Supplementary Material (ESI) for Dalton Transactions This journal is © The Royal Society of Chemistry 2005 data_global _journal_coden_Cambridge 222 _publ_contact_author_name 'Dr. Cristina Tejel' _publ_contact_author_address ; Dr. Cristina Tejel Departamento de Quimica Inorganica Instituto de Ciencia de Materiales de Aragon C.S.I.C.-Universidad de Zaragoza 50009 Zaragoza, Spain ; _publ_contact_author_phone '+34 976 762285' _publ_contact_author_fax '+34 976 761187' _publ_contact_author_email ctejel@unizar.es loop_ _publ_author_name _publ_author_address 'Miguel A. Casado' ; Dep Quim. Inorg. Inst. Ciencia Mater. Aragon Inst. Univ. Cat. Hom. Univ. Zaragoza-CSIC 50009 Zaragoza Spain ; 'Miguel A. Ciriano' ; Dep Quim. Inorg. Inst. Ciencia Mater. Aragon Univ. Zaragoza-CSIC 50009 Zaragoza Spain ; 'Jose A. Camerano' ; Dep Quim. Inorg. Inst. Ciencia Mater. Aragon Univ. Zaragoza-CSIC 50009 Zaragoza Spain ; 'Cristina Tejel' ; Dep Quim. Inorg. Inst. Ciencia Mater. Aragon Univ. Zaragoza-CSIC 50009 Zaragoza Spain ; 'Luis A. Oro' ;Dep Quim. Inorg. Inst. Ciencia Mater. Aragon Inst. Univ. Cat. Hom. Univ. Zaragoza-CSIC 50009 Zaragoza Spain ; _publ_requested_journal 'Dalton Transactions' _publ_section_title ; Peripheral SH-Functionalisation of Carbosilane Dendrimers Including the Synthesis of the Model Compound Dimethylbis(propanethiol)silane and their Interaction with Rhodium Complexes ; # Data for compound1 (local labelling cta13ac) data_cta13ac _database_code_depnum_ccdc_archive 'CCDC 267204' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety '(C48 H84 Rh4 S4 Si2);2(C H2 Cl2)' _chemical_formula_sum 'C50 H88 Cl4 Rh4 S4 Si2' _chemical_formula_weight 1427.06 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M P21/c loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 19.6558(17) _cell_length_b 12.1246(11) _cell_length_c 24.755(2) _cell_angle_alpha 90.00 _cell_angle_beta 95.801(2) _cell_angle_gamma 90.00 _cell_volume 5869.4(9) _cell_formula_units_Z 4 _cell_measurement_temperature 100(2) _cell_measurement_reflns_used 2459 _cell_measurement_theta_min 2.18 _cell_measurement_theta_max 22.69 _exptl_crystal_description prism _exptl_crystal_colour yellow _exptl_crystal_size_max 0.247 _exptl_crystal_size_mid 0.052 _exptl_crystal_size_min 0.052 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.615 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2912 _exptl_absorpt_coefficient_mu 1.503 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.734 _exptl_absorpt_correction_T_max 0.878 _exptl_absorpt_process_details ; SADABS: Area-Detector Absorption Correction (1996) Bruker-AXS Nithin SAINT+ package, v. 6.01 ; _diffrn_ambient_temperature 100(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker SMART APEX CCD system' _diffrn_measurement_method '\W rotations with narrow frames' _diffrn_detector_area_resol_mean 8.26 _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% 'no decay' _diffrn_reflns_number 37039 _diffrn_reflns_av_R_equivalents 0.0805 _diffrn_reflns_av_sigmaI/netI 0.1554 _diffrn_reflns_limit_h_min -12 _diffrn_reflns_limit_h_max 25 _diffrn_reflns_limit_k_min -15 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_l_min -30 _diffrn_reflns_limit_l_max 31 _diffrn_reflns_theta_min 1.65 _diffrn_reflns_theta_max 27.05 _reflns_number_total 12795 _reflns_number_gt 7190 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'SMART v. 5.611 (Bruker AXS, 2000)' _computing_cell_refinement 'SAINT+ v. 6.01 (Bruker AXS, 2000)' _computing_data_reduction 'SAINT+ v. 6.01 (Bruker AXS, 2000)' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'XP program, SHELXTL v. 6.10, Bruker 2000' _computing_publication_material 'XCIF program, SHELXTL v. 6.10, Bruker 2000' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. All of the non-hydrogen atoms were refined with anisotropic displacement parameters. The hydrogen atoms were included in calculated positions and refined riding on carbon atoms. The hydrogen atoms linked to the olefinic cod ligands were found from difference Fourier maps and refined with coordinates riding on the carbon atoms. All electron residual peaks above 1 e/\%A^3^ were located close to the solvent and Rh atoms and have no chemical sense. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0130P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 12795 _refine_ls_number_parameters 629 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.1040 _refine_ls_R_factor_gt 0.0493 _refine_ls_wR_factor_ref 0.0851 _refine_ls_wR_factor_gt 0.0729 _refine_ls_goodness_of_fit_ref 0.772 _refine_ls_restrained_S_all 0.772 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Rh1 Rh 0.06018(3) 0.68051(4) 0.12337(2) 0.01392(12) Uani 1 1 d . . . Rh2 Rh 0.08382(3) 0.44222(4) 0.14001(2) 0.01515(12) Uani 1 1 d . . . S1 S -0.02006(8) 0.53905(14) 0.12679(6) 0.0170(4) Uani 1 1 d . . . S2 S 0.09234(8) 0.54893(14) 0.06223(6) 0.0149(4) Uani 1 1 d . . . Si1 Si -0.25711(10) 0.62373(15) 0.08587(8) 0.0193(4) Uani 1 1 d . . . C1 C 0.1150(4) 0.8196(6) 0.0976(3) 0.0198(16) Uani 1 1 d . . . H1 H 0.118(3) 0.807(5) 0.067(2) 0.030 Uiso 1 1 d . . . C2 C 0.1561(4) 0.7573(6) 0.1350(3) 0.0207(17) Uani 1 1 d . . . H2 H 0.183(3) 0.724(5) 0.123(3) 0.031 Uiso 1 1 