# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2012


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#  This CIF contains data from an original supplementary publication 
#  deposited with the CCDC, and may include chemical, crystal,   
#  experimental, refinement, atomic coordinates, 
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted. 
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data_2
_database_code_depnum_ccdc_archive 'CCDC 875487'
#TrackingRef '2.cif'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C11 H16 Ag4 N2 O11'
_chemical_formula_weight         783.74

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P b c n'
_symmetry_space_group_name_Hall  '-P 2n 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z+1/2'
'-x, y, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y-1/2, -z-1/2'
'x, -y, z-1/2'
'-x-1/2, y-1/2, z'

_cell_length_a                   25.0570(16)
_cell_length_b                   11.1882(4)
_cell_length_c                   13.0591(9)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     3661.0(4)
_cell_formula_units_Z            8
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    1535
_cell_measurement_theta_min      3.0374
_cell_measurement_theta_max      29.1810

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.844
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2976
_exptl_absorpt_coefficient_mu    4.277
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4817
_exptl_absorpt_correction_T_max  0.5132
_exptl_absorpt_process_details   SADABS

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            8683
_diffrn_reflns_av_R_equivalents  0.0440
_diffrn_reflns_av_sigmaI/netI    0.0548
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_theta_min         3.04
_diffrn_reflns_theta_max         25.00
_reflns_number_total             3224
_reflns_number_gt                2342
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.2000P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3224
_refine_ls_number_parameters     264
_refine_ls_number_restraints     58
_refine_ls_R_factor_all          0.1059
_refine_ls_R_factor_gt           0.0815
_refine_ls_wR_factor_ref         0.2981
_refine_ls_wR_factor_gt          0.2761
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_restrained_S_all      1.083
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.75079(4) 0.48524(11) 0.32996(13) 0.0508(5) Uani 1 1 d . . .
Ag2 Ag 0.70944(6) 0.23585(12) 0.30914(15) 0.0627(6) Uani 1 1 d . . .
Ag3 Ag 0.60571(6) 0.22655(14) 0.17543(12) 0.0554(5) Uani 1 1 d . . .
C1 C 0.5539(5) 0.6016(12) 0.3954(10) 0.032(3) Uani 1 1 d . . .
C2 C 0.6039(4) 0.6657(12) 0.4027(10) 0.032(3) Uani 1 1 d D A .
C3 C 0.6050(5) 0.7948(12) 0.4065(11) 0.031(3) Uani 1 1 d . . .
C4 C 0.5559(5) 0.8597(9) 0.4042(10) 0.030(3) Uani 1 1 d D . .
C5 C 0.5076(5) 0.7981(12) 0.3966(10) 0.026(3) Uani 1 1 d U . .
H5 H 0.4757 0.8401 0.3928 0.031 Uiso 1 1 calc R . .
C6 C 0.5075(5) 0.6743(13) 0.3946(11) 0.035(3) Uani 1 1 d . . .
H6 H 0.4745 0.6360 0.3927 0.042 Uiso 1 1 calc R . .
C7 C 0.5510(6) 0.4735(12) 0.3876(14) 0.045(4) Uani 1 1 d U . .
C8 C 0.6541(5) 0.5978(12) 0.4017(12) 0.037(3) Uani 1 1 d D . .
C9 C 0.6563(6) 0.8566(11) 0.4077(13) 0.038(4) Uani 1 1 d . . .
C10 C 0.5563(5) 0.9904(9) 0.4102(10) 0.027(3) Uani 1 1 d DU . .
C11 C 0.6214(7) 0.2377(12) 0.4496(14) 0.042(4) Uani 1 1 d U . .
H11A H 0.6088 0.3087 0.4830 0.063 Uiso 1 1 calc R B .
H11B H 0.6097 0.1687 0.4870 0.063 Uiso 1 1 calc R . .
H11C H 0.6074 0.2345 0.3812 0.063 Uiso 1 1 calc R . .
N1 N 0.6078(6) 0.4147(15) 0.1673(12) 0.064(4) Uani 1 1 d . . .
H1A H 0.6239 0.4370 0.1097 0.096 Uiso 1 1 calc R B .
H1B H 0.6257 0.4434 0.2208 0.096 Uiso 1 1 calc R . .
H1C H 0.5746 0.4432 0.1681 0.096 Uiso 1 1 calc R . .
N2 N 0.5990(6) 0.0371(13) 0.1790(10) 0.054(4) Uani 1 1 d . . .
H2A H 0.5668 0.0168 0.2022 0.081 Uiso 1 1 calc R B .
H2B H 0.6239 0.0071 0.2201 0.081 Uiso 1 1 calc R . .
H2C H 0.6034 0.0081 0.1161 0.081 Uiso 1 1 calc R . .
O1 O 0.5079(4) 0.4268(8) 0.3693(7) 0.0313(16) Uani 1 1 d U B .
O2 O 0.5906(6) 0.4157(13) 0.4128(11) 0.085(4) Uani 1 1 d U . .
O3 O 0.6740(4) 0.5719(9) 0.3171(8) 0.042(3) Uani 1 1 d . A .
O4 O 0.6647(13) 0.543(3) 0.483(2) 0.060(5) Uani 0.50(3) 1 d PU A 1
O4' O 0.6844(12) 0.594(3) 0.487(2) 0.060(5) Uani 0.50(3) 1 d PU A 2
O5 O 0.6854(5) 0.8492(11) 0.4872(10) 0.067(4) Uani 1 1 d . . .
O6 O 0.6721(4) 0.8993(8) 0.3240(8) 0.037(2) Uani 1 1 d . . .
O7 O 0.5921(4) 1.0439(9) 0.4518(9) 0.056(3) Uani 1 1 d . . .
