# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_p

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C40 H46 Ag2 N4 O13'
_chemical_formula_weight         1006.55

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           Triclinic
_symmetry_space_group_name_H-M   P-1

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'

_cell_length_a                   11.2602(8)
_cell_length_b                   13.3780(10)
_cell_length_c                   14.7418(10)
_cell_angle_alpha                90.3790(10)
_cell_angle_beta                 102.6810(10)
_cell_angle_gamma                111.4350(10)
_cell_volume                     2007.4(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    173(2)
_cell_measurement_reflns_used    ?
_cell_measurement_theta_min      ?
_cell_measurement_theta_max      ?

_exptl_crystal_description       block
_exptl_crystal_colour            colorless
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.665
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1024
_exptl_absorpt_coefficient_mu    1.047
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.8587
_exptl_absorpt_correction_T_max  0.9025
_exptl_absorpt_process_details   sadabs

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      173(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            10860
_diffrn_reflns_av_R_equivalents  0.0170
_diffrn_reflns_av_sigmaI/netI    0.0404
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_theta_min         2.00
_diffrn_reflns_theta_max         26.00
_reflns_number_total             7739
_reflns_number_gt                6188
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0383P)²+1.9240P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    mixed
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7739
_refine_ls_number_parameters     532
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0486
_refine_ls_R_factor_gt           0.0354
_refine_ls_wR_factor_ref         0.0911
_refine_ls_wR_factor_gt          0.0826
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_restrained_S_all      1.036
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.83935(3) 0.82666(2) 0.22165(2) 0.03441(9) Uani 1 1 d . . .
Ag2 Ag 0.13754(3) 0.29022(2) 0.692063(19) 0.02881(9) Uani 1 1 d . . .
C1 C -0.6288(3) 0.7948(3) 0.3803(2) 0.0271(7) Uani 1 1 d . . .
H1A H -0.6396 0.8501 0.4144 0.033 Uiso 1 1 calc R . .
C2 C -0.5399(3) 0.7517(3) 0.4232(2) 0.0235(7) Uani 1 1 d . . .
H2A H -0.4907 0.7776 0.4855 0.028 Uiso 1 1 calc R . .
C3 C -0.5215(3) 0.6707(3) 0.3759(2) 0.0208(7) Uani 1 1 d . . .
C4 C -0.5965(3) 0.6370(3) 0.2847(2) 0.0235(7) Uani 1 1 d . . .
H4A H -0.5869 0.5820 0.2493 0.028 Uiso 1 1 calc R . .
C5 C -0.6842(3) 0.6831(3) 0.2458(2) 0.0267(7) Uani 1 1 d . . .
H5A H -0.7348 0.6583 0.1837 0.032 Uiso 1 1 calc R . .
C6 C -0.4282(3) 0.6201(3) 0.4178(2) 0.0187(6) Uani 1 1 d . . .
C7 C -0.3155(3) 0.6749(3) 0.4882(2) 0.0217(7) Uani 1 1 d . . .
H7A H -0.2967 0.7476 0.5091 0.026 Uiso 1 1 calc R . .
C8 C -0.2314(3) 0.6254(3) 0.5279(2) 0.0217(7) Uani 1 1 d . . .
H8A H -0.1560 0.6644 0.5760 0.026 Uiso 1 1 calc R . .
C9 C -0.2551(3) 0.5188(3) 0.4984(2) 0.0182(6) Uani 1 1 d . . .
C10 C -0.3668(3) 0.4644(3) 0.4271(2) 0.0225(7) Uani 1 1 d . . .
H10A H -0.3845 0.3923 0.4052 0.027 Uiso 1 1 calc R . .
C11 C -0.4512(3) 0.5135(3) 0.3883(2) 0.0221(7) Uani 1 1 d . . .
H11A H -0.5268 0.4743 0.3404 0.027 Uiso 1 1 calc R . .
C12 C -0.0089(3) 0.4448(3) 0.6719(2) 0.0278(8) Uani 1 1 d . . .
