Electronic Supplementary Material for Dalton Transactions This journal is (c) The Royal Society of Chemistry 2006 data_global _journal_name_full 'Dalton Trans.' _journal_coden_Cambridge 0222 _publ_contact_author_name 'Wanzhi Chen' _publ_contact_author_address ; Department of Chemistry Zhejiang University Tianmushan Road 148 Hangzhou 310023 CHINA ; _publ_contact_author_email CHENWZZ@ZJU.EDU.CN _publ_section_title ; Synthesis and structural characterization of 1-, 2-dimensional coordination polymers based on platinum-silver metallic backbones ; loop_ _publ_author_name 'Wanzhi Chen' 'Fenghui Liu' # Attachment 'CIFs.txt' data_ag _database_code_depnum_ccdc_archive 'CCDC 286687' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C10 H28 Ag Cl N4 O7 Pt' _chemical_formula_weight 654.77 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting monoclinic _symmetry_space_group_name_H-M P2(1)/c loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 16.753(14) _cell_length_b 11.156(9) _cell_length_c 11.221(9) _cell_angle_alpha 90.00 _cell_angle_beta 100.550(11) _cell_angle_gamma 90.00 _cell_volume 2062(3) _cell_formula_units_Z 4 _cell_measurement_temperature 293(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description prism _exptl_crystal_colour colorless _exptl_crystal_size_max 0.38 _exptl_crystal_size_mid 0.30 _exptl_crystal_size_min 0.12 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.110 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1256 _exptl_absorpt_coefficient_mu 7.892 _exptl_absorpt_correction_type none _exptl_absorpt_correction_T_min 0.1534 _exptl_absorpt_correction_T_max 0.4510 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 293(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 5205 _diffrn_reflns_av_R_equivalents 0.0535 _diffrn_reflns_av_sigmaI/netI 0.0752 _diffrn_reflns_limit_h_min -18 _diffrn_reflns_limit_h_max 12 _diffrn_reflns_limit_k_min -11 _diffrn_reflns_limit_k_max 12 _diffrn_reflns_limit_l_min -12 _diffrn_reflns_limit_l_max 12 _diffrn_reflns_theta_min 4.73 _diffrn_reflns_theta_max 23.75 _reflns_number_total 2578 _reflns_number_gt 1876 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.1855P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method SHELXL _refine_ls_extinction_coef 0.0013(7) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_number_reflns 2578 _refine_ls_number_parameters 254 _refine_ls_number_restraints 230 _refine_ls_R_factor_all 0.1024 _refine_ls_R_factor_gt 0.0870 _refine_ls_wR_factor_ref 0.2613 _refine_ls_wR_factor_gt 0.2470 _refine_ls_goodness_of_fit_ref 1.080 _refine_ls_restrained_S_all 1.055 _refine_ls_shift/su_max 0.000 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Pt1 Pt 0.67837(4) 0.25217(4) 0.56103(6) 0.0365(5) Uani 1 1 d . . . Ag2 Ag 0.72805(15) 0.23087(14) 0.32867(17) 0.0680(8) Uani 1 1 d . . . Cl1 Cl 0.5346(4) 0.9851(5) 0.2719(4) 0.0739(16) Uani 1 1 d DU . . N1 N 0.6907(9) 0.4285(12) 0.5353(12) 0.051(4) Uani 1 1 d . . . H1 H 0.7224 0.4545 0.6040 0.061 Uiso 1 1 d R . . N2 N 0.8014(13) 0.2467(10) 0.614(2) 0.050(5) Uani 1 1 d . . . H2 H 0.8237 0.3153 0.6326 0.060 Uiso 1 1 calc R . . N3 N 0.6662(10) 0.0719(12) 0.5958(12) 0.055(4) Uani 1 1 d . . . H3D H 0.7139 0.0356 0.5999 0.083 Uiso 1 1 calc R . . H3E H 0.6301 0.0393 0.5365 0.083 Uiso 1 1 calc R . . H3F H 0.6493 0.0630 0.6660 0.083 Uiso 1 1 calc R . . N4 N 0.5519(12) 0.2670(12) 0.5093(19) 0.053(5) Uani 1 1 d . . . H4D H 0.5400 0.3304 0.4612 0.080 Uiso 1 1 calc R . . H4E H 0.5297 0.2759 0.5750 0.080 Uiso 1 1 calc R . . H4F H 0.5324 0.2011 0.4698 0.080 Uiso 1 1 calc R . . O1 O 0.7353(10) 0.4256(11) 0.3577(10) 0.070(4) Uani 1 1 d . . . O2 O 0.8337(8) 0.0517(11) 0.5879(12) 0.069(4) Uani 1 1 d . . . O3 O 0.7769(11) 0.0372(14) 0.3401(13) 0.096(5) Uani 1 1 d . . . H1A H 0.8238 0.0270 0.3824 0.115 Uiso 1 1 d R . . H1B H 0.7470 -0.0158 0.3644 0.115 Uiso 1 1 d R . . O4 O 0.4688(14) 0.943(3) 0.189(2) 0.121(8) Uani 0.50 1 d PDU A 1 O5 O 0.6085(13) 0.933(3) 0.249(2) 0.117(7) Uani 0.50 1 d PDU A 1 O6 O 0.5293(19) 0.965(3) 0.3917(15) 0.117(7) Uani 0.50 1 d PDU A 1 O7 O 0.543(2) 1.1133(15) 0.255(3) 0.123(8) Uani 0.50 1 d PDU A 1 O4' O 0.6161(11) 0.966(3) 0.321(2) 0.121(8) Uani 0.50 1 d PDU A 2 O5' O 0.4995(19) 1.073(2) 0.334(2) 0.128(8) Uani 0.50 1 d PDU A 2 O6' O 0.5249(19) 1.016(2) 0.1467(13) 0.112(7) Uani 0.50 1 d PDU A 2 O7' O 0.4890(18) 0.874(2) 0.271(2) 0.110(7) Uani 0.50 1 d PDU A 2 C1 C 0.7201(10) 0.4849(14) 0.4451(13) 0.047(4) Uani 1 1 d . . . C2 C 0.7367(12) 0.6181(13) 0.4550(15) 0.053(5) Uani 1 1 d . . . C3 C 0.6734(19) 0.682(2) 0.512(3) 0.125(11) Uani 1 1 d . . . H3A H 0.6998 0.7281 0.5803 0.188 Uiso 1 1 calc R . . H3B H 0.6383 0.6236 0.5393 0.188 Uiso 1 1 calc R . . H3C H 0.6418 0.7338 0.4537 0.188 Uiso 1 1 calc R . . C4 C 0.735(2) 0.670(2) 0.329(2) 0.140(13) Uani 1 1 d . . . H4A H 0.7684 0.6220 0.2871 0.210 Uiso 1 1 calc R . . H4B H 0.7546 0.7506 0.3361 0.210 Uiso 1 1 calc R . . H4C H 0.6799 0.6690 0.2850 0.210 Uiso 1 1 calc R . . C5 C 0.8153(15) 0.636(2) 0.531(2) 0.109(9) Uani 1 1 d . . . H5A H 0.8269 0.7201 0.5381 0.163 Uiso 1 1 calc R . . H5B H 0.8561 0.5967 0.4948 0.163 Uiso 1 1 calc R . . H5C H 0.8151 0.6026 0.6096 0.163 Uiso 1 1 calc R . . C6 C 0.8531(12) 0.1556(15) 0.6253(14) 0.050(4) Uani 1 1 d . . . C7 C 0.9391(13) 0.175(2) 0.697(2) 0.062(6) Uani 1 1 d . . . C8 C 0.9599(16) 0.313(3) 0.712(3) 0.110(11) Uani 1 1 d . . . H8A H 0.9563 0.3486 0.6334 0.165 Uiso 1 1 calc R . . H8B H 1.0139 0.3221 0.7572 0.165 Uiso 1 1 calc R . . H8C H 0.9220 0.3509 0.7543 0.165 Uiso 1 1 calc R . . C9 C 0.9438(13) 0.116(3) 0.8158(18) 0.101(9) Uani 1 1 d . . . H9A H 0.8999 0.1430 0.8531 0.152 Uiso 1 1 calc R . . H9B H 0.9946 0.1353 0.8670 0.152 Uiso 1 1 calc R . . H9C H 0.9401 0.0305 0.8046 0.152 Uiso 1 1 calc R . . C10 C 1.0003(14) 0.114(2) 0.623(2) 0.088(7) Uani 1 1 d . . . H10A H 1.0519 0.1029 0.6754 0.131 Uiso 1 1 calc R . . H10B H 1.0069 0.1646 0.5563 0.131 Uiso 1 1 calc R . . H10C H 0.9791 0.0378 0.5929 0.131 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt1 0.0461(8) 0.0365(7) 0.0283(7) 0.00117(18) 0.0107(4) 0.0008(2) Ag2 0.126(2) 0.0456(10) 0.0402(10) -0.0013(6) 0.0360(10) 0.0071(8) Cl1 0.103(5) 0.070(3) 0.053(3) 0.003(2) 0.027(3) -0.009(3) N1 0.074(12) 0.039(8) 0.043(8) -0.004(6) 0.019(8) -0.001(7) N2 0.054(13) 0.026(10) 0.072(15) 0.002(5) 0.016(10) -0.006(6) N3 0.085(13) 0.037(9) 0.045(8) -0.002(6) 0.016(8) 0.004(7) N4 0.047(12) 0.055(10) 0.060(12) 0.004(7) 0.018(9) 0.016(7) O1 0.139(14) 0.042(8) 0.043(7) 0.002(5) 0.056(8) -0.005(7) O2 0.062(10) 0.045(8) 0.098(9) -0.011(6) 0.008(7) 0.014(6) O3 0.135(16) 0.071(11) 0.077(10) 0.014(8) 0.010(10) 0.007(10) O4 0.141(16) 0.126(15) 0.083(14) -0.036(13) -0.016(13) -0.017(14) O5 0.142(15) 0.123(15) 0.089(14) -0.023(13) 0.035(13) 0.003(14) O6 0.158(15) 0.127(15) 0.067(12) -0.010(12) 0.022(12) -0.023(14) O7 0.162(16) 0.110(15) 0.101(14) -0.012(13) 0.033(14) -0.003(15) O4' 0.135(16) 0.131(15) 0.093(14) -0.023(13) 0.006(14) -0.007(14) O5' 0.154(16) 0.118(15) 0.113(14) -0.025(13) 0.027(13) -0.010(14) O6' 0.154(15) 0.127(15) 0.058(12) -0.025(12) 0.028(12) -0.019(14) O7' 0.149(16) 0.119(15) 0.066(13) -0.020(12) 0.028(13) -0.038(14) C1 0.052(12) 0.045(10) 0.043(9) 0.013(7) 0.008(8) 0.003(8) C2 0.080(15) 0.018(9) 0.067(11) 0.002(7) 0.030(10) -0.005(8) C3 0.20(3) 0.046(16) 0.16(2) -0.014(14) 0.11(2) -0.016(16) C4 0.32(4) 0.028(13) 0.086(16) 0.009(10) 0.06(2) -0.022(18) C5 0.10(2) 0.066(16) 0.15(2) 0.020(15) -0.008(18) -0.036(14) C6 0.060(14) 0.042(11) 0.049(10) -0.007(7) 0.010(9) 0.012(9) C7 0.048(14) 0.059(13) 0.080(15) -0.006(10) 0.011(11) 0.023(10) C8 0.057(19) 0.11(2) 0.15(3) 0.00(2) -0.022(17) -0.037(16) C9 0.049(17) 0.18(3) 0.071(15) 0.008(15) -0.007(12) 0.027(15) C10 0.089(19) 0.077(16) 0.100(16) -0.005(12) 0.025(14) 0.011(13) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt1 N1 2.004(14) . ? Pt1 N2 2.04(2) . ? Pt1 N3 2.066(14) . ? Pt1 N4 2.10(2) . ? Pt1 Ag2 2.888(3) . ? Pt1 Ag2 2.972(3) 4_566 ? Ag2 O1 2.197(12) . ? Ag2 O3 2.306(16) . ? Ag2 Pt1 2.972(3) 4_565 ? Cl1 O6 1.381(14) . ? Cl1 O4 1.383(14) . ? Cl1 O4' 1.392(15) . ? Cl1 O5' 1.397(14) . ? Cl1 O6' 1.426(14) . ? Cl1 O5 1.432(15) . ? Cl1 O7 1.453(15) . ? Cl1 O7' 1.455(15) . ? N1 C1 1.36(2) . ? N2 C6 1.33(2) . ? O1 C1 1.248(18) . ? O2 C6 1.26(2) . ? C1 C2 1.51(2) . ? C2 C5 1.44(3) . ? C2 C3 1.51(3) . ? C2 C4 1.52(2) . ? C6 C7 1.53(3) . ? C7 C9 1.48(3) . ? C7 C8 1.57(4) . ? C7 C10 1.58(3) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N1 Pt1 N2 86.9(5) . . ? N1 Pt1 N3 177.4(4) . . ? N2 Pt1 N3 92.6(5) . . ? N1 Pt1 N4 90.5(6) . . ? N2 Pt1 N4 177.0(5) . . ? N3 Pt1 N4 90.0(6) . . ? N1 Pt1 Ag2 84.1(4) . . ? N2 Pt1 Ag2 79.6(6) . . ? N3 Pt1 Ag2 98.3(4) . . ? N4 Pt1 Ag2 101.5(6) . . ? N1 Pt1 Ag2 93.8(4) . 4_566 ? N2 Pt1 Ag2 68.0(6) . 4_566 ? N3 Pt1 Ag2 83.7(4) . 4_566 ? N4 Pt1 Ag2 110.9(6) . 4_566 ? Ag2 Pt1 Ag2 147.54(10) . 4_566 ? O1 Ag2 O3 155.4(7) . . ? O1 Ag2 Pt1 78.6(3) . . ? O3 Ag2 Pt1 100.6(4) . . ? O1 Ag2 Pt1 94.8(3) . 4_565 ? O3 Ag2 Pt1 98.5(4) . 4_565 ? Pt1 Ag2 Pt1 146.44(10) . 4_565 ? O6 Cl1 O4 114.3(15) . . ? O6 Cl1 O4' 79.9(17) . . ? O4 Cl1 O4' 144.7(18) . . ? O6 Cl1 O5' 61.0(16) . . ? O4 Cl1 O5' 102.4(19) . . ? O4' Cl1 O5' 112.5(13) . . ? O6 Cl1 O6' 168.9(17) . . ? O4 Cl1 O6' 59.2(15) . . ? O4' Cl1 O6' 110.6(13) . . ? O5' Cl1 O6' 110.2(14) . . ? O6 Cl1 O5 108.7(14) . . ? O4 Cl1 O5 110.8(13) . . ? O4' Cl1 O5 35.8(13) . . ? O5' Cl1 O5 146.2(18) . . ? O6' Cl1 O5 82.4(15) . . ? O6 Cl1 O7 107.9(13) . . ? O4 Cl1 O7 109.2(14) . . ? O4' Cl1 O7 95.2(18) . . ? O5' Cl1 O7 55.5(16) . . ? O6' Cl1 O7 68.6(14) . . ? O5 Cl1 O7 105.5(13) . . ? O6 Cl1 O7' 75.1(14) . . ? O4 Cl1 O7' 49.9(15) . . ? O4' Cl1 O7' 110.3(14) . . ? O5' Cl1 O7' 109.4(13) . . ? O6' Cl1 O7' 103.4(12) . . ? O5 Cl1 O7' 97.1(18) . . ? O7 Cl1 O7' 154.3(17) . . ? C1 N1 Pt1 128.5(11) . . ? C6 N2 Pt1 131.1(13) . . ? C1 O1 Ag2 128.8(10) . . ? O1 C1 N1 119.6(15) . . ? O1 C1 C2 121.1(13) . . ? N1 C1 C2 119.2(14) . . ? C5 C2 C1 108.3(16) . . ? C5 C2 C3 109(2) . . ? C1 C2 C3 110.9(15) . . ? C5 C2 C4 111(2) . . ? C1 C2 C4 109.4(14) . . ? C3 C2 C4 108.6(19) . . ? O2 C6 N2 123.5(18) . . ? O2 C6 C7 117.9(16) . . ? N2 C6 C7 118.4(16) . . ? C9 C7 C6 107.3(18) . . ? C9 C7 C8 111(2) . . ? C6 C7 C8 111.3(17) . . ? C9 C7 C10 110.2(17) . . ? C6 C7 C10 107.6(17) . . ? C8 C7 C10 108.9(17) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N1 Pt1 Ag2 O1 2.4(6) . . . . ? N2 Pt1 Ag2 O1 -85.5(5) . . . . ? N3 Pt1 Ag2 O1 -176.6(6) . . . . ? N4 Pt1 Ag2 O1 91.7(6) . . . . ? Ag2 Pt1 Ag2 O1 -85.3(4) 4_566 . . . ? N1 Pt1 Ag2 O3 157.3(6) . . . . ? N2 Pt1 Ag2 O3 69.4(6) . . . . ? N3 Pt1 Ag2 O3 -21.7(6) . . . . ? N4 Pt1 Ag2 O3 -113.4(6) . . . . ? Ag2 Pt1 Ag2 O3 69.6(5) 4_566 . . . ? N1 Pt1 Ag2 Pt1 -79.0(4) . . . 4_565 ? N2 Pt1 Ag2 Pt1 -167.0(3) . . . 4_565 ? N3 Pt1 Ag2 Pt1 101.9(4) . . . 4_565 ? N4 Pt1 Ag2 Pt1 10.2(4) . . . 4_565 ? Ag2 Pt1 Ag2 Pt1 -166.72(12) 4_566 . . 4_565 ? N2 Pt1 N1 C1 73.7(16) . . . . ? N3 Pt1 N1 C1 152(12) . . . . ? N4 Pt1 N1 C1 -107.6(15) . . . . ? Ag2 Pt1 N1 C1 -6.1(14) . . . . ? Ag2 Pt1 N1 C1 141.4(14) 4_566 . . . ? N1 Pt1 N2 C6 -163(2) . . . . ? N3 Pt1 N2 C6 20(2) . . . . ? N4 Pt1 N2 C6 170(12) . . . . ? Ag2 Pt1 N2 C6 -78(2) . . . . ? Ag2 Pt1 N2 C6 102(2) 4_566 . . . ? O3 Ag2 O1 C1 -90.9(18) . . . . ? Pt1 Ag2 O1 C1 -0.2(15) . . . . ? Pt1 Ag2 O1 C1 146.6(16) 4_565 . . . ? Ag2 O1 C1 N1 -4(2) . . . . ? Ag2 O1 C1 C2 173.8(13) . . . . ? Pt1 N1 C1 O1 8(2) . . . . ? Pt1 N1 C1 C2 -170.0(12) . . . . ? O1 C1 C2 C5 -95(2) . . . . ? N1 C1 C2 C5 82(2) . . . . ? O1 C1 C2 C3 145(2) . . . . ? N1 C1 C2 C3 -37(2) . . . . ? O1 C1 C2 C4 26(3) . . . . ? N1 C1 C2 C4 -156.8(19) . . . . ? Pt1 N2 C6 O2 10(3) . . . . ? Pt1 N2 C6 C7 -165.1(16) . . . . ? O2 C6 C7 C9 -70(2) . . . . ? N2 C6 C7 C9 105(2) . . . . ? O2 C6 C7 C8 167.5(18) . . . . ? N2 C6 C7 C8 -17(2) . . . . ? O2 C6 C7 C10 48(2) . . . . ? N2 C6 C7 C10 -136.7(19) . . . . ? _diffrn_measured_fraction_theta_max 0.818 _diffrn_reflns_theta_full 23.75 _diffrn_measured_fraction_theta_full 0.818 _refine_diff_density_max 5.628 _refine_diff_density_min -2.221 _refine_diff_density_rms 0.358 #===END data_l228 _database_code_depnum_ccdc_archive 'CCDC 286688' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C28 H60 Ag2 N8 O10 Pt2' _chemical_formula_weight 1274.76 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Monoclinic _symmetry_space_group_name_H-M P2(1)/c loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 24.233(4) _cell_length_b 11.1380(19) _cell_length_c 15.983(3) _cell_angle_alpha 90.00 _cell_angle_beta 94.223(3) _cell_angle_gamma 90.00 _cell_volume 4302.1(13) _cell_formula_units_Z 4 _cell_measurement_temperature 120(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description prism _exptl_crystal_colour colorless _exptl_crystal_size_max 0.52 _exptl_crystal_size_mid 0.49 _exptl_crystal_size_min 0.47 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.968 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2456 _exptl_absorpt_coefficient_mu 7.435 _exptl_absorpt_correction_type none _exptl_absorpt_correction_T_min 0.1130 _exptl_absorpt_correction_T_max 0.1279 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 120(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 20991 _diffrn_reflns_av_R_equivalents 0.0348 _diffrn_reflns_av_sigmaI/netI 0.0446 _diffrn_reflns_limit_h_min -26 _diffrn_reflns_limit_h_max 28 _diffrn_reflns_limit_k_min -13 _diffrn_reflns_limit_k_max 11 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_theta_min 0.84 _diffrn_reflns_theta_max 25.01 _reflns_number_total 7571 _reflns_number_gt 4943 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0246P)^2^+272.8788P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 7571 _refine_ls_number_parameters 451 _refine_ls_number_restraints 126 _refine_ls_R_factor_all 0.1036 _refine_ls_R_factor_gt 0.0738 _refine_ls_wR_factor_ref 0.1813 _refine_ls_wR_factor_gt 0.1677 _refine_ls_goodness_of_fit_ref 1.184 _refine_ls_restrained_S_all 1.178 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Pt1 Pt 0.50146(3) 0.13161(5) 0.75729(4) 0.01172(17) Uani 1 1 d . . . Pt2 Pt 1.00090(3) 0.63937(6) 0.75723(5) 0.0232(2) Uani 1 1 d . . . Ag1 Ag 0.51074(5) 0.38299(11) 0.75261(8) 0.0179(3) Uani 1 1 d . . . Ag2 Ag 0.98909(5) 0.39165(11) 0.74792(10) 0.0221(3) Uani 1 1 d . . . N1 N 0.5362(6) 0.1152(15) 0.6481(9) 0.023(4) Uani 1 1 d . . . H1 H 0.5082 0.1265 0.6068 0.028 Uiso 1 1 d R . . N2 N 0.4246(6) 0.6082(14) 0.6804(9) 0.021(3) Uani 1 1 d . . . H2 H 0.3988 0.6306 0.7169 0.026 Uiso 1 1 d R . . N3 N 0.4665(6) 0.1559(13) 0.8693(9) 0.020(3) Uani 1 1 d . . . H3D H 0.4528 0.2318 0.8716 0.030 Uiso 1 1 calc R . . H3E H 0.4926 0.1446 0.9124 0.030 Uiso 1 1 calc R . . H3F H 0.4386 0.1021 0.8734 0.030 Uiso 1 1 calc R . . N4 N 0.4248(6) 0.1621(15) 0.6918(9) 0.024(3) Uani 1 1 d . . . H4D H 0.4253 0.2344 0.6654 0.036 Uiso 1 1 calc R . . H4E H 0.3977 0.1621 0.7285 0.036 Uiso 1 1 calc R . . H4F H 0.4179 0.1030 0.6532 0.036 Uiso 1 1 calc R . . N5 N 1.0367(7) 0.6136(13) 0.6485(10) 0.024(3) Uani 1 1 d U . . H5 H 1.0606 0.6773 0.6446 0.029 Uiso 1 1 d R . . N6 N 1.0743(6) 0.6089(14) 0.8198(10) 0.025(4) Uani 1 1 d . . . H6 H 1.0967 0.6710 0.8261 0.029 Uiso 1 1 calc R . . N7 N 0.9262(6) 0.6699(15) 0.6912(10) 0.029(4) Uani 1 1 d . . . H7A H 0.9254 0.6307 0.6412 0.043 Uiso 1 1 calc R . . H7B H 0.9219 0.7501 0.6820 0.043 Uiso 1 1 calc R . . H7C H 0.8983 0.6425 0.7213 0.043 Uiso 1 1 calc R . . N8 N 0.9671(7) 0.6643(15) 0.8701(10) 0.028(4) Uani 1 1 d . . . H8D H 0.9941 0.6578 0.9126 0.042 Uiso 1 1 calc R . . H8E H 0.9407 0.6075 0.8765 0.042 Uiso 1 1 calc R . . H8F H 0.9515 0.7385 0.8713 0.042 Uiso 1 1 calc R . . O1 O 0.4358(5) 0.4135(12) 0.6426(7) 0.022(3) Uani 1 1 d . . . O2 O 0.5611(5) -0.0802(12) 0.6577(7) 0.026(3) Uani 1 1 d . . . O3 O 1.0609(5) 0.4157(13) 0.6592(8) 0.030(3) Uani 1 1 d . . . O4 O 1.0646(5) 0.4109(12) 0.8568(8) 0.024(3) Uani 1 1 d . . . O5 O 0.6026(5) 0.3709(11) 0.7723(7) 0.020(3) Uani 1 1 d . . . O6 O 0.6117(5) 0.4520(14) 0.6449(8) 0.030(3) Uani 1 1 d . . . O7 O 0.8973(6) 0.3734(14) 0.7276(9) 0.039(4) Uani 1 1 d . . . O8 O 0.8885(6) 0.4496(17) 0.8547(9) 0.043(4) Uani 1 1 d . . . O9 O 0.9781(6) 0.3575(14) 0.9565(9) 0.040(4) Uani 1 1 d . . . O10 O 0.4773(5) 0.6376(12) 0.4560(8) 0.027(3) Uani 1 1 d . . . C1 C 0.5648(7) 0.0200(14) 0.6245(11) 0.016(3) Uani 1 1 d . . . C2 C 0.6025(7) 0.0333(16) 0.5521(10) 0.017(3) Uani 1 1 d . . . C3 C 0.5699(8) 0.087(2) 0.4735(11) 0.030(4) Uani 1 1 d . . . H3A H 0.5932 0.0860 0.4260 0.046 Uiso 1 1 calc R . . H3B H 0.5594 0.1701 0.4852 0.046 Uiso 1 1 calc R . . H3C H 0.5365 0.0394 0.4598 0.046 Uiso 1 1 calc R . . C4 C 0.6254(11) -0.085(3) 0.5294(16) 0.054(7) Uani 1 1 d . . . H4A H 0.6470 -0.1189 0.5781 0.081 Uiso 1 1 calc R . . H4B H 0.6492 -0.0752 0.4830 0.081 Uiso 1 1 calc R . . H4C H 0.5949 -0.1399 0.5123 0.081 Uiso 1 1 calc R . . C5 C 0.6499(7) 0.124(2) 0.5804(13) 0.035(5) Uani 1 1 d . . . H5A H 0.6695 0.0950 0.6324 0.052 Uiso 1 1 calc R . . H5B H 0.6340 0.2029 0.5900 0.052 Uiso 1 1 calc R . . H5C H 0.6759 0.1297 0.5364 0.052 Uiso 1 1 calc R . . C6 C 0.4063(8) 0.5076(16) 0.6466(11) 0.021(4) Uani 1 1 d U . . C7 C 0.3449(8) 0.5002(18) 0.6131(13) 0.029(4) Uani 1 1 d U . . C8 C 0.3116(10) 0.471(3) 0.6811(16) 0.064(6) Uani 1 1 d U . . H8A H 0.2772 0.4325 0.6589 0.096 Uiso 1 1 calc R . . H8B H 0.3029 0.5445 0.7110 0.096 Uiso 1 1 calc R . . H8C H 0.3321 0.4159 0.7198 0.096 Uiso 1 1 calc R . . C9 C 0.3224(10) 0.619(2) 0.5821(19) 0.058(6) Uani 1 1 d U . . H9A H 0.2850 0.6081 0.5552 0.087 Uiso 1 1 calc R . . H9B H 0.3465 0.6526 0.5413 0.087 Uiso 1 1 calc R . . H9C H 0.3209 0.6746 0.6295 0.087 Uiso 1 1 calc R . . C10 C 0.3385(10) 0.412(3) 0.5398(16) 0.051(6) Uani 1 1 d U . . H10A H 0.3586 0.3376 0.5550 0.077 Uiso 1 1 calc R . . H10B H 0.3537 0.4476 0.4904 0.077 Uiso 1 1 calc R . . H10C H 0.2992 0.3937 0.5270 0.077 Uiso 1 1 calc R . . C11 C 1.0646(7) 0.5186(19) 0.6242(11) 0.025(4) Uani 1 1 d . . . C12 C 1.1020(8) 0.537(2) 0.5503(12) 0.030(4) Uani 1 1 d . . . C13 C 1.0699(9) 0.583(2) 0.4732(12) 0.036(5) Uani 1 1 d . . . H13A H 1.0422 0.5234 0.4535 0.054 Uiso 1 1 calc R . . H13B H 1.0952 0.5978 0.4292 0.054 Uiso 1 1 calc R . . H13C H 1.0514 0.6581 0.4865 0.054 Uiso 1 1 calc R . . C14 C 1.1285(11) 0.412(2) 0.5318(15) 0.049(6) Uani 1 1 d . . . H14A H 1.1496 0.3831 0.5824 0.073 Uiso 1 1 calc R . . H14B H 1.1533 0.4211 0.4864 0.073 Uiso 1 1 calc R . . H14C H 1.0992 0.3547 0.5149 0.073 Uiso 1 1 calc R . . C15 C 1.1485(10) 0.621(2) 0.5789(15) 0.047(6) Uani 1 1 d . . . H15A H 1.1331 0.6991 0.5937 0.071 Uiso 1 1 calc R . . H15B H 1.1731 0.6322 0.5334 0.071 Uiso 1 1 calc R . . H15C H 1.1696 0.5873 0.6280 0.071 Uiso 1 1 calc R . . C16 C 1.0931(8) 0.507(2) 0.8527(13) 0.032(4) Uani 1 1 d U . . C17 C 1.1548(8) 0.500(2) 0.8895(13) 0.034(4) Uani 1 1 d U . . C18 C 1.1613(10) 0.409(3) 0.9589(16) 0.053(6) Uani 1 1 d U . . H18A H 1.2002 0.4057 0.9805 0.079 Uiso 1 1 calc R . . H18B H 1.1497 0.3302 0.9372 0.079 Uiso 1 1 calc R . . H18C H 1.1384 0.4324 1.0042 0.079 Uiso 1 1 calc R . . C19 C 1.1740(13) 0.621(3) 0.927(2) 0.074(7) Uani 1 1 d U . . H19A H 1.1754 0.6807 0.8820 0.111 Uiso 1 1 calc R . . H19B H 1.2109 0.6121 0.9557 0.111 Uiso 1 1 calc R . . H19C H 1.1480 0.6481 0.9671 0.111 Uiso 1 1 calc R . . C20 C 1.1865(10) 0.438(3) 0.8165(18) 0.066(7) Uani 1 1 d U . . H20A H 1.1729 0.4714 0.7621 0.100 Uiso 1 1 calc R . . H20B H 1.1798 0.3513 0.8169 0.100 Uiso 1 1 calc R . . H20C H 1.2263 0.4534 0.8259 0.100 Uiso 1 1 calc R . . C21 C 0.6313(8) 0.4113(18) 0.7146(11) 0.027(4) Uani 1 1 d . . . C22 C 0.6932(7) 0.4132(17) 0.7333(11) 0.021(4) Uani 1 1 d . . . C23 C 0.7276(8) 0.412(2) 0.6680(12) 0.031(5) Uani 1 1 d . . . H23 H 0.7124 0.4138 0.6115 0.037 Uiso 1 1 calc R . . C24 C 0.7844(8) 0.408(2) 0.6857(12) 0.031(5) Uani 1 1 d . . . H24 H 0.8077 0.4045 0.6405 0.037 Uiso 1 1 calc R . . C25 C 0.8081(7) 0.4094(17) 0.7671(12) 0.024(4) Uani 1 1 d . . . C26 C 0.8697(7) 0.4106(17) 0.7854(10) 0.020(4) Uani 1 1 d . . . C27 C 0.7727(8) 0.414(2) 0.8320(12) 0.033(5) Uani 1 1 d . . . H27 H 0.7878 0.4181 0.8885 0.039 Uiso 1 1 calc R . . C28 C 0.7155(7) 0.4120(19) 0.8154(12) 0.027(4) Uani 1 1 d . . . H28 H 0.6919 0.4098 0.8603 0.032 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt1 0.0112(3) 0.0121(3) 0.0119(3) 0.0035(3) 0.0010(2) -0.0047(2) Pt2 0.0239(4) 0.0240(4) 0.0220(4) -0.0074(3) 0.0040(3) 0.0005(3) Ag1 0.0183(7) 0.0183(6) 0.0173(6) 0.0010(5) 0.0037(5) 0.0071(5) Ag2 0.0169(7) 0.0181(7) 0.0320(8) 0.0012(6) 0.0066(6) 0.0022(5) N1 0.013(7) 0.044(10) 0.012(7) 0.009(6) -0.003(6) 0.000(7) N2 0.013(7) 0.034(10) 0.018(7) -0.012(6) 0.007(6) 0.004(6) N3 0.021(8) 0.022(8) 0.017(7) 0.013(6) 0.007(6) 0.000(6) N4 0.026(9) 0.026(9) 0.020(8) 0.000(6) 0.007(6) -0.010(6) N5 0.030(7) 0.015(6) 0.027(7) -0.010(5) 0.006(6) 