# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2012


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#                                CCDC 
# 
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# 
#  This CIF contains data from an original supplementary publication 
#  deposited with the CCDC, and may include chemical, crystal,   
#  experimental, refinement, atomic coordinates, 
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted. 
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#  fide research purposes only. It may contain copyright material 
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#  except for the purpose of generating routine backup copies 
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data_mmm
_database_code_depnum_ccdc_archive 'CCDC 880351'
#TrackingRef 'mmm.cif'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C63 H110 Ag20 Cl F27 O23 S10'
_chemical_formula_weight         4261.96

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   16.612(3)
_cell_length_b                   26.014(4)
_cell_length_c                   26.372(4)
_cell_angle_alpha                90.00
_cell_angle_beta                 91.580(2)
_cell_angle_gamma                90.00
_cell_volume                     11392(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    19314
_cell_measurement_theta_min      1.45
_cell_measurement_theta_max      20.82

_exptl_crystal_description       colorless
_exptl_crystal_colour            block
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.485
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             8128
_exptl_absorpt_coefficient_mu    3.656
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.432
_exptl_absorpt_correction_T_max  0.447
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       '\w scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            19314
_diffrn_reflns_av_R_equivalents  0.0859
_diffrn_reflns_av_sigmaI/netI    0.1132
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         1.45
_diffrn_reflns_theta_max         20.82
_reflns_number_total             5954
_reflns_number_gt                2957
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'SMART (Bruker, 1997)'
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_reduction        SAINT
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'SHELXTL-PLUS (Sheldrick, 1990)'
_computing_publication_material  SHELXL-97

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.012 0.000 0.000 2321 963 ' '
2 0.118 0.500 0.147 2321 963 ' '
_platon_squeeze_details          
;
;
_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0934P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         5954
_refine_ls_number_parameters     240
_refine_ls_number_restraints     93
_refine_ls_R_factor_all          0.1312
_refine_ls_R_factor_gt           0.0760
_refine_ls_wR_factor_ref         0.2060
_refine_ls_wR_factor_gt          0.1900
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_restrained_S_all      1.118
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6000(10) 0.0974(5) 0.3387(5) 0.073(8) Uiso 1 1 d D . .
C2 C 0.6323(18) 0.0468(5) 0.3590(9) 0.168(6) Uiso 1 1 d D . .
C3 C 0.6470(17) 0.1139(10) 0.2931(6) 0.168(6) Uiso 1 1 d D . .
C4 C 0.5116(11) 0.0925(10) 0.3249(9) 0.168(6) Uiso 1 1 d D . .
C5 C 0.4203(8) 0.1726(7) 0.5747(6) 0.103(10) Uiso 1 1 d D . .
C6 C 0.3646(10) 0.2120(10) 0.5501(11) 0.179(17) Uiso 1 1 d D . .
C7 C 0.3855(12) 0.1193(8) 0.5675(11) 0.156(14) Uiso 1 1 d D . .
C8 C 0.4318(15) 0.1843(12) 0.6307(6) 0.202(19) Uiso 1 1 d D . .
C9 C 0.7788(10) 0.0155(4) 0.5276(6) 0.139(13) Uiso 1 1 d D . .
C10 C 0.8663(10) 0.0141(4) 0.5134(11) 0.168(6) Uiso 1 1 d D . .
C11 C 0.7270(15) -0.0078(3) 0.4859(7) 0.168(6) Uiso 1 1 d D . .
C12 C 0.7666(17) -0.0126(3) 0.5770(5) 0.168(6) Uiso 1 1 d D . .
C13 C 0.7065(11) 0.2161(7) 0.7275(5) 0.124(12) Uiso 1 1 d D . .
C14 C 0.6161(11) 0.2080(12) 0.7275(9) 0.167(6) Uiso 1 1 d D . .
C15 C 0.7245(19) 0.2713(8) 0.7428(8) 0.167(6) Uiso 1 1 d D . .