H12A H 0.0412 0.4678 0.7344 0.033 Uiso 1 1 calc R . .
C13 C -0.0915(3) 0.4956(3) 0.6335(2) 0.0249(7) Uani 1 1 d . . .
H13A H -0.0979 0.5518 0.6695 0.030 Uiso 1 1 calc R . .
C14 C -0.1660(3) 0.4647(2) 0.5419(2) 0.0201(7) Uani 1 1 d . . .
C15 C -0.1524(3) 0.3813(3) 0.4938(2) 0.0223(7) Uani 1 1 d . . .
H15A H -0.2011 0.3574 0.4311 0.027 Uiso 1 1 calc R . .
C16 C -0.0684(3) 0.3335(3) 0.5369(2) 0.0235(7) Uani 1 1 d . . .
H16A H -0.0615 0.2762 0.5028 0.028 Uiso 1 1 calc R . .
C17 C 0.3509(3) 0.2635(3) 0.8497(2) 0.0242(7) Uani 1 1 d . . .
H17A H 0.3359 0.3184 0.8812 0.029 Uiso 1 1 calc R . .
C18 C 0.4423(3) 0.2250(3) 0.8971(2) 0.0232(7) Uani 1 1 d . . .
H18A H 0.4902 0.2543 0.9590 0.028 Uiso 1 1 calc R . .
C19 C 0.4645(3) 0.1423(2) 0.8536(2) 0.0198(7) Uani 1 1 d . . .
C20 C 0.3914(3) 0.1043(3) 0.7623(2) 0.0217(7) Uani 1 1 d . . .
H20A H 0.4022 0.0478 0.7299 0.026 Uiso 1 1 calc R . .
C21 C 0.3038(3) 0.1487(3) 0.7194(2) 0.0232(7) Uani 1 1 d . . .
H21A H 0.2564 0.1223 0.6568 0.028 Uiso 1 1 calc R . .
C22 C 0.5606(3) 0.0980(3) 0.9022(2) 0.0199(7) Uani 1 1 d . . .
C23 C 0.6694(3) 0.1599(3) 0.9731(2) 0.0222(7) Uani 1 1 d . . .
H23A H 0.6824 0.2325 0.9895 0.027 Uiso 1 1 calc R . .
C24 C 0.7580(3) 0.1177(3) 1.0193(2) 0.0229(7) Uani 1 1 d . . .
H24A H 0.8307 0.1615 1.0672 0.027 Uiso 1 1 calc R . .
C25 C 0.7425(3) 0.0111(3) 0.9969(2) 0.0193(6) Uani 1 1 d . . .
C26 C 0.6342(3) -0.0501(3) 0.9255(2) 0.0233(7) Uani 1 1 d . . .
H26A H 0.6216 -0.1226 0.9086 0.028 Uiso 1 1 calc R . .
C27 C 0.5457(3) -0.0083(3) 0.8792(2) 0.0232(7) Uani 1 1 d . . .
H27A H 0.4735 -0.0520 0.8310 0.028 Uiso 1 1 calc R . .
C28 C 0.9917(3) -0.0417(3) 1.1850(2) 0.0251(7) Uani 1 1 d . . .
H28A H 1.0379 -0.0147 1.2477 0.030 Uiso 1 1 calc R . .
C29 C 0.9048(3) 0.0020(3) 1.1400(2) 0.0223(7) Uani 1 1 d . . .
H29A H 0.8916 0.0577 1.1717 0.027 Uiso 1 1 calc R . .
C30 C 0.8355(3) -0.0352(2) 1.0474(2) 0.0188(6) Uani 1 1 d . . .
C31 C 0.8590(3) -0.1179(3) 1.0062(2) 0.0233(7) Uani 1 1 d . . .
H31A H 0.8142 -0.1465 0.9435 0.028 Uiso 1 1 calc R . .
C32 C 0.9464(3) -0.1581(3) 1.0556(2) 0.0261(7) Uani 1 1 d . . .
H32A H 0.9597 -0.2150 1.0259 0.031 Uiso 1 1 calc R . .
