# Supplementary Material (ESI) for Dalton Transactions
# This journal is (c) The Royal Society of Chemistry 2010

data_global
_journal_name_full               'Dalton Trans.'

_journal_coden_Cambridge         0222

_publ_contact_author_name        'Berth-Jan Deelman'
_publ_contact_author_email       B.J.DEELMAN@UU.NL

_publ_section_title              
;
Dichlorostannylene complexes of group 10 metals, a unique
bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands.
;
loop_
_publ_author_name
'Berth-Jan Deelman'
'Yves Cabon'
'Robertus J. M. Klein Gebbink'
'Henk Kleijn'
'Maxime A. Siegler'
;
A.L.Spek
;

# Attachment '1BF4_corr.cif'

data_1.BF4
_database_code_depnum_ccdc_archive 'CCDC 746884'
#TrackingRef '1BF4_corr.cif'

#data_s4241a
#
# X-Ray Study: M.A.Siegler & A.L.Spek
# Utrecht University, Utrecht, NL.
# a.l.spek@uu.nl
#
# Note: 4% (whole molecule) disorder of the cation
# Only the heaviest atoms (Sn, Pt, Cl & P) are included
# in the disorder model.
#
_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C35 H31 Cl2 N2 P2 Pt Sn, B F4'
_chemical_formula_sum            'C35 H31 B Cl2 F4 N2 P2 Pt Sn'
_chemical_formula_weight         1013.05

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P c c n'
_symmetry_space_group_name_Hall  '-P 2ab 2ac'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'x+1/2, -y, -z+1/2'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'-x-1/2, y, z-1/2'
'x, -y-1/2, z-1/2'

_cell_length_a                   16.6611(3)
_cell_length_b                   20.3193(7)
_cell_length_c                   21.1892(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     7173.4(3)
_cell_formula_units_Z            8
_cell_measurement_temperature    110(2)
_cell_measurement_reflns_used    10663
_cell_measurement_theta_min      1.85
_cell_measurement_theta_max      27.49

_exptl_crystal_description       'thick plate'
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.06
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.876
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3904
_exptl_absorpt_coefficient_mu    4.880
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_correction_T_min  0.32
_exptl_absorpt_correction_T_max  0.78
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2008)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      110(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Nonius KappaCCD diffractometer'
_diffrn_measurement_method       '\f and \w scans'
_diffrn_reflns_number            61256
_diffrn_reflns_av_R_equivalents  0.0351
_diffrn_reflns_av_sigmaI/netI    0.0234
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_theta_min         1.58
_diffrn_reflns_theta_max         27.50
_reflns_number_total             8246
_reflns_number_gt                5980
_reflns_threshold_expression     I>2\s(I)

_computing_data_collection       'COLLECT (Nonius, 1999)'
_computing_cell_refinement       'PEAKREF (Schreurs, 2005)'
_computing_data_reduction        'EVAL15 (Xian et al., 2006)'
_computing_structure_solution    'DIRDIF08 (Beurskens et al., 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  'PLATON (Spek, 2003)'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0245P)^2^+21.8423P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   difmap
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         8246
_refine_ls_number_parameters     521
_refine_ls_number_restraints     161
_refine_ls_R_factor_all          0.0512
_refine_ls_R_factor_gt           0.0306
_refine_ls_wR_factor_ref         0.0700
_refine_ls_wR_factor_gt          0.0627
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_restrained_S_all      1.051
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.307425(14) 0.001073(13) 0.128277(11) 0.01523(6) Uani 0.9560(10) 1 d
PDU A 1
Sn1 Sn 0.15642(3) 0.00344(2) 0.127239(19) 0.01397(8) Uani 0.9560(10) 1 d PDU A
1
Cl1 Cl 0.06714(7) 0.06392(6) 0.19075(5) 0.0283(3) Uani 0.9560(10) 1 d PD A 1
Cl2 Cl 0.06778(7) -0.05557(6) 0.06157(5) 0.0272(2) Uani 0.9560(10) 1 d PD A 1
P1 P 0.30519(6) -0.07785(5) 0.20397(5) 0.0149(2) Uani 0.9560(10) 1 d PD A 1
P2 P 0.31174(6) 0.07876(5) 0.05133(5) 0.0155(2) Uani 0.9560(10) 1 d PD A 1
C1 C 0.4356(3) 0.0000(2) 0.1305(2) 0.0370(12) Uani 0.9560(10) 1 d PDU A 1
H1A H 0.4539 -0.0216 0.1693 0.055 Uiso 1 1 calc R A 1
H1B H 0.4558 0.0453 0.1294 0.055 Uiso 1 1 calc R A 1
H1C H 0.4560 -0.0242 0.0938 0.055 Uiso 1 1 calc R A 1
Pt1' Pt 0.1885(4) -0.0005(3) 0.1164(2) 0.0214(13) Uani 0.0440(10) 1 d PDU A 2
Sn1' Sn 0.3374(6) -0.0023(5) 0.1189(4) 0.0177(17) Uani 0.0440(10) 1 d PDU A 2
Cl1' Cl 0.4298(12) -0.0629(11) 0.0559(10) 0.027(5) Uani 0.0440(10) 1 d PDU A 2
Cl2' Cl 0.4316(12) 0.0536(11) 0.1837(9) 0.029(5) Uani 0.0440(10) 1 d PDU A 2
P1' P 0.1859(16) -0.0777(11) 0.1939(10) 0.022(6) Uani 0.0440(10) 1 d PDU A 2
P2' P 0.1931(15) 0.0775(11) 0.0395(10) 0.018(5) Uani 0.0440(10) 1 d PDU A 2
C1' C 0.0620(12) 0.009(3) 0.124(3) 0.021(10) Uani 0.0440(10) 1 d PDU A 2
C2 C 0.3351(2) -0.0468(2) 0.28065(19) 0.0226(9) Uani 1 1 d . . .
C3 C 0.3369(3) 0.0211(2) 0.2893(2) 0.0309(10) Uani 1 1 d . A .
H3 H 0.3277 0.0495 0.2545 0.037 Uiso 1 1 calc R . .
C4 C 0.3521(3) 0.0475(3) 0.3487(2) 0.0375(12) Uani 1 1 d . . .
H4 H 0.3535 0.0938 0.3545 0.045 Uiso 1 1 calc R A .
C5 C 0.3652(3) 0.0054(3) 0.3992(2) 0.0412(13) Uani 1 1 d . A .
H5 H 0.3755 0.0233 0.4398 0.049 Uiso 1 1 calc R . .
C6 C 0.3634(2) -0.0615(3) 0.3916(2) 0.0331(11) Uani 1 1 d . . .
H6 H 0.3718 -0.0896 0.4268 0.040 Uiso 1 1 calc R A .
C7 C 0.3493(2) -0.0882(2) 0.33247(19) 0.0282(10) Uani 1 1 d . A .
H7 H 0.3492 -0.1346 0.3270 0.034 Uiso 1 1 calc R . .
C8 C 0.3653(2) -0.14883(19) 0.18348(18) 0.0186(8) Uani 1 1 d . . .
C9 C 0.3384(3) -0.1908(2) 0.1359(2) 0.0295(10) Uani 1 1 d . A .
H9 H 0.2862 -0.1851 0.1187 0.035 Uiso 1 1 calc R . .
C10 C 0.3880(3) -0.2412(2) 0.1135(2) 0.0352(11) Uani 1 1 d . . .
H10 H 0.3691 -0.2705 0.0819 0.042 Uiso 1 1 calc R A .
C11 C 0.4645(3) -0.2484(2) 0.1376(2) 0.0315(11) Uani 1 1 d . A .
H11 H 0.4983 -0.2825 0.1223 0.038 Uiso 1 1 calc R . .
C12 C 0.4924(3) -0.2062(2) 0.1840(2) 0.0331(11) Uani 1 1 d . . .
H12 H 0.5454 -0.2111 0.2000 0.040 Uiso 1 1 calc R A .
C13 C 0.4425(3) -0.1563(2) 0.2073(2) 0.0271(10) Uani 1 1 d . A .
