# Electronic Supplementary Material (ESI) for Dalton Transactions.
# This journal is © The Royal Society of Chemistry 2014

#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
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#  data retrieval see:
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#  from this site to visualise CIF-encoded structures and 
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data_Compound-1

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C72 H48 Ag6 Cl2 N24 O42 Si W12'
_chemical_formula_weight         4873.75

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   P2(1)/n

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'

_cell_length_a                   13.819(4)
_cell_length_b                   13.641(4)
_cell_length_c                   27.456(7)
_cell_angle_alpha                90.00
_cell_angle_beta                 91.330(5)
_cell_angle_gamma                90.00
_cell_volume                     5174(2)
_cell_formula_units_Z            2
_cell_measurement_temperature    293(2)
_cell_measurement_reflns_used    11057
_cell_measurement_theta_min      2.6415
_cell_measurement_theta_max      27.4972

_exptl_crystal_description       block
_exptl_crystal_colour            yellow
_exptl_crystal_size_max          0.2000
_exptl_crystal_size_mid          0.2000
_exptl_crystal_size_min          0.1500
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.128
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             4404
_exptl_absorpt_coefficient_mu    14.538
_exptl_absorpt_correction_type   Multi-scan
_exptl_absorpt_correction_T_min  0.8306
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      293(2)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  'Mercury70 (2x2 bin mode)'
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_detector_area_resol_mean 14.6306
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            57642
_diffrn_reflns_av_R_equivalents  0.0404
_diffrn_reflns_av_unetI/netI     0.0351
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_theta_min         2.59
_diffrn_reflns_theta_max         27.49
_reflns_number_total             11832
_reflns_number_gt                10499
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0369P)²+184.1030P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         11832
_refine_ls_number_parameters     735
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.0667
_refine_ls_R_factor_gt           0.0590
_refine_ls_wR_factor_ref         0.1336
_refine_ls_wR_factor_gt          0.1289
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_restrained_S_all      1.023
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.02860(8) 0.13615(11) 0.38912(4) 0.0583(3) Uani 1 1 d . . .
Ag2 Ag 0.54168(8) 0.15573(12) -0.02400(4) 0.0588(3) Uani 1 1 d . . .
Ag3 Ag 0.06472(8) 0.06611(12) -0.44195(4) 0.0609(3) Uani 1 1 d . . .
Cl1 Cl -0.0174(3) 0.1270(3) 0.47637(12) 0.0529(9) Uani 1 1 d . . .
C1 C 0.2509(10) 0.1349(11) 0.3764(5) 0.047(3) Uani 1 1 d . . .
H1A H 0.2486 0.1313 0.4102 0.056 Uiso 1 1 calc R . .
C2 C 0.3407(10) 0.1329(11) 0.3552(5) 0.042(3) Uani 1 1 d . . .
H2A H 0.3970 0.1280 0.3743 0.050 Uiso 1 1 calc R . .
C3 C 0.3450(9) 0.1385(10) 0.3046(5) 0.038(3) Uani 1 1 d . . .
C4 C 0.2582(10) 0.1459(12) 0.2778(5) 0.049(4) Uani 1 1 d . . .
H4A H 0.2576 0.1491 0.2439 0.059 Uiso 1 1 calc R . .
C5 C 0.1731(11) 0.1483(13) 0.3033(6) 0.055(4) Uani 1 1 d . . .
H5A H 0.1154 0.1552 0.2855 0.066 Uiso 1 1 calc R . .
C6 C 0.8682(11) 0.1315(16) 0.3049(5) 0.064(5) Uani 1 1 d . . .
H6A H 0.9241 0.1277 0.2868 0.077 Uiso 1 1 calc R . .
C7 C 0.7798(11) 0.1286(15) 0.2801(5) 0.061(5) Uani 1 1 d . . .
H7A H 0.7766 0.1191 0.2466 0.073 Uiso 1 1 calc R . .
C8 C 0.6962(8) 0.1401(12) 0.3065(4) 0.042(3) Uani 1 1 d . . .
C9 C 0.7053(10) 0.1496(12) 0.3556(5) 0.046(3) Uani 1 1 d . . .
H9A H 0.6500 0.1543 0.3742 0.055 Uiso 1 1 calc R . .
C10 C 0.7959(10) 0.1525(12) 0.3785(4) 0.045(3) Uani 1 1 d . . .
H10A H 0.8003 0.1637 0.4119 0.054 Uiso 1 1 calc R . .
C11 C 0.4454(9) 0.1606(15) 0.0769(5) 0.060(5) Uani 1 1 d . . .
H11A H 0.3889 0.1608 0.0578 0.072 Uiso 1 1 calc R . .
C12 C 0.4371(11) 0.1554(14) 0.1262(5) 0.056(4) Uani 1 1 d . . .
H12A H 0.3765 0.1523 0.1401 0.068 Uiso 1 1 calc R . .
C13 C 0.5206(8) 0.1546(11) 0.1554(5) 0.039(3) Uani 1 1 d . . .
C14 C 0.6068(9) 0.1638(15) 0.1324(5) 0.058(5) Uani 1 1 d . . .
H14A H 0.6644 0.1653 0.1506 0.069 Uiso 1 1 calc R . .
C15 C 0.6085(11) 0.1707(16) 0.0819(5) 0.064(5) Uani 1 1 d . . .
H15A H 0.6676 0.1793 0.0670 0.077 Uiso 1 1 calc R . .
C16 C 0.4386(9) 0.1383(10) 0.2793(4) 0.036(3) Uani 1 1 d . . .
C17 C 0.6006(9) 0.1394(12) 0.2799(5) 0.042(3) Uani 1 1 d . . .
C18 C 0.5181(9) 0.1472(11) 0.2085(5) 0.041(3) Uani 1 1 d . . .
C19 C 0.6387(9) 0.1047(12) -0.1232(4) 0.047(4) Uani 1 1 d . . .
H19A H 0.6944 0.0939 -0.1043 0.056 Uiso 1 1 calc R . .
C20 C 0.6463(9) 0.1050(12) -0.1725(4) 0.044(3) Uani 1 1 d . . .
H20A H 0.7069 0.1011 -0.1864 0.053 Uiso 1 1 calc R . .
C21 C 0.5633(10) 0.1112(11) -0.2022(5) 0.042(3) Uani 1 1 d . . .
C22 C 0.4743(10) 0.1236(13) -0.1789(5) 0.051(4) Uani 1 1 d . . .
H22A H 0.4168 0.1297 -0.1969 0.061 Uiso 1 1 calc R . .
C23 C 0.4750(10) 0.1264(13) -0.1287(5) 0.051(4) Uani 1 1 d . . .
H23A H 0.4159 0.1337 -0.1135 0.062 Uiso 1 1 calc R . .
C24 C 0.8345(10) 0.0899(11) -0.4231(5) 0.045(3) Uani 1 1 d . . .
H24A H 0.8354 0.0859 -0.4569 0.054 Uiso 1 1 calc R . .
C25 C 0.7461(9) 0.0983(11) -0.4006(5) 0.040(3) Uani 1 1 d . . .
H25A H 0.6892 0.0994 -0.4193 0.049 Uiso 1 1 calc R . .
C26 C 0.7425(9) 0.1049(9) -0.3511(4) 0.034(3) Uani 1 1 d . . .
C27 C 0.8296(9) 0.1032(11) -0.3240(5) 0.044(3) Uani 1 1 d . . .
H27A H 0.8300 0.1067 -0.2902 0.052 Uiso 1 1 calc R . .
C28 C 0.9149(11) 0.0963(13) -0.3491(5) 0.051(4) Uani 1 1 d . . .
H28A H 0.9727 0.0981 -0.3311 0.061 Uiso 1 1 calc R . .
C29 C 0.2184(10) 0.1090(14) -0.3583(6) 0.057(4) Uani 1 1 d . . .
H29A H 0.1615 0.1199 -0.3418 0.068 Uiso 1 1 calc R . .
C30 C 0.3053(10) 0.1185(14) -0.3334(5) 0.054(4) Uani 1 1 d . . .
H30A H 0.3061 0.1357 -0.3006 0.064 Uiso 1 1 calc R . .
C31 C 0.3906(9) 0.1031(11) -0.3565(5) 0.039(3) Uani 1 1 d . . .
C32 C 0.3851(10) 0.0786(12) -0.4062(5) 0.046(3) Uani 1 1 d . . .
H32A H 0.4413 0.0685 -0.4235 0.056 Uiso 1 1 calc R . .
C33 C 0.2979(10) 0.0699(11) -0.4285(5) 0.043(3) Uani 1 1 d . . .
H33A H 0.2958 0.0532 -0.4614 0.051 Uiso 1 1 calc R . .
C34 C 0.4855(9) 0.1058(10) -0.3289(4) 0.037(3) Uani 1 1 d . . .
C35 C 0.5645(9) 0.1109(10) -0.2558(4) 0.038(3) Uani 1 1 d . . .
C36 C 0.6491(9) 0.1084(10) -0.3258(4) 0.037(3) Uani 1 1 d . . .
N1 N 0.1678(9) 0.1415(9) 0.3514(4) 0.047(3) Uani 1 1 d . . .
N2 N 0.8778(8) 0.1395(11) 0.3535(4) 0.049(3) Uani 1 1 d . . .
