data_stand _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'Ge4 Pd5, 2(Ba)' _chemical_formula_sum 'Ba2 Ge4 Pd5' _chemical_formula_weight 1097.04 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'Ge' 'Ge' 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Pd' 'Pd' -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Ba' 'Ba' -0.3244 2.2819 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting ? _symmetry_space_group_name_H-M 'C m c a' _symmetry_space_group_name_Hall '-C 2bc 2' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y+1/2, z+1/2' '-x, y+1/2, -z+1/2' 'x, -y, -z' 'x+1/2, y+1/2, z' '-x+1/2, -y+1, z+1/2' '-x+1/2, y+1, -z+1/2' 'x+1/2, -y+1/2, -z' '-x, -y, -z' 'x, y-1/2, -z-1/2' 'x, -y-1/2, z-1/2' '-x, y, z' '-x+1/2, -y+1/2, -z' 'x+1/2, y, -z-1/2' 'x+1/2, -y, z-1/2' '-x+1/2, y+1/2, z' _cell_length_a 10.9296(9) _cell_length_b 14.1639(12) _cell_length_c 5.8808(5) _cell_angle_alpha 90.00 _cell_angle_beta 90.00 _cell_angle_gamma 90.00 _cell_volume 910.38(13) _cell_formula_units_Z 4 _cell_measurement_temperature 173(2) _cell_measurement_reflns_used 604 _cell_measurement_theta_min 2.88 _cell_measurement_theta_max 28.31 _exptl_crystal_description needle _exptl_crystal_colour black _exptl_crystal_size_max 0.08 _exptl_crystal_size_mid 0.08 _exptl_crystal_size_min 0.06 _exptl_crystal_density_meas . _exptl_crystal_density_diffrn 8.004 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1880 _exptl_absorpt_coefficient_mu 31.029 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.1958 _exptl_absorpt_correction_T_max 0.2708 _exptl_absorpt_process_details ; SADABS (Sheldrick, 2003) ; _exptl_special_details ; Data collection is performed with four batch runs at \f = 0.00 \% (600 frames), at \f = 90.00 \% (600 frames), at \f = 180.00 \% (600 frames), and at \f = 270.00 (600 frames). Frame width = 0.30 \& in \w. Data are merged and treated with multi-scan absorption corrections. ; _diffrn_ambient_temperature 173(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'CCD area detector' _diffrn_measurement_method 'phi and omega scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 5930 _diffrn_reflns_av_R_equivalents 0.0360 _diffrn_reflns_av_sigmaI/netI 0.0181 _diffrn_reflns_limit_h_min -14 _diffrn_reflns_limit_h_max 14 _diffrn_reflns_limit_k_min -18 _diffrn_reflns_limit_k_max 18 _diffrn_reflns_limit_l_min -7 _diffrn_reflns_limit_l_max 7 _diffrn_reflns_theta_min 2.88 _diffrn_reflns_theta_max 28.31 _reflns_number_total 604 _reflns_number_gt 594 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'Bruker SMART' _computing_cell_refinement 'Bruker SMART' _computing_data_reduction 'Bruker SAINT' _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics 'Bruker SHELXTL' _computing_publication_material 'Bruker SHELXTL' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0118P)^2^+2.0699P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens . _refine_ls_hydrogen_treatment . _refine_ls_extinction_method SHELXL _refine_ls_extinction_coef 0.00266(7) _refine_ls_extinction_expression 'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin(2\q)]^-1/4^' _refine_ls_number_reflns 604 _refine_ls_number_parameters 31 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0148 _refine_ls_R_factor_gt 0.0144 _refine_ls_wR_factor_ref 0.0325 _refine_ls_wR_factor_gt 0.0322 _refine_ls_goodness_of_fit_ref 1.212 _refine_ls_restrained_S_all 1.212 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ba1 Ba 0.0000 0.357581(19) 0.03559(5) 0.01149(9) Uani 1 2 d S . . Pd1 Pd 0.2500 0.27287(2) 0.2500 0.00911(10) Uani 1 2 d S . . Pd2 Pd 0.2500 0.47629(2) 0.2500 0.01003(10) Uani 1 2 d S . . Pd3 Pd 0.0000 0.0000 0.0000 0.01287(12) Uani 1 4 d S . . Ge1 Ge 0.16875(3) 0.12426(2) 0.05896(6) 0.00953(10) Uani 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ba1 0.00997(15) 0.01526(15) 0.00923(15) -0.00004(9) 0.000 0.000 Pd1 0.01126(17) 0.00796(17) 0.00811(18) 0.000 0.00043(11) 0.000 Pd2 0.01405(18) 0.00824(17) 0.00781(18) 0.000 0.00076(12) 0.000 Pd3 0.0106(2) 0.0133(2) 0.0147(2) 0.00273(18) 0.000 0.000 Ge1 0.01188(19) 0.00890(17) 0.00782(17) -0.00003(10) 0.00067(13) -0.00069(10) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ba1 Pd1 3.2396(3) . ? Ba1 Pd1 3.2397(3) 14_456 ? Ba1 Ge1 3.3652(5) 2_554 ? Ba1 Ge1 3.3652(5) 11_565 ? Ba1 Pd3 3.3953(3) 2 ? Ba1 Pd2 3.4472(3) . ? Ba1 Pd2 3.4472(3) 14_456 ? Ba1 Ge1 3.5974(5) 11_566 ? Ba1 Ge1 3.5974(5) 2 ? Ba1 Ge1 3.6719(5) 8_455 ? Ba1 Ge1 3.6719(5) 