# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2014

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#                                CCDC 
# 
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#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
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#  fide research purposes only. It may contain copyright material
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data_compound-1

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C16 H24 Ag3 Mo12 N8 O42 P'
_chemical_formula_weight         2506

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   Cm

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z'

_cell_length_a                   12.973(5)
_cell_length_b                   19.165(5)
_cell_length_c                   9.998(5)
_cell_angle_alpha                90.000(5)
_cell_angle_beta                 101.712(5)
_cell_angle_gamma                90.000(5)
_cell_volume                     2434.0(17)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    6579
_cell_measurement_theta_min      1.92
_cell_measurement_theta_max      25.75

_exptl_crystal_description       block
_exptl_crystal_colour            orange
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.412
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2332
_exptl_absorpt_coefficient_mu    4.306
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.403
_exptl_absorpt_correction_T_max  0.461
_exptl_absorpt_process_details   'ABSCOR by T.Higashi    8  March, 1995'

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        none
_diffrn_reflns_number            6579
_diffrn_reflns_av_R_equivalents  0.0115
_diffrn_reflns_av_sigmaI/netI    0.0173
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_theta_min         1.92
_diffrn_reflns_theta_max         25.75
_reflns_number_total             4813
_reflns_number_gt                3548
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0273P)²+21.5010P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.00
_refine_ls_number_reflns         3694
_refine_ls_number_parameters     391
_refine_ls_number_restraints     2
_refine_ls_R_factor_all          0.0259
_refine_ls_R_factor_gt           0.0243
_refine_ls_wR_factor_ref         0.0588
_refine_ls_wR_factor_gt          0.0577
_refine_ls_goodness_of_fit_ref   0.960
_refine_ls_restrained_S_all      0.960
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P -1.1133(3) 0.0000 -0.3893(4) 0.0152(3) Uani 1 2 d S . .
O1W O -0.5769(9) 0.0000 0.5035(16) 0.100(5) Uani 1 2 d S . .
O1' O -1.1707(9) -0.0453(5) -0.5033(11) 0.020(2) Uiso 0.50 1 d P . .
O1 O -1.0546(9) -0.0440(5) -0.2730(10) 0.016(2) Uiso 0.50 1 d P . .
O2W O -0.6166(14) 0.0000 0.192(2) 0.129(7) Uani 1 2 d S . .
O2' O -1.1928(8) -0.0477(5) -0.3367(10) 0.015(2) Uani 0.50 1 d P . .
O2 O -1.0338(8) -0.0474(6) -0.4452(11) 0.018(2) Uiso 0.50 1 d P . .
O3 O -1.0221(8) -0.1657(4) -0.2201(11) 0.073(3) Uani 1 1 d . . .
O4 O -1.3442(7) -0.0671(5) -0.6284(9) 0.071(3) Uani 1 1 d . . .
O5 O -1.4325(7) 0.0000 -0.1533(9) 0.037(2) Uani 1 2 d S . .
O6 O -0.8813(10) 0.0000 0.0991(11) 0.085(5) Uani 1 2 d S . .
O7 O -0.9770(7) -0.0710(5) -0.6469(9) 0.078(3) Uani 1 1 d . . .
O8 O -1.2491(7) 0.0710(5) -0.1285(8) 0.079(3) Uani 1 1 d . . .
O9 O -1.4120(5) -0.1845(4) -0.5223(10) 0.059(2) Uani 1 1 d . . .
O10 O -1.0743(8) -0.1986(4) -0.7267(8) 0.063(3) Uani 1 1 d . . .
O11 O -1.1548(6) -0.2023(4) -0.0523(7) 0.052(2) Uani 1 1 d . . .
O12 O -0.8199(6) -0.1862(4) -0.2512(9) 0.057(2) Uani 1 1 d . . .
O13 O -1.1770(7) -0.0700(5) -0.7368(10) 0.073(3) Uani 1 1 d . . .
O14 O -1.2344(8) -0.1649(5) -0.3152(8) 0.085(4) Uani 1 1 d . . .
O15 O -1.0509(8) -0.0724(5) -0.0409(10) 0.075(3) Uani 1 1 d . . .
O16 O -1.3732(7) -0.0655(4) -0.3729(8) 0.073(3) Uani 1 1 d . . .
O17 O -1.2038(6) -0.1656(4) -0.5581(10) 0.062(2) Uani 1 1 d . . .
O18 O -0.9942(8) -0.1647(5) -0.4631(10) 0.085(4) Uani 1 1 d . . .
O20 O -0.8812(7) -0.0660(4) -0.1480(10) 0.071(3) Uani 1 1 d . . .
O21 O -1.3493(8) 0.0000 -0.8761(9) 0.057(3) Uani 1 2 d S . .
O22 O -0.7903(7) 0.0000 -0.6257(9) 0.036(2) Uani 1 2 d S . .
Mo1 Mo -1.32570(8) 0.0000 -0.21712(10) 0.0268(3) Uani 1 2 d S . .
Mo2 Mo -0.90770(6) -0.12472(4) -0.29666(8) 0.02961(19) Uani 1 1 d . . .
Mo3 Mo -1.08644(6) -0.13791(4) -0.61699(7) 0.02981(18) Uani 1 1 d . . .
Mo4 Mo -0.96046(8) 0.0000 -0.05126(10) 0.0278(3) Uani 1 2 d S . .
Mo5 Mo -1.14129(6) -0.13880(4) -0.16123(8) 0.0350(2) Uani 1 1 d . . .
Mo6 Mo -0.89820(8) 0.0000 -0.55925(10) 0.0291(3) Uani 1 2 d S . .
Mo7 Mo -1.31963(5) -0.12383(4) -0.48236(7) 0.02646(18) Uani 1 1 d . . .
Mo8 Mo -1.26766(9) 0.0000 -0.72561(10) 0.0316(3) Uani 1 2 d S . .
Ag1 Ag -0.63859(7) -0.13226(5) -0.44835(9) 0.0622(2) Uani 1 1 d . . .
Ag2 Ag -0.70488(9) 0.0000 -0.18350(19) 0.0772(5) Uani 1 2 d S . .
C1 C -0.2985(7) -0.3030(4) 0.3136(8) 0.0357(19) Uani 1 1 d . . .
H1A H -0.3372 -0.2846 0.3741 0.043 Uiso 1 1 calc R . .
C2 C -0.3212(6) -0.2946(4) 0.1792(8) 0.0266(18) Uani 1 1 d . . .
C3 C -0.2464(8) -0.3310(5) 0.1314(9) 0.052(3) Uani 1 1 d . . .
H3A H -0.2424 -0.3352 0.0399 0.062 Uiso 1 1 calc R . .
C4 C -0.4083(7) -0.2582(5) 0.0952(11) 0.058(3) Uani 1 1 d . . .
H4A H -0.4669 -0.2574 0.1420 0.070 Uiso 1 1 calc R . .
H4B H -0.4307 -0.2837 0.0105 0.070 Uiso 1 1 calc R . .
C5 C -0.3823(7) -0.1863(5) 0.0634(10) 0.040(2) Uani 1 1 d . . .
H5A H -0.3728 -0.1583 0.1458 0.048 Uiso 1 1 calc R . .
H5B H -0.3166 -0.1861 0.0314 0.048 Uiso 1 1 calc R . .
C6 C -0.4875(6) -0.1694(4) -0.1737(9) 0.0323(18) Uani 1 1 d . . .
H6A H -0.4480 -0.1990 -0.2173 0.039 Uiso 1 1 calc R . .
C7 C -0.4657(5) -0.1556(3) -0.0413(7) 0.0203(13) Uani 1 1 d . . .
C8 C -0.5412(7) -0.1113(5) -0.0215(9) 0.036(2) Uani 1 1 d . . .
H8A H -0.5464 -0.0923 0.0624 0.043 Uiso 1 1 calc R . .
N1 N -0.2131(6) -0.3412(4) 0.3486(8) 0.0353(17) Uani 1 1 d . . .
N2 N -0.1808(9) -0.3591(4) 0.2336(9) 0.058(3) Uani 1 1 d . . .
H2A H -0.1270 -0.3844 0.2283 0.070 Uiso 1 1 calc R . .
N3 N -0.6062(5) -0.0986(3) -0.1364(7) 0.0329(14) Uani 1 1 d . . .
N4 N -0.5722(5) -0.1358(3) -0.2360(7) 0.0306(14) Uani 1 1 d . . .
O19 O -0.8481(7) -0.0684(5) -0.4069(8) 0.078(3) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1' 1.505(11) . ?
P1 O1' 1.505(11) 2 ?
P1 O1 1.512(10) 2 ?
P1 O1 1.512(10) . ?
P1 O2' 1.549(11) 2 ?
P1 O2' 1.549(11) . ?
P1 O2 1.560(11) 2 ?
P1 O2 1.560(11) . ?
O1' O1' 1.74(2) 2 ?
O1' O2' 1.748(15) . ?
O1' O2 1.753(15) . ?
O1' Mo8 2.478(11) . ?
O1' Mo3 2.477(11) . ?
O1' Mo7 2.491(11) . ?
O1 O1 1.69(2) 2 ?
O1 O2' 1.779(15) . ?
O1 O2 1.798(16) . ?
O1 Mo4 2.453(10) . ?
O1 Mo2 2.502(11) . ?
O1 Mo5 2.514(11) . ?
O2' Mo7 2.446(10) . ?
O2' Mo1 2.465(11) . ?
O2' Mo5 2.469(10) . ?
O2 O2 1.82(2) 2 ?
O2 Mo3 2.439(11) . ?
O2 Mo6 2.456(11) . ?
O2 Mo2 2.469(10) . ?
O3 Mo5 1.837(10) . ?
O3 Mo2 1.966(9) . ?
O4 Mo7 1.796(7) . ?
O4 Mo8 1.994(8) . ?
O5 Mo1 1.639(9) . ?
O6 Mo4 1.639(11) . ?
O7 Mo6 1.816(8) . ?
O7 Mo3 1.981(8) . ?
O8 Mo1 1.807(8) . ?
O8 Mo5 1.985(7) 2 ?
O9 Mo7 1.659(6) . ?
O10 Mo3 1.629(7) . ?
O11 Mo5 1.665(7) . ?
O12 Mo2 1.638(7) . ?
O13 Mo8 1.803(8) . ?
O13 Mo3 1.984(8) . ?
O14 Mo5 1.823(9) . ?
O14 Mo7 1.971(8) . ?
O15 Mo4 1.833(9) . ?
O15 Mo5 1.968(9) . ?
O16 Mo7 1.800(8) . ?
O16 Mo1 1.997(7) . ?
O17 Mo3 1.819(8) . ?
O17 Mo7 1.984(8) . ?
O18 Mo3 1.821(9) . ?
O18 Mo2 1.964(9) . ?
O20 Mo2 1.840(8) . ?
O20 Mo4 1.999(8) . ?
O21 Mo8 1.655(8) . ?
O22 Mo6 1.667(9) . ?
Mo1 O8 1.807(8) 2 ?
Mo1 O16 1.997(7) 2 ?
Mo1 O2' 2.465(11) 2 ?
Mo2 O19 1.823(7) . ?
Mo4 O15 1.833(9) 2 ?
Mo4 O20 1.999(8) 2 ?
Mo4 O1 2.453(10) 2 ?
Mo5 O8 1.985(7) 2 ?
Mo6 O7 1.816(8) 2 ?
Mo6 O19 2.015(8) 2 ?
Mo6 O19 2.015(8) . ?
Mo6 O2 2.456(11) 2 ?
Mo8 O13 1.803(8) 2 ?
Mo8 O4 1.994(8) 2 ?
Mo8 O1' 2.478(11) 2 ?
Ag1 N1 2.126(8) 4_444 ?
Ag1 N4 2.124(7) . ?
Ag2 N3 2.278(6) 2 ?
Ag2 N3 2.278(6) . ?
C1 N1 1.315(11) . ?
C1 C2 1.326(11) . ?
C2 C3 1.358(13) . ?
C2 C4 1.443(11) . ?
C3 N2 1.305(12) . ?
C4 C5 1.469(12) . ?
C5 C7 1.468(10) . ?
C6 N4 1.316(10) . ?
C6 C7 1.323(11) . ?
C7 C8 1.341(11) . ?
C8 N3 1.303(10) . ?
N1 N2 1.346(12) . ?
N1 Ag1 2.126(8) 4_546 ?
N3 N4 1.367(9) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1' P1 O1' 70.5(8) . 2 ?
O1' P1 O1 178.7(7) . 2 ?
O1' P1 O1 110.8(4) 2 2 ?
O1' P1 O1 110.8(4) . . ?
O1' P1 O1 178.7(7) 2 . ?
O1 P1 O1 67.9(8) 2 . ?
O1' P1 O2' 109.7(6) . 2 ?
O1' P1 O2' 69.8(6) 2 2 ?
O1 P1 O2' 71.1(6) 2 2 ?
O1 P1 O2' 109.6(6) . 2 ?
O1' P1 O2' 69.8(6) . . ?
O1' P1 O2' 109.7(6) 2 . ?
O1 P1 O2' 109.6(6) 2 . ?
O1 P1 O2' 71.1(6) . . ?
O2' P1 O2' 72.4(8) 2 . ?
O1' P1 O2 109.0(6) . 2 ?
O1' P1 O2 69.7(6) 2 2 ?
O1 P1 O2 71.6(6) 2 2 ?
O1 P1 O2 109.5(6) . 2 ?
O2' P1 O2 108.2(3) 2 2 ?
O2' P1 O2 178.8(7) . 2 ?
O1' P1 O2 69.7(6) . . ?
O1' P1 O2 109.0(6) 2 . ?
O1 P1 O2 109.5(6) 2 . ?
O1 P1 O2 71.6(6) . . ?
O2' P1 O2 178.8(7) 2 . ?
O2' P1 O2 108.2(3) . . ?
O2 P1 O2 71.2(8) 2 . ?
P1 O1' O1' 54.7(4) . 2 ?
P1 O1' O2' 56.3(5) . . ?
O1' O1' O2' 91.5(5) 2 . ?
P1 O1' O2 56.6(5) . . ?
O1' O1' O2 91.3(5) 2 . ?
O2' O1' O2 92.0(7) . . ?
P1 O1' Mo8 124.1(6) . . ?
O1' O1' Mo8 69.5(2) 2 . ?
O2' O1' Mo8 135.4(7) . . ?
O2 O1' Mo8 126.9(7) . . ?
P1 O1' Mo3 124.4(6) . . ?
O1' O1' Mo3 135.7(3) 2 . ?
O2' O1' Mo3 126.3(6) . . ?
O2 O1' Mo3 68.0(5) . . ?
Mo8 O1' Mo3 91.8(4) . . ?
P1 O1' Mo7 123.9(6) . . ?
O1' O1' Mo7 127.1(3) 2 . ?
O2' O1' Mo7 67.9(5) . . ?
O2 O1' Mo7 135.2(7) . . ?
Mo8 O1' Mo7 91.5(4) . . ?
Mo3 O1' Mo7 91.6(3) . . ?
P1 O1 O1 56.1(4) . 2 ?
P1 O1 O2' 55.4(5) . . ?
O1 O1 O2' 92.3(5) 2 . ?
P1 O1 O2 55.4(5) . . ?
O1 O1 O2 92.0(5) 2 . ?
O2' O1 O2 89.5(6) . . ?
P1 O1 Mo4 125.7(6) . . ?
O1 O1 Mo4 69.9(2) 2 . ?
O2' O1 Mo4 128.2(7) . . ?
O2 O1 Mo4 137.2(7) . . ?
P1 O1 Mo2 123.1(6) . . ?
O1 O1 Mo2 128.2(2) 2 . ?
O2' O1 Mo2 132.3(6) . . ?
O2 O1 Mo2 67.8(5) . . ?
Mo4 O1 Mo2 92.8(3) . . ?
P1 O1 Mo5 123.0(6) . . ?
O1 O1 Mo5 136.2(2) 2 . ?
O2' O1 Mo5 67.7(5) . . ?
O2 O1 Mo5 124.6(6) . . ?
Mo4 O1 Mo5 91.9(3) . . ?
Mo2 O1 Mo5 90.8(3) . . ?
P1 O2' O1' 53.9(5) . . ?
P1 O2' O1 53.5(5) . . ?
O1' O2' O1 89.5(8) . . ?
P1 O2' Mo7 124.3(6) . . ?
O1' O2' Mo7 70.7(5) . . ?
O1 O2' Mo7 138.1(6) . . ?
P1 O2' Mo1 121.7(5) . . ?
O1' O2' Mo1 136.0(6) . . ?
O1 O2' Mo1 124.4(6) . . ?
Mo7 O2' Mo1 93.3(4) . . ?
P1 O2' Mo5 123.8(6) . . ?
O1' O2' Mo5 128.5(6) . . ?
O1 O2' Mo5 70.5(5) . . ?
Mo7 O2' Mo5 93.1(3) . . ?
Mo1 O2' Mo5 91.9(4) . . ?
P1 O2 O1' 53.7(5) . . ?
P1 O2 O1 52.9(5) . . ?
O1' O2 O1 88.7(7) . . ?
P1 O2 O2 54.4(4) . 2 ?
O1' O2 O2 88.7(5) . 2 ?
O1 O2 O2 88.0(5) . 2 ?
P1 O2 Mo3 123.7(6) . . ?
O1' O2 Mo3 70.3(5) . . ?
O1 O2 Mo3 128.7(6) . . ?
O2 O2 Mo3 135.4(3) 2 . ?
P1 O2 Mo6 122.6(6) . . ?
O1' O2 Mo6 127.6(7) . . ?
O1 O2 Mo6 133.8(6) . . ?
O2 O2 Mo6 68.3(2) 2 . ?
Mo3 O2 Mo6 93.5(4) . . ?
P1 O2 Mo2 122.6(6) . . ?
O1' O2 Mo2 135.7(7) . . ?
O1 O2 Mo2 69.8(5) . . ?
O2 O2 Mo2 126.9(2) 2 . ?
Mo3 O2 Mo2 93.0(4) . . ?
Mo6 O2 Mo2 93.0(4) . . ?
Mo5 O3 Mo2 139.8(5) . . ?
Mo7 O4 Mo8 139.7(5) . . ?
Mo6 O7 Mo3 139.7(6) . . ?
Mo1 O8 Mo5 138.4(5) . 2 ?
Mo8 O13 Mo3 139.9(5) . . ?
Mo5 O14 Mo7 140.2(6) . . ?
Mo4 O15 Mo5 139.8(6) . . ?
Mo7 O16 Mo1 140.2(5) . . ?
Mo3 O17 Mo7 139.0(5) . . ?
Mo3 O18 Mo2 140.4(6) . . ?
Mo2 O20 Mo4 138.4(5) . . ?
O5 Mo1 O8 103.5(4) . . ?
O5 Mo1 O8 103.5(4) . 2 ?
O8 Mo1 O8 97.7(6) . 2 ?
O5 Mo1 O16 98.7(4) . . ?
O8 Mo1 O16 155.1(4) . . ?
O8 Mo1 O16 87.8(3) 2 . ?
O5 Mo1 O16 98.7(4) . 2 ?
O8 Mo1 O16 87.8(3) . 2 ?
O8 Mo1 O16 155.1(4) 2 2 ?
O16 Mo1 O16 77.8(5) . 2 ?
O5 Mo1 O2' 156.7(2) . 2 ?
O8 Mo1 O2' 65.8(4) . 2 ?
O8 Mo1 O2' 98.5(4) 2 2 ?
O16 Mo1 O2' 89.5(4) . 2 ?
O16 Mo1 O2' 61.6(4) 2 2 ?
O5 Mo1 O2' 156.7(2) . . ?
O8 Mo1 O2' 98.5(4) . . ?
O8 Mo1 O2' 65.8(4) 2 . ?
O16 Mo1 O2' 61.6(4) . . ?
O16 Mo1 O2' 89.5(4) 2 . ?
O2' Mo1 O2' 43.6(5) 2 . ?
O12 Mo2 O19 103.8(5) . . ?
O12 Mo2 O20 102.1(4) . . ?
O19 Mo2 O20 95.3(4) . . ?
O12 Mo2 O18 101.6(4) . . ?
O19 Mo2 O18 87.6(4) . . ?
O20 Mo2 O18 154.7(5) . . ?
O12 Mo2 O3 98.1(4) . . ?
O19 Mo2 O3 156.6(4) . . ?
O20 Mo2 O3 87.8(4) . . ?
O18 Mo2 O3 80.0(4) . . ?
O12 Mo2 O2 159.7(4) . . ?
O19 Mo2 O2 65.9(4) . . ?
O20 Mo2 O2 96.4(4) . . ?
O18 Mo2 O2 61.9(4) . . ?
O3 Mo2 O2 90.8(4) . . ?
O12 Mo2 O1 156.7(4) . . ?
O19 Mo2 O1 96.6(4) . . ?
O20 Mo2 O1 64.3(4) . . ?
O18 Mo2 O1 90.3(4) . . ?
O3 Mo2 O1 63.9(4) . . ?
O2 Mo2 O1 42.4(4) . . ?
O10 Mo3 O18 103.4(5) . . ?
O10 Mo3 O17 102.2(5) . . ?
O18 Mo3 O17 95.4(4) . . ?
O10 Mo3 O7 101.0(5) . . ?
O18 Mo3 O7 86.7(3) . . ?
O17 Mo3 O7 155.5(4) . . ?
O10 Mo3 O13 100.9(4) . . ?
O18 Mo3 O13 154.4(5) . . ?
O17 Mo3 O13 87.4(3) . . ?
O7 Mo3 O13 80.7(4) . . ?
O10 Mo3 O2 158.6(4) . . ?
O18 Mo3 O2 64.1(4) . . ?
O17 Mo3 O2 96.5(4) . . ?
O7 Mo3 O2 62.5(4) . . ?
O13 Mo3 O2 90.3(4) . . ?
O10 Mo3 O1' 158.8(4) . . ?
O18 Mo3 O1' 95.1(5) . . ?
O17 Mo3 O1' 65.5(4) . . ?
O7 Mo3 O1' 90.1(4) . . ?
O13 Mo3 O1' 62.9(4) . . ?
O2 Mo3 O1' 41.8(3) . . ?
O6 Mo4 O15 103.7(4) . . ?
O6 Mo4 O15 103.7(4) . 2 ?
O15 Mo4 O15 98.3(6) . 2 ?
O6 Mo4 O20 98.9(5) . 2 ?
O15 Mo4 O20 154.7(4) . 2 ?
O15 Mo4 O20 86.9(4) 2 2 ?
O6 Mo4 O20 98.9(5) . . ?
O15 Mo4 O20 86.9(4) . . ?
O15 Mo4 O20 154.7(4) 2 . ?
O20 Mo4 O20 78.5(5) 2 . ?
O6 Mo4 O1 158.9(3) . . ?
O15 Mo4 O1 65.4(4) . . ?
O15 Mo4 O1 96.0(4) 2 . ?
O20 Mo4 O1 89.5(4) 2 . ?
O20 Mo4 O1 63.6(4) . . ?
O6 Mo4 O1 158.9(3) . 2 ?
O15 Mo4 O1 96.0(4) . 2 ?
O15 Mo4 O1 65.4(4) 2 2 ?
O20 Mo4 O1 63.6(4) 2 2 ?
O20 Mo4 O1 89.5(4) . 2 ?
O1 Mo4 O1 40.2(5) . 2 ?
O11 Mo5 O14 102.2(5) . . ?
O11 Mo5 O3 102.2(4) . . ?
O14 Mo5 O3 96.2(4) . . ?
O11 Mo5 O15 101.6(4) . . ?
O14 Mo5 O15 154.7(4) . . ?
O3 Mo5 O15 86.7(4) . . ?
O11 Mo5 O8 101.5(4) . 2 ?
O14 Mo5 O8 87.2(4) . 2 ?
O3 Mo5 O8 154.7(4) . 2 ?
O15 Mo5 O8 80.1(4) . 2 ?
O11 Mo5 O2' 158.7(4) . . ?
O14 Mo5 O2' 63.7(4) . . ?
O3 Mo5 O2' 95.4(4) . . ?
O15 Mo5 O2' 91.1(4) . . ?
O8 Mo5 O2' 63.6(4) 2 . ?
O11 Mo5 O1 159.1(4) . . ?
O14 Mo5 O1 95.9(4) . . ?
O3 Mo5 O1 65.1(4) . . ?
O15 Mo5 O1 62.6(4) . . ?
O8 Mo5 O1 89.7(4) 2 . ?
O2' Mo5 O1 41.8(3) . . ?
O22 Mo6 O7 104.1(4) . . ?
O22 Mo6 O7 104.1(4) . 2 ?
O7 Mo6 O7 97.0(6) . 2 ?
O22 Mo6 O19 97.7(4) . 2 ?
O7 Mo6 O19 156.3(4) . 2 ?
O7 Mo6 O19 86.7(3) 2 2 ?
O22 Mo6 O19 97.7(4) . . ?
O7 Mo6 O19 86.7(3) . . ?
O7 Mo6 O19 156.3(4) 2 . ?
O19 Mo6 O19 81.1(5) 2 . ?
O22 Mo6 O2 157.5(3) . . ?
O7 Mo6 O2 64.0(4) . . ?
O7 Mo6 O2 96.6(4) 2 . ?
O19 Mo6 O2 92.3(4) 2 . ?
O19 Mo6 O2 63.9(4) . . ?
O22 Mo6 O2 157.5(3) . 2 ?
O7 Mo6 O2 96.6(4) . 2 ?
O7 Mo6 O2 64.0(4) 2 2 ?
O19 Mo6 O2 63.9(4) 2 2 ?
O19 Mo6 O2 92.3(4) . 2 ?
O2 Mo6 O2 43.4(5) . 2 ?
O9 Mo7 O4 103.2(5) . . ?
O9 Mo7 O16 103.4(5) . . ?
O4 Mo7 O16 95.3(4) . . ?
O9 Mo7 O14 100.2(5) . . ?
O4 Mo7 O14 155.1(5) . . ?
O16 Mo7 O14 87.2(3) . . ?
O9 Mo7 O17 101.0(4) . . ?
O4 Mo7 O17 87.5(3) . . ?
O16 Mo7 O17 154.0(4) . . ?
O14 Mo7 O17 79.9(4) . . ?
O9 Mo7 O2' 157.9(4) . . ?
O4 Mo7 O2' 96.3(4) . . ?
O16 Mo7 O2' 64.1(4) . . ?
O14 Mo7 O2' 62.6(4) . . ?
O17 Mo7 O2' 89.9(4) . . ?
O9 Mo7 O1' 159.7(4) . . ?
O4 Mo7 O1' 65.1(4) . . ?
O16 Mo7 O1' 94.5(4) . . ?
O14 Mo7 O1' 90.1(4) . . ?
O17 Mo7 O1' 63.3(4) . . ?
O2' Mo7 O1' 41.5(4) . . ?
O21 Mo8 O13 104.4(4) . 2 ?
O21 Mo8 O13 104.4(4) . . ?
O13 Mo8 O13 96.2(6) 2 . ?
O21 Mo8 O4 98.8(4) . 2 ?
O13 Mo8 O4 86.9(3) 2 2 ?
O13 Mo8 O4 155.0(4) . 2 ?
O21 Mo8 O4 98.8(4) . . ?
O13 Mo8 O4 155.0(4) 2 . ?
O13 Mo8 O4 86.9(3) . . ?
O4 Mo8 O4 80.4(5) 2 . ?
O21 Mo8 O1' 158.4(3) . 2 ?
O13 Mo8 O1' 64.9(4) 2 2 ?
O13 Mo8 O1' 95.6(4) . 2 ?
O4 Mo8 O1' 63.2(4) 2 2 ?
O4 Mo8 O1' 90.1(4) . 2 ?
O21 Mo8 O1' 158.4(3) . . ?
O13 Mo8 O1' 95.6(4) 2 . ?
O13 Mo8 O1' 64.9(4) . . ?
O4 Mo8 O1' 90.1(4) 2 . ?
O4 Mo8 O1' 63.2(4) . . ?
O1' Mo8 O1' 41.0(5) 2 . ?
N1 Ag1 N4 163.9(3) 4_444 . ?
N3 Ag2 N3 112.1(3) 2 . ?
N1 C1 C2 109.8(8) . . ?
C1 C2 C3 105.5(7) . . ?
C1 C2 C4 129.4(10) . . ?
C3 C2 C4 125.1(9) . . ?
N2 C3 C2 109.6(8) . . ?
C2 C4 C5 113.1(7) . . ?
C7 C5 C4 111.3(7) . . ?
N4 C6 C7 111.3(8) . . ?
C6 C7 C8 105.1(7) . . ?
C6 C7 C5 127.7(8) . . ?
C8 C7 C5 127.1(8) . . ?
N3 C8 C7 110.4(7) . . ?
C1 N1 N2 107.9(8) . . ?
C1 N1 Ag1 125.6(6) . 4_546 ?
N2 N1 Ag1 126.5(6) . 4_546 ?
C3 N2 N1 107.3(9) . . ?
C8 N3 N4 107.4(7) . . ?
C8 N3 Ag2 125.0(6) . . ?
N4 N3 Ag2 122.2(5) . . ?
C6 N4 N3 105.8(7) . . ?
C6 N4 Ag1 128.2(6) . . ?
N3 N4 Ag1 125.9(5) . . ?
Mo2 O19 Mo6 137.0(5) . . ?