C16 C 0.7477(18) 0.1792(10) 0.7637(5) 0.167(6) Uiso 1 1 d D . .
C17 C 1.0656(8) 0.1494(6) 0.5868(7) 0.094(9) Uiso 1 1 d D . .
C18 C 1.1117(12) 0.1635(11) 0.6350(9) 0.167(6) Uiso 1 1 d D . .
C19 C 1.1154(11) 0.1602(11) 0.5410(9) 0.167(6) Uiso 1 1 d D . .
C20 C 1.0415(14) 0.0932(5) 0.5882(12) 0.167(6) Uiso 1 1 d D . .
C21 C 0.3546(9) 0.1650(9) 0.3953(9) 0.088(9) Uiso 1 1 d D . .
C22 C 0.2628(10) 0.1575(6) 0.3851(6) 0.200(19) Uiso 1 1 d D . .
F1 F 0.2254(12) 0.1999(6) 0.3687(8) 0.202(10) Uiso 1 1 d D . .
F2 F 0.2465(13) 0.1214(7) 0.3507(7) 0.210(10) Uiso 1 1 d D . .
F3 F 0.2244(11) 0.1435(7) 0.4266(6) 0.192(9) Uiso 1 1 d D . .
Cl1 Cl 0.7500 0.2500 0.5000 0.049(2) Uani 1 2 d S . .
O1 O 0.3870(13) 0.1982(8) 0.3733(8) 0.113(7) Uiso 1 1 d . . .
O2 O 0.3806(11) 0.1333(7) 0.4264(7) 0.096(6) Uiso 1 1 d . . .
Ag1 Ag 0.51695(12) 0.22191(7) 0.37881(7) 0.0669(6) Uani 1 1 d . . .
Ag2 Ag 0.53709(13) 0.25410(8) 0.49288(8) 0.0793(7) Uani 1 1 d . . .
Ag3 Ag 0.63021(15) 0.21043(11) 0.59837(8) 0.1072(10) Uani 1 1 d U . .
Ag4 Ag 0.89189(15) 0.18124(9) 0.66183(8) 0.0915(8) Uani 1 1 d . . .
Ag5 Ag 0.86376(15) 0.14332(8) 0.53755(11) 0.1159(10) Uani 1 1 d DU . .
Ag6 Ag 0.70658(18) 0.12401(8) 0.45810(9) 0.1152(11) Uani 1 1 d DU . .
Ag7 Ag 0.50982(13) 0.13702(8) 0.45688(7) 0.0767(7) Uani 1 1 d . . .
Ag8 Ag 0.70906(16) 0.21430(9) 0.37153(8) 0.1010(9) Uani 1 1 d . . .
Ag9 Ag 0.7464(2) 0.11871(11) 0.62477(10) 0.1598(15) Uani 1 1 d DU . .
Ag10 Ag 0.60177(17) 0.09740(9) 0.55533(10) 0.1199(11) Uani 1 1 d U . .
S1 S 0.6126(4) 0.1470(2) 0.3891(2) 0.0582(18) Uani 1 1 d D . .
S2 S 0.5194(4) 0.1758(3) 0.5439(2) 0.065(2) Uani 1 1 d D . .
S3 S 0.7484(5) 0.08372(19) 0.5372(3) 0.098(3) Uani 1 1 d D . .
S4 S 0.7436(4) 0.2050(3) 0.6627(2) 0.088(3) Uani 1 1 d D . .