d . . . C3 C 0.1732(3) 0.7853(6) 0.1943(3) 0.0247(17) Uani 1 1 d . . . H3A H 0.2079 0.8448 0.1975 0.037 Uiso 1 1 calc R . . H3B H 0.1935 0.7197 0.2135 0.037 Uiso 1 1 calc R . . C4 C 0.1113(3) 0.8223(6) 0.2215(3) 0.0279(18) Uani 1 1 d . . . H4A H 0.1192 0.8072 0.2610 0.042 Uiso 1 1 calc R . . H4B H 0.1051 0.9028 0.2166 0.042 Uiso 1 1 calc R . . C5 C 0.0472(4) 0.7630(6) 0.1979(3) 0.0197(16) Uani 1 1 d . . . H5 H 0.029(3) 0.720(5) 0.219(2) 0.030 Uiso 1 1 d . . . C6 C 0.0015(4) 0.8077(6) 0.1571(3) 0.0244(18) Uani 1 1 d . . . H6 H -0.041(3) 0.784(5) 0.144(3) 0.037 Uiso 1 1 d . . . C7 C 0.0117(4) 0.9157(5) 0.1275(3) 0.0253(18) Uani 1 1 d . . . H7A H 0.0026 0.9780 0.1516 0.038 Uiso 1 1 calc R . . H7B H -0.0219 0.9199 0.0950 0.038 Uiso 1 1 calc R . . C8 C 0.0837(4) 0.9281(6) 0.1100(3) 0.0282(18) Uani 1 1 d . . . H8A H 0.0816 0.9756 0.0773 0.042 Uiso 1 1 calc R . . H8B H 0.1132 0.9653 0.1393 0.042 Uiso 1 1 calc R . . C9 C 0.0778(4) 0.3888(6) 0.2224(3) 0.0215(17) Uani 1 1 d . . . H9 H 0.055(3) 0.444(5) 0.236(2) 0.032 Uiso 1 1 d . . . C10 C 0.0483(4) 0.3116(7) 0.1864(3) 0.0257(18) Uani 1 1 d . . . H10 H 0.008(3) 0.311(6) 0.178(3) 0.039 Uiso 1 1 d . . . C11 C 0.0809(4) 0.2040(5) 0.1722(3) 0.0242(17) Uani 1 1 d . . . H11A H 0.0531 0.1701 0.1410 0.036 Uiso 1 1 calc R . . H11B H 0.0809 0.1529 0.2034 0.036 Uiso 1 1 calc R . . C12 C 0.1541(4) 0.2181(5) 0.1580(3) 0.0277(18) Uani 1 1 d . . . H12A H 0.1860 0.2082 0.1912 0.042 Uiso 1 1 calc R . . H12B H 0.1641 0.1600 0.1318 0.042 Uiso 1 1 calc R . . C13 C 0.1662(3) 0.3301(6) 0.1336(3) 0.0183(16) Uani 1 1 d . . . H13 H 0.171(3) 0.329(5) 0.096(2) 0.027 Uiso 1 1 d . . . C14 C 0.1898(4) 0.4223(6) 0.1632(3) 0.0240(18) Uani 1 1 d . . . H14 H 0.210(3) 0.481(5) 0.143(2) 0.036 Uiso 1 1 d . . . C15 C 0.2036(3) 0.4272(5) 0.2239(2) 0.0246(17) Uani 1 1 d . . . H15A H 0.2079 0.5054 0.2353 0.037 Uiso 1 1 calc R . . H15B H 0.2478 0.3904 0.2350 0.037 Uiso 1 1 calc R . . C16 C 0.1482(4) 0.3730(6) 0.2528(3) 0.0281(18) Uani 1 1 d . . . H16A H 0.1486 0.4048 0.2897 0.042 Uiso 1 1 calc R . . H16B H 0.1580 0.2932 0.2567 0.042 Uiso 1 1 calc R . . C17 C -0.0722(3) 0.5430(6) 0.1829(2) 0.0212(16) Uani 1 1 d . . . H17A H -0.0601 0.4802 0.2076 0.032 Uiso 1 1 calc R . . H17B H -0.0633 0.6122 0.2036 0.032 Uiso 1 1 calc R . . C18 C -0.1481(3) 0.5365(5) 0.1616(3) 0.0233(17) Uani 1 1 d . . . H18A H -0.1753 0.5266 0.1929 0.035 Uiso 1 1 calc R . . H18B H -0.1554 0.4706 0.1382 0.035 Uiso 1 1 calc R . . C19 C -0.1751(3) 0.6392(5) 0.1291(3) 0.0199(16) Uani 1 1 d . . . H19A H -0.1398 0.6623 0.1056 0.030 Uiso 1 1 calc R . . H19B H -0.1803 0.6998 0.1551 0.030 Uiso 1 1 calc R . . C20 C -0.3279(3) 0.5907(5) 0.1281(3) 0.0224(17) Uani 1 1 d . . . H20A H -0.3160 0.5247 0.1499 0.034 Uiso 1 1 calc R . . H20B H -0.3701 0.5771 0.1044 0.034 Uiso 1 1 calc R . . H20C H -0.3348 0.6529 0.1522 0.034 Uiso 1 1 calc R . . C21 C -0.2745(4) 0.7566(5) 0.0487(3) 0.0297(19) Uani 1 1 d . . . H21A H -0.2780 0.8164 0.0749 0.045 Uiso 1 1 calc R . . H21B H -0.3174 0.7507 0.0251 0.045 Uiso 1 1 calc R . . H21C H -0.2370 0.7724 0.0266 0.045 Uiso 1 1 calc R . . C22 C 0.1749(3) 0.5648(5) 0.0361(2) 0.0176(15) Uani 1 1 d . . . H22A H 0.1788 0.6399 0.0210 0.026 Uiso 1 1 calc R . . H22B H 0.2119 0.5549 0.0659 0.026 Uiso 1 1 calc R . . C23 C 0.1820(3) 0.4795(5) -0.0080(2) 0.0206(16) Uani 1 1 d . . . H23A H 0.1424 0.4864 -0.0359 0.031 Uiso 1 1 calc R . . H23B H 0.1803 0.4050 0.0082 0.031 Uiso 1 1 calc R . . C24 C 0.2482(3) 0.4896(5) -0.0360(2) 0.0171(15) Uani 1 1 d . . . H24A H 0.2880 0.4881 -0.0081 0.026 Uiso 1 1 calc R . . H24B H 0.2484 0.5615 -0.0550 0.026 Uiso 1 1 calc R . . Rh3 Rh 0.40593(3) 1.05036(5) 0.12098(2) 0.01800(13) Uani 1 1 d . . . Rh4 Rh 0.41794(3) 0.81596(5) 0.10234(2) 0.01887(13) Uani 1 1 d . . . S3 S 0.35657(8) 0.94732(15) 0.04667(6) 0.0200(4) Uani 1 1 d . . . S4 S 0.49834(8) 0.95395(15) 0.09049(7) 0.0210(4) Uani 1 1 d . . . Si2 Si 0.24354(10) 0.85331(15) -0.12887(8) 0.0209(5) Uani 1 1 d . . . C25 C 0.3144(4) 1.0785(7) 0.1566(3) 0.0283(19) Uani 1 1 d . . . H25 H 0.281(3) 1.020(5) 0.143(3) 0.043 Uiso 1 1 d . . . C26 C 0.3264(4) 1.1671(7) 0.1244(3) 0.038(2) Uani 1 1 d . . . H26 H 0.306(4) 1.167(6) 0.091(3) 0.056 Uiso 1 1 d . . . C27 C 0.3547(5) 1.2766(7) 0.1462(5) 0.084(4) Uani 1 1 d . . . H27A H 0.3513 1.3301 0.1158 0.126 Uiso 1 1 calc R . . H27B H 0.3248 1.3038 0.1732 0.126 Uiso 1 1 calc R . . C28 C 0.4242(4) 1.2772(6) 0.1711(3) 0.046(2) Uani 1 1 d . . . H28A H 0.4238 1.2994 0.2096 0.070 Uiso 1 1 calc R . . H28B H 0.4499 1.3342 0.1530 0.070 Uiso 1 1 calc R . . C29 C 0.4624(4) 1.1697(7) 0.1695(3) 0.0280(19) Uani 1 1 d . . . H29 H 0.500(3) 1.175(6) 0.158(3) 0.042 Uiso 1 1 d . . . C30 C 0.4502(4) 1.0771(6) 0.2016(3) 0.0231(17) Uani 1 1 d . . . H30 H 0.489(3) 1.021(5) 0.207(2) 0.035 Uiso 1 1 d . . . C31 C 0.3969(4) 1.0742(8) 0.2416(3) 0.048(2) Uani 1 1 d . . . H31A H 0.4037 1.0060 0.2635 0.072 Uiso 1 1 calc R . . H31B H 0.4050 1.1374 0.2667 0.072 Uiso 1 1 calc R . . C32 C 0.3273(4) 1.0777(9) 0.2188(3) 0.062(3) Uani 1 1 d . . . H32A H 0.3060 1.1445 0.2327 0.093 Uiso 1 1 calc R . . H32B H 0.3034 1.0131 0.2324 0.093 Uiso 1 1 calc R . . C33 C 0.4679(4) 0.7530(6) 0.1754(3) 0.0240(17) Uani 1 1 d . . . H33 H 0.502(3) 0.809(5) 0.184(2) 0.036 Uiso 1 1 