C33 C 0.1805(3) 0.2564(2) 0.2436(2) 0.0193(6) Uani 1 1 d . . .
C34 C 0.2895(3) 0.3139(2) 0.1967(2) 0.0165(6) Uani 1 1 d . . .
C35 C 0.2758(3) 0.3885(3) 0.1332(2) 0.0235(7) Uani 1 1 d . . .
H35A H 0.1967 0.4019 0.1189 0.028 Uiso 1 1 calc R . .
C36 C 0.3760(3) 0.4428(3) 0.0912(2) 0.0303(8) Uani 1 1 d . . .
H36A H 0.3664 0.4943 0.0491 0.036 Uiso 1 1 calc R . .
C37 C 0.4909(3) 0.4227(3) 0.1102(2) 0.0261(7) Uani 1 1 d . . .
H37A H 0.5591 0.4599 0.0804 0.031 Uiso 1 1 calc R . .
C38 C 0.5070(3) 0.3484(2) 0.1727(2) 0.0200(7) Uani 1 1 d . . .
C39 C 0.4061(3) 0.2946(2) 0.2160(2) 0.0179(6) Uani 1 1 d . . .
H39A H 0.4166 0.2442 0.2591 0.021 Uiso 1 1 calc R . .
C40 C 0.6339(3) 0.3273(3) 0.1926(2) 0.0253(7) Uani 1 1 d . . .
N1 N -0.7014(3) 0.7621(2) 0.2921(2) 0.0275(6) Uani 1 1 d . . .
N2 N 0.0048(3) 0.3641(2) 0.62572(18) 0.0229(6) Uani 1 1 d . . .
N3 N 0.2816(3) 0.2278(2) 0.76140(19) 0.0222(6) Uani 1 1 d . . .
N4 N 1.0147(3) -0.1213(2) 1.14433(19) 0.0237(6) Uani 1 1 d . . .
O1 O 0.0811(2) 0.28198(19) 0.22629(16) 0.0273(5) Uani 1 1 d . . .
O1W O 0.7302(3) 0.0152(3) 0.4862(2) 0.0523(8) Uani 1 1 d . . .
H1WA H 0.8104 0.0568 0.5051 0.063 Uiso 1 1 d R . .
H1WB H 0.6838 0.0450 0.4521 0.063 Uiso 1 1 d R . .
O2 O 0.1956(2) 0.18810(18) 0.29833(16) 0.0246(5) Uani 1 1 d . . .
O2W O 0.8164(3) 0.5956(2) 0.13373(19) 0.0411(7) Uani 1 1 d . . .
H2WA H 0.8867 0.6135 0.1147 0.049 Uiso 1 1 d R . .
H2WB H 0.7684 0.5297 0.1343 0.049 Uiso 1 1 d R . .
O3W O 0.5745(3) 0.1107(2) 0.37685(19) 0.0487(8) Uani 1 1 d . . .
H3WA H 0.4954 0.0795 0.3809 0.058 Uiso 1 1 d R . .
H3WB H 0.6091 0.1704 0.3552 0.058 Uiso 1 1 d R . .
O3 O 0.6490(2) 0.2656(2) 0.25317(19) 0.0366(6) Uani 1 1 d . . .
O4W O 0.8567(3) 0.1996(3) 0.2946(2) 0.0572(9) Uani 1 1 d . . .
H4WA H 0.7964 0.2247 0.2808 0.069 Uiso 1 1 d R . .
H4WB H 0.9162 0.2212 0.2643 0.069 Uiso 1 1 d R . .
O4 O 0.7156(2) 0.3736(2) 0.14464(18) 0.0342(6) Uani 1 1 d . . .
O5W O 0.0040(2) 0.09382(19) 0.38579(16) 0.0305(6) Uani 1 1 d . . .
H5WA H 0.0681 0.1216 0.3605 0.037 Uiso 1 1 d R . .
H5WB H -0.0579 0.1145 0.3617 0.037 Uiso 1 1 d R . .