S5 S 0.9729(4) 0.1891(2) 0.5821(2) 0.0551(17) Uani 1 1 d D . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Cl1 0.047(6) 0.056(5) 0.045(5) -0.006(4) 0.000(4) -0.005(4)
Ag1 0.0665(15) 0.0579(12) 0.0759(14) 0.0015(11) -0.0058(11) -0.0072(11)
Ag2 0.0657(15) 0.0937(16) 0.0789(15) 0.0273(13) 0.0091(12) 0.0056(13)
Ag3 0.0825(18) 0.191(3) 0.0475(13) 0.0018(15) -0.0089(12) -0.0578(17)
Ag4 0.103(2) 0.0991(17) 0.0721(15) 0.0159(13) -0.0007(14) -0.0322(14)
Ag5 0.0830(18) 0.0602(14) 0.201(3) -0.0127(16) -0.0651(18) -0.0010(13)
Ag6 0.169(3) 0.0697(15) 0.1030(19) -0.0162(13) -0.0731(18) 0.0249(15)
Ag7 0.0815(17) 0.0911(16) 0.0567(13) 0.0041(11) -0.0140(11) -0.0077(13)
Ag8 0.126(2) 0.1083(19) 0.0692(15) -0.0224(14) 0.0217(15) -0.0484(16)
Ag9 0.238(4) 0.133(2) 0.104(2) 0.0518(17) -0.091(2) -0.097(2)
Ag10 0.129(2) 0.0903(17) 0.137(2) 0.0377(16) -0.0618(18) -0.0416(16)
S1 0.056(4) 0.059(4) 0.059(4) -0.012(3) -0.008(3) -0.007(3)
S2 0.059(5) 0.100(5) 0.036(4) 0.005(3) 0.003(3) -0.037(4)
S3 0.119(7) 0.034(4) 0.137(7) 0.019(4) -0.078(6) -0.020(4)
S4 0.082(6) 0.151(7) 0.031(4) 0.012(4) -0.010(4) -0.045(5)
S5 0.050(4) 0.054(4) 0.061(4) -0.003(3) -0.015(3) 0.007(3)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C4 1.509(9) . ?
C1 C3 1.513(9) . ?
C1 C2 1.515(9) . ?
C1 S1 1.860(9) . ?
C5 C7 1.513(9) . ?
C5 C8 1.514(9) . ?
C5 C6 1.515(9) . ?
C5 S2 1.857(9) . ?
C9 C11 1.505(9) . ?
C9 C10 1.510(9) . ?
C9 C12 1.513(9) . ?
C9 S3 1.864(9) . ?
C13 C16 1.505(9) . ?
C13 C14 1.515(9) . ?
C13 C15 1.518(9) . ?
C13 S4 1.855(9) . ?
C17 C19 1.509(9) . ?
C17 C18 1.513(9) . ?
C17 C20 1.515(9) . ?
C17 S5 1.855(9) . ?
C21 O1 1.18(3) . ?
C21 O2 1.23(3) . ?
C21 C22 1.554(9) . ?
C22 F2 1.327(10) . ?
C22 F1 1.334(10) . ?
C22 F3 1.334(10) . ?
O1 Ag1 2.25(2) . ?
O2 Ag7 2.273(19) . ?
Ag1 S1 2.524(6) . ?
Ag1 S5 2.538(6) 7_656 ?
Ag1 Ag7 3.024(3) . ?
Ag1 Ag2 3.132(3) . ?
Ag1 Ag4 3.143(3) 7_656 ?
Ag1 Ag8 3.209(3) . ?
Ag2 S2 2.463(7) . ?
Ag2 S5 2.469(6) 7_656 ?
Ag2 Ag7 3.219(3) . ?
Ag2 Ag5 3.248(3) 7_656 ?
Ag2 Ag3 3.344(3) . ?
Ag3 S2 2.473(6) . ?
Ag3 S4 2.503(7) . ?
Ag3 Ag9 3.135(5) . ?
Ag3 Ag10 3.182(4) . ?
Ag4 S5 2.537(7) . ?
Ag4 S4 2.541(8) . ?
Ag4 Ag9 3.052(3) . ?
Ag4 Ag1 3.143(3) 7_656 ?
Ag4 Ag8 3.300(4) 7_656 ?
Ag5 S5 2.442(6) . ?
Ag5 S3 2.465(7) . ?
