# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_1

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C75 H56 Ag2 O9.22 P4'
_chemical_formula_weight         1444.37

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           trigonal
_symmetry_space_group_name_H-M   R-3c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x-y, -y, -z+1/2'
'-x, -x+y, -z+1/2'
'y, x, -z+1/2'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x-y+2/3, -y+1/3, -z+5/6'
'-x+2/3, -x+y+1/3, -z+5/6'
'y+2/3, x+1/3, -z+5/6'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'x-y+1/3, -y+2/3, -z+7/6'
'-x+1/3, -x+y+2/3, -z+7/6'
'y+1/3, x+2/3, -z+7/6'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-x+y, y, z-1/2'
'x, x-y, z-1/2'
'-y, -x, z-1/2'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-x+y+2/3, y+1/3, z-1/6'
'x+2/3, x-y+1/3, z-1/6'
'-y+2/3, -x+1/3, z-1/6'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-x+y+1/3, y+2/3, z+1/6'
'x+1/3, x-y+2/3, z+1/6'
'-y+1/3, -x+2/3, z+1/6'

_cell_length_a                   36.6284(4)
_cell_length_b                   36.6284(4)
_cell_length_c                   27.5127(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_volume                     31966.8(7)
_cell_formula_units_Z            18
_cell_measurement_temperature    150(2)
_cell_measurement_reflns_used    15108
_cell_measurement_theta_min      0.09663
_cell_measurement_theta_max      1.00000

_exptl_crystal_description       rod
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    1.351
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             13208
_exptl_absorpt_coefficient_mu    5.715
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.4810
_exptl_absorpt_correction_T_max  0.8943
_exptl_absorpt_process_details   
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      150(2)
_diffrn_radiation_wavelength     1.54184
_diffrn_radiation_type           CuK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  ?
_diffrn_measurement_method       ?
_diffrn_detector_area_resol_mean ?
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            38595
_diffrn_reflns_av_R_equivalents  0.0515
_diffrn_reflns_av_unetlI/netI    0.0295
_diffrn_reflns_limit_h_min       -44
_diffrn_reflns_limit_h_max       42
_diffrn_reflns_limit_k_min       -45
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_theta_min         3.50
_diffrn_reflns_theta_max         74.01
_reflns_number_total             7131
_reflns_number_gt                5051
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. Weakly diffusely scattering 
solvated molecules located in the pore channels cannot be located so that 
solvent accessible voids of 220 ang^3 are left.
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.2000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         7131
_refine_ls_number_parameters     409
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1345
_refine_ls_R_factor_gt           0.1076
_refine_ls_wR_factor_ref         0.3455
_refine_ls_wR_factor_gt          0.3131
_refine_ls_goodness_of_fit_ref   1.357
_refine_ls_restrained_S_all      1.357
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.07568(2) 0.20254(2) 0.68607(3) 0.0741(3) Uani 1 1 d . . .
P1 P 0.11563(5) 0.25126(6) 0.75162(8) 0.0577(5) Uani 1 1 d . . .
P2 P 0.39632(5) 0.51993(5) 0.76650(8) 0.0568(5) Uani 1 1 d . . .
C1 C 0.3075(3) 0.3275(3) 0.7439(10) 0.162(10) Uani 1 1 d . . .
C2 C 0.2602(2) 0.3061(2) 0.7499(5) 0.087(3) Uani 1 1 d . . .
C3 C 0.2360(3) 0.2926(4) 0.7073(6) 0.103(4) Uani 1 1 d . . .
H3A H 0.2496 0.2948 0.6772 0.124 Uiso 1 1 calc R . .
C4 C 0.1930(3) 0.2763(3) 0.7078(4) 0.077(2) Uani 1 1 d . . .
H4A H 0.1775 0.2680 0.6783 0.093 Uiso 1 1 calc R . .
C5 C 0.1720(2) 0.2717(2) 0.7525(3) 0.0560(16) Uani 1 1 d . . .
C6 C 0.1954(2) 0.2831(3) 0.7938(4) 0.074(2) Uani 1 1 d . . .
H6A H 0.1822 0.2794 0.8246 0.088 Uiso 1 1 calc R . .
C7 C 0.2399(3) 0.3007(3) 0.7909(5) 0.083(3) Uani 1 1 d . . .