O6W O 0.9513(2) 0.39399(18) 0.11388(16) 0.0266(5) Uani 1 1 d . . .
H6WB H 0.9895 0.3543 0.1411 0.032 Uiso 1 1 d R . .
H6WA H 0.8805 0.3801 0.1316 0.032 Uiso 1 1 d R . .
O7W O 0.3039(2) 0.0311(2) 0.33731(19) 0.0401(6) Uani 1 1 d . . .
H7WA H 0.2723 0.0793 0.3229 0.048 Uiso 1 1 d R . .
H7WB H 0.2955 0.0150 0.3918 0.048 Uiso 1 1 d R . .
O8W O 0.0467(2) 0.6156(2) 0.07610(17) 0.0346(6) Uani 1 1 d . . .
H8WB H 0.0576 0.6189 0.0208 0.042 Uiso 1 1 d R . .
H8WA H 0.0557 0.5570 0.0906 0.042 Uiso 1 1 d R . .
O9W O 0.0068(2) 0.11070(19) 0.57063(17) 0.0340(6) Uani 1 1 d . . .
H9WB H 0.0370 0.1183 0.5220 0.041 Uiso 1 1 d R . .
H9WA H 0.0289 0.0605 0.5943 0.041 Uiso 1 1 d R . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.123(3) 1_364 ?
Ag1 N1 2.126(3) . ?
Ag2 N2 2.148(2) . ?
Ag2 N3 2.156(2) . ?
Ag2 O9W 2.710(2) . ?
C1 N1 1.348(4) . ?
C1 C2 1.372(4) . ?
C1 H1A 0.9500 . ?
C2 C3 1.387(4) . ?
C2 H2A 0.9500 . ?
C3 C4 1.392(4) . ?
C3 C6 1.477(4) . ?
C4 C5 1.373(4) . ?
C4 H4A 0.9500 . ?
C5 N1 1.349(4) . ?
C5 H5A 0.9500 . ?
C6 C7 1.399(4) . ?
C6 C11 1.401(4) . ?
C7 C8 1.378(4) . ?
C7 H7A 0.9500 . ?
C8 C9 1.400(4) . ?
C8 H8A 0.9500 . ?
C9 C10 1.398(4) . ?
C9 C14 1.480(4) . ?
C10 C11 1.373(4) . ?
C10 H10A 0.9500 . ?
C11 H11A 0.9500 . ?
C12 N2 1.346(4) . ?
C12 C13 1.373(4) . ?
C12 H12A 0.9500 . ?
C13 C14 1.394(4) . ?
C13 H13A 0.9500 . ?
C14 C15 1.391(4) . ?
C15 C16 1.375(4) . ?
C15 H15A 0.9500 . ?
C16 N2 1.354(4) . ?
C16 H16A 0.9500 . ?
C17 N3 1.344(4) . ?
C17 C18 1.375(4) . ?
C17 H17A 0.9500 . ?
C18 C19 1.400(4) . ?
C18 H18A 0.9500 . ?
C19 C20 1.396(4) . ?
C19 C22 1.473(4) . ?
C20 C21 1.373(4) . ?
C20 H20A 0.9500 . ?
C21 N3 1.348(4) . ?
C21 H21A 0.9500 . ?
C22 C27 1.399(4) . ?
C22 C23 1.401(4) . ?
C23 C24 1.377(4) . ?
C23 H23A 0.9500 . ?
C24 C25 1.399(4) . ?
C24 H24A 0.9500 . ?
C25 C26 1.400(4) . ?
C25 C30 1.474(4) . ?
C26 C27 1.373(4) . ?
C26 H26A 0.9500 . ?
C27 H27A 0.9500 . ?
C28 N4 1.350(4) . ?
C28 C29 1.370(4) . ?
C28 H28A 0.9500 . ?
C29 C30 1.399(4) . ?
C29 H29A 0.9500 . ?
C30 C31 1.394(4) . ?
C31 C32 1.365(4) . ?
C31 H31A 0.9500 . ?
C32 N4 1.348(4) . ?
