# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2012


data_global
_journal_name_full               'Dalton Trans.'
_journal_coden_cambridge         0222
_journal_year                    ?
_journal_volume                  ?
_journal_page_first              ?
_publ_contact_author_name        'Jianyong Zhang'
_publ_contact_author_email       zhjyong@mail.sysu.edu.cn
_publ_author_name                'Jianyong Zhang'

data_Ag-OTf
_database_code_depnum_ccdc_archive 'CCDC 857926'
#TrackingRef '- cifs.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C67 H48 Ag F3 N6 O3 P2 S'
_chemical_formula_weight         1243.98

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   10.0247(2)
_cell_length_b                   28.8156(4)
_cell_length_c                   20.0865(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 103.282(2)
_cell_angle_gamma                90.00
_cell_volume                     5647.13(18)
_cell_formula_units_Z            4
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    7958
_cell_measurement_theta_min      3.0647
_cell_measurement_theta_max      62.4223

_exptl_crystal_description       plate
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.05
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.463
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2544
_exptl_absorpt_coefficient_mu    4.280
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.2793
_exptl_absorpt_correction_T_max  0.8145
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            16501
_diffrn_reflns_av_R_equivalents  0.0393
_diffrn_reflns_av_sigmaI/netI    0.0339
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_theta_min         3.07
_diffrn_reflns_theta_max         62.51
_reflns_number_total             4494
_reflns_number_gt                4178
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0361P)^2^+3.2869P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     SHELXL
_refine_ls_extinction_coef       0.000065(12)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^
_refine_ls_number_reflns         4494
_refine_ls_number_parameters     404
_refine_ls_number_restraints     3
_refine_ls_R_factor_all          0.0313
_refine_ls_R_factor_gt           0.0278
_refine_ls_wR_factor_ref         0.0711
_refine_ls_wR_factor_gt          0.0676
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_restrained_S_all      1.094
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.0000 0.598923(7) 0.7500 0.02134(10) Uani 1 2 d S . .
P1 P 0.99237(6) 0.554535(18) 0.64418(3) 0.02159(14) Uani 1 1 d . . .
N1 N 1.3265(2) 0.15726(6) 0.73376(11) 0.0278(5) Uani 1 1 d . . .
N2 N 0.4095(2) 0.21783(8) 0.52430(14) 0.0465(7) Uani 1 1 d . . .
N3 N 0.9042(2) 0.24766(6) 0.63510(10) 0.0239(4) Uani 1 1 d . . .
C1 C 0.7998(2) 0.27772(8) 0.61779(12) 0.0232(5) Uani 1 1 d . . .
C2 C 0.8165(2) 0.32525(8) 0.62710(12) 0.0239(5) Uani 1 1 d . . .
H2A H 0.7393 0.3453 0.6163 0.029 Uiso 1 1 calc R . .
C3 C 0.9472(2) 0.34341(7) 0.65241(12) 0.0216(5) Uani 1 1 d . . .
C4 C 1.0563(2) 0.31220(7) 0.67111(12) 0.0223(5) Uani 1 1 d . . .
H4A H 1.1469 0.3231 0.6889 0.027 Uiso 1 1 calc R . .
C5 C 1.0293(2) 0.26472(7) 0.66317(12) 0.0224(5) Uani 1 1 d . . .
C6 C 0.9666(2) 0.39457(7) 0.65610(11) 0.0204(5) Uani 1 1 d . . .
C7 C 0.8697(2) 0.42310(8) 0.67578(12) 0.0229(5) Uani 1 1 d . . .
H7A H 0.7945 0.4096 0.6901 0.027 Uiso 1 1 calc R . .
C8 C 0.8827(2) 0.47092(7) 0.67448(12) 0.0226(5) Uani 1 1 d . . .
H8A H 0.8181 0.4900 0.6895 0.027 Uiso 1 1 calc R . .
C9 C 0.9902(2) 0.49133(7) 0.65134(11) 0.0215(5) Uani 1 1 d . . .
C10 C 1.0878(2) 0.46293(8) 0.63329(12) 0.0224(5) Uani 1 1 d . . .
H10A H 1.1625 0.4764 0.6186 0.027 Uiso 1 1 calc R . .
C11 C 1.0773(2) 0.41490(8) 0.63650(12) 0.0222(5) Uani 1 1 d . . .
H11A H 1.1463 0.3959 0.6252 0.027 Uiso 1 1 calc R . .
C12 C 0.6638(2) 0.25701(8) 0.58621(13) 0.0259(5) Uani 1 1 d . . .
C13 C 0.5420(3) 0.27773(8) 0.59242(15) 0.0358(6) Uani 1 1 d . . .
H13A H 0.5431 0.3059 0.6172 0.043 Uiso 1 1 calc R . .
C14 C 0.4186(3) 0.25655(9) 0.56176(18) 0.0456(8) Uani 1 1 d . . .
H14A H 0.3361 0.2704 0.5678 0.055 Uiso 1 1 calc R . .
C15 C 0.5276(3) 0.19846(9) 0.51891(15) 0.0372(6) Uani 1 1 d . . .
H15A H 0.5234 0.1710 0.4923 0.045 Uiso 1 1 calc R . .
C16 C 0.6553(3) 0.21578(8) 0.54950(13) 0.0298(6) Uani 1 1 d . . .
H16A H 0.7361 0.1998 0.5455 0.036 Uiso 1 1 calc R . .
C17 C 1.1361(2) 0.22863(8) 0.68672(12) 0.0232(5) Uani 1 1 d . . .
C18 C 1.1133(3) 0.18338(8) 0.66315(15) 0.0349(6) Uani 1 1 d . . .
H18A H 1.0313 0.1757 0.6308 0.042 Uiso 1 1 calc R . .
C19 C 1.2099(3) 0.14969(8) 0.68688(15) 0.0356(6) Uani 1 1 d . . .
H19A H 1.1929 0.1192 0.6689 0.043 Uiso 1 1 calc R . .
C20 C 1.3455(3) 0.20077(8) 0.75760(13) 0.0295(5) Uani 1 1 d . . .
H20A H 1.4254 0.2071 0.7922 0.035 Uiso 1 1 calc R . .
C21 C 1.2565(3) 0.23702(8) 0.73506(13) 0.0268(5) Uani 1 1 d . . .
H21A H 1.2776 0.2674 0.7526 0.032 Uiso 1 1 calc R . .
C22 C 0.8510(2) 0.56607(8) 0.57050(12) 0.0260(5) Uani 1 1 d . . .
C23 C 0.7725(3) 0.53175(9) 0.53187(13) 0.0320(6) Uani 1 1 d . . .
H23A H 0.7927 0.5000 0.5426 0.038 Uiso 1 1 calc R . .
C24 C 0.6644(3) 0.54332(10) 0.47748(14) 0.0374(6) Uani 1 1 d . . .
H24A H 0.6103 0.5195 0.4517 0.045 Uiso 1 1 calc R . .
C25 C 0.6354(3) 0.58943(10) 0.46078(14) 0.0379(6) Uani 1 1 d . . .
H25A H 0.5624 0.5973 0.4232 0.046 Uiso 1 1 calc R . .
C26 C 0.7128(3) 0.62374(10) 0.49886(15) 0.0411(7) Uani 1 1 d . . .
H26A H 0.6934 0.6554 0.4874 0.049 Uiso 1 1 calc R . .
C27 C 0.8192(3) 0.61228(9) 0.55410(14) 0.0348(6) Uani 1 1 d . . .
H27A H 0.8707 0.6362 0.5808 0.042 Uiso 1 1 calc R . .
C28 C 1.1481(3) 0.56669(7) 0.61488(12) 0.0249(5) Uani 1 1 d . . .
C29 C 1.1509(3) 0.57585(8) 0.54728(13) 0.0315(6) Uani 1 1 d . . .
H29A H 1.0681 0.5755 0.5129 0.038 Uiso 1 1 calc R . .
C30 C 1.2739(3) 0.58553(9) 0.52980(15) 0.0385(6) Uani 1 1 d . . .
H30A H 1.2744 0.5925 0.4836 0.046 Uiso 1 1 calc R . .
C31 C 1.3954(3) 0.58517(10) 0.57869(16) 0.0424(7) Uani 1 1 d . . .
H31A H 1.4795 0.5917 0.5663 0.051 Uiso 1 1 calc R . .
C32 C 1.3941(3) 0.57523(11) 0.64625(16) 0.0461(7) Uani 1 1 d . . .
H32A H 1.4775 0.5741 0.6801 0.055 Uiso 1 1 calc R . .
C33 C 1.2709(3) 0.56697(10) 0.66392(14) 0.0364(6) Uani 1 1 d . . .
H33A H 1.2702 0.5614 0.7104 0.044 Uiso 1 1 calc R . .
C34 C 0.5000 0.43500(13) 0.7500 0.0402(10) Uani 1 2 d SD . .
S1 S 0.5000 0.37232(3) 0.7500 0.0308(2) Uani 1 2 d S . .
F1 F 0.4546(4) 0.44859(12) 0.81154(19) 0.0560(10) Uani 0.50 1 d PD . .
F2 F 0.6204(4) 0.45541(15) 0.7620(3) 0.0515(12) Uani 0.50 1 d PD . .
O1 O 0.6054(4) 0.35941(13) 0.8140(2) 0.0459(10) Uani 0.50 1 d P . .
O2 O 0.3724(4) 0.35755(14) 0.7483(3) 0.0519(12) Uani 0.50 1 d P . .
O3 O 0.4398(5) 0.36626(14) 0.8089(2) 0.0502(11) Uani 0.50 1 d P A -1
F3 F 0.5871(5) 0.45336(15) 0.7972(3) 0.0593(13) Uani 0.50 1 d PD B -1