O8 O 0.5162(4) 1.0422(9) 0.3675(8) 0.039(2) Uani 1 1 d . . .
O9 O 0.6693(6) 0.2391(11) 0.4464(15) 0.081(5) Uani 1 1 d . B .
H9 H 0.6886 0.2417 0.5072 0.098 Uiso 1 1 calc R . .
O2W O 0.7644(6) 0.5258(13) 0.5957(13) 0.096(5) Uani 1 1 d . . .
H2WA H 0.7363 0.5393 0.5611 0.115 Uiso 1 1 d R . .
H2WB H 0.7818 0.4689 0.5683 0.144 Uiso 1 1 d R . .
O1W O 0.790(2) 0.237(3) 0.206(4) 0.083(7) Uani 0.39(3) 1 d PU B 1
H1WA H 0.8175 0.2399 0.2446 0.124 Uiso 0.39(3) 1 d PR B 1
H1WB H 0.7900 0.2913 0.1718 0.124 Uiso 0.39(3) 1 d PR B 1
O1W' O 0.7555(15) 0.241(2) 0.182(2) 0.083(7) Uani 0.61(3) 1 d PU B 2
H1WC H 0.7500 0.1787 0.1465 0.124 Uiso 0.61(3) 1 d PR B 2
H1WD H 0.7477 0.3026 0.1469 0.124 Uiso 0.61(3) 1 d PR B 2
Ag4 Ag 0.51757(5) 0.23396(9) 0.37170(12) 0.0448(5) Uani 1 1 d U . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ag1 0.0246(8) 0.0444(8) 0.0833(12) -0.0020(6) 0.0013(5) 0.0091(5)
Ag2 0.0513(10) 0.0465(9) 0.0902(14) 0.0007(7) -0.0102(8) -0.0031(6)
Ag3 0.0415(9) 0.0666(10) 0.0580(10) 0.0030(7) -0.0095(6) -0.0038(6)
C1 0.032(7) 0.038(7) 0.025(7) -0.003(6) 0.004(6) 0.004(6)
C2 0.022(7) 0.048(8) 0.026(7) 0.002(7) 0.011(6) 0.018(6)
C3 0.020(7) 0.030(6) 0.042(8) -0.014(7) 0.000(6) 0.008(5)
C4 0.035(8) 0.030(7) 0.026(7) 0.001(6) -0.003(6) -0.007(6)
C5 0.026(3) 0.026(3) 0.026(3) -0.0002(10) 0.0003(10) 0.0006(10)
C6 0.026(7) 0.038(8) 0.039(8) 0.010(7) 0.006(6) 0.005(6)
C7 0.041(9) 0.024(7) 0.071(11) 0.018(7) 0.026(8) 0.017(6)
C8 0.031(8) 0.033(7) 0.048(9) 0.003(7) -0.012(7) 0.013(6)
C9 0.029(8) 0.027(7) 0.059(10) -0.003(7) 0.014(8) -0.003(6)
C10 0.027(3) 0.027(3) 0.027(3) -0.0001(10) 0.0008(10) -0.0007(10)
C11 0.042(4) 0.042(4) 0.043(4) 0.0003(10) -0.0001(10) 0.0001(10)
N1 0.045(9) 0.073(11) 0.074(11) -0.003(8) -0.015(8) -0.006(7)
N2 0.048(8) 0.067(10) 0.046(8) 0.003(7) -0.009(6) -0.005(7)
O1 0.0327(19) 0.0285(16) 0.0327(19) -0.0002(10) -0.0005(10) 0.0010(10)
O2 0.084(4) 0.084(4) 0.085(4) 0.0004(10) 0.0002(10) 0.0003(10)
O3 0.035(6) 0.048(6) 0.045(6) -0.010(5) 0.002(5) 0.012(5)
O4 0.060(5) 0.060(5) 0.060(5) 0.0000(7) 0.0000(7) 0.0002(7)
O4' 0.060(5) 0.060(5) 0.060(5) 0.0000(7) 0.0000(7) 0.0002(7)
O5 0.053(7) 0.081(9) 0.066(8) 0.011(7) -0.028(6) -0.018(7)
O6 0.031(5) 0.028(5) 0.053(6) -0.006(5) 0.010(5) -0.012(4)
O7 0.052(7) 0.042(6) 0.073(8) -0.003(6) -0.007(6) -0.022(5)
O8 0.034(6) 0.032(5) 0.051(6) 0.001(5) -0.012(5) -0.001(4)
O9 0.049(9) 0.092(10) 0.103(13) -0.005(8) -0.006(9) -0.008(6)
O2W 0.094(11) 0.106(11) 0.089(12) -0.025(10) -0.023(10) 0.026(9)
O1W 0.083(7) 0.083(7) 0.083(7) 0.0000(7) 0.0000(7) 0.0000(7)
O1W' 0.083(7) 0.083(7) 0.083(7) 0.0000(7) 0.0000(7) 0.0000(7)
Ag4 0.0512(9) 0.0158(6) 0.0675(10) -0.0006(5) -0.0061(7) -0.0011(4)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O6 2.159(9) 8_755 ?
Ag1 O3 2.161(10) . ?
Ag1 Ag2 2.9881(18) 8_765 ?
Ag1 Ag2 2.9887(18) . ?
Ag2 O1W' 2.02(3) . ?
Ag2 O9 2.056(19) . ?
Ag2 O1W 2.43(5) . ?
Ag2 Ag1 2.9881(18) 8_755 ?
Ag2 Ag3 3.133(2) . ?
Ag3 N1 2.109(17) . ?
Ag3 N2 2.127(15) . ?
Ag3 Ag4 3.1508(19) 3_655 ?
