# Supplementary Material (ESI) for Dalton Transactions
# This journal is (c) The Royal Society of Chemistry 2010

data_global
_journal_name_full               'Dalton Trans.'

_journal_coden_Cambridge         0222
_journal_volume                  ?
_journal_page_first              ?
_journal_year                    ?

_publ_contact_author_name        'G. Hix'
_publ_contact_author_email       GARY.HIX@NTU.AC.UK

_publ_section_title              
;
Tailoring the Photoluminescent
Properties of Transition Metal Phosphonates
;
loop_
_publ_author_name
'G. Hix'
'Gary Baker'
'James Bye'
'James Dyson'
'Robert M. Ranson'
'Richard Singleton'

# Attachment 'Ag_phosphonobenzoate.cif'

data_agphosphonobenzoate
_database_code_depnum_ccdc_archive 'CCDC 761289'
#TrackingRef 'Ag_phosphonobenzoate.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
'silver phosphonobenzoate'
;
_chemical_name_common            "'silver phosphonobenzoate'"
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C14 H8 Ag6 O10 P2'
_chemical_formula_weight         1045.36

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P b c a'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   7.9377(7)
_cell_length_b                   16.1575(10)
_cell_length_c                   29.873(7)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3831.3(10)
_cell_formula_units_Z            8
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    2679
_cell_measurement_theta_min      2.9302
_cell_measurement_theta_max      26.32