C32 H32A 0.9500 . ?
C33 O2 1.256(4) . ?
C33 O1 1.261(4) . ?
C33 C34 1.505(4) . ?
C34 C39 1.398(4) . ?
C34 C35 1.400(4) . ?
C35 C36 1.378(5) . ?
C35 H35A 0.9500 . ?
C36 C37 1.385(5) . ?
C36 H36A 0.9500 . ?
C37 C38 1.394(4) . ?
C37 H37A 0.9500 . ?
C38 C39 1.394(4) . ?
C38 C40 1.523(4) . ?
C39 H39A 0.9500 . ?
C40 O3 1.245(4) . ?
C40 O4 1.266(4) . ?
N4 Ag1 2.123(3) 1_746 ?
O1W H1WA 0.8501 . ?
O1W H1WB 0.8500 . ?
O2W H2WA 0.8500 . ?
O2W H2WB 0.8500 . ?
O3W H3WA 0.8501 . ?
O3W H3WB 0.8499 . ?
O4W H4WA 0.8501 . ?
O4W H4WB 0.8500 . ?
O5W H5WA 0.8500 . ?
O5W H5WB 0.8500 . ?
O6W H6WB 0.8500 . ?
O6W H6WA 0.8500 . ?
O7W H7WA 0.8501 . ?
O7W H7WB 0.8500 . ?
O8W H8WB 0.8499 . ?
O8W H8WA 0.8500 . ?
O9W H9WB 0.8500 . ?
O9W H9WA 0.8500 . ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 N1 175.23(11) 1_364 . ?
N2 Ag2 N3 175.82(11) . . ?
N2 Ag2 O9W 91.08(9) . . ?
N3 Ag2 O9W 92.57(9) . . ?
N1 C1 C2 122.9(3) . . ?
N1 C1 H1A 118.5 . . ?
C2 C1 H1A 118.5 . . ?
C1 C2 C3 120.3(3) . . ?
C1 C2 H2A 119.9 . . ?
C3 C2 H2A 119.9 . . ?
C2 C3 C4 116.8(3) . . ?
C2 C3 C6 123.2(3) . . ?
C4 C3 C6 120.0(3) . . ?
C5 C4 C3 120.2(3) . . ?
C5 C4 H4A 119.9 . . ?
C3 C4 H4A 119.9 . . ?
N1 C5 C4 122.8(3) . . ?
N1 C5 H5A 118.6 . . ?
C4 C5 H5A 118.6 . . ?
C7 C6 C11 117.4(3) . . ?
C7 C6 C3 122.2(3) . . ?
C11 C6 C3 120.4(3) . . ?
C8 C7 C6 121.3(3) . . ?
C8 C7 H7A 119.3 . . ?
C6 C7 H7A 119.3 . . ?
C7 C8 C9 121.1(3) . . ?
C7 C8 H8A 119.5 . . ?
C9 C8 H8A 119.5 . . ?
C8 C9 C10 117.7(3) . . ?
C8 C9 C14 121.2(3) . . ?
C10 C9 C14 121.1(3) . . ?
C11 C10 C9 121.2(3) . . ?
C11 C10 H10A 119.4 . . ?
C9 C10 H10A 119.4 . . ?
C10 C11 C6 121.3(3) . . ?
C10 C11 H11A 119.3 . . ?
C6 C11 H11A 119.3 . . ?
N2 C12 C13 123.5(3) . . ?
N2 C12 H12A 118.3 . . ?
C13 C12 H12A 118.3 . . ?
C12 C13 C14 120.0(3) . . ?
C12 C13 H13A 120.0 . . ?
C14 C13 H13A 120.0 . . ?
C15 C14 C13 116.8(3) . . ?
C15 C14 C9 122.0(3) . . ?
C13 C14 C9 121.2(3) . . ?
C16 C15 C14 120.0(3) . . ?
C16 C15 H15A 120.0 . . ?
C14 C15 H15A 120.0 . . ?
N2 C16 C15 123.2(3) . . ?
