15 C11 -83.1(8) . . . . ? C161 Rh1 C15 C11 170.7(7) . . . . ? C14 Rh1 C15 C11 -148.0(9) . . . . ? C162 Rh1 C15 C11 137.7(8) . . . . ? C15 Rh1 C15 C11 -156.0(14) . . . . ? C161 Rh1 C15 C11 -13.5(9) . . . . ? C12 Rh1 C15 C14 -94.4(11) . . . . ? C12 Rh1 C15 C14 78.4(10) . . . . ? C11 Rh1 C15 C14 118.3(11) . . . . ? C11 Rh1 C15 C14 -95.0(12) . . . . ? C13 Rh1 C15 C14 -55.5(12) . . . . ? C13 Rh1 C15 C14 35.2(8) . . . . ? C161 Rh1 C15 C14 -71.0(10) . . . . ? C14 Rh1 C15 C14 -29.7(10) . . . . ? C162 Rh1 C15 C14 -103.9(10) . . . . ? C15 Rh1 C15 C14 -37.6(10) . . . . ? C161 Rh1 C15 C14 104.9(12) . . . . ? C12 Rh1 C161 C162 -29.1(10) . . . . ? C12 Rh1 C161 C162 -149.1(13) . . . . ? C11 Rh1 C161 C162 -53.7(14) . . . . ? C11 Rh1 C161 C162 -48.8(9) . . . . ? C13 Rh1 C161 C162 -109(2) . . . . ? C13 Rh1 C161 C162 -136.0(9) . . . . ? C14 Rh1 C161 C162 -114.0(11) . . . . ? C15 Rh1 C161 C162 -66.3(10) . . . . ? C15 Rh1 C161 C162 -85.9(10) . . . . ? C161 Rh1 C161 C162 171(10) . . . . ? C12 Rh1 C162 C161 94(3) . . . . ? C12 Rh1 C162 C161 132(2) . . . . ? C11 Rh1 C162 C161 154.2(8) . . . . ? C11 Rh1 C162 C161 117.2(10) . . . . ? C13 Rh1 C162 C161 30.0(10) . . . . ? C13 Rh1 C162 C161 67.0(11) . . . . ? C14 Rh1 C162 C161 53.4(9) . . . . ? C15 Rh1 C162 C161 124.9(9) . . . . ? C15 Rh1 C162 C161 90.6(10) . . . . ? C161 Rh1 C162 C161 -178.6(14) . . . . ? C12 Rh1 C11 C12 172.9(12) . . . . ? C11 Rh1 C11 C12 -161.4(11) . . . . ? C13 Rh1 C11 C12 42.5(14) . . . . ? C13 Rh1 C11 C12 136.9(11) . . . . ? C161 Rh1 C11 C12 20.8(11) . . . . ? C14 Rh1 C11 C12 83.1(14) . . . . ? C15 Rh1 C11 C12 179.0(14) . . . . ? C162 Rh1 C11 C12 -11.7(12) . . . . ? C15 Rh1 C11 C12 121.8(18) . . . . ? C161 Rh1 C11 C12 -162.2(12) . . . . ? C12 Rh1 C11 C15 -121.8(18) . . . . ? C12 Rh1 C11 C15 51.2(15) . . . . ? C11 Rh1 C11 C15 76.8(13) . . . . ? C13 Rh1 C11 C15 -79.3(16) . . . . ? C13 Rh1 C11 C15 15.2(14) . . . . ? C161 Rh1 C11 C15 -101.0(14) . . . . ? C14 Rh1 C11 C15 -38.7(14) . . . . ? C15 Rh1 C11 C15 57.3(13) . . . . ? C162 Rh1 C11 C15 -133.5(15) . . . . ? C161 Rh1 C11 C15 76.0(15) . . . . ? C15 C11 C12 C13 -4(2) . . . . ? Rh1 C11 C12 C13 -66.6(12) . . . . ? C15 C11 C12 Rh1 62.9(14) . . . . ? C12 Rh1 C12 C11 -12(2) . . . . ? C11 Rh1 C12 C11 20.0(12) . . . . ? C13 Rh1 C12 C11 -113.4(17) . . . . ? C13 Rh1 