0.002(5) N6 0.020(8) 0.028(10) 0.026(8) -0.014(7) 0.002(6) -0.001(6) N7 0.023(9) 0.027(9) 0.034(9) 0.004(7) -0.006(7) -0.009(7) N8 0.033(9) 0.031(9) 0.021(8) -0.017(7) 0.009(7) -0.009(7) O1 0.017(6) 0.028(7) 0.020(6) 0.002(5) -0.002(5) 0.002(5) O2 0.030(7) 0.029(7) 0.019(6) -0.003(6) -0.003(5) -0.001(6) O3 0.032(7) 0.029(8) 0.029(7) 0.012(6) 0.009(6) 0.000(6) O4 0.022(6) 0.023(7) 0.027(7) 0.005(5) 0.002(5) -0.010(5) O5 0.011(6) 0.027(7) 0.021(6) 0.001(5) 0.003(5) -0.006(5) O6 0.011(6) 0.053(10) 0.026(7) 0.004(6) 0.000(5) 0.001(6) O7 0.023(7) 0.058(10) 0.035(8) 0.004(7) 0.001(6) 0.002(7) O8 0.026(8) 0.080(13) 0.025(8) -0.008(8) 0.003(6) -0.009(8) O9 0.033(8) 0.055(10) 0.033(8) -0.003(7) 0.003(6) -0.008(7) O10 0.024(7) 0.039(8) 0.019(6) -0.003(6) 0.008(5) 0.004(6) C1 0.009(8) 0.010(8) 0.027(9) 0.001(7) -0.007(7) -0.005(6) C2 0.018(9) 0.018(9) 0.016(8) -0.002(7) 0.006(7) -0.001(7) C3 0.031(10) 0.045(13) 0.015(9) 0.008(8) 0.003(8) -0.007(9) C4 0.059(16) 0.061(17) 0.046(14) 0.025(13) 0.029(12) 0.025(13) C5 0.014(9) 0.061(15) 0.030(11) 0.004(10) 0.004(8) -0.004(9) C6 0.021(8) 0.030(9) 0.012(7) 0.002(6) -0.006(7) 0.006(7) C7 0.018(8) 0.038(10) 0.029(9) -0.005(7) -0.005(7) -0.004(7) C8 0.028(11) 0.119(17) 0.043(12) 0.002(12) -0.001(10) -0.015(12) C9 0.036(11) 0.044(12) 0.088(14) -0.016(11) -0.042(11) 0.003(10) C10 0.035(11) 0.066(13) 0.050(12) -0.015(11) -0.016(10) 0.009(10) C11 0.013(9) 0.052(13) 0.009(8) -0.010(8) -0.002(7) 0.000(8) C12 0.016(9) 0.048(13) 0.026(10) 0.000(9) 0.005(8) 0.001(8) C13 0.037(12) 0.045(13) 0.027(10) -0.006(10) 0.009(9) 0.006(10) C14 0.058(16) 0.049(15) 0.043(13) -0.012(11) 0.030(12) 0.006(12) C15 0.039(13) 0.070(18) 0.035(12) -0.003(11) 0.012(10) -0.016(12) C16 0.017(9) 0.053(11) 0.028(9) 0.006(8) 0.004(7) 0.006(8) C17 0.017(9) 0.058(12) 0.027(9) 0.000(8) -0.004(8) 0.001(8) C18 0.037(11) 0.065(14) 0.054(12) 0.022(11) -0.017(10) -0.006(10) C19 0.052(13) 0.080(16) 0.087(16) 0.006(13) -0.025(12) -0.017(12) C20 0.031(11) 0.108(17) 0.060(13) -0.001(13) 0.004(11) 0.013(12) C21 0.026(10) 0.032(11) 0.022(10) -0.006(8) -0.001(8) 0.004(8) C22 0.017(9) 0.023(9) 0.022(9) 0.003(7) 0.002(7) -0.006(7) C23 0.026(10) 0.051(13) 0.017(9) -0.006(9) 0.002(8) 0.000(9) C24 0.030(11) 0.047(13) 0.018(9) -0.004(9) 0.014(8) -0.002(9) C25 0.019(9) 0.023(10) 0.029(10) 0.006(8) 0.003(7) -0.002(7) C26 0.017(9) 0.027(10) 0.016(9) 0.010(7) 0.000(7) -0.001(7) C27 0.018(9) 0.062(14) 0.018(9) -0.007(9) 0.002(7) -0.009(9) C28 0.016(9) 0.040(12) 0.025(10) -0.006(8) 0.003(7) -0.004(8) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt1 N1 2.001(15) . ? Pt1 N2 2.002(14) 2_646 ? Pt1 N3 2.054(14) . ? Pt1 N4 2.092(16) . ? Pt1 Ag1 2.7881(15) 2_646 ? Pt1 Ag1 2.8104(15) . ? Pt2 N6 2.005(15) . ? Pt2 N5 2.020(15) . ? Pt2 N8 2.054(14) . ? Pt2 N7 2.055(15) . ? Pt2 Ag2 2.7768(15) . ? Pt2 Ag2 2.8220(15) 2_756 ? Ag1 O5 2.229(11) . ? Ag1 O2 2.371(13) 2_656 ? Ag1 O1 2.456(11) . ? Ag1 Pt1 2.7881(15) 2_656 ? Ag2 O7 2.234(14) . ? Ag2 O3 2.339(13) . ? Ag2 O4 2.440(12) . ? Ag2 Pt2 2.8220(15) 2_746 ? N1 C1 1.34(2) . ? N1 H1 0.9200 . ? N2 C6 1.31(2) . ? N2 Pt1 2.002(14) 2_656 ? N2 H2 0.9200 . ? N3 H3D 0.9100 . ? N3 H3E 0.9100 . ? N3 H3F 0.9100 . ? N4 H4D 0.9100 . ? N4 H4E 0.9100 . ? N4 H4F 0.9100 . ? N5 C11 1.33(2) . ? N5 H5 0.9200 . ? N6 C16 1.32(3) . ? N6 H6 0.8800 . ? N7 H7A 0.9100 . ? N7 H7B 0.9100 . ? N7 H7C 0.9100 . ? N8 H8D 0.9100 . ? N8 H8E 0.9100 . ? N8 H8F 0.9100 . ? O1 C6 1.27(2) . ? O2 C1 1.24(2) . ? O2 Ag1 2.371(13) 2_646 ? O3 C11 1.28(2) . ? O4 C16 1.28(2) . ? O5 C21 1.28(2) . ? O6 C21 1.26(2) . ? O7 C26 1.25(2) . ? O8 C26 1.24(2) . ? C1 C2 1.53(2) . ? C2 C4 1.49(3) . ? C2 C3 1.55(2) . ? C2 C5 1.57(3) . ? C3 H3A 0.9800 . ? C3 H3B 0.9800 . ? C3 H3C 0.9800 . ? C4 H4A 0.9800 . ? C4 H4B 0.9800 . ? C4 H4C 0.9800 . ? C5 H5A 0.9800 . ? C5 H5B 0.9800 . ? C5 H5C 0.9800 . ? C6 C7 1.55(3) . ? C7 C8 1.44(3) . ? C7 C9 1.50(3) . ? C7 C10 1.53(3) . ? C8 H8A 0.9800 . ? C8 H8B 0.9800 . ? C8 H8C 0.9800 . ? C9 H9A 0.9800 . ? C9 H9B 0.9800 . ? C9 H9C 0.9800 . ? C10 H10A 0.9800 . ? C10 H10B 0.9800 . ? C10 H10C 0.9800 . ? C11 C12 1.55(2) . ? C12 C13 1.50(3) . ? C12 C15 1.51(3) . ? C12 C14 1.57(3) . ? C13 H13A 0.9800 . ? C13 H13B 0.9800 . ? C13 H13C 0.9800 . ? C14 H14A 0.9800 . ? C14 H14B 0.9800 . ? C14 H14C 0.9800 . ? C15 H15A 0.9800 . ? C15 H15B 0.9800 . ? C15 H15C 0.9800 . ? C16 C17 1.57(3) . ? C17 C18 1.50(3) . ? C17 C19 1.53(4) . ? C17 C20 1.60(3) . ? C18 H18A 0.9800 . ? C18 H18B 0.9800 . ? C18 H18C 0.9800 . ? C19 H19A 0.9800 . ? C19 H19B 0.9800 . ? C19 H19C 0.9800 . ? C20 H20A 0.9800 . ? C20 H20B 0.9800 . ? C20 H20C 0.9800 . ? C21 C22 1.51(2) . ? C22 C28 1.38(3) . ? C22 C23 1.38(3) . ? C23 C24 1.39(3) . ? C23 H23 0.9500 . ? C24 C25 1.38(3) . ? C24 H24 0.9500 . ? C25 C27 1.39(3) . ? C25 C26 1.50(2) . ? C27 C28 1.39(3) . ? C27 H27 0.9500 . ? C28 H28 0.9500 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N1 Pt1 N2 90.2(6) . 2_646 ? N1 Pt1 N3 177.6(6) . . ? N2 Pt1 N3 89.7(6) 2_646 . ? N1 Pt1 N4 89.7(6) . . ? N2 Pt1 N4 178.1(6) 2_646 . ? N3 Pt1 N4 90.3(6) . . ? N1 Pt1 Ag1 84.8(5) . 2_646 ? N2 Pt1 Ag1 89.2(4) 2_646 2_646 ? N3 Pt1 Ag1 97.6(4) . 2_646 ? N4 Pt1 Ag1 92.6(4) . 2_646 ? N1 Pt1 Ag1 91.6(5) . . ? N2 Pt1 Ag1 94.2(4) 2_646 . ? N3 Pt1 Ag1 86.0(4) . . ? N4 Pt1 Ag1 84.0(4) . . ? Ag1 Pt1 Ag1 175.10(3) 2_646 . ? N6 Pt2 N5 89.1(6) . . ? N6 Pt2 N8 88.9(7) . . ? N5 Pt2 N8 178.0(7) . . ? N6 Pt2 N7 179.0(7) . . ? N5 Pt2 N7 90.0(7) . . ? N8 Pt2 N7 92.0(7) . . ? N6 Pt2 Ag2 86.7(4) . . ? N5 Pt2 Ag2 82.1(4) . . ? N8 Pt2 Ag2 97.8(5) . . ? N7 Pt2 Ag2 93.1(5) . . ? N6 Pt2 Ag2 96.2(5) . 2_756 ? N5 Pt2 Ag2 94.2(4) . 2_756 ? N8 Pt2 Ag2 86.1(5) . 2_756 ? N7 Pt2 Ag2 83.9(5) . 2_756 ? Ag2 Pt2 Ag2 175.23(3) . 2_756 ? O5 Ag1 O2 134.1(4) . 2_656 ? O5 Ag1 O1 141.9(4) . . ? O2 Ag1 O1 82.6(4) 2_656 . ? O5 Ag1 Pt1 99.7(3) . 2_656 ? O2 Ag1 Pt1 77.5(3) 2_656 2_656 ? O1 Ag1 Pt1 75.7(3) . 2_656 ? O5 Ag1 Pt1 91.0(3) . . ? O2 Ag1 Pt1 95.3(3) 2_656 . ? O1 Ag1 Pt1 95.8(3) . . ? Pt1 Ag1 Pt1 169.31(5) 2_656 . ? O7 Ag2 O3 134.4(5) . . ? O7 Ag2 O4 143.0(5) . . ? O3 Ag2 O4 82.5(4) . . ? O7 Ag2 Pt2 101.3(4) . . ? O3 Ag2 Pt2 80.8(4) . . ? O4 Ag2 Pt2 78.8(3) . . ? O7 Ag2 Pt2 89.6(4) . 2_746 ? O3 Ag2 Pt2 91.5(4) . 2_746 ? O4 Ag2 Pt2 92.7(3) . 2_746 ? Pt2 Ag2 Pt2 169.17(5) . 2_746 ? C1 N1 Pt1 125.4(12) . . ? C1 N1 H1 106.1 . . ? Pt1 N1 H1 106.2 . . ? C6 N2 Pt1 125.5(12) . 2_656 ? C6 N2 H2 105.6 . . ? Pt1 N2 H2 105.9 2_656 . ? Pt1 N3 H3D 109.5 . . ? Pt1 N3 H3E 109.5 . . ? H3D N3 H3E 109.5 . . ? Pt1 N3 H3F 109.5 . . ? H3D N3 H3F 109.5 . . ? H3E N3 H3F 109.5 . . ? Pt1 N4 H4D 109.5 . . ? Pt1 N4 H4E 109.5 . . ? H4D N4 H4E 109.5 . . ? Pt1 N4 H4F 109.5 . . ? H4D N4 H4F 109.5 . . ? H4E N4 H4F 109.5 . . ? C11 N5 Pt2 128.7(13) . . ? C11 N5 H5 105.0 . . ? Pt2 N5 H5 105.1 . . ? C16 N6 Pt2 127.8(14) . . ? C16 N6 H6 116.1 . . ? Pt2 N6 H6 116.1 . . ? Pt2 N7 H7A 109.5 . . ? Pt2 N7 H7B 109.5 . . ? H7A N7 H7B 109.5 . . ? Pt2 N7 H7C 109.5 . . ? H7A N7 H7C 109.5 . . ? H7B N7 H7C 109.5 . . ? Pt2 N8 H8D 109.5 . . ? Pt2 N8 H8E 109.5 . . ? H8D N8 H8E 109.5 . . ? Pt2 N8 H8F 109.5 . . ? H8D N8 H8F 109.5 . . ? H8E N8 H8F 109.5 . . ? C6 O1 Ag1 117.8(11) . . ? C1 O2 Ag1 119.6(11) . 2_646 ? C11 O3 Ag2 116.5(11) . . ? C16 O4 Ag2 114.6(12) . . ? C21 O5 Ag1 118.0(11) . . ? C26 O7 Ag2 116.3(12) . . ? O2 C1 N1 122.5(16) . . ? O2 C1 C2 118.4(15) . . ? N1 C1 C2 119.1(14) . . ? C4 C2 C1 110.6(15) . . ? C4 C2 C3 108.8(17) . . ? C1 C2 C3 110.6(14) . . ? C4 C2 C5 111.2(18) . . ? C1 C2 C5 108.0(14) . . ? C3 C2 C5 107.6(15) . . ? C2 C3 H3A 109.5 . . ? C2 C3 H3B 109.5 . . ? H3A C3 H3B 109.5 . . ? C2 C3 H3C 109.5 . . ? H3A C3 H3C 109.5 . . ? H3B C3 H3C 109.5 . . ? C2 C4 H4A 109.5 . . ? C2 C4 H4B 109.5 . . ? H4A C4 H4B 109.5 . . ? C2 C4 H4C 109.5 . . ? H4A C4 H4C 109.5 . . ? H4B C4 H4C 109.5 . . ? C2 C5 H5A 109.5 . . ? C2 C5 H5B 109.5 . . ? H5A C5 H5B 109.5 . . ? C2 C5 H5C 109.5 . . ? H5A C5 H5C 109.5 . . ? H5B C5 H5C 109.5 . . ? O1 C6 N2 123.5(17) . . ? O1 C6 C7 118.0(16) . . ? N2 C6 C7 118.5(16) . . ? C8 C7 C9 104(2) . . ? C8 C7 C10 114(2) . . ? C9 C7 C10 107.6(19) . . ? C8 C7 C6 109.2(18) . . ? C9 C7 C6 112.6(16) . . ? C10 C7 C6 109.8(16) . . ? C7 C8 H8A 109.5 . . ? C7 C8 H8B 109.5 . . ? H8A C8 H8B 109.5 . . ? C7 C8 H8C 109.5 . . ? H8A C8 H8C 109.5 . . ? H8B C8 H8C 109.5 . . ? C7 C9 H9A 109.5 . . ? C7 C9 H9B 109.5 . . ? H9A C9 H9B 109.5 . . ? C7 C9 H9C 109.5 . . ? H9A C9 H9C 109.5 . . ? H9B C9 H9C 109.5 . . ? C7 C10 H10A 109.5 . . ? C7 C10 H10B 109.5 . . ? H10A C10 H10B 109.5 . . ? C7 C10 H10C 109.5 . . ? H10A C10 H10C 109.5 . . ? H10B C10 H10C 109.5 . . ? O3 C11 N5 122.1(16) . . ? O3 C11 C12 120.8(17) . . ? N5 C11 C12 117.1(18) . . ? C13 C12 C15 111.4(19) . . ? C13 C12 C11 111.9(16) . . ? C15 C12 C11 108.4(16) . . ? C13 C12 C14 110.1(18) . . ? C15 C12 C14 107.6(18) . . ? C11 C12 C14 107.4(17) . . ? C12 C13 H13A 109.5 . . ? C12 C13 H13B 109.5 . . ? H13A C13 H13B 109.5 . . ? C12 C13 H13C 109.5 . . ? H13A C13 H13C 109.5 . . ? H13B C13 H13C 109.5 . . ? C12 C14 H14A 109.5 . . ? C12 C14 H14B 109.5 . . ? H14A C14 H14B 109.5 . . ? C12 C14 H14C 109.5 . . ? H14A C14 H14C 109.5 . . ? H14B C14 H14C 109.5 . . ? C12 C15 H15A 109.5 . . ? C12 C15 H15B 109.5 . . ? H15A C15 H15B 109.5 . . ? C12 C15 H15C 109.5 . . ? H15A C15 H15C 109.5 . . ? H15B C15 H15C 109.5 . . ? O4 C16 N6 124.7(18) . . ? O4 C16 C17 116.4(18) . . ? N6 C16 C17 118.9(19) . . ? C18 C17 C19 107(2) . . ? C18 C17 C16 110.8(18) . . ? C19 C17 C16 111.0(19) . . ? C18 C17 C20 102(2) . . ? C19 C17 C20 121(2) . . ? C16 C17 C20 104.1(17) . . ? C17 C18 H18A 109.5 . . ? C17 C18 H18B 109.5 . . ? H18A C18 H18B 109.5 . . ? C17 C18 H18C 109.5 . . ? H18A C18 H18C 109.5 . . ? H18B C18 H18C 109.5 . . ? C17 C19 H19A 109.5 . . ? C17 C19 H19B 109.5 . . ? H19A C19 H19B 109.5 . . ? C17 C19 H19C 109.5 . . ? H19A C19 H19C 109.5 . . ? H19B C19 H19C 109.5 . . ? C17 C20 H20A 109.5 . . ? C17 C20 H20B 109.5 . . ? H20A C20 H20B 109.5 . . ? C17 C20 H20C 109.5 . . ? H20A C20 H20C 109.5 . . ? H20B C20 H20C 109.5 . . ? O6 C21 O5 124.9(17) . . ? O6 C21 C22 118.4(17) . . ? O5 C21 C22 116.7(16) . . ? C28 C22 C23 120.0(17) . . ? C28 C22 C21 120.2(16) . . ? C23 C22 C21 119.8(16) . . ? C22 C23 C24 119.5(17) . . ? C22 C23 H23 120.2 . . ? C24 C23 H23 120.2 . . ? C25 C24 C23 121.9(17) . . ? C25 C24 H24 119.0 . . ? C23 C24 H24 119.0 . . ? C24 C25 C27 117.7(17) . . ? C24 C25 C26 121.5(17) . . ? C27 C25 C26 120.8(16) . . ? O8 C26 O7 126.5(17) . . ? O8 C26 C25 118.0(16) . . ? O7 C26 C25 115.5(16) . . ? C28 C27 C25 121.1(17) . . ? C28 C27 H27 119.5 . . ? C25 C27 H27 119.5 . . ? C22 C28 C27 119.7(17) . . ? C22 C28 H28 120.2 . . ? C27 C28 H28 120.2 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N1 Pt1 Ag1 O5 -68.7(5) . . . . ? N2 Pt1 Ag1 O5 21.6(5) 2_646 . . . ? N3 Pt1 Ag1 O5 111.1(5) . . . . ? N4 Pt1 Ag1 O5 -158.2(5) . . . . ? Ag1 Pt1 Ag1 O5 -111.7(5) 2_646 . . . ? N1 Pt1 Ag1 O2 156.9(5) . . . 2_656 ? N2 Pt1 Ag1 O2 -112.8(5) 2_646 . . 2_656 ? N3 Pt1 Ag1 O2 -23.4(5) . . . 2_656 ? N4 Pt1 Ag1 O2 67.4(5) . . . 2_656 ? Ag1 Pt1 Ag1 O2 113.8(4) 2_646 . . 2_656 ? N1 Pt1 Ag1 O1 73.8(5) . . . . ? N2 Pt1 Ag1 O1 164.1(5) 2_646 . . . ? N3 Pt1 Ag1 O1 -106.5(5) . . . . ? N4 Pt1 Ag1 O1 -15.7(5) . . . . ? Ag1 Pt1 Ag1 O1 30.7(4) 2_646 . . . ? N1 Pt1 Ag1 Pt1 110.0(5) . . . 2_656 ? N2 Pt1 Ag1 Pt1 -159.7(5) 2_646 . . 2_656 ? N3 Pt1 Ag1 Pt1 -70.3(5) . . . 2_656 ? N4 Pt1 Ag1 Pt1 20.5(5) . . . 2_656 ? Ag1 Pt1 Ag1 Pt1 66.9(4) 2_646 . . 2_656 ? N6 Pt2 Ag2 O7 157.8(6) . . . . ? N5 Pt2 Ag2 O7 -112.7(6) . . . . ? N8 Pt2 Ag2 O7 69.3(6) . . . . ? N7 Pt2 Ag2 O7 -23.2(6) . . . . ? Ag2 Pt2 Ag2 O7 -74.3(6) 2_756 . . . ? N6 Pt2 Ag2 O3 -68.6(6) . . . . ? N5 Pt2 Ag2 O3 20.9(6) . . . . ? N8 Pt2 Ag2 O3 -157.1(6) . . . . ? N7 Pt2 Ag2 O3 110.5(6) . . . . ? Ag2 Pt2 Ag2 O3 59.3(5) 2_756 . . . ? N6 Pt2 Ag2 O4 15.5(5) . . . . ? N5 Pt2 Ag2 O4 105.0(5) . . . . ? N8 Pt2 Ag2 O4 -72.9(6) . . . . ? N7 Pt2 Ag2 O4 -165.4(6) . . . . ? Ag2 Pt2 Ag2 O4 143.4(5) 2_756 . . . ? N6 Pt2 Ag2 Pt2 -23.0(5) . . . 2_746 ? N5 Pt2 Ag2 Pt2 66.5(6) . . . 2_746 ? N8 Pt2 Ag2 Pt2 -111.5(6) . . . 2_746 ? N7 Pt2 Ag2 Pt2 156.1(6) . . . 2_746 ? Ag2 Pt2 Ag2 Pt2 104.9(5) 2_756 . . 2_746 ? N2 Pt1 N1 C1 58.3(14) 2_646 . . . ? N3 Pt1 N1 C1 146(14) . . . . ? N4 Pt1 N1 C1 -123.6(14) . . . . ? Ag1 Pt1 N1 C1 -30.9(13) 2_646 . . . ? Ag1 Pt1 N1 C1 152.4(13) . . . . ? N6 Pt2 N5 C11 56.6(16) . . . . ? N8 Pt2 N5 C11 55(19) . . . . ? N7 Pt2 N5 C11 -123.3(16) . . . . ? Ag2 Pt2 N5 C11 -30.2(15) . . . . ? Ag2 Pt2 N5 C11 152.7(15) 2_756 . . . ? N5 Pt2 N6 C16 -95.4(17) . . . . ? N8 Pt2 N6 C16 84.6(17) . . . . ? N7 Pt2 N6 C16 -91(40) . . . . ? Ag2 Pt2 N6 C16 -13.3(16) . . . . ? Ag2 Pt2 N6 C16 170.5(16) 2_756 . . . ? O5 Ag1 O1 C6 -115.5(13) . . . . ? O2 Ag1 O1 C6 50.9(13) 2_656 . . . ? Pt1 Ag1 O1 C6 -28.0(12) 2_656 . . . ? Pt1 Ag1 O1 C6 145.5(12) . . . . ? O7 Ag2 O3 C11 72.4(15) . . . . ? O4 Ag2 O3 C11 -104.2(13) . . . . ? Pt2 Ag2 O3 C11 -24.4(12) . . . . ? Pt2 Ag2 O3 C11 163.3(12) 2_746 . . . ? O7 Ag2 O4 C16 -119.7(14) . . . . ? O3 Ag2 O4 C16 56.2(13) . . . . ? Pt2 Ag2 O4 C16 -25.8(12) . . . . ? Pt2 Ag2 O4 C16 147.4(13) 2_746 . . . ? O2 Ag1 O5 C21 -143.9(12) 2_656 . . . ? O1 Ag1 O5 C21 17.1(16) . . . . ? Pt1 Ag1 O5 C21 -62.0(13) 2_656 . . . ? Pt1 Ag1 O5 C21 117.7(13) . . . . ? O3 Ag2 O7 C26 -151.4(12) . . . . ? O4 Ag2 O7 C26 23.1(19) . . . . ? Pt2 Ag2 O7 C26 -63.2(14) . . . . ? Pt2 Ag2 O7 C26 116.9(14) 2_746 . . . ? Ag1 O2 C1 N1 12(2) 2_646 . . . ? Ag1 O2 C1 C2 -166.1(11) 2_646 . . . ? Pt1 N1 C1 O2 19(2) . . . . ? Pt1 N1 C1 C2 -162.7(12) . . . . ? O2 C1 C2 C4 5(2) . . . . ? N1 C1 C2 C4 -173.5(18) . . . . ? O2 C1 C2 C3 125.4(17) . . . . ? N1 C1 C2 C3 -53(2) . . . . ? O2 C1 C2 C5 -117.1(17) . . . . ? N1 C1 C2 C5 65(2) . . . . ? Ag1 O1 C6 N2 29(2) . . . . ? Ag1 O1 C6 C7 -148.1(13) . . . . ? Pt1 N2 C6 O1 -7(3) 2_656 . . . ? Pt1 N2 C6 C7 170.4(12) 2_656 . . . ? O1 C6 C7 C8 93(2) . . . . ? N2 C6 C7 C8 -84(2) . . . . ? O1 C6 C7 C9 -152(2) . . . . ? N2 C6 C7 C9 31(3) . . . . ? O1 C6 C7 C10 -32(2) . . . . ? N2 C6 C7 C10 150.3(19) . . . . ? Ag2 O3 C11 N5 13(2) . . . . ? Ag2 O3 C11 C12 -166.9(12) . . . . ? Pt2 N5 C11 O3 18(3) . . . . ? Pt2 N5 C11 C12 -162.3(13) . . . . ? O3 C11 C12 C13 122(2) . . . . ? N5 C11 C12 C13 -57(2) . . . . ? O3 C11 C12 C15 -114(2) . . . . ? N5 C11 C12 C15 66(2) . . . . ? O3 C11 C12 C14 2(2) . . . . ? N5 C11 C12 C14 -178.1(17) . . . . ? Ag2 O4 C16 N6 27(2) . . . . ? Ag2 O4 C16 C17 -152.5(13) . . . . ? Pt2 N6 C16 O4 -7(3) . . . . ? Pt2 N6 C16 C17 172.6(13) . . . . ? O4 C16 C17 C18 -29(3) . . . . ? N6 C16 C17 C18 151(2) . . . . ? O4 C16 C17 C19 -148(2) . . . . ? N6 C16 C17 C19 33(3) . . . . ? O4 C16 C17 C20 80(2) . . . . ? N6 C16 C17 C20 -99(2) . . . . ? Ag1 O5 C21 O6 -4(3) . . . . ? Ag1 O5 C21 C22 174.1(12) . . . . ? O6 C21 C22 C28 156.6(19) . . . . ? O5 C21 C22 C28 -22(3) . . . . ? O6 C21 C22 C23 -26(3) . . . . ? O5 C21 C22 C23 156.1(19) . . . . ? C28 C22 C23 C24 1(3) . . . . ? C21 C22 C23 C24 -177.0(19) . . . . ? C22 C23 C24 C25 -2(3) . . . . ? C23 C24 C25 C27 0(3) . . . . ? C23 C24 C25 C26 -177.3(19) . . . . ? Ag2 O7 C26 O8 -5(3) . . . . ? Ag2 O7 C26 C25 173.9(12) . . . . ? C24 C25 C26 O8 157(2) . . . . ? C27 C25 C26 O8 -20(3) . . . . ? C24 C25 C26 O7 -21(3) . . . . ? C27 C25 C26 O7 160.9(19) . . . . ? C24 C25 C27 C28 3(3) . . . . ? C26 C25 C27 C28 -179.6(19) . . . . ? C23 C22 C28 C27 2(3) . . . . ? C21 C22 C28 C27 -180.0(19) . . . . ? C25 C27 C28 C22 -4(3) . . . . ? _diffrn_measured_fraction_theta_max 0.998 _diffrn_reflns_theta_full 25.01 _diffrn_measured_fraction_theta_full 0.998 _refine_diff_density_max 8.028 _refine_diff_density_min -4.101 _refine_diff_density_rms 0.338 #===END data_l479 _database_code_depnum_ccdc_archive 'CCDC 286689' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C32 H66 Ag2 N8 O11 Pt2' _chemical_formula_weight 1344.85 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Monoclinic _symmetry_space_group_name_H-M P2(1)/c loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 20.868(3) _cell_length_b 11.2548(13) _cell_length_c 19.991(2) _cell_angle_alpha 90.00 _cell_angle_beta 98.217(2) _cell_angle_gamma 90.00 _cell_volume 4647.0(9) _cell_formula_units_Z 4 _cell_measurement_temperature 120(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description plate _exptl_crystal_colour colorless _exptl_crystal_size_max 0.48 _exptl_crystal_size_mid 0.43 _exptl_crystal_size_min 0.39 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.922 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2608 _exptl_absorpt_coefficient_mu 6.890 _exptl_absorpt_correction_type none _exptl_absorpt_correction_T_min 0.1366 _exptl_absorpt_correction_T_max 0.1742 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 120(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 26514 _diffrn_reflns_av_R_equivalents 0.0493 _diffrn_reflns_av_sigmaI/netI 0.0750 _diffrn_reflns_limit_h_min -27 _diffrn_reflns_limit_h_max 17 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_k_max 14 _diffrn_reflns_limit_l_min -25 _diffrn_reflns_limit_l_max 24 _diffrn_reflns_theta_min 0.99 _diffrn_reflns_theta_max 27.53 _reflns_number_total 10401 _reflns_number_gt 8990 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0465P)^2^+10.3079P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method SHELXL _refine_ls_extinction_coef 0.00016(3) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_number_reflns 10401 _refine_ls_number_parameters 509 _refine_ls_number_restraints 120 _refine_ls_R_factor_all 0.0473 _refine_ls_R_factor_gt 0.0403 _refine_ls_wR_factor_ref 0.1134 _refine_ls_wR_factor_gt 0.1067 _refine_ls_goodness_of_fit_ref 1.024 _refine_ls_restrained_S_all 1.029 _refine_ls_shift/su_max 0.002 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Pt1 Pt 0.498201(9) 1.230530(19) 0.254481(9) 0.01927(8) Uani 1 1 d . . . Pt2 Pt 1.003972(9) 0.862455(18) 0.252399(10) 0.02208(8) Uani 1 1 d . . . Ag1 Ag 0.492914(19) 0.97947(3) 0.282530(19) 0.02069(10) Uani 1 1 d . . . Ag2 Ag 0.98491(2) 1.11346(3) 0.25090(2) 0.02507(11) Uani 1 1 d . . . N1 N 0.4312(2) 1.1996(4) 0.1738(2) 0.0281(10) Uani 1 1 d . . . H1 H 0.4222 1.2593 0.1456 0.034 Uiso 1 1 calc R . . N2 N 0.4284(2) 0.6989(4) 0.2981(2) 0.0242(9) Uani 1 1 d . . . H2 H 0.4086 0.6300 0.2913 0.029 Uiso 1 1 calc R . . N3 N 0.5605(2) 1.2695(4) 0.3413(2) 0.0275(10) Uani 1 1 d . . . H3D H 0.5906 1.2099 0.3504 0.033 Uiso 1 1 calc R . . H3E H 0.5820 1.3394 0.3358 0.033 Uiso 1 1 calc R . . N4 N 0.4277(2) 1.2713(4) 0.3125(2) 0.0273(10) Uani 1 1 d . . . H4D H 0.3955 1.3153 0.2877 0.033 Uiso 1 1 calc R . . H4E H 0.4096 1.2028 0.3265 0.033 Uiso 1 1 calc R . . N5 N 0.9732(2) 0.8431(4) 0.3429(2) 0.0279(10) Uani 1 1 d . . . N6 N 0.9126(2) 0.8407(4) 0.2059(2) 0.0262(10) Uani 1 1 d . . . H6 H 0.8869 0.8760 0.2340 0.031 Uiso 1 1 d R . . N7 N 1.0419(2) 0.8844(4) 0.1639(3) 0.0278(10) Uani 1 1 d . . . H7A H 1.0445 0.8119 0.1432 0.033 Uiso 1 1 calc R . . H7B H 1.0152 0.9327 0.1351 0.033 Uiso 1 1 calc R . . N8 N 1.0981(2) 0.8943(4) 0.2956(3) 0.0297(11) Uani 1 1 d . . . H8D H 1.1012 0.9690 0.3144 0.036 Uiso 1 1 calc R . . H8E H 1.1103 0.8398 0.3293 0.036 Uiso 1 1 calc R . . O1 O 0.4133(2) 1.0056(3) 0.1911(2) 0.0408(12) Uani 1 1 d . . . O2 O 0.4347(2) 0.8705(3) 0.3573(2) 0.0301(9) Uani 1 1 d . . . O3 O 0.99875(19) 0.6479(3) 0.36338(19) 0.0290(8) Uani 1 1 d . . . O4 O 0.9110(2) 0.6416(3) 0.1878(2) 0.0404(11) Uani 1 1 d . . . O5 O 0.58894(18) 1.0066(3) 0.3561(2) 0.0278(8) Uani 1 1 d . . . O6 O 0.6321(2) 0.9636(3) 0.26339(19) 0.0295(9) Uani 1 1 d . . . O7 O 0.9250(2) 1.1217(4) 0.3447(3) 0.0508(13) Uani 1 1 d . . . O8 O 0.8598(2) 1.0713(4) 0.2514(3) 0.0420(11) Uani 1 1 d . . . O9 O 0.8621(2) 0.1800(3) 0.1216(2) 0.0395(10) Uani 1 1 d . . . O10 O 0.5474(3) 0.8945(5) 0.4643(3) 0.0624(15) Uani 1 1 d . . . O11 O 0.3919(2) 0.0859(3) 0.3999(2) 0.0399(10) Uani 1 1 d . . . C1 C 0.3995(3) 1.1016(4) 0.1586(3) 0.0219(10) Uani 1 1 d U . . C2 C 0.3444(3) 1.0995(5) 0.0989(3) 0.0384(15) Uani 1 1 d U . . C3 C 0.3753(5) 1.0842(10) 0.0339(4) 0.090(3) Uani 1 1 d U . . H3A H 0.3421 1.0939 -0.0056 0.135 Uiso 1 1 calc R . . H3B H 0.3944 1.0047 0.0332 0.135 Uiso 1 1 calc R . . H3C H 0.4092 1.1442 0.0327 0.135 Uiso 1 1 calc R . . C4 C 0.2983(5) 0.9993(9) 0.1061(7) 0.106(4) Uani 1 1 d U . . H4A H 0.2786 1.0108 0.1473 0.159 Uiso 1 1 calc R . . H4B H 0.3219 0.9238 0.1089 0.159 Uiso 1 1 calc R . . H4C H 0.2644 0.9980 0.0668 0.159 Uiso 1 1 calc R . . C5 C 0.3075(4) 1.2146(6) 0.0902(4) 0.063(2) Uani 1 1 d U . . H5A H 0.2694 1.2048 0.0558 0.094 Uiso 1 1 calc R . . H5B H 0.3354 1.2769 0.0759 0.094 Uiso 1 1 calc R . . H5C H 0.2936 1.2372 0.1332 0.094 Uiso 1 1 calc R . . C6 C 0.4072(3) 0.7714(4) 0.3415(3) 0.0213(11) Uani 1 1 d . . . C7 C 0.3480(3) 0.7389(4) 0.3746(3) 0.0231(11) Uani 1 1 d . . . C8 C 0.3595(4) 0.7770(7) 0.4485(4) 0.054(2) Uani 1 1 d . . . H8A H 0.3971 0.7346 0.4721 0.081 Uiso 1 1 calc