d . . . C34 C 0.4854(4) 0.6869(7) 0.1328(3) 0.0290(19) Uani 1 1 d . . . H34 H 0.518(3) 0.700(6) 0.114(3) 0.043 Uiso 1 1 d . . . C35 C 0.4550(4) 0.5717(6) 0.1202(3) 0.038(2) Uani 1 1 d . . . H35A H 0.4893 0.5258 0.1040 0.058 Uiso 1 1 calc R . . H35B H 0.4450 0.5362 0.1545 0.058 Uiso 1 1 calc R . . C36 C 0.3904(4) 0.5760(6) 0.0817(3) 0.042(2) Uani 1 1 d . . . H36A H 0.4025 0.5648 0.0443 0.062 Uiso 1 1 calc R . . H36B H 0.3605 0.5141 0.0903 0.062 Uiso 1 1 calc R . . C37 C 0.3509(4) 0.6810(6) 0.0834(3) 0.0263(17) Uani 1 1 d . . . H37 H 0.322(3) 0.703(5) 0.047(3) 0.040 Uiso 1 1 d . . . C38 C 0.3335(4) 0.7293(7) 0.1297(3) 0.028(2) Uani 1 1 d . . . H38 H 0.304(4) 0.776(6) 0.129(3) 0.042 Uiso 1 1 d . . . C39 C 0.3494(4) 0.6800(7) 0.1856(3) 0.041(2) Uani 1 1 d . . . H39A H 0.3525 0.5988 0.1823 0.062 Uiso 1 1 calc R . . H39B H 0.3115 0.6967 0.2078 0.062 Uiso 1 1 calc R . . C40 C 0.4162(4) 0.7239(7) 0.2145(3) 0.041(2) Uani 1 1 d . . . H40A H 0.4063 0.7903 0.2356 0.061 Uiso 1 1 calc R . . H40B H 0.4361 0.6675 0.2404 0.061 Uiso 1 1 calc R . . C41 C 0.2635(3) 0.9364(6) 0.0383(2) 0.0237(16) Uani 1 1 d . . . H41A H 0.2496 0.8670 0.0551 0.035 Uiso 1 1 calc R . . H41B H 0.2437 0.9986 0.0573 0.035 Uiso 1 1 calc R . . C42 C 0.2358(3) 0.9380(5) -0.0210(2) 0.0209(16) Uani 1 1 d . . . H42A H 0.2536 1.0043 -0.0382 0.031 Uiso 1 1 calc R . . H42B H 0.1853 0.9448 -0.0233 0.031 Uiso 1 1 calc R . . C43 C 0.2540(3) 0.8358(5) -0.0531(2) 0.0182(15) Uani 1 1 d . . . H43A H 0.2248 0.7737 -0.0434 0.027 Uiso 1 1 calc R . . H43B H 0.3021 0.8155 -0.0416 0.027 Uiso 1 1 calc R . . C44 C 0.1525(3) 0.8804(5) -0.1520(3) 0.0265(18) Uani 1 1 d . . . H44A H 0.1252 0.8154 -0.1450 0.040 Uiso 1 1 calc R . . H44B H 0.1477 0.8962 -0.1910 0.040 Uiso 1 1 calc R . . H44C H 0.1366 0.9438 -0.1323 0.040 Uiso 1 1 calc R . . C45 C 0.2720(4) 0.7249(5) -0.1620(3) 0.0280(18) Uani 1 1 d . . . H45A H 0.2471 0.6614 -0.1494 0.042 Uiso 1 1 calc R . . H45B H 0.3212 0.7144 -0.1524 0.042 Uiso 1 1 calc R . . H45C H 0.2627 0.7317 -0.2015 0.042 Uiso 1 1 calc R . . C46 C 0.5794(3) 0.9478(6) 0.1336(3) 0.0236(16) Uani 1 1 d . . . H46A H 0.5713 0.9620 0.1718 0.035 Uiso 1 1 calc R . . H46B H 0.5995 0.8733 0.1315 0.035 Uiso 1 1 calc R . . C47 C 0.6283(3) 1.0329(5) 0.1153(3) 0.0194(16) Uani 1 1 d . . . H47A H 0.6084 1.1071 0.1191 0.029 Uiso 1 1 calc R . . H47B H 0.6333 1.0210 0.0763 0.029 Uiso 1 1 calc R . . C48 C 0.3002(3) 0.9698(5) -0.1470(2) 0.0196(16) Uani 1 1 d . . . H48A H 0.3053 0.9663 -0.1864 0.029 Uiso 1 1 calc R . . H48B H 0.2779 1.0407 -0.1398 0.029 Uiso 1 1 calc R . . C70 C 0.0282(4) 0.2541(6) 0.0162(3) 0.042(2) Uani 1 1 d . . . H70A H 0.0105 0.2879 -0.0188 0.063 Uiso 1 1 calc R . . H70B H 0.0426 0.3145 0.0418 0.063 Uiso 1 1 calc R . . Cl1 Cl 0.09898(11) 0.17315(17) 0.00641(8) 0.0422(5) Uani 1 1 d . . . Cl2 Cl -0.03778(11) 0.1787(2) 0.04203(8) 0.0595(7) Uani 1 1 d . . . C71 C 0.4892(4) 0.7432(6) 0.9727(3) 0.038(2) Uani 1 1 d . . . H71A H 0.5085 0.8023 0.9513 0.057 Uiso 1 1 calc R . . H71B H 0.4675 0.7783 1.0028 0.057 Uiso 1 1 calc R . . Cl3 Cl 0.55426(12) 0.6562(2) 0.99921(9) 0.0634(7) Uani 1 1 d . . . Cl4 Cl 0.42693(11) 0.66906(17) 0.93085(8) 0.0464(6) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Rh1 0.0151(3) 0.0130(3) 0.0140(3) -0.0010(2) 0.0029(2) -0.0005(2) Rh2 0.0176(3) 0.0139(3) 0.0141(3) 0.0004(2) 0.0024(2) -0.0002(3) S1 0.0165(9) 0.0172(9) 0.0177(9) -0.0002(7) 0.0034(7) -0.0007(7) S2 0.0159(9) 0.0147(9) 0.0146(9) 0.0003(7) 0.0038(7) -0.0008(8) Si1 0.0189(11) 0.0184(11) 0.0215(11) -0.0021(8) 0.0061(9) 0.0019(9) C1 0.029(4) 0.018(4) 0.013(4) -0.001(3) 0.005(3) -0.015(3) C2 0.021(4) 0.019(4) 0.023(4) -0.012(3) 0.005(3) -0.003(3) C3 0.020(4) 0.028(4) 0.026(4) -0.009(3) 0.002(3) 0.001(3) C4 0.039(5) 0.031(4) 0.014(4) -0.010(3) 0.006(3) -0.002(4) C5 0.021(4) 0.021(4) 0.018(4) -0.002(3) 0.007(3) -0.001(3) C6 0.030(4) 0.020(4) 0.024(4) -0.017(3) 0.005(4) 0.004(4) C7 0.032(5) 0.009(4) 0.033(4) -0.007(3) -0.005(4) 0.005(3) C8 0.039(5) 0.016(4) 0.030(4) 0.002(3) 0.002(4) -0.003(4) C9 0.028(5) 0.020(4) 0.018(4) 0.003(3) 0.008(3) 0.005(3) C10 0.026(4) 0.025(4) 0.027(4) 0.005(3) 0.005(4) -0.003(4) C11 0.036(5) 0.023(4) 0.014(4) 0.008(3) 0.004(3) 0.000(4) C12 0.041(5) 0.022(4) 0.019(4) 0.002(3) -0.006(4) 0.007(4) C13 0.023(4) 0.018(4) 0.013(4) 0.002(3) -0.006(3) 0.007(3) C14 0.020(4) 0.023(4) 0.027(4) 0.005(3) -0.008(3) 0.001(3) C15 0.030(4) 0.020(4) 0.021(4) -0.003(3) -0.008(3) 0.005(4) C16 0.040(5) 0.029(4) 0.014(4) 0.002(3) -0.003(3) -0.003(4) C17 0.022(4) 0.026(4) 0.016(4) 0.004(3) 0.005(3) -0.004(3) C18 0.021(4) 0.025(4) 0.025(4) -0.004(3) 0.009(3) -0.005(3) C19 0.016(4) 0.020(4) 0.026(4) -0.003(3) 0.013(3) -0.004(3) C20 0.016(4) 0.024(4) 0.029(4) -0.002(3) 0.010(3) -0.001(3) C21 0.025(4) 0.026(4) 0.041(5) -0.003(4) 0.013(4) 0.005(4) C22 0.018(4) 0.015(4) 0.021(4) 0.000(3) 0.005(3) -0.006(3) C23 0.019(4) 0.021(4) 0.023(4) -0.008(3) 0.004(3) 0.000(3) C24 0.013(4) 0.025(4) 0.014(4) -0.002(3) 0.004(3) 0.000(3) Rh3 0.0168(3) 0.0195(3) 0.0174(3) -0.0006(2) 0.0001(2) -0.0015(3) Rh4 0.0140(3) 0.0197(3) 0.0225(3) -0.0018(3) -0.0002(2) -0.0010(3) S3 0.0158(9) 0.0257(10) 0.0181(9) -0.0011(8) -0.0012(7) -0.0032(8) S4 0.0158(10) 0.0238(10) 0.0229(10) -0.0010(8) -0.0006(8) -0.0030(8) Si2 