# Electronic Supplementary Material (ESI) for Dalton Transactions
# This journal is © The Royal Society of Chemistry 2013


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#                                CCDC 
# 
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# 
#  This CIF contains data from an original supplementary publication 
#  deposited with the CCDC, and may include chemical, crystal,   
#  experimental, refinement, atomic coordinates, 
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted. 
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data_complex_1
_database_code_depnum_ccdc_archive 'CCDC 885040'
#TrackingRef 'Complex1.cif'


_audit_creation_method           SHELXL-97
_chemical_name_systematic        
;
?
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         'C36 H38 Ag2 Br4 N4 Se2'
_chemical_formula_sum            'C36 H38 Ag2 Br4 N4 Se2'
_chemical_formula_weight         1219.96

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Monoclinic
_symmetry_space_group_name_H-M   'P 21/c'
_symmetry_space_group_name_Hall  '-P 2ybc'
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'

_cell_length_a                   11.534(2)
_cell_length_b                   13.521(2)
_cell_length_c                   12.778(2)
_cell_angle_alpha                90.00
_cell_angle_beta                 97.081(3)
_cell_angle_gamma                90.00
_cell_volume                     1977.6(5)
_cell_formula_units_Z            2
_cell_measurement_temperature    298(2)
_cell_measurement_reflns_used    6834
_cell_measurement_theta_min      2.20
_cell_measurement_theta_max      26.97

_exptl_crystal_description       block
_exptl_crystal_colour            white
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.21
_exptl_crystal_density_meas      2.049
_exptl_crystal_density_diffrn    2.049
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1168.0
_exptl_absorpt_coefficient_mu    6.903
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.004
_exptl_absorpt_correction_T_max  0.025
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'

_exptl_special_details           
;
?
;