Ag3 Ag4 3.384(2) . ?
C1 C6 1.419(18) . ?
C1 C7 1.439(19) . ?
C1 C2 1.447(18) . ?
C2 C3 1.44(2) . ?
C2 C8 1.469(9) . ?
C3 C4 1.428(17) . ?
C3 C9 1.461(18) . ?
C4 C5 1.396(17) . ?
C4 C10 1.465(9) . ?
C5 C6 1.39(2) . ?
C5 H5 0.9300 . ?
C6 H6 0.9300 . ?
C7 O1 1.225(18) . ?
C7 O2 1.228(19) . ?
C8 O3 1.247(17) . ?
C8 O4 1.25(3) . ?
C8 O4' 1.35(3) . ?
C9 O6 1.257(18) . ?
C9 O5 1.27(2) . ?
C10 O7 1.208(16) . ?
C10 O8 1.285(16) . ?
C11 O9 1.20(2) . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
N1 H1A 0.8900 . ?
N1 H1B 0.8900 . ?
N1 H1C 0.8900 . ?
N2 H2A 0.8900 . ?
N2 H2B 0.8900 . ?
N2 H2C 0.8900 . ?
O1 Ag4 2.172(9) . ?
O6 Ag1 2.159(9) 8_765 ?
O8 Ag4 2.146(10) 1_565 ?
O9 H9 0.9300 . ?
O2W H2WA 0.8499 . ?
O2W H2WB 0.8500 . ?
O1W H1WA 0.8498 . ?
O1W H1WB 0.7500 . ?
O1W' H1WB 1.0386 . ?
O1W' H1WC 0.8499 . ?
O1W' H1WD 0.8500 . ?
Ag4 O8 2.146(10) 1_545 ?
Ag4 Ag3 3.1508(19) 3_655 ?
Ag4 Ag4 3.298(3) 3_655 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Ag1 O3 173.5(4) 8_755 . ?
O6 Ag1 Ag2 96.7(3) 8_755 8_765 ?
O3 Ag1 Ag2 82.4(3) . 8_765 ?
O6 Ag1 Ag2 83.8(3) 8_755 . ?
O3 Ag1 Ag2 95.9(3) . . ?
Ag2 Ag1 Ag2 169.53(10) 8_765 . ?
O1W' Ag2 O9 173.9(11) . . ?
O1W' Ag2 O1W 21.6(13) . . ?
O9 Ag2 O1W 152.9(14) . . ?
O1W' Ag2 Ag1 84.9(8) . 8_755 ?
O9 Ag2 Ag1 95.8(4) . 8_755 ?
O1W Ag2 Ag1 77.3(9) . 8_755 ?
O1W' Ag2 Ag1 81.3(7) . . ?
O9 Ag2 Ag1 94.2(4) . . ?
O1W Ag2 Ag1 75.8(8) . . ?
Ag1 Ag2 Ag1 138.78(6) 8_755 . ?
O1W' Ag2 Ag3 91.0(11) . . ?
O9 Ag2 Ag3 94.6(4) . . ?
O1W Ag2 Ag3 112.5(13) . . ?
Ag1 Ag2 Ag3 107.23(6) 8_755 . ?
Ag1 Ag2 Ag3 111.67(6) . . ?
N1 Ag3 N2 176.5(6) . . ?
N1 Ag3 Ag2 88.5(4) . . ?
N2 Ag3 Ag2 95.0(4) . . ?
N1 Ag3 Ag4 89.3(4) . 3_655 ?
N2 Ag3 Ag4 87.3(4) . 3_655 ?
Ag2 Ag3 Ag4 157.12(7) . 3_655 ?
N1 Ag3 Ag4 91.7(4) . . ?
N2 Ag3 Ag4 87.5(4) . . ?
Ag2 Ag3 Ag4 96.80(6) . . ?
Ag4 Ag3 Ag4 60.50(5) 3_655 . ?
C6 C1 C7 122.0(13) . . ?
C6 C1 C2 115.2(12) . . ?
C7 C1 C2 122.8(12) . . ?
C1 C2 C3 120.9(9) . . ?
C1 C2 C8 118.9(12) . . ?
C3 C2 C8 120.1(11) . . ?
C4 C3 C2 119.4(10) . . ?
C4 C3 C9 121.2(11) . . ?
C2 C3 C9 119.4(10) . . ?
C5 C4 C3 119.8(10) . . ?
C5 C4 C10 120.1(12) . . ?
C3 C4 C10 120.1(12) . . ?
C4 C5 C6 119.8(11) . . ?
C4 C5 H5 120.1 . . ?
C6 C5 H5 120.1 . . ?
C5 C6 C1 124.7(12) . . ?
C5 C6 H6 117.6 . . ?
C1 C6 H6 117.6 . . ?
O1 C7 O2 122.7(14) . . ?
O1 C7 C1 118.8(13) . . ?
O2 C7 C1 117.8(16) . . ?
O3 C8 O4 123.5(15) . . ?
O3 C8 O4' 120.0(15) . . ?
O3 C8 C2 118.1(12) . . ?
O4 C8 C2 115.3(17) . . ?
O4' C8 C2 119.4(16) . . ?
O6 C9 O5 123.7(13) . . ?
O6 C9 C3 116.6(15) . . ?
O5 C9 C3 118.9(14) . . ?
O7 C10 O8 123.5(11) . . ?
O7 C10 C4 121.5(12) . . ?
O8 C10 C4 115.0(11) . . ?
O9 C11 H11A 109.5 . . ?
O9 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
O9 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
Ag3 N1 H1A 109.5 . . ?
Ag3 N1 H1B 109.5 . . ?