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ag1 0.02196(14) 0.01314(13) 0.02757(15) 0.000 0.00290(9) 0.000
P1 0.0255(3) 0.0137(3) 0.0243(3) -0.0003(2) 0.0031(2) -0.0003(2)
N1 0.0248(11) 0.0196(10) 0.0384(12) 0.0018(9) 0.0058(9) 0.0064(8)
N2 0.0315(13) 0.0281(12) 0.0684(18) 0.0084(11) -0.0123(12) -0.0062(10)
N3 0.0238(10) 0.0165(9) 0.0300(11) 0.0005(8) 0.0031(8) 0.0007(8)
C1 0.0218(12) 0.0182(11) 0.0278(13) 0.0014(9) 0.0019(10) -0.0010(9)
C2 0.0230(12) 0.0173(11) 0.0299(13) 0.0026(9) 0.0032(10) 0.0019(9)
C3 0.0242(12) 0.0164(11) 0.0240(12) -0.0002(9) 0.0049(9) 0.0002(9)
C4 0.0208(11) 0.0172(11) 0.0266(13) -0.0012(9) 0.0008(9) -0.0006(9)
C5 0.0223(12) 0.0177(11) 0.0261(12) 0.0001(9) 0.0036(10) 0.0011(9)
C6 0.0217(11) 0.0152(10) 0.0214(12) 0.0001(9) -0.0009(9) -0.0001(8)
C7 0.0216(11) 0.0195(11) 0.0270(12) 0.0003(9) 0.0042(10) -0.0002(9)
C8 0.0239(12) 0.0173(11) 0.0260(12) -0.0023(9) 0.0042(10) 0.0024(9)
C9 0.0248(12) 0.0158(10) 0.0211(11) -0.0006(9) -0.0005(9) -0.0018(9)
C10 0.0217(11) 0.0203(11) 0.0244(12) -0.0012(9) 0.0039(9) -0.0019(9)
C11 0.0204(11) 0.0173(11) 0.0278(12) -0.0010(9) 0.0035(10) 0.0027(9)
C12 0.0235(12) 0.0190(11) 0.0317(13) 0.0066(10) -0.0010(10) -0.0020(9)
C13 0.0247(13) 0.0188(12) 0.0587(18) 0.0045(11) -0.0010(12) 0.0000(10)
C14 0.0243(14) 0.0232(13) 0.082(2) 0.0098(14) -0.0028(14) 0.0012(10)
C15 0.0375(15) 0.0280(13) 0.0417(16) 0.0004(11) 0.0000(12) -0.0084(11)
C16 0.0284(13) 0.0250(12) 0.0340(14) 0.0011(10) 0.0027(11) -0.0058(10)
C17 0.0226(12) 0.0181(11) 0.0289(13) 0.0011(9) 0.0057(10) 0.0012(9)
C18 0.0246(13) 0.0205(12) 0.0533(17) -0.0043(11) -0.0037(12) 0.0017(10)
C19 0.0281(13) 0.0167(12) 0.0582(18) -0.0044(11) 0.0018(12) -0.0005(10)
C20 0.0269(12) 0.0256(12) 0.0323(14) -0.0053(10) -0.0007(10) 0.0059(10)
C21 0.0282(12) 0.0181(11) 0.0318(13) -0.0053(10) 0.0023(10) 0.0020(9)
C22 0.0277(13) 0.0228(12) 0.0273(13) 0.0017(10) 0.0059(10) 0.0012(10)
C23 0.0367(14) 0.0261(12) 0.0297(14) -0.0024(10) 0.0007(11) 0.0021(10)
C24 0.0360(15) 0.0434(16) 0.0299(14) -0.0032(12) 0.0013(12) -0.0005(12)
C25 0.0306(14) 0.0511(17) 0.0303(14) 0.0112(12) 0.0034(11) 0.0071(12)
C26 0.0404(16) 0.0338(14) 0.0472(18) 0.0182(13) 0.0060(13) 0.0070(12)
C27 0.0352(14) 0.0246(12) 0.0422(16) 0.0089(11) 0.0042(12) -0.0002(11)
C28 0.0320(13) 0.0127(10) 0.0298(13) -0.0016(9) 0.0071(11) -0.0031(9)
C29 0.0402(15) 0.0232(12) 0.0316(14) 0.0012(10) 0.0090(12) -0.0008(11)
C30 0.0557(18) 0.0278(13) 0.0375(16) 0.0011(11) 0.0217(14) -0.0040(12)
C31 0.0435(17) 0.0363(15) 0.0543(19) -0.0110(13) 0.0252(15) -0.0153(13)
C32 0.0326(15) 0.0611(19) 0.0450(18) -0.0131(15) 0.0094(13) -0.0166(14)
C33 0.0337(14) 0.0431(15) 0.0316(15) -0.0032(12) 0.0058(12) -0.0106(12)
C34 0.0224(19) 0.034(2) 0.061(3) 0.000 0.0038(19) 0.000
S1 0.0341(5) 0.0257(4) 0.0326(5) 0.000 0.0074(4) 0.000
F1 0.071(3) 0.0447(19) 0.060(2) -0.0163(17) 0.030(2) 0.0064(18)
F2 0.037(2) 0.035(2) 0.083(4) -0.006(2) 0.017(2) -0.0094(15)
O1 0.047(2) 0.036(2) 0.045(2) 0.0041(18) -0.0088(19) 0.0011(18)
O2 0.028(2) 0.037(2) 0.091(4) -0.004(2) 0.014(2) -0.0100(16)
O3 0.070(3) 0.043(2) 0.043(3) 0.0067(19) 0.025(2) -0.006(2)
F3 0.063(4) 0.036(2) 0.060(3) -0.011(2) -0.023(2) -0.008(2)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.3870(19) 4_756 ?
Ag1 N1 2.3870(19) 3_455 ?
Ag1 P1 2.4667(6) . ?
Ag1 P1 2.4667(6) 2_756 ?
P1 C28 1.824(3) . ?
P1 C9 1.828(2) . ?
P1 C22 1.829(2) . ?
N1 C19 1.339(3) . ?
N1 C20 1.340(3) . ?
N1 Ag1 2.3870(19) 3_545 ?
N2 C15 1.335(4) . ?
N2 C14 1.337(4) . ?
N3 C1 1.341(3) . ?
N3 C5 1.344(3) . ?
C1 C2 1.387(3) . ?
C1 C12 1.490(3) . ?
C2 C3 1.394(3) . ?
C2 H2A 0.9500 . ?
C3 C4 1.399(3) . ?
C3 C6 1.487(3) . ?
C4 C5 1.397(3) . ?
C4 H4A 0.9500 . ?
C5 C17 1.490(3) . ?
C6 C11 1.390(3) . ?
C6 C7 1.397(3) . ?
C7 C8 1.385(3) . ?
C7 H7A 0.9500 . ?
C8 C9 1.397(3) . ?
C8 H8A 0.9500 . ?
C9 C10 1.386(3) . ?
C10 C11 1.391(3) . ?
C10 H10A 0.9500 . ?
C11 H11A 0.9500 . ?
C12 C13 1.390(4) . ?
C12 C16 1.391(4) . ?
C13 C14 1.390(4) . ?
C13 H13A 0.9500 . ?
C14 H14A 0.9500 . ?
C15 C16 1.380(4) . ?
C15 H15A 0.9500 . ?
C16 H16A 0.9500 . ?
C17 C21 1.385(3) . ?
C17 C18 1.388(3) . ?
C18 C19 1.377(4) . ?
C18 H18A 0.9500 . ?
C19 H19A 0.9500 . ?
C20 C21 1.381(3) . ?
C20 H20A 0.9500 . ?
C21 H21A 0.9500 . ?
C22 C23 1.385(4) . ?
C22 C27 1.391(4) . ?
C23 C24 1.391(4) . ?
C23 H23A 0.9500 . ?
C24 C25 1.385(4) . ?
C24 H24A 0.9500 . ?
C25 C26 1.375(4) . ?
C25 H25A 0.9500 . ?
C26 C27 1.391(4) . ?
C26 H26A 0.9500 . ?
C27 H27A 0.9500 . ?
C28 C33 1.389(4) . ?
C28 C29 1.390(4) . ?
C29 C30 1.385(4) . ?
C29 H29A 0.9500 . ?
C30 C31 1.378(4) . ?
C30 H30A 0.9500 . ?
C31 C32 1.390(4) . ?
C31 H31A 0.9500 . ?
C32 C33 1.381(4) . ?
C32 H32A 0.9500 . ?
C33 H33A 0.9500 . ?
C34 F3 1.250(4) . ?
C34 F3 1.250(4) 2_656 ?
C34 F2 1.314(4) . ?
C34 F2 1.314(4) 2_656 ?
C34 F1 1.465(3) . ?
C34 F1 1.465(3) 2_656 ?
C34 S1 1.806(4) . ?
S1 O2 1.341(4) . ?
S1 O2 1.341(4) 2_656 ?
S1 O3 1.456(4) . ?
S1 O3 1.456(4) 2_656 ?
S1 O1 1.511(4) . ?
S1 O1 1.511(4) 2_656 ?
F1 F3 1.428(7) . ?
F1 F2 1.509(7) 2_656 ?
F2 F3 0.851(5) . ?
F2 F1 1.509(7) 2_656 ?
O1 O2 1.321(7) 2_656 ?
O1 O3 1.652(7) . ?
O2 O3 1.273(7) . ?
O2 O1 1.321(7) 2_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N1 90.47(10) 4_756 3_455 ?
N1 Ag1 P1 111.11(5) 4_756 . ?
N1 Ag1 P1 111.72(5) 3_455 . ?
N1 Ag1 P1 111.72(5) 4_756 2_756 ?
N1 Ag1 P1 111.11(5) 3_455 2_756 ?
P1 Ag1 P1 117.53(3) . 2_756 ?
C28 P1 C9 104.08(11) . . ?
C28 P1 C22 105.39(11) . . ?
C9 P1 C22 102.93(10) . . ?
C28 P1 Ag1 108.60(8) . . ?
C9 P1 Ag1 116.59(8) . . ?
C22 P1 Ag1 117.89(8) . . ?
C19 N1 C20 115.7(2) . . ?
C19 N1 Ag1 118.17(16) . 3_545 ?
C20 N1 Ag1 124.77(16) . 3_545 ?