_exptl_crystal_description       needle
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_size_max          0.3907
_exptl_crystal_size_mid          0.0660
_exptl_crystal_size_min          0.0353
_exptl_crystal_density_meas      'not measured'
_exptl_crystal_density_diffrn    3.625
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3872
_exptl_absorpt_coefficient_mu    6.237
_exptl_absorpt_correction_type   multiscan
_exptl_absorpt_correction_T_min  0.72686
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   
;
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_special_details           
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov 6 2009,16:24:50)
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            8902
_diffrn_reflns_av_R_equivalents  0.0351
_diffrn_reflns_av_sigmaI/netI    0.0714
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         2.94
_diffrn_reflns_theta_max         29.04
_reflns_number_total             4299
_reflns_number_gt                2951
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov 6 2009,16:24:50)
;
_computing_cell_refinement       
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov 6 2009,16:24:50)
;
_computing_data_reduction        
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.52 (release 06-11-2009 CrysAlis171 .NET)
(compiled Nov 6 2009,16:24:50)
;
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0223P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.000090(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_number_reflns         4299
_refine_ls_number_parameters     290
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0684
_refine_ls_R_factor_gt           0.0378
_refine_ls_wR_factor_ref         0.0627
_refine_ls_wR_factor_gt          0.0584
_refine_ls_goodness_of_fit_ref   0.890
_refine_ls_restrained_S_all      0.890
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O3 O 0.6337(5) 0.3884(2) 0.55330(14) 0.0145(10) Uani 1 1 d . . .
O4 O 0.4528(4) 0.4615(2) 0.44110(13) 0.0105(9) Uani 1 1 d . . .
O10 O 0.7912(5) 0.2076(3) 0.64227(15) 0.0215(11) Uani 1 1 d . . .
O9 O 1.0462(5) 0.2180(2) 0.56781(13) 0.0133(10) Uani 1 1 d . . .
O8 O 1.1617(5) 0.3576(3) 0.54732(15) 0.0185(10) Uani 1 1 d . . .
O7 O 0.8372(5) 0.2697(3) 0.46874(14) 0.0169(11) Uani 1 1 d . . .
O11 O 0.7368(5) 0.1840(3) 0.71557(14) 0.0172(11) Uani 1 1 d . . .
O5 O 1.1686(5) 0.4982(3) 0.47478(14) 0.0164(11) Uani 1 1 d . . .
C14 C 0.6978(8) 0.2105(4) 0.6771(2) 0.0129(14) Uani 1 1 d . . .
C12 C 0.5252(7) 0.2467(4) 0.6700(2) 0.0117(14) Uani 1 1 d . . .
C8 C 0.2988(7) 0.2770(4) 0.6180(2) 0.0105(14) Uani 1 1 d . . .
C10 C 0.2771(8) 0.3174(4) 0.6960(2) 0.0219(17) Uani 1 1 d . . .
H10 H 0.2168 0.3425 0.719 0.026 Uiso 1 1 calc R . .
C13 C 0.4545(8) 0.2426(4) 0.6270(2) 0.0141(14) Uani 1 1 d . . .
H13 H 0.5134 0.2162 0.6042 0.017 Uiso 1 1 calc R . .
C9 C 0.2093(8) 0.3137(4) 0.6531(2) 0.0173(15) Uani 1 1 d . . .
H9 H 0.1031 0.3359 0.6477 0.021 Uiso 1 1 calc R . .