_diffrn_ambient_temperature      298(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            18117
_diffrn_reflns_av_R_equivalents  0.0430
_diffrn_reflns_av_sigmaI/netI    0.0348
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         1.78
_diffrn_reflns_theta_max         25.00
_reflns_number_total             3476
_reflns_number_gt                2933
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker SMART'
_computing_cell_refinement       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
;
Refinement of F^2^ against ALL reflections. The weighted R-factor wR and
goodness of fit S are based on F^2^, conventional R-factors R are based
on F, with F set to zero for negative F^2^. The threshold expression of
F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is
not relevant to the choice of reflections for refinement. R-factors based
on F^2^ are statistically about twice as large as those based on F, and R-
factors based on ALL data will be even larger.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[\s^2^(Fo^2^)+(0.0279P)^2^+1.2960P] where P=(Fo^2^+2Fc^2^)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         3476
_refine_ls_number_parameters     217
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0354
_refine_ls_R_factor_gt           0.0271
_refine_ls_wR_factor_ref         0.0683
_refine_ls_wR_factor_gt          0.0652
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_restrained_S_all      1.052
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.05928(3) 0.01327(2) 0.39769(2) 0.05381(11) Uani 1 1 d . . .
Br1 Br 0.90824(3) 0.14392(3) 0.45818(3) 0.04790(12) Uani 1 1 d . . .
Br2 Br 1.26643(3) 0.09383(3) 0.38447(3) 0.04548(12) Uani 1 1 d . . .
C1 C 0.8612(3) 0.0508(3) 0.1385(3) 0.0460(9) Uani 1 1 d . . .
H1 H 0.8758 0.0810 0.2042 0.055 Uiso 1 1 calc R . .
C2 C 0.7898(4) 0.0962(3) 0.0572(4) 0.0574(11) Uani 1 1 d . . .
H2 H 0.7569 0.1576 0.0679 0.069 Uiso 1 1 calc R . .
C3 C 0.7676(4) 0.0505(3) -0.0396(3) 0.0562(11) Uani 1 1 d . . .
H3 H 0.7190 0.0811 -0.0935 0.067 Uiso 1 1 calc R . .
C4 C 0.8159(4) -0.0388(3) -0.0571(3) 0.0541(10) Uani 1 1 d . . .
H4 H 0.8000 -0.0689 -0.1228 0.065 Uiso 1 1 calc R . .
C5 C 0.8887(4) -0.0852(3) 0.0223(3) 0.0475(9) Uani 1 1 d . . .
H5 H 0.9226 -0.1458 0.0100 0.057 Uiso 1 1 calc R . .
C6 C 0.9106(3) -0.0405(3) 0.1203(3) 0.0391(8) Uani 1 1 d . . .
C7 C 0.9279(3) -0.2169(3) 0.2604(3) 0.0474(9) Uani 1 1 d . . .
H7A H 0.8916 -0.2447 0.1944 0.057 Uiso 1 1 calc R . .
H7B H 0.9816 -0.2661 0.2934 0.057 Uiso 1 1 calc R . .
C8 C 0.8348(3) -0.2004(3) 0.3300(3) 0.0486(10) Uani 1 1 d . . .
H8A H 0.7993 -0.2636 0.3429 0.058 Uiso 1 1 calc R . .
H8B H 0.8707 -0.1752 0.3973 0.058 Uiso 1 1 calc R . .
C9 C 0.7161(3) -0.0491(3) 0.3341(3) 0.0426(9) Uani 1 1 d . . .
H9 H 0.7541 -0.0248 0.3973 0.051 Uiso 1 1 calc R . .
C10 C 0.6673(3) -0.1434(3) 0.1961(3) 0.0460(9) Uani 1 1 d . . .
H10 H 0.6662 -0.1951 0.1481 0.055 Uiso 1 1 calc R . .
C11 C 0.5948(3) -0.0644(3) 0.1903(3) 0.0522(10) Uani 1 1 d . . .
H11 H 0.5343 -0.0516 0.1369 0.063 Uiso 1 1 calc R . .
C12 C 0.5694(5) 0.0839(3) 0.3105(4) 0.0717(14) Uani 1 1 d . . .
H12A H 0.6105 0.1055 0.3774 0.086 Uiso 1 1 calc R . .
H12B H 0.4900 0.0679 0.3219 0.086 Uiso 1 1 calc R . .
C13 C 0.5661(3) 0.1675(3) 0.2340(3) 0.0464(9) Uani 1 1 d . . .
C14 C 0.4776(4) 0.1785(3) 0.1518(4) 0.0655(13) Uani 1 1 d . . .
H14 H 0.4191 0.1309 0.1410 0.079 Uiso 1 1 calc R . .
C15 C 0.4747(5) 0.2587(4) 0.0856(4) 0.0852(18) Uani 1 1 d . . .
H15 H 0.4146 0.2656 0.0305 0.102 Uiso 1 1 calc R . .
C16 C 0.5619(6) 0.3290(4) 0.1018(4) 0.0754(15) Uani 1 1 d . . .
H16 H 0.5604 0.3834 0.0571 0.090 Uiso 1 1 calc R . .
C17 C 0.6486(4) 0.3197(4) 0.1812(4) 0.0674(13) Uani 1 1 d . . .
H17 H 0.7068 0.3676 0.1913 0.081 Uiso 1 1 calc R . .
C18 C 0.6519(4) 0.2393(3) 0.2479(3) 0.0537(10) Uani 1 1 d . . .
H18 H 0.7125 0.2333 0.3028 0.064 Uiso 1 1 calc R . .
N1 N 0.7429(2) -0.1318(2) 0.2869(2) 0.0357(7) Uani 1 1 d . . .
N2 N 0.6263(3) -0.0068(2) 0.2767(3) 0.0452(8) Uani 1 1 d . . .
Se1 Se 1.01883(3) -0.10162(3) 0.22781(3) 0.04508(12) Uani 1 1 d . . .

loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ag1 0.04592(19) 0.0586(2) 0.0554(2) 0.00111(15) 0.00034(14) -0.01072(14)
Br1 0.0454(2) 0.0434(2) 0.0524(2) 0.00608(17) -0.00389(17) 0.00191(16)
Br2 0.0361(2) 0.0450(2) 0.0552(2) 0.00505(17) 0.00474(17) -0.00563(15)
C1 0.052(2) 0.046(2) 0.042(2) -0.0023(17) 0.0156(18) -0.0056(18)
C2 0.063(3) 0.047(2) 0.066(3) 0.009(2) 0.021(2) 0.005(2)
C3 0.052(2) 0.065(3) 0.051(3) 0.015(2) 0.003(2) -0.004(2)
C4 0.060(3) 0.059(3) 0.042(2) -0.0051(19) 0.000(2) -0.013(2)
C5 0.051(2) 0.046(2) 0.045(2) -0.0084(18) 0.0033(18) -0.0032(18)
C6 0.0335(18) 0.042(2) 0.042(2) 0.0003(16) 0.0061(15) -0.0090(16)
C7 0.038(2) 0.034(2) 0.067(3) -0.0009(18) -0.0037(19) 0.0044(16)
C8 0.044(2) 0.041(2) 0.058(2) 0.0170(18) -0.0058(19) -0.0015(17)
C9 0.050(2) 0.041(2) 0.0381(19) 0.0040(17) 0.0111(17) -0.0093(18)
C10 0.045(2) 0.041(2) 0.049(2) -0.0041(17) -0.0036(18) -0.0034(17)
C11 0.035(2) 0.063(3) 0.056(2) 0.014(2) -0.0058(18) 0.0014(19)
C12 0.086(4) 0.057(3) 0.081(3) 0.015(2) 0.048(3) 0.024(2)
C13 0.045(2) 0.045(2) 0.051(2) 0.0040(18) 0.0153(18) 0.0158(18)
C14 0.039(2) 0.059(3) 0.094(3) -0.015(3) -0.008(2) 0.009(2)
C15 0.097(4) 0.089(4) 0.060(3) -0.012(3) -0.028(3) 0.048(3)
C16 0.121(5) 0.054(3) 0.055(3) 0.011(2) 0.025(3) 0.026(3)
C17 0.068(3) 0.053(3) 0.085(4) -0.005(3) 0.023(3) -0.001(2)
C18 0.043(2) 0.061(3) 0.054(2) -0.009(2) -0.0041(18) 0.010(2)
N1 0.0302(15) 0.0334(15) 0.0432(17) 0.0055(13) 0.0035(13) -0.0041(12)
N2 0.0492(19) 0.0398(17) 0.0497(19) 0.0091(15) 0.0185(16) 0.0077(15)
Se1 0.0319(2) 0.0540(2) 0.0484(2) -0.00483(18) 0.00112(16) -0.00458(16)