N3 N 0.5297(9) 0.1655(11) 0.0546(4) 0.051(3) Uani 1 1 d . . .
N4 N 0.4335(8) 0.1478(9) 0.2306(4) 0.042(3) Uani 1 1 d . . .
N5 N 0.5207(8) 0.1352(9) 0.3063(4) 0.040(2) Uani 1 1 d . . .
N6 N 0.6033(7) 0.1426(11) 0.2323(4) 0.049(3) Uani 1 1 d . . .
N7 N 0.5543(9) 0.1193(10) -0.1005(4) 0.045(3) Uani 1 1 d . . .
N8 N 0.9202(8) 0.0872(10) -0.3973(4) 0.050(3) Uani 1 1 d . . .
N9 N 0.2124(8) 0.0843(10) -0.4058(4) 0.049(3) Uani 1 1 d . . .
N10 N 0.4800(8) 0.1098(9) -0.2803(4) 0.042(3) Uani 1 1 d . . .
N11 N 0.6516(7) 0.1106(8) -0.2774(4) 0.037(2) Uani 1 1 d . . .
N12 N 0.5673(7) 0.1064(9) -0.3533(3) 0.037(2) Uani 1 1 d . . .
Si1 Si 0.0000 0.0000 0.0000 0.0223(8) Uani 1 2 d S . .
W1 W 0.11140(4) -0.08763(4) -0.10639(2) 0.04400(14) Uani 1 1 d . . .
W2 W 0.16852(4) -0.19297(5) 0.008225(19) 0.04413(15) Uani 1 1 d . . .
W3 W 0.04948(4) -0.11311(5) 0.11342(2) 0.04469(15) Uani 1 1 d . . .
W4 W 0.13794(4) 0.12483(5) 0.09058(2) 0.04283(14) Uani 1 1 d . . .
W5 W 0.07804(5) 0.24298(4) -0.02091(2) 0.04462(15) Uani 1 1 d . . .
W6 W 0.24601(4) 0.04814(5) -0.018738(19) 0.04387(15) Uani 1 1 d . . .
O1 O 0.1633(8) -0.1261(9) -0.1578(4) 0.054(3) Uani 1 1 d . . .
OW1 O 1.0645(19) 0.108(2) -0.2490(10) 0.076(7) Uiso 0.50 1 d P . .
O2 O 0.0087(9) 0.1457(9) 0.1129(7) 0.108(7) Uani 1 1 d . . .
OW2 O 0.238(2) 0.094(2) -0.1860(11) 0.090(9) Uiso 0.50 1 d P . .
O3 O 0.0547(8) 0.0316(10) -0.1286(8) 0.118(7) Uani 1 1 d . . .
O4 O 0.2098(12) -0.0027(10) -0.0804(4) 0.090(5) Uani 1 1 d . . .
O5 O 0.1522(12) -0.1818(10) -0.0616(4) 0.088(5) Uani 1 1 d . . .
O6 O 0.2505(9) -0.2827(9) 0.0115(4) 0.069(4) Uani 1 1 d . . .
O7 O 0.0516(9) -0.2659(13) 0.0061(4) 0.091(5) Uani 1 1 d . . .
O8 O 0.1504(8) -0.1694(13) 0.0745(4) 0.085(5) Uani 1 1 d . . .
O9 O 0.2502(13) -0.0845(11) 0.0062(4) 0.092(5) Uani 1 1 d . . .
O10 O -0.0345(8) -0.2040(13) 0.0857(4) 0.086(5) Uani 1 1 d . . .
O11 O 0.0742(8) -0.1629(9) 0.1681(3) 0.056(3) Uani 1 1 d . . .
O12 O 0.1318(8) -0.0015(10) 0.1159(8) 0.116(7) Uani 1 1 d . . .
O13 O 0.2011(8) 0.1819(9) 0.1338(4) 0.057(3) Uani 1 1 d . . .
O14 O 0.2354(10) 0.0822(11) 0.0487(4) 0.082(4) Uani 1 1 d . . .
O15 O 0.1083(10) 0.2283(11) 0.0451(4) 0.082(4) Uani 1 1 d . . .
O16 O 0.1195(11) 0.3559(9) -0.0303(5) 0.082(4) Uani 1 1 d . . .
O17 O 0.3631(8) 0.0713(12) -0.0266(4) 0.077(4) Uani 1 1 d . . .
O18 O 0.1905(11) 0.1674(12) -0.0353(4) 0.092(5) Uani 1 1 d . . .
O19 O -0.1004(10) 0.0421(11) 0.0198(5) 0.026(3) Uani 0.50 1 d P . .
O20 O -0.0163(10) -0.0193(12) -0.0609(5) 0.028(3) Uani 0.50 1 d P . .
O21 O 0.0846(11) 0.0747(13) 0.0074(5) 0.032(4) Uani 0.50 1 d P . .
O22 O 0.0260(10) -0.1042(13) 0.0246(6) 0.032(4) Uani 0.50 1 d P . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.207(11) . ?
Ag1 N2 2.282(11) 1_455 ?
Ag1 Cl1 2.495(4) . ?
Ag2 N7 2.168(11) . ?
Ag2 N3 2.171(10) . ?
Ag3 N9 2.262(11) . ?
Ag3 N8 2.385(11) 1_455 ?
Ag3 Cl1 2.625(4) 1_554 ?
Ag3 Cl1 2.869(5) 3 ?
Cl1 Ag3 2.625(4) 1_556 ?
Cl1 Ag3 2.869(5) 3 ?
C1 N1 1.326(18) . ?
C1 C2 1.383(18) . ?
C2 C3 1.394(17) . ?
C3 C4 1.396(18) . ?
C3 C16 1.482(16) . ?
C4 C5 1.385(19) . ?
C5 N1 1.327(19) . ?
C6 N2 1.343(18) . ?
C6 C7 1.38(2) . ?
C7 C8 1.387(18) . ?
C8 C9 1.359(18) . ?
C8 C17 1.494(17) . ?
C9 C10 1.389(19) . ?
C10 N2 1.349(16) . ?
C11 N3 1.331(17) . ?
C11 C12 1.36(2) . ?
C12 C13 1.389(18) . ?
C13 C14 1.367(17) . ?
C13 C18 1.461(17) . ?
C14 C15 1.391(19) . ?
C15 N3 1.310(18) . ?
C16 N4 1.342(16) . ?
C16 N5 1.343(16) . ?
C17 N6 1.309(16) . ?
C17 N5 1.337(15) . ?
C18 N4 1.330(15) . ?
C18 N6 1.334(16) . ?
C19 N7 1.351(17) . ?
C19 C20 1.358(17) . ?
C20 C21 1.395(18) . ?
C21 C22 1.409(18) . ?
C21 C35 1.472(17) . ?
C22 C23 1.379(18) . ?
C23 N7 1.332(17) . ?
C24 N8 1.365(17) . ?
C24 C25 1.386(18) . ?
C25 C26 1.363(17) . ?
C26 C27 1.400(17) . ?
C26 C36 1.482(17) . ?
C27 C28 1.382(19) . ?
C28 N8 1.334(18) . ?
C29 N9 1.346(19) . ?
C29 C30 1.374(19) . ?
C30 C31 1.367(18) . ?
C31 C32 1.406(18) . ?
C31 C34 1.499(16) . ?
C32 C33 1.345(18) . ?
C33 N9 1.363(17) . ?
C34 N12 1.328(15) . ?
C34 N10 1.338(15) . ?
C35 N10 1.334(16) . ?
C35 N11 1.355(16) . ?
C36 N11 1.326(15) . ?
C36 N12 1.344(16) . ?
N2 Ag1 2.282(11) 1_655 ?
N8 Ag3 2.385(11) 1_655 ?
Si1 O21 1.560(16) 3 ?
Si1 O21 1.560(16) . ?
Si1 O19 1.608(14) . ?
Si1 O19 1.608(14) 3 ?
Si1 O22 1.611(17) 3 ?
Si1 O22 1.611(17) . ?
Si1 O20 1.703(14) 3 ?
Si1 O20 1.703(14) . ?
W1 O1 1.683(9) . ?
W1 O2 1.845(13) 3 ?
W1 O5 1.858(13) . ?
W1 O3 1.900(14) . ?
W1 O4 1.911(13) . ?
W1 O20 2.376(14) . ?
W1 O19 2.466(14) 3 ?
W2 O6 1.669(11) . ?
W2 O9 1.863(15) . ?
W2 O8 1.870(10) . ?
W2 O7 1.897(14) . ?
W2 O5 1.930(11) . ?
W2 O22 2.364(15) . ?
W2 O19 2.383(14) 3 ?
W3 O11 1.675(10) . ?
W3 O10 1.849(13) . ?
W3 O3 1.874(14) 3 ?
W3 O12 1.900(14) . ?
W3 O8 1.936(12) . ?
W3 O20 2.349(16) 3 ?
W3 O22 2.456(15) . ?
W4 O13 1.652(10) . ?
W4 O12 1.862(14) . ?
W4 O14 1.883(11) . ?
W4 O2 1.922(11) . ?
W4 O15 1.922(13) . ?
W4 O20 2.345(15) 3 ?
W4 O21 2.480(15) . ?
W5 O16 1.666(11) . ?
W5 O15 1.862(11) . ?
W5 O7 1.872(12) 3 ?
W5 O18 1.913(13) . ?
W5 O10 1.940(11) 3 ?
W5 O22 2.378(17) 3 ?
W5 O21 2.425(17) . ?
W6 O17 1.668(10) . ?
W6 O18 1.851(15) . ?
W6 O4 1.888(12) . ?
W6 O14 1.918(11) . ?
W6 O9 1.934(14) . ?
W6 O19 2.359(16) 3 ?
W6 O21 2.387(16) . ?
O2 W1 1.845(13) 3 ?
O3 W3 1.874(14) 3 ?
O7 W5 1.872(12) 3 ?
O10 W5 1.940(11) 3 ?
O19 O21 1.77(2) 3 ?
O19 W6 2.359(16) 3 ?
O19 W2 2.383(14) 3 ?
O19 W1 2.466(14) 3 ?
O20 W4 2.345(15) 3 ?
O20 W3 2.349(16) 3 ?
O21 O19 1.77(2) 3 ?
O21 O22 1.79(2) 3 ?
O22 O21 1.79(2) 3 ?
O22 W5 2.378(17) 3 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N2 126.6(4) . 1_455 ?
N1 Ag1 Cl1 134.1(3) . . ?
N2 Ag1 Cl1 99.3(3) 1_455 . ?
N7 Ag2 N3 170.3(5) . . ?
N9 Ag3 N8 121.3(4) . 1_455 ?
N9 Ag3 Cl1 135.1(3) . 1_554 ?
N8 Ag3 Cl1 92.9(3) 1_455 1_554 ?
N9 Ag3 Cl1 116.2(4) . 3 ?
N8 Ag3 Cl1 95.3(3) 1_455 3 ?
Cl1 Ag3 Cl1 85.33(14) 1_554 3 ?
Ag1 Cl1 Ag3 136.17(17) . 1_556 ?
Ag1 Cl1 Ag3 77.93(11) . 3 ?
Ag3 Cl1 Ag3 94.67(14) 1_556 3 ?
N1 C1 C2 124.0(13) . . ?
C1 C2 C3 118.5(13) . . ?
C2 C3 C4 118.2(11) . . ?
C2 C3 C16 121.7(12) . . ?
C4 C3 C16 120.0(11) . . ?
C5 C4 C3 117.6(13) . . ?
N1 C5 C4 124.8(14) . . ?
N2 C6 C7 123.7(13) . . ?
C6 C7 C8 118.5(13) . . ?
C9 C8 C7 118.0(12) . . ?
C9 C8 C17 123.1(11) . . ?
C7 C8 C17 118.8(11) . . ?
C8 C9 C10 120.9(12) . . ?
N2 C10 C9 121.6(12) . . ?
N3 C11 C12 123.7(13) . . ?
C11 C12 C13 119.1(13) . . ?
C14 C13 C12 117.0(12) . . ?
C14 C13 C18 120.5(11) . . ?
C12 C13 C18 122.5(11) . . ?
C13 C14 C15 120.1(12) . . ?
N3 C15 C14 122.3(13) . . ?
N4 C16 N5 125.3(11) . . ?
N4 C16 C3 116.2(11) . . ?
N5 C16 C3 118.4(11) . . ?
N6 C17 N5 125.9(12) . . ?
N6 C17 C8 116.3(10) . . ?
N5 C17 C8 117.8(11) . . ?
N4 C18 N6 123.5(12) . . ?
N4 C18 C13 119.7(11) . . ?
N6 C18 C13 116.8(10) . . ?
