# Electronic Supplementary Material (ESI) for Dalton Transactions # This journal is © The Royal Society of Chemistry 2012 data_global _journal_name_full 'Dalton Trans.' _journal_coden_cambridge 0222 _journal_year ? _journal_volume ? _journal_page_first ? loop_ _publ_author_name T.Sato H.Awano O.Haba H.Katagiri Y.-J.Pu T.Takahashi ; K.Yonetake ; _publ_contact_author_name 'Takeshi Sato' _publ_contact_author_email twn34755@st.yamagata-u.ac.jp data_ydkr _database_code_depnum_ccdc_archive 'CCDC 854595' #TrackingRef 'ydkr.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C28 H37 F2 N O2 Pt' _chemical_formula_sum 'C28 H37 F2 N O2 Pt' _chemical_formula_weight 652.68 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting triclinic _symmetry_space_group_name_H-M 'P -1' _symmetry_space_group_name_Hall '-P 1' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 5.4867(13) _cell_length_b 11.059(3) _cell_length_c 21.565(5) _cell_angle_alpha 81.946(7) _cell_angle_beta 84.414(8) _cell_angle_gamma 82.446(7) _cell_volume 1280.2(5) _cell_formula_units_Z 2 _cell_measurement_temperature 103 _cell_measurement_reflns_used 3696 _cell_measurement_theta_min 3.2201 _cell_measurement_theta_max 27.5204 _exptl_crystal_description Prism _exptl_crystal_colour yellow _exptl_crystal_size_max 0.15 _exptl_crystal_size_mid 0.10 _exptl_crystal_size_min 0.05 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.693 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 648 _exptl_absorpt_coefficient_mu 5.520 _exptl_absorpt_correction_type Numerical _exptl_absorpt_correction_T_min 0.4915 _exptl_absorpt_correction_T_max 0.7698 _exptl_absorpt_process_details ; Higashi, T. (1995). Program for Absorption Correction. Rigaku Corporation, Tokyo, Japan. ; _diffrn_ambient_temperature 103 _diffrn_radiation_wavelength 0.71075 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'Rotating Anode' _diffrn_radiation_monochromator 'Graphite Monochromator' _diffrn_radiation_detector CCD _diffrn_measurement_device 'Rigaku Saturn' _diffrn_measurement_method \w _diffrn_detector_area_resol_mean 28.5714 _diffrn_standards_number 5834 _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 19375 _diffrn_reflns_av_R_equivalents 0.0484 _diffrn_reflns_av_sigmaI/netI 0.0611 _diffrn_reflns_limit_h_min -7 _diffrn_reflns_limit_h_max 7 _diffrn_reflns_limit_k_min -14 _diffrn_reflns_limit_k_max 14 _diffrn_reflns_limit_l_min -27 _diffrn_reflns_limit_l_max 27 _diffrn_reflns_theta_min 3.63 _diffrn_reflns_theta_max 27.52 _reflns_number_total 5834 _reflns_number_gt 5106 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'CrystalClear (Rigaku Inc., 2008)' _computing_cell_refinement 'CrystalClear (Rigaku Inc., 2008)' _computing_data_reduction 'CrystalClear (Rigaku Inc., 2008)' _computing_structure_solution 'SHELXS-97 (Sheldrick, 2008)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 2008)' _computing_molecular_graphics 'PLATON (Spek, 2009)' _computing_publication_material 'Yadokari-XG 2009 (Wakita, Kabuto et al., 2009)' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0232P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment constr _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 5834 _refine_ls_number_parameters 319 _refine_ls_number_restraints 42 _refine_ls_R_factor_all 0.0378 _refine_ls_R_factor_gt 0.0315 _refine_ls_wR_factor_ref 0.0653 _refine_ls_wR_factor_gt 0.0621 _refine_ls_goodness_of_fit_ref 1.067 _refine_ls_restrained_S_all 1.065 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Pt1 Pt 0.44151(3) 0.310796(13) 0.134893(7) 0.01766(6) Uani 1 1 d . . . N1 N 0.4788(6) 0.4831(3) 0.09748(14) 0.0170(7) Uani 1 1 d . . . C1 C 0.6720(7) 0.5157(4) 0.05740(18) 0.0218(9) Uani 1 1 d . . . H1 H 0.7985 0.4534 0.0462 0.026 Uiso 1 1 calc R . . C2 C 0.6912(8) 0.6352(4) 0.03253(18) 0.0232(10) Uani 1 1 d . . . H2 H 0.8291 0.6556 0.0047 0.028 Uiso 1 1 calc R . . C3 C 0.5068(8) 0.7258(4) 0.04863(19) 0.0242(10) Uani 1 1 d . . . H3 H 0.5156 0.8091 0.0313 0.029 Uiso 1 1 calc R . . C4 C 0.3100(8) 0.6948(4) 0.08996(18) 0.0232(10) Uani 1 1 d . . . H4 H 0.1833 0.7567 0.1015 0.028 Uiso 1 1 calc R . . C5 C 0.2979(7) 0.5719(4) 0.11475(18) 0.0177(9) Uani 1 1 d . . . C6 C 0.1432(7) 0.3919(3) 0.17646(17) 0.0144(8) Uani 1 1 d . . . C7 C 0.1073(7) 0.5213(4) 0.15989(18) 0.0179(9) Uani 1 1 d . . . C8 C -0.0982(8) 0.5875(4) 0.18685(18) 0.0208(9) Uani 1 1 d . . . C9 C -0.2640(7) 0.5302(4) 0.22957(18) 0.0189(9) Uani 1 1 d . . . C10 C -0.2345(7) 0.4043(4) 0.24789(17) 0.0171(9) Uani 1 1 d . . . C11 C -0.0288(7) 0.3372(3) 0.22020(17) 0.0168(9) Uani 1 1 d . . . H11 H -0.0045 0.2506 0.2316 0.020 Uiso 1 1 calc R . . F1 F -0.1444(4) 0.7122(2) 0.17267(11) 0.0266(6) Uani 1 1 d . . . F2 F -0.4615(4) 0.6005(2) 0.25446(11) 0.0252(5) Uani 1 1 d . . . C12 C -0.4189(7) 0.3459(3) 0.29620(18) 0.0190(9) Uani 1 1 d . . . H12 H -0.5824 