C15 N2 C14 116.6(2) . . ?
C1 N3 C5 117.98(19) . . ?
N3 C1 C2 122.7(2) . . ?
N3 C1 C12 115.76(19) . . ?
C2 C1 C12 121.5(2) . . ?
C1 C2 C3 119.6(2) . . ?
C1 C2 H2A 120.2 . . ?
C3 C2 H2A 120.2 . . ?
C2 C3 C4 117.9(2) . . ?
C2 C3 C6 119.4(2) . . ?
C4 C3 C6 122.6(2) . . ?
C5 C4 C3 118.7(2) . . ?
C5 C4 H4A 120.7 . . ?
C3 C4 H4A 120.7 . . ?
N3 C5 C4 122.9(2) . . ?
N3 C5 C17 114.28(19) . . ?
C4 C5 C17 122.8(2) . . ?
C11 C6 C7 119.0(2) . . ?
C11 C6 C3 120.5(2) . . ?
C7 C6 C3 120.4(2) . . ?
C8 C7 C6 120.4(2) . . ?
C8 C7 H7A 119.8 . . ?
C6 C7 H7A 119.8 . . ?
C7 C8 C9 120.5(2) . . ?
C7 C8 H8A 119.7 . . ?
C9 C8 H8A 119.7 . . ?
C10 C9 C8 118.9(2) . . ?
C10 C9 P1 123.10(18) . . ?
C8 C9 P1 118.00(17) . . ?
C9 C10 C11 120.7(2) . . ?
C9 C10 H10A 119.7 . . ?
C11 C10 H10A 119.7 . . ?
C6 C11 C10 120.4(2) . . ?
C6 C11 H11A 119.8 . . ?
C10 C11 H11A 119.8 . . ?
C13 C12 C16 117.8(2) . . ?
C13 C12 C1 121.8(2) . . ?
C16 C12 C1 120.4(2) . . ?
C12 C13 C14 118.8(3) . . ?
C12 C13 H13A 120.6 . . ?
C14 C13 H13A 120.6 . . ?
N2 C14 C13 123.6(3) . . ?
N2 C14 H14A 118.2 . . ?
C13 C14 H14A 118.2 . . ?
N2 C15 C16 124.2(3) . . ?
N2 C15 H15A 117.9 . . ?
C16 C15 H15A 117.9 . . ?
C15 C16 C12 118.8(2) . . ?
C15 C16 H16A 120.6 . . ?
C12 C16 H16A 120.6 . . ?
C21 C17 C18 116.8(2) . . ?
C21 C17 C5 123.2(2) . . ?
C18 C17 C5 119.8(2) . . ?
C19 C18 C17 119.8(2) . . ?
C19 C18 H18A 120.1 . . ?
C17 C18 H18A 120.1 . . ?
N1 C19 C18 124.0(2) . . ?
N1 C19 H19A 118.0 . . ?
C18 C19 H19A 118.0 . . ?
N1 C20 C21 124.2(2) . . ?
N1 C20 H20A 117.9 . . ?
C21 C20 H20A 117.9 . . ?
C20 C21 C17 119.4(2) . . ?
C20 C21 H21A 120.3 . . ?
C17 C21 H21A 120.3 . . ?
C23 C22 C27 118.8(2) . . ?
C23 C22 P1 123.94(18) . . ?
C27 C22 P1 117.26(19) . . ?
C22 C23 C24 120.6(2) . . ?
C22 C23 H23A 119.7 . . ?
C24 C23 H23A 119.7 . . ?
C25 C24 C23 120.2(3) . . ?
C25 C24 H24A 119.9 . . ?
C23 C24 H24A 119.9 . . ?
C26 C25 C24 119.7(2) . . ?
C26 C25 H25A 120.2 . . ?
C24 C25 H25A 120.2 . . ?
C25 C26 C27 120.3(2) . . ?
C25 C26 H26A 119.9 . . ?
C27 C26 H26A 119.9 . . ?
C22 C27 C26 120.5(3) . . ?
C22 C27 H27A 119.7 . . ?
C26 C27 H27A 119.7 . . ?
C33 C28 C29 118.5(2) . . ?
C33 C28 P1 117.22(19) . . ?
C29 C28 P1 124.24(19) . . ?
C30 C29 C28 120.3(3) . . ?
C30 C29 H29A 119.8 . . ?
C28 C29 H29A 119.8 . . ?
C31 C30 C29 120.7(3) . . ?
C31 C30 H30A 119.6 . . ?
C29 C30 H30A 119.6 . . ?
C30 C31 C32 119.4(3) . . ?
C30 C31 H31A 120.3 . . ?
C32 C31 H31A 120.3 . . ?
C33 C32 C31 119.7(3) . . ?
C33 C32 H32A 120.1 . . ?
C31 C32 H32A 120.1 . . ?
C32 C33 C28 121.2(3) . . ?
C32 C33 H33A 119.4 . . ?
C28 C33 H33A 119.4 . . ?
F3 C34 F3 129.9(5) . 2_656 ?
F3 C34 F2 38.7(2) . . ?
F3 C34 F2 113.7(3) 2_656 . ?
F3 C34 F2 113.7(3) . 2_656 ?
F3 C34 F2 38.7(2) 2_656 2_656 ?
F2 C34 F2 126.8(5) . 2_656 ?
F3 C34 F1 62.9(3) . . ?
F3 C34 F1 103.3(3) 2_656 . ?
F2 C34 F1 100.1(3) . . ?
F2 C34 F1 65.5(3) 2_656 . ?
F3 C34 F1 103.3(3) . 2_656 ?
F3 C34 F1 62.9(3) 2_656 2_656 ?
F2 C34 F1 65.5(3) . 2_656 ?
F2 C34 F1 100.1(3) 2_656 2_656 ?
F1 C34 F1 149.0(4) . 2_656 ?
F3 C34 S1 115.1(3) . . ?
F3 C34 S1 115.1(3) 2_656 . ?
F2 C34 S1 116.6(2) . . ?
F2 C34 S1 116.6(2) 2_656 . ?
F1 C34 S1 105.5(2) . . ?
F1 C34 S1 105.5(2) 2_656 . ?
O2 S1 O2 143.0(4) . 2_656 ?
O2 S1 O3 53.9(3) . . ?
O2 S1 O3 120.8(3) 2_656 . ?
O2 S1 O3 120.8(3) . 2_656 ?
O2 S1 O3 53.9(3) 2_656 2_656 ?
O3 S1 O3 166.2(3) . 2_656 ?
O2 S1 O1 114.8(3) . . ?
O2 S1 O1 54.8(3) 2_656 . ?
O3 S1 O1 67.6(3) . . ?
O3 S1 O1 108.7(3) 2_656 . ?
O2 S1 O1 54.8(3) . 2_656 ?
O2 S1 O1 114.8(3) 2_656 2_656 ?
O3 S1 O1 108.7(3) . 2_656 ?
O3 S1 O1 67.6(3) 2_656 2_656 ?
O1 S1 O1 151.5(3) . 2_656 ?
O2 S1 C34 108.50(18) . . ?
O2 S1 C34 108.50(18) 2_656 . ?
O3 S1 C34 96.88(17) . . ?
O3 S1 C34 96.88(17) 2_656 . ?
O1 S1 C34 104.26(15) . . ?
O1 S1 C34 104.26(15) 2_656 . ?
F3 F1 C34 51.2(2) . . ?
F3 F1 F2 93.9(3) . 2_656 ?
C34 F1 F2 52.4(2) . 2_656 ?
F3 F2 C34 66.6(4) . . ?
F3 F2 F1 127.0(6) . 2_656 ?
C34 F2 F1 62.1(3) . 2_656 ?
O2 O1 S1 56.1(2) 2_656 . ?
O2 O1 O3 109.4(3) 2_656 . ?
S1 O1 O3 54.6(2) . . ?
O3 O2 O1 136.8(4) . 2_656 ?
O3 O2 S1 67.7(3) . . ?
O1 O2 S1 69.1(3) 2_656 . ?
O2 O3 S1 58.4(3) . . ?
O2 O3 O1 109.9(4) . . ?
S1 O3 O1 57.7(2) . . ?
F2 F3 C34 74.8(5) . . ?
F2 F3 F1 137.3(6) . . ?
C34 F3 F1 66.0(3) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ag1 P1 C28 14.27(10) 4_756 . . . ?
N1 Ag1 P1 C28 113.67(9) 3_455 . . . ?
P1 Ag1 P1 C28 -116.17(8) 2_756 . . . ?
N1 Ag1 P1 C9 131.36(10) 4_756 . . . ?
N1 Ag1 P1 C9 -129.24(10) 3_455 . . . ?
P1 Ag1 P1 C9 0.92(8) 2_756 . . . ?
N1 Ag1 P1 C22 -105.41(10) 4_756 . . . ?
N1 Ag1 P1 C22 -6.01(11) 3_455 . . . ?
P1 Ag1 P1 C22 124.15(9) 2_756 . . . ?
C5 N3 C1 C2 0.6(4) . . . . ?
C5 N3 C1 C12 179.4(2) . . . . ?
N3 C1 C2 C3 3.1(4) . . . . ?
C12 C1 C2 C3 -175.5(2) . . . . ?
C1 C2 C3 C4 -3.5(3) . . . . ?
C1 C2 C3 C6 174.2(2) . . . . ?
C2 C3 C4 C5 0.4(3) . . . . ?
C6 C3 C4 C5 -177.3(2) . . . . ?
C1 N3 C5 C4 -4.0(4) . . . . ?
C1 N3 C5 C17 174.6(2) . . . . ?
C3 C4 C5 N3 3.5(4) . . . . ?
C3 C4 C5 C17 -175.0(2) . . . . ?
C2 C3 C6 C11 -137.2(2) . . . . ?
C4 C3 C6 C11 40.4(3) . . . . ?
C2 C3 C6 C7 39.3(3) . . . . ?
C4 C3 C6 C7 -143.1(2) . . . . ?
C11 C6 C7 C8 1.2(3) . . . . ?
C3 C6 C7 C8 -175.3(2) . . . . ?
C6 C7 C8 C9 2.2(3) . . . . ?
C7 C8 C9 C10 -3.5(3) . . . . ?
C7 C8 C9 P1 174.85(17) . . . . ?
C28 P1 C9 C10 -3.0(2) . . . . ?
C22 P1 C9 C10 106.8(2) . . . . ?
Ag1 P1 C9 C10 -122.56(18) . . . . ?
C28 P1 C9 C8 178.70(18) . . . . ?
C22 P1 C9 C8 -71.5(2) . . . . ?
Ag1 P1 C9 C8 59.14(19) . . . . ?
C8 C9 C10 C11 1.6(3) . . . . ?
P1 C9 C10 C11 -176.73(17) . . . . ?
C7 C6 C11 C10 -3.2(3) . . . . ?
C3 C6 C11 C10 173.4(2) . . . . ?
C9 C10 C11 C6 1.8(3) . . . . ?
N3 C1 C12 C13 151.7(2) . . . . ?