_geom_special_details            
;
All esds (except the esd in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell esds are taken
into account individually in the estimation of esds in distances, angles
and torsion angles; correlations between esds in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell esds is used for estimating esds involving l.s. planes.
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Br2 2.6501(6) . ?
Ag1 Br1 2.6618(6) . ?
Ag1 Se1 2.6633(6) . ?
Ag1 Br1 2.8070(6) 3_756 ?
Ag1 Ag1 3.1172(8) 3_756 ?
Br1 Ag1 2.8070(6) 3_756 ?
C1 C2 1.387(6) . ?
C1 C6 1.391(5) . ?
C1 H1 0.9300 . ?
C2 C3 1.377(6) . ?
C2 H2 0.9300 . ?
C3 C4 1.361(6) . ?
C3 H3 0.9300 . ?
C4 C5 1.385(6) . ?
C4 H4 0.9300 . ?
C5 C6 1.385(5) . ?
C5 H5 0.9300 . ?
C6 Se1 1.925(4) . ?
C7 C8 1.493(6) . ?
C7 Se1 1.952(4) . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 N1 1.464(4) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 N2 1.323(5) . ?
C9 N1 1.325(5) . ?
C9 H9 0.9300 . ?
C10 C11 1.353(6) . ?
C10 N1 1.371(5) . ?
C10 H10 0.9300 . ?
C11 N2 1.364(5) . ?
C11 H11 0.9300 . ?
C12 N2 1.480(5) . ?
C12 C13 1.492(6) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.380(6) . ?
C13 C18 1.381(6) . ?
C14 C15 1.373(7) . ?
C14 H14 0.9300 . ?
C15 C16 1.380(8) . ?
C15 H15 0.9300 . ?
C16 C17 1.340(7) . ?
C16 H16 0.9300 . ?
C17 C18 1.379(6) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Br2 Ag1 Br1 111.91(2) . . ?
Br2 Ag1 Se1 104.864(17) . . ?
Br1 Ag1 Se1 124.652(18) . . ?
Br2 Ag1 Br1 107.734(17) . 3_756 ?
Br1 Ag1 Br1 110.558(17) . 3_756 ?
Se1 Ag1 Br1 95.10(2) . 3_756 ?
Br2 Ag1 Ag1 126.370(19) . 3_756 ?
Br1 Ag1 Ag1 57.473(15) . 3_756 ?
Se1 Ag1 Ag1 124.44(2) . 3_756 ?
Br1 Ag1 Ag1 53.085(14) 3_756 3_756 ?
Ag1 Br1 Ag1 69.442(17) . 3_756 ?
C2 C1 C6 119.0(4) . . ?
C2 C1 H1 120.5 . . ?
C6 C1 H1 120.5 . . ?
C3 C2 C1 120.1(4) . . ?
C3 C2 H2 120.0 . . ?
C1 C2 H2 120.0 . . ?
C4 C3 C2 120.8(4) . . ?
C4 C3 H3 119.6 . . ?
C2 C3 H3 119.6 . . ?
C3 C4 C5 120.3(4) . . ?
C3 C4 H4 119.8 . . ?
C5 C4 H4 119.8 . . ?
C6 C5 C4 119.4(4) . . ?
C6 C5 H5 120.3 . . ?
C4 C5 H5 120.3 . . ?
C5 C6 C1 120.4(3) . . ?
C5 C6 Se1 119.2(3) . . ?
C1 C6 Se1 120.3(3) . . ?
C8 C7 Se1 116.9(3) . . ?
C8 C7 H7A 108.1 . . ?
Se1 C7 H7A 108.1 . . ?
C8 C7 H7B 108.1 . . ?
Se1 C7 H7B 108.1 . . ?
H7A C7 H7B 107.3 . . ?
N1 C8 C7 114.3(3) . . ?
N1 C8 H8A 108.7 . . ?
C7 C8 H8A 108.7 . . ?
N1 C8 H8B 108.7 . . ?
C7 C8 H8B 108.7 . . ?
H8A C8 H8B 107.6 . . ?
N2 C9 N1 108.9(3) . . ?
N2 C9 H9 125.6 . . ?
N1 C9 H9 125.6 . . ?
C11 C10 N1 106.3(3) . . ?
C11 C10 H10 126.9 . . ?
N1 C10 H10 126.9 . . ?
C10 C11 N2 107.8(3) . . ?
C10 C11 H11 126.1 . . ?
N2 C11 H11 126.1 . . ?
N2 C12 C13 114.4(3) . . ?
N2 C12 H12A 108.7 . . ?