_diffrn_measured_fraction_theta_max 0.995
_diffrn_reflns_theta_full        25.75
_diffrn_measured_fraction_theta_full 0.995
_refine_diff_density_max         1.001
_refine_diff_density_min         -1.198
_refine_diff_density_rms         0.118

_database_code_depnum_ccdc_archive 'CCDC 979424'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_compound-2

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C22 H42 Ag N8 O44 P W12'
_chemical_formula_weight         3467

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   12.863(5)
_cell_length_b                   12.959(5)
_cell_length_c                   19.517(5)
_cell_angle_alpha                80.885(5)
_cell_angle_beta                 89.984(5)
_cell_angle_gamma                78.821(5)
_cell_volume                     3149.7(19)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    17951
_cell_measurement_theta_min      1.61
_cell_measurement_theta_max      26.42

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.646
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3044
_exptl_absorpt_coefficient_mu    22.239
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.011
_exptl_absorpt_correction_T_max  0.027
_exptl_absorpt_process_details   'ABSCOR by T.Higashi    8  March, 1995'

_exptl_special_details           
; 
During the refinement, the restraint command 'ISOR' is used to refine the non-H atoms with ADP problems. 
These atoms are as follows: O22 O25 O26 C6 C37 C11 C15 O7 C20 C37 O1 O1' O2 O2' O3 O21 O21' O22' C10 O11 O30 C3 C4 and C8. 
The command 'delu' was used to solve the non-H atoms with 'Large Hirshfeld Difference...' problems. 
These atoms are as follows: W6 O9 W7 O28 W10 O38 N4 N5 C8 C15 C12 C37 W2 O11 W8 O28 N2 and C8. 
These restraint refinement leads to a relatively high restraint value 152. 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        none
_diffrn_reflns_number            17951
_diffrn_reflns_av_R_equivalents  0.0441
_diffrn_reflns_av_sigmaI/netI    0.1188
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.61
_diffrn_reflns_theta_max         26.42
_reflns_number_total             12948
_reflns_number_gt                7702
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0687P)²+164.3226P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         12695
_refine_ls_number_parameters     832
_refine_ls_number_restraints     152
_refine_ls_R_factor_all          0.1324
_refine_ls_R_factor_gt           0.0726
_refine_ls_wR_factor_ref         0.1892
_refine_ls_wR_factor_gt          0.1637
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_restrained_S_all      1.012
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P -0.5000 0.0000 0.0000 0.020(2) Uani 1 2 d S . .
P2 P 0.0000 0.5000 -0.5000 0.026(2) Uani 1 2 d S . .
W1 W -0.48678(10) 0.21384(11) 0.09209(6) 0.0384(3) Uani 1 1 d . . .
W2 W -0.51704(9) -0.03841(10) 0.18439(5) 0.0362(3) Uani 1 1 d U . .
W3 W -0.27129(8) -0.00752(11) 0.10544(6) 0.0355(3) Uani 1 1 d . . .
W4 W -0.52730(9) -0.25283(10) 0.09168(5) 0.0302(3) Uani 1 1 d . . .
W5 W -0.28340(8) -0.22084(10) 0.01187(6) 0.0301(3) Uani 1 1 d . . .
W6 W -0.25504(8) 0.03315(10) -0.07894(6) 0.0307(3) Uani 1 1 d U . .
W7 W -0.26799(9) 0.60824(13) -0.55801(6) 0.0430(4) Uani 1 1 d . . .
W8 W -0.13984(9) 0.73786(12) -0.44483(6) 0.0396(3) Uani 1 1 d U . .
W9 W -0.20777(9) 0.36582(12) -0.43847(6) 0.0411(3) Uani 1 1 d . . .
W10 W 0.06049(10) 0.25695(12) -0.38004(6) 0.0448(4) Uani 1 1 d U . .
W11 W -0.07918(9) 0.49515(11) -0.32507(5) 0.0359(3) Uani 1 1 d . . .
W12 W -0.12833(8) 0.37180(11) -0.61376(5) 0.0337(3) Uani 1 1 d . . .
O1' O -0.614(3) 0.036(3) -0.0013(17) 0.031(8) Uani 0.50 1 d PU . .
O1 O -0.458(2) 0.031(3) 0.0690(15) 0.018(7) Uani 0.50 1 d PU . .
O1W O -0.442(3) 0.325(2) -0.2918(13) 0.098(11) Uani 1 1 d . . .
O2' O -0.445(2) 0.061(3) -0.0613(15) 0.018(7) Uani 0.50 1 d PU . .
O2 O -0.462(2) -0.124(3) 0.0083(15) 0.019(7) Uani 0.50 1 d PU . .
O2W O -0.957(2) 0.929(3) -0.367(2) 0.118(13) Uani 1 1 d . . .
O3W O -0.0243(19) 0.745(2) 0.1669(11) 0.066(7) Uani 1 1 d . . .
O3 O -0.3634(18) -0.052(2) 0.1747(13) 0.067(7) Uani 1 1 d U . .
O4W O -0.290(2) 0.730(2) 0.2499(11) 0.072(8) Uani 1 1 d . . .
O4 O -0.2483(19) -0.1453(18) 0.0833(10) 0.055(6) Uani 1 1 d . . .
O5 O -0.1396(17) 0.052(2) -0.1172(13) 0.063(7) Uani 1 1 d . . .
O6 O -0.339(2) 0.020(2) -0.1565(12) 0.071(8) Uani 1 1 d . . .
O7 O -0.6309(18) 0.243(2) 0.0596(12) 0.065(7) Uani 1 1 d U . .
O8 O -0.347(2) 0.133(2) 0.1032(17) 0.091(10) Uani 1 1 d . . .
O9 O -0.3325(18) 0.176(2) -0.0881(11) 0.062(7) Uani 1 1 d U . .
O10 O -0.4808(17) 0.3132(18) 0.1369(11) 0.051(6) Uani 1 1 d . . .
O11 O -0.5259(18) 0.111(2) 0.1631(13) 0.069(6) Uani 1 1 d U . .
O12 O -0.5402(16) -0.3737(18) 0.1341(12) 0.054(6) Uani 1 1 d . . .
O13 O -0.4998(17) -0.178(2) 0.1636(12) 0.062(7) Uani 1 1 d . . .
O14 O -0.3792(16) -0.277(2) 0.0738(10) 0.065(8) Uani 1 1 d . . .
O15 O -0.238(2) -0.117(2) -0.0529(10) 0.063(7) Uani 1 1 d . . .
O16 O -0.224(2) 0.039(2) 0.0158(10) 0.078(9) Uani 1 1 d . . .
O17 O -0.4502(14) 0.269(2) -0.0001(9) 0.053(7) Uani 1 1 d . . .
O18 O -0.1825(18) -0.3267(18) 0.0177(11) 0.059(7) Uani 1 1 d . . .
O19 O -0.5215(16) -0.057(2) 0.2690(9) 0.054(7) Uani 1 1 d . . .
O20 O -0.1640(17) -0.0125(19) 0.1548(10) 0.051(6) Uani 1 1 d . . .
O21' O -0.105(2) 0.470(3) -0.5195(15) 0.024(7) Uani 0.50 1 d PU . .
O21 O -0.038(3) 0.439(3) -0.4356(19) 0.040(10) Uani 0.50 1 d PU . .
O22 O -0.010(3) 0.554(3) -0.4385(17) 0.031(8) Uani 0.50 1 d PU . .
O22' O -0.086(2) 0.602(3) -0.5216(15) 0.021(7) Uani 0.50 1 d PU . .
O23 O -0.0463(15) 0.448(2) -0.6740(13) 0.070(8) Uani 1 1 d . . .
O24 O 0.099(2) 0.208(3) -0.4647(11) 0.088(10) Uani 1 1 d . . .
O25 O 0.1950(19) 0.299(2) -0.3809(12) 0.072(7) Uani 1 1 d U . .
O26 O 0.0048(16) 0.7330(18) -0.4140(10) 0.049(5) Uani 1 1 d U . .
O27 O -0.082(2) 0.265(2) -0.4059(15) 0.091(10) Uani 1 1 d . . .
O28 O -0.1512(15) 0.633(2) -0.3671(13) 0.063(7) Uani 1 1 d U . .
O29 O -0.1150(15) 0.495(2) -0.2428(10) 0.070(9) Uani 1 1 d . . .
O30 O -0.251(2) 0.691(2) -0.4892(12) 0.073(7) Uani 1 1 d U . .
O31 O 0.0106(19) 0.365(2) -0.3214(13) 0.080(9) Uani 1 1 d . . .
O32 O -0.288(2) 0.498(2) -0.4858(11) 0.084(10) Uani 1 1 d . . .
O33 O -0.1858(18) 0.441(2) -0.3638(14) 0.079(9) Uani 1 1 d . . .
O34 O -0.185(2) 0.324(2) -0.5256(10) 0.083(10) Uani 1 1 d . . .
O35 O -0.2270(19) 0.503(2) -0.6147(11) 0.073(9) Uani 1 1 d . . .
O36 O -0.186(2) 0.310(2) -0.6671(12) 0.068(7) Uani 1 1 d . . .
O37 O -0.2035(18) 0.8501(19) -0.4199(13) 0.064(7) Uani 1 1 d . . .
O38 O 0.0909(18) 0.143(2) -0.3229(11) 0.059(6) Uani 1 1 d U . .
O39 O -0.3938(16) 0.660(2) -0.5868(12) 0.062(7) Uani 1 1 d . . .
O40 O -0.3055(15) 0.3029(19) -0.4069(12) 0.054(6) Uani 1 1 d . . .
Ag1 Ag -0.29555(18) 0.4805(2) -0.16468(11) 0.0448(6) Uani 1 1 d . . .
C1 C 0.020(2) 0.432(3) 0.1014(18) 0.066(12) Uani 1 1 d . . .
H1A H 0.0616 0.4860 0.1017 0.099 Uiso 1 1 calc R . .
H1B H 0.0047 0.4255 0.0543 0.099 Uiso 1 1 calc R . .
H1C H 0.0578 0.3655 0.1256 0.099 Uiso 1 1 calc R . .
C2 C -0.372(2) 0.679(3) -0.2802(16) 0.047(9) Uani 1 1 d . . .
C3 C -0.027(2) 0.174(3) 0.0241(17) 0.055(9) Uani 1 1 d U . .
H3A H 0.0111 0.1538 -0.0158 0.082 Uiso 1 1 calc R . .
H3B H -0.0569 0.1157 0.0464 0.082 Uiso 1 1 calc R . .
H3C H 0.0215 0.1915 0.0560 0.082 Uiso 1 1 calc R . .
C4 C -0.538(3) 0.604(3) -0.4092(16) 0.054(9) Uani 1 1 d U . .
H4A H -0.5437 0.5307 -0.4010 0.081 Uiso 1 1 calc R . .
H4B H -0.5107 0.6216 -0.4544 0.081 Uiso 1 1 calc R . .
H4C H -0.6073 0.6480 -0.4068 0.081 Uiso 1 1 calc R . .
C5 C -0.302(3) 0.744(3) -0.2483(17) 0.052(9) Uani 1 1 d . . .
H5A H -0.2694 0.7039 -0.2056 0.078 Uiso 1 1 calc R . .
H5B H -0.3455 0.8094 -0.2393 0.078 Uiso 1 1 calc R . .
H5C H -0.2484 0.7600 -0.2801 0.078 Uiso 1 1 calc R . .
C6 C -0.657(3) 0.882(3) -0.3688(16) 0.046(8) Uani 1 1 d U . .
C7 C -0.338(3) 0.461(3) 0.2143(16) 0.066(12) Uani 1 1 d . . .
H7A H -0.3689 0.5231 0.2339 0.100 Uiso 1 1 calc R . .
H7B H -0.3252 0.3999 0.2502 0.100 Uiso 1 1 calc R . .
H7C H -0.3866 0.4503 0.1798 0.100 Uiso 1 1 calc R . .
C8 C -0.081(2) 0.463(3) 0.1360(15) 0.045(7) Uani 1 1 d U . .
C9 C -0.428(2) 0.716(3) -0.3414(17) 0.044(8) Uani 1 1 d . . .
C10 C -0.238(2) 0.477(2) 0.1819(13) 0.032(6) Uani 1 1 d U . .
C11 C -0.113(2) 0.268(3) 0.0016(15) 0.040(7) Uani 1 1 d U . .
C12 C -0.573(2) 0.864(3) -0.4077(17) 0.050(8) Uani 1 1 d U . .
C13 C -0.668(3) 0.871(4) -0.289(2) 0.076(13) Uani 1 1 d . . .
H13A H -0.7407 0.8920 -0.2785 0.114 Uiso 1 1 calc R . .
H13B H -0.6269 0.9166 -0.2718 0.114 Uiso 1 1 calc R . .
H13C H -0.6415 0.7986 -0.2683 0.114 Uiso 1 1 calc R . .
C14 C -0.255(2) 0.398(2) -0.0042(13) 0.032(7) Uani 1 1 d . . .
C15 C -0.167(2) 0.412(3) 0.1474(13) 0.036(6) Uani 1 1 d U . .
C16 C -0.180(2) 0.317(3) 0.1205(14) 0.045(8) Uani 1 1 d . . .
H16A H -0.2442 0.2964 0.1386 0.054 Uiso 1 1 calc R . .
H16B H -0.1212 0.2595 0.1389 0.054 Uiso 1 1 calc R . .
C17 C -0.464(2) 0.625(3) -0.3544(14) 0.049(9) Uani 1 1 d . . .
C18 C -0.1842(19) 0.323(2) 0.0429(14) 0.032(6) Uani 1 1 d . . .
C19 C -0.343(2) 0.482(2) 0.0100(15) 0.036(7) Uani 1 1 d . . .
H19A H -0.3766 0.5196 -0.0330 0.054 Uiso 1 1 calc R . .
H19B H -0.3161 0.5301 0.0345 0.054 Uiso 1 1 calc R . .
H19C H -0.3936 0.4499 0.0379 0.054 Uiso 1 1 calc R . .
C20 C -0.452(2) 0.822(3) -0.3834(17) 0.049(8) Uani 1 1 d U . .
H20A H -0.4094 0.8218 -0.4243 0.059 Uiso 1 1 calc R . .
H20B H -0.4313 0.8722 -0.3567 0.059 Uiso 1 1 calc R . .
C37 C -0.607(3) 0.888(3) -0.476(2) 0.067(10) Uani 1 1 d U . .
C42 C -0.560(4) 0.882(4) -0.5451(18) 0.090(15) Uani 1 1 d . . .
H42A H -0.4838 0.8659 -0.5397 0.134 Uiso 1 1 calc R . .
H42B H -0.5816 0.9491 -0.5750 0.134 Uiso 1 1 calc R . .
H42C H -0.5828 0.8269 -0.5653 0.134 Uiso 1 1 calc R . .
N1 N -0.198(2) 0.563(2) 0.1948(12) 0.047(7) Uani 1 1 d . . .
N2 N -0.1001(18) 0.554(2) 0.1622(11) 0.042(6) Uani 1 1 d U . .
H2A H -0.0592 0.6000 0.1595 0.051 Uiso 1 1 calc R . .
N3 N -0.3652(17) 0.580(3) -0.2565(13) 0.055(9) Uani 1 1 d . . .
N4 N -0.2260(19) 0.389(2) -0.0703(12) 0.046(7) Uani 1 1 d U . .
N5 N -0.1423(15) 0.302(2) -0.0613(12) 0.037(6) Uani 1 1 d U . .
H5D H -0.1134 0.2729 -0.0953 0.045 Uiso 1 1 calc R . .
N6 N -0.4250(17) 0.546(2) -0.3062(13) 0.046(7) Uani 1 1 d . . .
H6A H -0.4340 0.4816 -0.3048 0.056 Uiso 1 1 calc R . .
N7 N -0.719(2) 0.913(2) -0.4752(16) 0.064(9) Uani 1 1 d . . .
N12 N -0.744(3) 0.912(3) -0.407(2) 0.085(11) Uani 1 1 d . . .
H12A H -0.8071 0.9277 -0.3918 0.102 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1' 1.45(3) 2_455 ?
P1 O1' 1.45(3) . ?
P1 O2' 1.57(3) . ?
P1 O2' 1.57(3) 2_455 ?
P1 O2 1.57(3) 2_455 ?
P1 O2 1.57(3) . ?
P1 O1 1.59(3) . ?
P1 O1 1.59(3) 2_455 ?
P2 O22 1.47(3) . ?
P2 O22 1.47(3) 2_564 ?
P2 O21 1.51(4) 2_564 ?
P2 O21 1.51(4) . ?
P2 O21' 1.54(3) 2_564 ?
P2 O21' 1.54(3) . ?
P2 O22' 1.55(3) . ?
P2 O22' 1.55(3) 2_564 ?
W1 O10 1.68(2) . ?
W1 O8 1.90(2) . ?
W1 O11 1.90(2) . ?
W1 O7 1.91(2) . ?
W1 O17 1.922(18) . ?
W1 O1 2.44(3) . ?
W2 O19 1.633(18) . ?
W2 O13 1.89(2) . ?
W2 O6 1.89(2) 2_455 ?
W2 O11 1.90(3) . ?
W2 O3 1.96(2) . ?
W2 O1 2.47(3) . ?
W2 O2' 2.53(3) 2_455 ?
W3 O20 1.669(19) . ?
W3 O4 1.87(2) . ?
W3 O8 1.88(3) . ?
W3 O16 1.90(2) . ?
W3 O3 1.89(2) . ?
W3 O1 2.43(3) . ?
W4 O12 1.69(2) . ?
W4 O17 1.862(17) 2_455 ?
W4 O9 1.88(2) 2_455 ?
W4 O13 1.90(2) . ?
W4 O14 1.91(2) . ?
W4 O2 2.41(3) . ?
W4 O2' 2.42(3) 2_455 ?
W5 O18 1.69(2) . ?
W5 O7 1.87(2) 2_455 ?
W5 O15 1.87(2) . ?
W5 O14 1.89(2) . ?
W5 O4 1.93(2) . ?
W5 O2 2.39(3) . ?
W5 O1' 2.48(4) 2_455 ?
W6 O5 1.704(18) . ?
W6 O15 1.90(3) . ?
W6 O6 1.91(2) . ?
W6 O9 1.91(2) . ?
W6 O16 1.91(2) . ?
W6 O2' 2.43(3) . ?
W6 O1' 2.50(3) 2_455 ?
W7 O39 1.69(2) . ?
W7 O30 1.88(3) . ?
W7 O35 1.89(3) . ?
W7 O32 1.90(2) . ?
W7 O25 1.93(3) 2_564 ?
W7 O22' 2.44(3) . ?
W7 O21' 2.51(3) . ?
W8 O37 1.67(2) . ?
W8 O28 1.90(2) . ?
W8 O24 1.91(2) 2_564 ?
W8 O30 1.92(2) . ?
W8 O26 1.94(2) . ?
W8 O22' 2.49(3) . ?
W9 O40 1.69(2) . ?
W9 O34 1.87(2) . ?
W9 O27 1.91(2) . ?
W9 O32 1.92(2) . ?
W9 O33 1.92(3) . ?
W9 O21' 2.47(3) . ?
W10 O38 1.68(2) . ?
W10 O27 1.88(3) . ?
W10 O24 1.90(2) . ?
W10 O25 1.91(2) . ?
W10 O31 1.96(3) . ?
W10 O22' 2.50(3) 2_564 ?
W10 O21 2.52(4) . ?
W11 O29 1.671(19) . ?
W11 O31 1.85(3) . ?
W11 O33 1.87(2) . ?
W11 O28 1.90(2) . ?
W11 O23 1.90(2) 2_564 ?
W11 O21 2.41(4) . ?
W11 O22 2.45(3) . ?
W12 O36 1.66(2) . ?
W12 O23 1.87(2) . ?
W12 O26 1.90(2) 2_564 ?
W12 O35 1.91(2) . ?
W12 O34 1.93(2) . ?
W12 O21' 2.44(3) . ?
W12 O22 2.47(4) 2_564 ?
O1' O2 1.64(5) 2_455 ?
O1' O2' 1.67(5) 2_455 ?
O1' W5 2.48(4) 2_455 ?
O1' W6 2.50(3) 2_455 ?
O2' O1' 1.67(5) 2_455 ?
O2' O2 1.74(4) 2_455 ?
O2' W4 2.42(3) 2_455 ?
O2' W2 2.53(3) 2_455 ?
O2 O1' 1.64(5) 2_455 ?
O2 O2' 1.74(4) 2_455 ?
O6 W2 1.89(2) 2_455 ?
O7 W5 1.87(2) 2_455 ?
O9 W4 1.88(2) 2_455 ?
O17 W4 1.862(17) 2_455 ?
O21' O22 1.68(4) 2_564 ?
O21' O22' 1.77(5) . ?
O21' O21 1.80(5) . ?
O21 O22 1.60(6) . ?
O22 O21' 1.68(4) 2_564 ?
O22 W12 2.47(4) 2_564 ?
O22' W10 2.50(3) 2_564 ?
O23 W11 1.90(2) 2_564 ?
O24 W8 1.91(2) 2_564 ?
O25 W7 1.93(3) 2_564 ?
O26 W12 1.90(2) 2_564 ?
Ag1 N4 2.12(2) . ?
Ag1 N3 2.12(2) . ?
C1 C8 1.47(4) . ?
C2 N3 1.27(4) . ?
C2 C9 1.37(4) . ?
C2 C5 1.54(5) . ?
C3 C11 1.49(4) . ?