0.0184(11) 0.0239(11) 0.0194(12) 0.0028(8) -0.0033(9) -0.0048(9) C25 0.021(4) 0.046(6) 0.018(4) -0.010(4) 0.001(3) 0.008(4) C26 0.026(5) 0.032(5) 0.052(6) 0.000(5) -0.008(4) 0.001(4) C27 0.052(7) 0.030(6) 0.164(12) -0.022(7) -0.019(7) 0.008(5) C28 0.056(6) 0.020(5) 0.063(6) -0.007(4) 0.002(5) 0.001(4) C29 0.022(4) 0.031(5) 0.029(5) -0.009(4) -0.002(4) -0.003(4) C30 0.019(4) 0.030(5) 0.019(4) -0.002(3) -0.002(3) 0.001(3) C31 0.032(5) 0.085(7) 0.027(5) 0.004(5) 0.003(4) -0.006(5) C32 0.035(6) 0.133(10) 0.017(5) -0.011(5) -0.006(4) 0.002(6) C33 0.016(4) 0.029(5) 0.026(4) 0.004(3) -0.005(3) -0.001(3) C34 0.020(4) 0.031(5) 0.036(5) 0.008(4) 0.003(4) -0.002(4) C35 0.031(5) 0.034(5) 0.048(5) 0.002(4) -0.007(4) 0.004(4) C36 0.043(6) 0.027(5) 0.054(6) -0.002(4) -0.002(4) -0.010(4) C37 0.019(4) 0.020(4) 0.040(5) 0.003(4) -0.002(3) -0.007(4) C38 0.021(5) 0.037(5) 0.028(5) 0.013(4) 0.007(4) 0.002(4) C39 0.020(4) 0.057(6) 0.048(5) 0.025(5) 0.009(4) -0.003(4) C40 0.036(5) 0.051(6) 0.034(5) 0.018(4) -0.003(4) -0.003(4) C41 0.018(4) 0.033(4) 0.019(4) 0.001(3) -0.002(3) 0.001(4) C42 0.024(4) 0.020(4) 0.020(4) 0.001(3) 0.004(3) -0.003(3) C43 0.019(4) 0.018(4) 0.019(4) 0.000(3) 0.004(3) -0.009(3) C44 0.026(4) 0.029(4) 0.024(4) 0.007(3) 0.002(3) -0.018(4) C45 0.034(5) 0.021(4) 0.028(4) 0.002(3) 0.000(4) -0.003(4) C46 0.008(4) 0.031(4) 0.031(4) 0.001(3) -0.005(3) 0.000(3) C47 0.012(4) 0.022(4) 0.024(4) 0.001(3) -0.001(3) 0.003(3) C48 0.022(4) 0.019(4) 0.018(4) 0.005(3) 0.002(3) -0.008(3) C70 0.038(5) 0.042(5) 0.044(5) 0.017(4) -0.007(4) -0.020(4) Cl1 0.0512(14) 0.0359(12) 0.0391(12) 0.0004(10) 0.0024(10) 0.0004(11) Cl2 0.0459(14) 0.0929(19) 0.0382(13) 0.0204(13) -0.0038(11) -0.0251(14) C71 0.042(5) 0.043(5) 0.027(5) -0.004(4) -0.002(4) 0.000(4) Cl3 0.0461(15) 0.086(2) 0.0552(16) -0.0103(14) -0.0086(12) 0.0167(14) Cl4 0.0448(14) 0.0370(13) 0.0546(14) -0.0034(11) -0.0082(11) 0.0039(11) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Rh1 C2 2.097(7) . ? Rh1 C1 2.133(7) . ? Rh1 C5 2.138(7) . ? Rh1 C6 2.145(7) . ? Rh1 S2 2.3300(16) . ? Rh1 S1 2.3373(17) . ? Rh2 C10 2.116(7) . ? Rh2 C14 2.119(7) . ? Rh2 C13 2.132(7) . ? Rh2 C9 2.154(7) . ? Rh2 S2 2.3398(16) . ? Rh2 S1 2.3495(17) . ? S1 C17 1.808(6) . ? S2 C22 1.817(6) . ? Si1 C19 1.851(6) . ? Si1 C20 1.867(6) . ? Si1 C24 1.868(6) 3_565 ? Si1 C21 1.869(7) . ? C1 C2 1.389(10) . ? C1 C8 1.497(9) . ? C1 H1 0.78(6) . ? C2 C3 1.510(9) . ? C2 H2 0.76(6) . ? C3 C4 1.517(8) . ? C3 H3A 0.9900 . ? C3 H3B 0.9900 . ? C4 C5 1.516(9) . ? C4 H4A 0.9900 . ? C4 H4B 0.9900 . ? C5 C6 1.393(9) . ? C5 H5 0.85(6) . ? C6 C7 1.524(9) . ? C6 H6 0.91(6) . ? C7 C8 1.527(9) . ? C7 H7A 0.9900 . ? C7 H7B 0.9900 . ? C8 H8A 0.9900 . ? C8 H8B 0.9900 . ? C9 C10 1.379(9) . ? C9 C16 1.519(9) . ? C9 H9 0.89(6) . ? C10 C11 1.511(10) . ? C10 H10 0.79(6) . ? C11 C12 1.524(9) . ? C11 H11A 0.9900 . ? C11 H11B 0.9900 . ? C12 C13 1.515(9) . ? C12 H12A 0.9900 . ? C12 H12B 0.9900 . ? C13 C14 1.391(9) . ? C13 H13 0.95(5) . ? C14 C15 1.500(8) . ? C14 H14 0.97(6) . ? C15 C16 1.513(9) . ? C15 H15A 0.9900 . ? C15 H15B 0.9900 . ? C16 H16A 0.9900 . ? C16 H16B 0.9900 . ? C17 C18 1.534(8) . ? C17 H17A 0.9900 . ? C17 H17B 0.9900 . ? C18 C19 1.548(8) . ? C18 H18A 0.9900 . ? C18 H18B 0.9900 . ? C19 H19A 0.9900 . ? C19 H19B 0.9900 . ? C20 H20A 0.9800 . ? C20 H20B 0.9800 . ? C20 H20C 0.9800 . ? C21 H21A 0.9800 . ? C21 H21B 0.9800 . ? C21 H21C 0.9800 . ? C22 C23 1.520(8) . ? C22 H22A 0.9900 . ? C22 H22B 0.9900 . ? C23 C24 1.540(8) . ? C23 H23A 0.9900 . ? C23 H23B 0.9900 . ? C24 Si1 1.868(6) 3_565 ? C24 H24A 0.9900 . ? C24 H24B 0.9900 . ? Rh3 C25 2.109(7) . ? Rh3 C26 2.116(8) . ? Rh3 C30 2.120(7) . ? Rh3 C29 2.121(7) . ? Rh3 S4 2.3479(18) . ? Rh3 S3 2.3506(17) . ? Rh4 C33 2.111(7) . ? Rh4 C37 2.123(7) . ? Rh4 C38 2.133(8) . ? Rh4 C34 2.138(8) . ? Rh4 S4 2.3401(18) . ? Rh4 S3 2.3568(18) . ? S3 C41 1.824(6) . ? S4 C46 1.827(6) . ? Si2 C44 1.851(7) . ? Si2 C45 1.871(7) . ? Si2 C43 1.879(6) . ? Si2 C48 1.881(6) . ? C25 C26 1.371(10) . ? C25 C32 1.536(9) . ? C25 H25 1.01(6) . ? C26 C27 1.517(11) . ? C26 H26 0.89(7) . ? C27 C28 1.442(11) . ? C27 H27A 0.9900 . ? C27 H27B 0.9900 . ? C28 C29 1.507(10) . ? C28 H28A 0.9900 . ? C28 H28B 0.9900 . ? C29 C30 1.409(10) . ? C29 H29 0.82(6) . ? C30 C31 1.514(9) . ? C30 H30 1.02(6) . ? C31 C32 1.426(9) . ? C31 H31A 0.9900 . ? C31 H31B 0.9900 . ? C32 H32A 0.9900 . ? C32 H32B 0.9900 . ? C33 C34 1.394(10) . ? C33 C40 1.515(9) . ? C33 H33 0.97(6) . ? C34 C35 1.539(10) . ? C34 H34 0.85(6) . ? C35 C36 1.509(9) . ? C35 H35A 0.9900 . ? C35 H35B 0.9900 . ? C36 C37 1.493(10) . ? C36 H36A 0.9900 . ? C36 H36B 0.9900 . ? C37 C38 1.362(10) . ? C37 H37 1.05(6) . ? C38 C39 1.510(9) . ? C38 H38 0.81(6) . ? C39 C40 1.526(9) . ? C39 H39A 0.9900 . ? C39 H39B 0.9900 . ? C40 H40A 0.9900 . ? C40 H40B 0.9900 . ? C41 C42 1.512(8) . ? C41 H41A 0.9900 . ? C41 H41B 0.9900 . ? C42 C43 1.534(8) . ? C42 H42A 0.9900 . ? C42 H42B 0.9900 . ? C43 H43A 0.9900 . ? C43 H43B 0.9900 . ? C44 H44A 0.9800 . ? C44 H44B 0.9800 . ? C44 H44C 0.9800 . ? C45 H45A 0.9800 . ? C45 H45B 0.9800 . ? C45 H45C 0.9800 . ? C46 C47 1.511(8) . ? C46 H46A 0.9900 . ? C46 H46B 0.9900 . ? C47 C48 1.539(8) 3_675 ? C47 H47A 0.9900 . ? C47 H47B 0.9900 . ? C48 C47 