H13 H 0.4614 -0.1276 0.2394 0.033 Uiso 1 1 calc R . .
C14 C 0.2049(2) -0.1135(2) 0.22216(19) 0.0202(8) Uani 1 1 d . . .
C15 C 0.1975(3) -0.1662(2) 0.26339(19) 0.0255(9) Uani 1 1 d . A .
H15 H 0.2440 -0.1886 0.2780 0.031 Uiso 1 1 calc R B 2
C16 C 0.1220(3) -0.1860(2) 0.2831(2) 0.0286(10) Uani 1 1 d . . .
H16 H 0.1162 -0.2214 0.3120 0.034 Uiso 1 1 calc R A .
C17 C 0.0551(3) -0.1531(2) 0.2601(2) 0.0292(10) Uani 1 1 d . A .
H17 H 0.0027 -0.1653 0.2735 0.035 Uiso 1 1 calc R . .
C18 C 0.0657(3) -0.1028(2) 0.21753(19) 0.0255(9) Uani 1 1 d . . .
H18 H 0.0199 -0.0814 0.2005 0.031 Uiso 1 1 calc R A 2
C19 C 0.3741(2) 0.14913(19) 0.07071(18) 0.0207(9) Uani 1 1 d . . .
C20 C 0.4529(2) 0.1540(2) 0.0488(2) 0.0268(10) Uani 1 1 d . A .
H20 H 0.4729 0.1237 0.0185 0.032 Uiso 1 1 calc R . .
C21 C 0.5020(3) 0.2044(2) 0.0722(2) 0.0319(11) Uani 1 1 d . . .
H21 H 0.5560 0.2079 0.0581 0.038 Uiso 1 1 calc R A .
C22 C 0.4727(3) 0.2488(2) 0.1155(2) 0.0304(11) Uani 1 1 d . A .
H22 H 0.5062 0.2835 0.1300 0.037 Uiso 1 1 calc R . .
C23 C 0.3955(3) 0.2437(2) 0.1381(2) 0.0324(11) Uani 1 1 d . . .
H23 H 0.3762 0.2741 0.1686 0.039 Uiso 1 1 calc R A .
C24 C 0.3458(3) 0.1936(2) 0.1160(2) 0.0265(9) Uani 1 1 d . A .
H24 H 0.2926 0.1895 0.1317 0.032 Uiso 1 1 calc R . .
C25 C 0.3413(2) 0.0454(2) -0.02467(19) 0.0221(9) Uani 1 1 d . . .
C26 C 0.3588(2) 0.0854(2) -0.0767(2) 0.0276(10) Uani 1 1 d . A .
H26 H 0.3638 0.1317 -0.0716 0.033 Uiso 1 1 calc R . .
C27 C 0.3687(3) 0.0568(2) -0.1356(2) 0.0321(11) Uani 1 1 d . . .
H27 H 0.3797 0.0836 -0.1713 0.039 Uiso 1 1 calc R A .
C28 C 0.3628(3) -0.0100(2) -0.1426(2) 0.0362(12) Uani 1 1 d . A .
H28 H 0.3696 -0.0289 -0.1832 0.043 Uiso 1 1 calc R . .
C29 C 0.3474(3) -0.0504(2) -0.0917(2) 0.0344(11) Uani 1 1 d . . .
H29 H 0.3445 -0.0968 -0.0971 0.041 Uiso 1 1 calc R A .
C30 C 0.3359(2) -0.0225(2) -0.0326(2) 0.0270(9) Uani 1 1 d . A .
H30 H 0.3245 -0.0498 0.0027 0.032 Uiso 1 1 calc R . .
C31 C 0.2139(2) 0.1174(2) 0.03114(18) 0.0183(8) Uani 1 1 d . . .
C32 C 0.2099(3) 0.1686(2) -0.0120(2) 0.0258(9) Uani 1 1 d . A .
H32 H 0.2578 0.1874 -0.0283 0.031 Uiso 1 1 calc R C 2
C33 C 0.1352(3) 0.1924(2) -0.0314(2) 0.0264(10) Uani 1 1 d . . .
H33 H 0.1315 0.2271 -0.0613 0.032 Uiso 1 1 calc R A .
C34 C 0.0668(3) 0.1643(2) -0.00623(19) 0.0245(9) Uani 1 1 d . A .
H34 H 0.0151 0.1794 -0.0186 0.029 Uiso 1 1 calc R . .
C35 C 0.0747(2) 0.1144(2) 0.03689(18) 0.0227(9) Uani 1 1 d . . .
H35 H 0.0276 0.0957 0.0546 0.027 Uiso 1 1 calc R A 2
N1 N 0.1394(2) -0.08315(17) 0.19934(15) 0.0192(7) Uani 1 1 d . A .
N2 N 0.1464(2) 0.09078(16) 0.05513(15) 0.0176(7) Uani 1 1 d . A .
B1 B 0.7500 0.2500 0.0615(4) 0.0351(19) Uani 1 2 d S . .
F1 F 0.7228(3) 0.1996(2) 0.0261(2) 0.0992(15) Uani 1 1 d . . .
F2 F 0.6893(3) 0.2709(2) 0.0991(2) 0.1081(17) Uani 1 1 d . . .
B2 B 0.2580(10) 0.2454(8) 0.3077(5) 0.083(3) Uani 0.50 1 d PDU . .
F3 F 0.2894(7) 0.2792(7) 0.3585(4) 0.102(3) Uani 0.50 1 d PDU . .
F4 F 0.2604(6) 0.2862(4) 0.2595(3) 0.104(3) Uani 0.50 1 d PDU . .
F5 F 0.3199(6) 0.2013(4) 0.3014(4) 0.104(3) Uani 0.50 1 d PDU . .