C12 C11 -52.2(12) . . . . ? C161 Rh1 C12 C11 -148.3(16) . . . . ? C14 Rh1 C12 C11 -76.3(12) . . . . ? C15 Rh1 C12 C11 -0.7(10) . . . . ? C162 Rh1 C12 C11 149(3) . . . . ? C15 Rh1 C12 C11 -34.9(11) . . . . ? C161 Rh1 C12 C11 29(2) . . . . ? C12 Rh1 C12 C13 101.5(19) . . . . ? C11 Rh1 C12 C13 133.4(14) . . . . ? C11 Rh1 C12 C13 113.4(17) . . . . ? C13 Rh1 C12 C13 61.2(15) . . . . ? C161 Rh1 C12 C13 -34.9(12) . . . . ? C14 Rh1 C12 C13 37.1(13) . . . . ? C15 Rh1 C12 C13 112.7(15) . . . . ? C162 Rh1 C12 C13 -98(3) . . . . ? C15 Rh1 C12 C13 78.4(15) . . . . ? C161 Rh1 C12 C13 142.5(18) . . . . ? C11 C12 C13 C14 1.7(19) . . . . ? Rh1 C12 C13 C14 -66.0(12) . . . . ? C11 C12 C13 Rh1 67.6(12) . . . . ? C12 Rh1 C13 C14 113.9(17) . . . . ? C12 Rh1 C13 C14 -16.0(17) . . . . ? C11 Rh1 C13 C14 39.7(17) . . . . ? C11 Rh1 C13 C14 74.9(12) . . . . ? C13 Rh1 C13 C14 -16.6(11) . . . . ? C161 Rh1 C13 C14 -172(3) . . . . ? C15 Rh1 C13 C14 45.0(12) . . . . ? C162 Rh1 C13 C14 139.2(15) . . . . ? C15 Rh1 C13 C14 33.0(12) . . . . ? C161 Rh1 C13 C14 -3(3) . . . . ? C12 Rh1 C13 C12 -129.9(13) . . . . ? C11 Rh1 C13 C12 -74.2(18) . . . . ? C11 Rh1 C13 C12 -39.0(11) . . . . ? C13 Rh1 C13 C12 -130.5(13) . . . . ? C161 Rh1 C13 C12 74(2) . . . . ? C14 Rh1 C13 C12 -113.9(17) . . . . ? C15 Rh1 C13 C12 -68.9(14) . . . . ? C162 Rh1 C13 C12 25.3(9) . . . . ? C15 Rh1 C13 C12 -80.8(14) . . . . ? C161 Rh1 C13 C12 -117(2) . . . . ? C12 C13 C14 C15 1(2) . . . . ? Rh1 C13 C14 C15 -57.7(15) . . . . ? C12 C13 C14 Rh1 58.6(11) . . . . ? C12 Rh1 C14 C13 -42.9(13) . . . . ? C12 Rh1 C14 C13 168.3(12) . . . . ? C11 Rh1 C14 C13 -152.9(12) . . . . ? C11 Rh1 C14 C13 -86.5(13) . . . . ? C13 Rh1 C14 C13 160.9(13) . . . . ? C161 Rh1 C14 C13 3.6(13) . . . . ? C15 Rh1 C14 C13 -133.7(12) . . . . ? C162 Rh1 C14 C13 -29.6(12) . . . . ? C15 Rh1 C14 C13 -125.7(19) . . . . ? C161 Rh1 C14 C13 178.6(12) . . . . ? C12 Rh1 C14 C15 82.8(15) . . . . ? C12 Rh1 C14 C15 -66.0(15) . . . . ? C11 Rh1 C14 C15 -27.2(15) . . . . ? C11 Rh1 C14 C15 39.2(14) . . . . ? C13 Rh1 C14 C15 125.7(19) . . . . ? C13 Rh1 C14 C15 -73.4(14) . . . . ? C161 Rh1 C14 C15 129.3(16) . . . . ? C15 Rh1 C14 C15 -8.1(14) . . . . ? C162 Rh1 C14 C15 96.1(15) . . . . ? C161 Rh1 C14 C15 -55.7(16) . . . . ? C12 C11 C15 C14 4(2) . . . . ? Rh1 C11 C15 C14 