H7A H 0.2557 0.3088 0.8202 0.100 Uiso 1 1 calc R . .
C8 C 0.3287(2) 0.3747(3) 0.7498(5) 0.084(3) Uani 1 1 d . . .
C9 C 0.3404(4) 0.3994(3) 0.7094(6) 0.103(4) Uani 1 1 d . . .
H9A H 0.3357 0.3871 0.6780 0.123 Uiso 1 1 calc R . .
C10 C 0.3597(4) 0.4436(3) 0.7147(4) 0.088(3) Uani 1 1 d . . .
H10A H 0.3665 0.4603 0.6861 0.106 Uiso 1 1 calc R . .
C11 C 0.3690(2) 0.4633(2) 0.7583(3) 0.0602(19) Uani 1 1 d . . .
C12 C 0.3562(4) 0.4389(3) 0.7985(4) 0.103(4) Uani 1 1 d . . .
H12A H 0.3605 0.4518 0.8295 0.124 Uiso 1 1 calc R . .
C13 C 0.3367(5) 0.3954(3) 0.7953(6) 0.117(5) Uani 1 1 d . . .
H13A H 0.3287 0.3791 0.8242 0.141 Uiso 1 1 calc R . .
C14 C 0.1105(2) 0.2975(3) 0.7472(3) 0.0610(18) Uani 1 1 d . . .
C15 C 0.0701(3) 0.2926(3) 0.7471(5) 0.087(3) Uani 1 1 d . . .
H15A H 0.0460 0.2653 0.7507 0.104 Uiso 1 1 calc R . .
C16 C 0.0651(4) 0.3277(4) 0.7418(5) 0.099(4) Uani 1 1 d . . .
H16A H 0.0375 0.3240 0.7401 0.119 Uiso 1 1 calc R . .
C17 C 0.0987(3) 0.3668(3) 0.7389(4) 0.083(3) Uani 1 1 d . . .
H17A H 0.0948 0.3905 0.7357 0.100 Uiso 1 1 calc R . .
C18 C 0.1387(3) 0.3724(3) 0.7405(4) 0.082(3) Uani 1 1 d . . .
H18A H 0.1624 0.4001 0.7389 0.099 Uiso 1 1 calc R . .
C19 C 0.1446(2) 0.3388(2) 0.7443(3) 0.0648(19) Uani 1 1 d . . .
H19A H 0.1725 0.3433 0.7451 0.078 Uiso 1 1 calc R . .
C20 C 0.0990(2) 0.2330(2) 0.8130(3) 0.0588(17) Uani 1 1 d . . .
C21 C 0.0925(3) 0.1925(3) 0.8240(4) 0.079(3) Uani 1 1 d . . .
H21A H 0.0954 0.1755 0.8001 0.095 Uiso 1 1 calc R . .
C22 C 0.0812(4) 0.1786(4) 0.8729(5) 0.094(3) Uani 1 1 d . . .
H22A H 0.0765 0.1515 0.8815 0.113 Uiso 1 1 calc R . .
C23 C 0.0767(3) 0.2022(4) 0.9077(4) 0.084(3) Uani 1 1 d . . .
H23A H 0.0701 0.1920 0.9400 0.101 Uiso 1 1 calc R . .
C24 C 0.0819(3) 0.2410(4) 0.8963(4) 0.083(3) Uani 1 1 d . . .
H24A H 0.0777 0.2573 0.9202 0.099 Uiso 1 1 calc R . .
C25 C 0.0936(3) 0.2565(3) 0.8481(3) 0.070(2) Uani 1 1 d . . .
H25A H 0.0978 0.2836 0.8401 0.084 Uiso 1 1 calc R . .
C26 C 0.3692(3) 0.5381(3) 0.7255(5) 0.077(3) Uani 1 1 d . . .
C27 C 0.3697(3) 0.5343(3) 0.6766(5) 0.085(3) Uani 1 1 d . . .
H27A H 0.3856 0.5234 0.6617 0.102 Uiso 1 1 calc R . .
C28 C 0.3461(4) 0.5467(4) 0.6487(6) 0.112(5) Uani 1 1 d . . .
H28A H 0.3455 0.5432 0.6144 0.135 Uiso 1 1 calc R . .
C29 C 0.3249(3) 0.5629(4) 0.6672(7) 0.105(5) Uani 1 1 d . . .