H1A N1 H1B 109.5 . . ?
Ag3 N1 H1C 109.5 . . ?
H1A N1 H1C 109.5 . . ?
H1B N1 H1C 109.5 . . ?
Ag3 N2 H2A 109.5 . . ?
Ag3 N2 H2B 109.5 . . ?
H2A N2 H2B 109.5 . . ?
Ag3 N2 H2C 109.5 . . ?
H2A N2 H2C 109.5 . . ?
H2B N2 H2C 109.5 . . ?
C7 O1 Ag4 108.8(8) . . ?
C8 O3 Ag1 113.1(8) . . ?
C9 O6 Ag1 114.8(9) . 8_765 ?
C10 O8 Ag4 115.3(8) . 1_565 ?
C11 O9 Ag2 121.2(16) . . ?
C11 O9 H9 119.4 . . ?
Ag2 O9 H9 119.4 . . ?
H2WA O2W H2WB 109.5 . . ?
Ag2 O1W H1WA 109.9 . . ?
Ag2 O1W H1WB 109.1 . . ?
H1WA O1W H1WB 109.5 . . ?
Ag2 O1W H1WC 73.2 . . ?
H1WA O1W H1WC 154.6 . . ?
H1WB O1W H1WC 92.3 . . ?
Ag2 O1W' H1WB 126.6 . . ?
Ag2 O1W' H1WC 109.4 . . ?
H1WB O1W' H1WC 120.5 . . ?
Ag2 O1W' H1WD 109.5 . . ?
H1WB O1W' H1WD 71.7 . . ?
H1WC O1W' H1WD 109.5 . . ?
O8 Ag4 O1 172.3(4) 1_545 . ?
O8 Ag4 Ag3 87.3(2) 1_545 3_655 ?
O1 Ag4 Ag3 85.0(2) . 3_655 ?
O8 Ag4 Ag4 88.4(3) 1_545 3_655 ?
O1 Ag4 Ag4 87.5(2) . 3_655 ?
Ag3 Ag4 Ag4 63.26(5) 3_655 3_655 ?
O8 Ag4 Ag3 88.1(3) 1_545 . ?
O1 Ag4 Ag3 95.0(2) . . ?
Ag3 Ag4 Ag3 119.42(5) 3_655 . ?
Ag4 Ag4 Ag3 56.24(5) 3_655 . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O6 Ag1 Ag2 O1W' -56.4(11) 8_755 . . . ?
O3 Ag1 Ag2 O1W' 117.0(11) . . . . ?
Ag2 Ag1 Ag2 O1W' 36.5(11) 8_765 . . . ?
O6 Ag1 Ag2 O9 119.3(5) 8_755 . . . ?
O3 Ag1 Ag2 O9 -67.3(5) . . . . ?
Ag2 Ag1 Ag2 O9 -147.8(5) 8_765 . . . ?
O6 Ag1 Ag2 O1W -35.1(14) 8_755 . . . ?
O3 Ag1 Ag2 O1W 138.3(14) . . . . ?
Ag2 Ag1 Ag2 O1W 57.8(14) 8_765 . . . ?
O6 Ag1 Ag2 Ag1 15.6(3) 8_755 . . 8_755 ?
O3 Ag1 Ag2 Ag1 -171.0(3) . . . 8_755 ?
Ag2 Ag1 Ag2 Ag1 108.5(2) 8_765 . . 8_755 ?
O6 Ag1 Ag2 Ag3 -144.0(3) 8_755 . . . ?
O3 Ag1 Ag2 Ag3 29.4(3) . . . . ?
Ag2 Ag1 Ag2 Ag3 -51.1(2) 8_765 . . . ?
O1W' Ag2 Ag3 N1 -85.2(8) . . . . ?
O9 Ag2 Ag3 N1 92.3(6) . . . . ?
O1W Ag2 Ag3 N1 -87.2(10) . . . . ?
Ag1 Ag2 Ag3 N1 -170.2(4) 8_755 . . . ?
Ag1 Ag2 Ag3 N1 -4.1(4) . . . . ?
O1W' Ag2 Ag3 N2 95.2(8) . . . . ?
O9 Ag2 Ag3 N2 -87.3(5) . . . . ?
O1W Ag2 Ag3 N2 93.2(9) . . . . ?
Ag1 Ag2 Ag3 N2 10.2(4) 8_755 . . . ?
Ag1 Ag2 Ag3 N2 176.3(4) . . . . ?
O1W' Ag2 Ag3 Ag4 -169.9(7) . . . 3_655 ?
O9 Ag2 Ag3 Ag4 7.6(4) . . . 3_655 ?
O1W Ag2 Ag3 Ag4 -171.9(9) . . . 3_655 ?
Ag1 Ag2 Ag3 Ag4 105.07(15) 8_755 . . 3_655 ?
Ag1 Ag2 Ag3 Ag4 -88.85(16) . . . 3_655 ?
O1W' Ag2 Ag3 Ag4 -176.7(7) . . . . ?
O9 Ag2 Ag3 Ag4 0.8(4) . . . . ?
O1W Ag2 Ag3 Ag4 -178.7(9) . . . . ?
Ag1 Ag2 Ag3 Ag4 98.28(7) 8_755 . . . ?
Ag1 Ag2 Ag3 Ag4 -95.64(7) . . . . ?
C6 C1 C2 C3 -1.2(18) . . . . ?
C7 C1 C2 C3 177.6(14) . . . . ?
C6 C1 C2 C8 -178.7(13) . . . . ?
C7 C1 C2 C8 0(2) . . . . ?
C1 C2 C3 C4 0.6(19) . . . . ?
C8 C2 C3 C4 178.0(14) . . . . ?