N2 C16 H16A 118.4 . . ?
C15 C16 H16A 118.4 . . ?
N3 C17 C18 123.6(3) . . ?
N3 C17 H17A 118.2 . . ?
C18 C17 H17A 118.2 . . ?
C17 C18 C19 119.7(3) . . ?
C17 C18 H18A 120.2 . . ?
C19 C18 H18A 120.2 . . ?
C20 C19 C18 116.7(3) . . ?
C20 C19 C22 121.9(3) . . ?
C18 C19 C22 121.4(3) . . ?
C21 C20 C19 119.9(3) . . ?
C21 C20 H20A 120.1 . . ?
C19 C20 H20A 120.1 . . ?
N3 C21 C20 123.4(3) . . ?
N3 C21 H21A 118.3 . . ?
C20 C21 H21A 118.3 . . ?
C27 C22 C23 117.6(3) . . ?
C27 C22 C19 120.8(3) . . ?
C23 C22 C19 121.6(3) . . ?
C24 C23 C22 121.4(3) . . ?
C24 C23 H23A 119.3 . . ?
C22 C23 H23A 119.3 . . ?
C23 C24 C25 121.0(3) . . ?
C23 C24 H24A 119.5 . . ?
C25 C24 H24A 119.5 . . ?
C24 C25 C26 117.4(3) . . ?
C24 C25 C30 121.2(3) . . ?
C26 C25 C30 121.4(3) . . ?
C27 C26 C25 121.8(3) . . ?
C27 C26 H26A 119.1 . . ?
C25 C26 H26A 119.1 . . ?
C26 C27 C22 120.8(3) . . ?
C26 C27 H27A 119.6 . . ?
C22 C27 H27A 119.6 . . ?
N4 C28 C29 123.0(3) . . ?
N4 C28 H28A 118.5 . . ?
C29 C28 H28A 118.5 . . ?
C28 C29 C30 120.2(3) . . ?
C28 C29 H29A 119.9 . . ?
C30 C29 H29A 119.9 . . ?
C31 C30 C29 116.5(3) . . ?
C31 C30 C25 122.1(3) . . ?
C29 C30 C25 121.4(3) . . ?
C32 C31 C30 120.1(3) . . ?
C32 C31 H31A 120.0 . . ?
C30 C31 H31A 120.0 . . ?
N4 C32 C31 123.6(3) . . ?
N4 C32 H32A 118.2 . . ?
C31 C32 H32A 118.2 . . ?
O2 C33 O1 124.6(3) . . ?
O2 C33 C34 118.0(3) . . ?
O1 C33 C34 117.3(3) . . ?
C39 C34 C35 118.8(3) . . ?
C39 C34 C33 121.0(3) . . ?
C35 C34 C33 120.2(3) . . ?
C36 C35 C34 120.5(3) . . ?
C36 C35 H35A 119.8 . . ?
C34 C35 H35A 119.8 . . ?
C35 C36 C37 120.3(3) . . ?
C35 C36 H36A 119.8 . . ?
C37 C36 H36A 119.8 . . ?
C36 C37 C38 120.5(3) . . ?
C36 C37 H37A 119.8 . . ?
C38 C37 H37A 119.8 . . ?
C37 C38 C39 119.1(3) . . ?
C37 C38 C40 119.7(3) . . ?
C39 C38 C40 121.2(3) . . ?
C38 C39 C34 120.8(3) . . ?
C38 C39 H39A 119.6 . . ?
C34 C39 H39A 119.6 . . ?
O3 C40 O4 125.2(3) . . ?
O3 C40 C38 118.2(3) . . ?
O4 C40 C38 116.6(3) . . ?
C1 N1 C5 117.1(3) . . ?
C1 N1 Ag1 124.6(2) . . ?
C5 N1 Ag1 118.3(2) . . ?
C12 N2 C16 116.5(3) . . ?
C12 N2 Ag2 120.5(2) . . ?
C16 N2 Ag2 123.0(2) . . ?
C17 N3 C21 116.7(3) . . ?