R . . H8B H 0.3211 0.7581 0.4697 0.081 Uiso 1 1 calc R . . H8C H 0.3675 0.8627 0.4513 0.081 Uiso 1 1 calc R . . C9 C 0.2917(3) 0.8103(8) 0.3375(5) 0.071(3) Uani 1 1 d . . . H9A H 0.3014 0.8953 0.3423 0.106 Uiso 1 1 calc R . . H9B H 0.2522 0.7926 0.3570 0.106 Uiso 1 1 calc R . . H9C H 0.2853 0.7888 0.2895 0.106 Uiso 1 1 calc R . . C10 C 0.3307(4) 0.6074(5) 0.3720(4) 0.050(2) Uani 1 1 d . . . H10A H 0.3250 0.5800 0.3250 0.076 Uiso 1 1 calc R . . H10B H 0.2903 0.5955 0.3909 0.076 Uiso 1 1 calc R . . H10C H 0.3655 0.5621 0.3986 0.076 Uiso 1 1 calc R . . C11 C 0.4580(3) 1.3406(5) 0.3717(3) 0.0375(15) Uani 1 1 d . . . H11A H 0.4295 1.3414 0.4072 0.045 Uiso 1 1 calc R . . H11B H 0.4655 1.4236 0.3584 0.045 Uiso 1 1 calc R . . C12 C 0.5219(3) 1.2810(5) 0.3980(3) 0.0375(15) Uani 1 1 d . . . H12A H 0.5460 1.3292 0.4347 0.045 Uiso 1 1 calc R . . H12B H 0.5139 1.2015 0.4163 0.045 Uiso 1 1 calc R . . C13 C 0.8826(3) 0.7408(4) 0.1862(3) 0.0236(11) Uani 1 1 d . . . C14 C 0.8086(3) 0.7429(4) 0.1615(3) 0.0272(12) Uani 1 1 d . . . C15 C 0.7758(3) 0.7221(6) 0.2239(4) 0.0449(16) Uani 1 1 d . . . H15A H 0.7890 0.7844 0.2573 0.067 Uiso 1 1 calc R . . H15B H 0.7887 0.6443 0.2434 0.067 Uiso 1 1 calc R . . H15C H 0.7287 0.7242 0.2111 0.067 Uiso 1 1 calc R . . C16 C 0.7860(3) 0.8607(5) 0.1274(4) 0.0463(18) Uani 1 1 d . . . H16A H 0.7392 0.8577 0.1127 0.069 Uiso 1 1 calc R . . H16B H 0.8083 0.8736 0.0880 0.069 Uiso 1 1 calc R . . H16C H 0.7961 0.9261 0.1595 0.069 Uiso 1 1 calc R . . C17 C 0.7902(3) 0.6424(6) 0.1099(3) 0.0381(14) Uani 1 1 d . . . H17A H 0.7433 0.6431 0.0956 0.057 Uiso 1 1 calc R . . H17B H 0.8031 0.5657 0.1309 0.057 Uiso 1 1 calc R . . H17C H 0.8125 0.6546 0.0705 0.057 Uiso 1 1 calc R . . C18 C 0.9754(3) 0.7464(4) 0.3797(3) 0.0252(11) Uani 1 1 d U . . C19 C 0.9468(4) 0.7518(5) 0.4464(3) 0.0391(15) Uani 1 1 d U . . C20 C 0.9550(7) 0.6383(9) 0.4848(5) 0.113(4) Uani 1 1 d U . . H20A H 1.0013 0.6221 0.4978 0.169 Uiso 1 1 calc R . . H20B H 0.9352 0.5734 0.4565 0.169 Uiso 1 1 calc R . . H20C H 0.9341 0.6447 0.5255 0.169 Uiso 1 1 calc R . . C21 C 0.8681(5) 0.7504(10) 0.4253(5) 0.085(3) Uani 1 1 d U . . H21A H 0.8558 0.6839 0.3945 0.128 Uiso 1 1 calc R . . H21B H 0.8541 0.8252 0.4027 0.128 Uiso 1 1 calc R . . H21C H 0.8473 0.7412 0.4660 0.128 Uiso 1 1 calc R . . C22 C 0.9604(7) 0.8619(10) 0.4846(6) 0.113(4) Uani 1 1 d U . . H22A H 0.9459 0.8541 0.5289 0.169 Uiso 1 1 calc R . . H22B H 0.9375 0.9279 0.4598 0.169 Uiso 1 1 calc R . . H22C H 1.0071 0.8775 0.4908 0.169 Uiso 1 1 calc R . . C23 C 1.1073(3) 0.9382(5) 0.1783(3) 0.0336(13) Uani 1 1 d . . . H23A H 1.1037 1.0255 0.1826 0.040 Uiso 1 1 calc R . . H23B H 1.1324 0.9208 0.1410 0.040 Uiso 1 1 calc R . . C24 C 1.1409(3) 0.8853(5) 0.2440(3) 0.0326(13) Uani 1 1 d . . . H24A H 1.1516 0.8009 0.2370 0.039 Uiso 1 1 calc R . . H24B H 1.1817 0.9286 0.2590 0.039 Uiso 1 1 calc R . . C25 C 0.6367(2) 0.9963(4) 0.3241(3) 0.0227(10) Uani 1 1 d . . . C26 C 0.7027(3) 1.0331(5) 0.3596(3) 0.0243(11) Uani 1 1 d . . . C27 C 0.7541(3) 1.0423(4) 0.3231(3) 0.0245(11) Uani 1 1 d . . . H27 H 0.7481 1.0218 0.2766 0.029 Uiso 1 1 calc R . . C28 C 0.8147(3) 1.0813(5) 0.3538(3) 0.0297(12) Uani 1 1 d . . . C29 C 0.8703(3) 1.0914(5) 0.3132(4) 0.0401(16) Uani 1 1 d . . . C30 C 0.8223(3) 1.1092(7) 0.4227(4) 0.0510(19) Uani 1 1 d . . . H30 H 0.8630 1.1370 0.4444 0.061 Uiso 1 1 calc R . . C31 C 0.7723(3) 1.0974(8) 0.4593(4) 0.057(2) Uani 1 1 d . . . H31 H 0.7788 1.1149 0.5062 0.069 Uiso 1 1 calc R . . C32 C 0.7118(3) 1.0597(6) 0.4281(3) 0.0367(14) Uani 1 1 d . . . H32 H 0.6769 1.0522 0.4535 0.044 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt1 0.01937(12) 0.01421(12) 0.02325(12) 0.00276(6) -0.00028(9) -0.00080(7) Pt2 0.01671(12) 0.01158(12) 0.03637(14) 0.00130(7) -0.00167(9) -0.00039(7) Ag1 0.02083(19) 0.01371(18) 0.0263(2) 0.00030(13) -0.00069(15) -0.00065(14) Ag2 0.01680(19) 0.01308(19) 0.0443(3) 0.00045(14) 0.00069(17) -0.00067(15) N1 0.028(3) 0.024(2) 0.030(2) 0.0090(19) -0.006(2) -0.0044(19) N2 0.025(2) 0.017(2) 0.030(2) -0.0035(17) 0.0036(19) -0.0055(18) N3 0.024(2) 0.019(2) 0.036(3) -0.0018(18) -0.009(2) 0.0020(18) N4 0.026(3) 0.026(2) 0.029(3) 0.0077(18) 0.002(2) 0.0024(19) N5 0.027(2) 0.016(2) 0.039(3) -0.0021(18) 0.002(2) 0.0011(18) N6 0.014(2) 0.020(2) 0.042(3) -0.0031(19) -0.0036(19) 0.0015(17) N7 0.018(2) 0.026(2) 0.040(3) 0.0064(19) 0.003(2) -0.0004(18) N8 0.020(2) 0.015(2) 0.050(3) 0.0025(19) -0.008(2) -0.0022(17) O1 0.049(3) 0.0147(18) 0.049(3) 0.0000(17) -0.029(2) 0.0004(18) O2 0.030(2) 0.0240(19) 0.038(2) -0.0081(16) 0.0106(18) -0.0080(16) O3 0.033(2) 0.0197(18) 0.033(2) 0.0006(15) 0.0000(17) 0.0012(16) O4 0.024(2) 0.0197(19) 0.071(3) -0.005(2) -0.015(2) 0.0014(17) O5 0.0197(18) 0.031(2) 0.032(2) 0.0046(16) 0.0019(16) -0.0013(16) O6 0.037(2) 0.0248(19) 0.025(2) -0.0014(15) -0.0034(17) -0.0042(17) O7 0.022(2) 0.035(2) 0.097(4) 0.014(2) 0.014(3) -0.0019(19) O8 0.042(3) 0.027(2) 0.064(3) 0.005(2) 0.032(2) 0.0022(19) O9 0.032(2) 0.026(2) 0.057(3) -0.0071(19) -0.004(2) 0.0001(18) O10 0.050(3) 0.090(4) 0.047(3) 0.015(3) 0.008(3) -0.023(3) O11 0.052(3) 0.024(2) 0.047(3) 0.0033(18) 0.018(2) 0.0034(19) C1 0.021(3) 0.022(2) 0.022(2) -0.0029(19) -0.002(2) 0.004(2) C2 0.045(4) 0.030(3) 0.033(3) -0.005(2) -0.021(3) 0.010(3) C3 0.095(7) 0.128(8) 0.037(4) -0.031(5) -0.024(4) 0.052(6) C4 0.077(7) 0.079(6) 0.138(10) 0.047(6) -0.069(7) -0.032(5) C5 0.057(5) 0.047(4) 0.071(5) -0.019(4) -0.039(4) 0.022(4) C6 0.020(3) 0.021(2) 0.022(3) -0.0032(19) -0.002(2) -0.001(2) C7 0.025(3) 0.022(3) 0.021(3) -0.0024(19) 0.001(2) -0.005(2) C8 0.063(5) 0.066(5) 0.038(4) -0.015(3) 0.023(4) -0.022(4) C9 0.023(3) 0.090(6) 0.102(7) 0.050(6) 0.015(4) 0.011(4) C10 0.074(5) 0.034(3) 0.052(4) -0.013(3) 0.038(4) -0.025(3) C11 0.054(4) 0.030(3) 0.031(3) -0.003(2) 0.013(3) 0.002(3) C12 0.052(4) 0.033(3) 0.025(3) 0.001(2) -0.004(3) -0.001(3) C13 0.017(3) 0.018(2) 0.034(3) 0.002(2) 0.001(2) 0.0011(19) C14 0.019(3) 0.020(3) 0.041(3) -0.002(2) -0.002(2) 0.001(2) C15 0.026(3) 0.051(4) 0.059(5) -0.003(3) 0.008(3) 0.007(3) C16 0.029(3) 0.025(3) 0.076(5) -0.001(3) -0.023(3) 0.005(3) C17 0.026(3) 0.037(3) 0.049(4) -0.006(3) -0.003(3) -0.001(3) C18 0.019(3) 0.022(2) 0.032(3) -0.004(2) -0.007(2) -0.001(2) C19 0.050(4) 0.035(3) 0.031(3) -0.003(2) -0.001(3) 0.004(3) C20 0.200(12) 0.068(6) 0.089(7) -0.001(5) 0.084(8) 0.006(7) C21 0.081(7) 0.110(8) 0.066(6) -0.013(5) 0.016(6) -0.002(6) C22 0.166(11) 0.090(7) 0.096(7) -0.034(6) 0.069(8) -0.019(8) C23 0.024(3) 0.020(3) 0.056(4) 0.009(2) 0.003(3) 0.001(2) C24 0.019(3) 0.020(3) 0.057(4) 0.004(2) 0.000(3) 0.001(2) C25 0.020(2) 0.017(2) 0.028(3) 0.0046(19) -0.005(2) 0.001(2) C26 0.022(3) 0.023(3) 0.028(3) -0.005(2) 0.002(2) -0.003(2) C27 0.022(3) 0.021(2) 0.031(3) 0.002(2) 0.006(2) 0.006(2) C28 0.018(3) 0.022(3) 0.049(3) -0.003(2) 0.007(3) 0.002(2) C29 0.031(3) 0.017(3) 0.077(5) 0.010(3) 0.019(3) 0.006(2) C30 0.026(3) 0.066(5) 0.058(4) -0.025(4) -0.002(3) -0.009(3) C31 0.031(4) 0.098(6) 0.041(4) -0.034(4) -0.002(3) -0.002(4) C32 0.023(3) 0.058(4) 0.030(3) -0.014(3) 0.006(2) -0.002(3) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt1 N1 2.009(4) . ? Pt1 N2 2.009(5) 2_655 ? Pt1 N4 2.051(5) . ? Pt1 N3 2.060(4) . ? Pt1 Ag1 2.8860(5) . ? Pt1 Ag1 2.9104(5) 2_655 ? Pt2 N6 2.014(4) . ? Pt2 N5 2.016(5) . ? Pt2 N7 2.053(5) . ? Pt2 N8 2.060(5) . ? Pt2 Ag2 2.8135(5) 2_745 ? Pt2 Ag2 2.8524(5) . ? Ag1 O1 2.306(4) . ? Ag1 O5 2.330(4) . ? Ag1 O2 2.393(4) . ? Ag1 Pt1 2.9104(5) 2_645 ? Ag2 O4 2.357(4) 2_755 ? Ag2 O3 2.389(4) 2_755 ? Ag2 O7 2.401(6) . ? Ag2 Pt2 2.8135(5) 2_755 ? N1 C1 1.299(6) . ? N1 H1 0.8800 . ? N2 C6 1.313(7) . ? N2 Pt1 2.009(5) 2_645 ? N2 H2 0.8800 . ? N3 C12 1.486(8) . ? N3 H3D 0.9200 . ? N3 H3E 0.9200 . ? N4 C11 1.482(7) . ? N4 H4D 0.9200 . ? N4 H4E 0.9200 . ? N5 C18 1.310(7) . ? N6 C13 1.319(6) . ? N6 H6 0.9200 . ? N7 C23 1.484(7) . ? N7 H7A 0.9200 . ? N7 H7B 0.9200 . ? N8 C24 1.461(8) . ? N8 H8D 0.9200 . ? N8 H8E 0.9200 . ? O1 C1 1.273(6) . ? O2 C6 1.274(6) . ? O3 C18 1.272(6) . ? O3 Ag2 2.389(4) 2_745 ? O4 C13 1.263(6) . ? O4 Ag2 2.357(4) 2_745 ? O5 C25 1.265(7) . ? O6 C25 1.258(7) . ? O7 C29 1.268(8) . ? O8 C29 1.246(9) . ? C1 C2 1.535(7) . ? C2 C4 1.501(11) . ? C2 C5 1.505(9) . ? C2 C3 1.541(11) . ? C3 H3A 0.9800 . ? C3 H3B 0.9800 . ? C3 H3C 0.9800 . ? C4 H4A 0.9800 . ? C4 H4B 0.9800 . ? C4 H4C 0.9800 . ? C5 H5A 0.9800 . ? C5 H5B 0.9800 . ? C5 H5C 0.9800 . ? C6 C7 1.527(8) . ? C7 C10 1.523(7) . ? C7 C8 1.524(8) . ? C7 C9 1.526(9) . ? C8 H8A 0.9800 . ? C8 H8B 0.9800 . ? C8 H8C 0.9800 . ? C9 H9A 0.9800 . ? C9 H9B 0.9800 . ? C9 H9C 0.9800 . ? C10 H10A 0.9800 . ? C10 H10B 0.9800 . ? C10 H10C 0.9800 . ? C11 C12 1.517(9) . ? C11 H11A 0.9900 . ? C11 H11B 0.9900 . ? C12 H12A 0.9900 . ? C12 H12B 0.9900 . ? C13 C14 1.552(7) . ? C14 C15 1.524(9) . ? C14 C16 1.535(8) . ? C14 C17 1.541(8) . ? C15 H15A 0.9800 . ? C15 H15B 0.9800 . ? C15 H15C 0.9800 . ? C16 H16A 0.9800 . ? C16 H16B 0.9800 . ? C16 H16C 0.9800 . ? C17 H17A 0.9800 . ? C17 H17B 0.9800 . ? C17 H17C 0.9800 . ? C18 C19 1.538(9) . ? C19 C22 1.462(11) . ? C19 C20 1.487(11) . ? C19 C21 1.637(13) . ? C20 H20A 0.9800 . ? C20 H20B 0.9800 . ? C20 H20C 0.9800 . ? C21 H21A 0.9800 . ? C21 H21B 0.9800 . ? C21 H21C 0.9800 . ? C22 H22A 0.9800 . ? C22 H22B 0.9800 . ? C22 H22C 0.9800 . ? C23 C24 1.520(8) . ? C23 H23A 0.9900 . ? C23 H23B 0.9900 . ? C24 H24A 0.9900 . ? C24 H24B 0.9900 . ? C25 C26 1.513(7) . ? C26 C27 1.384(8) . ? C26 C32 1.388(8) . ? C27 C28 1.395(8) . ? C27 H27 0.9500 . ? C28 C30 1.399(9) . ? C28 C29 1.512(9) . ? C30 C31 1.362(10) . ? C30 H30 0.9500 . ? C31 C32 1.393(9) . ? C31 H31 0.9500 . ? C32 H32 0.9500 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N1 Pt1 N2 92.59(19) . 2_655 ? N1 Pt1 N4 91.1(2) . . ? N2 Pt1 N4 175.75(18) 2_655 . ? N1 Pt1 N3 174.8(2) . . ? N2 Pt1 N3 92.40(19) 2_655 . ? N4 Pt1 N3 83.9(2) . . ? N1 Pt1 Ag1 86.83(13) . . ? N2 Pt1 Ag1 88.93(12) 2_655 . ? N4 Pt1 Ag1 93.39(13) . . ? N3 Pt1 Ag1 94.70(12) . . ? N1 Pt1 Ag1 91.44(13) . 2_655 ? N2 Pt1 Ag1 87.51(12) 2_655 2_655 ? N4 Pt1 Ag1 90.28(13) . 2_655 ? N3 Pt1 Ag1 87.35(12) . 2_655 ? Ag1 Pt1 Ag1 175.969(8) . 2_655 ? N6 Pt2 N5 90.0(2) . . ? N6 Pt2 N7 94.16(19) . . ? N5 Pt2 N7 175.89(18) . . ? N6 Pt2 N8 176.06(18) . . ? N5 Pt2 N8 92.9(2) . . ? N7 Pt2 N8 83.0(2) . . ? N6 Pt2 Ag2 86.79(12) . 2_745 ? N5 Pt2 Ag2 87.19(12) . 2_745 ? N7 Pt2 Ag2 93.22(13) . 2_745 ? N8 Pt2 Ag2 96.09(12) . 2_745 ? N6 Pt2 Ag2 89.66(12) . . ? N5 Pt2 Ag2 93.15(12) . . ? N7 Pt2 Ag2 86.69(13) . . ? N8 Pt2 Ag2 87.44(12) . . ? Ag2 Pt2 Ag2 176.431(8) 2_745 . ? O1 Ag1 O5 160.14(15) . . ? O1 Ag1 O2 100.83(16) . . ? O5 Ag1 O2 98.07(14) . . ? O1 Ag1 Pt1 76.37(10) . . ? O5 Ag1 Pt1 86.62(9) . . ? O2 Ag1 Pt1 131.29(9) . . ? O1 Ag1 Pt1 89.21(10) . 2_645 ? O5 Ag1 Pt1 101.90(9) . 2_645 ? O2 Ag1 Pt1 73.85(9) . 2_645 ? Pt1 Ag1 Pt1 152.568(16) . 2_645 ? O4 Ag2 O3 103.21(16) 2_755 2_755 ? O4 Ag2 O7 97.62(18) 2_755 . ? O3 Ag2 O7 154.49(15) 2_755 . ? O4 Ag2 Pt2 78.79(10) 2_755 2_755 ? O3 Ag2 Pt2 78.01(9) 2_755 2_755 ? O7 Ag2 Pt2 91.94(10) . 2_755 ? O4 Ag2 Pt2 90.62(10) 2_755 . ? O3 Ag2 Pt2 97.59(9) 2_755 . ? O7 Ag2 Pt2 96.74(10) . . ? Pt2 Ag2 Pt2 167.126(18) 2_755 . ? C1 N1 Pt1 127.5(4) . . ? C1 N1 H1 116.3 . . ? Pt1 N1 H1 116.3 . . ? C6 N2 Pt1 126.1(4) . 2_645 ? C6 N2 H2 116.9 . . ? Pt1 N2 H2 116.9 2_645 . ? C12 N3 Pt1 108.4(4) . . ? C12 N3 H3D 110.0 . . ? Pt1 N3 H3D 110.0 . . ? C12 N3 H3E 110.0 . . ? Pt1 N3 H3E 110.0 . . ? H3D N3 H3E 108.4 . . ? C11 N4 Pt1 108.1(4) . . ? C11 N4 H4D 110.1 . . ? Pt1 N4 H4D 110.1 . . ? C11 N4 H4E 110.1 . . ? Pt1 N4 H4E 110.1 . . ? H4D N4 H4E 108.4 . . ? C18 N5 Pt2 127.2(4) . . ? C13 N6 Pt2 128.2(4) . . ? C13 N6 H6 105.0 . . ? Pt2 N6 H6 105.1 . . ? C23 N7 Pt2 109.8(4) . . ? C23 N7 H7A 109.7 . . ? Pt2 N7 H7A 109.7 . . ? C23 N7 H7B 109.7 . . ? Pt2 N7 H7B 109.7 . . ? H7A N7 H7B 108.2 . . ? C24 N8 Pt2 109.6(4) . . ? C24 N8 H8D 109.8 . . ? Pt2 N8 H8D 109.8 . . ? C24 N8 H8E 109.8 . . ? Pt2 N8 H8E 109.8 . . ? H8D N8 H8E 108.2 . . ? C1 O1 Ag1 126.8(3) . . ? C6 O2 Ag1 123.1(3) . . ? C18 O3 Ag2 119.9(3) . 2_745 ? C13 O4 Ag2 121.8(3) . 2_745 ? C25 O5 Ag1 109.7(3) . . ? C29 O7 Ag2 97.7(5) . . ? O1 C1 N1 122.0(5) . . ? O1 C1 C2 118.3(5) . . ? N1 C1 C2 119.7(5) . . ? C4 C2 C5 109.5(8) . . ? C4 C2 C1 110.8(6) . . ? C5 C2 C1 112.9(5) . . ? C4 C2 C3 110.4(8) . . ? C5 C2 C3 105.6(7) . . ? C1 C2 C3 107.4(6) . . ? C2 C3 H3A 109.5 . . ? C2 C3 H3B 109.5 . . ? H3A C3 H3B 109.5 . . ? C2 C3 H3C 109.5 . . ? H3A C3 H3C 109.5 . . ? H3B C3 H3C 109.5 . . ? C2 C4 H4A 109.5 . . ? C2 C4 H4B 109.5 . . ? H4A C4 H4B 109.5 . . ? C2 C4 H4C 109.5 . . ? H4A C4 H4C 109.5 . . ? H4B C4 H4C 109.5 . . ? C2 C5 H5A 109.5 . . ? C2 C5 H5B 109.5 . . ? H5A C5 H5B 109.5 . . ? C2 C5 H5C 109.5 . . ? H5A C5 H5C 109.5 . . ? H5B C5 H5C 109.5 . . ? O2 C6 N2 121.7(5) . . ? O2 C6 C7 117.8(4) . . ? N2 C6 C7 120.5(4) . . ? C10 C7 C8 108.0(5) . . ? C10 C7 C9 109.4(6) . . ? C8 C7 C9 109.0(6) . . ? C10 C7 C6 114.9(5) . . ? C8 C7 C6 109.2(5) . . ? C9 C7 C6 106.2(5) . . ? C7 C8 H8A 109.5 . . ? C7 C8 H8B 109.5 . . ? H8A C8 H8B 109.5 . . ? C7 C8 H8C 109.5 . . ? H8A C8 H8C 109.5 . . ? H8B C8 H8C 109.5 . . ? C7 C9 H9A 109.5 . . ? C7 C9 H9B 109.5 . . ? H9A C9 H9B 109.5 . . ? C7 C9 H9C 109.5 . . ? H9A C9 H9C 109.5 . . ? H9B C9 H9C 109.5 . . ? C7 C10 H10A 109.5 . . ? C7 C10 H10B 109.5 . . ? H10A C10 H10B 109.5 . . ? C7 C10 H10C 109.5 . . ? H10A C10 H10C 109.5 . . ? H10B C10 H10C 109.5 . . ? N4 C11 C12 107.3(5) . . ? N4 C11 H11A 110.3 . . ? C12 C11 H11A 110.3 . . ? N4 C11 H11B 110.3 . . ? C12 C11 H11B 110.3 . . ? H11A C11 H11B 108.5 . . ? N3 C12 C11 108.6(5) . . ? N3 C12 H12A 110.0 . . ? C11 C12 H12A 110.0 . . ? N3 C12 H12B 110.0 . . ? C11 C12 H12B 110.0 . . ? H12A C12 H12B 108.3 . . ? O4 C13 N6 123.0(5) . . ? O4 C13 C14 117.7(4) . . ? N6 C13 C14 119.3(4) . . ? C15 C14 C16 110.6(5) . . ? C15 C14 C17 109.7(5) . . ? C16 C14 C17 107.8(5) . . ? C15 C14 C13 106.3(5) . . ? C16 C14 C13 112.5(5) . . ? C17 C14 C13 110.0(5) . . ? C14 C15 H15A 109.5 . . ? C14 C15 H15B 109.5 . . ? H15A C15 H15B 109.5 . . ? C14 C15 H15C 109.5 . . ? H15A C15 H15C 109.5 . . ? H15B C15 H15C 109.5 . . ? C14 C16 H16A 109.5 . . ? C14 C16 H16B 109.5 . . ? H16A C16 H16B 109.5 . . ? C14 C16 H16C 109.5 . . ? H16A C16 H16C 109.5 . . ? H16B C16 H16C 109.5 . . ? C14 C17 H17A 109.5 . . ? C14 C17 H17B 109.5 . . ? H17A C17 H17B 109.5 . . ? C14 C17 H17C 109.5 . . ? H17A C17 H17C 109.5 . . ? H17B C17 H17C 109.5 . . ? O3 C18 N5 124.3(6) . . ? O3 C18 C19 117.8(5) . . ? N5 C18 C19 117.9(5) . . ? C22 C19 C20 117.3(8) . . ? C22 C19 C18 114.6(7) . . ? C20 C19 C18 112.6(6) . . ? C22 C19 C21 104.8(8) . . ? C20 C19 C21 99.4(8) . . ? C18 C19 C21 105.9(6) . . ? C19 C20 H20A 109.5 . . ? C19 C20 H20B 109.5 . . ? H20A C20 H20B 109.5 . . ? C19 C20 H20C 109.5 . . ? H20A C20 H20C 109.5 . . ? H20B C20 H20C 109.5 . . ? C19 C21 H21A 109.5 . . ? C19 C21 H21B 109.5 . . ? H21A C21 H21B 109.5 . . ? C19 C21 H21C 109.5 . . ? H21A C21 H21C 109.5 . . ? H21B C21 H21C 109.5 . . ? C19 C22 H22A 109.5 . . ? C19 C22 H22B 109.5 . . ? H22A C22 H22B 109.5 . . ? C19 C22 H22C 109.5 . . ? H22A C22 H22C 109.5 . . ? H22B C22 H22C 109.5 . . ? N7 C23 C24 107.8(5) . . ? N7 C23 H23A 110.1 . . ? C24 C23 H23A 110.1 . . ? N7 C23 H23B 110.1 . . ? C24 C23 H23B 110.1 . . ? H23A C23 H23B 108.5 . . ? N8 C24 C23 109.2(5) . . ? N8 C24 H24A 109.8 . . ? C23 C24 H24A 109.8 . . ? N8 C24 H24B 109.8 . . ? C23 C24 H24B 109.8 . . ? H24A C24 H24B 108.3 . . ? O6 C25 O5 123.8(5) . . ? O6 C25 C26 118.2(5) . . ? O5 C25 C26 117.9(5) . . ? C27 C26 C32 119.7(5) . . ? C27 C26 C25 119.7(5) . . ? C32 C26 C25 120.6(5) . . ? C26 C27 C28 120.9(5) . . ? C26 C27 H27 119.5 . . ? C28 C27 H27 119.5 . . ? C27 C28 C30 118.1(6) . . ? C27 C28 C29 120.3(6) . . ? C30 C28 C29 121.6(6) . . ? O8 C29 O7 124.1(7) . . ? O8 C29 C28 118.6(6) . . ? O7 C29 C28 117.3(7) . . ? C31 C30 C28 121.2(6) . . ? C31 C30 H30 119.4 . . ? C28 C30 H30 119.4 . . ? C30 C31 C32 120.3(6) . . ? C30 C31 H31 119.9 . . ? C32 C31 H31 119.9 . . ? C26 C32 C31 119.7(6) . . ? C26 C32 H32 120.2 . . ? C31 C32 H32 120.2 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N1 Pt1 Ag1 O1 -4.5(2) . . . . ? N2 Pt1 Ag1 O1 -97.13(19) 2_655 . . . ? N4 Pt1 Ag1 O1 86.44(19) . . . . ? N3 Pt1 Ag1 O1 170.6(2) . . . . ? Ag1 Pt1 Ag1 O1 -69.13(18) 2_655 . . . ? N1 Pt1 Ag1 O5 165.21(18) . . . . ? N2 Pt1 Ag1 O5 72.56(16) 2_655 . . . ? N4 Pt1 Ag1 O5 -103.88(17) . . . . ? N3 Pt1 Ag1 O5 -19.76(18) . . . . ? Ag1 Pt1 Ag1 O5 100.55(15) 2_655 . . . ? N1 Pt1 Ag1 O2 -97.0(2) . . . . ? N2 Pt1 Ag1 O2 170.34(18) 2_655 . . . ? N4 Pt1 Ag1 O2 -6.10(19) . . . . ? N3 Pt1 Ag1 O2 78.0(2) . . . . ? Ag1 Pt1 Ag1 O2 -161.67(17) 2_655 . . . ? N1 Pt1 Ag1 Pt1 55.66(15) . . . 2_645 ? N2 Pt1 Ag1 Pt1 -36.99(13) 2_655 . . 2_645 ? N4 Pt1 Ag1 Pt1 146.57(14) . . . 2_645 ? N3 Pt1 Ag1 Pt1 -129.31(15) . . . 2_645 ? Ag1 Pt1 Ag1 Pt1 -9.00(11) 2_655 . . 2_645 ? N6 Pt2 Ag2 O4 176.22(19) . . . 2_755 ? N5 Pt2 Ag2 O4 86.29(18) . . . 2_755 ? N7 Pt2 Ag2 O4 -89.60(18) . . . 2_755 ? N8 Pt2 Ag2 O4 -6.4(2) . . . 2_755 ? Ag2 Pt2 Ag2 O4 -178(19) 2_745 . . 2_755 ? N6 Pt2 Ag2 O3 -80.36(17) . . . 2_755 ? N5 Pt2 Ag2 O3 -170.30(17) . . . 2_755 ? N7 Pt2 Ag2 O3 13.82(16) . . . 2_755 ? N8 Pt2 Ag2 O3 96.98(18) . . . 2_755 ? Ag2 Pt2 Ag2 O3 -74.93(17) 2_745 . . 2_755 ? N6 Pt2 Ag2 O7 78.48(19) . . . . ? N5 Pt2 Ag2 O7 -11.46(18) . . . . ? N7 Pt2 Ag2 O7 172.66(18) . . . . ? N8 Pt2 Ag2 O7 -104.2(2) . . . . ? Ag2 Pt2 Ag2 O7 83.90(18) 2_745 . . . ? N6 Pt2 Ag2 Pt2 -149.45(16) . . . 2_755 ? N5 Pt2 Ag2 Pt2 120.62(15) . . . 2_755 ? N7 Pt2 Ag2 Pt2 -55.27(15) . . . 2_755 ? N8 Pt2 Ag2 Pt2 27.89(17) . . . 2_755 ? Ag2 Pt2 Ag2 Pt2 -144.02(16) 2_745 . . 2_755 ? N2 Pt1 N1 C1 97.2(5) 2_655 . . . ? N4 Pt1 N1 C1 -84.9(5) . . . . ? N3 Pt1 N1 C1 -99(2) . . . . ? Ag1 Pt1 N1 C1 8.4(5) . . . . ? Ag1 Pt1 N1 C1 -175.2(5) 2_655 . . . ? N1 Pt1 N3 C12 25(2) . . . . ? N2 Pt1 N3 C12 -171.3(4) 2_655 . . . ? N4 Pt1 N3 C12 10.7(3) . . . . ? Ag1 Pt1 N3 C12 -82.2(3) . . . . ? Ag1 Pt1 N3 C12 101.3(3) 2_655 . . . ? N1 Pt1 N4 C11 -160.5(4) . . . . ? N2 Pt1 N4 C11 -10(2) 2_655 . . . ? N3 Pt1 N4 C11 18.2(4) . . . . ? Ag1 Pt1 N4 C11 112.6(3) . . . . ? Ag1 Pt1 N4 C11 -69.1(3) 2_655 . . . ? N6 Pt2 N5 C18 98.2(5) . . . . ? N7 Pt2 N5 C18 -84(2) . . . . ? N8 Pt2 N5 C18 -84.6(5) . . . . ? Ag2 Pt2 N5 C18 11.4(5) 2_745 . . . ? Ag2 Pt2 N5 C18 -172.2(5) . . . . ? N5 Pt2 N6 C13 -88.4(5) . . . . ? N7 Pt2 N6 C13 91.8(5) . . . . ? N8 Pt2 N6 C13 136(3) . . . . ? Ag2 Pt2 N6 C13 -1.2(5) 2_745 . . . ? Ag2 Pt2 N6 C13 178.5(5) . . . . ? N6 Pt2 N7 C23 163.3(3) . . . . ? N5 Pt2 N7 C23 -14(3) . . . . ? N8 Pt2 N7 C23 -13.9(3) . . . . ? Ag2 Pt2 N7 C23 -109.6(3) 2_745 . . . ? Ag2 Pt2 N7 C23 73.9(3) . . . . ? N6 Pt2 N8 C24 -58(3) . . . . ? N5 Pt2 N8 C24 166.3(3) . . . . ? N7 Pt2 N8 C24 -13.7(3) . . . . ? Ag2 Pt2 N8 C24 78.8(3) 2_745 . . . ? Ag2 Pt2 N8 C24 -100.7(3) . . . . ? O5 Ag1 O1 C1 -28.2(9) . . . . ? O2 Ag1 O1 C1 133.7(5) . . . . ? Pt1 Ag1 O1 C1 3.5(5) . . . . ? Pt1 Ag1 O1 C1 -152.9(5) 2_645 . . . ? O1 Ag1 O2 C6 58.1(4) . . . . ? O5 Ag1 O2 C6 -128.0(4) . . . . ? Pt1 Ag1 O2 C6 139.4(4) . . . . ? Pt1 Ag1 O2 C6 -27.9(4) 2_645 . . . ? O1 Ag1 O5 C25 -56.5(6) . . . . ? O2 Ag1 O5 C25 141.4(3) . . . . ? Pt1 Ag1 O5 C25 -87.3(3) . . . . ? Pt1 Ag1 O5 C25 66.3(3) 2_645 . . . ? O4 Ag2 O7 C29 -172.1(3) 2_755 . . . ? O3 Ag2 O7 C29 43.3(5) 2_755 . . . ? Pt2 Ag2 O7 C29 109.0(3) 2_755 . . . ? Pt2 Ag2 O7 C29 -80.5(3) . . . . ? Ag1 O1 C1 N1 1.0(8) . . . . ? Ag1 O1 C1 C2 179.9(4) . . . . ? Pt1 N1 C1 O1 -8.1(8) . . . . ? Pt1 N1 C1 C2 173.0(4) . . . . ? O1 C1 C2 C4 23.7(10) . . . . ? N1 C1 C2 C4 -157.4(8) . . . . ? O1 C1 C2 C5 147.0(7) . . . . ? N1 C1 C2 C5 -34.1(9) . . . . ? O1 C1 C2 C3 -97.0(7) . . . . ? N1 C1 C2 C3 81.9(7) . . . . ? Ag1 O2 C6 N2 28.0(7) . . . . ? Ag1 O2 C6 C7 -151.7(4) . . . . ? Pt1 N2 C6 O2 -3.6(8) 2_645 . . . ? Pt1 N2 C6 C7 176.1(4) 2_645 . . . ? O2 C6 C7 C10 -161.3(5) . . . . ? N2 C6 C7 C10 19.0(8) . . . . ? O2 C6 C7 C8 -39.8(7) . . . . ? N2 C6 C7 C8 140.5(6) . . . . ? O2 C6 C7 C9 77.6(7) . . . . ? N2 C6 C7 C9 -102.1(7) . . . . ? Pt1 N4 C11 C12 -43.1(5) . . . . ? Pt1 N3 C12 C11 -37.3(5) . . . . ? N4 C11 C12 N3 53.8(6) . . . . ? Ag2 O4 C13 N6 14.5(8) 2_745 . . . ? Ag2 O4 C13 C14 -163.8(4) 2_745 . . . ? Pt2 N6 C13 O4 -8.0(9) . . . . ? Pt2 N6 C13 C14 170.3(4) . . . . ? O4 C13 C14 C15 88.5(6) . . . . ? N6 C13 C14 C15 -89.9(6) . . . . ? O4 C13 C14 C16 -150.4(6) . . . . ? N6 C13 C14 C16 31.3(8) . . . . ? O4 C13 C14 C17 -30.2(7) . . . . ? N6 C13 C14 C17 151.4(5) . . . . ? Ag2 O3 C18 N5 -17.0(7) 2_745 . . . ? Ag2 O3 C18 C19 162.0(4) 2_745 . . . ? Pt2 N5 C18 O3 0.9(8) . . . . ? Pt2 N5 C18 C19 -178.1(4) . . . . ? O3 C18 C19 C22 141.0(8) . . . . ? N5 C18 C19 C22 -39.9(10) . . . . ? O3 C18 C19 C20 3.6(10) . . . . ? N5 C18 C19 C20 -177.3(8) . . . . ? O3 C18 C19 C21 -103.9(7) . . . . ? N5 C18 C19 C21 75.1(7) . . . . ? Pt2 N7 C23 C24 