F6 F 0.1950(7) 0.2160(8) 0.3347(6) 0.120(4) Uani 0.50 1 d PDU . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Pt1 0.00916(11) 0.01659(8) 0.01994(10) 0.00286(7) -0.00024(8) -0.00069(10)
Sn1 0.00958(16) 0.02012(16) 0.01220(17) -0.00033(13) 0.00023(14) -0.00024(18)
Cl1 0.0273(6) 0.0368(6) 0.0207(5) -0.0015(5) 0.0054(4) 0.0101(5)
Cl2 0.0256(6) 0.0359(6) 0.0200(5) -0.0021(5) -0.0050(4) -0.0080(5)
P1 0.0136(5) 0.0160(5) 0.0150(5) -0.0003(4) -0.0014(4) -0.0002(4)
P2 0.0130(5) 0.0162(5) 0.0171(5) 0.0004(4) 0.0007(4) -0.0003(4)
C1 0.013(2) 0.043(3) 0.056(3) 0.025(3) -0.001(2) 0.000(2)
Pt1' 0.033(3) 0.0163(19) 0.015(2) 0.0050(17) 0.000(2) -0.005(2)
Sn1' 0.017(3) 0.022(3) 0.015(3) 0.004(3) -0.008(3) -0.009(3)
Cl1' 0.026(9) 0.032(9) 0.025(8) -0.011(7) 0.005(7) 0.000(7)
Cl2' 0.030(8) 0.037(8) 0.020(8) 0.000(7) -0.004(7) -0.008(7)
P1' 0.020(9) 0.023(9) 0.021(9) 0.006(8) -0.006(8) 0.000(8)
P2' 0.016(9) 0.021(9) 0.018(8) 0.003(7) -0.006(7) -0.008(8)
C1' 0.023(13) 0.020(13) 0.019(13) 0.000(9) 0.002(9) -0.010(9)
C2 0.016(2) 0.031(2) 0.021(2) -0.0056(17) 0.0014(16) -0.0018(17)
C3 0.022(2) 0.034(2) 0.037(3) -0.008(2) -0.001(2) -0.0039(19)
C4 0.025(3) 0.047(3) 0.041(3) -0.020(2) 0.003(2) -0.005(2)
C5 0.022(2) 0.068(4) 0.033(3) -0.032(3) 0.000(2) -0.007(2)
C6 0.016(2) 0.063(3) 0.020(2) -0.002(2) -0.0018(18) -0.001(2)
C7 0.022(2) 0.041(3) 0.022(2) -0.0029(19) -0.0003(18) 0.0024(19)
C8 0.020(2) 0.021(2) 0.0142(19) 0.0020(16) 0.0038(16) 0.0023(16)
C9 0.029(2) 0.032(2) 0.027(2) -0.0050(19) -0.0015(19) 0.000(2)
C10 0.045(3) 0.035(3) 0.025(2) -0.008(2) 0.004(2) -0.001(2)
C11 0.042(3) 0.030(2) 0.023(2) -0.002(2) 0.014(2) 0.009(2)
C12 0.024(2) 0.036(3) 0.040(3) 0.009(2) 0.008(2) 0.008(2)
C13 0.025(2) 0.029(2) 0.027(2) 0.0013(19) 0.0023(19) 0.0014(18)
C14 0.021(2) 0.022(2) 0.017(2) -0.0042(17) 0.0006(16) -0.0012(17)
C15 0.026(2) 0.027(2) 0.023(2) 0.0029(18) -0.0014(18) -0.0036(18)
C16 0.032(3) 0.029(2) 0.025(2) 0.0037(19) 0.0070(19) -0.0079(19)
C17 0.025(2) 0.037(3) 0.026(2) -0.0003(19) 0.0068(19) -0.0087(19)
C18 0.018(2) 0.034(2) 0.024(2) -0.0009(19) 0.0021(17) -0.0029(18)
C19 0.023(2) 0.020(2) 0.019(2) 0.0050(17) -0.0055(16) -0.0034(16)
C20 0.022(2) 0.027(2) 0.031(2) 0.0087(19) -0.0005(18) -0.0014(18)
C21 0.025(2) 0.030(2) 0.041(3) 0.015(2) -0.012(2) -0.0080(19)
C22 0.040(3) 0.019(2) 0.032(2) 0.0050(19) -0.020(2) -0.0056(18)
C23 0.043(3) 0.026(2) 0.028(2) -0.0032(19) -0.014(2) -0.001(2)
C24 0.028(2) 0.026(2) 0.026(2) 0.0000(18) -0.0060(19) 0.0019(19)
C25 0.0126(19) 0.029(2) 0.025(2) -0.0031(18) -0.0008(17) 0.0008(17)
C26 0.023(2) 0.032(2) 0.028(2) -0.0021(19) -0.0006(18) 0.0008(18)
C27 0.024(2) 0.046(3) 0.025(2) -0.003(2) 0.0016(19) 0.000(2)
C28 0.017(2) 0.057(3) 0.034(3) -0.022(2) -0.0017(19) 0.002(2)
C29 0.022(2) 0.035(3) 0.046(3) -0.019(2) -0.004(2) 0.002(2)
C30 0.016(2) 0.030(2) 0.035(2) -0.0060(19) 0.0018(18) -0.0015(18)
C31 0.017(2) 0.018(2) 0.020(2) -0.0050(17) 0.0015(16) 0.0003(16)
C32 0.025(2) 0.023(2) 0.029(2) 0.0015(18) -0.0002(18) -0.0007(17)
C33 0.033(2) 0.022(2) 0.025(2) 0.0019(18) -0.0039(19) 0.0017(18)
C34 0.022(2) 0.029(2) 0.022(2) -0.0022(18) -0.0060(17) 0.0061(18)
C35 0.019(2) 0.031(2) 0.018(2) -0.0034(18) -0.0016(16) -0.0003(17)
N1 0.0182(19) 0.0219(19) 0.0175(18) -0.0003(14) 0.0002(15) -0.0027(15)
N2 0.0183(18) 0.0220(18) 0.0124(16) -0.0024(14) -0.0019(14) 0.0024(14)
B1 0.037(5) 0.043(5) 0.026(4) 0.000 0.000 -0.018(3)
F1 0.110(4) 0.085(3) 0.102(3) -0.045(3) -0.041(3) -0.005(3)
F2 0.101(4) 0.102(3) 0.121(4) -0.042(3) 0.070(3) -0.037(3)
B2 0.089(5) 0.095(5) 0.064(5) 0.011(5) 0.010(5) -0.017(4)
F3 0.121(7) 0.133(6) 0.050(5) -0.005(5) -0.022(5) 0.008(5)
F4 0.126(6) 0.135(6) 0.050(4) 0.040(4) 0.011(4) 0.024(5)
F5 0.108(5) 0.098(5) 0.106(5) 0.004(5) 0.045(5) 0.012(5)
F6 0.101(6) 0.140(7) 0.119(7) 0.013(6) 0.001(6) -0.042(5)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 2.137(4) . ?
Pt1 P1 2.2684(10) . ?
Pt1 P2 2.2705(10) . ?
Pt1 Sn1 2.5165(4) . ?
Sn1 N1 2.347(3) . ?
Sn1 N2 2.348(3) . ?
Sn1 Cl1 2.3524(11) . ?
Sn1 Cl2 2.3569(11) . ?
P1 C8 1.809(4) . ?
P1 C2 1.813(4) . ?
P1 C14 1.861(4) . ?
P2 C25 1.815(4) . ?
P2 C19 1.815(4) . ?
P2 C31 1.859(4) . ?
C1 H1A 0.9800 . ?
C1 H1B 0.9800 . ?
C1 H1C 0.9800 . ?
Pt1' C1' 2.123(18) . ?
Pt1' P1' 2.271(15) . ?
Pt1' P2' 2.275(15) . ?
Pt1' N2 2.370(7) . ?
Pt1' Sn1' 2.481(9) . ?
Pt1' N1 2.565(7) . ?
Sn1' Cl2' 2.374(14) . ?
Sn1' Cl1' 2.381(14) . ?
P1' N1 0.79(2) . ?
P1' C14 0.994(17) . ?
P1' C18 2.13(3) . ?
P1' C15 2.332(16) . ?
P2' N2 0.89(3) . ?
P2' C31 0.900(19) . ?
P2' C35 2.11(2) . ?
P2' C32 2.166(17) . ?
C2 C3 1.392(6) . ?
C2 C7 1.402(6) . ?
C3 C4 1.390(6) . ?
C3 H3 0.9500 . ?
C4 C5 1.389(7) . ?
C4 H4 0.9500 . ?
C5 C6 1.369(7) . ?
C5 H5 0.9500 . ?
C6 C7 1.384(6) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C8 C13 1.390(6) . ?
C8 C9 1.394(6) . ?
C9 C10 1.399(6) . ?
C9 H9 0.9500 . ?
C10 C11 1.381(7) . ?
C10 H10 0.9500 . ?
C11 C12 1.383(7) . ?
C11 H11 0.9500 . ?
C12 C13 1.401(6) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 N1 1.345(5) . ?
C14 C15 1.387(6) . ?
C15 C16 1.385(6) . ?
C15 H15 0.9500 . ?
C16 C17 1.389(6) . ?
C16 H16 0.9500 . ?
C17 C18 1.374(6) . ?
C17 H17 0.9500 . ?
C18 N1 1.348(5) . ?
C18 H18 0.9500 . ?
C19 C20 1.397(6) . ?
C19 C24 1.400(6) . ?
C20 C21 1.401(6) . ?
C20 H20 0.9500 . ?
C21 C22 1.378(6) . ?
C21 H21 0.9500 . ?
C22 C23 1.377(7) . ?
C22 H22 0.9500 . ?
C23 C24 1.393(6) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C30 1.393(6) . ?
C25 C26 1.400(6) . ?
C26 C27 1.389(6) . ?
C26 H26 0.9500 . ?
C27 C28 1.368(6) . ?
C27 H27 0.9500 . ?
C28 C29 1.379(7) . ?
C28 H28 0.9500 . ?
C29 C30 1.389(6) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 N2 1.348(5) . ?
C31 C32 1.385(6) . ?
C32 C33 1.398(6) . ?
C32 H32 0.9500 . ?
C33 C34 1.381(6) . ?
C33 H33 0.9500 . ?
C34 C35 1.372(6) . ?
C34 H34 0.9500 . ?
C35 N2 1.344(5) . ?