1.539(8) 3_675 ? C48 H48A 0.9900 . ? C48 H48B 0.9900 . ? C70 Cl1 1.740(8) . ? C70 Cl2 1.758(7) . ? C70 H70A 0.9900 . ? C70 H70B 0.9900 . ? C71 Cl3 1.735(7) . ? C71 Cl4 1.767(7) . ? C71 H71A 0.9900 . ? C71 H71B 0.9900 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C2 Rh1 C1 38.3(3) . . ? C2 Rh1 C5 81.8(3) . . ? C1 Rh1 C5 89.8(3) . . ? C2 Rh1 C6 98.0(3) . . ? C1 Rh1 C6 81.7(3) . . ? C5 Rh1 C6 38.0(2) . . ? C2 Rh1 S2 95.42(18) . . ? C1 Rh1 S2 99.72(19) . . ? C5 Rh1 S2 161.0(2) . . ? C6 Rh1 S2 159.6(2) . . ? C2 Rh1 S1 157.2(2) . . ? C1 Rh1 S1 162.56(19) . . ? C5 Rh1 S1 99.91(19) . . ? C6 Rh1 S1 97.0(2) . . ? S2 Rh1 S1 75.49(6) . . ? C10 Rh2 C14 97.9(3) . . ? C10 Rh2 C13 81.9(3) . . ? C14 Rh2 C13 38.2(2) . . ? C10 Rh2 C9 37.7(3) . . ? C14 Rh2 C9 81.7(3) . . ? C13 Rh2 C9 89.6(3) . . ? C10 Rh2 S2 156.3(2) . . ? C14 Rh2 S2 97.80(19) . . ? C13 Rh2 S2 99.96(18) . . ? C9 Rh2 S2 163.88(19) . . ? C10 Rh2 S1 96.9(2) . . ? C14 Rh2 S1 155.8(2) . . ? C13 Rh2 S1 164.58(18) . . ? C9 Rh2 S1 98.76(19) . . ? S2 Rh2 S1 75.08(6) . . ? C17 S1 Rh1 116.4(2) . . ? C17 S1 Rh2 117.3(2) . . ? Rh1 S1 Rh2 77.97(5) . . ? C22 S2 Rh1 118.0(2) . . ? C22 S2 Rh2 119.5(2) . . ? Rh1 S2 Rh2 78.31(5) . . ? C19 Si1 C20 110.7(3) . . ? C19 Si1 C24 108.8(3) . 3_565 ? C20 Si1 C24 109.7(3) . 3_565 ? C19 Si1 C21 107.6(3) . . ? C20 Si1 C21 110.6(3) . . ? C24 Si1 C21 109.5(3) 3_565 . ? C2 C1 C8 124.4(6) . . ? C2 C1 Rh1 69.4(4) . . ? C8 C1 Rh1 113.8(5) . . ? C2 C1 H1 117(5) . . ? C8 C1 H1 116(5) . . ? Rh1 C1 H1 102(5) . . ? C1 C2 C3 125.7(6) . . ? C1 C2 Rh1 72.3(4) . . ? C3 C2 Rh1 110.1(5) . . ? C1 C2 H2 114(5) . . ? C3 C2 H2 114(5) . . ? Rh1 C2 H2 112(5) . . ? C2 C3 C4 112.8(6) . . ? C2 C3 H3A 109.0 . . ? C4 C3 H3A 109.0 . . ? C2 C3 H3B 109.0 . . ? C4 C3 H3B 109.0 . . ? H3A C3 H3B 107.8 . . ? C5 C4 C3 111.2(5) . . ? C5 C4 H4A 109.4 . . ? C3 C4 H4A 109.4 . . ? C5 C4 H4B 109.4 . . ? C3 C4 H4B 109.4 . . ? H4A C4 H4B 108.0 . . ? C6 C5 C4 123.0(6) . . ? C6 C5 Rh1 71.3(4) . . ? C4 C5 Rh1 112.8(4) . . ? C6 C5 H5 115(5) . . ? C4 C5 H5 116(5) . . ? Rh1 C5 H5 110(4) . . ? C5 C6 C7 125.2(7) . . ? C5 C6 Rh1 70.7(4) . . ? C7 C6 Rh1 109.2(4) . . ? C5 C6 H6 129(4) . . ? C7 C6 H6 105(4) . . ? Rh1 C6 H6 99(4) . . ? C6 C7 C8 113.1(6) . . ? C6 C7 H7A 109.0 . . ? C8 C7 H7A 109.0 . . ? C6 C7 H7B 109.0 . . ? C8 C7 H7B 109.0 . . ? H7A C7 H7B 107.8 . . ? C1 C8 C7 112.5(6) . . ? C1 C8 H8A 109.1 . . ? C7 C8 H8A 109.1 . . ? C1 C8 H8B 109.1 . . ? C7 C8 H8B 109.1 . . ? H8A C8 H8B 107.8 . . ? C10 C9 C16 122.6(6) . . ? C10 C9 Rh2 69.7(4) . . ? C16 C9 Rh2 111.9(4) . . ? C10 C9 H9 124(4) . . ? C16 C9 H9 112(4) . . ? Rh2 C9 H9 102(4) . . ? C9 C10 C11 125.1(7) . . ? C9 C10 Rh2 72.7(4) . . ? C11 C10 Rh2 110.4(5) . . ? C9 C10 H10 120(6) . . ? C11 C10 H10 112(6) . . ? Rh2 C10 H10 104(5) . . ? C10 C11 C12 112.9(6) . . ? C10 C11 H11A 109.0 . . ? C12 C11 H11A 109.0 . . ? C10 C11 H11B 109.0 . . ? C12 C11 H11B 109.0 . . ? H11A C11 H11B 107.8 . . ? C13 C12 C11 112.5(6) . . ? C13 C12 H12A 109.1 . . ? C11 C12 H12A 109.1 . . ? C13 C12 H12B 109.1 . . ? C11 C12 H12B 109.1 . . ? H12A C12 H12B 107.8 . . ? C14 C13 C12 124.6(6) . . ? C14 C13 Rh2 70.4(4) . . ? C12 C13 Rh2 113.0(5) . . ? C14 C13 H13 118(4) . . ? C12 C13 H13 115(4) . . ? Rh2 C13 H13 104(4) . . ? C13 C14 C15 125.2(6) . . ? C13 C14 Rh2 71.4(4) . . ? C15 C14 Rh2 109.9(5) . . ? C13 C14 H14 116(4) . . ? C15 C14 H14 117(4) . . ? Rh2 C14 H14 102(4) . . ? C14 C15 C16 113.0(6) . . ? C14 C15 H15A 109.0 . . ? C16 C15 H15A 109.0 . . ? C14 C15 H15B 109.0 . . ? C16 C15 H15B 109.0 . . ? H15A C15 H15B 107.8 . . ? C15 C16 C9 112.0(5) . . ? C15 C16 H16A 109.2 . . ? C9 C16 H16A 109.2 . . ? C15 C16 H16B 109.2 . . ? C9 C16 H16B 109.2 . . ? H16A C16 H16B 107.9 . . ? C18 C17 S1 110.0(4) . . ? C18 C17 H17A 109.7 . . ? S1 C17 H17A 109.7 . . ? C18 C17 H17B 109.7 . . ? S1 C17 H17B 109.7 . . ? H17A C17 H17B 108.2 . . ? C17 C18 C19 114.1(5) . . ? C17 C18 H18A 108.7 . . ? C19 C18 H18A 108.7 . . ? C17 C18 H18B 108.7 . . ? C19 C18 H18B 108.7 . . ? H18A C18 H18B 107.6 . . ? C18 C19 Si1 116.9(4) . . ? C18 C19 H19A 108.1 . . ? Si1 C19 H19A 108.1 . . ? C18 C19 H19B 108.1 . . ? Si1 C19 H19B 108.1 . . ? H19A C19 H19B 107.3 . . ? Si1 C20 H20A 109.5 . . ? Si1 C20 H20B 109.5 . . ? H20A C20 H20B 109.5 . . ? Si1 C20 H20C 109.5 . . ? H20A C20 H20C 109.5 . . ? H20B C20 H20C 109.5 . . ? Si1 C21 H21A 109.5 . . ? Si1 C21 H21B 109.5 . . ? H21A C21 H21B 109.5 . . ? Si1 C21 H21C 109.5 . . ? H21A C21 H21C 109.5 . . ? H21B C21 H21C 109.5 . . ? C23 C22 S2 109.5(4) . . ? C23 C22 H22A 109.8 . . ? S2 C22 H22A 109.8 . . ? C23 C22 H22B 109.8 . . ? S2 C22 H22B 109.8 . . ? H22A C22 H22B 108.2 . . ? C22 C23 C24 114.3(5) . . ? C22 C23 H23A 108.7 . . ? C24 C23 H23A 108.7 . . ? C22 C23 H23B 108.7 . . ? C24 C23 H23B 108.7 . . ? H23A C23 H23B 107.6 . . ? C23 C24 Si1 112.2(4) . 