61.5(12) . . . . ? C12 C11 C15 Rh1 -57.4(12) . . . . ? C13 C14 C15 C11 -3(2) . . . . ? Rh1 C14 C15 C11 -58.5(11) . . . . ? C13 C14 C15 Rh1 55.5(14) . . . . ? C12 Rh1 C15 C11 35.7(13) . . . . ? C12 Rh1 C15 C11 -131.3(14) . . . . ? C11 Rh1 C15 C11 -92.8(12) . . . . ? C13 Rh1 C15 C11 82.4(15) . . . . ? C13 Rh1 C15 C11 -161.9(16) . . . . ? C161 Rh1 C15 C11 72.8(13) . . . . ? C14 Rh1 C15 C11 115(2) . . . . ? C15 Rh1 C15 C11 -78.1(14) . . . . ? C162 Rh1 C15 C11 36.8(12) . . . . ? C161 Rh1 C15 C11 -111.6(14) . . . . ? C12 Rh1 C15 C14 -78.9(15) . . . . ? C12 Rh1 C15 C14 114.1(15) . . . . ? C11 Rh1 C15 C14 152.5(15) . . . . ? C11 Rh1 C15 C14 -115(2) . . . . ? C13 Rh1 C15 C14 -32.3(12) . . . . ? C13 Rh1 C15 C14 83.4(14) . . . . ? C161 Rh1 C15 C14 -41.8(14) . . . . ? C15 Rh1 C15 C14 167(2) . . . . ? C162 Rh1 C15 C14 -77.8(14) . . . . ? C161 Rh1 C15 C14 133.8(15) . . . . ? C12 Rh1 C161 C162 -151.2(13) . . . . ? C12 Rh1 C161 C162 -39.8(19) . . . . ? C11 Rh1 C161 C162 -134(3) . . . . ? C11 Rh1 C161 C162 -132.7(14) . . . . ? C13 Rh1 C161 C162 -64(2) . . . . ? C13 Rh1 C161 C162 -48.2(14) . . . . ? C161 Rh1 C161 C162 7(11) . . . . ? C14 Rh1 C161 C162 -65.8(16) . . . . ? C15 Rh1 C161 C162 -118.0(17) . . . . ? C162 Rh1 C161 C162 176.5(12) . . . . ? C15 Rh1 C161 C162 -96.0(15) . . . . ? C12 Rh1 C162 C161 96(3) . . . . ? C12 Rh1 C162 C161 43(2) . . . . ? C11 Rh1 C162 C161 24.4(15) . . . . ? C11 Rh1 C162 C161 63.1(17) . . . . ? C13 Rh1 C162 C161 151.5(16) . . . . ? C13 Rh1 C162 C161 106.9(18) . . . . ? C161 Rh1 C162 C161 -179.2(13) . . . . ? C14 Rh1 C162 C161 125.9(16) . . . . ? C15 Rh1 C162 C161 53.3(16) . . . . ? C162 Rh1 C162 C161 -154(9) . . . . ? C15 Rh1 C162 C161 88.3(16) . . . . ? C12 Rh1 Ga1 C21 91.9(7) . . . . ? C12 Rh1 Ga1 C21 -77.9(6) . . . . ? C11 Rh1 Ga1 C21 -104.5(4) . . . . ? C11 Rh1 Ga1 C21 83.5(9) . . . . ? C13 Rh1 Ga1 C21 56.2(9) . . . . ? C13 Rh1 Ga1 C21 -39.6(4) . . . . ? C161 Rh1 Ga1 C21 75.0(4) . . . . ? C14 Rh1 Ga1 C21 23.1(7) . . . . ? C15 Rh1 Ga1 C21 -68.1(13) . . . . ? C162 Rh1 Ga1 C21 103.3(5) . . . . ? C15 Rh1 Ga1 C21 10.3(12) . . . . ? C161 Rh1 Ga1 C21 -101.9(8) . . . . ? C12 Rh1 Ga1 Rh1 -86.7(7) . . . 5_566 ? C12 Rh1 Ga1 Rh1 103.6(5) . . . 5_566 ? C11 Rh1 Ga1 Rh1 77.0(4) . . . 5_566 ? C11 Rh1 Ga1 Rh1 -95.0(9) . . . 5_566 ? C13 Rh1 Ga1 Rh1 -122.4(8) . . . 