C35 H35 0.9500 . ?
B1 F1 1.346(5) 2_655 ?
B1 F1 1.346(5) . ?
B1 F2 1.357(6) 2_655 ?
B1 F2 1.357(6) . ?
B2 B2 0.32(3) 2 ?
B2 F4 1.244(15) 2 ?
B2 F6 1.25(3) 2 ?
B2 F4 1.316(11) . ?
B2 F6 1.335(12) . ?
B2 F5 1.373(13) . ?
B2 F3 1.379(13) . ?
B2 F3 1.424(17) 2 ?
B2 F5 1.70(2) 2 ?
F3 F6 0.576(19) 2 ?
F3 B2 1.424(17) 2 ?
F3 F3 1.77(3) 2 ?
F4 B2 1.244(15) 2 ?
F4 F4 1.510(18) 2 ?
F4 F5 1.626(13) 2 ?
F4 F6 1.758(15) 2 ?
F5 F4 1.626(13) 2 ?
F5 B2 1.70(2) 2 ?
F6 F3 0.576(19) 2 ?
F6 B2 1.25(3) 2 ?
F6 F4 1.758(15) 2 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 P1 89.63(12) . . ?
C1 Pt1 P2 89.50(12) . . ?
P1 Pt1 P2 178.73(4) . . ?
C1 Pt1 Sn1 179.08(16) . . ?
P1 Pt1 Sn1 90.19(3) . . ?
P2 Pt1 Sn1 90.69(3) . . ?
N1 Sn1 N2 168.99(12) . . ?
N1 Sn1 Cl1 86.72(9) . . ?
N2 Sn1 Cl1 86.14(9) . . ?
N1 Sn1 Cl2 85.82(9) . . ?
N2 Sn1 Cl2 87.48(8) . . ?
Cl1 Sn1 Cl2 101.96(4) . . ?
N1 Sn1 Pt1 95.79(9) . . ?
N2 Sn1 Pt1 95.22(9) . . ?
Cl1 Sn1 Pt1 129.58(3) . . ?
Cl2 Sn1 Pt1 128.45(3) . . ?
C8 P1 C2 109.87(19) . . ?
C8 P1 C14 103.67(18) . . ?
C2 P1 C14 101.34(18) . . ?
C8 P1 Pt1 112.64(13) . . ?
C2 P1 Pt1 112.54(14) . . ?
C14 P1 Pt1 115.88(14) . . ?
C25 P2 C19 109.85(19) . . ?
C25 P2 C31 101.01(18) . . ?
C19 P2 C31 102.76(18) . . ?
C25 P2 Pt1 112.74(14) . . ?
C19 P2 Pt1 113.79(13) . . ?
C31 P2 Pt1 115.56(14) . . ?
C1' Pt1' P1' 89.4(11) . . ?
C1' Pt1' P2' 91.4(11) . . ?
P1' Pt1' P2' 179.0(9) . . ?
C1' Pt1' N2 71.1(12) . . ?
P1' Pt1' N2 158.5(7) . . ?
P2' Pt1' N2 21.9(6) . . ?
C1' Pt1' Sn1' 173(2) . . ?
P1' Pt1' Sn1' 89.6(7) . . ?
P2' Pt1' Sn1' 89.6(7) . . ?
N2 Pt1' Sn1' 108.6(3) . . ?
C1' Pt1' N1 72.0(11) . . ?
P1' Pt1' N1 17.5(6) . . ?
P2' Pt1' N1 163.3(7) . . ?
N2 Pt1' N1 142.5(3) . . ?
Sn1' Pt1' N1 107.1(3) . . ?
Cl2' Sn1' Cl1' 98.3(8) . . ?
Cl2' Sn1' Pt1' 131.8(7) . . ?
Cl1' Sn1' Pt1' 129.9(7) . . ?
N1 P1' C14 97.0(18) . . ?
C14 P1' C18 89.0(14) . . ?
N1 P1' Pt1' 102.8(16) . . ?
C14 P1' Pt1' 159(2) . . ?
C18 P1' Pt1' 110.7(10) . . ?
N1 P1' C15 83.2(12) . . ?
C18 P1' C15 75.2(6) . . ?
Pt1' P1' C15 170.8(14) . . ?
N2 P2' C31 98(2) . . ?
C31 P2' C35 92.0(17) . . ?
N2 P2' C32 92.4(14) . . ?
C35 P2' C32 78.7(7) . . ?
N2 P2' Pt1' 85.1(12) . . ?
C31 P2' Pt1' 141.4(18) . . ?
C35 P2' Pt1' 103.6(9) . . ?
C32 P2' Pt1' 163.8(12) . . ?
C3 C2 C7 119.1(4) . . ?
C3 C2 P1 117.9(3) . . ?
C7 C2 P1 122.7(3) . . ?
C4 C3 C2 120.4(5) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C5 C4 C3 119.2(5) . . ?
C5 C4 H4 120.4 . . ?
C3 C4 H4 120.4 . . ?
C6 C5 C4 121.1(4) . . ?
C6 C5 H5 119.4 . . ?
C4 C5 H5 119.4 . . ?
C5 C6 C7 120.0(5) . . ?
C5 C6 H6 120.0 . . ?
C7 C6 H6 120.0 . . ?
C6 C7 C2 120.2(4) . . ?
C6 C7 H7 119.9 . . ?
C2 C7 H7 119.9 . . ?
C13 C8 C9 119.6(4) . . ?
C13 C8 P1 120.8(3) . . ?
C9 C8 P1 118.9(3) . . ?
C8 C9 C10 120.2(4) . . ?
C8 C9 H9 119.9 . . ?
C10 C9 H9 119.9 . . ?
C11 C10 C9 119.8(4) . . ?
C11 C10 H10 120.1 . . ?
C9 C10 H10 120.1 . . ?
C10 C11 C12 120.5(4) . . ?
C10 C11 H11 119.7 . . ?
C12 C11 H11 119.7 . . ?
C11 C12 C13 119.9(4) . . ?
C11 C12 H12 120.0 . . ?
C13 C12 H12 120.0 . . ?
C8 C13 C12 120.0(4) . . ?
C8 C13 H13 120.0 . . ?
C12 C13 H13 120.0 . . ?
P1' C14 C15 156.3(15) . . ?
N1 C14 C15 120.5(4) . . ?
P1' C14 P1 82.9(15) . . ?
N1 C14 P1 118.4(3) . . ?
C15 C14 P1 120.7(3) . . ?
C16 C15 C14 119.7(4) . . ?
C16 C15 P1' 109.8(7) . . ?
C16 C15 H15 120.2 . . ?
C14 C15 H15 120.2 . . ?
P1' C15 H15 130.0 . . ?
C15 C16 C17 119.0(4) . . ?
C15 C16 H16 120.5 . . ?
C17 C16 H16 120.5 . . ?
C18 C17 C16 119.0(4) . . ?
C18 C17 H17 120.5 . . ?
C16 C17 H17 120.5 . . ?
N1 C18 C17 121.7(4) . . ?
C17 C18 P1' 117.0(6) . . ?
N1 C18 H18 119.2 . . ?
C17 C18 H18 119.2 . . ?
P1' C18 H18 123.8 . . ?
C20 C19 C24 119.9(4) . . ?
C20 C19 P2 121.3(3) . . ?
C24 C19 P2 118.1(3) . . ?
C19 C20 C21 118.9(4) . . ?
C19 C20 H20 120.6 . . ?
C21 C20 H20 120.6 . . ?
C22 C21 C20 120.6(4) . . ?
C22 C21 H21 119.7 . . ?
C20 C21 H21 119.7 . . ?
C23 C22 C21 120.9(4) . . ?
C23 C22 H22 119.6 . . ?
C21 C22 H22 119.6 . . ?
C22 C23 C24 119.6(4) . . ?
C22 C23 H23 120.2 . . ?
C24 C23 H23 120.2 . . ?
C23 C24 C19 120.2(4) . . ?
C23 C24 H24 119.9 . . ?
C19 C24 H24 119.9 . . ?
C30 C25 C26 119.6(4) . . ?