C1 C2 C3 C9 -176.4(14) . . . . ?
C8 C2 C3 C9 1(2) . . . . ?
C2 C3 C4 C5 -1(2) . . . . ?
C9 C3 C4 C5 176.0(14) . . . . ?
C2 C3 C4 C10 178.7(12) . . . . ?
C9 C3 C4 C10 -4(2) . . . . ?
C3 C4 C5 C6 2.0(19) . . . . ?
C10 C4 C5 C6 -177.7(12) . . . . ?
C4 C5 C6 C1 -2.9(19) . . . . ?
C7 C1 C6 C5 -176.5(14) . . . . ?
C2 C1 C6 C5 2.4(19) . . . . ?
C6 C1 C7 O1 8(2) . . . . ?
C2 C1 C7 O1 -171.2(14) . . . . ?
C6 C1 C7 O2 -163.1(15) . . . . ?
C2 C1 C7 O2 18(2) . . . . ?
C1 C2 C8 O3 86.0(17) . . . . ?
C3 C2 C8 O3 -91.5(17) . . . . ?
C1 C2 C8 O4 -75(2) . . . . ?
C3 C2 C8 O4 108(2) . . . . ?
C1 C2 C8 O4' -112(2) . . . . ?
C3 C2 C8 O4' 71(2) . . . . ?
C4 C3 C9 O6 -76.9(17) . . . . ?
C2 C3 C9 O6 100.0(15) . . . . ?
C4 C3 C9 O5 113.1(17) . . . . ?
C2 C3 C9 O5 -69.9(18) . . . . ?
C5 C4 C10 O7 153.2(14) . . . . ?
C3 C4 C10 O7 -27(2) . . . . ?
C5 C4 C10 O8 -27.3(19) . . . . ?
C3 C4 C10 O8 153.0(13) . . . . ?
O2 C7 O1 Ag4 -7(2) . . . . ?
C1 C7 O1 Ag4 -176.7(12) . . . . ?
O4 C8 O3 Ag1 -26(3) . . . . ?
O4' C8 O3 Ag1 13(2) . . . . ?
C2 C8 O3 Ag1 175.2(10) . . . . ?
Ag2 Ag1 O3 C8 -93.0(10) 8_765 . . . ?
Ag2 Ag1 O3 C8 97.4(10) . . . . ?
O5 C9 O6 Ag1 -8.9(18) . . . 8_765 ?
C3 C9 O6 Ag1 -178.4(8) . . . 8_765 ?
O7 C10 O8 Ag4 1.4(18) . . . 1_565 ?
C4 C10 O8 Ag4 -178.1(9) . . . 1_565 ?
O1W Ag2 O9 C11 179(2) . . . . ?
Ag1 Ag2 O9 C11 -108.2(12) 8_755 . . . ?
Ag1 Ag2 O9 C11 111.8(12) . . . . ?
Ag3 Ag2 O9 C11 -0.3(13) . . . . ?
C7 O1 Ag4 Ag3 179.0(10) . . . 3_655 ?
C7 O1 Ag4 Ag4 -117.6(10) . . . 3_655 ?
C7 O1 Ag4 Ag3 -61.8(10) . . . . ?
N1 Ag3 Ag4 O8 177.6(4) . . . 1_545 ?
N2 Ag3 Ag4 O8 1.0(4) . . . 1_545 ?
Ag2 Ag3 Ag4 O8 -93.7(2) . . . 1_545 ?
Ag4 Ag3 Ag4 O8 89.3(2) 3_655 . . 1_545 ?
N1 Ag3 Ag4 O1 4.6(4) . . . . ?
N2 Ag3 Ag4 O1 -171.9(4) . . . . ?
Ag2 Ag3 Ag4 O1 93.4(2) . . . . ?
Ag4 Ag3 Ag4 O1 -83.6(2) 3_655 . . . ?
N1 Ag3 Ag4 Ag3 91.7(4) . . . 3_655 ?
N2 Ag3 Ag4 Ag3 -84.8(4) . . . 3_655 ?
Ag2 Ag3 Ag4 Ag3 -179.56(4) . . . 3_655 ?
Ag4 Ag3 Ag4 Ag3 3.47(7) 3_655 . . 3_655 ?
N1 Ag3 Ag4 Ag4 88.3(4) . . . 3_655 ?
N2 Ag3 Ag4 Ag4 -88.3(4) . . . 3_655 ?
Ag2 Ag3 Ag4 Ag4 176.97(5) . . . 3_655 ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2W H2WB O5 0.85 1.89 2.737(19) 170.6 8_755
O2W H2WA O4 0.85 2.06 2.91(3) 170.5 .
O1W H1WB O2W 0.75 2.36 3.08(4) 161.5 7_565
O1W H1WA O6 0.85 2.08 2.56(5) 115.2 8_755

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         1.775
_refine_diff_density_min         -1.997
_refine_diff_density_rms         0.256


data_3
_database_code_depnum_ccdc_archive 'CCDC 875488'
#TrackingRef '3.cif'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C11 H5 Ag5 O12'
_chemical_formula_weight         868.50

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'P b c n'
_symmetry_space_group_name_Hall  '-P 2n 2ab'

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y, z-1/2'

_cell_length_a                   18.1669(13)
_cell_length_b                   13.5876(7)
_cell_length_c                   6.4273(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_volume                     1586.54(17)
_cell_formula_units_Z            4
_cell_measurement_temperature    296
_cell_measurement_reflns_used    1185
_cell_measurement_theta_min      2.9925
_cell_measurement_theta_max      28.9985

_exptl_crystal_description       ?
_exptl_crystal_colour            ?