C2 C1 C12 C13 -29.6(4) . . . . ?
N3 C1 C12 C16 -28.0(3) . . . . ?
C2 C1 C12 C16 150.7(2) . . . . ?
C16 C12 C13 C14 -0.2(4) . . . . ?
C1 C12 C13 C14 -179.9(3) . . . . ?
C15 N2 C14 C13 2.3(5) . . . . ?
C12 C13 C14 N2 -2.3(5) . . . . ?
C14 N2 C15 C16 0.3(4) . . . . ?
N2 C15 C16 C12 -2.7(4) . . . . ?
C13 C12 C16 C15 2.5(4) . . . . ?
C1 C12 C16 C15 -177.7(2) . . . . ?
N3 C5 C17 C21 -158.8(2) . . . . ?
C4 C5 C17 C21 19.8(4) . . . . ?
N3 C5 C17 C18 17.1(3) . . . . ?
C4 C5 C17 C18 -164.3(3) . . . . ?
C21 C17 C18 C19 -1.4(4) . . . . ?
C5 C17 C18 C19 -177.6(3) . . . . ?
C20 N1 C19 C18 0.1(4) . . . . ?
Ag1 N1 C19 C18 -167.1(2) 3_545 . . . ?
C17 C18 C19 N1 1.8(5) . . . . ?
C19 N1 C20 C21 -2.4(4) . . . . ?
Ag1 N1 C20 C21 163.9(2) 3_545 . . . ?
N1 C20 C21 C17 2.7(4) . . . . ?
C18 C17 C21 C20 -0.7(4) . . . . ?
C5 C17 C21 C20 175.4(2) . . . . ?
C28 P1 C22 C23 106.4(2) . . . . ?
C9 P1 C22 C23 -2.4(3) . . . . ?
Ag1 P1 C22 C23 -132.2(2) . . . . ?
C28 P1 C22 C27 -75.4(2) . . . . ?
C9 P1 C22 C27 175.8(2) . . . . ?
Ag1 P1 C22 C27 45.9(2) . . . . ?
C27 C22 C23 C24 0.3(4) . . . . ?
P1 C22 C23 C24 178.4(2) . . . . ?
C22 C23 C24 C25 0.9(4) . . . . ?
C23 C24 C25 C26 -0.9(4) . . . . ?
C24 C25 C26 C27 -0.3(5) . . . . ?
C23 C22 C27 C26 -1.6(4) . . . . ?
P1 C22 C27 C26 -179.8(2) . . . . ?
C25 C26 C27 C22 1.6(4) . . . . ?
C9 P1 C28 C33 -80.9(2) . . . . ?
C22 P1 C28 C33 171.15(19) . . . . ?
Ag1 P1 C28 C33 43.9(2) . . . . ?
C9 P1 C28 C29 99.5(2) . . . . ?
C22 P1 C28 C29 -8.4(2) . . . . ?
Ag1 P1 C28 C29 -135.64(18) . . . . ?
C33 C28 C29 C30 -0.7(4) . . . . ?
P1 C28 C29 C30 178.88(19) . . . . ?
C28 C29 C30 C31 1.5(4) . . . . ?
C29 C30 C31 C32 -0.4(4) . . . . ?
C30 C31 C32 C33 -1.6(5) . . . . ?
C31 C32 C33 C28 2.4(5) . . . . ?
C29 C28 C33 C32 -1.3(4) . . . . ?
P1 C28 C33 C32 179.1(2) . . . . ?
F3 C34 S1 O2 126.8(4) . . . . ?
F3 C34 S1 O2 -53.2(4) 2_656 . . . ?
F2 C34 S1 O2 170.0(4) . . . . ?
F2 C34 S1 O2 -10.0(4) 2_656 . . . ?
F1 C34 S1 O2 59.9(3) . . . . ?
F1 C34 S1 O2 -120.1(3) 2_656 . . . ?
F3 C34 S1 O2 -53.2(4) . . . 2_656 ?
F3 C34 S1 O2 126.8(4) 2_656 . . 2_656 ?
F2 C34 S1 O2 -10.0(4) . . . 2_656 ?
F2 C34 S1 O2 170.0(4) 2_656 . . 2_656 ?
F1 C34 S1 O2 -120.1(3) . . . 2_656 ?
F1 C34 S1 O2 59.9(3) 2_656 . . 2_656 ?
F3 C34 S1 O3 72.6(4) . . . . ?
F3 C34 S1 O3 -107.4(4) 2_656 . . . ?
F2 C34 S1 O3 115.7(3) . . . . ?
F2 C34 S1 O3 -64.3(3) 2_656 . . . ?
F1 C34 S1 O3 5.7(3) . . . . ?
F1 C34 S1 O3 -174.3(3) 2_656 . . . ?
F3 C34 S1 O3 -107.4(4) . . . 2_656 ?
F3 C34 S1 O3 72.6(4) 2_656 . . 2_656 ?
F2 C34 S1 O3 -64.3(3) . . . 2_656 ?
F2 C34 S1 O3 115.7(3) 2_656 . . 2_656 ?
F1 C34 S1 O3 -174.3(3) . . . 2_656 ?
F1 C34 S1 O3 5.7(3) 2_656 . . 2_656 ?
F3 C34 S1 O1 4.0(4) . . . . ?
F3 C34 S1 O1 -176.0(4) 2_656 . . . ?
F2 C34 S1 O1 47.1(3) . . . . ?
F2 C34 S1 O1 -132.9(3) 2_656 . . . ?
F1 C34 S1 O1 -62.9(3) . . . . ?
F1 C34 S1 O1 117.1(3) 2_656 . . . ?
F3 C34 S1 O1 -176.0(4) . . . 2_656 ?
F3 C34 S1 O1 4.0(4) 2_656 . . 2_656 ?
F2 C34 S1 O1 -132.9(3) . . . 2_656 ?
F2 C34 S1 O1 47.1(3) 2_656 . . 2_656 ?
F1 C34 S1 O1 117.1(3) . . . 2_656 ?
F1 C34 S1 O1 -62.9(3) 2_656 . . 2_656 ?
F3 C34 F1 F3 -128.3(5) 2_656 . . . ?
F2 C34 F1 F3 -10.8(4) . . . . ?
F2 C34 F1 F3 -136.8(3) 2_656 . . . ?
F1 C34 F1 F3 -69.4(3) 2_656 . . . ?
S1 C34 F1 F3 110.6(3) . . . . ?
F3 C34 F1 F2 136.8(3) . . . 2_656 ?
F3 C34 F1 F2 8.5(4) 2_656 . . 2_656 ?
F2 C34 F1 F2 126.0(5) . . . 2_656 ?
F1 C34 F1 F2 67.4(2) 2_656 . . 2_656 ?
S1 C34 F1 F2 -112.6(2) . . . 2_656 ?
F3 C34 F2 F3 124.9(6) 2_656 . . . ?
F2 C34 F2 F3 82.4(5) 2_656 . . . ?
F1 C34 F2 F3 15.5(6) . . . . ?
F1 C34 F2 F3 166.6(6) 2_656 . . . ?
S1 C34 F2 F3 -97.6(5) . . . . ?
F3 C34 F2 F1 -166.6(6) . . . 2_656 ?
F3 C34 F2 F1 -41.7(3) 2_656 . . 2_656 ?
F2 C34 F2 F1 -84.2(2) 2_656 . . 2_656 ?
F1 C34 F2 F1 -151.1(4) . . . 2_656 ?
S1 C34 F2 F1 95.8(2) . . . 2_656 ?
O2 S1 O1 O2 138.6(4) . . . 2_656 ?
O3 S1 O1 O2 165.5(3) . . . 2_656 ?
O3 S1 O1 O2 -0.3(3) 2_656 . . 2_656 ?
O1 S1 O1 O2 77.2(2) 2_656 . . 2_656 ?
C34 S1 O1 O2 -102.8(2) . . . 2_656 ?
O2 S1 O1 O3 -26.9(3) . . . . ?
O2 S1 O1 O3 -165.5(3) 2_656 . . . ?
O3 S1 O1 O3 -165.8(3) 2_656 . . . ?
O1 S1 O1 O3 -88.3(2) 2_656 . . . ?
C34 S1 O1 O3 91.7(2) . . . . ?
O2 S1 O2 O3 95.0(3) 2_656 . . . ?
O3 S1 O2 O3 164.7(4) 2_656 . . . ?
O1 S1 O2 O3 31.2(3) . . . . ?
O1 S1 O2 O3 -179.7(4) 2_656 . . . ?
C34 S1 O2 O3 -85.0(3) . . . . ?
O2 S1 O2 O1 -85.3(2) 2_656 . . 2_656 ?
O3 S1 O2 O1 179.7(4) . . . 2_656 ?
O3 S1 O2 O1 -15.6(4) 2_656 . . 2_656 ?
O1 S1 O2 O1 -149.1(3) . . . 2_656 ?
C34 S1 O2 O1 94.7(2) . . . 2_656 ?
O1 O2 O3 S1 -0.4(5) 2_656 . . . ?
O1 O2 O3 O1 -27.6(7) 2_656 . . . ?
S1 O2 O3 O1 -27.2(3) . . . . ?
O2 S1 O3 O2 -135.7(4) 2_656 . . . ?
O3 S1 O3 O2 -72.1(3) 2_656 . . . ?
O1 S1 O3 O2 -149.5(3) . . . . ?
O1 S1 O3 O2 0.3(3) 2_656 . . . ?
C34 S1 O3 O2 107.9(2) . . . . ?
O2 S1 O3 O1 149.5(3) . . . . ?
O2 S1 O3 O1 13.7(3) 2_656 . . . ?
O3 S1 O3 O1 77.37(18) 2_656 . . . ?
O1 S1 O3 O1 149.7(3) 2_656 . . . ?
C34 S1 O3 O1 -102.63(18) . . . . ?
O2 O1 O3 O2 14.7(4) 2_656 . . . ?
S1 O1 O3 O2 27.4(3) . . . . ?
O2 O1 O3 S1 -12.7(3) 2_656 . . . ?
F1 F2 F3 C34 14.8(7) 2_656 . . . ?
C34 F2 F3 F1 -23.5(8) . . . . ?
F1 F2 F3 F1 -8.6(14) 2_656 . . . ?
F3 C34 F3 F2 -78.1(5) 2_656 . . . ?
F2 C34 F3 F2 -120.0(6) 2_656 . . . ?
F1 C34 F3 F2 -162.8(6) . . . . ?
F1 C34 F3 F2 -12.5(6) 2_656 . . . ?
S1 C34 F3 F2 101.9(5) . . . . ?
F3 C34 F3 F1 84.7(2) 2_656 . . . ?
F2 C34 F3 F1 162.8(6) . . . . ?
F2 C34 F3 F1 42.8(3) 2_656 . . . ?
F1 C34 F3 F1 150.3(4) 2_656 . . . ?
S1 C34 F3 F1 -95.3(2) . . . . ?
C34 F1 F3 F2 24.9(9) . . . . ?
F2 F1 F3 F2 -8.0(9) 2_656 . . . ?
F2 F1 F3 C34 -32.9(3) 2_656 . . . ?