N7 C19 C20 123.2(12) . . ?
C19 C20 C21 120.1(12) . . ?
C20 C21 C22 117.1(12) . . ?
C20 C21 C35 123.8(12) . . ?
C22 C21 C35 119.0(12) . . ?
C23 C22 C21 118.2(12) . . ?
N7 C23 C22 124.5(13) . . ?
N8 C24 C25 122.3(12) . . ?
C26 C25 C24 120.1(12) . . ?
C25 C26 C27 118.5(12) . . ?
C25 C26 C36 121.5(11) . . ?
C27 C26 C36 119.9(11) . . ?
C28 C27 C26 117.9(12) . . ?
N8 C28 C27 124.6(13) . . ?
N9 C29 C30 122.6(13) . . ?
C31 C30 C29 120.6(13) . . ?
C30 C31 C32 117.2(12) . . ?
C30 C31 C34 121.1(11) . . ?
C32 C31 C34 121.6(11) . . ?
C33 C32 C31 119.5(12) . . ?
C32 C33 N9 123.7(12) . . ?
N12 C34 N10 124.8(11) . . ?
N12 C34 C31 119.4(10) . . ?
N10 C34 C31 115.8(11) . . ?
N10 C35 N11 123.7(11) . . ?
N10 C35 C21 118.3(12) . . ?
N11 C35 C21 118.0(11) . . ?
N11 C36 N12 124.3(11) . . ?
N11 C36 C26 117.9(11) . . ?
N12 C36 C26 117.8(10) . . ?
C1 N1 C5 116.9(12) . . ?
C1 N1 Ag1 120.6(9) . . ?
C5 N1 Ag1 122.5(10) . . ?
C6 N2 C10 116.9(12) . . ?
C6 N2 Ag1 119.5(9) . 1_655 ?
C10 N2 Ag1 123.6(9) . 1_655 ?
C15 N3 C11 117.6(12) . . ?
C15 N3 Ag2 119.4(10) . . ?
C11 N3 Ag2 122.9(9) . . ?
C18 N4 C16 115.3(11) . . ?
C17 N5 C16 113.4(11) . . ?
C17 N6 C18 116.5(11) . . ?
C23 N7 C19 116.7(11) . . ?
C23 N7 Ag2 117.6(9) . . ?
C19 N7 Ag2 124.9(9) . . ?
C28 N8 C24 116.4(12) . . ?
C28 N8 Ag3 126.0(9) . 1_655 ?
C24 N8 Ag3 117.7(9) . 1_655 ?
C29 N9 C33 116.4(11) . . ?
C29 N9 Ag3 119.1(9) . . ?
C33 N9 Ag3 124.5(9) . . ?
C35 N10 C34 115.7(11) . . ?
C36 N11 C35 115.8(11) . . ?
C34 N12 C36 115.6(10) . . ?
O21 Si1 O21 180.0(16) 3 . ?
O21 Si1 O19 68.1(8) 3 . ?
O21 Si1 O19 111.9(8) . . ?
O21 Si1 O19 111.9(8) 3 3 ?
O21 Si1 O19 68.1(8) . 3 ?
O19 Si1 O19 180.0(14) . 3 ?
O21 Si1 O22 111.3(8) 3 3 ?
O21 Si1 O22 68.7(8) . 3 ?
O19 Si1 O22 68.9(7) . 3 ?
O19 Si1 O22 111.1(7) 3 3 ?
O21 Si1 O22 68.7(8) 3 . ?
O21 Si1 O22 111.3(8) . . ?
O19 Si1 O22 111.1(7) . . ?
O19 Si1 O22 68.9(7) 3 . ?
O22 Si1 O22 180.0(15) 3 . ?
O21 Si1 O20 108.1(7) 3 3 ?
O21 Si1 O20 71.9(7) . 3 ?
O19 Si1 O20 73.1(7) . 3 ?
O19 Si1 O20 106.9(7) 3 3 ?
O22 Si1 O20 107.4(8) 3 3 ?
O22 Si1 O20 72.6(8) . 3 ?
O21 Si1 O20 71.9(7) 3 . ?
O21 Si1 O20 108.1(7) . . ?
O19 Si1 O20 106.9(7) . . ?
O19 Si1 O20 73.1(7) 3 . ?
O22 Si1 O20 72.6(8) 3 . ?
O22 Si1 O20 107.4(8) . . ?
O20 Si1 O20 180.0(2) 3 . ?
O1 W1 O2 100.7(7) . 3 ?
O1 W1 O5 102.2(6) . . ?
O2 W1 O5 91.5(6) 3 . ?
O1 W1 O3 100.2(7) . . ?
O2 W1 O3 88.5(5) 3 . ?
O5 W1 O3 157.1(8) . . ?
O1 W1 O4 100.9(6) . . ?
O2 W1 O4 158.0(7) 3 . ?
O5 W1 O4 88.3(5) . . ?
O3 W1 O4 83.4(7) . . ?
O1 W1 O20 154.1(5) . . ?
O2 W1 O20 62.7(6) 3 . ?
O5 W1 O20 98.1(6) . . ?
O3 W1 O20 61.8(7) . . ?
O4 W1 O20 95.6(6) . . ?
O1 W1 O19 157.7(5) . 3 ?
O2 W1 O19 97.2(7) 3 3 ?
O5 W1 O19 63.9(6) . 3 ?
O3 W1 O19 93.4(8) . 3 ?
O4 W1 O19 63.1(6) . 3 ?
O20 W1 O19 48.0(5) . 3 ?
O6 W2 O9 100.0(7) . . ?
O6 W2 O8 100.4(6) . . ?
O9 W2 O8 89.3(6) . . ?
O6 W2 O7 101.2(7) . . ?
O9 W2 O7 158.7(8) . . ?
O8 W2 O7 89.2(5) . . ?
O6 W2 O5 100.0(6) . . ?
O9 W2 O5 87.9(5) . . ?
O8 W2 O5 159.6(7) . . ?
O7 W2 O5 86.1(6) . . ?
O6 W2 O22 158.9(6) . . ?
O9 W2 O22 96.1(7) . . ?
O8 W2 O22 66.2(6) . . ?
O7 W2 O22 64.0(7) . . ?
O5 W2 O22 94.0(6) . . ?
O6 W2 O19 155.9(6) . 3 ?
O9 W2 O19 62.6(6) . 3 ?
O8 W2 O19 96.0(6) . 3 ?
O7 W2 O19 96.5(7) . 3 ?
O5 W2 O19 64.9(6) . 3 ?
O22 W2 O19 45.1(5) . 3 ?
O11 W3 O10 102.1(6) . . ?
O11 W3 O3 100.5(7) . 3 ?
O10 W3 O3 90.7(7) . 3 ?
O11 W3 O12 100.6(7) . . ?
O10 W3 O12 157.1(8) . . ?
O3 W3 O12 88.8(5) 3 . ?
O11 W3 O8 101.5(6) . . ?
O10 W3 O8 87.7(5) . . ?
O3 W3 O8 157.8(8) 3 . ?
O12 W3 O8 84.2(6) . . ?
O11 W3 O20 153.4(6) . 3 ?
O10 W3 O20 98.7(6) . 3 ?
O3 W3 O20 62.7(6) 3 3 ?
O12 W3 O20 61.0(6) . 3 ?
O8 W3 O20 95.7(6) . 3 ?
O11 W3 O22 158.3(6) . . ?
O10 W3 O22 63.8(6) . . ?
O3 W3 O22 96.2(8) 3 . ?
O12 W3 O22 93.5(8) . . ?
O8 W3 O22 63.3(5) . . ?
O20 W3 O22 48.2(6) 3 . ?
O13 W4 O12 101.3(8) . . ?
O13 W4 O14 102.2(6) . . ?
O12 W4 O14 89.0(6) . . ?
O13 W4 O2 100.4(7) . . ?
O12 W4 O2 88.1(5) . . ?
O14 W4 O2 157.4(8) . . ?
O13 W4 O15 102.8(6) . . ?
O12 W4 O15 155.8(8) . . ?
O14 W4 O15 88.6(5) . . ?
O2 W4 O15 84.9(6) . . ?
O13 W4 O20 154.4(5) . 3 ?
O12 W4 O20 61.5(7) . 3 ?
O14 W4 O20 96.6(6) . 3 ?
O2 W4 O20 62.5(6) . 3 ?
O15 W4 O20 94.9(6) . 3 ?
O13 W4 O21 158.9(5) . . ?
O12 W4 O21 94.2(8) . . ?
O14 W4 O21 63.5(5) . . ?
O2 W4 O21 94.3(7) . . ?
O15 W4 O21 63.3(6) . . ?
O20 W4 O21 46.8(5) 3 . ?
O16 W5 O15 100.4(7) . . ?
O16 W5 O7 102.4(8) . 3 ?
O15 W5 O7 90.0(6) . 3 ?
O16 W5 O18 100.5(8) . . ?
O15 W5 O18 88.7(5) . . ?
O7 W5 O18 157.0(8) 3 . ?
O16 W5 O10 102.2(7) . 3 ?
O15 W5 O10 157.2(7) . 3 ?
O7 W5 O10 88.1(5) 3 3 ?
O18 W5 O10 84.2(6) . 3 ?
O16 W5 O22 159.9(7) . 3 ?
O15 W5 O22 94.4(6) . 3 ?
O7 W5 O22 64.0(7) 3 3 ?
O18 W5 O22 93.2(7) . 3 ?
O10 W5 O22 64.4(6) 3 3 ?
O16 W5 O21 156.2(7) . . ?
O15 W5 O21 65.2(6) . . ?
O7 W5 O21 96.7(7) 3 . ?
O18 W5 O21 62.1(6) . . ?
O10 W5 O21 92.4(6) 3 . ?
O22 W5 O21 43.8(5) 3 . ?
O17 W6 O18 101.5(8) . . ?
O17 W6 O4 101.0(7) . . ?
O18 W6 O4 90.2(6) . . ?
O17 W6 O14 100.1(6) . . ?
O18 W6 O14 89.0(5) . . ?
O4 W6 O14 158.6(7) . . ?
O17 W6 O9 101.6(8) . . ?
O18 W6 O9 156.6(7) . . ?
O4 W6 O9 88.8(5) . . ?
O14 W6 O9 83.6(6) . . ?
O17 W6 O19 158.0(7) . 3 ?
O18 W6 O19 96.2(6) . 3 ?
O4 W6 O19 65.7(6) . 3 ?
O14 W6 O19 93.1(6) . 3 ?
O9 W6 O19 62.3(6) . 3 ?
O17 W6 O21 157.9(7) . . ?
O18 W6 O21 63.6(6) . . ?
O4 W6 O21 95.4(6) . . ?
O14 W6 O21 65.2(5) . . ?
O9 W6 O21 93.2(7) . . ?
O19 W6 O21 43.9(5) 3 . ?
W1 O2 W4 138.3(10) 3 . ?
W3 O3 W1 138.6(10) 3 . ?
W6 O4 W1 136.8(8) . . ?
W1 O5 W2 137.6(9) . . ?
W5 O7 W2 136.4(10) 3 . ?
W2 O8 W3 136.0(8) . . ?
W2 O9 W6 137.8(9) . . ?
W3 O10 W5 137.7(8) . 3 ?
W4 O12 W3 139.5(10) . . ?
W4 O14 W6 137.4(7) . . ?
W5 O15 W4 138.7(8) . . ?
W6 O18 W5 139.2(9) . . ?
Si1 O19 O21 54.6(7) . 3 ?
Si1 O19 W6 123.5(8) . 3 ?
O21 O19 W6 68.9(7) 3 3 ?
Si1 O19 W2 122.5(8) . 3 ?
O21 O19 W2 133.7(9) 3 3 ?
W6 O19 W2 96.7(5) 3 3 ?
Si1 O19 W1 119.3(7) . 3 ?
O21 O19 W1 130.0(9) 3 3 ?
W6 O19 W1 94.1(5) 3 3 ?
W2 O19 W1 93.5(5) 3 3 ?
Si1 O20 W4 120.9(7) . 3 ?
Si1 O20 W3 120.2(8) . 3 ?
W4 O20 W3 97.5(5) 3 3 ?
Si1 O20 W1 119.6(7) . . ?
W4 O20 W1 96.4(6) 3 . ?
W3 O20 W1 96.6(5) 3 . ?
Si1 O21 O19 57.2(7) . 3 ?
Si1 O21 O22 57.0(7) . 3 ?
O19 O21 O22 96.2(10) 3 3 ?
Si1 O21 W6 124.4(9) . . ?
O19 O21 W6 67.2(7) 3 . ?
O22 O21 W6 132.9(9) 3 . ?
Si1 O21 W5 123.7(9) . . ?
O19 O21 W5 136.0(9) 3 . ?
O22 O21 W5 66.7(8) 3 . ?
W6 O21 W5 94.3(5) . . ?
Si1 O21 W4 120.4(8) . . ?
O19 O21 W4 126.7(9) 3 . ?
O22 O21 W4 128.4(10) 3 . ?
W6 O21 W4 93.3(5) . . ?
W5 O21 W4 92.4(6) . . ?
Si1 O22 O21 54.3(7) . 3 ?
Si1 O22 W2 123.5(8) . . ?
O21 O22 W2 136.7(10) 3 . ?
Si1 O22 W5 123.8(8) . 3 ?
O21 O22 W5 69.5(8) 3 3 ?
W2 O22 W5 95.1(6) . 3 ?
Si1 O22 W3 118.9(9) . . ?
O21 O22 W3 126.1(9) 3 . ?
W2 O22 W3 94.1(5) . . ?
W5 O22 W3 93.9(5) 3 . ?