3_565 ? C23 C24 H24A 109.2 . . ? Si1 C24 H24A 109.2 3_565 . ? C23 C24 H24B 109.2 . . ? Si1 C24 H24B 109.2 3_565 . ? H24A C24 H24B 107.9 . . ? C25 Rh3 C26 37.9(3) . . ? C25 Rh3 C30 82.5(3) . . ? C26 Rh3 C30 95.4(3) . . ? C25 Rh3 C29 94.2(3) . . ? C26 Rh3 C29 82.4(3) . . ? C30 Rh3 C29 38.8(3) . . ? C25 Rh3 S4 159.2(2) . . ? C26 Rh3 S4 160.8(2) . . ? C30 Rh3 S4 97.0(2) . . ? C29 Rh3 S4 98.3(2) . . ? C25 Rh3 S3 96.4(2) . . ? C26 Rh3 S3 98.0(2) . . ? C30 Rh3 S3 156.3(2) . . ? C29 Rh3 S3 163.1(2) . . ? S4 Rh3 S3 75.83(6) . . ? C33 Rh4 C37 97.7(3) . . ? C33 Rh4 C38 81.9(3) . . ? C37 Rh4 C38 37.3(3) . . ? C33 Rh4 C34 38.3(3) . . ? C37 Rh4 C34 82.1(3) . . ? C38 Rh4 C34 90.1(3) . . ? C33 Rh4 S4 96.0(2) . . ? C37 Rh4 S4 159.3(2) . . ? C38 Rh4 S4 161.7(2) . . ? C34 Rh4 S4 99.5(2) . . ? C33 Rh4 S3 155.7(2) . . ? C37 Rh4 S3 97.0(2) . . ? C38 Rh4 S3 98.6(2) . . ? C34 Rh4 S3 164.4(2) . . ? S4 Rh4 S3 75.86(6) . . ? C41 S3 Rh3 117.2(2) . . ? C41 S3 Rh4 117.8(2) . . ? Rh3 S3 Rh4 75.83(5) . . ? C46 S4 Rh4 117.2(2) . . ? C46 S4 Rh3 119.3(2) . . ? Rh4 S4 Rh3 76.20(5) . . ? C44 Si2 C45 109.5(3) . . ? C44 Si2 C43 109.5(3) . . ? C45 Si2 C43 109.6(3) . . ? C44 Si2 C48 111.7(3) . . ? C45 Si2 C48 108.0(3) . . ? C43 Si2 C48 108.4(3) . . ? C26 C25 C32 124.5(8) . . ? C26 C25 Rh3 71.4(5) . . ? C32 C25 Rh3 110.9(5) . . ? C26 C25 H25 120(4) . . ? C32 C25 H25 112(4) . . ? Rh3 C25 H25 108(4) . . ? C25 C26 C27 124.0(8) . . ? C25 C26 Rh3 70.8(5) . . ? C27 C26 Rh3 110.8(6) . . ? C25 C26 H26 117(5) . . ? C27 C26 H26 117(5) . . ? Rh3 C26 H26 103(5) . . ? C28 C27 C26 116.9(7) . . ? C28 C27 H27A 108.1 . . ? C26 C27 H27A 108.1 . . ? C28 C27 H27B 108.1 . . ? C26 C27 H27B 108.1 . . ? H27A C27 H27B 107.3 . . ? C27 C28 C29 116.0(7) . . ? C27 C28 H28A 108.3 . . ? C29 C28 H28A 108.3 . . ? C27 C28 H28B 108.3 . . ? C29 C28 H28B 108.3 . . ? H28A C28 H28B 107.4 . . ? C30 C29 C28 124.1(7) . . ? C30 C29 Rh3 70.5(4) . . ? C28 C29 Rh3 111.8(5) . . ? C30 C29 H29 118(6) . . ? C28 C29 H29 114(6) . . ? Rh3 C29 H29 107(5) . . ? C29 C30 C31 123.7(7) . . ? C29 C30 Rh3 70.7(4) . . ? C31 C30 Rh3 111.5(5) . . ? C29 C30 H30 116(4) . . ? C31 C30 H30 117(4) . . ? Rh3 C30 H30 105(3) . . ? C32 C31 C30 116.1(6) . . ? C32 C31 H31A 108.3 . . ? C30 C31 H31A 108.3 . . ? C32 C31 H31B 108.3 . . ? C30 C31 H31B 108.3 . . ? H31A C31 H31B 107.4 . . ? C31 C32 C25 116.8(7) . . ? C31 C32 H32A 108.1 . . ? C25 C32 H32A 108.1 . . ? C31 C32 H32B 108.1 . . ? C25 C32 H32B 108.1 . . ? H32A C32 H32B 107.3 . . ? C34 C33 C40 125.6(7) . . ? C34 C33 Rh4 71.9(4) . . ? C40 C33 Rh4 110.4(5) . . ? C34 C33 H33 110(4) . . ? C40 C33 H33 122(4) . . ? Rh4 C33 H33 100(4) . . ? C33 C34 C35 123.7(7) . . ? C33 C34 Rh4 69.8(4) . . ? C35 C34 Rh4 112.3(5) . . ? C33 C34 H34 125(5) . . ? C35 C34 H34 111(5) . . ? Rh4 C34 H34 99(5) . . ? C36 C35 C34 112.4(6) . . ? C36 C35 H35A 109.1 . . ? C34 C35 H35A 109.1 . . ? C36 C35 H35B 109.1 . . ? C34 C35 H35B 109.1 . . ? H35A C35 H35B 107.9 . . ? C37 C36 C35 114.8(7) . . ? C37 C36 H36A 108.6 . . ? C35 C36 H36A 108.6 . . ? C37 C36 H36B 108.6 . . ? C35 C36 H36B 108.6 . . ? H36A C36 H36B 107.6 . . ? C38 C37 C36 124.5(7) . . ? C38 C37 Rh4 71.7(5) . . ? C36 C37 Rh4 110.5(5) . . ? C38 C37 H37 117(4) . . ? C36 C37 H37 116(4) . . ? Rh4 C37 H37 105(4) . . ? C37 C38 C39 123.6(7) . . ? C37 C38 Rh4 70.9(4) . . ? C39 C38 Rh4 113.0(5) . . ? C37 C38 H38 122(5) . . ? C39 C38 H38 112(5) . . ? Rh4 C38 H38 103(5) . . ? C38 C39 C40 112.4(6) . . ? C38 C39 H39A 109.1 . . ? C40 C39 H39A 109.1 . . ? C38 C39 H39B 109.1 . . ? C40 C39 H39B 109.1 . . ? H39A C39 H39B 107.9 . . ? C33 C40 C39 112.5(6) . . ? C33 C40 H40A 109.1 . . ? C39 C40 H40A 109.1 . . ? C33 C40 H40B 109.1 . . ? C39 C40 H40B 109.1 . . ? H40A C40 H40B 107.8 . . ? C42 C41 S3 111.7(4) . . ? C42 C41 H41A 109.3 . . ? S3 C41 H41A 109.3 . . ? C42 C41 H41B 109.3 . . ? S3 C41 H41B 109.3 . . ? H41A C41 H41B 107.9 . . ? C41 C42 C43 114.3(6) . . ? C41 C42 H42A 108.7 . . ? C43 C42 H42A 108.7 . . ? C41 C42 H42B 108.7 . . ? C43 C42 H42B 108.7 . . ? H42A C42 H42B 107.6 . . ? C42 C43 Si2 114.7(4) . . ? C42 C43 H43A 108.6 . . ? Si2 C43 H43A 108.6 . . ? C42 C43 H43B 108.6 . . ? Si2 C43 H43B 108.6 . . ? H43A C43 H43B 107.6 . . ? Si2 C44 H44A 109.5 . . ? Si2 C44 H44B 109.5 . . ? H44A C44 H44B 109.5 . . ? Si2 C44 H44C 109.5 . . ? H44A C44 H44C 109.5 . . ? H44B C44 H44C 109.5 . . ? Si2 C45 H45A 109.5 . . ? Si2 C45 H45B 109.5 . . ? H45A C45 H45B 109.5 . . ? Si2 C45 H45C 109.5 . . ? H45A C45 H45C 109.5 . . ? H45B C45 H45C 109.5 . . ? C47 C46 S4 109.9(4) . . ? C47 C46 H46A 109.7 . . ? S4 C46 H46A 109.7 . . ? C47 C46 H46B 109.7 . . ? S4 C46 H46B 109.7 . . ? H46A C46 H46B 108.2 . . ? C46 C47 C48 114.1(5) . 3_675 ? C46 C47 H47A 108.7 . . ? C48 C47 H47A 108.7 3_675 . ? C46 C47 H47B 108.7 . . ? C48 C47 H47B 108.7 3_675 . ? H47A C47 H47B 107.6 . . ? C47 C48 Si2 113.2(4) 3_675 . ? C47 C48 H48A 108.9 3_675 . ? Si2 C48 H48A 108.9 . . ? C47 C48 H48B 108.9 3_675 . ? Si2 C48 H48B 108.9 . . ? H48A C48 H48B 107.7 . . ? Cl1 C70 Cl2 112.8(4) . . ? Cl1 C70 H70A 109.0 . . ? Cl2 C70 H70A 109.0 . . ? Cl1 C70 H70B 109.0 . . ? Cl2 C70 H70B 109.0 . . ? H70A C70 H70B 107.8 . . ? Cl3 C71 Cl4 110.7(4) . . ? Cl3 C71 H71A 109.5 . . ? Cl4 C71 H71A 109.5 . . ? Cl3 C71 H71B 109.5 . . ? Cl4 C71 H71B 109.5 . . ? H71A C71 H71B 108.1 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag C2 Rh1 S1 C17 97.2(5) . . . . ? C1 Rh1 S1 C17 -118.1(7) . . . . ? C5 Rh1 S1 C17 4.8(3) . . . . ? C6 Rh1 S1 C17 -33.5(3) . . . . ? S2 Rh1 S1 C17 165.9(2) . . . . ? C2 Rh1 S1 Rh2 -17.5(5) . . . . ? C1 Rh1 S1 Rh2 127.3(7) . . . . ? C5 Rh1 S1 Rh2 -109.9(2) . . . . ? C6 Rh1 S1 Rh2 -148.1(2) . . . . ? S2 Rh1 S1 Rh2 51.23(5) . . . . ? C10 Rh2 S1 C17 