C4 C17 1.52(4) . ?
C6 N12 1.30(4) . ?
C6 C12 1.33(4) . ?
C6 C13 1.54(5) . ?
C7 C10 1.47(4) . ?
C8 N2 1.34(4) . ?
C8 C15 1.40(4) . ?
C9 C17 1.40(5) . ?
C9 C20 1.47(4) . ?
C10 C15 1.37(4) . ?
C10 N1 1.38(4) . ?
C11 N5 1.27(3) . ?
C11 C18 1.39(4) . ?
C12 C37 1.37(5) . ?
C12 C20 1.58(4) . ?
C14 N4 1.36(3) . ?
C14 C18 1.41(3) . ?
C14 C19 1.47(4) . ?
C15 C16 1.45(4) . ?
C16 C18 1.50(4) . ?
C17 N6 1.30(4) . ?
C37 N7 1.41(4) . ?
C37 C42 1.49(5) . ?
N1 N2 1.40(3) . ?
N3 N6 1.42(4) . ?
N4 N5 1.39(3) . ?
N7 N12 1.37(4) . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1' P1 O1' 180(3) 2_455 . ?
O1' P1 O2' 67.1(17) 2_455 . ?
O1' P1 O2' 112.9(17) . . ?
O1' P1 O2' 112.9(17) 2_455 2_455 ?
O1' P1 O2' 67.1(17) . 2_455 ?
O2' P1 O2' 180(3) . 2_455 ?
O1' P1 O2 114.5(18) 2_455 2_455 ?
O1' P1 O2 65.5(18) . 2_455 ?
O2' P1 O2 67.4(15) . 2_455 ?
O2' P1 O2 112.6(15) 2_455 2_455 ?
O1' P1 O2 65.5(18) 2_455 . ?
O1' P1 O2 114.5(18) . . ?
O2' P1 O2 112.6(15) . . ?
O2' P1 O2 67.4(15) 2_455 . ?
O2 P1 O2 180(3) 2_455 . ?
O1' P1 O1 74.6(17) 2_455 . ?
O1' P1 O1 105.4(17) . . ?
O2' P1 O1 105.8(15) . . ?
O2' P1 O1 74.2(15) 2_455 . ?
O2 P1 O1 75.4(16) 2_455 . ?
O2 P1 O1 104.6(16) . . ?
O1' P1 O1 105.4(17) 2_455 2_455 ?
O1' P1 O1 74.6(17) . 2_455 ?
O2' P1 O1 74.2(15) . 2_455 ?
O2' P1 O1 105.8(15) 2_455 2_455 ?
O2 P1 O1 104.6(16) 2_455 2_455 ?
O2 P1 O1 75.4(16) . 2_455 ?
O1 P1 O1 180(3) . 2_455 ?
O22 P2 O22 180.0(12) . 2_564 ?
O22 P2 O21 115(2) . 2_564 ?
O22 P2 O21 65(2) 2_564 2_564 ?
O22 P2 O21 65(2) . . ?
O22 P2 O21 115(2) 2_564 . ?
O21 P2 O21 180.000(6) 2_564 . ?
O22 P2 O21' 67.9(17) . 2_564 ?
O22 P2 O21' 112.1(17) 2_564 2_564 ?
O21 P2 O21' 72.2(18) 2_564 2_564 ?
O21 P2 O21' 107.8(18) . 2_564 ?
O22 P2 O21' 112.1(17) . . ?
O22 P2 O21' 67.9(17) 2_564 . ?
O21 P2 O21' 107.8(18) 2_564 . ?
O21 P2 O21' 72.2(18) . . ?
O21' P2 O21' 180(2) 2_564 . ?
O22 P2 O22' 75.4(18) . . ?
O22 P2 O22' 104.6(18) 2_564 . ?
O21 P2 O22' 73.2(18) 2_564 . ?
O21 P2 O22' 106.8(18) . . ?
O21' P2 O22' 109.8(17) 2_564 . ?
O21' P2 O22' 70.2(17) . . ?
O22 P2 O22' 104.6(18) . 2_564 ?
O22 P2 O22' 75.4(18) 2_564 2_564 ?
O21 P2 O22' 106.8(18) 2_564 2_564 ?
O21 P2 O22' 73.2(18) . 2_564 ?
O21' P2 O22' 70.2(17) 2_564 2_564 ?
O21' P2 O22' 109.8(17) . 2_564 ?
O22' P2 O22' 180(2) . 2_564 ?
O10 W1 O8 102.5(13) . . ?
O10 W1 O11 100.6(12) . . ?
O8 W1 O11 87.6(11) . . ?
O10 W1 O7 103.5(11) . . ?
O8 W1 O7 154.0(13) . . ?
O11 W1 O7 86.7(10) . . ?
O10 W1 O17 103.5(11) . . ?
O8 W1 O17 87.1(11) . . ?
O11 W1 O17 155.9(11) . . ?
O7 W1 O17 87.9(9) . . ?
O10 W1 O1 157.1(10) . . ?
O8 W1 O1 62.3(12) . . ?
O11 W1 O1 63.7(11) . . ?
O7 W1 O1 92.6(11) . . ?
O17 W1 O1 93.1(10) . . ?
O19 W2 O13 102.8(12) . . ?
O19 W2 O6 102.8(11) . 2_455 ?
O13 W2 O6 87.0(10) . 2_455 ?
O19 W2 O11 102.1(12) . . ?
O13 W2 O11 154.9(11) . . ?
O6 W2 O11 89.9(11) 2_455 . ?
O19 W2 O3 99.2(10) . . ?
O13 W2 O3 86.8(11) . . ?
O6 W2 O3 158.0(11) 2_455 . ?
O11 W2 O3 86.9(10) . . ?
O19 W2 O1 156.9(11) . . ?
O13 W2 O1 92.3(11) . . ?
O6 W2 O1 95.2(11) 2_455 . ?
O11 W2 O1 63.2(11) . . ?
O3 W2 O1 63.9(10) . . ?
O19 W2 O2' 158.0(11) . 2_455 ?
O13 W2 O2' 61.6(10) . 2_455 ?
O6 W2 O2' 63.1(10) 2_455 2_455 ?
O11 W2 O2' 94.9(11) . 2_455 ?
O3 W2 O2' 95.5(10) . 2_455 ?
O1 W2 O2' 44.9(10) . 2_455 ?
O20 W3 O4 101.9(11) . . ?
O20 W3 O8 103.2(13) . . ?
O4 W3 O8 154.9(12) . . ?
O20 W3 O16 101.5(11) . . ?
O4 W3 O16 87.9(10) . . ?
O8 W3 O16 87.0(12) . . ?
O20 W3 O3 99.8(10) . . ?
O4 W3 O3 87.8(11) . . ?
O8 W3 O3 88.1(12) . . ?
O16 W3 O3 158.7(12) . . ?
O20 W3 O1 158.5(10) . . ?
O4 W3 O1 93.3(11) . . ?
O8 W3 O1 62.5(12) . . ?
O16 W3 O1 94.1(11) . . ?
O3 W3 O1 65.4(10) . . ?
O12 W4 O17 100.8(11) . 2_455 ?
O12 W4 O9 101.8(11) . 2_455 ?
O17 W4 O9 87.1(9) 2_455 2_455 ?
O12 W4 O13 104.0(11) . . ?
O17 W4 O13 155.2(11) 2_455 . ?
O9 W4 O13 87.3(9) 2_455 . ?
O12 W4 O14 101.4(11) . . ?
O17 W4 O14 87.2(8) 2_455 . ?
O9 W4 O14 156.8(12) 2_455 . ?
O13 W4 O14 88.5(10) . . ?
O12 W4 O2 158.2(11) . . ?
O17 W4 O2 66.7(10) 2_455 . ?
O9 W4 O2 95.5(11) 2_455 . ?
O13 W4 O2 89.8(11) . . ?
O14 W4 O2 61.7(11) . . ?
O12 W4 O2' 159.4(10) . 2_455 ?
O17 W4 O2' 92.1(11) 2_455 2_455 ?
O9 W4 O2' 62.6(11) 2_455 2_455 ?
O13 W4 O2' 63.9(10) . 2_455 ?
O14 W4 O2' 95.2(11) . 2_455 ?
O2 W4 O2' 42.4(10) . 2_455 ?
O18 W5 O7 102.4(12) . 2_455 ?
O18 W5 O15 103.6(10) . . ?
O7 W5 O15 87.2(10) 2_455 . ?
O18 W5 O14 100.7(11) . . ?
O7 W5 O14 86.6(9) 2_455 . ?
O15 W5 O14 155.6(12) . . ?
O18 W5 O4 103.5(11) . . ?
O7 W5 O4 154.1(11) 2_455 . ?
O15 W5 O4 87.7(9) . . ?
O14 W5 O4 87.7(10) . . ?
O18 W5 O2 158.3(12) . . ?
O7 W5 O2 65.3(11) 2_455 . ?
O15 W5 O2 93.9(11) . . ?
O14 W5 O2 62.2(11) . . ?
O4 W5 O2 89.7(10) . . ?
O18 W5 O1' 162.4(12) . 2_455 ?
O7 W5 O1' 88.8(12) 2_455 2_455 ?
O15 W5 O1' 63.0(11) . 2_455 ?
O14 W5 O1' 93.4(12) . 2_455 ?
O4 W5 O1' 66.3(10) . 2_455 ?
O2 W5 O1' 39.3(11) . 2_455 ?
O5 W6 O15 104.6(11) . . ?
O5 W6 O6 101.5(12) . . ?
O15 W6 O6 87.3(10) . . ?
O5 W6 O9 101.4(12) . . ?
O15 W6 O9 154.0(11) . . ?
O6 W6 O9 86.2(9) . . ?
O5 W6 O16 102.0(12) . . ?
O15 W6 O16 87.4(9) . . ?
O6 W6 O16 156.5(13) . . ?
O9 W6 O16 88.6(10) . . ?
O5 W6 O2' 157.9(12) . . ?
O15 W6 O2' 92.6(11) . . ?
O6 W6 O2' 64.9(11) . . ?
O9 W6 O2' 61.9(11) . . ?
O16 W6 O2' 92.4(12) . . ?
O5 W6 O1' 162.5(12) . 2_455 ?
O15 W6 O1' 62.3(11) . 2_455 ?
O6 W6 O1' 89.9(12) . 2_455 ?
O9 W6 O1' 92.6(12) . 2_455 ?
O16 W6 O1' 67.4(12) . 2_455 ?
O2' W6 O1' 39.6(10) . 2_455 ?
O39 W7 O30 101.8(12) . . ?
O39 W7 O35 101.6(11) . . ?
O30 W7 O35 156.6(11) . . ?
O39 W7 O32 101.5(12) . . ?
O30 W7 O32 87.8(12) . . ?
O35 W7 O32 88.1(11) . . ?
O39 W7 O25 99.5(12) . 2_564 ?
O30 W7 O25 87.1(11) . 2_564 ?
O35 W7 O25 88.6(11) . 2_564 ?
O32 W7 O25 159.0(11) . 2_564 ?
O39 W7 O22' 159.4(13) . . ?
O30 W7 O22' 64.7(11) . . ?
O35 W7 O22' 92.6(11) . . ?
O32 W7 O22' 93.8(12) . . ?
O25 W7 O22' 65.6(10) 2_564 . ?
O39 W7 O21' 158.6(12) . . ?
O30 W7 O21' 94.3(11) . . ?
O35 W7 O21' 63.2(10) . . ?
O32 W7 O21' 64.9(10) . . ?
O25 W7 O21' 95.2(11) 2_564 . ?
O22' W7 O21' 42.0(11) . . ?
O37 W8 O28 102.9(11) . . ?
O37 W8 O24 100.4(13) . 2_564 ?
O28 W8 O24 156.7(13) . 2_564 ?
O37 W8 O30 102.4(12) . . ?
O28 W8 O30 87.4(10) . . ?
O24 W8 O30 87.5(10) 2_564 . ?
O37 W8 O26 101.6(11) . . ?
O28 W8 O26 88.5(8) . . ?
O24 W8 O26 87.0(10) 2_564 . ?
O30 W8 O26 156.0(11) . . ?
O37 W8 O22' 158.6(11) . . ?
O28 W8 O22' 92.5(11) . . ?
O24 W8 O22' 65.0(12) 2_564 . ?
O30 W8 O22' 63.1(11) . . ?
O26 W8 O22' 93.4(9) . . ?
O40 W9 O34 103.1(13) . . ?
O40 W9 O27 102.9(13) . . ?
O34 W9 O27 87.6(11) . . ?
O40 W9 O32 101.3(11) . . ?
O34 W9 O32 87.4(10) . . ?
O27 W9 O32 155.8(13) . . ?
O40 W9 O33 101.1(12) . . ?
O34 W9 O33 155.8(14) . . ?
O27 W9 O33 87.8(10) . . ?
O32 W9 O33 87.1(12) . . ?
O40 W9 O21' 160.7(10) . . ?
O34 W9 O21' 63.5(13) . . ?
O27 W9 O21' 90.9(13) . . ?
O32 W9 O21' 65.8(11) . . ?
O33 W9 O21' 92.8(12) . . ?
O38 W10 O27 104.0(12) . . ?
O38 W10 O24 101.1(13) . . ?
O27 W10 O24 88.2(12) . . ?
O38 W10 O25 99.0(11) . . ?
O27 W10 O25 157.0(13) . . ?
O24 W10 O25 86.2(10) . . ?
O38 W10 O31 103.5(12) . . ?
O27 W10 O31 87.7(11) . . ?
O24 W10 O31 155.3(13) . . ?
O25 W10 O31 88.1(11) . . ?
O38 W10 O22' 157.9(11) . 2_564 ?
O27 W10 O22' 93.0(12) . 2_564 ?
O24 W10 O22' 64.9(12) . 2_564 ?
O25 W10 O22' 64.4(10) . 2_564 ?
O31 W10 O22' 91.0(12) . 2_564 ?
O38 W10 O21 159.3(12) . . ?
O27 W10 O21 64.4(12) . . ?
O24 W10 O21 95.7(13) . . ?
O25 W10 O21 94.0(12) . . ?
O31 W10 O21 60.8(12) . . ?
O22' W10 O21 42.5(11) 2_564 . ?
O29 W11 O31 103.0(13) . . ?
O29 W11 O33 103.0(12) . . ?
O31 W11 O33 89.3(11) . . ?
O29 W11 O28 100.8(12) . . ?
O31 W11 O28 156.0(12) . . ?
O33 W11 O28 87.3(11) . . ?
O29 W11 O23 101.8(11) . 2_564 ?
O31 W11 O23 85.8(11) . 2_564 ?
O33 W11 O23 155.3(12) . 2_564 ?
O28 W11 O23 87.4(9) . 2_564 ?
O29 W11 O21 161.8(15) . . ?
O31 W11 O21 64.4(12) . . ?
O33 W11 O21 65.5(13) . . ?
O28 W11 O21 92.8(13) . . ?
O23 W11 O21 90.7(12) 2_564 . ?
O29 W11 O22 159.7(14) . . ?
O31 W11 O22 89.2(13) . . ?
O33 W11 O22 93.2(12) . . ?
O28 W11 O22 67.4(11) . . ?
O23 W11 O22 62.5(11) 2_564 . ?
O21 W11 O22 38.3(13) . . ?
O36 W12 O23 102.3(13) . . ?
O36 W12 O26 99.8(12) . 2_564 ?
O23 W12 O26 88.9(9) . 2_564 ?
O36 W12 O35 103.3(12) . . ?
O23 W12 O35 87.8(10) . . ?
O26 W12 O35 156.8(11) 2_564 . ?
O36 W12 O34 102.1(14) . . ?
O23 W12 O34 155.7(13) . . ?
O26 W12 O34 87.1(9) 2_564 . ?
O35 W12 O34 86.5(9) . . ?
O36 W12 O21' 160.4(12) . . ?
O23 W12 O21' 92.9(12) . . ?
O26 W12 O21' 92.7(10) 2_564 . ?
O35 W12 O21' 64.6(11) . . ?
O34 W12 O21' 63.4(13) . . ?
O36 W12 O22 159.5(12) . 2_564 ?
O23 W12 O22 62.5(11) . 2_564 ?
O26 W12 O22 68.0(11) 2_564 2_564 ?
O35 W12 O22 90.3(13) . 2_564 ?
O34 W12 O22 93.9(12) . 2_564 ?
O21' W12 O22 40.1(10) . 2_564 ?
P1 O1' O2 60.8(17) . 2_455 ?
P1 O1' O2' 59.9(15) . 2_455 ?
O2 O1' O2' 104(2) 2_455 2_455 ?
P1 O1' W5 128(2) . 2_455 ?
O2 O1' W5 67.7(17) 2_455 2_455 ?
O2' O1' W5 138(2) 2_455 2_455 ?
P1 O1' W6 128.1(19) . 2_455 ?
O2 O1' W6 140(2) 2_455 2_455 ?
O2' O1' W6 68.2(15) 2_455 2_455 ?
W5 O1' W6 91.7(11) 2_455 2_455 ?
P1 O1 W3 123.5(14) . . ?
P1 O1 W1 122.9(16) . . ?
W3 O1 W1 93.8(11) . . ?
P1 O1 W2 121.6(16) . . ?
W3 O1 W2 93.9(10) . . ?
W1 O1 W2 93.2(10) . . ?
P1 O2' O1' 53.0(15) . 2_455 ?
P1 O2' O2 56.3(14) . 2_455 ?
O1' O2' O2 96(2) 2_455 2_455 ?
P1 O2' W4 124.8(15) . 2_455 ?
O1' O2' W4 139(2) 2_455 2_455 ?
O2 O2' W4 68.5(15) 2_455 2_455 ?
P1 O2' W6 125.1(16) . . ?
O1' O2' W6 72.2(15) 2_455 . ?
O2 O2' W6 138.7(19) 2_455 . ?
W4 O2' W6 94.5(11) 2_455 . ?
P1 O2' W2 119.2(16) . 2_455 ?
O1' O2' W2 125(2) 2_455 2_455 ?
O2 O2' W2 124.8(17) 2_455 2_455 ?
W4 O2' W2 92.5(10) 2_455 2_455 ?
W6 O2' W2 91.9(9) . 2_455 ?
P1 O2 O1' 53.7(16) . 2_455 ?
P1 O2 O2' 56.3(15) . 2_455 ?
O1' O2 O2' 96(2) 2_455 2_455 ?
P1 O2 W5 126.8(16) . . ?
O1' O2 W5 73.1(15) 2_455 . ?
O2' O2 W5 140.7(19) 2_455 . ?
P1 O2 W4 125.4(14) . . ?
O1' O2 W4 142(2) 2_455 . ?
O2' O2 W4 69.1(14) 2_455 . ?
W5 O2 W4 96.0(11) . . ?
W3 O3 W2 136.5(14) . . ?
W3 O4 W5 140.4(12) . . ?
W2 O6 W6 139.9(15) 2_455 . ?
W5 O7 W1 141.5(15) 2_455 . ?
W3 O8 W1 140.8(18) . . ?
W4 O9 W6 140.4(15) 2_455 . ?
W2 O11 W1 139.5(15) . . ?
W2 O13 W4 141.2(13) . . ?
W5 O14 W4 139.6(15) . . ?
W5 O15 W6 141.5(14) . . ?
W3 O16 W6 139.3(16) . . ?
W4 O17 W1 139.6(12) 2_455 . ?
P2 O21' O22 54.3(16) . 2_564 ?
P2 O21' O22' 55.1(15) . . ?
O22 O21' O22' 88(2) 2_564 . ?
P2 O21' O21 53.2(15) . . ?
O22 O21' O21 93(2) 2_564 . ?
O22' O21' O21 87(2) . . ?
P2 O21' W12 125.0(18) . . ?
O22 O21' W12 70.8(17) 2_564 . ?
O22' O21' W12 130.7(19) . . ?
O21 O21' W12 136(2) . . ?
P2 O21' W9 124.5(16) . . ?
O22 O21' W9 137(2) 2_564 . ?
O22' O21' W9 129.2(19) . . ?
O21 O21' W9 71.3(16) . . ?
W12 O21' W9 93.1(12) . . ?
P2 O21' W7 121.8(19) . . ?
O22 O21' W7 128(2) 2_564 . ?
O22' O21' W7 66.6(14) . . ?
O21 O21' W7 128(2) . . ?
W12 O21' W7 92.0(9) . . ?
W9 O21' W7 91.1(10) . . ?
P2 O21 O22 56.6(18) . . ?
P2 O21 O21' 54.6(16) . . ?
O22 O21 O21' 95(3) . . ?
P2 O21 W11 129(2) . . ?
O22 O21 W11 72.2(19) . . ?
O21' O21 W11 134(2) . . ?
P2 O21 W10 122(2) . . ?
O22 O21 W10 131(2) . . ?
O21' O21 W10 125(2) . . ?
W11 O21 W10 92.9(13) . . ?
P2 O22 O21 58.8(19) . . ?
P2 O22 O21' 57.9(15) . 2_564 ?
O21 O22 O21' 97(3) . 2_564 ?
P2 O22 W11 128(2) . . ?
O21 O22 W11 69.5(18) . . ?
O21' O22 W11 138(2) 2_564 . ?
P2 O22 W12 127.0(17) . 2_564 ?
O21 O22 W12 136(2) . 2_564 ?
O21' O22 W12 69.2(15) 2_564 2_564 ?
W11 O22 W12 92.6(11) . 2_564 ?
P2 O22' O21' 54.7(15) . . ?
P2 O22' W7 126.0(18) . . ?
O21' O22' W7 71.4(14) . . ?
P2 O22' W8 123.2(15) . . ?
O21' O22' W8 133.4(18) . . ?
W7 O22' W8 92.6(10) . . ?
P2 O22' W10 121.8(16) . 2_564 ?
O21' O22' W10 131.8(18) . 2_564 ?
W7 O22' W10 92.8(10) . 2_564 ?
W8 O22' W10 91.1(12) . 2_564 ?
W12 O23 W11 141.2(14) . 2_564 ?
W10 O24 W8 138.8(19) . 2_564 ?
W10 O25 W7 137.0(14) . 2_564 ?
W12 O26 W8 137.7(13) 2_564 . ?
W10 O27 W9 141.5(17) . . ?
W11 O28 W8 139.5(13) . . ?
W7 O30 W8 138.9(15) . . ?
W11 O31 W10 140.5(13) . . ?
W7 O32 W9 137.8(13) . . ?
W11 O33 W9 139.9(16) . . ?
W9 O34 W12 139.5(19) . . ?
W7 O35 W12 139.7(13) . . ?
N4 Ag1 N3 176.5(12) . . ?
N3 C2 C9 116(3) . . ?
N3 C2 C5 120(3) . . ?
C9 C2 C5 123(3) . . ?
N12 C6 C12 111(3) . . ?
N12 C6 C13 118(3) . . ?
C12 C6 C13 131(3) . . ?
N2 C8 C15 110(3) . . ?
N2 C8 C1 120(3) . . ?
C15 C8 C1 130(3) . . ?
C2 C9 C17 102(3) . . ?
C2 C9 C20 131(3) . . ?
C17 C9 C20 127(3) . . ?
C15 C10 N1 111(3) . . ?
C15 C10 C7 131(3) . . ?
N1 C10 C7 117(3) . . ?
N5 C11 C18 108(3) . . ?
N5 C11 C3 123(3) . . ?
C18 C11 C3 128(3) . . ?
C6 C12 C37 107(3) . . ?
C6 C12 C20 129(3) . . ?
C37 C12 C20 124(3) . . ?
N4 C14 C18 110(3) . . ?
N4 C14 C19 121(2) . . ?
C18 C14 C19 129(3) . . ?
C10 C15 C8 105(3) . . ?
C10 C15 C16 129(3) . . ?
C8 C15 C16 126(3) . . ?
C15 C16 C18 117(3) . . ?
N6 C17 C9 109(3) . . ?
N6 C17 C4 117(3) . . ?
C9 C17 C4 134(3) . . ?
C11 C18 C14 105(2) . . ?
C11 C18 C16 128(2) . . ?
C14 C18 C16 126(3) . . ?
C9 C20 C12 115(3) . . ?
C12 C37 N7 106(3) . . ?
C12 C37 C42 137(4) . . ?
N7 C37 C42 116(3) . . ?
C10 N1 N2 105(2) . . ?
C8 N2 N1 109(2) . . ?
C2 N3 N6 103(3) . . ?
C2 N3 Ag1 133(3) . . ?
N6 N3 Ag1 124(2) . . ?
C14 N4 N5 103(2) . . ?
C14 N4 Ag1 129(2) . . ?
N5 N4 Ag1 128.0(19) . . ?
C11 N5 N4 114(2) . . ?
C17 N6 N3 110(3) . . ?
N12 N7 C37 106(3) . . ?
C6 N12 N7 109(3) . . ?

