# Electronic Supplementary Material (ESI) for Dalton Transactions # This journal is © The Royal Society of Chemistry 2013 ####################################################################### # # Cambridge Crystallographic Data Centre # CCDC # ####################################################################### # # This CIF contains data from an original supplementary publication # deposited with the CCDC, and may include chemical, crystal, # experimental, refinement, atomic coordinates, # anisotropic displacement parameters and molecular geometry data, # as required by the journal to which it was submitted. # # This CIF is provided on the understanding that it is used for bona # fide research purposes only. It may contain copyright material # of the CCDC or of third parties, and may not be copied or further # disseminated in any form, whether machine-readable or not, # except for the purpose of generating routine backup copies # on your local computer system. # # For further information on the CCDC, data deposition and # data retrieval see: # www.ccdc.cam.ac.uk # # Bona fide researchers may freely download Mercury and enCIFer # from this site to visualise CIF-encoded structures and # to carry out CIF format checking respectively. # ####################################################################### data_pi3dc _database_code_depnum_ccdc_archive 'CCDC 915914' #TrackingRef '16232_web_deposit_cif_file_0_PiotrSmolenski_1355649748.compound-1.cif' _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety 'C16 H20 Ag N5 P, C H4 O, N O3' _chemical_formula_sum 'C17 H24 Ag N6 O4 P' _chemical_formula_weight 515.26 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Monoclinic _symmetry_space_group_name_H-M 'P 21/c ' _symmetry_space_group_name_Hall '-P 2ybc' loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' _cell_length_a 6.915(3) _cell_length_b 20.208(3) _cell_length_c 15.138(5) _cell_angle_alpha 90.00 _cell_angle_beta 107.36(4) _cell_angle_gamma 90.00 _cell_volume 2019.0(11) _cell_formula_units_Z 4 _cell_measurement_temperature 100(2) _cell_measurement_reflns_used 2812 _cell_measurement_theta_min 2.82 _cell_measurement_theta_max 25.12 _exptl_crystal_description plate _exptl_crystal_colour colorless _exptl_crystal_size_max 0.15 _exptl_crystal_size_mid 0.14 _exptl_crystal_size_min 0.12 _exptl_crystal_density_meas ? _exptl_crystal_density_diffrn 1.695 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 1048 _exptl_absorpt_coefficient_mu 1.115 _exptl_absorpt_correction_type analytical _exptl_absorpt_correction_T_min 0.456 _exptl_absorpt_correction_T_max 0.567 _exptl_absorpt_process_details 'crysAlis, Oxford