13 ? Ba1 Pd1 3.7015(3) 2_554 ? Pd1 Ge1 2.4926(4) 11_566 ? Pd1 Ge1 2.4926(4) 13 ? Pd1 Ge1 2.5460(4) . ? Pd1 Ge1 2.5460(4) 7_545 ? Pd1 Pd2 2.8812(5) . ? Pd1 Pd1 3.0109(3) 13 ? Pd1 Pd1 3.0109(3) 13_556 ? Pd1 Ba1 3.2397(3) 14_556 ? Pd1 Ba1 3.7015(3) 2 ? Pd1 Ba1 3.7015(3) 13 ? Pd2 Ge1 2.4734(4) 13 ? Pd2 Ge1 2.4734(4) 11_566 ? Pd2 Ge1 2.5382(4) 10_566 ? Pd2 Ge1 2.5382(4) 16 ? Pd2 Pd2 3.0161(3) 6 ? Pd2 Pd2 3.0161(3) 6_554 ? Pd2 Pd3 3.1209(2) 5 ? Pd2 Pd3 3.1209(2) 2 ? Pd2 Ba1 3.4472(3) 14_556 ? Pd2 Ba1 3.9779(3) 6 ? Pd3 Ge1 2.5728(4) 9 ? Pd3 Ge1 2.5728(4) 12 ? Pd3 Ge1 2.5728(4) 4 ? Pd3 Ge1 2.5728(4) . ? Pd3 Pd2 3.1209(2) 10_556 ? Pd3 Pd2 3.1209(2) 2_554 ? Pd3 Pd2 3.1209(2) 5_445 ? Pd3 Pd2 3.1209(2) 13 ? Pd3 Ba1 3.3953(3) 2_554 ? Pd3 Ba1 3.3953(3) 10_556 ? Pd3 Ba1 3.7403(4) 10 ? Pd3 Ba1 3.7403(4) 2 ? Ge1 Pd2 2.4735(4) 13 ? Ge1 Pd1 2.4926(4) 13 ? Ge1 Pd2 2.5382(4) 10_556 ? Ge1 Ge1 2.8641(7) 7_545 ? Ge1 Ba1 3.3652(5) 2 ? Ge1 Ba1 3.5974(5) 2_554 ? Ge1 Ba1 3.6719(5) 13 ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag Pd1 Ba1 Pd1 115.007(12) . 14_456 ? Pd1 Ba1 Ge1 144.564(10) . 2_554 ? Pd1 Ba1 Ge1 83.698(8) 14_456 2_554 ? Pd1 Ba1 Ge1 83.698(8) . 11_565 ? Pd1 Ba1 Ge1 144.564(10) 14_456 11_565 ? Ge1 Ba1 Ge1 66.471(14) 2_554 11_565 ? Pd1 Ba1 Pd3 84.661(7) . 2 ? Pd1 Ba1 Pd3 84.662(7) 14_456 2 ? Ge1 Ba1 Pd3 128.650(10) 2_554 2 ? Ge1 Ba1 Pd3 128.650(9) 11_565 2 ? Pd1 Ba1 Pd2 50.930(9) . . ? Pd1 Ba1 Pd2 134.977(10) 14_456 . ? Ge1 Ba1 Pd2 134.572(10) 2_554 . ? Ge1 Ba1 Pd2 80.383(8) 11_565 . ? Pd3 Ba1 Pd2 54.267(5) 2 . ? Pd1 Ba1 Pd2 134.976(10) . 14_456 ? Pd1 Ba1 Pd2 50.932(9) 14_456 14_456 ? Ge1 Ba1 Pd2 80.383(8) 2_554 14_456 ? Ge1 Ba1 Pd2 134.572(10) 11_565 14_456 ? Pd3 Ba1 Pd2 54.266(5) 2 14_456 ? Pd2 Ba1 Pd2 104.867(11) . 14_456 ? Pd1 Ba1 Ge1 42.359(7) . 11_566 ? Pd1 Ba1 Ge1 97.234(10) 14_456 11_566 ? Ge1 Ba1 Ge1 171.177(13) 2_554 11_566 ? Ge1 Ba1 Ge1 115.224(12) 11_565 11_566 ? Pd3 Ba1 Ge1 43.055(7) 2 11_566 ? Pd2 Ba1 Ge1 41.041(6) . 11_566 ? Pd2 Ba1 Ge1 93.357(10) 14_456 11_566 ? Pd1 Ba1 Ge1 97.234(10) . 2 ? Pd1 Ba1 Ge1 42.359(7) 14_456 2 ? Ge1 Ba1 Ge1 115.224(11) 2_554 2 ? Ge1 Ba1 Ge1 171.177(13) 11_565 2 ? Pd3 Ba1 Ge1 43.055(7) 2 2 ? Pd2 Ba1 Ge1 93.357(10) . 