C11 C 0.4336(8) 0.2840(4) 0.7045(2) 0.0150(15) Uani 1 1 d . . .
H11 H 0.4784 0.2862 0.7332 0.018 Uiso 1 1 calc R . .
Ag1 Ag 0.49756(6) 0.37680(3) 0.367127(16) 0.01701(12) Uani 1 1 d . . .
Ag2 Ag 0.80754(6) 0.28894(3) 0.568163(19) 0.02178(14) Uani 1 1 d . . .
Ag3 Ag 0.50483(6) 0.36938(4) 0.270868(18) 0.02550(14) Uani 1 1 d . . .
Ag4 Ag 0.97087(6) 0.38862(3) 0.485887(17) 0.01857(13) Uani 1 1 d . . .
Ag5 Ag 0.44900(6) 0.35719(3) 0.494944(17) 0.01906(13) Uani 1 1 d . . .
Ag6 Ag 0.71147(6) 0.52129(3) 0.441001(19) 0.02231(14) Uani 1 1 d . . .
P1 P 0.69615(18) 0.47761(10) 0.55912(5) 0.0101(3) Uani 1 1 d . . .
P2 P 1.20687(19) 0.26945(10) 0.56228(6) 0.0111(4) Uani 1 1 d . . .
O1 O 0.7162(5) 0.4550(3) 0.36273(14) 0.0176(10) Uani 1 1 d . . .
O2 O 0.7642(5) 0.4290(3) 0.28961(15) 0.0206(11) Uani 1 1 d . . .
C1 C 0.8086(8) 0.4539(4) 0.3274(2) 0.0140(14) Uani 1 1 d . . .
C5 C 0.6933(8) 0.4494(4) 0.6512(2) 0.0181(15) Uani 1 1 d . . .
H5 H 0.5867 0.4273 0.6464 0.022 Uiso 1 1 calc R . .
C4 C 0.7586(7) 0.4517(4) 0.6948(2) 0.0206(16) Uani 1 1 d . . .
H4 H 0.6947 0.433 0.7188 0.025 Uiso 1 1 calc R . .
C6 C 0.7860(7) 0.4800(4) 0.6150(2) 0.0110(14) Uani 1 1 d . . .
C3 C 1.0801(8) 0.5179(4) 0.2986(2) 0.0171(15) Uani 1 1 d . . .
H3 H 1.0347 0.518 0.2699 0.021 Uiso 1 1 calc R . .
C2 C 0.9849(7) 0.4872(4) 0.3339(2) 0.0146(14) Uani 1 1 d . . .
C7 C 0.9463(7) 0.5117(4) 0.6231(2) 0.0106(13) Uani 1 1 d . . .
H7 H 1.0088 0.5326 0.5993 0.013 Uiso 1 1 calc R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
O3 0.015(2) 0.006(2) 0.022(3) 0.000(2) -0.006(2) -0.0003(18)
O4 0.013(2) 0.008(2) 0.011(2) -0.0007(18) -0.0022(19) 0.0003(18)
O10 0.019(2) 0.028(3) 0.017(3) 0.006(2) 0.002(2) 0.009(2)
O9 0.011(2) 0.016(2) 0.013(2) -0.002(2) -0.0018(19) -0.0022(19)
O8 0.025(2) 0.011(2) 0.020(3) 0.004(2) -0.010(2) -0.001(2)
O7 0.018(2) 0.022(3) 0.010(3) -0.005(2) -0.004(2) 0.004(2)
O11 0.016(2) 0.027(3) 0.008(2) 0.001(2) -0.005(2) 0.005(2)
O5 0.013(2) 0.018(2) 0.019(3) 0.003(2) 0.0007(19) -0.0018(19)
C14 0.021(3) 0.004(3) 0.014(4) -0.004(3) -0.001(3) 0.000(3)
C12 0.010(3) 0.017(3) 0.009(3) -0.005(3) 0.000(3) -0.002(3)
C8 0.010(3) 0.014(3) 0.008(3) -0.003(3) 0.002(3) -0.006(3)
C10 0.023(4) 0.019(4) 0.023(4) -0.008(3) 0.008(3) 0.006(3)
C13 0.020(3) 0.011(3) 0.011(4) 0.002(3) 0.008(3) 0.003(3)
C9 0.015(3) 0.019(4) 0.018(4) -0.001(3) 0.001(3) 0.003(3)
C11 0.021(3) 0.014(3) 0.010(4) 0.001(3) 0.001(3) -0.002(3)
Ag1 0.0171(2) 0.0179(2) 0.0160(3) 0.0016(2) -0.0005(2) -0.0061(2)
Ag2 0.0184(3) 0.0170(3) 0.0300(3) 0.0044(3) -0.0006(2) 0.0060(2)
Ag3 0.0215(3) 0.0362(3) 0.0188(3) -0.0025(3) 0.0022(2) -0.0155(2)
Ag4 0.0216(3) 0.0157(3) 0.0184(3) -0.0017(2) -0.0049(2) -0.0029(2)
Ag5 0.0294(3) 0.0156(2) 0.0121(3) 0.0005(2) 0.0023(2) 0.0005(2)
Ag6 0.0181(3) 0.0203(3) 0.0285(3) -0.0098(3) -0.0005(3) -0.0051(2)
P1 0.0113(8) 0.0095(8) 0.0097(9) 0.0013(7) 0.0009(8) -0.0012(7)
P2 0.0115(8) 0.0088(8) 0.0129(10) 0.0010(7) -0.0011(8) -0.0002(7)