C13 C12 H12A 108.7 . . ?
N2 C12 H12B 108.7 . . ?
C13 C12 H12B 108.7 . . ?
H12A C12 H12B 107.6 . . ?
C14 C13 C18 118.3(4) . . ?
C14 C13 C12 122.5(4) . . ?
C18 C13 C12 119.2(4) . . ?
C15 C14 C13 120.9(5) . . ?
C15 C14 H14 119.6 . . ?
C13 C14 H14 119.6 . . ?
C14 C15 C16 119.3(5) . . ?
C14 C15 H15 120.3 . . ?
C16 C15 H15 120.3 . . ?
C17 C16 C15 120.7(5) . . ?
C17 C16 H16 119.7 . . ?
C15 C16 H16 119.7 . . ?
C16 C17 C18 120.2(5) . . ?
C16 C17 H17 119.9 . . ?
C18 C17 H17 119.9 . . ?
C17 C18 C13 120.6(4) . . ?
C17 C18 H18 119.7 . . ?
C13 C18 H18 119.7 . . ?
C9 N1 C10 108.8(3) . . ?
C9 N1 C8 124.3(3) . . ?
C10 N1 C8 126.9(3) . . ?
C9 N2 C11 108.3(3) . . ?
C9 N2 C12 122.8(4) . . ?
C11 N2 C12 128.7(4) . . ?
C6 Se1 C7 100.17(15) . . ?
C6 Se1 Ag1 111.36(11) . . ?
C7 Se1 Ag1 109.69(12) . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Br2 Ag1 Br1 Ag1 -120.10(2) . . . 3_756 ?
Se1 Ag1 Br1 Ag1 112.01(2) . . . 3_756 ?
Br1 Ag1 Br1 Ag1 0.0 3_756 . . 3_756 ?
C6 C1 C2 C3 0.7(6) . . . . ?
C1 C2 C3 C4 -0.7(6) . . . . ?
C2 C3 C4 C5 -0.2(6) . . . . ?
C3 C4 C5 C6 0.9(6) . . . . ?
C4 C5 C6 C1 -0.9(6) . . . . ?
C4 C5 C6 Se1 -176.5(3) . . . . ?
C2 C1 C6 C5 0.1(6) . . . . ?
C2 C1 C6 Se1 175.6(3) . . . . ?
Se1 C7 C8 N1 61.4(4) . . . . ?
N1 C10 C11 N2 -0.3(4) . . . . ?
N2 C12 C13 C14 86.9(5) . . . . ?
N2 C12 C13 C18 -95.9(5) . . . . ?
C18 C13 C14 C15 -0.1(6) . . . . ?
C12 C13 C14 C15 177.1(4) . . . . ?
C13 C14 C15 C16 0.1(7) . . . . ?
C14 C15 C16 C17 -0.1(8) . . . . ?
C15 C16 C17 C18 0.1(7) . . . . ?
C16 C17 C18 C13 0.0(7) . . . . ?
C14 C13 C18 C17 0.1(6) . . . . ?
C12 C13 C18 C17 -177.3(4) . . . . ?
N2 C9 N1 C10 -0.3(4) . . . . ?
N2 C9 N1 C8 -177.4(3) . . . . ?
C11 C10 N1 C9 0.3(4) . . . . ?
C11 C10 N1 C8 177.3(3) . . . . ?
C7 C8 N1 C9 -121.2(4) . . . . ?
C7 C8 N1 C10 62.2(5) . . . . ?
N1 C9 N2 C11 0.1(4) . . . . ?
N1 C9 N2 C12 176.0(3) . . . . ?
C10 C11 N2 C9 0.1(4) . . . . ?
C10 C11 N2 C12 -175.5(4) . . . . ?
C13 C12 N2 C9 123.5(4) . . . . ?
C13 C12 N2 C11 -61.5(6) . . . . ?
C5 C6 Se1 C7 -70.7(3) . . . . ?
C1 C6 Se1 C7 113.8(3) . . . . ?
C5 C6 Se1 Ag1 173.4(3) . . . . ?
C1 C6 Se1 Ag1 -2.2(3) . . . . ?
C8 C7 Se1 C6 -78.8(3) . . . . ?
C8 C7 Se1 Ag1 38.4(3) . . . . ?
Br2 Ag1 Se1 C6 -102.53(11) . . . . ?
Br1 Ag1 Se1 C6 28.23(11) . . . . ?
Br1 Ag1 Se1 C6 147.59(11) 3_756 . . . ?
Ag1 Ag1 Se1 C6 99.66(11) 3_756 . . . ?
Br2 Ag1 Se1 C7 147.52(11) . . . . ?
Br1 Ag1 Se1 C7 -81.72(12) . . . . ?
Br1 Ag1 Se1 C7 37.64(12) 3_756 . . . ?
Ag1 Ag1 Se1 C7 -10.30(12) 3_756 . . . ?

_diffrn_measured_fraction_theta_max 1.000
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 1.000
_refine_diff_density_max         0.526
_refine_diff_density_min         -0.625
_refine_diff_density_rms         0.087