_diffrn_measured_fraction_theta_max 0.997
_diffrn_reflns_theta_full        27.49
_diffrn_measured_fraction_theta_full 0.997
_refine_diff_density_max         2.151
_refine_diff_density_min         -2.076
_refine_diff_density_rms         0.243
_database_code_depnum_ccdc_archive 'CCDC 1011392'
#######################################################################
#
#                 Cambridge Crystallographic Data Centre
#                                CCDC 
# 
#######################################################################
# 
#  This CIF contains data from an original supplementary publication
#  deposited with the CCDC, and may include chemical, crystal,
#  experimental, refinement, atomic coordinates,
#  anisotropic displacement parameters and molecular geometry data,
#  as required by the journal to which it was submitted.
#
#  This CIF is provided on the understanding that it is used for bona
#  fide research purposes only. It may contain copyright material
#  of the CCDC or of third parties, and may not be copied or further
#  disseminated in any form, whether machine-readable or not,
#  except for the purpose of generating routine backup copies
#  on your local computer system.
# 
#  For further information on the CCDC, data deposition and
#  data retrieval see:
#                         www.ccdc.cam.ac.uk
#
#  Bona fide researchers may freely download Mercury and enCIFer
#  from this site to visualise CIF-encoded structures and 
#  to carry out CIF format checking respectively.
#
data_Compound-2