O1 0.016(2) 0.022(2) 0.016(3) -0.007(2) 0.000(2) -0.004(2)
O2 0.022(3) 0.025(3) 0.014(3) -0.006(2) -0.005(2) -0.009(2)
C1 0.020(3) 0.006(3) 0.016(4) -0.001(3) 0.001(3) 0.000(3)
C5 0.014(3) 0.019(4) 0.021(4) 0.009(3) 0.000(3) -0.002(3)
C4 0.017(3) 0.026(4) 0.018(4) 0.008(3) 0.010(3) -0.003(3)
C6 0.009(3) 0.011(3) 0.013(4) 0.002(3) -0.002(3) -0.002(3)
C3 0.023(4) 0.016(3) 0.012(4) -0.002(3) 0.001(3) 0.008(3)
C2 0.013(3) 0.012(3) 0.019(4) -0.005(3) 0.002(3) -0.001(3)
C7 0.014(3) 0.010(3) 0.007(3) -0.001(3) 0.000(3) 0.001(3)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
O3 P1 1.534(4) . ?
O3 Ag2 2.165(4) . ?
O3 Ag5 2.333(4) . ?
O4 P1 1.538(4) 5_666 ?
O4 Ag6 2.270(4) . ?
O4 Ag5 2.329(4) . ?
O10 C14 1.278(7) . ?
O10 Ag1 2.150(4) 4_556 ?
O10 Ag2 2.577(4) . ?
O9 P2 1.532(4) . ?
O9 Ag2 2.215(4) . ?
O9 Ag5 2.363(4) 4_556 ?
O9 Ag1 2.504(4) 4_556 ?
O8 P2 1.535(4) . ?
O8 Ag6 2.229(4) 5_766 ?
O8 Ag4 2.432(4) . ?
O7 P2 1.526(4) 4_456 ?
O7 Ag4 2.254(4) . ?
O7 Ag5 2.483(4) 4_556 ?
O11 C14 1.266(7) . ?
O11 Ag3 2.331(4) 4_556 ?
O5 P1 1.527(4) 5_766 ?
O5 Ag4 2.389(4) . ?
O5 Ag4 2.440(4) 5_766 ?
C14 C12 1.504(8) . ?
C12 C11 1.396(8) . ?
C12 C13 1.404(8) . ?
C8 C13 1.382(8) . ?
C8 C9 1.399(8) . ?
C8 P2 1.822(6) 1_455 ?
C10 C11 1.378(8) . ?
C10 C9 1.391(9) . ?
Ag1 O10 2.150(4) 4_456 ?
Ag1 O1 2.150(4) . ?
Ag1 O9 2.504(4) 4_456 ?
Ag1 Ag3 2.8786(10) . ?
Ag2 Ag4 3.2118(9) . ?
Ag2 Ag5 3.2233(8) 4_556 ?
Ag3 O11 2.331(4) 4_456 ?
Ag3 O2 2.341(4) . ?
Ag4 O5 2.440(4) 5_766 ?
Ag4 Ag6 3.2608(7) . ?
Ag5 O9 2.363(4) 4_456 ?
Ag5 O7 2.483(4) 4_456 ?
Ag5 Ag6 3.0231(8) 5_666 ?
Ag5 Ag2 3.2233(8) 4_456 ?
Ag6 O8 2.229(4) 5_766 ?
Ag6 O1 2.572(4) . ?
Ag6 Ag5 3.0231(8) 5_666 ?
P1 O5 1.527(4) 5_766 ?
P1 O4 1.538(4) 5_666 ?
P1 C6 1.817(6) . ?
P2 O7 1.526(4) 4_556 ?
P2 C8 1.822(6) 1_655 ?
O1 C1 1.286(7) . ?
O2 C1 1.248(7) . ?
C1 C2 1.512(8) . ?
C5 C6 1.398(8) . ?
C5 C4 1.400(9) . ?
C4 C3 1.386(9) 5_766 ?
C6 C7 1.393(8) . ?
C3 C4 1.386(8) 5_766 ?
C3 C2 1.390(8) . ?
C2 C7 1.396(8) 5_766 ?
C7 C2 1.396(8) 5_766 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 O3 Ag2 117.9(2) . . ?
P1 O3 Ag5 119.4(2) . . ?
Ag2 O3 Ag5 113.15(17) . . ?
P1 O4 Ag6 115.0(2) 5_666 . ?
P1 O4 Ag5 117.1(2) 5_666 . ?
Ag6 O4 Ag5 108.70(15) . . ?
C14 O10 Ag1 124.8(4) . 4_556 ?
C14 O10 Ag2 135.2(4) . . ?
Ag1 O10 Ag2 99.96(16) 4_556 . ?
P2 O9 Ag2 115.6(2) . . ?
P2 O9 Ag5 117.7(2) . 4_556 ?
Ag2 O9 Ag5 89.46(13) . 4_556 ?
P2 O9 Ag1 123.0(2) . 4_556 ?
Ag2 O9 Ag1 100.43(14) . 4_556 ?
Ag5 O9 Ag1 104.55(14) 4_556 4_556 ?
P2 O8 Ag6 131.6(2) . 5_766 ?
P2 O8 Ag4 123.8(2) . . ?
Ag6 O8 Ag4 102.61(16) 5_766 . ?
P2 O7 Ag4 144.1(3) 4_456 . ?
P2 O7 Ag5 99.5(2) 4_456 4_556 ?
Ag4 O7 Ag5 115.86(16) . 4_556 ?
C14 O11 Ag3 120.4(4) . 4_556 ?
P1 O5 Ag4 138.1(3) 5_766 . ?
P1 O5 Ag4 116.5(2) 5_766 5_766 ?
Ag4 O5 Ag4 100.98(14) . 5_766 ?
O11 C14 O10 125.8(6) . . ?
O11 C14 C12 118.8(6) . . ?
O10 C14 C12 115.4(5) . . ?
C11 C12 C13 119.1(5) . . ?
C11 C12 C14 122.6(6) . . ?
C13 C12 C14 118.3(5) . . ?
C13 C8 C9 118.6(6) . . ?