37.7(5) . . . . ? Pt2 N8 C24 C23 38.2(5) . . . . ? N7 C23 C24 N8 -50.3(6) . . . . ? Ag1 O5 C25 O6 -7.1(6) . . . . ? Ag1 O5 C25 C26 168.9(3) . . . . ? O6 C25 C26 C27 7.0(7) . . . . ? O5 C25 C26 C27 -169.2(5) . . . . ? O6 C25 C26 C32 -174.2(5) . . . . ? O5 C25 C26 C32 9.6(8) . . . . ? C32 C26 C27 C28 -1.8(8) . . . . ? C25 C26 C27 C28 177.0(5) . . . . ? C26 C27 C28 C30 0.9(8) . . . . ? C26 C27 C28 C29 -179.7(5) . . . . ? Ag2 O7 C29 O8 -2.2(6) . . . . ? Ag2 O7 C29 C28 178.7(4) . . . . ? C27 C28 C29 O8 4.3(8) . . . . ? C30 C28 C29 O8 -176.3(6) . . . . ? C27 C28 C29 O7 -176.6(5) . . . . ? C30 C28 C29 O7 2.8(9) . . . . ? C27 C28 C30 C31 0.9(11) . . . . ? C29 C28 C30 C31 -178.6(7) . . . . ? C28 C30 C31 C32 -1.6(13) . . . . ? C27 C26 C32 C31 1.1(10) . . . . ? C25 C26 C32 C31 -177.8(6) . . . . ? C30 C31 C32 C26 0.6(12) . . . . ? _diffrn_measured_fraction_theta_max 0.973 _diffrn_reflns_theta_full 27.53 _diffrn_measured_fraction_theta_full 0.973 _refine_diff_density_max 1.858 _refine_diff_density_min -1.282 _refine_diff_density_rms 0.217 #===END data_l488a _database_code_depnum_ccdc_archive 'CCDC 286690' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C48 H114 Ag3 N12 O19 Pt3' _chemical_formula_weight 2072.39 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Monoclinic _symmetry_space_group_name_H-M P2(1)/c loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 31.263(7) _cell_length_b 11.318(2) _cell_length_c 20.495(4) _cell_angle_alpha 90.00 _cell_angle_beta 99.676(4) _cell_angle_gamma 90.00 _cell_volume 7149(3) _cell_formula_units_Z 4 _cell_measurement_temperature 120(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description prism _exptl_crystal_colour colorless _exptl_crystal_size_max 0.38 _exptl_crystal_size_mid 0.32 _exptl_crystal_size_min 0.30 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.925 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 4052 _exptl_absorpt_coefficient_mu 6.723 _exptl_absorpt_correction_type none _exptl_absorpt_correction_T_min 0.1844 _exptl_absorpt_correction_T_max 0.2376 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 120(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 41985 _diffrn_reflns_av_R_equivalents 0.0532 _diffrn_reflns_av_sigmaI/netI 0.0462 _diffrn_reflns_limit_h_min -39 _diffrn_reflns_limit_h_max 40 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_k_max 14 _diffrn_reflns_limit_l_min -26 _diffrn_reflns_limit_l_max 21 _diffrn_reflns_theta_min 0.66 _diffrn_reflns_theta_max 27.57 _reflns_number_total 15889 _reflns_number_gt 13422 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0416P)^2^+74.5441P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 15889 _refine_ls_number_parameters 779 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0531 _refine_ls_R_factor_gt 0.0431 _refine_ls_wR_factor_ref 0.1117 _refine_ls_wR_factor_gt 0.1069 _refine_ls_goodness_of_fit_ref 1.051 _refine_ls_restrained_S_all 1.051 _refine_ls_shift/su_max 0.004 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Pt1 Pt 0.999007(7) 0.20347(2) 0.256381(11) 0.01076(6) Uani 1 1 d . . . Pt2 Pt 0.670141(8) 0.31722(2) 0.428591(12) 0.01361(7) Uani 1 1 d . . . Pt3 Pt 0.671397(8) -0.18371(2) 0.421738(12) 0.01389(7) Uani 1 1 d . . . Ag1 Ag 1.007510(15) -0.04904(4) 0.28218(2) 0.01360(10) Uani 1 1 d . . . Ag2 Ag 0.658792(16) 0.06721(4) 0.39676(3) 0.01556(11) Uani 1 1 d . . . Ag3 Ag 0.677361(15) -0.43051(4) 0.45748(3) 0.01610(11) Uani 1 1 d . . . N1 N 1.04002(19) 0.1784(5) 0.1922(3) 0.0179(11) Uani 1 1 d . . . H1 H 1.0468 0.2417 0.1711 0.021 Uiso 1 1 calc R . . N2 N 0.94787(17) 0.1701(4) 0.1858(3) 0.0140(11) Uani 1 1 d . . . H2 H 0.9347 0.1016 0.1875 0.017 Uiso 1 1 calc R . . N3 N 0.96044(17) 0.2391(5) 0.3262(3) 0.0150(11) Uani 1 1 d . . . H3D H 0.9469 0.3109 0.3175 0.018 Uiso 1 1 calc R . . H3E H 0.9395 0.1818 0.3251 0.018 Uiso 1 1 calc R . . N4 N 1.04852(18) 0.2436(5) 0.3318(3) 0.0190(12) Uani 1 1 d . . . H4D H 1.0628 0.1757 0.3475 0.023 Uiso 1 1 calc R . . H4E H 1.0681 0.2929 0.3166 0.023 Uiso 1 1 calc R . . N5 N 0.70091(19) 0.3451(5) 0.3519(3) 0.0191(12) Uani 1 1 d . . . H5 H 0.7233 0.2912 0.3569 0.023 Uiso 1 1 d R . . N6 N 0.61277(17) 0.3448(5) 0.3695(3) 0.0158(11) Uani 1 1 d . . . H6 H 0.5934 0.3592 0.3978 0.019 Uiso 1 1 d R . . N7 N 0.6424(2) 0.2785(5) 0.5104(3) 0.0226(13) Uani 1 1 d . . . H7A H 0.6295 0.3450 0.5242 0.027 Uiso 1 1 calc R . . H7B H 0.6214 0.2214 0.4999 0.027 Uiso 1 1 calc R . . N8 N 0.72725(19) 0.2924(5) 0.4935(3) 0.0229(13) Uani 1 1 d . . . H8D H 0.7389 0.2200 0.4860 0.027 Uiso 1 1 calc R . . H8E H 0.7469 0.3499 0.4871 0.027 Uiso 1 1 calc R . . N9 N 0.63671(19) -0.1577(5) 0.4948(3) 0.0192(12) Uani 1 1 d . . . H9 H 0.6170 -0.2187 0.4910 0.023 Uiso 1 1 d R . . N10 N 0.72710(19) -0.1556(5) 0.4843(3) 0.0201(12) Uani 1 1 d . . . H10 H 0.7463 -0.1274 0.4585 0.024 Uiso 1 1 d R . . N11 N 0.70347(19) -0.2169(5) 0.3436(3) 0.0194(12) Uani 1 1 d . . . H11C H 0.7243 -0.1602 0.3419 0.023 Uiso 1 1 calc R . . H11D H 0.7168 -0.2895 0.3488 0.023 Uiso 1 1 calc R . . N12 N 0.61699(19) -0.2172(5) 0.3532(3) 0.0204(12) Uani 1 1 d . . . H12C H 0.5984 -0.2654 0.3713 0.024 Uiso 1 1 calc R . . H12D H 0.6028 -0.1477 0.3403 0.024 Uiso 1 1 calc R . . O1 O 1.04995(18) -0.0187(4) 0.2035(3) 0.0287(13) Uani 1 1 d . . . O2 O 0.9485(2) 0.3435(5) 0.1305(3) 0.0365(14) Uani 1 1 d . . . O3 O 0.60689(16) 0.1723(4) 0.3135(3) 0.0240(11) Uani 1 1 d . . . O4 O 0.61622(18) 0.0329(4) 0.4745(3) 0.0290(12) Uani 1 1 d . . . O5 O 0.73650(16) -0.3403(4) 0.5296(2) 0.0235(11) Uani 1 1 d . . . O6 O 0.71729(18) 0.5398(4) 0.3686(3) 0.0258(11) Uani 1 1 d . . . O7 O 0.94684(16) -0.0291(4) 0.3318(3) 0.0229(11) Uani 1 1 d . . . O8 O 0.91185(16) -0.0669(4) 0.2299(2) 0.0227(11) Uani 1 1 d . . . O9 O 0.71461(16) 0.0542(5) 0.3359(3) 0.0263(12) Uani 1 1 d . . . O10 O 0.75066(16) 0.0800(4) 0.4383(3) 0.0227(10) Uani 1 1 d . . . O11 O 0.61924(16) -0.4715(5) 0.5249(3) 0.0286(12) Uani 1 1 d . . . O12 O 0.59259(17) -0.4163(4) 0.4219(3) 0.0283(12) Uani 1 1 d . . . O13 O 0.57371(19) 0.9593(5) 0.2672(3) 0.0412(15) Uani 1 1 d . . . O14 O 0.78487(18) 0.4902(5) 0.4772(3) 0.0392(14) Uani 1 1 d . . . O15 O 0.0773(2) 0.0528(5) 0.4261(3) 0.0492(18) Uani 1 1 d . . . O16 O 0.6637(2) 0.1480(5) 0.2240(3) 0.0427(15) Uani 1 1 d . . . O17 O 0.6234(2) 0.5457(6) 0.6606(3) 0.0477(17) Uani 1 1 d . . . O18 O 0.9743(3) 0.9101(7) 0.4620(4) 0.099(4) Uani 1 1 d . . . O19 O 0.7136(4) 0.5997(10) 0.6544(6) 0.105(3) Uiso 1 1 d . . . C1 C 1.0578(2) 0.0793(6) 0.1779(3) 0.0184(13) Uani 1 1 d . . . C2 C 1.0883(3) 0.0803(6) 0.1266(4) 0.0281(17) Uani 1 1 d . . . C3 C 1.0595(4) 0.0805(10) 0.0580(5) 0.058(3) Uani 1 1 d . . . H3A H 1.0403 0.0114 0.0539 0.088 Uiso 1 1 calc R . . H3B H 1.0778 0.0777 0.0237 0.088 Uiso 1 1 calc R . . H3C H 1.0419 0.1527 0.0528 0.088 Uiso 1 1 calc R . . C4 C 1.1176(4) 0.1899(8) 0.1353(7) 0.065(4) Uani 1 1 d . . . H4A H 1.0999 0.2610 0.1254 0.097 Uiso 1 1 calc R . . H4B H 1.1387 0.1850 0.1050 0.097 Uiso 1 1 calc R . . H4C H 1.1330 0.1936 0.1810 0.097 Uiso 1 1 calc R . . C5 C 1.1169(2) -0.0308(7) 0.1342(4) 0.0291(17) Uani 1 1 d . . . H5A H 1.1321 -0.0367 0.1800 0.044 Uiso 1 1 calc R . . H5B H 1.1381 -0.0258 0.1043 0.044 Uiso 1 1 calc R . . H5C H 1.0986 -0.1008 0.1233 0.044 Uiso 1 1 calc R . . C6 C 0.9323(2) 0.2421(6) 0.1371(3) 0.0180(13) Uani 1 1 d . . . C7 C 0.8927(2) 0.2061(6) 0.0857(4) 0.0238(15) Uani 1 1 d . . . C8 C 0.8819(3) 0.0753(7) 0.0876(4) 0.037(2) Uani 1 1 d . . . H8A H 0.8745 0.0555 0.1308 0.055 Uiso 1 1 calc R . . H8B H 0.9072 0.0288 0.0804 0.055 Uiso 1 1 calc R . . H8C H 0.8573 0.0573 0.0528 0.055 Uiso 1 1 calc R . . C9 C 0.8550(3) 0.2813(11) 0.0981(6) 0.066(4) Uani 1 1 d . . . H9A H 0.8308 0.2715 0.0614 0.100 Uiso 1 1 calc R . . H9B H 0.8639 0.3644 0.1013 0.100 Uiso 1 1 calc R . . H9C H 0.8460 0.2567 0.1396 0.100 Uiso 1 1 calc R . . C10 C 0.9031(4) 0.2348(9) 0.0175(4) 0.051(3) Uani 1 1 d . . . H10A H 0.8769 0.2246 -0.0159 0.076 Uiso 1 1 calc R . . H10B H 0.9259 0.1815 0.0076 0.076 Uiso 1 1 calc R . . H10C H 0.9131 0.3167 0.0168 0.076 Uiso 1 1 calc R . . C11 C 0.9883(2) 0.2416(7) 0.3925(3) 0.0252(15) Uani 1 1 d . . . H11A H 0.9943 0.1601 0.4090 0.030 Uiso 1 1 calc R . . H11B H 0.9735 0.2845 0.4243 0.030 Uiso 1 1 calc R . . C12 C 1.0301(2) 0.3029(7) 0.3861(3) 0.0244(15) Uani 1 1 d . . . H12A H 1.0246 0.3875 0.3755 0.029 Uiso 1 1 calc R . . H12B H 1.0508 0.2974 0.4282 0.029 Uiso 1 1 calc R . . C13 C 0.7181(2) 0.4449(6) 0.3351(3) 0.0193(14) Uani 1 1 d . . . C14 C 0.7391(3) 0.4474(6) 0.2724(4) 0.0280(17) Uani 1 1 d . . . C15 C 0.7653(3) 0.3360(8) 0.2658(6) 0.051(3) Uani 1 1 d . . . H15A H 0.7867 0.3249 0.3060 0.077 Uiso 1 1 calc R . . H15B H 0.7802 0.3437 0.2276 0.077 Uiso 1 1 calc R . . H15C H 0.7458 0.2677 0.2594 0.077 Uiso 1 1 calc R . . C16 C 0.7691(3) 0.5553(7) 0.2741(4) 0.0299(17) Uani 1 1 d . . . H16A H 0.7894 0.5564 0.3161 0.045 Uiso 1 1 calc R . . H16B H 0.7516 0.6277 0.2700 0.045 Uiso 1 1 calc R . . H16C H 0.7854 0.5506 0.2373 0.045 Uiso 1 1 calc R . . C17 C 0.7022(3) 0.4587(8) 0.2127(4) 0.042(2) Uani 1 1 d . . . H17A H 0.7145 0.4673 0.1720 0.063 Uiso 1 1 calc R . . H17B H 0.6845 0.5282 0.2185 0.063 Uiso 1 1 calc R . . H17C H 0.6840 0.3877 0.2095 0.063 Uiso 1 1 calc R . . C18 C 0.5925(2) 0.2728(6) 0.3242(3) 0.0160(13) Uani 1 1 d . . . C19 C 0.5482(2) 0.3114(6) 0.2838(4) 0.0241(15) Uani 1 1 d . . . C20 C 0.5408(3) 0.2506(8) 0.2172(4) 0.042(2) Uani 1 1 d . . . H20A H 0.5141 0.2811 0.1904 0.063 Uiso 1 1 calc R . . H20B H 0.5379 0.1653 0.2235 0.063 Uiso 1 1 calc R . . H20C H 0.5654 0.2661 0.1946 0.063 Uiso 1 1 calc R . . C21 C 0.5455(3) 0.4461(7) 0.2735(5) 0.039(2) Uani 1 1 d . . . H21A H 0.5693 0.4722 0.2514 0.058 Uiso 1 1 calc R . . H21B H 0.5477 0.4856 0.3165 0.058 Uiso 1 1 calc R . . H21C H 0.5177 0.4664 0.2460 0.058 Uiso 1 1 calc R . . C22 C 0.5131(3) 0.2726(10) 0.3247(5) 0.049(3) Uani 1 1 d . . . H22A H 0.4842 0.2881 0.2992 0.074 Uiso 1 1 calc R . . H22B H 0.5168 0.3173 0.3662 0.074 Uiso 1 1 calc R . . H22C H 0.5162 0.1880 0.3345 0.074 Uiso 1 1 calc R . . C23 C 0.6146(2) -0.0630(6) 0.5051(3) 0.0184(13) Uani 1 1 d . . . C24 C 0.5825(2) -0.0720(6) 0.5546(4) 0.0229(15) Uani 1 1 d . . . C25 C 0.5739(3) 0.0513(8) 0.5808(5) 0.039(2) Uani 1 1 d . . . H25A H 0.5504 0.0468 0.6068 0.059 Uiso 1 1 calc R . . H25B H 0.5656 0.1054 0.5435 0.059 Uiso 1 1 calc R . . H25C H 0.6003 0.0805 0.6089 0.059 Uiso 1 1 calc R . . C26 C 0.5401(2) -0.1224(8) 0.5151(5) 0.0358(19) Uani 1 1 d . . . H26A H 0.5453 -0.2026 0.5003 0.054 Uiso 1 1 calc R . . H26B H 0.5303 -0.0721 0.4766 0.054 Uiso 1 1 calc R . . H26C H 0.5178 -0.1246 0.5434 0.054 Uiso 1 1 calc R . . C27 C 0.5981(3) -0.1544(9) 0.6125(5) 0.044(2) Uani 1 1 d . . . H27A H 0.6016 -0.2344 0.5958 0.066 Uiso 1 1 calc R . . H27B H 0.5768 -0.1555 0.6425 0.066 Uiso 1 1 calc R . . H27C H 0.6261 -0.1263 0.6364 0.066 Uiso 1 1 calc R . . C28 C 0.7185(3) 0.2982(8) 0.5627(4) 0.039(2) Uani 1 1 d . . . H28A H 0.7425 0.2603 0.5933 0.047 Uiso 1 1 calc R . . H28B H 0.7162 0.3815 0.5763 0.047 Uiso 1 1 calc R . . C29 C 0.6772(3) 0.2350(8) 0.5643(4) 0.0360(19) Uani 1 1 d . . . H29A H 0.6681 0.2476 0.6078 0.043 Uiso 1 1 calc R . . H29B H 0.6815 0.1492 0.5588 0.043 Uiso 1 1 calc R . . C30 C 0.6710(3) -0.2150(8) 0.2817(4) 0.0329(18) Uani 1 1 d . . . H30A H 0.6826 -0.2566 0.2459 0.040 Uiso 1 1 calc R . . H30B H 0.6644 -0.1325 0.2676 0.040 Uiso 1 1 calc R . . C31 C 0.6306(3) -0.2758(6) 0.2954(4) 0.0285(17) Uani 1 1 d . . . H31A H 0.6073 -0.2697 0.2564 0.034 Uiso 1 1 calc R . . H31B H 0.6365 -0.3606 0.3050 0.034 Uiso 1 1 calc R . . C32 C 0.7492(2) -0.2348(6) 0.5243(3) 0.0164(13) Uani 1 1 d . . . C33 C 0.7942(2) -0.1991(6) 0.5632(4) 0.0258(16) Uani 1 1 d . . . C34 C 0.7953(3) -0.0681(7) 0.5836(4) 0.0329(18) Uani 1 1 d . . . H34A H 0.7708 -0.0511 0.6063 0.049 Uiso 1 1 calc R . . H34B H 0.7932 -0.0184 0.5440 0.049 Uiso 1 1 calc R . . H34C H 0.8225 -0.0513 0.6134 0.049 Uiso 1 1 calc R . . C35 C 0.8276(3) -0.2183(9) 0.5163(5) 0.043(2) Uani 1 1 d . . . H35A H 0.8566 -0.1966 0.5393 0.064 Uiso 1 1 calc R . . H35B H 0.8199 -0.1688 0.4768 0.064 Uiso 1 1 calc R . . H35C H 0.8275 -0.3015 0.5031 0.064 Uiso 1 1 calc R . . C36 C 0.8061(3) -0.2755(8) 0.6240(4) 0.040(2) Uani 1 1 d . . . H36A H 0.7849 -0.2638 0.6536 0.060 Uiso 1 1 calc R . . H36B H 0.8350 -0.2535 0.6471 0.060 Uiso 1 1 calc R . . H36C H 0.8062 -0.3587 0.6108 0.060 Uiso 1 1 calc R . . C37 C 0.9124(2) -0.0385(5) 0.2886(3) 0.0169(13) Uani 1 1 d . . . C38 C 0.8701(2) -0.0082(6) 0.3110(3) 0.0159(13) Uani 1 1 d . . . C39 C 0.8694(2) 0.0317(6) 0.3755(4) 0.0210(14) Uani 1 1 d . . . H39 H 0.8959 0.0423 0.4053 0.025 Uiso 1 1 calc R . . C40 C 0.8308(2) 0.0555(6) 0.3960(3) 0.0210(14) Uani 1 1 d . . . H40 H 0.8307 0.0835 0.4397 0.025 Uiso 1 1 calc R . . C41 C 0.7916(2) 0.0391(6) 0.3534(3) 0.0174(13) Uani 1 1 d . . . C42 C 0.7499(2) 0.0603(5) 0.3784(4) 0.0188(14) Uani 1 1 d . . . C43 C 0.7921(2) 0.0003(6) 0.2884(4) 0.0216(14) Uani 1 1 d . . . H43 H 0.7657 -0.0102 0.2586 0.026 Uiso 1 1 calc R . . C44 C 0.8310(2) -0.0225(6) 0.2680(3) 0.0207(14) Uani 1 1 d . . . H44 H 0.8312 -0.0483 0.2240 0.025 Uiso 1 1 calc R . . C45 C 0.5879(2) -0.4517(6) 0.4781(4) 0.0223(15) Uani 1 1 d . . . C46 C 0.5423(2) -0.4764(6) 0.4900(4) 0.0184(13) Uani 1 1 d . . . C47 C 0.5349(2) -0.5394(6) 0.5457(4) 0.0247(15) Uani 1 1 d . . . H47 H 0.5588 -0.5664 0.5772 0.030 Uiso 1 1 calc R . . C48 C 0.5071(2) -0.4374(6) 0.4449(4) 0.0232(15) Uani 1 1 d . . . H48 H 0.5118 -0.3941 0.4071 0.028 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt1 0.01338(11) 0.01018(11) 0.00826(12) 0.00061(8) 0.00047(9) 0.00066(8) Pt2 0.01457(12) 0.01410(12) 0.01130(12) 0.00062(9) -0.00031(9) 0.00063(8) Pt3 0.01454(12) 0.01334(12) 0.01354(12) 0.00222(9) 0.00163(9) 0.00170(8) Ag1 0.0161(2) 0.0114(2) 0.0140(2) 0.00043(17) 0.00456(18) -0.00019(16) Ag2 0.0155(2) 0.0153(2) 0.0162(2) 0.00200(18) 0.00395(19) 0.00063(17) Ag3 0.0134(2) 0.0147(2) 0.0200(3) 0.00193(19) 0.00209(19) 0.00004(17) N1 0.027(3) 0.014(3) 0.014(3) -0.001(2) 0.008(2) 0.002(2) N2 0.019(3) 0.009(2) 0.013(3) 0.002(2) -0.002(2) 0.0002(19) N3 0.018(3) 0.018(3) 0.011(3) 0.000(2) 0.009(2) -0.001(2) N4 0.019(3) 0.016(3) 0.021(3) -0.001(2) 0.000(2) -0.002(2) N5 0.021(3) 0.023(3) 0.013(3) -0.002(2) 0.001(2) 0.000(2) N6 0.017(3) 0.019(3) 0.011(3) -0.001(2) 0.001(2) 0.001(2) N7 0.036(3) 0.019(3) 0.015(3) 0.001(2) 0.010(3) 0.002(2) N8 0.020(3) 0.028(3) 0.019(3) -0.002(2) -0.003(2) 0.010(2) N9 0.025(3) 0.018(3) 0.017(3) 0.001(2) 0.009(2) 0.002(2) N10 0.024(3) 0.017(3) 0.021(3) -0.001(2) 0.008(2) -0.002(2) N11 0.025(3) 0.019(3) 0.016(3) -0.001(2) 0.010(2) -0.001(2) N12 0.021(3) 0.018(3) 0.018(3) 0.005(2) -0.007(2) 0.000(2) O1 0.042(3) 0.013(2) 0.039(3) 0.002(2) 0.031(3) 0.002(2) O2 0.050(4) 0.024(3) 0.026(3) 0.012(2) -0.019(3) -0.014(2) O3 0.021(2) 0.022(2) 0.026(3) -0.003(2) -0.002(2) 0.0033(19) O4 0.038(3) 0.022(2) 0.033(3) 0.007(2) 0.024(3) 0.006(2) O5 0.025(3) 0.020(2) 0.022(3) 0.005(2) -0.006(2) -0.002(2) O6 0.036(3) 0.021(2) 0.024(3) 0.001(2) 0.015(2) -0.003(2) O7 0.019(2) 0.029(3) 0.021(3) -0.003(2) 0.006(2) -0.001(2) O8 0.029(3) 0.023(2) 0.019(3) -0.003(2) 0.010(2) 0.003(2) O9 0.018(3) 0.032(3) 0.031(3) 0.001(2) 0.008(2) -0.001(2) O10 0.023(3) 0.019(2) 0.028(3) 0.000(2) 0.010(2) 0.0017(19) O11 0.014(2) 0.031(3) 0.040(3) -0.006(2) 0.003(2) -0.002(2) O12 0.026(3) 0.025(3) 0.039(3) 0.003(2) 0.019(2) -0.003(2) O13 0.035(3) 0.029(3) 0.054(4) 0.005(3) -0.011(3) 0.000(2) O14 0.029(3) 0.032(3) 0.052(4) -0.005(3) -0.008(3) 0.001(2) O15 0.060(4) 0.024(3) 0.051(4) 0.003(3) -0.030(3) -0.006(3) O16 0.049(4) 0.038(3) 0.043(4) 0.001(3) 0.013(3) -0.001(3) O17 0.047(4) 0.049(4) 0.042(4) 0.002(3) -0.009(3) -0.002(3) O18 0.135(8) 0.053(5) 0.077(6) 0.034(4) -0.075(6) -0.043(5) C1 0.021(3) 0.015(3) 0.020(3) -0.001(3) 0.005(3) -0.002(3) C2 0.042(5) 0.018(3) 0.030(4) -0.003(3) 0.022(4) -0.002(3) C3 0.093(9) 0.061(6) 0.026(5) 0.012(5) 0.023(5) 0.045(6) C4 0.068(7) 0.033(5) 0.114(10) -0.010(6) 0.074(8) -0.012(5) C5 0.027(4) 0.023(4) 0.042(5) -0.002(3) 0.018(4) 0.002(3) C6 0.020(3) 0.020(3) 0.012(3) 0.002(3) -0.003(3) -0.002(3) C7 0.022(4) 0.025(4) 0.021(4) -0.003(3) -0.007(3) 0.001(3) C8 0.049(5) 0.030(4) 0.024(4) 0.005(3) -0.015(4) -0.015(4) C9 0.023(5) 0.082(8) 0.089(9) -0.037(7) -0.007(5) 0.012(5) C10 0.074(7) 0.048(6) 0.021(4) 0.005(4) -0.018(4) -0.025(5) C11 0.032(4) 0.031(4) 0.013(3) 0.000(3) 0.006(3) -0.002(3) C12 0.026(4) 0.032(4) 0.014(3) -0.004(3) -0.001(3) -0.001(3) C13 0.021(3) 0.020(3) 0.017(3) 0.000(3) 0.005(3) 0.001(3) C14 0.036(4) 0.024(4) 0.029(4) -0.003(3) 0.019(3) -0.002(3) C15 0.065(7) 0.031(5) 0.072(7) -0.003(5) 0.053(6) 0.005(4) C16 0.030(4) 0.035(4) 0.027(4) -0.001(3) 0.013(3) -0.007(3) C17 0.057(6) 0.051(5) 0.018(4) -0.005(4) 0.004(4) -0.019(4) C18 0.017(3) 0.019(3) 0.010(3) 0.003(2) -0.005(2) -0.001(2) C19 0.018(3) 0.021(3) 0.029(4) 0.003(3) -0.006(3) 0.003(3) C20 0.053(6) 0.032(4) 0.030(5) -0.001(4) -0.023(4) 0.005(4) C21 0.036(5) 0.025(4) 0.047(5) 0.002(4) -0.016(4) 0.007(3) C22 0.018(4) 0.070(7) 0.058(6) 0.014(5) 0.000(4) 0.002(4) C23 0.017(3) 0.023(3) 0.015(3) 0.001(3) 0.002(3) -0.001(3) C24 0.021(3) 0.026(4) 0.024(4) 0.003(3) 0.010(3) 0.001(3) C25 0.042(5) 0.043(5) 0.039(5) -0.012(4) 0.024(4) -0.006(4) C26 0.019(4) 0.046(5) 0.044(5) -0.004(4) 0.010(4) -0.002(3) C27 0.050(6) 0.056(6) 0.032(5) 0.017(4) 0.020(4) 0.008(4) C28 0.038(5) 0.047(5) 0.029(5) -0.003(4) -0.002(4) 0.004(4) C29 0.049(5) 0.041(5) 0.017(4) 0.006(3) 0.003(4) -0.002(4) C30 0.046(5) 0.038(4) 0.016(4) 0.000(3) 0.010(3) 0.005(4) C31 0.036(4) 0.020(4) 0.025(4) -0.002(3) -0.008(3) 0.002(3) C32 0.016(3) 0.023(3) 0.010(3) 0.000(2) -0.001(2) -0.002(2) C33 0.023(4) 0.024(4) 0.026(4) 0.000(3) -0.006(3) -0.005(3) C34 0.038(5) 0.027(4) 0.029(4) -0.005(3) -0.007(4) -0.004(3) C35 0.020(4) 0.054(6) 0.053(6) -0.007(5) 0.004(4) -0.010(4) C36 0.039(5) 0.036(5) 0.036(5) 0.007(4) -0.015(4) -0.012(4) C37 0.021(3) 0.010(3) 0.020(3) 0.002(2) 0.005(3) 0.000(2) C38 0.016(3) 0.014(3) 0.018(3) 0.001(2) 0.005(3) 0.001(2) C39 0.017(3) 0.026(3) 0.019(4) -0.008(3) 0.001(3) -0.001(3) C40 0.023(4) 0.026(4) 0.014(3) -0.004(3) 0.004(3) -0.002(3) C41 0.018(3) 0.014(3) 0.021(4) 0.000(3) 0.005(3) 0.001(2) C42 0.023(3) 0.013(3) 0.022(4) 0.002(3) 0.007(3) 0.001(2) C43 0.018(3) 0.026(4) 0.019(4) -0.006(3) -0.001(3) -0.003(3) C44 0.029(4) 0.021(3) 0.012(3) -0.006(3) 0.002(3) -0.001(3) C45 0.019(3) 0.016(3) 0.034(4) -0.003(3) 0.011(3) 0.000(3) C46 0.016(3) 0.019(3) 0.022(4) 0.001(3) 0.008(3) 0.000(2) C47 0.023(4) 0.027(4) 0.025(4) 0.007(3) 0.006(3) 0.003(3) C48 0.023(4) 0.027(4) 0.020(4) 0.008(3) 0.008(3) 0.001(3) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt1 N2 2.003(5) . ? Pt1 N1 2.006(5) . ? Pt1 N4 2.046(6) . ? Pt1 N3 2.061(5) . ? Pt1 Ag1 2.9084(7) 2_755 ? Pt1 Ag1 2.9105(8) . ? Pt2 N5 2.002(6) . ? Pt2 N6 2.012(5) . ? Pt2 N8 2.059(6) . ? Pt2 N7 2.060(6) . ? Pt2 Ag2 2.9122(8) . ? Pt2 Ag3 2.9171(8) 1_565 ? Pt3 N10 2.007(6) . ? Pt3 N9 2.013(5) . ? Pt3 N12 2.051(6) . ? Pt3 N11 2.061(5) . ? Pt3 Ag3 2.8859(8) . ? Pt3 Ag2 2.9008(8) . ? Ag1 O1 2.280(5) . ? Ag1 O7 2.309(5) . ? Ag1 O2 2.397(5) 2_745 ? Ag1 Pt1 2.9084(7) 2_745 ? Ag2 O4 2.275(5) . ? Ag2 O9 2.314(5) . ? Ag2 O3 2.456(5) . ? Ag3 O5 2.393(5) . ? Ag3 O6 2.398(5) 1_545 ? Ag3 O11 2.503(5) . ? Ag3 Pt2 2.9171(8) 1_545 ? N1 C1 1.307(8) . ? N1 H1 0.8800 . ? N2 C6 1.317(8) . ? N2 H2 0.8800 . ? N3 C11 1.486(9) . ? N3 H3D 0.9200 . ? N3 H3E 0.9200 . ? N4 C12 1.496(9) . ? N4 H4D 0.9200 . ? N4 H4E 0.9200 . ? N5 C13 1.320(9) . ? N5 H5 0.9200 . ? N6 C18 1.317(8) . ? N6 H6 0.9200 . ? N7 C29 1.498(10) . ? N7 H7A 0.9200 . ? N7 H7B 0.9200 . ? N8 C28 1.489(10) . ? N8 H8D 0.9200 . ? N8 H8E 0.9200 . ? N9 C23 1.312(8) . ? N9 H9 0.9200 . ? N10 C32 1.328(9) . ? N10 H10 0.9200 . ? N11 C30 1.485(10) . ? N11 H11C 0.9200 . ? N11 H11D 0.9200 . ? N12 C31 1.481(9) . ? N12 H12C 0.9200 . ? N12 H12D 0.9200 . ? O1 C1 1.270(8) . ? O2 C6 1.271(8) . ? O2 Ag1 2.397(5) 2_755 ? O3 C18 1.256(8) . ? O4 C23 1.259(8) . ? O5 C32 1.270(8) . ? O6 C13 1.278(8) . ? O6 Ag3 2.398(5) 1_565 ? O7 C37 1.279(9) . ? O8 C37 1.243(8) . ? O9 C42 1.288(9) . ? O10 C42 1.244(9) . ? O11 C45 1.270(9) . ? O12 C45 1.251(9) . ? C1 C2 1.532(9) . ? C2 C5 1.535(10) . ? C2 C4 1.535(12) . ? C2 C3 1.538(13) . ? C3 H3A 0.9800 . ? C3 H3B 0.9800 . ? C3 H3C 0.9800 . ? C4 H4A 0.9800 . ? C4 H4B 0.9800 . ? C4 H4C 0.9800 . ? C5 H5A 0.9800 . ? C5 H5B 0.9800 . ? C5 H5C 0.9800 . ? C6 C7 1.540(9) . ? C7 C9 1.507(11) . ? C7 C8 1.520(10) . ? C7 C10 1.523(12) . ? C8 H8A 0.9800 . ? C8 H8B 0.9800 . ? C8 H8C 0.9800 . ? C9 H9A 0.9800 . ? C9 H9B 0.9800 . ? C9 H9C 0.9800 . ? C10 H10A 0.9800 . ? C10 H10B 0.9800 . ? C10 H10C 0.9800 . ? C11 C12 1.504(10) . ? C11 H11A 0.9900 . ? C11 H11B 0.9900 . ? C12 H12A 0.9900 . ? C12 H12B 0.9900 . ? C13 C14 1.540(10) . ? C14 C15 1.522(11) . ? C14 C16 1.537(10) . ? C14 C17 1.539(12) . ? C15 H15A 0.9800 . ? C15 H15B 0.9800 . ? C15 H15C 0.9800 . ? C16 H16A 0.9800 . ? C16 H16B 0.9800 . ? C16 H16C 0.9800 . ? C17 H17A 0.9800 . ? C17 H17B 0.9800 . ? C17 H17C 0.9800 . ? C18 C19 1.552(9) . ? C19 C20 1.511(11) . ? C19 C21 1.540(10) . ? C19 C22 1.551(11) . ? C20 H20A 0.9800 . ? C20 H20B 0.9800 . ? C20 H20C 0.9800 . ? C21 H21A 0.9800 . ? C21 H21B 0.9800 . ? C21 H21C 0.9800 . ? C22 H22A 0.9800 . ? C22 H22B 0.9800 . ? C22 H22C 0.9800 . ? C23 C24 1.545(9) . ? C24 C27 1.524(11) . ? C24 C25 1.535(11) . ? C24 C26 1.540(11) . ? C25 H25A 0.9800 . ? C25 H25B 0.9800 . ? C25 H25C 0.9800 . ? C26 H26A 0.9800 . ? C26 H26B 0.9800 . ? C26 H26C 0.9800 . ? C27 H27A 0.9800 . ? C27 H27B 0.9800 . ? C27 H27C 0.9800 . ? C28 C29 1.484(12) . ? C28 H28A 0.9900 . ? C28 H28B 0.9900 . ? C29 H29A 0.9900 . ? C29 H29B 0.9900 . ? C30 C31 1.507(11) . ? C30 H30A 0.9900 . ? C30 H30B 0.9900 . ? C31 H31A 0.9900 . ? C31 H31B 0.9900 . ? C32 C33 1.547(9) . ? C33 C36 1.511(11) . ? C33 C34 1.539(10) . ? C33 C35 1.550(11) . ? C34 H34A 0.9800 . ? C34 H34B 0.9800 . ? C34 H34C 0.9800 . ? C35 H35A 0.9800 . ? C35 H35B 0.9800 . ? C35 H35C 0.9800 . ? C36 H36A 0.9800 . ? C36 H36B 0.9800 . ? C36 H36C 0.9800 . ? C37 C38 1.508(9) . ? C38 C44 1.392(10) . ? C38 C39 1.400(9) . ? C39 C40 1.372(9) . ? C39 H39 0.9500 . ? C40 C41 1.393(10) . ? C40 H40 0.9500 . ? C41 C43 1.406(10) . ? C41 C42 1.498(9) . ? C43 C44 1.375(10) . ? C43 H43 0.9500 . ? C44 H44 0.9500 . ? C45 C46 1.511(9) . ? C46 C48 1.386(10) . ? C46 C47 1.398(10) . ? C47 C48 1.384(10) 3_646 ? C47 H47 0.9500 . ? C48 C47 1.384(10) 3_646 ? C48 H48 0.9500 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N2 Pt1 N1 91.2(2) . . ? N2 Pt1 N4 176.2(2) . . ? N1 Pt1 N4 92.3(2) . . ? N2 Pt1 N3 92.8(2) . . ? N1 Pt1 N3 175.3(2) . . ? N4 Pt1 N3 83.6(2) . . ? N2 Pt1 Ag1 88.55(15) . 