C30 C25 P2 117.3(3) . . ?
C26 C25 P2 122.6(3) . . ?
C27 C26 C25 119.3(4) . . ?
C27 C26 H26 120.3 . . ?
C25 C26 H26 120.3 . . ?
C28 C27 C26 120.3(5) . . ?
C28 C27 H27 119.9 . . ?
C26 C27 H27 119.9 . . ?
C27 C28 C29 121.3(4) . . ?
C27 C28 H28 119.3 . . ?
C29 C28 H28 119.3 . . ?
C28 C29 C30 119.2(4) . . ?
C28 C29 H29 120.4 . . ?
C30 C29 H29 120.4 . . ?
C29 C30 C25 120.3(4) . . ?
C29 C30 H30 119.9 . . ?
C25 C30 H30 119.9 . . ?
P2' C31 C32 141.9(13) . . ?
N2 C31 C32 120.6(4) . . ?
P2' C31 P2 84.9(15) . . ?
N2 C31 P2 118.3(3) . . ?
C32 C31 P2 120.8(3) . . ?
C31 C32 C33 119.8(4) . . ?
C33 C32 P2' 109.2(7) . . ?
C31 C32 H32 120.1 . . ?
C33 C32 H32 120.1 . . ?
P2' C32 H32 129.5 . . ?
C34 C33 C32 118.6(4) . . ?
C34 C33 H33 120.7 . . ?
C32 C33 H33 120.7 . . ?
C35 C34 C33 118.9(4) . . ?
C35 C34 H34 120.6 . . ?
C33 C34 H34 120.6 . . ?
N2 C35 C34 122.8(4) . . ?
C34 C35 P2' 111.7(5) . . ?
N2 C35 H35 118.6 . . ?
C34 C35 H35 118.6 . . ?
P2' C35 H35 128.4 . . ?
P1' N1 C14 47.2(12) . . ?
P1' N1 C18 167.3(13) . . ?
C14 N1 C18 120.1(4) . . ?
P1' N1 Sn1 71.4(13) . . ?
C14 N1 Sn1 118.7(3) . . ?
C18 N1 Sn1 121.2(3) . . ?
P1' N1 Pt1' 59.7(12) . . ?
C14 N1 Pt1' 106.7(3) . . ?
C18 N1 Pt1' 132.9(3) . . ?
P2' N2 C35 141.2(12) . . ?
C35 N2 C31 119.3(3) . . ?
P2' N2 Sn1 87.2(10) . . ?
C35 N2 Sn1 121.3(3) . . ?
C31 N2 Sn1 119.3(3) . . ?
P2' N2 Pt1' 73.0(10) . . ?
C35 N2 Pt1' 134.4(3) . . ?
C31 N2 Pt1' 105.9(3) . . ?
F1 B1 F1 112.5(7) 2_655 . ?
F1 B1 F2 108.3(3) 2_655 2_655 ?
F1 B1 F2 109.9(3) . 2_655 ?
F1 B1 F2 109.9(3) 2_655 . ?
F1 B1 F2 108.3(3) . . ?
F2 B1 F2 108.0(7) 2_655 . ?
B2 B2 F4 95(3) 2 2 ?
B2 B2 F6 99(5) 2 2 ?
F4 B2 F6 148.7(14) 2 2 ?
B2 B2 F4 70(3) 2 . ?
F4 B2 F4 72.2(10) 2 . ?
F6 B2 F4 86.6(12) 2 . ?
B2 B2 F6 67(5) 2 . ?
F4 B2 F6 85.8(12) 2 . ?
F6 B2 F6 125.4(14) 2 . ?
F4 B2 F6 129.6(15) . . ?
B2 B2 F5 172(5) 2 . ?
F4 B2 F5 76.7(10) 2 . ?
F6 B2 F5 89.0(13) 2 . ?
F4 B2 F5 108.2(10) . . ?
F6 B2 F5 109.9(11) . . ?
B2 B2 F3 91(4) 2 . ?
F4 B2 F3 172.0(14) 2 . ?
F4 B2 F3 106.3(11) . . ?
F6 B2 F3 100.8(9) . . ?
F5 B2 F3 96.6(11) . . ?
B2 B2 F3 75(4) 2 2 ?
F4 B2 F3 107.6(14) 2 2 ?
F6 B2 F3 102.8(11) 2 2 ?
F4 B2 F3 145.5(15) . 2 ?
F5 B2 F3 105.1(11) . 2 ?
F3 B2 F3 78.2(12) . 2 ?
F4 B2 F5 94.4(10) 2 2 ?
F6 B2 F5 96.6(13) 2 2 ?
F4 B2 F5 63.9(8) . 2 ?
F6 B2 F5 73.6(11) . 2 ?
F5 B2 F5 169.9(11) . 2 ?
F3 B2 F5 91.9(10) . 2 ?
F3 B2 F5 81.9(10) 2 2 ?
F6 F3 B2 65(2) 2 . ?
F6 F3 B2 69.4(15) 2 2 ?
F6 F3 F3 117(2) 2 2 ?
B2 F3 F3 52.1(6) . 2 ?
B2 F3 F3 49.8(9) 2 2 ?
B2 F4 F4 56.1(8) 2 2 ?
B2 F4 F4 51.7(8) . 2 ?
B2 F4 F5 55.2(7) 2 2 ?
B2 F4 F5 69.5(9) . 2 ?
F4 F4 F5 87.9(8) 2 2 ?
B2 F4 F6 49.3(7) 2 2 ?
B2 F4 F6 45.1(10) . 2 ?
F4 F4 F6 94.2(6) 2 2 ?
F5 F4 F6 81.8(6) 2 2 ?
B2 F5 F4 48.1(7) . 2 ?
F4 F5 B2 46.6(5) 2 2 ?
F3 F6 B2 91(2) 2 2 ?
F3 F6 B2 86.8(19) 2 . ?
F3 F6 F4 127(2) 2 2 ?
B2 F6 F4 48.3(6) 2 2 ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 Pt1 Sn1 N1 -4.07(9) . . . . ?
P2 Pt1 Sn1 N1 175.01(8) . . . . ?
P1 Pt1 Sn1 N2 175.75(8) . . . . ?
P2 Pt1 Sn1 N2 -5.16(8) . . . . ?
P1 Pt1 Sn1 Cl1 86.45(5) . . . . ?
P2 Pt1 Sn1 Cl1 -94.47(5) . . . . ?
P1 Pt1 Sn1 Cl2 -93.32(5) . . . . ?
P2 Pt1 Sn1 Cl2 85.76(5) . . . . ?
C1 Pt1 P1 C8 -53.1(2) . . . . ?
Sn1 Pt1 P1 C8 127.80(14) . . . . ?
C1 Pt1 P1 C2 71.8(2) . . . . ?
Sn1 Pt1 P1 C2 -107.32(15) . . . . ?
C1 Pt1 P1 C14 -172.2(2) . . . . ?
Sn1 Pt1 P1 C14 8.66(14) . . . . ?
C1 Pt1 P2 C25 74.2(2) . . . . ?
Sn1 Pt1 P2 C25 -106.74(14) . . . . ?
C1 Pt1 P2 C19 -51.8(2) . . . . ?
Sn1 Pt1 P2 C19 127.31(15) . . . . ?
C1 Pt1 P2 C31 -170.4(2) . . . . ?
Sn1 Pt1 P2 C31 8.73(14) . . . . ?
P1' Pt1' Sn1' Cl2' -84.6(12) . . . . ?
P2' Pt1' Sn1' Cl2' 94.9(12) . . . . ?
N2 Pt1' Sn1' Cl2' 83.9(10) . . . . ?
N1 Pt1' Sn1' Cl2' -84.5(10) . . . . ?
P1' Pt1' Sn1' Cl1' 94.9(12) . . . . ?
P2' Pt1' Sn1' Cl1' -85.7(12) . . . . ?
N2 Pt1' Sn1' Cl1' -96.7(10) . . . . ?
N1 Pt1' Sn1' Cl1' 95.0(9) . . . . ?
C1' Pt1' P1' N1 7(3) . . . . ?