Ag5 Ag9 3.122(5) . ?
Ag5 Ag2 3.248(3) 7_656 ?
Ag5 Ag6 3.340(3) . ?
Ag6 S3 2.419(7) . ?
Ag6 S1 2.440(6) . ?
Ag6 Ag10 3.214(4) . ?
Ag6 Ag8 3.277(3) . ?
Ag6 Ag7 3.285(4) . ?
Ag7 S2 2.508(6) . ?
Ag7 S1 2.520(7) . ?
Ag7 Ag10 3.149(3) . ?
Ag8 S4 2.425(8) 7_656 ?
Ag8 S1 2.425(6) . ?
Ag8 Ag4 3.300(4) 7_656 ?
Ag9 S4 2.458(9) . ?
Ag9 S3 2.484(8) . ?
Ag9 Ag10 3.032(3) . ?
Ag10 S2 2.470(8) . ?
Ag10 S3 2.520(9) . ?
S4 Ag8 2.425(8) 7_656 ?
S5 Ag2 2.469(6) 7_656 ?
S5 Ag1 2.538(6) 7_656 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C4 C1 C3 110.5(8) . . ?
C4 C1 C2 110.2(8) . . ?
C3 C1 C2 110.0(8) . . ?
C4 C1 S1 108.7(7) . . ?
C3 C1 S1 108.7(7) . . ?
C2 C1 S1 108.7(7) . . ?
C7 C5 C8 110.2(8) . . ?
C7 C5 C6 109.8(8) . . ?
C8 C5 C6 109.9(8) . . ?
C7 C5 S2 109.1(8) . . ?
C8 C5 S2 109.1(8) . . ?
C6 C5 S2 108.7(8) . . ?
C11 C9 C10 110.1(8) . . ?
C11 C9 C12 110.3(8) . . ?
C10 C9 C12 110.7(8) . . ?
C11 C9 S3 109.4(7) . . ?
C10 C9 S3 108.9(7) . . ?
C12 C9 S3 107.4(7) . . ?
C16 C13 C14 110.1(8) . . ?
C16 C13 C15 110.5(8) . . ?
C14 C13 C15 108.7(8) . . ?
C16 C13 S4 109.1(8) . . ?
C14 C13 S4 109.4(8) . . ?
C15 C13 S4 109.0(8) . . ?
C19 C17 C18 110.6(8) . . ?
C19 C17 C20 110.5(8) . . ?
C18 C17 C20 109.9(8) . . ?
C19 C17 S5 108.4(7) . . ?
C18 C17 S5 108.8(7) . . ?
C20 C17 S5 108.7(8) . . ?
O1 C21 O2 131.5(18) . . ?
O1 C21 C22 117.7(19) . . ?
O2 C21 C22 110.7(16) . . ?
F2 C22 F1 106.2(9) . . ?
F2 C22 F3 106.0(9) . . ?
F1 C22 F3 105.2(9) . . ?
F2 C22 C21 112.9(9) . . ?
F1 C22 C21 113.5(9) . . ?
F3 C22 C21 112.4(9) . . ?
C21 O1 Ag1 128.3(16) . . ?
C21 O2 Ag7 121.0(13) . . ?
O1 Ag1 S1 113.3(5) . . ?
O1 Ag1 S5 109.3(5) . 7_656 ?
S1 Ag1 S5 128.72(19) . 7_656 ?
O1 Ag1 Ag7 77.8(5) . . ?
S1 Ag1 Ag7 53.11(15) . . ?
S5 Ag1 Ag7 113.11(15) 7_656 . ?
O1 Ag1 Ag2 102.3(5) . . ?
S1 Ag1 Ag2 93.04(14) . . ?
S5 Ag1 Ag2 50.31(14) 7_656 . ?
Ag7 Ag1 Ag2 63.02(6) . . ?
O1 Ag1 Ag4 132.0(5) . 7_656 ?
S1 Ag1 Ag4 110.32(16) . 7_656 ?