5_566 ? C13 Rh1 Ga1 Rh1 141.8(3) . . . 5_566 ? C161 Rh1 Ga1 Rh1 -103.5(3) . . . 5_566 ? C14 Rh1 Ga1 Rh1 -155.5(7) . . . 5_566 ? C15 Rh1 Ga1 Rh1 113.3(13) . . . 5_566 ? C162 Rh1 Ga1 Rh1 -75.3(4) . . . 5_566 ? C15 Rh1 Ga1 Rh1 -168.2(12) . . . 5_566 ? C161 Rh1 Ga1 Rh1 79.6(7) . . . 5_566 ? C12 Rh1 Ga1 Ga1 -86.7(7) . . . 5_566 ? C12 Rh1 Ga1 Ga1 103.6(5) . . . 5_566 ? C11 Rh1 Ga1 Ga1 77.0(4) . . . 5_566 ? C11 Rh1 Ga1 Ga1 -95.0(9) . . . 5_566 ? C13 Rh1 Ga1 Ga1 -122.4(8) . . . 5_566 ? C13 Rh1 Ga1 Ga1 141.8(3) . . . 5_566 ? C161 Rh1 Ga1 Ga1 -103.5(3) . . . 5_566 ? C14 Rh1 Ga1 Ga1 -155.5(7) . . . 5_566 ? C15 Rh1 Ga1 Ga1 113.3(13) . . . 5_566 ? C162 Rh1 Ga1 Ga1 -75.3(4) . . . 5_566 ? C15 Rh1 Ga1 Ga1 -168.2(12) . . . 5_566 ? C161 Rh1 Ga1 Ga1 79.6(7) . . . 5_566 ? Rh1 Ga1 C21 C22 41.2(6) 5_566 . . . ? Rh1 Ga1 C21 C22 -136.9(3) . . . . ? Ga1 Ga1 C21 C22 -125.7(19) 5_566 . . . ? Rh1 Ga1 C21 C25 -64.1(5) 5_566 . . . ? Rh1 Ga1 C21 C25 117.8(3) . . . . ? Ga1 Ga1 C21 C25 129(2) 5_566 . . . ? Rh1 Ga1 C21 C211 169.3(6) 5_566 . . . ? Rh1 Ga1 C21 C211 -8.8(8) . . . . ? Ga1 Ga1 C21 C211 2(3) 5_566 . . . ? C25 C21 C22 C23 4.5(6) . . . . ? C211 C21 C22 C23 142.5(7) . . . . ? Ga1 C21 C22 C23 -94.9(5) . . . . ? C25 C21 C22 C221 -174.4(6) . . . . ? C211 C21 C22 C221 -36.4(10) . . . . ? Ga1 C21 C22 C221 86.2(7) . . . . ? C21 C22 C23 C24 -2.6(7) . . . . ? C221 C22 C23 C24 176.3(6) . . . . ? C21 C22 C23 C231 178.5(6) . . . . ? C221 C22 C23 C231 -2.6(10) . . . . ? C22 C23 C24 C25 -0.6(7) . . . . ? C231 C23 C24 C25 178.3(6) . . . . ? C22 C23 C24 C241 179.4(6) . . . . ? C231 C23 C24 C241 -1.6(10) . . . . ? C23 C24 C25 C21 3.6(7) . . . . ? C241 C24 C25 C21 -176.4(6) . . . . ? C23 C24 C25 C251 -172.2(6) . . . . ? C241 C24 C25 C251 7.8(11) . . . . ? C22 C21 C25 C24 -4.9(6) . . . . ? C211 C21 C25 C24 -142.1(6) . . . . ? Ga1 C21 C25 C24 98.6(5) . . . . ? C22 C21 C25 C251 171.0(6) . . . . ? C211 C21 C25 C251 33.9(9) . . . . ? Ga1 C21 C25 C251 -85.4(6) . . . . ? _diffrn_measured_fraction_theta_max 0.997 _diffrn_reflns_theta_full 25.05 _diffrn_measured_fraction_theta_full 0.997 _refine_diff_density_max 0.556 _refine_diff_density_min -1.434 _refine_diff_density_rms 0.139 #=================================================END #=================================================END