2 ? Pd2 Ba1 Ge1 41.041(6) 14_456 2 ? Ge1 Ba1 Ge1 61.689(13) 11_566 2 ? Pd1 Ba1 Ge1 156.418(11) . 8_455 ? Pd1 Ba1 Ge1 41.694(7) 14_456 8_455 ? Ge1 Ba1 Ge1 47.787(10) 2_554 8_455 ? Ge1 Ba1 Ge1 114.136(9) 11_565 8_455 ? Pd3 Ba1 Ge1 94.599(7) 2 8_455 ? Pd2 Ba1 Ge1 143.393(10) . 8_455 ? Pd2 Ba1 Ge1 40.507(6) 14_456 8_455 ? Ge1 Ba1 Ge1 129.055(9) 11_566 8_455 ? Ge1 Ba1 Ge1 67.606(10) 2 8_455 ? Pd1 Ba1 Ge1 41.694(7) . 13 ? Pd1 Ba1 Ge1 156.418(11) 14_456 13 ? Ge1 Ba1 Ge1 114.136(9) 2_554 13 ? Ge1 Ba1 Ge1 47.787(10) 11_565 13 ? Pd3 Ba1 Ge1 94.599(7) 2 13 ? Pd2 Ba1 Ge1 40.507(6) . 13 ? Pd2 Ba1 Ge1 143.393(10) 14_456 13 ? Ge1 Ba1 Ge1 67.606(10) 11_566 13 ? Ge1 Ba1 Ge1 129.055(9) 2 13 ? Ge1 Ba1 Ge1 160.789(13) 8_455 13 ? Pd1 Ba1 Pd1 127.904(9) . 2_554 ? Pd1 Ba1 Pd1 50.885(6) 14_456 2_554 ? Ge1 Ba1 Pd1 41.897(7) 2_554 2_554 ? Ge1 Ba1 Pd1 93.717(10) 11_565 2_554 ? Pd3 Ba1 Pd1 131.419(5) 2 2_554 ? Pd2 Ba1 Pd1 174.034(8) . 2_554 ? Pd2 Ba1 Pd1 79.883(7) 14_456 2_554 ? Ge1 Ba1 Pd1 143.359(9) 11_566 2_554 ? Ge1 Ba1 Pd1 92.604(8) 2 2_554 ? Ge1 Ba1 Pd1 40.397(7) 8_455 2_554 ? Ge1 Ba1 Pd1 133.957(10) 13 2_554 ? Ge1 Pd1 Ge1 108.454(19) 11_566 13 ? Ge1 Pd1 Ge1 132.901(15) 11_566 . ? Ge1 Pd1 Ge1 106.614(10) 13 . ? Ge1 Pd1 Ge1 106.615(10) 11_566 7_545 ? Ge1 Pd1 Ge1 132.902(15) 13 7_545 ? Ge1 Pd1 Ge1 68.454(18) . 7_545 ? Ge1 Pd1 Pd2 54.227(10) 11_566 . ? Ge1 Pd1 Pd2 54.227(10) 13 . ? Ge1 Pd1 Pd2 145.773(9) . . ? Ge1 Pd1 Pd2 145.774(9) 7_545 . ? Ge1 Pd1 Pd1 146.894(14) 11_566 13 ? Ge1 Pd1 Pd1 54.122(10) 13 13 ? Ge1 Pd1 Pd1 52.492(11) . 13 ? Ge1 Pd1 Pd1 104.655(16) 7_545 13 ? Pd2 Pd1 Pd1 102.427(12) . 13 ? Ge1 Pd1 Pd1 54.122(10) 11_566 13_556 ? Ge1 Pd1 Pd1 146.894(15) 13 13_556 ? Ge1 Pd1 Pd1 104.655(16) . 13_556 ? Ge1 Pd1 Pd1 52.492(11) 7_545 13_556 ? Pd2 Pd1 Pd1 102.427(12) . 13_556 ? Pd1 Pd1 Pd1 155.15(2) 13 13_556 ? Ge1 Pd1 Ba1 76.511(11) 11_566 . ? Ge1 Pd1 Ba1 78.479(11) 13 . ? Ge1 Pd1 Ba1 80.809(10) . . ? Ge1 Pd1 Ba1 140.545(12) 7_545 . ? Pd2 Pd1 Ba1 68.263(7) . . ? Pd1 Pd1 Ba1 72.519(7) 13 . ? Pd1 Pd1 Ba1 117.373(6) 13_556 . ? Ge1 Pd1 Ba1 78.479(11) 11_566 14_556 ? Ge1 Pd1 Ba1 76.511(11) 13 14_556 ? Ge1 Pd1 Ba1 140.546(12) . 14_556 ? Ge1 Pd1 Ba1 80.810(10) 7_545 14_556 ? Pd2 Pd1 Ba1 68.263(7) . 