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Paper b503794h
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Crystal structure data
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Solid-state HETCOR NMR spectrum of [Pt(
1
)(C≡C–Ph)
2
] and [Pt(
1
)(C≡C–
p
-C
6
H
4
–C≡C–Fc)
2
] (Fig. S1). ORTEP diagram of the molecular structure of [Pt(
1
)Cl
2
]·2CHCl
3
in the crystal (Fig. S2). Absorption spectra at room temperature of [Pt(phen)](C≡C–Ph)
2
], [Pt(
1
)(C≡C–Ph)
2
], [Pt(
1
)(C≡C–Ph–C≡C–Fc)
2
] and [Pt(
1
)(C≡C–Fc)
2
] in different solvents (Fig. S3). Emission spectra upon shock-freezing of [Pt(
1
)(C≡C–Ph)
2
] in different solvents and in microcrystalline form (Fig. S4). Concentration dependence of normalised luminescence spectra of [Pt(
1
)(C≡C–Ph)
2
] at 77 K in frozen glassy solution (Fig. S5)
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