S5 Ag1 Ag4 51.71(15) 7_656 7_656 ?
Ag7 Ag1 Ag4 147.77(9) . 7_656 ?
Ag2 Ag1 Ag4 94.22(7) . 7_656 ?
O1 Ag1 Ag8 159.2(5) . . ?
S1 Ag1 Ag8 48.26(15) . . ?
S5 Ag1 Ag8 91.46(15) 7_656 . ?
Ag7 Ag1 Ag8 93.06(8) . . ?
Ag2 Ag1 Ag8 89.65(7) . . ?
Ag4 Ag1 Ag8 62.59(7) 7_656 . ?
S2 Ag2 S5 157.8(2) . 7_656 ?
S2 Ag2 Ag1 107.01(16) . . ?
S5 Ag2 Ag1 52.28(14) 7_656 . ?
S2 Ag2 Ag7 50.27(15) . . ?
S5 Ag2 Ag7 108.93(15) 7_656 . ?
Ag1 Ag2 Ag7 56.85(6) . . ?
S2 Ag2 Ag5 152.04(16) . 7_656 ?
S5 Ag2 Ag5 48.24(14) 7_656 7_656 ?
Ag1 Ag2 Ag5 91.36(8) . 7_656 ?
Ag7 Ag2 Ag5 140.60(10) . 7_656 ?
S2 Ag2 Ag3 47.48(14) . . ?
S5 Ag2 Ag3 152.65(17) 7_656 . ?
Ag1 Ag2 Ag3 137.98(9) . . ?
Ag7 Ag2 Ag3 88.97(8) . . ?
Ag5 Ag2 Ag3 104.98(8) 7_656 . ?
S2 Ag3 S4 155.1(3) . . ?
S2 Ag3 Ag9 107.2(2) . . ?
S4 Ag3 Ag9 50.2(2) . . ?
S2 Ag3 Ag10 49.88(18) . . ?
S4 Ag3 Ag10 106.9(2) . . ?
Ag9 Ag3 Ag10 57.35(8) . . ?
S2 Ag3 Ag2 47.23(15) . . ?
S4 Ag3 Ag2 154.81(18) . . ?
Ag9 Ag3 Ag2 135.32(10) . . ?
Ag10 Ag3 Ag2 87.50(7) . . ?
S5 Ag4 S4 121.6(2) . . ?
S5 Ag4 Ag9 102.17(16) . . ?
S4 Ag4 Ag9 51.16(19) . . ?
S5 Ag4 Ag1 51.76(14) . 7_656 ?
S4 Ag4 Ag1 106.54(19) . 7_656 ?
Ag9 Ag4 Ag1 134.66(9) . 7_656 ?
S5 Ag4 Ag8 89.41(14) . 7_656 ?
S4 Ag4 Ag8 46.87(18) . 7_656 ?
Ag9 Ag4 Ag8 87.79(10) . 7_656 ?
Ag1 Ag4 Ag8 59.68(7) 7_656 7_656 ?
S5 Ag5 S3 151.1(3) . . ?
S5 Ag5 Ag9 102.49(18) . . ?
S3 Ag5 Ag9 51.2(2) . . ?
S5 Ag5 Ag2 48.96(15) . 7_656 ?
S3 Ag5 Ag2 156.24(17) . 7_656 ?
Ag9 Ag5 Ag2 132.98(10) . 7_656 ?
S5 Ag5 Ag6 158.71(16) . . ?
S3 Ag5 Ag6 46.26(16) . . ?
Ag9 Ag5 Ag6 86.45(9) . . ?
Ag2 Ag5 Ag6 111.19(9) 7_656 . ?
S3 Ag6 S1 155.8(3) . . ?
S3 Ag6 Ag10 50.8(2) . . ?
S1 Ag6 Ag10 107.37(19) . . ?
S3 Ag6 Ag8 154.51(18) . . ?
S1 Ag6 Ag8 47.48(15) . . ?