0.3605 0.2789 0.023 Uiso 1 1 calc R . . H12A H -0.4324 0.3884 0.3341 0.023 Uiso 1 1 calc R . . C13 C -0.3590(7) 0.2080(3) 0.31626(18) 0.0197(9) Uani 1 1 d . . . H13 H -0.1997 0.1926 0.3357 0.024 Uiso 1 1 calc R . . H13A H -0.3406 0.1646 0.2786 0.024 Uiso 1 1 calc R . . C14 C -0.5586(7) 0.1559(3) 0.36295(18) 0.0176(6) Uani 1 1 d U B . H14 H -0.5853 0.2033 0.3992 0.021 Uiso 1 1 calc R . . H14A H -0.7152 0.1661 0.3425 0.021 Uiso 1 1 calc R . . C15 C -0.4913(7) 0.0209(3) 0.38639(18) 0.0170(5) Uani 1 1 d U . . H15 H -0.3339 0.0107 0.4065 0.020 Uiso 0.70 1 calc PR A 1 H15A H -0.4657 -0.0265 0.3501 0.020 Uiso 0.70 1 calc PR A 1 H15B H -0.4041 -0.0178 0.3504 0.020 Uiso 0.30 1 calc PR A 2 H15C H -0.3695 0.0167 0.4179 0.020 Uiso 0.30 1 calc PR A 2 C16B C -0.679(3) -0.0577(13) 0.4145(7) 0.0163(6) Uani 0.30 1 d PU B 2 H16B H -0.8044 -0.0058 0.4385 0.020 Uiso 0.30 1 calc PR B 2 H16C H -0.7613 -0.0791 0.3793 0.020 Uiso 0.30 1 calc PR B 2 C16A C -0.6922(11) -0.0319(5) 0.4341(3) 0.0157(6) Uani 0.70 1 d PU B 1 H16A H -0.8510 -0.0202 0.4145 0.019 Uiso 0.70 1 calc PR B 1 H16D H -0.7144 0.0132 0.4712 0.019 Uiso 0.70 1 calc PR B 1 C17 C -0.6193(7) -0.1715(3) 0.45547(18) 0.0171(5) Uani 1 1 d U . . H17 H -0.5963 -0.2161 0.4182 0.021 Uiso 0.70 1 calc PR B 1 H17A H -0.4601 -0.1826 0.4748 0.021 Uiso 0.70 1 calc PR B 1 H17B H -0.4824 -0.1588 0.4797 0.021 Uiso 0.30 1 calc PR B 2 H17C H -0.5530 -0.2349 0.4281 0.021 Uiso 0.30 1 calc PR B 2 C18 C -0.8144(7) -0.2269(3) 0.50277(18) 0.0176(6) Uani 1 1 d U B . H18 H -0.8428 -0.1794 0.5390 0.021 Uiso 1 1 calc R . . H18A H -0.9715 -0.2185 0.4827 0.021 Uiso 1 1 calc R . . C19 C -0.7438(7) -0.3614(3) 0.52668(18) 0.0188(9) Uani 1 1 d . . . H19 H -0.5861 -0.3699 0.5465 0.023 Uiso 1 1 calc R B . H19A H -0.7165 -0.4090 0.4905 0.023 Uiso 1 1 calc R . . C20 C -0.9380(7) -0.4168(3) 0.57428(18) 0.0182(9) Uani 1 1 d . B . H20 H -0.9655 -0.3689 0.6104 0.022 Uiso 1 1 calc R . . H20A H -1.0955 -0.4083 0.5543 0.022 Uiso 1 1 calc R . . C21 C -0.8689(7) -0.5515(3) 0.59866(18) 0.0193(9) Uani 1 1 d . . . H21 H -0.8426 -0.5996 0.5627 0.023 Uiso 1 1 calc R B . H21A H -0.7110 -0.5602 0.6184 0.023 Uiso 1 1 calc R . . C22 C -1.0617(7) -0.6052(4) 0.64605(18) 0.0221(9) Uani 1 1 d . B . H22 H -1.2179 -0.5994 0.6258 0.027 Uiso 1 1 calc R . . H22A H -1.0926 -0.5553 0.6813 0.027 Uiso 1 1 calc R . . C23 C -0.9881(8) -0.7384(4) 0.6721(2) 0.0296(11) Uani 1 1 d . . . H23 H -0.9655 -0.7893 