H29A H 0.3097 0.5714 0.6465 0.126 Uiso 1 1 calc R . .
C30 C 0.3242(4) 0.5678(5) 0.7152(8) 0.129(6) Uani 1 1 d . . .
H30A H 0.3084 0.5795 0.7288 0.155 Uiso 1 1 calc R . .
C31 C 0.3475(3) 0.5554(3) 0.7460(6) 0.096(3) Uani 1 1 d . . .
H31 H 0.3479 0.5591 0.7802 0.116 Uiso 1 1 calc R . .
C32 C 0.4461(2) 0.5396(2) 0.7357(3) 0.0597(17) Uani 1 1 d . . .
C33 C 0.4616(3) 0.5149(4) 0.7212(5) 0.098(4) Uani 1 1 d . . .
H33A H 0.4452 0.4852 0.7253 0.118 Uiso 1 1 calc R . .
C34 C 0.5024(4) 0.5328(5) 0.6999(6) 0.122(5) Uani 1 1 d . . .
H34A H 0.5126 0.5151 0.6884 0.146 Uiso 1 1 calc R . .
C35 C 0.5266(3) 0.5755(5) 0.6961(6) 0.117(5) Uani 1 1 d . . .
H35A H 0.5553 0.5881 0.6864 0.140 Uiso 1 1 calc R . .
C36 C 0.5091(4) 0.6002(4) 0.7064(8) 0.148(8) Uani 1 1 d . . .
H36A H 0.5238 0.6294 0.6985 0.178 Uiso 1 1 calc R . .
C37 C 0.4695(4) 0.5821(3) 0.7285(8) 0.136(7) Uani 1 1 d . . .
H37A H 0.4586 0.5996 0.7387 0.163 Uiso 1 1 calc R . .
C38 C 0.0000 0.1435(3) 0.7500 0.063(3) Uani 1 2 d S . .
O1 O 0.0248(2) 0.1371(2) 0.7232(3) 0.102(3) Uani 1 1 d . . .
O2 O 0.0000 0.1768(3) 0.7500 0.078(2) Uani 1 2 d S . .
O2S O 0.9920(8) 0.0565(7) 0.6910(16) 0.40(2) Uani 1 1 d . . .
O3S O 0.9969(5) 0.3615(4) 0.7211(7) 0.192(8) Uani 1 1 d . . .
O1S O 0.0000 0.0000 0.7500 0.16(2) Uani 0.60 6 d SP . .
O5S O 0.1436(15) 0.1595(10) 0.693(2) 0.66(6) Uani 1 1 d . . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O1 2.407(7) . ?
Ag1 P1 2.443(2) . ?
Ag1 P2 2.457(2) 29_455 ?
P1 C14 1.799(8) . ?
P1 C20 1.805(8) . ?
P1 C5 1.812(7) . ?
P2 C32 1.804(8) . ?
P2 C11 1.811(7) . ?
P2 C26 1.834(9) . ?
P2 Ag1 2.457(2) 35 ?
C1 C1 1.31(2) 6_556 ?
C1 C8 1.510(12) . ?
C1 C2 1.512(11) . ?
C2 C7 1.308(17) . ?
C2 C3 1.40(2) . ?
C3 C4 1.376(14) . ?
C3 H3A 0.9500 . ?
C4 C5 1.415(13) . ?
C4 H4A 0.9500 . ?
C5 C6 1.357(13) . ?
C6 C7 1.425(11) . ?
C6 H6A 0.9500 . ?
C7 H7A 0.9500 . ?
C8 C9 1.359(19) . ?
C8 C13 1.42(2) . ?
C9 C10 1.413(13) . ?
C9 H9A 0.9500 . ?
C10 C11 1.354(14) . ?
C10 H10A 0.9500 . ?
C11 C12 1.349(13) . ?
C12 C13 1.386(15) . ?
C12 H12A 0.9500 . ?
C13 H13A 0.9500 . ?
C14 C15 1.400(11) . ?
C14 C19 1.401(11) . ?
C15 C16 1.394(15) . ?
C15 H15A 0.9500 . ?
C16 C17 1.345(15) . ?
C16 H16A 0.9500 . ?
C17 C18 1.377(14) . ?
C17 H17A 0.9500 . ?
C18 C19 1.358(12) . ?