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.636
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1608
_exptl_absorpt_coefficient_mu    6.131
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.3735
_exptl_absorpt_correction_T_max  0.4049
_exptl_absorpt_process_details   SADABS(2009)

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      296
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            3851
_diffrn_reflns_av_R_equivalents  0.0549
_diffrn_reflns_av_sigmaI/netI    0.0536
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_l_min       -5
_diffrn_reflns_limit_l_max       7
_diffrn_reflns_theta_min         3.00
_diffrn_reflns_theta_max         25.00
_reflns_number_total             1401
_reflns_number_gt                1179
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.1194P)^2^+7.6477P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         1401
_refine_ls_number_parameters     133
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0621
_refine_ls_R_factor_gt           0.0547
_refine_ls_wR_factor_ref         0.1832
_refine_ls_wR_factor_gt          0.1742
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_restrained_S_all      1.047
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.22896(5) 0.65128(6) 0.10818(15) 0.0387(4) Uani 1 1 d . . .
Ag2 Ag 0.28646(5) 0.56287(7) 0.49006(14) 0.0394(4) Uani 1 1 d . . .
Ag3 Ag 0.07985(14) 0.74694(17) 0.2403(3) 0.0586(7) Uani 0.50 1 d P . .
O3 O 0.3308(5) 0.7380(6) 0.0597(14) 0.0400(19) Uani 1 1 d . . .
O2 O 0.3412(4) 0.7180(5) 0.4017(12) 0.0374(19) Uani 1 1 d . . .
C6 C 0.3621(6) 0.7514(6) 0.2318(17) 0.025(2) Uani 1 1 d . . .
O1 O 0.4570(5) 0.6065(5) 0.1274(12) 0.0396(19) Uani 1 1 d . . .
C1 C 0.5000 0.7597(9) 0.2500 0.020(3) Uani 1 2 d S . .
C4 C 0.5000 0.9658(9) 0.2500 0.018(3) Uani 1 2 d S . .
H4 H 0.5000 1.0343 0.2500 0.021 Uiso 1 2 calc SR . .
C5 C 0.5000 0.6490(10) 0.2500 0.026(3) Uani 1 2 d S . .
C3 C 0.4326(5) 0.9148(6) 0.2371(14) 0.0186(18) Uani 1 1 d . . .
C2 C 0.4328(5) 0.8108(7) 0.2352(12) 0.0206(19) Uani 1 1 d . . .
C7 C 0.3621(6) 0.9737(7) 0.2266(14) 0.025(2) Uani 1 1 d . . .
O4 O 0.3022(4) 0.9300(5) 0.2478(13) 0.0302(16) Uani 1 1 d . . .
O5 O 0.3694(4) 1.0655(4) 0.2000(12) 0.0289(17) Uani 1 1 d . . .
O1W O 0.3736(5) 0.4634(6) 0.3041(11) 0.0384(19) Uani 1 1 d . . .
H1WA H 0.3982 0.4291 0.3901 0.058 Uiso 1 1 d R . .
H1WB H 0.4025 0.5005 0.2360 0.058 Uiso 1 1 d R . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ag1 0.0348(6) 0.0289(6) 0.0524(7) 0.0092(4) -0.0107(4) -0.0145(3)
Ag2 0.0414(7) 0.0381(6) 0.0386(6) 0.0066(4) 0.0066(4) -0.0065(4)
Ag3 0.0662(15) 0.0608(14) 0.0487(12) -0.0102(10) 0.0053(11) 0.0010(11)
O3 0.035(4) 0.028(4) 0.057(5) -0.001(4) -0.021(4) -0.008(3)
O2 0.039(4) 0.015(3) 0.058(5) 0.005(3) 0.021(4) 0.000(3)
C6 0.023(5) 0.006(4) 0.045(6) -0.002(4) -0.003(5) 0.004(3)
O1 0.053(5) 0.021(4) 0.045(4) -0.009(3) -0.016(4) -0.004(4)
C1 0.024(7) 0.013(6) 0.023(6) 0.000 0.005(6) 0.000
C4 0.030(7) 0.006(5) 0.017(6) 0.000 0.005(6) 0.000
C5 0.031(8) 0.022(7) 0.026(6) 0.000 0.003(7) 0.000
C3 0.024(5) 0.014(4) 0.018(4) 0.002(3) 0.002(4) 0.001(4)
C2 0.031(5) 0.016(4) 0.014(4) 0.004(3) -0.003(4) -0.007(4)
C7 0.033(6) 0.022(5) 0.019(4) -0.004(4) 0.001(4) 0.006(4)
O4 0.019(3) 0.028(4) 0.043(4) 0.014(3) -0.004(3) -0.001(3)
O5 0.028(4) 0.010(3) 0.049(4) 0.006(3) -0.002(4) 0.006(3)
O1W 0.048(5) 0.039(4) 0.028(4) 0.008(3) -0.001(4) -0.005(4)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O5 2.213(7) 7_655 ?
Ag1 O3 2.216(8) . ?
Ag1 O2 2.558(7) 2_564 ?
Ag1 Ag2 2.9255(13) . ?
Ag1 Ag3 3.122(3) . ?
Ag1 Ag2 3.1835(12) 8_565 ?
Ag2 O4 2.312(7) 2_565 ?
Ag2 O2 2.399(7) . ?
Ag2 O1W 2.400(8) . ?
Ag2 O1W 2.589(8) 8_566 ?
Ag2 Ag1 3.1835(12) 8_566 ?
Ag3 Ag3 2.904(5) 4 ?
O3 C6 1.257(14) . ?
O2 C6 1.242(13) . ?
O2 Ag1 2.558(7) 2_565 ?
C6 C2 1.518(14) . ?
O1 C5 1.251(9) . ?