_diffrn_measured_fraction_theta_max 0.994
_diffrn_reflns_theta_full        62.51
_diffrn_measured_fraction_theta_full 0.994
_refine_diff_density_max         0.398
_refine_diff_density_min         -0.464
_refine_diff_density_rms         0.057

#=======================================#

data_Ag-BF4
_database_code_depnum_ccdc_archive 'CCDC 857927'
#TrackingRef '- cifs.cif'

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C66 H48 Ag B F4 N6 O2 P2'
_chemical_formula_weight         1213.72

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   10.2064(2)
_cell_length_b                   28.9067(4)
_cell_length_c                   20.2929(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 105.763(2)
_cell_angle_gamma                90.00
_cell_volume                     5761.9(2)
_cell_formula_units_Z            4
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    4087
_cell_measurement_theta_min      3.8016
_cell_measurement_theta_max      62.4421

_exptl_crystal_description       block
_exptl_crystal_colour            colourless
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.399
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2480
_exptl_absorpt_coefficient_mu    3.860
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.5123
_exptl_absorpt_correction_T_max  0.5123
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     1.54178
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            8220
_diffrn_reflns_av_R_equivalents  0.0323
_diffrn_reflns_av_sigmaI/netI    0.0435
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_theta_min         3.80
_diffrn_reflns_theta_max         62.53
_reflns_number_total             4465
_reflns_number_gt                3945
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0817P)^2^+3.9284P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         4465
_refine_ls_number_parameters     367
_refine_ls_number_restraints     1
_refine_ls_R_factor_all          0.0523
_refine_ls_R_factor_gt           0.0459
_refine_ls_wR_factor_ref         0.1273
_refine_ls_wR_factor_gt          0.1201
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_restrained_S_all      1.027
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.5000 -0.100284(11) 0.7500 0.03979(16) Uani 1 2 d SU . .
P1 P 0.48933(9) -0.05653(3) 0.64317(5) 0.0394(2) Uani 1 1 d U . .
N1 N 0.8283(3) 0.34011(11) 0.72740(18) 0.0492(8) Uani 1 1 d . . .
N2 N -0.0839(4) 0.28166(14) 0.5217(3) 0.0831(14) Uani 1 1 d . . .
N3 N 0.4077(3) 0.24920(10) 0.63424(16) 0.0418(7) Uani 1 1 d . . .
C1 C 0.5325(3) 0.23231(12) 0.66241(18) 0.0394(8) Uani 1 1 d . . .
C2 C 0.5588(3) 0.18525(12) 0.67148(18) 0.0406(8) Uani 1 1 d . . .
H2B H 0.6473 0.1747 0.6896 0.049 Uiso 1 1 calc R . .
C3 C 0.4510(4) 0.15418(12) 0.65305(18) 0.0385(7) Uani 1 1 d . . .
C4 C 0.3214(3) 0.17223(12) 0.62621(19) 0.0401(8) Uani 1 1 d . . .
H4A H 0.2465 0.1526 0.6147 0.048 Uiso 1 1 calc R . .
C5 C 0.3034(3) 0.21961(12) 0.61650(18) 0.0395(8) Uani 1 1 d . . .
C6 C 0.4705(3) 0.10296(12) 0.65687(18) 0.0372(8) Uani 1 1 d . . .
C7 C 0.3751(3) 0.07455(12) 0.67503(18) 0.0399(8) Uani 1 1 d . . .
H7A H 0.3030 0.0877 0.6882 0.048 Uiso 1 1 calc R . .
C8 C 0.3876(4) 0.02710(12) 0.67346(18) 0.0401(8) Uani 1 1 d . . .
H8A H 0.3255 0.0085 0.6872 0.048 Uiso 1 1 calc R . .
C9 C 0.4921(3) 0.00663(12) 0.65163(17) 0.0377(7) Uani 1 1 d . . .
C10 C 0.5885(4) 0.03453(13) 0.63608(19) 0.0434(8) Uani 1 1 d . . .
H10A H 0.6607 0.0212 0.6232 0.052 Uiso 1 1 calc R . .
C11 C 0.5795(4) 0.08252(13) 0.63935(19) 0.0434(8) Uani 1 1 d . . .
H11A H 0.6468 0.1009 0.6298 0.052 Uiso 1 1 calc R . .
C12 C 0.6395(4) 0.26854(12) 0.68414(19) 0.0412(8) Uani 1 1 d . . .
C13 C 0.6207(4) 0.31168(14) 0.6540(3) 0.0590(11) Uani 1 1 d . . .
H13A H 0.5437 0.3177 0.6182 0.071 Uiso 1 1 calc R . .
C14 C 0.7161(4) 0.34574(14) 0.6769(3) 0.0616(12) Uani 1 1 d . . .
H14A H 0.7009 0.3745 0.6556 0.074 Uiso 1 1 calc R . .
C15 C 0.8470(4) 0.29842(15) 0.7565(2) 0.0534(10) Uani 1 1 d . . .
H15A H 0.9246 0.2935 0.7924 0.064 Uiso 1 1 calc R . .
C16 C 0.7571(4) 0.26209(14) 0.7362(2) 0.0505(9) Uani 1 1 d . . .
H16A H 0.7757 0.2334 0.7576 0.061 Uiso 1 1 calc R . .
C17 C 0.1682(4) 0.24058(13) 0.58416(19) 0.0431(8) Uani 1 1 d . . .
C18 C 0.0473(4) 0.22016(16) 0.5883(3) 0.0683(14) Uani 1 1 d . . .
H18A H 0.0478 0.1924 0.6115 0.082 Uiso 1 1 calc R . .
C19 C -0.0739(5) 0.24241(18) 0.5570(4) 0.0877(19) Uani 1 1 d . . .
H19A H -0.1541 0.2289 0.5609 0.105 Uiso 1 1 calc R . .
C20 C 0.0344(5) 0.30076(16) 0.5194(3) 0.0633(12) Uani 1 1 d . . .
H20A H 0.0312 0.3283 0.4955 0.076 Uiso 1 1 calc R . .
C21 C 0.1589(4) 0.28247(14) 0.5499(2) 0.0512(9) Uani 1 1 d . . .
H21A H 0.2375 0.2980 0.5478 0.061 Uiso 1 1 calc R . .
C22 C 0.6371(4) -0.07030(12) 0.6128(2) 0.0450(8) Uani 1 1 d . . .
C23 C 0.6367(5) -0.07105(15) 0.5447(2) 0.0565(10) Uani 1 1 d . . .
H23A H 0.5579 -0.0631 0.5112 0.068 Uiso 1 1 calc R . .
C24 C 0.7517(6) -0.08347(17) 0.5259(3) 0.0675(13) Uani 1 1 d . . .
H24A H 0.7492 -0.0842 0.4797 0.081 Uiso 1 1 calc R . .
C25 C 0.8689(6) -0.0946(2) 0.5739(3) 0.0779(15) Uani 1 1 d . . .
H25A H 0.9465 -0.1027 0.5609 0.093 Uiso 1 1 calc R . .
C26 C 0.8711(6) -0.0938(3) 0.6416(3) 0.097(2) Uani 1 1 d . . .
H26A H 0.9509 -0.1011 0.6749 0.117 Uiso 1 1 calc R . .
C27 C 0.7557(5) -0.0822(2) 0.6606(2) 0.0706(14) Uani 1 1 d . . .
H27A H 0.7580 -0.0825 0.7067 0.085 Uiso 1 1 calc R . .
C28 C 0.3444(4) -0.06651(13) 0.56824(19) 0.0458(9) Uani 1 1 d . . .
C29 C 0.2596(5) -0.03235(17) 0.5334(2) 0.0645(12) Uani 1 1 d . . .
H29A H 0.2746 -0.0018 0.5478 0.077 Uiso 1 1 calc R . .
C30 C 0.1518(5) -0.0431(2) 0.4771(3) 0.0767(15) Uani 1 1 d . . .
H30A H 0.0944 -0.0197 0.4545 0.092 Uiso 1 1 calc R . .
C31 C 0.1295(5) -0.0875(2) 0.4548(3) 0.0765(15) Uani 1 1 d . . .
H31A H 0.0574 -0.0946 0.4170 0.092 Uiso 1 1 calc R . .
C32 C 0.2139(6) -0.1216(2) 0.4883(3) 0.0854(17) Uani 1 1 d . . .
H32A H 0.2005 -0.1519 0.4725 0.103 Uiso 1 1 calc R . .
C33 C 0.3186(5) -0.11174(16) 0.5453(3) 0.0663(12) Uani 1 1 d . . .
H33A H 0.3728 -0.1356 0.5687 0.080 Uiso 1 1 calc R . .
O1 O 0.0514(13) 0.0031(5) 0.7147(7) 0.354(11) Uani 1 1 d . . .
B1 B 0.0000 0.1447(3) 0.7500 0.079(2) Uani 1 2 d S . .
F1 F 0.0715(11) 0.1257(4) 0.7068(5) 0.121(3) Uiso 0.50 1 d P A .
F2 F 0.0000 0.1910(6) 0.7500 0.283(7) Uiso 1 2 d S . .
F3 F 0.0997(12) 0.1508(4) 0.8083(6) 0.142(3) Uiso 0.50 1 d P A .
F4 F 0.114(2) 0.1204(8) 0.7507(13) 0.266(10) Uiso 0.50 1 d P A -1