Diffraction, England' _exptl_special_details ; ? ; _diffrn_ambient_temperature 100(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type KM4-CCD _diffrn_measurement_method /w _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 22933 _diffrn_reflns_av_R_equivalents 0.0640 _diffrn_reflns_av_sigmaI/netI 0.0390 _diffrn_reflns_limit_h_min -8 _diffrn_reflns_limit_h_max 8 _diffrn_reflns_limit_k_min -24 _diffrn_reflns_limit_k_max 20 _diffrn_reflns_limit_l_min -17 _diffrn_reflns_limit_l_max 18 _diffrn_reflns_theta_min 2.82 _diffrn_reflns_theta_max 25.15 _reflns_number_total 3614 _reflns_number_gt 2812 _reflns_threshold_expression >2sigma(I) _computing_data_collection ? _computing_cell_refinement ? _computing_data_reduction ? _computing_structure_solution 'SHELXS-97 (Sheldrick, 1990)' _computing_structure_refinement 'SHELXL-97 (Sheldrick, 1997)' _computing_molecular_graphics ? _computing_publication_material ? _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0466P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 3614 _refine_ls_number_parameters 267 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0480 _refine_ls_R_factor_gt 0.0312 _refine_ls_wR_factor_ref 0.0741 _refine_ls_wR_factor_gt 0.0683 _refine_ls_goodness_of_fit_ref 0.965 _refine_ls_restrained_S_all 0.965 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group Ag1 Ag 1.29933(4) 0.068764(13) 0.244547(18) 0.02121(10) Uani 1 1 d . . . P1 P 0.96232(12) 0.09741(4) 0.17111(6) 0.0184(2) Uani 1 1 d . . . N1 N 1.4537(4) -0.03296(14) 0.29171(19) 0.0199(6) Uani 1 1 d . . . N2 N 1.5342(4) 0.08131(13) 0.38999(19) 0.0213(6) Uani 1 1 d . . . C1 C 1.4038(5) -0.08870(18) 0.2430(2) 0.0244(8) Uani 1 1 d . . . H1 H 1.3089 -0.0862 0.1830 0.029 Uiso 1 1 calc R . . C2 C 1.4831(5) -0.14986(18) 0.2754(3) 0.0296(9) Uani 1 1 d . . . H2 H 1.4432 -0.1885 0.2388 0.035 Uiso 1 1 calc R . . C3 C 1.6213(6) -0.15314(19) 0.3620(3) 0.0310(9) Uani 1 1 d . . . H3 H 1.6794 -0.1944 0.3862 0.037 Uiso 1 1 calc R . . C4 C 1.6749(5) -0.09629(19) 0.4133(3) 0.0259(8) Uani 1 1 d . . . H4 H 1.7706 -0.0980 0.4732 0.031 Uiso 1 1 calc R . . C5 C 1.7823(5) 0.0304(2) 0.5167(2) 0.0283(8) Uani 1 1 d . . . H5 H 1.8514 -0.0083 0.5452 0.034 Uiso 1 1 calc R . . C6 C 1.8230(6) 0.0913(2) 0.5606(3) 0.0339(10) Uani 1 1 d . . . H6 H 1.9226 0.0947 0.6193 0.041 Uiso 1 1 calc R . . C7 C 1.7195(6) 0.1467(2) 0.5195(3) 0.0320(9) Uani 1 1 d . . . H7 H 1.7458 0.1888 0.5485 0.038 Uiso 1 1 calc R . . C8 C 1.5757(6) 0.13897(19) 0.4342(3) 0.0285(8) Uani 1 1 d . . . H8 H 1.5023 0.1769 0.4056 0.034 Uiso 1 1 calc R . . C9 C 1.5886(5) -0.03632(17) 0.3774(2) 0.0198(7) Uani 1 1 d . . . C10 C 1.6378(5) 0.02696(17) 0.4298(2) 