0.6378 0.044 Uiso 1 1 calc R B . H23A H -1.1179 -0.7667 0.7031 0.044 Uiso 1 1 calc R . . H23B H -0.8334 -0.7451 0.6922 0.044 Uiso 1 1 calc R . . O1 O 0.3722(5) 0.1450(2) 0.17829(12) 0.0202(6) Uani 1 1 d . . . O2 O 0.7627(5) 0.2356(2) 0.08755(12) 0.0192(6) Uani 1 1 d . . . C24 C 0.4097(8) -0.0669(4) 0.2102(2) 0.0269(10) Uani 1 1 d . . . H24 H 0.4529 -0.0732 0.2536 0.040 Uiso 1 1 calc R . . H24A H 0.4814 -0.1415 0.1922 0.040 Uiso 1 1 calc R . . H24B H 0.2298 -0.0579 0.2095 0.040 Uiso 1 1 calc R . . C25 C 0.5098(8) 0.0438(4) 0.17192(19) 0.0210(9) Uani 1 1 d . . . C26 C 0.7284(8) 0.0295(4) 0.13408(19) 0.0236(10) Uani 1 1 d . . . H26 H 0.8092 -0.0520 0.1347 0.028 Uiso 1 1 calc R . . C27 C 0.8448(7) 0.1218(4) 0.09484(18) 0.0196(9) Uani 1 1 d . . . C28 C 1.0850(7) 0.0890(4) 0.05818(19) 0.0218(9) Uani 1 1 d . . . H28 H 1.0631 0.1070 0.0131 0.033 Uiso 1 1 calc R . . H28A H 1.1402 0.0012 0.0687 0.033 Uiso 1 1 calc R . . H28B H 1.2089 0.1375 0.0687 0.033 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Pt1 0.02129(11) 0.01402(10) 0.01666(10) 0.00018(6) 0.00180(7) -0.00315(7) N1 0.024(2) 0.0149(18) 0.0107(16) 0.0023(13) -0.0010(14) -0.0012(15) C1 0.023(2) 0.020(2) 0.020(2) -0.0015(17) 0.0023(17) -0.0014(18) C2 0.026(3) 0.023(2) 0.020(2) -0.0025(18) 0.0058(18) -0.0096(19) C3 0.028(3) 0.018(2) 0.025(2) 0.0046(18) -0.0007(19) -0.0043(19) C4 0.030(3) 0.015(2) 0.022(2) 0.0022(17) 0.0018(18) 0.0002(18) C5 0.023(2) 0.016(2) 0.014(2) 0.0025(16) -0.0067(16) -0.0011(18) C6 0.019(2) 0.0100(19) 0.015(2) 0.0001(15) -0.0056(16) -0.0038(16) C7 0.019(2) 0.020(2) 0.015(2) -0.0013(16) -0.0002(16) -0.0036(18) C8 0.031(3) 0.011(2) 0.018(2) 0.0029(16) -0.0010(18) -0.0025(18) C9 0.017(2) 0.020(2) 0.017(2) -0.0025(17) 0.0012(16) 0.0024(18) C10 0.021(2) 0.021(2) 0.0093(19) 0.0002(16) -0.0006(16) -0.0035(18) C11 0.024(2) 0.013(2) 0.014(2) -0.0004(15) -0.0046(16) -0.0057(17) F1 0.0307(15) 0.0132(12) 0.0312(14) 0.0043(10) 0.0077(11) -0.0006(10) F2 0.0234(14) 0.0201(13) 0.0281(14) -0.0006(10) 0.0104(10) 0.0006(10) C12 0.023(2) 0.018(2) 0.016(2) 0.0011(16) 0.0021(17) -0.0061(18) C13 0.023(2) 0.019(2) 0.017(2) -0.0022(16) 0.0046(17) -0.0061(18) C14 0.0164(13) 0.0161(13) 0.0194(13) 0.0006(11) 0.0011(11) -0.0032(11) C15 0.0159(11) 0.0152(11) 0.0189(12) 0.0003(9) 0.0011(9) -0.0030(10) C16B 0.0147(12) 0.0145(12) 0.0186(12) 0.0007(10) 0.0014(10) -0.0032(10) C16A 0.0146(12) 0.0137(12) 0.0181(12) 0.0000(10) 