38.0(3) . . . . ? C14 Rh2 S1 C17 -89.3(5) . . . . ? C13 Rh2 S1 C17 122.2(7) . . . . ? C9 Rh2 S1 C17 0.0(3) . . . . ? S2 Rh2 S1 C17 -164.8(3) . . . . ? C10 Rh2 S1 Rh1 151.7(2) . . . . ? C14 Rh2 S1 Rh1 24.5(5) . . . . ? C13 Rh2 S1 Rh1 -124.0(7) . . . . ? C9 Rh2 S1 Rh1 113.7(2) . . . . ? S2 Rh2 S1 Rh1 -51.07(5) . . . . ? C2 Rh1 S2 C22 -10.1(3) . . . . ? C1 Rh1 S2 C22 28.4(3) . . . . ? C5 Rh1 S2 C22 -90.6(6) . . . . ? C6 Rh1 S2 C22 120.7(6) . . . . ? S1 Rh1 S2 C22 -168.8(2) . . . . ? C2 Rh1 S2 Rh2 107.3(2) . . . . ? C1 Rh1 S2 Rh2 145.7(2) . . . . ? C5 Rh1 S2 Rh2 26.7(6) . . . . ? C6 Rh1 S2 Rh2 -122.0(6) . . . . ? S1 Rh1 S2 Rh2 -51.44(5) . . . . ? C10 Rh2 S2 C22 -120.5(6) . . . . ? C14 Rh2 S2 C22 10.6(3) . . . . ? C13 Rh2 S2 C22 -28.0(3) . . . . ? C9 Rh2 S2 C22 97.7(8) . . . . ? S1 Rh2 S2 C22 166.9(2) . . . . ? C10 Rh2 S2 Rh1 123.8(5) . . . . ? C14 Rh2 S2 Rh1 -105.1(2) . . . . ? C13 Rh2 S2 Rh1 -143.75(19) . . . . ? C9 Rh2 S2 Rh1 -18.0(7) . . . . ? S1 Rh2 S2 Rh1 51.20(5) . . . . ? C5 Rh1 C1 C2 77.0(4) . . . . ? C6 Rh1 C1 C2 114.2(4) . . . . ? S2 Rh1 C1 C2 -86.4(4) . . . . ? S1 Rh1 C1 C2 -158.8(5) . . . . ? C2 Rh1 C1 C8 -119.6(7) . . . . ? C5 Rh1 C1 C8 -42.6(5) . . . . ? C6 Rh1 C1 C8 -5.4(5) . . . . ? S2 Rh1 C1 C8 154.0(5) . . . . ? S1 Rh1 C1 C8 81.6(8) . . . . ? C8 C1 C2 C3 3.0(11) . . . . ? Rh1 C1 C2 C3 -102.3(7) . . . . ? C8 C1 C2 Rh1 105.3(7) . . . . ? C5 Rh1 C2 C1 -100.1(4) . . . . ? C6 Rh1 C2 C1 -65.7(4) . . . . ? S2 Rh1 C2 C1 98.8(4) . . . . ? S1 Rh1 C2 C1 163.8(4) . . . . ? C1 Rh1 C2 C3 122.3(7) . . . . ? C5 Rh1 C2 C3 22.2(5) . . . . ? C6 Rh1 C2 C3 56.7(5) . . . . ? S2 Rh1 C2 C3 -138.8(4) . . . . ? S1 Rh1 C2 C3 -73.9(7) . . . . ? C1 C2 C3 C4 45.0(10) . . . . ? Rh1 C2 C3 C4 -37.1(7) . . . . ? C2 C3 C4 C5 33.5(8) . . . . ? C3 C4 C5 C6 -96.0(8) . . . . ? C3 C4 C5 Rh1 -14.2(7) . . . . ? C2 Rh1 C5 C6 114.3(5) . . . . ? C1 Rh1 C5 C6 76.7(5) . . . . ? S2 Rh1 C5 C6 -162.9(5) . . . . ? S1 Rh1 C5 C6 -88.7(4) . . . . ? C2 Rh1 C5 C4 -4.5(5) . . . . ? C1 Rh1 C5 C4 -42.1(5) . . . . ? C6 Rh1 C5 C4 -118.8(7) . . . . ? S2 Rh1 C5 C4 78.3(8) . . . . ? S1 Rh1 C5 C4 152.5(5) . . . . ? C4 C5 C6 C7 5.2(11) . . . . ? Rh1 C5 C6 C7 -100.3(6) . . . . ? C4 C5 C6 Rh1 105.5(6) . . . . ? C2 Rh1 C6 C5 -65.6(5) . . . . ? C1 Rh1 C6 C5 -100.4(4) . . . . ? S2 Rh1 C6 C5 164.0(4) . . . . ? S1 Rh1 C6 C5 97.1(4) . . . . ? C2 Rh1 C6 C7 56.1(5) . . . . ? C1 Rh1 C6 C7 21.3(5) . . . . ? C5 Rh1 C6 C7 121.7(7) . . . . ? S2 Rh1 C6 C7 -74.3(8) . . . . ? S1 Rh1 C6 C7 -141.2(4) . . . . ? C5 C6 C7 C8 45.3(9) . . . . ? Rh1 C6 C7 C8 -34.3(7) . . . . ? C2 C1 C8 C7 -92.5(8) . . . . ? Rh1 C1 C8 C7 -12.0(7) . . . . ? C6 C7 C8 C1 30.8(8) . . . . ? C14 Rh2 C9 C10 -114.6(5) . . . . ? C13 Rh2 C9 C10 -77.1(5) . . . . ? S2 Rh2 C9 C10 156.0(6) . . . . ? S1 Rh2 C9 C10 89.9(4) . . . . ? C10 Rh2 C9 C16 118.0(7) . . . . ? C14 Rh2 C9 C16 3.4(5) . . . . ? C13 Rh2 C9 C16 40.9(5) . . . . ? S2 Rh2 C9 C16 -86.0(8) . . . . ? S1 Rh2 C9 C16 -152.1(4) . . . . ? C16 C9 C10 C11 -0.4(11) . . . . ? Rh2 C9 C10 C11 103.2(7) . . . . ? C16 C9 C10 Rh2 -103.6(6) . . . . ? C14 Rh2 C10 C9 65.3(5) . . . . ? C13 Rh2 C10 C9 100.0(4) . . . . ? S2 Rh2 C10 C9 -163.7(4) . . . . ? S1 Rh2 C10 C9 -95.5(4) . . . . ? C14 Rh2 C10 C11 -56.5(5) . . . . ? C13 Rh2 C10 C11 -21.7(5) . . . . ? C9 Rh2 C10 C11 -121.7(7) . . . . ? S2 Rh2 C10 C11 74.6(7) . . . . ? S1 Rh2 C10 C11 142.8(5) . . . . ? C9 C10 C11 C12 -48.8(9) . . . . ? Rh2 C10 C11 C12 33.9(7) . . . . ? C10 C11 C12 C13 -29.1(8) . . . . ? C11 C12 C13 C14 91.7(8) . . . . ? C11 C12 C13 Rh2 10.4(7) . . . . ? C10 Rh2 C13 C14 -114.0(4) . . . . ? C9 Rh2 C13 C14 -77.0(4) . . . . ? S2 Rh2 C13 C14 90.0(4) . . . . ? S1 Rh2 C13 C14 159.7(6) . . . . ? C10 Rh2 C13 C12 6.3(5) . . . . ? C14 Rh2 C13 C12 120.3(6) . . . . ? C9 Rh2 C13 C12 43.3(5) . . . . ? S2 Rh2 C13 C12 -149.7(4) . . . . ? S1 Rh2 C13 C12 -80.0(8) . . . . ? C12 C13 C14 C15 -3.2(11) . . . . ? Rh2 C13 C14 C15 101.7(7) . . . . ? C12 C13 C14 Rh2 -104.9(7) . . . . ? C10 Rh2 C14 C13 65.9(4) . . . . ? C9 Rh2 C14 C13 100.1(4) . . . . ? S2 Rh2 C14 C13 -96.2(4) . . . . ? S1 Rh2 C14 C13 -167.0(4) . . . . ? C10 Rh2 C14 C15 -55.7(5) . . . . ? C13 Rh2 C14 C15 -121.7(7) . . . . ? C9 Rh2 C14 C15 -21.6(5) . . . . ? S2 Rh2 C14 C15 142.1(4) . . . . ? S1 Rh2 C14 C15 71.3(7) . . . . ? C13 C14 C15 C16 -43.8(9) . . . . ? Rh2 C14 C15 C16 37.1(7) . . . . ? C14 C15 C16 C9 -34.8(8) . . . . ? C10 C9 C16 C15 94.7(8) . . . . ? Rh2 C9 C16 C15 15.5(7) . . . . ? Rh1 S1 C17 C18 127.3(4) . . . . ? Rh2 S1 C17 C18 -143.0(4) . . . . ? S1 C17 C18 C19 -67.5(6) . . . . ? C17 C18 C19 Si1 163.1(4) . . . . ? C20 Si1 C19 C18 62.3(5) . . . . ? C24 Si1 C19 C18 -58.3(5) 3_565 . . . ? C21 Si1 C19 C18 -176.8(5) . . . . ? Rh1 S2 C22 C23 -173.0(4) . . . . ? Rh2 S2 C22 C23 94.9(4) . . . . ? S2 C22 C23 C24 176.2(5) . . . . ? C22 C23 C24 Si1 175.6(4) . . . 