0.0205(7) Uani 1 1 d . . . N3 N 0.6222(4) 0.08702(14) 0.0188(2) 0.0225(6) Uani 1 1 d . . . N4 N 0.5592(4) 0.10032(13) 0.17032(18) 0.0177(6) Uani 1 1 d . . . N5 N 0.6802(4) 0.19508(14) 0.09776(19) 0.0210(6) Uani 1 1 d . . . C11 C 0.7643(4) 0.07855(17) 0.2265(2) 0.0181(7) Uani 1 1 d . . . H11A H 0.7621 0.0302 0.2370 0.022 Uiso 1 1 calc R . . H11B H 0.7991 0.1006 0.2876 0.022 Uiso 1 1 calc R . . C12 C 0.4998(5) 0.06772(18) 0.0786(2) 0.0205(7) Uani 1 1 d . . . H12A H 0.5101 0.0192 0.0878 0.025 Uiso 1 1 calc R . . H12B H 0.3562 0.0783 0.0465 0.025 Uiso 1 1 calc R . . C13 C 0.8330(5) 0.06250(18) 0.0557(2) 0.0227(7) Uani 1 1 d . . . H13A H 0.9097 0.0745 0.0123 0.027 Uiso 1 1 calc R . . H13B H 0.8315 0.0136 0.0601 0.027 Uiso 1 1 calc R . . C14 C 0.8984(5) 0.18534(17) 0.1451(2) 0.0210(7) Uani 1 1 d . . . H14A H 0.9373 0.2109 0.2035 0.025 Uiso 1 1 calc R . . H14B H 0.9776 0.2026 0.1053 0.025 Uiso 1 1 calc R . . C15 C 0.5566(5) 0.17262(16) 0.1550(2) 0.0215(7) Uani 1 1 d . . . H15A H 0.4148 0.1867 0.1254 0.026 Uiso 1 1 calc R . . H15B H 0.6045 0.1949 0.2159 0.026 Uiso 1 1 calc R . . C16 C 0.6173(5) 0.15890(17) 0.0092(2) 0.0240(8) Uani 1 1 d . . . H16A H 0.4778 0.1726 -0.0254 0.029 Uiso 1 1 calc R . . H16B H 0.7071 0.1719 -0.0279 0.029 Uiso 1 1 calc R . . O1 O 0.1230(4) 0.25898(14) 0.47248(19) 0.0408(7) Uani 1 1 d . . . O2 O -0.1466(4) 0.24725(13) 0.35634(19) 0.0378(7) Uani 1 1 d . . . O3 O 0.0698(4) 0.16721(14) 0.39441(19) 0.0400(7) Uani 1 1 d . . . N6 N 0.0156(5) 0.22364(16) 0.4074(2) 0.0285(7) Uani 1 1 d . . . O4 O 0.0628(4) 0.38776(15) 0.40616(19) 0.0324(6) Uani 1 1 d . . . H4W H 0.057(6) 0.349(2) 0.421(3) 0.031(12) Uiso 1 1 d . . . C20 C 0.1167(7) 0.3854(2) 0.3240(3) 0.0450(11) Uani 1 1 d . . . H20A H 0.0603 0.4240 0.2857 0.068 Uiso 1 1 calc R . . H20B H 0.0628 0.3448 0.2901 0.068 Uiso 1 1 calc R . . H20C H 0.2647 0.3857 0.3387 0.068 Uiso 1 1 calc R . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Ag1 0.01141(13) 0.02758(15) 0.02308(15) 0.00201(12) 0.00277(10) 0.00261(12) P1 0.0106(4) 0.0243(5) 0.0200(5) 0.0014(4) 0.0039(3) 0.0003(3) N1 0.0147(14) 0.0240(16) 0.0202(15) -0.0003(12) 0.0038(12) -0.0018(12) N2 0.0174(14) 0.0241(17) 0.0226(15) -0.0002(12) 0.0064(12) -0.0013(12) C1 0.0177(17) 0.032(2) 0.0228(19) -0.0019(15) 0.0058(15) -0.0036(15) C2 0.026(2) 0.023(2) 0.043(2) -0.0035(17) 0.0131(18) -0.0025(16) C3 0.0242(19) 0.024(2) 0.046(2) 0.0079(17) 0.0123(18) 0.0031(16) C4 0.0136(17) 0.035(2) 0.029(2) 0.0074(17) 0.0050(15) 0.0005(16) C5 0.0121(17) 0.047(2) 0.024(2) 0.0005(17) 0.0033(15) 0.0012(16) C6 0.0180(18) 0.062(3) 0.022(2) -0.0125(19) 0.0070(16) -0.0090(19) C7 0.025(2) 0.042(2) 0.032(2) -0.0108(18) 0.0133(18) -0.0125(18) C8 