N2 Pt1' P1' N1 31(4) . . . . ?
Sn1' Pt1' P1' N1 180(2) . . . . ?
C1' Pt1' P1' C14 168(7) . . . . ?
N2 Pt1' P1' C14 -168(5) . . . . ?
Sn1' Pt1' P1' C14 -19(6) . . . . ?
N1 Pt1' P1' C14 161(8) . . . . ?
C1' Pt1' P1' C18 7(2) . . . . ?
N2 Pt1' P1' C18 32(3) . . . . ?
Sn1' Pt1' P1' C18 -179.6(11) . . . . ?
N1 Pt1' P1' C18 0.6(12) . . . . ?
C1' Pt1' P2' N2 22(3) . . . . ?
Sn1' Pt1' P2' N2 -151.0(16) . . . . ?
N1 Pt1' P2' N2 27(4) . . . . ?
C1' Pt1' P2' C31 119(4) . . . . ?
N2 Pt1' P2' C31 96(4) . . . . ?
Sn1' Pt1' P2' C31 -55(4) . . . . ?
N1 Pt1' P2' C31 123(3) . . . . ?
C1' Pt1' P2' C35 7(2) . . . . ?
N2 Pt1' P2' C35 -14.6(8) . . . . ?
Sn1' Pt1' P2' C35 -165.6(9) . . . . ?
N1 Pt1' P2' C35 12(3) . . . . ?
C1' Pt1' P2' C32 104(5) . . . . ?
N2 Pt1' P2' C32 82(5) . . . . ?
Sn1' Pt1' P2' C32 -69(5) . . . . ?
N1 Pt1' P2' C32 109(4) . . . . ?
C8 P1 C2 C3 141.6(3) . . . . ?
C14 P1 C2 C3 -109.2(4) . . . . ?
Pt1 P1 C2 C3 15.2(4) . . . . ?
C8 P1 C2 C7 -44.3(4) . . . . ?
C14 P1 C2 C7 64.9(4) . . . . ?
Pt1 P1 C2 C7 -170.7(3) . . . . ?
C7 C2 C3 C4 -0.4(6) . . . . ?
P1 C2 C3 C4 174.0(3) . . . . ?
C2 C3 C4 C5 -0.2(7) . . . . ?
C3 C4 C5 C6 0.0(7) . . . . ?
C4 C5 C6 C7 0.8(7) . . . . ?
C5 C6 C7 C2 -1.4(6) . . . . ?
C3 C2 C7 C6 1.2(6) . . . . ?
P1 C2 C7 C6 -172.9(3) . . . . ?
C2 P1 C8 C13 -27.5(4) . . . . ?
C14 P1 C8 C13 -135.1(3) . . . . ?
Pt1 P1 C8 C13 98.8(3) . . . . ?
C2 P1 C8 C9 162.4(3) . . . . ?
C14 P1 C8 C9 54.7(4) . . . . ?
Pt1 P1 C8 C9 -71.3(3) . . . . ?
C13 C8 C9 C10 1.7(6) . . . . ?
P1 C8 C9 C10 172.0(3) . . . . ?
C8 C9 C10 C11 -1.5(7) . . . . ?
C9 C10 C11 C12 0.3(7) . . . . ?
C10 C11 C12 C13 0.7(7) . . . . ?
C9 C8 C13 C12 -0.6(6) . . . . ?
P1 C8 C13 C12 -170.7(3) . . . . ?
C11 C12 C13 C8 -0.6(7) . . . . ?
C18 P1' C14 N1 0.3(15) . . . . ?
Pt1' P1' C14 N1 -162(8) . . . . ?
C15 P1' C14 N1 -2(6) . . . . ?
N1 P1' C14 C15 2(6) . . . . ?
C18 P1' C14 C15 2(4) . . . . ?
Pt1' P1' C14 C15 -160(3) . . . . ?
N1 P1' C14 P1 -174(2) . . . . ?
C18 P1' C14 P1 -173.3(9) . . . . ?
Pt1' P1' C14 P1 25(6) . . . . ?
C15 P1' C14 P1 -176(3) . . . . ?
C8 P1 C14 P1' -132.0(16) . . . . ?
C2 P1 C14 P1' 114.1(16) . . . . ?
Pt1 P1 C14 P1' -8.0(16) . . . . ?
C8 P1 C14 N1 -136.2(3) . . . . ?
C2 P1 C14 N1 109.9(3) . . . . ?
Pt1 P1 C14 N1 -12.3(4) . . . . ?
C8 P1 C14 C15 50.1(4) . . . . ?
C2 P1 C14 C15 -63.8(4) . . . . ?
Pt1 P1 C14 C15 174.1(3) . . . . ?
P1' C14 C15 C16 -4(4) . . . . ?
N1 C14 C15 C16 -2.6(6) . . . . ?
P1 C14 C15 C16 170.9(3) . . . . ?
N1 C14 C15 P1' 1(4) . . . . ?
P1 C14 C15 P1' 175(4) . . . . ?
N1 P1' C15 C16 -2(2) . . . . ?
C14 P1' C15 C16 176(4) . . . . ?
C18 P1' C15 C16 -1.3(9) . . . . ?
N1 P1' C15 C14 -178(6) . . . . ?
C18 P1' C15 C14 -178(4) . . . . ?
C14 C15 C16 C17 1.2(6) . . . . ?
P1' C15 C16 C17 0.5(9) . . . . ?
C15 C16 C17 C18 1.2(6) . . . . ?
C16 C17 C18 N1 -2.3(6) . . . . ?
C16 C17 C18 P1' -2.4(10) . . . . ?
C14 P1' C18 N1 -178(11) . . . . ?
Pt1' P1' C18 N1 -4(9) . . . . ?
C15 P1' C18 N1 -177(10) . . . . ?
C14 P1' C18 C17 1.4(19) . . . . ?
Pt1' P1' C18 C17 174.6(7) . . . . ?
C15 P1' C18 C17 1.9(9) . . . . ?
C25 P2 C19 C20 -29.5(4) . . . . ?
C31 P2 C19 C20 -136.3(3) . . . . ?
Pt1 P2 C19 C20 98.0(3) . . . . ?
C25 P2 C19 C24 160.2(3) . . . . ?
C31 P2 C19 C24 53.3(3) . . . . ?
Pt1 P2 C19 C24 -72.4(3) . . . . ?
C24 C19 C20 C21 -0.9(6) . . . . ?
P2 C19 C20 C21 -171.1(3) . . . . ?
C19 C20 C21 C22 -0.9(6) . . . . ?
C20 C21 C22 C23 2.0(7) . . . . ?
C21 C22 C23 C24 -1.2(7) . . . . ?
C22 C23 C24 C19 -0.6(6) . . . . ?
C20 C19 C24 C23 1.6(6) . . . . ?
P2 C19 C24 C23 172.1(3) . . . . ?
C19 P2 C25 C30 145.4(3) . . . . ?
C31 P2 C25 C30 -106.5(3) . . . . ?
Pt1 P2 C25 C30 17.4(4) . . . . ?
C19 P2 C25 C26 -42.8(4) . . . . ?
C31 P2 C25 C26 65.2(4) . . . . ?
Pt1 P2 C25 C26 -170.8(3) . . . . ?
C30 C25 C26 C27 1.5(6) . . . . ?
P2 C25 C26 C27 -170.1(3) . . . . ?
C25 C26 C27 C28 -1.2(7) . . . . ?
C26 C27 C28 C29 -0.3(7) . . . . ?
C27 C28 C29 C30 1.3(7) . . . . ?
C28 C29 C30 C25 -0.9(6) . . . . ?
C26 C25 C30 C29 -0.5(6) . . . . ?
P2 C25 C30 C29 171.5(3) . . . . ?
C35 P2' C31 N2 22.8(10) . . . . ?
C32 P2' C31 N2 78(3) . . . . ?
Pt1' P2' C31 N2 -92(4) . . . . ?
N2 P2' C31 C32 -78(3) . . . . ?
C35 P2' C31 C32 -55(3) . . . . ?
Pt1' P2' C31 C32 -169.6(12) . . . . ?