_diffrn_measured_fraction_theta_max 0.980
_diffrn_reflns_theta_full        26.42
_diffrn_measured_fraction_theta_full 0.980
_refine_diff_density_max         3.121
_refine_diff_density_min         -2.050
_refine_diff_density_rms         0.442

_database_code_depnum_ccdc_archive 'CCDC 979425'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_compound-3

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C66 H101 Ag6 N24 O40 P W12'
_chemical_formula_weight         4755

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   14.1484(14)
_cell_length_b                   14.2546(15)
_cell_length_c                   16.6307(16)
_cell_angle_alpha                72.529(2)
_cell_angle_beta                 72.936(2)
_cell_angle_gamma                61.456(2)
_cell_volume                     2765.1(5)
_cell_formula_units_Z            1
_cell_measurement_temperature    296(2)
_cell_measurement_reflns_used    14213
_cell_measurement_theta_min      1.66
_cell_measurement_theta_max      25.00

_exptl_crystal_description       block
_exptl_crystal_colour            'dark red'
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.18
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    2.852
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2165
_exptl_absorpt_coefficient_mu    13.553
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.048
_exptl_absorpt_correction_T_max  0.087
_exptl_absorpt_process_details   'ABSCOR by T.Higashi    8  March, 1995'

_exptl_special_details           
; 
During the refinement of compound 3, the restraint command 'ISOR' is used to refine the non-H atoms with ADP problems. 
These atoms are as follows: O4 O6 O7 O11 O13 N12 C10 C19 O3 O9 C20 C23 C33 O1' O1 O2 O2' O5 N8 O10 O16 C21 and P1. 
The command 'delu' was used to solve the non-H atoms with 'Large Hirshfeld Difference...' problems. 
These atoms are as follows: W5 O13 Ag1 O11 C12 C18 C21 and C13. 
These restraint refinement leads to a relatively high restraint value 142. 
In the final refinement, the water molecule could not be modeled properly, thus the SQUEEZE routine of PLATON was applied to remove the contributions to the scattering from the solvent molecules. 
The reported refinements are of the guest-free structures using the *.hkp files produced by using the SQUEEZE routine. 
The SQUEEZE program indicates that there is at least one solvent water molecule in the crystal structure. 
This water molecule was directly included in the final molecular formula based on the elemental analysis, TG and SQUEEZE analysis. 
;