0.026(2) 0.031(2) 0.032(2) -0.0054(17) 0.0134(17) -0.0046(16) C9 0.0102(15) 0.0262(19) 0.0250(19) 0.0037(15) 0.0084(14) -0.0020(14) C10 0.0114(16) 0.032(2) 0.0191(18) 0.0001(15) 0.0067(14) -0.0038(15) N3 0.0175(14) 0.0287(17) 0.0195(15) 0.0001(12) 0.0029(12) 0.0011(12) N4 0.0098(13) 0.0220(14) 0.0185(14) 0.0001(12) 0.0000(11) 0.0010(11) N5 0.0124(13) 0.0222(15) 0.0255(16) 0.0028(12) 0.0013(12) 0.0012(12) C11 0.0116(15) 0.0246(19) 0.0180(17) 0.0016(13) 0.0044(13) 0.0026(13) C12 0.0145(15) 0.0260(18) 0.0193(17) -0.0020(15) 0.0024(13) -0.0019(15) C13 0.0168(16) 0.0291(19) 0.0227(18) -0.0016(15) 0.0067(14) 0.0035(15) C14 0.0153(16) 0.0237(19) 0.0223(18) 0.0021(14) 0.0032(14) -0.0008(14) C15 0.0145(16) 0.0243(18) 0.0251(19) 0.0002(14) 0.0049(15) 0.0049(14) C16 0.0165(17) 0.033(2) 0.0206(19) 0.0047(15) 0.0026(15) 0.0014(15) O1 0.0370(16) 0.0500(18) 0.0258(15) -0.0066(13) -0.0055(13) -0.0062(14) O2 0.0256(14) 0.0419(17) 0.0353(16) -0.0009(13) -0.0070(12) 0.0040(12) O3 0.0364(16) 0.0430(18) 0.0335(16) -0.0037(13) -0.0002(13) 0.0115(14) N6 0.0226(16) 0.041(2) 0.0202(16) 0.0006(14) 0.0034(14) -0.0022(15) O4 0.0301(15) 0.0371(18) 0.0290(15) -0.0022(13) 0.0072(12) -0.0031(13) C20 0.036(2) 0.066(3) 0.035(2) 0.005(2) 0.013(2) -0.003(2) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag Ag1 N2 2.327(3) . ? Ag1 N1 2.328(3) . ? Ag1 P1 2.3358(14) . ? Ag1 N4 2.471(3) 1_655 ? P1 C14 1.845(3) . ? P1 C11 1.846(3) . ? P1 C13 1.848(4) . ? N1 C1 1.334(5) . ? N1 C9 1.355(4) . ? N2 C8 1.332(5) . ? N2 C10 1.351(4) . ? C1 C2 1.381(5) . ? C1 H1 0.9500 . ? C2 C3 1.374(6) . ? C2 H2 0.9500 . ? C3 C4 1.375(5) . ? C3 H3 0.9500 . ? C4 C9 1.388(5) . ? C4 H4 0.9500 . ? C5 C6 1.388(6) . ? C5 C10 1.396(5) . ? C5 H5 0.9500 . ? C6 C7 1.375(6) . ? C6 H6 0.9500 . ? C7 C8 1.383(5) . ? C7 H7 0.9500 . ? C8 H8 0.9500 . ? C9 C10 1.489(5) . ? N3 C16 1.459(5) . ? N3 C12 1.463(4) . ? N3 C13 1.482(4) . ? N4 C15 1.479(4) . ? N4 C12 1.481(4) . ? N4 C11 1.486(4) . ? N4 Ag1 2.471(3) 1_455 ? N5 C15 1.459(4) . ? N5 C16 1.474(4) . ? N5 C14 1.478(4) . ? C11 H11A 0.9900 . ? C11 H11B 0.9900 . ? C12 H12A 0.9900 . ? C12 H12B 0.9900 . ? C13 H13A 0.9900 . ? C13 H13B 0.9900 . ? C14 H14A 0.9900 . ? C14 H14B 0.9900 . ? C15 H15A 0.9900 . ? C15 H15B 0.9900 . ? C16 H16A 0.9900 . ? C16 H16B 0.9900 . ? O1 N6 1.263(4) . ? O2 N6 1.251(4) . ? O3 N6 1.234(4) . ? O4 C20 1.402(5) . ? O4 H4W 0.83(4) . ? C20 H20A 0.9800 . ? C20 H20B 0.9800 . ? C20 H20C 0.9800 . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag N2 Ag1 N1 71.29(10) . . ? N2 Ag1 P1 137.64(7) . . ? N1 Ag1 P1 131.75(7) . . ? N2 Ag1 N4 90.29(10) . 1_655 ? N1 Ag1 N4 92.18(9) . 1_655 ? P1 Ag1 N4 118.52(7) . 