N2 P2' C31 P2 146.5(16) . . . . ?
C35 P2' C31 P2 169.3(8) . . . . ?
C32 P2' C31 P2 -136(2) . . . . ?
Pt1' P2' C31 P2 54(3) . . . . ?
C25 P2 C31 P2' 87.6(16) . . . . ?
C19 P2 C31 P2' -158.9(16) . . . . ?
Pt1 P2 C31 P2' -34.4(16) . . . . ?
C25 P2 C31 N2 111.8(3) . . . . ?
C19 P2 C31 N2 -134.7(3) . . . . ?
Pt1 P2 C31 N2 -10.2(3) . . . . ?
C25 P2 C31 C32 -62.4(4) . . . . ?
C19 P2 C31 C32 51.1(4) . . . . ?
Pt1 P2 C31 C32 175.6(3) . . . . ?
P2' C31 C32 C33 47(3) . . . . ?
N2 C31 C32 C33 -0.6(6) . . . . ?
P2 C31 C32 C33 173.4(3) . . . . ?
N2 C31 C32 P2' -48(3) . . . . ?
P2 C31 C32 P2' 126(3) . . . . ?
N2 P2' C32 C31 104(4) . . . . ?
C35 P2' C32 C31 124(3) . . . . ?
Pt1' P2' C32 C31 24(3) . . . . ?
N2 P2' C32 C33 -33.2(18) . . . . ?
C31 P2' C32 C33 -138(3) . . . . ?
C35 P2' C32 C33 -14.0(8) . . . . ?
Pt1' P2' C32 C33 -114(5) . . . . ?
C31 C32 C33 C34 0.6(6) . . . . ?
P2' C32 C33 C34 12.1(9) . . . . ?
C32 C33 C34 C35 0.2(6) . . . . ?
C33 C34 C35 N2 -1.0(6) . . . . ?
C33 C34 C35 P2' -12.9(9) . . . . ?
C31 P2' C35 N2 -105(3) . . . . ?
C32 P2' C35 N2 -124(3) . . . . ?
Pt1' P2' C35 N2 39.2(17) . . . . ?
N2 P2' C35 C34 139(2) . . . . ?
C31 P2' C35 C34 33.6(18) . . . . ?
C32 P2' C35 C34 14.4(8) . . . . ?
Pt1' P2' C35 C34 178.0(6) . . . . ?
C18 P1' N1 C14 -2(11) . . . . ?
Pt1' P1' N1 C14 173(3) . . . . ?
C15 P1' N1 C14 0.5(14) . . . . ?
C14 P1' N1 C18 2(11) . . . . ?
Pt1' P1' N1 C18 176(8) . . . . ?
C15 P1' N1 C18 3(10) . . . . ?
C14 P1' N1 Sn1 -179(2) . . . . ?
Pt1' P1' N1 Sn1 -5.6(5) . . . . ?
C15 P1' N1 Sn1 -178.6(11) . . . . ?
C14 P1' N1 Pt1' -173(3) . . . . ?
C18 P1' N1 Pt1' -176(8) . . . . ?
C15 P1' N1 Pt1' -172.9(16) . . . . ?
C15 C14 N1 P1' -179(3) . . . . ?
P1 C14 N1 P1' 7(3) . . . . ?
P1' C14 N1 C18 -179(3) . . . . ?
C15 C14 N1 C18 1.5(6) . . . . ?
P1 C14 N1 C18 -172.2(3) . . . . ?
P1' C14 N1 Sn1 1(3) . . . . ?
C15 C14 N1 Sn1 -178.0(3) . . . . ?
P1 C14 N1 Sn1 8.3(4) . . . . ?
P1' C14 N1 Pt1' 6(3) . . . . ?
C15 C14 N1 Pt1' -173.1(3) . . . . ?
P1 C14 N1 Pt1' 13.2(4) . . . . ?
C17 C18 N1 P1' -1(10) . . . . ?
C17 C18 N1 C14 1.0(6) . . . . ?
P1' C18 N1 C14 2(9) . . . . ?
C17 C18 N1 Sn1 -179.5(3) . . . . ?
C17 C18 N1 Pt1' 174.0(3) . . . . ?
P1' C18 N1 Pt1' 175(10) . . . . ?
Cl1 Sn1 N1 P1' -130(2) . . . . ?
Cl2 Sn1 N1 P1' 128(2) . . . . ?
Pt1 Sn1 N1 P1' -1(2) . . . . ?
N2 Sn1 N1 C14 179.3(5) . . . . ?
Cl1 Sn1 N1 C14 -131.0(3) . . . . ?
Cl2 Sn1 N1 C14 126.7(3) . . . . ?
Pt1 Sn1 N1 C14 -1.6(3) . . . . ?
N2 Sn1 N1 C18 -0.2(8) . . . . ?
Cl1 Sn1 N1 C18 49.4(3) . . . . ?
Cl2 Sn1 N1 C18 -52.8(3) . . . . ?
Pt1 Sn1 N1 C18 178.9(3) . . . . ?
N2 Sn1 N1 Pt1' 157.6(9) . . . . ?
Cl1 Sn1 N1 Pt1' -152.7(6) . . . . ?
Cl2 Sn1 N1 Pt1' 105.0(6) . . . . ?
Pt1 Sn1 N1 Pt1' -23.2(6) . . . . ?
C1' Pt1' N1 P1' -173(3) . . . . ?
P2' Pt1' N1 P1' -178(3) . . . . ?
N2 Pt1' N1 P1' -162(2) . . . . ?
Sn1' Pt1' N1 P1' 0(2) . . . . ?
C1' Pt1' N1 C14 -178(2) . . . . ?
P1' Pt1' N1 C14 -5(2) . . . . ?
P2' Pt1' N1 C14 177(2) . . . . ?
N2 Pt1' N1 C14 -167.0(4) . . . . ?
Sn1' Pt1' N1 C14 -5.3(4) . . . . ?
C1' Pt1' N1 C18 8(2) . . . . ?
P1' Pt1' N1 C18 -179(2) . . . . ?
P2' Pt1' N1 C18 3(3) . . . . ?
N2 Pt1' N1 C18 19.3(7) . . . . ?
Sn1' Pt1' N1 C18 -179.0(4) . . . . ?
C1' Pt1' N1 Sn1 -18(2) . . . . ?
P1' Pt1' N1 Sn1 155(2) . . . . ?
P2' Pt1' N1 Sn1 -23(2) . . . . ?
N2 Pt1' N1 Sn1 -6.8(3) . . . . ?
Sn1' Pt1' N1 Sn1 154.9(8) . . . . ?
C31 P2' N2 C35 77(3) . . . . ?
C32 P2' N2 C35 54(2) . . . . ?
Pt1' P2' N2 C35 -141.9(15) . . . . ?
C35 P2' N2 C31 -77(3) . . . . ?
C32 P2' N2 C31 -22.7(9) . . . . ?
Pt1' P2' N2 C31 141.3(19) . . . . ?
C31 P2' N2 Sn1 -142.8(15) . . . . ?
C35 P2' N2 Sn1 140.4(19) . . . . ?
C32 P2' N2 Sn1 -165.5(7) . . . . ?
Pt1' P2' N2 Sn1 -1.5(4) . . . . ?
C31 P2' N2 Pt1' -141.3(19) . . . . ?
C35 P2' N2 Pt1' 141.9(15) . . . . ?
C32 P2' N2 Pt1' -164.0(11) . . . . ?
C34 C35 N2 P2' -47(2) . . . . ?
C34 C35 N2 C31 1.0(6) . . . . ?
P2' C35 N2 C31 48(2) . . . . ?
C34 C35 N2 Sn1 -178.5(3) . . . . ?
P2' C35 N2 Sn1 -132(2) . . . . ?
C34 C35 N2 Pt1' -171.1(3) . . . . ?
P2' C35 N2 Pt1' -124(2) . . . . ?
C32 C31 N2 P2' 136(2) . . . . ?
P2 C31 N2 P2' -39(2) . . . . ?
P2' C31 N2 C35 -136(2) . . . . ?