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ag1 0.0389(2) 0.0266(2) 0.0521(2) 0.000 0.00944(16) 0.000
P1 0.0440(5) 0.0257(4) 0.0468(5) 0.0009(3) 0.0096(4) 0.0010(3)
N1 0.0397(17) 0.0360(17) 0.068(2) -0.0010(15) 0.0084(15) -0.0097(13)
N2 0.046(2) 0.045(2) 0.134(4) 0.001(2) -0.015(2) 0.0084(17)
N3 0.0374(15) 0.0295(15) 0.0546(16) -0.0011(13) 0.0061(13) -0.0038(12)
C1 0.0329(16) 0.0305(18) 0.0505(19) -0.0008(15) 0.0040(14) -0.0041(14)
C2 0.0345(16) 0.0320(18) 0.0509(19) -0.0002(16) 0.0040(15) -0.0032(15)
C3 0.0375(17) 0.0288(17) 0.0461(18) -0.0023(15) 0.0063(14) -0.0031(14)
C4 0.0323(16) 0.0279(17) 0.055(2) -0.0020(15) 0.0028(15) -0.0035(14)
C5 0.0353(17) 0.0313(18) 0.0475(18) -0.0013(15) 0.0038(14) -0.0021(14)
C6 0.0339(16) 0.0303(18) 0.0416(18) -0.0005(14) 0.0002(14) -0.0008(13)
C7 0.0361(16) 0.0341(19) 0.0475(19) -0.0014(15) 0.0078(15) -0.0002(14)
C8 0.0393(17) 0.0298(17) 0.0494(19) 0.0027(15) 0.0088(15) -0.0065(14)
C9 0.0403(17) 0.0264(16) 0.0418(17) 0.0010(14) 0.0032(14) 0.0018(14)
C10 0.0400(18) 0.0344(19) 0.056(2) -0.0018(16) 0.0126(16) 0.0021(15)
C11 0.0394(18) 0.0333(19) 0.058(2) 0.0034(17) 0.0138(16) -0.0024(15)
C12 0.0358(17) 0.0330(18) 0.053(2) -0.0019(16) 0.0090(15) -0.0044(15)
C13 0.0400(19) 0.040(2) 0.084(3) 0.010(2) -0.005(2) -0.0066(17)
C14 0.042(2) 0.033(2) 0.100(3) 0.013(2) 0.003(2) -0.0073(17)
C15 0.045(2) 0.047(2) 0.059(2) 0.0064(19) -0.0009(18) -0.0150(18)
C16 0.048(2) 0.041(2) 0.057(2) 0.0086(18) 0.0045(17) -0.0079(17)
C17 0.0348(17) 0.0326(18) 0.056(2) -0.0069(16) 0.0026(15) -0.0016(15)
C18 0.038(2) 0.038(2) 0.117(4) 0.000(2) 0.002(2) -0.0031(18)
C19 0.038(2) 0.050(3) 0.159(6) 0.001(3) -0.001(3) -0.003(2)
C20 0.055(2) 0.047(2) 0.077(3) 0.006(2) 0.001(2) 0.011(2)
C21 0.046(2) 0.040(2) 0.064(2) 0.0016(19) 0.0087(18) 0.0022(17)
C22 0.054(2) 0.0282(18) 0.053(2) 0.0028(16) 0.0156(17) 0.0049(16)
C23 0.067(3) 0.051(2) 0.051(2) 0.0006(19) 0.0144(19) 0.003(2)
C24 0.095(4) 0.055(3) 0.064(3) -0.006(2) 0.042(3) 0.001(3)
C25 0.074(3) 0.077(4) 0.095(4) 0.019(3) 0.045(3) 0.027(3)
C26 0.066(3) 0.144(6) 0.087(4) 0.034(4) 0.029(3) 0.043(4)
C27 0.058(3) 0.097(4) 0.059(2) 0.016(3) 0.019(2) 0.020(3)
C28 0.049(2) 0.0351(19) 0.052(2) -0.0025(17) 0.0113(17) -0.0026(17)
C29 0.072(3) 0.048(2) 0.060(2) -0.005(2) -0.004(2) -0.001(2)
C30 0.068(3) 0.075(3) 0.070(3) -0.003(3) -0.010(2) 0.004(3)
C31 0.060(3) 0.096(4) 0.065(3) -0.017(3) 0.001(2) -0.013(3)
C32 0.077(3) 0.064(3) 0.106(4) -0.039(3) 0.008(3) -0.018(3)
C33 0.064(3) 0.040(2) 0.090(3) -0.015(2) 0.010(2) -0.006(2)
O1 0.208(13) 0.362(16) 0.41(2) 0.210(16) -0.051(11) -0.106(13)
B1 0.055(4) 0.068(5) 0.111(7) 0.000 0.019(5) 0.000