0.0016(10) -0.0031(10) C17 0.0153(12) 0.0154(11) 0.0195(12) -0.0001(9) 0.0023(9) -0.0032(10) C18 0.0159(13) 0.0164(13) 0.0195(13) -0.0008(11) 0.0031(11) -0.0035(11) C19 0.020(2) 0.014(2) 0.022(2) 0.0010(16) 0.0009(17) -0.0049(17) C20 0.017(2) 0.018(2) 0.019(2) -0.0020(16) 0.0020(16) -0.0034(17) C21 0.021(2) 0.019(2) 0.018(2) -0.0022(16) 0.0028(17) -0.0051(18) C22 0.026(2) 0.020(2) 0.019(2) 0.0026(17) 0.0012(18) -0.0094(19) C23 0.035(3) 0.026(3) 0.026(2) 0.0055(19) 0.002(2) -0.008(2) O1 0.0272(17) 0.0144(15) 0.0170(15) 0.0017(11) 0.0025(12) -0.0025(13) O2 0.0230(16) 0.0109(14) 0.0232(16) -0.0013(11) -0.0003(12) -0.0021(12) C24 0.026(3) 0.022(2) 0.030(3) 0.0029(19) 0.0042(19) -0.0009(19) C25 0.028(3) 0.014(2) 0.020(2) 0.0034(16) -0.0070(18) -0.0012(19) C26 0.026(2) 0.014(2) 0.029(2) 0.0008(17) 0.0022(19) 0.0015(18) C27 0.021(2) 0.023(2) 0.016(2) -0.0050(17) -0.0032(17) -0.0025(18) C28 0.019(2) 0.018(2) 0.027(2) -0.0015(18) 0.0037(18) -0.0001(18) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Pt1 C6 1.960(4) . ? Pt1 N1 1.991(3) . ? Pt1 O1 2.004(3) . ? Pt1 O2 2.084(3) . ? N1 C1 1.355(5) . ? N1 C5 1.364(5) . ? C1 C2 1.368(5) . ? C1 H1 0.9500 . ? C2 C3 1.382(6) . ? C2 H2 0.9500 . ? C3 C4 1.379(5) . ? C3 H3 0.9500 . ? C4 C5 1.397(5) . ? C4 H4 0.9500 . ? C5 C7 1.469(5) . ? C6 C11 1.401(5) . ? C6 C7 1.418(5) . ? C7 C8 1.386(5) . ? C8 F1 1.365(4) . ? C8 C9 1.379(5) . ? C9 F2 1.360(4) . ? C9 C10 1.385(5) . ? C10 C11 1.398(5) . ? C10 C12 1.518(5) . ? C11 H11 0.9500 . ? C12 C13 1.527(5) . ? C12 H12 0.9900 . ? C12 H12A 0.9900 . ? C13 C14 1.527(5) . ? C13 H13 0.9900 . ? C13 H13A 0.9900 . ? C14 C15 1.517(5) . ? C14 H14 0.9900 . ? C14 H14A 0.9900 . ? C15 C16B 1.466(15) . ? C15 C16A 1.548(7) . ? C15 H15 0.9900 . ? C15 H15A 0.9900 . ? C15 H15B 0.9900 . ? C15 H15C 0.9900 . ? C16B C17 1.452(15) . ? C16B H16B 0.9900 . ? C16B H16C 0.9900 . ? C16A C17 1.558(7) . ? C16A H16A 0.9900 . ? C16A H16D 0.9900 . ? C17 C18 1.532(5) . ? C17 H17 0.9900 . ? C17 H17A 0.9900 . ? C17 H17B 0.9900 . ? C17 H17C 0.9900 . ? C18 C19 1.517(5) . ? C18 H18 0.9900 . ? C18 H18A 0.9900 . ? C19 C20 1.532(5) . ? C19 H19 0.9900 . ? C19 H19A 0.9900 . ? C20 C21 1.520(5) . ? C20 H20 0.9900 . ? C20 H20A 0.9900 . ? C21 C22 1.517(5) . ? C21 H21 0.9900 . ? C21 H21A 0.9900 . ? C22 C23 1.518(6) . ? C22 H22 0.9900 . ? C22 H22A 0.9900 . ? C23 H23 0.9800 . ? C23 H23A 0.9800 . ? C23 H23B 0.9800 . ? O1 C25 1.282(5) . ? O2 C27 1.273(5) . ? C24 