_diffrn_ambient_temperature      296(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        none
_diffrn_reflns_number            14213
_diffrn_reflns_av_R_equivalents  0.0348
_diffrn_reflns_av_sigmaI/netI    0.0834
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_theta_min         1.66
_diffrn_reflns_theta_max         25.00
_reflns_number_total             9733
_reflns_number_gt                6853
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0341P)²+227.7129P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         9668
_refine_ls_number_parameters     691
_refine_ls_number_restraints     142
_refine_ls_R_factor_all          0.1145
_refine_ls_R_factor_gt           0.0802
_refine_ls_wR_factor_ref         0.1800
_refine_ls_wR_factor_gt          0.1669
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_restrained_S_all      1.062
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 0.500 0.000 0.000 159.1 11.4
2 0.382 -0.039 0.563 35.8 13.0
3 0.617 0.039 0.437 35.8 10.3
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.5000 -0.5000 0.5000 0.0101(14) Uani 1 2 d SU . .
W1 W 0.48746(8) -0.57872(9) 0.31972(6) 0.0303(3) Uani 1 1 d . . .
W2 W 0.29701(9) -0.25164(8) 0.56226(7) 0.0362(3) Uani 1 1 d . . .
W3 W 0.27873(9) -0.33417(9) 0.38676(6) 0.0316(3) Uani 1 1 d . . .
W4 W 0.56719(8) -0.28109(9) 0.47120(7) 0.0359(3) Uani 1 1 d . . .
W5 W 0.76708(10) -0.52654(11) 0.40146(8) 0.0491(3) Uani 1 1 d U . .
W6 W 0.54797(8) -0.35202(9) 0.29090(6) 0.0335(3) Uani 1 1 d . . .
O1' O 0.4836(18) -0.4043(19) 0.5411(14) 0.005(5) Uani 0.50 1 d PU . .
O1 O 0.528(2) -0.543(2) 0.5845(16) 0.012(5) Uani 0.50 1 d PU . .
O2' O 0.4387(19) -0.560(2) 0.5623(15) 0.009(5) Uani 0.50 1 d PU . .
O2 O 0.625(2) -0.580(2) 0.4942(16) 0.013(6) Uani 0.50 1 d PU . .
O3 O 0.2645(17) -0.2417(17) 0.4578(12) 0.054(5) Uani 1 1 d U . .
O4 O 0.2092(18) -0.4043(16) 0.4828(12) 0.057(5) Uani 1 1 d U . .
O5 O 0.6271(17) -0.6820(18) 0.3426(13) 0.060(6) Uani 1 1 d U . .
O6 O 0.2254(19) -0.3441(17) 0.6133(13) 0.061(6) Uani 1 1 d U . .
O7 O 0.4102(15) -0.2118(16) 0.4996(12) 0.055(5) Uani 1 1 d U . .
O8 O 0.2005(12) -0.1354(14) 0.5904(10) 0.033(4) Uani 1 1 d . . .
O9 O 0.5723(14) -0.3377(17) 0.5877(12) 0.055(5) Uani 1 1 d U . .
O10 O 0.5956(14) -0.1772(15) 0.4579(11) 0.041(4) Uani 1 1 d U . .
O11 O 0.5412(14) -0.2664(14) 0.3615(12) 0.042(4) Uani 1 1 d U . .
O12 O 0.5723(14) -0.2833(14) 0.1912(11) 0.043(5) Uani 1 1 d . . .
O13 O 0.7020(13) -0.3895(15) 0.4398(11) 0.041(4) Uani 1 1 d U . .
O14 O 0.5461(14) -0.4763(14) 0.2664(11) 0.040(4) Uani 1 1 d . . .
O15 O 0.3499(14) -0.4592(15) 0.3376(13) 0.048(5) Uani 1 1 d . . .
O16 O 0.6940(15) -0.4470(16) 0.3052(12) 0.048(5) Uani 1 1 d U . .
O17 O 0.4810(14) -0.6130(16) 0.2349(11) 0.044(5) Uani 1 1 d . . .
O18 O 0.3924(12) -0.2905(13) 0.3112(10) 0.030(4) Uani 1 1 d . . .
O19 O 0.1778(13) -0.2559(14) 0.3303(11) 0.038(4) Uani 1 1 d . . .
O20 O 0.8889(13) -0.5359(14) 0.3562(10) 0.031(4) Uani 1 1 d . . .
Ag1 Ag 0.5354(2) -0.0813(2) 0.28773(19) 0.0749(9) Uani 1 1 d U . .
Ag2 Ag 0.44776(15) 0.41698(17) -0.09272(12) 0.0380(5) Uani 1 1 d . . .
Ag3 Ag 0.12571(17) 0.32738(18) 0.64916(11) 0.0393(5) Uani 1 1 d . . .
C1 C 0.1459(19) 0.389(2) 0.3790(14) 0.035(6) Uani 1 1 d . . .
C2 C 0.1199(18) 0.306(2) 0.3967(15) 0.028(5) Uani 1 1 d . . .
C3 C 0.1087(17) 0.2742(19) 0.4875(15) 0.027(5) Uani 1 1 d . . .
C4 C 0.167(3) 0.468(3) 0.2980(19) 0.054(8) Uani 1 1 d . . .
H4A H 0.1641 0.4472 0.2490 0.081 Uiso 1 1 calc R . .
H4B H 0.2379 0.4644 0.2922 0.081 Uiso 1 1 calc R . .
H4C H 0.1121 0.5402 0.3018 0.081 Uiso 1 1 calc R . .
C5 C 0.078(2) 0.186(3) 0.5408(15) 0.048(8) Uani 1 1 d . . .
H5A H 0.0779 0.1812 0.5998 0.072 Uiso 1 1 calc R . .
H5B H 0.1305 0.1188 0.5233 0.072 Uiso 1 1 calc R . .
H5C H 0.0069 0.2019 0.5341 0.072 Uiso 1 1 calc R . .
C6 C 0.1099(19) 0.252(2) 0.3371(15) 0.031(6) Uani 1 1 d . . .
H6A H 0.0394 0.2498 0.3547 0.038 Uiso 1 1 calc R . .
H6B H 0.1122 0.2965 0.2800 0.038 Uiso 1 1 calc R . .
C7 C 0.185(2) 0.046(2) 0.3571(14) 0.038(6) Uani 1 1 d . . .
C8 C 0.195(2) 0.1436(19) 0.3341(15) 0.029(5) Uani 1 1 d . . .
C9 C 0.305(3) 0.115(2) 0.3116(19) 0.065(10) Uani 1 1 d . . .
C10 C 0.369(3) 0.182(3) 0.282(2) 0.075(10) Uani 1 1 d U . .
H10A H 0.4461 0.1350 0.2719 0.112 Uiso 1 1 calc R . .
H10B H 0.3534 0.2225 0.3245 0.112 Uiso 1 1 calc R . .
H10C H 0.3493 0.2314 0.2292 0.112 Uiso 1 1 calc R . .
C11 C 0.086(2) 0.024(2) 0.394(2) 0.049(8) Uani 1 1 d . . .
H11A H 0.0214 0.0912 0.3972 0.074 Uiso 1 1 calc R . .
H11B H 0.0917 -0.0200 0.4506 0.074 Uiso 1 1 calc R . .
H11C H 0.0801 -0.0146 0.3582 0.074 Uiso 1 1 calc R . .
C12 C 0.779(2) 0.037(2) 0.1965(16) 0.036(6) Uani 1 1 d U . .
C13 C 0.775(2) 0.018(2) 0.1197(15) 0.033(6) Uani 1 1 d U . .
C14 C 0.712(2) -0.035(2) 0.1351(15) 0.038(6) Uani 1 1 d . . .
C15 C 0.831(3) 0.084(4) 0.223(2) 0.084(13) Uani 1 1 d . . .
H15A H 0.8698 0.1155 0.1739 0.127 Uiso 1 1 calc R . .
H15B H 0.8818 0.0290 0.2593 0.127 Uiso 1 1 calc R . .
H15C H 0.7771 0.1400 0.2546 0.127 Uiso 1 1 calc R . .
C16 C 0.678(2) -0.070(3) 0.077(2) 0.055(8) Uani 1 1 d . . .
H16A H 0.7100 -0.0505 0.0191 0.083 Uiso 1 1 calc R . .
H16B H 0.5994 -0.0341 0.0830 0.083 Uiso 1 1 calc R . .
H16C H 0.7012 -0.1471 0.0920 0.083 Uiso 1 1 calc R . .
C17 C 0.8254(19) 0.060(2) 0.0324(14) 0.029(6) Uani 1 1 d . . .
H17A H 0.8764 -0.0015 0.0049 0.035 Uiso 1 1 calc R . .
H17B H 0.8671 0.0941 0.0392 0.035 Uiso 1 1 calc R . .
C18 C 0.753(2) 0.1338(19) -0.1093(14) 0.029(5) Uani 1 1 d U . .
C19 C 0.7447(17) 0.141(2) -0.0264(15) 0.030(5) Uani 1 1 d U . .
C20 C 0.6463(17) 0.234(2) -0.0070(14) 0.027(5) Uani 1 1 d U . .
C21 C 0.830(2) 0.053(2) -0.1633(17) 0.043(6) Uani 1 1 d U . .
H21A H 0.8090 0.0756 -0.2182 0.064 Uiso 1 1 calc R . .
H21B H 0.8301 -0.0163 -0.1362 0.064 Uiso 1 1 calc R . .
H21C H 0.9025 0.0480 -0.1707 0.064 Uiso 1 1 calc R . .
C22 C 0.599(2) 0.277(2) 0.0702(17) 0.052(8) Uani 1 1 d . . .
H22A H 0.5306 0.3396 0.0633 0.078 Uiso 1 1 calc R . .
H22B H 0.6479 0.2984 0.0821 0.078 Uiso 1 1 calc R . .
H22C H 0.5869 0.2229 0.1168 0.078 Uiso 1 1 calc R . .
C23 C -0.0384(15) 0.7255(17) 0.1561(13) 0.019(5) Uani 1 1 d U . .
C24 C -0.0402(17) 0.7093(17) 0.0760(13) 0.020(5) Uani 1 1 d . . .
C25 C -0.105(2) 0.658(2) 0.0934(14) 0.031(6) Uani 1 1 d . . .
C26 C -0.142(3) 0.622(3) 0.0380(17) 0.056(9) Uani 1 1 d . . .
H26A H -0.1115 0.6407 -0.0208 0.085 Uiso 1 1 calc R . .
H26B H -0.2206 0.6575 0.0453 0.085 Uiso 1 1 calc R . .
H26C H -0.1184 0.5448 0.0538 0.085 Uiso 1 1 calc R . .
C27 C 0.021(2) 0.7757(19) 0.1769(15) 0.032(6) Uani 1 1 d . . .
H27A H 0.0042 0.7737 0.2375 0.048 Uiso 1 1 calc R . .
H27B H -0.0019 0.8499 0.1470 0.048 Uiso 1 1 calc R . .
H27C H 0.0981 0.7359 0.1596 0.048 Uiso 1 1 calc R . .
C28 C 0.0132(18) 0.7491(19) -0.0112(15) 0.032(6) Uani 1 1 d . . .
H28A H 0.0312 0.8041 -0.0054 0.039 Uiso 1 1 calc R . .
H28B H -0.0414 0.7853 -0.0479 0.039 Uiso 1 1 calc R . .
C29 C 0.2132(17) 0.5903(17) -0.0266(13) 0.021(5) Uani 1 1 d . . .
C30 C 0.1143(17) 0.6696(19) -0.0580(13) 0.022(5) Uani 1 1 d . . .
C31 C 0.1332(18) 0.6601(19) -0.1420(14) 0.025(5) Uani 1 1 d . . .
C32 C 0.062(2) 0.721(2) -0.2058(18) 0.050(8) Uani 1 1 d . . .
H32A H 0.0986 0.6950 -0.2587 0.075 Uiso 1 1 calc R . .
H32B H 0.0438 0.7968 -0.2152 0.075 Uiso 1 1 calc R . .
H32C H -0.0041 0.7104 -0.1856 0.075 Uiso 1 1 calc R . .
C33 C 0.241(2) 0.558(2) 0.0601(16) 0.048(7) Uani 1 1 d U . .
H33A H 0.3152 0.5042 0.0588 0.072 Uiso 1 1 calc R . .
H33B H 0.1931 0.5274 0.0999 0.072 Uiso 1 1 calc R . .
H33C H 0.2315 0.6202 0.0777 0.072 Uiso 1 1 calc R . .
N1 N 0.1251(18) 0.336(2) 0.5231(13) 0.041(6) Uani 1 1 d . . .
N2 N 0.1486(16) 0.4116(19) 0.4529(14) 0.039(5) Uani 1 1 d . . .
H2A H 0.1623 0.4630 0.4560 0.047 Uiso 1 1 calc R . .
N3 N 0.363(2) 0.003(2) 0.3189(19) 0.072(9) Uani 1 1 d . . .
N4 N 0.2837(18) -0.0339(17) 0.3464(16) 0.051(7) Uani 1 1 d . . .
H4D H 0.2966 -0.1013 0.3558 0.061 Uiso 1 1 calc R . .
N5 N 0.6778(19) -0.057(2) 0.2232(15) 0.049(6) Uani 1 1 d . . .
N6 N 0.718(2) -0.015(2) 0.2558(14) 0.057(8) Uani 1 1 d . . .
H6C H 0.7080 -0.0190 0.3101 0.069 Uiso 1 1 calc R . .
N7 N 0.5980(15) 0.2834(15) -0.0775(13) 0.030(5) Uani 1 1 d . . .
N8 N 0.6635(16) 0.2208(17) -0.1351(13) 0.034(5) Uani 1 1 d U . .
H8A H 0.6498 0.2349 -0.1856 0.040 Uiso 1 1 calc R . .
N9 N -0.1007(15) 0.6832(17) 0.2173(12) 0.030(5) Uani 1 1 d . . .
N10 N -0.1410(17) 0.6439(19) 0.1804(12) 0.039(6) Uani 1 1 d . . .
H10D H -0.1840 0.6131 0.2073 0.046 Uiso 1 1 calc R . .
N11 N 0.2892(14) 0.5412(16) -0.0916(11) 0.023(4) Uani 1 1 d . . .
N12 N 0.2367(13) 0.5866(15) -0.1583(10) 0.022(4) Uani 1 1 d U . .
H12A H 0.2674 0.5697 -0.2080 0.026 Uiso 1 1 calc R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O1 1.45(2) . ?
P1 O1 1.45(2) 2_646 ?
P1 O2' 1.49(2) . ?
P1 O2' 1.49(2) 2_646 ?
P1 O2 1.57(2) 2_646 ?
P1 O2 1.57(2) . ?
P1 O1' 1.60(2) 2_646 ?
P1 O1' 1.60(2) . ?
W1 O17 1.664(16) . ?
W1 O5 1.88(2) . ?
W1 O14 1.886(17) . ?
W1 O15 1.890(17) . ?
W1 O9 1.898(18) 2_646 ?
W1 O1' 2.39(2) 2_646 ?
W2 O8 1.660(16) . ?
W2 O7 1.873(18) . ?
W2 O3 1.87(2) . ?
W2 O6 1.89(2) . ?
W2 O5 1.92(2) 2_646 ?
W2 O2 2.47(3) 2_646 ?
W2 O1' 2.50(2) . ?
W3 O19 1.674(16) . ?
W3 O15 1.880(17) . ?
W3 O4 1.89(2) . ?
W3 O3 1.928(19) . ?
W3 O18 1.963(15) . ?
W3 O2 2.41(3) 2_646 ?
W4 O10 1.650(18) . ?
W4 O13 1.839(16) . ?
W4 O9 1.870(19) . ?
W4 O11 1.897(17) . ?
W4 O7 1.924(18) . ?
W4 O1' 2.41(2) . ?
W5 O20 1.623(15) . ?
W5 O6 1.88(2) 2_646 ?
W5 O16 1.918(19) . ?
W5 O4 1.93(2) 2_646 ?
W5 O13 1.938(17) . ?
W5 O2 2.44(3) . ?
W5 O2' 2.52(2) 2_646 ?
W6 O12 1.685(16) . ?
W6 O11 1.887(16) . ?
W6 O16 1.892(18) . ?
W6 O18 1.904(15) . ?
W6 O14 1.946(17) . ?
W6 O2' 2.40(2) 2_646 ?
W6 O1 2.47(3) 2_646 ?
O1' O1 1.74(3) . ?
O1' O2' 1.82(3) 2_646 ?
O1' W1 2.39(2) 2_646 ?
O1 O2' 1.56(3) . ?
O1 O2 1.73(3) . ?
O1 W6 2.47(3) 2_646 ?
O2' O1' 1.82(3) 2_646 ?
O2' W6 2.40(2) 2_646 ?
O2' W5 2.52(2) 2_646 ?
O2 W3 2.41(3) 2_646 ?
O2 W2 2.47(3) 2_646 ?
O4 W5 1.93(2) 2_646 ?
O5 W2 1.92(2) 2_646 ?
O6 W5 1.88(2) 2_646 ?
O9 W1 1.898(18) 2_646 ?
O11 Ag1 2.53(2) . ?
Ag1 N3 2.12(3) . ?
Ag1 N5 2.12(2) . ?
Ag2 N11 2.090(17) . ?
Ag2 N7 2.090(18) . ?
Ag3 N1 2.07(2) . ?
Ag3 N9 2.114(19) 2_566 ?
C1 C2 1.34(4) . ?
C1 N2 1.37(3) . ?
C1 C4 1.52(4) . ?
C2 C3 1.42(3) . ?
C2 C6 1.49(3) . ?
C3 N1 1.33(3) . ?
C3 C5 1.47(4) . ?
C4 H4A 0.9600 . ?
C4 H4B 0.9600 . ?
C4 H4C 0.9600 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 C8 1.44(3) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 N4 1.31(3) . ?
C7 C8 1.39(3) . ?
C7 C11 1.51(4) . ?
C8 C9 1.37(4) . ?
C9 N3 1.39(4) . ?
C9 C10 1.51(5) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 N6 1.39(3) . ?
C12 C13 1.40(4) . ?
C12 C15 1.43(4) . ?
C13 C14 1.35(4) . ?
C13 C17 1.50(3) . ?
C14 N5 1.39(3) . ?
C14 C16 1.48(4) . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C16 H16A 0.9600 . ?
C16 H16B 0.9600 . ?
C16 H16C 0.9600 . ?