C17 N3 Ag2 121.6(2) . . ?
C21 N3 Ag2 121.7(2) . . ?
C32 N4 C28 116.7(3) . . ?
C32 N4 Ag1 125.2(2) . 1_746 ?
C28 N4 Ag1 118.0(2) . 1_746 ?
H1WA O1W H1WB 113.0 . . ?
H2WA O2W H2WB 121.3 . . ?
H3WA O3W H3WB 128.3 . . ?
H4WA O4W H4WB 115.6 . . ?
H5WA O5W H5WB 109.9 . . ?
H6WB O6W H6WA 107.6 . . ?
H7WA O7W H7WB 108.3 . . ?
H8WB O8W H8WA 102.5 . . ?
Ag2 O9W H9WB 109.9 . . ?
Ag2 O9W H9WA 107.4 . . ?
H9WB O9W H9WA 101.9 . . ?

loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 -0.2(5) . . . . ?
C1 C2 C3 C4 0.2(5) . . . . ?
C1 C2 C3 C6 -179.6(3) . . . . ?
C2 C3 C4 C5 -0.4(5) . . . . ?
C6 C3 C4 C5 179.4(3) . . . . ?
C3 C4 C5 N1 0.6(5) . . . . ?
C2 C3 C6 C7 -27.6(5) . . . . ?
C4 C3 C6 C7 152.6(3) . . . . ?
C2 C3 C6 C11 151.7(3) . . . . ?
C4 C3 C6 C11 -28.1(5) . . . . ?
C11 C6 C7 C8 -0.8(5) . . . . ?
C3 C6 C7 C8 178.5(3) . . . . ?
C6 C7 C8 C9 0.6(5) . . . . ?
C7 C8 C9 C10 0.2(5) . . . . ?
C7 C8 C9 C14 -179.0(3) . . . . ?
C8 C9 C10 C11 -0.9(5) . . . . ?
C14 C9 C10 C11 178.4(3) . . . . ?
C9 C10 C11 C6 0.6(5) . . . . ?
C7 C6 C11 C10 0.2(5) . . . . ?
C3 C6 C11 C10 -179.1(3) . . . . ?
N2 C12 C13 C14 -0.5(6) . . . . ?
C12 C13 C14 C15 0.5(5) . . . . ?
C12 C13 C14 C9 -179.5(3) . . . . ?
C8 C9 C14 C15 -153.1(3) . . . . ?
C10 C9 C14 C15 27.6(5) . . . . ?
C8 C9 C14 C13 26.8(5) . . . . ?
C10 C9 C14 C13 -152.4(3) . . . . ?
C13 C14 C15 C16 0.0(5) . . . . ?
C9 C14 C15 C16 180.0(3) . . . . ?
C14 C15 C16 N2 -0.6(5) . . . . ?
N3 C17 C18 C19 -1.6(5) . . . . ?
C17 C18 C19 C20 0.7(5) . . . . ?
C17 C18 C19 C22 -179.4(3) . . . . ?
C18 C19 C20 C21 0.6(5) . . . . ?
C22 C19 C20 C21 -179.4(3) . . . . ?
C19 C20 C21 N3 -1.1(5) . . . . ?
C20 C19 C22 C27 -27.6(5) . . . . ?
C18 C19 C22 C27 152.5(3) . . . . ?
C20 C19 C22 C23 152.7(3) . . . . ?
C18 C19 C22 C23 -27.3(5) . . . . ?
C27 C22 C23 C24 -0.7(5) . . . . ?
C19 C22 C23 C24 179.0(3) . . . . ?
C22 C23 C24 C25 0.2(5) . . . . ?
C23 C24 C25 C26 0.3(5) . . . . ?
C23 C24 C25 C30 -178.7(3) . . . . ?
C24 C25 C26 C27 -0.3(5) . . . . ?
C30 C25 C26 C27 178.8(3) . . . . ?
C25 C26 C27 C22 -0.2(5) . . . . ?
C23 C22 C27 C26 0.7(5) . . . . ?