C25 1.513(5) . ? C24 H24 0.9800 . ? C24 H24A 0.9800 . ? C24 H24B 0.9800 . ? C25 C26 1.387(6) . ? C26 C27 1.410(5) . ? C26 H26 0.9500 . ? C27 C28 1.499(5) . ? C28 H28 0.9800 . ? C28 H28A 0.9800 . ? C28 H28B 0.9800 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C6 Pt1 N1 81.91(14) . . ? C6 Pt1 O1 91.87(13) . . ? N1 Pt1 O1 173.75(11) . . ? C6 Pt1 O2 176.31(12) . . ? N1 Pt1 O2 94.40(12) . . ? O1 Pt1 O2 91.82(10) . . ? C1 N1 C5 119.4(3) . . ? C1 N1 Pt1 123.9(3) . . ? C5 N1 Pt1 116.6(3) . . ? N1 C1 C2 122.3(4) . . ? N1 C1 H1 118.9 . . ? C2 C1 H1 118.9 . . ? C1 C2 C3 118.9(4) . . ? C1 C2 H2 120.5 . . ? C3 C2 H2 120.5 . . ? C4 C3 C2 119.8(4) . . ? C4 C3 H3 120.1 . . ? C2 C3 H3 120.1 . . ? C3 C4 C5 119.6(4) . . ? C3 C4 H4 120.2 . . ? C5 C4 H4 120.2 . . ? N1 C5 C4 120.0(4) . . ? N1 C5 C7 112.4(3) . . ? C4 C5 C7 127.6(4) . . ? C11 C6 C7 118.4(4) . . ? C11 C6 Pt1 127.6(3) . . ? C7 C6 Pt1 114.0(3) . . ? C8 C7 C6 118.6(4) . . ? C8 C7 C5 126.4(4) . . ? C6 C7 C5 115.1(4) . . ? F1 C8 C9 117.2(4) . . ? F1 C8 C7 121.5(3) . . ? C9 C8 C7 121.3(4) . . ? F2 C9 C8 118.4(4) . . ? F2 C9 C10 119.4(3) . . ? C8 C9 C10 122.2(4) . . ? C9 C10 C11 116.6(3) . . ? C9 C10 C12 120.2(4) . . ? C11 C10 C12 123.2(3) . . ? C10 C11 C6 123.0(4) . . ? C10 C11 H11 118.5 . . ? C6 C11 H11 118.5 . . ? C10 C12 C13 115.8(3) . . ? C10 C12 H12 108.3 . . ? C13 C12 H12 108.3 . . ? C10 C12 H12A 108.3 . . ? C13 C12 H12A 108.3 . . ? H12 C12 H12A 107.4 . . ? C12 C13 C14 112.3(3) . . ? C12 C13 H13 109.1 . . ? C14 C13 H13 109.1 . . ? C12 C13 H13A 109.1 . . ? C14 C13 H13A 109.1 . . ? H13 C13 H13A 107.9 . . ? C15 C14 C13 112.4(3) . . ? C15 C14 H14 109.1 . . ? C13 C14 H14 109.1 . . ? C15 C14 H14A 109.1 . . ? C13 C14 H14A 109.1 . . ? H14 C14 H14A 107.9 . . ? C16B C15 C14 121.6(7) . . ? C16B C15 C16A 20.3(5) . . ? C14 C15 C16A 112.5(4) . . ? C16B C15 H15 117.3 . . ? C14 C15 H15 109.1 . . ? C16A C15 H15 109.1 . . ? C16B C15 H15A 88.8 . . ? C14 C15 H15A 109.1 . . ? C16A C15 H15A 109.1 . . ? H15 C15 H15A 107.8 . . ? C16B C15 H15B 106.9 . . ? C14 C15 H15B 106.9 . . ? C16A C15 H15B 126.7 . . ? H15 C15 H15B 89.4 . . ? H15A C15 H15B 21.2 . . ? C16B C15 H15C 106.9 . . ? C14 C15 H15C 106.9 . . ? C16A C15 H15C 94.7 . . ? H15 C15 H15C 17.8 . . ? H15A C15 H15C 123.9 . . ? H15B C15 H15C 106.7 . . ? C17 C16B C15 122.4(11) . . ? C17 C16B H16B 106.7 . . ? C15 C16B H16B 106.7 . . ? C17 C16B H16C 106.7 . . ? C15 C16B H16C 106.7 . . ? H16B