C17 C19 1.52(3) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 N8 1.35(3) . ?
C18 C19 1.38(3) . ?
C18 C21 1.47(3) . ?
C19 C20 1.42(3) . ?
C20 N7 1.36(3) . ?
C20 C22 1.43(3) . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 H22A 0.9600 . ?
C22 H22B 0.9600 . ?
C22 H22C 0.9600 . ?
C23 N9 1.34(3) . ?
C23 C24 1.43(3) . ?
C23 C27 1.49(3) . ?
C24 C25 1.35(3) . ?
C24 C28 1.51(3) . ?
C25 N10 1.37(3) . ?
C25 C26 1.49(4) . ?
C26 H26A 0.9600 . ?
C26 H26B 0.9600 . ?
C26 H26C 0.9600 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C28 C30 1.50(3) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 N11 1.37(3) . ?
C29 C30 1.44(3) . ?
C29 C33 1.48(3) . ?
C30 C31 1.38(3) . ?
C31 N12 1.34(3) . ?
C31 C32 1.46(3) . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
C33 H33A 0.9600 . ?
C33 H33B 0.9600 . ?
C33 H33C 0.9600 . ?
N1 N2 1.41(3) . ?
N2 H2A 0.8600 . ?
N3 N4 1.36(3) . ?
N4 H4D 0.8600 . ?
N5 N6 1.29(4) . ?
N6 H6C 0.8600 . ?
N7 N8 1.33(3) . ?
N8 H8A 0.8600 . ?
N9 N10 1.32(3) . ?
N9 Ag3 2.114(19) 2_566 ?
N10 H10D 0.8600 . ?
N11 N12 1.34(2) . ?
N12 H12A 0.8600 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 P1 O1 180(2) . 2_646 ?
O1 P1 O2' 64.3(13) . . ?
O1 P1 O2' 115.7(13) 2_646 . ?
O1 P1 O2' 115.7(13) . 2_646 ?
O1 P1 O2' 64.3(13) 2_646 2_646 ?
O2' P1 O2' 180(3) . 2_646 ?
O1 P1 O2 110.2(13) . 2_646 ?
O1 P1 O2 69.8(13) 2_646 2_646 ?
O2' P1 O2 73.1(13) . 2_646 ?
O2' P1 O2 106.9(13) 2_646 2_646 ?
O1 P1 O2 69.8(13) . . ?
O1 P1 O2 110.2(13) 2_646 . ?
O2' P1 O2 106.9(13) . . ?
O2' P1 O2 73.1(13) 2_646 . ?
O2 P1 O2 180.0(19) 2_646 . ?
O1 P1 O1' 110.4(13) . 2_646 ?
O1 P1 O1' 69.6(13) 2_646 2_646 ?
O2' P1 O1' 72.2(12) . 2_646 ?
O2' P1 O1' 107.8(12) 2_646 2_646 ?
O2 P1 O1' 105.2(12) 2_646 2_646 ?
O2 P1 O1' 74.8(12) . 2_646 ?
O1 P1 O1' 69.6(13) . . ?
O1 P1 O1' 110.4(13) 2_646 . ?
O2' P1 O1' 107.8(12) . . ?
O2' P1 O1' 72.2(12) 2_646 . ?
O2 P1 O1' 74.8(12) 2_646 . ?
O2 P1 O1' 105.2(12) . . ?
O1' P1 O1' 180.0(13) 2_646 . ?
O17 W1 O5 102.1(9) . . ?
O17 W1 O14 101.1(8) . . ?
O5 W1 O14 88.6(9) . . ?
O17 W1 O15 102.1(9) . . ?
O5 W1 O15 155.8(9) . . ?
O14 W1 O15 87.1(7) . . ?
O17 W1 O9 102.4(9) . 2_646 ?
O5 W1 O9 88.0(9) . 2_646 ?
O14 W1 O9 156.5(9) . 2_646 ?
O15 W1 O9 86.5(8) . 2_646 ?
O17 W1 O1' 160.1(9) . 2_646 ?
O5 W1 O1' 65.5(8) . 2_646 ?
O14 W1 O1' 94.3(8) . 2_646 ?
O15 W1 O1' 91.1(8) . 2_646 ?
O9 W1 O1' 63.2(9) 2_646 2_646 ?
O8 W2 O7 101.8(9) . . ?
O8 W2 O3 101.4(8) . . ?
O7 W2 O3 88.0(9) . . ?
O8 W2 O6 100.8(9) . . ?
O7 W2 O6 157.4(9) . . ?
O3 W2 O6 87.6(8) . . ?
O8 W2 O5 101.9(8) . 2_646 ?
O7 W2 O5 88.7(9) . 2_646 ?
O3 W2 O5 156.6(9) . 2_646 ?
O6 W2 O5 86.6(9) . 2_646 ?
O8 W2 O2 156.7(8) . 2_646 ?
O7 W2 O2 94.3(9) . 2_646 ?
O3 W2 O2 62.1(9) . 2_646 ?
O6 W2 O2 64.2(9) . 2_646 ?
O5 W2 O2 95.1(9) 2_646 2_646 ?
O8 W2 O1' 157.7(8) . . ?
O7 W2 O1' 64.0(8) . . ?
O3 W2 O1' 95.3(8) . . ?
O6 W2 O1' 94.4(9) . . ?
O5 W2 O1' 62.6(8) 2_646 . ?
O2 W2 O1' 45.5(8) 2_646 . ?
O19 W3 O15 101.2(9) . . ?
O19 W3 O4 101.6(9) . . ?
O15 W3 O4 91.0(8) . . ?
O19 W3 O3 103.9(9) . . ?
O15 W3 O3 154.5(9) . . ?
O4 W3 O3 88.6(8) . . ?
O19 W3 O18 98.8(7) . . ?
O15 W3 O18 86.4(7) . . ?
O4 W3 O18 159.6(8) . . ?
O3 W3 O18 85.1(7) . . ?
O19 W3 O2 160.7(9) . 2_646 ?
O15 W3 O2 93.9(9) . 2_646 ?
O4 W3 O2 65.9(9) . 2_646 ?
O3 W3 O2 62.8(9) . 2_646 ?
O18 W3 O2 94.0(8) . 2_646 ?
O10 W4 O13 102.7(8) . . ?
O10 W4 O9 100.5(9) . . ?
O13 W4 O9 91.9(8) . . ?
O10 W4 O11 102.3(8) . . ?
O13 W4 O11 86.0(7) . . ?
O9 W4 O11 157.0(9) . . ?
O10 W4 O7 100.4(9) . . ?
O13 W4 O7 156.3(9) . . ?
O9 W4 O7 89.1(8) . . ?
O11 W4 O7 83.8(8) . . ?
O10 W4 O1' 157.2(8) . . ?
O13 W4 O1' 94.0(8) . . ?
O9 W4 O1' 63.2(8) . . ?
O11 W4 O1' 94.0(8) . . ?
O7 W4 O1' 65.5(8) . . ?
O20 W5 O6 102.0(9) . 2_646 ?
O20 W5 O16 99.3(8) . . ?
O6 W5 O16 90.2(9) 2_646 . ?
O20 W5 O4 99.7(9) . 2_646 ?
O6 W5 O4 88.8(8) 2_646 2_646 ?
O16 W5 O4 160.8(9) . 2_646 ?
O20 W5 O13 101.0(8) . . ?
O6 W5 O13 157.0(9) 2_646 . ?
O16 W5 O13 86.9(8) . . ?
O4 W5 O13 86.6(8) 2_646 . ?
O20 W5 O2 158.9(8) . . ?
O6 W5 O2 65.1(9) 2_646 . ?
O16 W5 O2 97.4(8) . . ?
O4 W5 O2 64.9(9) 2_646 . ?
O13 W5 O2 92.7(8) . . ?
O20 W5 O2' 157.9(8) . 2_646 ?
O6 W5 O2' 93.6(9) 2_646 2_646 ?
O16 W5 O2' 64.8(8) . 2_646 ?
O4 W5 O2' 96.1(8) 2_646 2_646 ?
O13 W5 O2' 64.6(7) . 2_646 ?
O2 W5 O2' 43.1(8) . 2_646 ?
O12 W6 O11 103.2(9) . . ?
O12 W6 O16 99.0(8) . . ?
O11 W6 O16 89.8(8) . . ?
O12 W6 O18 100.4(8) . . ?
O11 W6 O18 89.7(7) . . ?
O16 W6 O18 160.2(8) . . ?
O12 W6 O14 101.3(8) . . ?
O11 W6 O14 155.5(8) . . ?
O16 W6 O14 85.3(8) . . ?
O18 W6 O14 87.0(7) . . ?
O12 W6 O2' 161.2(9) . 2_646 ?
O11 W6 O2' 64.7(8) . 2_646 ?
O16 W6 O2' 67.8(8) . 2_646 ?
O18 W6 O2' 94.2(7) . 2_646 ?
O14 W6 O2' 91.3(8) . 2_646 ?
O12 W6 O1 161.5(9) . 2_646 ?
O11 W6 O1 90.7(8) . 2_646 ?
O16 W6 O1 93.1(8) . 2_646 ?
O18 W6 O1 67.1(8) . 2_646 ?
O14 W6 O1 65.7(8) . 2_646 ?
O2' W6 O1 37.3(8) 2_646 2_646 ?
P1 O1' O1 51.1(11) . . ?
P1 O1' O2' 51.1(10) . 2_646 ?
O1 O1' O2' 88.4(15) . 2_646 ?
P1 O1' W1 126.6(12) . 2_646 ?
O1 O1' W1 75.5(11) . 2_646 ?
O2' O1' W1 139.9(14) 2_646 2_646 ?
P1 O1' W4 123.2(12) . . ?
O1 O1' W4 136.5(14) . . ?
O2' O1' W4 72.1(11) 2_646 . ?
W1 O1' W4 94.5(8) 2_646 . ?
P1 O1' W2 118.4(11) . . ?
O1 O1' W2 129.9(14) . . ?
O2' O1' W2 124.3(13) 2_646 . ?
W1 O1' W2 93.1(8) 2_646 . ?
W4 O1' W2 92.3(8) . . ?
P1 O1 O2' 59.1(13) . . ?
P1 O1 O2 58.5(12) . . ?
O2' O1 O2 96.5(18) . . ?
P1 O1 O1' 59.3(12) . . ?
O2' O1 O1' 97.9(18) . . ?
O2 O1 O1' 93.0(17) . . ?
P1 O1 W6 128.3(14) . 2_646 ?
O2' O1 W6 69.2(13) . 2_646 ?
O2 O1 W6 131.9(16) . 2_646 ?
O1' O1 W6 133.3(15) . 2_646 ?
P1 O2' O1 56.6(13) . . ?
P1 O2' O1' 56.7(11) . 2_646 ?
O1 O2' O1' 95.1(16) . 2_646 ?
P1 O2' W6 130.1(13) . 2_646 ?
O1 O2' W6 73.5(13) . 2_646 ?
O1' O2' W6 135.1(14) 2_646 2_646 ?
P1 O2' W5 121.6(13) . 2_646 ?
O1 O2' W5 132.7(16) . 2_646 ?
O1' O2' W5 124.2(13) 2_646 2_646 ?
W6 O2' W5 91.3(8) 2_646 2_646 ?
P1 O2 O1 51.7(11) . . ?
P1 O2 W3 125.3(13) . 2_646 ?
O1 O2 W3 73.7(12) . 2_646 ?
P1 O2 W5 122.2(14) . . ?
O1 O2 W5 136.5(16) . . ?
W3 O2 W5 93.5(9) 2_646 . ?
P1 O2 W2 121.3(13) . 2_646 ?
O1 O2 W2 129.5(16) . 2_646 ?
W3 O2 W2 94.2(9) 2_646 2_646 ?
W5 O2 W2 92.0(8) . 2_646 ?
W2 O3 W3 140.1(12) . . ?
W3 O4 W5 135.2(12) . 2_646 ?
W1 O5 W2 138.4(12) . 2_646 ?
W5 O6 W2 138.4(12) 2_646 . ?
W2 O7 W4 137.6(11) . . ?
W4 O9 W1 138.4(12) . 2_646 ?
W6 O11 W4 140.1(11) . . ?
W6 O11 Ag1 116.2(8) . . ?
W4 O11 Ag1 102.1(7) . . ?
W4 O13 W5 140.6(10) . . ?
W1 O14 W6 138.9(9) . . ?
W3 O15 W1 141.6(10) . . ?
W6 O16 W5 135.2(10) . . ?
W6 O18 W3 136.2(9) . . ?
N3 Ag1 N5 142.4(9) . . ?
N3 Ag1 O11 94.6(8) . . ?
N5 Ag1 O11 123.0(8) . . ?
N11 Ag2 N7 172.2(8) . . ?
N1 Ag3 N9 170.2(8) . 2_566 ?
C2 C1 N2 111(2) . . ?
C2 C1 C4 135(2) . . ?
N2 C1 C4 114(2) . . ?
C1 C2 C3 104(2) . . ?
C1 C2 C6 129(2) . . ?
C3 C2 C6 127(2) . . ?
N1 C3 C2 113(2) . . ?
N1 C3 C5 121(2) . . ?
C2 C3 C5 126(2) . . ?
C1 C4 H4A 109.5 . . ?
C1 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
C1 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
C3 C5 H5A 109.5 . . ?
C3 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C3 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C8 C6 C2 113(2) . . ?
C8 C6 H6A 108.9 . . ?
C2 C6 H6A 108.9 . . ?
C8 C6 H6B 108.9 . . ?
C2 C6 H6B 108.9 . . ?
H6A C6 H6B 107.7 . . ?
N4 C7 C8 109(2) . . ?
N4 C7 C11 121(3) . . ?
C8 C7 C11 130(2) . . ?
C9 C8 C7 105(2) . . ?
C9 C8 C6 126(2) . . ?
C7 C8 C6 129(2) . . ?
C8 C9 N3 110(3) . . ?
C8 C9 C10 131(3) . . ?
N3 C9 C10 118(3) . . ?
C9 C10 H10A 109.5 . . ?
C9 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C9 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C7 C11 H11A 109.5 . . ?
C7 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C7 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
N6 C12 C13 101(2) . . ?
N6 C12 C15 121(3) . . ?
C13 C12 C15 138(3) . . ?
C14 C13 C12 110(2) . . ?
C14 C13 C17 125(2) . . ?
C12 C13 C17 124(2) . . ?
C13 C14 N5 107(2) . . ?
C13 C14 C16 132(2) . . ?
N5 C14 C16 121(3) . . ?
C12 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C12 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C14 C16 H16A 109.5 . . ?
C14 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C14 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
C13 C17 C19 114.9(19) . . ?
C13 C17 H17A 108.6 . . ?
C19 C17 H17A 108.6 . . ?
C13 C17 H17B 108.6 . . ?
C19 C17 H17B 108.6 . . ?
H17A C17 H17B 107.5 . . ?
N8 C18 C19 104(2) . . ?
N8 C18 C21 123(2) . . ?
C19 C18 C21 133(2) . . ?
C18 C19 C20 107(2) . . ?
C18 C19 C17 125(2) . . ?
C20 C19 C17 128(2) . . ?
N7 C20 C19 109(2) . . ?
N7 C20 C22 121(2) . . ?
C19 C20 C22 130(2) . . ?
C18 C21 H21A 109.5 . . ?
C18 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C18 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C20 C22 H22A 109.5 . . ?
C20 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C20 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N9 C23 C24 108(2) . . ?
N9 C23 C27 121.5(19) . . ?
C24 C23 C27 130.7(19) . . ?
C25 C24 C23 106.4(19) . . ?
C25 C24 C28 127(2) . . ?
C23 C24 C28 127(2) . . ?
C24 C25 N10 107(2) . . ?
C24 C25 C26 133(2) . . ?
N10 C25 C26 121(2) . . ?
C25 C26 H26A 109.5 . . ?
C25 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C25 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C23 C27 H27A 109.5 . . ?
C23 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
C23 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C24 C28 C30 120(2) . . ?
C24 C28 H28A 107.4 . . ?
C30 C28 H28A 107.4 . . ?
C24 C28 H28B 107.4 . . ?
C30 C28 H28B 107.4 . . ?
H28A C28 H28B 106.9 . . ?
N11 C29 C30 109.6(18) . . ?
N11 C29 C33 120(2) . . ?
C30 C29 C33 130.7(19) . . ?
C31 C30 C29 105.1(18) . . ?
C31 C30 C28 127(2) . . ?
C29 C30 C28 127.9(19) . . ?
N12 C31 C30 106.2(19) . . ?
N12 C31 C32 124(2) . . ?
C30 C31 C32 129(2) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C29 C33 H33A 109.5 . . ?
C29 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C29 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C3 N1 N2 104.1(19) . . ?
C3 N1 Ag3 131.1(18) . . ?
N2 N1 Ag3 124.7(16) . . ?
C1 N2 N1 108(2) . . ?
C1 N2 H2A 125.8 . . ?
N1 N2 H2A 125.8 . . ?
N4 N3 C9 104(2) . . ?
N4 N3 Ag1 131.3(18) . . ?
C9 N3 Ag1 125(2) . . ?
C7 N4 N3 112(2) . . ?
C7 N4 H4D 124.0 . . ?
N3 N4 H4D 124.0 . . ?
N6 N5 C14 106(2) . . ?
N6 N5 Ag1 121.9(18) . . ?
C14 N5 Ag1 126(2) . . ?
N5 N6 C12 115(2) . . ?
N5 N6 H6C 122.5 . . ?
C12 N6 H6C 122.5 . . ?
N8 N7 C20 104.4(18) . . ?
N8 N7 Ag2 125.8(16) . . ?
C20 N7 Ag2 129.5(15) . . ?
N7 N8 C18 116(2) . . ?
N7 N8 H8A 122.1 . . ?
C18 N8 H8A 122.1 . . ?
N10 N9 C23 108.0(18) . . ?
N10 N9 Ag3 124.9(14) . 2_566 ?
C23 N9 Ag3 127.0(16) . 2_566 ?
N9 N10 C25 111.1(19) . . ?
N9 N10 H10D 124.4 . . ?
C25 N10 H10D 124.4 . . ?
N12 N11 C29 103.8(17) . . ?
N12 N11 Ag2 125.1(13) . . ?
C29 N11 Ag2 130.9(14) . . ?
C31 N12 N11 115.2(17) . . ?
C31 N12 H12A 122.4 . . ?
N11 N12 H12A 122.4 . . ?