C19 C22 C27 C26 -179.0(3) . . . . ?
N4 C28 C29 C30 -0.4(5) . . . . ?
C28 C29 C30 C31 0.8(5) . . . . ?
C28 C29 C30 C25 -179.3(3) . . . . ?
C24 C25 C30 C31 -152.3(3) . . . . ?
C26 C25 C30 C31 28.6(5) . . . . ?
C24 C25 C30 C29 27.8(5) . . . . ?
C26 C25 C30 C29 -151.2(3) . . . . ?
C29 C30 C31 C32 -0.3(5) . . . . ?
C25 C30 C31 C32 179.8(3) . . . . ?
C30 C31 C32 N4 -0.7(5) . . . . ?
O2 C33 C34 C39 -2.2(4) . . . . ?
O1 C33 C34 C39 176.5(3) . . . . ?
O2 C33 C34 C35 178.2(3) . . . . ?
O1 C33 C34 C35 -3.0(4) . . . . ?
C39 C34 C35 C36 -0.7(5) . . . . ?
C33 C34 C35 C36 178.9(3) . . . . ?
C34 C35 C36 C37 1.1(5) . . . . ?
C35 C36 C37 C38 -0.8(5) . . . . ?
C36 C37 C38 C39 -0.1(5) . . . . ?
C36 C37 C38 C40 180.0(3) . . . . ?
C37 C38 C39 C34 0.5(4) . . . . ?
C40 C38 C39 C34 -179.5(3) . . . . ?
C35 C34 C39 C38 -0.1(4) . . . . ?
C33 C34 C39 C38 -179.7(3) . . . . ?
C37 C38 C40 O3 175.5(3) . . . . ?
C39 C38 C40 O3 -4.5(5) . . . . ?
C37 C38 C40 O4 -5.4(4) . . . . ?
C39 C38 C40 O4 174.7(3) . . . . ?
C2 C1 N1 C5 0.3(5) . . . . ?
C2 C1 N1 Ag1 -179.4(3) . . . . ?
C4 C5 N1 C1 -0.5(5) . . . . ?
C4 C5 N1 Ag1 179.2(3) . . . . ?
N4 Ag1 N1 C1 -154.4(12) 1_364 . . . ?
N4 Ag1 N1 C5 25.8(14) 1_364 . . . ?
C13 C12 N2 C16 -0.1(5) . . . . ?
C13 C12 N2 Ag2 179.8(3) . . . . ?
C15 C16 N2 C12 0.6(5) . . . . ?
C15 C16 N2 Ag2 -179.2(3) . . . . ?
N3 Ag2 N2 C12 -50.6(15) . . . . ?
O9W Ag2 N2 C12 158.5(3) . . . . ?
N3 Ag2 N2 C16 129.2(13) . . . . ?
O9W Ag2 N2 C16 -21.7(3) . . . . ?
C18 C17 N3 C21 1.0(5) . . . . ?
C18 C17 N3 Ag2 179.1(3) . . . . ?
C20 C21 N3 C17 0.3(5) . . . . ?
C20 C21 N3 Ag2 -177.7(2) . . . . ?
N2 Ag2 N3 C17 52.4(15) . . . . ?
O9W Ag2 N3 C17 -156.7(2) . . . . ?
N2 Ag2 N3 C21 -129.6(13) . . . . ?
O9W Ag2 N3 C21 21.2(3) . . . . ?
C31 C32 N4 C28 1.1(5) . . . . ?
C31 C32 N4 Ag1 -175.8(3) . . . 1_746 ?
C29 C28 N4 C32 -0.6(5) . . . . ?
C29 C28 N4 Ag1 176.5(3) . . . 1_746 ?

_diffrn_measured_fraction_theta_max 0.981
_diffrn_reflns_theta_full        26.00
_diffrn_measured_fraction_theta_full 0.981
_refine_diff_density_max         0.782
_refine_diff_density_min         -0.413
_refine_diff_density_rms         0.091
_database_code_depnum_ccdc_archive 'CCDC 973454'