2_755 ? N1 Pt1 Ag1 88.92(16) . 2_755 ? N4 Pt1 Ag1 90.06(16) . 2_755 ? N3 Pt1 Ag1 88.72(15) . 2_755 ? N2 Pt1 Ag1 89.04(15) . . ? N1 Pt1 Ag1 86.07(16) . . ? N4 Pt1 Ag1 92.66(16) . . ? N3 Pt1 Ag1 96.45(15) . . ? Ag1 Pt1 Ag1 174.395(10) 2_755 . ? N5 Pt2 N6 90.0(2) . . ? N5 Pt2 N8 92.9(2) . . ? N6 Pt2 N8 176.7(2) . . ? N5 Pt2 N7 175.3(2) . . ? N6 Pt2 N7 93.9(2) . . ? N8 Pt2 N7 83.3(2) . . ? N5 Pt2 Ag2 91.93(16) . . ? N6 Pt2 Ag2 87.32(15) . . ? N8 Pt2 Ag2 94.13(17) . . ? N7 Pt2 Ag2 85.61(16) . . ? N5 Pt2 Ag3 88.52(16) . 1_565 ? N6 Pt2 Ag3 90.06(15) . 1_565 ? N8 Pt2 Ag3 88.46(17) . 1_565 ? N7 Pt2 Ag3 94.12(16) . 1_565 ? Ag2 Pt2 Ag3 177.340(16) . 1_565 ? N10 Pt3 N9 91.1(2) . . ? N10 Pt3 N12 176.0(2) . . ? N9 Pt3 N12 92.7(2) . . ? N10 Pt3 N11 92.4(2) . . ? N9 Pt3 N11 176.1(2) . . ? N12 Pt3 N11 83.7(2) . . ? N10 Pt3 Ag3 88.80(16) . . ? N9 Pt3 Ag3 88.43(16) . . ? N12 Pt3 Ag3 90.32(16) . . ? N11 Pt3 Ag3 90.09(16) . . ? N10 Pt3 Ag2 92.01(16) . . ? N9 Pt3 Ag2 85.06(16) . . ? N12 Pt3 Ag2 89.30(16) . . ? N11 Pt3 Ag2 96.36(16) . . ? Ag3 Pt3 Ag2 173.454(16) . . ? O1 Ag1 O7 156.29(19) . . ? O1 Ag1 O2 106.0(2) . 2_745 ? O7 Ag1 O2 97.6(2) . 2_745 ? O1 Ag1 Pt1 88.58(12) . 2_745 ? O7 Ag1 Pt1 100.88(13) . 2_745 ? O2 Ag1 Pt1 73.69(12) 2_745 2_745 ? O1 Ag1 Pt1 76.71(12) . . ? O7 Ag1 Pt1 85.82(13) . . ? O2 Ag1 Pt1 131.11(13) 2_745 . ? Pt1 Ag1 Pt1 153.67(2) 2_745 . ? O4 Ag2 O9 161.77(19) . . ? O4 Ag2 O3 100.00(19) . . ? O9 Ag2 O3 97.24(18) . . ? O4 Ag2 Pt3 77.73(13) . . ? O9 Ag2 Pt3 86.58(13) . . ? O3 Ag2 Pt3 130.63(12) . . ? O4 Ag2 Pt2 94.15(13) . . ? O9 Ag2 Pt2 96.21(13) . . ? O3 Ag2 Pt2 74.12(12) . . ? Pt3 Ag2 Pt2 154.68(2) . . ? O5 Ag3 O6 94.72(18) . 1_545 ? O5 Ag3 O11 107.17(18) . . ? O6 Ag3 O11 155.73(18) 1_545 . ? O5 Ag3 Pt3 75.77(11) . . ? O6 Ag3 Pt3 87.85(12) 1_545 . ? O11 Ag3 Pt3 107.29(12) . . ? O5 Ag3 Pt2 124.63(12) . 1_545 ? O6 Ag3 Pt2 75.00(12) 1_545 1_545 ? O11 Ag3 Pt2 83.81(12) . 1_545 ? Pt3 Ag3 Pt2 153.69(2) . 1_545 ? C1 N1 Pt1 127.7(5) . . ? C1 N1 H1 116.1 . . ? Pt1 N1 H1 116.1 . . ? C6 N2 Pt1 125.4(4) . . ? C6 N2 H2 117.3 . . ? Pt1 N2 H2 117.3 . . ? C11 N3 Pt1 108.5(4) . . ? C11 N3 H3D 110.0 . . ? Pt1 N3 H3D 110.0 . . ? C11 N3 H3E 110.0 . . ? Pt1 N3 H3E 110.0 . . ? H3D N3 H3E 108.4 . . ? C12 N4 Pt1 109.0(4) . . ? C12 N4 H4D 109.9 . . ? Pt1 N4 H4D 109.9 . . ? C12 N4 H4E 109.9 . . ? Pt1 N4 H4E 109.9 . . ? H4D N4 H4E 108.3 . . ? C13 N5 Pt2 127.5(5) . . ? C13 N5 H5 105.2 . . ? Pt2 N5 H5 105.2 . . ? C18 N6 Pt2 127.1(5) . . ? C18 N6 H6 105.3 . . ? Pt2 N6 H6 105.3 . . ? C29 N7 Pt2 108.5(5) . . ? C29 N7 H7A 110.0 . . ? Pt2 N7 H7A 110.0 . . ? C29 N7 H7B 110.0 . . ? Pt2 N7 H7B 110.0 . . ? H7A N7 H7B 108.4 . . ? C28 N8 Pt2 109.4(5) . . ? C28 N8 H8D 109.8 . . ? Pt2 N8 H8D 109.8 . . ? C28 N8 H8E 109.8 . . ? Pt2 N8 H8E 109.8 . . ? H8D N8 H8E 108.2 . . ? C23 N9 Pt3 127.1(5) . . ? C23 N9 H9 105.2 . . ? Pt3 N9 H9 105.3 . . ? C32 N10 Pt3 126.4(5) . . ? C32 N10 H10 105.5 . . ? Pt3 N10 H10 105.5 . . ? C30 N11 Pt3 108.0(4) . . ? C30 N11 H11C 110.1 . . ? Pt3 N11 H11C 110.1 . . ? C30 N11 H11D 110.1 . . ? Pt3 N11 H11D 110.1 . . ? H11C N11 H11D 108.4 . . ? C31 N12 Pt3 108.3(4) . . ? C31 N12 H12C 110.0 . . ? Pt3 N12 H12C 110.0 . . ? C31 N12 H12D 110.0 . . ? Pt3 N12 H12D 110.0 . . ? H12C N12 H12D 108.4 . . ? C1 O1 Ag1 126.9(4) . . ? C6 O2 Ag1 124.6(4) . 2_755 ? C18 O3 Ag2 122.1(4) . . ? C23 O4 Ag2 125.0(4) . . ? C32 O5 Ag3 124.7(4) . . ? C13 O6 Ag3 125.8(4) . 1_565 ? C37 O7 Ag1 110.3(4) . . ? C42 O9 Ag2 105.6(4) . . ? C45 O11 Ag3 95.2(4) . . ? O1 C1 N1 122.5(6) . . ? O1 C1 C2 118.4(6) . . ? N1 C1 C2 119.0(6) . . ? C1 C2 C5 110.1(6) . . ? C1 C2 C4 110.8(6) . . ? C5 C2 C4 108.9(7) . . ? C1 C2 C3 106.9(7) . . ? C5 C2 C3 109.6(7) . . ? C4 C2 C3 110.6(8) . . ? C2 C3 H3A 109.5 . . ? C2 C3 H3B 109.5 . . ? H3A C3 H3B 109.5 . . ? C2 C3 H3C 109.5 . . ? H3A C3 H3C 109.5 . . ? H3B C3 H3C 109.5 . . ? C2 C4 H4A 109.5 . . ? C2 C4 H4B 109.5 . . ? H4A C4 H4B 109.5 . . ? C2 C4 H4C 109.5 . . ? H4A C4 H4C 109.5 . . ? H4B C4 H4C 109.5 . . ? C2 C5 H5A 109.5 . . ? C2 C5 H5B 109.5 . . ? H5A C5 H5B 109.5 . . ? C2 C5 H5C 109.5 . . ? H5A C5 H5C 109.5 . . ? H5B C5 H5C 109.5 . . ? O2 C6 N2 122.4(6) . . ? O2 C6 C7 117.1(6) . . ? N2 C6 C7 120.5(6) . . ? C9 C7 C8 111.3(8) . . ? C9 C7 C10 109.1(8) . . ? C8 C7 C10 108.2(7) . . ? C9 C7 C6 107.2(7) . . ? C8 C7 C6 113.3(6) . . ? C10 C7 C6 107.5(6) . . ? C7 C8 H8A 109.5 . . ? C7 C8 H8B 109.5 . . ? H8A C8 H8B 109.5 . . ? C7 C8 H8C 109.5 . . ? H8A C8 H8C 109.5 . . ? H8B C8 H8C 109.5 . . ? C7 C9 H9A 109.5 . . ? C7 C9 H9B 109.5 . . ? H9A C9 H9B 109.5 . . ? C7 C9 H9C 109.5 . . ? H9A C9 H9C 109.5 . . ? H9B C9 H9C 109.5 . . ? C7 C10 H10A 109.5 . . ? C7 C10 H10B 109.5 . . ? H10A C10 H10B 109.5 . . ? C7 C10 H10C 109.5 . . ? H10A C10 H10C 109.5 . . ? H10B C10 H10C 109.5 . . ? N3 C11 C12 108.3(5) . . ? N3 C11 H11A 110.0 . . ? C12 C11 H11A 110.0 . . ? N3 C11 H11B 110.0 . . ? C12 C11 H11B 110.0 . . ? H11A C11 H11B 108.4 . . ? N4 C12 C11 107.8(6) . . ? N4 C12 H12A 110.1 . . ? C11 C12 H12A 110.1 . . ? N4 C12 H12B 110.1 . . ? C11 C12 H12B 110.1 . . ? H12A C12 H12B 108.5 . . ? O6 C13 N5 122.3(6) . . ? O6 C13 C14 118.9(6) . . ? N5 C13 C14 118.8(6) . . ? C15 C14 C16 109.0(7) . . ? C15 C14 C17 109.9(8) . . ? C16 C14 C17 109.0(7) . . ? C15 C14 C13 111.7(6) . . ? C16 C14 C13 109.9(6) . . ? C17 C14 C13 107.3(6) . . ? C14 C15 H15A 109.5 . . ? C14 C15 H15B 109.5 . . ? H15A C15 H15B 109.5 . . ? C14 C15 H15C 109.5 . . ? H15A C15 H15C 109.5 . . ? H15B C15 H15C 109.5 . . ? C14 C16 H16A 109.5 . . ? C14 C16 H16B 109.5 . . ? H16A C16 H16B 109.5 . . ? C14 C16 H16C 109.5 . . ? H16A C16 H16C 109.5 . . ? H16B C16 H16C 109.5 . . ? C14 C17 H17A 109.5 . . ? C14 C17 H17B 109.5 . . ? H17A C17 H17B 109.5 . . ? C14 C17 H17C 109.5 . . ? H17A C17 H17C 109.5 . . ? H17B C17 H17C 109.5 . . ? O3 C18 N6 122.6(6) . . ? O3 C18 C19 118.5(6) . . ? N6 C18 C19 118.9(6) . . ? C20 C19 C21 109.3(7) . . ? C20 C19 C22 110.2(7) . . ? C21 C19 C22 109.1(7) . . ? C20 C19 C18 109.9(6) . . ? C21 C19 C18 112.0(6) . . ? C22 C19 C18 106.3(6) . . ? C19 C20 H20A 109.5 . . ? C19 C20 H20B 109.5 . . ? H20A C20 H20B 109.5 . . ? C19 C20 H20C 109.5 . . ? H20A C20 H20C 109.5 . . ? H20B C20 H20C 109.5 . . ? C19 C21 H21A 109.5 . . ? C19 C21 H21B 109.5 . . ? H21A C21 H21B 109.5 . . ? C19 C21 H21C 109.5 . . ? H21A C21 H21C 109.5 . . ? H21B C21 H21C 109.5 . . ? C19 C22 H22A 109.5 . . ? C19 C22 H22B 109.5 . . ? H22A C22 H22B 109.5 . . ? C19 C22 H22C 109.5 . . ? H22A C22 H22C 109.5 . . ? H22B C22 H22C 109.5 . . ? O4 C23 N9 123.9(6) . . ? O4 C23 C24 118.0(6) . . ? N9 C23 C24 118.0(6) . . ? C27 C24 C25 109.6(7) . . ? C27 C24 C26 108.5(7) . . ? C25 C24 C26 109.6(7) . . ? C27 C24 C23 113.1(6) . . ? C25 C24 C23 109.9(6) . . ? C26 C24 C23 106.0(6) . . ? C24 C25 H25A 109.5 . . ? C24 C25 H25B 109.5 . . ? H25A C25 H25B 109.5 . . ? C24 C25 H25C 109.5 . . ? H25A C25 H25C 109.5 . . ? H25B C25 H25C 109.5 . . ? C24 C26 H26A 109.5 . . ? C24 C26 H26B 109.5 . . ? H26A C26 H26B 109.5 . . ? C24 C26 H26C 109.5 . . ? H26A C26 H26C 109.5 . . ? H26B C26 H26C 109.5 . . ? C24 C27 H27A 109.5 . . ? C24 C27 H27B 109.5 . . ? H27A C27 H27B 109.5 . . ? C24 C27 H27C 109.5 . . ? H27A C27 H27C 109.5 . . ? H27B C27 H27C 109.5 . . ? C29 C28 N8 107.5(7) . . ? C29 C28 H28A 110.2 . . ? N8 C28 H28A 110.2 . . ? C29 C28 H28B 110.2 . . ? N8 C28 H28B 110.2 . . ? H28A C28 H28B 108.5 . . ? C28 C29 N7 110.6(7) . . ? C28 C29 H29A 109.5 . . ? N7 C29 H29A 109.5 . . ? C28 C29 H29B 109.5 . . ? N7 C29 H29B 109.5 . . ? H29A C29 H29B 108.1 . . ? N11 C30 C31 108.0(6) . . ? N11 C30 H30A 110.1 . . ? C31 C30 H30A 110.1 . . ? N11 C30 H30B 110.1 . . ? C31 C30 H30B 110.1 . . ? H30A C30 H30B 108.4 . . ? N12 C31 C30 107.9(6) . . ? N12 C31 H31A 110.1 . . ? C30 C31 H31A 110.1 . . ? N12 C31 H31B 110.1 . . ? C30 C31 H31B 110.1 . . ? H31A C31 H31B 108.4 . . ? O5 C32 N10 123.3(6) . . ? O5 C32 C33 118.2(6) . . ? N10 C32 C33 118.4(6) . . ? C36 C33 C34 109.7(7) . . ? C36 C33 C32 110.6(6) . . ? C34 C33 C32 111.6(6) . . ? C36 C33 C35 109.4(7) . . ? C34 C33 C35 108.4(7) . . ? C32 C33 C35 107.0(6) . . ? C33 C34 H34A 109.5 . . ? C33 C34 H34B 109.5 . . ? H34A C34 H34B 109.5 . . ? C33 C34 H34C 109.5 . . ? H34A C34 H34C 109.5 . . ? H34B C34 H34C 109.5 . . ? C33 C35 H35A 109.5 . . ? C33 C35 H35B 109.5 . . ? H35A C35 H35B 109.5 . . ? C33 C35 H35C 109.5 . . ? H35A C35 H35C 109.5 . . ? H35B C35 H35C 109.5 . . ? C33 C36 H36A 109.5 . . ? C33 C36 H36B 109.5 . . ? H36A C36 H36B 109.5 . . ? C33 C36 H36C 109.5 . . ? H36A C36 H36C 109.5 . . ? H36B C36 H36C 109.5 . . ? O8 C37 O7 124.3(6) . . ? O8 C37 C38 119.0(6) . . ? O7 C37 C38 116.7(6) . . ? C44 C38 C39 118.9(6) . . ? C44 C38 C37 120.1(6) . . ? C39 C38 C37 120.9(6) . . ? C40 C39 C38 120.5(6) . . ? C40 C39 H39 119.8 . . ? C38 C39 H39 119.8 . . ? C39 C40 C41 120.6(6) . . ? C39 C40 H40 119.7 . . ? C41 C40 H40 119.7 . . ? C40 C41 C43 119.1(6) . . ? C40 C41 C42 119.2(6) . . ? C43 C41 C42 121.7(6) . . ? O10 C42 O9 123.4(6) . . ? O10 C42 C41 119.5(6) . . ? O9 C42 C41 117.1(6) . . ? C44 C43 C41 120.0(6) . . ? C44 C43 H43 120.0 . . ? C41 C43 H43 120.0 . . ? C43 C44 C38 120.9(6) . . ? C43 C44 H44 119.6 . . ? C38 C44 H44 119.6 . . ? O12 C45 O11 123.8(6) . . ? O12 C45 C46 117.9(7) . . ? O11 C45 C46 118.3(7) . . ? C48 C46 C47 119.0(6) . . ? C48 C46 C45 119.9(6) . . ? C47 C46 C45 121.1(6) . . ? C48 C47 C46 120.1(7) 3_646 . ? C48 C47 H47 120.0 3_646 . ? C46 C47 H47 120.0 . . ? C47 C48 C46 120.9(7) 3_646 . ? C47 C48 H48 119.5 3_646 . ? C46 C48 H48 119.5 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N2 Pt1 Ag1 O1 90.2(2) . . . . ? N1 Pt1 Ag1 O1 -1.1(2) . . . . ? N4 Pt1 Ag1 O1 -93.2(2) . . . . ? N3 Pt1 Ag1 O1 -177.1(2) . . . . ? Ag1 Pt1 Ag1 O1 25.63(19) 2_755 . . . ? N2 Pt1 Ag1 O7 -73.7(2) . . . . ? N1 Pt1 Ag1 O7 -164.9(2) . . . . ? N4 Pt1 Ag1 O7 102.9(2) . . . . ? N3 Pt1 Ag1 O7 19.0(2) . . . . ? Ag1 Pt1 Ag1 O7 -138.22(16) 2_755 . . . ? N2 Pt1 Ag1 O2 -170.1(3) . . . 2_745 ? N1 Pt1 Ag1 O2 98.7(3) . . . 2_745 ? N4 Pt1 Ag1 O2 6.5(3) . . . 2_745 ? N3 Pt1 Ag1 O2 -77.4(3) . . . 2_745 ? Ag1 Pt1 Ag1 O2 125.4(2) 2_755 . . 2_745 ? N2 Pt1 Ag1 Pt1 32.51(16) . . . 2_745 ? N1 Pt1 Ag1 Pt1 -58.72(17) . . . 2_745 ? N4 Pt1 Ag1 Pt1 -150.89(16) . . . 2_745 ? N3 Pt1 Ag1 Pt1 125.25(16) . . . 2_745 ? Ag1 Pt1 Ag1 Pt1 -32.02(10) 2_755 . . 2_745 ? N10 Pt3 Ag2 O4 -97.9(2) . . . . ? N9 Pt3 Ag2 O4 -6.9(2) . . . . ? N12 Pt3 Ag2 O4 85.9(2) . . . . ? N11 Pt3 Ag2 O4 169.5(2) . . . . ? Ag3 Pt3 Ag2 O4 -0.8(2) . . . . ? N10 Pt3 Ag2 O9 72.8(2) . . . . ? N9 Pt3 Ag2 O9 163.7(2) . . . . ? N12 Pt3 Ag2 O9 -103.4(2) . . . . ? N11 Pt3 Ag2 O9 -19.9(2) . . . . ? Ag3 Pt3 Ag2 O9 169.9(2) . . . . ? N10 Pt3 Ag2 O3 169.4(2) . . . . ? N9 Pt3 Ag2 O3 -99.7(2) . . . . ? N12 Pt3 Ag2 O3 -6.8(2) . . . . ? N11 Pt3 Ag2 O3 76.7(2) . . . . ? Ag3 Pt3 Ag2 O3 -93.5(2) . . . . ? N10 Pt3 Ag2 Pt2 -24.52(17) . . . . ? N9 Pt3 Ag2 Pt2 66.43(18) . . . . ? N12 Pt3 Ag2 Pt2 159.25(17) . . . . ? N11 Pt3 Ag2 Pt2 -117.17(17) . . . . ? Ag3 Pt3 Ag2 Pt2 72.55(16) . . . . ? N5 Pt2 Ag2 O4 -173.3(2) . . . . ? N6 Pt2 Ag2 O4 -83.3(2) . . . . ? N8 Pt2 Ag2 O4 93.7(2) . . . . ? N7 Pt2 Ag2 O4 10.8(2) . . . . ? Ag3 Pt2 Ag2 O4 -73.5(4) 1_565 . . . ? N5 Pt2 Ag2 O9 21.8(2) . . . . ? N6 Pt2 Ag2 O9 111.7(2) . . . . ? N8 Pt2 Ag2 O9 -71.3(2) . . . . ? N7 Pt2 Ag2 O9 -154.2(2) . . . . ? Ag3 Pt2 Ag2 O9 121.5(4) 1_565 . . . ? N5 Pt2 Ag2 O3 -74.0(2) . . . . ? N6 Pt2 Ag2 O3 15.9(2) . . . . ? N8 Pt2 Ag2 O3 -167.1(2) . . . . ? N7 Pt2 Ag2 O3 110.0(2) . . . . ? Ag3 Pt2 Ag2 O3 25.7(4) 1_565 . . . ? N5 Pt2 Ag2 Pt3 116.92(17) . . . . ? N6 Pt2 Ag2 Pt3 -153.14(16) . . . . ? N8 Pt2 Ag2 Pt3 23.89(18) . . . . ? N7 Pt2 Ag2 Pt3 -59.05(18) . . . . ? Ag3 Pt2 Ag2 Pt3 -143.3(3) 1_565 . . . ? N10 Pt3 Ag3 O5 5.4(2) . . . . ? N9 Pt3 Ag3 O5 -85.7(2) . . . . ? N12 Pt3 Ag3 O5 -178.5(2) . . . . ? N11 Pt3 Ag3 O5 97.8(2) . . . . ? Ag2 Pt3 Ag3 O5 -91.8(2) . . . . ? N10 Pt3 Ag3 O6 -90.0(2) . . . 1_545 ? N9 Pt3 Ag3 O6 178.8(2) . . . 1_545 ? N12 Pt3 Ag3 O6 86.1(2) . . . 1_545 ? N11 Pt3 Ag3 O6 2.4(2) . . . 1_545 ? Ag2 Pt3 Ag3 O6 172.7(2) . . . 1_545 ? N10 Pt3 Ag3 O11 109.3(2) . . . . ? N9 Pt3 Ag3 O11 18.1(2) . . . . ? N12 Pt3 Ag3 O11 -74.6(2) . . . . ? N11 Pt3 Ag3 O11 -158.3(2) . . . . ? Ag2 Pt3 Ag3 O11 12.0(2) . . . . ? N10 Pt3 Ag3 Pt2 -138.68(17) . . . 1_545 ? N9 Pt3 Ag3 Pt2 130.17(18) . . . 1_545 ? N12 Pt3 Ag3 Pt2 37.43(18) . . . 1_545 ? N11 Pt3 Ag3 Pt2 -46.27(17) . . . 1_545 ? Ag2 Pt3 Ag3 Pt2 124.07(14) . . . 1_545 ? N2 Pt1 N1 C1 -88.7(6) . . . . ? N4 Pt1 N1 C1 92.8(6) . . . . ? N3 Pt1 N1 C1 123(3) . . . . ? Ag1 Pt1 N1 C1 -177.2(6) 2_755 . . . ? Ag1 Pt1 N1 C1 0.3(6) . . . . ? N1 Pt1 N2 C6 -74.0(6) . . . . ? N4 Pt1 N2 C6 83(3) . . . . ? N3 Pt1 N2 C6 103.6(6) . . . . ? Ag1 Pt1 N2 C6 14.9(5) 2_755 . . . ? Ag1 Pt1 N2 C6 -160.0(5) . . . . ? N2 Pt1 N3 C11 166.8(4) . . . . ? N1 Pt1 N3 C11 -45(3) . . . . ? N4 Pt1 N3 C11 -14.5(4) . . . . ? Ag1 Pt1 N3 C11 -104.7(4) 2_755 . . . ? Ag1 Pt1 N3 C11 77.5(4) . . . . ? N2 Pt1 N4 C12 6(3) . . . . ? N1 Pt1 N4 C12 163.7(4) . . . . ? N3 Pt1 N4 C12 -13.9(4) . . . . ? Ag1 Pt1 N4 C12 74.8(4) 2_755 . . . ? Ag1 Pt1 N4 C12 -110.1(4) . . . . ? N6 Pt2 N5 C13 95.1(6) . . . . ? N8 Pt2 N5 C13 -83.3(6) . . . . ? N7 Pt2 N5 C13 -119(3) . . . . ? Ag2 Pt2 N5 C13 -177.6(6) . . . . ? Ag3 Pt2 N5 C13 5.1(6) 1_565 . . . ? N5 Pt2 N6 C18 74.0(6) . . . . ? N8 Pt2 N6 C18 -134(4) . . . . ? N7 Pt2 N6 C18 -103.3(6) . . . . ? Ag2 Pt2 N6 C18 -17.9(5) . . . . ? Ag3 Pt2 N6 C18 162.5(5) 1_565 . . . ? N5 Pt2 N7 C29 26(3) . . . . ? N6 Pt2 N7 C29 171.9(5) . . . . ? N8 Pt2 N7 C29 -9.8(5) . . . . ? Ag2 Pt2 N7 C29 84.9(5) . . . . ? Ag3 Pt2 N7 C29 -97.7(5) 1_565 . . . ? N5 Pt2 N8 C28 165.8(5) . . . . ? N6 Pt2 N8 C28 14(4) . . . . ? N7 Pt2 N8 C28 -17.0(5) . . . . ? Ag2 Pt2 N8 C28 -102.1(5) . . . . ? Ag3 Pt2 N8 C28 77.3(5) 1_565 . . . ? N10 Pt3 N9 C23 103.0(6) . . . . ? N12 Pt3 N9 C23 -77.9(6) . . . . ? N11 Pt3 N9 C23 -101(3) . . . . ? Ag3 Pt3 N9 C23 -168.2(6) . . . . ? Ag2 Pt3 N9 C23 11.1(6) . . . . ? N9 Pt3 N10 C32 84.1(6) . . . . ? N12 Pt3 N10 C32 -82(3) . . . . ? N11 Pt3 N10 C32 -94.4(6) . . . . ? Ag3 Pt3 N10 C32 -4.3(5) . . . . ? Ag2 Pt3 N10 C32 169.2(5) . . . . ? N10 Pt3 N11 C30 -166.8(5) . . . . ? N9 Pt3 N11 C30 37(4) . . . . ? N12 Pt3 N11 C30 14.0(5) . . . . ? Ag3 Pt3 N11 C30 104.4(4) . . . . ? Ag2 Pt3 N11 C30 -74.5(5) . . . . ? N10 Pt3 N12 C31 2(3) . . . . ? N9 Pt3 N12 C31 -163.3(4) . . . . ? N11 Pt3 N12 C31 15.2(4) . . . . ? Ag3 Pt3 N12 C31 -74.9(4) . . . . ? Ag2 Pt3 N12 C31 111.6(4) . . . . ? O7 Ag1 O1 C1 46.2(9) . . . . ? O2 Ag1 O1 C1 -126.8(6) 2_745 . . . ? Pt1 Ag1 O1 C1 160.6(6) 2_745 . . . ? Pt1 Ag1 O1 C1 2.6(6) . . . . ? O4 Ag2 O3 C18 66.7(5) . . . . ? O9 Ag2 O3 C18 -119.2(5) . . . . ? Pt3 Ag2 O3 C18 149.1(4) . . . . ? Pt2 Ag2 O3 C18 -24.8(5) . . . . ? O9 Ag2 O4 C23 -24.2(11) . . . . ? O3 Ag2 O4 C23 136.7(6) . . . . ? Pt3 Ag2 O4 C23 7.0(6) . . . . ? Pt2 Ag2 O4 C23 -148.7(6) . . . . ? O6 Ag3 O5 C32 76.6(5) 1_545 . . . ? O11 Ag3 O5 C32 -114.1(5) . . . . ? Pt3 Ag3 O5 C32 -10.0(5) . . . . ? Pt2 Ag3 O5 C32 151.6(5) 1_545 . . . ? O1 Ag1 O7 C37 44.1(7) . . . . ? O2 Ag1 O7 C37 -142.7(4) 2_745 . . . ? Pt1 Ag1 O7 C37 -67.9(4) 2_745 . . . ? Pt1 Ag1 O7 C37 86.4(4) . . . . ? O4 Ag2 O9 C42 -52.0(8) . . . . ? O3 Ag2 O9 C42 147.0(4) . . . . ? Pt3 Ag2 O9 C42 -82.5(4) . . . . ? Pt2 Ag2 O9 C42 72.3(4) . . . . ? O5 Ag3 O11 C45 145.3(4) . . . . ? O6 Ag3 O11 C45 -61.2(6) 1_545 . . . ? Pt3 Ag3 O11 C45 65.3(4) . . . . ? Pt2 Ag3 O11 C45 -90.3(4) 1_545 . . . ? Ag1 O1 C1 N1 -3.3(11) . . . . ? Ag1 O1 C1 C2 178.6(5) . . . . ? Pt1 N1 C1 O1 1.7(11) . . . . ? Pt1 N1 C1 C2 179.7(5) . . . . ? O1 C1 C2 C5 -21.0(10) . . . . ? N1 C1 C2 C5 160.9(7) . . . . ? O1 C1 C2 C4 -141.5(8) . . . . ? N1 C1 C2 C4 40.4(11) . . . . ? O1 C1 C2 C3 98.0(8) . . . . ? N1 C1 C2 C3 -80.1(8) . . . . ? Ag1 O2 C6 N2 -21.1(10) 2_755 . . . ? Ag1 O2 C6 C7 158.3(5) 2_755 . . . ? Pt1 N2 C6 O2 -0.7(10) . . . . ? Pt1 N2 C6 C7 179.9(5) . . . . ? O2 C6 C7 C9 -70.1(10) . . . . ? N2 C6 C7 C9 109.3(9) . . . . ? O2 C6 C7 C8 166.6(7) . . . . ? N2 C6 C7 C8 -14.0(10) . . . . ? O2 C6 C7 C10 47.1(9) . . . . ? N2 C6 C7 C10 -133.5(7) . . . . ? Pt1 N3 C11 C12 40.2(7) . . . . ? Pt1 N4 C12 C11 39.6(6) . . . . ? N3 C11 C12 N4 -52.9(7) . . . . ? Ag3 O6 C13 N5 -9.2(10) 1_565 . . . ? Ag3 O6 C13 C14 169.8(5) 1_565 . . . ? Pt2 N5 C13 O6 0.9(10) . . . . ? Pt2 N5 C13 C14 -178.0(5) . . . . ? O6 C13 C14 C15 140.2(8) . . . . ? N5 C13 C14 C15 -40.8(10) . . . . ? O6 C13 C14 C16 19.1(10) . . . . ? N5 C13 C14 C16 -161.9(7) . . . . ? O6 C13 C14 C17 -99.2(8) . . . . ? N5 C13 C14 C17 79.8(8) . . . . ? Ag2 O3 C18 N6 21.9(9) . . . . ? Ag2 O3 C18 C19 -155.9(5) . . . . ? Pt2 N6 C18 O3 2.1(10) . . . . ? Pt2 N6 C18 C19 180.0(5) . . . . ? O3 C18 C19 C20 -28.4(9) . . . . ? N6 C18 C19 C20 153.7(7) . . . . ? O3 C18 C19 C21 -150.1(7) . . . . ? N6 C18 C19 C21 32.0(9) . . . . ? O3 C18 C19 C22 90.8(8) . . . . ? N6 C18 C19 C22 -87.1(8) . . . . ? Ag2 O4 C23 N9 -1.8(10) . . . . ? Ag2 O4 C23 C24 -177.8(5) . . . . ? Pt3 N9 C23 O4 -9.1(11) . . . . ? Pt3 N9 C23 C24 166.9(5) . . . . ? O4 C23 C24 C27 -149.1(8) . . . . ? N9 C23 C24 C27 34.7(10) . . . . ? O4 C23 C24 C25 -26.3(9) . . . . ? N9 C23 C24 C25 157.5(7) . . . . ? O4 C23 C24 C26 92.1(8) . . . . ? N9 C23 C24 C26 -84.1(8) . . . . ? Pt2 N8 C28 C29 40.5(8) . . . . ? N8 C28 C29 N7 -50.5(9) . . . . ? Pt2 N7 C29 C28 35.6(8) . . . . ? Pt3 N11 C30 C31 -40.3(7) . . . . ? Pt3 N12 C31 C30 -41.3(7) . . . . ? N11 C30 C31 N12 54.6(8) . . . . ? Ag3 O5 C32 N10 10.8(9) . . . . ? Ag3 O5 C32 C33 -165.2(4) . . . . ? Pt3 N10 C32 O5 -2.6(10) . . . . ? Pt3 N10 C32 C33 173.3(5) . . . . ? O5 C32 C33 C36 -26.6(9) . . . . ? N10 C32 C33 C36 157.2(7) . . . . ? O5 C32 C33 C34 -149.0(7) . . . . ? N10 C32 C33 C34 34.8(9) . . . . ? O5 C32 C33 C35 92.5(8) . . . . ? N10 C32 C33 C35 -83.7(8) . . . . ? Ag1 O7 C37 O8 7.1(8) . . . . ? Ag1 O7 C37 C38 -170.5(4) . . . . ? O8 C37 C38 C44 5.8(9) . . . . ? O7 C37 C38 C44 -176.4(6) . . . . ? O8 C37 C38 C39 -175.8(6) . . . . ? O7 C37 C38 C39 2.0(9) . . . . ? C44 C38 C39 C40 0.4(10) . . . . ? C37 C38 C39 C40 -178.0(6) . . . . ? C38 C39 C40 C41 0.8(11) . . . . ? C39 C40 C41 C43 -1.5(10) . . . . ? C39 C40 C41 C42 177.0(6) . . . . ? Ag2 O9 C42 O10 -5.6(7) . . . . ? Ag2 O9 C42 C41 172.7(4) . . . . ? C40 C41 C42 O10 -7.6(9) . . . . ? C43 C41 C42 O10 170.9(6) . . . . ? C40 C41 C42 O9 174.1(6) . . . . ? C43 C41 C42 O9 -7.5(9) . . . . ? C40 C41 C43 C44 0.9(10) . . . . ? C42 C41 C43 C44 -177.6(6) . . . . ? C41 C43 C44 C38 0.3(11) . . . . ? C39 C38 C44 C43 -1.0(10) . . . . ? C37 C38 C44 C43 177.5(6) . . . . ? Ag3 O11 C45 O12 -3.9(7) . . . . ? Ag3 O11 C45 C46 173.8(5) . . . . ? O12 C45 C46 C48 -13.2(10) . . . . ? O11 C45 C46 C48 168.9(7) . . . . ? O12 C45 C46 C47 166.1(7) . . . . ? O11 C45 C46 C47 -11.8(10) . . . . ? C48 C46 C47 C48 0.3(12) . . . 3_646 ? C45 C46 C47 C48 -179.0(7) . . . 3_646 ? C47 C46 C48 C47 -0.3(12) . . . 3_646 ? C45 C46 C48 C47 179.0(7) . . . 