C1 C2 1.408(11) 4_655 ?
C1 C2 1.408(11) . ?
C1 C5 1.504(17) . ?
C4 C3 1.410(11) . ?
C4 C3 1.410(11) 4_655 ?
C4 H4 0.9300 . ?
C5 O1 1.251(9) 4_655 ?
C3 C2 1.413(12) . ?
C3 C7 1.513(13) . ?
C7 O4 1.247(12) . ?
C7 O5 1.266(12) . ?
O4 Ag2 2.312(7) 2_564 ?
O5 Ag1 2.213(7) 7_665 ?
O1W Ag2 2.589(8) 8_565 ?
O1W H1WA 0.8501 . ?
O1W H1WB 0.8499 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Ag1 O3 172.6(3) 7_655 . ?
O5 Ag1 O2 95.8(3) 7_655 2_564 ?
O3 Ag1 O2 88.5(3) . 2_564 ?
O5 Ag1 Ag2 81.27(19) 7_655 . ?
O3 Ag1 Ag2 92.2(2) . . ?
O2 Ag1 Ag2 153.95(18) 2_564 . ?
O5 Ag1 Ag3 56.38(18) 7_655 . ?
O3 Ag1 Ag3 122.8(2) . . ?
O2 Ag1 Ag3 54.5(2) 2_564 . ?
Ag2 Ag1 Ag3 104.63(5) . . ?
O5 Ag1 Ag2 81.21(17) 7_655 8_565 ?
O3 Ag1 Ag2 100.3(2) . 8_565 ?
O2 Ag1 Ag2 132.43(17) 2_564 8_565 ?
Ag2 Ag1 Ag2 73.00(3) . 8_565 ?
Ag3 Ag1 Ag2 136.89(5) . 8_565 ?
O4 Ag2 O2 114.9(2) 2_565 . ?
O4 Ag2 O1W 147.1(3) 2_565 . ?
O2 Ag2 O1W 95.9(3) . . ?
O4 Ag2 O1W 82.7(3) 2_565 8_566 ?
O2 Ag2 O1W 93.0(3) . 8_566 ?
O1W Ag2 O1W 84.7(2) . 8_566 ?
O4 Ag2 Ag1 109.6(2) 2_565 . ?
O2 Ag2 Ag1 65.7(2) . . ?
O1W Ag2 Ag1 92.80(17) . . ?
O1W Ag2 Ag1 158.25(19) 8_566 . ?
O4 Ag2 Ag1 68.83(17) 2_565 8_566 ?
O2 Ag2 Ag1 174.63(18) . 8_566 ?
O1W Ag2 Ag1 79.65(19) . 8_566 ?
O1W Ag2 Ag1 83.60(18) 8_566 8_566 ?
Ag1 Ag2 Ag1 117.27(4) . 8_566 ?
Ag3 Ag3 Ag1 151.46(7) 4 . ?
C6 O3 Ag1 109.3(7) . . ?
C6 O2 Ag2 131.0(6) . . ?
C6 O2 Ag1 110.7(6) . 2_565 ?
Ag2 O2 Ag1 106.3(3) . 2_565 ?
O2 C6 O3 125.7(9) . . ?
O2 C6 C2 116.1(9) . . ?
O3 C6 C2 118.1(9) . . ?
C2 C1 C2 120.8(11) 4_655 . ?
C2 C1 C5 119.6(5) 4_655 . ?
C2 C1 C5 119.6(5) . . ?
C3 C4 C3 121.0(11) . 4_655 ?
C3 C4 H4 119.5 . . ?
C3 C4 H4 119.5 4_655 . ?
O1 C5 O1 125.0(12) . 4_655 ?
O1 C5 C1 117.5(6) . . ?
O1 C5 C1 117.5(6) 4_655 . ?
C2 C3 C4 119.4(9) . . ?
C2 C3 C7 122.1(8) . . ?
C4 C3 C7 118.5(8) . . ?
C1 C2 C3 119.7(8) . . ?
C1 C2 C6 118.2(8) . . ?
C3 C2 C6 122.0(8) . . ?
O4 C7 O5 125.1(9) . . ?
O4 C7 C3 118.8(8) . . ?
O5 C7 C3 116.0(9) . . ?
C7 O4 Ag2 120.6(6) . 2_564 ?
C7 O5 Ag1 118.1(7) . 7_665 ?
Ag2 O1W Ag2 93.6(3) . 8_565 ?
Ag2 O1W H1WA 109.4 . . ?
Ag2 O1W H1WA 138.8 8_565 . ?
Ag2 O1W H1WB 109.4 . . ?
Ag2 O1W H1WB 93.4 8_565 . ?
H1WA O1W H1WB 109.5 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O5 Ag1 Ag2 O4 -43.1(3) 7_655 . . 2_565 ?
O3 Ag1 Ag2 O4 133.4(3) . . . 2_565 ?
O2 Ag1 Ag2 O4 42.4(4) 2_564 . . 2_565 ?
Ag3 Ag1 Ag2 O4 8.70(19) . . . 2_565 ?
Ag2 Ag1 Ag2 O4 -126.47(18) 8_565 . . 2_565 ?
O5 Ag1 Ag2 O2 -152.4(3) 7_655 . . . ?
O3 Ag1 Ag2 O2 24.1(3) . . . . ?
O2 Ag1 Ag2 O2 -67.0(5) 2_564 . . . ?
Ag3 Ag1 Ag2 O2 -100.61(19) . . . . ?
Ag2 Ag1 Ag2 O2 124.22(19) 8_565 . . . ?
O5 Ag1 Ag2 O1W 112.4(3) 7_655 . . . ?
O3 Ag1 Ag2 O1W -71.1(3) . . . . ?