3_565 ? C25 Rh3 S3 C41 6.1(3) . . . . ? C26 Rh3 S3 C41 -32.0(4) . . . . ? C30 Rh3 S3 C41 91.8(5) . . . . ? C29 Rh3 S3 C41 -122.2(8) . . . . ? S4 Rh3 S3 C41 166.5(3) . . . . ? C25 Rh3 S3 Rh4 -108.1(2) . . . . ? C26 Rh3 S3 Rh4 -146.3(2) . . . . ? C30 Rh3 S3 Rh4 -22.4(5) . . . . ? C29 Rh3 S3 Rh4 123.6(7) . . . . ? S4 Rh3 S3 Rh4 52.28(5) . . . . ? C33 Rh4 S3 C41 -93.3(5) . . . . ? C37 Rh4 S3 C41 33.7(3) . . . . ? C38 Rh4 S3 C41 -3.9(3) . . . . ? C34 Rh4 S3 C41 119.5(8) . . . . ? S4 Rh4 S3 C41 -166.1(3) . . . . ? C33 Rh4 S3 Rh3 20.3(5) . . . . ? C37 Rh4 S3 Rh3 147.3(2) . . . . ? C38 Rh4 S3 Rh3 109.7(2) . . . . ? C34 Rh4 S3 Rh3 -126.9(8) . . . . ? S4 Rh4 S3 Rh3 -52.51(5) . . . . ? C33 Rh4 S4 C46 11.9(3) . . . . ? C37 Rh4 S4 C46 -119.3(6) . . . . ? C38 Rh4 S4 C46 94.2(7) . . . . ? C34 Rh4 S4 C46 -26.6(3) . . . . ? S3 Rh4 S4 C46 168.6(3) . . . . ? C33 Rh4 S4 Rh3 -104.2(2) . . . . ? C37 Rh4 S4 Rh3 124.5(6) . . . . ? C38 Rh4 S4 Rh3 -21.9(7) . . . . ? C34 Rh4 S4 Rh3 -142.7(2) . . . . ? S3 Rh4 S4 Rh3 52.48(5) . . . . ? C25 Rh3 S4 C46 -96.5(6) . . . . ? C26 Rh3 S4 C46 120.4(7) . . . . ? C30 Rh3 S4 C46 -9.4(3) . . . . ? C29 Rh3 S4 C46 29.8(3) . . . . ? S3 Rh3 S4 C46 -166.4(3) . . . . ? C25 Rh3 S4 Rh4 17.3(6) . . . . ? C26 Rh3 S4 Rh4 -125.9(7) . . . . ? C30 Rh3 S4 Rh4 104.3(2) . . . . ? C29 Rh3 S4 Rh4 143.5(2) . . . . ? S3 Rh3 S4 Rh4 -52.69(5) . . . . ? C30 Rh3 C25 C26 109.0(5) . . . . ? C29 Rh3 C25 C26 71.9(5) . . . . ? S4 Rh3 C25 C26 -161.3(5) . . . . ? S3 Rh3 C25 C26 -94.8(5) . . . . ? C26 Rh3 C25 C32 -120.7(8) . . . . ? C30 Rh3 C25 C32 -11.7(6) . . . . ? C29 Rh3 C25 C32 -48.8(7) . . . . ? S4 Rh3 C25 C32 78.0(8) . . . . ? S3 Rh3 C25 C32 144.5(6) . . . . ? C32 C25 C26 C27 0.4(13) . . . . ? Rh3 C25 C26 C27 -102.6(8) . . . . ? C32 C25 C26 Rh3 103.0(7) . . . . ? C30 Rh3 C26 C25 -70.3(5) . . . . ? C29 Rh3 C26 C25 -107.0(5) . . . . ? S4 Rh3 C26 C25 159.7(5) . . . . ? S3 Rh3 C26 C25 90.1(4) . . . . ? C25 Rh3 C26 C27 120.0(9) . . . . ? C30 Rh3 C26 C27 49.7(7) . . . . ? C29 Rh3 C26 C27 13.1(7) . . . . ? S4 Rh3 C26 C27 -80.2(10) . . . . ? S3 Rh3 C26 C27 -149.9(6) . . . . ? C25 C26 C27 C28 67.2(13) . . . . ? Rh3 C26 C27 C28 -13.1(12) . . . . ? C26 C27 C28 C29 3.8(14) . . . . ? C27 C28 C29 C30 -73.2(11) . . . . ? C27 C28 C29 Rh3 7.4(10) . . . . ? C25 Rh3 C29 C30 72.5(5) . . . . ? C26 Rh3 C29 C30 108.6(5) . . . . ? S4 Rh3 C29 C30 -90.8(4) . . . . ? S3 Rh3 C29 C30 -159.0(6) . . . . ? C25 Rh3 C29 C28 -47.4(6) . . . . ? C26 Rh3 C29 C28 -11.3(6) . . . . ? C30 Rh3 C29 C28 -119.9(7) . . . . ? S4 Rh3 C29 C28 149.3(5) . . . . ? S3 Rh3 C29 C28 81.1(9) . . . . ? C28 C29 C30 C31 0.2(11) . . . . ? Rh3 C29 C30 C31 -103.4(7) . . . . ? C28 C29 C30 Rh3 103.6(7) . . . . ? C25 Rh3 C30 C29 -106.4(5) . . . . ? C26 Rh3 C30 C29 -70.7(5) . . . . ? S4 Rh3 C30 C29 94.6(4) . . . . ? S3 Rh3 C30 C29 165.0(4) . . . . ? C25 Rh3 C30 C31 13.3(6) . . . . ? C26 Rh3 C30 C31 48.9(6) . . . . ? C29 Rh3 C30 C31 119.6(8) . . . . ? S4 Rh3 C30 C31 -145.8(5) . . . . ? S3 Rh3 C30 C31 -75.4(8) . . . . ? C29 C30 C31 C32 67.9(11) . . . . ? Rh3 C30 C31 C32 -12.6(10) . . . . ? C30 C31 C32 C25 2.8(13) . . . . ? C26 C25 C32 C31 -72.9(12) . . . . ? Rh3 C25 C32 C31 8.3(11) . . . . ? C37 Rh4 C33 C34 66.7(5) . . . . ? C38 Rh4 C33 C34 100.6(5) . . . . ? S4 Rh4 C33 C34 -97.7(4) . . . . ? S3 Rh4 C33 C34 -166.4(4) . . . . ? C37 Rh4 C33 C40 -55.5(6) . . . . ? C38 Rh4 C33 C40 -21.5(5) . . . . ? C34 Rh4 C33 C40 -122.1(7) . . . . ? S4 Rh4 C33 C40 140.1(5) . . . . ? S3 Rh4 C33 C40 71.5(7) . . . . ? C40 C33 C34 C35 -1.3(12) . . . . ? Rh4 C33 C34 C35 -103.9(7) . . . . ? C40 C33 C34 Rh4 102.5(7) . . . . ? C37 Rh4 C34 C33 -113.3(5) . . . . ? C38 Rh4 C34 C33 -76.7(5) . . . . ? S4 Rh4 C34 C33 87.6(4) . . . . ? S3 Rh4 C34 C33 158.9(6) . . . . ? C33 Rh4 C34 C35 119.3(7) . . . . ? C37 Rh4 C34 C35 6.0(5) . . . . ? C38 Rh4 C34 C35 42.6(5) . . . . ? S4 Rh4 C34 C35 -153.1(5) . . . . ? S3 Rh4 C34 C35 -81.9(9) . . . . ? C33 C34 C35 C36 89.1(9) . . . . ? Rh4 C34 C35 C36 9.3(8) . . . . ? C34 C35 C36 C37 -27.2(10) . . . . ? C35 C36 C37 C38 -49.6(11) . . . . ? C35 C36 C37 Rh4 31.8(8) . . . . ? C33 Rh4 C37 C38 65.7(5) . . . . ? C34 Rh4 C37 C38 100.7(5) . . . . ? S4 Rh4 C37 C38 -163.4(4) . . . . ? S3 Rh4 C37 C38 -95.0(4) . . . . ? C33 Rh4 C37 C36 -55.2(6) . . . . ? C38 Rh4 C37 C36 -120.9(8) . . . . ? C34 Rh4 C37 C36 -20.2(5) . . . . ? S4 Rh4 C37 C36 75.8(8) . . . . ? S3 Rh4 C37 C36 144.1(5) . . . . ? C36 C37 C38 C39 -2.7(12) . . . . ? Rh4 C37 C38 C39 -105.4(7) . . . . ? C36 C37 C38 Rh4 102.8(7) . . . . ? C33 Rh4 C38 C37 -114.2(5) . . . . ? C34 Rh4 C38 C37 -76.7(5) . . . . ? S4 Rh4 C38 C37 161.2(5) . . . . ? S3 Rh4 C38 C37 90.3(4) . . . . ? C33 Rh4 C38 C39 5.1(6) . . . . ? C37 Rh4 C38 C39 119.3(8) . . . . ? C34 Rh4 C38 C39 42.6(6) . . . . ? S4 Rh4 C38 C39 -79.5(9) . . . . ? S3 Rh4 C38 C39 -150.4(5) . . . . ? C37 C38 C39 C40 94.2(10) . . . . ? Rh4 C38 C39 C40 12.5(9) . . . . ? C34 C33 C40 C39 -47.1(10) . . . . ? Rh4 C33 C40 C39 34.7(8) . . . . ? C38 C39 C40 C33 -31.0(10) . . . . ? Rh3 S3 C41 C42 143.4(4) . . . . ? Rh4 S3 C41 C42 -128.9(4) . . . . ? S3 C41 C42 C43 67.9(7) . . . . ? C41 C42 C43 Si2 -162.6(4) . . . . ? C44 Si2 C43 C42 -62.8(5) . . . . ? C45 Si2 C43 C42 177.0(4) . . . . ? C48 Si2 C43 C42 59.3(5) . . . . ? Rh4 S4 C46 C47 172.2(4) . . . . ? Rh3 S4 C46 C47 -98.9(4) . . . . ? S4 C46 C47 C48 -176.7(4) . . . 3_675 ? C44 Si2 C48 C47 163.6(4) . . . 3_675 ? C45 Si2 C48 C47 -75.9(5) . . . 3_675 ? C43 Si2 C48 C47 42.9(5) . . . 3_675 ? _diffrn_measured_fraction_theta_max 0.992 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.998 _refine_diff_density_max 2.556 _refine_diff_density_min -0.651 _refine_diff_density_rms 0.132