1_655 ? C14 P1 C11 97.66(15) . . ? C14 P1 C13 98.52(16) . . ? C11 P1 C13 97.77(15) . . ? C14 P1 Ag1 118.79(11) . . ? C11 P1 Ag1 120.17(11) . . ? C13 P1 Ag1 119.20(11) . . ? C1 N1 C9 118.5(3) . . ? C1 N1 Ag1 123.8(2) . . ? C9 N1 Ag1 117.4(2) . . ? C8 N2 C10 118.8(3) . . ? C8 N2 Ag1 123.7(2) . . ? C10 N2 Ag1 117.4(2) . . ? N1 C1 C2 123.4(3) . . ? N1 C1 H1 118.3 . . ? C2 C1 H1 118.3 . . ? C3 C2 C1 118.1(3) . . ? C3 C2 H2 121.0 . . ? C1 C2 H2 121.0 . . ? C2 C3 C4 119.5(3) . . ? C2 C3 H3 120.2 . . ? C4 C3 H3 120.2 . . ? C3 C4 C9 119.8(3) . . ? C3 C4 H4 120.1 . . ? C9 C4 H4 120.1 . . ? C6 C5 C10 118.8(4) . . ? C6 C5 H5 120.6 . . ? C10 C5 H5 120.6 . . ? C7 C6 C5 120.1(3) . . ? C7 C6 H6 119.9 . . ? C5 C6 H6 119.9 . . ? C6 C7 C8 117.5(4) . . ? C6 C7 H7 121.2 . . ? C8 C7 H7 121.2 . . ? N2 C8 C7 123.7(4) . . ? N2 C8 H8 118.1 . . ? C7 C8 H8 118.1 . . ? N1 C9 C4 120.7(3) . . ? N1 C9 C10 116.7(3) . . ? C4 C9 C10 122.6(3) . . ? N2 C10 C5 121.0(3) . . ? N2 C10 C9 117.0(3) . . ? C5 C10 C9 122.0(3) . . ? C16 N3 C12 109.0(3) . . ? C16 N3 C13 111.2(3) . . ? C12 N3 C13 111.3(3) . . ? C15 N4 C12 107.8(3) . . ? C15 N4 C11 110.3(2) . . ? C12 N4 C11 110.8(3) . . ? C15 N4 Ag1 110.47(19) . 1_455 ? C12 N4 Ag1 106.02(18) . 1_455 ? C11 N4 Ag1 111.28(19) . 1_455 ? C15 N5 C16 108.6(3) . . ? C15 N5 C14 111.4(3) . . ? C16 N5 C14 110.9(3) . . ? N4 C11 P1 112.9(2) . . ? N4 C11 H11A 109.0 . . ? P1 C11 H11A 109.0 . . ? N4 C11 H11B 109.0 . . ? P1 C11 H11B 109.0 . . ? H11A C11 H11B 107.8 . . ? N3 C12 N4 114.3(3) . . ? N3 C12 H12A 108.7 . . ? N4 C12 H12A 108.7 . . ? N3 C12 H12B 108.7 . . ? N4 C12 H12B 108.7 . . ? H12A C12 H12B 107.6 . . ? N3 C13 P1 111.9(2) . . ? N3 C13 H13A 109.2 . . ? P1 C13 H13A 109.2 . . ? N3 C13 H13B 109.2 . . ? P1 C13 H13B 109.2 . . ? H13A C13 H13B 107.9 . . ? N5 C14 P1 112.1(2) . . ? N5 C14 H14A 109.2 . . ? P1 C14 H14A 109.2 . . ? N5 C14 H14B 109.2 . . ? P1 C14 H14B 109.2 . . ? H14A C14 H14B 107.9 . . ? N5 C15 N4 114.7(3) . . ? N5 C15 H15A 108.6 . . ? N4 C15 H15A 108.6 . . ? N5 C15 H15B 108.6 . . ? N4 C15 H15B 108.6 . . ? H15A C15 H15B 107.6 . . ? N3 C16 N5 114.3(3) . . ? N3 C16 H16A 108.7 . . ? N5 C16 H16A 108.7 . . ? N3 C16 H16B 108.7 . . ? N5 C16 H16B 108.7 . . ? H16A C16 H16B 107.6 . . ? O3 N6 O2 120.9(3) . . ? O3 N6 O1 120.7(3) . . ? O2 N6 O1 118.4(3) . . ? C20 O4 H4W 105(3) . . ? O4 C20 H20A 109.5 . . ? O4 C20 H20B 109.5 . . ? H20A C20 H20B 109.5 . . ? O4 C20 H20C 109.5 . . ? H20A C20 H20C 109.5 . . ? H20B C20 H20C 109.5 . . ? loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_2 _geom_torsion_site_symmetry_3 _geom_torsion_site_symmetry_4 _geom_torsion_publ_flag N2 Ag1 P1 C14 69.85(17) . . . . ? N1 Ag1 P1 C14 179.76(16) . . . . ? N4 Ag1 P1 