O2 Ag1 Ag2 O1W -162.2(4) 2_564 . . . ?
Ag3 Ag1 Ag2 O1W 164.1(2) . . . . ?
Ag2 Ag1 Ag2 O1W 29.0(2) 8_565 . . . ?
O5 Ag1 Ag2 O1W -164.9(5) 7_655 . . 8_566 ?
O3 Ag1 Ag2 O1W 11.6(5) . . . 8_566 ?
O2 Ag1 Ag2 O1W -79.5(6) 2_564 . . 8_566 ?
Ag3 Ag1 Ag2 O1W -113.2(5) . . . 8_566 ?
Ag2 Ag1 Ag2 O1W 111.7(5) 8_565 . . 8_566 ?
O5 Ag1 Ag2 Ag1 32.59(18) 7_655 . . 8_566 ?
O3 Ag1 Ag2 Ag1 -150.9(2) . . . 8_566 ?
O2 Ag1 Ag2 Ag1 118.0(4) 2_564 . . 8_566 ?
Ag3 Ag1 Ag2 Ag1 84.34(6) . . . 8_566 ?
Ag2 Ag1 Ag2 Ag1 -50.82(5) 8_565 . . 8_566 ?
O5 Ag1 Ag3 Ag3 -33.6(3) 7_655 . . 4 ?
O3 Ag1 Ag3 Ag3 155.2(3) . . . 4 ?
O2 Ag1 Ag3 Ag3 95.0(3) 2_564 . . 4 ?
Ag2 Ag1 Ag3 Ag3 -102.4(2) . . . 4 ?
Ag2 Ag1 Ag3 Ag3 -21.8(3) 8_565 . . 4 ?
O2 Ag1 O3 C6 128.7(7) 2_564 . . . ?
Ag2 Ag1 O3 C6 -25.3(6) . . . . ?
Ag3 Ag1 O3 C6 83.7(7) . . . . ?
Ag2 Ag1 O3 C6 -98.4(6) 8_565 . . . ?
O4 Ag2 O2 C6 -143.5(9) 2_565 . . . ?
O1W Ag2 O2 C6 48.2(9) . . . . ?
O1W Ag2 O2 C6 133.2(9) 8_566 . . . ?
Ag1 Ag2 O2 C6 -42.2(9) . . . . ?
O4 Ag2 O2 Ag1 -5.6(4) 2_565 . . 2_565 ?
O1W Ag2 O2 Ag1 -173.9(3) . . . 2_565 ?
O1W Ag2 O2 Ag1 -88.9(3) 8_566 . . 2_565 ?
Ag1 Ag2 O2 Ag1 95.7(3) . . . 2_565 ?
Ag2 O2 C6 O3 37.0(14) . . . . ?
Ag1 O2 C6 O3 -99.5(10) 2_565 . . . ?
Ag2 O2 C6 C2 -141.0(7) . . . . ?
Ag1 O2 C6 C2 82.5(9) 2_565 . . . ?
Ag1 O3 C6 O2 2.9(12) . . . . ?
Ag1 O3 C6 C2 -179.1(6) . . . . ?
C2 C1 C5 O1 -139.2(6) 4_655 . . . ?
C2 C1 C5 O1 40.8(6) . . . . ?
C2 C1 C5 O1 40.8(6) 4_655 . . 4_655 ?
C2 C1 C5 O1 -139.2(6) . . . 4_655 ?
C3 C4 C3 C2 -0.6(6) 4_655 . . . ?
C3 C4 C3 C7 179.2(9) 4_655 . . . ?
C2 C1 C2 C3 -0.6(6) 4_655 . . . ?
C5 C1 C2 C3 179.4(6) . . . . ?
C2 C1 C2 C6 -176.6(8) 4_655 . . . ?
C5 C1 C2 C6 3.4(8) . . . . ?
C4 C3 C2 C1 1.2(11) . . . . ?
C7 C3 C2 C1 -178.6(7) . . . . ?
C4 C3 C2 C6 177.0(7) . . . . ?
C7 C3 C2 C6 -2.7(13) . . . . ?
O2 C6 C2 C1 76.5(10) . . . . ?
O3 C6 C2 C1 -101.6(9) . . . . ?
O2 C6 C2 C3 -99.4(10) . . . . ?
O3 C6 C2 C3 82.4(11) . . . . ?
C2 C3 C7 O4 10.8(13) . . . . ?
C4 C3 C7 O4 -168.9(8) . . . . ?
C2 C3 C7 O5 -170.4(8) . . . . ?
C4 C3 C7 O5 9.9(11) . . . . ?
O5 C7 O4 Ag2 59.4(12) . . . 2_564 ?
C3 C7 O4 Ag2 -121.9(7) . . . 2_564 ?
O4 C7 O5 Ag1 -15.7(13) . . . 7_665 ?
C3 C7 O5 Ag1 165.6(6) . . . 7_665 ?
O4 Ag2 O1W Ag2 99.1(5) 2_565 . . 8_565 ?
O2 Ag2 O1W Ag2 -100.7(3) . . . 8_565 ?
O1W Ag2 O1W Ag2 166.9(3) 8_566 . . 8_565 ?
Ag1 Ag2 O1W Ag2 -34.79(19) . . . 8_565 ?
Ag1 Ag2 O1W Ag2 82.43(19) 8_566 . . 8_565 ?

loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1WA O1 0.85 1.92 2.742(10) 161.0 8_566
O1W H1WB O1 0.85 1.88 2.714(11) 166.0 .

_diffrn_measured_fraction_theta_max 0.999
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.999
_refine_diff_density_max         3.639
_refine_diff_density_min         -1.268
_refine_diff_density_rms         0.272