_diffrn_measured_fraction_theta_max 0.993
_diffrn_reflns_theta_full        25.00
_diffrn_measured_fraction_theta_full 0.993
_refine_diff_density_max         2.555
_refine_diff_density_min         -3.824
_refine_diff_density_rms         0.364

_database_code_depnum_ccdc_archive 'CCDC 979426'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_compound-4

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C22 H32 Ag2 N8 O31 P W9'
_chemical_formula_weight         2806

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   14.978(5)
_cell_length_b                   29.229(5)
_cell_length_c                   25.515(5)
_cell_angle_alpha                90.000(5)
_cell_angle_beta                 95.961(5)
_cell_angle_gamma                90.000(5)
_cell_volume                     11110(5)
_cell_formula_units_Z            8
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    30835
_cell_measurement_theta_min      1.53
_cell_measurement_theta_max      26.31

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.355
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             9944
_exptl_absorpt_coefficient_mu    19.353
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_correction_T_min  0.021
_exptl_absorpt_correction_T_max  0.045
_exptl_absorpt_process_details   'ABSCOR by T.Higashi    8  March, 1995'

_exptl_special_details           
; 
During the refinement of compound 4, the restraint command 'ISOR' is used to refine the non-H atoms with ADP problems. 
These atoms are as follows: O17 C7 O6 N1 O9 O10 O23 C8 C19 O30 O6 O27 P1 O4 C13 C16 O11 C1 and O3.
The command 'delu' was used to solve the non-H atoms with 'Large Hirshfeld Difference...' problems. 
These atoms are as follows: P1 O4 C14 and C16. These restraint refinement leads to a relatively high restraint value 116.
In the final refinement, the water molecule could not be modeled properly, thus the SQUEEZE routine of PLATON was applied to remove the contributions to the scattering from the solvent molecules. 
The reported refinements are of the guest-free structures using the *.hkp files produced by using the SQUEEZE routine. 
The SQUEEZE program indicates that there is at least two solvent water molecule in the crystal structure. 
This water molecule was directly included in the final molecular formula based on the elemental analysis, TG and SQUEEZE analysis. 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71069
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        none
_diffrn_reflns_number            30835
_diffrn_reflns_av_R_equivalents  0.0659
_diffrn_reflns_av_sigmaI/netI    0.0815
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_k_min       -36
_diffrn_reflns_limit_k_max       31
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_theta_min         1.53
_diffrn_reflns_theta_max         26.31
_reflns_number_total             11312
_reflns_number_gt                7523
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       'Bruker XSCANS'
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0508P)²+296.7278P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11219
_refine_ls_number_parameters     658
_refine_ls_number_restraints     116
_refine_ls_R_factor_all          0.0907
_refine_ls_R_factor_gt           0.0496
_refine_ls_wR_factor_ref         0.1325
_refine_ls_wR_factor_gt          0.1147
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_restrained_S_all      1.064
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
1 0.000 0.000 0.000 28.2 -0.1
2 0.000 0.000 0.500 28.2 0.1
3 0.000 0.210 0.750 404.6 114.6
4 0.000 0.300 0.250 13.3 -2.0
5 0.000 0.790 0.250 404.6 111.6
6 0.000 0.700 0.750 13.2 -1.3
7 0.500 0.290 0.250 404.6 111.6
8 0.500 0.710 0.750 404.6 114.5
9 0.500 0.500 0.500 28.2 0.1
10 0.500 0.500 0.000 28.2 -0.1
11 0.500 0.200 0.750 13.3 -1.3
12 0.500 0.800 0.250 13.3 -2.0
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
P1 P 0.8833(2) 0.10756(12) 0.20577(15) 0.0044(7) Uani 1 1 d U . .
W1 W 0.82841(5) 0.20959(2) 0.26825(3) 0.01966(17) Uani 1 1 d . . .
W2 W 0.76149(4) 0.07383(2) 0.08562(3) 0.01607(16) Uani 1 1 d . . .
W3 W 0.99892(4) 0.11141(2) 0.09193(3) 0.01697(16) Uani 1 1 d . . .
W4 W 0.94883(5) 0.21100(2) 0.14922(3) 0.01874(17) Uani 1 1 d . . .
W5 W 0.65544(4) 0.07452(2) 0.19673(3) 0.01680(16) Uani 1 1 d . . .
W6 W 0.71113(4) 0.17446(2) 0.13971(3) 0.01784(16) Uani 1 1 d . . .
W7 W 0.77924(4) 0.10941(2) 0.32483(3) 0.01735(16) Uani 1 1 d . . .
W8 W 0.94474(4) 0.00227(2) 0.15169(3) 0.01507(16) Uani 1 1 d . . .
W9 W 0.83673(4) 0.00154(2) 0.26181(3) 0.01546(16) Uani 1 1 d . . .
O1 O 0.9496(7) 0.1328(4) 0.1739(4) 0.014(2) Uani 1 1 d . . .
O2 O 0.8699(7) 0.1325(4) 0.2577(4) 0.015(2) Uani 1 1 d . . .
O3 O 0.9083(7) 0.0576(3) 0.2150(4) 0.010(2) Uani 1 1 d U . .
O4 O 0.7906(7) 0.1074(3) 0.1708(4) 0.014(2) Uani 1 1 d U . .
O5 O 0.7884(8) -0.0446(4) 0.2880(5) 0.033(3) Uani 1 1 d . . .
O6 O 0.7322(7) 0.0244(4) 0.2201(4) 0.016(2) Uani 1 1 d U . .
O7 O 1.0018(7) 0.0508(4) 0.1204(5) 0.019(3) Uani 1 1 d . . .
O8 O 0.8177(7) 0.0495(4) 0.3091(4) 0.019(3) Uani 1 1 d . . .
O9 O 0.8333(7) 0.0244(3) 0.1162(4) 0.013(2) Uani 1 1 d U . .
O10 O 0.6229(7) 0.1330(4) 0.1653(5) 0.022(3) Uani 1 1 d U . .
O11 O 0.7646(8) 0.1745(4) 0.3143(5) 0.022(3) Uani 1 1 d U . .
O12 O 0.8244(8) 0.1950(4) 0.1255(5) 0.019(3) Uani 1 1 d . . .
O13 O 0.9063(7) 0.2201(4) 0.2150(5) 0.024(3) Uani 1 1 d . . .
O14 O 0.7078(9) 0.1009(5) 0.3713(5) 0.034(3) Uani 1 1 d . . .
O15 O 0.9622(8) -0.0425(4) 0.1114(5) 0.029(3) Uani 1 1 d . . .
O16 O 0.6672(7) 0.0536(4) 0.1262(4) 0.017(3) Uani 1 1 d . . .
O17 O 0.9817(8) 0.1757(4) 0.0909(4) 0.022(3) Uani 1 1 d U . .
O18 O 1.0333(8) 0.1045(5) 0.0312(5) 0.035(3) Uani 1 1 d . . .
O19 O 1.0662(8) 0.2097(4) 0.1811(5) 0.021(3) Uani 1 1 d . . .
O20 O 0.5537(8) 0.0525(4) 0.2063(5) 0.026(3) Uani 1 1 d . . .
O21 O 0.8741(8) 0.1011(4) 0.0745(5) 0.020(3) Uani 1 1 d . . .
O22 O 0.9526(8) -0.0050(4) 0.2983(4) 0.020(3) Uani 1 1 d . . .
O23 O 0.9483(9) 0.2652(4) 0.1233(5) 0.032(3) Uani 1 1 d U . .
O24 O 0.7234(8) 0.0495(4) 0.0272(5) 0.025(3) Uani 1 1 d . . .
O25 O 0.8756(7) -0.0288(4) 0.2009(4) 0.016(2) Uani 1 1 d . . .
O26 O 0.7068(7) 0.1333(4) 0.0808(4) 0.018(3) Uani 1 1 d . . .
O27 O 0.7399(7) 0.1956(4) 0.2098(5) 0.020(3) Uani 1 1 d U . .
O28 O 0.7876(8) 0.2623(4) 0.2808(6) 0.035(3) Uani 1 1 d . . .
O29 O 0.8851(7) 0.1194(4) 0.3692(5) 0.019(3) Uani 1 1 d . . .
O30 O 0.6909(7) 0.1009(4) 0.2620(5) 0.018(3) Uani 1 1 d U . .
O31 O 0.6384(8) 0.2167(4) 0.1124(5) 0.029(3) Uani 1 1 d . . .
Ag1 Ag 0.95792(14) 0.19770(7) -0.01981(8) 0.0605(6) Uani 1 1 d . . .
Ag2 Ag 1.12082(10) 0.44208(5) 0.21033(6) 0.0353(4) Uani 1 1 d . . .
C1 C 1.1112(14) 0.2677(7) 0.0216(8) 0.034(5) Uani 1 1 d U . .
C2 C 1.1321(13) 0.3131(6) 0.0151(8) 0.028(4) Uani 1 1 d . . .
C3 C 1.0627(16) 0.3321(8) -0.0170(8) 0.046(6) Uani 1 1 d . . .
C4 C 1.1641(16) 0.2319(8) 0.0545(10) 0.056(7) Uani 1 1 d . . .
H4A H 1.1330 0.2032 0.0511 0.084 Uiso 1 1 calc R . .
H4B H 1.1706 0.2412 0.0908 0.084 Uiso 1 1 calc R . .
H4C H 1.2224 0.2286 0.0424 0.084 Uiso 1 1 calc R . .
C5 C 1.0452(17) 0.3798(9) -0.0374(11) 0.070(9) Uani 1 1 d . . .
H5A H 0.9893 0.3805 -0.0595 0.104 Uiso 1 1 calc R . .
H5B H 1.0929 0.3890 -0.0574 0.104 Uiso 1 1 calc R . .
H5C H 1.0421 0.4003 -0.0083 0.104 Uiso 1 1 calc R . .
C6 C 1.2158(13) 0.3371(7) 0.0386(10) 0.043(6) Uani 1 1 d . . .
H6A H 1.2517 0.3154 0.0604 0.051 Uiso 1 1 calc R . .
H6B H 1.2503 0.3461 0.0102 0.051 Uiso 1 1 calc R . .
C7 C 1.1520(11) 0.3805(6) 0.1162(7) 0.023(4) Uani 1 1 d U . .
C8 C 1.2017(12) 0.3786(6) 0.0713(7) 0.023(4) Uani 1 1 d U . .
C9 C 1.2313(13) 0.4220(7) 0.0657(7) 0.032(5) Uani 1 1 d . . .
C10 C 1.1023(13) 0.3416(6) 0.1406(8) 0.034(5) Uani 1 1 d . . .
H10A H 1.0747 0.3529 0.1704 0.051 Uiso 1 1 calc R . .
H10B H 1.1441 0.3178 0.1519 0.051 Uiso 1 1 calc R . .
H10C H 1.0570 0.3296 0.1149 0.051 Uiso 1 1 calc R . .
C11 C 1.2864(15) 0.4404(7) 0.0246(8) 0.042(6) Uani 1 1 d . . .
H11A H 1.2974 0.4724 0.0306 0.064 Uiso 1 1 calc R . .
H11B H 1.2545 0.4361 -0.0097 0.064 Uiso 1 1 calc R . .
H11C H 1.3426 0.4243 0.0265 0.064 Uiso 1 1 calc R . .
C12 C 1.1157(12) 0.4104(6) 0.3257(8) 0.031(5) Uani 1 1 d . . .
C13 C 1.1074(13) 0.4256(6) 0.3760(8) 0.029(4) Uani 1 1 d U . .
C14 C 1.0784(14) 0.4696(7) 0.3716(9) 0.041(5) Uani 1 1 d U . .
C15 C 1.1442(15) 0.3651(7) 0.3081(9) 0.043(6) Uani 1 1 d . . .
H15A H 1.1427 0.3649 0.2704 0.064 Uiso 1 1 calc R . .
H15B H 1.1042 0.3420 0.3189 0.064 Uiso 1 1 calc R . .
H15C H 1.2041 0.3588 0.3236 0.064 Uiso 1 1 calc R . .
C16 C 1.0601(17) 0.5052(8) 0.4105(10) 0.054(6) Uani 1 1 d U . .
H16A H 1.0403 0.5328 0.3924 0.082 Uiso 1 1 calc R . .
H16B H 1.1140 0.5114 0.4333 0.082 Uiso 1 1 calc R . .
H16C H 1.0142 0.4946 0.4312 0.082 Uiso 1 1 calc R . .
C17 C 1.1342(13) 0.3984(8) 0.4245(8) 0.037(5) Uani 1 1 d . . .
H17A H 1.1030 0.3693 0.4218 0.045 Uiso 1 1 calc R . .
H17B H 1.1153 0.4145 0.4547 0.045 Uiso 1 1 calc R . .
C18 C 1.2755(16) 0.3476(6) 0.4494(8) 0.040(5) Uani 1 1 d . . .
C19 C 1.2340(12) 0.3896(6) 0.4337(7) 0.024(4) Uani 1 1 d U . .
C20 C 1.3036(13) 0.4201(7) 0.4302(7) 0.029(4) Uani 1 1 d . . .
C21 C 1.2305(18) 0.3026(8) 0.4609(11) 0.061(7) Uani 1 1 d . . .
H21A H 1.2756 0.2799 0.4703 0.092 Uiso 1 1 calc R . .