Ag10 Ag6 Ag8 136.70(11) . . ?
S3 Ag6 Ag7 108.4(2) . . ?
S1 Ag6 Ag7 49.57(16) . . ?
Ag10 Ag6 Ag7 57.95(8) . . ?
Ag8 Ag6 Ag7 87.19(8) . . ?
S3 Ag6 Ag5 47.43(17) . . ?
S1 Ag6 Ag5 154.69(18) . . ?
Ag10 Ag6 Ag5 87.90(9) . . ?
Ag8 Ag6 Ag5 107.74(10) . . ?
Ag7 Ag6 Ag5 138.67(11) . . ?
O2 Ag7 S2 112.1(5) . . ?
O2 Ag7 S1 113.9(5) . . ?
S2 Ag7 S1 125.5(2) . . ?
O2 Ag7 Ag1 81.1(5) . . ?
S2 Ag7 Ag1 109.07(17) . . ?
S1 Ag7 Ag1 53.22(15) . . ?
O2 Ag7 Ag10 135.1(5) . . ?
S2 Ag7 Ag10 50.22(17) . . ?
S1 Ag7 Ag10 107.22(16) . . ?
Ag1 Ag7 Ag10 140.64(9) . . ?
O2 Ag7 Ag2 105.6(4) . . ?
S2 Ag7 Ag2 49.05(15) . . ?
S1 Ag7 Ag2 91.07(15) . . ?
Ag1 Ag7 Ag2 60.13(6) . . ?
Ag10 Ag7 Ag2 90.31(8) . . ?
O2 Ag7 Ag6 158.2(5) . . ?
S2 Ag7 Ag6 89.69(16) . . ?
S1 Ag7 Ag6 47.47(14) . . ?
Ag1 Ag7 Ag6 91.39(8) . . ?
Ag10 Ag7 Ag6 59.89(8) . . ?
Ag2 Ag7 Ag6 87.86(7) . . ?
S4 Ag8 S1 156.7(3) 7_656 . ?
S4 Ag8 Ag1 107.6(2) 7_656 . ?
S1 Ag8 Ag1 50.93(16) . . ?
S4 Ag8 Ag6 152.92(18) 7_656 . ?
S1 Ag8 Ag6 47.85(15) . . ?
Ag1 Ag8 Ag6 88.33(8) . . ?
S4 Ag8 Ag4 49.9(2) 7_656 7_656 ?
S1 Ag8 Ag4 108.14(18) . 7_656 ?
Ag1 Ag8 Ag4 57.73(7) . 7_656 ?
Ag6 Ag8 Ag4 139.46(10) . 7_656 ?
S4 Ag9 S3 135.6(2) . . ?
S4 Ag9 Ag10 112.9(2) . . ?
S3 Ag9 Ag10 53.26(19) . . ?
S4 Ag9 Ag4 53.63(19) . . ?
S3 Ag9 Ag4 117.6(2) . . ?
Ag10 Ag9 Ag4 153.95(11) . . ?
S4 Ag9 Ag5 97.58(18) . . ?
S3 Ag9 Ag5 50.62(19) . . ?
Ag10 Ag9 Ag5 95.34(10) . . ?
Ag4 Ag9 Ag5 67.76(9) . . ?
S4 Ag9 Ag3 51.45(18) . . ?
S3 Ag9 Ag3 95.52(16) . . ?
Ag10 Ag9 Ag3 62.11(9) . . ?
Ag4 Ag9 Ag3 98.21(10) . . ?
Ag5 Ag9 Ag3 94.21(9) . . ?
S2 Ag10 S3 128.9(2) . . ?
S2 Ag10 Ag9 110.48(17) . . ?
S3 Ag10 Ag9 52.17(18) . . ?
S2 Ag10 Ag7 51.30(14) . . ?
S3 Ag10 Ag7 109.81(19) . . ?
Ag9 Ag10 Ag7 142.79(10) . . ?