C18 H18A 0.9500 . ?
C19 H19A 0.9500 . ?
C20 C25 1.375(13) . ?
C20 C21 1.410(12) . ?
C21 C22 1.424(16) . ?
C21 H21A 0.9500 . ?
C22 C23 1.353(18) . ?
C22 H22A 0.9500 . ?
C23 C24 1.373(16) . ?
C23 H23A 0.9500 . ?
C24 C25 1.420(14) . ?
C24 H24A 0.9500 . ?
C25 H25A 0.9500 . ?
C26 C27 1.355(16) . ?
C26 C31 1.360(16) . ?
C27 C28 1.391(16) . ?
C27 H27A 0.9500 . ?
C28 C29 1.29(2) . ?
C28 H28A 0.9500 . ?
C29 C30 1.33(2) . ?
C29 H29A 0.9500 . ?
C30 C31 1.429(18) . ?
C30 H30A 0.9500 . ?
C31 H31 0.9500 . ?
C32 C33 1.345(14) . ?
C32 C37 1.366(13) . ?
C33 C34 1.424(15) . ?
C33 H33A 0.9500 . ?
C34 C35 1.36(2) . ?
C34 H34A 0.9500 . ?
C35 C36 1.38(2) . ?
C35 H35A 0.9500 . ?
C36 C37 1.396(17) . ?
C36 H36A 0.9500 . ?
C37 H37A 0.9500 . ?
C38 O2 1.221(15) . ?
C38 O1 1.279(10) 5_556 ?
C38 O1 1.279(10) . ?
O3S O3S 1.60(4) 5_766 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Ag1 P1 107.3(2) . . ?
O1 Ag1 P2 115.0(2) . 29_455 ?
P1 Ag1 P2 135.31(7) . 29_455 ?
C14 P1 C20 103.8(4) . . ?
C14 P1 C5 104.2(3) . . ?
C20 P1 C5 104.1(4) . . ?
C14 P1 Ag1 109.4(3) . . ?
C20 P1 Ag1 116.8(3) . . ?
C5 P1 Ag1 117.1(3) . . ?
C32 P2 C11 105.6(4) . . ?
C32 P2 C26 100.9(4) . . ?
C11 P2 C26 104.5(4) . . ?
C32 P2 Ag1 109.4(3) . 35 ?
C11 P2 Ag1 112.0(3) . 35 ?
C26 P2 Ag1 122.9(4) . 35 ?
C1 C1 C8 120.1(11) 6_556 . ?
C1 C1 C2 119.9(11) 6_556 . ?
C8 C1 C2 112.4(8) . . ?
C7 C2 C3 117.1(8) . . ?
C7 C2 C1 126.1(15) . . ?
C3 C2 C1 116.7(14) . . ?
C4 C3 C2 121.8(11) . . ?
C4 C3 H3A 119.1 . . ?
C2 C3 H3A 119.1 . . ?
C3 C4 C5 119.7(11) . . ?
C3 C4 H4A 120.1 . . ?
C5 C4 H4A 120.1 . . ?
C6 C5 C4 118.1(8) . . ?
C6 C5 P1 123.5(6) . . ?
C4 C5 P1 118.4(7) . . ?
C5 C6 C7 119.6(10) . . ?
C5 C6 H6A 120.2 . . ?
C7 C6 H6A 120.2 . . ?
C2 C7 C6 123.5(10) . . ?
C2 C7 H7A 118.2 . . ?
C6 C7 H7A 118.2 . . ?
C9 C8 C13 117.1(8) . . ?
C9 C8 C1 119.0(14) . . ?
C13 C8 C1 123.9(14) . . ?
C8 C9 C10 119.2(12) . . ?
C8 C9 H9A 120.4 . . ?
C10 C9 H9A 120.4 . . ?
C11 C10 C9 123.4(11) . . ?
C11 C10 H10A 118.3 . . ?
C9 C10 H10A 118.3 . . ?
C12 C11 C10 117.5(8) . . ?
C12 C11 P2 117.8(8) . . ?
C10 C11 P2 124.7(7) . . ?
C11 C12 C13 121.1(11) . . ?
C11 C12 H12A 119.4 . . ?
C13 C12 H12A 119.4 . . ?
C12 C13 C8 121.4(11) . . ?
C12 C13 H13A 119.3 . . ?