14_556 ? Pd1 Pd1 Ba1 117.373(6) 13 14_556 ? Pd1 Pd1 Ba1 72.519(6) 13_556 14_556 ? Ba1 Pd1 Ba1 136.527(14) . 14_556 ? Ge1 Pd1 Ba1 72.427(10) 11_566 2 ? Ge1 Pd1 Ba1 152.319(9) 13 2 ? Ge1 Pd1 Ba1 61.966(10) . 2 ? Ge1 Pd1 Ba1 69.176(11) 7_545 2 ? Pd2 Pd1 Ba1 119.947(6) . 2 ? Pd1 Pd1 Ba1 109.614(10) 13 2 ? Pd1 Pd1 Ba1 56.596(7) 13_556 2 ? Ba1 Pd1 Ba1 74.863(8) . 2 ? Ba1 Pd1 Ba1 129.115(5) 14_556 2 ? Ge1 Pd1 Ba1 152.319(9) 11_566 13 ? Ge1 Pd1 Ba1 72.427(10) 13 13 ? Ge1 Pd1 Ba1 69.176(11) . 13 ? Ge1 Pd1 Ba1 61.966(10) 7_545 13 ? Pd2 Pd1 Ba1 119.947(6) . 13 ? Pd1 Pd1 Ba1 56.596(7) 13 13 ? Pd1 Pd1 Ba1 109.614(10) 13_556 13 ? Ba1 Pd1 Ba1 129.115(6) . 13 ? Ba1 Pd1 Ba1 74.863(7) 14_556 13 ? Ba1 Pd1 Ba1 120.106(12) 2 13 ? Ge1 Pd2 Ge1 109.69(2) 13 11_566 ? Ge1 Pd2 Ge1 157.837(15) 13 10_566 ? Ge1 Pd2 Ge1 91.412(13) 11_566 10_566 ? Ge1 Pd2 Ge1 91.412(13) 13 16 ? Ge1 Pd2 Ge1 157.837(15) 11_566 16 ? Ge1 Pd2 Ge1 68.691(18) 10_566 16 ? Ge1 Pd2 Pd1 54.847(10) 13 . ? Ge1 Pd2 Pd1 54.847(10) 11_566 . ? Ge1 Pd2 Pd1 145.654(9) 10_566 . ? Ge1 Pd2 Pd1 145.654(9) 16 . ? Ge1 Pd2 Pd2 147.601(15) 13 6 ? Ge1 Pd2 Pd2 53.989(10) 11_566 6 ? Ge1 Pd2 Pd2 52.023(11) 10_566 6 ? Ge1 Pd2 Pd2 104.340(16) 16 6 ? Pd1 Pd2 Pd2 102.865(12) . 6 ? Ge1 Pd2 Pd2 53.988(10) 13 6_554 ? Ge1 Pd2 Pd2 147.601(15) 11_566 6_554 ? Ge1 Pd2 Pd2 104.340(16) 10_566 6_554 ? Ge1 Pd2 Pd2 52.023(11) 16 6_554 ? Pd1 Pd2 Pd2 102.865(12) . 6_554 ? Pd2 Pd2 Pd2 154.27(2) 6 6_554 ? Ge1 Pd2 Pd3 53.244(8) 13 5 ? Ge1 Pd2 Pd3 136.245(11) 11_566 5 ? Ge1 Pd2 Pd3 115.212(12) 10_566 5 ? Ge1 Pd2 Pd3 52.870(8) 16 5 ? Pd1 Pd2 Pd3 96.177(6) . 5 ? Pd2 Pd2 Pd3 115.804(5) 6 5 ? Pd2 Pd2 Pd3 61.105(3) 6_554 5 ? Ge1 Pd2 Pd3 136.245(11) 13 2 ? Ge1 Pd2 Pd3 53.244(8) 11_566 2 ? Ge1 Pd2 Pd3 52.870(8) 10_566 2 ? Ge1 Pd2 Pd3 115.212(12) 16 2 ? Pd1 Pd2 Pd3 96.177(6) . 2 ? Pd2 Pd2 Pd3 61.105(3) 6 2 ? Pd2 Pd2 Pd3 115.804(5) 6_554 2 ? Pd3 Pd2 Pd3 167.647(12) 5 2 ? Ge1 Pd2 Ba1 72.740(11) 13 14_556 ? Ge1 Pd2 Ba1 74.635(11) 11_566 14_556 ? Ge1 Pd2 Ba1 121.206(10) 10_566 14_556 ? Ge1 Pd2 Ba1 106.697(10) 16 14_556 ? Pd1 Pd2 Ba1 60.806(7) . 