Additions and corrections
The influence of ligand conformation on the thermal spin transitions in iron(
Ruth Pritchard, Simon A. Barrett, Colin A. Kilner and Malcolm A. Halcrow
Dalton Trans., 2008, 3159–3168 (DOI: 10.1039/b801892h). Amendment published 29th April 2009.
The value of α for high-spin [Fe(L1)][Ni(dmit)2] in Table 4 was mis-calculated. The true value should be 106.9°, not 73.1° as given. The discussion of that compound in the Conclusion therefore needs to be modified; its saltrien ligand conformation does not remain rigid during spin-crossover.
The overall conclusions of the literature survey in the paper remain valid. There are large changes in the saltrien ligand conformation between the high-spin and low-spin forms of these complexes, which are difficult to accommodate in a solid lattice, and this contributes to the highly variable spin state behaviour shown by this class of compound in the solid state.
The Royal Society of Chemistry apologises for this error and any consequent inconvenience to authors and readers.