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.411(3) 3_445 ?
Ag1 N1 2.411(3) 4_646 ?
Ag1 P1 2.4866(9) 2_656 ?
Ag1 P1 2.4866(9) . ?
P1 C22 1.821(4) . ?
P1 C9 1.833(3) . ?
P1 C28 1.834(4) . ?
N1 C14 1.323(6) . ?
N1 C15 1.333(5) . ?
N1 Ag1 2.411(3) 3 ?
N2 C19 1.331(7) . ?
N2 C20 1.340(7) . ?
N3 C5 1.336(5) . ?
N3 C1 1.339(5) . ?
C1 C2 1.389(5) . ?
C1 C12 1.491(5) . ?
C2 C3 1.391(5) . ?
C2 H2B 0.9300 . ?
C3 C4 1.388(5) . ?
C3 C6 1.493(5) . ?
C4 C5 1.389(5) . ?
C4 H4A 0.9300 . ?
C5 C17 1.487(5) . ?
C6 C11 1.389(5) . ?
C6 C7 1.397(5) . ?
C7 C8 1.379(5) . ?
C7 H7A 0.9300 . ?
C8 C9 1.393(5) . ?
C8 H8A 0.9300 . ?
C9 C10 1.373(5) . ?
C10 C11 1.393(5) . ?
C10 H10A 0.9300 . ?
C11 H11A 0.9300 . ?
C12 C16 1.379(5) . ?
C12 C13 1.379(6) . ?
C13 C14 1.374(6) . ?
C13 H13A 0.9300 . ?
C14 H14A 0.9300 . ?
C15 C16 1.382(6) . ?
C15 H15A 0.9300 . ?
C16 H16A 0.9300 . ?
C17 C21 1.387(6) . ?
C17 C18 1.391(6) . ?
C18 C19 1.386(6) . ?
C18 H18A 0.9300 . ?
C19 H19A 0.9300 . ?
C20 C21 1.360(6) . ?
C20 H20A 0.9300 . ?
C21 H21A 0.9300 . ?
C22 C27 1.374(6) . ?
C22 C23 1.380(6) . ?
C23 C24 1.377(7) . ?
C23 H23A 0.9300 . ?
C24 C25 1.362(8) . ?
C24 H24A 0.9300 . ?
C25 C26 1.367(9) . ?
C25 H25A 0.9300 . ?
C26 C27 1.377(8) . ?
C26 H26A 0.9300 . ?
C27 H27A 0.9300 . ?
C28 C29 1.375(6) . ?
C28 C33 1.389(6) . ?
C29 C30 1.389(7) . ?
C29 H29A 0.9300 . ?
C30 C31 1.361(8) . ?
C30 H30A 0.9300 . ?
C31 C32 1.363(9) . ?
C31 H31A 0.9300 . ?
C32 C33 1.373(7) . ?
C32 H32A 0.9300 . ?
C33 H33A 0.9300 . ?
B1 F2 1.339(19) . ?
B1 F3 1.346(11) . ?
B1 F3 1.346(11) 2_556 ?
B1 F4 1.35(2) 2_556 ?
B1 F4 1.35(2) . ?
B1 F1 1.396(11) 2_556 ?
B1 F1 1.396(11) . ?
F1 F4 0.89(2) . ?
F2 F3 1.770(15) . ?
F2 F3 1.770(15) 2_556 ?
F3 F4 1.50(2) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N1 88.77(16) 3_445 4_646 ?
N1 Ag1 P1 112.76(9) 3_445 2_656 ?
N1 Ag1 P1 109.89(8) 4_646 2_656 ?
N1 Ag1 P1 109.89(8) 3_445 . ?
N1 Ag1 P1 112.76(9) 4_646 . ?
P1 Ag1 P1 118.85(4) 2_656 . ?
C22 P1 C9 104.83(17) . . ?
C22 P1 C28 103.92(18) . . ?
C9 P1 C28 102.89(16) . . ?
C22 P1 Ag1 109.87(12) . . ?
C9 P1 Ag1 115.41(12) . . ?
C28 P1 Ag1 118.51(13) . . ?
C14 N1 C15 116.4(3) . . ?
C14 N1 Ag1 119.4(3) . 3 ?
C15 N1 Ag1 123.6(2) . 3 ?
C19 N2 C20 115.6(4) . . ?
C5 N3 C1 118.5(3) . . ?
N3 C1 C2 122.7(3) . . ?
N3 C1 C12 113.9(3) . . ?
C2 C1 C12 123.3(3) . . ?
C1 C2 C3 119.1(3) . . ?
C1 C2 H2B 120.4 . . ?
C3 C2 H2B 120.4 . . ?
C4 C3 C2 117.6(3) . . ?
C4 C3 C6 119.5(3) . . ?
C2 C3 C6 122.8(3) . . ?
C3 C4 C5 120.1(3) . . ?
C3 C4 H4A 120.0 . . ?
C5 C4 H4A 120.0 . . ?
N3 C5 C4 121.9(3) . . ?
N3 C5 C17 115.7(3) . . ?
C4 C5 C17 122.4(3) . . ?
C11 C6 C7 118.8(3) . . ?
C11 C6 C3 120.9(3) . . ?
C7 C6 C3 120.3(3) . . ?
C8 C7 C6 120.2(3) . . ?
C8 C7 H7A 119.9 . . ?
C6 C7 H7A 119.9 . . ?
C7 C8 C9 120.9(3) . . ?
C7 C8 H8A 119.6 . . ?
C9 C8 H8A 119.6 . . ?
C10 C9 C8 118.8(3) . . ?
C10 C9 P1 123.9(3) . . ?
C8 C9 P1 117.3(3) . . ?
C9 C10 C11 120.9(3) . . ?
C9 C10 H10A 119.6 . . ?
C11 C10 H10A 119.6 . . ?
C6 C11 C10 120.2(3) . . ?
C6 C11 H11A 119.9 . . ?
C10 C11 H11A 119.9 . . ?
C16 C12 C13 116.7(3) . . ?
C16 C12 C1 123.1(3) . . ?
C13 C12 C1 120.1(3) . . ?
C14 C13 C12 119.8(4) . . ?
C14 C13 H13A 120.1 . . ?
C12 C13 H13A 120.1 . . ?
N1 C14 C13 124.0(4) . . ?
N1 C14 H14A 118.0 . . ?
C13 C14 H14A 118.0 . . ?
N1 C15 C16 123.5(4) . . ?
N1 C15 H15A 118.3 . . ?
C16 C15 H15A 118.3 . . ?
C12 C16 C15 119.7(4) . . ?
C12 C16 H16A 120.2 . . ?
C15 C16 H16A 120.2 . . ?
C21 C17 C18 117.4(4) . . ?
C21 C17 C5 120.4(3) . . ?
C18 C17 C5 122.2(4) . . ?
C19 C18 C17 118.1(5) . . ?
C19 C18 H18A 120.9 . . ?
C17 C18 H18A 120.9 . . ?
N2 C19 C18 124.8(5) . . ?
N2 C19 H19A 117.6 . . ?
C18 C19 H19A 117.6 . . ?
N2 C20 C21 124.3(4) . . ?
N2 C20 H20A 117.8 . . ?
C21 C20 H20A 117.8 . . ?
C20 C21 C17 119.7(4) . . ?
C20 C21 H21A 120.1 . . ?
C17 C21 H21A 120.1 . . ?
C27 C22 C23 117.7(4) . . ?
C27 C22 P1 117.9(3) . . ?
C23 C22 P1 124.4(3) . . ?
C24 C23 C22 120.7(4) . . ?
C24 C23 H23A 119.6 . . ?
C22 C23 H23A 119.6 . . ?
C25 C24 C23 120.8(4) . . ?
C25 C24 H24A 119.6 . . ?
C23 C24 H24A 119.6 . . ?
C24 C25 C26 119.1(5) . . ?
C24 C25 H25A 120.4 . . ?
C26 C25 H25A 120.4 . . ?
C25 C26 C27 120.2(5) . . ?
C25 C26 H26A 119.9 . . ?
C27 C26 H26A 119.9 . . ?
C22 C27 C26 121.3(5) . . ?
C22 C27 H27A 119.3 . . ?
C26 C27 H27A 119.3 . . ?
C29 C28 C33 117.9(4) . . ?
C29 C28 P1 124.5(3) . . ?
C33 C28 P1 117.6(3) . . ?
C28 C29 C30 120.6(4) . . ?
C28 C29 H29A 119.7 . . ?
C30 C29 H29A 119.7 . . ?
C31 C30 C29 120.5(5) . . ?
C31 C30 H30A 119.7 . . ?
C29 C30 H30A 119.7 . . ?
C30 C31 C32 119.4(5) . . ?
C30 C31 H31A 120.3 . . ?
C32 C31 H31A 120.3 . . ?
C31 C32 C33 120.8(5) . . ?
C31 C32 H32A 119.6 . . ?
C33 C32 H32A 119.6 . . ?
C32 C33 C28 120.7(5) . . ?
C32 C33 H33A 119.7 . . ?
C28 C33 H33A 119.7 . . ?
F2 B1 F3 82.5(7) . . ?
F2 B1 F3 82.5(7) . 2_556 ?
F3 B1 F3 164.9(13) . 2_556 ?
F2 B1 F4 121.3(11) . 2_556 ?
F3 B1 F4 121.2(12) . 2_556 ?
F3 B1 F4 67.5(11) 2_556 2_556 ?
F2 B1 F4 121.3(11) . . ?
F3 B1 F4 67.5(11) . . ?
F3 B1 F4 121.2(12) 2_556 . ?
F4 B1 F4 117(2) 2_556 . ?
F2 B1 F1 113.2(6) . 2_556 ?
F3 B1 F1 84.2(6) . 2_556 ?
F3 B1 F1 101.8(6) 2_556 2_556 ?
F4 B1 F1 37.8(10) 2_556 2_556 ?
F4 B1 F1 112.4(11) . 2_556 ?
F2 B1 F1 113.2(6) . . ?
F3 B1 F1 101.8(6) . . ?
F3 B1 F1 84.2(6) 2_556 . ?