C14 -57.34(15) 1_655 . . . ? N2 Ag1 P1 C11 -49.85(17) . . . . ? N1 Ag1 P1 C11 60.07(16) . . . . ? N4 Ag1 P1 C11 -177.03(14) 1_655 . . . ? N2 Ag1 P1 C13 -170.11(16) . . . . ? N1 Ag1 P1 C13 -60.19(17) . . . . ? N4 Ag1 P1 C13 62.70(16) 1_655 . . . ? N2 Ag1 N1 C1 177.1(3) . . . . ? P1 Ag1 N1 C1 39.0(3) . . . . ? N4 Ag1 N1 C1 -93.4(3) 1_655 . . . ? N2 Ag1 N1 C9 3.3(2) . . . . ? P1 Ag1 N1 C9 -134.7(2) . . . . ? N4 Ag1 N1 C9 92.9(2) 1_655 . . . ? N1 Ag1 N2 C8 176.9(3) . . . . ? P1 Ag1 N2 C8 -50.9(3) . . . . ? N4 Ag1 N2 C8 84.7(3) 1_655 . . . ? N1 Ag1 N2 C10 -1.0(2) . . . . ? P1 Ag1 N2 C10 131.2(2) . . . . ? N4 Ag1 N2 C10 -93.2(2) 1_655 . . . ? C9 N1 C1 C2 -0.2(5) . . . . ? Ag1 N1 C1 C2 -173.9(3) . . . . ? N1 C1 C2 C3 -0.4(5) . . . . ? C1 C2 C3 C4 0.4(5) . . . . ? C2 C3 C4 C9 0.2(5) . . . . ? C10 C5 C6 C7 1.1(5) . . . . ? C5 C6 C7 C8 0.2(5) . . . . ? C10 N2 C8 C7 -0.2(5) . . . . ? Ag1 N2 C8 C7 -178.1(3) . . . . ? C6 C7 C8 N2 -0.7(5) . . . . ? C1 N1 C9 C4 0.8(5) . . . . ? Ag1 N1 C9 C4 174.9(2) . . . . ? C1 N1 C9 C10 -179.2(3) . . . . ? Ag1 N1 C9 C10 -5.1(4) . . . . ? C3 C4 C9 N1 -0.8(5) . . . . ? C3 C4 C9 C10 179.2(3) . . . . ? C8 N2 C10 C5 1.6(5) . . . . ? Ag1 N2 C10 C5 179.6(2) . . . . ? C8 N2 C10 C9 -179.2(3) . . . . ? Ag1 N2 C10 C9 -1.2(4) . . . . ? C6 C5 C10 N2 -2.0(5) . . . . ? C6 C5 C10 C9 178.8(3) . . . . ? N1 C9 C10 N2 4.2(4) . . . . ? C4 C9 C10 N2 -175.8(3) . . . . ? N1 C9 C10 C5 -176.6(3) . . . . ? C4 C9 C10 C5 3.4(5) . . . . ? C15 N4 C11 P1 -59.8(3) . . . . ? C12 N4 C11 P1 59.5(3) . . . . ? Ag1 N4 C11 P1 177.21(14) 1_455 . . . ? C14 P1 C11 N4 50.1(3) . . . . ? C13 P1 C11 N4 -49.7(3) . . . . ? Ag1 P1 C11 N4 179.86(17) . . . . ? C16 N3 C12 N4 -55.2(4) . . . . ? C13 N3 C12 N4 67.8(4) . . . . ? C15 N4 C12 N3 54.5(3) . . . . ? C11 N4 C12 N3 -66.3(3) . . . . ? Ag1 N4 C12 N3 172.9(2) 1_455 . . . ? C16 N3 C13 P1 60.2(3) . . . . ? C12 N3 C13 P1 -61.6(3) . . . . ? C14 P1 C13 N3 -48.9(3) . . . . ? C11 P1 C13 N3 50.1(3) . . . . ? Ag1 P1 C13 N3 -178.79(18) . . . . ? C15 N5 C14 P1 61.0(3) . . . . ? C16 N5 C14 P1 -60.2(3) . . . . ? C11 P1 C14 N5 -49.9(3) . . . . ? C13 P1 C14 N5 49.2(3) . . . . ? Ag1 P1 C14 N5 179.35(18) . . . . ? C16 N5 C15 N4 54.9(3) . . . . ? C14 N5 C15 N4 -67.5(3) . . . . ? C12 N4 C15 N5 -54.8(3) . . . . ? C11 N4 C15 N5 66.4(3) . . . . ? Ag1 N4 C15 N5 -170.2(2) 1_455 . . . ? C12 N3 C16 N5 54.9(4) . . . . ? C13 N3 C16 N5 -68.2(4) . . . . ? C15 N5 C16 N3 -54.6(3) . . . . ? C14 N5 C16 N3 68.1(3) . . . . ? _diffrn_measured_fraction_theta_max 0.996 _diffrn_reflns_theta_full 25.00 _diffrn_measured_fraction_theta_full 0.999 _refine_diff_density_max 1.095 _refine_diff_density_min -0.505 _refine_diff_density_rms 0.093