3_646 ? _diffrn_measured_fraction_theta_max 0.959 _diffrn_reflns_theta_full 27.57 _diffrn_measured_fraction_theta_full 0.959 _refine_diff_density_max 3.495 _refine_diff_density_min -4.012 _refine_diff_density_rms 0.210 #===END data_l512 _database_code_depnum_ccdc_archive 'CCDC 286691' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C16 H50 Ag N5 O14 Pt' _chemical_formula_weight 839.57 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Orthorhombic _symmetry_space_group_name_H-M Pnma loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z' 'x+1/2, -y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, y, -z-1/2' 'x, -y-1/2, z' '-x-1/2, y-1/2, z-1/2' _cell_length_a 11.868(2) _cell_length_b 23.175(4) _cell_length_c 11.228(2) _cell_angle_alpha 90.00 _cell_angle_beta 90.00 _cell_angle_gamma 90.00 _cell_volume 3088.1(10) _cell_formula_units_Z 4 _cell_measurement_temperature 120(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description needle _exptl_crystal_colour colorless _exptl_crystal_size_max 0.36 _exptl_crystal_size_mid 0.16 _exptl_crystal_size_min 0.14 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.806 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1672 _exptl_absorpt_coefficient_mu 5.224 _exptl_absorpt_correction_type none _exptl_absorpt_correction_T_min 0.2550 _exptl_absorpt_correction_T_max 0.5283 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 120(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 17142 _diffrn_reflns_av_R_equivalents 0.0209 _diffrn_reflns_av_sigmaI/netI 0.0156 _diffrn_reflns_limit_h_min -15 _diffrn_reflns_limit_h_max 13 _diffrn_reflns_limit_k_min -29 _diffrn_reflns_limit_k_max 24 _diffrn_reflns_limit_l_min -13 _diffrn_reflns_limit_l_max 14 _diffrn_reflns_theta_min 1.76 _diffrn_reflns_theta_max 27.51 _reflns_number_total 3576 _reflns_number_gt 3395 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0154P)^2^+3.2266P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method SHELXL _refine_ls_extinction_coef 0.00051(3) _refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^ _refine_ls_number_reflns 3576 _refine_ls_number_parameters 220 _refine_ls_number_restraints 10 _refine_ls_R_factor_all 0.0162 _refine_ls_R_factor_gt 0.0146 _refine_ls_wR_factor_ref 0.0361 _refine_ls_wR_factor_gt 0.0355 _refine_ls_goodness_of_fit_ref 1.068 _refine_ls_restrained_S_all 1.073 _refine_ls_shift/su_max 0.002 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group O1 O 0.81383(12) 0.33223(6) 0.68892(12) 0.0176(3) Uani 1 1 d . . . Ag Ag 0.327406(17) 0.2500 0.691060(17) 0.01342(5) Uani 1 2 d S . . C1 C 0.73175(15) 0.34025(8) 0.61814(16) 0.0116(3) Uani 1 1 d . . . C2 C 0.74707(16) 0.38329(8) 0.51431(17) 0.0155(4) Uani 1 1 d . . . C3 C 0.63810(18) 0.41576(9) 0.4858(2) 0.0218(4) Uani 1 1 d . . . H3A H 0.6113 0.4356 0.5574 0.033 Uiso 1 1 calc R . . H3B H 0.5807 0.3883 0.4587 0.033 Uiso 1 1 calc R . . H3C H 0.6525 0.4441 0.4229 0.033 Uiso 1 1 calc R . . C4 C 0.7833(2) 0.34773(11) 0.40588(19) 0.0313(5) Uani 1 1 d . . . H4A H 0.7944 0.3734 0.3375 0.047 Uiso 1 1 calc R . . H4B H 0.7247 0.3194 0.3870 0.047 Uiso 1 1 calc R . . H4C H 0.8540 0.3277 0.4237 0.047 Uiso 1 1 calc R . . C5 C 0.83749(19) 0.42773(11) 0.5442(2) 0.0297(6) Uani 1 1 d . . . H5A H 0.8483 0.4536 0.4760 0.045 Uiso 1 1 calc R . . H5B H 0.9085 0.4079 0.5620 0.045 Uiso 1 1 calc R . . H5C H 0.8138 0.4503 0.6136 0.045 Uiso 1 1 calc R . . C6 C 0.40080(17) 0.29941(8) 0.44449(17) 0.0169(4) Uani 1 1 d . . . H6 H 0.3804 0.3349 0.4811 0.020 Uiso 1 1 calc R . . C7 C 0.45552(17) 0.30113(8) 0.33606(17) 0.0164(4) Uani 1 1 d . . . H7 H 0.4721 0.3371 0.2995 0.020 Uiso 1 1 calc R . . C8 C 0.4861(2) 0.2500 0.2810(2) 0.0138(5) Uani 1 2 d S . . C9 C 0.5508(2) 0.2500 0.1639(2) 0.0157(5) Uani 1 2 d S . . H41 H 0.454(2) 0.4757(12) 0.303(2) 0.043(8) Uiso 1 1 d D . . H42 H 0.530(3) 0.4649(14) 0.205(3) 0.090(14) Uiso 1 1 d D . . H51 H 0.606(2) 0.3763(8) 0.135(2) 0.032(7) Uiso 1 1 d D . . H52 H 0.625(4) 0.423(2) 0.043(2) 0.14(2) Uiso 1 1 d D . . H61 H 0.364(2) 0.4343(13) 0.4747(16) 0.044(9) Uiso 1 1 d D . . H62 H 0.2819(16) 0.4315(14) 0.379(3) 0.049(9) Uiso 1 1 d D . . H71 H 0.7110(15) 0.4368(13) 0.868(3) 0.046(9) Uiso 1 1 d D . . H72 H 0.587(4) 0.4582(19) 0.838(4) 0.14(2) Uiso 1 1 d D . . H81 H 0.587(2) 0.5509(11) 0.312(3) 0.046(9) Uiso 1 1 d D . . H82 H 0.635(3) 0.6072(11) 0.299(2) 0.042(8) Uiso 1 1 d D . . N1 N 0.63741(14) 0.31184(7) 0.62768(14) 0.0150(3) Uani 1 1 d . . . H1 H 0.5849 0.3210 0.5756 0.018 Uiso 1 1 calc R . . N2 N 0.55167(14) 0.31248(7) 0.86499(14) 0.0133(3) Uani 1 1 d . . . H2A H 0.4762 0.3189 0.8607 0.020 Uiso 1 1 calc R . . H2B H 0.5893 0.3456 0.8478 0.020 Uiso 1 1 calc R . . H2C H 0.5699 0.3007 0.9398 0.020 Uiso 1 1 calc R . . N3 N 0.3750(2) 0.2500 0.5008(2) 0.0140(4) Uani 1 2 d S . . O3 O 0.57398(13) 0.29796(6) 0.11923(12) 0.0219(3) Uani 1 1 d . . . O4 O 0.49687(14) 0.49362(7) 0.24816(13) 0.0195(3) Uani 1 1 d D . . O5 O 0.62444(14) 0.41393(7) 0.12406(14) 0.0218(3) Uani 1 1 d D . . O6 O 0.35607(13) 0.43645(7) 0.39527(14) 0.0230(3) Uani 1 1 d D . . O7 O 0.63663(13) 0.43332(7) 0.88122(14) 0.0200(3) Uani 1 1 d D . . O8 O 0.63179(14) 0.57791(7) 0.35020(14) 0.0232(3) Uani 1 1 d D . . Pt Pt 0.595658(8) 0.2500 0.745290(8) 0.00955(4) Uani 1 2 d S . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 O1 0.0157(7) 0.0171(7) 0.0199(7) 0.0074(6) -0.0051(6) -0.0020(5) Ag 0.01517(10) 0.01464(10) 0.01045(9) 0.000 0.00406(7) 0.000 C1 0.0129(9) 0.0103(8) 0.0115(8) -0.0001(6) 0.0010(7) 0.0016(7) C2 0.0146(9) 0.0168(9) 0.0152(9) 0.0066(7) -0.0002(7) 0.0004(8) C3 0.0184(10) 0.0189(10) 0.0282(11) 0.0084(9) -0.0025(8) 0.0020(8) C4 0.0438(14) 0.0342(13) 0.0160(10) 0.0068(9) 0.0112(10) 0.0122(11) C5 0.0240(12) 0.0300(13) 0.0351(13) 0.0209(10) -0.0086(9) -0.0115(10) C6 0.0239(11) 0.0129(10) 0.0140(9) -0.0008(7) 0.0005(7) 0.0025(8) C7 0.0236(10) 0.0124(9) 0.0132(9) 0.0027(7) -0.0009(8) -0.0006(8) C8 0.0152(13) 0.0164(13) 0.0097(12) 0.000 -0.0028(10) 0.000 C9 0.0173(13) 0.0179(13) 0.0118(12) 0.000 -0.0005(10) 0.000 N1 0.0118(8) 0.0212(8) 0.0120(8) 0.0054(6) -0.0024(6) -0.0018(6) N2 0.0141(8) 0.0112(7) 0.0145(8) -0.0007(6) 0.0002(6) -0.0010(6) N3 0.0155(11) 0.0141(11) 0.0123(11) 0.000 -0.0001(9) 0.000 O3 0.0324(8) 0.0185(7) 0.0148(7) 0.0017(6) 0.0063(6) -0.0035(6) O4 0.0199(8) 0.0184(8) 0.0202(7) 0.0021(6) 0.0027(6) -0.0009(6) O5 0.0250(8) 0.0193(8) 0.0211(8) 0.0006(6) 0.0035(6) -0.0018(6) O6 0.0217(8) 0.0259(8) 0.0214(8) 0.0032(6) 0.0026(6) -0.0023(6) O7 0.0186(7) 0.0193(7) 0.0222(8) 0.0011(6) -0.0006(6) -0.0008(6) O8 0.0242(8) 0.0276(8) 0.0180(7) 0.0015(6) -0.0025(6) -0.0062(7) Pt 0.00908(6) 0.01127(6) 0.00829(6) 0.000 0.00049(3) 0.000 _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag O1 C1 1.271(2) . ? O1 Ag 2.3396(14) 6_657 ? Ag N3 2.210(2) . ? Ag O1 2.3396(14) 6_557 ? Ag O1 2.3396(14) 4_456 ? Ag Pt 2.8417(5) 6_557 ? Ag Pt 3.2413(6) . ? C1 N1 1.303(2) . ? C1 C2 1.545(2) . ? C2 C5 1.525(3) . ? C2 C3 1.530(3) . ? C2 C4 1.532(3) . ? C6 N3 1.343(2) . ? C6 C7 1.380(3) . ? C7 C8 1.385(2) . ? C8 C7 1.385(2) 7_565 ? C8 C9 1.522(4) . ? C9 O3 1.2503(19) 7_565 ? C9 O3 1.2503(19) . ? N1 Pt 2.0108(16) . ? N2 Pt 2.0433(15) . ? N3 C6 1.343(2) 7_565 ? Pt N1 2.0108(16) 7_565 ? Pt N2 2.0433(16) 7_565 ? Pt Ag 2.8417(5) 6_657 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C1 O1 Ag 122.15(12) . 6_657 ? N3 Ag O1 125.06(4) . 6_557 ? N3 Ag O1 125.06(4) . 4_456 ? O1 Ag O1 109.09(7) 6_557 4_456 ? N3 Ag Pt 119.37(6) . 6_557 ? O1 Ag Pt 77.79(3) 6_557 6_557 ? O1 Ag Pt 77.79(3) 4_456 6_557 ? N3 Ag Pt 86.02(6) . . ? O1 Ag Pt 87.68(4) 6_557 . ? O1 Ag Pt 87.68(4) 4_456 . ? Pt Ag Pt 154.606(10) 6_557 . ? O1 C1 N1 122.22(17) . . ? O1 C1 C2 118.43(16) . . ? N1 C1 C2 119.29(16) . . ? C5 C2 C3 107.98(17) . . ? C5 C2 C4 109.90(19) . . ? C3 C2 C4 109.61(18) . . ? C5 C2 C1 110.67(16) . . ? C3 C2 C1 112.08(16) . . ? C4 C2 C1 106.59(16) . . ? N3 C6 C7 123.16(19) . . ? C6 C7 C8 119.48(19) . . ? C7 C8 C7 117.7(3) . 7_565 ? C7 C8 C9 121.16(13) . . ? C7 C8 C9 121.16(13) 7_565 . ? O3 C9 O3 125.5(3) 7_565 . ? O3 C9 C8 117.24(13) 7_565 . ? O3 C9 C8 117.24(13) . . ? C1 N1 Pt 128.74(13) . . ? C6 N3 C6 116.9(2) 7_565 . ? C6 N3 Ag 120.88(12) 7_565 . ? C6 N3 Ag 120.88(12) . . ? N1 Pt N1 90.92(10) 7_565 . ? N1 Pt N2 179.43(6) 7_565 . ? N1 Pt N2 89.42(7) . . ? N1 Pt N2 89.42(7) 7_565 7_565 ? N1 Pt N2 179.43(6) . 7_565 ? N2 Pt N2 90.24(9) . 7_565 ? N1 Pt Ag 85.79(5) 7_565 6_657 ? N1 Pt Ag 85.79(5) . 6_657 ? N2 Pt Ag 94.69(5) . 6_657 ? N2 Pt Ag 94.69(5) 7_565 6_657 ? N1 Pt Ag 96.82(5) 7_565 . ? N1 Pt Ag 96.82(5) . . ? N2 Pt Ag 82.68(5) . . ? N2 Pt Ag 82.68(5) 7_565 . ? Ag Pt Ag 176.262(4) 6_657 . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag Ag O1 C1 N1 17.4(2) 6_657 . . . ? Ag O1 C1 C2 -159.86(12) 6_657 . . . ? O1 C1 C2 C5 -24.9(2) . . . . ? N1 C1 C2 C5 157.73(19) . . . . ? O1 C1 C2 C3 -145.52(18) . . . . ? N1 C1 C2 C3 37.1(2) . . . . ? O1 C1 C2 C4 94.6(2) . . . . ? N1 C1 C2 C4 -82.8(2) . . . . ? N3 C6 C7 C8 0.0(3) . . . . ? C6 C7 C8 C7 2.6(4) . . . 7_565 ? C6 C7 C8 C9 -177.4(2) . . . . ? C7 C8 C9 O3 -179.1(2) . . . 7_565 ? C7 C8 C9 O3 0.8(4) 7_565 . . 7_565 ? C7 C8 C9 O3 -0.8(4) . . . . ? C7 C8 C9 O3 179.1(2) 7_565 . . . ? O1 C1 N1 Pt -1.4(3) . . . . ? C2 C1 N1 Pt 175.86(13) . . . . ? C7 C6 N3 C6 -2.6(4) . . . 7_565 ? C7 C6 N3 Ag 164.44(16) . . . . ? O1 Ag N3 C6 167.64(16) 6_557 . . 7_565 ? O1 Ag N3 C6 -1.1(2) 4_456 . . 7_565 ? Pt Ag N3 C6 -96.71(19) 6_557 . . 7_565 ? Pt Ag N3 C6 83.29(19) . . . 7_565 ? O1 Ag N3 C6 1.1(2) 6_557 . . . ? O1 Ag N3 C6 -167.64(16) 4_456 . . . ? Pt Ag N3 C6 96.71(19) 6_557 . . . ? Pt Ag N3 C6 -83.29(19) . . . . ? C1 N1 Pt N1 -96.21(17) . . . 7_565 ? C1 N1 Pt N2 84.26(17) . . . . ? C1 N1 Pt N2 138(7) . . . 7_565 ? C1 N1 Pt Ag -10.49(17) . . . 6_657 ? C1 N1 Pt Ag 166.82(16) . . . . ? N3 Ag Pt N1 -45.87(5) . . . 7_565 ? O1 Ag Pt N1 -171.27(6) 6_557 . . 7_565 ? O1 Ag Pt N1 79.52(6) 4_456 . . 7_565 ? Pt Ag Pt N1 134.13(5) 6_557 . . 7_565 ? N3 Ag Pt N1 45.87(5) . . . . ? O1 Ag Pt N1 -79.52(6) 6_557 . . . ? O1 Ag Pt N1 171.27(6) 4_456 . . . ? Pt Ag Pt N1 -134.13(5) 6_557 . . . ? N3 Ag Pt N2 134.41(5) . . . . ? O1 Ag Pt N2 9.02(6) 6_557 . . . ? O1 Ag Pt N2 -100.20(6) 4_456 . . . ? Pt Ag Pt N2 -45.59(5) 6_557 . . . ? N3 Ag Pt N2 -134.41(5) . . . 7_565 ? O1 Ag Pt N2 100.20(6) 6_557 . . 7_565 ? O1 Ag Pt N2 -9.02(6) 4_456 . . 7_565 ? Pt Ag Pt N2 45.59(5) 6_557 . . 7_565 ? N3 Ag Pt Ag 180.0 . . . 6_657 ? O1 Ag Pt Ag 54.61(4) 6_557 . . 6_657 ? O1 Ag Pt Ag -54.61(4) 4_456 . . 6_657 ? Pt Ag Pt Ag 0.0 6_557 . . 6_657 ? _diffrn_measured_fraction_theta_max 0.981 _diffrn_reflns_theta_full 27.51 _diffrn_measured_fraction_theta_full 0.981 _refine_diff_density_max 1.041 _refine_diff_density_min -0.618 _refine_diff_density_rms 0.078 #===END data_l513 _database_code_depnum_ccdc_archive 'CCDC 286692' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C30 H60 Ag2 Cl N9 O10 Pt2' _chemical_formula_weight 1348.24 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting orthorhombic _symmetry_space_group_name_H-M P2(1)2(1)2(1) loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x+1/2, -y+1/2, -z' _cell_length_a 11.2677(17) _cell_length_b 19.592(3) _cell_length_c 19.601(3) _cell_angle_alpha 90.00 _cell_angle_beta 90.00 _cell_angle_gamma 90.00 _cell_volume 4326.9(11) _cell_formula_units_Z 4 _cell_measurement_temperature 120(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description prism _exptl_crystal_colour colorless _exptl_crystal_size_max 0.22 _exptl_crystal_size_mid 0.20 _exptl_crystal_size_min 0.12 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 2.070 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 2600 _exptl_absorpt_coefficient_mu 7.459 _exptl_absorpt_correction_type ? _exptl_absorpt_correction_T_min 0.2907 _exptl_absorpt_correction_T_max 0.4681 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 120(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 24793 _diffrn_reflns_av_R_equivalents 0.0275 _diffrn_reflns_av_sigmaI/netI 0.0521 _diffrn_reflns_limit_h_min -14 _diffrn_reflns_limit_h_max 10 _diffrn_reflns_limit_k_min -25 _diffrn_reflns_limit_k_max 25 _diffrn_reflns_limit_l_min -21 _diffrn_reflns_limit_l_max 24 _diffrn_reflns_theta_min 2.08 _diffrn_reflns_theta_max 27.48 _reflns_number_total 9343 _reflns_number_gt 8499 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881' _refine_ls_abs_structure_Flack 0.003(3) _refine_ls_number_reflns 9343 _refine_ls_number_parameters 499 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0249 _refine_ls_R_factor_gt 0.0202 _refine_ls_wR_factor_ref 0.0449 _refine_ls_wR_factor_gt 0.0434 _refine_ls_goodness_of_fit_ref 0.816 _refine_ls_restrained_S_all 0.816 _refine_ls_shift/su_max 0.004 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 0.48045(3) 0.495309(16) 0.845864(17) 0.01431(7) Uani 1 1 d . . . Ag2 Ag -0.02039(3) 0.490529(17) 0.870730(16) 0.01457(7) Uani 1 1 d . . . Pt1 Pt 0.736184(13) 0.505907(7) 0.839275(8) 0.01146(4) Uani 1 1 d . . . Pt2 Pt 0.226924(14) 0.479639(7) 0.843934(8) 0.01091(4) Uani 1 1 d . . . Cl Cl 0.58634(12) 0.74954(5) 0.74535(6) 0.0227(3) Uani 1 1 d . . . N1 N 0.7161(4) 0.41315(17) 0.88165(19) 0.0178(8) Uani 1 1 d . . . H1 H 0.7859 0.4060 0.9049 0.021 Uiso 1 1 d R . . N2 N -0.2219(3) 0.45714(17) 0.75181(17) 0.0164(8) Uani 1 1 d . . . H2 H -0.2916 0.4384 0.7361 0.020 Uiso 1 1 d R . . N3 N 0.7767(4) 0.60170(16) 0.80189(18) 0.0186(8) Uani 1 1 d . . . H3D H 0.8464 0.6002 0.7775 0.022 Uiso 1 1 calc R . . H3E H 0.7172 0.6167 0.7734 0.022 Uiso 1 1 calc R . . N4 N 0.6988(3) 0.55845(17) 0.92780(17) 0.0148(8) Uani 1 1 d . . . H4D H 0.6277 0.5437 0.9456 0.018 Uiso 1 1 calc R . . H4E H 0.7573 0.5505 0.9596 0.018 Uiso 1 1 calc R . . N5 N 0.2423(3) 0.57041(16) 0.89093(18) 0.0138(8) Uani 1 1 d . . . H5 H 0.1857 0.6000 0.8817 0.017 Uiso 1 1 calc R . . N6 N 0.1901(3) 0.52600(18) 0.75491(16) 0.0143(8) Uani 1 1 d . . . H6A H 0.1857 0.4915 0.7232 0.017 Uiso 1 1 d R . . N7 N 0.1892(3) 0.38442(18) 0.80643(19) 0.0184(9) Uani 1 1 d . . . H7A H 0.1199 0.3857 0.7816 0.022 Uiso 1 1 calc R . . H7B H 0.2494 0.3700 0.7782 0.022 Uiso 1 1 calc R . . N8 N 0.2652(4) 0.42676(16) 0.93177(17) 0.0160(8) Uani 1 1 d . . . H8A H 0.3364 0.4414 0.9495 0.019 Uiso 1 1 calc R . . H8B H 0.2070 0.4342 0.9638 0.019 Uiso 1 1 calc R . . N9 N 0.4846(3) 0.49960(18) 0.73280(17) 0.0154(8) Uani 1 1 d . . . O1 O 0.5380(3) 0.42021(15) 0.93406(15) 0.0179(7) Uani 1 1 d . . . O2 O 0.4245(3) 0.56419(16) 0.93765(16) 0.0195(7) Uani 1 1 d . . . O3 O 0.0183(3) 0.57665(16) 0.78648(15) 0.0196(7) Uani 1 1 d . . . O4 O -0.0623(3) 0.40057(16) 0.79119(16) 0.0193(7) Uani 1 1 d . . . O5 O 0.5660(3) 0.4538(2) 0.48671(16) 0.0331(9) Uani 1 1 d . . . O6 O 0.4725(3) 0.5540(2) 0.48432(16) 0.0316(9) Uani 1 1 d . . . O7 O 0.6564(3) 0.70392(17) 0.70408(19) 0.0337(10) Uani 1 1 d . . . O8 O 0.6641(4) 0.79153(18) 0.78542(19) 0.0362(10) Uani 1 1 d . . . O9 O 0.5169(4) 0.79304(19) 0.70270(18) 0.0360(10) Uani 1 1 d . . . O10 O 0.5140(4) 0.71039(18) 0.78959(19) 0.0385(10) Uani 1 1 d . . . C1 C 0.6345(4) 0.3893(2) 0.9228(2) 0.0124(9) Uani 1 1 d . . . C2 C 0.6624(4) 0.3228(2) 0.9603(2) 0.0155(10) Uani 1 1 d . . . C3 C 0.5476(5) 0.2866(2) 0.9816(3) 0.0259(12) Uani 1 1 d . . . H3A H 0.4975 0.3183 1.0074 0.039 Uiso 1 1 calc R . . H3B H 0.5669 0.2471 1.0101 0.039 Uiso 1 1 calc R . . H3C H 0.5049 0.2713 0.9407 0.039 Uiso 1 1 calc R . . C4 C 0.7369(5) 0.3426(2) 1.0238(2) 0.0250(11) Uani 1 1 d . . . H4A H 0.7527 0.3018 1.0512 0.038 Uiso 1 1 calc R . . H4B H 0.6927 0.3758 1.0513 0.038 Uiso 1 1 calc R . . H4C H 0.8122 0.3629 1.0091 0.038 Uiso 1 1 calc R . . C5 C 0.7356(5) 0.2735(2) 0.9161(2) 0.0292(12) Uani 1 1 d . . . H5A H 0.7412 0.2291 0.9389 0.044 Uiso 1 1 calc R . . H5B H 0.8155 0.2922 0.9093 0.044 Uiso 1 1 calc R . . H5C H 0.6968 0.2678 0.8717 0.044 Uiso 1 1 calc R . . C6 C 0.4823(4) 0.4412(2) 0.6961(2) 0.0187(11) Uani 1 1 d . . . H6 H 0.4717 0.3991 0.7192 0.022 Uiso 1 1 calc R . . C7 C 0.4949(5) 0.4409(3) 0.6256(2) 0.0207(11) Uani 1 1 d . . . H7 H 0.4959 0.3990 0.6011 0.025 Uiso 1 1 calc R . . C8 C 0.5060(4) 0.5021(2) 0.5916(2) 0.0173(11) Uani 1 1 d . . . C9 C 0.5071(4) 0.5620(3) 0.6298(2) 0.0184(11) Uani 1 1 d . . . H9 H 0.5158 0.6049 0.6077 0.022 Uiso 1 1 calc R . . C10 C 0.4957(4) 0.5590(2) 0.7000(2) 0.0151(10) Uani 1 1 d . . . H10 H 0.4957 0.6002 0.7255 0.018 Uiso 1 1 calc R . . C11 C 0.7892(5) 0.6487(2) 0.8610(2) 0.0206(11) Uani 1 1 d . . . H11A H 0.7826 0.6966 0.8455 0.025 Uiso 1 1 calc R . . H11B H 0.8680 0.6425 0.8825 0.025 Uiso 1 1 calc R . . C12 C 0.6922(4) 0.6329(2) 0.9122(2) 0.0202(11) Uani 1 1 d . . . H12A H 0.7039 0.6600 0.9543 0.024 Uiso 1 1 calc R . . H12B H 0.6135 0.6444 0.8928 0.024 Uiso 1 1 calc R . . C13 C 0.3234(4) 0.5921(2) 0.9330(2) 0.0149(10) Uani 1 1 d . . . C14 C 0.2961(4) 0.6509(2) 0.9823(2) 0.0177(10) Uani 1 1 d . . . C15 C 0.2971(5) 0.6184(3) 1.0538(2) 0.0288(13) Uani 1 1 d . . . H15A H 0.3756 0.5988 1.0629 0.043 Uiso 1 1 calc R . . H15B H 0.2370 0.5823 1.0560 0.043 Uiso 1 1 calc R . . H15C H 0.2794 0.6534 1.0880 0.043 Uiso 1 1 calc R . . C16 C 0.1746(5) 0.6838(2) 0.9695(3) 0.0251(12) Uani 1 1 d . . . H16A H 0.1128 0.6486 0.9706 0.038 Uiso 1 1 calc R . . H16B H 0.1746 0.7060 0.9246 0.038 Uiso 1 1 calc R . . H16C H 0.1588 0.7179 1.0049 0.038 Uiso 1 1 calc R . . C17 C 0.3942(5) 0.7055(3) 0.9769(3) 0.0350(14) Uani 1 1 d . . . H17A H 0.4001 0.7214 0.9296 0.052 Uiso 1 1 calc R . . H17B H 0.4702 0.6857 0.9910 0.052 Uiso 1 1 calc R . . H17C H 0.3746 0.7440 1.0067 0.052 Uiso 1 1 calc R . . C18 C 0.2721(5) 0.3529(2) 0.9150(2) 0.0205(10) Uani 1 1 d . . . H18A H 0.2605 0.3252 0.9567 0.025 Uiso 1 1 calc R . . H18B H 0.3509 0.3419 0.8956 0.025 Uiso 1 1 calc R . . C19 C 0.1765(5) 0.3372(2) 0.8640(2) 0.0200(11) Uani 1 1 d . . . H19A H 0.1840 0.2895 0.8480 0.024 Uiso 1 1 calc R . . H19B H 0.0974 0.3428 0.8853 0.024 Uiso 1 1 calc R . . C20 C 0.0975(4) 0.5649(2) 0.7429(2) 0.0132(9) Uani 1 1 d . . . C21 C 0.0796(4) 0.5942(2) 0.6702(2) 0.0154(10) Uani 1 1 d . . . C22 C 0.1940(5) 0.5954(3) 0.6284(2) 0.0250(12) Uani 1 1 d . . . H22A H 0.1784 0.6161 0.5838 0.037 Uiso 1 1 calc R . . H22B H 0.2229 0.5487 0.6221 0.037 Uiso 1 1 calc R . . H22C H 0.2541 0.6223 0.6526 0.037 Uiso 1 1 calc R . . C23 C 0.0297(5) 0.6667(2) 0.6757(2) 0.0248(12) Uani 1 1 d . . . H23A H 0.0198 0.6859 0.6299 0.037 Uiso 1 1 calc R . . H23B H 0.0847 0.6952 0.7019 0.037 Uiso 1 1 calc R . . H23C H -0.0474 0.6653 0.6988 0.037 Uiso 1 1 calc R . . C24 C -0.0102(5) 0.5468(3) 0.6350(2) 0.0281(13) Uani 1 1 d . . . H24A H 0.0232 0.5007 0.6317 0.042 Uiso 1 1 calc R . . H24B H -0.0274 0.5640 0.5892 0.042 Uiso 1 1 calc R . . H24C H -0.0836 0.5454 0.6618 0.042 Uiso 1 1 calc R . . C25 C -0.1412(4) 0.4081(2) 0.7464(2) 0.0134(9) Uani 1 1 d . . . C26 C -0.1481(4) 0.3562(2) 0.6887(2) 0.0194(11) Uani 1 1 d . . . C27 C -0.1838(5) 0.3877(2) 0.6193(2) 0.0233(11) Uani 1 1 d . . . H27A H -0.1941 0.3513 0.5855 0.035 Uiso 1 1 calc R . . H27B H -0.1214 0.4190 0.6039 0.035 Uiso 1 1 calc R . . H27C H -0.2585 0.4129 0.6244 0.035 Uiso 1 1 calc R . . C28 C -0.0287(4) 0.3203(2) 0.6807(2) 0.0227(11) Uani 1 1 d . . . H28A H -0.0337 0.2868 0.6436 0.034 Uiso 1 1 calc R . . H28B H -0.0084 0.2968 0.7233 0.034 Uiso 1 1 calc R . . H28C H 0.0328 0.3540 0.6700 0.034 Uiso 1 1 calc R . . C29 C -0.2421(5) 0.3037(2) 0.7099(2) 0.0267(12) Uani 1 1 d . . . H29A H -0.2230 0.2859 0.7553 0.040 Uiso 1 1 calc R . . H29B H -0.2430 0.2661 0.6770 0.040 Uiso 1 1 calc R . . H29C H -0.3203 0.3256 0.7110 0.040 Uiso 1 1 calc R . . C30 C 0.5164(4) 0.5028(3) 0.5148(2) 0.0254(12) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.01112(14) 0.02275(17) 0.00906(14) 0.00086(15) 0.00028(12) 0.00097(13) Ag2 0.01138(15) 0.02331(19) 0.00901(14) 0.00006(14) -0.00018(12) 0.00073(15) Pt1 0.00950(8) 0.01407(7) 0.01081(8) 0.00001(7) 0.00080(6) 0.00138(6) Pt2 0.00959(8) 0.01396(8) 0.00917(7) 0.00106(7) -0.00110(7) 0.00045(6) Cl 0.0265(7) 0.0164(6) 0.0254(7) 0.0043(5) 0.0018(5) 0.0008(5) N1 0.016(2) 0.0196(19) 0.017(2) -0.0004(16) -0.0038(17) 0.0030(18) N2 0.012(2) 0.0231(19) 0.0144(19) -0.0028(15) -0.0019(16) -0.0014(18) N3 0.017(2) 0.0169(18) 0.022(2) 0.0038(15) 0.0053(17) 0.0071(18) N4 0.012(2) 0.018(2) 0.014(2) -0.0016(15) 0.0020(15) -0.0007(16) N5 0.012(2) 0.0162(17) 0.0131(18) 0.0036(14) -0.0013(15) 0.0014(17) N6 0.022(2) 0.0146(19) 0.0059(17) 0.0000(14) -0.0035(14) 0.0025(16) N7 0.014(2) 0.019(2) 0.022(2) 0.0005(17) 0.0008(16) 0.0046(17) N8 0.017(2) 0.0215(19) 0.0093(19) 0.0020(14) -0.0018(16) 0.0027(19) N9 0.018(2) 0.018(2) 0.0097(18) 0.0033(16) -0.0016(14) 0.0031(18) O1 0.0165(19) 0.0203(18) 0.0170(18) 0.0045(13) 0.0036(13) 0.0062(14) O2 0.0146(19) 0.0229(18) 0.0210(18) -0.0068(14) -0.0021(13) 0.0069(14) O3 0.0174(19) 0.0254(19) 0.0160(18) 0.0061(14) 0.0056(14) 0.0043(15) O4 0.0167(19) 0.0249(18) 0.0162(18) -0.0077(14) -0.0028(14) 0.0048(14) O5 0.024(2) 0.058(3) 0.0180(19) -0.0126(18) 0.0037(15) -0.0091(19) O6 0.024(2) 0.056(3) 0.0149(19) 0.0072(17) -0.0026(15) -0.0055(19) O7 0.037(3) 