F4 B1 F1 112.4(11) 2_556 . ?
F4 B1 F1 37.8(10) . . ?
F1 B1 F1 133.7(11) 2_556 . ?
F4 F1 B1 68.5(19) . . ?
B1 F2 F3 48.9(6) . . ?
B1 F2 F3 48.9(6) . 2_556 ?
F3 F2 F3 97.9(12) . 2_556 ?
B1 F3 F4 56.4(10) . . ?
B1 F3 F2 48.6(7) . . ?
F4 F3 F2 91.3(11) . . ?
F1 F4 B1 73.7(19) . . ?
F1 F4 F3 124(3) . . ?
B1 F4 F3 56.0(11) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ag1 P1 C22 -109.11(16) 3_445 . . . ?
N1 Ag1 P1 C22 -11.82(16) 4_646 . . . ?
P1 Ag1 P1 C22 118.90(14) 2_656 . . . ?
N1 Ag1 P1 C9 132.67(15) 3_445 . . . ?
N1 Ag1 P1 C9 -130.04(15) 4_646 . . . ?
P1 Ag1 P1 C9 0.68(12) 2_656 . . . ?
N1 Ag1 P1 C28 10.05(17) 3_445 . . . ?
N1 Ag1 P1 C28 107.35(17) 4_646 . . . ?
P1 Ag1 P1 C28 -121.93(15) 2_656 . . . ?
C5 N3 C1 C2 2.6(6) . . . . ?
C5 N3 C1 C12 -176.4(3) . . . . ?
N3 C1 C2 C3 -2.5(6) . . . . ?
C12 C1 C2 C3 176.4(3) . . . . ?
C1 C2 C3 C4 0.0(5) . . . . ?
C1 C2 C3 C6 176.1(3) . . . . ?
C2 C3 C4 C5 2.1(6) . . . . ?
C6 C3 C4 C5 -174.1(3) . . . . ?
C1 N3 C5 C4 -0.3(5) . . . . ?
C1 N3 C5 C17 -178.7(3) . . . . ?
C3 C4 C5 N3 -2.0(6) . . . . ?
C3 C4 C5 C17 176.3(4) . . . . ?
C4 C3 C6 C11 137.5(4) . . . . ?
C2 C3 C6 C11 -38.4(5) . . . . ?
C4 C3 C6 C7 -39.3(5) . . . . ?
C2 C3 C6 C7 144.7(4) . . . . ?
C11 C6 C7 C8 -1.9(5) . . . . ?
C3 C6 C7 C8 175.0(3) . . . . ?
C6 C7 C8 C9 -2.2(5) . . . . ?
C7 C8 C9 C10 4.4(5) . . . . ?
C7 C8 C9 P1 -173.9(3) . . . . ?
C22 P1 C9 C10 0.8(3) . . . . ?
C28 P1 C9 C10 -107.6(3) . . . . ?
Ag1 P1 C9 C10 121.8(3) . . . . ?
C22 P1 C9 C8 179.1(3) . . . . ?
C28 P1 C9 C8 70.7(3) . . . . ?
Ag1 P1 C9 C8 -59.9(3) . . . . ?
C8 C9 C10 C11 -2.5(5) . . . . ?
P1 C9 C10 C11 175.7(3) . . . . ?
C7 C6 C11 C10 3.8(5) . . . . ?
C3 C6 C11 C10 -173.1(3) . . . . ?
C9 C10 C11 C6 -1.6(6) . . . . ?
N3 C1 C12 C16 153.3(4) . . . . ?
C2 C1 C12 C16 -25.7(6) . . . . ?
N3 C1 C12 C13 -23.7(5) . . . . ?
C2 C1 C12 C13 157.3(4) . . . . ?
C16 C12 C13 C14 -0.9(7) . . . . ?
C1 C12 C13 C14 176.3(4) . . . . ?
C15 N1 C14 C13 0.2(8) . . . . ?
Ag1 N1 C14 C13 171.1(4) 3 . . . ?
C12 C13 C14 N1 0.0(8) . . . . ?
C14 N1 C15 C16 0.5(7) . . . . ?
Ag1 N1 C15 C16 -170.0(3) 3 . . . ?
C13 C12 C16 C15 1.5(6) . . . . ?
C1 C12 C16 C15 -175.6(4) . . . . ?
N1 C15 C16 C12 -1.4(7) . . . . ?
N3 C5 C17 C21 25.3(5) . . . . ?
C4 C5 C17 C21 -153.1(4) . . . . ?
N3 C5 C17 C18 -152.9(4) . . . . ?
C4 C5 C17 C18 28.6(6) . . . . ?
C21 C17 C18 C19 1.3(7) . . . . ?
C5 C17 C18 C19 179.5(5) . . . . ?
C20 N2 C19 C18 -2.3(10) . . . . ?
C17 C18 C19 N2 1.5(10) . . . . ?
C19 N2 C20 C21 0.5(8) . . . . ?
N2 C20 C21 C17 2.2(8) . . . . ?
C18 C17 C21 C20 -3.0(6) . . . . ?
C5 C17 C21 C20 178.7(4) . . . . ?
C9 P1 C22 C27 95.1(4) . . . . ?
C28 P1 C22 C27 -157.2(4) . . . . ?
Ag1 P1 C22 C27 -29.5(4) . . . . ?
C9 P1 C22 C23 -87.2(4) . . . . ?
C28 P1 C22 C23 20.5(4) . . . . ?
Ag1 P1 C22 C23 148.2(3) . . . . ?
C27 C22 C23 C24 0.1(7) . . . . ?
P1 C22 C23 C24 -177.6(4) . . . . ?
C22 C23 C24 C25 -1.0(8) . . . . ?
C23 C24 C25 C26 0.6(9) . . . . ?
C24 C25 C26 C27 0.6(11) . . . . ?
C23 C22 C27 C26 1.1(8) . . . . ?
P1 C22 C27 C26 179.0(5) . . . . ?
C25 C26 C27 C22 -1.5(11) . . . . ?
C22 P1 C28 C29 -112.8(4) . . . . ?
C9 P1 C28 C29 -3.7(4) . . . . ?
Ag1 P1 C28 C29 125.0(4) . . . . ?
C22 P1 C28 C33 67.3(4) . . . . ?
C9 P1 C28 C33 176.4(4) . . . . ?
Ag1 P1 C28 C33 -54.9(4) . . . . ?
C33 C28 C29 C30 0.0(7) . . . . ?
P1 C28 C29 C30 -179.9(4) . . . . ?
C28 C29 C30 C31 -1.0(9) . . . . ?
C29 C30 C31 C32 0.1(10) . . . . ?
C30 C31 C32 C33 1.7(10) . . . . ?
C31 C32 C33 C28 -2.8(9) . . . . ?
C29 C28 C33 C32 1.9(8) . . . . ?
P1 C28 C33 C32 -178.2(5) . . . . ?
F2 B1 F1 F4 111.8(19) . . . . ?
F3 B1 F1 F4 25(2) . . . . ?
F3 B1 F1 F4 -169(2) 2_556 . . . ?
F4 B1 F1 F4 -106(3) 2_556 . . . ?
F1 B1 F1 F4 -68.2(19) 2_556 . . . ?
F3 B1 F2 F3 180.000(3) 2_556 . . . ?
F4 B1 F2 F3 122.1(12) 2_556 . . . ?
F4 B1 F2 F3 -57.9(12) . . . . ?
F1 B1 F2 F3 80.4(6) 2_556 . . . ?
F1 B1 F2 F3 -99.6(6) . . . . ?
F3 B1 F2 F3 180.000(3) . . . 2_556 ?
F4 B1 F2 F3 -57.9(12) 2_556 . . 2_556 ?
F4 B1 F2 F3 122.1(12) . . . 2_556 ?
F1 B1 F2 F3 -99.6(6) 2_556 . . 2_556 ?
F1 B1 F2 F3 80.4(6) . . . 2_556 ?
F2 B1 F3 F4 -128.5(12) . . . . ?
F3 B1 F3 F4 -128.5(12) 2_556 . . . ?
F4 B1 F3 F4 109(2) 2_556 . . . ?
F1 B1 F3 F4 117.2(13) 2_556 . . . ?
F1 B1 F3 F4 -16.3(13) . . . . ?
F3 B1 F3 F2 0.001(8) 2_556 . . . ?
F4 B1 F3 F2 -122.2(14) 2_556 . . . ?
F4 B1 F3 F2 128.5(12) . . . . ?
F1 B1 F3 F2 -114.3(6) 2_556 . . . ?
F1 B1 F3 F2 112.2(6) . . . . ?
F3 F2 F3 B1 0.000(2) 2_556 . . . ?
B1 F2 F3 F4 40.7(10) . . . . ?
F3 F2 F3 F4 40.7(10) 2_556 . . . ?
B1 F1 F4 F3 -27(2) . . . . ?
F2 B1 F4 F1 -88.1(18) . . . . ?
F3 B1 F4 F1 -153(2) . . . . ?
F3 B1 F4 F1 13(2) 2_556 . . . ?
F4 B1 F4 F1 91.9(18) 2_556 . . . ?
F1 B1 F4 F1 133.4(16) 2_556 . . . ?
F2 B1 F4 F3 65.3(11) . . . . ?
F3 B1 F4 F3 166.2(13) 2_556 . . . ?
F4 B1 F4 F3 -114.7(11) 2_556 . . . ?
F1 B1 F4 F3 -73.2(9) 2_556 . . . ?
F1 B1 F4 F3 153(2) . . . . ?
B1 F3 F4 F1 31(2) . . . . ?
F2 F3 F4 F1 -5(3) . . . . ?
F2 F3 F4 B1 -36.0(8) . . . . ?

_diffrn_measured_fraction_theta_max 0.967
_diffrn_reflns_theta_full        62.53
_diffrn_measured_fraction_theta_full 0.966
_refine_diff_density_max         0.799
_refine_diff_density_min         -0.822
_refine_diff_density_rms         0.076

#=========================END