14_556 ? Pd2 Pd2 Ba1 75.641(7) 6 14_556 ? Pd2 Pd2 Ba1 117.723(7) 6_554 14_556 ? Pd3 Pd2 Ba1 62.019(7) 5 14_556 ? Pd3 Pd2 Ba1 125.040(7) 2 14_556 ? Ge1 Pd2 Ba1 74.635(11) 13 . ? Ge1 Pd2 Ba1 72.740(11) 11_566 . ? Ge1 Pd2 Ba1 106.698(10) 10_566 . ? Ge1 Pd2 Ba1 121.207(10) 16 . ? Pd1 Pd2 Ba1 60.806(7) . . ? Pd2 Pd2 Ba1 117.723(7) 6 . ? Pd2 Pd2 Ba1 75.641(7) 6_554 . ? Pd3 Pd2 Ba1 125.039(7) 5 . ? Pd3 Pd2 Ba1 62.019(6) 2 . ? Ba1 Pd2 Ba1 121.613(13) 14_556 . ? Ge1 Pd2 Ba1 113.836(10) 13 6 ? Ge1 Pd2 Ba1 106.083(10) 11_566 6 ? Ge1 Pd2 Ba1 64.217(11) 10_566 6 ? Ge1 Pd2 Ba1 57.192(10) 16 6 ? Pd1 Pd2 Ba1 126.265(6) . 6 ? Pd2 Pd2 Ba1 57.090(7) 6 6 ? Pd2 Pd2 Ba1 106.255(11) 6_554 6 ? Pd3 Pd2 Ba1 62.216(6) 5 6 ? Pd3 Pd2 Ba1 109.807(8) 2 6 ? Ba1 Pd2 Ba1 65.771(9) 14_556 6 ? Ba1 Pd2 Ba1 170.907(7) . 6 ? Ge1 Pd3 Ge1 88.404(16) 9 12 ? Ge1 Pd3 Ge1 91.596(16) 9 4 ? Ge1 Pd3 Ge1 180.000(14) 12 4 ? Ge1 Pd3 Ge1 180.0 9 . ? Ge1 Pd3 Ge1 91.595(16) 12 . ? Ge1 Pd3 Ge1 88.405(16) 4 . ? Ge1 Pd3 Pd2 128.137(10) 9 10_556 ? Ge1 Pd3 Pd2 129.624(9) 12 10_556 ? Ge1 Pd3 Pd2 50.376(9) 4 10_556 ? Ge1 Pd3 Pd2 51.864(10) . 10_556 ? Ge1 Pd3 Pd2 51.863(10) 9 2_554 ? Ge1 Pd3 Pd2 50.376(9) 12 2_554 ? Ge1 Pd3 Pd2 129.624(9) 4 2_554 ? Ge1 Pd3 Pd2 128.136(10) . 2_554 ? Pd2 Pd3 Pd2 180.0 10_556 2_554 ? Ge1 Pd3 Pd2 50.376(9) 9 5_445 ? Ge1 Pd3 Pd2 51.863(10) 12 5_445 ? Ge1 Pd3 Pd2 128.137(10) 4 5_445 ? Ge1 Pd3 Pd2 129.623(9) . 5_445 ? Pd2 Pd3 Pd2 122.210(6) 10_556 5_445 ? Pd2 Pd3 Pd2 57.790(6) 2_554 5_445 ? Ge1 Pd3 Pd2 129.624(9) 9 13 ? Ge1 Pd3 Pd2 128.137(10) 12 13 ? Ge1 Pd3 Pd2 51.863(10) 4 13 ? Ge1 Pd3 Pd2 50.377(9) . 13 ? Pd2 Pd3 Pd2 57.790(6) 10_556 13 ? Pd2 Pd3 Pd2 122.210(6) 2_554 13 ? Pd2 Pd3 Pd2 180.0 5_445 13 ? Ge1 Pd3 Ba1 107.337(9) 9 2_554 ? Ge1 Pd3 Ba1 72.663(9) 12 2_554 ? Ge1 Pd3 Ba1 107.337(9) 4 2_554 ? Ge1 Pd3 Ba1 72.662(9) . 2_554 ? Pd2 Pd3 Ba1 116.285(5) 10_556 2_554 ? Pd2 Pd3 Ba1 63.715(5) 2_554 2_554 ? Pd2 Pd3 Ba1 116.285(5) 5_445 2_554 ? Pd2 Pd3 Ba1 63.715(5) 13 2_554 ? Ge1 Pd3 Ba1 72.663(9) 9 10_556 ? Ge1 Pd3 Ba1 107.337(9) 12 10_556 ? Ge1 Pd3 Ba1 72.663(9) 4 10_556 ? Ge1 Pd3 Ba1 107.338(9) . 10_556 ? Pd2 Pd3 Ba1 63.715(5) 10_556 10_556 ? Pd2 Pd3 Ba1 116.285(5) 2_554 10_556 ? Pd2 Pd3 Ba1 63.715(5) 5_445 10_556 ? Pd2 Pd3 Ba1 116.285(5) 13 10_556 ? Ba1 Pd3 Ba1 180.000(9) 2_554 10_556 ? Ge1 Pd3 Ba1 61.158(8) 9 10 ? Ge1 Pd3 Ba1 118.842(8) 12 10 ? Ge1 Pd3 Ba1 61.158(8) 4 10 ? Ge1 Pd3 Ba1 118.843(8) . 