0.024(2) 0.040(2) -0.0023(17) 0.0103(18) 0.0071(17) O8 0.044(3) 0.025(2) 0.040(2) -0.0014(18) -0.0097(19) -0.0034(18) O9 0.038(3) 0.040(2) 0.030(2) 0.0072(17) -0.0028(18) 0.0100(19) O10 0.049(3) 0.031(2) 0.036(2) 0.0075(17) 0.0147(19) -0.0077(19) C1 0.015(3) 0.014(2) 0.008(2) 0.0006(18) -0.0007(17) 0.0002(18) C2 0.017(3) 0.015(2) 0.014(2) 0.0038(18) 0.0018(19) 0.0018(19) C3 0.030(3) 0.022(3) 0.026(3) 0.009(2) -0.005(2) 0.001(2) C4 0.031(3) 0.025(2) 0.019(3) 0.005(2) -0.003(2) 0.005(2) C5 0.046(4) 0.024(2) 0.018(3) 0.004(2) 0.007(2) 0.014(3) C6 0.016(3) 0.015(2) 0.025(3) 0.005(2) -0.001(2) 0.000(2) C7 0.016(3) 0.027(3) 0.019(3) -0.007(2) -0.004(2) 0.001(2) C8 0.008(2) 0.028(3) 0.015(2) 0.003(2) -0.0016(16) 0.000(2) C9 0.019(3) 0.022(3) 0.014(2) 0.004(2) -0.002(2) 0.000(2) C10 0.015(3) 0.020(3) 0.010(2) -0.0037(19) 0.0021(18) -0.001(2) C11 0.024(3) 0.016(2) 0.022(3) 0.0001(18) -0.001(2) -0.001(2) C12 0.021(3) 0.015(2) 0.025(3) -0.007(2) 0.002(2) 0.005(2) C13 0.016(3) 0.015(2) 0.014(2) 0.0048(18) 0.0005(19) -0.0005(19) C14 0.021(3) 0.017(2) 0.016(2) -0.0037(19) 0.0001(19) 0.001(2) C15 0.028(3) 0.038(3) 0.020(3) -0.012(2) 0.002(2) 0.005(2) C16 0.031(3) 0.018(3) 0.027(3) -0.005(2) 0.002(2) 0.001(2) C17 0.031(3) 0.028(3) 0.046(4) -0.018(3) 0.009(3) -0.010(3) C18 0.023(3) 0.015(2) 0.023(3) 0.0070(19) -0.002(2) 0.002(2) C19 0.023(3) 0.017(2) 0.020(3) 0.0015(19) -0.0028(19) -0.004(2) C20 0.017(3) 0.012(2) 0.011(2) 0.0010(18) -0.0035(18) -0.0022(19) C21 0.017(3) 0.016(2) 0.013(3) 0.0042(18) -0.0017(18) -0.0001(18) C22 0.028(3) 0.032(3) 0.014(2) 0.010(2) 0.006(2) 0.003(2) C23 0.033(3) 0.018(2) 0.023(3) 0.003(2) 0.003(2) 0.006(2) C24 0.035(3) 0.034(3) 0.016(3) 0.003(2) -0.009(2) -0.002(3) C25 0.010(2) 0.018(2) 0.012(2) 0.0021(19) 0.0011(17) -0.0027(18) C26 0.018(3) 0.022(3) 0.018(3) -0.004(2) 0.0019(19) -0.003(2) C27 0.025(3) 0.030(3) 0.014(3) -0.007(2) -0.004(2) -0.001(2) C28 0.022(3) 0.026(3) 0.020(3) -0.011(2) 0.002(2) 0.000(2) C29 0.028(3) 0.030(3) 0.022(3) -0.009(2) 0.006(2) -0.013(2) C30 0.015(2) 0.046(4) 0.015(2) -0.004(2) 0.0011(18) -0.007(3) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 N9 2.218(3) . ? Ag1 O2 2.336(3) . ? Ag1 O1 2.361(3) . ? Ag1 Pt2 2.8733(5) . ? Ag1 Pt1 2.8919(5) . ? Ag2 O4 2.400(3) . ? Ag2 O3 2.401(3) . ? Ag2 O6 2.451(3) 2_565 ? Ag2 O5 2.573(4) 2_565 ? Ag2 Pt1 2.8274(5) 1_455 ? Ag2 Pt2 2.8437(5) . ? Pt1 N1 2.011(3) . ? Pt1 N2 2.019(3) 1_655 ? Pt1 N4 2.061(3) . ? Pt1 N3 2.066(3) . ? Pt1 Ag2 2.8274(5) 1_655 ? Pt2 N5 2.010(3) . ? Pt2 N6 2.011(3) . ? Pt2 N7 2.050(4) . ? Pt2 N8 2.055(3) . ? Cl O10 1.416(4) . ? Cl O9 1.427(4) . ? Cl O8 1.436(4) . ? Cl O7 1.441(4) . ? N1 C1 1.309(6) . ? N2 C25 1.326(5) . ? N2 Pt1 2.019(3) 1_455 ? N3 C11 1.487(5) . ? N4 C12 1.493(5) . ? N5 C13 1.302(6) . ? N6 C20 1.313(5) . ? N7 C19 1.466(5) . ? N8 C18 1.486(5) . ? N9 C10 1.335(6) . ? N9 C6 1.352(6) . ? O1 C1 1.264(5) . ? O2 C13 1.267(5) . ? O3 C20 1.258(5) . ? O4 C25 1.258(5) . ? O5 C30 1.240(6) . ? O5 Ag2 2.573(4) 2_564 ? O6 C30 1.267(6) . ? O6 Ag2 2.451(3) 2_564 ? C1 C2 1.529(6) . ? C2 C3 1.533(7) . ? C2 C5 1.538(6) . ? C2 C4 1.551(6) . ? C6 C7 1.389(6) . ? C7 C8 1.378(6) . ? C8 C9 1.392(6) . ? C8 C30 1.510(6) . ? C9 C10 1.384(6) . ? C11 C12 1.515(6) . ? C13 C14 1.534(6) . ? C14 C16 1.535(7) . ? C14 C15 1.539(6) . ? C14 C17 1.542(7) . ? C18 C19 1.502(6) . ? C20 C21 1.549(6) . ? C21 C22 1.527(6) . ? C21 C23 1.531(6) . ? C21 C24 1.536(6) . ? C25 C26 1.524(6) . ? C26 C28 1.527(6) . ? C26 C29 1.533(6) . ? C26 C27 1.547(6) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N9 Ag1 O2 138.88(12) . . ? N9 Ag1 O1 138.54(12) . . ? O2 Ag1 O1 82.54(11) . . ? N9 Ag1 Pt2 90.67(9) . . ? O2 Ag1 Pt2 78.66(8) . . ? O1 Ag1 Pt2 102.47(8) . . ? N9 Ag1 Pt1 86.09(9) . . ? O2 Ag1 Pt1 105.19(8) . . ? O1 Ag1 Pt1 78.69(8) . . ? Pt2 Ag1 Pt1 176.123(13) . . ? O4 Ag2 O3 96.02(11) . . ? O4 Ag2 O6 111.85(12) . 2_565 ? O3 Ag2 O6 146.60(12) . 2_565 ? O4 Ag2 O5 147.77(12) . 2_565 ? O3 Ag2 O5 110.25(11) . 2_565 ? O6 Ag2 O5 52.58(13) 2_565 2_565 ? O4 Ag2 Pt1 75.28(8) . 1_455 ? O3 Ag2 Pt1 87.20(8) . 1_455 ? O6 Ag2 Pt1 116.71(8) 2_565 1_455 ? O5 Ag2 Pt1 87.35(8) 2_565 1_455 ? O4 Ag2 Pt2 91.01(8) . . ? O3 Ag2 Pt2 75.40(8) . . ? O6 Ag2 Pt2 85.72(8) 2_565 . ? O5 Ag2 Pt2 113.00(8) 2_565 . ? Pt1 Ag2 Pt2 156.686(14) 1_455 . ? N1 Pt1 N2 87.10(14) . 1_655 ? N1 Pt1 N4 94.62(14) . . ? N2 Pt1 N4 177.69(15) 1_655 . ? N1 Pt1 N3 172.94(16) . . ? N2 Pt1 N3 94.41(14) 1_655 . ? N4 Pt1 N3 83.69(13) . . ? N1 Pt1 Ag2 85.58(12) . 1_655 ? N2 Pt1 Ag2 84.70(11) 1_655 1_655 ? N4 Pt1 Ag2 93.88(11) . 1_655 ? N3 Pt1 Ag2 87.69(12) . 1_655 ? N1 Pt1 Ag1 78.72(12) . . ? N2 Pt1 Ag1 103.72(11) 1_655 . ? N4 Pt1 Ag1 78.16(11) . . ? N3 Pt1 Ag1 107.54(11) . . ? Ag2 Pt1 Ag1 161.666(12) 1_655 . ? N5 Pt2 N6 90.91(14) . . ? N5 Pt2 N7 170.88(15) . . ? N6 Pt2 N7 93.27(14) . . ? N5 Pt2 N8 92.52(14) . . ? N6 Pt2 N8 176.53(14) . . ? N7 Pt2 N8 83.41(14) . . ? N5 Pt2 Ag2 86.19(11) . . ? N6 Pt2 Ag2 85.64(10) . . ? N7 Pt2 Ag2 86.05(11) . . ? N8 Pt2 Ag2 95.10(12) . . ? N5 Pt2 Ag1 79.26(11) . . ? N6 Pt2 Ag1 99.70(10) . . ? N7 Pt2 Ag1 107.96(11) . . ? N8 Pt2 Ag1 80.44(12) . . ? Ag2 Pt2 Ag1 164.534(11) . . ? O10 Cl O9 111.5(3) . . ? O10 Cl O8 109.1(2) . . ? O9 Cl O8 108.2(2) . . ? O10 Cl O7 108.9(2) . . ? O9 Cl O7 110.0(2) . . ? O8 Cl O7 109.1(3) . . ? C1 N1 Pt1 131.0(3) . . ? C25 N2 Pt1 124.8(3) . 1_455 ? C11 N3 Pt1 107.9(3) . . ? C12 N4 Pt1 109.0(3) . . ? C13 N5 Pt2 129.7(3) . . ? C20 N6 Pt2 125.6(3) . . ? C19 N7 Pt2 108.6(3) . . ? C18 N8 Pt2 108.5(2) . . ? C10 N9 C6 118.9(4) . . ? C10 N9 Ag1 121.0(3) . . ? C6 N9 Ag1 120.0(3) . . ? C1 O1 Ag1 114.0(3) . . ? C13 O2 Ag1 115.9(3) . . ? C20 O3 Ag2 117.9(3) . . ? C25 O4 Ag2 120.4(3) . . ? C30 O5 Ag2 88.5(3) . 2_564 ? C30 O6 Ag2 93.5(3) . 2_564 ? O1 C1 N1 122.8(4) . . ? O1 C1 C2 120.1(4) . . ? N1 C1 C2 117.1(4) . . ? C1 C2 C3 110.5(4) . . ? C1 C2 C5 112.0(4) . . ? C3 C2 C5 108.4(4) . . ? C1 C2 C4 106.5(4) . . ? C3 C2 C4 110.8(4) . . ? C5 C2 C4 108.7(4) . . ? N9 C6 C7 122.2(5) . . ? C8 C7 C6 119.0(5) . . ? C7 C8 C9 118.3(4) . . ? C7 C8 C30 119.8(4) . . ? C9 C8 C30 121.9(4) . . ? C10 C9 C8 119.9(5) . . ? N9 C10 C9 121.6(5) . . ? N3 C11 C12 108.8(4) . . ? N4 C12 C11 107.4(4) . . ? O2 C13 N5 122.4(4) . . ? O2 C13 C14 117.3(4) . . ? N5 C13 C14 120.2(4) . . ? C13 C14 C16 113.1(4) . . ? C13 C14 C15 105.2(4) . . ? C16 C14 C15 109.2(4) . . ? C13 C14 C17 109.6(4) . . ? C16 C14 C17 109.6(4) . . ? C15 C14 C17 110.1(4) . . ? N8 C18 C19 108.0(4) . . ? N7 C19 C18 108.3(4) . . ? O3 C20 N6 123.2(4) . . ? O3 C20 C21 117.7(4) . . ? N6 C20 C21 118.9(4) . . ? C22 C21 C23 109.5(4) . . ? C22 C21 C24 109.0(4) . . ? C23 C21 C24 110.5(4) . . ? C22 C21 C20 112.9(4) . . ? C23 C21 C20 109.0(4) . . ? C24 C21 C20 105.9(4) . . ? O4 C25 N2 120.9(4) . . ? O4 C25 C26 118.4(4) . . ? N2 C25 C26 120.5(4) . . ? C25 C26 C28 109.8(4) . . ? C25 C26 C29 106.4(4) . . ? C28 C26 C29 109.1(4) . . ? C25 C26 C27 113.5(4) . . ? C28 C26 C27 108.8(4) . . ? C29 C26 C27 109.1(4) . . ? O5 C30 O6 125.4(5) . . ? O5 C30 C8 118.0(5) . . ? O6 C30 C8 116.5(4) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N9 Ag1 Pt1 N1 -116.46(14) . . . . ? O2 Ag1 Pt1 N1 103.74(14) . . . . ? O1 Ag1 Pt1 N1 24.78(13) . . . . ? Pt2 Ag1 Pt1 N1 -83.1(2) . . . . ? N9 Ag1 Pt1 N2 -32.30(13) . . . 1_655 ? O2 Ag1 Pt1 N2 -172.10(13) . . . 1_655 ? O1 Ag1 Pt1 N2 108.94(13) . . . 1_655 ? Pt2 Ag1 Pt1 N2 1.1(2) . . . 1_655 ? N9 Ag1 Pt1 N4 146.32(13) . . . . ? O2 Ag1 Pt1 N4 6.51(13) . . . . ? O1 Ag1 Pt1 N4 -72.45(13) . . . . ? Pt2 Ag1 Pt1 N4 180(39) . . . . ? N9 Ag1 Pt1 N3 66.92(14) . . . . ? O2 Ag1 Pt1 N3 -72.88(13) . . . . ? O1 Ag1 Pt1 N3 -151.84(13) . . . . ? Pt2 Ag1 Pt1 N3 100.3(2) . . . . ? N9 Ag1 Pt1 Ag2 -148.06(10) . . . 1_655 ? O2 Ag1 Pt1 Ag2 72.13(9) . . . 1_655 ? O1 Ag1 Pt1 Ag2 -6.83(8) . . . 1_655 ? Pt2 Ag1 Pt1 Ag2 -114.7(2) . . . 1_655 ? O4 Ag2 Pt2 N5 165.41(12) . . . . ? O3 Ag2 Pt2 N5 69.45(13) . . . . ? O6 Ag2 Pt2 N5 -82.76(14) 2_565 . . . ? O5 Ag2 Pt2 N5 -36.69(14) 2_565 . . . ? Pt1 Ag2 Pt2 N5 112.38(10) 1_455 . . . ? O4 Ag2 Pt2 N6 74.21(13) . . . . ? O3 Ag2 Pt2 N6 -21.76(13) . . . . ? O6 Ag2 Pt2 N6 -173.96(13) 2_565 . . . ? O5 Ag2 Pt2 N6 -127.89(13) 2_565 . . . ? Pt1 Ag2 Pt2 N6 21.18(11) 1_455 . . . ? O4 Ag2 Pt2 N7 -19.38(13) . . . . ? O3 Ag2 Pt2 N7 -115.34(13) . . . . ? O6 Ag2 Pt2 N7 92.45(14) 2_565 . . . ? O5 Ag2 Pt2 N7 138.52(14) 2_565 . . . ? Pt1 Ag2 Pt2 N7 -72.41(11) 1_455 . . . ? O4 Ag2 Pt2 N8 -102.39(12) . . . . ? O3 Ag2 Pt2 N8 161.64(13) . . . . ? O6 Ag2 Pt2 N8 9.44(13) 2_565 . . . ? O5 Ag2 Pt2 N8 55.51(13) 2_565 . . . ? Pt1 Ag2 Pt2 N8 -155.42(10) 1_455 . . . ? O4 Ag2 Pt2 Ag1 -174.80(9) . . . . ? O3 Ag2 Pt2 Ag1 89.24(9) . . . . ? O6 Ag2 Pt2 Ag1 -62.97(10) 2_565 . . . ? O5 Ag2 Pt2 Ag1 -16.90(11) 2_565 . . . ? Pt1 Ag2 Pt2 Ag1 132.17(4) 1_455 . . . ? N9 Ag1 Pt2 N5 -115.61(14) . . . . ? O2 Ag1 Pt2 N5 24.39(13) . . . . ? O1 Ag1 Pt2 N5 104.02(13) . . . . ? Pt1 Ag1 Pt2 N5 -148.9(2) . . . . ? N9 Ag1 Pt2 N6 -26.53(13) . . . . ? O2 Ag1 Pt2 N6 113.47(13) . . . . ? O1 Ag1 Pt2 N6 -166.90(13) . . . . ? Pt1 Ag1 Pt2 N6 -59.8(2) . . . . ? N9 Ag1 Pt2 N7 70.14(14) . . . . ? O2 Ag1 Pt2 N7 -149.86(13) . . . . ? O1 Ag1 Pt2 N7 -70.23(13) . . . . ? Pt1 Ag1 Pt2 N7 36.9(2) . . . . ? N9 Ag1 Pt2 N8 149.96(13) . . . . ? O2 Ag1 Pt2 N8 -70.05(13) . . . . ? O1 Ag1 Pt2 N8 9.58(12) . . . . ? Pt1 Ag1 Pt2 N8 116.7(2) . . . . ? N9 Ag1 Pt2 Ag2 -135.72(10) . . . . ? O2 Ag1 Pt2 Ag2 4.28(9) . . . . ? O1 Ag1 Pt2 Ag2 83.91(9) . . . . ? Pt1 Ag1 Pt2 Ag2 -169.01(19) . . . . ? N2 Pt1 N1 C1 -137.1(4) 1_655 . . . ? N4 Pt1 N1 C1 44.4(4) . . . . ? N3 Pt1 N1 C1 120.3(11) . . . . ? Ag2 Pt1 N1 C1 138.0(4) 1_655 . . . ? Ag1 Pt1 N1 C1 -32.5(4) . . . . ? N1 Pt1 N3 C11 -61.2(12) . . . . ? N2 Pt1 N3 C11 -163.4(3) 1_655 . . . ? N4 Pt1 N3 C11 15.3(3) . . . . ? Ag2 Pt1 N3 C11 -78.9(3) 1_655 . . . ? Ag1 Pt1 N3 C11 90.7(3) . . . . ? N1 Pt1 N4 C12 -173.4(3) . . . . ? N2 Pt1 N4 C12 49(4) 1_655 . . . ? N3 Pt1 N4 C12 13.5(3) . . . . ? Ag2 Pt1 N4 C12 100.7(3) 1_655 . . . ? Ag1 Pt1 N4 C12 -96.0(3) . . . . ? N6 Pt2 N5 C13 -134.4(4) . . . . ? N7 Pt2 N5 C13 108.4(10) . . . . ? N8 Pt2 N5 C13 45.1(4) . . . . ? Ag2 Pt2 N5 C13 140.1(4) . . . . ? Ag1 Pt2 N5 C13 -34.6(4) . . . . ? N5 Pt2 N6 C20 -62.8(4) . . . . ? N7 Pt2 N6 C20 109.1(4) . . . . ? N8 Pt2 N6 C20 126(3) . . . . ? Ag2 Pt2 N6 C20 23.3(3) . . . . ? Ag1 Pt2 N6 C20 -142.0(3) . . . . ? N5 Pt2 N7 C19 -48.0(11) . . . . ? N6 Pt2 N7 C19 -165.1(3) . . . . ? N8 Pt2 N7 C19 15.9(3) . . . . ? Ag2 Pt2 N7 C19 -79.7(3) . . . . ? Ag1 Pt2 N7 C19 93.6(3) . . . . ? N5 Pt2 N8 C18 -175.3(3) . . . . ? N6 Pt2 N8 C18 -4(3) . . . . ? N7 Pt2 N8 C18 12.9(3) . . . . ? Ag2 Pt2 N8 C18 98.3(3) . . . . ? Ag1 Pt2 N8 C18 -96.6(3) . . . . ? O2 Ag1 N9 C10 28.3(4) . . . . ? O1 Ag1 N9 C10 -148.4(3) . . . . ? Pt2 Ag1 N9 C10 101.7(3) . . . . ? Pt1 Ag1 N9 C10 -80.4(3) . . . . ? O2 Ag1 N9 C6 -155.3(3) . . . . ? O1 Ag1 N9 C6 27.9(4) . . . . ? Pt2 Ag1 N9 C6 -81.9(3) . . . . ? Pt1 Ag1 N9 C6 96.0(3) . . . . ? N9 Ag1 O1 C1 37.7(4) . . . . ? O2 Ag1 O1 C1 -140.2(3) . . . . ? Pt2 Ag1 O1 C1 143.2(3) . . . . ? Pt1 Ag1 O1 C1 -33.0(3) . . . . ? N9 Ag1 O2 C13 47.7(4) . . . . ? O1 Ag1 O2 C13 -134.5(3) . . . . ? Pt2 Ag1 O2 C13 -30.1(3) . . . . ? Pt1 Ag1 O2 C13 149.4(3) . . . . ? O4 Ag2 O3 C20 -56.5(3) . . . . ? O6 Ag2 O3 C20 90.7(4) 2_565 . . . ? O5 Ag2 O3 C20 142.5(3) 2_565 . . . ? Pt1 Ag2 O3 C20 -131.3(3) 1_455 . . . ? Pt2 Ag2 O3 C20 33.0(3) . . . . ? O3 Ag2 O4 C25 -55.4(3) . . . . ? O6 Ag2 O4 C25 143.4(3) 2_565 . . . ? O5 Ag2 O4 C25 89.7(4) 2_565 . . . ? Pt1 Ag2 O4 C25 30.1(3) 1_455 . . . ? Pt2 Ag2 O4 C25 -130.8(3) . . . . ? Ag1 O1 C1 N1 24.1(6) . . . . ? Ag1 O1 C1 C2 -158.6(3) . . . . ? Pt1 N1 C1 O1 13.1(7) . . . . ? Pt1 N1 C1 C2 -164.3(3) . . . . ? O1 C1 C2 C3 26.0(6) . . . . ? N1 C1 C2 C3 -156.6(4) . . . . ? O1 C1 C2 C5 146.9(4) . . . . ? N1 C1 C2 C5 -35.6(6) . . . . ? O1 C1 C2 C4 -94.4(5) . . . . ? N1 C1 C2 C4 83.1(5) . . . . ? C10 N9 C6 C7 2.1(7) . . . . ? Ag1 N9 C6 C7 -174.4(4) . . . . ? N9 C6 C7 C8 -2.3(8) . . . . ? C6 C7 C8 C9 1.6(7) . . . . ? C6 C7 C8 C30 -178.3(4) . . . . ? C7 C8 C9 C10 -0.8(7) . . . . ? C30 C8 C9 C10 179.1(4) . . . . ? C6 N9 C10 C9 -1.3(7) . . . . ? Ag1 N9 C10 C9 175.2(4) . . . . ? C8 C9 C10 N9 0.7(8) . . . . ? Pt1 N3 C11 C12 -41.3(4) . . . . ? Pt1 N4 C12 C11 -39.1(4) . . . . ? N3 C11 C12 N4 53.6(5) . . . . ? Ag1 O2 C13 N5 18.3(6) . . . . ? Ag1 O2 C13 C14 -165.0(3) . . . . ? Pt2 N5 C13 O2 19.1(7) . . . . ? Pt2 N5 C13 C14 -157.5(3) . . . . ? O2 C13 C14 C16 176.5(4) . . . . ? N5 C13 C14 C16 -6.8(6) . . . . ? O2 C13 C14 C15 -64.5(5) . . . . ? N5 C13 C14 C15 112.3(5) . . . . ? O2 C13 C14 C17 53.8(6) . . . . ? N5 C13 C14 C17 -129.5(5) . . . . ? Pt2 N8 C18 C19 -38.8(4) . . . . ? Pt2 N7 C19 C18 -41.5(4) . . . . ? N8 C18 C19 N7 53.6(5) . . . . ? Ag2 O3 C20 N6 -29.4(6) . . . . ? Ag2 O3 C20 C21 146.4(3) . . . . ? Pt2 N6 C20 O3 -1.5(6) . . . . ? Pt2 N6 C20 C21 -177.3(3) . . . . ? O3 C20 C21 C22 163.0(4) . . . . ? N6 C20 C21 C22 -21.0(6) . . . . ? O3 C20 C21 C23 41.1(5) . . . . ? N6 C20 C21 C23 -142.8(4) . . . . ? O3 C20 C21 C24 -77.8(5) . . . . ? N6 C20 C21 C24 98.2(5) . . . . ? Ag2 O4 C25 N2 -16.7(6) . . . . ? Ag2 O4 C25 C26 168.0(3) . . . . ? Pt1 N2 C25 O4 -19.4(6) 1_455 . . . ? Pt1 N2 C25 C26 155.7(3) 1_455 . . . ? O4 C25 C26 C28 -22.1(6) . . . . ? N2 C25 C26 C28 162.7(4) . . . . ? O4 C25 C26 C29 95.9(5) . . . . ? N2 C25 C26 C29 -79.4(5) . . . . ? O4 C25 C26 C27 -144.1(4) . . . . ? N2 C25 C26 C27 40.6(6) . . . . ? Ag2 O5 C30 O6 -1.9(5) 2_564 . . . ? Ag2 O5 C30 C8 177.7(4) 2_564 . . . ? Ag2 O6 C30 O5 2.0(5) 2_564 . . . ? Ag2 O6 C30 C8 -177.6(3) 2_564 . . . ? C7 C8 C30 O5 -31.5(6) . . . . ? C9 C8 C30 O5 148.5(5) . . . . ? C7 C8 C30 O6 148.1(5) . . . . ? C9 C8 C30 O6 -31.8(6) . . . . ? _diffrn_measured_fraction_theta_max 0.973 _diffrn_reflns_theta_full 27.48 _diffrn_measured_fraction_theta_full 0.973 _refine_diff_density_max 0.854 _refine_diff_density_min -0.771 _refine_diff_density_rms 0.114 #===END #===END data_praga _database_code_depnum_ccdc_archive 'CCDC 286693' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C26 H60 Ag2 Cl N9 O11 Pt2' _chemical_formula_weight 1316.20 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M P-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 11.099(6) _cell_length_b 11.343(6) _cell_length_c 17.752(10) _cell_angle_alpha 96.903(6) _cell_angle_beta 90.673(8) _cell_angle_gamma 91.118(7) _cell_volume 2218(2) _cell_formula_units_Z 2 _cell_measurement_temperature 193(2) _cell_measurement_reflns_used ? _cell_measurement_theta_min ? _cell_measurement_theta_max ? _exptl_crystal_description prism _exptl_crystal_colour colorless _exptl_crystal_size_max 0.43 _exptl_crystal_size_mid 0.39 _exptl_crystal_size_min 0.36 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.971 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1268 _exptl_absorpt_coefficient_mu 7.273 _exptl_absorpt_correction_type empirical _exptl_absorpt_correction_T_min 0.1460 _exptl_absorpt_correction_T_max 0.1793 _exptl_absorpt_process_details sadabs _exptl_special_details ; ? ; _diffrn_ambient_temperature 193(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'Bruker P4' _diffrn_measurement_method '\w scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 6922 _diffrn_reflns_av_R_equivalents 0.0337 _diffrn_reflns_av_sigmaI/netI 0.0538 _diffrn_reflns_limit_h_min -12 _diffrn_reflns_limit_h_max 9 _diffrn_reflns_limit_k_min -12 _diffrn_reflns_limit_k_max 12 _diffrn_reflns_limit_l_min -16 _diffrn_reflns_limit_l_max 19 _diffrn_reflns_theta_min 4.86 _diffrn_reflns_theta_max 23.71 _reflns_number_total 5391 _reflns_number_gt 4139 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker XSCANS' _computing_cell_refinement 'Bruker XSCANS' _computing_data_reduction 'Bruker SHELXTL' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0995P)^2^+5.8534P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 5391 _refine_ls_number_parameters 472 _refine_ls_number_restraints 961 _refine_ls_R_factor_all 0.0723 _refine_ls_R_factor_gt 0.0539 _refine_ls_wR_factor_ref 0.1578 _refine_ls_wR_factor_gt 0.1470 _refine_ls_goodness_of_fit_ref 1.031 _refine_ls_restrained_S_all 1.029 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Pt1 Pt 0.65738(5) 0.30933(5) 0.25978(4) 0.0426(2) Uani 1 1 d . . . Pt2 Pt 1.15599(5) 0.29493(5) 0.28497(3) 0.0412(2) Uani 1 1 d . . . Ag1 Ag 0.90688(9) 0.31826(10) 0.28034(7) 0.0460(3) Uani 1 1 d . . . Ag2 Ag 1.40541(10) 0.27782(10) 0.26411(7) 0.0476(3) Uani 1 1 d . . . C1 C 0.7730(15) 0.0762(14) 0.2773(11) 0.059(4) Uani 1 1 d U . . C2 C 0.7623(17) -0.0606(16) 0.2717(13) 0.077(4) Uani 1 1 d U . . C3 C 0.8681(19) -0.1102(18) 0.2291(14) 0.101(6) Uani 1 1 d U . . H3A H 0.8767 -0.1938 0.2368 0.152 Uiso 1 1 calc R . . H3B H 0.9411 -0.0652 0.2475 0.152 Uiso 1 1 calc R . . H3C H 0.8563 -0.1043 0.1749 0.152 Uiso 1 1 calc R . . C4 C 0.780(3) -0.091(2) 0.3525(17) 0.139(7) Uani 1 1 d U . . H4A H 0.7093 -0.0669 0.3826 0.209 Uiso 1 1 calc R . . H4B H 0.8519 -0.0489 0.3754 0.209 Uiso 1 1 calc R . . H4C H 0.7903 -0.1769 0.3513 0.209 Uiso 1 1 calc R . . C5 C 0.651(2) -0.111(2) 0.2390(18) 0.133(7) Uani 1 1 d U . . H5A H 0.5836 -0.0771 0.2686 0.199 Uiso 1 1 calc R . . H5B H 0.6509 -0.1972 0.2395 0.199 Uiso 1 1 calc R . . H5C H 0.6436 -0.0928 0.1866 0.199 Uiso 1 1 calc R . . C6 C 0.5547(15) 0.2923(15) 0.4144(10) 0.058(4) Uani 1 1 d U . . C7 C 0.5813(15) 0.2839(16) 0.4984(11) 0.063(4) Uani 1 1 d U . . C8 C 0.687(2) 0.358(2) 0.5299(14) 0.125(6) Uani 1 1 d U . . H8A H 0.6726 0.4417 0.5251 0.188 Uiso 1 1 calc R . . H8B H 0.7595 0.3327 0.5017 0.188 Uiso 1 1 calc R . . H8C H 0.6988 0.3480 0.5835 0.188 Uiso 1 1 calc R . . C9 C 0.595(3) 0.158(2) 0.5032(15) 0.129(7) Uani 1 1 d U . . H9A H 0.6760 0.1346 0.4872 0.194 Uiso 1 1 calc R . . H9B H 0.5350 0.1128 0.4700 0.194 Uiso 1 1 calc R . . H9C H 0.5830 0.1424 0.5557 0.194 Uiso 1 1 calc R . . C10 C 0.484(2) 0.341(2) 0.5472(14) 0.119(6) Uani 1 1 d U . . H10A H 0.4266 0.3786 0.5154 0.179 Uiso 1 1 calc R . . H10B H 0.5197 0.4015 0.5854 0.179 Uiso 1 1 calc R . . H10C H 0.4415 0.2806 0.5725 0.179 Uiso 1 1 calc R . . C11 C 0.674(2) 0.523(2) 0.1867(14) 0.100(5) Uani 1 1 d U . . H11A H 0.6405 0.6005 0.1768 0.120 Uiso 1 1 calc R . . H11B H 0.7626 0.5302 0.1876 0.120 Uiso 1 1 calc R . . C12 C 0.635(2) 0.433(2) 0.1301(14) 0.094(5) Uani 1 1 d U . . H12 H 0.5445 0.4273 0.1302 0.112 Uiso 1 1 calc R . . C13 C 0.673(3) 0.468(3) 0.0584(18) 0.149(8) Uani 1 1 d U . . H13A H 0.6977 0.5520 0.0653 0.223 Uiso 1 1 calc R . . H13B H 0.6062 0.4557 0.0215 0.223 Uiso 1 1 calc R . . H13C H 0.7412 0.4197 0.0398 0.223 Uiso 1 1 calc R . . C14 C 1.0448(15) 0.2762(13) 0.1287(9) 0.050(3) Uani 1 1 d U . . C15 C 1.0501(17) 0.2429(15) 0.0449(10) 0.066(4) Uani 1 1 d U . . C16 C 0.9384(19) 0.171(2) 0.0134(13) 0.097(6) Uani 1 1 d U . . H16A H 0.9622 0.1099 -0.0269 0.145 Uiso 1 1 calc R . . H16B H 0.8813 0.2244 -0.0072 0.145 Uiso 1 1 calc R . . H16C H 0.9001 0.1338 0.0542 0.145 Uiso 1 1 calc R . . C17 C 1.035(2) 0.356(2) 0.0057(13) 0.107(6) Uani 1 1 d U . . H17A H 1.1083 0.4062 0.0145 0.160 Uiso 1 1 calc R . . H17B H 0.9658 0.3997 0.0266 0.160 Uiso 1 1 calc R . . H17C H 1.0231 0.3338 -0.0490 0.160 Uiso 1 1 calc R . . C18 C 1.164(2) 0.178(2) 0.0176(13) 0.105(6) Uani 1 1 d U . . H18A H 1.2328 0.2088 0.0495 0.157 Uiso 1 1 calc R . . H18B H 1.1789 0.1899 -0.0352 0.157 Uiso 1 1 calc R . . H18C H 1.1529 0.0926 0.0211 0.157 Uiso 1 1 calc R . . C19 C 1.2701(15) 0.5183(13) 0.2418(9) 0.051(3) Uani 1 1 d U . . C20 C 1.2615(14) 0.6420(13) 0.2168(10) 0.053(3) Uani 1 1 d U . . C21 C 1.273(2) 0.6277(17) 0.1323(12) 0.096(6) Uani 1 1 d U . . H21A H 1.2060 0.5784 0.1091 0.144 Uiso 1 1 calc R . . H21B H 1.3495 0.5894 0.1184 0.144 Uiso 1 1 calc R . . H21C H 1.2719 0.7059 0.1142 0.144 Uiso 1 1 calc R . . C22 C 1.145(2) 0.7048(18) 0.2399(15) 0.107(6) Uani 1 1 d U . . H22A H 1.1364 0.7096 0.2951 0.161 Uiso 1 1 calc R . . H22B H 1.0765 0.6601 0.2147 0.161 Uiso 1 1 calc R . . H22C H 1.1478 0.7851 0.2248 0.161 Uiso 1 1 calc R . . C23 C 1.3647(17) 0.7203(15) 0.2483(12) 0.077(5) Uani 1 1 d U . . H23A H 1.3594 0.7978 0.2293 0.115 Uiso 1 1 calc R . . H23B H 1.4408 0.6835 0.2322 0.115 Uiso 1 1 calc R . . H23C H 1.3615 0.7311 0.3038 0.115 Uiso 1 1 calc R . . C24 C 1.140(2) 0.2148(18) 0.4354(12) 0.089(4) Uani 1 1 d U . . H24A H 1.1766 0.2125 0.4863 0.107 Uiso 1 1 calc R . . H24B H 1.0511 0.2161 0.4408 0.107 Uiso 1 1 calc R . . C25 C 1.1736(18) 0.1102(16) 0.3849(11) 0.073(4) Uani 1 1 d U . . H25 H 1.2635 0.1079 0.3833 0.088 Uiso 1 1 calc R . . C26 C 1.130(2) 0.007(2) 0.4147(15) 0.121(7) Uani 1 1 d U . . H26A H 1.0515 0.0223 0.4375 0.181 Uiso 1 1 calc R . . H26B H 1.1872 -0.0140 0.4534 0.181 Uiso 1 1 calc R . . H26C H 1.1230 -0.0590 0.3737 0.181 Uiso 1 1 calc R . . N1 N 0.6800(11) 0.1340(11) 0.2546(9) 0.064(3) Uani 1 1 d U . . H1 H 0.6708 0.1063 0.2039 0.077 Uiso 1 1 d R . . N2 N 0.6422(12) 0.3151(13) 0.3723(9) 0.066(3) Uani 1 1 d U . . H2 H 0.6660 0.3914 0.3906 0.079 Uiso 1 1 d R . . N3 N 0.6294(14) 0.4905(14) 0.2607(11) 0.089(4) Uani 1 1 d U . . H3D H 0.5488 0.5065 0.2659 0.106 Uiso 1 1 calc R . . H3E H 0.6713 0.5329 0.3003 0.106 Uiso 1 1 calc R . . N4 N 0.6851(14) 0.3170(15) 0.1473(9) 0.083(4) Uani 1 1 d U . . H4D H 0.7661 0.3141 0.1369 0.100 Uiso 1 1 calc R . . H4E H 0.6462 0.2544 0.1185 0.100 Uiso 1 1 calc R . . N5 N 1.1338(12) 0.2516(11) 0.1716(7) 0.057(3) Uani 1 1 d U . . H5 H 1.1383 0.1701 0.1640 0.068 Uiso 1 1 d R . . N6 N 1.1798(12) 0.4643(12) 0.2673(8) 0.059(3) Uani 1 1 d U . . H6 H 1.1650 0.5070 0.3136 0.071 Uiso 1 1 d R . . N7 N 1.1841(13) 0.3270(13) 0.4020(8) 0.069(3) Uani 1 1 d U . . H7A H 1.2647 0.3414 0.4131 0.083 Uiso 1 1 calc R . . H7B H 1.1416 0.3921 0.4220 0.083 Uiso 1 1 calc R . . N8 N 1.1269(12) 0.1232(12) 0.3067(8) 0.063(3) Uani 1 1 d U . . H8D H 1.0458 0.1047 0.3033 0.076 Uiso 1 1 calc R . . H8E H 1.1660 0.0720 0.2714 0.076 Uiso 1 1 calc R . . N9 N 1.3667(15) 0.0296(12) 0.1590(9) 0.071(4) Uani 1 1 d DU . . Cl1 Cl 0.8997(8) 0.5620(8) 0.3860(6) 0.144(3) Uani 1 1 d DU . . O1 O 0.8647(10) 0.1247(9) 0.3030(7) 0.061(3) Uani 1 1 d U . . O2 O 0.9528(10) 0.3274(10) 0.1534(6) 0.064(3) Uani 1 1 d U . . O3 O 0.9021(14) 0.5490(14) 0.3075(9) 0.115(4) Uani 1 1 d DU . . O4 O 0.9282(15) 0.4522(13) 0.4081(10) 0.118(4) Uani 1 1 d DU . . O5 O 0.9969(18) 0.643(2) 0.4156(14) 0.181(7) Uani 1 1 d DU . . O6 O 0.7874(13) 0.6022(15) 0.4125(10) 0.120(5) Uani 1 1 d DU . . O7 O 1.3713(9) 0.4658(9) 0.2315(6) 0.056(3) Uani 1 1 d U . . O8 O 0.4513(10) 0.2768(11) 0.3897(7) 0.071(3) Uani 1 1 d U . . O9 O 1.4075(14) 0.1304(12) 0.1501(9) 0.104(4) Uani 1 1 d DU . . O10 O 1.3495(19) 0.0321(15) 0.2255(11) 0.143(5) Uani 1 1 d DU . . O11 O 1.364(2) -0.0458(14) 0.1104(10) 0.148(6) Uani 1 1 d DU . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt1 0.0255(4) 0.0420(4) 0.0618(5) 0.0131(3) -0.0038(3) 0.0000(3) Pt2 0.0258(4) 0.0420(4) 0.0570(4) 0.0115(3) -0.0049(3) -0.0004(3) Ag1 0.0247(7) 0.0452(6) 0.0697(8) 0.0141(6) -0.0020(5) -0.0005(5) Ag2 0.0261(7) 0.0479(7) 0.0721(9) 0.0212(6) -0.0035(5) 0.0012(5) C1 0.034(7) 0.043(7) 0.100(8) 0.010(7) -0.001(7) 0.011(6) C2 0.059(8) 0.053(8) 0.119(10) 0.012(8) -0.007(8) 0.007(7) C3 0.083(12) 0.069(10) 0.150(14) 0.000(11) 0.014(11) 0.029(10) C4 0.156(14) 0.090(12) 0.174(15) 0.024(13) 0.030(14) 0.005(12) C5 0.095(13) 0.076(11) 0.220(16) -0.006(13) -0.018(13) -0.004(11) C6 0.042(7) 0.060(7) 0.075(8) 0.021(7) -0.003(7) -0.003(7) C7 0.047(8) 0.068(8) 0.075(8) 0.022(7) -0.005(7) 0.001(7) C8 0.129(13) 0.144(13) 0.105(12) 0.031(12) -0.009(11) -0.036(12) C9 0.158(14) 0.122(13) 0.113(13) 0.036(12) -0.021(12) 0.013(13) C10 0.125(13) 0.148(14) 0.090(12) 0.029(12) -0.009(11) 0.041(12) C11 0.082(9) 0.098(9) 0.123(10) 0.034(9) -0.020(9) 0.001(8) C12 0.085(9) 0.104(9) 0.100(9) 0.045(8) -0.015(8) 0.003(8) C13 0.121(15) 0.166(17) 0.163(17) 0.033(16) 0.000(15) 0.005(15) C14 0.053(8) 0.044(7) 0.056(7) 0.013(6) -0.003(6) 0.007(6) C15 0.072(8) 0.056(7) 0.069(8) 0.008(7) -0.003(7) 0.011(7) C16 0.085(12) 0.104(12) 0.094(12) -0.016(11) -0.010(10) -0.010(11) C17 0.127(13) 0.107(12) 0.087(12) 0.021(11) -0.014(11) -0.002(11) C18 0.095(12) 0.128(12) 0.088(11) -0.006(11) 0.004(10) 0.015(11) C19 0.047(7) 0.044(6) 0.064(7) 0.020(6) -0.012(6) 0.004(6) C20 0.046(7) 0.044(7) 0.070(8) 0.016(7) -0.007(7) 0.011(6) C21 0.130(13) 0.066(10) 0.093(12) 0.011(10) -0.020(11) 0.013(10) C22 0.103(11) 0.069(10) 0.152(13) 0.020(10) 0.008(11) 0.014(10) C23 0.081(11) 0.054(9) 0.098(11) 0.022(9) -0.024(9) -0.001(9) C24 0.091(9) 0.095(9) 0.087(9) 0.028(8) -0.006(8) 0.012(8) C25 0.082(8) 0.067(8) 0.078(8) 0.037(7) -0.011(7) -0.001(7) C26 0.136(15) 0.116(14) 0.116(15) 0.037(13) -0.007(13) 0.025(13) N1 0.043(6) 0.054(6) 0.095(7) 0.013(6) -0.010(5) 0.000(5) N2 0.046(6) 0.071(6) 0.083(6) 0.014(6) -0.003(5) 0.004(5) N3 0.065(7) 0.082(7) 0.121(8) 0.026(7) -0.020(7) 0.006(6) N4 0.060(7) 0.096(8) 0.096(8) 0.027(7) -0.013(6) -0.007(7) N5 0.058(6) 0.048(5) 0.064(6) 0.010(5) -0.008(5) 0.009(5) N6 0.051(6) 0.056(5) 0.071(6) 0.014(5) -0.005(5) 0.002(5) N7 0.061(7) 0.075(7) 0.072(7) 0.010(6) -0.009(6) 0.002(6) N8 0.057(7) 0.057(6) 0.080(7) 0.027(6) -0.006(6) -0.001(6) N9 0.119(10) 0.049(7) 0.050(8) 0.014(7) 0.002(8) 0.039(8) Cl1 0.138(6) 0.125(5) 0.163(6) -0.013(5) -0.017(5) 0.007(5) O1 0.047(5) 0.052(5) 0.089(6) 0.026(5) -0.011(5) 0.002(5) O2 0.053(6) 0.073(6) 0.068(6) 0.019(5) -0.010(5) 0.005(5) O3 0.112(7) 0.111(7) 0.114(7) -0.012(7) -0.015(7) -0.002(6) O4 0.113(7) 0.108(7) 0.134(7) 0.023(7) -0.010(7) 0.013(7) O5 0.154(13) 0.180(13) 0.197(14) -0.024(12) -0.010(12) -0.041(12) O6 0.070(9) 0.132(11) 0.150(11) -0.013(10) 0.034(9) 0.010(9) O7 0.043(6) 0.047(5) 0.082(6) 0.026(5) 0.003(5) 0.006(5) O8 0.051(6) 0.095(7) 0.069(6) 0.026(6) -0.010(5) -0.016(6) O9 0.119(9) 0.078(8) 0.115(9) 0.003(8) 0.014(8) -0.006(8) O10 0.199(13) 0.097(10) 0.138(12) 0.028(10) 0.033(11) 0.059(10) O11 0.258(17) 0.077(10) 0.105(12) -0.002(9) -0.020(12) -0.009(11) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt1 N2 2.000(15) . ? Pt1 N1 2.001(13) . ? Pt1 N4 2.036(16) . ? Pt1 N3 2.082(15) . ? Pt1 Ag1 2.7872(19) . ? Pt1 Ag2 2.8157(19) 1_455 ? Pt2 N6 1.997(13) . ? Pt2 N5 2.024(13) . ? Pt2 N8 2.050(13) . ? Pt2 N7 2.085(14) . ? Pt2 Ag1 2.7839(19) . ? Pt2 Ag2 2.8047(19) . ? Ag1 O1 2.319(10) . ? Ag1 O2 2.330(12) . ? Ag1 O4 2.580(17) . ? Ag1 O3 2.605(16) . ? Ag2 O8 2.283(12) 1_655 ? Ag2 O7 2.313(10) . ? Ag2 O9 2.465(15) . ? Ag2 Pt1 2.8157(19) 1_655 ? C1 O1 1.204(17) . ? C1 N1 1.319(19) . ? C1 C2 1.55(2) . ? C2 C5 1.43(3) . ? C2 C3 1.49(3) . ? C2 C4 1.53(3) . ? C3 H3A 0.9800 . ? C3 H3B 0.9800 . ? C3 H3C 0.9800 . ? C4 H4A 0.9800 . ? C4 H4B 0.9800 . ? C4 H4C 0.9800 . ? C5 H5A 0.9800 . ? C5 H5B 0.9800 . ? C5 H5C 0.9800 . ? C6 O8 1.225(18) . ? C6 N2 1.27(2) . ? C6 C7 1.53(2) . ? C7 C9 1.45(3) . ? C7 C8 1.49(3) . ? C7 C10 1.50(3) . ? C8 H8A 0.9800 . ? C8 H8B 0.9800 . ? C8 H8C 0.9800 . ? C9 H9A 0.9800 . ? C9 H9B 0.9800 . ? C9 H9C 0.9800 . ? C10 H10A 0.9800 . ? C10 H10B 0.9800 . ? C10 H10C 0.9800 . ? C11 C12 1.40(3) . ? C11 N3 1.49(3) . ? C11 H11A 0.9900 . ? C11 H11B 0.9900 . ? C12 C13 1.44(3) . ? C12 N4 1.50(2) . ? C12 H12 1.0000 . ? C13 H13A 0.9800 . ? C13 H13B 0.9800 . ? C13 H13C 0.9800 . ? C14 O2 1.243(17) . ? C14 N5 1.295(19) . ? C14 C15 1.49(2) . ? C15 C18 1.53(3) . ? C15 C16 1.53(2) . ? C15 C17 1.54(3) . ? C16 H16A 0.9800 . ? C16 H16B 0.9800 . ? C16 H16C 0.9800 . ? C17 H17A 0.9800 . ? C17 H17B 0.9800 . ? C17 H17C 0.9800 . ? C18 H18A 0.9800 . ? C18 H18B 0.9800 . ? C18 H18C 0.9800 . ? C19 N6 1.280(19) . ? C19 O7 1.287(17) . ? C19 C20 1.53(2) . ? C20 C23 1.50(2) . ? C20 C21 1.50(3) . ? C20 C22 1.52(2) . ? C21 H21A 0.9800 . ? C21 H21B 0.9800 . ? C21 H21C 0.9800 . ? C22 H22A 0.9800 . ? C22 H22B 0.9800 . ? C22 H22C 0.9800 . ? C23 H23A 0.9800 . ? C23 H23B 0.9800 . ? C23 H23C 0.9800 . ? C24 C25 1.46(3) . ? C24 N7 1.54(2) . ? C24 H24A 0.9900 . ? C24 H24B 0.9900 . ? C25 C26 1.42(3) . ? C25 N8 1.50(2) . ? C25 H25 1.0000 . ? C26 H26A 0.9800 . ? C26 H26B 0.9800 . ? C26 H26C 0.9800 . ? N1 H1 0.9200 . ? N2 H2 0.9200 . ? N3 H3D 0.9200 . ? N3 H3E 0.9200 . ? N4 H4D 0.9200 . ? N4 H4E 0.9200 . ? N5 H5 0.9200 . ? N6 H6 0.9200 . ? N7 H7A 0.9200 . ? N7 H7B 0.9200 . ? N8 H8D 0.9200 . ? N8 H8E 0.9200 . ? N9 O11 1.139(14) . ? N9 O10 1.196(15) . ? N9 O9 1.250(14) . ? Cl1 O3 1.385(13) . ? Cl1 O4 1.391(13) . ? Cl1 O6 1.402(12) . ? Cl1 O5 1.454(15) . ? O8 Ag2 2.283(12) 1_455 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N2 Pt1 N1 88.4(6) . . ? N2 Pt1 N4 174.3(6) . . ? N1 Pt1 N4 95.2(7) . . ? N2 Pt1 N3 93.6(7) . . ? N1 Pt1 N3 177.4(6) . . ? N4 Pt1 N3 82.9(7) . . ? N2 Pt1 Ag1 88.2(4) . . ? N1 Pt1 Ag1 83.2(4) . . ? N4 Pt1 Ag1 87.9(4) . . ? N3 Pt1 Ag1 98.4(4) . . ? N2 Pt1 Ag2 82.3(4) . 1_455 ? N1 Pt1 Ag2 90.9(4) . 1_455 ? N4 Pt1 Ag2 102.0(4) . 1_455 ? N3 Pt1 Ag2 87.8(4) . 1_455 ? Ag1 Pt1 Ag2 169.01(4) . 1_455 ? N6 Pt2 N5 88.8(5) . . ? N6 Pt2 N8 177.7(6) . . ? N5 Pt2 N8 92.8(5) . . ? N6 Pt2 N7 94.9(6) . . ? N5 Pt2 N7 175.7(5) . . ? N8 Pt2 N7 83.6(6) . . ? N6 Pt2 Ag1 90.8(4) . . ? N5 Pt2 Ag1 83.0(4) . . ? N8 Pt2 Ag1 87.8(4) . . ? N7 Pt2 Ag1 99.1(4) . . ? N6 Pt2 Ag2 85.3(4) . . ? N5 Pt2 Ag2 88.2(4) . . ? N8 Pt2 Ag2 96.4(4) . . ? N7 Pt2 Ag2 90.0(4) . . ? Ag1 Pt2 Ag2 170.43(4) . . ? O1 Ag1 O2 111.3(4) . . ? O1 Ag1 O4 109.3(5) . . ? O2 Ag1 O4 138.1(5) . . ? O1 Ag1 O3 155.6(5) . . ? O2 Ag1 O3 91.6(5) . . ? O4 Ag1 O3 50.8(5) . . ? O1 Ag1 Pt2 94.8(3) . . ? O2 Ag1 Pt2 79.4(3) . . ? O4 Ag1 Pt2 87.3(4) . . ? O3 Ag1 Pt2 97.7(4) . . ? O1 Ag1 Pt1 79.5(3) . . ? O2 Ag1 Pt1 96.1(3) . . ? O4 Ag1 Pt1 101.1(4) . . ? O3 Ag1 Pt1 90.1(3) . . ? Pt2 Ag1 Pt1 171.05(5) . . ? O8 Ag2 O7 113.3(4) 1_655 . ? O8 Ag2 O9 135.4(5) 1_655 . ? O7 Ag2 O9 110.8(5) . . ? O8 Ag2 Pt2 95.1(3) 1_655 . ? O7 Ag2 Pt2 78.8(3) . . ? O9 Ag2 Pt2 99.8(4) . . ? O8 Ag2 Pt1 80.3(3) 1_655 1_655 ? O7 Ag2 Pt1 92.7(3) . 1_655 ? O9 Ag2 Pt1 91.2(4) . 1_655 ? Pt2 Ag2 Pt1 167.89(5) . 1_655 ? O1 C1 N1 123.4(15) . . ? O1 C1 C2 118.7(15) . . ? N1 C1 C2 117.8(15) . . ? C5 C2 C3 112(2) . . ? C5 C2 C4 111(2) . . ? C3 C2 C4 105.4(18) . . ? C5 C2 C1 114.9(17) . . ? C3 C2 C1 107.6(16) . . ? C4 C2 C1 105.7(18) . . ? C2 C3 H3A 109.5 . . ? C2 C3 H3B 109.5 . . ? H3A C3 H3B 109.5 . . ? C2 C3 H3C 109.5 . . ? H3A C3 H3C 109.5 . . ? H3B C3 H3C 109.5 . . ? C2 C4 H4A 109.5 . . ? C2 C4 H4B 109.5 . . ? H4A C4 H4B 109.5 . . ? C2 C4 H4C 109.5 . . ? H4A C4 H4C 109.5 . . ? H4B C4 H4C 109.5 . . ? C2 C5 H5A 109.5 . . ? C2 C5 H5B 109.5 . . ? H5A C5 H5B 109.5 . . ? C2 C5 H5C 109.5 . . ? H5A C5 H5C 109.5 . . ? H5B C5 H5C 109.5 . . ? O8 C6 N2 122.2(17) . . ? O8 C6 C7 119.7(16) . . ? N2 C6 C7 118.2(15) . . ? C9 C7 C8 113.3(19) . . ? C9 C7 C10 115(2) . . ? C8 C7 C10 100(2) . . ? C9 C7 C6 104.9(17) . . ? C8 C7 C6 114.1(16) . . ? C10 C7 C6 110.7(15) . . ? C7 C8 H8A 109.5 . . ? C7 C8 H8B 109.5 . . ? H8A C8 H8B 109.5 . . ? C7 C8 H8C 109.5 . . ? H8A C8 H8C 109.5 . . ? H8B C8 H8C 109.5 . . ? C7 C9 H9A 109.5 . . ? C7 C9 H9B 109.5 . . ? H9A C9 H9B 109.5 . . ? C7 C9 H9C 109.5 . . ? H9A C9 H9C 109.5 . . ? H9B C9 H9C 109.5 . . ? C7 C10 H10A 109.5 . . ? C7 C10 H10B 109.5 . . ? H10A C10 H10B 109.5 . . ? C7 C10 H10C 109.5 . . ? H10A C10 H10C 109.5 . . ? H10B C10 H10C 109.5 . . ? C12 C11 N3 107.3(19) . . ? C12 C11 H11A 110.3 . . ? N3 C11 H11A 110.3 . . ? C12 C11 H11B 110.3 . . ? N3 C11 H11B 110.3 . . ? H11A C11 H11B 108.5 . . ? C11 C12 C13 107(2) . . ? C11 C12 N4 108.9(18) . . ? C13 C12 N4 114(2) . . ? C11 C12 H12 109.1 . . ? C13 C12 H12 109.1 . . ? N4 C12 H12 109.1 . . ? C12 C13 H13A 109.5 . . ? C12 C13 H13B 109.5 . . ? H13A C13 H13B 109.5 . . ? C12 C13 H13C 109.5 . . ? H13A C13 H13C 109.5 . . ? H13B C13 H13C 109.5 . . ? O2 C14 N5 123.5(15) . . ? O2 C14 C15 116.7(15) . . ? N5 C14 C15 119.8(16) . . ? C14 C15 C18 114.7(16) . . ? C14 C15 C16 112.2(17) . . ? C18 C15 C16 109.6(16) . . ? C14 C15 C17 108.6(15) . . ? C18 C15 C17 110.6(18) . . ? C16 C15 C17 100.1(16) . . ? C15 C16 H16A 109.5 . . ? C15 C16 H16B 109.5 . . ? H16A C16 H16B 109.5 . . ? C15 C16 H16C 109.5 . . ? H16A C16 H16C 109.5 . . ? H16B C16 H16C 109.5 . . ? C15 C17 H17A 109.5 . . ? C15 C17 H17B 109.5 . . ? H17A C17 H17B 109.5 . . ? C15 C17 H17C 109.5 . . ? H17A C17 H17C 109.5 . . ? H17B C17 H17C 109.5 . . ? C15 C18 H18A 109.5 . . ? C15 C18 H18B 109.5 . . ? H18A C18 H18B 109.5 . . ? C15 C18 H18C 109.5 . . ? H18A C18 H18C 109.5 . . ? H18B C18 H18C 109.5 . . ? N6 C19 O7 120.4(14) . . ? N6 C19 C20 122.6(15) . . ? O7 C19 C20 116.9(14) . . ? C23 C20 C21 106.6(16) . . ? C23 C20 C22 107.9(16) . . ? C21 C20 C22 110.3(16) . . ? C23 C20 C19 111.1(13) . . ? C21 C20 C19 106.9(14) . . ? C22 C20 C19 113.9(15) . . ? C20 C21 H21A 109.5 . . ? C20 C21 H21B 109.5 . . ? H21A C21 H21B 109.5 . . ? C20 C21 H21C 109.5 . . ? H21A C21 H21C 109.5 . . ? H21B C21 H21C 109.5 . . ? C20 C22 H22A 109.5 . . ? C20 C22 H22B 109.5 . . ? H22A C22 H22B 109.5 . . ? C20 C22 H22C 109.5 . . ? H22A C22 H22C 109.5 . . ? H22B C22 H22C 109.5 . . ? C20 C23 H23A 109.5 . . ? C20 C23 H23B 109.5 . . ? H23A C23 H23B 109.5 . . ? C20 C23 H23C 109.5 . . ? H23A C23 H23C 109.5 . . ? H23B C23 H23C 109.5 . . ? C25 C24 N7 109.0(17) . . ? C25 C24 H24A 109.9 . . ? N7 C24 H24A 109.9 . . ? C25 C24 H24B 109.9 . . ? N7 C24 H24B 109.9 . . ? H24A C24 H24B 108.3 . . ? C26 C25 C24 109.0(19) . . ? C26 C25 N8 114.4(17) . . ? C24 C25 N8 108.2(15) . . ? C26 C25 H25 108.4 . . ? C24 C25 H25 108.4 . . ? N8 C25 H25 108.4 . . ? C25 C26 H26A 109.5 . . ? C25 C26 H26B 109.5 . . ? H26A C26 H26B 109.5 . . ? C25 C26 H26C 109.5 . . ? H26A C26 H26C 109.5 . . ? H26B C26 H26C 109.5 . . ? C1 N1 Pt1 128.9(11) . . ? C1 N1 H1 104.4 . . ? Pt1 N1 H1 104.6 . . ? C6 N2 Pt1 132.5(12) . . ? C6 N2 H2 104.1 . . ? Pt1 N2 H2 104.1 . . ? C11 N3 Pt1 106.7(13) . . ? C11 N3 H3D 110.4 . . ? Pt1 N3 H3D 110.4 . . ? C11 N3 H3E 110.4 . . ? Pt1 N3 H3E 110.4 . . ? H3D N3 H3E 108.6 . . ? C12 N4 Pt1 106.2(13) . . ? C12 N4 H4D 110.5 . . ? Pt1 N4 H4D 110.5 . . ? C12 N4 H4E 110.5 . . ? Pt1 N4 H4E 110.5 . . ? H4D N4 H4E 108.7 . . ? C14 N5 Pt2 128.3(12) . . ? C14 N5 H5 104.8 . . ? Pt2 N5 H5 104.9 . . ? C19 N6 Pt2 131.0(12) . . ? C19 N6 H6 104.3 . . ? Pt2 N6 H6 104.4 . . ? C24 N7 Pt2 106.8(11) . . ? C24 N7 H7A 110.4 . . ? Pt2 N7 H7A 110.4 . . ? C24 N7 H7B 110.4 . . ? Pt2 N7 H7B 110.4 . . ? H7A N7 H7B 108.6 . . ? C25 N8 Pt2 109.1(10) . . ? C25 N8 H8D 109.9 . . ? Pt2 N8 H8D 109.9 . . ? C25 N8 H8E 109.9 . . ? Pt2 N8 H8E 109.9 . . ? H8D N8 H8E 108.3 . . ? O11 N9 O10 132.4(19) . . ? O11 N9 O9 121.3(18) . . ? O10 N9 O9 105.7(17) . . ? O3 Cl1 O4 106.6(12) . . ? O3 Cl1 O6 111.1(12) . . ? O4 Cl1 O6 112.9(13) . . ? O3 Cl1 O5 109.0(14) . . ? O4 Cl1 O5 105.6(14) . . ? O6 Cl1 O5 111.4(13) . . ? C1 O1 Ag1 119.2(10) . . ? C14 O2 Ag1 117.3(10) . . ? Cl1 O3 Ag1 99.8(9) . . ? Cl1 O4 Ag1 100.8(9) . . ? C19 O7 Ag2 123.2(9) . . ? C6 O8 Ag2 121.9(12) . 1_455 ? N9 O9 Ag2 115.2(12) . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N6 Pt2 Ag1 O1 -178.9(5) . . . . ? N5 Pt2 Ag1 O1 92.4(5) . . . . ? N8 Pt2 Ag1 O1 -0.7(5) . . . . ? N7 Pt2 Ag1 O1 -83.8(5) . . . . ? Ag2 Pt2 Ag1 O1 115.7(4) . . . . ? N6 Pt2 Ag1 O2 70.3(5) . . . . ? N5 Pt2 Ag1 O2 -18.4(5) . . . . ? N8 Pt2 Ag1 O2 -111.6(5) . . . . ? N7 Pt2 Ag1 O2 165.3(5) . . . . ? Ag2 Pt2 Ag1 O2 4.8(4) . . . . ? N6 Pt2 Ag1 O4 -69.8(5) . . . . ? N5 Pt2 Ag1 O4 -158.5(5) . . . . ? N8 Pt2 Ag1 O4 108.4(5) . . . . ? N7 Pt2 Ag1 O4 25.3(5) . . . . ? Ag2 Pt2 Ag1 O4 -135.2(4) . . . . ? N6 Pt2 Ag1 O3 -19.9(5) . . . . ? N5 Pt2 Ag1 O3 -108.6(5) . . . . ? N8 Pt2 Ag1 O3 158.3(5) . . . . ? N7 Pt2 Ag1 O3 75.2(5) . . . . ? Ag2 Pt2 Ag1 O3 -85.3(4) . . . . ? N6 Pt2 Ag1 Pt1 130.5(5) . . . . ? N5 Pt2 Ag1 Pt1 41.8(5) . . . . ? N8 Pt2 Ag1 Pt1 -51.3(5) . . . . ? N7 Pt2 Ag1 Pt1 -134.4(5) . . . . ? Ag2 Pt2 Ag1 Pt1 65.1(4) . . . . ? N2 Pt1 Ag1 O1 73.5(5) . . . . ? N1 Pt1 Ag1 O1 -15.1(6) . . . . ? N4 Pt1 Ag1 O1 -110.6(6) . . . . ? N3 Pt1 Ag1 O1 166.9(6) . . . . ? Ag2 Pt1 Ag1 O1 43.3(4) 1_455 . . . ? N2 Pt1 Ag1 O2 -175.9(5) . . . . ? N1 Pt1 Ag1 O2 95.5(5) . . . . ? N4 Pt1 Ag1 O2 0.0(5) . . . . ? N3 Pt1 Ag1 O2 -82.5(6) . . . . ? Ag2 Pt1 Ag1 O2 153.9(4) 1_455 . . . ? N2 Pt1 Ag1 O4 -34.3(5) . . . . ? N1 Pt1 Ag1 O4 -122.9(6) . . . . ? N4 Pt1 Ag1 O4 141.5(6) . . . . ? N3 Pt1 Ag1 O4 59.1(6) . . . . ? Ag2 Pt1 Ag1 O4 -64.5(4) 1_455 . . . ? N2 Pt1 Ag1 O3 -84.3(5) . . . . ? N1 Pt1 Ag1 O3 -172.9(6) . . . . ? N4 Pt1 Ag1 O3 91.6(6) . . . . ? N3 Pt1 Ag1 O3 9.1(6) . . . . ? Ag2 Pt1 Ag1 O3 -114.5(4) 1_455 . . . ? N2 Pt1 Ag1 Pt2 125.1(5) . . . . ? N1 Pt1 Ag1 Pt2 36.4(6) . . . . ? N4 Pt1 Ag1 Pt2 -59.1(6) . . . . ? N3 Pt1 Ag1 Pt2 -141.6(6) . . . . ? Ag2 Pt1 Ag1 Pt2 94.9(4) 1_455 . . . ? N6 Pt2 Ag2 O8 104.9(5) . . . 1_655 ? N5 Pt2 Ag2 O8 -166.2(5) . . . 1_655 ? N8 Pt2 Ag2 O8 -73.6(5) . . . 1_655 ? N7 Pt2 Ag2 O8 10.0(5) . . . 1_655 ? Ag1 Pt2 Ag2 O8 170.7(4) . . . 1_655 ? N6 Pt2 Ag2 O7 -7.9(5) . . . . ? N5 Pt2 Ag2 O7 81.0(5) . . . . ? N8 Pt2 Ag2 O7 173.7(5) . . . . ? N7 Pt2 Ag2 O7 -102.8(5) . . . . ? Ag1 Pt2 Ag2 O7 57.9(4) . . . . ? N6 Pt2 Ag2 O9 -117.3(6) . . . . ? N5 Pt2 Ag2 O9 -28.4(5) . . . . ? N8 Pt2 Ag2 O9 64.2(6) . . . . ? N7 Pt2 Ag2 O9 147.7(5) . . . . ? Ag1 Pt2 Ag2 O9 -51.5(4) . . . . ? N6 Pt2 Ag2 Pt1 37.6(5) . . . 1_655 ? N5 Pt2 Ag2 Pt1 126.5(4) . . . 1_655 ? N8 Pt2 Ag2 Pt1 -140.9(5) . . . 1_655 ? N7 Pt2 Ag2 Pt1 -57.4(5) . . . 1_655 ? Ag1 Pt2 Ag2 Pt1 103.4(3) . . . 1_655 ? O1 C1 C2 C5 -179(2) . . . . ? N1 C1 C2 C5 2(3) . . . . ? O1 C1 C2 C3 -54(3) . . . . ? N1 C1 C2 C3 127.1(19) . . . . ? O1 C1 C2 C4 58(2) . . . . ? N1 C1 C2 C4 -121(2) . . . . ? O8 C6 C7 C9 84(2) . . . . ? N2 C6 C7 C9 -96(2) . . . . ? O8 C6 C7 C8 -151.8(19) . . . . ? N2 C6 C7 C8 28(3) . . . . ? O8 C6 C7 C10 -40(2) . . . . ? N2 C6 C7 C10 139.9(19) . . . . ? N3 C11 C12 C13 177.5(19) . . . . ? N3 C11 C12 N4 -59(2) . . . . ? O2 C14 C15 C18 -178.7(16) . . . . ? N5 C14 C15 C18 1(2) . . . . ? O2 C14 C15 C16 -53(2) . . . . ? N5 C14 C15 C16 127.4(17) . . . . ? O2 C14 C15 C17 57(2) . . . . ? N5 C14 C15 C17 -122.8(17) . . . . ? N6 C19 C20 C23 134.0(17) . . . . ? O7 C19 C20 C23 -51(2) . . . . ? N6 C19 C20 C21 -110.1(19) . . . . ? O7 C19 C20 C21 65.4(19) . . . . ? N6 C19 C20 C22 12(2) . . . . ? O7 C19 C20 C22 -172.5(16) . . . . ? N7 C24 C25 C26 -178.7(17) . . . . ? N7 C24 C25 N8 -54(2) . . . . ? O1 C1 N1 Pt1 -3(3) . . . . ? C2 C1 N1 Pt1 175.5(14) . . . . ? N2 Pt1 N1 C1 -70.9(17) . . . . ? N4 Pt1 N1 C1 104.7(17) . . . . ? N3 Pt1 N1 C1 147(14) . . . . ? Ag1 Pt1 N1 C1 17.5(16) . . . . ? Ag2 Pt1 N1 C1 -153.2(16) 1_455 . . . ? O8 C6 N2 Pt1 -11(3) . . . . ? C7 C6 N2 Pt1 168.7(12) . . . . ? N1 Pt1 N2 C6 -81.1(17) . . . . ? N4 Pt1 N2 C6 149(5) . . . . ? N3 Pt1 N2 C6 97.3(17) . . . . ? Ag1 Pt1 N2 C6 -164.4(17) . . . . ? Ag2 Pt1 N2 C6 10.1(16) 1_455 . . . ? C12 C11 N3 Pt1 42.4(19) . . . . ? N2 Pt1 N3 C11 162.3(12) . . . . ? N1 Pt1 N3 C11 -56(15) . . . . ? N4 Pt1 N3 C11 -13.1(12) . . . . ? Ag1 Pt1 N3 C11 73.6(12) . . . . ? Ag2 Pt1 N3 C11 -115.5(12) 1_455 . . . ? C11 C12 N4 Pt1 46(2) . . . . ? C13 C12 N4 Pt1 165.1(18) . . . . ? N2 Pt1 N4 C12 -68(6) . . . . ? N1 Pt1 N4 C12 162.2(12) . . . . ? N3 Pt1 N4 C12 -16.0(12) . . . . ? Ag1 Pt1 N4 C12 -114.8(12) . . . . ? Ag2 Pt1 N4 C12 70.1(12) 1_455 . . . ? O2 C14 N5 Pt2 -4(2) . . . . ? C15 C14 N5 Pt2 175.7(11) . . . . ? N6 Pt2 N5 C14 -69.7(14) . . . . ? N8 Pt2 N5 C14 108.6(14) . . . . ? N7 Pt2 N5 C14 141(7) . . . . ? Ag1 Pt2 N5 C14 21.2(13) . . . . ? Ag2 Pt2 N5 C14 -155.0(14) . . . . ? O7 C19 N6 Pt2 -9(2) . . . . ? C20 C19 N6 Pt2 166.8(12) . . . . ? N5 Pt2 N6 C19 -75.7(15) . . . . ? N8 Pt2 N6 C19 150(12) . . . . ? N7 Pt2 N6 C19 102.1(15) . . . . ? Ag1 Pt2 N6 C19 -158.7(15) . . . . ? Ag2 Pt2 N6 C19 12.6(15) . . . . ? C25 C24 N7 Pt2 39.2(18) . . . . ? N6 Pt2 N7 C24 166.0(11) . . . . ? N5 Pt2 N7 C24 -45(8) . . . . ? N8 Pt2 N7 C24 -12.3(12) . . . . ? Ag1 Pt2 N7 C24 74.4(11) . . . . ? Ag2 Pt2 N7 C24 -108.8(11) . . . . ? C26 C25 N8 Pt2 163.7(16) . . . . ? C24 C25 N8 Pt2 41.9(18) . . . . ? N6 Pt2 N8 C25 -64(13) . . . . ? N5 Pt2 N8 C25 162.4(12) . . . . ? N7 Pt2 N8 C25 -15.3(12) . . . . ? Ag1 Pt2 N8 C25 -114.7(11) . . . . ? Ag2 Pt2 N8 C25 73.9(11) . . . . ? N1 C1 O1 Ag1 -19(2) . . . . ? C2 C1 O1 Ag1 162.2(14) . . . . ? O2 Ag1 O1 C1 -69.8(14) . . . . ? O4 Ag1 O1 C1 120.9(14) . . . . ? O3 Ag1 O1 C1 89.0(17) . . . . ? Pt2 Ag1 O1 C1 -150.3(13) . . . . ? Pt1 Ag1 O1 C1 22.7(13) . . . . ? N5 C14 O2 Ag1 -22(2) . . . . ? C15 C14 O2 Ag1 157.9(11) . . . . ? O1 Ag1 O2 C14 -64.0(11) . . . . ? O4 Ag1 O2 C14 100.8(12) . . . . ? O3 Ag1 O2 C14 124.5(11) . . . . ? Pt2 Ag1 O2 C14 27.1(11) . . . . ? Pt1 Ag1 O2 C14 -145.1(11) . . . . ? O4 Cl1 O3 Ag1 13.1(12) . . . . ? O6 Cl1 O3 Ag1 -110.2(10) . . . . ? O5 Cl1 O3 Ag1 126.7(12) . . . . ? O1 Ag1 O3 Cl1 31.3(16) . . . . ? O2 Ag1 O3 Cl1 -168.4(9) . . . . ? O4 Ag1 O3 Cl1 -8.7(8) . . . . ? Pt2 Ag1 O3 Cl1 -88.8(9) . . . . ? Pt1 Ag1 O3 Cl1 95.6(8) . . . . ? O3 Cl1 O4 Ag1 -13.3(12) . . . . ? O6 Cl1 O4 Ag1 108.9(11) . . . . ? O5 Cl1 O4 Ag1 -129.1(12) . . . . ? O1 Ag1 O4 Cl1 -155.0(8) . . . . ? O2 Ag1 O4 Cl1 40.0(13) . . . . ? O3 Ag1 O4 Cl1 8.7(8) . . . . ? Pt2 Ag1 O4 Cl1 110.9(9) . . . . ? Pt1 Ag1 O4 Cl1 -72.3(9) . . . . ? N6 C19 O7 Ag2 -4(2) . . . . ? C20 C19 O7 Ag2 -179.6(10) . . . . ? O8 Ag2 O7 C19 -81.7(12) 1_655 . . . ? O9 Ag2 O7 C19 105.4(12) . . . . ? Pt2 Ag2 O7 C19 9.1(11) . . . . ? Pt1 Ag2 O7 C19 -162.3(11) 1_655 . . . ? N2 C6 O8 Ag2 3(2) . . . 1_455 ? C7 C6 O8 Ag2 -176.6(11) . . . 1_455 ? O11 N9 O9 Ag2 -179.2(17) . . . . ? O10 N9 O9 Ag2 -7(2) . . . . ? O8 Ag2 O9 N9 43.0(16) 1_655 . . . ? O7 Ag2 O9 N9 -146.3(13) . . . . ? Pt2 Ag2 O9 N9 -64.7(13) . . . . ? Pt1 Ag2 O9 N9 120.4(13) 1_655 . . . ? _diffrn_measured_fraction_theta_max 0.801 _diffrn_reflns_theta_full 23.71 _diffrn_measured_fraction_theta_full 0.801 _refine_diff_density_max 1.798 _refine_diff_density_min -1.250 _refine_diff_density_rms 0.196