S2 Ag10 Ag3 49.97(15) . . ?
S3 Ag10 Ag3 93.64(15) . . ?
Ag9 Ag10 Ag3 60.55(9) . . ?
Ag7 Ag10 Ag3 93.18(8) . . ?
S2 Ag10 Ag6 92.03(16) . . ?
S3 Ag10 Ag6 48.03(17) . . ?
Ag9 Ag10 Ag6 90.27(10) . . ?
Ag7 Ag10 Ag6 62.16(8) . . ?
Ag3 Ag10 Ag6 90.41(8) . . ?
C1 S1 Ag8 115.2(6) . . ?
C1 S1 Ag6 114.8(6) . . ?
Ag8 S1 Ag6 84.7(2) . . ?
C1 S1 Ag7 111.7(6) . . ?
Ag8 S1 Ag7 132.4(2) . . ?
Ag6 S1 Ag7 83.0(2) . . ?
C1 S1 Ag1 113.6(6) . . ?
Ag8 S1 Ag1 80.8(2) . . ?
Ag6 S1 Ag1 131.1(2) . . ?
Ag7 S1 Ag1 73.67(18) . . ?
C5 S2 Ag2 113.4(6) . . ?
C5 S2 Ag10 113.8(6) . . ?
Ag2 S2 Ag10 132.5(3) . . ?
C5 S2 Ag3 114.6(6) . . ?
Ag2 S2 Ag3 85.3(2) . . ?
Ag10 S2 Ag3 80.1(2) . . ?
C5 S2 Ag7 110.3(6) . . ?
Ag2 S2 Ag7 80.68(18) . . ?
Ag10 S2 Ag7 78.5(2) . . ?
Ag3 S2 Ag7 134.8(3) . . ?
C9 S3 Ag6 111.6(5) . . ?
C9 S3 Ag5 112.7(5) . . ?
Ag6 S3 Ag5 86.3(2) . . ?
C9 S3 Ag9 119.1(5) . . ?
Ag6 S3 Ag9 129.2(3) . . ?
Ag5 S3 Ag9 78.2(2) . . ?
C9 S3 Ag10 115.3(5) . . ?
Ag6 S3 Ag10 81.2(2) . . ?
Ag5 S3 Ag10 131.7(3) . . ?
Ag9 S3 Ag10 74.6(3) . . ?
C13 S4 Ag8 109.1(6) . 7_656 ?
C13 S4 Ag9 121.9(6) . . ?
Ag8 S4 Ag9 129.0(3) 7_656 . ?
C13 S4 Ag3 110.7(6) . . ?
Ag8 S4 Ag3 86.8(2) 7_656 . ?
Ag9 S4 Ag3 78.4(2) . . ?
C13 S4 Ag4 113.1(6) . . ?
Ag8 S4 Ag4 83.2(2) 7_656 . ?
Ag9 S4 Ag4 75.2(3) . . ?
Ag3 S4 Ag4 136.0(3) . . ?
C17 S5 Ag5 111.4(6) . . ?
C17 S5 Ag2 115.1(6) . 7_656 ?
Ag5 S5 Ag2 82.80(19) . 7_656 ?
C17 S5 Ag4 111.0(6) . . ?
Ag5 S5 Ag4 87.5(2) . . ?
Ag2 S5 Ag4 133.4(2) 7_656 . ?
C17 S5 Ag1 115.8(6) . 7_656 ?
Ag5 S5 Ag1 132.9(2) . 7_656 ?
Ag2 S5 Ag1 77.41(17) 7_656 7_656 ?
Ag4 S5 Ag1 76.53(18) . 7_656 ?

_diffrn_measured_fraction_theta_max 0.996
_diffrn_reflns_theta_full        20.82
_diffrn_measured_fraction_theta_full 0.996
_refine_diff_density_max         1.426
_refine_diff_density_min         -0.987
_refine_diff_density_rms         0.184