_audit_creation_method           SHELXL-97
_chemical_name_systematic        
; 
 ? 
;
_chemical_name_common            ?
_chemical_melting_point          ?
_chemical_formula_moiety         ?
_chemical_formula_sum            'C72 H48 Ag6 Cl2 N24 O42 Si W12'
_chemical_formula_weight         4873.75

loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   C2/c

loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'

_cell_length_a                   22.6655(5)
_cell_length_b                   18.8656(3)
_cell_length_c                   24.6036(5)
_cell_angle_alpha                90.00
_cell_angle_beta                 107.228(2)
_cell_angle_gamma                90.00
_cell_volume                     10048.4(3)
_cell_formula_units_Z            4
_cell_measurement_temperature    100.00(15)
_cell_measurement_reflns_used    15073
_cell_measurement_theta_min      2.7560
_cell_measurement_theta_max      29.1940

_exptl_crystal_description       prism
_exptl_crystal_colour            'pale green'
_exptl_crystal_size_max          0.2500
_exptl_crystal_size_mid          0.2000
_exptl_crystal_size_min          0.1500
_exptl_crystal_density_meas      ?
_exptl_crystal_density_diffrn    3.222
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             8808
_exptl_absorpt_coefficient_mu    14.972
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_correction_T_min  0.12632
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_process_details   ?

_exptl_special_details           
; 
 ? 
;

_diffrn_ambient_temperature      100.00(15)
_diffrn_radiation_wavelength     0.71073
_diffrn_radiation_type           MoK\a
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_monochromator  graphite
_diffrn_measurement_device_type  mirror
_diffrn_measurement_method       'ω scans'
_diffrn_detector_area_resol_mean 10.3503
_diffrn_standards_number         ?
_diffrn_standards_interval_count ?
_diffrn_standards_interval_time  ?
_diffrn_standards_decay_%        ?
_diffrn_reflns_number            26956
_diffrn_reflns_av_R_equivalents  0.0616
_diffrn_reflns_av_unetI/netI     0.0652
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_theta_min         2.71
_diffrn_reflns_theta_max         26.50
_reflns_number_total             10410
_reflns_number_gt                9095
_reflns_threshold_expression     >2sigma(I)

_computing_data_collection       ?
_computing_cell_refinement       ?
_computing_data_reduction        ?
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_molecular_graphics    ?
_computing_publication_material  ?

_refine_special_details          
; 
 Refinement of F² against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F², conventional R-factors R are based 
 on F, with F set to zero for negative F². The threshold expression of 
 F² > 2sigma(F²) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F² are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;

_refine_ls_structure_factor_coef Fsqd
_refine_ls_matrix_type           full
_refine_ls_weighting_scheme      calc
_refine_ls_weighting_details     
'calc w=1/[σ²(Fo²)+(0.0428P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_atom_sites_solution_hydrogens   geom
_refine_ls_hydrogen_treatment    constr
_refine_ls_extinction_method     none
_refine_ls_extinction_coef       ?
_refine_ls_number_reflns         10410
_refine_ls_number_parameters     716
_refine_ls_number_restraints     138
_refine_ls_R_factor_all          0.0492
_refine_ls_R_factor_gt           0.0417
_refine_ls_wR_factor_ref         0.1053
_refine_ls_wR_factor_gt          0.0992
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_restrained_S_all      1.102
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000

loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.23663(4) -0.40462(5) 0.94711(3) 0.0285(2) Uani 1 1 d . . .
Ag2 Ag 1.06788(4) 0.07225(4) 0.52235(3) 0.02103(19) Uani 1 1 d . . .
Ag3 Ag 0.83410(4) 0.72747(4) 0.48353(3) 0.0288(2) Uani 1 1 d . . .
Cl1 Cl 1.3102(2) -0.32604(18) 1.03140(12) 0.0578(11) Uani 1 1 d U . .
C1 C 1.2301(5) -0.4102(5) 0.8234(4) 0.019(2) Uani 1 1 d . . .
H1A H 1.2346 -0.4578 0.8336 0.022 Uiso 1 1 calc R . .
C2 C 1.2239(4) -0.3921(5) 0.7682(3) 0.0114(19) Uani 1 1 d U . .
H2B H 1.2238 -0.4267 0.7413 0.014 Uiso 1 1 calc R . .
C3 C 1.2176(4) -0.3207(5) 0.7528(4) 0.0127(19) Uani 1 1 d U . .
C4 C 1.2187(4) -0.2707(5) 0.7941(3) 0.0122(19) Uani 1 1 d . . .
H4B H 1.2160 -0.2225 0.7855 0.015 Uiso 1 1 calc R . .
C5 C 1.2240(5) -0.2943(5) 0.8487(4) 0.017(2) Uani 1 1 d . . .
H5B H 1.2232 -0.2608 0.8762 0.020 Uiso 1 1 calc R . .
C6 C 1.1941(5) -0.4424(5) 0.4724(4) 0.017(2) Uani 1 1 d U . .
H6B H 1.1805 -0.4372 0.4330 0.020 Uiso 1 1 calc R . .
C7 C 1.1839(5) -0.3868(5) 0.5059(4) 0.016(2) Uani 1 1 d . . .
H7A H 1.1620 -0.3468 0.4892 0.019 Uiso 1 1 calc R . .
C8 C 1.2069(4) -0.3925(5) 0.5639(3) 0.0106(18) Uani 1 1 d U . .
C9 C 1.2371(4) -0.4540(5) 0.5871(4) 0.014(2) Uani 1 1 d . . .
H9A H 1.2520 -0.4596 0.6264 0.016 Uiso 1 1 calc R . .
C10 C 1.2448(5) -0.5069(5) 0.5513(3) 0.015(2) Uani 1 1 d . . .
H10B H 1.2664 -0.5474 0.5673 0.018 Uiso 1 1 calc R . .
C11 C 1.1386(5) -0.0304(5) 0.6139(4) 0.016(2) Uani 1 1 d U . .
H11B H 1.1336 0.0051 0.6384 0.019 Uiso 1 1 calc R . .
C12 C 1.1617(5) -0.0941(5) 0.6369(4) 0.018(2) Uani 1 1 d . . .
H12B H 1.1725 -0.1013 0.6761 0.022 Uiso 1 1 calc R . .
C13 C 1.1685(4) -0.1476(5) 0.6010(4) 0.0114(19) Uani 1 1 d . . .
C14 C 1.1545(5) -0.1327(5) 0.5425(4) 0.017(2) Uani 1 1 d . . .
H14A H 1.1600 -0.1669 0.5171 0.020 Uiso 1 1 calc R . .
C15 C 1.1325(5) -0.0661(5) 0.5237(4) 0.017(2) Uani 1 1 d . . .
H15A H 1.1240 -0.0556 0.4852 0.020 Uiso 1 1 calc R . .
C16 C 1.2094(4) -0.3012(4) 0.6930(4) 0.0097(19) Uani 1 1 d . . .
C17 C 1.2021(4) -0.3353(5) 0.6036(3) 0.0091(18) Uani 1 1 d U . .
C18 C 1.1862(4) -0.2222(5) 0.6214(3) 0.0105(19) Uani 1 1 d . . .
C19 C 1.0023(5) 0.1562(5) 0.4183(4) 0.019(2) Uani 1 1 d . . .
H19A H 1.0106 0.1157 0.4003 0.023 Uiso 1 1 calc R . .
C20 C 0.9806(5) 0.2148(5) 0.3868(4) 0.019(2) Uani 1 1 d . . .
H20A H 0.9751 0.2144 0.3478 0.023 Uiso 1 1 calc R . .
C21 C 0.9667(5) 0.2743(5) 0.4118(3) 0.0128(19) Uani 1 1 d . . .
C22 C 0.9724(5) 0.2728(5) 0.4699(3) 0.0124(19) Uani 1 1 d . . .
H22A H 0.9610 0.3115 0.4879 0.015 Uiso 1 1 calc R . .
C23 C 0.9955(5) 0.2117(5) 0.4996(4) 0.018(2) Uani 1 1 d . . .
H23A H 0.9996 0.2099 0.5383 0.022 Uiso 1 1 calc R . .
C24 C 0.9203(5) 0.4497(5) 0.1448(4) 0.016(2) Uani 1 1 d U . .
H24A H 0.9224 0.4909 0.1248 0.019 Uiso 1 1 calc R . .
C25 C 0.9232(4) 0.4558(5) 0.2013(4) 0.015(2) Uani 1 1 d . . .
H25A H 0.9253 0.4998 0.2187 0.018 Uiso 1 1 calc R . .
C26 C 0.9227(4) 0.3932(5) 0.2315(3) 0.0096(18) Uani 1 1 d . . .
C27 C 0.9200(4) 0.3303(5) 0.2052(3) 0.0084(17) Uani 1 1 d U . .
H27A H 0.9215 0.2883 0.2253 0.010 Uiso 1 1 calc R . .
C28 C 0.9148(4) 0.3292(5) 0.1475(3) 0.0122(19) Uani 1 1 d . . .
H28A H 0.9114 0.2855 0.1294 0.015 Uiso 1 1 calc R . .
C29 C 0.8980(5) 0.5866(5) 0.4786(4) 0.016(2) Uani 1 1 d . . .
H29A H 0.9109 0.5928 0.5179 0.019 Uiso 1 1 calc R . .
C30 C 0.9166(4) 0.5266(4) 0.4556(3) 0.0100(18) Uani 1 1 d U . .
H30A H 0.9410 0.4927 0.4794 0.012 Uiso 1 1 calc R . .
C31 C 0.8988(4) 0.5170(4) 0.3971(3) 0.0082(18) Uani 1 1 d U . .
C32 C 0.8613(5) 0.5692(5) 0.3633(4) 0.014(2) Uani 1 1 d . . .
H32A H 0.8478 0.5646 0.3239 0.017 Uiso 1 1 calc R . .
C33 C 0.8448(5) 0.6277(5) 0.3896(4) 0.019(2) Uani 1 1 d U . .
H33A H 0.8207 0.6627 0.3670 0.022 Uiso 1 1 calc R . .
C34 C 0.9456(4) 0.3401(4) 0.3779(3) 0.0079(17) Uani 1 1 d . . .
C35 C 0.9252(4) 0.3960(5) 0.2944(3) 0.0083(18) Uani 1 1 d U . .
C36 C 0.9166(4) 0.4539(4) 0.3707(3) 0.0082(18) Uani 1 1 d U . .
N1 N 1.2301(4) -0.3614(4) 0.8638(3) 0.0164(18) Uani 1 1 d . . .
N2 N 1.2225(4) -0.5028(4) 0.4940(3) 0.0163(18) Uani 1 1 d . . .
N3 N 1.1231(4) -0.0160(4) 0.5590(3) 0.0148(17) Uani 1 1 d . . .
N4 N 1.1981(3) -0.2332(4) 0.6775(3) 0.0095(15) Uani 1 1 d U . .
N5 N 1.2112(4) -0.3538(4) 0.6572(3) 0.0120(16) Uani 1 1 d . . .
N6 N 1.1873(3) -0.2700(4) 0.5824(3) 0.0102(16) Uani 1 1 d . . .
N7 N 1.0121(4) 0.1552(4) 0.4752(3) 0.0159(18) Uani 1 1 d . . .
N8 N 0.9146(4) 0.3873(4) 0.1170(3) 0.0163(18) Uani 1 1 d . . .
N9 N 0.8620(4) 0.6359(4) 0.4459(3) 0.0159(17) Uani 1 1 d . . .
N10 N 0.9351(3) 0.3982(4) 0.4045(3) 0.0083(15) Uani 1 1 d . . .
N11 N 0.9396(3) 0.3350(4) 0.3222(3) 0.0092(15) Uani 1 1 d U . .
N12 N 0.9123(3) 0.4565(4) 0.3154(3) 0.0082(15) Uani 1 1 d U . .
Si1 Si 1.0000 0.20030(16) 0.7500 0.0027(6) Uani 1 2 d SU . .
W1 W 1.019472(17) 0.335809(18) 0.852827(13) 0.00760(9) Uani 1 1 d . . .
W2 W 0.903476(17) 0.19467(2) 0.838591(14) 0.01014(10) Uani 1 1 d U . .
W3 W 0.884467(17) 0.070623(19) 0.735875(14) 0.00951(9) Uani 1 1 d . . .
W4 W 0.873086(16) 0.206629(17) 0.625734(13) 0.00596(9) Uani 1 1 d . . .
W5 W 0.989473(17) 0.065566(18) 0.647850(13) 0.00866(9) Uani 1 1 d . . .
W6 W 0.881773(16) 0.329894(19) 0.726732(14) 0.00724(9) Uani 1 1 d . . .
O1 O 1.0492(3) 0.2495(3) 0.7957(2) 0.0107(13) Uani 1 1 d . . .
O2 O 0.9625(3) 0.1503(3) 0.7830(2) 0.0132(14) Uani 1 1 d . . .
O3 O 1.0142(3) 0.3983(3) 0.9011(2) 0.0147(14) Uani 1 1 d . . .
O4 O 0.9671(3) 0.2610(3) 0.8662(2) 0.0171(15) Uani 1 1 d . . .
O5 O 0.9535(3) 0.3572(3) 0.7884(2) 0.0122(14) Uani 1 1 d . . .
O6 O 0.8586(3) 0.2076(3) 0.8823(2) 0.0108(13) Uani 1 1 d . . .
O7 O 0.8556(3) 0.1210(3) 0.7893(2) 0.0139(14) Uani 1 1 d U . .
O8 O 0.8693(3) 0.2585(3) 0.7769(2) 0.0116(13) Uani 1 1 d U . .
O9 O 0.8287(3) 0.0066(3) 0.7156(2) 0.0182(15) Uani 1 1 d . . .
O10 O 0.8570(3) 0.1404(3) 0.6811(2) 0.0127(13) Uani 1 1 d . . .
O11 O 0.9405(3) 0.0426(3) 0.6948(2) 0.0144(14) Uani 1 1 d . . .
O12 O 0.8124(3) 0.1911(4) 0.5669(3) 0.0190(15) Uani 1 1 d . . .
O13 O 0.9129(3) 0.2800(3) 0.5977(2) 0.0121(13) Uani 1 1 d U . .
O14 O 0.9324(3) 0.1396(3) 0.6176(2) 0.0144(14) Uani 1 1 d . . .
O15 O 0.8354(3) 0.2771(3) 0.6626(2) 0.0129(14) Uani 1 1 d . . .
O16 O 0.9676(3) 0.0041(3) 0.5947(2) 0.0160(14) Uani 1 1 d U . .
O17 O 1.0469(3) 0.1191(3) 0.6184(2) 0.0121(13) Uani 1 1 d . . .
O18 O 1.0592(3) 0.0201(3) 0.6987(2) 0.0122(13) Uani 1 1 d . . .
O19 O 0.8281(3) 0.3926(3) 0.7299(2) 0.0148(14) Uani 1 1 d . . .
O20 O 0.9217(3) 0.3790(3) 0.6783(3) 0.0157(14) Uani 1 1 d . . .
OW1 O 1.1503(9) -0.1322(10) 0.8311(7) 0.055(5) Uiso 0.50 1 d P . .
OW2 O 0.9488(10) 0.1314(11) 0.2606(8) 0.057(5) Uiso 0.50 1 d P . .