C8 C13 H13A 119.3 . . ?
C15 C14 C19 117.0(8) . . ?
C15 C14 P1 118.7(7) . . ?
C19 C14 P1 124.3(6) . . ?
C16 C15 C14 119.9(9) . . ?
C16 C15 H15A 120.0 . . ?
C14 C15 H15A 120.0 . . ?
C17 C16 C15 121.2(9) . . ?
C17 C16 H16A 119.4 . . ?
C15 C16 H16A 119.4 . . ?
C16 C17 C18 119.7(9) . . ?
C16 C17 H17A 120.2 . . ?
C18 C17 H17A 120.2 . . ?
C19 C18 C17 120.6(9) . . ?
C19 C18 H18A 119.7 . . ?
C17 C18 H18A 119.7 . . ?
C18 C19 C14 121.5(8) . . ?
C18 C19 H19A 119.2 . . ?
C14 C19 H19A 119.2 . . ?
C25 C20 C21 120.3(8) . . ?
C25 C20 P1 123.6(6) . . ?
C21 C20 P1 116.1(7) . . ?
C20 C21 C22 116.6(11) . . ?
C20 C21 H21A 121.7 . . ?
C22 C21 H21A 121.7 . . ?
C23 C22 C21 123.0(10) . . ?
C23 C22 H22A 118.5 . . ?
C21 C22 H22A 118.5 . . ?
C22 C23 C24 120.2(10) . . ?
C22 C23 H23A 119.9 . . ?
C24 C23 H23A 119.9 . . ?
C23 C24 C25 119.0(11) . . ?
C23 C24 H24A 120.5 . . ?
C25 C24 H24A 120.5 . . ?
C20 C25 C24 121.0(9) . . ?
C20 C25 H25A 119.5 . . ?
C24 C25 H25A 119.5 . . ?
C27 C26 C31 119.9(11) . . ?
C27 C26 P2 122.5(8) . . ?
C31 C26 P2 117.6(10) . . ?
C26 C27 C28 118.3(13) . . ?
C26 C27 H27A 120.9 . . ?
C28 C27 H27A 120.9 . . ?
C29 C28 C27 123.1(16) . . ?
C29 C28 H28A 118.5 . . ?
C27 C28 H28A 118.5 . . ?
C28 C29 C30 120.4(13) . . ?
C28 C29 H29A 119.8 . . ?
C30 C29 H29A 119.8 . . ?
C29 C30 C31 119.4(15) . . ?
C29 C30 H30A 120.3 . . ?
C31 C30 H30A 120.3 . . ?
C26 C31 C30 118.9(15) . . ?
C26 C31 H31 120.5 . . ?
C30 C31 H31 120.5 . . ?
C33 C32 C37 119.4(9) . . ?
C33 C32 P2 123.5(7) . . ?
C37 C32 P2 117.1(8) . . ?
C32 C33 C34 120.7(11) . . ?
C32 C33 H33A 119.7 . . ?
C34 C33 H33A 119.7 . . ?
C35 C34 C33 119.4(14) . . ?
C35 C34 H34A 120.3 . . ?
C33 C34 H34A 120.3 . . ?
C34 C35 C36 119.3(10) . . ?
C34 C35 H35A 120.3 . . ?
C36 C35 H35A 120.3 . . ?
C35 C36 C37 119.5(13) . . ?
C35 C36 H36A 120.3 . . ?
C37 C36 H36A 120.3 . . ?
C32 C37 C36 121.0(13) . . ?
C32 C37 H37A 119.5 . . ?
C36 C37 H37A 119.5 . . ?
O2 C38 O1 122.6(6) . 5_556 ?
O2 C38 O1 122.6(6) . . ?
O1 C38 O1 114.9(12) 5_556 . ?
C38 O1 Ag1 109.2(6) . . ?

_diffrn_measured_fraction_theta_max 0.987
_diffrn_reflns_theta_full        74.01
_diffrn_measured_fraction_theta_full 0.987
_refine_diff_density_max         2.881
_refine_diff_density_min         -0.814
_refine_diff_density_rms         0.191
_exptl_crystal_recrystallization_method 
'Re-crystallisation from solvent: toluene-acetonitrile'
_exptl_crystal_preparation       Luminescent
_database_code_depnum_ccdc_archive 'CCDC 1006156'