C13 C8 P2 120.6(5) . 1_455 ?
C9 C8 P2 120.7(5) . 1_455 ?
C11 C10 C9 120.1(6) . . ?
C8 C13 C12 121.2(6) . . ?
C10 C9 C8 120.8(6) . . ?
C10 C11 C12 120.2(6) . . ?
O10 Ag1 O1 168.38(17) 4_456 . ?
O10 Ag1 O9 80.26(15) 4_456 4_456 ?
O1 Ag1 O9 106.39(15) . 4_456 ?
O10 Ag1 Ag3 81.86(12) 4_456 . ?
O1 Ag1 Ag3 86.98(12) . . ?
O9 Ag1 Ag3 138.31(9) 4_456 . ?
O3 Ag2 O9 158.27(15) . . ?
O3 Ag2 O10 121.51(15) . . ?
O9 Ag2 O10 77.48(14) . . ?
O3 Ag2 Ag4 74.21(11) . . ?
O9 Ag2 Ag4 84.88(10) . . ?
O10 Ag2 Ag4 158.93(9) . . ?
O3 Ag2 Ag5 130.25(11) . 4_556 ?
O9 Ag2 Ag5 47.14(10) . 4_556 ?
O10 Ag2 Ag5 98.43(10) . 4_556 ?
Ag4 Ag2 Ag5 77.24(2) . 4_556 ?
O11 Ag3 O2 155.96(15) 4_456 . ?
O11 Ag3 Ag1 79.83(11) 4_456 . ?
O2 Ag3 Ag1 76.21(11) . . ?
O7 Ag4 O5 155.43(15) . . ?
O7 Ag4 O8 106.79(14) . . ?
O5 Ag4 O8 81.28(14) . . ?
O7 Ag4 O5 122.34(14) . 5_766 ?
O5 Ag4 O5 79.02(14) . 5_766 ?
O8 Ag4 O5 94.24(14) . 5_766 ?
O7 Ag4 Ag2 63.66(11) . . ?
O5 Ag4 Ag2 137.99(11) . . ?
O8 Ag4 Ag2 64.57(10) . . ?
O5 Ag4 Ag2 79.88(10) 5_766 . ?
O7 Ag4 Ag6 99.77(10) . . ?
O5 Ag4 Ag6 82.57(10) . . ?
O8 Ag4 Ag6 147.06(10) . . ?
O5 Ag4 Ag6 54.45(10) 5_766 . ?
Ag2 Ag4 Ag6 112.92(2) . . ?
O4 Ag5 O3 110.57(14) . . ?
O4 Ag5 O9 79.61(14) . 4_456 ?
O3 Ag5 O9 119.92(13) . 4_456 ?
O4 Ag5 O7 154.58(13) . 4_456 ?
O3 Ag5 O7 94.41(14) . 4_456 ?
O9 Ag5 O7 92.24(14) 4_456 4_456 ?
O4 Ag5 Ag6 88.44(10) . 5_666 ?
O3 Ag5 Ag6 69.59(10) . 5_666 ?
O9 Ag5 Ag6 166.77(10) 4_456 5_666 ?
O7 Ag5 Ag6 96.26(10) 4_456 5_666 ?
O4 Ag5 Ag2 97.49(9) . 4_456 ?
O3 Ag5 Ag2 144.53(10) . 4_456 ?
O9 Ag5 Ag2 43.39(9) 4_456 4_456 ?
O7 Ag5 Ag2 61.72(10) 4_456 4_456 ?
Ag6 Ag5 Ag2 134.36(2) 5_666 4_456 ?
O8 Ag6 O4 141.50(14) 5_766 . ?
O8 Ag6 O1 120.11(15) 5_766 . ?
O4 Ag6 O1 80.61(13) . . ?
O8 Ag6 Ag5 61.36(11) 5_766 5_666 ?
O4 Ag6 Ag5 83.95(10) . 5_666 ?
O1 Ag6 Ag5 148.43(10) . 5_666 ?
O8 Ag6 Ag4 103.17(10) 5_766 . ?
O4 Ag6 Ag4 106.90(10) . . ?
O1 Ag6 Ag4 95.21(10) . . ?
Ag5 Ag6 Ag4 115.64(2) 5_666 . ?
O5 P1 O3 113.1(2) 5_766 . ?
O5 P1 O4 111.9(2) 5_766 5_666 ?
O3 P1 O4 110.6(2) . 5_666 ?
O5 P1 C6 109.2(3) 5_766 . ?
O3 P1 C6 104.5(3) . . ?
O4 P1 C6 107.0(3) 5_666 . ?
O7 P2 O9 113.9(2) 4_556 . ?
O7 P2 O8 111.5(3) 4_556 . ?
O9 P2 O8 109.9(2) . . ?
O7 P2 C8 108.1(3) 4_556 1_655 ?
O9 P2 C8 105.7(3) . 1_655 ?
O8 P2 C8 107.3(3) . 1_655 ?
C1 O1 Ag1 120.2(4) . . ?
C1 O1 Ag6 139.5(4) . . ?
Ag1 O1 Ag6 100.22(16) . . ?
C1 O2 Ag3 126.6(4) . . ?
O2 C1 O1 125.8(6) . . ?
O2 C1 C2 119.5(6) . . ?
O1 C1 C2 114.7(5) . . ?
C6 C5 C4 121.0(6) . . ?
C3 C4 C5 119.0(6) 5_766 . ?
C7 C6 C5 118.5(6) . . ?
C7 C6 P1 121.7(5) . . ?
C5 C6 P1 119.8(5) . . ?
C4 C3 C2 121.3(6) 5_766 . ?
C3 C2 C7 118.8(6) . 5_766 ?
C3 C2 C1 122.2(6) . . ?
C7 C2 C1 119.1(6) 5_766 . ?
C6 C7 C2 121.4(6) . 5_766 ?

_diffrn_measured_fraction_theta_max 0.9865
_diffrn_reflns_theta_full        26.32
_diffrn_measured_fraction_theta_full 0.9865
_refine_diff_density_max         1.264
_refine_diff_density_min         -1.398
_refine_diff_density_rms         0.205