_geom_special_details            
; 
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;

loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.169(7) . ?
Ag1 N2 2.168(8) 6_546 ?
Ag1 Cl1 2.689(3) . ?
Ag2 N3 2.117(7) . ?
Ag2 N7 2.127(8) . ?
Ag3 N9 2.142(7) . ?
Ag3 Cl1 2.348(3) 8_455 ?
Cl1 Ag3 2.348(3) 8_556 ?
C1 N1 1.355(13) . ?
C1 C2 1.368(12) . ?
C2 C3 1.394(12) . ?
C3 C4 1.382(13) . ?
C3 C16 1.474(12) . ?
C4 C5 1.387(13) . ?
C5 N1 1.315(12) . ?
C6 N2 1.339(12) . ?
C6 C7 1.394(13) . ?
C7 C8 1.373(12) . ?
C8 C9 1.382(12) . ?
C8 C17 1.479(12) . ?
C9 C10 1.376(13) . ?
C10 N2 1.353(11) . ?
C11 N3 1.318(11) . ?
C11 C12 1.365(13) . ?
C12 C13 1.381(13) . ?
C13 C14 1.408(12) . ?
C13 C18 1.507(12) . ?
C14 C15 1.379(12) . ?
C15 N3 1.343(12) . ?
C16 N5 1.336(11) . ?
C16 N4 1.341(11) . ?
C17 N5 1.321(10) . ?
C17 N6 1.341(11) . ?
C18 N6 1.322(11) . ?
C18 N4 1.343(10) . ?
C19 N7 1.351(11) . ?
C19 C20 1.357(13) . ?
C20 C21 1.361(13) . ?
C21 C22 1.396(11) . ?
C21 C34 1.494(12) . ?
C22 C23 1.383(12) . ?
C23 N7 1.330(12) . ?
C24 N8 1.349(12) . ?
C24 C25 1.377(12) . ?
C25 C26 1.396(12) . ?
C26 C27 1.343(12) . ?
C26 C35 1.534(11) . ?
C27 C28 1.389(11) . ?
C28 N8 1.327(11) . ?
C29 N9 1.336(12) . ?
C29 C30 1.388(12) . ?
C30 C31 1.386(11) . ?
C31 C32 1.402(12) . ?
C31 C36 1.468(12) . ?
C32 C33 1.385(13) . ?
C33 N9 1.333(11) . ?
C34 N10 1.333(11) . ?
C34 N11 1.339(10) . ?
C35 N12 1.320(11) . ?
C35 N11 1.329(11) . ?
C36 N10 1.330(10) . ?
C36 N12 1.337(10) . ?
N2 Ag1 2.168(8) 6_545 ?
Si1 O1 1.620(6) . ?
Si1 O1 1.620(6) 2_756 ?
Si1 O2 1.638(7) 2_756 ?
Si1 O2 1.638(7) . ?
W1 O3 1.702(6) . ?
W1 O5 1.874(6) . ?
W1 O20 1.906(7) 2_756 ?
W1 O4 1.934(7) . ?
W1 O13 1.959(6) 2_756 ?
W1 O1 2.375(6) . ?
W2 O6 1.703(6) . ?
W2 O4 1.877(7) . ?
W2 O8 1.912(6) . ?
W2 O17 1.927(6) 2_756 ?
W2 O7 1.949(6) . ?
W2 O2 2.333(6) . ?
W3 O9 1.712(6) . ?
W3 O10 1.855(6) . ?
W3 O7 1.890(6) . ?
W3 O11 1.916(6) . ?
W3 O18 1.978(6) 2_756 ?
W3 O2 2.348(6) . ?
W4 O12 1.701(7) . ?
W4 O13 1.890(6) . ?
W4 O14 1.898(6) . ?
W4 O15 1.945(6) . ?
W4 O10 1.961(6) . ?
W4 O1 2.340(6) 2_756 ?
W5 O16 1.709(6) . ?
W5 O11 1.875(6) . ?
W5 O14 1.901(6) . ?
W5 O18 1.904(6) . ?
W5 O17 1.950(6) . ?
W5 O2 2.353(6) 2_756 ?
W6 O19 1.716(6) . ?
W6 O15 1.898(6) . ?
W6 O8 1.904(6) . ?
W6 O20 1.932(6) . ?
W6 O5 1.935(6) . ?
W6 O1 2.360(6) 2_756 ?
O1 W4 2.340(6) 2_756 ?
O1 W6 2.360(6) 2_756 ?
O2 W5 2.353(6) 2_756 ?
O13 W1 1.959(6) 2_756 ?
O17 W2 1.927(6) 2_756 ?
O18 W3 1.978(6) 2_756 ?
O20 W1 1.906(6) 2_756 ?

loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N2 145.6(3) . 6_546 ?
N1 Ag1 Cl1 112.0(2) . . ?
N2 Ag1 Cl1 100.9(2) 6_546 . ?
N3 Ag2 N7 172.6(3) . . ?
N9 Ag3 Cl1 175.3(2) . 8_455 ?
Ag3 Cl1 Ag1 103.42(11) 8_556 . ?
N1 C1 C2 122.4(9) . . ?
C1 C2 C3 118.9(9) . . ?
C4 C3 C2 118.8(8) . . ?
C4 C3 C16 122.2(8) . . ?
C2 C3 C16 119.0(8) . . ?
C5 C4 C3 118.0(9) . . ?
N1 C5 C4 123.7(9) . . ?
N2 C6 C7 123.3(8) . . ?
C8 C7 C6 118.6(9) . . ?
C7 C8 C9 118.9(8) . . ?
C7 C8 C17 123.4(8) . . ?
C9 C8 C17 117.7(7) . . ?
C10 C9 C8 119.1(8) . . ?
N2 C10 C9 123.1(9) . . ?
N3 C11 C12 124.1(8) . . ?
C11 C12 C13 118.6(8) . . ?
C12 C13 C14 118.3(8) . . ?
C12 C13 C18 122.6(8) . . ?
C14 C13 C18 118.9(8) . . ?
C15 C14 C13 118.3(9) . . ?
N3 C15 C14 122.4(8) . . ?
N5 C16 N4 124.4(8) . . ?
N5 C16 C3 116.9(8) . . ?
N4 C16 C3 118.6(8) . . ?
N5 C17 N6 125.3(8) . . ?
N5 C17 C8 116.5(8) . . ?
N6 C17 C8 118.2(7) . . ?
N6 C18 N4 126.8(8) . . ?
N6 C18 C13 117.1(7) . . ?
N4 C18 C13 116.1(8) . . ?
N7 C19 C20 121.6(9) . . ?
C21 C20 C19 120.4(9) . . ?
C20 C21 C22 118.9(8) . . ?
C20 C21 C34 120.7(8) . . ?
C22 C21 C34 120.4(8) . . ?
C23 C22 C21 117.6(8) . . ?
N7 C23 C22 122.9(9) . . ?
N8 C24 C25 123.6(9) . . ?
C24 C25 C26 117.4(8) . . ?
C27 C26 C25 119.8(7) . . ?
C27 C26 C35 120.0(8) . . ?
C25 C26 C35 120.2(7) . . ?
C26 C27 C28 118.9(8) . . ?
N8 C28 C27 123.4(8) . . ?
N9 C29 C30 121.8(8) . . ?
C31 C30 C29 120.0(8) . . ?
C30 C31 C32 117.6(8) . . ?
C30 C31 C36 122.1(8) . . ?
C32 C31 C36 120.3(7) . . ?
C33 C32 C31 118.8(8) . . ?
N9 C33 C32 122.9(9) . . ?
N10 C34 N11 125.6(7) . . ?
N10 C34 C21 118.8(7) . . ?
N11 C34 C21 115.6(7) . . ?
N12 C35 N11 126.7(7) . . ?
N12 C35 C26 118.5(7) . . ?
N11 C35 C26 114.8(7) . . ?
N10 C36 N12 125.5(8) . . ?
N10 C36 C31 116.2(7) . . ?
N12 C36 C31 118.3(7) . . ?
C5 N1 C1 118.0(8) . . ?
C5 N1 Ag1 126.9(7) . . ?
C1 N1 Ag1 115.0(6) . . ?
C6 N2 C10 116.7(8) . . ?
C6 N2 Ag1 127.1(6) . 6_545 ?
C10 N2 Ag1 116.1(6) . 6_545 ?
C11 N3 C15 118.2(8) . . ?
C11 N3 Ag2 122.9(6) . . ?
C15 N3 Ag2 117.8(6) . . ?
C16 N4 C18 113.8(7) . . ?
C17 N5 C16 115.9(8) . . ?
C18 N6 C17 113.7(7) . . ?
C23 N7 C19 118.3(8) . . ?
C23 N7 Ag2 123.1(6) . . ?
C19 N7 Ag2 117.7(6) . . ?
C28 N8 C24 116.7(7) . . ?
C33 N9 C29 118.9(8) . . ?
C33 N9 Ag3 120.7(6) . . ?
C29 N9 Ag3 120.4(6) . . ?
C36 N10 C34 114.3(7) . . ?
C35 N11 C34 113.5(7) . . ?
C35 N12 C36 114.0(7) . . ?
O1 Si1 O1 110.2(4) . 2_756 ?
O1 Si1 O2 108.8(3) . 2_756 ?
O1 Si1 O2 109.7(3) 2_756 2_756 ?
O1 Si1 O2 109.7(3) . . ?
O1 Si1 O2 108.8(3) 2_756 . ?
O2 Si1 O2 109.6(5) 2_756 . ?
O3 W1 O5 103.7(3) . . ?
O3 W1 O20 100.8(3) . 2_756 ?
O5 W1 O20 92.6(3) . 2_756 ?
O3 W1 O4 102.3(3) . . ?
O5 W1 O4 85.7(3) . . ?
O20 W1 O4 156.6(3) 2_756 . ?
O3 W1 O13 98.2(3) . 2_756 ?
O5 W1 O13 157.5(3) . 2_756 ?
O20 W1 O13 88.1(3) 2_756 2_756 ?
O4 W1 O13 84.8(3) . 2_756 ?
O3 W1 O1 168.1(3) . . ?
O5 W1 O1 86.7(2) . . ?
O20 W1 O1 72.6(2) 2_756 . ?
O4 W1 O1 84.0(3) . . ?
O13 W1 O1 72.0(2) 2_756 . ?
O6 W2 O4 102.4(3) . . ?
O6 W2 O8 103.5(3) . . ?
O4 W2 O8 87.4(3) . . ?
O6 W2 O17 96.9(3) . 2_756 ?
O4 W2 O17 91.9(3) . 2_756 ?
O8 W2 O17 159.3(3) . 2_756 ?
O6 W2 O7 99.7(3) . . ?
O4 W2 O7 157.9(3) . . ?
O8 W2 O7 86.3(2) . . ?
O17 W2 O7 86.6(2) 2_756 . ?
O6 W2 O2 167.2(3) . . ?
O4 W2 O2 86.5(3) . . ?
O8 W2 O2 85.9(2) . . ?
O17 W2 O2 73.4(2) 2_756 . ?
O7 W2 O2 71.9(2) . . ?
O9 W3 O10 103.3(3) . . ?
O9 W3 O7 100.4(3) . . ?
O10 W3 O7 92.1(3) . . ?
O9 W3 O11 101.5(3) . . ?
O10 W3 O11 86.9(3) . . ?
O7 W3 O11 157.7(3) . . ?
O9 W3 O18 98.0(3) . 2_756 ?
O10 W3 O18 158.5(3) . 2_756 ?
O7 W3 O18 87.1(3) . 2_756 ?
O11 W3 O18 85.8(3) . 2_756 ?
O9 W3 O2 168.0(2) . . ?
O10 W3 O2 86.9(2) . . ?
O7 W3 O2 72.5(2) . . ?
O11 W3 O2 85.2(2) . . ?
O18 W3 O2 72.3(2) 2_756 . ?
O12 W4 O13 99.7(3) . . ?
O12 W4 O14 102.4(3) . . ?
O13 W4 O14 91.2(3) . . ?
O12 W4 O15 99.1(3) . . ?
O13 W4 O15 89.6(3) . . ?
O14 W4 O15 158.0(3) . . ?
O12 W4 O10 102.2(3) . . ?
O13 W4 O10 158.0(3) . . ?
O14 W4 O10 86.2(3) . . ?
O15 W4 O10 85.0(3) . . ?
O12 W4 O1 169.6(3) . 2_756 ?
O13 W4 O1 74.0(2) . 2_756 ?
O14 W4 O1 86.2(2) . 2_756 ?
O15 W4 O1 72.9(2) . 2_756 ?
O10 W4 O1 84.0(2) . 2_756 ?
O16 W5 O11 103.0(3) . . ?
O16 W5 O14 100.9(3) . . ?
O11 W5 O14 87.3(3) . . ?
O16 W5 O18 101.2(3) . . ?
O11 W5 O18 91.0(3) . . ?
O14 W5 O18 157.7(3) . . ?
O16 W5 O17 98.1(3) . . ?
O11 W5 O17 158.7(3) . . ?
O14 W5 O17 85.7(3) . . ?
O18 W5 O17 87.9(3) . . ?
O16 W5 O2 169.1(3) . 2_756 ?
O11 W5 O2 86.7(2) . 2_756 ?
O14 W5 O2 84.3(2) . 2_756 ?
O18 W5 O2 73.4(2) . 2_756 ?
O17 W5 O2 72.5(2) . 2_756 ?
O19 W6 O15 100.0(3) . . ?
O19 W6 O8 102.4(3) . . ?
O15 W6 O8 90.9(3) . . ?
O19 W6 O20 99.5(3) . . ?
O15 W6 O20 89.1(3) . . ?
O8 W6 O20 157.7(3) . . ?
O19 W6 O5 102.9(3) . . ?
O15 W6 O5 157.0(3) . . ?
O8 W6 O5 86.1(2) . . ?
O20 W6 O5 85.3(3) . . ?
O19 W6 O1 169.3(2) . 2_756 ?
O15 W6 O1 73.2(2) . 2_756 ?
O8 W6 O1 86.2(2) . 2_756 ?
O20 W6 O1 72.5(2) . 2_756 ?
O5 W6 O1 83.9(2) . 2_756 ?
Si1 O1 W4 124.8(3) . 2_756 ?
Si1 O1 W6 125.0(3) . 2_756 ?
W4 O1 W6 91.5(2) 2_756 2_756 ?
Si1 O1 W1 123.1(3) . . ?
W4 O1 W1 91.40(19) 2_756 . ?
W6 O1 W1 91.2(2) 2_756 . ?
Si1 O2 W2 123.7(3) . . ?
Si1 O2 W3 123.3(3) . . ?
W2 O2 W3 92.3(2) . . ?
Si1 O2 W5 123.5(3) . 2_756 ?
W2 O2 W5 92.5(2) . 2_756 ?
W3 O2 W5 92.4(2) . 2_756 ?
W2 O4 W1 150.4(3) . . ?
W1 O5 W6 151.7(4) . . ?
W3 O7 W2 123.2(3) . . ?
W6 O8 W2 149.0(4) . . ?
W3 O10 W4 149.9(4) . . ?
W5 O11 W3 150.1(4) . . ?
W4 O13 W1 122.5(3) . 2_756 ?
W4 O14 W5 150.4(3) . . ?
W6 O15 W4 122.3(3) . . ?
W2 O17 W5 121.6(3) 2_756 . ?
W5 O18 W3 121.8(3) . 2_756 ?
W1 O20 W6 123.7(3) 2_756 . ?

_diffrn_measured_fraction_theta_max 0.998
_diffrn_reflns_theta_full        26.50
_diffrn_measured_fraction_theta_full 0.998
_refine_diff_density_max         4.118
_refine_diff_density_min         -3.808
_refine_diff_density_rms         0.368
_database_code_depnum_ccdc_archive 'CCDC 1011393'