10 ? Pd2 Pd3 Ba1 109.796(5) 10_556 10 ? Pd2 Pd3 Ba1 70.204(5) 2_554 10 ? Pd2 Pd3 Ba1 109.796(5) 5_445 10 ? Pd2 Pd3 Ba1 70.204(5) 13 10 ? Ba1 Pd3 Ba1 69.087(9) 2_554 10 ? Ba1 Pd3 Ba1 110.913(10) 10_556 10 ? Ge1 Pd3 Ba1 118.842(8) 9 2 ? Ge1 Pd3 Ba1 61.158(8) 12 2 ? Ge1 Pd3 Ba1 118.842(8) 4 2 ? Ge1 Pd3 Ba1 61.157(8) . 2 ? Pd2 Pd3 Ba1 70.204(5) 10_556 2 ? Pd2 Pd3 Ba1 109.796(5) 2_554 2 ? Pd2 Pd3 Ba1 70.204(5) 5_445 2 ? Pd2 Pd3 Ba1 109.796(5) 13 2 ? Ba1 Pd3 Ba1 110.913(10) 2_554 2 ? Ba1 Pd3 Ba1 69.087(9) 10_556 2 ? Ba1 Pd3 Ba1 180.000(7) 10 2 ? Pd2 Ge1 Pd1 70.927(14) 13 13 ? Pd2 Ge1 Pd2 73.987(10) 13 10_556 ? Pd1 Ge1 Pd2 132.894(15) 13 10_556 ? Pd2 Ge1 Pd1 132.453(15) 13 . ? Pd1 Ge1 Pd1 73.386(10) 13 . ? Pd2 Ge1 Pd1 111.427(15) 10_556 . ? Pd2 Ge1 Pd3 76.379(10) 13 . ? Pd1 Ge1 Pd3 123.851(14) 13 . ? Pd2 Ge1 Pd3 75.266(11) 10_556 . ? Pd1 Ge1 Pd3 151.056(15) . . ? Pd2 Ge1 Ge1 110.711(16) 13 7_545 ? Pd1 Ge1 Ge1 110.546(16) 13 7_545 ? Pd2 Ge1 Ge1 55.653(9) 10_556 7_545 ? Pd1 Ge1 Ge1 55.774(9) . 7_545 ? Pd3 Ge1 Ge1 123.384(13) . 7_545 ? Pd2 Ge1 Ba1 148.498(14) 13 2 ? Pd1 Ge1 Ba1 139.264(14) 13 2 ? Pd2 Ge1 Ba1 83.465(11) 10_556 2 ? Pd1 Ge1 Ba1 76.138(10) . 2 ? Pd3 Ge1 Ba1 76.800(10) . 2 ? Ge1 Ge1 Ba1 71.724(15) 7_545 2 ? Pd2 Ge1 Ba1 66.219(10) 13 2_554 ? Pd1 Ge1 Ba1 61.131(9) 13 2_554 ? Pd2 Ge1 Ba1 128.106(12) 10_556 2_554 ? Pd1 Ge1 Ba1 119.818(13) . 2_554 ? Pd3 Ge1 Ba1 64.283(8) . 2_554 ? Ge1 Ge1 Ba1 171.554(17) 7_545 2_554 ? Ba1 Ge1 Ba1 115.225(11) 2 2_554 ? Pd2 Ge1 Ba1 64.857(9) 13 13 ? Pd1 Ge1 Ba1 59.827(8) 13 13 ? Pd2 Ge1 Ba1 77.286(10) 10_556 13 ? Pd1 Ge1 Ba1 70.427(9) . 13 ? Pd3 Ge1 Ba1 137.252(12) . 13 ? Ge1 Ge1 Ba1 60.488(14) 7_545 13 ? Ba1 Ge1 Ba1 131.389(10) 2 13 ? Ba1 Ge1 Ba1 111.774(10) 2_554 13 ? Pd2 Ge1 Ba1 130.590(14) 13 . ? Pd1 Ge1 Ba1 68.712(10) 13 . ? Pd2 Ge1 Ba1 155.085(13) 10_556 . ? Pd1 Ge1 Ba1 57.613(9) . . ? Pd3 Ge1 Ba1 104.058(12) . . ? Ge1 Ge1 Ba1 109.298(9) 7_545 . ? Ba1 Ge1 Ba1 72.338(9) 2 . ? Ba1 Ge1 Ba1 69.931(8) 2_554 . ? Ba1 Ge1 Ba1 114.428(9) 13 . ? _diffrn_measured_fraction_theta_max 1.000 _diffrn_reflns_theta_full 28.31 _diffrn_measured_fraction_theta_full 1.000 _refine_diff_density_max 0.733 _refine_diff_density_min -0.993 _refine_diff_density_rms 0.233