C32 C31 N2 C35 -0.1(6) . . . . ?
P2 C31 N2 C35 -174.3(3) . . . . ?
P2' C31 N2 Sn1 44(2) . . . . ?
C32 C31 N2 Sn1 179.3(3) . . . . ?
P2 C31 N2 Sn1 5.1(4) . . . . ?
P2' C31 N2 Pt1' 38(2) . . . . ?
C32 C31 N2 Pt1' 174.0(3) . . . . ?
P2 C31 N2 Pt1' -0.2(4) . . . . ?
N1 Sn1 N2 P2' -152.4(16) . . . . ?
Cl1 Sn1 N2 P2' 157.9(16) . . . . ?
Cl2 Sn1 N2 P2' -99.9(16) . . . . ?
Pt1 Sn1 N2 P2' 28.5(16) . . . . ?
N1 Sn1 N2 C35 -0.2(8) . . . . ?
Cl1 Sn1 N2 C35 -49.9(3) . . . . ?
Cl2 Sn1 N2 C35 52.3(3) . . . . ?
Pt1 Sn1 N2 C35 -179.3(3) . . . . ?
N1 Sn1 N2 C31 -179.7(5) . . . . ?
Cl1 Sn1 N2 C31 130.6(3) . . . . ?
Cl2 Sn1 N2 C31 -127.2(3) . . . . ?
Pt1 Sn1 N2 C31 1.2(3) . . . . ?
N1 Sn1 N2 Pt1' -158.4(9) . . . . ?
Cl1 Sn1 N2 Pt1' 151.9(6) . . . . ?
Cl2 Sn1 N2 Pt1' -105.9(6) . . . . ?
Pt1 Sn1 N2 Pt1' 22.5(5) . . . . ?
C1' Pt1' N2 P2' -157(3) . . . . ?
P1' Pt1' N2 P2' 178(3) . . . . ?
Sn1' Pt1' N2 P2' 30.8(17) . . . . ?
N1 Pt1' N2 P2' -167.7(17) . . . . ?
C1' Pt1' N2 C35 -9(2) . . . . ?
P1' Pt1' N2 C35 -35(2) . . . . ?
P2' Pt1' N2 C35 147.3(17) . . . . ?
Sn1' Pt1' N2 C35 178.1(4) . . . . ?
N1 Pt1' N2 C35 -20.4(7) . . . . ?
C1' Pt1' N2 C31 178(2) . . . . ?
P1' Pt1' N2 C31 152.1(19) . . . . ?
P2' Pt1' N2 C31 -25.5(16) . . . . ?
Sn1' Pt1' N2 C31 5.3(4) . . . . ?
N1 Pt1' N2 C31 166.8(4) . . . . ?
C1' Pt1' N2 Sn1 17(2) . . . . ?
P1' Pt1' N2 Sn1 -8.7(18) . . . . ?
P2' Pt1' N2 Sn1 173.7(17) . . . . ?
Sn1' Pt1' N2 Sn1 -155.5(8) . . . . ?
N1 Pt1' N2 Sn1 6.1(2) . . . . ?
B2 B2 F3 F6 -108(5) 2 . . 2 ?
F4 B2 F3 F6 -38(3) . . . 2 ?
F6 B2 F3 F6 -175(2) . . . 2 ?
F5 B2 F3 F6 73(3) . . . 2 ?
F3 B2 F3 F6 177(3) 2 . . 2 ?
F5 B2 F3 F6 -102(3) 2 . . 2 ?
F6 B2 F3 B2 108(5) 2 . . 2 ?
F4 B2 F3 B2 70(4) . . . 2 ?
F6 B2 F3 B2 -67(5) . . . 2 ?
F5 B2 F3 B2 -179(5) . . . 2 ?
F3 B2 F3 B2 -75(4) 2 . . 2 ?
F5 B2 F3 B2 7(4) 2 . . 2 ?
B2 B2 F3 F3 75(4) 2 . . 2 ?
F6 B2 F3 F3 -177(3) 2 . . 2 ?
F4 B2 F3 F3 144.7(15) . . . 2 ?
F6 B2 F3 F3 7.6(13) . . . 2 ?
F5 B2 F3 F3 -104.1(11) . . . 2 ?
F5 B2 F3 F3 81.3(10) 2 . . 2 ?
F4 B2 F4 B2 103(5) 2 . . 2 ?
F6 B2 F4 B2 -101(5) 2 . . 2 ?
F6 B2 F4 B2 34(4) . . . 2 ?
F5 B2 F4 B2 172(6) . . . 2 ?
F3 B2 F4 B2 -86(5) . . . 2 ?
F3 B2 F4 B2 7(3) 2 . . 2 ?
F5 B2 F4 B2 -1(5) 2 . . 2 ?
B2 B2 F4 F4 -103(5) 2 . . 2 ?
F6 B2 F4 F4 156.7(15) 2 . . 2 ?
F6 B2 F4 F4 -68.6(16) . . . 2 ?
F5 B2 F4 F4 68.9(12) . . . 2 ?
F3 B2 F4 F4 171.7(15) . . . 2 ?
F3 B2 F4 F4 -95(3) 2 . . 2 ?
F5 B2 F4 F4 -104.2(10) 2 . . 2 ?
B2 B2 F4 F5 1(5) 2 . . 2 ?
F4 B2 F4 F5 104.2(10) 2 . . 2 ?
F6 B2 F4 F5 -99.1(11) 2 . . 2 ?
F6 B2 F4 F5 35.6(14) . . . 2 ?
F5 B2 F4 F5 173.1(13) . . . 2 ?
F3 B2 F4 F5 -84.0(10) . . . 2 ?
F3 B2 F4 F5 9(2) 2 . . 2 ?
B2 B2 F4 F6 101(5) 2 . . 2 ?
F4 B2 F4 F6 -156.7(15) 2 . . 2 ?
F6 B2 F4 F6 135(2) . . . 2 ?
F5 B2 F4 F6 -87.8(14) . . . 2 ?
F3 B2 F4 F6 15.1(11) . . . 2 ?
F3 B2 F4 F6 108(3) 2 . . 2 ?
F5 B2 F4 F6 99.1(11) 2 . . 2 ?
F6 B2 F5 F4 -152.0(12) 2 . . 2 ?
F4 B2 F5 F4 -65.9(12) . . . 2 ?
F6 B2 F5 F4 80.5(13) . . . 2 ?
F3 B2 F5 F4 -175.5(12) . . . 2 ?
F3 B2 F5 F4 105.0(15) 2 . . 2 ?
F5 B2 F5 F4 -28(6) 2 . . 2 ?
B2 B2 F6 F3 -106(4) 2 . . 2 ?
F4 B2 F6 F3 157(3) 2 . . 2 ?
F6 B2 F6 F3 -21(2) 2 . . 2 ?
F4 B2 F6 F3 -141(3) . . . 2 ?
F5 B2 F6 F3 82(3) . . . 2 ?
F3 B2 F6 F3 -19(3) . . . 2 ?
F5 B2 F6 F3 -108(3) 2 . . 2 ?
F4 B2 F6 B2 -98(3) 2 . . 2 ?
F6 B2 F6 B2 85(3) 2 . . 2 ?
F4 B2 F6 B2 -35(2) . . . 2 ?
F5 B2 F6 B2 -172(3) . . . 2 ?
F3 B2 F6 B2 87(3) . . . 2 ?
F3 B2 F6 B2 106(4) 2 . . 2 ?
F5 B2 F6 B2 -2(3) 2 . . 2 ?
B2 B2 F6 F4 98(3) 2 . . 2 ?
F6 B2 F6 F4 -178(2) 2 . . 2 ?
F4 B2 F6 F4 62.8(14) . . . 2 ?
F5 B2 F6 F4 -74.2(12) . . . 2 ?
F3 B2 F6 F4 -175.4(15) . . . 2 ?
F3 B2 F6 F4 -157(3) 2 . . 2 ?
F5 B2 F6 F4 95.8(9) 2 . . 2 ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        27.50
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         1.164
_refine_diff_density_min         -0.786
_refine_diff_density_rms         0.113