C16B H16C 106.6 . . ? C15 C16A C17 110.8(4) . . ? C15 C16A H16A 109.5 . . ? C17 C16A H16A 109.5 . . ? C15 C16A H16D 109.5 . . ? C17 C16A H16D 109.5 . . ? H16A C16A H16D 108.1 . . ? C16B C17 C18 121.4(6) . . ? C16B C17 C16A 20.1(5) . . ? C18 C17 C16A 112.3(4) . . ? C16B C17 H17 89.0 . . ? C18 C17 H17 109.1 . . ? C16A C17 H17 109.1 . . ? C16B C17 H17A 117.3 . . ? C18 C17 H17A 109.1 . . ? C16A C17 H17A 109.1 . . ? H17 C17 H17A 107.9 . . ? C16B C17 H17B 107.0 . . ? C18 C17 H17B 107.0 . . ? C16A C17 H17B 94.9 . . ? H17 C17 H17B 123.7 . . ? H17A C17 H17B 17.6 . . ? C16B C17 H17C 107.0 . . ? C18 C17 H17C 107.0 . . ? C16A C17 H17C 126.7 . . ? H17 C17 H17C 21.0 . . ? H17A C17 H17C 89.6 . . ? H17B C17 H17C 106.7 . . ? C19 C18 C17 113.6(3) . . ? C19 C18 H18 108.9 . . ? C17 C18 H18 108.9 . . ? C19 C18 H18A 108.9 . . ? C17 C18 H18A 108.9 . . ? H18 C18 H18A 107.7 . . ? C18 C19 C20 113.6(3) . . ? C18 C19 H19 108.8 . . ? C20 C19 H19 108.8 . . ? C18 C19 H19A 108.8 . . ? C20 C19 H19A 108.8 . . ? H19 C19 H19A 107.7 . . ? C21 C20 C19 114.1(3) . . ? C21 C20 H20 108.7 . . ? C19 C20 H20 108.7 . . ? C21 C20 H20A 108.7 . . ? C19 C20 H20A 108.7 . . ? H20 C20 H20A 107.6 . . ? C22 C21 C20 113.7(3) . . ? C22 C21 H21 108.8 . . ? C20 C21 H21 108.8 . . ? C22 C21 H21A 108.8 . . ? C20 C21 H21A 108.8 . . ? H21 C21 H21A 107.7 . . ? C21 C22 C23 113.5(4) . . ? C21 C22 H22 108.9 . . ? C23 C22 H22 108.9 . . ? C21 C22 H22A 108.9 . . ? C23 C22 H22A 108.9 . . ? H22 C22 H22A 107.7 . . ? C22 C23 H23 109.5 . . ? C22 C23 H23A 109.5 . . ? H23 C23 H23A 109.5 . . ? C22 C23 H23B 109.5 . . ? H23 C23 H23B 109.5 . . ? H23A C23 H23B 109.5 . . ? C25 O1 Pt1 125.0(3) . . ? C27 O2 Pt1 124.0(2) . . ? C25 C24 H24 109.5 . . ? C25 C24 H24A 109.5 . . ? H24 C24 H24A 109.5 . . ? C25 C24 H24B 109.5 . . ? H24 C24 H24B 109.5 . . ? H24A C24 H24B 109.5 . . ? O1 C25 C26 126.5(4) . . ? O1 C25 C24 113.2(4) . . ? C26 C25 C24 120.3(4) . . ? C25 C26 C27 127.7(4) . . ? C25 C26 H26 116.2 . . ? C27 C26 H26 116.2 . . ? O2 C27 C26 125.0(4) . . ? O2 C27 C28 114.9(3) . . ? C26 C27 C28 120.1(4) . . ? C27 C28 H28 109.5 . . ? C27 C28 H28A 109.5 . . ? H28 C28 H28A 109.5 . . ? C27 C28 H28B 109.5 . . ? H28 C28 H28B 109.5 . . ? H28A C28 H28B 109.5 . . ? _diffrn_measured_fraction_theta_max 0.991 _diffrn_reflns_theta_full 27.52 _diffrn_measured_fraction_theta_full 0.991 _refine_diff_density_max 1.820 _refine_diff_density_min -1.232 _refine_diff_density_rms 0.153