H21B H 1.1932 0.2928 0.4300 0.092 Uiso 1 1 calc R . .
H21C H 1.1943 0.3067 0.4894 0.092 Uiso 1 1 calc R . .
C22 C 1.3097(16) 0.4692(7) 0.4181(10) 0.049(6) Uani 1 1 d . . .
H22A H 1.3717 0.4778 0.4190 0.073 Uiso 1 1 calc R . .
H22B H 1.2817 0.4866 0.4437 0.073 Uiso 1 1 calc R . .
H22C H 1.2798 0.4751 0.3836 0.073 Uiso 1 1 calc R . .
N1 N 1.0329(13) 0.2582(6) -0.0053(8) 0.049(5) Uani 1 1 d U . .
N2 N 1.0045(14) 0.2975(8) -0.0266(9) 0.069(7) Uani 1 1 d . . .
H2A H 0.9534 0.3006 -0.0450 0.083 Uiso 1 1 calc R . .
N3 N 1.1543(11) 0.4221(6) 0.1367(6) 0.034(4) Uani 1 1 d . . .
N4 N 1.2042(12) 0.4465(5) 0.1048(6) 0.037(4) Uani 1 1 d . . .
H4D H 1.2168 0.4750 0.1096 0.044 Uiso 1 1 calc R . .
N5 N 1.0941(10) 0.4426(5) 0.2891(7) 0.031(4) Uani 1 1 d . . .
N6 N 1.0723(10) 0.4792(5) 0.3183(7) 0.031(4) Uani 1 1 d . . .
H6C H 1.0566 0.5054 0.3051 0.038 Uiso 1 1 calc R . .
N7 N 1.3797(12) 0.3963(6) 0.4422(7) 0.043(5) Uani 1 1 d . . .
H7A H 1.4323 0.4080 0.4421 0.052 Uiso 1 1 calc R . .
N8 N 1.3647(12) 0.3512(6) 0.4547(7) 0.039(5) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
P1 O3 1.521(10) . ?
P1 O1 1.536(10) . ?
P1 O2 1.544(11) . ?
P1 O4 1.571(11) . ?
W1 O28 1.700(12) . ?
W1 O11 1.893(11) . ?
W1 O13 1.905(12) . ?
W1 O19 1.933(12) 2_755 ?
W1 O27 1.933(12) . ?
W1 O2 2.360(11) . ?
W2 O24 1.696(12) . ?
W2 O21 1.913(11) . ?
W2 O9 1.918(10) . ?
W2 O26 1.919(10) . ?
W2 O16 1.930(10) . ?
W2 O4 2.382(11) . ?
W3 O18 1.694(12) . ?
W3 O17 1.896(11) . ?
W3 O21 1.900(12) . ?
W3 O7 1.914(11) . ?
W3 O29 1.924(11) 2_755 ?
W3 O1 2.374(10) . ?
W4 O23 1.715(11) . ?
W4 O19 1.860(12) . ?
W4 O13 1.875(12) . ?
W4 O17 1.918(12) . ?
W4 O12 1.955(12) . ?
W4 O1 2.371(10) . ?
W5 O20 1.695(11) . ?
W5 O30 1.861(12) . ?
W5 O6 1.918(11) . ?
W5 O16 1.926(11) . ?
W5 O10 1.930(11) . ?
W5 O4 2.396(10) . ?
W6 O31 1.744(12) . ?
W6 O12 1.871(11) . ?
W6 O27 1.900(12) . ?
W6 O26 1.922(11) . ?
W6 O10 1.955(11) . ?
W6 O4 2.386(10) . ?
W7 O14 1.696(11) . ?
W7 O29 1.872(11) . ?
W7 O8 1.900(11) . ?
W7 O11 1.930(11) . ?
W7 O30 1.986(12) . ?
W7 O2 2.390(10) . ?
W8 O15 1.701(11) . ?
W8 O7 1.876(11) . ?
W8 O22 1.904(12) 2_755 ?
W8 O9 1.927(10) . ?
W8 O25 1.936(10) . ?
W8 O3 2.388(10) . ?
W9 O5 1.699(12) . ?
W9 O8 1.889(11) . ?
W9 O22 1.893(12) . ?
W9 O6 1.920(11) . ?
W9 O25 1.931(11) . ?
W9 O3 2.350(10) . ?
O19 W1 1.933(12) 2_755 ?
O22 W8 1.904(12) 2_755 ?
O29 W3 1.924(11) 2_755 ?
Ag1 N8 2.056(15) 8_455 ?
Ag1 N1 2.108(17) . ?
Ag2 N3 2.078(16) . ?
Ag2 N5 2.091(16) . ?
C1 N1 1.32(3) . ?
C1 C2 1.38(3) . ?
C1 C4 1.51(3) . ?
C2 C3 1.37(3) . ?
C2 C6 1.51(3) . ?
C3 N2 1.34(3) . ?
C3 C5 1.50(3) . ?
C6 C8 1.50(3) . ?
C7 N3 1.32(2) . ?
C7 C8 1.43(2) . ?
C7 C10 1.53(2) . ?
C8 C9 1.36(3) . ?
C9 N4 1.32(2) . ?
C9 C11 1.50(3) . ?
C12 N5 1.34(2) . ?
C12 C13 1.38(3) . ?
C12 C15 1.48(3) . ?
C13 C14 1.36(3) . ?
C13 C17 1.49(3) . ?
C14 N6 1.38(3) . ?
C14 C16 1.48(3) . ?
C17 C19 1.51(3) . ?
C18 N8 1.33(3) . ?
C18 C19 1.41(2) . ?
C18 C21 1.52(3) . ?
C19 C20 1.38(3) . ?
C20 N7 1.34(2) . ?
C20 C22 1.47(3) . ?
N1 N2 1.32(3) . ?
N3 N4 1.36(2) . ?
N5 N6 1.36(2) . ?
N7 N8 1.38(2) . ?
N8 Ag1 2.056(15) 8_556 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 P1 O1 112.4(6) . . ?
O3 P1 O2 111.9(6) . . ?
O1 P1 O2 112.1(6) . . ?
O3 P1 O4 105.9(6) . . ?
O1 P1 O4 106.4(6) . . ?
O2 P1 O4 107.7(6) . . ?
O28 W1 O11 99.2(6) . . ?
O28 W1 O13 104.3(6) . . ?
O11 W1 O13 156.4(5) . . ?
O28 W1 O19 99.0(5) . 2_755 ?
O11 W1 O19 90.9(5) . 2_755 ?
O13 W1 O19 87.6(5) . 2_755 ?
O28 W1 O27 96.1(5) . . ?
O11 W1 O27 90.8(5) . . ?
O13 W1 O27 84.6(5) . . ?
O19 W1 O27 164.3(4) 2_755 . ?
O28 W1 O2 172.1(5) . . ?
O11 W1 O2 73.1(4) . . ?
O13 W1 O2 83.4(4) . . ?
O19 W1 O2 82.6(4) 2_755 . ?
O27 W1 O2 83.0(4) . . ?
O24 W2 O21 105.4(5) . . ?
O24 W2 O9 99.5(5) . . ?
O21 W2 O9 84.7(4) . . ?
O24 W2 O26 102.8(5) . . ?
O21 W2 O26 89.5(4) . . ?
O9 W2 O26 157.8(5) . . ?
O24 W2 O16 98.3(5) . . ?
O21 W2 O16 156.0(5) . . ?
O9 W2 O16 87.8(4) . . ?
O26 W2 O16 88.9(4) . . ?
O24 W2 O4 170.8(5) . . ?
O21 W2 O4 83.3(4) . . ?
O9 W2 O4 84.2(4) . . ?
O26 W2 O4 73.9(4) . . ?
O16 W2 O4 73.3(4) . . ?
O18 W3 O17 99.1(6) . . ?
O18 W3 O21 98.8(6) . . ?
O17 W3 O21 91.4(5) . . ?
O18 W3 O7 103.9(6) . . ?
O17 W3 O7 157.0(5) . . ?
O21 W3 O7 85.7(5) . . ?
O18 W3 O29 98.2(6) . 2_755 ?
O17 W3 O29 90.0(5) . 2_755 ?
O21 W3 O29 162.5(5) . 2_755 ?
O7 W3 O29 86.2(5) . 2_755 ?
O18 W3 O1 171.5(5) . . ?
O17 W3 O1 72.4(4) . . ?
O21 W3 O1 81.9(4) . . ?
O7 W3 O1 84.6(4) . . ?
O29 W3 O1 81.9(4) 2_755 . ?
O23 W4 O19 98.9(6) . . ?
O23 W4 O13 103.1(5) . . ?
O19 W4 O13 90.3(5) . . ?
O23 W4 O17 100.9(5) . . ?
O19 W4 O17 91.2(5) . . ?
O13 W4 O17 155.5(5) . . ?
O23 W4 O12 97.8(6) . . ?
O19 W4 O12 163.3(4) . . ?
O13 W4 O12 84.8(5) . . ?
O17 W4 O12 86.8(5) . . ?
O23 W4 O1 172.8(5) . . ?
O19 W4 O1 83.4(4) . . ?
O13 W4 O1 83.8(4) . . ?
O17 W4 O1 72.1(4) . . ?
O12 W4 O1 80.2(4) . . ?
O20 W5 O30 101.9(5) . . ?
O20 W5 O6 100.7(5) . . ?
O30 W5 O6 86.1(5) . . ?
O20 W5 O16 100.6(5) . . ?
O30 W5 O16 157.2(4) . . ?
O6 W5 O16 86.4(5) . . ?
O20 W5 O10 101.7(5) . . ?
O30 W5 O10 92.3(5) . . ?
O6 W5 O10 157.4(4) . . ?
O16 W5 O10 86.4(5) . . ?
O20 W5 O4 172.0(5) . . ?
O30 W5 O4 84.9(4) . . ?
O6 W5 O4 84.0(4) . . ?
O16 W5 O4 73.0(4) . . ?
O10 W5 O4 73.4(4) . . ?
O31 W6 O12 103.7(5) . . ?
O31 W6 O27 102.5(5) . . ?
O12 W6 O27 87.5(5) . . ?
O31 W6 O26 99.3(5) . . ?
O12 W6 O26 90.4(5) . . ?
O27 W6 O26 157.9(5) . . ?
O31 W6 O10 99.0(5) . . ?
O12 W6 O10 157.3(5) . . ?
O27 W6 O10 89.0(5) . . ?
O26 W6 O10 84.5(5) . . ?
O31 W6 O4 169.8(5) . . ?
O12 W6 O4 84.1(4) . . ?
O27 W6 O4 84.2(4) . . ?
O26 W6 O4 73.7(4) . . ?
O10 W6 O4 73.2(4) . . ?
O14 W7 O29 99.0(6) . . ?
O14 W7 O8 103.9(5) . . ?
O29 W7 O8 90.9(5) . . ?
O14 W7 O11 99.8(6) . . ?
O29 W7 O11 90.4(5) . . ?
O8 W7 O11 155.7(5) . . ?
O14 W7 O30 97.5(6) . . ?
O29 W7 O30 163.5(4) . . ?
O8 W7 O30 84.5(5) . . ?
O11 W7 O30 87.4(5) . . ?
O14 W7 O2 171.4(5) . . ?
O29 W7 O2 83.1(4) . . ?
O8 W7 O2 84.3(4) . . ?
O11 W7 O2 71.8(4) . . ?
O30 W7 O2 80.6(4) . . ?
O15 W8 O7 102.7(5) . . ?
O15 W8 O22 98.9(6) . 2_755 ?
O7 W8 O22 89.9(5) . 2_755 ?
O15 W8 O9 98.8(5) . . ?
O7 W8 O9 87.5(5) . . ?
O22 W8 O9 162.2(4) 2_755 . ?
O15 W8 O25 99.0(5) . . ?
O7 W8 O25 158.3(5) . . ?
O22 W8 O25 87.8(5) 2_755 . ?
O9 W8 O25 88.1(4) . . ?
O15 W8 O3 171.8(5) . . ?
O7 W8 O3 85.5(4) . . ?
O22 W8 O3 81.2(4) 2_755 . ?
O9 W8 O3 81.0(4) . . ?
O25 W8 O3 72.8(4) . . ?
O5 W9 O8 103.9(5) . . ?
O5 W9 O22 97.7(6) . . ?
O8 W9 O22 87.2(5) . . ?
O5 W9 O6 97.9(5) . . ?
O8 W9 O6 85.8(5) . . ?
O22 W9 O6 164.0(4) . . ?
O5 W9 O25 97.3(5) . . ?
O8 W9 O25 158.8(4) . . ?
O22 W9 O25 90.7(5) . . ?
O6 W9 O25 90.6(5) . . ?
O5 W9 O3 171.1(5) . . ?
O8 W9 O3 85.1(4) . . ?
O22 W9 O3 82.9(4) . . ?
O6 W9 O3 82.2(4) . . ?
O25 W9 O3 73.8(4) . . ?
P1 O1 W4 128.2(6) . . ?
P1 O1 W3 128.1(6) . . ?
W4 O1 W3 90.7(4) . . ?
P1 O2 W1 127.4(6) . . ?
P1 O2 W7 128.0(6) . . ?
W1 O2 W7 90.7(4) . . ?
P1 O3 W9 129.0(6) . . ?
P1 O3 W8 128.0(6) . . ?
W9 O3 W8 91.2(3) . . ?
P1 O4 W2 126.0(6) . . ?
P1 O4 W6 124.5(6) . . ?
W2 O4 W6 89.9(4) . . ?
P1 O4 W5 124.5(6) . . ?
W2 O4 W5 90.4(4) . . ?
W6 O4 W5 90.8(4) . . ?
W5 O6 W9 150.0(6) . . ?
W8 O7 W3 150.3(6) . . ?
W9 O8 W7 152.6(7) . . ?
W2 O9 W8 149.9(6) . . ?
W5 O10 W6 122.5(6) . . ?
W1 O11 W7 124.3(6) . . ?
W6 O12 W4 150.6(7) . . ?
W4 O13 W1 154.9(7) . . ?
W5 O16 W2 123.1(6) . . ?
W3 O17 W4 124.6(6) . . ?
W4 O19 W1 164.1(7) . 2_755 ?
W3 O21 W2 153.2(7) . . ?
W9 O22 W8 162.5(6) . 2_755 ?
W9 O25 W8 122.2(5) . . ?
W2 O26 W6 122.5(6) . . ?
W6 O27 W1 149.9(6) . . ?
W7 O29 W3 162.8(6) . 2_755 ?
W5 O30 W7 151.5(6) . . ?
N8 Ag1 N1 166.2(7) 8_455 . ?
N3 Ag2 N5 163.7(6) . . ?
N1 C1 C2 109.8(19) . . ?
N1 C1 C4 121.9(19) . . ?
C2 C1 C4 128(2) . . ?
C3 C2 C1 107.0(17) . . ?
C3 C2 C6 126.7(18) . . ?
C1 C2 C6 126.2(19) . . ?
N2 C3 C2 104.1(19) . . ?
N2 C3 C5 123(2) . . ?
C2 C3 C5 133(2) . . ?
C8 C6 C2 116.1(16) . . ?
N3 C7 C8 111.0(15) . . ?
N3 C7 C10 121.2(17) . . ?
C8 C7 C10 127.8(16) . . ?
C9 C8 C7 104.4(16) . . ?
C9 C8 C6 129.3(17) . . ?
C7 C8 C6 126.2(16) . . ?
N4 C9 C8 107.4(16) . . ?
N4 C9 C11 124.6(18) . . ?
C8 C9 C11 128.0(18) . . ?
N5 C12 C13 112.6(17) . . ?
N5 C12 C15 118.4(18) . . ?
C13 C12 C15 129.1(19) . . ?
C14 C13 C12 106.6(19) . . ?
C14 C13 C17 129.1(19) . . ?
C12 C13 C17 124.1(18) . . ?
C13 C14 N6 105.2(18) . . ?
C13 C14 C16 133(2) . . ?
N6 C14 C16 121.2(19) . . ?
C13 C17 C19 113.3(16) . . ?
N8 C18 C19 111.5(19) . . ?
N8 C18 C21 120.5(19) . . ?
C19 C18 C21 128(2) . . ?
C20 C19 C18 105.4(17) . . ?
C20 C19 C17 128.5(17) . . ?
C18 C19 C17 126.1(19) . . ?
N7 C20 C19 106.2(17) . . ?
N7 C20 C22 118.9(19) . . ?
C19 C20 C22 134.9(18) . . ?
C1 N1 N2 105.2(17) . . ?
C1 N1 Ag1 133.8(16) . . ?
N2 N1 Ag1 120.9(15) . . ?
N1 N2 C3 114(2) . . ?
C7 N3 N4 103.8(15) . . ?
C7 N3 Ag2 128.2(13) . . ?
N4 N3 Ag2 126.2(12) . . ?
C9 N4 N3 113.3(15) . . ?
C12 N5 N6 103.0(16) . . ?
C12 N5 Ag2 127.4(12) . . ?
N6 N5 Ag2 127.7(12) . . ?
N5 N6 C14 112.5(16) . . ?
C20 N7 N8 113.2(17) . . ?
C18 N8 N7 103.7(15) . . ?
C18 N8 Ag1 128.2(15) . 8_556 ?
N7 N8 Ag1 128.0(14) . 8_556 ?

_diffrn_measured_fraction_theta_max 0.992
_diffrn_reflns_theta_full        26.31
_diffrn_measured_fraction_theta_full 0.992
_refine_diff_density_max         4.985
_refine_diff_density_min         -2.138
_refine_diff_density_rms         0.414
_database_code_depnum_ccdc_archive 'CCDC 979427'
